98-9613. National Emission Standards for Hazardous Air Pollutants for Source Category: Pulp and Paper Production; Effluent Limitations Guidelines, Pretreatment Standards, and New Source Performance Standards: Pulp, Paper, and Paperboard Category  

  • [Federal Register Volume 63, Number 72 (Wednesday, April 15, 1998)]
    [Rules and Regulations]
    [Pages 18504-18751]
    From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
    [FR Doc No: 98-9613]
    
    
    
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    _______________________________________________________________________
    
    Part II
    
    
    
    
    
    Environmental Protection Agency
    
    
    
    
    
    _______________________________________________________________________
    
    
    
    40 CFR Parts 63, 261, and 430 National Emissions Standards for 
    Hazardous Air Pollutants for Source Category: Pulp and Paper 
    Production; Effluent Limitations Guidelines, Pretreatment Standards, 
    and New Source Performance Standards: Pulp, Paper, and Paperboard 
    Category; Final Rule
    
    Federal Register / Vol. 63, No. 72 / Wednesday, April 15, 1998 / 
    Rules and Regulations
    
    [[Page 18504]]
    
    
    
    ENVIRONMENTAL PROTECTION AGENCY
    
    40 CFR Parts 63, 261, and 430
    
    [FRL-5924-8]
    RIN 2040-AB53
    
    
    National Emission Standards for Hazardous Air Pollutants for 
    Source Category: Pulp and Paper Production; Effluent Limitations 
    Guidelines, Pretreatment Standards, and New Source Performance 
    Standards: Pulp, Paper, and Paperboard Category
    
    AGENCY: Environmental Protection Agency (EPA).
    
    ACTION: Final rules.
    
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    SUMMARY: This action promulgates effluent limitations guidelines and 
    standards under the Clean Water Act (CWA) for a portion of the pulp, 
    paper, and paperboard industry, and national emission standards for 
    hazardous air pollutants (NESHAP) under the Clean Air Act (CAA) as 
    amended in 1990 for the pulp and paper production source category.
        EPA is also promulgating best management practices under the CWA 
    for a portion of the pulp, paper, and paperboard industry, and new 
    analytical methods for 12 chlorinated phenolic pollutants and for 
    adsorbable organic halides (AOX). This action consolidates into 12 
    subcategories what had once been 26 subcategories of effluent 
    limitations guidelines and standards for the pulp, paper, and 
    paperboard industry, and revises the existing effluent limitations 
    guidelines and standards for the Bleached Papergrade Kraft and Soda 
    subcategory and the Papergrade Sulfite subcategory. The revised 
    effluent limitations guidelines and standards require existing and new 
    facilities within these two subcategories to limit the discharge of 
    pollutants into navigable waters of the United States and to limit the 
    introduction of pollutants into publicly owned treatment works. The 
    NESHAP requires existing and new major sources within the pulp and 
    paper production source category to control emissions using the maximum 
    achievable control technology (MACT) to control hazardous air 
    pollutants (HAP).
        EPA is revising the effluent limitations guidelines and standards 
    for the Bleached Papergrade Kraft and Soda subcategory and the 
    Papergrade Sulfite subcategory primarily to reduce the discharge of 
    toxic and nonconventional chemical compounds found in the effluents 
    from these mills. Discharge of these pollutants into the freshwater, 
    estuarine, and marine ecosystems may alter aquatic habitats, affect 
    aquatic life, and adversely impact human health. Discharges of 
    chlorinated organic compounds from chlorine bleaching, particularly 
    dioxins and furans, are human carcinogens and human system toxicants 
    and are extremely toxic to aquatic life. The final effluent limitations 
    guidelines and standards for the Bleached Papergrade Kraft and Soda and 
    Papergrade Sulfite subcategory are estimated to reduce the discharge of 
    adsorbable organic halides (AOX) by 28,210 kkg/year; chloroform by 45 
    kkg/year; chlorinated phenolics by 47 kkg/year; and 2,3,7,8-TCDD 
    (dioxin) and 2,3,7,8-TCDF (furan) by 125 gm/year. These reductions will 
    permit all 19 dioxin/furan-related fish consumption advisories 
    downstream of pulp and paper mills to be lifted.
        EPA is revising the subcategorization scheme for the effluent 
    limitations guidelines and standards because the new scheme better 
    defines the processes typically found in U.S. mills and thus results in 
    what ultimately will be a streamlined regulation that can be 
    implemented more easily by the permit writer. With the exception of the 
    new effluent limitations guidelines and standards for the Bleached 
    Papergrade Kraft and Soda and Papergrade Sulfite subcategories, EPA is 
    making no substantive changes to the limitations and standards 
    applicable to the newly reorganized subcategories. Those portions of 
    the existing pulp, paper, and paperboard effluent limitations 
    guidelines and standards that are not substantively amended by this 
    action are not subject to judicial review; nor is their effective date 
    affected by this reorganization.
        The HAPs emitted by facilities covered by the NESHAP include such 
    compounds as methanol, chlorinated compounds, formaldehyde, benzene, 
    and xylene. The health effects of exposure to these and other HAPs at 
    pulp and paper mills can include cancer, respiratory irritation, and 
    damage to the nervous system. The final NESHAP is expected to reduce 
    baseline emissions of HAP by 65 percent or 139,000 Mg/yr.
        The pollutant reductions resulting from these rules will achieve 
    the primary goals of both the CAA and CWA, which are to ``enhance the 
    quality of the Nation's air resources so as to promote the public 
    health and welfare and productive capacity of its population'' and to 
    ``restore and maintain the chemical, physical, and biological integrity 
    of the Nation's waters,'' respectively. These rules will result in 
    continued environmental improvement at reasonable cost by providing 
    flexibility in when and how results are achieved and, for certain 
    mills, by providing incentives to surpass baseline requirements.
        Elsewhere in today's Federal Register, EPA is concurrently 
    proposing NESHAP to control hazardous air pollutants from chemical 
    recovery combustion sources at kraft, soda, sulfite, and stand-alone 
    semi-chemical pulp mills.
        In another proposed rule published in today's Federal Register, EPA 
    is also proposing a regulation that would require mills enrolled in the 
    Voluntary Advanced Technology Incentives Program being promulgated for 
    the Bleached Papergrade Kraft and Soda subcategory to submit a plan 
    specifying research, construction, and other activities leading to 
    achievement of the Voluntary Advanced Technology effluent limitations, 
    with accompanying dates for achieving these milestones. Second, EPA 
    proposes to authorize Bleached Papergrade Kraft and Soda subcategory 
    mills under certain circumstances to submit a certification based on 
    process changes in lieu of monitoring for chloroform. Third, although 
    not proposing totally chlorine-free (TCF) technologies for new source 
    performance standards under the CWA for Bleached Papergrade Kraft and 
    Soda subcategory at this time, EPA is requesting comments and data 
    regarding the feasibility of TCF processes for this subcategory, 
    especially the range of products made and their specifications. In that 
    proposal EPA is also requesting comments and data regarding the 
    effluent reduction performance of TCF processes for this subcategory.
    
    DATES: In accordance with the Small Business Regulatory Enforcement 
    Fairness Act of 1996, the regulations shall become effective June 15, 
    1998. For compliance dates, see the SUPPLEMENTARY INFORMATION section 
    under the heading ``Compliance Dates.''
    
    ADDRESSES: Air Dockets. The Air Dockets are available for public 
    inspection between 8 a.m. and 4 p.m., Monday through Friday except for 
    Federal holidays, at the following address: U.S. Environmental 
    Protection Agency, Air and Radiation Docket and Information Center (MC-
    6102), 401 M Street SW, Washington, DC 20460, Room M-1500, Waterside 
    Mall; telephone: (202) 260-7548.
        Water Docket. The complete public record for the effluent 
    limitations guidelines and standards rulemaking is available for 
    review, Monday through Friday except for federal holidays, at EPA's 
    Water Docket, Room M2616, 401
    
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    M Street SW, Washington, DC 20460. For access to Docket materials, call 
    (202) 260-3027. The Docket staff requests that interested parties call 
    between 9:00 am and 3:30 pm for an appointment before visiting the 
    docket.
        For additional information about the dockets, see section X.A 
    below.
        Background and support documents containing technical, cost, 
    economic, and health information, as well as EPA's response to public 
    comments, are available for public use. A listing and how to obtain 
    these background documents is provided in section XI in this notice.
    
    FOR FURTHER INFORMATION CONTACT: For questions regarding air emissions 
    standards for chemical wood pulping mills, contact Ms. Penny Lassiter, 
    Emissions Standards Division (MD-13), U.S. Environmental Protection 
    Agency, Research Triangle Park, NC 27711, telephone number (919) 541-
    5396; or Mr. Stephen Shedd, at the same address, telephone number (919) 
    541-5397. For information concerning the final air standards for 
    mechanical pulping processes, secondary fiber pulping processes, and 
    nonwood fiber pulping processes, contact Ms. Elaine Manning, at the 
    same Research Triangle Park address, telephone number (919) 541-5499. 
    For questions on compliance, enforcement and applicability 
    determinations, contact Ms. Maria Eisemann, Office of Enforcement and 
    Compliance Assurance (2223A), U.S. Environmental Protection Agency, 401 
    M St., S.W., Washington, D.C. 20460, telephone number (202) 564-7106.
        For questions regarding wastewater standards, contact Mr. Donald 
    Anderson at the following address: Engineering and Analysis Division 
    (4303), EPA, 401 M Street, S.W., Washington, D.C. 20460, telephone 
    number (202) 260-7189; or Ms. Wendy D. Smith at the same address, 
    telephone number (202) 260-7184.
        For additional information on the economic impact analyses, contact 
    Dr. William Wheeler, Office of Water, Engineering and Analysis Division 
    (4303), U.S. Environmental Protection Agency, 401 M Street, SW, 
    Washington, DC, 20460, (202) 260-7905.
    
    SUPPLEMENTARY INFORMATION:
    
    Overview
    
        The preamble summarizes the legal authority for these rules, 
    background information, the technical and economic methodologies used 
    by the Agency to develop these rules, the impacts of the rules, 
    regulatory implementation, and the availability of supporting 
    documents.
    
    Regulated Entities
    
        Entities regulated by today's action are those operations that 
    chemically pulp and nonchemically pulp wood and nonwood fibers for pulp 
    and paper production. EPA projects that approximately 490 mills are 
    subject to the air regulations promulgated today. Of these mills, 155 
    will be affected by MACT standards for mills that chemically pulp wood. 
    Within that group, 96 are subject to the effluent limitations 
    guidelines and standards promulgated today. Regulated categories and 
    entities include:
    
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               Category                            Rule                         Examples of regulated entities      
    ----------------------------------------------------------------------------------------------------------------
    Industry.....................  NESHAP..............................  Pulp mills and integrated mills (mills that
                                                                          manufacture pulp and paper/paperboard)    
                                                                          that: chemically pulp wood fiber (using   
                                                                          kraft, sulfite, soda, or semi-chemical    
                                                                          methods); pulp secondary fiber; pulp      
                                                                          nonwood fiber; and mechanically pulp wood 
                                                                          fiber.                                    
                                   Effluent Guidelines.................  Subset of mills subject to the NESHAP that 
                                                                          chemically pulp wood fiber using kraft,   
                                                                          sulfite, or soda methods to produce       
                                                                          bleached papergrade pulp and/or bleached  
                                                                          paper/paperboard.                         
    ----------------------------------------------------------------------------------------------------------------
    
        The foregoing table is not intended to be exhaustive, but rather 
    provides a guide for readers regarding entities likely to be regulated 
    by the NESHAP and effluent limitations guidelines and standards 
    promulgated today. This table lists the types of entities that EPA is 
    now aware could potentially be regulated by this action. Other types of 
    entities not listed in the table could also be regulated. To determine 
    whether your facility or company is regulated by this NESHAP, you 
    should carefully examine the applicability criteria in Sec. 63.440 of 
    the air rule and the applicability criteria in part 63, Subpart A of 
    Title 40 of the Code of Federal Regulations. To determine whether your 
    facility is regulated by the effluent limitations guidelines and 
    standards, you should carefully examine the applicability criteria in 
    Sec. 430.20 and Sec. 430.50 of Title 40 of the Code of Federal 
    Regulations.
        If you have questions regarding the applicability of the NESHAP or 
    the effluent limitations guidelines and standards, see the section 
    entitled FOR FURTHER INFORMATION CONTACT.
    
    Judicial Review
    
        In accordance with 40 CFR Sec. 23.2, the water portion of today's 
    rule shall be considered promulgated for the purposes of judicial 
    review at 1 pm Eastern time on April 29, 1998. Under section 509(b)(1) 
    of the Clean Water Act (CWA), judicial review of today's effluent 
    limitations guidelines and standards is available in the United States 
    Court of Appeals by filing a petition for review within 120 days from 
    the date of promulgation of those guidelines and standards. Under 
    section 307(b)(1) of the CAA, judicial review of the NESHAP is 
    available only by petition for review in the U.S. Court of Appeals for 
    the District of Columbia Circuit within 60 days of today's publication 
    of this NESHAP. Under section 509(b)(2) of the CWA and section 
    307(b)(2) of the CAA, the requirements in this regulation may not be 
    challenged later in civil or criminal proceedings brought by EPA to 
    enforce these requirements.
    
    Compliance Dates
    
        Existing direct dischargers must comply with limitations based on 
    the best available technology economically achievable (BAT) as soon as 
    such requirements are imposed in their National Pollutant Discharge 
    Elimination System (NPDES) permits. The water regulation also 
    establishes specific deadlines for compliance with best management 
    practices (BMPs), which apply to all sources. The new reporting and 
    recordkeeping requirements promulgated today are not effective until 
    the Office of Management and Budget approves Information Collection 
    Requests for those requirements.
        Except as provided in today's BMP regulation, existing indirect 
    dischargers subject to today's water regulations must comply with the 
    pretreatment standards for existing sources being promulgated today by 
    April 16, 2001. In addition, these dischargers must continue to comply 
    with the pretreatment standards for existing sources for 
    pentachlorophenol and trichlorophenol.
    
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        Except as provided in today's BMP regulation, new direct and 
    indirect discharging sources must comply with applicable treatment 
    standards on the date the new source begins operation. For purposes of 
    new source performance standards (NSPS), a source is a new source if it 
    meets the definition of ``new source'' in 40 CFR 430.01(j) and if it 
    commences construction after June 15, 1998. For purposes of 
    pretreatment standards for new sources (PSNS), a source is a new source 
    if it meets the definition of ``new source'' in 40 CFR 430.01(j) and if 
    it commenced construction after December 17, 1993.
        The following compliance dates apply to the Voluntary Advanced 
    Technology Incentives Program being codified today as part of the water 
    regulations for Subpart B. Each existing direct discharging mill that 
    enrolls in the Voluntary Advanced Technology Incentives Program must 
    comply immediately with limitations based on the mill's existing 
    effluent quality or its current technology-based permit limits for the 
    baseline BAT parameters, whichever are more stringent. Participating 
    mills must also comply with mill-specific interim milestones by the 
    dates specified in their NPDES permits. They must also achieve the 
    baseline BAT effluent limitations for dioxin, furan, chloroform, 12 
    specified chlorinated organic pollutants and, for mills enrolled at the 
    Tier II or Tier III level, AOX no later than April 15, 2004. Finally, 
    participating mills must achieve BAT limitations corresponding to the 
    most stringent phase of the Voluntary Advanced Technology Incentives 
    Program by the dates specified below:
        Voluntary BAT limitations for Tier I must be achieved by April 15, 
    2004.
        Voluntary BAT limitations for Tier II must be achieved by April 15, 
    2009.
        Voluntary BAT limitations for Tier III must be achieved by April 
    15, 2014.
        For new direct discharging mills in Subpart B, EPA is promulgating 
    Voluntary NSPS at the Tier II and Tier III levels. Participating new 
    sources must achieve NSPS at the selected level upon commencing 
    operation.
        Compliance dates for the NESHAP are as follows: Existing sources 
    must comply with the NESHAP no later than April 16, 2001 except for the 
    following cases. Equipment in the high volume low concentration (HVLC) 
    system at existing sources at kraft mills (e.g., pulp washer systems, 
    oxygen delignification systems) must comply no later than April 17, 
    2006. Bleach plants at existing source kraft and soda mills 
    participating in the effluent limitations guidelines Voluntary Advanced 
    Technology Incentives Program must comply with the first stage of the 
    NESHAP no later June 15, 1998 and with the second stage no later than 
    April 15, 2004.
        Once today's rules take effect on June 15, 1998, new sources must 
    comply with applicable MACT requirements upon start-up. For a 
    discussion of the circumstances under which a source becomes a new 
    source for compliance with new source air emissions standards, see 
    Sections II.B.2.b. and VI.A.1.
    
    Technology Transfer Network
    
        The Technology Transfer Network (TTN) is one of EPA's electronic 
    bulletin boards. The TTN provides information and technology exchange 
    in various areas of air pollution control. New air regulations are now 
    being posted on the TTN through the world wide web at ``http://
    www.epa.gov/ttn.'' For more information on the TTN, call the HELP line 
    at (919) 591-5384.
        Information on the water regulations may be accessed through the 
    world wide web at http://www.epa.gov/OST/Rules/#final.
    
    Organization of This Document
    
    I. Legal Authority
    II. Scope of This Rulemaking
        A. EPA's Long-Term Environmental Goals
        B. National Emission Standards for Hazardous Air Pollutants 
    (NESHAP)
        C. Effluent Limitations Guidelines and Standards
    III. Background
        A. Prior Regulations, Proposal, Notices of Data Availability, 
    and Public Participation
        B. Clean Air Act Statutory Authority
        C. Clean Water Act Statutory Authority
        D. Other EPA Activities Concerning the Pulp and Paper Industry
    IV. Changes in the Industry Since Proposal
    V. Summary of Data Gathering Activities Since Proposal
        A. Data Gathering for the Development of Air Emissions Standards
        B. Data Gathering for the Development of Effluent Limitations 
    Guidelines and Standards
    VI. Summary of the Major Changes Since Proposal and Rationale for 
    the Selection of the Final Regulations
        A. Air Emission Standards
        B. Effluent Limitations Guidelines and Standards
    VII. Environmental Impacts
        A. Summary of Sources and Level of Control
        B. Air Emissions and Water Effluent Reductions
        C. Non-Water Quality Environmental Impacts of Effluent 
    Limitations Guidelines and Standards (BAT, PSES, and BMPs)
        D. Non-Water Quality Environmental Impacts of New Source 
    Performance Standards and Pretreatment Standards for New Source 
    (NSPS and PSNS)
    VIII. Analysis of Costs, Economic Impacts, and Benefits
        A. Summary of Costs and Economic Impacts
        B. Overview of Economic Analysis
        C. Costs and Economic Impacts for Air Emissions Standards
        D. Costs and Economic Impacts for Effluent Limitations 
    Guidelines and Standards
        E. Costs and Impacts for the Integrated Rule
        F. Costs and Impacts of Rejected BAT/PSES Options for the 
    Bleached Papergrade Kraft and Soda Subcategory
        G. Benefits
        H. Comparison of Costs and Benefits
        I. Costs and Benefits of Rejected Options for the Bleached 
    Papergrade Kraft and Soda Subcategory--Option B and TCF
        J. Benefit-Cost Comparison Using Case Studies
    IX. Incentives for Further Environmental Improvements
        A. The Voluntary Advances Technology Incentives Program
        B. Incentives Available After Achievement of Advanced Technology 
    BAT Limitations and NSPS
    X. Administrative Requirements and Related Government Acts or 
    Initiatives
        A. Dockets
        B. Executive Order 12866 and OMB Review
        C. Regulatory Flexibility Act and the Small Business Regulatory 
    Enforcement Fairness Act of 1996 (SBREFA)
        D. Paperwork Reduction Act
        E. Unfunded Mandates Reform Act
        F. Pollution Prevention Act
        G. Common Sense Initiative
        H. Executive Order 12875
        I. Executive Order 12898
        J. Submission to Congress and the General Accounting Office
        K. National Technology Transfer and Advancement Act
    XI. Background Documents
    
    I. Legal Authority
    
        These regulations are being promulgated under the authority of 
    sections 301, 304, 306, 307, 308, 402, and 501 of the Clean Water Act, 
    33 U.S.C. sections 1311, 1314, 1316, 1317, 1318, 1342, and 1361, and 
    sections 112, 114, and 301 of the Clean Air Act, 42 U.S.C. sections 
    7412, 7414, and 7601.
    
    II. Scope of This Rulemaking
    
        Today's Cluster Rules consist of effluent limitations guidelines 
    and standards for the control of wastewater pollutants and national 
    emission standards for hazardous air pollutants. The final rules issued 
    today are based on extensive information gathered by the Agency and on 
    comments received from interested parties during the development of 
    these regulations.
        Section VI of this notice discusses the major changes since 
    proposal and the rationale for the regulatory decisions
    
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    underlying the rules promulgated today. This summary section highlights 
    the technology bases and other key aspects of the final rules. More 
    detailed descriptions are included in the supporting documents listed 
    in section XI.
        In addition, the Agency is today codifying the subcategorization 
    scheme that was proposed for 40 CFR parts 430 and 431, see 58 FR 66078, 
    66098-100 (Dec. 17, 1993) and is redesignating the section and subpart 
    numbers in 40 CFR part 430 accordingly.
    
    A. EPA's Long-Term Environmental Goals
    
        EPA has integrated the development of the regulations discussed 
    today to provide greater protection of human health and the 
    environment, reduce the cost of complying with the wastewater 
    regulations and air emissions controls, promote and facilitate 
    coordinated compliance planning by industry, promote and facilitate 
    pollution prevention, and emphasize the multimedia nature of pollution 
    control.
        The Agency envisions a long-term approach to environmental 
    improvement that is consistent with sound capital expenditures. This 
    approach, which is presented in today's notice, stems from extensive 
    discussions with a range of stakeholders. The effluent limitations 
    guidelines and standards and air emissions standards are only one 
    component of the framework to achieve long-term environmental goals. 
    The overall regulatory framework also includes incentives to reward and 
    encourage mills that implement pollution prevention beyond regulatory 
    requirements. The Agency will continue to encourage mill-specific 
    solutions to remaining environmental problems through water quality-
    based requirements in permits and enforcement of those requirements. In 
    addition, continuing research on minimum impact technologies, such as 
    closed-loop and totally chlorine-free bleaching processes, will help to 
    identify economical ways of furthering environmental improvement in 
    this industry.
        EPA's long-term goals include improved air quality, improved water 
    quality, the elimination of fish consumption advisories downstream of 
    mills, and the elimination of ecologically significant bioaccumulation. 
    An integral part of these goals is an industry committed to continuous 
    environmental improvement--an industry that aggressively pursues 
    research and pilot projects to identify technologies that will reduce, 
    and ultimately eliminate, pollutant discharges from existing and new 
    sources. A holistic approach to implementing these pollution prevention 
    technologies would contribute to the long-term goal of minimizing 
    impacts of mills in all environmental media by moving mills toward 
    closed-loop process operations. Effective implementation of these 
    technologies is capable of increasing reuse of recoverable materials 
    and energy while concurrently reducing consumption of raw materials 
    (e.g., process water, unrecoverable chemicals, etc.), and reducing air 
    emissions and generation of hazardous and non-hazardous wastes. EPA 
    expects that this combination of regulation, research, pilot projects, 
    and incentives will foster continuous environmental improvement with 
    each mill investment cycle. For this reason, EPA is including an 
    incentives program as part of the effluent limitations guidelines and 
    standards being promulgated today for bleached papergrade kraft and 
    soda mills that accept enforceable permit limits requiring effluent 
    reductions well beyond the rule's regulatory baseline (see Section IX). 
    To ensure that today's air emission standards do not present barriers 
    or disincentives to mills in choosing technologies beyond baseline BAT, 
    EPA is providing additional time to comply with MACT beyond the three-
    year compliance time for certain process units. See Sections VI.A.3.b 
    and VI.A.7 for details on MACT compliance times.
    
    B. National Emission Standards for Hazardous Air Pollutants (NESHAP)
    
    1. Purpose of the NESHAP
        The main purposes of the Clean Air Act (CAA) are to protect and 
    enhance the quality of our Nation's air resources, and to promote the 
    public health and welfare and the productive capacity of the 
    population. See CAA, section 101(b)(1). To this end, section 112(d) of 
    the CAA directs EPA to set standards for stationary sources emitting 
    greater than ten tons of any one HAP or 25 tons of total HAPs annually 
    (one ton is equal to 0.908 megagrams). EPA is promulgating this NESHAP 
    because pulp and paper mills are major sources of HAP emissions. 
    Individual mills are capable of emitting as much as several hundred 
    tons per year (tpy) of HAPs. The HAPs emitted may adversely affect air 
    quality and public health. The HAPs controlled by this rule are 
    associated with a variety of adverse health effects including cancer; a 
    number of other toxic health effects such as headaches, nausea, and 
    respiratory distress; and possible reproductive effects.
        a. Hazardous Air Pollutants. Table II-1 lists the 14 HAPs emitted 
    in the largest quantities from pulp and paper mills. A few HAPs emitted 
    from pulp and paper mills have been classified as possible, probable, 
    or known human carcinogens. These include acetaldehyde, benzene, carbon 
    tetrachloride, chloroform, formaldehyde, and methylene chloride. The 
    total reduction in national HAP emissions by compliance with the NESHAP 
    is estimated to be 139,000 megagrams per year (Mg/yr).
    
       Table II-1.--Highest Emitted Hazardous Air Pollutants From Pulp and  
                                   Paper Mills                              
    ------------------------------------------------------------------------
                                                                            
    ------------------------------------------------------------------------
                            Hazardous Air Pollutants                        
    ------------------------------------------------------------------------
    Acrolein..................................  Methanol.                   
    Acetaldehyde..............................  Methylene chloride.         
    o-Cresol..................................  Methyl ethyl ketone.        
    Carbon tetrachloride......................  Phenol.                     
    Chloroform................................  Propionaldehyde.            
    Cumene....................................  1,2,4-Trichlorobenzene.     
    Formaldehyde..............................  o-Xylene.                   
    ------------------------------------------------------------------------
    
        b. Volatile Organic Compounds. Emissions of volatile organic 
    compounds (VOC) have been associated with a variety of health and 
    welfare impacts. Volatile organic compound emissions, together with 
    nitrogen oxides (NOX), are precursors to the formation of 
    tropospheric ozone. Exposure to ozone is responsible for a series of 
    health impacts, such as alterations in lung capacity; eye, nose, and 
    throat irritation; malaise and nausea; and aggravation of existing 
    respiratory disease. Among the welfare impacts from exposure to ozone 
    include damage to selected commercial timber species and economic 
    losses for commercially valuable crops, such as soybeans and cotton. 
    The total reduction in national VOC emissions by compliance with the 
    NESHAP is estimated to be 409,000 Mg/yr.
        c. Total Reduced Sulfur Compounds. Total reduced sulfur (TRS) 
    compound emissions are responsible for the malodors often associated 
    with pulp and paper production. The total reduction in TRS compound 
    emissions estimated as a result of compliance with this NESHAP is 
    79,000 Mg/yr. Surveys of odor pollution caused by pulp mills have 
    supported a link between odor and health symptoms such as headaches, 
    watery eyes, nasal problems, and breathing difficulties.
    2. Summary of the NESHAP
        The MACT standards apply to pulp and paper mills that have the 
    potential to emit ten tons per year of any one HAP
    
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    or 25 tons per year of all HAPs (one ton is equal to 0.908 megagrams). 
    Potential to emit is based on the total of all HAP emissions from all 
    activities at the mill.
        The NESHAP specifies emission standards for pulping processes and 
    bleaching processes. The emission standards for pulping and bleaching 
    processes provide several options for compliance, including an 
    alternative pollution prevention option (the ``clean condensate 
    alternative'') for the kraft pulping process. The standards specify 
    compliance dates for new and existing sources, require control devices 
    to be properly operated and maintained at all times, and clarify the 
    applicability of the NESHAP General Provisions (40 CFR part 63, subpart 
    A) to sources subject to this rule.
        The rule subcategorizes the industry to specify different emission 
    standards based on the type of pulping process (kraft, sulfite, semi-
    chemical, soda, mechanical wood pulping, secondary fiber pulping, or 
    non-wood pulping) and bleaching process (papergrade or dissolving 
    grade). Mills that chemically pulp wood using kraft, semi-chemical, 
    sulfite, or soda processes are referred to in later sections as MACT I 
    mills. Mills that mechanically pulp wood, or that pulp secondary fiber 
    or non-wood fibers, or that produce paper or paperboard from purchased 
    pulp are referred to in later sections as MACT III mills.
        The emission control requirements for new and existing sources 
    within each subcategory are the same, except that more emission points 
    are covered for sources subject to the new source provisions. Where two 
    or more subcategories are located at the same mill site and share a 
    piece of equipment, that piece of equipment would be considered a part 
    of the subcategory with the more stringent MACT requirements for that 
    piece of equipment. For example, the foul condensates from an 
    evaporation set processing both kraft weak black liquor and spent 
    liquor from a semi-chemical process would have to comply with the kraft 
    subcategory requirements for foul condensate. This more stringent 
    requirement is appropriate because there is no way to isolate the 
    emissions for each pulping source to determine compliance separately.
        These standards do not address emissions from recovery area 
    combustion sources (referred to in later sections as MACT II). These 
    sources are being regulated under a separate NESHAP, which is proposed 
    elsewhere in today's Federal Register. A summary of the specific 
    provisions that apply to each of the subcategories is given in the 
    later parts of this section.
        a. Definition of Affected Source. At chemical wood pulping mills, 
    the affected source is all emission points in the pulping and bleaching 
    systems. At mills that mechanically pulp wood, secondary fibers, or 
    non-wood materials, the affected source is all emission points in the 
    bleaching system. For kraft mills complying with the clean condensate 
    alternative, the affected source is the pulping system, bleaching 
    system, causticizing system, and papermaking system.
        b. New Source MACT.  New source MACT applies to: (1) An affected 
    source that commenced construction or reconstruction after initial 
    proposal; (2) pulping or bleaching systems that are reconstructed after 
    initial proposal; and (3) new pulping systems, pulping lines, bleaching 
    systems, and bleaching lines that are added to existing sources after 
    initial proposal. The initial proposal date for mills that chemically 
    pulp wood is December 17, 1993. The initial proposal date for mills 
    that mechanically pulp wood, pulp secondary fibers, or pulp non-wood 
    materials is March 8, 1996.
        Descriptions of equipment in each subcategory subject to new source 
    MACT requirements are presented in later sections of this preamble.
        c. Compliance Times. The rule requires existing sources to comply 
    with the NESHAP no later than April 16, 2001, except for the following 
    cases. Existing kraft sources are required to control all the equipment 
    in the HVLC collection system no later than April 17, 2006. Dissolving-
    grade mills are required to comply with bleaching system standards no 
    later than three years after publication of the wastewater effluent 
    limitations guidelines and standards under 40 CFR part 430, subparts A 
    and D.
        In addition, the NESHAP sets out a two-phased standard for existing 
    source papergrade kraft and soda bleach mills that elect, under the 
    Voluntary Advanced Technology Incentives Program, to control wastewater 
    discharges to levels surpassing today's BAT baseline. The first phase 
    for existing source MACT requires no increase in the existing HAP 
    emission levels from the papergrade bleaching system--i.e., no 
    backsliding--during the initial period when the mill is working toward 
    meeting its Voluntary Advanced Technology BAT requirements. EPA has 
    determined that immediate compliance with this requirement is 
    practicable because the requirement reflects, for each mill, the 
    performance level it is presently achieving. Therefore, the effective 
    date of the first phase requirements is June 15, 1998. The second phase 
    of existing source MACT requires the mill either to comply with BAT for 
    all pollutant parameters at the baseline level for the Bleached 
    Papergrade Kraft and Soda subcategory, or to certify that chlorine and 
    hypochlorite are not used in the bleach plant, in order to achieve the 
    MACT standard for chloroform emission reduction; it also requires the 
    mill to apply controls for other chlorinated HAPs. All such mills that 
    enroll in the Voluntary Advanced Technology Incentives Program must 
    comply with the second phase of existing source MACT no later than 
    April 15, 2004.
        Once today's rules take effect on June 15, 1998, new sources must 
    comply with applicable MACT requirements upon start-up.
        d. Kraft Pulping Standards. For existing sources, the kraft pulping 
    standards promulgated today apply to the following equipment systems: 
    The low volume high concentration (LVHC) system, the pulp washing 
    system, the oxygen delignification system, decker systems that do not 
    use fresh water or whitewater from papermaking systems or that use 
    process water with HAP concentrations greater than or equal to 400 
    parts per million by weight (ppmw), and knotter systems and screening 
    systems that have total system emissions greater than or equal to 0.05 
    and 0.10 kilograms of HAP per megagram of oven-dried pulp (ODP) 
    produced, respectively (or have total [i.e., knotter and screening] 
    system emissions greater than or equal to 0.15 kilograms of HAP per 
    megagram of ODP produced combined). For new sources, the kraft pulping 
    standards apply to the equipment systems listed above for existing 
    sources, plus weak liquor storage tanks, all knotter systems, all 
    screening systems, and all decker systems.
        Sources subject to the kraft pulping standards must enclose open 
    process equipment and route all emissions through a closed-vent system 
    to a control device. The closed-vent system must be designed and 
    operated with no detectable leaks. The rule provides three control 
    device options, as follows: (1) Reduce the HAP content by 98 percent by 
    weight (or, for thermal oxidizers, to a level of 20 parts per million 
    volume [ppmv] of total HAP, corrected to 10 percent oxygen on a dry 
    basis); (2) reduce HAPs by using a properly operated design thermal 
    oxidizer (operated at a minimum temperature of 1,600  deg.F and a 
    minimum residence time of 0.75 seconds); or (3) reduce HAPs by using a 
    boiler, lime kiln, or recovery
    
    [[Page 18509]]
    
    furnace that introduces all emission streams to be controlled with the 
    primary fuel or into the flame zone.
        The kraft condensate standards apply to condensate streams 
    generated in the following kraft pulping processes: Digester system, 
    evaporator system, turpentine recovery system, LVHC collection system, 
    and the high volume-low concentration (HVLC) collection system. The HAP 
    mass loading in the condensates from these systems must be reduced by 
    92 percent, based upon performance of steam stripping. The NESHAP also 
    includes the following four alternative ways to meet the kraft 
    condensate standard: (1) Recycle applicable condensate streams to 
    process equipment that is controlled in accordance with the kraft 
    pulping standards; (2) reduce the concentration of HAP (measured as 
    methanol) in the condensate to 330 ppmw for kraft mills with bleaching 
    systems, or 210 ppmw for kraft mills without bleaching systems; (3) 
    remove at least 5.1 kilograms of HAP (measured as methanol) per 
    megagram of ODP produced for kraft mills with bleaching systems, or 
    remove at least 3.3 kilogram of HAP per megagram of ODP produced for 
    kraft mills without bleaching systems; or (4) discharge pulping process 
    condensates to a biological treatment system achieving at least 92 
    percent destruction of total HAP.
        The pulping process condensates must be conveyed to the treatment 
    system in a closed collection system that is designed and operated to 
    meet the individual drain system requirements specified in 
    Secs. 63.960, 63.961, 63.962, and 63.964 of subpart RR. These 
    essentially require that the means of conveyance be leak-free. Air 
    emissions of HAP from vents on any condensate treatment systems (except 
    biological treatment systems) that are used to comply with the 
    standards must be routed to a control device meeting the kraft pulping 
    standards.
        All the pulping process condensates from the LVHC and HVLC 
    collection systems must be treated. However, the facility has the 
    option of minimizing the condensate volume sent to treatment from the 
    digester system, turpentine recovery system, and weak liquor feed 
    stages in the evaporator system (i.e., condensate segregation). If 
    sufficient segregation is not achieved, then the entire volume of 
    condensate from the digester system, turpentine recovery system, and 
    weak liquor feed stages in the evaporator system and the LVHC and HVLC 
    collection systems must be treated.
        Two options are provided in the rule for determining if sufficient 
    segregation has been achieved. The first option is to isolate at least 
    65 percent of the total HAP mass in the total of all condensates from 
    the digester system, turpentine recovery system, and weak liquor feed 
    stages in the evaporator system.
        The second option requires that a minimum total HAP mass from the 
    high HAP-concentrated condensates from the digester system, turpentine 
    recovery system, and weak liquor feed stages in the evaporator system 
    and the LVHC and HVLC collection system condensates be sent to 
    treatment.
        e. Clean Condensate Alternative Standards for Kraft Pulping. The 
    final rule provides an alternative compliance option to the kraft 
    pulping standards for subject equipment in the HVLC systems. This 
    alternative compliance option is referred to as the clean condensate 
    alternative (CCA). The CCA focuses on reducing the HAP concentration in 
    process water (such as from the digestion and liquor evaporation areas) 
    that is introduced into process equipment throughout the mill. By 
    reducing the amount of HAP in the process water, reductions in HAP 
    emissions will also be achieved since less HAP will be available to 
    volatilize off the process to the atmosphere. To demonstrate 
    compliance, the mass emission reduction of HAPs achieved by the 
    alternative technology must equal or exceed that which would have been 
    achieved by implementing the kraft pulping vent controls.
        Eligibility for this compliance alternative is determined on a 
    case-by-case basis during the permitting process.
        For purposes of developing a compliance strategy, sources may use 
    either emission test data or engineering assessment to determine the 
    baseline HAP emission reductions that would be achieved by complying 
    with the kraft pulping vent standard. To demonstrate that the 
    alternative technology complies with the emission reduction 
    requirements of the standards, emission test data must be used. Two 
    conditions must be met for a CCA compliance demonstration: (1) Owners 
    and operators that choose this alternative must first comply with 
    pulping process condensate standards before implementing the 
    alternative technology; and (2) the HAP emission reductions cannot 
    include reductions associated with any control equipment required by 
    local, state, or Federal agencies' regulations or statutes or with 
    emission reductions attributed to equipment installed prior to December 
    17, 1993 (i.e., the date of publication of the proposed rule).
        For purposes of the CCA, the rule provides an alternative 
    definition of the affected source. The alternative definition allows 
    for the CCA to apply to process systems outside of the kraft pulping 
    system. The expanded source includes the causticizing system and the 
    papermaking system. The mill must specify the process equipment within 
    the expanded source with which to generate the required HAP emissions 
    reductions using the CCA. The mass emission reduction of HAPs must 
    equal or exceed the reduction that would have been achieved through 
    application of the kraft pulping vent standards. The final 
    determination of equivalency shall be made by the permitting authority 
    based on an evaluation of the HAP emission reductions.
        f. Sulfite Pulping Standards. For existing sources, the sulfite 
    pulping standards apply to the digester system vents, evaporator system 
    vents, and the pulp washing system. The sulfite pulping standards also 
    apply to air emissions from the effluent from any equipment used to 
    reduce HAP emissions to comply with the standards (e.g., acid plant 
    scrubber and nuisance scrubber). For new sources, the sulfite pulping 
    standards apply to the equipment systems listed for existing sources, 
    plus weak liquor tanks, strong liquor storage tanks, and acid 
    condensate storage tanks.
        Sources subject to the sulfite pulping standards for equipment 
    systems must enclose open process equipment and route all HAP emissions 
    through a closed-vent system to a control device. The closed-vent 
    system must be designed and operated with no detectable leaks. The 
    total HAP emissions from the equipment systems and from the effluent 
    from any control device used to reduce HAP emissions must meet a mass 
    emission limit or a percent reduction requirement. Calcium- and sodium-
    based sulfite pulping mills must meet an emission limit of 0.44 
    kilograms of methanol per megagram of ODP or achieve a 92 percent 
    methanol reduction. Ammonium- and magnesium-based sulfite pulping mills 
    must meet an emission limit of 1.1 kilograms of methanol per megagram 
    of ODP limit or achieve an 87 percent methanol removal.
        g. Semi-Chemical Pulping Standards. For existing sources, the semi-
    chemical pulping standards apply to the LVHC vent system. For new 
    sources, semi-chemical pulping standards apply to the LVHC system and 
    the pulp washing system.
        Sources subject to the semi-chemical pulping standards must enclose 
    open process equipment and route all emissions through a closed-vent 
    system
    
    [[Page 18510]]
    
    to a control device. Positive-pressure portions of the closed-vent 
    system must be designed and operated with no detectable leaks. The rule 
    provides three control device options, as follows: (1) Reduce the HAP 
    content by 98 percent by weight (or, for thermal oxidizers, to a level 
    of 20 ppmv of total HAP, corrected to 10 percent oxygen on a dry 
    basis); (2) reduce HAPs by using a properly operated thermal oxidizer 
    (operated at a minimum temperature of 1,600  deg.F and a minimum 
    residence time of 0.75 seconds); or (3) reduce HAPs by using a boiler, 
    lime kiln, or recovery furnace that introduces all emission streams to 
    be controlled with the primary fuel or into the flame zone.
        h. Soda Pulping Standards. For existing sources, the soda pulping 
    standards apply to the LVHC vent system. For new sources, the soda 
    pulping standards apply to the LVHC system and the pulp washing system.
        Sources subject to the soda pulping standards must enclose open 
    process equipment and route all emissions through a closed-vent system 
    to a control device. Positive pressure portions of the closed-vent 
    system must be designed and operated with no detectable leaks. The rule 
    provides three control device options, as follows: (1) Reduce the HAP 
    content by 98 percent by weight (or, for thermal oxidizers, to a level 
    of 20 ppmv of total HAP, corrected to 10 percent oxygen on a dry 
    basis); (2) reduce HAPs by using a properly operated thermal oxidizer 
    (operated at a minimum temperature of 1,600  deg.F and a minimum 
    residence time of 0.75 seconds); or (3) reduce HAPs by using a boiler, 
    lime kiln, or recovery furnace that introduces all emission streams to 
    be controlled with the primary fuel or into the flame zone.
        i. Bleaching System Standards. The bleaching provisions apply to 
    bleaching systems that use elemental chlorine to bleach pulp. At kraft, 
    sulfite, and soda pulping processes, the bleaching system provisions 
    also apply to bleaching systems that use chlorinated compounds to 
    bleach pulp. At mechanical pulping, non-wood fiber pulping, and 
    secondary fiber pulping mills, only bleaching systems that use 
    elemental chlorine or chlorine dioxide to bleach pulp are subject to 
    the NESHAP. Bleaching systems that do not use chlorine or chlorinated 
    compounds are considered to be in compliance with the bleaching system 
    requirements. For the applicable systems (i.e., bleaching or 
    brightening in the different subcategories), the chlorinated HAP 
    emissions from bleaching systems that use elemental chlorine or 
    chlorinated compounds must be controlled. Existing source and new 
    source requirements are the same.
        Sources subject to the bleaching system standards must enclose 
    process equipment in the bleaching stages and route all emissions 
    through a closed-vent system to a control device that achieves either a 
    99 percent reduction of chlorinated HAP's (other than chloroform), an 
    outlet concentration at or below 10 ppmv total chlorinated HAP (other 
    than chloroform), or a mass emission limit at or below 0.001 kg of 
    total chlorinated HAP (other than chloroform) per Mg ODP produced. 
    Chlorine may be used as a surrogate for measuring total chlorinated 
    HAP. The closed-vent system must be designed and operated with no 
    detectable leaks.
        With respect to chloroform emissions from bleaching systems, EPA is 
    closely correlating the air and water standards. This is because EPA is 
    relying on the same process change technology basis to control both 
    chloroform emissions to air and pollutant discharges to water. Thus, 
    MACT to control chloroform for bleaching systems requires a mill either 
    to meet the applicable baseline effluent limitations guidelines and 
    standards for all pollutants being promulgated today under the Clean 
    Water Act or to certify that chlorine and hypochlorite are not used in 
    the bleaching system.
        However, EPA at present lacks sufficient information to establish 
    new effluent limitations guidelines and standards for dissolving grade 
    mills, and also lacks information to reliably ascertain what a MACT 
    standard for chloroform air emissions would be for this unit operation. 
    (It is not appropriate to set MACT standards for chloroform based on 
    the control technology in use today to comply with current effluent 
    limitations guidelines and standards for dissolving grade mills because 
    these technologies are at the wastewater treatment system, rather than 
    in the bleaching process where the chloroform-emitting vents are 
    located.) EPA intends to set new effluent limitations guidelines and 
    standards for dissolving grade mills after analyses currently underway 
    by EPA are complete, and is deferring establishing MACT standards for 
    chloroform until these effluent limitations guidelines and standards 
    are established. Therefore, dissolving grade mills will be required to 
    control chloroform air emissions three years after the new effluent 
    limitations guidelines and standards are promulgated.
        In a related action, EPA is also deferring establishing MACT for 
    chlorinated HAPs other than chloroform from dissolving grade bleaching 
    operations until three years after promulgation of new effluent 
    limitations guidelines and standards for mills performing those 
    operations. The Agency is doing so in order to avoid imposition of CAA 
    requirements which would be inconsistent with, or superseded by, 
    forthcoming CWA regulations.
        EPA is not aware of any control presently in place or any available 
    control technology for reducing chloroform air emissions at mechanical, 
    secondary fiber, and non-wood pulping mills. Therefore, MACT for 
    chloroform at these mills is no control. Today's water rule does not 
    set new effluent limitations guidelines and standards for control of 
    chloroform at mechanical, secondary fiber, and non-wood pulping mills, 
    but EPA will evaluate whether it is appropriate to do so at a later 
    time. At that time, EPA will also determine whether it is appropriate 
    to revise MACT (pursuant to CAA section 112(d)(6)) in order to control 
    chloroform emissions at those mills.
        In addition, EPA is establishing MACT in two phases for bleach 
    plant emissions from existing source papergrade kraft and soda 
    bleaching plants which elect, under the Voluntary Advanced Technology 
    Incentives Program, to control wastewater discharges to levels 
    surpassing the baseline BAT limitations being promulgated today under 
    the CWA. Phase one represents the present MACT floor for existing 
    sources, i.e., no backsliding from existing controls during the initial 
    period when a mill is working toward meeting its Voluntary Advanced 
    Technology BAT requirements; phase two requires the mill either to meet 
    baseline BAT requirements for all pollutants for bleached papergrade 
    kraft and soda mills or to certify that chlorine and hypochlorite are 
    not used in the bleaching system. EPA is establishing MACT in two 
    phases in order to avoid discouraging plants from electing 
    environmentally superior levels of wastewater treatment represented by 
    the Voluntary Advanced Technology Incentives Program. These points are 
    discussed in detail in section VI.A.7.
        j. Mechanical Pulping Mill, Secondary Fiber Pulping Mill, Non-wood 
    Pulping Mill, and Papermaking System Standards. Mechanical pulping 
    (groundwood, thermomechanical, pressurized) mills, secondary fiber 
    pulping mills, and non-wood pulping mills must comply with the 
    bleaching system standards described in section II.B.2.i. There are no 
    control requirements for pulping systems or process condensates at 
    these mills. For
    
