§ 141.23 - Inorganic chemical sampling and analytical requirements.  


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  • § 141.23 Inorganic chemical sampling and analytical requirements.

    Community water systems shall conduct monitoring to determine compliance with the maximum contaminant levels specified in § 141.62 in accordance with this section. Non-transient, non-community water systems shall conduct monitoring to determine compliance with the maximum contaminant levels specified in § 141.62 in accordance with this section. Transient, non-community water systems shall conduct monitoring to determine compliance with the nitrate and nitrite maximum contaminant levels in §§ 141.11 and 141.62 (as appropriate) in accordance with this section.

    (a) Monitoring shall be conducted as follows:

    (1) Groundwater systems shall take a minimum of one sample at every entry point to the distribution system which is representative of each well after treatment (hereafter called a sampling point) beginning in the initial compliance period. The system shall take each sample at the same sampling point unless conditions make another sampling point more representative of each source or treatment plant.

    (2) Surface water systems shall take a minimum of one sample at every entry point to the distribution system after any application of treatment or in the distribution system at a point which is representative of each source after treatment (hereafter called a sampling point) beginning in the initial compliance period. The system shall take each sample at the same sampling point unless conditions make another sampling point more representative of each source or treatment plant.

    Note:

    For purposes of this paragraph, surface water systems include systems with a combination of surface and ground sources.

    (3) If a system draws water from more than one source and the sources are combined before distribution, the system must sample at an entry point to the distribution system during periods of normal operating conditions (i.e., when water is representative of all sources being used).

    (4) The State may reduce the total number of samples which must be analyzed by allowing the use of compositing. Composite samples from a maximum of five samples are allowed, provided that the detection limit of the method used for analysis is less than one-fifth of the MCL. Compositing of samples must be done in the laboratory.

    (i) If the concentration in the composite sample is greater than or equal to one-fifth of the MCL of any inorganic chemical, then a follow-up sample must be taken within 14 days at each sampling point included in the composite. These samples must be analyzed for the contaminants which exceeded one-fifth of the MCL in the composite sample. Detection limits for each analytical method and MCLs for each inorganic contaminant are the following:

    Detection Limits for Inorganic Contaminants

    Contaminant MCL (mg/l) Methodology Detection limit (mg/l)
    Antimony0.006Atomic Absorption; Furnace0.003
    Atomic Absorption; Platform0.00085
    ICP-Mass Spectrometry0.0004
    Hydride-Atomic Absorption0.001
    Arsenic0.0106 Atomic Absorption; Furnace0.001
    Atomic Absorption; Platform—Stabilized Temperature0.00057
    Atomic Absorption; Gaseous Hydride0.001
    ICP-Mass Spectrometry0.00148
    Asbestos7 MFL1 Transmission Electron Microscopy0.01 MFL
    Barium2Atomic Absorption; furnace technique0.002
    Atomic Absorption; direct aspiration0.1
    Inductively Coupled Plasma0.002 (0.001)
    Beryllium0.004Atomic Absorption; Furnace0.0002
    Atomic Absorption; Platform0.000025
    Inductively Coupled Plasma2 0.0003
    ICP-Mass Spectrometry0.0003
    Cadmium0.005Atomic Absorption; furnace technique0.0001
    Inductively Coupled Plasma0.001
    Chromium0.1Atomic Absorption; furnace technique0.001
    Inductively Coupled Plasma0.007 (0.001)
    Cyanide0.2Distillation, Spectrophotometric3 0.02
    Distillation, Automated, Spectrophotometric3 0.005
    Distillation, Amenable, Spectrophotometric4 0.02
    Distillation, Selective Electrode3 4 0.05
    UV, Distillation, Spectrophotometric9 0.0005
    Micro Distillation, Flow Injection, Spectrophotometric3 0.0006
    Ligand Exchange with Amperometry4 0.0005
    Mercury0.002Manual Cold Vapor Technique0.0002
    Automated Cold Vapor Technique0.0002
    NickelxlAtomic Absorption; Furnace0.001
    Atomic Absorption; Platform0.00065
    Inductively Coupled Plasma2 0.005
    ICP-Mass Spectrometry0.0005
    Nitrate10 (as N)Manual Cadmium Reduction0.01
    Automated Hydrazine Reduction0.01
    Automated Cadmium Reduction0.05
    Ion Selective Electrode1
    Ion Chromatography0.01
    Capillary Ion Electrophoresis0.076
    Nitrite1 (as N)Spectrophotometric0.01
    Automated Cadmium Reduction0.05
    Manual Cadmium Reduction0.01
    Ion Chromatography0.004
    Capillary Ion Electrophoresis0.103
    Selenium0.05Atomic Absorption; furnace0.002
    Atomic Absorption; gaseous hydride0.002
    Thallium0.002Atomic Absorption; Furnace0.001
    Atomic Absorption; Platform0.00075
    ICP-Mass Spectrometry0.0003

