§ 1910.1000 - Air contaminants.  


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  • § 1910.1000 Air contaminants.

    An employee's exposure to any substance listed in Tables Z-1, Z-2Z–1, Z–2, or Z-3 Z–3 of this section shall be limited in accordance with the requirements of the following paragraphs of this section.

    (a) Table Z-1 - Z–1

    (1) Substances with limits preceded by “C” - Ceiling “C”—Ceiling Values. An employee's exposure to any substance in Table Z-1Z–1, the exposure limit of which is preceded by a “C”, shall at no time exceed the exposure limit given for that substance. If instantaneous monitoring is not feasible, then the ceiling shall be assessed as a 15-minute time weighted average exposure which shall not be exceeded at any time during the working day.

    (2) Other substances substances—8- 8-hour Time Weighted Averages. An employee's exposure to any substance in Table Z-1Z–1, the exposure limit of which is not preceded by a “C”, shall not exceed the 8-hour Time Weighted Average given for that substance in any 8-hour work shift of a 40-hour work week.

    (b) Table Z-2Z–2. An employee's exposure to any substance listed in Table Z-2 Z–2 shall not exceed the exposure limits specified as follows:

    (1) 8-hour time weighted averages. An employee's exposure to any substance listed in Table Z-2Z–2, in any 8-hour work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average limit given for that substance in Table Z-2Z–2.

    (2) Acceptable ceiling concentrations. An employee's exposure to a substance listed in Table Z-2 Z–2 shall not exceed at any time during an 8-hour shift the acceptable ceiling concentration limit given for the substance in the table, except for a time period, and up to a concentration not exceeding the maximum duration and concentration allowed in the column under “acceptable maximum peak above the acceptable ceiling concentration for an 8-hour shift.”

    (3) Example. During an 8-hour work shift, an employee may be exposed to a concentration of Substance A (with a 10 ppm TWA, 25 ppm ceiling and 50 ppm peak) above 25 ppm (but never above 50 ppm) only for a maximum period of 10 minutes. Such exposure must be compensated by exposures to concentrations less than 10 ppm so that the cumulative exposure for the entire 8-hour work shift does not exceed a weighted average of 10 ppm.

    (c) Table Z-3Z–3. An employee's exposure to any substance listed in Table Z-3Z–3, in any 8-hour work shift of a 40-hour work week, shall not exceed the 8-hour time weighted average limit given for that substance in the table.

    (d) Computation formulae. The computation formula which shall apply to employee exposure to more than one substance for which 8-hour time weighted averages are listed in subpart Z of 29 CFR part 1910 in order to determine whether an employee is exposed over the regulatory limit is as follows:

    (1)

    (i) The cumulative exposure for an 8-hour work shift shall be computed as follows:

    E = (Ca Ta + Cb Tb + . . .Cn Tn) ÷ 8

    Where:

    E is the equivalent exposure for the working shift.

    C is the concentration during any period of time T where the concentration remains constant.

    T is the duration in hours of the exposure at the concentration C.

    The value of E shall not exceed the 8-hour time weighted average specified in subpart Z of 29 CFR part 1910 for the substance involved.

    (ii) To illustrate the formula prescribed in paragraph (d)(1)(i) of this section, assume that Substance A has an 8-hour time weighted average limit of 100 ppm noted in Table Z-1Z–1. Assume that an employee is subject to the following exposure:

    Two hours exposure at 150 ppm

    Two hours exposure at 75 ppm

    Four hours exposure at 50 ppm

    Substituting this information in the formula, we have

    (2 × 150 + 2 × 75 + 4 × 50) ÷ 8 = 81.25 ppm

    Since 81.25 ppm is less than 100 ppm, the 8-hour time weighted average limit, the exposure is acceptable.

    (2)

    (i) In case of a mixture of air contaminants an employer shall compute the equivalent exposure as follows:

    Em = (C1 ÷ L1 + C2 ÷ L2) + . . .(Cn ÷ Ln)

    Where:

    Em is the equivalent exposure for the mixture.

    C is the concentration of a particular contaminant.

    L is the exposure limit for that substance specified in subpart Z of 29 CFR part 1910.

    The value of Em shall not exceed unity (1).

    (ii) To illustrate the formula prescribed in paragraph (d)(2)(i) of this section, consider the following exposures:

    Substance Actual concentration of 8-hour exposure (ppm) 8-hour TWA PEL (ppm)
    B5001,000
    C45200
    D40200

    Substituting in the formula, we have:

    Em = 500 ÷ 1,000 + 45 ÷ 200 + 40 ÷ 200

    Em = 0.500 + 0.225 + 0.200

    Em = 0.925

    Since Em is less than unity (1), the exposure combination is within acceptable limits.

    (e) To achieve compliance with paragraphs (a) through (d) of this section, administrative or engineering controls must first be determined and implemented whenever feasible. When such controls are not feasible to achieve full compliance, protective equipment or any other protective measures shall be used to keep the exposure of employees to air contaminants within the limits prescribed in this section. Any equipment and/or technical measures used for this purpose must be approved for each particular use by a competent industrial hygienist or other technically qualified person. Whenever respirators are used, their use shall comply with 1910.134.