    [[Page 18511]]
    
    papermaking systems, there are no control requirements.
        k. Test Methods. The standards specify test methods and procedures 
    for demonstrating that process equipment and condensate streams are in 
    compliance with the MACT standards or are exempt from the rule. The 
    rule also includes provisions to test for no detectable leaks from 
    closed-vent systems. Because the majority of all non-chlorinated HAP 
    emissions from process equipment and in pulping process condensates is 
    methanol, in most cases the owner or operator has the option of 
    measuring methanol as a surrogate for total HAP. For demonstrating 
    compliance using biological treatment or the CCA, the owner or operator 
    must measure total HAP. To demonstrate compliance with the 
    concentration limit requirements, mass emission limit requirements, and 
    percent reduction requirements for bleaching systems, chlorine may be 
    measured as a surrogate for total chlorinated HAP emissions (other than 
    chloroform).
        l. Monitoring Provisions. Sources subject to the NESHAP are 
    required to continuously monitor specific process or operating 
    parameters for control devices and collection systems. Continuous 
    emissions monitoring is not required, except as an alternative to 
    certain control requirements. Parameter values are to be established 
    during an initial performance test. Alternative monitoring parameters 
    must be demonstrated to the Administrator's satisfaction to comply with 
    the standards. As at proposal, excursions outside the selected 
    parameter values are violations except for biological treatment 
    systems. If a biological treatment system monitoring parameter is 
    outside the established range, a performance test must be performed. 
    The parameters that must be monitored for vent and condensate 
    compliance are explained below.
        Mills using a thermal oxidizer must install, calibrate, maintain, 
    and operate a temperature monitoring device and continuous recorder to 
    measure the temperature in the firebox or in the ductwork immediately 
    downstream of the firebox before any substantial heat exchange occurs. 
    Mills using gas scrubbers at bleaching systems or sulfite processes 
    must install, calibrate, maintain, and operate a device to monitor and 
    continuously record (1) pH or the oxidation/reduction potential of 
    scrubber effluent, (2) vent gas inlet flow rate, and (3) scrubber 
    liquid influent flow rate. As an alternative to monitoring these 
    parameters, mills complying with the bleaching system outlet 
    concentration option must install, calibrate, maintain, and operate a 
    device to monitor and continuously record the chlorine outlet 
    concentration. Mills complying with the bleaching system outlet mass 
    emission limit option must install, calibrate, maintain, and operate a 
    device to monitor and continuously record the chlorine outlet 
    concentration and the scrubber outlet vent gas flow. Bleached 
    papergrade kraft and soda mills enrolling in the Voluntary Advanced 
    Technology Incentives Program in the effluent limitations guidelines 
    and standards portion of today's rule must monitor the application 
    rates of chlorine and hypochlorite to demonstrate that no increase in 
    chlorine or hypochlorite use occurs between June 15, 1998 and April 15, 
    2004.
        Mills using steam strippers must install, calibrate, maintain, and 
    operate a device to monitor and continuously record process water feed 
    rate, steam feed rate, and process water feed temperature. As an 
    alternative to monitoring those parameters, mills complying with the 
    steam stripper outlet concentration option may install, calibrate, 
    maintain, and operate a device to monitor the methanol outlet 
    concentration. In addition to monitoring around the stream stripper, 
    mills that choose to treat a smaller, more concentrated volume of 
    condensate rather than the whole volume of subject condensates must 
    also continuously monitor the condensates to demonstrate that the 
    minimum mass or percent of total mass is being treated. This practice 
    is often referred to as condensate segregation. Mills complying with 
    the condensate segregation requirements shall install, calibrate, 
    maintain, and operate monitors for appropriate parameters as determined 
    during the initial performance test.
        Mills using a biological treatment system to treat pulping process 
    condensates must monitor on a daily basis samples of outlet soluble 
    BOD5 concentration (maximum daily and monthly averages), 
    inlet liquid flow, mixed liquor volatile suspended solids (MLVSS), 
    liquid temperature, and the horsepower of aerator units. Additionally, 
    inlet and outlet grab samples from each biological treatment system 
    unit must be collected and stored for 5 days. These samples must be 
    collected and stored since some of the monitoring parameters (e.g., 
    soluble BOD5) cannot be determined within a short period of 
    time. These samples are to be used in conjunction with the WATER8 
    emissions model to demonstrate compliance if the soluble 
    BOD5, MLVSS, or the aerator horsepower monitoring parameters 
    fall outside the range established during the initial performance test.
        Monitoring requirements for the pulping process condensate 
    collection systems include initial and monthly visual inspections of 
    individual drain system components and vent control devices (if used), 
    and repair of defects. Additionally, inspection and monitoring 
    requirements from Sec. 63.964 of subpart RR (National Emission 
    Standards for Individual Drain Systems) are incorporated in the final 
    rule. Monitoring requirements for vent collection systems are (1) a 
    visual inspection of the closed-vent system and enclosure opening seals 
    initially and every 30 days, (2) demonstration of no detectable leaks 
    initially and annually for positive pressure systems or portions of 
    systems, and (3) repair of defects and leaks as soon as practical.
        For the CCA, EPA is not specifying the parameters to be monitored 
    in the final rule since the types of equipment that would be used in 
    the CCA are not known at this time. Consequently, the final rule 
    specifies that owners or operators choosing to use the CCA must conduct 
    an initial performance test to determine the appropriate parameters and 
    corresponding parameter values to be monitored continuously. Rationale 
    for the parameter selection must also be provided for the 
    Administrator's approval.
        m. Reporting and Recordkeeping Provisions. Sources subject to the 
    NESHAP are required to comply with recordkeeping and reporting 
    provisions in the part 63 General Provisions, and other specified 
    requirements in the NESHAP.
        Sources subject to the rule are required to keep readily accessible 
    records of monitored parameters. The monitoring records must be 
    maintained for five years (two years on-site, three years off-site). 
    For each enclosure opening, closed-vent system, and pulping process 
    condensate storage tank, the owner or operator must record the 
    equipment type and identification; results of negative pressure tests 
    and leak detection tests; and specific information on the nature of the 
    defect and repairs. The position of bypass line valves, the condition 
    of valve seals, and the duration of the use of bypass valves on 
    computer controlled valves must also be recorded.
        Sources subject to the NESHAP are required to submit the following 
    types of reports: (1) Initial Notification, (2) Notification of 
    Performance Tests, (3) Exceedance Reports, and (4) Semi-annual Summary 
    Reports. Exceedance and summary reports are not required
    
    [[Page 18512]]
    
    for emission points that are exempt from the rule. Kraft mills must 
    also submit, initially and bi-annually, a non-binding compliance 
    strategy report for pulping sources electing to comply with the eight-
    year compliance extension (including the CCA) and for bleaching sources 
    at bleached papergrade kraft and soda mills electing to comply with the 
    Voluntary Advanced Technology BAT requirements. The compliance strategy 
    report must contain, among other information, a description of the 
    emission controls or process modifications selected for compliance and 
    a compliance schedule indicating when each step toward compliance will 
    be reached. For mills complying with the CCA, the report must contain a 
    description of alternative control technology used, identify each piece 
    of equipment affected by the alternative technology, and estimate total 
    HAP emissions and emission reductions.
    
    C. Effluent Limitations Guidelines and Standards
    
    1. Subcategorization and Schedule
        EPA is replacing the subcategorization scheme under the former 
    effluent limitations guidelines for this industry (in 40 CFR parts 430 
    and 431) with a revised subcategorization scheme. EPA is redesignating 
    the Builders' Paper and Roofing Felt category, formerly regulated in 40 
    CFR part 431, to a subcategory in part 430. This eliminates CFR part 
    431. The Agency is also redesignating the previous subpart numbers and 
    section numbers, which are shown in Table II-2.
        EPA is making no substantive changes to the limitations and 
    standards for any newly redesignated subcategory except for the 
    Bleached Papergrade Kraft and Soda subcategory (new subpart B) and the 
    Papergrade Sulfite subcategory (new subpart E). The rationale for 
    changing the existing subcategorization scheme is discussed in the 
    proposal (58 FR at 66098-66100), the Development Document for Proposed 
    Effluent Limitations Guidelines and Standards for the Pulp, Paper and 
    Paperboard Point Source Category, also referred to as the proposal 
    Technical Development Document (EPA 821-R93-019), and EPA's response to 
    comments on this issue (DCN 14497, Vol. 1).
        Although the Agency is codifying the revised subcategorization 
    scheme for the whole industry today, EPA will promulgate revised 
    effluent limitations guidelines and standards, as appropriate, for this 
    industrial category in stages consisting of several subcategories at a 
    time. The Agency has labeled these groupings of subcategories as 
    ``Phase I,'' ``Phase II,'' and ``Phase III.'' The schedule for these 
    phases is explained below and in the following table.
    
          Table II-2.--Final Codified Subcategorization Scheme (With Previous Subparts Noted) and Schedule for      
                          Promulgating Effluent Limitations Guidelines and Standards (by Phase)                     
    ----------------------------------------------------------------------------------------------------------------
                                                           Types of facilities covered including       Promulgation 
     Final codified subpart    Final subcategorization    previous subcategories (with previous 40       schedule   
                                       scheme                   CFR part 430 subparts noted)             (phase)*   
    ----------------------------------------------------------------------------------------------------------------
    A.......................  Dissolving Kraft........  Dissolving Kraft (F).......................  III            
    B.......................  Bleached Papergrade       Market Bleached Kraft (G), BCT Bleached      I **           
                               Kraft and Soda.           Kraft (H), Fine Bleached Kraft (I), Soda                   
                                                         (P).                                                       
    C.......................  Unbleached Kraft........  Unbleached Kraft (A).......................  II             
                                                          Linerboard                                                
                                                          Bag and Other Products                                    
                                                          Unbleached Kraft and Semi-Chemical (D, V)                 
    D.......................  Dissolving Sulfite......  Dissolving Sulfite (K).....................  III            
                                                          Nitration                                                 
                                                          Viscose                                                   
                                                          Cellophane                                                
                                                          Acetate                                                   
    E.......................  Papergrade Sulfite......  Papergrade Sulfite (J, U)..................  I **           
                                Calcium-, Magnesium-,     Blow Pit Wash                                             
                               and Sodium-based pulps.    Drum Wash                                                 
                                Ammonium-based pulps..                                                              
                                Specialty grade pulps.                                                              
    F.......................  Semi-Chemical...........  Semi-Chemical (B)..........................  II             
                                                          Ammonia                                                   
                                                          Sodium                                                    
    G.......................  Mechanical Pulp.........  Groundwood-Thermo-Mechanical (M),            II             
                                                         Groundwood-Coarse, Molded, News (N),                       
                                                         Groundwood-Fine Papers (O), Groundwood-                    
                                                         Chemi-Mechanical (L).                                      
    H.......................  Non-Wood Chemical Pulp..  Miscellaneous mills not covered by a         II             
                                                         specific subpart.                                          
    I.......................  Secondary Fiber Deink...  Deink Secondary Fiber (Q)..................  II             
                                                          Fine Papers                                               
                                                          Tissue Papers                                             
                                                          Newsprint                                                 
    J.......................  Secondary Fiber Non-      Tissue from Wastepaper (T), Paperboard from  II             
                               Deink.                    Wastepaper (E).                                            
                                                          Corrugating Medium                                        
                                                          Non-Corrugating Medium                                    
                                                          Wastepaper-Molded Products (W)                            
                                                          Builders' Paper and Roofing Felt (40 CFR                  
                                                         Part 431, Subpart A)                                       
    K.......................  Fine and Lightweight      Non integrated Fine Papers (R).............  II             
                               Papers from Purchased      Wood Fiber Furnish                                        
                               Pulp.                      Cotton Fiber Furnish                                      
                                                          Nonintegrated Lightweight Papers (X)                      
                                                          Lightweight Papers                                        
                                                          Lightweight Electrical Papers                             
    
    [[Page 18513]]
    
                                                                                                                    
    L.......................  Tissue, Filter, Non-      Non integrated.............................  II             
                               Woven, and Paperboard      Tissue Papers (S)                                         
                               from Purchased Pulp.       Filter and Non-Woven (Y)                                  
                                                          Paperboard (Z)                                            
    ----------------------------------------------------------------------------------------------------------------
    * Phase I: Promulgation today; Phases II and III: Promulgation dates to be determined.                          
    ** Certain parameter limits to be promulgated as part of Phase II.                                              
    
        a. Bleached Papergrade Kraft and Soda Subcategory and Papergrade 
    Sulfite Subcategory (subparts B and E). Under the consent decree 
    entered in the case Environmental Defense Fund and National Wildlife 
    Federation v. Thomas, Civ. No. 85-0973 (D.D.C.), and subsequently 
    amended, EPA was required to use its best efforts to promulgate 
    regulations addressing discharges of dioxins and furans from 104 
    bleaching pulp mills by June 17, 1995. Despite making its best efforts, 
    EPA was not able to promulgate final effluent limitations guidelines 
    and standards applicable to those mills by that date. However, in 
    today's rule, EPA is promulgating effluent limitations guidelines and 
    standards for mills in the Bleached Papergrade Kraft and Soda 
    subcategory (subpart B) and the Papergrade Sulfite subcategory (subpart 
    E), thereby addressing discharges from 96 of the mills covered by the 
    consent decree. Regulating the discharge of dioxins and furans from the 
    mills in the dissolving kraft and dissolving sulfite subcategories 
    remains a very high priority; as discussed in more detail below, EPA 
    will promulgate effluent limitations guidelines and standards for 
    discharges of dioxins and furans from those mills as soon as possible.
        b. Dissolving Kraft Subcategory and Dissolving Sulfite Subcategory 
    (subparts A and D). EPA is evaluating comments and preliminary new data 
    received since proposal affecting the Dissolving Kraft and Dissolving 
    Sulfite subcategories. The Agency anticipates that the final effluent 
    limitations guidelines and standards for these subcategories will be 
    based on different technologies than those that served as the basis for 
    the proposed limitations and standards. For example, EPA has received 
    data suggesting that oxygen delignification is not a feasible process 
    for making some dissolving pulp products, particularly high grade 
    products. In addition, some use of hypochlorite appears to be necessary 
    to maintain product quality for some products. Affected companies have 
    undertaken laboratory studies and mill trials to develop alternative 
    bleaching processes and to document the effects on wastewater and air 
    emissions. The Agency expects to receive data on these studies and 
    trials as the companies' efforts progress.
        Because EPA's record presently is incomplete, EPA is not 
    promulgating final effluent limitations guidelines and standards for 
    these subcategories now. Even in the absence of these limitations and 
    standards, however, EPA anticipates that alternative bleaching 
    processes developed as a result of these studies and trials should 
    contribute to substantial reductions in the generation and release of 
    pollutants, when compared to current operating practices. Among the 
    pollutants EPA expects to be reduced are dioxin, furan, and chlorinated 
    phenolic pollutants at levels comparable to those achieved by subpart B 
    mills. The Agency also expects to see significant reductions in AOX and 
    chloroform. EPA encourages mills in these subcategories to 
    expeditiously complete developmental work that will facilitate 
    installation of alternative process technologies that achieve these 
    pollution prevention goals.
        As defined today, the Dissolving Sulfite subcategory (subpart D) 
    applies to discharges from dissolving sulfite mills, including mills 
    that manufacture dissolving grade sulfite pulps and papergrade sulfite 
    pulps at the same site. See 40 CFR 430.40. This definition is based on 
    EPA's analysis of data collected in the ``1990 National Census of Pulp, 
    Paper, and Paperboard Manufacturing Facilities.'' Data from the survey 
    indicate that most sulfite mills that produce dissolving grade pulp do 
    so at a very high percentage (typically greater than 85 percent) of 
    their total pulp output. It has come to EPA's attention, however, that 
    some specialty grade papergrade sulfite mills now have the capability 
    to produce low percentages of dissolving grade pulp. EPA does not 
    intend for these mills to be regulated under subpart D; rather, they 
    are specialty grade sulfite mills within the Papergrade Sulfite 
    subcategory (subpart E).
        c. Schedule for the Remaining Subcategories. EPA is assessing 
    comments and data received since proposal for the remaining eight 
    subcategories. These eight subcategories are: (1) Unbleached Kraft; (2) 
    Semi-Chemical; (3) Mechanical Pulp; (4) Non-Wood Chemical Pulp; (5) 
    Secondary Fiber Deink; (6) Secondary Fiber Non-Deink; (7) Fine and 
    Lightweight Papers from Purchased Pulp; and (8) Tissue, Filter, Non-
    Woven, and Paperboard from Purchased Pulp. For example, EPA has 
    received additional information from an industry-sponsored survey of 
    secondary fiber non-deink mills. The Agency also has received 
    additional data from mills in other subcategories, including semi-
    chemical, unbleached kraft, and secondary fiber deink. EPA plans to 
    promulgate effluent limitations guidelines and standards for these 
    subcategories in the near future. It should be noted that air emission 
    standards are being promulgated today for these subcategories.
    2. Best Practicable Control Technology Currently Available (BPT) and 
    Best Conventional Pollutant Control Technology (BCT) for the Bleached 
    Papergrade Kraft and Soda Subcategory and the Papergrade Sulfite 
    Subcategory
        Although the Agency has the statutory authority to revise BPT 
    effluent limitations guidelines, the Agency is exercising its 
    discretion not to revise BPT for Subparts B and E at this time. In 
    addition, none of the technologies that EPA evaluated for the purpose 
    of setting more stringent effluent limitations for the conventional 
    pollutants biochemical oxygen demand (BOD5) and total 
    suspended solids (TSS) passed the BCT cost test for either subcategory. 
    Therefore, EPA is not revising BCT effluent limitations guidelines for 
    Subparts B and E in this rulemaking.
    
    [[Page 18514]]
    
    3. Final Regulations for the Bleached Papergrade Kraft and Soda 
    Subcategory (Subpart B)
        a. Pollutants Regulated. In this rule, EPA is promulgating effluent 
    limitations guidelines and standards for 2,3,7,8-TCDD (``dioxin''), 
    2,3,7,8-TCDF (``furan''), 12 specific chlorinated phenolic pollutants, 
    the volatile organic pollutant, chloroform, and adsorbable organic 
    halides (AOX). EPA is also promulgating new source performance 
    standards for BOD5 and TSS. As explained in section VI.B.3 
    below, the Agency is not promulgating effluent limitations guidelines 
    and standards for chemical oxygen demand (COD) at this time. EPA is 
    also not promulgating effluent limitations guidelines and standards for 
    methylene chloride, methyl ethyl ketone (MEK), acetone, or color. See 
    Section VI.B.3.
        b. Best Available Technology Economically Achievable (BAT). After 
    re-evaluating technologies for mills in the Bleached Papergrade Kraft 
    and Soda subcategory, EPA has determined that the model technology for 
    effluent limitations based on best available technology economically 
    achievable (BAT) should be complete (100 percent) substitution of 
    chlorine dioxide for chlorine as the key process technology, along with 
    other in-process technologies and existing end-of-pipe biological 
    treatment technologies. See Section VI.B.5.a.
        c. New Source Performance Standards. The Agency has determined that 
    the technology basis defining new source performance standards (NSPS) 
    for toxics and non-conventional pollutants is the BAT model technology 
    with the addition of oxygen delignification and/or extended cooking. 
    See Section VI.B.5.b. EPA is also promulgating NSPS for the 
    conventional pollutants BOD5 and TSS.
        As discussed elsewhere in today's Federal Register, EPA also is 
    soliciting comment and intends to gather additional data with respect 
    to totally chlorine-free processes that may be available for the full 
    range of market products. EPA will determine whether to propose 
    revisions to NSPS based upon TCF and, if appropriate, flow reduction 
    technologies.
        In this rule, NSPS are effective June 15, 1998. A source is a new 
    source if it meets the definition of new source in 40 CFR 430.01(j) and 
    if it commences construction after that date.
        d. Pretreatment Standards. The Agency is promulgating pretreatment 
    standards for existing sources (PSES) based on the BAT model 
    technology, excluding biological treatment. EPA is promulgating 
    pretreatment standards for new sources (PSNS) based on the model 
    technology for NSPS, excluding secondary biological treatment. A source 
    is a new source for purposes of PSNS if it meets the definition of new 
    source in 40 CFR 430.01(j) and if it commences construction after the 
    date of proposal, i.e., December 17, 1993. However, a new indirect 
    discharger is not required to meet PSNS for subpart B until those 
    standards become effective, i.e., June 15, 1998.
        e. Voluntary Incentives Program Based on Advanced Technology. As 
    noted earlier in this notice, EPA's vision of long-term environmental 
    goals for the pulp and paper industry includes continuing research and 
    progress toward environmental improvement. EPA recognizes that 
    technologies exist, or are currently under development at some mills, 
    that have the ability to surpass the environmental protection that 
    would be provided by compliance with the baseline BAT effluent 
    limitations guidelines and NSPS promulgated today. The Agency believes 
    that individual mills could be encouraged to explore and install these 
    advanced technologies. Accordingly, EPA is establishing a Voluntary 
    Advanced Technology Incentives Program for direct discharging mills in 
    the Bleached Papergrade Kraft and Soda subcategory. This program is 
    discussed in Section IX.
    4. Final Regulations for the Papergrade Sulfite Subcategory (Subpart E)
        a. Segmentation of Subpart E and Best Available Technology 
    Economically Achievable (BAT). After assessing comments and data 
    received after the proposal, EPA is segmenting the Papergrade Sulfite 
    subcategory to account for production of specialty grade pulps and the 
    applicability of technologies to ammonium-based pulping processes.
        The Agency is segmenting this subcategory and establishing BAT 
    technology bases set forth below. (EPA has established the same 
    segments for new source performance standards and pretreatment 
    standards for subpart E.)
        (1) For production of pulp and paper at papergrade sulfite mills 
    using an acidic cooking liquor of calcium, magnesium, or sodium sulfite 
    (unless the mill is a specialty grade sulfite mill), the BAT technology 
    basis is totally chlorine-free bleaching. EPA is promulgating 
    limitations for AOX for this segment. See Section VI.B.6.b.
        (2) For production of pulp and paper at papergrade sulfite mills 
    using an acidic cooking liquor of ammonium sulfite (unless the mill is 
    a specialty grade sulfite mill), the BAT technology bases for this 
    segment are elemental chlorine-free (ECF) technologies (complete 
    substitution of chlorine dioxide for elemental chlorine, peroxide 
    enhanced extraction, and elimination of hypochlorite) and biological 
    wastewater treatment. EPA is promulgating effluent limitations for 
    dioxin, furan, and 12 chlorinated phenolic pollutants for this segment, 
    but is reserving promulgation of chloroform, AOX, and COD limitations 
    until sufficient performance data are available. See Section VI.B.6.b.
        (3) For production of pulp and paper at specialty grade sulfite 
    mills, the BAT technology bases for this segment are ECF technologies 
    (complete substitution of chlorine dioxide for elemental chlorine, 
    oxygen and peroxide enhanced extraction, and elimination of 
    hypochlorite) and biological wastewater treatment. EPA is promulgating 
    effluent limitations for dioxin, furan, and 12 chlorinated phenolic 
    pollutants for this segment, but is reserving promulgation of 
    chloroform, AOX, and COD limitations for this segment until sufficient 
    performance data are available. See Section VI.B.6.b.
        b. New Source Performance Standards. For each segment identified 
    above, EPA is establishing NSPS based on the model BAT technologies 
    selected for the particular segment. The pollutants are the same as 
    those regulated by BAT for the applicable segment. EPA is also 
    exercising its discretion not to revise NSPS for BOD5, TSS, 
    and pH. See Section VI.B.6.c.
        c. Pretreatment Standards. The Agency is promulgating pretreatment 
    standards for the segments identified above. The pretreatment standards 
    for existing sources (PSES) control the same pollutants controlled by 
    BAT for the particular segment. EPA is promulgating pretreatment 
    standards for new sources (PSNS) for the same toxic and nonconventional 
    pollutants controlled by NSPS for the particular segment. A source is a 
    new source for purposes of PSNS if it meets the definition of new 
    source in 40 CFR 430.01(j) and if it commences construction after the 
    date of proposal, i.e., December 17, 1993. However, a new indirect 
    discharger is not required to meet PSNS for subpart E until those 
    standards become effective, i.e., June 15, 1998. The technology bases 
    for PSES and PSNS for the Papergrade Sulfite subcategory are the same 
    as those chosen for the particular segments at the BAT and NSPS levels, 
    respectively, excluding secondary biological treatment. For the 
    ammonium-based and specialty grade segments, EPA is deferring making a 
    pass-through determination, and hence,
    
    [[Page 18515]]
    
    promulgating pretreatment standards, for chloroform and AOX until it 
    has sufficient performance data to set limitations and standards for 
    those parameters. EPA is promulgating pretreatment standards for AOX 
    for the calcium-, magnesium-, and sodium-based sulfite segment. EPA has 
    made no pass-through determination at this time for COD for any 
    segment. More details are described below in section VI.B.6.d.
    5. Best Management Practices for the Bleached Papergrade Kraft and Soda 
    Subcategory and the Papergrade Sulfite Subcategory
        EPA is codifying best management practices (BMPs) applicable to 
    direct-and indirect-discharging mills in the Bleached Papergrade Kraft 
    and Soda and Papergrade Sulfite subcategories. In response to comments, 
    EPA changed the scope of the BMPs to focus on spent pulping liquor, 
    turpentine, and soap control and to allow for more flexibility in 
    implementation. See Section VI.B.7.
    
    III. Background
    
    A. Prior Regulations, Proposal, Notices of Data Availability, and 
    Public Participation
    
        The regulations that EPA developed for the pulp, paper, and 
    paperboard industry prior to this date are discussed in the proposal. 
    See 58 FR at 66089-92.
        In a Federal Register notice published on December 17, 1993 (58 FR 
    66078), EPA proposed integrated air and water rules that included 
    proposed limitations and standards to reduce the discharge of toxic, 
    conventional, and nonconventional pollutants in wastewaters and to 
    reduce emissions of hazardous air pollutants from the pulp, paper, and 
    paperboard industry. These proposed integrated regulations subsequently 
    became known as ``the Cluster Rules.'' EPA held a public hearing in 
    Washington, D.C., on February 10, 1994, to provide interested persons 
    the opportunity for oral presentation of data, views, or arguments 
    concerning the proposed pretreatment standards. On March 17, 1994 (59 
    FR 12567), EPA published a correction notice to the proposed rules and 
    extended the comment period to April 18, 1994.
        In the preamble to the proposed rules, EPA solicited data on 
    various issues and questions related to the proposed effluent 
    limitations guidelines and standards and air emissions standards. The 
    Agency received and added new material to the Air and Water Dockets. In 
    a notice of data availability published on February 22, 1995 (60 FR 
    9813), EPA announced the availability of new data related to the 
    proposed air emissions standards. Those new data are located in Air 
    Docket A-92-40.
        In a second notice of data availability published on July 5, 1995 
    (60 FR 34938), EPA announced the availability of new information and 
    data related to the proposed effluent limitations guidelines and 
    standards. Those new data are located starting at Section 18.0 of the 
    Post-Proposal Rulemaking Record, which is a continuation of the 
    proposal record. The Post-Proposal Rulemaking Record is located in the 
    Water Docket. EPA did not solicit comment on the new air and water data 
    in either notice.
        On March 8, 1996, EPA published a Federal Register notice 
    pertaining to the air portions of the proposed rules and announced the 
    availability of supplemental information (61 FR 9383). The comment 
    period for that notice closed on April 8, 1996. EPA also proposed MACT 
    standards for mechanical pulping mills, secondary fiber pulping 
    (deinked and non-deinked) mills, and non-wood mills, and asked for 
    additional information on these mills. Furthermore, EPA announced that 
    it was continuing to investigate paper machines and that no MACT 
    standard for paper machines was being proposed at the time. EPA 
    acknowledged an industry testing program was underway; EPA also 
    acknowledged its request to States for data on non-wood pulping mills. 
    EPA requested additional data on HAP emissions from, and control 
    technologies for, paper machines to supplement information previously 
    collected under the MACT process.
        On July 15, 1996, the Agency published a Federal Register notice 
    announcing the Agency's thinking, based on preliminary evaluation of 
    the supplemented record and stakeholder discussions, regarding the 
    technology options being considered as a basis for final effluent 
    limitations guidelines and standards for the proposed Bleached 
    Papergrade Kraft and Soda and Papergrade Sulfite subcategories (61 FR 
    36835). Data were added to the record and comments were solicited from 
    interested parties. The comment period for that notice closed on August 
    14, 1996.
        The Agency has held numerous meetings on these proposed integrated 
    rules with many pulp and paper industry stakeholders, including a trade 
    association (American Forest and Paper Association, or AF&PA), numerous 
    individual companies, environmental groups, States, laboratories, 
    consultants and vendors, labor unions, and other interested parties. 
    EPA has added materials to the Air and Water Dockets to document these 
    meetings.
    
    B. Clean Air Act Statutory Authority
    
        Section 112(b) of the CAA lists 189 HAPs and directs EPA to develop 
    rules to control all major and some area sources emitting HAPs. Major 
    sources are facilities that emit 10 tons of any single HAP or 25 tons 
    of total HAPs annually. On July 16, 1992 (57 FR 31576), EPA published a 
    list of major and area sources for which NESHAP are to be promulgated. 
    The goal of NESHAP is to require the implementation of maximum 
    achievable control technology (MACT) to reduce emissions and, 
    therefore, reduce public health hazards from pollutants emitted from 
    stationary sources. Pulp and paper production was listed as a category 
    of major sources. On December 3, 1993 (58 FR 83941), EPA published a 
    schedule for promulgating standards for the listed major and area 
    sources. Standards for the pulp and paper source category were 
    scheduled for promulgation by November 1997.
        NESHAP established under section 112 of the Act reflect MACT or:
    
    * * * the maximum degree of reduction in emissions of the [HAP] * * 
    * that the Administrator, taking into consideration the cost of 
    achieving such emission reduction, and any nonair quality health and 
    environmental impacts and energy requirements, determines is 
    achievable for new or existing sources in the category or 
    subcategory to which such emission standard applies * * * (See CAA 
    section 112(d)(2)).
    
    C. Clean Water Act Statutory Authority
    
        The objective of the Clean Water Act (CWA) is to ``restore and 
    maintain the chemical, physical, and biological integrity of the 
    Nation's waters.'' CWA Section 101(a). To assist in achieving this 
    objective, EPA issues effluent limitations guidelines, pretreatment 
    standards, and new source performance standards for industrial 
    dischargers. The statutory requirements of these guidelines and 
    standards are summarized in the proposal. See 58 FR at 66088-89.
    
    D. Other EPA Activities Concerning the Pulp and Paper Industry
    
    1. Land Disposal Restrictions Activities
        At the time of proposal, it appeared that many of the surface 
    impoundments used for wastewater treatment in the pulp and paper 
    industry might become subject to Resource Conservation and Recovery Act 
    (RCRA) regulation under the Land Disposal Restriction (LDR) program. 
    See 58 FR at 66091. This program establishes treatment standards that 
    hazardous wastes must meet before
    
    [[Page 18516]]
    
    they can be land disposed--placement in surface impoundments being a 
    type of land disposal. This requirement extends not only to wastes that 
    are identified or listed as hazardous under the RCRA rules when they 
    are land disposed, but also to wastes that are hazardous when 
    generated, cease to be hazardous as a result of dilution, and are then 
    disposed. Chemical Waste Management v. EPA, 976 F.2d 2 (D.C. Cir. 
    1992), cert. denied, 507 U.S. 1057 (1993).
        The pulp and paper industry has many mills that fit this pattern: 
    Numerous wastewater streams are generated, some of them exhibit a 
    characteristic of hazardous waste (corrosivity or toxicity in 
    particular), the streams are commingled before centralized wastewater 
    treatment occurs, and, in the course of commingling, the wastes no 
    longer exhibit the characteristic, and the commingled wastewaters are 
    then treated in a surface impoundment. EPA actually took action to 
    temporarily defer applying LDR rules to this type of situation in the 
    pulp and paper industry in order to allow unhindered promulgation of 
    these Cluster Rules. See 61 FR at 15660, 15574 (April 8, 1996).
        This issue, however, is now moot, at least for the time being. As 
    discussed in the April 8, 1996, notice partially withdrawing the LDR 
    Phase III final rule, 61 FR 15660, the Land Disposal Program 
    Flexibility Act of 1996 provides, among other things, that RCRA 
    characteristic wastewaters are no longer prohibited from land disposal 
    once they are rendered nonhazardous, provided that they are managed in 
    either a treatment system whose ultimate discharge is regulated under 
    the CWA (including both direct and indirect dischargers), a CWA-
    equivalent treatment system, or a Class I nonhazardous injection well 
    regulated under the Safe Drinking Water Act. Under the Land Disposal 
    Program Flexibility Act of 1996, the LDR treatment standards for RCRA 
    characteristic wastes in the pulp and paper industry (or any other 
    industry) do not apply if the characteristic is removed and the wastes 
    are subsequently treated in a surface impoundment that is part of a 
    wastewater treatment system whose ultimate discharge is regulated by 
    the CWA, or if a mill's treatment system provides wastewater treatment 
    that is CWA-equivalent.
        It should be noted that the Act requires EPA to undertake a five-
    year study to determine any potential risks posed by cross-media 
    transfer of hazardous constituents from surface impoundments that 
    accept these ``de-characterized'' wastes and warrant RCRA regulation. 
    The findings of this study, begun by the Agency in April 1996, could 
    eventually result in RCRA regulations for these units.
    2. Land Application of Sludges
        Under the Consent Decree entered in the case Environmental Defense 
    Fund and National Wildlife Federation v. Thomas, Civ. No. 85-0973 
    (D.D.C.), EPA was required to propose rules under section 6 of the 
    Toxic Substances Control Act (TSCA) to regulate the use of sludge 
    produced from the treatment of wastewater effluent of pulp and paper 
    mills using chlorine and chlorine-derivative bleaching processes (56 FR 
    21802; Docket OPTS-62100). EPA published the proposed rules on May 10, 
    1991. The proposed regulations sought to establish a final maximum 
    dioxin and furan soil concentration of ten parts per trillion (ppt) 
    toxic equivalents (TEQ) and site management practices for the land 
    application of bleached kraft and sulfite mill sludge. EPA originally 
    planned to promulgate the rule by November 1992.
        On December 11, 1992, EPA informed the plaintiffs of the Consent 
    Decree that the decision on the promulgation of the proposed sludge 
    land application rule was deferred pending promulgation of the 
    integrated rulemaking for effluent limitations guidelines and standards 
    and national emission standards. EPA reasoned that the effluent 
    limitations guidelines and standards and air emissions standards would 
    have the potential to result in bleach plant process changes that EPA 
    expected would result in reduced dioxin and furan contamination levels 
    in sludge. In addition, EPA was awaiting the results of its dioxin 
    reassessment activities.
        In light of the anticipated impact of the effluent limitations 
    guidelines and standards and air emissions standards on reducing dioxin 
    in pulp and paper mill sludges, as well as reduction in sludge dioxin 
    levels from industry-initiated improvements, EPA chose to defer the 
    decision on promulgation of the final sludge land application rule. 
    When EPA has determined the final impact of today's effluent 
    limitations guidelines and standards on sludge dioxin concentration, 
    EPA will re-evaluate the risk from sludge land application and will 
    choose the appropriate regulatory or non-regulatory mechanism to 
    address the situation.
        Prior to that determination, however, EPA has taken action to 
    achieve risk reduction for situations where sludge is being applied to 
    land.
        While awaiting completion of the effluent limitations guidelines 
    and standards, air emission standards and the dioxin reassessment, EPA 
    has promoted the establishment of an industry environmental stewardship 
    program for the practice of sludge land application.
    3. Hazardous Listing Determination
        Under the consent decree entered in the case of Environmental 
    Defense Fund v. Browner, Civ. No. 89-0598 (D.D.C.), ``EPA shall 
    promulgate a listing determination for sludges from pulp and paper mill 
    effluent on or before the date 24 months after promulgation of an 
    effluent guideline regulation under the Clean Water Act for pulp and 
    paper mills. This listing determination shall be proposed for public 
    comment on or before the date 12 months after promulgation of such 
    effluent guideline regulation. However, EPA shall not be required to 
    propose or promulgate such a listing determination if the final rule 
    for the pending effluent guideline rulemaking (amending 40 CFR part 
    430) under the Clean Water Act to regulate the discharge of dioxins 
    from pulp and paper mills is based on the use of oxygen 
    delignification, ozone bleaching, prenox bleaching, enzymatic 
    bleaching, hydrogen peroxide bleaching, oxygen and peroxide enhanced 
    extraction, or any other technology involving substantially similar 
    reductions in uses of chlorine-containing compounds. If EPA concludes 
    that the final effluent guideline regulation is based on use of such a 
    process and that, as a result, no listing determination is required, 
    EPA shall so inform plaintiff in writing within 30 days of the 
    promulgation of the effluent guideline regulation.''
        At this time, EPA is assessing whether the technology bases for the 
    effluent limitations guidelines and standards promulgated today would 
    fulfill the condition described in the Consent Decree. If so, the 
    Agency would conclude that a listing determination is not warranted. If 
    EPA concludes it does not fulfill the condition, a listing 
    determination would be conducted.
    4. Dioxin Reassessment
        In the spring of 1991, EPA initiated an effort to reassess the 
    scientific bases for estimating dioxin risk. The activities associated 
    with the dioxin reassessment before proposal are described in the 
    proposal. See 58 FR at 66092-93. After the proposal, in September 1994, 
    EPA published a public review draft of this effort, which is commonly 
    referred to as the EPA Dioxin Reassessment. The draft reassessment 
    addressed not only the health effects of dioxin-like chemicals
    
    [[Page 18517]]
    
    but also dioxin sources and pathways for human exposure. Since the 
    draft documents were released, EPA received thousands of pages of 
    public comments. EPA submitted the documents to formal peer review by 
    the EPA Science Advisory Board (SAB). The SAB was supportive of the 
    overall reassessment effort and endorsed the major conclusions of the 
    exposure document and chapters one through seven of the health 
    document. They did, however, believe that additional work was needed on 
    the dose-response modeling chapter and the risk characterization 
    chapter.
        The reassessment is currently being revised and updated in response 
    to public comments. The two chapters singled out by the SAB are being 
    revised by specially established panels composed of scientists from 
    both inside and outside the Agency. Once the work of the special panels 
    is completed these two revised chapters will be examined by peer review 
    panels, and then resubmitted to the SAB for final review. EPA currently 
    anticipates completion and release of the dioxin reassessment in the 
    spring of 1998.
    5. Clean Water Act Section 307(a) Petition
        On September 14, 1993, the Natural Resources Defense Council and 
    the Natural Resources Council of Maine filed with EPA on behalf of 57 
    individuals and environmental groups a petition to prohibit the 
    discharge of dioxin by pulp and paper mills. The petitioners ask EPA to 
    accomplish this prohibition by prohibiting the use of chlorine and 
    chlorine-containing compounds as inputs in the manufacturing process. 
    The petitioners believe that the prohibition is warranted by the 
    dangers to human health and the environment posed by dioxin. The 
    petitioners invoke CWA section 307(a)(2) for authority for such a 
    prohibition.
        Authority for the petition and requested prohibition derives from a 
    different section of the Clean Water Act than today's technology-based 
    effluent limitations guidelines and standards. However, because the 
    petition raised many issues related to the effluent guidelines 
    rulemaking, EPA solicited comment on the issues raised in the petition 
    at the time it proposed effluent limitations guidelines and standards 
    for the pulp and paper industry. See 58 FR at 66174. EPA received 
    thousands of pages of comments and expects to issue a decision granting 
    or denying the petition after completion of the dioxin reassessment.
    6. Cooling Tower Intake Assessment
        EPA is developing regulations under section 316(b) of the Clean 
    Water Act, which provides that any standard established pursuant to 
    Section 301 or 306 and applicable to a point source shall require that 
    the location, design, construction, and capacity of cooling water 
    intake structures reflect the best technology available for minimizing 
    adverse environmental impact. Section 316(b) applies only to the intake 
    of water, not the discharge. A primary goal of the regulation that EPA 
    is developing would be to minimize the destruction of fish and other 
    aquatic organisms as they are drawn into an industrial facility's water 
    intake. EPA plans to conduct screening level and detailed surveys to 
    estimate the number and type of facilities that utilize cooling water 
    intake structures and thus are within the scope of Section 316(b). The 
    pulp and paper industry uses a significant amount of cooling water. EPA 
    intends to gather data on pulp and paper facilities during the Section 
    316(b) rulemaking through questionnaires and site visits. The Section 
    316(b) regulation is scheduled for proposal in 1999 with the final rule 
    due in 2001.
    
    IV. Changes in the Industry Since Proposal
    
        A description of the pulp and paper industry, including 
    manufacturing processes, pulping processes, bleaching processes, and 
    papermaking is included in the proposal. See 58 FR at 66095-96.
        The proposed water regulation encompassed the entire pulp and paper 
    industry of approximately 500 facilities. The proposed air regulations 
    (MACT I and MACT III) covered approximately the same number. Under 
    today's action, approximately 490 mills will be covered by the final 
    MACT I and MACT III rules. Of these mills, 155 will be affected by MACT 
    standards for mills that chemically pulp wood. A subset of these 
    mills--96 mills--will be covered by the final effluent limitations 
    guidelines and standards promulgated today.
        Since the proposal, some facilities have modified their processes. 
    There has been a substantial move toward elemental chlorine-free (ECF) 
    bleaching, and mills are continuing to increase their substitution of 
    chlorine dioxide for chlorine. Additionally, more mills are utilizing 
    oxygen delignification and extended cooking than at proposal. All these 
    developments result in decreased discharges of dioxins and furans to 
    receiving waters.
        The U.S. pulp and paper industry's involvement with totally 
    chlorine-free (TCF) bleaching has not changed substantially since 
    proposal. As was the case at the time of proposal, only one U.S. mill 
    produces TCF kraft pulp; however, this mill is now able to attain 
    higher brightness than was achieved at the time of the proposal.
        The number of companies in the industry is constantly changing as 
    new companies enter the market and other companies leave the industry 
    or merge with other companies. In the subcategories now designated as 
    Subparts B and E, only one mill has closed since proposal and one has 
    changed subcategories. No new Subpart B or E mills have commenced 
    construction since the time of proposal.
        For more details on the technology status of mills covered by the 
    final Cluster Rules, see the ``Supplemental Technical Development 
    Document,'' DCN 14487.
    
