§ 414.91 - Toxic pollutant effluent limitations and standards for direct discharge point sources that use end-of-pipe biological treatment.

§ 414.91 Toxic pollutant effluent limitations and standards for direct discharge point sources that use end-of-pipe biological treatment.

(a) Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

(b) In the case of chromium, copper, lead, nickel, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal-bearing waste streams for the metals and times the flow from cyanide bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in Appendix appendix A of this part, plus any additional OCPSF process wastewater streams identified by the permitting authority on a case-by-case basis as metal or cyanide bearing based upon a determination that such streams contain significant amounts of the pollutants identified above. Any such streams designated as metal or cyanide bearing must be treated independently of other metal or cyanide bearing waste streams unless the permitting authority determines that the combination of such streams, prior to treatment, with the Appendix appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information.

Effluent characteristics	Effluent limitations BAT and NSPS1
	Maximum for any one day	Maximum for any monthly average
Acenaphthene	59	22
Acenaphthylene	59	22
Acrylonitrile	242	96
Anthracene	59	22
Benzene	136	37
Benzo(a)anthracene	59	22
3,4-Benzofluoranthene	61	23
Benzo(k)fluoranthene	59	22
Benzo(a)pyrene	61	23
Bis(2-ethylhexyl) phthalate	279	103
Carbon Tetrachloride	38	18
Chlorobenzene	28	15
Chloroethane	268	104
Chloroform	46	21
2-Chlorophenol	98	31
Chrysene	59	22
Di-n-butyl phthalate	57	27
1,2-Dichlorobenzene	163	77
1,3-Dichlorobenzene	44	31
1,4-Dichlorobenzene	28	15
1,1-Dichloroethane	59	22
1,2-Dichloroethane	211	68
1,1-Dichloroethylene	25	16
1,2-trans-Dichloroethylene	54	21
2,4-Dichlorophenol	112	39
1,2-Dichloropropane	230	153
1,3-Dichloropropylene	44	29
Diethyl phthalate	203	81
2,4-Dimethylphenol	36	18
Dimethyl phthalate	47	19
4,6-Dinitro-o-cresol	277	78
2,4-Dinitrophenol	123	71
2,4-Dinitrotoluene	285	113
2,6-Dinitrotoluene	641	255
Ethylbenzene	108	32
Fluoranthene	68	25
Fluorene	59	22
Hexachlorobenzene	28	15
Hexachlorobutadiene	49	20
Hexachloroethane	54	21
Methyl Chloride	190	86
Methylene Chloride	89	40
Naphthalene	59	22
Nitrobenzene	68	27
2-Nitrophenol	69	41
4-Nitrophenol	124	72
Phenanthrene	59	22
Phenol	26	15
Pyrene	67	25
Tetrachloroethylene	56	22
Toluene	80	26
Total Chromium	2,770	1,110
Total Copper	3,380	1,450
Total Cyanide	1,200	420
Total Lead	690	320
Total Nickel	3,980	1,690
Total Zinc2	2,610	1,050
1,2,4-Trichlorobenzene	140	68
1,1,1-Trichloroethane	54	21
1,1,2-Trichloroethane	54	21
Trichloroethylene	54	21
Vinyl Chloride	268	104

¹ All units are micrograms per liter.

² Total Zinc for Rayon Fiber Manufacture that uses the viscose process and Acrylic Fiber Manufacture that uses the zinc chloride/solvent process is 6,796 µg/l and 3,325 µg/l for maximum for any one day and maximum for monthly average, respectively.

[52 FR 42568, Nov. 5, 1987, as amended at 58 FR 36892, July 9, 1993]