    Table Z-1 - Limits Z–1—Limits for Air Contaminants

    Substance CAS No. (c) ppm (a)1 mg/m3 (b)1 Skin designation
    Acetaldehyde75-07-075–07–0200360
    Acetic acid64-19-764–19–71025
    Acetic anhydride108-24-7108–24–7520
    Acetone67-64-167–64–110002400
    Acetonitrile75-05-875–05–84070
    2-Acetylaminofluorine; see 1910.101453-96-3 53–96–3
    Acetylene dichloride; see 1,2-Dichloroethylene.
    Acetylene tetrabromide79-27-679–27–6114
    Acrolein107-02-8107–02–80.10.25
    Acrylamide79-06-179–06–10.3X
    Acrylonitrile; see 1910.1045107-13-1 Aldrin309-00-2107–13–1
    Aldrin309–00–20.25X
    Allyl alcohol107-18-6107–18–625X
    Allyl chloride107-05-107–05–1113
    Allyl glycidyl ether (AGE)106-92-3106–92–3(C)10(C)45
    Allyl propyl disulfide2179-59-12179–59–1212
    alpha-Alumina1344-28-1 1344–28–1
    Total dust15
    Respirable fraction5
    Aluminum, metal (as Al)7429-90-5 7429–90–5
    Total dust15
    Respirable fraction5
    4-Aminodiphenyl; see 1910.101192-67-1 92–67–1
    2-Aminoethanol; see Ethanolamine.
    2-Aminopyridine504-29-504–29–000.52
    Ammonia7664-41-77664–41–75035
    Ammonium sulfamate7773-06-0 7773–06–0
    Total dust15
    Respirable fraction5
    n-Amyl acetate628-63-7628–63–7100525
    sec-Amyl acetate626-38-0626–38–0125650
    Aniline and homologs62-53-362–53–3519X
    Anisidine (o-, p-isomers)29191-52-429191–52–40.5X
    Antimony and compounds (as Sb)7440-36-7440–36–000.5
    ANTU (alpha Naphthylthiourea)86-88-486–88–40.3
    Arsenic, inorganic compounds (as As); see 1910.10187440-38-2 7440–38–2
    Arsenic, organic compounds (as As)7440-38-27440–38–20.5
    Arsine7784-42-17784–42–10.050.2
    Asbestos; see 1910.1001(4)
    Azinphos-methyl86-50-86–50–000.2X
    Barium, soluble compounds (as Ba)7440-39-37440–39–30.5
    Barium sulfate7727-43-7 7727–43–7
    Total dust15
    Respirable fraction5
    Benomyl17804-35-2 17804–35–2
    Total dust15
    Respirable fraction5
    Benzene; see 1910.102871-43-2 71–43–2
    See Table Z-2 Z–2 for the limits applicable in the operations or sectors excluded in 1910.1028d
    Benzidine; see 1910.101092-87-5 92–87–5
    p-Benzoquinone; see Quinone.
    Benzo(a)pyrene; see Coal tar pitch volatiles.
    Benzoyl peroxide94-36-094–36–05
    Benzyl chloride100-44-7100–44–715
    Beryllium and beryllium compounds (as Be)7440-41-7(2) ; see 1926.11248 7440–41–7
    Biphenyl; see Diphenyl.
    Bismuth telluride, Undoped1304-82-1 1304–82–1
    Total dust15
    Respirable fraction5
    Boron oxide1303-86-2 1303–86–2
    Total dust15
    Boron trifluoride7637-07-27637–07–2(C)1(C)3
    Bromine7726-95-67726–95–60.10.7
    Bromoform75-25-275–25–20.55X
    Butadiene (1,3-Butadiene); See 29 CFR 1910.1051; 29 CFR 1910.19(l)106-99-0106–99–01 ppm/5 ppm STEL
    Butanethiol; see Butyl mercaptan.
    2-Butanone (Methyl ethyl ketone)78-93-378–93–3200590
    2-Butoxyethanol111-76-2111–76–250240X
    n-Butyl-acetate123-86-4123–86–4150710
    sec-Butyl acetate105-46-4105–46–4200950
    tert-Butyl acetate540-88-5540–88–5200950
    n-Butyl alcohol71-36-371–36–3100300
    sec-Butyl alcohol78-92-278–92–2150450
    tert-Butyl alcohol75-65-075–65–0100300
    Butylamine109-73-9109–73–9(C)5(C)15X
    tert-Butyl chromate (as CrO3); see 1910.102661189-85-1 1189–85–1
    n-Butyl glycidyl ether (BGE)2426-08-62426–08–650270
    Butyl mercaptan109-79-5109–79–51035
    p-tert-Butyltoluene98-51-198–51–11060
    Cadmium (as Cd); see 1910.10277440-43-9 7440–43–9
    Calcium carbonate1317-65-3 1317–65–3
    Total dust15
    Respirable fraction5
    Calcium hydroxide1305-62-0 1305–62–0
    Total dust15
    Respirable fraction5
    Calcium oxide1305-78-81305–78–85
    Calcium silicate1344-95-2 1344–95–2
    Total dust15
    Respirable fraction5
    Calcium sulfate7778-18-9 7778–18–9
    Total dust15
    Respirable fraction5
    Camphor, synthetic76-22-76–22–22 2
    Carbaryl (Sevin)63-25-263–25–25
    Carbon black1333-86-41333–86–43.5
    Carbon dioxide124-38-9124–38–950009000
    Carbon disulfide75-15-075–15–0(2)
    Carbon monoxide630-08-0630–08–05055
    Carbon tetrachloride56-23-556–23–5(2)
    Cellulose9004-34-6 9004–34–6
    Total dust15
    Respirable fraction5
    Chlordane57-74-957–74–90.5X
    Chlorinated camphene8001-35-28001–35–20.5X