    V. Summary of Data Gathering Activities Since Proposal
    
    A. Data Gathering for the Development of Air Emissions Standards
    
        To develop today's standards, extensive data collection and 
    technical analyses were conducted. Prior to proposal, EPA used 
    information in a 1990 census of pulp and paper mills, a 1992 voluntary 
    mill survey, an EPA sampling program, site visits at a number of mills, 
    and a review of State and local regulations to obtain information on 
    emissions, emission control technologies, and emission control costs 
    for pulp and paper mill emission points. After proposal, EPA obtained 
    additional information from the industry. This information included 
    test reports from a variety of testing programs, as well as numerous 
    reports, studies, and memoranda on other issues related to the 
    development of emission control requirements. The information collected 
    before and after proposal was used as the technical basis in 
    determining the MACT level of control.
        EPA also used information on pulp and paper mill production 
    processes available in the general literature and information on 
    control technology performance and cost information developed under 
    other EPA standards to determine MACT.
        Industry commenters indicated that they would be completing a 
    comprehensive emission testing program after proposal, and EPA 
    considered this information to be vital to the development of the final 
    regulation. Therefore, EPA agreed to consider the new data and issued 
    two notices of availability of supplemental information on February 22, 
    1995 (60 FR 9813) and March 8, 1996 (61 FR
    
    [[Page 18518]]
    
    9383) announcing the information and offering the likely implications 
    to the final rule. The opportunity for a public hearing was offered on 
    the March 8, 1996 action, but no request for a hearing was received. 
    Public comments on the March 8, 1996 action were accepted from March 8, 
    1996 to April 8, 1996. Commenters included industry representatives, 
    States, environmental organizations, and other members of the public.
        In the March 8, 1996 supplemental notice, EPA solicited additional 
    data and comments on proposed changes to the December 17, 1993 proposed 
    rule.
        Data added to Air Docket A-92-40 since the March 8, 1996 
    supplemental notice are located in section IV of this docket. These 
    items include additional information on sulfite mills (IV-D1-98, IV-D1-
    100), comments on definitions (IV-D1-97, IV-D1-99, IV-D1-104), comments 
    on the emission factor document (IV-D1-102), clarification of the 1992 
    MACT survey responses (IV-D1-101), and other information.
    
    B. Data Gathering for the Development of Effluent Limitations 
    Guidelines and Standards
    
        EPA has gathered a substantial amount of new information and data 
    since proposal in connection with today's water regulations. Much of 
    this information was collected with the cooperation and support of the 
    American Forest and Paper Association (AF&PA) and the National Council 
    of the Paper Industry for Air and Stream Improvement (NCASI), and with 
    the assistance of many individual mills in the United States. 
    Additional information also has been submitted by environmental groups. 
    EPA has gathered additional information from pulp and paper mills 
    outside of the United States, primarily in Canada and Europe.
        Some of the new information and data were generated through EPA-
    sponsored field sampling or visits at individual mills in the United 
    States, Canada, and Europe. Additional sampling data were voluntarily 
    supplied by many facilities, and information from laboratory and pilot-
    scale studies was shared with the Agency. In order to clarify comments 
    on the proposal, the Agency also gathered information from several 
    surveys administered by AF&PA and NCASI, including data on secondary 
    fiber mill processes, recovery furnace capacities, best management 
    practices, capital and operating costs, process operations, and impacts 
    of technology on the recovery cycle.
        The data gathering activities for this final rule are summarized in 
    detail in the proposal, see 58 FR at 66096, and in the July 15, 1996, 
    notice of data availability, see 61 FR at 36837.
    
    VI. Summary of the Major Changes Since Proposal and Rationale for 
    the Selection of the Final Regulations
    
    A. Air Emission Standards
    
        At proposal, the standards for mills that chemically pulp wood were 
    based on the MACT floor control level. A uniform set of requirements 
    would have applied to all mills that chemically pulp wood using the 
    kraft, sulfite, soda, or semi-chemical process. The proposed standards 
    would have required that, with the exception of some with very low 
    volumetric and mass flow rates, all emission points in the pulping and 
    bleaching area of these mills be controlled. The proposed standards 
    also would have required that all wastewater streams produced in the 
    pulping area of the mill be controlled except for those with a 
    specified low concentration of hazardous air pollutants (HAPs). The 
    proposed control technology basis was to enclose any open process 
    equipment in the pulping and bleaching areas and route all vents and 
    pulping wastewater to a control device. The proposed control technology 
    basis was combustion for pulping area vent sources, scrubbing for 
    bleaching area vent sources, and steam stripping for pulping 
    wastewater.
        Following proposal, EPA received a large number of comments and 
    data to support the need for subcategories with separate MACT standards 
    for each. After considering the data and comments, the final rule 
    specifies separate MACT requirements for each of the four types of 
    pulping processes subject to the standard. The low volumetric and mass 
    flow rates for pulping and bleaching vents and the low concentration 
    value for pulping wastewater are no longer used to determine 
    applicability to the standard. Rather, for each subcategory, the 
    standard lists the specific equipment and pulping area condensates that 
    require control.
        For each subcategory, the Agency determined the MACT floor level of 
    control for existing and new sources, and analyzed the cost and impacts 
    for control options more stringent than the floor. This analysis is 
    presented in chapter 20 of the background information document for the 
    promulgated NESHAP, and is also discussed in the proposal preamble. 
    Based on the results of this analysis, the Agency determined that it 
    was not reasonable to go beyond the MACT floor level of control for 
    sources at kraft, semi-chemical, and sulfite pulp mills, bleaching 
    systems, or kraft condensate systems. The Agency determined that 
    control beyond the floor at soda mills was technically feasible and 
    could be achieved at a reasonable cost. A discussion of the Agency's 
    decision for soda mills is presented in the March 8 supplemental notice 
    and in section VI.A.5.
        In response to comments received on the proposed standards, several 
    changes have been made to the final rule. While some of these changes 
    are clarifications designed to make the Agency's intent clearer, a 
    number of them are significant changes to the compliance requirements. 
    A summary of the substantive comments and changes made since the 
    proposal are described in the following sections. Detailed Agency 
    responses to public comments and the revised analysis for the final 
    rule are contained in the background information document and docket. 
    See Section X.A.
    1. Definition of Source
        At proposal, EPA defined a single broad source that was subject to 
    both existing and new source MACT. That single source included the 
    pulping processes, the bleaching processes, and the pulping and 
    bleaching process wastewater streams at a pulp and paper mill. EPA also 
    considered and solicited comments on the concept of multiple smaller 
    sources that would be subject to the existing and new source MACT 
    requirements.
        In defining the source at proposal, EPA considered the impact of 
    the definition on mills making changes to existing facilities. In 
    general, the narrower the definition of source, the more likely it is 
    that changes to existing facilities would be deemed ``new sources'' 
    under the CAA. With limited exceptions, these new sources must be in 
    compliance with new source MACT standards on the date of startup or 
    June 15, 1998, whichever is later. However, the CAA and the CWA differ 
    regarding applicability requirements and compliance deadlines for new 
    sources. As such, EPA was concerned that a pulp and paper mill planning 
    to construct or reconstruct a source of HAPs between proposal and 
    promulgation of these integrated regulations would find it necessary to 
    plan for compliance with the NESHAP (required on the date it becomes 
    effective) without knowing the requirements of the effluent guidelines 
    for the industry. This situation appeared to be inconsistent with one 
    objective of the integrated rulemaking: allowing facilities to do 
    integrated compliance planning. EPA thus determined that the
    
    [[Page 18519]]
    
    best solution to these concerns was to define a single broad source at 
    proposal.
        In the March 8, 1996 supplemental notice, EPA indicated a 
    continuing inclination for a broad, single source definition. EPA also 
    discussed broadening the source definition further to include 
    papermaking systems and causticizing equipment and solicited comments 
    on these additions. EPA's reason for considering the addition of these 
    two equipment systems was to facilitate implementation of the clean 
    condensate alternative for kraft mills.
        Commenters on the proposed standards and on the March 8 notice 
    largely agreed with the broad, single source definition. One commenter 
    supported a narrow source definition, noting it was inappropriate for 
    new construction at an existing source to be classified as a 
    modification (and hence subject to existing source MACT). The commenter 
    further stated that the final regulation should specify a narrow source 
    definition for determining applicability to new source MACT. Some 
    commenters also stated that EPA should clarify for the final regulation 
    that mill processes not included in the source definition should not be 
    subject to future case-by-case MACT requirements under CAA section 
    112(g).
        EPA considered all of the comments received on this issue since 
    proposal and maintains that the definition of source should be broad 
    enough such that small changes to an existing mill do not trigger new 
    source requirements in the NESHAP. However, EPA also agrees with the 
    commenter that at some point, changes to an existing mill are 
    substantial enough that new source MACT should apply.
        In considering how best to define the source, EPA did not want to 
    define it so narrowly that changes to or additions of individual pieces 
    of equipment would be subject to new source MACT and be required to be 
    in compliance with new source MACT at startup. In fact, EPA was 
    concerned that to do so could discourage mills from implementing 
    pollution-prevention changes as soon as practicable after promulgation 
    of the Cluster Rules. Such changes might include replacing an existing 
    rotary vacuum washer system with a low-flow washer system or installing 
    an oxygen delignification system, both of which, if subject to existing 
    source requirements, would get the eight-year compliance time, 
    discussed later in section VI.A.3.b. Once mills are complying with the 
    existing source MACT requirements, it also did not seem reasonable that 
    they should have to tear out and rebuild that vent collection system to 
    accommodate small equipment changes in the future unless those changes 
    occurred along with other substantial changes that would justify 
    rebuilding the vent collection system.
        For the final regulation, EPA is defining the affected source to 
    which existing MACT requirements apply to include the total of all HAP 
    emission points in the pulping and bleaching systems (including pulping 
    condensates). In considering how mills might engineer their vent 
    collection systems and control devices, EPA has concluded that the 
    following actions occurring after proposal are substantial enough that 
    new source MACT requirements apply:
         A pulping or bleaching system at an existing mill is 
    constructed or reconstructed; or
         A new pulping line or bleaching line is added to an 
    existing mill.
        The proposal date for mills that chemically pulp wood is December 
    17, 1993. The proposal date for mills that mechanically pulp wood, pulp 
    secondary fibers, or pulp non-wood materials is March 8, 1996.
        The final regulation also provides for an alternative definition of 
    source to facilitate implementation of the clean condensate 
    alternative. For mills using the alternative to comply with the kraft 
    pulping standards, the final regulation defines a single broad source 
    that includes the total of all pulping, bleach, causticizing, and 
    papermaking systems. A more detailed discussion of the clean condensate 
    alternative is given in section VI.A.3.d.
        EPA agrees with the commenters that certain emission points that 
    are excluded from the definition of affected source in today's rule, or 
    are subject to a determination that MACT for these operations is no 
    control, should not be required to undergo CAA section 112(g) review. 
    The sources that have been so identified are wood yard operations 
    (including wood piles); tall oil recovery systems at kraft mills; 
    pulping systems at mechanical, secondary fiber, and non-wood fiber 
    pulping mills; and papermaking systems. With regard to wood yard 
    operations, tall oil recovery systems, and pulping systems at 
    mechanical, secondary fiber, and non-wood fiber pulping mills, EPA has 
    determined that these sources do not emit significant quantities of 
    HAPs and EPA is not aware of any reasonable technologies for 
    controlling HAPs from these sources. For papermaking systems, EPA has 
    not identified any reasonable control technology, other than the clean 
    condensate alternative, that can reduce HAP emissions attributable to 
    HAPs present in the pulp arriving from the pulping and bleaching 
    systems. Additionally, EPA has determined that the use of papermaking 
    systems additives and solvents do not result in significant emissions 
    of HAPs (Air Docket A-92-40, IV-B-27). Therefore, based on the 
    applicability requirements of section 112(g) [40 CFR 63 part B, 
    63.40(b)], the following sources would not be required to undergo 
    section 112(g) review: wood yard operations; pulping systems at 
    mechanical, secondary fiber, and non-wood fiber mills; tall oil 
    recovery systems; and papermaking systems.
    2. Named Stream Approach
        At proposal, the rule proposed applicability cutoff values (i.e., 
    volumetric flow rate and mass flow rate) as a way to distinguish the 
    vent and condensate streams that would be required to meet the rule. 
    Since proposal, the pulp and paper industry submitted additional data 
    that allowed EPA to better characterize the vent and condensate streams 
    that should be controlled.
        In the final rule, the applicability cutoffs contained in the 
    proposed rule have been replaced in favor of specifically naming 
    process equipment and condensate streams that would be required to meet 
    the rule, with the exception of decker, knotter, and screen systems at 
    existing sources. For these systems, the additional industry data was 
    used to determine applicability cutoffs in the form of HAP emission 
    limits (for knotter and screen systems) and HAP concentration limits in 
    process water (for decker systems) to identify the systems that should 
    be controlled at existing sources. A description of the vent and 
    condensate streams to be controlled is presented in sections II.B.2, 
    VI.A.3.a, and VI.A.4-7. The Agency added language in the definitions 
    for the named systems to make the definitions applicable to equipment 
    that serves a similar function as those specifically listed. This 
    addition was made because there are no standard names for process 
    equipment. The EPA's intent was to include the equipment that function 
    the same as the equipment specifically named in the definitions, even 
    though the mill may use a different name for that piece of equipment.
        The different approach used in the final rule does not 
    significantly change the number of emission points controlled from 
    those intended to be controlled in the proposed rule. The emission 
    points and condensate streams that are being controlled in the final 
    rule are fundamentally the same emission sources that EPA intended to 
    be controlled in the proposed rule. EPA
    
    [[Page 18520]]
    
    concluded that the revised approach is easier and less costly to 
    implement, for both the affected industry and the enforcement 
    officials, since extensive emission source testing is not required to 
    identify the vent and condensate streams to be controlled.
    
    3. Kraft Pulping Standards
    
        a. Applicability for Existing Kraft Sources. In the December 17, 
    1993 proposal, all pulping system equipment, with some exceptions, 
    would have been required to be controlled. The exceptions were for 
    deckers and screens at existing sources and small vents below specified 
    volumetric mass flow rates and mass loadings. EPA proposed to require 
    that treatment of all pulping wastewater streams except those with HAP 
    concentrations below 500 ppmw and flow rates below 1.0 liter per 
    minute.
        In the March 8, 1996 supplemental notice, the Agency presented 
    potential changes to the kraft mill standards. These changes included 
    specifically naming equipment systems and pulping wastewater subject to 
    the standards. For existing sources, the named equipment systems in the 
    supplemental notice included: the LVHC system, pulp washing system, 
    oxygen delignification system, the pre-washer knotter and screening 
    system, and weak liquor storage tanks. The subject wastewater streams 
    are the pulping process condensates from the digester, evaporator, 
    turpentine recovery, LVHC collection, and the HVLC collection systems. 
    EPA identified these systems and condensates to be controlled based on 
    information presented in responses to industry surveys available prior 
    to proposal and on updates and clarifications to survey responses 
    submitted by the pulp and paper industry after proposal. At proposal, 
    EPA did not have sufficient information to define these equipment 
    systems.
        At proposal, the Agency solicited comments on its determination of 
    the control technology basis for the MACT floor and for MACT. The 
    proposed MACT floor level of control at existing kraft sources was 98 
    percent reduction of emissions from the LVHC system, pulp washing 
    system, and oxygen delignification system. In considering information 
    received after proposal, the Agency continued to have questions, which 
    were discussed with representatives of the pulp and paper industry, on 
    the data provided in the survey responses on weak liquor storage tanks, 
    the knotter and screening system, and the decker system at existing 
    sources (Air Docket A-92-40, IV-D1-101). In the March 8, 1996 notice, 
    the Agency requested further information on whether to distinguish 
    between types or ages of weak liquor storage tanks, methods and costs 
    of controlling them, and the level of control that represents the MACT 
    floor for the different tanks. The Agency also requested data on the 
    type of controls present on knotter and screening systems.
        Commenters to the March 8 notice provided additional information on 
    the kraft mills which control vents from knotter system, screen 
    systems, decker systems, weak liquor storage tanks, and oxygen 
    delignification systems. The commenters noted that many of the mills 
    surveyed originally had misinterpreted survey questions for these 
    systems. The commenters concluded that the revised information 
    indicated that less than 6 percent of the knotter and screen systems, 
    decker systems, and weak liquor storage tanks were actually controlled; 
    they concluded, therefore, that the existing source floor for these 
    vents is no control. Additionally, the commenters asserted that it 
    would not be cost-effective to go beyond the floor to control weak 
    liquor storage tanks because tanks at existing sources would not have 
    the structural integrity to withstand a vacuum on them caused by the 
    vent collection system. The commenters asserted that, to control 
    emissions, these tanks would either need to be replaced or be 
    retrofitted with expensive add-on controls that would not be cost-
    effective. One commenter supported using age as a means to indicate 
    structural integrity and, therefore, rule applicability for weak liquor 
    storage tanks. Several commenters disagreed that age was an appropriate 
    indicator.
        The Agency has evaluated the information submitted by the 
    commenters on the control level for the knotter system, screen system, 
    decker system, and weak liquor storage tanks. Information submitted by 
    the commenters indicated that of the 597 weak liquor storage tanks in 
    the survey only 28 (4.7 percent) actually had emissions routed to a 
    control device (Air Docket A-92-40, IV-D1-106). Some respondents had 
    previously included other types of controlled tanks, such as washer 
    filtrate tanks, in their totals because EPA's original survey did not 
    provide a definition of weak liquor storage tanks. The Agency, 
    therefore, has concluded that the MACT floor level of control for weak 
    liquor storage tanks at existing sources is no control. While some 
    tanks are controlled, available information does not support the 
    supposition that age is a good parameter for distinguishing structural 
    integrity. In addition, the Agency evaluated the cost of going beyond 
    the floor to control weak liquor tanks. The results of EPA's analysis 
    indicated that a significant cost would be incurred for a limited 
    emission reduction. This analysis is presented in Chapter 20 of the 
    background information document for the promulgated NESHAP. Therefore, 
    the Agency agrees with the commenters that control beyond the floor is 
    not justified. Weak liquor tanks at new sources are required to be 
    controlled.
        The Agency disagrees with the comments that decker systems are not 
    controlled at the floor at existing sources. Information supplied by 
    the pulp and paper industry indicates there are 170 decker systems in 
    mills responding to EPA's industry survey questionnaires. All the 
    decker systems are associated with bleached mills. Of the 170 decker 
    systems, 14 are controlled (8 percent) (Air Docket A-92-40, IV-B-16).
        The majority of decker systems controlled at the floor (10 systems) 
    are associated with oxygen delignification systems or are being used as 
    an additional stage of pulp washing. The Agency believes that these 
    types of decker systems are operated similarly to and have similar 
    emissions as pulp washers. Decker systems used in this manner receive 
    contaminated condensates or filtrates that may be recycled from other 
    processes, such as the oxygen delignification system or combined 
    condensate tanks. The process water may have a HAP concentration that 
    would release significant amounts of HAP to the air from the air-water 
    interface. The Agency characterized the emissions from this source to 
    identify the types of decker systems with high emissions. Information 
    supplied in NCASI technical bulletin 678 provided a relationship 
    between air emissions and methanol concentrations in process water used 
    in rotary vacuum drums. EPA evaluated this relationship and determined 
    that decker controls and higher HAP emission rates were associated with 
    deckers that used process water with HAP concentrations greater than or 
    equal to 400 ppmw, or that did not use fresh water or ``whitewater'' 
    from papermaking systems (Air Docket A-92-40, IV-B-22).
        Therefore, the Agency has determined that it is appropriate to make 
    a distinction among types of decker systems at existing sources for the 
    purpose of setting the MACT standard. Decker systems at existing 
    sources using fresh water or ``whitewater'' from papermaking systems, 
    or using process
    
    [[Page 18521]]
    
    water with HAP concentrations less than 400 ppmw, are not required to 
    be controlled. Decker systems at new sources are required to be 
    controlled regardless of the HAP concentration in the process water 
    introduced into the decker.
        EPA has reviewed available data on knotter and screen systems and 
    has concluded that these systems are controlled sufficiently to 
    establish a MACT floor level of control, and also that control more 
    stringent than the floor is not warranted. Data used to reach this 
    conclusion include survey responses from the 1992 voluntary survey, 
    follow-up telephone surveys conducted by the National Council of the 
    Paper Industry for Air and Stream Improvement (NCASI), and emissions 
    data from the NCASI 16-mill study. Although the data indicate that many 
    of these systems are currently controlled to some degree, the survey 
    responses were not detailed enough in their equipment system 
    descriptions and the test data were too limited for the Agency to use 
    these two sources of information alone to develop the MACT control 
    requirements. Because these equipment systems, nomenclature, and 
    control configurations vary across the industry, the Agency decided 
    that a HAP emissions limit would be the best way for mills to determine 
    which systems would require control. EPA lacks sufficient data, 
    however, to pinpoint any single value that represents the MACT floor. 
    Rather, based on the survey and test data, there are a range of values 
    from which EPA could choose. EPA further considered the costs of 
    control in choosing from this zone of reasonable values.
        Of the 171 knotter systems reported in the 1992 voluntary survey, 
    12 knotter systems at 5 mills were reported as controlled and ducted 
    into the noncondensible gas (NCG) collection system and another 49 
    knotter systems at 23 mills were reported as having no vents. NCASI 
    followed up by telephone surveys with these 28 mills (Air Docket A-92-
    40, IV-D1-101, IV-D1-112, IV-D1-114). The follow-up surveys indicated a 
    fair amount of misreporting at these 28 mills. NCASI did not resurvey 
    for all 171 knotter systems. Therefore, the following knotter system 
    floor determination assumes that the mills not resurveyed that 
    originally reported no knotter system controls did not control any 
    vents.
        From the 28 mills resurveyed, it was determined that six knotter 
    systems or 3.6 percent (6/171) route all vents into the NCG collection 
    system; another two knotter systems or 1.2 percent (2/171) route all 
    knotter hood vents into the NCG collection system; another eight 
    knotter systems or 4.7 percent (8/171) use only pressure knotters; and 
    another two knotter systems or 1.2 percent (2/171) route all vents to 
    the smelt dissolving tank scrubber. Industry collected data at seven 
    pressure/open (also referred to as pressure/vibrating) knotter systems 
    and found the methanol emissions to range from 0.005-0.07 kilograms per 
    megagram of oven-dried pulp (ODP) produced, and collected data at one 
    pressure knotter system and found the methanol emissions to be 0.0042 
    kilograms per megagram ODP produced. Emissions data are summarized in 
    the Chemical Pulping Emission Factor Development Document (Air Docket 
    A-92-40, IV-A-8). Because the pressure knotter system emissions were 
    lower than the emissions at the pressure/open systems, pressure systems 
    can be considered a type of controlled system. Therefore, 18 or 10.5 
    percent (6+2+8+2 = 18/171) of the knotter systems have some level of 
    emissions control. The Agency believes that this estimate of the number 
    of knotter systems controlled may be somewhat low because it is 
    uncertain how many of the mills not resurveyed may have had the lower 
    emitting pressure systems.
        The 1992 voluntary MACT survey responses indicated that 96 
    screening systems out of the 199 reported are not vented. NCASI 
    resurveyed by telephone 41 of these 96 mills. Assuming that the 55 
    mills not resurveyed look similar to the 41, the follow-up survey 
    determined that seven percent (6/41  x  96/199) route their vents to 
    the NCG collection system and 41 percent (35/41  x  96/199) have closed 
    screens that vent through auxiliary tanks. Therefore, 48 percent of the 
    screening systems have some level of control.
        Industry collected data at one closed screen system and one open 
    screen system. The closed screen system tested had methanol emissions 
    of 0.004 kilograms per megagram of ODP produced. The open screen system 
    tested had methanol emissions of 0.22 kilograms per megagram of ODP 
    produced.
        The Agency considered how best to characterize the average 
    emissions limitation achieved by the best controlled 12 percent of the 
    knotter systems and screen systems given the wide variety of control 
    scenarios present in the industry. Either collecting and controlling 
    vents on an open system or using closed equipment results in lower air 
    emissions. The Agency decided to select the emissions limitation using 
    the test data from the closed and open equipment systems. The Agency's 
    decision is due in part to the fact that the technology basis for the 
    effluent limitations guidelines and standards being promulgated in 
    these Cluster Rules at 40 CFR Part 430 for bleached papergrade kraft 
    and soda mills include closing the screening areas and returning 
    wastewater to the recovery system. Thus, it is likely that many mills 
    will move toward wider use of the lower air emitting pressure systems.
        Because there is only one test data point for the pressure knotter 
    systems and that emissions value is similar to the low end of the range 
    of data points for the pressure/open knotter systems, the Agency did 
    not believe it would be appropriate to set the emission limit equal to 
    the one pressure knotter system. Similarly, because there is only one 
    test data point for closed screens, the Agency did not believe it would 
    be appropriate to use that single data point to set the emission limit 
    for screening systems. The Agency could have selected any emission 
    limit within the range of all available data for knotters (i.e., 0.0042 
    to 0.07 kilograms per megagram of ODP produced) and screens (i.e., 
    0.004 to 0.22 kilograms per megagram of ODP produced). However, 
    recognizing the limited data available, the Agency also considered the 
    cost effectiveness of controlling these systems to aid in setting the 
    emission limits within the range of reasonable values (Air Docket A-92-
    40, IV-B-21).
        Based on considering all available data, the final rule requires 
    that existing kraft sources are required to control knotter systems 
    with total mass emission rates greater than or equal to 0.05 kilograms 
    of HAP per megagram ODP produced. Existing kraft sources are required 
    to control screening systems with total mass emission rates greater 
    than or equal to 0.10 kilograms of HAP per megagram ODP produced. Since 
    it is often difficult to distinguish between the knotter system and 
    screening system at mills, a mill may also choose to meet a total mass 
    emissions limit of 0.15 kilograms of HAP per megagram ODP produced 
    across the knotting and screening combined system. New sources are 
    required to control all knotter and screen systems, regardless of 
    emissions level.
        b. Compliance Times for Kraft Mills. In the March 8, 1996 
    supplemental notice, the Agency discussed that it was considering 
    allowing kraft mills an extended compliance time of five additional 
    years (eight years total) for pulp washing and oxygen delignification 
    systems (61 FR at 9394-95). The notice discussed how the additional 
    time would encourage the
    
    [[Page 18522]]
    
    maximum degree of overall multi-media pollution reduction and, in 
    particular, would avoid discouraging mills from installing oxygen 
    delignification equipment to reduce water pollution. The notice 
    recognized the time constraints mills would face in trying to comply 
    with both air and water rules essentially at the same time and that too 
    short a compliance time could preclude mills from considering pollution 
    prevention techniques with considerable environmental benefits, such as 
    oxygen delignification and low-flow washers. These technologies reduce 
    the amount of pollutants discharged into the wastewater. The March 8, 
    1996 notice also solicited comment on whether this compliance extension 
    should be extended only to mills that commit to install these 
    technologies (if EPA were to decide not to include that equipment as 
    part of its BAT model technology).
        Commenters supported the extension of compliance time for pulp 
    washing and oxygen delignification systems at existing sources. Several 
    commenters also requested that the compliance time be extended for weak 
    liquor tanks, knotter and screening systems, and other HVLC vent 
    streams because emissions from these sources will be transported and 
    controlled by the same HVLC collection and incineration system as the 
    pulp washing and oxygen delignification systems. The commenters noted 
    that extension of the compliance period for all HVLC sources also 
    allows for proper consideration of the full range of emerging 
    innovative water and air pollution control options. Comments were not 
    received on whether to provide the compliance extension only to mills 
    that elect to install more stringent control technologies than 
    necessary to comply with the baseline BAT requirements.
        The Agency reviewed the comments and agrees that vents included in 
    the HVLC system should be allowed a similar compliance time as the pulp 
    washing and oxygen delignification systems. The majority of emissions 
    and vent gas flow from equipment associated with the HVLC vent streams 
    occur from the pulp washing system and the oxygen delignification 
    system. Therefore, the design of the HVLC collection and transport 
    system would be significantly influenced by these two systems. The 
    Agency determined if different compliance times were provided for the 
    components of the HVLC system, an affected source would expend 
    significant amounts of capital to control systems required to comply in 
    the three-year time frame. The source would have to re-design the gas 
    transport and control devices five years later to accommodate 
    controlling the washing system and oxygen delignification system. This 
    entire cost could discourage the implementation of low-flow washing 
    systems and oxygen delignification.
        This would serve as an obvious disincentive to installation of 
    advanced wastewater treatment technology since mills would be 
    understandably reluctant to replace a newly installed air pollution 
    control system. Therefore, EPA concluded that additional compliance 
    time is appropriate and necessary for the remaining equipment 
    controlled by the HVLC collection and transport system as well as the 
    pulp washing system and the oxygen delignification system. See 
    generally 61 FR at 9394-95. The final rule thus allows affected sources 
    to control all the equipment in the HVLC system at kraft pulping 
    systems at the same time, not later than April 17, 2006. A mill that 
    installs an oxygen delignification system at an existing source after 
    April 17, 2006 must comply with the NESHAP upon commencing operation of 
    that system.
        Regarding EPA's solicitation of comments on providing a compliance 
    extension to all kraft mills, no negative comments were received. 
    Therefore, EPA has decided to extend the compliance time for all kraft 
    mills.
        The final rule includes requirements for kraft mills to submit a 
    non-binding control strategy report along with the initial notification 
    required by the part 63 General Provisions. The purpose of the control 
    strategy report is to provide the Agency and the permitting authority 
    with the status of progress towards compliance with the MACT standards. 
    The control strategy report must contain, among other information, a 
    description of the emission controls or process modifications selected 
    for compliance with the control requirements and a compliance schedule. 
    The information in the control strategy report must be revised or 
    updated every two years until the mill is in compliance with the 
    standards.
        c. Condensate Segregation. The proposed standards for process 
    wastewater would have required that all pulping wastewaters that met 
    the mass emission rate and flow rate applicability criteria had to be 
    treated to achieve the specified control options. Comments and data 
    submitted to EPA indicated that kraft mills typically steam stripped 
    the condensates from the digester, turpentine recovery, LVHC, and HVLC 
    systems, and certain evaporator condensates. The data also indicated 
    that mills that use steam strippers also practiced varying degrees of 
    condensate segregation in order to minimize the flow rate and maximize 
    the HAP mass in condensate streams sent to treatment.
        In the March 8, 1996 Federal Register supplemental notice, EPA 
    presented a discussion of condensate segregation and included 
    definitions for condensate segregation and a segregated condensate 
    stream. Commenters on the March 8 notice supported the definitions for 
    condensate segregation and segregated condensate stream. Commenters 
    also submitted additional information suggesting definitions for 
    condensate segregation and segregated condensate stream as well as 
    options for demonstrating compliance with the condensate segregation 
    requirements. EPA evaluated the information and included some of the 
    concepts in the final rule.
        The final rule states that the condensates from pulping process 
    equipment at kraft mills must be treated and allows a number of 
    alternative methods of complying with the standards, all of which 
    represent MACT. The final rule also states that the entire volume of 
    condensate generated from the named pulping process equipment at kraft 
    mills must be treated unless the volume from the digester, turpentine 
    recovery, and weak liquor feed stages in the evaporator systems can be 
    reduced using condensate segregation. If adequate segregation (as 
    specified in the rule) is performed, only the high-HAP fraction streams 
    from the digester system, turpentine recovery system, and the weak 
    liquor feed stages in the evaporator system and the non-segregated 
    streams from the LVHC and HVLC collection systems must be sent to 
    treatment.
        Discussions with the pulp and paper industry after the March 8, 
    1996 supplemental notice indicated that some mills might not be able to 
    achieve the proposed 65 percent mass isolation with their existing 
    equipment even though they are achieving high levels of HAP removal in 
    the steam stripper system (Air Docket A-92-40, IV-E-84). Therefore, the 
    final rule contains two options for demonstrating compliance with the 
    segregation requirements. The first option is to isolate at least 65 
    percent of the HAP mass in the total of all condensates from the 
    digester system, turpentine recovery system, and the weak liquor feed 
    stages in the evaporator system (condensate streams from the LVHC and 
    HVLC collection systems are not segregated). The second option requires 
    that a minimum total HAP mass from the high HAP concentrated 
    condensates from the digester system, turpentine recovery
    
    [[Page 18523]]
    
    system, and the weak liquor feed stages in the evaporator system and 
    the total LVHC and HVLC collection system condensates be sent to 
    treatment. The second option was included in the final rule because it 
    achieves the same objective by sending a large enough mass to treatment 
    to meet the floor-level control requirements.
        For a detailed explanation of the concept of condensate segregation 
    readers are referred to the docket (Air Docket A-92-40, IV-D1-107).
        d. Clean Condensate Alternative. The proposed rule did not contain 
    any provisions for emissions averaging. Industry comments on the 
    proposal indicated support for incorporating an emission averaging 
    approach in the final rule. After the public comment period, the pulp 
    and paper industry submitted a comparison between an option developed 
    by industry and the proposed MACT standards. The option formed the 
    basis for the clean condensate alternative (CCA) in the final rule. The 
    CCA focuses on reducing HAP emissions throughout the mill by reducing 
    the HAP mass in process water streams that are recycled to various 
    process areas in the mill. By lowering the HAP mass loading in the 
    recycled streams, less HAP will be volatilized to the atmosphere.
        The March 8, 1996 Federal Register supplemental notice presented a 
    discussion of the industry's alternative (referred to as the ``clean 
    water alternative'' in the notice). In the March 8 notice, EPA 
    indicated that while the industry's concept was innovative, additional 
    information would need to be submitted to the Agency to make the 
    concept a viable compliance option, such as specific design parameters 
    and data supporting the relationship between condensate stream HAP 
    concentrations and HAP emissions from process equipment receiving the 
    condensates.
        Design specifications for the CCA were not available since no mills 
    to date have implemented such a technology. However, the test data 
    collected by the pulp and paper industry following the December 17, 
    1993 proposal included data on vent emissions and process water HAP 
    concentrations that were used by industry to develop equations showing 
    the relationship between HAP emissions from specific process equipment 
    (e.g., pulp washers) and the HAP concentrations present in the process 
    water sent to the equipment.
        EPA evaluated these data and concluded that sufficient relationship 
    appears to exist between HAP concentrations in recycled process 
    wastewater and HAP emissions from process equipment, such that the CCA 
    has the potential to achieve or exceed the requirements of the final 
    standards. However, EPA has determined that the correlation equations 
    developed by industry, because they were derived from small data sets, 
    would not be sufficient for demonstrating compliance or equivalency 
    with the final standards at a specific mill. Variability at a specific 
    mill, such as types of process equipment, operating practices, process 
    water recycle practices, and even type of wood pulped, can strongly 
    influence the relationship between concentration in the process water 
    and the process emissions.
        The final rule contains provisions for using the CCA as a 
    compliance option to the kraft pulping standards for the subject 
    equipment in the HVLC system. An owner or operator must demonstrate to 
    the Administrator's satisfaction that the total HAP emissions 
    reductions achieved using the CCA are equal to or greater than the 
    total HAP emission reductions that would have been achieved by 
    compliance with the kraft pulping system standards for equipment in the 
    HVLC system. The baseline HAP emissions for each equipment system and 
    the total of all equipment systems in the CCA affected source (which is 
    the existing MACT affected source expanded to include the causticizing 
    and papermaking systems) must be determined after compliance with the 
    pulping process condensate standards; after consideration of the 
    effects of the effluent limitations guidelines and standards in 40 CFR 
    part 430, subpart B; and after all other applicable requirements of 
    local, State, and Federal agencies or statutes have been implemented. 
    While engineering assessments or test data may be used to determine the 
    feasibility of using the CCA, only test data may be used to demonstrate 
    compliance with the kraft pulping system standards using the CCA.
        e. Biological Treatment. At proposal, owners or operators using a 
    biological treatment system to comply with the MACT requirements for 
    pulping wastewater would have been required to measure the HAP or 
    methanol concentration in the influent and effluent across the unit 
    every 30 days and to identify appropriate parameters to be monitored to 
    ensure continuous compliance. The proposed standards would have 
    required that during the initial performance test, mills collect 
    samples and analyze them using Method 304 to calculate a site-specific 
    biorate constant. That constant, along with the operating parameters 
    associated with the biological treatment system were to be entered into 
    the WATER7 (updated to WATER8 since proposal) emissions model to 
    demonstrate that the biological treatment system could achieve the 
    treatment level required by the standards. Those operating parameters 
    measured during the initial performance test were then to be monitored 
    continuously to demonstrate compliance.
        EPA acknowledged at proposal that industry was collecting 
    information on the performance of biological treatment systems and 
    monitoring techniques. EPA also noted that the industry was 
    investigating the possibility of monitoring inlet and outlet soluble 
    biochemical oxygen demand (BOD5). EPA requested comments on 
    applicable monitoring parameters for biological treatment systems and 
    supporting data on biorates and corresponding parameters for 
    monitoring.
        EPA received a number of comments on testing and monitoring 
    requirements for biological treatment systems. The industry submitted 
    studies on biological treatment systems and on monitoring soluble 
    BOD5. Discussions were also held with the industry 
    representatives on this issue.
        In general, commenters objected to the proposed requirements to use 
    Method 304 to calculate the site-specific biorate constants. Commenters 
    felt that the laboratory-scale simulation of the biological treatment 
    unit, which is basically what Method 304 requires, does not accurately 
    reflect the biological degradation rates of the full-scale system. 
    Commenters also stated that according to data collected, performance 
    testing to demonstrate that biological treatment systems can meet the 
    standards does not appear to be warranted given that methanol is highly 
    biodegradable. Commenters further requested that if they had to conduct 
    a performance test, they should also be permitted to use the inlet and 
    outlet concentration procedures for calculating a site-specific 
    biological degradation rate (biorate) constant as set forth in Appendix 
    C of the Hazardous Organic NESHAP (HON). See 59 FR 19402 (April 22, 
    1994). Commenters also objected to having to demonstrate continuous 
    compliance with the operating parameters, pointing out that a parameter 
    could be exceeded and the biological treatment system could still be 
    meeting the standards.
        Following proposal, industry also submitted data on soluble 
    BOD5 across biological treatment system units. Industry 
    stated that their data indicated that as long as the biological 
    treatment system was achieving at least 80 percent
    
    [[Page 18524]]
    
    removal of soluble BOD5, the biological treatment system was 
    operating properly and that the unit would be meeting the standards. 
    However, industry argued that soluble BOD5 removal should 
    not be a continuous monitoring parameter that if exceeded, would 
    indicate a violation of the standards. Rather, a mill should be allowed 
    to start measuring methanol removal across the system to verify 
    compliance.
        The Agency considered the comments and data received and agrees 
    that the provisions in Appendix C of the HON are an acceptable 
    alternative to Method 304 for calculating site-specific biorate 
    constants. However, EPA disagrees with the commenters on the issue of 
    the need to conduct performance testing. While EPA agrees that methanol 
    degrades more rapidly than many compounds, there are other HAPs present 
    in the condensate streams subject to the standards, and biological 
    treatment systems can vary widely in their operation and performance, 
    depending on their design, maintenance, and even their geographical 
    location. As such, the final regulation retains the proposed 
    requirements for performance testing.
        EPA also became concerned that allowing the use of methanol as a 
    surrogate for total HAP may not be appropriate for this particular 
    treatment technology. Because methanol is one of the most difficult 
    HAPs to remove with a steam stripper (the technology on which the 
    standards are based), even greater removals of total HAP would occur 
    when a steam stripper is used. Thus, methanol is a reasonable surrogate 
    under such conditions. The opposite is true for biological treatment 
    systems, where methanol is one of the easier HAPs to degrade. As such, 
    the final regulation specifies that a total HAP removal (not just 
    methanol) of 92 percent be achieved by biological treatment systems.
        EPA agrees with the commenters that soluble BOD5 is an 
    appropriate monitoring parameter for biological treatment systems. 
    However, EPA disagrees with the commenters on their position regarding 
    the monitoring of soluble BOD5 and operating parameters for 
    demonstrating continuous compliance. After discussion with the industry 
    on this issue, EPA has concluded that soluble BOD5 and 
    operating parameters are the most appropriate means available for 
    monitoring to demonstrate continuous compliance (A-92-40, IV-E-87). EPA 
    understands the concerns raised on this point, and as such the final 
    regulation provides flexibility. The regulation allows mills to 
    establish, through performance testing, their own range of treatment 
    system outlet soluble BOD5 and operating parameter values to 
    monitor. The final rule also allows owners and operators to demonstrate 
    compliance with the standard using the WATER8 model and inlet and 
    outlet samples from each biological treatment system unit when the 
    specified monitoring parameters are outside of the range established 
    during the initial performance test.
    4. Sulfite Standards--Emission Limits for Sulfite Pulping Processes
        In the March 8, 1996 supplemental notice (61 FR 9383), the Agency 
    presented potential changes to the proposed standards for sulfite 
    pulping processes. EPA had proposed that all pulping equipment at 
    kraft, sulfite, soda, and semi-chemical processes must be enclosed and 
    routed to a control device achieving 98 percent reduction in emissions. 
    In the March 8 notice, the Agency proposed that the MACT floor level of 
    control at existing sulfite processes was control of vents from the 
    digester system, evaporator system, and pulp washing system. The MACT 
    floor level of control at new sulfite processes would be control of the 
    equipment systems listed for existing sources, plus weak liquor tanks, 
    strong liquor storage tanks, and acid condensate storage tanks. In the 
    March 8 notice, the Agency discussed in detail its preliminary 
    determination that the sulfite standards should instead apply to the 
    total emissions from specific named vents and to any wastewater 
    emissions associated with air pollution control devices used to comply 
    with the rule. For calcium-based sulfite pulping processes, the new 
    proposed emission limit was 0.65 lb methanol/ODTP and the percent 
    reduction was 92 percent. For ammonium-and magnesium-based sulfite 
    pulping processes, the new proposed emission limit was 1.10 lb 
    methanol/ODTP, and the percent HAP reduction was 87 percent. The Agency 
    developed applicability cutoffs based on methanol because only methanol 
    emissions data were obtained for all of the equipment systems and 
    wastewater streams considered for control at sulfite mills. The test 
    data from sulfite mills also indicated that for the equipment systems 
    tested for other HAPs, methanol comprised the majority of HAP 
    emissions. Therefore, the Agency believes that the maximum control of 
    HAP emissions will be achieved by controlling methanol as a surrogate.
        Several commenters objected that the proposed emission limits were 
    not appropriate because they were based on data that only indicated 
    possible levels of methanol emissions and not a rigorous assessment of 
    emission rates. The commenters contended that the proposed emission 
    limits were derived from limited data which may not be representative 
    of the range of mills in the industry; therefore, they argued, the 
    limits did not account for variability in emissions and are not 
    achievable. The commenters provided the Agency with emissions test data 
    that illustrated fluctuations in the methanol mass emissions over an 
    extended time period due to variations in products and process 
    conditions.
        The Agency evaluated the information provided by the commenters and 
    subsequently agreed with the commenters regarding process variability 
    at sulfite mills. The Agency determined the amount of variability 
    associated with a 99.9 percent confidence level in the data supplied by 
    the commenters (Air Docket A-92-40, IV-B-20). This amount of 
    variability (confidence interval), therefore, was applied to the 
    average emission limits from the best controlled mills to develop the 
    final emission limit.
        For ammonium- and magnesium-based sulfite pulping processes, the 
    final emission limit is 1.1 kilograms of methanol per megagram of ODP 
    produced. After the close of the March 8, 1996, Federal Register 
    supplemental notice comment period, additional information was provided 
    to the Agency that indicated that the sodium-based sulfite pulping 
    process is in use at some mills (A-92-40, IV-E-94). No emissions 
    information was available for this process. However, the Agency 
    determined, that due to the similarities in processes between calcium- 
    and sodium-based sulfite pulping processes, the same limit developed 
    for calcium-based mills would be applicable to sodium-based mills. For 
    calcium- and sodium-based sulfite pulping processes, the final emission 
    limit is 0.44 kilograms of methanol per megagram of ODP produced. 
    Because the variability is incorporated into the mass emission limit, 
    these emission limits and corresponding monitoring parameters are 
    never-to-be-exceeded values.
    5. Soda and Semi-chemical Mill Standards
        The proposed standards would have required the owners or operators 
    of new or existing kraft, semi-chemical, soda, and sulfite mills to 
    comply with the same emission standards. In the March 8, 1996 notice, 
    EPA proposed to subcategorize the pulp and paper industry by pulping 
    type and develop different MACT control requirements for soda and semi-
    chemical mills based
    