    (ii) If the population served by the system is >3,300 persons, then compositing may only be permitted by the State at sampling points within a single system. In systems serving ≤3,300 persons, the State may permit compositing among different systems provided the 5-sample limit is maintained.

    (iii) If duplicates of the original sample taken from each sampling point used in the composite sample are available, the system may use these instead of resampling. The duplicates must be analyzed and the results reported to the State within 14 days after completing analysis of the composite sample, provided the holding time of the sample is not exceeded.

    (5) The frequency of monitoring for asbestos shall be in accordance with paragraph (b) of this section: the frequency of monitoring for antimony, arsenic, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, selenium and thallium shall be in accordance with paragraph (c) of this section; the frequency of monitoring for nitrate shall be in accordance with paragraph (d) of this section; and the frequency of monitoring for nitrite shall be in accordance with paragraph (e) of this section.

    (b) The frequency of monitoring conducted to determine compliance with the maximum contaminant level for asbestos specified in § 141.62(b) shall be conducted as follows:

    (1) Each community and non-transient, non-community water system is required to monitor for asbestos during the first three-year compliance period of each nine-year compliance cycle beginning in the compliance period starting January 1, 1993.

    (2) If the system believes it is not vulnerable to either asbestos contamination in its source water or due to corrosion of asbestos-cement pipe, or both, it may apply to the State for a waiver of the monitoring requirement in paragraph (b)(1) of this section. If the State grants the waiver, the system is not required to monitor.

    (3) The State may grant a waiver based on a consideration of the following factors:

    (i) Potential asbestos contamination of the water source, and

    (ii) The use of asbestos-cement pipe for finished water distribution and the corrosive nature of the water.

    (4) A waiver remains in effect until the completion of the three-year compliance period. Systems not receiving a waiver must monitor in accordance with the provisions of paragraph (b)(1) of this section.

    (5) A system vulnerable to asbestos contamination due solely to corrosion of asbestos-cement pipe shall take one sample at a tap served by asbestos-cement pipe and under conditions where asbestos contamination is most likely to occur.

    (6) A system vulnerable to asbestos contamination due solely to source water shall monitor in accordance with the provision of paragraph (a) of this section.

    (7) A system vulnerable to asbestos contamination due both to its source water supply and corrosion of asbestos-cement pipe shall take one sample at a tap served by asbestos-cement pipe and under conditions where asbestos contamination is most likely to occur.

    (8) A system which exceeds the maximum contaminant levels as determined in § 141.23(i) of this section shall monitor quarterly beginning in the next quarter after the violation occurred.

    (9) The State may decrease the quarterly monitoring requirement to the frequency specified in paragraph (b)(1) of this section provided the State has determined that the system is reliably and consistently below the maximum contaminant level. In no case can a State make this determination unless a groundwater system takes a minimum of two quarterly samples and a surface (or combined surface/ground) water system takes a minimum of four quarterly samples.

    (10) If monitoring data collected after January 1, 1990 are generally consistent with the requirements of § 141.23(b), then the State may allow systems to use that data to satisfy the monitoring requirement for the initial compliance period beginning January 1, 1993.

    (c) The frequency of monitoring conducted to determine compliance with the maximum contaminant levels in § 141.62 for antimony, arsenic, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, selenium and thallium shall be as follows:

    (1) Groundwater systems shall take one sample at each sampling point during each compliance period. Surface water systems (or combined surface/ground) shall take one sample annually at each sampling point.