    Chlorinated diphenyl oxide55720-99-555720–99–50.5
    Chlorine7782-50-57782–50–5(C)1(C)3
    Chlorine dioxide10049-04-410049–04–40.10.3
    Chlorine trifluoride7790-91-27790–91–2(C)0.1(C)0.4
    Chloroacetaldehyde107-20-0107–20–0(C)1(C)3
    a-Chloroacetophenone (Phenacyl chloride)532-27-4532–27–40.050.3
    Chlorobenzene108-90-7108–90–775350
    o-Chlorobenzylidene malononitrile2698-41-12698–41–10.050.4
    Chlorobromomethane74-97-574–97–52001050
    2-Chloro-1,3-butadiene; see beta-Chloroprene.
    Chlorodiphenyl (42% Chlorine) (PCB)53469-21-953469–21–91X
    Chlorodiphenyl (54% Chlorine) (PCB)11097-69-111097–69–10.5X
    1-Chloro-2,3-epoxypropane; see Epichlorohydrin.
    2-Chloroethanol; see Ethylene chlorohydrin.
    Chloroethylene; see Vinyl chloride.
    Chloroform (Trichloromethane)67-66-367–66–3(C)50(C)240
    bis(Chloromethyl) ether; see 1910.1008542-88-1 542–88–1
    Chloromethyl methyl ether; see 1910.1006107-30-2 107–30–2
    1-Chloro-1-nitropropane600-25-9600–25–920100
    Chloropicrin76-06-276–06–20.10.7
    beta-Chloroprene126-99-8126–99–82590X
    2-Chloro-6-(trichloromethyl) pyridine1929-82-4 1929–82–4
    Total dust15
    Respirable fraction5
    Chromium (II) compounds.
    (as Cr)7440-47-37440–47–30.5
    Chromium (III) compounds.
    (as Cr)7440-47-37440–47–30.5
    Chromium (VI) compounds; See 1910.10265
    Chromium metal and insol. salts (as Cr)7440-47-37440–47–31
    Chrysene; see Coal tar pitch volatiles.
    Clopidol2971-90-6 2971–90–6
    Total dust15
    Respirable fraction5
    Coal dust (less than 5% SiO2), respirable fraction(3)
    Coal dust (greater than or equal to 5% SiO2), respirable fraction(3)
    Coal tar pitch volatiles (benzene soluble fraction), anthracene, BaP, phenanthrene, acridine, chrysene, pyrene65966-93-265966–93–20.2
    Cobalt metal, dust, and fume (as Co)7440-48-47440–48–40.1
    Coke oven emissions; see 1910.1029.
    Copper7440-50-8 7440–50–8
    Fume (as Cu)0.1
    Dusts and mists (as Cu)1
    Cotton duste; see 1910.10431
    Crag herbicide (Sesone)136-78-7 136–78–7
    Total dust15
    Respirable fraction5
    Cresol, all isomers1319-77-31319–77–3522X
    Crotonaldehyde123-73-9; 4170-30-3123–73–9;
    4170–30–3
    26
    Cumene98-82-898–82–850245X
    Cyanides (as CN)(4)5X
    Cyclohexane110-82-7110–82–73001050
    Cyclohexanol108-93-0108–93–050200
    Cyclohexanone108-94-1108–94–150200
    Cyclohexene110-83-8110–83–83001015
    Cyclopentadiene542-92-7542–92–775200
    2,4-D (Dichlorophenoxyacetic acid)94-75-794–75–710
    Decaborane17702-41-917702–41–90.050.3X
    Demeton (Systox)8065-48-38065–48–30.1X
    Diacetone alcohol (4-Hydroxy-4-methyl-2-pentanone)123-42-2123–42–250240
    1,2-Diaminoethane; see Ethylenediamine.
    Diazomethane334-88-3334–88–30.20.4
    Diborane19287-45-719287–45–70.10.1
    1,2-Dibromo-3-chloropropane (DBCP); see 1910.104496-12-8 96–12–8
    1,2-Dibromoethane; see Ethylene dibromide.
    Dibutyl phosphate107-66-4107–66–415
    Dibutyl phthalate84-74-284–74–25
    o-Dichlorobenzene95-50-195–50–1(C)50(C)300
    p-Dichlorobenzene106-46-7106–46–775450
    3,′-Dichlorobenzidine; see 1910.100791-94-1 Dichlorodifluoromethane75-71-891–94–1
    Dichlorodifluoromethane75–71–810004950
    1,3-Dichloro-5,5-dimethyl hydantoin118-52-5118–52–50.2
    Dichlorodiphenyltrichloroethane (DDT)50-29-350–29–31X
    1,1-Dichloroethane75-34-375–34–3100400
    1,2-Dichloroethane; see Ethylene dichloride.
    1,2-Dichloroethylene540-59-0540–59–0200790
    Dichloroethyl ether111-44-4111–44–4(C)15(C)90X
    Dichloromethane; see Methylene chloride.
    Dichloromonofluoromethane75-43-475–43–410004200
    1,1-Dichloro-1-nitroethane594-72-9594–72–9(C)10(C)60
    1,2-Dichloropropane; see Propylene dichloride.
    Dichlorotetrafluoroethane76-14-276–14–210007000
    Dichlorvos (DDVP)62-73-762–73–71X
    Dicyclopentadienyl iron102-54-5 102–54–5
    Total dust15
    Respirable fraction5
    Dieldrin60-57-160–57–10.25X
    Diethylamine109-89-7109–89–72575
    2-Diethylaminoethanol100-37-8100–37–81050X
    Diethyl ether; see Ethyl ether.
    Difluorodibromomethane75-61-675–61–6100860
    Diglycidyl ether (DGE)2238-07-52238–07–5(C)0.5(C)2.8
    Dihydroxybenzene; see Hydroquinone.
    Diisobutyl ketone108-83-8108–83–850290
    Diisopropylamine108-18-9108–18–9520X