    [[Page 18525]]
    
    on emission characteristics. Existing soda and semi-chemical mills 
    would be required to control the digester and evaporator systems (LVHC 
    system). New soda and semi-chemical mills would be required to control 
    the LVHC and the pulp washing systems. EPA solicited comments on this 
    proposed change.
        Information provided by the pulp and paper industry in survey 
    responses and after proposal confirmed that the MACT floor level of 
    control at existing semi-chemical mills is collection and control of 
    the LVHC system. The Agency determined that it was not reasonable to 
    control other emission points at existing semi-chemical mills (Air 
    Docket A-92-40, IV-B-12). Data indicated that the best-controlled semi-
    chemical mills combust LVHC system emissions and emissions from pulp 
    washing systems. Therefore, the final rule requires that existing semi-
    chemical mills control the LVHC system, and new semi-chemical mills 
    control the LVHC and the pulp washing systems.
        As discussed in the March 8, 1996 notice, the MACT floor level of 
    control for soda mills is no control. The Agency has determined that 
    HAP emissions from soda mills are similar to kraft mills (with the 
    exception that TRS compounds are not emitted from the soda pulping 
    process) and control of LVHC system vents is technically feasible and 
    can be achieved at a reasonable cost. The Agency has also determined 
    that controlling additional vents at existing sources cannot be 
    achieved at a reasonable cost. However, controlling the pulp washing 
    system at new soda mills can be achieved at a reasonable cost (Air 
    Docket A-92-40, IV-B-12). Therefore, the final rule requires that 
    existing soda mills control the LVHC system, and new soda mills control 
    the LVHC and the pulp washing system.
    6. Mechanical Pulping Mill, Secondary Fiber Pulping Mill, Non-wood 
    Fiber Pulping Mill, and Papermaking System Standards
        In the March 8, 1996 Federal Register notice, EPA proposed 
    standards for pulping and bleaching processes at mechanical pulping 
    mills, secondary fiber pulping mills, and non-wood fiber pulping mills. 
    As discussed in the proposal, EPA believes that there are no air 
    pollution control technologies in use on these processes except for 
    those installed on bleaching systems using chlorine. The March 8 notice 
    proposed no add-on controls for pulping systems (and the associated 
    wastewater), papermaking systems, and nonchlorine bleaching systems for 
    these mills. For traditional bleaching systems using chlorine, the 
    proposed control was based on the performance of caustic scrubbers. The 
    proposal stated that EPA would continue to investigate the use of HAP 
    chemicals in papermaking, the magnitude of HAP emissions, and the 
    viability of chemical substitution to reduce HAP emissions from 
    papermaking systems.
        Some commenters questioned EPA's proceeding with the rule in 
    advance of the receipt of additional industry data that was being 
    collected. The commenters cautioned that EPA did not have sufficient 
    data on which to base a rule. Since the March 8, 1996 Federal Register 
    proposal, EPA has received the results of the NCASI-sponsored testing 
    program from these sources (A-92-40, IV-J-80 through IV-J-85). These 
    data have been used in the determination of the final standards for 
    these sources in today's rule. EPA has concluded that sufficient data 
    have been collected to include these sources in today's action.
        Commenters agreed with EPA's March 8, 1996 proposal for bleaching 
    systems at these mills. Comments on the March 8 proposal supported the 
    conclusion that caustic scrubbers are in use only on chlorine and 
    chlorine dioxide bleaching systems. Furthermore, information available 
    to EPA indicate that non-wood pulping mills typically use chlorine or 
    chlorine dioxide bleaching systems. For chlorine and chlorine dioxide 
    bleaching systems, EPA determined that scrubbers are used to control 
    chlorinated compound emissions for process and worker safety reasons. 
    Thus, the control achieved by this technology represents the floor for 
    chlorine and chlorine dioxide bleaching systems at these mills and is 
    the technological basis for the standard in today's rule. As stated in 
    the December 17, 1993 proposal, EPA analyzed more stringent controls, 
    such as combustion of bleaching vent gases after caustic scrubbing, for 
    bleaching systems at kraft, soda, and sulfite mills. EPA has determined 
    that these more stringent options are unreasonable considering cost and 
    environmental impacts. Because of the operational similarities of the 
    chlorine and chlorine dioxide bleaching systems at non-wood fiber mills 
    to those at kraft, soda, and sulfite mills, EPA has concluded that 
    combustion following caustic scrubbers is also not cost-effective at 
    non-wood fiber mills. In addition, data available to EPA indicate that 
    HAP emissions from chlorine bleaching systems at these mills are 
    relatively low. In fact, the data show that the three largest non-wood 
    pulping mills, of the ten currently in operation, use elemental 
    chlorine in their bleaching systems and total HAP emissions from each 
    of these three mills is less than five tons of total HAP per year (Air 
    Docket A-95-31, IV-B-5).
        For chlorine and chlorine dioxide bleaching systems at mechanical 
    pulping mills, secondary fiber pulping mills, and non-wood pulping 
    mills, today's rule requires the same level of control required for 
    bleaching systems at kraft, soda, and sulfite mills. Those requirements 
    are specified in Sec. 63.445 (a)-(c) of today's rule. However, 
    Sec. 63.445 (d) and (e) do not apply to these mills since there are no 
    effluent limitation guidelines for control of chloroform at mechanical, 
    secondary fiber, and non-wood fiber pulping mills. Additional 
    requirements for the control of chloroform emissions, based on the 
    effluent limitation guidelines for best available technology 
    economically achievable, are required in the standards for bleaching 
    systems for kraft, soda, and sulfite mills. However, EPA is not aware 
    of any controls presently in place or available for reducing chloroform 
    air emissions at mechanical, secondary fiber, and non-wood pulping 
    mills. Therefore, MACT is no control for chloroform air emissions from 
    bleaching systems at mechanical, secondary fiber, and non-wood fiber 
    pulping mills.
        Since the March 8 proposal, EPA has also determined that while 
    mechanical pulping, secondary fiber pulping, and other non-wood pulping 
    mills do not typically use chlorine or chlorine dioxide bleaching, 
    these mills may brighten the pulp stock through the use of hypochlorite 
    and non-chlorine bleaching compounds. However, data available to EPA 
    indicate that HAP emissions from these systems are relatively low, and 
    that none of the bleaching systems that use hypochlorite and non-
    chlorine compounds have installed emission controls. Based on these 
    findings, EPA established the MACT floor for bleaching systems at these 
    mills that use hypochlorite and non-chlorine bleaching to be no 
    control. EPA considered going beyond the floor and requiring HAP 
    control through incineration of vent streams for these sources but 
    determined that the minimal level of HAP emission reductions that would 
    be achieved did not justify going beyond the floor (Air Docket A-95-31, 
    IV-B-5).
        In the March 8, 1996 Federal Register notice, EPA proposed no 
    standards for papermaking systems. The three potential sources of HAP 
    emissions from papermaking systems are HAPs contained in the pulp 
    stock, HAPs contained in the whitewater, and HAPs from additives and 
    solvents. Information available to EPA indicated no papermaking systems 
    are operating with HAP controls; thus the floor level
    
    [[Page 18526]]
    
    of control for papermaking systems is no control. EPA evaluated two 
    possible control options for papermaking systems: (1) Removal of HAPs 
    from the pulp stock and whitewater before the papermaking system; and 
    (2) control of papermaking system vent streams. Analysis of these 
    control options showed that there are no demonstrated methods for 
    removing HAPs from the pulp stock or whitewater and that applying HAP 
    control to the vent streams of papermaking systems is not cost-
    effective (Air Docket A-95-31, IV-B-8). Therefore, EPA is not requiring 
    HAP control beyond the floor.
        In the March 8, 1996 notice, EPA indicated that it was 
    investigating the use of HAP-containing additives in papermaking 
    systems, the magnitude of HAP emissions resulting from the use of 
    papermaking system additives, and the viability of a MACT standard 
    based on additive substitution. EPA has concluded that based on 
    emission test reports and a survey conducted on additive use, additives 
    do not contribute significantly to HAP emissions (Air Docket A-95-31, 
    Item IV-B-6). The amount of HAPs contained in additives used by the 
    paper industry for papermaking systems is relatively low, an estimated 
    236 tpy in 1995. Furthermore, less than 20 percent of HAPs contained in 
    the additives is emitted to the air. About 80 percent of the HAPs 
    remain on the paper or in the whitewater. Consequently, total annual 
    HAP emissions attributable to additives are an estimated 50 tons per 
    year, industry-wide. In comparison to the baseline emission level of 
    210,000 tons per year of total HAPs from the entire pulp and paper 
    industry, the contribution of HAPs from papermaking system additives is 
    negligible (Air Docket A-95-31, IV-B-6).
        In a meeting between EPA and several representatives of the 
    Chemical Manufacturers Association (CMA), CMA stated that members have 
    been working to reduce HAP and solvent use in papermaking system 
    additives over the past 15 years, even in the absence of regulations. 
    Reductions have been achieved and CMA expects these efforts to 
    continue. CMA noted that HAP-free alternatives may not be possible for 
    all types of additives, as some HAPs are critical to product 
    performance. EPA believes that low-HAP additive substitution is 
    product-specific and it is not clear from the available information 
    that substitution options are technically feasible (Air Docket A-95-31, 
    IV-E-5). Therefore, EPA has concluded that a MACT standard for 
    papermaking systems based on low-HAP additive substitution is not 
    warranted.
        In the March 8, 1996 notice, EPA proposed no standards for pulping 
    systems at mechanical, secondary fiber, or non-wood fiber pulping 
    mills. Information available to EPA indicated that no pulping systems 
    at these mills are operating with HAP controls. Therefore, EPA has 
    concluded that the floor for pulping systems at these mills is no 
    control. EPA evaluated the feasibility of going beyond the floor and 
    requiring HAP controls for these sources. Specifically, EPA 
    investigated the feasibility of routing vent streams from these pulping 
    systems to a combustion device for HAP control. EPA determined that the 
    cost of combusting the vent streams was not justified by the HAP 
    emission reductions achieved, and that requiring HAP control beyond the 
    floor was not justified. Furthermore, pulping chemical usage, which 
    correlates with HAP emission levels at kraft, semi-chemical, soda, and 
    sulfite pulping mills, is much lower at non-wood fiber and secondary 
    fiber pulping mills and minimal at mechanical pulping mills; thus the 
    potential for HAP emissions is lower (Air Docket A-95-31, IV-B-7).
    7. Bleaching System Standards
        In the proposed rule, bleaching systems would have been required to 
    control all HAP emissions by 99 percent using a caustic scrubber. In 
    the March 8, 1996 supplemental notice, the Agency revised the proposal 
    for the bleaching system requirements based on information and comments 
    received after proposal. The new data indicated that caustic scrubbing 
    reduces emissions of chlorinated HAP compounds (except chloroform), but 
    does not control non-chlorinated HAP emissions. The Agency determined 
    that no other option was feasible to control non-chlorinated HAPs. EPA 
    has determined that reduction of chloroform emissions through the use 
    of additional, add-on air pollution control technology is cost 
    prohibitive. The only feasible option for controlling chloroform 
    emissions is process modification, such as chlorine dioxide 
    substitution and elimination of hypochlorite use.
        In the March 8 notice, the Agency proposed to require chlorinated 
    HAP emissions other than chloroform to be controlled by 99 percent 
    (with chlorine as a surrogate for chlorinated HAP) based on the 
    performance of a caustic scrubber. As an alternative to the percent 
    reduction standard, the Agency also proposed an emission limit of 10 
    ppmv chlorinated HAP at the caustic scrubber outlet (with chlorine as a 
    surrogate for chlorinated HAP). The Agency also solicited comments on 
    providing a mass emission limit alternative to the percent reduction 
    and the outlet concentration standards.
        Commenters on the March 8, 1996 notice supported the changes to the 
    scrubber requirements in the proposed rule. Commenters also expressed 
    concern that bleaching systems with new low-flow vent systems would not 
    be able to meet either the percent reduction or the outlet 
    concentration standards. Therefore, they asserted, these standards 
    would discourage the use of new low-flow bleaching vent technologies. 
    Based on this concern, one commenter advocated a chlorinated HAP mass 
    emission limit for bleaching systems of 0.023 lb of chlorinated HAP 
    (excluding chloroform) per ODTP produced. The commenter claimed that a 
    mass emission limit would not penalize new low-flow bleaching vent 
    systems.
        Based on available data, the Agency has concluded that low-flow 
    bleaching vent systems can achieve the 99 percent reduction and the 10 
    ppmv outlet concentration requirements for total chlorinated HAP (other 
    than chloroform). Based on a review of the information provided by the 
    commenter and the available data on bleaching system emissions, the 
    Agency has concluded that the commenter's recommended mass emission 
    limit of 0.023 lb of chlorinated HAP (excluding chloroform) per ODTP 
    produced is too high. The Agency evaluated the available data used to 
    develop the percent reduction and outlet concentration requirements for 
    bleaching systems (A-92-40, II-I-24). From this evaluation, the Agency 
    determined that a scrubber outlet mass emission rate of 0.001 kg of 
    total chlorinated HAP (other than chloroform) per Mg ODP produced 
    (0.002 lb/ODTP) would provide reductions equivalent to 99 percent 
    reduction standard (A-92-40, IV-B-29). The mass emission limit of 0.001 
    kg of chlorinated HAP (other than chloroform) per Mg ODP produced 
    represents a mass emission limit achievable by all units that also 
    achieved 99 percent reduction of chlorine. Furthermore, the available 
    data show that some of the scrubbers achieving the 99 percent chlorine 
    reduction standard, and the 10 ppmv outlet concentration limit, were 
    also operating on low-flow bleaching vent systems.
        For the final rule, the Agency has provided a mass emission limit 
    option for bleaching systems of 0.001 kg of chlorinated HAP (excluding 
    chloroform) per Mg ODP produced (0.002 lb/ODTP). The Agency maintains 
    that this option
    
    [[Page 18527]]
    
    allows more flexibility for sources affected by this rule, does not 
    penalize bleaching systems operating with low-flow technology, and will 
    provide reductions in chlorinated HAP emissions (other than chloroform) 
    equivalent to the 99 percent reduction standard. Therefore, the final 
    rule allows sources to comply with the bleaching system requirements if 
    they achieve an scrubber outlet mass emission limit at or below 0.001 
    kg of total chlorinated HAP (other than chloroform) per Mg ODP 
    produced. Chlorine may be used as a surrogate for measuring total 
    chlorinated HAP.
        After proposal, the Agency also evaluated the effect of process 
    modifications on chloroform emissions. The results of this analysis 
    indicated that the technology basis for MACT control of chloroform is 
    complete chlorine dioxide substitution and elimination of hypochlorite 
    as a bleaching agent. These process modifications were determined to 
    reduce chloroform emissions significantly. At the same time, EPA was 
    proposing complete chlorine dioxide substitution and hypochlorite 
    elimination as the technology bases for the effluent limitations 
    guidelines and standards under Subparts B and E (see 58 FR at 66109-11, 
    14-15). Since the control technologies that would be installed to 
    comply with effluent limitations guidelines and standards and MACT 
    would likely be the same for these bleached papergrade mills, EPA 
    therefore proposed in the March 8 notice that chloroform air emissions 
    at bleached papergrade mills be controlled by complying with the 
    effluent limitations guidelines and standards applicable to those 
    mills. No adverse comments were received on this proposal.
        In the March 8, 1996 notice, the Agency solicited comments on 
    whether an alternative numerical air emission limit for chloroform 
    (i.e., besides complying with the effluent limitations guidelines and 
    standards) was needed. Some commenters contended that a numerical air 
    emissions limit for chloroform would be unnecessary because the 
    effluent limitations guidelines and standards would achieve the 
    requisite reductions. The Agency did not receive any indication of any 
    benefit from a numerical air emission limit for chloroform. 
    Additionally, the Agency did not have sufficient data and did not 
    receive any further data after the March 8 notice to develop a 
    numerical air emission limit (and hence is finding that a numerical 
    standard is not feasible for purposes of CAA Sec. 112(h)). Therefore, 
    the final rule does not include a numerical air emission limit for 
    chloroform (see the proposal at 58 FR 66142 for a discussion on setting 
    MACT standards in a format other than an emission standard). The Agency 
    is, however, providing an alternative compliance mechanism in the form 
    of a work practice standard of complete substitution of chlorine 
    dioxide for elemental chlorine and complete hypochlorite elimination--
    the technical basis for BAT. (EPA also notes that although the Agency's 
    technical judgment is that compliance with BAT also will result in 
    control of air emissions to reflect the MACT level of control, the 
    Agency will continue to investigate whether this proves correct as the 
    rule is implemented.)
        Because MACT for new sources is equivalent to MACT for existing 
    sources, the new source MACT standards for bleaching systems require 
    compliance with BAT/PSES requirements (or implementation of 100 percent 
    substitution and elimination of hypochlorite). This requirement applies 
    even if the mill or bleaching system also meets the definition of new 
    source under the effluent guidelines limitations and standards, and 
    thus is required to meet the more stringent new source effluent 
    requirements of NSPS/PSNS. Although achievement of the NSPS/PSNS may 
    result in installation of technologies that reduce effluent loading 
    beyond what is achieved by 100 percent substitution and elimination of 
    hypochlorite, EPA is not aware that these advanced technologies will 
    provide air emission reductions beyond what the BAT/PSES requirements 
    will achieve.
        EPA notes that an affected bleached papergrade mill must comply 
    with the existing source MACT requirements no later than April 16, 2001 
    even if the mill's existing Clean Water Act NPDES permit does not yet 
    reflect the corresponding effluent limitations guidelines and standards 
    because its existing terms have not expired or it has been 
    administratively extended. Put another way, even if a mill's existing 
    NPDES permit serves as a shield (until reissuance) against imposition 
    of new limits based on new effluent limitations guidelines (see CWA 
    Section 402(k)), the MACT requirement for bleached papergrade mills to 
    control chloroform emissions through compliance with all parameter 
    requirements in the effluent limitations guidelines and standards takes 
    effect to satisfy the requirements of the Clean Air Act. Similarly, if 
    a bleached papergrade mill's NPDES permit is reissued sooner than the 
    expiration of the 3-year compliance schedule authorized for the 
    chloroform MACT requirements and calls for immediate compliance with 
    the BAT limitations, that deadline would prevail. The same principles 
    will apply when effluent limitations guidelines and MACT standards are 
    promulgated for dissolving grade mills. EPA's plans for promulgating 
    MACT standards for these mills are discussed immediately below.
        An additional issue relating to compliance dates concerns bleaching 
    systems at existing source papergrade kraft and soda mills which have 
    elected, under the Clean Water Act portion of this rule, to treat 
    wastewater to levels surpassing baseline BAT requirements (such as 
    adding oxygen delignification prior to bleaching, and in some cases, 
    engaging in additional reduction of process wastewater and further 
    reductions in chlorinated bleaching chemicals used and bleaching system 
    modifications than are necessary to meet BAT baseline limitations). As 
    an incentive to make this election, EPA is not requiring participating 
    mills to achieve compliance with the more stringent portions of the 
    ``Advanced Technology'' BAT limitations for six, eleven, and sixteen 
    years (for Tiers I, II, and III, respectively) in order to afford these 
    mills sufficient time to develop, finance, and install the Advanced 
    Technologies. In light of this, the Agency is concerned that requiring 
    bleached papergrade kraft and soda mills to comply in three years with 
    MACT standards based on process substitution of chlorine dioxide for 
    elemental chlorine would discourage these mills from electing to 
    participate in the Advanced Technology program. This is largely because 
    a mill that implements process substitution before it installs oxygen 
    or other extended delignification systems is likely to construct more 
    chlorine dioxide generating capacity than it ultimately will need. A 
    mill thus compelled to invest first in process substitution may be very 
    reluctant to abandon a portion of that investment soon afterwards in 
    order to participate in the voluntary incentives program.
        EPA also believes that requiring compliance in three years with a 
    chloroform MACT standard based on baseline BAT for bleached papergrade 
    kraft and soda mills would present similar disincentives to achieving 
    greater effluent reductions. A mill in those circumstances will have 
    made a substantially larger capital investment than it will need to 
    control chloroform once its array of advanced water technologies is 
    installed. Also, depending on the degree of process modifications the 
    mill makes, the mill may need a much smaller scrubber for
    
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    the non-chloroform chlorinated HAPs and, in some cases, a scrubber may 
    not be needed at all to meet the MACT standards for chlorinated HAP 
    concentration limit. Thus, a mill otherwise interested in participating 
    in the Voluntary Advanced Technology Incentives Program will find 
    itself diverting capital to environmental controls that it ultimately 
    will not need, instead of employing that capital to make more advanced 
    process modifications that will benefit both the water and the air.
        Under these unusual circumstances where imposition of MACT 
    requirements could likely result in foregoing substantial cross-media 
    environmental benefits, EPA believes that a two-stage MACT compliance 
    scheme is justified for existing sources at bleached papergrade kraft 
    and soda mills that enroll in the water Voluntary Advanced Technology 
    Incentives Program (see 61 FR 9394 for a similar argument relating to 
    compliance with MACT for washers and oxygen delignification systems). 
    The first stage is an interim MACT of no backsliding--which reflects 
    the current level of air emissions control. The second stage requires 
    compliance with revised MACT based on baseline BAT requirements for all 
    parameters for bleached papergrade kraft and soda mills. (The second 
    stage in effect revises MACT to reflect the control technologies which 
    will be available at this later date. See CAA Sec. 112 (d)(6).) The no-
    backsliding provisions apply to the period from June 15, 1998 until 
    compliance with the second-stage MACT standards is required April 15, 
    2004. This two-step alternative is available only to bleached 
    papergrade kraft and soda mills actually making the binding decision to 
    comply with Tier I, II, or III water limitations.
        EPA believes that providing these mills six years to comply with 
    second-stage MACT (i.e., baseline BAT requirements for all parameters) 
    is an appropriate and logical outgrowth of the discussions set forth in 
    the March 8, 1996 supplemental MACT notice (61 FR 9393) and the July 
    15, 1996 supplemental effluent guidelines notice (61 FR 36835-58). In 
    the March 8 notice, EPA solicited comments on its preliminary findings 
    that MACT for chloroform air emissions should be compliance with 
    baseline BAT. Commenters agreed with this preliminary determination. In 
    the July 15 notice, EPA set forth its vision of more stringent BAT for 
    mills that voluntarily enter the Advanced Technologies Incentives 
    program. As part of that voluntary program under the water standards, 
    EPA is promulgating a requirement that mills in Tiers II and III, at a 
    minimum, meet all the limitations promulgated as baseline BAT no later 
    than April 15, 2004. See Section IX.A. Thus, more stringent air 
    emission controls than stage one MACT will likewise be available at 
    this time since compliance with these interim BAT limitations will 
    result in compliance with MACT. For Tier II and Tier III mills, this 
    means that the second stage MACT requirement is compliance with the 
    baseline BAT limitations by April 15, 2004. The same is the case for 
    Tier I mills, even though under the water regulation Tier I mills will 
    be required to achieve more stringent limitations at that time. EPA is 
    defining MACT to be the baseline BAT limitations even in this situation 
    because compliance with the more stringent AOX limitations and other 
    requirements unique to Tier I are unnecessary to control chloroform 
    emissions at these mills.
        EPA further believes that most plants likely to elect to comply 
    with a tier option already control air emissions of chlorinated HAPs 
    (both chloroform and other chlorinated HAPs) through application of the 
    MACT technologies (process substitution for chloroform and caustic 
    scrubbing for the remaining chlorinated HAPs). Thus, there will be some 
    control of the emissions from these bleaching operations during the 
    time preceding compliance with the second stage of MACT. To ensure that 
    there is no lessening of existing controls, EPA also is promulgating a 
    no backsliding requirement as an interim MACT--reflecting current 
    control levels. During the extended compliance period, mills thus may 
    not increase their application rates of chlorine or hypochlorite above 
    the average rates determined for the three-month period prior to June 
    15, 1998.
        In the March 8 notice, the Agency proposed making a distinction 
    between requirements for bleaching systems at papergrade and dissolving 
    grade mills. The Agency solicited data concerning chloroform emissions 
    from dissolving grade bleaching processes and requested comment on an 
    appropriate chloroform MACT for dissolving grade bleaching systems. 
    Several commenters suggested that a separate MACT standard for 
    chloroform be developed for bleaching systems at dissolving grade 
    mills. Some commenters requested that the Agency defer chloroform 
    control requirements for dissolving grade mills until effluent 
    limitations guidelines and standards are established at those mills.
        As stated in the July 15, 1996 Federal Register notice (61 FR 
    36835), EPA is evaluating new data on the technical feasibility of 
    reducing hypochlorite usage and implementing high levels of chlorine 
    dioxide substitution on a range of dissolving grade pulp products. 
    Therefore, EPA is deferring issuing effluent limitations guidelines and 
    standards for dissolving grade mills until the comments and data can be 
    fully evaluated. EPA expects to promulgate final effluent limitations 
    guidelines and standards for dissolving grade subcategories at a later 
    date.
        EPA has decided to delay establishing these MACT standards for 
    chloroform and for other chlorinated HAPs for dissolving grade 
    bleaching operations until promulgation of effluent limitations 
    guidelines and standards for those operations, for the following 
    reasons. With respect to the MACT standard for chloroform, first, as 
    explained above and in the March 8 notice, the control technology basis 
    for the effluent limitations guidelines and standards and the MACT 
    requirements will be the same. Second, at present, the Agency is unsure 
    what level of chlorine substitution and hypochlorite use is achievable 
    for dissolving grade mills. Thus, although EPA has a reasonably good 
    idea what the technology basis of MACT and effluent limitations 
    guidelines and standards is likely to be for dissolving grade mills, 
    the precise level of the standards remains to be determined. 
    Consequently, at present, EPA is unable to establish what the MACT 
    floor would be for chloroform emissions from bleaching systems at these 
    mills, and there is no conceivable beyond-the-floor technology to 
    consider. EPA will make these determinations based on data being 
    developed, and then promulgate for these mills effluent limitations 
    guidelines and standards and, concurrently, MACT standards based on 
    those effluent limitations guidelines and standards. Covered mills 
    would therefore be required to comply with the MACT standards 
    reflecting performance of the effluent limitations guidelines and 
    standards no later than three years after the effective date of those 
    standards, pursuant to CAA section 112(i)(3)(A).
        The basis for delaying MACT requirements for chlorinated HAPs other 
    than chloroform (again, from dissolving-grade bleach operations only) 
    differs somewhat. As noted above, the technology basis for control of 
    these HAPs is use of a caustic scrubber. However, when plants 
    substitute chlorine dioxide for chlorine and eliminate hypochlorite (in 
    order to control chloroform emissions and discharges to water, as 
    explained above), a different scrubber will be needed that can 
    adequately control both the chlorine dioxide emissions for
    
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    worker safety reasons and the emissions of chlorinated, non-chloroform 
    HAPs. The Agency's concern (shared by the commenters who addressed this 
    question) is that immediate control of the non-chloroform chlorinated 
    HAPs could easily result in plants having to install and then replace a 
    caustic scrubber system in a few years due to promulgation of effluent 
    limitations guidelines and standards and MACT requirements for 
    chloroform. This result would be an inappropriate utilization of scarce 
    pollution control resources.
    8. Test Methods
        At proposal, the Agency proposed to require that Methods 308 and 
    26A be used to test for compliance with the provisions of the NESHAP. 
    Method 308 is used to measure methanol in the vent stream. Method 308 
    had not been validated using Method 301 at the time the NESHAP was 
    proposed. Method 26A is used to measure chlorine in vent streams.
        At proposal, commenters objected to the rule referencing an 
    unvalidated test method (Method 308). The commenters also contended 
    that Method 26A should not be used for measuring chlorine in the 
    bleaching system because chlorine dioxide, which is expected to be 
    present in bleaching system vents, is listed as a possible interferant 
    in Method 26A. The commenters suggested using a modified Method 26A 
    developed by the pulp and paper industry.
        Since proposal, Method 308 was revised to incorporate suggestions 
    made and data provided by representatives of the pulp and paper 
    industry.
        Since proposal, Method 308 has also been validated using Method 301 
    validation criteria. The validation was conducted by the Atmospheric 
    Research and Environmental Analysis Laboratory in EPA's Office of 
    Research and Development. The results of the validation were reported 
    in the January 1995 issue of the Journal of the Air and Waste 
    Management Association. The Agency has also evaluated the commenters' 
    claims regarding Method 26A. The Agency agrees that chlorine dioxide is 
    a potential positive interferant to the method (i.e., concentration 
    measurement could potentially be higher than actual emissions). The 
    final rule includes modifications to Method 26A (based on an NCASI 
    method) to eliminate potential problems with chlorine dioxide 
    interference.
        In March 1997, industry informed EPA that it had not used Method 
    305 to obtain the methanol steam stripper performance data (which was 
    used as the basis for the proposed pulping process condensate 
    standards). For the liquid sampling analysis, NCASI used a direct 
    aqueous injection gas chromatography/flame ionization detection (GC/
    FID) method described in NCASI Technical Bulletin No. 684, Appendix I. 
    Consequently, the industry contends that Method 305 should not be 
    specified in the final rule for determining compliance with the pulping 
    process condensate standards. However, the NCASI test method has not 
    been validated using EPA Method 301 procedures and it is unlikely that 
    the test method validation would be completed before promulgation of 
    the MACT standard.
        The Agency has considered industry's argument and has decided to 
    proceed with specifying Method 305 in the final rule to demonstrate 
    compliance with the pulping process condensate standards. However, if 
    the Agency approves the Method 301 validation procedures for NCASI's 
    GC/FID test method, this method will be referenced as either an 
    alternative or a replacement for Method 305 (for determining methanol 
    concentration only) with a supplemental Federal Register notice. EPA 
    believes that this course of action will adequately address the 
    industry's concerns. This decision was reached since the Method 301 
    validation procedures for NCASI's GC/FID method would likely be 
    completed before kraft mills would have to demonstrate compliance with 
    the pulping process condensate standards.
    9. Backup Control Devices and Downtime
        The proposal would have required emission limits for the NESHAP to 
    be met at all times, except during periods of startup, shutdown, or 
    malfunction. Allowance for control device or collection system downtime 
    was not specified in the proposed rule, and the need for backup control 
    devices was not addressed.
        Commenters asserted that EPA should recognize that control 
    technologies on which the proposed rule was based are not designed to 
    operate 100 percent of the time. Therefore, commenters requested 
    downtime allowances to account for safety related venting and periods 
    when the control device is inoperable. Otherwise, the commenters 
    asserted that costly backup control devices would be necessary to 
    achieve compliance with the NESHAP at all times. They further contended 
    that the environmental benefit for the additional cost associated with 
    the backup controls would be minimal. Commenters recommended a one 
    percent downtime for the LVHC system, four percent for the HVLC system, 
    and ten percent for steam stripper systems. Commenters contended that 
    while most of the LVHC systems had backup controls, very few of the 
    HVLC systems had backup controls. Several commenters added that the 
    Part 63 General Provisions do not address safety venting and downtime 
    necessary for trouble-shooting. Another commenter contended that the 
    Part 63 General Provisions already allow significant emissions and 
    should not be further weakened.
        Since proposal, EPA has re-evaluated the need to incorporate 
    downtime or excess emission allowances for LVHC, HVLC, and steam 
    stripper systems into the final rule. Based on data submitted by the 
    pulp and paper industry, EPA has concluded that some allowance for 
    excess emissions is part of the MACT floor level of control. For the 
    final rule, EPA established appropriate excess emission allowances to 
    approximate the level of backup control that exists at the best-
    performing mills and the associated period of time during which no 
    control device is available. The excess emission allowances in the 
    final rule include periods when the control device is inoperable and 
    when the operating parameter values established during the initial 
    performance test cannot be maintained at the appropriate level.
        Based on an analysis of the public comments and the available data 
    regarding excess emissions and the level of backup control in the 
    industry, EPA has determined that an appropriate excess emissions 
    allowance for LVHC systems would be one percent of the operating hours 
    on a semi-annual basis for the control devices used to reduce HAP 
    emissions. The best-performing mills achieve a one percent downtime in 
    their LVHC system control devices. For control devices used to reduce 
    emissions from HVLC systems, EPA has concluded that an appropriate 
    excess emissions allowance would be four percent. The best-performing 
    mills achieve a four percent downtime in the control devices used to 
    reduce emissions from their HVLC system to account for flow balancing 
    problems and unpredictable pressure changes inherent in HVLC systems. 
    For control devices used to control emissions from both LVHC and HVLC 
    systems, the Agency has determined that a four percent excess emissions 
    allowance is appropriate. This decision was made because the control 
    device would be used for the HVLC system, which has the higher 
    emissions allowance. For LVHC and HVLC system control devices, the 
    excess emissions allowances do not include scheduled
    
    [[Page 18530]]
    
    maintenance activities that are discussed in the Part 63 General 
    Provisions. The allowances address normal operating variations in the 
    LVHC and HVLC system control devices for which the equipment is 
    designed. The variations would not be considered startup, shutdown, or 
    malfunction under the Part 63 General Provisions (Air Docket A-92-40, 
    IV-D1-103, IV-D1-110, IV-D1-115, IV-E-85, and IV-E-88).
        The appropriate excess emissions allowance for steam stripper 
    systems was determined to be 10 percent. The allowance accounts for 
    stripper tray damage or plugging, efficiency losses in the stripper due 
    to contamination of condensate with fiber or black liquor, steam supply 
    downtime, and combustion control device downtime. This downtime 
    allowance includes all periods when the stripper systems are inoperable 
    including scheduled maintenance, malfunctions, startups, and shutdowns. 
    The startup, shutdown, malfunction allowances are included in the 
    stripper allowances because information was not available to 
    differentiate these emissions from normal stripper operating emissions.
        Regarding the commenters' discussion of whether the startup, 
    shutdown, or malfunction provisions of the General Provisions would 
    cover maintenance and troubleshooting downtime, EPA has taken public 
    comment and is currently revising the requirements of the General 
    Provisions. Among the changes to the language, EPA intends to 
    incorporate safety-related venting requirements into the General 
    Provisions. However, scheduled maintenance activities are not 
    considered by EPA to qualify for excess emissions allowances. The 
    start-up, shutdown, and malfunction plan specified in the General 
    Provisions should address the periods of excess emissions that are 
    caused by unforeseen or unexpected events.
    10. Equipment Enclosures, Closed-Vent Systems, and Control Equipment, 
    and Condensate Conveyance System
        a. Requirements for Closed-Vent Systems. At proposal, the Agency 
    required specific standards and monitoring requirements for closed-vent 
    systems. The standards required: (1) Maintaining a negative pressure at 
    each opening, (2) ensuring enclosure openings that were closed during 
    the performance test be closed during normal operation, (3) designing 
    and operating closed-vent systems to have no detectable leaks, (4) 
    installing flow indicators for bypass lines, and (5) securing bypass 
    line valves. Monitoring requirements included visual inspections of 
    seal/closure mechanisms and closed-vent systems, and demonstrations of 
    no detectable leaks in the closed-vent system.
        Commenters to the proposed NESHAP contended that visual inspections 
    were not necessary due to durability of the materials used by this 
    industry to construct the collection system. In addition, commenters 
    contended that leak detections were not necessary since systems are 
    typically operated at negative pressure. The commenters also opposed 
    requirements for seals and locks on bypass lines because the bypass 
    lines are installed for purposes of personnel safety, equipment 
    protection, and to prevent explosions.
        The Agency evaluated the comments and has decided to make the 
    following changes to the closed-vent system requirements. The Agency 
    agreed with the commenters that most closed-vent systems will be under 
    negative pressure. Any leaks, therefore, would pull air into the 
    collection system rather than release HAPs to the atmosphere. 
    Therefore, the Agency revised the requirement for demonstration of no 
    detectable emissions to apply only to portions of the closed-vent 
    system operated under positive pressure. The Agency also agreed that 
    requiring a lock and key-type seal on bypass lines would be 
    overburdensome and could potentially pose a safety hazard. The 
    intention of the requirements was to prevent circumvention of the 
    control device by venting directly to the atmosphere. The Agency 
    believes that this assurance can be achieved using car seals or seals 
    that could easily be broken, to indicate when a valve has been turned. 
    Proper recordkeeping is also necessary to demonstrate proper operation. 
    Therefore, the Agency revised the bypass line requirements to allow the 
    use of car seals but require log entries recording valve position, flow 
    rate, and other parameters. The Agency has modified the enclosure 
    requirements to allow for short-term openings for pulp sampling and 
    maintenance.
        The final rule retains the visual monitoring requirements. The 
    requirements are necessary to ensure proper operation of collection 
    systems and can be conducted at a reasonable cost.
        b. Concentration Limit for Combustion Devices and Design 
    Incinerator Operating Parameters. At proposal, the NESHAP would have 
    required vent streams to be controlled in a combustion device that 
    achieves 98 percent reduction of HAPs or outlet HAP emission 
    concentrations of 20 ppmv corrected to three percent oxygen. 
    Alternatively, mills could comply with the control requirements by 
    routing vent streams to a design incinerator operating at 1,600  deg.F 
    and a residence time of 0.75 seconds, or to a boiler, lime kiln, or 
    recovery furnace.
        Commenters on the proposed rule objected to the 20 ppmv limit at a 
    three percent oxygen correction factor. Some commenters claimed that 
    incinerator exhaust streams in the pulp and paper industry have an 
    oxygen content in excess of 10 percent. Therefore, if the outlet 
    concentration was corrected to three percent oxygen, the concentration 
    level would not be achievable. Some commenters recommended increasing 
    the correction factor to 10 percent oxygen.
        The 20 ppmv limit represents the performance that is achieved on 
    low concentration streams by a well designed combustion device. This 
    limit was based on previous EPA studies (Air Docket A-79-32, II-B-31). 
    The three percent oxygen correction factor at proposal was based on 
    stream characteristics of other industries, such as the synthetic 
    organic chemical manufacturing industry. The three percent correction 
    factor has been used on many previous standards for controlling organic 
    pollutants. EPA re-evaluated the three percent correction factor to 
    ensure that it is appropriate for the pulp and paper industry. Test 
    data supplied by the industry confirmed their comments that the oxygen 
    content of the incinerator flue gas is typically greater than ten 
    percent at pulp and paper mills. Based on the industry data and the 
    thermodynamic models, EPA changed the oxygen correction factor to ten 
    percent (Air Docket A-92-40, IV-B-19). Therefore, the final rule allows 
    combustion devices to be in compliance if they reduce HAP 
    concentrations to 20 ppmv at ten percent oxygen. Information supplied 
    by the pulp and paper industry indicates that many of the existing 
    incinerators meet this limit.
        Commenters on the proposed rule objected that the requirements for 
    the design incinerator were too stringent and that equivalent control 
    could be achieved at lower temperatures. Many commenters requested that 
    the Agency allow incinerators meeting the operating conditions in the 
    kraft NSPS of 1,200 oF and 0.5 seconds residence time to be 
    used for the NESHAP.
        EPA has decided not to change the proposed design incinerator 
    operating parameters for the NESHAP because the parameters are 
    necessary to meet the MACT floor. EPA would first like to clarify that 
    the final rule does not limit owners or operators of incinerators to 
    operate at the specified temperatures and residence times. Any control 
    device
    
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    that is demonstrated to achieve 98 percent destruction of HAPs will 
    comply with the rule. Any thermal oxidizer which reduces HAP emissions 
    to a concentration of 20 ppmv at ten percent oxygen will also comply 
    with the rule. The 98 percent destruction requirement represents the 
    control level achieved by well-operated combustion devices. The 20 ppmv 
    limit represents the performance achieved by well-operated combustion 
    devices on low concentration vent streams.
        Second, EPA has made this part of the rule as flexible as possible 
    while still achieving a level of control reflecting MACT. In the 
    December 17, 1993 proposal and in this final rule, EPA developed 
    compliance alternatives in order to reduce the compliance testing 
    burden. The compliance alternatives (i.e., operating thermal oxidizers 
    at a temperature of 1,600  deg.F and a residence time of 0.75 seconds) 
    were developed to ensure that the thermal oxidizers perform at a level 
    that would meet the destruction efficiency requirements. The operating 
    parameters are based on previous Agency studies that show that these 
    conditions are necessary to achieve 98 percent destruction of HAPs. 
    However, the NSPS operating parameters (1,200  deg.F and 0.5 seconds 
    residence time) do not destroy HAPs to this extent.
        The purpose of the kraft NSPS was to reduce emissions of TRS 
    compounds. EPA has evaluated the temperature and residence time 
    required by the NSPS to determine whether the NSPS temperature and 
    residence time are sufficient to achieve 98 percent reduction of HAPs. 
    EPA's analysis indicates that while the NSPS requirements are 
    sufficient to achieve 98 percent destruction of TRS compounds, kinetic 
    calculations for methanol (the majority of HAP in pulping vent gases) 
    show that the NSPS criteria will not achieve 98 percent reduction of 
    HAPs (Air Docket A-92-40, IV-B-18). Additionally, EPA evaluated 
    incinerator performance data submitted by industry (Air Docket A-92-40, 
    IV-J-33). The data indicated that the NSPS operating parameters were 
    not sufficient for achieving 98 percent destruction of methanol. This 
    conclusion was reached by EPA since the operating conditions (i.e., 
    temperature and residence time) of the incinerators that achieved 98 
    percent methanol destruction were greater than the levels specified in 
    the kraft NSPS. Therefore, the NSPS specifications will not meet the 
    requirements of MACT for new and existing sources.
        c. Condensate Collection System. In the December 17, 1993 proposal, 
    EPA proposed to require pulping process condensate collection systems 
    to be designed and operated without leaks. EPA proposed that all tanks, 
    containers, and surface impoundments storing applicable condensate 
    streams were required to be enclosed and all vent emissions must be 
    routed to a control device by means of a closed-vent system. A 
    submerged fill pipe would have been required on containers and tanks 
    storing an applicable condensate stream or any stream containing HAP 
    removed from a condensate stream. All drain systems that received or 
    managed applicable condensate streams would have been required to be 
    enclosed with no detectable leaks and any HAP emissions from vents were 
    required to be routed to a control device. Several commenters on the 
    proposed pulp and paper NESHAP contended that the proposed requirements 
    were overly burdensome and, in some cases, unnecessary.
        After the pulp and paper NESHAP was proposed, the Agency 
    promulgated a separate rulemaking in 40 CFR Part 63, Subpart RR 
    (National Emission Standards for Individual Drain Systems). This rule 
    established emission control, inspection and monitoring, and 
    recordkeeping and reporting requirements for individual drain systems. 
    The individual drain system requirements specify that air emissions 
    from collection systems must be controlled using covers or seals, hard-
    piping, or venting of individual drain systems through a closed-vent 
    system to a control device or a combination of these control options. 
    The emission control techniques specified in the individual drain 
    system standard (i.e., covers/seals and vent combustion) are common 
    techniques that are applicable to a variety of wastewater collection 
    systems, regardless of the type of process that produced the wastewater 
    streams.
        EPA compared the collection system requirements contained in the 
    proposed pulp and paper NESHAP with the individual drain system 
    requirements in subpart RR. Since the subpart RR requirements are 
    consistent with the intent of the proposed standards, EPA concluded 
    that the requirements of subpart RR constitute MACT for the pulp and 
    paper industry. The control costs presented in the ``Pulp, Paper, and 
    Paperboard Industry-Background Information for Promulgated Air Emission 
    Standards, Manufacturing Processes at Kraft, Sulfite, Soda, Semi-
    Chemical, Mechanical, and Secondary and Non-wood Fiber Mills, Final 
    EIS''(EPA-453/R-93-050b) were based on industry estimates for hard-
    piping systems. The Agency has concluded that these costs would be the 
    same or greater than would be needed for complying with the 
    requirements of subpart RR.
        The final pulp and paper NESHAP references 40 CFR Subpart RR for 
    the standards for individual drain systems for the pulping process 
    condensate closed collection system. The Subpart RR standards provide 
    uniform language that simplifies compliance and enforcement.
        The final rule requires tanks to be controlled as at proposal, but 
    containers and surface impoundments are not required to be controlled. 
    Public comments indicated that containers are not used in the pulp and 
    paper industry. The Agency's intention in the proposed rule was not to 
    require surface impoundments to be controlled, except when used as part 
    of the condensate collection system. After further review of this 
    issue, the Agency has determined that mills do not use and are unlikely 
    to use surface impoundments as part of their closed collection system 
    for condensate streams and therefore that the language on control of 
    surface impoundments does not need to appear in the rule.
    11. Interaction With Other Rules
        a. Prevention of Significant Deterioration/New Source Review (PSD/
    NSR). To comply with the MACT portion of the pulp and paper cluster 
    rule, mills will route vent gases from specified pulping and condensate 
    emission points to a combustion control device for destruction. The 
    incineration of these gases at kraft mills has the potential to 
    generate sulfur dioxide (SO2) and, to a lesser degree, 
    nitrogen oxides (NOX). The emission increases of 
    SO2 and NOX may be of such magnitude to trigger 
    the need for preconstruction permits under the nonattainment NSR or PSD 
    program (hereinafter referred to as major NSR).
        Industry and some States have commented extensively that in 
    developing the rule, EPA did not take into account the impacts that 
    would be incurred in triggering major NSR. Commenters indicated that 
    major NSR would: (1) Cost the pulp and paper industry significantly 
    more for permitting and implementation of additional SO2 or 
    NOX controls than predicted by EPA; (2) impose a large 
    permitting review burden on State air quality offices; and (3) present 
    difficulties for mills to meet the proposed NESHAP compliance schedule 
    of 3 years due to the time required to obtain a preconstruction permit. 
    Industry commenters have stated that the pollution control project
    
    [[Page 18532]]
    