    (2) The system may apply to the State for a waiver from the monitoring frequencies specified in paragraph (c)(1) of this section. States may grant a public water system a waiver for monitoring of cyanide, provided that the State determines that the system is not vulnerable due to lack of any industrial source of cyanide.

    (3) A condition of the waiver shall require that a system shall take a minimum of one sample while the waiver is effective. The term during which the waiver is effective shall not exceed one compliance cycle (i.e., nine years).

    (4) The State may grant a waiver provided surface water systems have monitored annually for at least three years and groundwater systems have conducted a minimum of three rounds of monitoring. (At least one sample shall have been taken since January 1, 1990). Both surface and groundwater systems shall demonstrate that all previous analytical results were less than the maximum contaminant level. Systems that use a new water source are not eligible for a waiver until three rounds of monitoring from the new source have been completed.

    (5) In determining the appropriate reduced monitoring frequency, the State shall consider:

    (i) Reported concentrations from all previous monitoring;

    (ii) The degree of variation in reported concentrations; and

    (iii) Other factors which may affect contaminant concentrations such as changes in groundwater pumping rates, changes in the system's configuration, changes in the system's operating procedures, or changes in stream flows or characteristics.

    (6) A decision by the State to grant a waiver shall be made in writing and shall set forth the basis for the determination. The determination may be initiated by the State or upon an application by the public water system. The public water system shall specify the basis for its request. The State shall review and, where appropriate, revise its determination of the appropriate monitoring frequency when the system submits new monitoring data or when other data relevant to the system's appropriate monitoring frequency become available.

    (7) Systems which exceed the maximum contaminant levels as calculated in § 141.23(i) of this section shall monitor quarterly beginning in the next quarter after the violation occurred.

    (8) The State may decrease the quarterly monitoring requirement to the frequencies specified in paragraphs (c)(1) and (c)(2) of this section provided it has determined that the system is reliably and consistently below the maximum contaminant level. In no case can a State make this determination unless a groundwater system takes a minimum of two quarterly samples and a surface water system takes a minimum of four quarterly samples.

    (9) All new systems or systems that use a new source of water that begin operation after January 22, 2004 must demonstrate compliance with the MCL within a period of time specified by the State. The system must also comply with the initial sampling frequencies specified by the State to ensure a system can demonstrate compliance with the MCL. Routine and increased monitoring frequencies shall be conducted in accordance with the requirements in this section.

    (d) All public water systems (community; non-transient, non-community; and transient, non-community systems) shall monitor to determine compliance with the maximum contaminant level for nitrate in § 141.62.

    (1) Community and non-transient, non-community water systems served by groundwater systems shall monitor annually beginning January 1, 1993; systems served by surface water shall monitor quarterly beginning January 1, 1993.

    (2) For community and non-transient, non-community water systems, the repeat monitoring frequency for groundwater systems shall be quarterly for at least one year following any one sample in which the concentration is ≥50 percent of the MCL. The State may allow a groundwater system to reduce the sampling frequency to annually after four consecutive quarterly samples are reliably and consistently less than the MCL.

    (3) For community and non-transient, non-community water systems, the State may allow a surface water system to reduce the sampling frequency to annually if all analytical results from four consecutive quarters are <50 percent of the MCL. A surface water system shall return to quarterly monitoring if any one sample is ≥50 percent of the MCL.

    (4) Each transient non-community water system shall monitor annually beginning January 1, 1993.

    (5) After the initial round of quarterly sampling is completed, each community and non-transient non-community system which is monitoring annually shall take subsequent samples during the quarter(s) which previously resulted in the highest analytical result.

    (e) All public water systems (community; non-transient, non-community; and transient, non-community systems) shall monitor to determine compliance with the maximum contaminant level for nitrite in § 141.62(b).

    (1) All public water systems shall take one sample at each sampling point in the compliance period beginning January 1, 1993 and ending December 31, 1995.

    (2) After the initial sample, systems where an analytical result for nitrite is <50 percent of the MCL shall monitor at the frequency specified by the State.