    4-Dimethylaminoazobenzene; see 1910.101560-11-7 60–11–7
    Dimethoxymethane; see Methylal.
    Dimethyl acetamide127-19-5127–19–51035X
    Dimethylamine124-40-3124–40–31018
    Dimethylaminobenzene; see Xylidine
    Dimethylaniline (N,N-Dimethylaniline)121-69-7121–69–7525X
    Dimethylbenzene; see Xylene.
    Dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate300-76-5300–76–53
    Dimethylformamide68-12-268–12–21030X
    2,6-Dimethyl-4-heptanone; see Diisobutyl ketone.
    1,1-Dimethylhydrazine57-14-757–14–70.51X
    Dimethylphthalate131-11-3131–11–35
    Dimethyl sulfate77-78-77–78–1115X
    Dinitrobenzene (all isomers)1X
    (ortho)528-29-0 528–29–0
    (meta)99-65-0 99–65–0
    (para)100-25-4 100–25–4
    Dinitro-o-cresol534-52-1534–52–10.2X
    Dinitrotoluene25321-14-625321–14–61.5X
    Dioxane (Diethylene dioxide)123-91-1123–91–1100360X
    Diphenyl (Biphenyl)92-52-492–52–40.21
    Diphenylmethane diisocyanate; see Methylene bisphenyl isocyanate.
    Dipropylene glycol methyl ether34590-94-834590–94–8100600X
    Di-sec octyl phthalate (Di-(2-ethylhexyl) phthalate)117-81-7117–81–75
    Emery12415-34-8 12415–34–8
    Total dust15
    Respirable fraction5
    Endrin72-20-872–20–80.1X
    Epichlorohydrin106-89-8106–89–8519X
    EPN2104-64-52104–64–50.5X
    1,2-Epoxypropane; see Propylene oxide.
    2,3-Epoxy-1-propanol; see Glycidol.
    Ethanethiol; see Ethyl mercaptan.
    Ethanolamine141-43-5141–43–536
    2-Ethoxyethanol (Cellosolve)110-80-5110–80–5200740X
    2-Ethoxyethyl acetate (Cellosolve acetate)111-15-9111–15–9100540X
    Ethyl acetate141-78-6141–78–64001400
    Ethyl acrylate140-88-5140–88–525100X
    Ethyl alcohol (Ethanol)64-17-564–17–510001900
    Ethylamine75-04-775–04–71018
    Ethyl amyl ketone (5-Methyl-3-heptanone)541-85-5541–85–525130
    Ethyl benzene100–41–4100-41-4100435
    Ethyl bromide74-96-474–96–4200890
    Ethyl butyl ketone (3-Heptanone)106-35-4106–35–450230
    Ethyl chloride75-00-375–00–310002600
    Ethyl ether60-29-760–29–74001200
    Ethyl formate109-94-4109–94–4100300
    Ethyl mercaptan75-08-175–08–1(C)10(C)25
    Ethyl silicate78-10-478–10–4100850
    Ethylene chlorohydrin107-07-3107–07–3516X
    Ethylenediamine107-15-3107–15–31025
    Ethylene dibromide106-93-4106–93–4(2)
    Ethylene dichloride (1,2-Dichloroethane)107-06-2107–06–2(2)
    Ethylene glycol dinitrate628-96-6628–96–6(C)0.2(C)1X
    Ethylene glycol methyl acetate; see Methyl cellosolve acetate.
    Ethyleneimine; see 1910.1012151-56-4 151–56–4
    Ethylene oxide; see 1910.104775-21-8 75–21–8
    Ethylidene chloride; see 1,1-Dichloroethane.
    N-Ethylmorpholine100-74-3100–74–32094X
    Ferbam14484-64-1 14484–64–1
    Total dust15
    Ferrovanadium dust12604-58-912604–58–91
    Fluorides (as F)(4)2.5
    Fluorine7782-41-47782–41–40.10.2
    Fluorotrichloromethane (Trichlorofluoromethane)75-69-475–69–410005600
    Formaldehyde; see 1910.104850-00-0 50–00–0
    Formic acid64-18-664–18–659
    Furfural98-01-198–01–1520X
    Furfuryl alcohol98-00-098–00–050200
    Grain dust (oat, wheat, barley)10
    Glycerin (mist)56-81-5 56–81–5
    Total dust15
    Respirable fraction5
    Glycidol556-52-5556–52–550150
    Glycol monoethyl ether; see 2-Ethoxyethanol.
    Graphite, natural, respirable dust7782-42-57782–42–5(3)
    Graphite, synthetic
    Total dust15
    Respirable fraction5
    Guthion; see Azinphos methyl.
    Gypsum13397-24-5 13397–24–5
    Total dust15
    Respirable fraction5
    Hafnium7440-58-67440–58–60.5
    Heptachlor76-44-876–44–80.5X
    Heptane (n-Heptane)142-82-5142–82–55002000
    Hexachloroethane67-72-67–72–11110X
    Hexachloronaphthalene1335-87-11335–87–10.2X
    n-Hexane110-54-3110–54–35001800
    2-Hexanone (Methyl n-butyl ketone)591-78-6591–78–6100410
    Hexone (Methyl isobutyl ketone)108-10-1108–10–1100410
    sec-Hexyl acetate108-84-9108–84–950300
    Hydrazine302-01-2302–01–211.3X
    Hydrogen bromide10035-10-610035–10–6310
    Hydrogen chloride7647-01-07647–01–0(C)5(C)7
    Hydrogen cyanide74-90-874–90–81011X
    Hydrogen fluoride (as F)7664-39-37664–39–3(2)
    Hydrogen peroxide7722-84-7722–84–1111.4
    Hydrogen selenide (as Se)7783-07-57783–07–50.050.2
    Hydrogen sulfide7783-06-47783–06–4(2)
    Hydroquinone123-31-9123–31–92