    (PCP) exemption allowed under the current PSD policy provides 
    inadequate relief from these potential impacts and recommended 
    including specific language in the pulp and paper rule exempting MACT 
    compliance projects from NSR/PSD.
        In a July 1, 1994 guidance memorandum issued by EPA (available on 
    the Technology Transfer Network; see ``Pollution Control Projects and 
    New Source Review (NSR) Applicability'' from John S. Seitz, Director, 
    OAQPS to EPA Regional Air Division Directors), EPA provided guidance 
    for permitting authorities on the approvability of PCP exclusions for 
    source categories other than electric utilities. In the guidance, EPA 
    indicated that add-on controls and fuel switches to less polluting 
    fuels qualify for an exclusion from major NSR. To be eligible to be 
    excluded from otherwise applicable major NSR requirements, a PCP must 
    on balance be ``environmentally beneficial,'' and the permitting 
    authority must ensure that the project will not cause or contribute to 
    a violation of a national ambient air quality standard (NAAQS) or PSD 
    increment, or adversely affect visibility or other air quality related 
    values (AQRV) in a Class I area, and that off-setting reductions are 
    secured in the case of a project which would result in a significant 
    increase of a non-attainment pollutant. The permitting authority can 
    make these determinations outside of the major NSR process. The 1994 
    guidance did not void or create an exclusion from any applicable minor 
    source preconstruction review requirements in an approved State 
    Implementation Plan (SIP). Any minor NSR permitting requirements in a 
    SIP would continue to apply, regardless of any exclusion from major NSR 
    that might be approved for a source under the PCP exclusion policy.
        In the July 1, 1994 guidance memorandum, EPA specifically 
    identified the combustion of organic toxic pollutants as an example of 
    an add-on control that could be considered a PCP and an appropriate 
    candidate for a case-by-case exclusion from major NSR. For the purposes 
    of the pulp and paper MACT rule, EPA considers that combustion for the 
    control of HAP emissions from pulping systems and condensate control 
    systems to be a PCP, because the combustion controls are being 
    installed to comply with MACT and will reduce emissions of hazardous 
    organic air pollutants. EPA also considers the reduction of these 
    pollutants to represent an environmental benefit. However, EPA 
    recognizes that the incidental formation of SO2 and 
    NOX due to the destruction of HAPs will occur. Consistent 
    with the 1994 guidance, the permitting authority should confirm that, 
    in each case, the resultant emissions increase would not cause or 
    contribute to a violation of a NAAQS, PSD increment, or adversely 
    affect an AQRV.
        The EPA believes that the current guidance on pollution control 
    projects adequately provides for the exclusion from major NSR of air 
    pollution control projects in the pulp and paper industry resulting 
    from today's rule. Such projects would be covered under minor source 
    regulations in the applicable state implementation plan (SIP), and 
    permitting authorities would be expected to provide adequate safeguards 
    against NAAQS and increment violations and adverse impacts on air 
    quality related values in Federal Class I areas. Only in those cases 
    where potential adverse impacts cannot be resolved through the minor 
    NSR programs or other mechanisms would major NSR apply.
        The EPA recognizes that, where there is a potential for an adverse 
    impact, some small percentage of mills located near Class I PSD areas 
    might be subject to major NSR, i.e., the permitting authority 
    determines that the impact or potential impact cannot be adequately 
    addressed by its minor NSR program or other SIP measures. If this 
    occurs, there is a question whether MACT and NSR compliance can both be 
    done within the respective rule deadlines. EPA believes, however, that 
    the eight year compliance deadline provided in the final MACT rule for 
    HVLC kraft pulping sources substantially mitigates the potential 
    scheduling problem. The equipment with the eight year compliance 
    deadline are the primary sources of the additional SO2 and 
    NOX emissions. The additional time should be sufficient to 
    resolve any preconstruction permitting issues.
        While the Agency believes that eight years is sufficient for kraft 
    mills with HVLC systems to meet permitting requirements, industry has 
    raised concerns that there could be a potential problem for a few mills 
    in Class I attainment areas that are required to comply with the final 
    rule in three years. The PCP exemption and extended compliance schedule 
    may not resolve all NSR conflicts for every mill. Although too 
    speculative to warrant disposition in this rule, EPA is alert to this 
    potential problem and will attempt to create implementation flexibility 
    on a case-by-case basis should a problem actually occur.
        Commenters requested that the PCP exclusion also be expanded to 
    actions undertaken at mills that enroll in the Voluntary Advanced 
    Technology (AT) Incentives Program in the effluent limitations 
    guidelines and standards portion of today's rule. In the July 23, 1996 
    notice on changes to the NSR Program (61 FR 38250), EPA solicited 
    comments on the appropriate scope of the PCP exclusion. EPA also 
    solicited comments in the July 15, 1996 supplemental pulp and paper 
    effluent guidelines notice (61 FR 36857) on whether advanced water 
    pollution control technologies implemented by the pulp and paper 
    industry should be eligible for an exclusion from major NSR and if so, 
    whether the exclusion should be implemented under the provisions of the 
    PCP exclusion under the NSR proposed regulations. In the context of 
    these notices, EPA received several comments in favor of extending the 
    PCP exclusion to multi-media activities, such as those that would be 
    undertaken for the Voluntary Advanced Technology Incentives Program but 
    received little information on appropriate criteria for determining the 
    relative benefits of reduced water pollution to potential coincident 
    increases in air pollution.
        The Agency believes that, depending on the control technologies 
    selected by a mill, the potential exists for an overall environmental 
    benefit to result from control strategies implemented under the 
    Voluntary Advanced Technology Incentives Program. However, unlike the 
    MACT rule in today's action, where the controls that would be installed 
    to reduce hazardous air pollutants are fairly well known and the 
    potential pollutant tradeoffs within the same environmental media are 
    fairly well understood, the Agency is less certain about the controls 
    that might be installed to comply with this Voluntary Advanced 
    Technology Incentives Program and the potential pollutant tradeoffs 
    that may occur across environmental media. Therefore, while the Agency 
    is continuing to consider extending this PCP status to activities 
    undertaken to implement the Voluntary Advanced Technology Incentives 
    Program, the Agency is not extending that status in today's action 
    because the Agency currently lacks sufficient information to establish 
    a process and set of criteria by which a determination could be made as 
    to whether these advanced control technologies result in an overall 
    environmental benefit at individual mills that participate in this 
    program. The Agency intends to continue discussions with stakeholders 
    on a process and set of criteria by which a determination could be made 
    as to the appropriateness of extending the PCP exclusion to controls 
    installed at
    
    [[Page 18533]]
    
    individual mills to comply with the Voluntary Advanced Technology 
    Incentives Program. Because the control technologies that could be 
    installed to implement the Voluntary Advanced Technology Incentives 
    Program may vary significantly from one mill to another, mills that 
    want controls implemented within the context of the Voluntary Advanced 
    Technology effluent program to be considered PCP will likely need to 
    make a site-specific demonstration that such controls result in an 
    overall environmental benefit. When a mill would need to make such a 
    demonstration would depend upon that particular mill's compliance 
    timeline--dictated by the AT Incentives Tier to which they commit and 
    the time necessary to get applicable permits approved. While it is not 
    possible at this time to identify the criteria the Agency would use for 
    approving a PCP exclusion, the Agency would not consider projects which 
    result in any increases in emissions of highly toxic compounds to be an 
    acceptable candidate PCP. For example, the Agency believes it would not 
    be environmentally acceptable to give the PCP exclusion to an activity 
    which results in a chlorinated material being sent to a boiler that 
    would result in the release of a chlorinated toxic air pollutant. The 
    Agency also believes that the public should be provided an opportunity 
    to review and comment on mill-specific cases where a PCP exclusion is 
    being considered for these advanced water technologies, particularly if 
    there would be a potentially significant emissions increase of criteria 
    air pollutants such as SO2 or NOX.
        Since mills must declare within one year of promulgation of the 
    cluster rules whether they will participate in the Voluntary AT 
    Incentives Program, the Agency is aware that mills would like to know 
    whether a mechanism exists whereby they may apply for a PCP exclusion 
    among the many factors that may influence their participation in this 
    incentives program. In order for the Agency to proceed further on this 
    issue, the Agency again is requesting that interested stakeholders 
    submit information on the types of control technologies that could be 
    installed under the Voluntary AT Incentives Program along with 
    information on the type and potential magnitude of collateral air 
    pollutant increases that may occur at mills. The Agency requests 
    information from stakeholders that could be useful for developing a 
    process by which mills would apply for the PCP exclusion and for 
    setting forth criteria for determining whether an activity performed 
    under the Voluntary AT Incentives Program qualifies for the PCP 
    exclusion. Given the potentially varying control strategies that could 
    be adopted by participating mills, the Agency also requests information 
    that may be useful in assessing whether generic guidance on when a PCP 
    exclusion may be appropriate should be set forth within the context of 
    the NSR Reform effort or whether NSR determinations should more 
    appropriately be made in the context of mill-specific applications. The 
    EPA needs this information within 60 days of the publishing of this 
    notice to evaluate the information and proceed with this issue in a 
    useful time period for mills to make their decisions on participation 
    in the Voluntary AT Incentives Program. Stakeholders should submit 
    information on this topic directly to Ms. Penny Lassiter, Emission 
    Standards Division (MD-13), U.S. Environmental Protection Agency, 
    Research Triangle Park, NC 27711.
        b. Resource Conservation and Recovery Act (RCRA)/Boilers and 
    Industrial Furnaces (BIF). One of the options for controlling emissions 
    from pulping process condensates is to steam strip HAPs, primarily 
    methanol, from kraft pulping process condensate streams. After the HAPs 
    are removed, the vent gas from the steam stripper is required to be 
    sent to a combustion device for destruction. Several commenters pointed 
    out that some mills may choose to concentrate the methanol in the steam 
    stripper vent gas, using a rectification column, and burn the 
    condensate as a fuel.
        However, the concentrated methanol condensate that would be derived 
    from the steam stripper overheads may be identified as hazardous waste 
    under the Resource Conservation and Recovery Act (RCRA) because it 
    exhibits the ignitability characteristic. See 40 CFR 261.21. Boilers 
    burning such a hazardous waste fuel would ordinarily be required to 
    comply with emission standards set out in 40 CFR Part 266 Subpart H 
    (the so-called BIF regulation, i.e., standards for boilers and 
    industrial furnaces burning hazardous waste). Several commenters 
    recommended incorporating a ``clean fuels'' exclusion into the pulp and 
    paper NESHAP so that the condensate can be burned for energy recovery 
    without the combustion unit also being subject to the RCRA rules. The 
    ``clean fuels'' exclusion is a recommendation from EPA's Solid Waste 
    Task Force to allow recovery of energy from waste-derived fuels that 
    are considered hazardous only because they exhibit the ignitability 
    characteristics and do not contain significant concentrations of HAP. 
    For background information see 61 FR at 17459-69 (April 19, 1996), 
    where EPA proposed such an exclusion based on similarity of waste-
    derived fuels to certain fossil fuels.
        The Agency proposed to exclude this practice from RCRA regulation 
    in the March 8, 1996 notice and solicited comments on this 
    determination (61 FR at 9396). All of the comments supported granting 
    this exemption. As stated in the notice, EPA does not believe that RCRA 
    regulation of the rectification and combustion of the condensate is 
    appropriate or necessary. The rectification practice would not increase 
    environmental risk, would reduce secondary environmental impacts, and 
    would provide a cost savings. Moreover, the burning of condensate will 
    not increase the potential environmental risk over the burning of the 
    steam stripper vent gases prior to condensation. (See generally 61 FR 
    at 9397.) Finally, consideration of risk would more appropriately be 
    handled as part of the section 112(f) residual risk determination 
    required for all sources after implementation of MACT standards. For 
    these reasons, EPA will exclude specific sources at kraft mills that 
    burn condensates derived from steam stripper overhead vent gases from 
    RCRA, including condensates from the steam stripper methanol 
    rectification process. The scope of this exclusion is limited to that 
    requested by commenters, combustion at the facility generating the 
    stream. (Limitation of the scope of the exclusion to on-site burning 
    also eliminates questions about whether RCRA regulation is needed to 
    assure proper tracking and transport of the material.)
    
    B. Effluent Limitations Guidelines and Standards
    
    1. Subcategorization
        The subcategorization scheme being promulgated today for effluent 
    limitations guidelines and standards for the pulp, paper, and 
    paperboard industry replaces the subcategorization of this industry 
    that dates back to 1974. EPA's reasons for combining and reorganizing 
    the 26 old subcategories (formerly found in Parts 430 and 431) into 12 
    new subcategories are set forth below, in the proposal, see 58 FR at 
    66098-100, and in ``Selected Issues Concerning Subcategorization'' (DCN 
    14497, Volume 1).
        In reorganizing Part 430 to comport with the new subcategorization 
    scheme, EPA has reprinted in their entirety the current effluent 
    limitations guidelines and standards applicable to the newly
    
    [[Page 18534]]
    
    formed subcategories. The only substantive changes to the current 
    effluent limitations guidelines and standards are the BAT limitations, 
    NSPS, PSES, PSNS, and best management practices being promulgated today 
    for the Bleached Papergrade Kraft and Soda subcategory (subpart B) and 
    the Papergrade Sulfite subcategory (subpart E). In addition, EPA is 
    promulgating the Voluntary Advanced Technology Incentives Program 
    applicable to subpart B. EPA is making no changes to the BPT and BCT 
    limitations previously promulgated for what are now subparts B and E. 
    Similarly, EPA is retaining the NSPS promulgated in 1982 in new 
    Subparts B and E for new sources that commenced discharge that met the 
    1982 NSPS after June 15, 1988 but before June 15, 1998 provided that 
    the new source was constructed to meet those standards. EPA is also 
    retaining, without substantive revision, the new source pretreatment 
    standards previously promulgated for subparts B and E for facilities 
    constructed between June 15, 1988 and June 15, 1998.
        These limitations and standards are recodified at subparts B and E 
    in the form of segments corresponding to the old subcategorization 
    scheme. (In re-codifying these limitations and standards, EPA has 
    simplified the text introducing the limitations tables, but has not 
    changed the former regulations' substance.) Direct discharging mills 
    currently subject to the 1982 NSPS remain subject to those standards 
    until the date ten years after the completion of construction of the 
    new source or during the period of depreciation or amortization of such 
    facility, whichever comes first. See CWA section 306(d). After such 
    time, the BAT limitations promulgated today apply for toxic and 
    nonconventional pollutants. Limitations on conventional pollutants will 
    be based on the formerly promulgated BPT/BCT limitations corresponding 
    to the BPT/BCT segment applicable to the discharger or on the 1982 NSPS 
    for conventional pollutants, whichever is more stringent.
        EPA is making no substantive changes to the limitations and 
    standards applicable to any other subcategory. EPA will promulgate new 
    or revised effluent limitations guidelines and standards, as 
    appropriate, for the remaining subcategories at a later date. See Table 
    II-2. Until then, the previously promulgated effluent limitations 
    guidelines and standards remain in effect.
        EPA is making one non-substantive revision in each subpart. Where 
    the existing regulation includes a narrative statement describing the 
    procedure to calculate the effluent limitations guidelines and 
    standards for non-continuous dischargers, e.g., 40 CFR 430.13, 430.15, 
    430.62(a)-(d), 430.65 (1996 ed.), EPA has performed the calculations 
    and presented the results in tables. The resulting effluent limitations 
    and standards are the same; this procedure was done simply to 
    streamline the regulation and to make it easier to apply for the permit 
    writer.
        In order to ensure that any facilities that would not have been 
    subject to the previous subparts will not inadvertently be subject to 
    limitations and standards set forth in the newly redesignated subparts, 
    EPA is using the applicability language of each previously promulgated 
    subpart to define the applicability of the newly redesignated subparts 
    that consolidate them. For example, rather than promulgate the 
    applicability statement proposed for subpart C, see 58 FR at 66199, EPA 
    has instead codified as a single applicability statement, the 
    applicability statements of former subparts A, D and V, which new 
    subpart C now comprises. See 40 CFR 430.30.
        The Agency received comments that the groupings comprising the new 
    subcategories are unreasonable because they purportedly ignore 
    distinctions among facilities that affect their ability to implement 
    the technologies that form the basis of the effluent limitations 
    guidelines and standards promulgated for subparts B and E. Thus, some 
    commenters asserted, these facilities would be unable to meet the same 
    limits as other mills in the same new subcategory. EPA considered these 
    comments in detail where they involved mills subject to new effluent 
    limitations guidelines and standards promulgated today in order to 
    determine whether the groupings of the mills into subparts B and E were 
    appropriate. In response to these comments, EPA segmented subpart E. 
    See section VI.B.6.a. When EPA develops the final regulations for the 
    remaining subcategories, EPA similarly will consider if it is 
    appropriate to fine-tune these initial groupings to better respond to 
    material differences between facilities.
        EPA also acknowledges that the subcategorization scheme promulgated 
    today was developed based on data received in the ``1990 National 
    Census of Pulp, Paper, and Paperboard Manufacturing Facilities,'' and 
    that there have been changes in the industry since that data gathering 
    effort. Because the resubcategorization has no substantive effect on 
    any mill other than those with production in subparts B and E (for whom 
    revised effluent limitations guidelines and standards are promulgated 
    today), EPA believes that changes in the industry affecting the 
    remaining subparts are best addressed when EPA makes the decision 
    whether to revise the regulations for those subcategories.
        a. Bleached Papergrade Kraft and Soda subcategory. The Bleached 
    Papergrade Kraft and Soda subcategory, for which regulations are 
    promulgated in this rulemaking at 40 CFR part 430 subpart B, 
    encompasses the former subparts G (market bleached kraft), H (BCT 
    bleached kraft), I (fine bleached kraft), and P (soda). EPA has 
    retained the applicability statements associated with those former 
    subparts. See 40 CFR 430.20. EPA intends for this merged subcategory to 
    apply to mills that chemically pulp wood fiber using a kraft method 
    with an alkaline sodium hydroxide and sodium sulfide cooking liquor to 
    produce bleached papergrade pulp and/or bleached paper/paperboard. It 
    also applies to mills that chemically pulp wood fiber using a soda 
    method with an alkaline sodium hydroxide cooking liquor. Principal 
    products of bleached kraft wood pulp include papergrade kraft market 
    pulp, paperboard, coarse papers, tissue papers, uncoated free sheet, 
    and fine papers, which include business, writing, and printing papers. 
    Principal products of bleached soda wood pulp are fine papers, which 
    include printing, writing, and business papers, and market pulp.
        b. Papergrade Sulfite subcategory. The Papergrade Sulfite 
    subcategory, for which regulations are promulgated in this rulemaking, 
    is defined as 40 CFR part 430 subpart E and encompasses former subpart 
    J (papergrade sulfite-blow pit wash) and subpart U (papergrade sulfite-
    drum wash). EPA has retained the applicability statements associated 
    with those former subparts. See 40 CFR 430.50. EPA intends for this 
    merged subcategory to apply to mills that chemically pulp wood fiber 
    using a sulfite method, with or without brightening or bleaching, using 
    an acidic cooking liquor of calcium, magnesium, ammonium, or sodium 
    sulfites to produce bleached papergrade pulp and/or bleached paper/
    paperboard. The provisions of this merged subpart apply regardless of 
    whether blow pit pulp washing techniques or vacuum or pressure drum 
    pulp washing techniques are used.
    2. BPT/BCT for the Bleached Papergrade Kraft and Soda Subcategory and 
    the Papergrade Sulfite Subcategory
        a. Background. EPA proposed to revise effluent limitations for the 
    conventional pollutants biochemical
    
    [[Page 18535]]
    
    oxygen demand (BOD5) and total suspended solids (TSS) based 
    on the best practicable control technology currently available (BPT) 
    for all of the proposed subcategories, including Bleached Papergrade 
    Kraft and Soda and Papergrade Sulfite. As presented in the proposal, 58 
    FR at 66105, EPA highlighted several controversial issues concerning 
    the BPT limitations, their calculation, and their interpretation. EPA 
    also presented a rationale and methodology and identified related 
    controversies for establishing limitations based on the best 
    conventional pollutant control technology (BCT).
        b. BPT. In December 1993, the Agency proposed to revise BPT for 
    conventional pollutants for subparts B and E and specifically solicited 
    comment on that proposed decision. See 58 FR at 66105-06. In response, 
    EPA received comments claiming that EPA lacks the legal authority to 
    revise BPT once BPT effluent limitations guidelines have been 
    promulgated. EPA also received other comments asserting that the Clean 
    Water Act compels EPA to revise BPT. Although the Agency believes that 
    it has the statutory authority to revise BPT, the Agency also believes 
    that it has the discretion to determine whether to revise BPT effluent 
    limitations guidelines in particular circumstances. The question of 
    EPA's legal authority is not relevant here, however, because EPA has 
    decided, in the exercise of its discretion, that it is not appropriate 
    to revise BPT effluent limitations guidelines for conventional 
    pollutants for subparts B and E at this time. Instead the current BPT 
    effluent limitations guidelines for conventional pollutants will 
    continue to apply to these subcategories.
        EPA bases this decision on its determination that the total cost of 
    applying the proposed BPT model technology is disproportionate in this 
    instance to the effluent reduction benefits to be achieved. See CWA 
    section 304(b)(1)(B). When setting BPT limitations, EPA is required 
    under section 304(b) to perform a limited cost-benefit balancing to 
    make sure that costs are not wholly out of proportion to the benefits 
    achieved. See, e.g., Weyerhaeuser Co. v. Costle, 590 F.2d 1011 (D.C. 
    Cir. 1978). It therefore follows that EPA is authorized to perform such 
    balancing when determining whether to revise existing BPT limitations.
        Mills in subparts B and E have significantly reduced their loadings 
    of BOD5 and TSS since promulgation of the current BPT 
    effluent limitations guidelines in 1977. Although additional removals 
    could be achieved if BPT were revised, EPA has determined for subpart B 
    and, separately, for subpart E that the costs of achieving that 
    incremental improvement beyond either the current BOD5 and 
    TSS limitations or the current long term average for BOD5 
    and TSS are disproportionate to the benefits. A single mill might have 
    to spend as much as $17.4 million in order to upgrade to advanced 
    secondary treatment. See the Supplemental Technical Development 
    Document, DCN 14487. These expenditures are particularly significant 
    when one considers the cumulative costs of this rulemaking. Therefore, 
    EPA has decided not to revise BPT limitations for conventional 
    pollutants for mills in the Bleached Papergrade Kraft and Soda 
    subcategory and the Papergrade Sulfite subcategory at this time.
        EPA's decision not to revise BPT limitations for subpart B at this 
    time is also informed by the Agency's long-term goal for this industry: 
    that the industry will continuously improve its environmental 
    performance primarily through sound capital planning and expenditures. 
    EPA has determined that this interplay between potentially more 
    stringent revised BPT limitations and the industry's long-term 
    environmental improvement is an appropriate factor to be considered in 
    this rulemaking with respect to BPT. See CWA section 304(b)(1)(B). It 
    is also consistent with the Clean Water Act's overarching objective, 
    which calls upon EPA to implement the statute's provisions with the 
    goal of eliminating the discharge of pollutants into the Nation's 
    waters. See CWA Section 101(a). In this rulemaking, EPA has determined 
    that the baseline regulatory requirements--effluent limitations 
    guidelines and standards and air emissions standards--are only one 
    component of the framework to achieve long-term environmental goals. 
    EPA believes that the mills of the future will approach closed loop 
    operations, thus achieving minimal impact on the aquatic environment. 
    To promote this, EPA is promulgating an incentives program to encourage 
    subpart B mills to implement pollution prevention leading to the mill 
    of the future. See Section IX.
        EPA believes that near-term investments to achieve more stringent 
    BPT effluent limitations for conventional pollutants would divert 
    limited resources away from environmentally more preferable investments 
    in advanced pollution prevention technologies. Thus, EPA is concerned 
    that revising BPT effluent limitations guidelines at this time could 
    discourage mills from achieving even greater environmental results 
    through the Voluntary Advanced Technology Incentives Program. Moreover, 
    EPA estimates that, even without revising BPT limitations for subpart 
    B, loadings of BOD5, for example, will decline by 
    approximately 20 percent when mills meet the baseline BAT limitations 
    and best management practices requirements promulgated today. 
    Incidental removals are even greater for subpart B mills implementing 
    more advanced technologies (e.g., loadings of BOD5 are 
    estimated to decline by approximately 30 percent at the Tier I level, 
    and EPA expects substantially greater reductions from Tiers II and 
    III). See Table IX-1. EPA also expects comparable TSS loading 
    reductions to occur. See the Voluntary Advanced Technology Incentives 
    Program Technical Support Document, DCN 14488. In short, because 
    sufficient additional removals of conventional pollutants from subpart 
    B mills can be obtained without revising BPT at this time, EPA has 
    determined that, on balance, the incremental benefits attributable to 
    revised BPT limits do not justify the comparatively high costs 
    associated with achieving those limits. For these additional reasons, 
    EPA has decided not to revise BPT for conventional pollutants for mills 
    in the Bleached Papergrade Kraft and Soda subcategory at this time.
        Finally, if additional removals of BOD5 and TSS are 
    needed to protect particular receiving waters, CWA section 301(b)(1)(C) 
    requires mills on a case-by-case basis to meet more stringent 
    limitations as necessary to achieve applicable water quality standards.
        For the foregoing reasons, therefore, EPA has decided, in the 
    exercise of its discretion, that it is not appropriate to revise BPT 
    limitations for conventional pollutants for subparts B and E at this 
    time. Rather, the BPT effluent limitations guidelines promulgated for 
    former subparts G, H, I, and P (now Bleached Papergrade Kraft and Soda 
    subcategory, subpart B) and former subparts J and U (now Papergrade 
    Sulfite subcategory, subpart E) remain in effect. These limitations are 
    recodified at subparts B and E in the form of segments corresponding to 
    the old subcategorization scheme. See 40 CFR 430.22 and 430.52.
        c. BCT Methodology. In considering whether to promulgate revised 
    BCT limits for subparts B and E, EPA considered whether there are 
    technologies that achieve greater removals of conventional pollutants 
    than the current BPT effluent limitations guidelines, and whether those 
    technologies are cost-reasonable according to the BCT cost test. At
    
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    proposal, EPA presented two alternative methodologies for developing 
    BCT limitations. The first assumed that BPT limits would be revised in 
    the final rulemaking; the alternative analysis was based on the 
    assumption that BPT limits would not be revised. See 58 FR at 66106-07. 
    The principal difference between the two methodologies involved the BPT 
    baseline that EPA would use to compare the incremental removals and 
    costs associated with the candidate BCT technologies. Because the 
    Agency is not revising BPT, EPA used the second alternative to 
    determine whether to revise the current BCT limits for subparts B and 
    E.
        d. BCT Technology Options Considered. For the Bleached Papergrade 
    Kraft and Soda subcategory, EPA identified two candidate BCT 
    technologies for the final rule. These were: (i) The technology 
    required to perform at the level achieved by the best 90 percent of 
    mills in the subcategory; and (ii) the technology required to perform 
    at the level achieved by the best 50 percent of mills in the 
    subcategory.
        The Papergrade Sulfite subcategory was not divided into segments 
    for the purpose of conducting a BCT analysis because EPA found that 
    treatability of BOD5 and TSS in the wastewater generated by 
    the three segments does not differ. EPA identified one candidate BCT 
    technology for the Papergrade Sulfite subcategory. This was the 
    technology required to perform at the average level achieved by three 
    mills in the subcategory with at least 85 percent of their production 
    in the segment. Development of candidate BCT technology options based 
    on the best 90 and 50 percent of mills, which EPA used for the Bleached 
    Papergrade Kraft and Soda subcategory, is not appropriate for this 
    subcategory because there are only 11 mills in this subcategory and 
    only four of these have at least 85 percent of their production in the 
    subcategory. The wastewater treatment performance of three of these 
    mills was determined to reflect BCT level performance for the 
    Papergrade Sulfite subcategory. EPA did not consider the wastewater 
    treatment performance of the fourth mill to be representative of the 
    subcategory as a whole because it treats wastewater from liquor by-
    products manufactured on site, and thus is unique among papergrade 
    sulfite mills.
        e. Results of BCT Analysis. EPA evaluated the candidate BCT 
    technologies for both the Bleached Papergrade Kraft and Soda 
    subcategory and the Papergrade Sulfite subcategory and concluded that 
    none of the candidate options passed the BCT cost test. For more 
    details, see the Supplemental Technical Development Document, Section 
    12, DCN 14487. Therefore, at this time, the Agency is not promulgating 
    more stringent BCT effluent limitations guidelines for the newly 
    constituted subparts B and E. Rather, the BCT limitations promulgated 
    for former subparts G, H, I, and P (now Bleached Papergrade Kraft and 
    Soda subcategory, subpart B) and former subparts J and U (now 
    Papergrade Sulfite subcategory, subpart E) remain in effect. These 
    limitations are recodified at subparts B and E in the form of segments 
    corresponding to the old subcategorization scheme. See 40 CFR 430.23 
    and 430.53.
    3. Pollutant Parameters for BAT/NSPS/PSES/PSNS
        a. Dioxin, Furan, and Chlorinated Phenolic Pollutants. EPA is 
    promulgating effluent limitations guidelines and standards for 2,3,7,8-
    TCDD (``dioxin''), 2,3,7,8-TCDF (``furan''), and 12 specific 
    chlorinated phenolic pollutants for subparts B and E (except for those 
    mills regulated by TCF limitations). For a discussion of EPA's 
    rationale for regulating these parameters, see the proposal, 58 FR at 
    66102-03 and the proposal Technical Development Document (EPA 821-R-93-
    019). For a discussion of EPA's pass-through analysis regarding these 
    pollutants, see Section VI.B.5.c(2) and VI.B.6.d.
        b. Volatile Compounds. EPA is promulgating effluent limitations 
    guidelines and standards for chloroform for subpart B. For a discussion 
    of EPA's rationale for regulating chloroform, see the proposal, 58 FR 
    at 66102 and the proposal Technical Development Document (EPA 821-R93-
    019). EPA is not promulgating effluent limitations guidelines and 
    standards for chloroform for subpart E at this time. For a discussion 
    of EPA's pass-through analysis regarding chloroform, see Section 
    VI.B.5.c(2). For the reasons set forth below and in the Supplemental 
    Technical Development Document, DCN 14487, EPA is not promulgating 
    effluent limitations guidelines and standards for the discharge of 
    acetone, methylene chloride, and methyl ethyl ketone (MEK). EPA 
    received no adverse comments in response to its preliminary 
    determination, presented in the July 1996 Notice of Availability, 61 FR 
    at 36839, not to regulate these pollutants.
        EPA has reviewed data from both hardwood and softwood mills 
    employing a variety of bleaching processes in an effort to identify 
    factors that contribute to the formation of acetone, methylene 
    chloride, and MEK in the bleach plant. The bleaching processes 
    evaluated included bleaching using elemental chlorine, BAT Option A 
    (elemental chlorine-free (ECF) bleaching using 100 percent chlorine 
    dioxide), BAT Option B (oxygen delignification plus ECF bleaching using 
    100 percent chlorine dioxide), ECF bleaching using ozone, and totally 
    chlorine-free bleaching. The ranges of loadings for each pollutant were 
    similar across the different bleaching technologies and for both 
    hardwood and softwood mills. The average loadings for these pollutants 
    do not exhibit a performance trend with regard to the bleaching 
    technologies.
        In the EPA/Industry long-term study, methylene chloride was found 
    to be a sample- and laboratory-contaminant in certain cases. Among the 
    more recent data reviewed by EPA, methylene chloride was detected in 
    the bleach plant effluent at ten percent of the sampled mills. Where 
    detected, methylene chloride was present at low concentrations. 
    Therefore, because methylene chloride is infrequently detected, because 
    its formation processes are not fully understood, and because the cases 
    in which it is detected are often attributed to sample and laboratory 
    contamination, EPA has decided not to promulgate effluent limitations 
    guidelines and standards for methylene chloride in this rulemaking.
        EPA had proposed limitations for acetone and MEK based on limited 
    data indicating that these parameters may be affected by the technology 
    options being considered. EPA has decided not to promulgate effluent 
    limitations guidelines or standards for these parameters because 
    additional data have shown that this is not the case. Moreover, EPA 
    believes that the limitations and new source performance standards 
    being promulgated today for adsorbable organic halides for subpart B 
    mills will ensure that mills will continue to operate their biological 
    wastewater systems at levels necessary to achieve very high removals of 
    these pollutants, thus obviating the need for separate limitations.
        In view of the efficacy of biological wastewater treatment in 
    removing acetone and MEK and the fact that process changes have no 
    effect on the levels at which they are generated, EPA is not convinced 
    that these pollutants pass through POTWs. Therefore, EPA is also not 
    setting pretreatment standards for acetone or MEK for subpart B at this 
    time.
        With respect to papergrade sulfite mills, EPA expects that, once 
    promulgated, the limitations and standards for AOX based on, among 
    other things, efficient biological
    
    [[Page 18537]]
    
    treatment, will ensure that treatment systems are operated at levels 
    necessary to obviate the need for separate limitations for acetone and 
    MEK. Therefore, EPA is deferring its decision on whether to regulate 
    acetone and MEK until that time.
        c. Adsorbable Organic Halides (AOX). EPA is establishing BAT 
    limitations, NSPS, and pretreatment standards for the control of 
    adsorbable organic halide (AOX) discharges from mills in the Bleached 
    Papergrade Kraft and Soda subcategory. EPA is also establishing BAT 
    limitations, NSPS, and pretreatment standards to control AOX discharges 
    from mills in the calcium-, magnesium-, or sodium-based segment of the 
    Papergrade Sulfite subcategory. For a discussion of EPA's pass through 
    analysis for AOX discharges from these mills, see Sections VI.B.5.c(2), 
    VI.B.6.d, and the Supplemental Technical Development Document, Section 
    8, DCN 14487. As discussed in more detail in those sections, EPA is not 
    setting effluent limitations guidelines and standards for AOX for other 
    mills in subpart E at this time.
        AOX is a measure of the total chlorinated organic matter in 
    wastewaters. At pulp and paper mills, almost all of the AOX results 
    from bleaching processes. Even though dioxin and furan are no longer 
    measurable using today's analytical methods at the end of the pipe at 
    many mills, the potential for formation of these pollutants continues 
    to exist at pulp and paper mills as long as any chlorine-containing 
    compounds (including chlorine dioxide) are used in the bleaching 
    process. The record demonstrates a correlation between the presence of 
    AOX and the amount of chlorinated bleaching chemical used in relation 
    to the residual lignin in the pulp (expressed as the kappa factor). The 
    record further shows that there is a correlation between the kappa 
    factor and the formation of dioxin and furan. Therefore, EPA concluded 
    that reducing AOX loadings will have the effect of reducing the mass of 
    dioxin, furan, and other chlorinated organic pollutants discharged by 
    this industry. For further discussion of EPA's rationale for regulating 
    AOX, see the Supplemental Technical Development Document (DCN 14487) 
    and response to comments on justification for establishing limitations 
    for AOX (DCN 14497, Vol. I).
        EPA's decision to regulate AOX is also based on the fact that AOX, 
    unlike most of the chlorinated organic compounds regulated today, is 
    comparatively inexpensive to monitor for and is easily quantified by 
    applicable analytical methods. Thus, while EPA could have decided to 
    control the formation of dioxin, furan, chloroform, and the 12 
    regulated chlorinated phenolic pollutants by requiring mills to monitor 
    for those pollutants on a daily basis, EPA also recognizes that testing 
    for those pollutants is expensive and time consuming. In contrast, 
    daily monitoring for AOX as required in today's rule is considerably 
    less expensive. See Section VI.B.8.b(4) and DCN 14487. Additionally, 
    under the Voluntary Advanced Technology Incentives Program, enrolled 
    mills are eligible for reduced AOX monitoring. See Section IX.B.2 and 
    DCN 14488. Moreover, the presence of AOX can be readily measured in 
    mill effluent, in contrast to the presence of many of the chlorinated 
    organic compounds regulated in today's rule, which for the most part 
    are likely to be present at levels that cannot be reliably measured by 
    today's analytical methods. See Section VI.B.5.a(4). Thus, although EPA 
    is not required under the Clean Water Act to consider the environmental 
    or human health effects of its technology-based regulations, EPA has 
    also determined that regulating AOX as part of BAT, NSPS, PSES and PSNS 
    provides further assurance that human health and the environment will 
    be protected against the potential harm associated with dioxin, furan, 
    and the other chlorinated organic pollutants.
        d. Chemical Oxygen Demand (COD). The proposed rule included end-of-
    pipe BAT limitations and PSES for COD. EPA continues to believe that 
    COD limitations can be used to ensure the operation of processes that 
    minimize the discharge of all organic compounds, including toxic 
    organic compounds that are not readily biodegraded. However, the 
    limited data available at this time do not adequately characterize 
    other sources of COD that may be present at some complex mills, 
    although it appears that the COD contributed by these sources may be as 
    great as the COD contribution from the pulp mill and bleach plant areas 
    of the mill. These other sources of COD could include paper machines, 
    mechanical pulping, other on-site chemical pulping, and secondary fiber 
    processing (including deinking). See DCN 13958 and DCN 14495. Even if 
    sufficient data were now available to establish COD limitations and 
    standards for pulp mill operations in subparts B and E, EPA does not 
    have sufficient information at present to evaluate the other sources of 
    COD and the performance of control technologies to limit COD at those 
    sources in order to set national effluent limitations guidelines and 
    standards.
        For this reason, EPA is not establishing final effluent limitations 
    guidelines and standards for COD at this time. EPA does, however, 
    intend to promulgate COD limitations and NSPS for the Bleached 
    Papergrade Kraft and Soda and Papergrade Sulfite subcategories in a 
    later rulemaking. For this purpose, EPA will gather additional data to 
    characterize other sources of COD that may be present at complex mills 
    subject to subparts B or E. This effort will be undertaken concurrently 
    with data gathering to assess the need for establishing COD limits for 
    mills operating in other subcategories (Phase II rulemaking). EPA 
    believes that this data-gathering effort will facilitate setting limits 
    in permits for complex mills with other onsite process operations. EPA 
    will also decide as part of the Phase II rulemaking whether COD passes 
    through or interferes with the operation of POTWs and, therefore, 
    whether pretreatment standards for COD would be appropriate for 
    subparts B and E.
        While EPA does not have sufficient data to issue national 
    technology-based regulations for COD at this time, EPA strongly urges 
    permitting authorities to consider including COD limitations in NPDES 
    permits for Subpart B and E mills on the basis of best professional 
    judgment. See 40 CFR 125.3(c)(3). Pretreatment authorities should 
    establish COD local limits if COD passes through or interferes with the 
    POTWs within the meaning of the general pretreatment regulations. See 
    40 CFR 403.5(c). EPA believes that permitting or pretreatment 
    authorities should address COD for the following reasons. Chronic 
    sublethal toxic effects have been found to result from the discharge of 
    treated effluent from bleached and unbleached kraft, mechanical, and 
    groundwood/sulfite pulp mills (see DCNs 3984, 13985, 13975, 13976, 
    13979, and 00012). These chronic toxic effects were measured as 
    increased liver mixed-function oxydase activity and symptoms of altered 
    reproductive capacity in fish (DCN 60002). This toxicity is associated 
    at least in part with families of non-chlorinated organic materials 
    that are measured by the existing COD analytical method. Some of these 
    materials, including several wood extractive constituents found in 
    pulping liquors, are refractory (i.e., resistant to rapid biological 
    degradation) and thus are not measurable by the five-day biochemical 
    oxygen demand (BOD5) analytical method.
        In order to assist permitting or pretreatment authorities in 
    developing
    
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    COD limitations, EPA describes below various processes that mills can 
    use to control COD. The major sources of COD (which includes slowly 
    biodegradable and non-biodegradable organic material) at a pulp mill 
    are the pulp mill and bleach plant areas. Pulping sources of COD 
    include digester condensates and spent pulping liquor. Open screening 
    processes can be a major source of COD discharges. Spent pulping liquor 
    can also be lost from the process through process spills and equipment 
    leaks. Bleach plant filtrates, the recovery area, leaks from turpentine 
    processing areas at softwood mills, and pulp dryers are examples of 
    other sources of COD at pulp mills.
        The process changes that form the basis of the effluent limitations 
    guidelines and standards promulgated today include processes that can 
    reduce discharges of primarily non-chlorinated organic compounds. These 
    as yet unidentified refractory organic compounds have been correlated 
    with chronic sublethal aquatic toxicity from pulp mill effluents. By 
    recovering much of the non-chlorinated organic compounds prior to 
    bleaching, discharges of chlorinated organic compounds also are 
    reduced. For example, improved brownstock washing, which is part of the 
    model technology basis for today's regulations, can be operated (for 
    the purposes of achieving COD limitations) to minimize black liquor 
    carryover to the bleach plant and thus reduce the formation of AOX and 
    toxic chlorinated compounds. Another process technology effective at 
    reducing organic discharges associated with pulping liquors is for a 
    mill to return all water from pulp screening to the process, termed a 
    closed screen room.
        EPA intends for the best management practices promulgated today for 
    Subparts B and E to lead mills to retain spent pulping liquors in the 
    process, to the maximum extent practicable, through preventing leaks 
    and spills and through capturing those leaks and spills that do occur 
    and returning the organic material to the recovery system. The BMPs are 
    also intended to lead mills to collect intentional diversions of spent 
    pulping liquors and return those materials to the process. However, the 
    BMP regulations do not require that the contained leaked and spilled 
    material be recovered in the process, nor are intentional diversions 
    required to be returned to the process. In the absence of COD 
    limitations, significant quantities of this organic material could be 
    metered to the wastewater treatment system. As a result, while the BMP 
    program will effectively prevent releases of pulping liquors (and soap 
    and turpentine) that would upset or otherwise interfere with the 
    operation of the wastewater treatment system, refractory organic 
    material believed to cause chronic toxic effects could still be 
    discharged at levels greater than the levels achievable through 
    optimized process technologies and effective end--of-pipe treatment. 
    For this additional reason, EPA believes that COD limitations 
    established on a best professional judgment basis would be appropriate.
        The COD data considered by EPA are presented in the support 
    document, Analysis of Data for COD Limitations, DCN 13958, for this 
    rule. This support document also presents EPA's estimates (based on 
    data available today) of the ranges of COD effluent load believed to be 
    contributed by other mill operations, which EPA is supplying as limited 
    guidance to permitting and pretreatment authorities. EPA urges 
    permitting authorities to include--and exercise--reopener clauses in 
    NPDES permits for mills subject to Subpart B or E in order to impose or 
    revise COD effluent limitations once effluent limitations guidelines 
    for COD are promulgated.
        e. Color and Other Pollutants. EPA proposed BAT limitations and 
    PSES for color for the Bleached Papergrade Kraft and Soda subcategory 
    only. Commenters asserted that EPA should not establish effluent 
    limitations guidelines and standards for color because it is a concern 
    more appropriately addressed in individual permits based on applicable 
    water quality standards. EPA agrees with this comment. The potential 
    for significant aesthetic or aquatic impacts from color discharges is 
    driven by highly site-specific conditions and is best dealt with on a 
    case-by-case basis through individual NPDES permits or, when 
    appropriate, through local limits. Therefore, the Agency is not 
    promulgating technology-based limitations or standards for color. See 
    DCN 14497, Vol. I.
        EPA did not propose effluent limitations for four pollutants, 
    including biphenyl, carbon disulfide, dimethyl sulfone, and mercury, 
    and indicated in the Technical Development Document (at Section 7.3.5) 
    that these four pollutants were remaining under consideration for 
    regulation. Based on limited data available to date, EPA has decided 
    not to establish effluent limitations and standards for these 
    pollutants. EPA has reached this decision because these pollutants are 
    not found consistently in effluents and thus they are not directly 
    related to pulping and bleaching processes serving as the basis for BAT 
    and NSPS. EPA notes that where mercury was found to be present, the 
    concentrations at which it was found suggests that a possible source of 
    this pollutant may be contaminants of purchased chemicals. However, the 
    Agency did not obtain any information or data which would either 
    clearly identify the source or sources of mercury or the other 
    pollutants, or provide a basis for identifying applicable control 
    technologies or establishing effluent limitations. Therefore, EPA is 
    not developing effluent limitations and standards. Individual mills may 
    still receive water quality based effluent limitations (Section 
    301(b)(1)(C)) for any of these pollutants where necessary to protect 
    local water quality.
        f. Biocides. EPA is retaining the current effluent limitations 
    guidelines and standards for the biocides pentachlorophenol and 
    trichlorophenol for former subparts G, H, I, and P (now Bleached 
    Papergrade Kraft and Soda subcategory, subpart B) and former subparts J 
    and U (now Papergrade Sulfite subcategory, subpart E). These 
    limitations and standards are recodified at subparts B and E. See 40 
    CFR 430.24(d), 430.25(d), 430.26(b), 430.27(b), 430.54(b), 430.55(c), 
    430.56(b), 430.57(b). For subpart B, the limitations and standards are 
    presented in the form of segments corresponding to the old 
    subcategorization scheme. (EPA did not need to track the old 
    subcategorization scheme for subpart E because the limitations and 
    standards for former subparts J and U were the same.) EPA is not 
    codifying any minimum monitoring frequency for these pollutants. See 40 
    CFR 430.02. In addition, unless the permitting or pretreatment 
    authority decides otherwise, EPA expects that mills would demonstrate 
    compliance with these limitations at the end of the pipe.
        As before, the regulations continue to provide that a discharger is 
    not required to meet the biocides limitations or standards if it 
    certifies to the permitting or pretreatment authority that it is not 
    using these compounds as biocides. See, e.g., 40 CFR 430.24(d). (These 
    certification provisions have been approved by the Office of Management 
    and Budget under control number 2040-0033. See 40 CFR 9.1.) EPA notes, 
    however, that mills using chlorine-containing compounds in their 
    bleaching processes are required to meet separate limitations or 
    standards for pentachlorophenol, 2,4,5-trichlorophenol, and 2,4,6-
    trichlorophenol in connection with the new effluent limitations and 
    standards promulgated today for subparts B and E regardless whether 
    these compounds are
    