    (3) For community, non-transient, non-community, and transient non-community water systems, the repeat monitoring frequency for any water system shall be quarterly for at least one year following any one sample in which the concentration is ≥50 percent of the MCL. The State may allow a system to reduce the sampling frequency to annually after determining the system is reliably and consistently less than the MCL.

    (4) Systems which are monitoring annually shall take each subsequent sample during the quarter(s) which previously resulted in the highest analytical result.

    (f) Confirmation samples:

    (1) Where the results of sampling for antimony, arsenic, asbestos, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, selenium or thallium indicate an exceedance of the maximum contaminant level, the State may require that one additional sample be collected as soon as possible after the initial sample was taken (but not to exceed two weeks) at the same sampling point.

    (2) Where nitrate or nitrite sampling results indicate an exceedance of the maximum contaminant level, the system shall take a confirmation sample within 24 hours of the system's receipt of notification of the analytical results of the first sample. Systems unable to comply with the 24-hour sampling requirement must immediately notify persons served by the public water system in accordance with § 141.202 and meet other Tier 1 public notification requirements under subpart Q of this part. Systems exercising this option must take and analyze a confirmation sample within two weeks of notification of the analytical results of the first sample.

    (3) If a State-required confirmation sample is taken for any contaminant, then the results of the initial and confirmation sample shall be averaged. The resulting average shall be used to determine the system's compliance in accordance with paragraph (i) of this section. States have the discretion to delete results of obvious sampling errors.

    (g) The State may require more frequent monitoring than specified in paragraphs (b), (c), (d) and (e) of this section or may require confirmation samples for positive and negative results at its discretion.

    (h) Systems may apply to the State to conduct more frequent monitoring than the minimum monitoring frequencies specified in this section.

    (i) Compliance with § 141.11 or § 141.62(b) (as appropriate) shall be determined based on the analytical result(s) obtained at each sampling point.

    (1) For systems which are conducting monitoring at a frequency greater than annual, compliance with the maximum contaminant levels for antimony, arsenic, asbestos, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, selenium or thallium is determined by a running annual average at any sampling point. If the average at any sampling point is greater than the MCL, then the system is out of compliance. If any one sample would cause the annual average to be exceeded, then the system is out of compliance immediately. Any sample below the method detection limit shall be calculated at zero for the purpose of determining the annual average. If a system fails to collect the required number of samples, compliance (average concentration) will be based on the total number of samples collected.

    (2) For systems which are monitoring annually, or less frequently, the system is out of compliance with the maximum contaminant levels for antimony, arsenic, asbestos, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, selenium or thallium if the level of a contaminant is greater than the MCL. If confirmation samples are required by the State, the determination of compliance will be based on the annual average of the initial MCL exceedance and any State-required confirmation samples. If a system fails to collect the required number of samples, compliance (average concentration) will be based on the total number of samples collected.

    (3) Compliance with the maximum contaminant levels for nitrate and nitrate is determined based on one sample if the levels of these contaminants are below the MCLs. If the levels of nitrate and/or nitrite exceed the MCLs in the initial sample, a confirmation sample is required in accordance with paragraph (f)(2) of this section, and compliance shall be determined based on the average of the initial and confirmation samples.

    (4) Arsenic sampling results will be reported to the nearest 0.001 mg/L.

    (j) Each public water system shall monitor at the time designated by the State during each compliance period.

    (k) Inorganic analysis:

    (1) Analysis for the following contaminants shall be conducted in accordance with the methods in the following table, or the alternative methods listed in appendix A to subpart C of this part, or their equivalent as determined by EPA. Criteria for analyzing arsenic, barium, beryllium, cadmium, calcium, chromium, copper, lead, nickel, selenium, sodium, and thallium with digestion or directly without digestion, and other analytical test procedures are contained in Technical Notes on Drinking Water Methods, EPA–600/R–94–173, October 1994. This document is available from the National Service Center for Environmental Publications (NSCEP), P.O. Box 42419, Cincinnati, OH 45242–0419 or http://www.epa.gov/nscep/.