    Iodine7553-56-27553–56–2(C)0.1(C)1
    Iron oxide fume1309-37-11309–37–110
    Isoamyl acetate123-92-2123–92–2100525
    Isoamyl alcohol (primary and secondary)123-51-3123–51–3100360
    Isobutyl acetate110-19-0110–19–0150700
    Isobutyl alcohol78-83-178–83–1100300
    Isophorone78-59-178–59–125140
    Isopropyl acetate108-21-4108–21–4250950
    Isopropyl alcohol67-63-067–63–0400980
    Isopropylamine75-31-075–31–0512
    Isopropyl ether108-20-3108–20–35002100
    Isopropyl glycidyl ether (IGE)4016-14-24016–14–250240
    Kaolin1332-58-7 1332–58–7
    Total dust15
    Respirable fraction5
    Ketene463-51-4463–51–40.50.9
    Lead, inorganic (as Pb); see 1910.10257439-92-1 Limestone1317-65-3 7439–92–1
    Limestone1317–65–3
    Total dust15
    Respirable fraction5
    Lindane58-89-958–89–90.5X
    Lithium hydride7580-67-87580–67–80.025
    L.P.G. (Liquefied petroleum gas)68476-85-768476–85–710001800
    Magnesite546-93-0 546–93–0
    Total dust15
    Respirable fraction5
    Magnesium oxide fume1309-48-4 1309–48–4
    Total particulate15
    Malathion121-75-5 121–75–5
    Total dust15X
    Maleic anhydride108-31-6108–31–60.251
    Manganese compounds (as Mn)7439-96-57439–96–5(C)5
    Manganese fume (as Mn)7439-96-57439–96–5(C)5
    Marble1317-65-3 1317–65–3
    Total dust15
    Respirable fraction5
    Mercury (aryl and inorganic) (as Hg)7439-97-67439–97–6(2)
    Mercury (organo) alkyl compounds (as Hg)7439-97-67439–97–6(2)
    Mercury (vapor) (as Hg)7439-97-67439–97–6(2)
    Mesityl oxide141-79-7141–79–725100
    Methanethiol; see Methyl mercaptan.
    Methoxychlor72-43-5 72–43–5
    Total dust15
    2-Methoxyethanol (Methyl cellosolve)109-86-4109–86–42580X
    2-Methoxyethyl acetate (Methyl cellosolve acetate)110-49-6110–49–625120X
    Methyl acetate79-20-979–20–9200610
    Methyl acetylene (Propyne)74-99-774–99–710001650
    Methyl acetylene-propadiene mixture (MAPP)10001800
    Methyl acrylate96-33-396–33–31035X
    Methylal (Dimethoxy-methane)109-87-5109–87–510003100
    Methyl alcohol67-56-167–56–1200260
    Methylamine74-89-574–89–51012
    Methyl amyl alcohol; see Methyl isobutyl carbinol.
    Methyl n-amyl ketone110-43-0110–43–0100465
    Methyl bromide74-83-974–83–9(C)20(C)80X
    Methyl butyl ketone; see 2-Hexanone.
    Methyl cellosolve; see 2-Methoxyethanol.
    Methyl cellosolve acetate; see 2-Methoxyethyl acetate.
    Methyl chloride74-87-374–87–3(2)
    Methyl chloroform (1,1,1-Trichloroethane)71-55-671–55–63501900
    Methylcyclohexane108-87-2108–87–25002000
    Methylcyclohexanol25639-42-325639–42–3100470
    o-Methylcyclohexanone583-60-8583–60–8100460X
    Methylene chloride75-09-275–09–2(2)
    Methyl ethyl ketone (MEK); see 2-Butanone.
    Methyl formate107-31-3107–31–3100250
    Methyl hydrazine (Monomethyl hydrazine)60-34-460–34–4(C)0.2(C)0.35X
    Methyl iodide74-88-474–88–4528X
    Methyl isoamyl ketone110-12-3110–12–3100475
    Methyl isobutyl carbinol108-11-2108–11–225100X
    Methyl isobutyl ketone; see Hexone.
    Methyl isocyanate624-83-9624–83–90.020.05X
    Methyl mercaptan74-93-174–93–1(C)10(C)20
    Methyl methacrylate80-62-680–62–6100410
    Methyl propyl ketone; see 2-Pentanone.
    alpha-Methyl styrene98-83-998–83–9(C)100(C)480
    Methylene bisphenyl isocyanate (MDI)101-68-8101–68–8(C)0.02(C)0.2
    Mica; see Silicates.
    Molybdenum (as Mo)7439-98-7 7439–98–7
    Soluble compounds5
    Insoluble compounds.
    Total dust15
    Monomethyl aniline100-61-8100–61–829X
    Monomethyl hydrazine; see Methyl hydrazine.
    Morpholine110-91-8110–91–82070X
    Naphtha (Coal tar)8030-30-68030–30–6100400
    Naphthalene91-20-391–20–31050
    alpha-Naphthylamine; see 1910.1004134-32-7 134–32–7
    beta-Naphthylamine; see 1910.100991-59-8 91–59–8
    Nickel carbonyl (as Ni)13463-39-313463–39–30.0010.007
    Nickel, metal and insoluble compounds (as Ni)7440-02-07440–02–01
    Nickel, soluble compounds (as Ni)7440-02-07440–02–01
    Nicotine54-11-554–11–50.5X
    Nitric acid7697-37-7697–37–2225
    Nitric oxide10102-43-910102–43–92530
    p-Nitroaniline100-01-6100–01–616X
    Nitrobenzene98-95-398–95–315X
    p-Nitrochlorobenzene100-00-5100–00–51X
    4-Nitrodiphenyl; see 1910.100392-93-3 Nitroethane79-24-392–93–3
    Nitroethane79–24–3100310