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    also used as biocides. See, e.g., 40 CFR 430.24(a)(1). (Those compounds 
    are included within the list of the 12 chlorinated phenolic pollutants 
    discussed in Section VI.B.3.a.) EPA is requiring dischargers to 
    demonstrate compliance with these limitations and standards by 
    monitoring for those pollutants at the point where the wastewater 
    containing those pollutants leaves the bleach plant. See, e.g., 40 CFR 
    430.24(e).
        EPA believes it is appropriate to codify separate limitations and 
    standards for those pollutants, even though in very rare cases a mill 
    may be required to comply with both sets. First, although for the same 
    pollutants the two sets of limitations arise from different chemical 
    applications in different parts of the mill. As biocides, 
    pentachlorophenol or trichlorophenol could be used virtually anywhere 
    in a mill's industrial process, but were typically used as slimicides 
    in whitewater recirculation systems. In the limitations and standards 
    promulgated today, however, pentachlorophenol, 2,4,5-trichlorophenol 
    and 2,4,6-trichlorophenol are being regulated because they are found in 
    bleach plant wastewater when chlorine-containing compounds are used for 
    bleaching. Second, EPA expects these pollutants to be reduced to 
    quantities below the minimum level of the applicable analytical method 
    as a result of bleach plant process changes, which is not the case when 
    they are used as biocides. Thus the different limitations and standards 
    found in subparts B and E for these pollutants respond to different 
    situations and reflect different model process technologies. Finally, 
    EPA believes that mills in the Bleached Papergrade Kraft and Soda 
    subcategory or the Papergrade Sulfite subcategory generally do not use 
    pentachlorophenol or trichlorophenol as biocides today. See the 
    Supplemental Technical Development Document, DCN 14487. Therefore, EPA 
    expects that each mill will be able to certify that it is not using the 
    compounds as biocides and therefore will not be subject to the 
    biocides-related limitations.
    4. Analytical Methods
        In this rule, EPA is promulgating Method 1650 for the analysis of 
    AOX and Method 1653 for the analysis of certain chlorinated phenolic 
    compounds.
        a. Authority. The analytical methods in this final rule are 
    promulgated under the authority of CWA sections 301, 304(h), 307, 308, 
    and 501(a). Section 301 of the Act prohibits the discharge of any 
    pollutant into navigable waters unless the discharge complies with an 
    NPDES permit issued under section 402 of the Act. Section 301 also 
    specifies levels of pollutant reductions to be achieved by certain 
    dates. Section 304(h) of the Act requires the EPA Administrator to 
    ``promulgate guidelines establishing test procedures for the analysis 
    of pollutants that shall include the factors which must be provided in 
    any certification pursuant to section 401 of this Act or permit 
    applications pursuant to section 402 of this Act.'' These test 
    procedures for the analysis of pollutants also assist in the 
    implementation of Section 301. Section 501(a) of the Act authorizes the 
    Administrator to prescribe such regulations as are necessary to carry 
    out her function under this Act.
        The Administrator has also made these test procedures (methods) 
    applicable to monitoring and reporting of NPDES permits (40 CFR part 
    122, Secs. 122.21, 122.41, 122.44, and 123.25), and implementation of 
    the pretreatment standards issued under section 307 of CWA (40 CFR part 
    403, Secs. 403.10 and 403.12). Section 308 provides authority for 
    information gathering.
        b. Background and History. In the December 17, 1993 proposal, EPA 
    referenced a compendium entitled ``Analytical Methods for the 
    Determination of Pollutants in Pulp and Paper Industry Wastewater.'' 
    This compendium contained methods that had not been promulgated at 40 
    CFR part 136, but would be applicable for monitoring compliance with 
    the limitations and standards proposed for part 430 at that time. The 
    compendium included methods for the analysis of CDDs and CDFs (i.e., 
    dioxin and furans), AOX, chlorinated phenolics, and color. These 
    methods were proposed for promulgation at 40 CFR part 430 to support 
    the proposed regulation and were included in the docket for the 
    proposed pulp and paper rule.
        EPA received more than 200 individual comments and suggestions 
    concerning the proposed analytical methods. Some of these were comments 
    on the methods not being promulgated today. Many of the comments and 
    suggestions were technically detailed, ranging from suggestions on 
    changing the integration time in Method 1650 (for AOX) to reducing the 
    spike levels for labeled compounds used in Method 1653 (for chlorinated 
    phenolics). Other comments raised questions about EPA's approach to 
    technical issues and policies regarding the handling of analytical 
    data. EPA has included a summary of the detailed comments and specific 
    responses to those comments in the record for today's rule.
        On July 15, 1996, EPA published a notice of availability that, 
    among other things, summarized the changes the Agency intended to make 
    to the proposed or promulgated analytical methods and stated that 
    detailed revisions to the methods would be added to the record at a 
    later date. See 61 FR at 36848-49. In promulgating today's rule, EPA 
    has implemented the changes identified in the July 1996 Notice. These 
    changes are summarized below and detailed in the response to comments 
    provided in the record.
        c. Analytical Methods Promulgated Today. EPA has revised the 
    analytical methods compendium entitled ``Analytical Methods for the 
    Determination of Pollutants in Pulp and Paper Industry Wastewater'' to 
    incorporate revisions to the methods made since proposal. This 
    compendium (EPA-821-B-97-001, August 1997) contains the analytical 
    methods to be used for monitoring compliance with the limitations and 
    standards promulgated today for subparts B and E. The compendium 
    includes Method 1650 for the determination of AOX and Method 1653 for 
    the determination of chlorinated phenolics. These two analytical 
    methods are being promulgated today as appendices to 40 CFR part 430. 
    They have not yet been promulgated at 40 CFR part 136.
        (1) Method 1650: AOX by Adsorption and Coulometric Titration
        Method 1650 can be used to measure AOX in water and wastewater. AOX 
    is a measure of halogenated organic compounds that adsorb onto granular 
    activated carbon (GAC). The method involves adsorption of the organic 
    halides (chlorine, bromine, iodine) in water onto GAC, removal of 
    inorganic halides by washing, combustion of the organic halides (along 
    with the GAC) to form hydrogen halides, and titration of the hydrogen 
    halides with silver ions in a microcoulometer. The results are reported 
    as organic chlorine even though other halides may be present because 
    chlorine is the halide of concern in pulp and paper wastewaters. EPA 
    studies have demonstrated a Method Detection Limit (MDL) of 6.6 
    g/L. Based on this MDL and on calibration of the 
    microcoulometer, the minimum level (ML) in Method 1650 has been 
    determined to be 20 g/L. The minimum level and other 
    performance attributes for this method have been validated in single 
    laboratory method validation studies and by use in data gathering for 
    today's final rule. All laboratories that used Method 1650 in the data 
    gathering effort calibrated their instruments at the ML.
    
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        Since proposal, EPA has made changes to Method 1650 to improve the 
    ease of use and the reliability of this method. These changes are 
    reflected in the version of Method 1650 being promulgated today and 
    they largely reflect comments and suggestions made following proposal 
    of the method. In response to comments, EPA made several changes to 
    Method 1650, including: adjustment of the breakthrough specification to 
    25 percent based on recent data; allowance of a 100- or 25-mL 
    adsorption volume, provided the sensitivity requirements in the method 
    are met; provision of greater flexibility in allowable glassware sizes; 
    use of 100-mL volumes of standards for calibration and other purposes 
    to conserve reagents; use of only 2-mm columns to make the column 
    procedure more reproducible; adjustment of the QC acceptance criteria 
    based on an industry interlaboratory method validation study; and the 
    addition of a minimum integration time of 10 minutes to assure that all 
    AOX is measured. In addition, the format of the method has been 
    modified to reflect the standardized format recommended by EPA's 
    Environmental Monitoring Management Council (EMMC). For a more detailed 
    discussion of the changes made to Method 1650 since proposal, see DCN 
    14497, Vol. VII.
        EPA disagreed with several comments on EPA's proposed Method 1650 
    and therefore did not make the changes suggested by commenters. In 
    particular, EPA disagrees that the method detection limit (MDL) should 
    be increased to 20 g/L to allow for blank contamination. In 
    EPA's view, blank contamination can be controlled to levels well below 
    20 g/L. EPA also disagrees that it should eliminate Section 
    8.1.2 of the proposed method. (Section 8.1.2 contained provisions for 
    flexibility.) EPA has received a large number of requests that 
    analytical methods be ``performance-based,'' and has attempted to 
    implement the means for allowing changes in Section 8.1.2 (Section 
    9.1.2 in the version of Method 1650 being promulgated today). Under 
    Section 8.1.2, the laboratory can make minor modifications to Method 
    1650 provided that the laboratory performs all quality control (QC) 
    tests and meets all QC acceptance criteria. In addition, contrary to a 
    suggestion from a commenter, EPA has not included examples of cell 
    maintenance in Method 1650 because EPA believes that analysts who 
    maintain the coulometric cell must be familiar with the cell 
    maintenance procedures provided by the instrument manufacturer. For 
    more information on these issues, see DCN 14497, Vol. VII.
        (2) Method 1653: Chlorophenolics by In-Situ Derivatization and 
    Isotope Dilution GC/MS
        Method 1653 can be used to measure chlorinated phenolic compounds 
    in water and wastewater amenable to in situ acetylation, extraction, 
    and determination by HRGC combined with low-resolution mass 
    spectrometry (LRMS). In this method, chlorophenolics are derivatized in 
    situ to form acetic acid phenolates that are extracted with hexane, 
    concentrated, and injected into the HRGC/LRMS where separation and 
    detection occurs.
        EPA studies have demonstrated MDLs of 0.09-1.39 g/L for 
    chlorophenolics in water. Based on these MDLs and on calibration of the 
    GCMS instrument, minimum levels have been determined for the 12 
    chlorinated phenolics in today's rule. These minimum levels of 2.5 or 
    5.0 g/L depend on the specific compound and have been 
    validated in single laboratory validation studies and by use in data 
    gathering for today's final rule. All laboratories that used Method 
    1653 in the data gathering effort calibrated their instruments at the 
    ML.
        Since proposal, EPA has made changes to Method 1653 to improve the 
    reliability of the method and to lower costs of measurements. These 
    changes are incorporated into the version of the method being 
    promulgated today; they largely reflect comments and suggestions made 
    following proposal of the method.
        In response to comments, EPA made several specific changes to 
    Method 1653, the most significant of which are as follows: lowering the 
    spike level of the labeled compounds to reduce interferences with trace 
    levels of the analytes of interest and to lower the cost of labeled 
    compounds; specifying more appropriate solvents for the analytical 
    standards containing labeled and native analytes; requiring 
    laboratories to add the labeled compounds to the sample prior to pH 
    adjustment; restating the quality control acceptance criteria for 
    recovery in terms of percent instead of concentration; and reducing 
    method flexibility in certain critical areas. In addition, as with 
    Method 1650, the method has been revised into the standardized EMMC 
    format.
        EPA disagreed with several comments on EPA's proposed Method 1653 
    and therefore did not make changes suggested by commenters. EPA 
    received comments that Method 1653 has not been validated adequately. 
    EPA disagrees. Method 1653 has been validated in multiple single-
    laboratory method validation studies and extensively validated in field 
    studies for this final rule. EPA believes that these extensive studies 
    are more than adequate to validate Method 1653 for use in data 
    gathering to support this final rule and for use in monitoring under 
    this final rule. EPA also disagrees with comments that Method 1653 is 
    inadequate for chlorocatechols. EPA believes that Method 1653 provides 
    more reliable data for catechols and the other chlorophenolics than any 
    other method available, and the commenter provided no suggestions for 
    how Method 1653 could be improved for determination of chlorocatechols. 
    EPA has, therefore, kept chlorocatechols in Method 1653. EPA also 
    disagrees with comments that initial precision and recovery (IPR) and 
    ongoing precision and recovery (OPR) tests should be replaced with 
    initial calibration (ICAL) and calibration verification (VER) tests. 
    (The ICAL and IPR are different in both form and function. The 
    calibration test is for calibrating the analytical system while the IPR 
    test is conducted to check performance. The OPR and VER tests are the 
    same; only the terminology is different. EPA has retained use of the 
    OPR terminology to be consistent with other methods.) EPA also 
    disagrees with comments that use of labeled compounds is not worth the 
    benefit and that all phenols and guaiacols should be quantitated 
    against 3,4,5-trichlorophenol. EPA believes that data gathered to 
    support today's final rule and in other studies demonstrate that 
    isotope dilution provides the most precise and accurate measurement of 
    chlorophenolics and other compounds determined by gas chromatography/
    mass spectrometry. EPA also received comments urging EPA not to allow 
    modifications to the method. However, EPA also received a large number 
    of requests that analytical methods be ``performance-based,'' and has 
    attempted to implement the means for allowing changes to improve 
    detection and quantitation or to lower costs of measurements. Limited 
    changes may be made, except where specifically prohibited in Method 
    1653, provided that the performance tests are repeated and the results 
    produced by the change are equivalent or superior to results produced 
    with the unmodified method. EPA has also decided to retain the mention 
    of field duplicates in the method in the event that a laboratory or 
    discharger desires to measure sampling precision. Finally, EPA has not 
    added the requirement that laboratories should be forced to overcome 
    emulsions. EPA believes that nearly all emulsions can be overcome and 
    provides specific steps in
    
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    the method that the laboratory must take to break the emulsion. 
    However, EPA does not wish to impose such a requirement on laboratories 
    in the event that a future sample is encountered that produces an 
    emulsion that cannot be broken. If all efforts to break the emulsion 
    fail, Method 1653 allows the use of a dilute aliquot. For more 
    discussion, see Comment Response Document, Vol. VII, DCN 14497.
        d. Other Methods. In addition to the methods promulgated today, the 
    effluent limitations guidelines and standards also call for the use of 
    Method 1613 (for 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) and 
    2,3,7,8-tetrachlorodibenzofuran (TCDF)) and any of the approved methods 
    for chloroform to monitor compliance. These methods are discussed 
    below.
    (1) Method 1613: CDDs and CDFs by HRGC/HRMS
        Method 1613 uses isotope dilution and high-resolution gas 
    chromatography combined with high-resolution mass spectrometry (HRGC/
    HRMS) for separation and detection of 17 tetra-through octa-substituted 
    dibenzo-p-dioxin and dibenzofuran isomers and congeners that are 
    chlorinated at the 2, 3, 7, and 8 positions. Separate procedures are 
    available for the determination of these analytes in water and solid 
    matrices. In the procedure, a 1-L sample is passed through a 0.45-
     glass fiber filter. The filter is extracted with toluene in a 
    Soxhlet/Dean-Stark (SDS) extractor. The aqueous filtrate is extracted 
    with methylene chloride in a separatory funnel. Extracts from the SDS 
    and separatory funnel extractions are combined and concentrated. To 
    remove interferences, the combined, concentrated extract is cleaned up 
    using various combinations of acid and base washes, acidic and basic 
    silica gel, gel permeation chromatography (GPC), high-performance 
    liquid chromatography (HPLC), and activated carbon. The cleaned up 
    extract is concentrated to 20 L and a 1-2 L aliquot 
    is injected into the HRGC/HRMS.
        The MDL determined for TCDD is 4.4 part-per-quadrillion (ppq). 
    Minimum levels for Method 1613 are 10 ppq for TCDD and TCDF. These MLs 
    have been validated through an interlaboratory study and by use in the 
    analysis of mill effluents.
        EPA recently promulgated Method 1613 for the determination of CDDs 
    and CDFs at 40 CFR 136, Appendix A in a final rule published on 
    September 15, 1997 (62 FR 48394). Of the 17 congeners that may be 
    measured with this method, only TCDD and TCDF are regulated under this 
    final rule. Method 1613 was first proposed for general use in 
    compliance monitoring and for other purposes at 40 CFR part 136 on 
    February 7, 1991 (56 FR 5090) and was proposed for use in pulp and 
    paper industry wastewaters at 40 CFR part 430 on December 17, 1993 (58 
    FR 66078). EPA received extensive comments and suggestions on both 
    proposals of Method 1613; in several cases, the same set of comments 
    was submitted. EPA updated the final Method 1613 based on suggestions 
    and comments received on the original proposal (56 FR 5090) and on the 
    proposal of Method 1613 for use at 40 CFR part 430 (58 FR 66078). In 
    the docket supporting promulgation of Method 1613, EPA provided a 
    listing of detailed comments received on both proposals of Method 1613, 
    along with detailed responses to all of those comments. Because Method 
    1613 was promulgated in a final rule prior to promulgation of today's 
    final rule, and because EPA received comments and provided responses in 
    support of that final rule, EPA is not promulgating Method 1613 as part 
    of today's final rule. See the final rule promulgating Method 1613 (62 
    FR 48394) for all information concerning that method.
    (2) Method 1624: Volatiles by Purge-and-Trap and Isotope Dilution GC/MS
        Method 1624 is used for the determination of volatile pollutants in 
    water and wastewater. It employs a gas chromatograph coupled to a mass 
    spectrometer (GC/MS) to separate and quantify volatile pollutants. 
    Detected pollutants are quantified by isotope dilution. Samples of 
    water or solids suspended in water are purged of volatile organic 
    pollutants by a stream of inert gas into the gaseous phase where they 
    are concentrated onto a trap. Subsequent heating of the trap introduces 
    the concentrated volatile organics into a GC/MS for separation and 
    quantification.
        With no interferences present, minimum levels of 10-50 g/L 
    can be achieved, depending on the specific pollutant. For chloroform, 
    the minimum level is 10 g/L. This minimum level has been 
    validated by use.
        When EPA initially proposed today's rule, it proposed to regulate 
    four volatile organic pollutants. Method 1624, Revision C was proposed 
    for monitoring the presence of these pollutants in effluent discharges. 
    Revision C contained updates and improvements to Method 1624, Revision 
    B, which was promulgated October 26, 1984 (49 FR 43234).
        In today's final rule, EPA is regulating only one of the originally 
    proposed volatile pollutants (chloroform); this pollutant can be 
    measured by already-approved EPA Methods 601, 624, and 1624B and 
    Standard Methods 6210B and 6230B. Therefore, EPA has not included 
    Method 1624C in today's final rule and has not formally addressed 
    comments concerning Method 1624C. EPA will consider comments on Method 
    1624C when this version of the method is promulgated for general use at 
    40 CFR 136 or when the method is further revised.
    (3) Other Issues Concerning Analytical Methods Promulgated in Today's 
    Final Rule
        The overall comments received from the regulated industry and 
    others provide suggestions for method improvement but, in some cases, 
    question EPA's approach to technical issues in the methods and the 
    handling of data. For example, commenters suggested that quality 
    control tests be performed at the minimum level (ML), that a 3-point 
    calibration should be used for labeled compounds in isotope dilution 
    methods, and that additional QC tests should be required. Commenters 
    also stated that all methods must be subjected to interlaboratory 
    validation, and that the compliance monitoring detection limit (CMDL) 
    and compliance monitoring quantitation limit (CMQL) should be used in 
    place of EPA's method detection limit (MDL) and ML, respectively. EPA 
    responded to these suggestions by providing specific reasons why they 
    are inconsistent with the provisions in other methods, are more 
    extensive than required to assure reliable results, or that they would 
    not substantively alter the conclusions of studies and data gathering 
    used to support this final rule. The detailed responses to these issues 
    are in the record for this rule.
    5. Bleached Papergrade Kraft and Soda Subcategory
        a. BAT. (1) Technology Options Considered.
        (a) Options Proposed. The Agency considered many combinations of 
    pollution prevention technologies as regulatory options to reduce the 
    discharge of toxic and nonconventional pollutants from bleached 
    papergrade kraft and soda mills. These options are discussed in the 
    proposal and the Notice of Availability published on July 15, 1996. See 
    58 FR at 66109-11 and 61 FR at 36838-39, 36848. Five different options 
    were presented in the proposal.
        The Agency proposed BAT effluent limitations guidelines based on an 
    option that included the use of oxygen delignification or extended 
    cooking
    
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    with elimination of hypochlorite and complete (100 percent) 
    substitution of chlorine dioxide for elemental chlorine as the key 
    process technologies. Complete substitution of chlorine dioxide for 
    elemental chlorine and elimination of hypochlorite is known as 
    elemental chlorine-free (ECF) bleaching. EPA's definition of ECF 
    bleaching includes high shear mixing to ensure adequate mixing of pulp 
    and bleaching chemicals, as well as other technology elements.
        EPA proposed this option because it believed, based on the record 
    at the time, that this combination of technologies was both available 
    and economically achievable and that no other available and 
    economically achievable option resulted in greater effluent reductions. 
    See 58 FR at 66110. In the July 1996 Notice, EPA identified this 
    technology option as Option B. See 61 FR at 36838.
        EPA also considered at proposal another option based on 
    conventional pulping--complete substitution of chlorine dioxide for 
    elemental chlorine, but without the use of oxygen delignification or 
    extended cooking (i.e., conventional pulping). See 58 FR at 66111. At 
    the time of proposal, EPA was unable to fully analyze this alternative 
    because very limited performance data were available from mills using 
    this technology. Therefore, EPA solicited further data and comments on 
    this option, Id. In the July 1996 Notice, EPA published preliminary 
    findings regarding this option, which it identified as Option A. See 61 
    FR at 36838-42.
        The Agency also considered a totally chlorine-free (TCF) option for 
    the Bleached Papergrade Kraft and Soda subcategory at proposal. See 58 
    FR at 66109. TCF bleaching processes are pulp bleaching operations that 
    are performed without the use of chlorine, sodium hypochlorite, calcium 
    hypochlorite, chlorine dioxide, chlorine monoxide, or any other 
    chlorine-containing compound. EPA concluded that TCF was not an 
    available pollution prevention technology at the time of proposal 
    because of limited worldwide experience with this process and a lack of 
    data for TCF bleaching of softwood to full market brightness. To 
    encourage continuing innovation in the development of processes to 
    reduce or eliminate the discharge of pollutants from the Bleached 
    Papergrade Kraft and Soda subcategory, however, EPA proposed 
    alternative BAT limits for mills adopting TCF processes.
        In the July 1996 Notice, EPA also described an incentives program 
    that it was considering for Subpart B mills in order to promote more 
    widespread use of advanced pollution prevention technologies. See 61 FR 
    at 36849-58. As part of this voluntary program, EPA proposed to 
    establish up to three sets of alternative BAT limitations that would 
    complement the compulsory baseline BAT requirements. EPA identified the 
    proposed alternative BAT limitations as Tier I, Tier II, and Tier III 
    BAT limitations. See 61 FR at 36850. EPA considered basing Tier I 
    limits on BAT Option B technology (if Option A were chosen as the basis 
    for the baseline BAT limitations). The Tier II and Tier III 
    limitations, in turn, would be based on technologies and processes that 
    EPA expected to achieve substantial reductions in pulping area 
    condensate, evaporator condensate, and bleach plant wastewater flow.
        (b) Final ECF Options Evaluated. For this final rule, EPA 
    considered two ECF technology options--Option A and Option B--as the 
    basis for BAT effluent limitations. Option A consists of conventional 
    pulping followed by complete substitution of chlorine dioxide for 
    elemental chlorine, as well as the following nine elements:
        (i) Adequate chip thickness control;
        (ii) Closed brownstock pulp screen room operation, such that 
    screening filtrates are returned to the recovery cycle;
        (iii) Use of dioxin- and furan-precursor-free defoamers (i.e., 
    water-based defoamers or defoamers made with precursor-free oils);
        (iv) Effective brownstock washing, i.e., washing that achieves a 
    soda loss of less than or equal to 10 kg Na2SO4 
    per ADMT of pulp (equivalent to approximately 99 percent recovery of 
    pulping chemicals from the pulp);
        (v) Elimination of hypochlorite, i.e., replacement of hypochlorite 
    with equivalent bleaching power in the form of additions of peroxide 
    and/or oxygen to the first extraction stage and/or additional chlorine 
    dioxide in final brightening stages;
        (vi) Oxygen- and peroxide-enhanced extraction, which allows 
    elimination of hypochlorite and/or use of a lower kappa factor in the 
    first bleaching stage;
        (vii) Use of strategies to minimize kappa factor and dioxin- and 
    furan-precursors in brownstock pulp;
        (viii) High shear mixing during bleaching to ensure adequate mixing 
    of pulp and bleaching chemicals; and
        (ix) Efficient biological wastewater treatment, achieving removal 
    of approximately 90 percent or more of influent BOD5. These 
    elements are discussed in detail in the Supplemental Technical 
    Development Document, DCN 14487. Option B is identical to Option A, 
    with the addition of extended delignification (oxygen delignification 
    and/or extended cooking). EPA also considered a TCF option, see 
    subsection (c) immediately below, and, in the context of the Voluntary 
    Advanced Technology Incentives Program, three sets of voluntary 
    alternative BAT limitations. See Section IX.A.
        In a slight change from the definition of the proposed BAT option, 
    EPA has defined Option B not only in terms of the presence of extended 
    delignification technology (i.e., oxygen delignification or extended 
    cooking) but also by the pre-bleaching kappa number achieved by 
    extended delignification. Kappa number is the measure of lignin content 
    in unbleached pulp and is commonly used by the industry. Many 
    researchers have shown (and EPA has confirmed) strong correlations 
    between the kappa number of the pulp entering the first stage of 
    bleaching and the bleach plant effluent loads of AOX and COD. See DCN 
    14497, Vol. I. EPA concluded that merely employing extended 
    delignification technologies, without reducing the unbleached pulp 
    kappa number, is not sufficient to achieve the low effluent loadings of 
    AOX and COD characteristic of Option B. Therefore, EPA has redefined 
    Option B as ECF with extended delignification resulting in a kappa 
    number at or below 20 for softwoods and below 13 for hardwoods (see the 
    Supplemental Technical Development Document, DCN 14487). EPA found that 
    these kappa numbers are achievable by virtually all mills that 
    currently have installed and are effectively operating extended 
    delignification technology.
        As part of the nine elements common to both Option A and Option B, 
    EPA has included strategies for minimizing kappa factor and dioxin- and 
    furan-precursors in brownstock pulp. These strategies are part of 
    Options A and B because EPA has determined that they minimize the 
    generation of dioxin, furan, and AOX and, hence, are part of the model 
    process sequence to achieve those limitations. See 61 FR at 36848 and 
    the Supplemental Technical Development Document, DCN 14487.
        Kappa factor, also known as active chlorine multiple, is the ratio 
    of chlorine bleaching power to the pulp kappa number. (The kappa factor 
    is different from the kappa number discussed above.) The kappa factor 
    used on a particular bleach line depends on the fiber furnish, final 
    product specifications, pre-bleaching processes employed, and 
    optimization of bleaching costs. At the mills whose data were used to 
    characterize Option A performance, kappa factors for softwood
    
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    furnish averaged 0.17 and all were less than 0.2. At the mills whose 
    data were used to characterize Option B performance, kappa factors for 
    softwood furnish averaged 0.23, with all but one at less than 0.21. 
    Well-operated and maintained mills using comparable kappa factors will 
    be capable of achieving limitations corresponding to Option A or B, 
    respectively. Based on certain site-specific factors, such as furnish, 
    some mills will be capable of achieving today's limitations with higher 
    kappa factors. There are numerous strategies a mill can employ to 
    minimize its kappa factor. See the Supplemental Technical Development 
    Document, DCN 14487.
        In addition, there are numerous strategies a mill can employ to 
    minimize precursors of dioxin and furan contained in brownstock pulp. 
    These strategies include, but are not limited to, improved brownstock 
    washing, improved screening to produce cleaner pulp, eliminating 
    compression wood (knots) from brownstock pulp, and using only 
    precursor-free condensates in brownstock washers. The strategy or 
    strategies appropriate for the production of a given pulp depend on the 
    raw material (wood species and the form it takes, i.e., chips, waste 
    wood, or sawdust), process equipment, and the specifications of the 
    final pulp product (brightness, cleanliness, strength, absorbency, and 
    others). For a discussion of these strategies, see the Supplemental 
    Technical Development Document, DCN 14487.
        (c) Totally Chlorine-Free (TCF) Bleaching Option Evaluated. The 
    Agency received many comments that it should continue to investigate 
    TCF bleaching because dioxin and furan are not generated at any level 
    with TCF bleaching, thus assuring that these pollutants are not 
    released to the environment. The Agency conducted two sampling programs 
    at the one U.S. mill that produces TCF bleached kraft softwood pulp. 
    EPA collected samples of bleach plant filtrates but could not collect 
    samples of treated effluent because the mill does not employ secondary 
    treatment. The Agency also conducted a sampling program at a Nordic 
    mill that produces hardwood and softwood kraft pulp on two bleach lines 
    that alternate between ECF and TCF bleaching. Samples collected at this 
    mill could not be used to characterize treated TCF bleaching effluents 
    because they are combined with ECF bleaching effluents for treatment.
        Both of the sampled TCF softwood fiber lines employed oxygen 
    delignification followed by multiple stages of peroxide bleaching. The 
    Nordic mill also uses extended cooking, and was able to reduce the 
    lignin content of unbleached pulp to a very low kappa number of four. 
    At the time of sampling, this mill bleached pulp to a brightness of 83 
    ISO. The U.S. mill's unbleached pulp kappa number was between seven and 
    ten. Bleached pulp brightness was approximately 79 during the first 
    sampling episode at the U.S. mill, but by the time of the second 
    sampling episode, the mill had improved its process to achieve a pulp 
    brightness of 83 ISO.
        At both mills, chloroform or chlorinated phenolic pollutants were 
    not detected in samples collected by EPA. At the U.S. mill, dioxin, 
    furan, and AOX were not detected above the analytical minimum level 
    during sampling fully representative of TCF operations. The average 
    bleach plant AOX loading measured by EPA at the Nordic mill was 0.002 
    kg/ADMT (compared to a long-term average of 0.51 kg/ADMT for Option A). 
    EPA's dioxin sampling results for the Nordic mill were surprising. 
    Dioxin was detected at a concentration just above the minimum level in 
    one sample of combined bleach plant filtrate, when the mill was 
    bleaching without the use of chlorine or any chlorinated compounds. 
    Furan was not detected. EPA believes the dioxin results were unique to 
    the operation of this mill and does not conclude that TCF bleaching 
    generates dioxin.
        Neither of the two sampled mills produced softwood pulp at full 
    market brightness. In the last three years, however, several non-U.S. 
    mills have reported the production of TCF softwood kraft pulp at full 
    market brightness. EPA's data are insufficient to confirm that TCF 
    processes are technically available for the full range of market 
    products currently served by ECF processes. See DCN 14497, Vol. I. 
    Further, EPA's data are insufficient to define a segment of the 
    Bleached Papergrade Kraft and Soda subcategory where TCF processing is 
    known to be technically feasible and thus could be the basis of 
    compulsory BAT limitations. Despite these impediments, EPA believes 
    that the progress being made in TCF process development is substantial, 
    and that additional data may demonstrate that TCF processes are indeed 
    available for the full range of market products. For this reason, EPA 
    also evaluated the performance of TCF mills in order to establish 
    alternative limitations for mills that voluntarily choose to employ TCF 
    processes. See Section VI.B.5.a(4).
        (2) Costs of Technology Options Considered. The Agency estimated 
    the cost for the Bleached Papergrade Kraft and Soda subcategory to 
    achieve each of the technology options considered today. These 
    estimated costs are summarized in this section and are discussed in 
    more detail in several technical support documents. (See the BAT Cost 
    Model Support Document, DCN 13953; Memorandum: Costing Revisions Made 
    Since Publication of July 15, 1996 Notice of Data Availability, DCN 
    14493; Supplemental Technical Development Document, DCN 14487; Analysis 
    of Impacts of BAT Options on the Kraft Recovery Cycle, DCN 14490; 
    Effect of Oxygen Delignification on Yield of the Bleached Papergrade 
    Kraft Pulp Manufacturing Process, DCN 14491; and the Technical Support 
    Document for Best Management Practices for Spent Pulping Liquors 
    Management, Spill Prevention, and Control, DCN 14489.) (For a 
    discussion of the costs associated with the Voluntary Advanced 
    Technology Incentives Program BAT technologies, see the Technical 
    Support Document, DCN 14488.) All cost estimates in this section are 
    expressed in 1995 dollars. The cost components reported in this section 
    are engineering estimates of the cost of purchasing and installing 
    equipment and the annual operating and maintenance costs associated 
    with that equipment. See Section VIII of this preamble for a discussion 
    of the costs used in the economic impact analysis.
        Because EPA considers efficient biological wastewater treatment to 
    be current industry practice, EPA has not included its costs in the 
    estimates of costs of BAT. See the Supplemental Technical Development 
    Document, DCN 14487. As discussed in Section VI.B.5.c. below, for PSES 
    for the Bleached Papergrade Kraft and Soda subcategory, EPA evaluated 
    the same process change technology options that it evaluated for BAT, 
    with the exception of biological wastewater treatment. As a result, EPA 
    used the same cost model to estimate the costs of PSES and BAT. Set 
    forth below are the total costs for all mills in the subcategory 
    (direct and indirect dischargers) to complete the process changes that 
    are the technology bases for the options considered for BAT and PSES. 
    The costs of complying with today's BMP requirements are also included.
        (i) Additional Data Gathering and Analysis Since Proposal. EPA 
    updated its database of mill process information by reviewing comments 
    on the proposed rule and the July 15, 1996 Notice, by examining 
    information from publicly available sources as well as information 
    gathered by AF&PA and NCASI, and by contacting mills directly. The 
    Agency revised the cost estimates it made at
    
    [[Page 18544]]
    
    proposal in many ways but retained two major assumptions: (1) Mills 
    would continue to make the same quantities and grades of pulp; and (2) 
    mills already using the technology bases for the BAT technology options 
    generally would incur only monitoring costs to comply with regulations 
    based on those options. See the Supplemental Technical Development 
    Document, DCN 14487.
        EPA received comments that it severely underestimated the costs of 
    its proposed option (now identified as Option B). Commenters contended 
    that this underestimate derived in large part from EPA's underestimate 
    of the increase in load of black liquor solids that will be routed to 
    the recovery system after installation of oxygen delignification, 
    closing screen rooms, improving brownstock washing, and recovering 
    additional pulping liquors through a best management practices (BMP) 
    program. In addition to underestimating the increase in load, 
    commenters claimed that EPA also underestimated the costs for recovery 
    boilers to accommodate the increased load. Commenters asserted that 
    most mills are recovery boiler-limited and, to employ the proposed BAT, 
    would have to install new recovery boilers at a very high cost.
        In response to these and other comments on the proposed rule, EPA 
    and NCASI undertook several data gathering efforts aimed specifically 
    at obtaining information to improve EPA's cost estimates. In late 1994, 
    NCASI distributed a survey to collect information about recovery 
    furnace capacity and a second survey about the implementation and cost 
    of pulping liquor spill prevention and control programs (i.e., BMPs).
        Based on this and other information, EPA concluded that there is no 
    foreseeable set of circumstances where implementation of either Option 
    A or B would force a mill to replace or even rebuild an existing 
    recovery boiler. Therefore, EPA strongly disagrees with comments that 
    it severely underestimated the costs of what is now known as Option B. 
    Based on data reported in the NCASI survey, almost 60 percent of the 
    recovery boilers operated by the industry have sufficient capacity to 
    accommodate the increased loads that would result from implementing 
    either Option A or B, in combination with the BMP program promulgated 
    today. At most of the remaining 40 percent of the recovery boilers, any 
    increased thermal load can be accommodated through improved boiler 
    operation requiring no capital expenditures, by increasing pulp yield 
    by using anthraquinone, or by reducing the caloric value of the black 
    liquor burned in the boiler by using oxygen-black liquor oxidation. EPA 
    estimates that only one boiler operated by a bleached papergrade kraft 
    and soda mill would need to be upgraded regardless which option is 
    selected as the technology basis for today's rule. The cost of the 
    upgrade is small in comparison to the cost of building or replacing a 
    boiler. See the Supplemental Technical Development Document, DCN 14487, 
    and Analysis of Impacts of BAT Options on the Kraft Recovery Cycle, DCN 
    14490.
        For the purposes of estimating the costs of Option B, EPA estimated 
    costs for implementation of oxygen delignification (OD) based on the 
    record as a whole that shows that OD does not have an impact on yield 
    of bleached pulp. Although some stakeholders asserted that EPA's yield 
    estimates were in error, the entire record on yield supports EPA's 
    basis for estimating the cost of BAT Option B. Some commenters asserted 
    that EPA overestimated the costs for Option B presented in the July 
    1996 Notice by failing to account for the increase in yield that would 
    result from implementation of OD. Industry commenters asserted that OD 
    would result in reduced bleached pulp yields. In response to these 
    comments, EPA reviewed all available literature reports and contacted 
    companies operating mills with OD systems. Although some laboratory and 
    modeling analyses indicate that OD following a modified kraft cooking 
    could increase yields by one to two percent, EPA found no documentation 
    that full-scale OD systems are being operated in this manner. One of 
    the two U.S. companies that operate more mills with OD systems than any 
    other has found no statistical difference in yield measured at the end 
    of the bleach plant with the installation of OD. The other company 
    offered no specific data on yield, but has seen no substantial impact 
    on recovery boilers, indicating that no appreciable change in yield has 
    been experienced. See DCN 14491.
        EPA also collected additional information about the costs of 
    process equipment and updated its information about the costs of 
    chemicals, wood, energy, and labor (record sections 21.1.2 to 21.1.6). 
    EPA used this information to revise the cost model spreadsheet. See the 
    Memorandum: Costing Revisions Made Since Publication of July 15, 1996 
    Notice of Data Availability, DCN 14493, and BAT Cost Model Support 
    Document, DCN 13953. These changes are discussed immediately below.
        (ii) Major Changes Since Proposal. Among other changes since 
    proposal, EPA's cost estimates for Option B now include the costs for 
    new or incremental increases in OD systems for mills unable to achieve 
    the kappa numbers used to characterize the Option B technology. In its 
    July 1996 Notice, EPA described this change and additional changes to 
    the cost model. See 61 FR at 36840-41 and BAT Cost Model Support 
    Document, DCN 13953.
        In response to comments on the July 1996 Notice, EPA corrected 
    mill-specific information and made additional changes to the cost 
    model. See the Memorandum: Costing Revisions Made Since Publication of 
    July 15, 1996 Notice of Availability, DCN 14493. Among those changes 
    was a correction of errors in the costs of caustic and hydrogen 
    peroxide that resulted from a unit conversion error (this error carried 
    through the proposal and the Notice cost estimates). As a result of the 
    changes, including the correction made to the cost of caustic and 
    hydrogen peroxide, the net engineering operating and maintenance (O&M) 
    costs for Option B for all mills in the Bleached Papergrade Kraft and 
    Soda subcategory increased from the savings of $7 million/year 
    presented in the July 1996 Notice, to the $2 million/year increased 
    costs estimated today. See the Supplemental Technical Development 
    Document, DCN 14487.
        For the purpose of estimating the cost of the regulations, EPA 
    excluded the costs of process changes that were either completed or 
    under construction as of mid-1995. EPA incorrectly stated in the July 
    1996 Notice that costs for process changes committed to but not yet 
    under construction as of mid-1995 were also excluded from the cost of 
    this regulation. These latter costs have been included. See the 
    Supplemental Technical Development Document, DCN 14487.
        (iii) Final Cost Estimates of the Options Considered. EPA's final 
    cost estimates for Option A and B for the Bleached Papergrade Kraft and 
    Soda subcategory (BAT, PSES, and BMPs) follow in Table VI-1.
    
        Table VI-1.--Total Bleached Papergrade Kraft and Soda Subcategory   
            Capital and Engineering O&M Costs for BAT, PSES and BMPs        
                                 [1995 dollars]                             
    ------------------------------------------------------------------------
                                                              Final cost    
                                                              estimates     
                                                        --------------------
                                                          Option            
                                                            A      Option  B
    ------------------------------------------------------------------------
    Capital ($ million)................................      966    2,130   
    
    [[Page 18545]]
    
                                                                            
    Engineering O&M ($ million/yr).....................      113        2.02
    ------------------------------------------------------------------------
    
        For both Option A and Option B, EPA excluded costs for the use of 
    dioxin- and furan-precursor-free defoamers, adequate wood chip size 
    control, and efficient biological wastewater treatment in its estimates 
    of the costs of the final BAT technology options. These processes 
    represent current industry practice. See the Supplemental Technical 
    Development Document, DCN 14487. However, EPA's estimate of the costs 
    of BAT also includes a general allowance for increased technical 
    supervision and process engineering that could be used, in part, to 
    design and implement a chip quality control program or to improve 
    operation of existing biological wastewater treatment. In addition, any 
    mill not currently using dioxin- and furan-precursor-free defoamers can 
    use them without incurring significant costs. See the Supplemental 
    Technical Development Document, DCN 14487. EPA evaluated the costs of 
    retrofitting U.S. bleached papergrade kraft and soda mills to TCF 
    bleaching to provide perspective on the likelihood of TCF processes 
    being found to be economically achievable once they are shown to be 
    technically available. EPA investigated the costs of two TCF bleach 
    sequences. These bleach sequences included all common elements that are 
    part of Option A and Option B (adequate chip thickness control, closed 
    brownstock pulp screen room operation, use of dioxin- and furan-
    precursor-free defoamers, effective brownstock washing, elimination of 
    hypochlorite, oxygen- and peroxide-enhanced extraction, use of 
    strategies to minimize kappa factor and dioxin- and furan-precursors in 
    brown stock pulp, high-shear mixing during bleaching, and efficient 
    biological wastewater treatment). The bleaching sequences also include 
    medium-consistency oxygen delignification. One TCF bleach sequence was 
    based on peroxide bleaching (OQPP) and the other was based on ozone and 
    peroxide bleaching (OZEopQPZP). EPA's final cost estimates 
    for TCF bleach sequences for the total Bleached Papergrade Kraft and 
    Soda subcategory (BAT, PSES, and BMPs) are as follows. See the 
    Supplemental Technical Development Document, DCN 14487.
    
        Table VI-2.--Total Bleached Papergrade Kraft and Soda Subcategory   
     Capital and Engineering O&M Costs of TCF Options for BAT, PSES, and BMP
                                 [1995 dollars]                             
    ------------------------------------------------------------------------
                                                          Estimated costs   
                                                     -----------------------
                                                      Peroxide-             
                                                         TCF      Ozone-TCF 
                                                        (OQPP)   (OZEopQPZP)
    ------------------------------------------------------------------------
    Capital ($ million).............................     3,090       5,630  
    Engineering O&M ($million/yr)...................       660         849  
    ------------------------------------------------------------------------
    
        (3) Effluent Reductions Associated with Technology Options 
    Considered. The Agency estimated the effluent reductions for the 
    Bleached Papergrade Kraft and Soda subcategory that will result from 
    the BAT options it analyzed. These estimated reductions are summarized 
    in this section and are discussed in more detail in the Supplemental 
    Technical Development Document, DCN 14487.
        As discussed in the July 1996 Notice, EPA recalculated the effluent 
    reduction benefits using a new baseline of mid-1995. See 61 FR at 
    36840. In addition, EPA revised and simplified the methodology used to 
    estimate that baseline (using a model mill approach). Id. EPA also used 
    a second approach to estimate the effluent loads of dioxin and furan 
    using data for individual mills as compiled in the NCASI 1994 Dioxin 
    Profile (see DCN 13764). The baseline calculation methodology 
    revisions, along with details of the effluent reduction calculations, 
    are described in record section 22.6.
        As explained in DCN 14487, after July 1996, EPA again recalculated 
    the effluent reductions. The baseline remains mid-1995. As before, EPA 
    used one-half of the minimum level specified in 40 CFR 430.01(i) or 
    one-half of the reported detection limits to estimate effluent 
    discharge loadings when pollutant concentrations were below minimum 
    levels. EPA considers this a reasonable approach for estimating mass 
    loads because the actual concentration of the sample is too small to 
    measure by current analytical methods, but is between zero and the 
    detection limit. Furthermore, ECF processes use and generate 
    chlorinated compounds, so EPA expects that chlorinated compounds were 
    present (i.e., with a concentration value greater than zero) in the 
    samples. Thus, EPA believes that it is appropriate to substitute a 
    value at the midpoint between zero and the detection limit (i.e., the 
    upper bound of the concentration in the sample) for ECF mills. The 
    methodology was modified slightly for mills that use TCF bleaching 
    sequences. Because chlorinated compounds are not used and are not 
    generated by TCF processes, EPA assumed that TCF mills would discharge 
    zero kilograms per year of AOX and the individual chlorinated 
    pollutants rather than an amount equivalent to one-half the minimum 
    level or detection limit multiplied by an appropriate production-
    normalized flow rate.
        EPA's revised baselines, which were again found to be comparable to 
    NCASI's industry-wide estimates for dioxin and furan, were used to 
    calculate effluent reductions summarized in Table VI-3. The table shows 
    the estimated baseline and the reduction from baseline expected if the 
    option were implemented by all the existing direct discharging mills in 
    the subcategory (i.e., those mills to which BAT will apply). The 
    slightly greater removals of the bleach plant pollutants by Option B 
    are a result of the reduced bleach plant flow found at mills employing 
    Option B technology.
    