    Alternative Testing Methods for Contaminants Listed at 40 CFR 141.23(k)(1)

    Contaminant Methodology13 EPA method SM 21st edition1 SM 22nd edition28 SM 23rd edition,49 SM 24th edition66 SM online3 ASTM4 Other
    AlkalinityTitrimetric2320 B2320 B2320 BD1067–06 B, 11 B, 16 B AntimonyHydride—Atomic AbsorptionD 3697–07, –12, –17 Atomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10 Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 ArsenicAtomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10D 2972–08 C, –15 C Hydride Atomic Absorption3114 B3114 B3114 B3114 B–09D 2972–08 B, –15 B Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 BariumInductively Coupled Plasma3120 B3120 B3120 B Atomic Absorption; Direct3111 D3111 D3111 D Atomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10 Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 BerylliumInductively Coupled Plasma3120 B3120 B3120 B Atomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10D 3645–08 B, –15 B Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 CadmiumAtomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10 Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 CalciumEDTA titrimetric3500-Ca B3500-Ca B3500-Ca BD 511–09, –14 A Atomic Absorption; Direct Aspiration3111 B3111 B3111 BD 511–09, –14 B Inductively Coupled Plasma3120 B3120 B3120 B Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 Ion ChromatographyD 6919–09, –17 ChromiumInductively Coupled Plasma3120 B3120 B3120 B Atomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10 Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 CopperAtomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10D 1688–07, –12 C, 17 C Atomic Absorption; Direct Aspiration3111 B3111 B3111 BD 1688–07, –12 A, 17 A Inductively Coupled Plasma3120 B3120 B3120 B Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 ColorimetryHach Method 8026,35 Hach Method 10272.36 ConductivityConductance2510 B2510 B2510 BD 1125–14 A CyanideManual Distillation with MgCl2 followed by:4500–CNC4500–CNC4500–CNC4500–CNC–99D 2036–06 A Spectrophotometric, Amenable4500–CNG4500–CNG4500–CNGD 2036–06 B Spectrophotometric Manual4500–CNE4500–CNE4500–CNED2036–06 A
    ASTM3 SM4 (18th, 19th ed.) SM4 (20th ed.) SM Online22 Other
    1. AlkalinityTitrimetricD1067–92, 02 B2320 B2320 B2320 B–97
    Electrometric titrationI–1030–855
    2. AntimonyInductively Coupled Plasma (ICP)—Mass Spectrometry200.82
    Hydride-Atomic AbsorptionD3697–92, 02
    Atomic Absorption; Platform200.92
    Atomic Absorption; Furnace3113 B3113 B–99
    3. Arsenic14 ICP-Mass Spectrometry200.82
    Atomic Absorption; Platform200.92
    Atomic Absorption; FurnaceD2972–97, 03 C3113 B3113 B–99
    Hydride Atomic AbsorptionD1972–97, 03 B3114 B3114 B–97
    4. AsbestosTransmission Electron Microscopy100.19
    Transmission Electron Microscopy100.210
    5. BariumInductively Coupled Plasma200.72 3120 B3120 B3120 B–99
    ICP-Mass Spectrometry200.82
    Atomic Absorption; Direct3111D3111 D–99
    Atomic Absorption; Furnace3113 B3113 B–99
    6. BerylliumInductively Coupled Plasma200.72 3120 B3120 B3120 B–99
    ICP-Mass Spectrometry200.82
    Atomic Absorption; Platform200.92
    Atomic Absorption; FurnaceD3645–97, 03 B3113 B3113 B–99