    Nitrogen dioxide10102-44-010102–44–0(C)5(C)9
    Nitrogen trifluoride7783-54-27783–54–21029
    Nitroglycerin55-63-055–63–0(C)0.2(C)2X
    Nitromethane75-52-575–52–5100250
    1-Nitropropane108-03-2108–03–22590
    2-Nitropropane79-46-979–46–92590
    N-Nitrosodimethylamine; see 1910.1016.
    Nitrotoluene (all isomers)530X
    o-isomer88-72-2 88–72–2
    m-isomer99-08-1 99–08–1
    p-isomer99-99-0 99–99–0
    Nitrotrichloromethane; see Chloropicrin.
    Octachloronaphthalene2234-13-12234–13–10.1X
    Octane111-65-9111–65–95002350
    Oil mist, mineral8012-95-18012–95–15
    Osmium tetroxide (as Os)20816-12-20816–12–000.002
    Oxalic acid144-62-7144–62–71
    Oxygen difluoride7783-41-77783–41–70.050.1
    Ozone10028-15-610028–15–60.10.2
    Paraquat, respirable dust4685-14-7; 1910-42-5; 2074-50-24685–14–7;
    1910–42–5;
    2074–50–2
    0.5X
    Parathion56-38-256–38–20.1X
    Particulates not otherwise regulated (PNOR)f.
    Total dust15
    Respirable fraction5
    PCB; see Chlorodiphenyl (42% and 54% chlorine).
    Pentaborane19624-22-719624–22–70.0050.01
    Pentachloronaphthalene1321-64-81321–64–80.5X
    Pentachlorophenol87-86-587–86–50.5X
    Pentaerythritol115-77-5 115–77–5
    Total dust15
    Respirable fraction5
    Pentane109-66-0109–66–010002950
    2-Pentanone (Methyl propyl ketone)107-87-9107–87–9200700
    Perchloroethylene (Tetrachloroethylene)127-18-4127–18–4(2)
    Perchloromethyl mercaptan594-42-3594–42–30.10.8
    Perchloryl fluoride7616-94-67616–94–6313.5
    Petroleum distillates (Naphtha) (Rubber Solvent)5002000
    Phenol108-95-2108–95–2519X
    p-Phenylene diamine106-50-3106–50–30.1X
    Phenyl ether, vapor101-84-8101–84–817
    Phenyl ether-biphenyl mixture, vapor17
    Phenylethylene; see Styrene.
    Phenyl glycidyl ether (PGE)122-60-1122–60–11060
    Phenylhydrazine100-63-0100–63–0522X
    Phosdrin (Mevinphos)7786-34-77786–34–70.1X
    Phosgene (Carbonyl chloride)75-44-575–44–50.10.4
    Phosphine7803-51-27803–51–20.30.4
    Phosphoric acid7664-38-27664–38–21
    Phosphorus (yellow)7723-14-7723–14–000.1
    Phosphorus pentachloride10026-13-810026–13–81
    Phosphorus pentasulfide1314-80-31314–80–31
    Phosphorus trichloride7719-12-27719–12–20.53
    Phthalic anhydride85-44-985–44–9212
    Picloram1918-02-1 1918–02–1
    Total dust15
    Respirable fraction5
    Picric acid88-89-188–89–10.1X
    Pindone (2-Pivalyl-1,3-indandione)83-26-183–26–10.1
    Plaster of Paris26499-65-0 26499–65–0
    Total dust15
    Respirable fraction5
    Platinum (as Pt)7440-06-4 7440–06–4
    Metal
    Soluble salts0.002
    Portland cement65997-15-1 65997–15–1
    Total dust15
    Respirable fraction5
    Propane74-98-674–98–610001800
    beta-Propriolactone; see 1910.101357-57-8 57–57–8
    n-Propyl acetate109-60-4109–60–4200840
    n-Propyl alcohol71-23-871–23–8200500
    n-Propyl nitrate627-13-4627–13–425110
    Propylene dichloride78-87-578–87–575350
    Propylene imine75-55-875–55–825X
    Propylene oxide75-56-975–56–9100240
    Propyne; see Methyl acetylene.
    Pyrethrum8003-34-78003–34–75
    Pyridine110-86-1110–86–1515
    Quinone106-51-4106–51–40.10.4
    RDX; see Cyclonite.
    Rhodium (as Rh), metal fume and insoluble compounds7440-16-67440–16–60.1
    Rhodium (as Rh), soluble compounds7440-16-67440–16–60.001
    Ronnel299-84-3299–84–315
    Rotenone83-79-483–79–45
    Rouge
    Total dust15
    Respirable fraction5
    Selenium compounds (as Se)7782-49-27782–49–20.2
    Selenium hexafluoride (as Se)7783-79-17783–79–10.050.4
    Silica, amorphous, precipitated and gel112926-00-8112926–00–8(3)
    Silica, amorphous, diatomaceous earth, containing less than 1% crystalline silica61790-53-261790–53–2(3)
    Silica, crystalline, respirable dust
    Cristobalite; see 1910.1053714464-46-1 14464–46–1
    Quartz; see 1910.1053714808-60-7 14808–60–7
    Tripoli (as quartz); see 1910.105371317-95-9 1317–95–9
    Tridymite; see 1910.1053715468-32-3 15468–32–3
    Silica, fused, respirable dust60676-86-060676–86–0(3)
    Silicates (less than 1% crystalline silica)
    Mica (respirable dust)12001-26-212001–26–2(3)
    Soapstone, total dust(3)
    Soapstone, respirable dust(3)
    Talc (containing asbestos); use asbestos limit; see 29 CFR 1910.1001(3)