     Table VI-3.--Baseline Discharges and Estimated Reductions of Pollutants for Bleached Papergrade Kraft and Soda 
                                Mills Complying With BAT Technology Options Considered a                            
    ----------------------------------------------------------------------------------------------------------------
                                                                Mid-1995      Estimated     Estimated     Estimated 
          Pollutant parameter                 Units             baseline     reductions:   reductions:   reductions:
                                                                discharge     option A      option B         TCF    
    ----------------------------------------------------------------------------------------------------------------
    2,3,7,8-TCDD...................  g/yr                             14.0          9.88          10.8          14.0
    2,3,7,8-TCDF...................  g/yr                            105           98.0           99.5         105  
    Chloroform.....................  kkg/yr                           43.6         35.5           35.5          43.6
    
    [[Page 18546]]
    
                                                                                                                    
    12 Chlorinated phenolic          kkg/yr                           51.7         42.3           44.1          51.7
     pollutants.                                                                                                    
    AOX............................  kkg/yr                       33,300       22,100         27,900       33,300   
    ----------------------------------------------------------------------------------------------------------------
    a The TCF calculations assumed that chlorinated pollutants will not be present. For all other calculations, EPA 
      assumed that pollutants reported as ``not detected'' were present in a concentration equivalent to one-half   
      the minimum level specified in 40 CFR 430.01(i) or one-half of the reported detection limit.                  
    
        The effluent reductions described and shown above are used in 
    Section VII to estimate reduced human health and environmental risk 
    attributable to today's rules. These estimates also form the basis for 
    estimating monetized benefits in Section VIII.
        (4) Development of Limitations. The proposed BAT regulations 
    included limitations for dioxin, furan, 12 chlorinated phenolic 
    pollutants, acetone, chloroform, methyl ethyl ketone (MEK), and 
    methylene chloride (based on BAT process changes); and limitations for 
    color, COD, and AOX (based on BAT process changes and biological 
    wastewater treatment). In today's rule, EPA is promulgating limitations 
    for dioxin, furan, 12 chlorinated phenolic pollutants, chloroform, and 
    AOX. See 40 CFR 430.24(a)(1). As discussed in Section VI.B.3. above, 
    EPA is not promulgating limitations for acetone, MEK, methylene 
    chloride, or color. EPA intends to promulgate effluent limitations 
    guidelines and standards for COD in a later rulemaking.
        In addition to the new effluent limitations guidelines and 
    standards for the Bleached Papergrade Kraft and Soda subcategory 
    promulgated today and discussed immediately below, mills in this 
    subcategory continue to be subject to existing limitations and 
    standards for pentachlorophenol and trichlorophenol (now denominated as 
    supplemental limitations and standards). These mills continue to have 
    the opportunity to be exempt from these supplemental limitations and 
    standards if they certify to the permitting or pretreatment authority 
    that they are not using these chemicals as biocides. See 40 CFR 
    430.24(d).
        Except where noted, the following discussion of BAT limitations 
    also applies to EPA's procedures for setting NSPS, PSES, and PSNS for 
    Subpart B.
        (a) Performance Data. EPA revised the proposed limitations and 
    standards based on data collected after proposal (see Pulp and Paper 
    Mill Data Available for BAT Limitations Development, DCN 13951) and 
    presented the revisions in the July 1996 Notice. See 61 FR at 36841-42. 
    Today's TCDF, chloroform, and AOX limitations and standards have been 
    further revised since the July 1996 Notice as a result of the selection 
    of data sets used for the long-term averages, variability factors, and 
    limitations. See DCN 14494, 14496, and Record Section 22.5. The 
    rationale for changes in the data set selections is provided 
    immediately below. See DCN 14487.
        (i) Dioxin, Furan, and Chlorinated Phenolic Pollutants. For non-TCF 
    mills, EPA had proposed mass-based limitations and standards for furan; 
    in July 1996, EPA presented preliminary revised limitations and 
    standards that were concentration-based. EPA has determined that a 
    limitation on the concentration of furan is a more direct, and hence, a 
    more reasonable measurement of the presence of furan than a mass-based 
    limitation would be. When detected, furan typically is present in the 
    effluent of Subpart B mills that use ECF bleaching at levels at or only 
    slightly above the minimum level specified in the applicable analytical 
    method. In this case, the value of mass-based limitations and standards 
    are predominantly influenced by the variability in the bleach plant 
    effluent flow rate and thus may not be a consistent and reliable 
    measurement of the presence of furan. Since the July 1996 Notice, EPA 
    has used one additional data set to calculate the furan limitation; 
    this data set was from an Option B bleach line with a typical 
    unbleached kappa number of 20. Because of this change and because of 
    changes to assumptions used in the statistical analysis and changes to 
    the computer programs, see Section VI.B.5.a(4)(b), the value of the 
    furan limitations and standards has changed slightly from that 
    presented in the July 1996 Notice.
        EPA has made no changes to the limitations for dioxin and the 12 
    chlorinated phenolic pollutants presented in the July 1996 Notice. Upon 
    further review after the July 1996 Notice, EPA discovered that some 
    sample-specific minimum levels for some chlorinated phenolic pollutants 
    were incorrectly entered into the databases. These values have been 
    corrected. See DCN 14496, and Record Section 22.5.
        EPA has determined that TCF bleaching processes do not result in 
    the generation of dioxin, furan, chloroform or chlorinated phenolic 
    pollutants. For this reason, EPA is not setting limitations for these 
    pollutants as part of the voluntary alternative BAT limitations and 
    standards promulgated today for mills that certify to the use of TCF 
    bleaching processes. See 40 CFR 430.24(a)(2).
        (ii) AOX. In the July 1996 Notice, EPA presented preliminary 
    revised AOX BAT limitations and NSPS for non-TCF mills.
        In the July 1996 Notice, EPA indicated that although it was 
    presenting revised limitations and standards it would continue to 
    analyze data from two mills representing the performance of BAT Option 
    A. These data were submitted to EPA by the industry without sufficient 
    time for the results to be reflected in the preliminary limitations and 
    standards presented in the July 1996 Notice.
        Commenters encouraged EPA to use the newly acquired data for the 
    two Option A mills, but also questioned why certain other data in the 
    record were not used to develop the preliminary revised AOX limitations 
    and standards. EPA continued its analysis of the new data and obtained 
    new information about mill operations associated with the other data 
    addressed by comments. As a result, EPA added data from the two Option 
    A mills to the data used to characterize the performance of Option A 
    and added data from two other mills to the data used to characterize 
    the performance of Option B. EPA ultimately used data from six mills to 
    develop the AOX limitations for each option, including at least one 
    mill for each option for which long-term monitoring data (for about one 
    and a half years) were available. The mills used to represent each 
    option pulp
    
    [[Page 18547]]
    
    primarily softwood and most of them subsequently bleach the pulp to 
    high brightness (i.e., greater than 88 ISO). Tables presented in DCN 
    14494 show several statistics for each mill (reflecting the mill 
    characteristics during the sampling period), including furnish, kappa 
    number, kappa factor, brightness, type of wastewater treatment system, 
    and approximate AOX removal in the treatment system. For a discussion 
    of EPA's development of pretreatment standards for AOX, see section 
    VI.B.5.c(6).
        Another factor that has contributed to revisions in today's AOX 
    limitations and standards is the adjustment for autocorrelation in the 
    data. See DCN 14496. EPA intended that this adjustment be made to the 
    preliminary AOX limitations presented in the July 1996 Notice; however, 
    comments on that notice stated correctly that this adjustment had been 
    excluded from the calculations. This oversight has been corrected in 
    the calculations of today's final AOX limitations and NSPS.
        Since proposal, EPA has gathered additional data in order to 
    establish a final limitation for AOX for TCF bleaching processes. See 
    40 CFR 430.24(a)(2). EPA sampled at two mills with TCF bleaching 
    processes, one U.S. mill and one European mill. Analytical data from 
    sampling these two mills during periods representative of TCF processes 
    indicate that AOX concentrations were consistently below minimum levels 
    in bleach plant wastewaters. See DCN 14494 and DCN 14488. Therefore, 
    EPA has concluded that TCF bleaching processes are capable of achieving 
    concentrations less than the minimum level for AOX in process 
    wastewaters, whether measured at the bleach plant or after secondary 
    biological treatment, and is setting AOX limitations and standards 
    accordingly for TCF bleaching processes. See 40 CFR 430.24(a)(2).
        (iii) Chloroform. EPA proposed a monthly average chloroform 
    limitation of 2.01 g/kkg based on sampling results from one mill that 
    used extended delignification and complete substitution of chlorine 
    dioxide for elemental chlorine, and that did not use hypochlorite 
    during bleaching. Data collected by EPA after proposal indicated that 
    bleach plant loads of chloroform did not differ between mills that used 
    conventional pulping (Option A) and extended delignification (Option 
    B), as long as bleaching was carried out without elemental chlorine or 
    hypochlorite. However, these data indicate that the type of pulp 
    washers used in a mill's bleach plant influence the partitioning of 
    chloroform between the air and effluent. Use of low air flow washers 
    results in less emission of chloroform to the air and greater loads of 
    chloroform in bleach plant effluent than use of high air flow washers. 
    See DCN 14494. In general, modern low air flow washers (such as 
    pressure diffusion) also use less water to accomplish equivalent 
    washing, i.e., they are more efficient than conventional vacuum drum 
    washers (high air flow washers). See DCN 14494, and DCN 14497, Vol. I. 
    Because of their efficient use of water and their potential to reduce 
    non-water quality environmental impacts, EPA encourages industry to use 
    modern low air flow washers. For this reason, EPA developed revised 
    chloroform limitations and standards using only data from mills that 
    use low air flow washers. In the July 1996 Notice, EPA presented a 
    revised bleach plant monthly average chloroform limitation of 2.80 g/
    kkg. This limitation was developed using data from four mills that did 
    not use elemental chlorine or hypochlorite during bleaching, and that 
    used low air flow bleach plant washers.
        EPA received comments that the revised chloroform limitations and 
    standards were not consistently achievable by mills with the process 
    technologies serving as the basis for Options A and B. As a result of 
    these comments, EPA re-evaluated the chloroform limitations and 
    standards presented in the July 1996 Notice.
        EPA has revised the long-term average and variability factors used 
    to calculate the chloroform limitations and standards after considering 
    data from five mills that did not use elemental chlorine or 
    hypochlorite during bleaching and that used low air flow bleach plant 
    washers (data from four of these mills were used in the July 1996 
    Notice). In developing the long-term average, EPA used data from two 
    mills that bleach pulp to a high brightness (88 to 90 ISO). In 
    developing the variability factors, EPA also considered data from the 
    other three mills with low air flow washers to obtain a more realistic 
    estimate of variability associated with operating low air flow washers. 
    Two of these mills bleach pulp to a lower brightness (80 to 85 ISO). 
    EPA believes that the resulting limitations and standards can be met by 
    all well-operated and maintained ECF mills regardless of the type of 
    bleach plant washers used. (EPA's revised bleach plant monthly average 
    chloroform limitation is now 4.14 g/kkg.) The data in the record 
    indicate that it is highly unlikely that a mill employing elemental 
    chlorine or hypochlorite in its bleach plant could comply with the 
    chloroform limitations promulgated in this rule. See DCN 14494.
        (iv) COD. As discussed in VI.B.3.d., EPA is reserving limitations 
    for COD at this time.
        (b) Changes to Statistical Methodology. After the July 1996 Notice, 
    EPA performed a detailed review of the results of the statistical 
    analyses, the documentation of the statistical methodology, the 
    computer programs, and the data for all of the limitations and 
    standards. As a result of this review, EPA revised the assumptions 
    regarding statistical analysis of data to ensure that long-term 
    averages for TCDF and chloroform were greater than or equal to the 
    minimum level of the analytical methods. EPA made other revisions to 
    the statistical assumptions and the computer programs that resulted in 
    minor changes to the values of the limitations and standards. All of 
    these revisions are identified and described in the Statistical Support 
    Document for the Pulp and Paper Industry: Subpart B, DCN 14496. In the 
    record, EPA has also provided detailed responses to comments about the 
    statistical methodology. See DCN 14497, Vol. VI.
        (c) Definition of Limitations and Standards Expressed at Less Than 
    the Minimum Level. In today's rulemaking, EPA is establishing 
    limitations and standards for Subparts B and E for 12 chlorinated 
    phenolic pollutants and dioxin that are expressed as less than the 
    minimum level (``g/L     
    3,4,5-trichlorocatechol.............         1653  5.0 g/L     
    3,4,6-trichlorocatechol.............         1653  5.0 g/L     
    3,4,5-trichloroguaiacol.............         1653  2.5 g/L     
    3,4,6-trichloroguaiacol.............         1653  2.5 g/L     
    4,5,6-trichloroguaiacol.............         1653  2.5 g/L     
    2,4,5-trichlorophenol...............         1653  2.5 g/L     
    2,4,6-trichlorophenol...............         1653  2.5 g/L     
    Tetrachlorocatechol.................         1653  5.0 g/L     
    Tetrachloroguaiacol.................         1653  5.0 g/L     
    2,3,4,6-tetrachlorophenol...........         1653  2.5 g/L     
    Pentachlorophenol...................         1653  5.0 g/L     
    AOX.................................         1650  20 g/L      
    ------------------------------------------------------------------------
    
        (d) Limitations. Table VI-5 presents the final effluent limitations 
    for Options A and B for the Bleached Papergrade Kraft and Soda 
    subcategory that are based on in-plant process changes. These 
    limitations are based on data obtained from bleach plant effluent prior 
    to mixing with other mill wastestreams.
    
                Table VI-5.--Bleached Papergrade Kraft and Soda Limitations Comparison of Options A and B           
    ----------------------------------------------------------------------------------------------------------------
                                                     Daily maximum limitation                    Monthly average    
                                      -----------------------------------------------------        limitation       
                                                                                           -------------------------
                                                Option A                  Option B            Option A     Option B 
    ----------------------------------------------------------------------------------------------------------------
    TCDD (pg/L)......................  g/L).                                                                                                
    Chloroform (g/kkg)...............  6.92                       6.92                             4.14        4.14 
    ----------------------------------------------------------------------------------------------------------------
    * Trichlorosyringol, 2,4,5-trichlorophenol, 2,4,6-trichlorophenol, 3,4,5-trichlorocatechol, 3,4,5-              
      trichloroguaiacol, 3,4,6-trichlorocatechol, 3,4,6-trichloroguaiacol, 4,5,6-trichloroguaiacol,                 
      tetrachlorocatechol, tetrachloroguaiacol, 2,3,4,6-tetrachlorophenol, and pentachlorophenol.                   
    ML or Minimum level--the level at which the analytical system gives recognizable signals and an acceptable      
      calibration point. See 40 CFR 430.01(i).                                                                      
    N/A Not applicable.                                                                                             
    
        EPA did not establish monthly average limitations and standards for 
    dioxin and the 12 chlorinated phenolic pollutants because the daily 
    maximum limitations and standards for these pollutants are expressed as 
    less than the Minimum Level (5 and TSS based on the single best 
    demonstrated end-of-pipe secondary wastewater treatment system. See 58 
    FR at 66116-18, 66197. To encourage continuing innovation in the 
    development of processes to reduce or eliminate the discharge of 
    pollutants from the Bleached Papergrade Kraft and Soda subcategory, EPA 
    also proposed alternative NSPS limits for mills adopting TCF processes. 
    See 58 FR at 66111.
        (2) Options Considered. In addition to the option proposed for 
    NSPS, EPA considered three other options for the technology basis of 
    NSPS for toxic and nonconventional pollutants. These options are 
    summarized below. For further discussion of these options, see the 
    Supplemental Technical Development Document, DCN 14487. The first 
    alternative option is identical to BAT Option B, described above. This 
    revised NSPS option includes extended delignification (i.e., oxygen 
    delignification and/or extended cooking) to produce softwood pulps with 
    a kappa number of approximately equal to or less than 20 (approximately 
    13 for hardwoods), followed by complete (100 percent) substitution of 
    chlorine dioxide for elemental chlorine and elimination of hypochlorite 
    for bleaching. EPA concluded that there are no performance differences 
    between the proposed NSPS option and this revised option. See the 
    Supplemental Technical Development Document, DCN 14487.
        EPA also considered an ECF technology used at two U.S. mills 
    consisting of oxygen delignification followed by ozone bleaching, 
    enhanced extraction, and final chlorine dioxide brightening. This 
    technology is used to produce pulps of somewhat lower brightness than 
    market pulps. Finally, the Agency considered a TCF process technology 
    that one U.S. mill is currently using to produce pulps with brightness 
    up to 83 ISO.
        For conventional pollutants, EPA considered the proposed NSPS 
    option based on the single best available demonstrated end-of-pipe 
    secondary wastewater treatment and a second option based on the best 
    available demonstrated performance of a
    
    [[Page 18553]]
    
    secondary wastewater treatment system as characterized by the average 
    of the best 50 percent of the existing mills in the subcategory.
        (3) Option Selected, Pollutants Regulated, and Costs. EPA is 
    promulgating NSPS for the Bleached Papergrade Kraft and Soda 
    subcategory for toxic and nonconventional pollutants based on the NSPS 
    option equivalent to BAT Option B. EPA has determined that Option B 
    technology represents the best demonstrated control technology, 
    process, operating method, or other alternative available at this time. 
    The toxic and nonconventional pollutants regulated by NSPS are the same 
    as those regulated by BAT. For further discussion of the NSPS model 
    technology, the Supplemental Technical Development Document, DCN 14487.
        EPA rejected as possible NSPS technologies the technologies that 
    have not been demonstrated to achieve full market pulp specifications. 
    EPA knows of two ECF bleach lines using ozone-based bleaching in the 
    U.S. One line uses an OZEoDD bleach sequence to bleach 
    hardwood to 83 GE brightness (less than 82 ISO). The other line uses an 
    OZEoD bleach sequence to bleach softwood to 84 ISO, somewhat 
    less than full market brightness. EPA collected data from this line 
    that confirm that OZEoD bleaching results in much lower 
    water use and pollutant loadings than either Option A or Option B. 
    Because of this level of performance, EPA strongly encourages further 
    development of ozone-based bleaching sequences--as part of either ECF 
    or TCF sequences. It is possible that lines using ozone-based bleaching 
    sequences will achieve the AOX limits promulgated as part of the 
    Voluntary Advanced Technology Incentives Program, which is described in 
    Section IX of this Notice.
        With respect to TCF bleaching processes, several non-U.S. mills 
    have reported the production of TCF softwood kraft pulp at full market 
    brightness. However, EPA's data are not sufficient to confirm that TCF 
    bleaching processes are technically demonstrated for the full range of 
    market products currently served by the kraft process. EPA is also 
    unable to define a segment of the Bleached Papergrade Kraft and Soda 
    subcategory for which TCF bleaching processes are known to be 
    technically feasible and thus could be the basis for NSPS. EPA believes 
    that progress being made in developing TCF bleaching processes is 
    substantial, however, and that additional data may demonstrate that TCF 
    processes are indeed available for the full range of market products. 
    To this end, elsewhere in today's Federal Register Notice, EPA is 
    inviting additional data and comment on the full range of market 
    specifications currently being achieved for TCF kraft pulp (e.g., 
    brightness, strength, and cleanliness). EPA will evaluate whether the 
    performance of this technology will result in greater removals than the 
    performance of the NSPS technology option being selected today. 
    Depending on these findings, EPA will determine whether to propose 
    revisions to NSPS based upon TCF and, if appropriate, flow reduction 
    technologies.
        In addition to NSPS relating to the Voluntary Advanced Technology 
    Incentives Program, which is discussed below in this section, EPA is 
    also promulgating alternative NSPS for Bleached Papergrade Kraft and 
    Soda mills voluntarily choosing to use TCF technologies. See 40 CFR 
    430.25(b)(2).
        For the conventional pollutants BOD5 and TSS, EPA is 
    basing NSPS upon the best available demonstrated performance of a 
    secondary wastewater treatment system as characterized by the average 
    of the best 50 percent of the existing mills in the subcategory. EPA 
    has determined that the performance of the single best mill does not 
    account for all sources of process-related variability in conventional 
    pollutant generation and treatability expected in the entire 
    subcategory, including raw materials (i.e., furnish), process 
    operations, and final products. In selecting the final NSPS technology 
    basis for conventional pollutants, EPA found it necessary to consider 
    the secondary wastewater treatment performance of the best 50 percent 
    of the existing mills in this subcategory in order to ensure that the 
    resulting standards reflect the full range of processes and raw 
    materials to produce the full range of products covered by this 
    subcategory. For further discussion, see the Supplemental Technical 
    Development Document, DCN 14487, and DCN 14497, Vol. I and II.
        EPA is not revising NSPS for pH for subpart B; however, for the 
    convenience of the permit writer, EPA has recodified the 1982 NSPS for 
    pH as part of the table of newly promulgated NSPS for toxic, non-
    conventional, and other conventional pollutants. See 40 CFR 430.25(b).
        In selecting its model NSPS technologies, EPA considered all of the 
    factors specified in CWA section 306, including the cost of achieving 
    effluent reductions. The incremental capital cost of complying with the 
    selected NSPS for all pollutants, as compared to the costs of complying 
    with standards based on the next best technology, BAT Option A, is only 
    0.5 to 2.0 percent of the total capital cost of constructing either a 
    new source fiber line at an existing mill or a new greenfield mill. 
    Moreover, the process technologies that form the basis for NSPS result 
    in lower pollutant loadings requiring biological treatment. Loadings of 
    BOD5 from a bleach line employing NSPS will be approximately 
    30 percent lower than loadings from a conventional bleach line. 
    Compared to the cost of treating wastewater from a conventional bleach 
    line to meet current BPT/BCT effluent limitations guidelines, the cost 
    of treating wastewater from a NSPS bleach line to meet NSPS for 
    conventional pollutants will be the same or lower. Finally, as of mid-
    1995 there are 14 existing mills representing approximately 16 percent 
    of the bleached papergrade kraft production that employ the Option B 
    technology. For these reasons, EPA concludes that the costs of 
    complying with NSPS for toxic, non-conventional or conventional 
    pollutants do not present a barrier to entry. See the Supplemental 
    Technical Development Document, DCN 14487. See also Section VIII and 
    Chapter 6 of the Economic Analysis, DCN 14649.
        The Agency also considered energy requirements and other non-water 
    quality environmental impacts for the selected NSPS option. EPA 
    concluded that increased chemical recovery and reduced energy 
    consumption and operating costs would occur for this option. EPA also 
    concluded that non-water quality environmental impacts were only 
    marginally different than for the selected BAT technology option and 
    are acceptable. Thus, EPA concluded that none of the statutory factors 
    justified selecting a different NSPS model technology than the one 
    chosen. See Section VII. See also the Supplemental Technical 
    Development Document, DCN 14487.
        EPA is also promulgating NSPS as part of the Voluntary Advanced 
    Technology Incentives Program with standards set at the Tier II and 
    Tier III levels. See 40 CFR 430.25(c). For a discussion of this 
    program, see Section IX. A new source may choose to enroll in the 
    Voluntary Advanced Technology Incentives Program at the Tier II or Tier 
    III NSPS level and therefore to commit to achieve those standards at 
    the time it commences operation. Alternatively, a new source may choose 
    to commence operation at the compulsory NSPS level and then later 
    enroll in the Incentives Program at the Tier II or Tier III level as an 
    existing source, or enroll in the Incentives Program once Tier II or 
    Tier III limitations are achieved.
        Finally, EPA notes that the previously promulgated NSPS for the 
    biocides pentachlorophenol and trichlorophenol
    
    [[Page 18554]]
    
    continue to apply to all new sources. See 40 CFR 430.25(d).
        (4) Limitations and Point of Compliance Monitoring. EPA is 
    promulgating NSPS for dioxin, furan, chloroform, the 12 chlorinated 
    phenolic pollutants, and AOX for Subpart B at the levels set forth in 
    Tables VI-5 and VI-6 for BAT Option B. See 40 CFR 430.25(b)(1). For a 
    discussion of EPA's development of those standards (presented in the 
    context of possible BAT limitations derived from Option B 
    technologies), see Section VI.B.5.a(4). The numerical values of today's 
    NSPS for BOD5 and TSS for the Bleached Papergrade Kraft and Soda 
    subcategory have been revised from those provided in the July notice. 
    For a discussion of these changes, see the Statistical Support 
    Document, DCN 14496. The final NSPS for BOD5, TSS and pH are 
    presented in Table VI-7 below.
    
     Table VI-7.--New Source Performance Standards for Conventional Pollutants for the Bleached Papergrade Kraft and
                                                    Soda Subcategory                                                
    ----------------------------------------------------------------------------------------------------------------
                                                          NSPS                                                      
    -----------------------------------------------------------------------------------------------------------------
                                                                          Continuous  dischargers          Non-     
                                                                     --------------------------------   continuous  
                                                                                                        dischargers 
                    Pollutant or  pollutant property                    Maximum for       Monthly    ---------------
                                                                      any 1 day  (kg/  average (kg/   Annual average
                                                                           kkg)            kkg)          (kg/kkg)   
    ----------------------------------------------------------------------------------------------------------------
    BOD5............................................................            4.52            2.41            1.73
    TSS.............................................................            8.47            3.86            2.72
    pH..............................................................           (\1\)           (\1\)           (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
        EPA is requiring mills to demonstrate compliance with the NSPS for 
    dioxin, furan, chloroform and the 12 chlorinated phenolic pollutants 
    inside the discharger's facility at the point where the wastewater 
    containing those pollutants leaves the bleach plant. See 40 CFR 
    430.25(e). EPA bases this decision on the reasons discussed in Section 
    VI.B.5.a(6) for BAT limitations. EPA is not specifying a point of 
    compliance monitoring for AOX, BOD5, TSS, pH, or the 
    biocides.
        c. Pretreatment Standards for Existing Sources (PSES) and 
    Pretreatment Standards for New Sources (PSNS). (1) Background. EPA 
    proposed the same technology option for PSES as it did for BAT. This 
    proposed option would have set PSES for the same pollutants controlled 
    by BAT. For new indirect discharging facilities, EPA proposed that PSNS 
    be set equal to NSPS for the toxic and nonconventional pollutants. At 
    proposal, EPA also discussed three options for implementing the 
    pretreatment standards. See 58 FR at 66123-25. EPA also solicited 
    comment on whether pretreatment standards for BOD5 and TSS 
    were warranted to ensure that pass-through of these and other 
    pollutants (e.g., AOX) did not occur.
        (2) Pass-through Analysis for PSES and PSNS. EPA promulgates 
    pretreatment standards for pollutants that pass through or interfere 
    with POTWs. EPA performed a pass-through analysis as part of this 
    rulemaking, which is summarized below. See also the Supplemental 
    Technical Development Document, DCN 14487. EPA has determined for 
    subpart B mills that dioxin, furan, chloroform, the 12 chlorinated 
    phenolic pollutants, and AOX pass through POTWs. Therefore, the Agency 
    is promulgating PSES and PSNS for these pollutants. See 40 CFR 
    430.26(a)(1) and 430.27(a)(1).
        EPA's record shows that both direct discharging mills and POTWs 
    accepting wastewaters from pulp and paper mills in the Bleached 
    Papergrade Kraft and Soda subcategory operate secondary biological 
    treatment systems. The indirect discharging mills in this subcategory 
    contribute the majority of the pollutant loading and up to 90 percent 
    of the flow to these POTWs. (EPA refers to these POTWs as ``industrial 
    POTWs.'') EPA has reviewed data available in the record for 
    BOD5 and TSS, among other pollutants, and has determined 
    that the biological treatment systems at these POTWs are comparable to 
    the biological treatment systems operated by direct discharging mills 
    in subpart B. See the Supplemental Technical Development Document, DCN 
    14487.
        EPA reviewed all available data in the record to conduct a pass-
    through analysis. EPA compared the percent of removals achieved by 
    subpart B mills implementing the BAT technologies to the percent of the 
    same pollutants removed by the industrial POTWs receiving effluent from 
    subpart B mills. EPA's record shows that dioxin and furan are not 
    removed by biological treatment systems and so are not removed by the 
    POTW. Therefore, these pollutants pass through untreated and are 
    discharged to receiving streams, where dioxin and furan bioaccumulate 
    in aquatic organisms. EPA bases this conclusion on data reported in the 
    ``104-Mill Study,'' which EPA undertook in cooperation with industry in 
    1988/89. That study shows that direct discharging bleached papergrade 
    kraft and soda mills operating secondary biological treatment systems 
    (without the addition of bleach plant process controls) discharge 
    dioxin and furan in detectable quantities. When mills in that 
    subcategory later implemented bleach plant process changes and controls 
    comparable to the model BAT technologies considered in promulgating 
    today's BAT effluent limitations guidelines, the data show that dioxin 
    and furan discharges dropped below the minimum level at which those 
    pollutants can be reliably measured. This was the case even where there 
    was no concurrent change to the secondary biological treatment systems. 
    (Indeed, EPA's candidate BAT technologies assume secondary biological 
    treatment systems operating at the 1989 level). Because, as discussed 
    above, the industrial POTWs receiving effluent from bleached papergrade 
    kraft and soda mills operate biological treatment systems that are 
    comparable to those operated by direct discharging mills in the ``104-
    Mill Study,'' EPA concluded that subpart B mills implementing the 
    selected in-plant BAT model technology achieve substantially greater 
    reductions of dioxin and furan than industrial POTWs can achieve from 
    effluent not subject to BAT-level process controls. EPA finds that in 
    the absence of PSES equivalent to BAT levels of control, dioxin and 
    furan would pass through POTWs. EPA also believes that the presence of 
    these pollutants in the POTWs' secondary
    
    [[Page 18555]]
    
    sludge could possibly interfere with their sludge disposal options.
        For chloroform, EPA also evaluated the removal efficiencies 
    achieved by POTWs by comparing the removals achieved by direct 
    discharging mills using BAT process technologies to the removals 
    achieved by POTWs receiving effluent from subpart B mills. The record 
    shows that, without the BAT process changes, a very high percentage of 
    chloroform volatilizes from collection, conveyance, and aeration 
    systems. EPA has consistently refused in these circumstances to regard 
    such transfers of pollutants from wastewater to air as treatment. See, 
    e.g., 59 FR 50638, 50665 (Sept. 28, 1993) (pesticides chemicals 
    guidelines); 58 FR 36872, 36886-88 (July 9, 1993)(organic chemicals, 
    plastics, and synthetic fibers guidelines). Therefore, because of this 
    volatilization of chloroform in the absence of bleach plant process 
    changes, the quantity of chloroform actually available to be removed by 
    the POTWs' secondary treatment works is less than the quantity of that 
    pollutant removed by the direct discharger employing BAT. Accordingly, 
    EPA concludes that there is pass-through of chloroform in the absence 
    of pretreatment standards for this pollutant, as well as unacceptable 
    non-water quality environmental impacts from air emissions. For a 
    detailed discussion of chloroform volatilization, see Section 8.8 of 
    the Supplemental Technical Development Document, DCN 14487, and the Air 
    Docket, No. A-92-40, Item IV-A-8.
        EPA's determination that the chlorinated phenolic pollutants pass 
    through the POTW is based on data in the record showing that the 
    selected BAT process technology option (Option A) reduces all 12 of the 
    chlorinated phenolic pollutants to concentrations less than minimum 
    levels for these pollutants in bleach plant wastewaters, prior to end-
    of-pipe biological wastewater treatment systems. While biological 
    wastewater treatment systems comparable to POTW treatment systems have 
    been found to remove a portion of these chlorinated phenolic 
    pollutants, the removals achieved are less than the removals achieved 
    by the BAT process changes alone. Therefore, because overall 
    chlorinated phenolic pollutant removals with implementation of the 
    model BAT technologies are substantially greater than removals achieved 
    by POTWs, chlorinated phenolic pollutants pass through POTWs.
        EPA has also determined that AOX passes through. EPA bases this 
    conclusion on its review of all available data regarding removals of 
    AOX achieved by industrial POTWs that receive a majority of their flow 
    or a majority of their BOD5 or TSS loadings from indirect 
    dischargers covered by subpart B. Although the data show that the 
    performance of these POTWs in removing AOX is comparable to the 
    performance of end-of-pipe biological treatment systems operated by 
    direct dischargers in this subcategory, the data also show that direct 
    dischargers meeting limitations based on the model BAT technology 
    consistently achieve far greater AOX removals than biological treatment 
    alone can achieve (e.g., at a POTW). (See the Supplemental Technical 
    Development Document, DCN 14487.) Therefore, in the absence of 
    pretreatment standards analogous to BAT, the affected POTWs receiving 
    pulp and paper wastewaters cannot achieve the same overall removals of 
    AOX as achieved by direct dischargers complying with the BAT 
    limitations for AOX. The same is also true when considering removals 
    achieved by new sources complying with NSPS. Therefore, contrary to the 
    preliminary finding in the July 1996 Notice, EPA concludes that AOX 
    passes through POTWs and is setting pretreatment standards for AOX for 
    new and existing indirect discharging mills. See 40 CFR 430.26(a) and 
    430.27(a).
        The pretreatment standards promulgated today for AOX are equivalent 
    to the AOX loadings present in the bleach plant wastewaters of mills 
    employing the BAT/NSPS technologies prior to biological treatment 
    systems at direct discharging mills. EPA expects that removals achieved 
    by indirect dischargers employing the PSES or PSNS model technology, in 
    combination with removals achieved by biological treatment systems at 
    POTWs, will be comparable to the removals achieved by direct 
    dischargers complying with BAT limitations or NSPS.
        In reviewing the information available in the record for the 
    pollutants BOD5 and TSS, EPA concluded that pollutant 
    reductions attained by direct dischargers' biological wastewater 
    treatment systems and by POTWs accepting similar wastewaters are 
    comparable and that pass-through of these pollutants does not occur. As 
    a result, EPA is not promulgating national PSES or PSNS for 
    BOD5 and TSS for the Bleached Papergrade Kraft and Soda 
    subcategory. Other regulatory authorities may determine, based on a 
    site-specific review of treatment system performance, that locally 
    imposed limits are necessary to prevent the POTW from violating its 
    NPDES permit. See 40 CFR 403.5.
        (3) Options Considered. In this final rule, EPA considered the same 
    process technology options and best management practices for PSES and 
    PSNS as it did for BAT and NSPS. In a change from the proposal, EPA did 
    not consider for PSES/PSNS the biological treatment technology that 
    forms part of the candidate BAT and NSPS technologies. Since proposal, 
    EPA has made new findings with respect to the pass-through of 
    BOD5 and TSS. EPA has also received comments indicating that 
    the lack of sufficient land for the installation of biological 
    treatment at some indirect dischargers makes such systems infeasible 
    and unavailable. This finding, combined with EPA's finding that 
    biological wastewater treatment systems at POTWs treating pulp and 
    paper wastewaters are comparable to the biological wastewater treatment 
    systems operated by direct discharging mills in subpart B, has lead EPA 
    to conclude that biological wastewater treatment should not be included 
    as part of the PSES or PSNS candidate technologies.
        (4) Effluent Reductions. As discussed in Section VI.B.5.a.(3) 
    above, after proposal EPA recalculated the effluent reductions 
    attributable to its PSES technology options using a new baseline of 
    mid-1995. See the Supplemental Technical Development Document, DCN 
    14487.
        Table VI-8 shows the estimated baseline and the reduction from 
    baseline expected if the presented options were implemented by all the 
    existing indirect discharging mills in the subcategory (i.e., those 
    mills to which PSES will apply).
    
     Table VI-8.--Baseline Discharges and Estimated Reductions of Pollutants for Bleached Papergrade Kraft and Soda 
                                        Mills for Technology Options Considereda                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                              Estimated     Estimated     Estimated 
          Pollutant parameter                 Units             Baseline     reductions:   reductions:   Reductions:
                                                                discharge     Option A      Option B         TCF    
    ----------------------------------------------------------------------------------------------------------------
    2,3,7,8-TCDD...................  g/yr...................          1.25          0.92          1.00          1.25
    
    [[Page 18556]]
    
                                                                                                                    
    2,3,7,8-TCDF...................  g/yr...................          9.47          8.94          9.04          9.47
    Chloroform.....................  kkg/yr.................          4.89          4.28          4.28          4.89
    12 Chlorinated phenolic          kkg/yr.................          3.58          2.81          2.97          3.58
     pollutants.                                                                                                    
    AOX............................  kkg/yr.................      3,010         2,100         2,600         3,010   
    ----------------------------------------------------------------------------------------------------------------
    a The TCF calculations assumed that chlorinated pollutants will not be present. For all other calculations, EPA 
      assumed that pollutants reported as ``not detected'' were present in a concentration equivalent to one-half   
      the minimum level of the analytical method.                                                                   
    
        (5) PSES/PSNS Option Selection. EPA is promulgating PSES and PSNS 
    for dioxin, furan, chloroform, 12 chlorinated phenolic pollutants, and 
    AOX based on the process technologies that form the bases for BAT and 
    NSPS, respectively.
        The Agency considered the age, size, processes, other engineering 
    factors, and non-water quality environmental impacts pertinent to 
    Subpart B mills in developing PSES/PSNS. None of these factors provided 
    any basis for establishing different PSES/PSNS. EPA has no data to 
    suggest that the combination of technologies upon which today's PSES/
    PSNS are based results in unacceptable non-water quality environmental 
    impacts.
        Because the costs of the selected BAT and PSES model technologies 
    are attributable solely to process changes, the costs for an existing 
    indirect-discharging bleached papergrade kraft and soda mill to comply 
    with PSES are comparable to a similar direct-discharging bleached 
    papergrade kraft and soda mill. See Section VI.B.5.a(2). As discussed 
    in Section VI.B.5.a(5), EPA found PSES based on BAT Option A to be 
    economically achievable. Similarly, EPA considered the cost of the PSNS 
    technology for new mills (based on BAT Option B) and determined that 
    such costs do not present a barrier to entry, as reflected in the 
    barrier to entry discussion for NSPS in Section VI.B.5.b(3).
        The rationale for choosing BAT Option A as the basis for PSES is 
    set forth in Section VI.B.5.a(5). The rationale for selecting NSPS 
    Option B as PSNS is the same as that provided in Section VI.B.5.b for 
    selecting that model technology as the basis for NSPS for this 
    subcategory. Although for the reasons set forth in those sections EPA 
    is not selecting TCF bleaching processes as the model technology for 
    PSES or PSNS, EPA nevertheless is promulgating voluntary alternative 
    pretreatment standards based on TCF bleaching processes in order to 
    encourage mills to use those processes when possible. See 40 CFR 
    430.26(a)(2) and 430.27(a)(2).
        The pretreatment standards for the Bleached Papergrade Kraft and 
    Soda subcategory also include best management practices. See 40 CFR 
    430.03. These regulations are described in Section VI.B.7. For a 
    discussion of the pass through of pollutants controlled by BMPs, see 
    Section VI.B.7. In addition, the previously promulgated PSES and PSNS 
    for former subparts G, H, I and P for the biocides pentachlorophenol 
    and trichlorophenol continue to apply unless the discharger certifies 
    that it does not use those compounds as biocides. See 40 CFR 430.26(b) 
    and 430.27(b).
        (6) Limitations. With the exception of AOX, the limitations 
    promulgated as PSES for Subpart B are identical to those promulgated as 
    BAT limitations for this subpart. See 40 CFR 430.26(a)(1). For a 
    discussion of the development of those pretreatment standards see 
    Section VI.B.5.a(4).
        EPA found that while end-of-pipe biological treatment systems at 
    industrial POTWs and at direct dischargers achieve comparable removals 
    of AOX, the total AOX removals achieved by direct discharging mills are 
    greater because of the process changes that are part of the model BAT/
    PSES technologies. Therefore, EPA has established AOX pretreatment 
    standards based on the performance of process changes alone (biological 
    treatment is not a component of PSES/PSNS). EPA has developed AOX 
    limits for PSES based on bleach plant data for eight mills that employ 
    the process technologies incorporated in Option A. These pretreatment 
    standards are presented in Table VI-9.
    
      Table VI-9.--Bleached Papergrade Kraft and Soda Subcategory PSES AOX  
                                   Limitations                              
    ------------------------------------------------------------------------
                                                         Daily      Monthly 
                                                        maximum     average 
                   Pollutant parameter                limitation  limitation
                                                       (kg/kkg)    (kg/kkg) 
    ------------------------------------------------------------------------
    AOX.............................................        2.64        1.41
    ------------------------------------------------------------------------
    
        Similarly, with the exception of AOX, the PSNS promulgated for 
    Subpart B for toxic and nonconventional pollutants are identical to the 
    NSPS promulgated for this subpart. See 40 CFR 430.27(a)(1). For a 
    discussion of the development of those pretreatment standards, see 
    Section VI.B.5.a(4). EPA has developed AOX limits for PSNS based on 
    bleach plant data for six mills that employ the process technologies 
    incorporated in Option B. These pretreatment standards are presented in 
    Table VI-10.
    