    7. CadmiumInductively Coupled Plasma200.72
    ICP-Mass Spectrometry200.82
    Atomic Absorption; Platform200.92
    Atomic Absorption; Furnace3113 B3113 B–99
    8. CalciumEDTA titrimetricD511–93, 03 A3500–Ca D3500–Ca B3500–Ca B–97
    Atomic Absorption; Direct AspirationD511–93, 03 B3111 B3111 B–99
    Inductively Coupled Plasma200.72 3120 B3120 B3120 B–99
    Ion ChromatographyD6919–03
    9. ChromiumInductively Coupled Plasma200.72 3120 B3120 B3120 B–99
    ICP-Mass Spectrometry200.82
    Atomic Absorption; Platform200.92
    Atomic Absorption; Furnace3113 B3113 B–99
    10. CopperAtomic Absorption; FurnaceD1688–95, 02 C3113 B3113 B–99
    Atomic Absorption; Direct AspirationD1688–95, 02 A3111 B3111 B–99
    Inductively Coupled Plasma200.72 3120 B3120 B3120 B–99
    ICP-Mass spectrometry200.82
    Atomic Absorption; Platform200.92
    11. ConductivityConductanceD1125–95 (Reapproved 1999) A2510 B2510 B2510 B–97
    12. CyanideManual Distillation followed byD2036–98 A4500–CN C4500–CN C
    Spectrophotometric, AmenableD2036–98 B4500–CN G4500–CN G4500–CN G–99
    Spectro-photometric ManualD2036–98 A4500–CN E4500–CN E4500–CN E–99I–3300–855
    Spectro-photometric Semi-automated335.46
    Selective Electrode4500–CN F4500–CN F4500–CNF Gas Chromatography/Mass Spectrometry HeadspaceME355.01.7 FluorideIon Chromatography F–99
    UV, Distillation, SpectrophotometricKelada–0117
    Micro Distillation, Flow Injection, SpectrophotometricQuikChem 10–204–00–1–X18
    Ligand Exchange and Amperometry21 D6888–04OIA–1677, DW20
    13. FluorideIon Chromatography300.06, 300.119 D4327–97, 034110 B4110 B4110 BD 4327–11, –17 Manual Distillation; Colorimetric B–00
    Manual Distill.; Color. SPADNS4500–F B, D4500–F B, D4500–F B, D D–97
    Manual ElectrodeD1179–93, 99 B4500–F C4500–F C4500–FCD 1179–04, 10 B, 16 B Automated C–97
    Automated Electrode380–75WE11
    Automated Alizarin4500–F E4500–F E4500–FE Arsenite-Free Colorimetric SPADNSHach SPADNS 2 Method 10225,22 Hach Method 10312.67 E–97129–71W11
    Capillary Ion ElectrophoresisD6508, Rev. 223
    14. LeadAtomic Absorption; FurnaceD3559–96, 03 D3113 B3113 B3113 B3113 B–04, B–10D 3559–08 D, 15 D Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 B–99
    ICP–Mass spectrometry200.82
    Atomic Absorption; Platform200.92
    Differential Pulse Anodic Stripping VoltametryMethod 1001, Rev. 1.1.57 16
    15. MagnesiumAtomic Absorption3111 D511–93, 03 B3111 B3111 BD 511–09, –14 B Inductively Coupled PlasmaB–99
    ICP200.72 3120 B3120 B3120 B B–99
    Complexation Titrimetric Methods3500-Mg B3500-Mg B3500-Mg BD 511–09, –14 A Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 Ion ChromatographyD 6919–09, –17 D511–93, 03 A3500–Mg E3500–Mg B3500–Mg B–97
    Ion ChromatographyD6919–03
    16. MercuryManual, Cold Vapor245.12 D3223–97, 023112 B3112 B3112 B3112 B–09D 3223–12, –17 B–99
    Automated, Cold Vapor245.21
    ICP–Mass Spectrometry200.82
    17. NickelInductively Coupled Plasma200.72 3120 B3120 B3120 B B–99
    ICP–Mass Spectrometry200.82
    Atomic Absorption; Platform200.92
    Atomic Absorption; Direct3111 B3111 B3111 B B–99
    Atomic Absorption; Furnace3113 B3113 B3113 B3113 B–04, B–10 Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 NitrateIon ChromatographyB–99