    Talc (containing no asbestos), respirable dust14807-96-614807–96–6(3)
    Tremolite, asbestiform; see 1910.1001.
    Silicon7440-21-3 7440–21–3
    Total dust15
    Respirable fraction5
    Silicon carbide409-21-2 409–21–2
    Total dust15
    Respirable fraction5
    Silver, metal and soluble compounds (as Ag)7440-22-47440–22–40.01
    Soapstone; see Silicates.
    Sodium fluoroacetate62-74-862–74–80.05X
    Sodium hydroxide1310-73-1310–73–22 2
    Starch9005-25-8 9005–25–8
    Total dust15
    Respirable fraction5
    Stibine7803-52-37803–52–30.10.5
    Stoddard solvent8052-41-38052–41–35002900
    Strychnine57-24-957–24–90.15
    Styrene100-42-5100–42–5(2)
    Sucrose57-50-1 57–50–1
    Total dust15
    Respirable fraction5
    Sulfur dioxide7446-09-7446–09–55513
    Sulfur hexafluoride2551-62-42551–62–410006000
    Sulfuric acid7664-93-97664–93–91
    Sulfur monochloride10025-67-910025–67–916
    Sulfur pentafluoride5714-22-75714–22–70.0250.25
    Sulfuryl fluoride2699-79-82699–79–8520
    Systox; see Demeton.
    2,4,5-T (2,4,5-trichlorophenoxyacetic acid)93-76-593–76–510
    Talc; see Silicates.
    Tantalum, metal and oxide dust7440-25-77440–25–75
    TEDP (Sulfotep)3689-24-53689–24–50.2X
    Tellurium and compounds (as Te)13494-80-913494–80–90.1
    Tellurium hexafluoride (as Te)7783-80-47783–80–40.020.2
    Temephos3383-96-8 3383–96–8
    Total dust15
    Respirable fraction5
    TEPP (Tetraethyl pyrophosphate)107-49-3107–49–30.05X
    Terphenyls26140-60-326140–60–3(C)1(C)9
    1,1,1,2-Tetrachloro-2,2-difluoroethane76-11-976–11–95004170
    1,1,2,2-Tetrachloro-1,2-difluoroethane76-12-076–12–05004170
    1,1,2,2-Tetrachloroethane79-34-79–34–55535X
    Tetrachloroethylene; see Perchloroethylene.
    Tetrachloromethane; see Carbon tetrachloride.
    Tetrachloronaphthalene1335-88-1335–88–222X
    Tetraethyl lead (as Pb)78-00-278–00–20.075X
    Tetrahydrofuran109-99-9109–99–9200590
    Tetramethyl lead (as Pb)75-74-175–74–10.075X
    Tetramethyl succinonitrile3333-52-63333–52–60.53X
    Tetranitromethane509-14-8509–14–818
    Tetryl (2,4,6-Trinitrophenylmethylnitramine)479-45-8479–45–81.5X
    Thallium, soluble compounds (as Tl)7440-28-7440–28–000.1X
    4,4′-Thiobis (6-tert, Butyl-m-cresol)96-69-5 96–69–5
    Total dust15
    Respirable fraction5
    Thiram137-26-8137–26–85
    Tin, inorganic compounds (except oxides) (as Sn)7440-31-57440–31–52
    Tin, organic compounds (as Sn)7440-31-57440–31–50.1
    Titanium dioxide13463-67-7 13463–67–7
    Total dust15
    Toluene108-88-3108–88–3(2)
    Toluene-2,4-diisocyanate (TDI)584-84-9584–84–9(C)0.02(C)0.14
    o-Toluidine95-53-495–53–4522X
    Toxaphene; see Chlorinated camphene.
    Tremolite; see Silicates.
    Tributyl phosphate126-73-8126–73–85
    1,1,1-Trichloroethane; see Methyl chloroform.
    1,1,2-Trichloroethane79-00-579–00–51045X
    Trichloroethylene79-01-679–01–6(2)
    Trichloromethane; see Chloroform.
    Trichloronaphthalene1321-65-91321–65–95X
    1,2,3-Trichloropropane96-18-496–18–450300
    1,1,2-Trichloro-1,2,2-trifluoroethane76-13-176–13–110007600
    Triethylamine121-44-8121–44–825100
    Trifluorobromomethane75-63-875–63–810006100
    2,4,6-Trinitrophenol; see Picric acid.
    2,4,6-Trinitrophenylmethylnitramine; see Tetryl.
    2,4,6-Trinitrotoluene (TNT)118-96-7118–96–71.5X
    Triorthocresyl phosphate78-30-878–30–80.1
    Triphenyl phosphate115-86-6115–86–63
    Turpentine8006-64-28006–64–2100560
    Uranium (as U)7440-61-1 7440–61–1
    Soluble compounds0.05
    Insoluble compounds0.25
    Vanadium1314-62-1 1314–62–1
    Respirable dust (as V2 O5)(C)0.5
    Fume (as V2 O5)(C)0.1
    Vegetable oil mist
    Total dust15
    Respirable fraction5
    Vinyl benzene; see Styrene.
    Vinyl chloride; see 1910.101775-01-4 75–01–4
    Vinyl cyanide; see Acrylonitrile.
    Vinyl toluene25013-15-425013–15–4100480
    Warfarin81-81-281–81–20.1
    Xylenes (o-, m-, p-isomers)1330-20-71330–20–7100435
    Xylidine1300-73-81300–73–8525X
    Yttrium7440-65-57440–65–51
    Zinc chloride fume7646-85-77646–85–71
    Zinc oxide fume1314-13-21314–13–25
    Zinc oxide1314-13-2 1314–13–2
    Total dust15
    Respirable fraction5
    Zinc stearate557-05-1 557–05–1
    Total dust15
    Respirable fraction5
    Zirconium compounds (as Zr)7440-67-77440–67–75

    Table Z-2

    Table Z–2

    Substance 8-hour time weighted average Acceptable ceiling concentration Acceptable maximum peak above the acceptable ceiling concentration for an 8-hr shift
    Concentration Maximum duration
    Benzenea (Z37.40-196940–1969)10 ppm25 ppm50 ppm10 minutes.
    Beryllium and beryllium compounds (Z37.29-197029–1970)d 2 µg/m3 5 µg/m3 25 µg/m3 30 minutes.
    Cadmium fumeb (Z37.5-19705–1970)0.1 mg/m3 0.3 mg/m3
    Cadmium dustb (Z37.5-19705–1970)0.2 mg/m3 0.6 mg/m3
    Carbon disulfide (Z37.3-19683–1968)20 ppm30 ppm100 ppm30 minutes.
    Carbon tetrachloride (Z37.17-196717–1967)10 ppm25 ppm200 ppm5 min. in any 4 hrs.
    Chromic acid and chromates (Z37.7-19717–1971) (as CrO3)c 1 mg/10m3
    Ethylene dibromide (Z37.31-197031–1970)20 ppm30 ppm50 ppm5 minutes.
    Ethylene dichloride (Z37.21-196921–1969)50 ppm100 ppm200 ppm5 min. in any 3 hrs.
    Fluoride as dust (Z37.28-196928–1969)2.5 mg/m3
    Formaldehyde; see 1910.1048
    Hydrogen fluoride (Z37.28-196928–1969)3 ppm
    Hydrogen sulfide (Z37.2-19662–1966)20 ppm50 ppm10 mins. once, only if no other meas. exp. occurs.
    Mercury (Z37.8-19718–1971)1 mg/10m3
    Methyl chloride (Z37.18-196918–1969)100 ppm200 ppm300 ppm5 mins. in any 3 hrs.
    Methylene Chloride: See § 1919.52.
    Organo (alkyl) mercury (Z37.30-196930–1969)0.01 mg/m3 0.04 mg/m3
    Styrene (Z37.15-196915–1969)100 ppm200 ppm600 ppm5 mins. in any 3 hrs.
    Tetrachloroethylene (Z37.22-196722–1967)100 ppm200 ppm300 ppm5 mins. in any 3 hrs.
    Toluene (Z37.12-196712–1967)200 ppm300 ppm500 ppm10 minutes.
    Trichloroethylene (Z37.19-196719–1967)100 ppm200 ppm300 ppm5 mins. in any 2 hrs.
    Table Z-3 - Mineral

    Table Z–3—Mineral Dusts

    Substance mppcfa mg/m3
    Silica:
    Crystalline
    Quartz (Respirable)f 250b 10 mg/m3e
    % SiO2 + 5% SiO2 + 2
    Cristobalite: Use 12 the value calculated from the count or mass formulae for quartzf
    Tridymite: Use 12 the value calculated from the formulae for quartzf
    Amorphous, including natural diatomaceous earth2080 mg/m3
    %SiO2
    Silicates (less than 1% crystalline silica):
    Mica20
    Soapstone20
    Talc (not containing asbestos)20c
    Talc (containing asbestos) Use asbestos limit
    Tremolite, asbestiform (see 29 CFR 1910.1001)
    Portland cement50
    Graphite (Natural)15
    Coal Dust:
    Respirable fraction less than 5% SiO2 2.4 mg/m3e
    10 mg/m3e
    Respirable fraction greater than 5% SiO2 _____
    %SiO2 + 2
    Inert or Nuisance Dust:d
    Respirable fraction155 mg/m3
    Total dust5015 mg/m3
    Aerodynamic diameter (unit density sphere) Percent passing selector
    290
    2.575
    3.550
    5.025
    100

    [58 FR 35340, June 30, 1993; 58 FR 40191, July 27, 1993, as amended at 61 FR 56831, Nov. 4, 1996; 62 FR 1600, Jan. 10, 1997; 62 FR 42018, Aug. 4, 1997; 71 FR 10373, Feb. 28, 2006; 71 FR 16673, Apr. 3, 2006; 71 FR 36008, June 23, 2006; 81 FR 16861, Mar. 25, 2016; 81 FR 31167, May 18, 2016; 81 FR 60272, Sept. 1, 2016; 82 FR 2735, Jan. 9, 2017]