    18. NitrateIon Chromatography300.06, 300.119 D4327–97, 034110 B4110 B4110 BD 4327–11, –17 B–00B–10118
    Automated Cadmium Reduction353.26 D3867–90 A4500–NO3 F4500–NO3 F4500–NO3F Manual Cadmium Reduction F–00
    Ion Selective Electrode4500–NO3 E D4500–NO3 E D4500–NO3 E Ion Selective Electrode D–006017
    Manual Cadmium ReductionD3867–90 B4500–NO3 D E4500–NO3 D E4500–NO3 D Reduction/ColorimetricSystea Easy (1-Reagent),8 NECi Nitrate-Reductase.40 Colorimetric; DirectHach TNTplusTM 835/836 Method 10206.23 E–00
    Capillary Ion ElectrophoresisD 6508–15 D6508–00.
    19. NitriteIon Chromatography300.06, 300.119 D4327–97, 034110 B4110 B4110 BD 4327–11, –17 B–00B–10118
    Automated Cadmium Reduction353.26 D3867–90 A4500–NO3 F4500–NO3 F4500–NO3F F–00
    Manual Cadmium ReductionD3867–90 B4500–NO3 E4500–NO3 E4500–NO3E E–00
    Spectrophotometric4500–NO2 B4500–NO2 B4500–NO2B Reduction/ColorimetricSystea Easy (1-Reagent),8 NECi Nitrate-Reductase.40 B–00
    Capillary Ion ElectrophoresisD 6508–15 D6508–00
    20. Ortho-phosphateIon Chromatography4110 B4110 B4110 BD 4327–11, –17 Colorimetric, Automated, Ascorbic Acid365.16 4500–P F4500–P F
    Colorimetric, ascorbic acid, single reagentD515–88 A4500–P E4500–P E 4500–P E4500–P E–99 Colorimetric, Automated, Ascorbic Acid4500–P F4500–P F4500–P F4500–P F–99Thermo Fisher Discrete Analyzer.41 Capillary Ion ElectrophoresisD 6508–15 pHElectrometric 48 150.3
    Colorimetric Phosphomolybdate; Automated-segmented flow; Automated DiscreteI–1601–855
    I–2601–905
    I–2598–855
    Ion Chromatography300.06, 300.119 D4327–97, 034110 B4110 B4110 B–00
    Capillary Ion ElectrophoresisD6508–00
    21. pHElectrometric150.1, 150.21 D1293–95, 994500–H+ B4500–H+ B4500–H+ BD 1293–12, –18 B–00
    22. SeleniumHydride-Atomic AbsorptionD3859–98, 03 A3114 B3114 B3114 B3114 B–09D 3859–08 A, –15 A B–97
    ICP–Mass Spectrometry200.82
    Atomic Absorption; Furnace3113 Platform200.92
    Atomic Absorption; FurnaceD3859–98, 03 B3113 B3113 B3113 B–04, B–10D 3859–08 B, –15 B Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 SilicaColorimetricD859–05, 10, 16 Molybdosilicate4500-SiO2 C4500-SiO2 C4500-SiO2 C Heteropoly blue4500-SiO2 D4500-SiO2 D4500-SiO2 D B–99
    23. SilicaColorimetric, Molybdate BlueI–1700–855
    Automated-segmented FlowI–2700–855
    ColorimetricD859–94, 00
    Molybdosilicate4500–Si D4500–SiO2 C4500–SiO2 C–97
    Heteropoly blue4500–Si E4500–SiO2 D4500–SiO2 D–97
    Automated for Molybdate-reactive Silica4500-SiO4500–Si F4500–SiO2 E4500-SiO2 E4500-SiO2 E Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 Inductively Coupled Plasma4500–SiO2 E–97
    Inductively Coupled Plasma200.72 3120 B3120 B3120 B SodiumB–99
    24. SodiumInductively Coupled Plasma200.72
    Atomic Absorption; Direct Aspiration3111 B3111 B–99
    Ion ChromatographyD6919–03
    25. TemperatureThermometric255025502550–00
    26. ThalliumICP–Mass Spectrometry200.82
    Atomic Absorption; Platform200.92
    B Axially viewed inductively coupled plasma-atomic emission spectrometry (AVICP–AES)200.5, Revision 4.22 Ion ChromatographyD 6919–09, –17 TemperatureThermometric2550255025502550–10
    (

    (2) Sample collection for antimony, arsenic, asbestos, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, nitrate, nitrite, selenium, and thallium under this section shall be conducted using the sample preservation, container, and maximum holding time procedures specified in the table below:

    Contaminant Preservative1 Container2 Time3
    AntimonyHNO3 P or G6 months
    ArsenicConc HNO3 to pH <2P or G6 months
    Asbestos4 °CP or G48 hours4
    BariumHNO3 P or G6 months
    BerylliumHNO3 P or G6 months
    CadmiumHNO3 P or G6 months
    ChromiumHNO3 P or G6 months
    Cyanide4 °C, NaOHP or G14 days
    FluorideNoneP or G1 month
    MercuryHNO3 P or G28 days
    NickelHNO3 P or G6 months
    Nitrate4 °CP or G48 hours5
    Nitrate-Nitrite6 H2SO4 P or G28 days
    Nitrite4 °CP or G48 hours
    SeleniumHNO3 P or G6 months
    ThalliumHNO3 P or G6 months

    (3) Analysis under this section shall only be conducted by laboratories that have been certified by EPA or the State. Laboratories may conduct sample analysis under provisional certification until January 1, 1996. To receive certification to conduct analyses for antimony, arsenic, asbestos, barium, beryllium, cadmium, chromium, cyanide, fluoride, mercury, nickel, nitrate, nitrite and selenium and thallium, the laboratory must:

    (i) Analyze Performance Evaluation (PE) samples provided by EPA, the State or by a third party (with the approval of the State or EPA) at least once a year.

    (ii) For each contaminant that has been included in the PE sample and for each method for which the laboratory desires certification achieve quantitative results on the analyses that are within the following acceptance limits:

    Contaminant Acceptance limit
    Antimony±30 at ≥0.006 mg/1
    Arsenic±30 at ≥0.003 mg/L
    Asbestos2 standard deviations based on study statistics.
    Barium±15% at ≥0.15 mg/1
    Beryllium±15% at ≥0.001 mg/1
    Cadmium±20% at ≥0.002 mg/1
    Chromium±15% at ≥0.01 mg/1
    Cyanide±25% at ≥0.1 mg/1
    Fluoride±10% at ≥1 to 10 mg/1
    Mercury±30% at ≥0.0005 mg/1
    Nickel±15% at ≥0.01 mg/1
    Nitrate±10% at ≥0.4 mg/1
    Nitrite±15% at ≥0.4 mg/1
    Selenium±20% at ≥0.01 mg/1
    Thallium±30% at ≥0.002 mg/1

    (l) Analyses for the purpose of determining compliance with § 141.11 shall be conducted using the requirements specified in paragraphs (l) through (q) of this section.

    (1) Analyses for all community water systems utilizing surface water sources shall be completed by June 24, 1978. These analyses shall be repeated at yearly intervals.

    (2) Analyses for all community water systems utilizing only ground water sources shall be completed by June 24, 1979. These analyses shall be repeated at three-year intervals.

    (3) For non-community water systems, whether supplied by surface or ground sources, analyses for nitrate shall be completed by December 24, 1980. These analyses shall be repeated at intervals determined by the State.

    (4) The State has the authority to determine compliance or initiate enforcement action based upon analytical results and other information compiled by their sanctioned representatives and agencies.

    (m) If the result of an analysis made under paragraph (l) of this section indicates that the level of any contaminant listed in § 141.11 exceeds the maximum contaminant level, the supplier of the water shall report to the State within 7 days and initiate three additional analyses at the same sampling point within one month.

    (n) When the average of four analyses made pursuant to paragraph (m) of this section, rounded to the same number of significant figures as the maximum contaminant level for the substance in question, exceeds the maximum contaminant level, the supplier of water shall notify the State pursuant to § 141.31 and give notice to the public pursuant to subpart Q. Monitoring after public notification shall be at a frequency designated by the State and shall continue until the maximum contaminant level has not been exceeded in two successive samples or until a monitoring schedule as a condition to a variance, exemption or enforcement action shall become effective.

    (o) The provisions of paragraphs (m) and (n) of this section notwithstanding, compliance with the maximum contaminant level for nitrate shall be determined on the basis of the mean of two analyses. When a level exceeding the maximum contaminant level for nitrate is found, a second analysis shall be initiated within 24 hours, and if the mean of the two analyses exceeds the maximum contaminant level, the supplier of water shall report his findings to the State pursuant to § 141.31 and shall notify the public pursuant to subpart Q.

    (p) For the initial analyses required by paragraph (l) (1), (2) or (3) of this section, data for surface waters acquired within one year prior to the effective date and data for ground waters acquired within 3 years prior to the effective date of this part may be substituted at the discretion of the State.

    (q) [Reserved]

    [56 FR 3579, Jan. 30, 1991]