      Table VI-10.--Bleached Papergrade Kraft and Soda Subcategory PSNS AOX 
                                   Limitations                              
    ------------------------------------------------------------------------
                                                         Daily      Monthly 
                                                        maximum     average 
                   Pollutant parameter                limitation  limitation
                                                       (kg/kkg)    (kg/kkg) 
    ------------------------------------------------------------------------
    AOX.............................................        1.16       0.814
    ------------------------------------------------------------------------
    
        (7) Point of Compliance Monitoring. For many of the same reasons 
    set forth in Section VI.B.5.a(6) above in connection with EPA's 
    decision to specify an in-plant point of compliance monitoring for many 
    of the BAT parameters, EPA is requiring indirect discharging mills 
    subject to Subpart B to demonstrate compliance with pretreatment 
    standards for dioxin, furan, chloroform, the chlorinated phenolic 
    pollutants, and AOX at the bleach plant. See 40 CFR 430.26(c) and 
    430.27(c). As is the case for direct dischargers, data for indirect 
    discharging mills show that standards imposed at the point of discharge 
    to the POTW would make it impractical for the permitting authority to 
    assure that
    
    [[Page 18557]]
    
    the indirect discharger is achieving removal of the pollutants as 
    required by the pretreatment standards. Moreover, EPA is concerned that 
    dioxin and furan, even when present in nondetectable amounts at the 
    point of discharge to the POTW, could pass through the POTW and 
    accumulate in the biosolids, thus possibly interfering with the 
    beneficial reuse of that biosolids material. The extent to which sludge 
    can be beneficially reused is the subject of a separate ongoing 
    rulemaking under CWA Section 405. Finally, under EPA's regulations, 
    indirect dischargers are prohibited from substituting dilution for 
    treatment, except where dilution is expressly authorized by the 
    applicable pretreatment standard. See 40 CFR 403.6(d). (That is not the 
    case here.) This prohibition theoretically could be enforced on a 
    pollutant-by-pollutant, case-by-case basis. However, EPA is concerned 
    that such a solution to the effluent's detection and dilution problems 
    may impose an unnecessary financial and technical burden on POTWs.
        At the time of proposal, EPA proposed that compliance with PSES/
    PSNS AOX limitations would be demonstrated at the point of discharge to 
    the POTW. Since biological treatment is no longer part of the model 
    technology for PSES/PSNS, AOX limitations based upon the performance of 
    the PSES/PSNS technology are more appropriately set, and compliance 
    demonstrated, at the bleach plant, prior to mixing with other 
    wastestreams. This will reduce the burden on the pretreatment authority 
    in implementing the PSES/PSNS limitations, as no additional allowance 
    will need to be factored into the AOX limitations that would apply due 
    to sources of AOX beyond the bleach plant. In this respect, the 
    decision to establish in-plant points of compliance monitoring for all 
    PSES/PSNS regulated parameters also furthers the goals of the Unfunded 
    Mandates Reform Act. For all of these reasons, EPA is establishing in-
    plant points of compliance monitoring for PSES/PSNS on a nationwide 
    level.
    6. Papergrade Sulfite Subcategory
        a. Segmentation of the Papergrade Sulfite Subcategory. In this 
    final rule, EPA is dividing the Papergrade Sulfite subcategory into 
    three segments to better reflect product considerations, the variation 
    in manufacturing processes, and the demonstration of pollution 
    prevention process changes within the category for the purpose of 
    establishing BAT, NSPS, PSES, and PSNS. EPA's reasons for doing so are 
    discussed in the July 1996 Notice, 61 FR at 36844-45, and in paragraphs 
    b(1)-(2) below. EPA is promulgating final effluent limitations 
    guidelines and standards for each segment. The three segments are:
        (1) Production of pulp and paper at papergrade sulfite mills that 
    use an acidic cooking liquor of calcium, magnesium, or sodium sulfite, 
    unless those mills are specialty grade sulfite mills. See 40 CFR 
    430.51(c)(1). Mills in this segment are ``calcium-, magne- sium-, or 
    sodium-based sulfite mills;''
        (2) Production of pulp and paper at papergrade sulfite mills that 
    use an acidic cooking liquor of ammonium sulfite, unless those mills 
    are specialty grade sulfite mills. See 40 CFR 430.51(c)(2). Mills in 
    this segment are ``ammonium-based sulfite mills;'' and
        (3) Production of pulp and paper at specialty grade sulfite mills, 
    or ``specialty grade sulfite mills.'' Specialty grade sulfite mills are 
    those mills where a significant portion of production is characterized 
    by pulp with a high percentage of alpha cellulose and high brightness 
    sufficient to produce end products such as plastic molding compounds, 
    saturating and laminating products, and photographic papers. EPA 
    considers a significant portion of production to be 25 percent or more. 
    The specialty grade segment also includes those mills where a major 
    portion of production is 91 ISO brightness and above. EPA considers a 
    major portion of production to be 50 percent or more.
        See 40 CFR 430.51(c)(3). In order to determine whether a sulfite 
    mill belongs in the specialty grade segment, permitting authorities 
    should consider the expected production mix over the full permit term. 
    For mills that are converting to production in the specialty grade 
    segment, EPA expects these mills will be subject to these limits prior 
    to the time that these mills achieve the production mixes described 
    above.
        b. BAT. (1) Options Considered. EPA had proposed BAT effluent 
    limitations for AOX and COD for the entire Papergrade Sulfite 
    subcategory based on totally chlorine-free bleaching processes. Totally 
    chlorine-free (TCF) bleaching processes are bleaching operations that 
    are performed without the use of chlorine, sodium or calcium 
    hypochlorite, chlorine dioxide, chlorine monoxide, or any other 
    chlorine-containing compound. After concluding that the proposed 
    technology was not demonstrated for the full range of products produced 
    by mills using ammonium sulfite cooking liquor or for specialty grade 
    products, EPA segmented the subcategory and considered other BAT 
    options as set forth below. EPA also included for all segments the 
    performance of existing secondary biological wastewater treatment as 
    part of the basis for nonconventional and conventional pollutant 
    effluent limitations and NSPS. For a more detailed discussion of these 
    options, see the Supplemental Technical Development Document, DCN 
    14487.
        (i) Calcium-, Magnesium-, or Sodium-Based Sulfite Mills. The 
    technology option considered for papergrade sulfite products made by 
    this segment was TCF bleaching, as proposed. See 58 FR at 66114-15. 
    Existing TCF mills in this segment produce the same products they had 
    been able to produce using elemental chlorine-free (ECF) bleaching 
    processes, at up to 91 ISO brightness. Therefore, EPA did not consider 
    ECF bleaching as a technology option for this segment, because, while 
    technically available and economically achievable, it was not the best 
    such technology for this segment.
        (ii) Ammonium-Based Sulfite Mills. The technology options 
    considered for this segment were TCF bleaching and ECF bleaching. ECF 
    bleaching is any process for bleaching pulps that does not employ 
    elemental chlorine or hypochlorite. There are numerous variations of 
    ECF bleaching processes. The ECF process considered for the ammonium-
    based segment includes peroxide-enhanced extraction.
        (iii) Specialty Grade Sulfite Mills. The technology bases 
    considered for this segment were TCF bleaching and ECF bleaching. The 
    ECF process considered for the specialty grade segment includes oxygen- 
    and peroxide-enhanced extraction.
        (2) Selection of BAT Technologies. In evaluating and selecting BAT 
    technologies for the segments in this subcategory, EPA considered the 
    age, size, processes, other engineering factors, and non-water quality 
    environmental impacts pertinent to Subpart E mills. None of these 
    factors provided a basis for selecting different BAT technologies. For 
    each segment, EPA selected the best technology available to produce the 
    products in each segment. Each of the selected BAT technologies is 
    economically achievable and has no unacceptable adverse non-water 
    quality environmental impacts. See the Supplemental Technical 
    Development Document, DCN 14487. The reasons discussed below also 
    support EPA's decision to select the BAT model technology for each 
    segment as the basis for PSES for that segment.
        (i) Calcium-, Magnesium-, or Sodium-Based Sulfite Mills. As 
    proposed, EPA has concluded that TCF bleaching is the
    
    [[Page 18558]]
    
    appropriate technology basis for BAT limitations for the calcium-, 
    magnesium-, or sodium-based segment of the Papergrade Sulfite 
    subcategory. (The following discussion also applies to PSES.) For this 
    segment, TCF technology consists of oxygen- and peroxide-enhanced 
    extraction, followed by peroxide bleaching, and with all chlorine-
    containing compounds eliminated (e.g., elemental chlorine, 
    hypochlorite, chlorine monoxide, etc.). Although still TCF, the 
    bleaching sequence is a change from proposal, when TCF bleaching was 
    based on an oxygen stage with peroxide addition, followed by a peroxide 
    bleaching stage. This change to the TCF bleaching sequence reflects the 
    more common approach to TCF bleaching within this segment of the 
    Papergrade Sulfite subcategory and also reflects the technology basis 
    of the mill from which TCF performance data have been collected. EPA 
    also included pulp cleaning to ensure that existing product quality 
    specifications would continue to be achieved. EPA has selected this 
    technology because it is technically available and economically 
    achievable for mills in this segment.
        In evaluating the technical availability of TCF processes for this 
    segment, EPA developed a database of mills in the United States and 
    Europe that produce pulp using TCF bleaching technology. There is at 
    least one mill in the United States and 13 in Europe using acid cooking 
    liquors of calcium, magnesium, or sodium sulfite that are using TCF 
    bleaching processes. Among them, these mills produce a full range of 
    paper products at up to 91 ISO brightness using TCF bleaching. These 
    mills are able to produce the same products using TCF technology that 
    they produced prior to converting to TCF, with no negative impact on 
    product quality. EPA has incorporated pulp cleaners as an element of 
    TCF technology to ensure that pulp quality requirements are maintained. 
    See the Supplemental Technical Development Document, DCN 14487. For 
    these reasons, EPA concluded that TCF bleaching is technically 
    available for the calcium-, magnesium-, or sodium-based segment. See 
    the record at section 21.2.1. (As noted above, EPA has established a 
    separate segment for specialty grade sulfite mills using these cooking 
    liquors.)
        In order to evaluate the economic achievability of TCF bleaching 
    for this segment, EPA considered the costs that existing mills would 
    incur to convert to TCF processes. However, costs for secondary 
    biological treatment systems have not been included because these 
    systems already are in place at direct discharging mills. (This is true 
    for the other papergrade sulfite segments as well.) As part of that 
    analysis, EPA also included the costs of complying with today's BMP 
    regulations. Because of the small size of this segment, EPA is not 
    disclosing here the estimated capital costs, operation and maintenance 
    costs, or post-tax annualized costs for this segment in order to 
    protect confidential business information. However, EPA has determined 
    that no mills are projected to close and no firms are projected to fail 
    as a result of today's BAT limitations and PSES for this segment. This 
    result obtains both when the impacts of today's BAT/PSES are considered 
    together with the impacts of compliance with the MACT I costs, and when 
    they are considered alone. Therefore, EPA has concluded that TCF 
    bleaching is economically achievable for the calcium-, magnesium-, or 
    sodium-based sulfite pulp segment. See DCN 14376 and DCN 14388 (both 
    CBI).
        For these reasons, EPA has selected the model TCF bleaching 
    processes described above as the basis for BAT limitations and PSES for 
    the calcium-, magnesium-, or sodium-based sulfite pulp segment.
        (ii) Ammonium-Based Sulfite Mills. EPA had proposed BAT based on 
    TCF bleaching technology for all mills in the Papergrade Sulfite 
    subcategory, including those mills using ammonium-based acidic cooking 
    liquor. EPA received comments and data challenging the applicability of 
    TCF bleaching to ammonium-based sulfite mills. After reviewing these 
    comments and data, EPA concluded that TCF bleaching is not demonstrated 
    and may not be feasible for the full range of products produced by 
    ammonium-based sulfite mills in the United States. See DCN 14497, Vol. 
    I. (The following discussion also applies to PSES for this segment.)
        This conclusion is based primarily on the greater difficulty in 
    bleaching ammonium-based sulfite pulps (especially those pulps derived 
    from softwood) without the use of chlorine-containing compounds 
    compared to other sulfite pulps, and the inability to maintain product 
    specifications for certain products within this segment using TCF 
    bleaching. TCF bleaching has not been demonstrated for products with a 
    high percentage of ammonium-based sulfite pulp that also require low 
    dirt count and high strength. Laboratory scale data submitted by a firm 
    producing such products indicate that such products can be produced 
    with elemental chlorine-free (ECF) technologies. See DCN 14497, Vol. I, 
    DCN 14494, and DCN 14118 in the record at Section 21.11.3.
        Therefore, for papergrade sulfite mills using an acidic cooking 
    liquor of ammonium sulfite, EPA is promulgating BAT limitations and 
    PSES based on an ECF bleaching technology. The technology basis for BAT 
    limitations for this segment is use of dioxin- and furan-precursor-free 
    defoamers, complete (100 percent) substitution of chlorine dioxide for 
    elemental chlorine, peroxide-enhanced extraction, and elimination of 
    hypochlorite. ECF bleaching also includes high shear mixing to ensure 
    adequate mixing of pulp and bleaching chemicals. This technology basis 
    reflects the results of laboratory trials showing the ability to 
    produce the full range of products manufactured by mills in the 
    ammonium segment, with acceptable final product characteristics. See 
    the record at section 30.11, DCN 14497, Vol. I, and DCN 14494. (The 
    only exception is specialty grade sulfite mills using ammonium cooking 
    liquors.)
        EPA is also promulgating voluntary alternative BAT limitations and 
    PSES based on TCF bleaching processes in order to encourage mills to 
    use this technology whenever it is consistent with their product mix. 
    See 40 CFR 430.54(a)(2) and 430.56(a)(2). Alternative TCF limitations 
    are also available for new sources in this segment.
        In addition to finding that the ECF bleaching process described 
    above is technically available for the ammonium-based segment, EPA has 
    also determined that it is economically achievable. In order to 
    evaluate the economic achievability of ECF bleaching for this segment, 
    EPA considered the costs that existing mills would incur to convert to 
    the ECF process under consideration. As part of that analysis, EPA also 
    included the costs of complying with today's BMP regulations. Because 
    of the small size of this segment, EPA is not disclosing here the 
    estimated capital costs, operation and maintenance costs, or post-tax 
    annualized costs for this segment in order to protect confidential 
    business information. However, EPA has determined that no mills are 
    projected to close and no firms are projected to fail as a result of 
    today's BAT limitations and PSES for this segment. This result obtains 
    both when the impacts of today's BAT/PSES are considered together with 
    the impacts of compliance with the MACT I costs, and when they are 
    considered alone. Therefore, EPA has concluded that ECF bleaching is 
    economically achievable for the ammonium-based segment. See DCN 14376 
    and DCN 14388 (both CBI).
    
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        For the foregoing reasons, EPA has selected the model ECF bleaching 
    processes described above as the basis for BAT limitations and PSES for 
    the ammonium-based segment.
        (iii) Specialty Grade Sulfite Mills
        EPA received comments and data indicating that key pulp and product 
    characteristics for specialty grade sulfite pulps have not been 
    achieved using TCF bleaching technologies. Firms producing specialty 
    grade pulps indicate that required product characteristics are 
    achievable using certain ECF bleaching technologies. See the record at 
    sections 19.1 and 21.11.6; DCN 25502; DCN 20071a8; DCN 14497, Vol. I; 
    and DCN 14494. As indicated in the July 1996 Notice, EPA has continued 
    to monitor research efforts of specialty grade pulp producers in the 
    field of pollution-preventing process changes. These research efforts 
    have progressed to the point where data are available at this time to 
    promulgate limitations for this segment for dioxin, furan, and 
    chlorinated phenolic pollutants. For specialty grade sulfite mills, the 
    technology basis for limitations is use of dioxin- and furan-precursor-
    free defoamers, complete (100 percent) substitution of chlorine dioxide 
    for elemental chlorine, oxygen- and peroxide-enhanced extraction, and 
    elimination of hypochlorite. ECF bleaching also includes high shear 
    mixing to ensure adequate mixing of pulp and bleaching chemicals. This 
    technology basis reflects the results of laboratory trials showing the 
    ability to produce the full range of products manufactured by specialty 
    grade mills, with acceptable final product characteristics. (This 
    discussion also applies to PSES for this segment.)
        EPA is also promulgating voluntary alternative BAT limitations 
    based on TCF bleaching processes in order to encourage mills to use 
    this technology whenever it is consistent with their product mix. See 
    40 CFR 430.54(a)(3) and 430.56(a)(3). Alternative TCF limitations are 
    also available for new sources in this segment.
        In addition to finding that the ECF bleaching process described 
    above is technically available for the specialty grade segment, EPA has 
    also determined that it is economically achievable. In order to 
    evaluate the economic achievability of ECF bleaching for this segment, 
    EPA considered the costs that the one mill currently in this segment 
    would incur to convert to ECF processes. As part of that analysis, EPA 
    also included the costs of complying with today's BMP regulations. 
    Because of the small size of this segment, EPA is not disclosing here 
    the estimated capital costs, operation and maintenance costs, or post-
    tax annualized costs for this segment in order to protect confidential 
    business information. However, EPA has determined that the sole 
    existing mill in this segment is not projected to close, nor is its 
    firm projected to fail, as a result of today's BAT limitations and PSES 
    for this segment. This result obtains both when the impacts of today's 
    BAT/PSES are considered together with the impacts of compliance with 
    the MACT I costs, and when they are considered alone. Therefore, EPA 
    has concluded that ECF bleaching is economically achievable for the 
    specialty grade segment. See DCN 14376 and DCN 14388 (both CBI).
        For the foregoing reasons, EPA has selected the model ECF bleaching 
    process described above as the basis for BAT limitations and PSES for 
    the specialty grade segment.
        (3) Pollutant Parameters Regulated for Each Segment. (i) Calcium-,
    Magnesium-, or Sodium-Based Sulfite Mills. Because the Agency is 
    promulgating BAT effluent limitations for this segment based on TCF 
    bleaching technology, the maximum reduction in the discharge of 
    chlorinated pollutants from bleaching operations will be achieved. This 
    is because no chlorine or chlorine-containing bleaching chemicals are 
    used and, hence, no chlorinated pollutants are generated during 
    bleaching. For this reason, EPA is not setting effluent limitations for 
    dioxin, furan, chloroform, or the 12 specified chlorinated phenolic 
    pollutants for TCF bleaching. However, EPA is setting limitations on 
    AOX (expressed as a level below the Minimum Level identified in today's 
    analytical method for AOX) for mills in the calcium-, magnesium-, or 
    sodium-based sulfite pulp segment of the Papergrade Sulfite subcategory 
    in order to reflect the performance of TCF bleaching processes. See 40 
    CFR 430.54(a)(1). EPA is reserving promulgation of COD limitations for 
    this segment until such time that sufficient performance data are 
    available because the performance of the BAT technology basis on this 
    parameter cannot be accurately predicted from laboratory-scale data.
        (ii) Ammonium-Based Sulfite Mills. EPA is promulgating effluent 
    limitations for dioxin, furan, and 12 chlorinated phenolic pollutants 
    for the ammonium-based segment. See 40 CFR 430.54(a)(2). EPA is 
    reserving promulgation of chloroform limitations, AOX limitations, and 
    COD limitations for this segment until such time that sufficient 
    performance data are available because the performance of the BAT 
    technology basis on these parameters cannot be accurately predicted 
    from laboratory-scale data. One mill is currently installing, on a full 
    scale, the promulgated BAT technology basis. EPA expects to have data 
    to develop chloroform, AOX, and COD limitations for this segment once 
    this installation is complete, the mill is operating the new equipment 
    in a routine manner, and appropriate samples are collected and 
    analyzed.
        (iii) Specialty Grade Sulfite Mills. EPA is promulgating effluent 
    limitations for dioxin, furan, and 12 chlorinated phenolic pollutants 
    for the specialty grade segment, based on laboratory scale data. See 40 
    CFR 430.54(a)(3). EPA is reserving promulgation of chloroform, AOX, and 
    COD limitations for this segment until such time that sufficient full 
    scale performance data are available because the performance of the BAT 
    technology basis on these parameters cannot be accurately predicted 
    from laboratory scale data.
        (4) Costs. As discussed in the July 1996 Notice, EPA revised its 
    cost estimates for mills in the Papergrade Sulfite subcategory by using 
    the revised bleaching sequences outlined in paragraph (2) above. EPA 
    also updated equipment cost curves and unit operating costs. See 61 FR 
    at 36845. The detailed basis of these revised cost estimates are 
    provided in the record.
        The following cost estimates reflect the total costs that mills in 
    the Papergrade Sulfite subcategory are likely to incur as a result of 
    today's BAT limitations, PSES, and BMP regulations, and are the bases 
    for EPA's economic impact analyses discussed in paragraph (2) above. 
    For this subcategory, EPA's estimated capital costs are $73.8 million, 
    operation and maintenance costs are $7 million, and post-tax annualized 
    costs are $9.8 million. (The general and administrative costs discussed 
    in Section VIII.B.1.c are already included here.) See Section VIII for 
    additional discussion of costs and economic impacts.
        (5) Effluent Reductions. EPA has updated the calculation of 
    effluent reductions for each papergrade sulfite mill, adjusting the 
    baseline to mid-1995. EPA used methodology similar to that used for the 
    Bleached Papergrade Kraft and Soda subcategory. As a result of the BAT 
    limitations and PSES promulgated today, EPA estimates that for the 
    Papergrade Sulfite subcategory, discharges of dioxin and furan will be 
    reduced by seven grams to less than one gram per year. (EPA expects no 
    discharges of dioxin and furan from TCF bleaching.) Total discharges of 
    chlorinated phenolic pollutants will be
    
    [[Page 18560]]
    
    reduced by 1,770 kilograms to 240 kilograms per year. As a result of 
    the TCF limitations and PSES on mills in the calcium-, magnesium-, or 
    sodium-based sulfite segment and as an incidental result of 
    implementing the ECF model technology by direct and indirect 
    discharging mills in the other two segments, discharges of AOX will be 
    reduced by 4,010 metric tons to 370 metric tons per year. For a 
    discussion of the environmental benefits resulting from these 
    reductions, see Section VIII.G.2, and Chapter 8 of the Economic 
    Analysis, DCN 14649.
        (6) Development of Limitations. All of the limitations and 
    standards promulgated today for Subpart E are expressed as ``5 discharge was 
    used to characterize the best demonstrated performance. EPA concluded 
    that data in the record is not representative of the performance that 
    can be achieved in the Papergrade Sulfite subcategory as a whole. For 
    this reason, the new source performance standards for conventional 
    pollutants promulgated today for each segment of the Papergrade Sulfite 
    subcategory are the same as those promulgated in the 1982 NSPS 
    regulation. See 47 FR 52006, 52036 (Nov. 18, 1982) (for former Subpart 
    O); 48 FR 13176, 13177 (Mar. 30, 1983) (for former Subpart J).
        In selecting its NSPS technology, EPA considered all of the factors 
    specified in CWA section 306, including the cost of
    
    [[Page 18561]]
    
    achieving effluent reductions. The selected NSPS technologies are 
    presently being employed at mills in each segment of this subcategory. 
    Moreover, the cost of the NSPS technology is an insignificant fraction 
    of the capital cost of a new mill (less than one percent). Finally, EPA 
    has determined that the costs of including the selected NSPS 
    technologies at a new source are substantially less on a per-ton basis 
    than the costs of retrofitting existing mills. See Chapter 6 of the 
    Economic Analysis document (DCN 14649). Therefore, EPA has concluded 
    that such costs do not present a barrier to entry. The Agency also 
    considered energy requirements and other non-water quality 
    environmental impacts for the selected NSPS options and concluded that 
    these impacts were no greater than for the selected BAT technology 
    options and are acceptable. See the Supplemental Technical Development 
    Document, DCN 14487. EPA therefore concluded that the NSPS technology 
    bases selected for each segment of the papergrade sulfite segment 
    constitutes the best available demonstrated control technology for that 
    segment.
        d. Pretreatment Standards. EPA is promulgating pretreatment 
    standards for new and existing sources for three segments of the 
    Papergrade Sulfite subcategory based on the BAT and NSPS technologies 
    selected for each segment. In determining PSES, EPA considered the age, 
    size, processes, other engineering factors, and non-water quality 
    environmental impacts pertinent to Subpart E mills. None of these 
    factors provided a basis for selecting different PSES technologies. For 
    each segment, EPA selected the best technology available to produce the 
    products in each segment. Each of the selected PSES technologies is 
    economically achievable and has no unacceptable adverse non-water 
    quality impacts. With respect to PSNS for these segments, EPA concluded 
    that the selected technologies represent the best available 
    demonstrated control technologies that are capable of producing each 
    segment's products. EPA also concluded that there was no barrier to 
    entry for the reasons set forth in section VI.B.6.c. above for NSPS for 
    this subcategory.
        In order to determine which pollutants to regulate under PSES and 
    PSNS, EPA used the same pass-through analysis it employed for the 
    Bleached Papergrade Kraft and Soda subcategory described in section 
    VI.B.5.c(2) above. EPA concluded that dioxin, furan, and the 12 
    chlorinated phenolic pollutants pass through or interfere with POTW 
    operations for the ammonium and specialty grade segments for the 
    reasons set forth in section VI.B.5.c(2) for Subpart B. This reasoning 
    applies because the BAT/PSES model technologies for Subparts B and E 
    are both based on ECF process technologies; the same is also true for 
    the NSPS/PSNS technologies (although in neither subpart does the model 
    pretreatment technology include secondary biological wastewater 
    treatment). Based on its pass-through determination, EPA is 
    promulgating national pretreatment standards for new and existing 
    sources for those pollutants for those segments. These standards are 
    expressed as `` The requirement to develop BMPs should be limited to spent 
    pulping liquor (e.g., kraft black liquor, sulfite red liquors) and 
    should exclude kraft green and white liquors and fresh sulfite pulping 
    liquors;
         The proposed regulation was overly prescriptive in general 
    and, in particular, the requirement for secondary containment was 
    unnecessary to meet the objectives of the proposed regulation;
         EPA underestimated the costs for implementing BMPs;
         EPA lacks the authority to establish BMPs to control 
    pollutants that are not identified as toxic under CWA section 307(a) or 
    hazardous under CWA section 311; and
         EPA lacks the authority to impose BMPs on indirect 
    dischargers.
        In response to comments, EPA undertook several initiatives to 
    understand industry's concerns about the proposed BMP requirements; to 
    better understand the status of the industry with respect to pulping 
    liquor management and spill prevention and control; and to better 
    assess the BMP compliance costs. To supplement its understanding of 
    industry's spent pulping liquor management and spill prevention and 
    control practices, EPA visited more than 25 chemical pulp mills in the 
    United States and 15 mills in Canada and Europe following its 1993 
    proposal. These mills included bleached and unbleached kraft mills and 
    papergrade sulfite mills (see Docket Sections 21.5.1 and 21.5.3). EPA 
    also reviewed the results of the NCASI BMP questionnaire distributed to 
    the industry. Questionnaire responses were received from approximately 
    70 bleached and unbleached kraft, soda, and sulfite mills. Through this 
    NCASI questionnaire EPA received a substantial amount of additional 
    information about mill practices and costs for equipment, monitoring 
    systems, and facility modifications (see Docket Section 21.1.3). In 
    addition, EPA held detailed discussions with stakeholders regarding 
    options for BMPs and associated costs. Much of this information was 
    included in the Docket and made available to the public in conjunction 
    with the Notice of Data Availability published in the Federal Register 
    on July 5, 1995 (60 FR 34938). Additional information related to 
    development of the BMP requirements, including changes in the wording 
    and organization of the proposed rule, was discussed in the July 1996 
    Notice. See 61 FR at 36835.
        Based on the information and data received since proposal, EPA 
    revised the scope of the BMP requirements to focus on control of spent 
    pulping liquor, turpentine, and soap. The BMP requirements were 
    restructured to allow greater flexibility in how BMPs are implemented 
    to address site-specific circumstances in achieving meaningful 
    prevention and control of leaks and spills. EPA also reorganized the 
    regulatory text from that presented in the record for the July 1996 
    Notice to provide greater ease of use by mill operators and permit 
    writers, and to clarify the intent of particular BMP requirements. The 
    most significant changes since proposal are discussed below.
        In December 1993, EPA proposed BMPs for seven subcategories of the 
    pulp, paper, and paperboard industry (58 FR at 66078), all of which 
    chemically pulp wood and non-wood fibers. EPA still believes BMPs are 
    appropriate for each of these chemical pulping subcategories; however, 
    to be consistent with the effluent limitations guidelines and standards 
    promulgated in this final rule, the BMPs promulgated today are 
    applicable only to the Bleached Papergrade Kraft and Soda and 
    Papergrade Sulfite subcategories. EPA expects to promulgate BMPs for 
    the remaining five chemical pulping subcategories [(Subparts A 
    (Dissolving Kraft), C (Unbleached Kraft), D (Dissolving Sulfite), F 
    (Semi-chemical), and H (Non-wood Chemical Pulp)] as it promulgates new 
    effluent limitations guidelines and standards for these subcategories. 
    Until new regulations for Subparts A, C, D, F, and H are promulgated, 
    permit writers may wish to use the BMP regulations in this rule as a 
    guide to issuing permits containing BMPs based on best professional 
    judgment for mills with production covered by these other subparts. See 
    CWA Section 402(a)(1); 40 CFR 122.44(k). POTWs may need to impose BMPs 
    as local limits to facilities in these subcategories. See 40 CFR 403.5.
        The BMP provisions in the proposed rule were structured to apply to 
    all pulping liquors. In response to comments, EPA has revised the scope 
    of the BMPs and for the final rule is limiting the BMP applicability to 
    spent pulping liquors, turpentine, and soap. EPA has determined that 
    spent pulping
    
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    liquors contain toxic components and that these materials, if 
    uncontrolled, pass through or interfere with the operation of POTWs and 
    may interfere with industrial wastewater treatment systems at mills 
    that discharge directly to surface waters. EPA has excluded green, 
    white and other intermediate pulping liquors (e.g., fresh sulfite 
    pulping liquors) from this BMP rule because the data in the record does 
    not indicate that these materials pass through wastewater treatment 
    systems. Turpentine and soap are included in the BMP rule because, if 
    spilled or lost, these materials can interfere with wastewater 
    treatment operations and lead to increased discharges of toxic, 
    nonconventional, and conventional pollutants.
        In December 1993, EPA proposed to require mills to provide 
    secondary containment for all pulping liquor bulk storage tanks. EPA 
    has since determined that spill prevention can be adequately achieved 
    for spent pulping liquor bulk storage tanks by substituting annual tank 
    integrity testing and other containment or diversion structures (e.g., 
    curbs and berms) in place of secondary containment. The final rule 
    provides flexibility for mills to choose either secondary containment 
    or annual tank integrity testing, coupled with other containment or 
    diversion structures, to comply with this requirement for spent pulping 
    liquor bulk storage tanks. See 40 CFR 430.03(c)(7). EPA determined that 
    secondary containment should be required at all times for turpentine 
    bulk storage tanks because of the extreme toxic effects a turpentine 
    spill would have on the biological treatment system, and because the 
    size of turpentine bulk storage tanks is such that secondary 
    containment is easily achieved. In fact, EPA has found that most mills 
    already provide secondary containment for their turpentine bulk storage 
    tanks. No secondary containment is required for soap bulk storage 
    tanks.
        As discussed in the July 1996 Notice, EPA also proposed adding a 
    requirement to the BMP regulation that would require mills to implement 
    a monitoring program for the purpose of detecting leaks and spills, 
    tracking the effectiveness of the BMPs, and detecting trends in spent 
    pulping liquor losses. EPA proposed requiring mills to monitor 
    wastewater treatment system influent for a short-term measure of 
    organic content that can be completed on a daily basis (e.g., Chemical 
    Oxygen Demand (COD) or Total Organic Carbon (TOC)). EPA has promulgated 
    this requirement (see 40 CFR 430.03 (h) and (i)), but in response to 
    comments, EPA is also allowing mills to use an alternative parameter 
    related to spent pulping liquor losses that can be measured 
    continuously and averaged over 24 hours (e.g., specific conductivity or 
    color). See 40 CFR 430.03(h)(2)(i). In conjunction with this 
    monitoring, mills are required by today's regulation to establish 
    action levels (using the measure of daily pollutant loading) that, when 
    exceeded, trigger investigative and corrective action, as appropriate, 
    to reduce the wastewater treatment system influent mass loading. See 40 
    CFR 430.03(h).
        The proposed rule would have required certification of the BMP plan 
    by a registered professional engineer (P.E.) and approval by the mill 
    manager. The intent of the proposed P.E. certification was to assure 
    preparation of a comprehensive BMP Plan that is tailored to the site-
    specific circumstances at the mill. Industry commented that many mills 
    have no registered professional engineers on site. For mills without a 
    P.E. onsite, the proposed requirement would result in the plan being 
    certified by someone not involved with the mill on a daily basis, and 
    someone not responsible for its operation. EPA has determined that 
    requiring certification by a P.E. is unnecessarily prescriptive and may 
    have unintended results. The final regulation deletes the requirement 
    for certification by a registered P.E. and now requires the BMP Plan to 
    be reviewed by the senior technical manager at the mill and approved 
    and signed by the mill manager. See 40 CFR 430.03(f).
        The regulation was proposed to be self-implementing for both direct 
    and indirect dischargers. EPA has revised the regulation to make it 
    clear that BMPs imposed on direct dischargers are not self-
    implementing, but rather apply only when incorporated into NPDES 
    permits. See 40 CFR 430.03(j). This is consistent with CWA sections 
    304(e) and 402. The final regulation remains self-implementing for 
    indirect dischargers. Id.
        The final regulation extends compliance schedules for plan 
    preparation and plan implementation to grant more time for the 
    preparation of the initial BMP Plan and installation of monitoring and 
    alarm systems. Based on information supplied by industry regarding the 
    time required in past efforts to develop spill prevention programs, EPA 
    determined that 12 months was reasonable to complete the development of 
    the BMP Plan and includes that deadline in the regulation. Similarly, 
    EPA determined that it is reasonable to require mills to commence 
    operation of any new monitoring systems no later than 24 months 
    following publication of the final rule. This compliance date provides 
    sufficient time between BMP Plan preparation and operation of new 
    monitoring systems (i.e., 12 months) to allow implementation of BMPs in 
    a rational and effective manner.
        The final BMP regulation is less prescriptive than proposed with 
    regard to inspection, repair and log-keeping requirements. While many 
    of the elements included in the proposed rule remain, EPA determined 
    that the specificity of the language in the proposed regulation could 
    be redundant to existing practices in place at some mills and be 
    unnecessarily burdensome. EPA believes the language in the final rule 
    will achieve the same results as it intended in the proposed rule while 
    allowing mills to use existing maintenance and repair tracking systems 
    to fulfill the requirement. See 40 CFR 430.03(c).
        As discussed in the July 1996 Notice, EPA used the information 
    obtained since proposal to revise its cost estimates for BMPs. See 61 
    FR at 36840. At proposal, EPA's estimated costs were based on the 
    reported total project costs for two older bleached kraft mills to 
    install spill prevention and control systems. After adjusting the costs 
    to reflect the size of a ``typical'' mill, EPA then assumed that these 
    costs reflected the average cost incurred by bleached papergrade kraft 
    and soda and papergrade sulfite mills to install BMPs. EPA then imputed 
    to some mills compliance costs less than that average cost depending on 
    the extent EPA judged they had implemented BMPs (see Technical Support 
    Document for Proposed Best Management Practices Programs: Pulping 
    Liquor Management, Spill Prevention and Control, November 1993. Docket 
    Section 17.4, DCN 08307).
        EPA improved its estimates of industry-wide costs for compliance 
    with the BMP requirements in the final rule, compared to the cost 
    methodology used for the proposed regulation. These changes were 
    discussed in the July 1996 Notice and in the accompanying Draft 
    Technical Support Document for Best Management Practices Programs: 
    Spent Pulping Liquor Management, Spill Prevention and Control, May 1996 
    (DCN 13894). EPA's supplemental mill visits and the NCASI survey 
    responses have resulted in a more accurate status of the existing BMP 
    infrastructure and programs at mills. This information was used to 
    create model BMP mill requirements for each level of mill complexity 
    and to classify mills by complexity level. EPA then used data
    
    [[Page 18565]]
    
    provided by the industry in comments and the NCASI survey to develop 
    unit costs for major equipment items, facility modifications, 
    monitoring systems and BMP Plan preparation, rather than using the 
    total project costs reported by two mills as was done at proposal. 
    Finally, EPA incorporated the estimates of net operating and 
    maintenance costs of BMPs into the BAT/PSES cost model. The cost model 
    tracked the impacts of increased pulping liquor recovery on the 
    evaporators and chemical recovery system and determined the need for 
    equipment upgrades resulting from the combined effect of BAT/PSES 
    process changes and BMPs. The savings from reduced load on the 
    wastewater treatment system and increased recovery of fiber, chemicals 
    and energy were subtracted from the BMP operating costs (i.e., 
    increased evaporation energy, tank integrity testing, operator 
    training, and O&M costs for new equipment).
        EPA disagrees with comments asserting that EPA lacks authority to 
    establish BMPs for pollutants that are not identified as toxic under 
    CWA section 307(a) or hazardous under CWA section 311. First, the non-
    toxic and non-hazardous pollutants controlled by these BMPs are found 
    in the same wastestreams bearing pollutants specifically identified as 
    toxic pollutants or hazardous substances under sections 307(a) and 311 
    and implementing regulations. Although reductions of these pollutants 
    are significant in environmental effect, their control is incidental to 
    the control of all the pollutants subject to section 304(e). Second, 
    EPA has independent authority under section 402(a)(1) to establish 
    NPDES permit conditions, including BMPs, for any pollutant when such 
    conditions are necessary to carry out the provisions of the statute. 
    See 40 CFR 122.44(k). This authority operates independently of section 
    304(e). Indeed, when Congress enacted section 304(e) specifically for 
    toxic pollutants and hazardous substances, it acknowledged that section 
    402(a)(1) already provided authority for imposing BMPs in NPDES 
    permits. See Statement of Sen. Muskie (Dec. 15, 1977), reprinted in 
    Legislative History of the Clean Water Act of 1977, at 453. EPA's 
    authority to establish permit conditions under section 402(a)(1) is 
    very broad. See NRDC v. Costle, 568 F.2d 1369, 1380 (D.C. Cir. 1977). 
    EPA has determined that mills without an adequate BMP program, such as 
    that codified today, may experience undetected and uncontrolled leaks 
    and spills that could disrupt the efficiency of their treatment 
    systems, thus resulting in exceedances of the BAT limitations and NSPS 
    promulgated today for subparts B and E. Moreover, the BMPs control 
    pollutants that are not explicitly regulated under BAT and NSPS. 
    Therefore, EPA determined that BMPs applicable to all pollutants in a 
    mill's spent pulping liquor, turpentine, and soap were necessary in 
    order to carry out the purposes of the Clean Water Act and hence are 
    authorized under section 402(a)(1) and 40 CFR 122.44(k). Similarly, as 
    discussed below, BMPs are authorized as pretreatment standards for 
    pollutants in the spent pulping liquor, turpentine, and soap when they 
    pass through or interfere with POTW operations.
        Some commenters also objected to EPA's decision to establish the 
    BMP program by regulation rather than deferring to the case-by-case 
    determinations of permit writers. EPA agrees that a requirement to 
    establish and implement BMPs of the type required by this rule could be 
    imposed on a case-by-case basis under CWA section 402(a)(1) and 40 CFR 
    122.44(k). However, EPA rejected this approach for a number of reasons. 
    First, section 304(e) expressly authorizes EPA to promulgate BMPs by 
    regulation on a categorical basis. The spent pulping liquors, soap, and 
    turpentine covered by these BMPs contain numerous toxic pollutants and 
    hazardous substances subject to section 304(e) and hence may be 
    controlled by regulation. Moreover, EPA determined that implementing 
    the BMP program by regulation is necessary to ensure that each pulp and 
    paper mill with pulp production in subparts B or E implements the type 
    of BMPs that EPA has determined are fundamental to an effective BMP 
    program for this industry. While the BMP regulation is intended to 
    provide considerable flexibility to mills in designing their BMP 
    programs, EPA has also determined that the various BMPs specified in 
    the regulation are necessary to assure uniform and fair application of 
    the requirements. Finally, EPA believes that the regulation represents 
    an appropriate and efficient use of its technical expertise and 
    resources that, when exercised at the national level, will relieve 
    permit writers of the burden of implementing this aspect of the Clean 
    Water Act on a case-by-case basis.
        EPA also disagrees with comments asserting that EPA lacks authority 
    to impose BMPs on indirect discharges. These BMPs are pretreatment 
    standards under section 307(b) and (c). Pretreatment standards for new 
    and existing sources under section 307 are designed to prevent the 
    discharge of pollutants that pass through POTWs or that interfere with 
    or are otherwise incompatible with treatment processes or sludge 
    disposal methods at POTWs. To determine whether pollutants associated 
    with spent kraft and sulfite pulping liquors, soap, and turpentine that 
    are indirectly discharged by mills with pulp production in subparts B 
    or E interfere with POTW operations or pass through untreated, EPA 
    reviewed data collected from 1988 through 1992 at a POTW that receives 
    effluent from a bleached papergrade kraft mill. Prior to 1990-91, the 
    mill had virtually no facilities for control and collection of spent 
    pulping liquor leaks and spills. POTW discharge monitoring records show 
    the fully treated effluent exhibited consistent chronic toxicity to 
    Daphnia from April 1988 until June 1991. The data further show that the 
    toxic effects of the POTW's effluent have been reduced since 
    implementation by the mill of effective spent pulping liquor management 
    and spill prevention and control. These effluent toxicity effects can 
    be related to the wood extractive components that are measurable by COD 
    and are found in leaks and spills of spent kraft and sulfite pulping 
    liquors that interfere with the performance of biological treatment 
    systems and allow toxic pollutants to pass through inadequately 
    treated. Indeed, evidence of such interference and pass-through was 
    found in data from this mill and the POTW, which showed higher mass 
    effluent loadings for COD, TSS and BOD5 before the mill 
    implemented a BMP program. After the BMP program was implemented, mass 
    effluent loadings of these pollutants were reduced. Data for COD, in 
    particular, indicated that short-term interference of POTW operations 
    previously observed at higher COD levels was being mitigated. EPA also 
    bases its pass-through finding on an incident occurring in 1993 at a 
    different mill where an intentional diversion of spent pulping liquor 
    debilitated the mill's secondary treatment system and killed fish in 
    the receiving waters. These data led EPA to conclude that inadequate 
    management and control of leaks and spills of spent pulping liquor, 
    soap, and turpentine interfered with POTW operations and caused pass-
    through of pollutants. Because direct discharging mills using these 
    BMPs achieve very high removals and because POTWs cannot achieve 
    similar removals in the absence of BMPs employed by the indirect 
    discharger, EPA has determined that pollutants in spent pulping liquor, 
    soap, and turpentine, in the absence of controls on leaks, spills, and 
    intentional diversions, can cause disruption and interference and do 
    indeed pass through
    
    [[Page 18566]]
    
    at POTWs. For this reason, EPA is including as part of its pretreatment 
    standards the requirement that indirect discharging mills implement 
    BMPs in accordance with this regulation.
    8. Regulatory Implementation for Effluent Limitations Guidelines and 
    Standards
        a. Applicability of Effluent Limitations Guidelines and Standards. 
    Effluent limitations act as a primary mechanism to control discharges 
    of pollutants to waters of the United States. These limitations are 
    applied to individual mills through NPDES permits issued by EPA or 
    authorized States under section 402 of the CWA. In addition, the 
    pretreatment standards are directly applicable to indirect dischargers. 
    Once today's regulations become effective, the effluent limitations and 
    standards for the appropriate subcategory must be applied in all 
    Federal and State NPDES permits issued to direct dischargers affected 
    by this rule. See Section 301(b)(2), 402(a). This section describes the 
    applicability of these limitations and standards to process and other 
    wastewaters generated by the mills in the Bleached Papergrade Kraft and 
    Soda and Papergrade Sulfite subcategories, defines new sources subject 
    to today's NSPS and PSNS, defines non-continuous dischargers and the 
    applicable limitations, and describes the retention of the previously 
    promulgated limitations and standards.
        (1) Applicability of Limitations to Process and Other Wastewaters. 
    The effluent limitations guidelines and standards for the pulp and 
    paper industry apply to discharges of process wastewaters directly 
    associated with the manufacturing of pulp and paper. See 40 CFR 430.00. 
    EPA proposed a definition of process wastewater as any water that, 
    during manufacturing or processing, comes into direct contact with or 
    results from the production or use of any raw material, intermediate 
    product, finished product, byproduct, or waste product. The proposed 
    definition specifically included boiler blowdown; wastewaters from 
    water treatment and other utility operations; blowdown from high rate 
    (e.g., greater than 98 percent) recycled non-contact cooling water 
    systems to the extent they are mixed and co-treated with other process 
    wastewaters; and stormwaters from the immediate process areas to the 
    extent they are mixed and co-treated with other process wastewaters. 
    The proposed definition specifically provided that contaminated 
    groundwaters from on-site or off-site groundwater remediation projects 
    would not be process wastewaters. EPA proposed to require separate 
    permitting for the discharge of such groundwaters. The proposed 
    definition also specifically excluded certain process materials from 
    the definition of process wastewater. These process materials included: 
    Green liquor at any liquor solids level; white liquor at any liquor 
    solids level; black liquor at any liquor solids level resulting from 
    processing knots and screen rejects; black liquor after any degree of 
    concentration in the kraft or soda chemical recovery process; 
    reconstituted sulfite and semi-chemical pulping liquors prior to use; 
    any pulping liquor at any liquor solids level resulting from spills or 
    intentional diversions from the process; lime mud and magnesium oxide; 
    pulp stock; bleach chemical solutions prior to use; and papermaking 
    additives prior to use (e.g., alum, starch and size, clays and 
    coatings). The proposed regulation then would have prohibited the 
    discharge of these materials into POTWs or waters of the United States 
    without an NPDES permit or other authorization.
        In this final rule, EPA is promulgating a definition of process 
    wastewater applicable to subparts B and E. In response to the comments 
    opposing the exclusion of these process materials, EPA revised the 
    proposed definition of process wastewaters to eliminate the exclusion 
    of the named process materials. See 40 CFR 430.01(m). The proposed 
    language would have effectively required ``closed cycle'' mills, which 
    was not EPA's intent. The exclusion of contaminated groundwater has 
    been retained. Because the quantity and quality of such groundwaters 
    are likely to be highly variable on a site-specific basis, the Agency 
    concluded that their discharge to surface waters should be regulated 
    separately from, or in addition to, process wastewaters on a case-by-
    case basis. EPA also has included leachate wastewaters from landfills 
    owned and operated by mills generating wastes associated with 
    manufacturing or processing subject to subparts B and E, where these 
    leachate wastewaters are commingled with other process wastewaters. 
    These leachate wastewaters typically comprise a very small proportion 
    of the total volume received in end-of-pipe wastewater treatment 
    facilities. In cases where the volumes or pollutants found in leachate 
    wastewaters are of concern, permit writers may develop individual 
    permit limitations on a case-by-case basis. EPA's definition continues 
    to define process wastewater in terms of manufacturing or processing. 
    EPA has promulgated a subcategory-specific definition of process 
    wastewater in order to clarify the applicability of subparts B and E 
    and to assist permit writers and pretreatment authorities in developing 
    limitations and standards. The effluent limitations guidelines and 
    standards promulgated today do not apply to discharges that are not 
    associated with manufacturing or processing. Any mill wishing to 
    discharge such wastewaters would need to obtain authorization in an 
    NPDES permit or individual control mechanism administered by a POTW.
        EPA's use of the term ``during manufacturing or processing'' should 
    not be taken to exclude wastewaters generated during routine 
    maintenance, including maintenance occurring during a scheduled 
    temporary mill shut-down. Maintenance wastewaters were not explicitly 
    excluded from the definition of process wastewater at proposal, nor are 
    they excluded from the definition promulgated today. Wastewaters 
    generated during routine maintenance are a result of pulp manufacturing 
    processes and as such are included in the definition of process 
    wastewater.
        (2) Definition of New Source. In today's rule, EPA is promulgating 
    a definition of ``new source'' applicable to Part 430, subparts B and 
    E. See 40 CFR 430.01(j). This definition restates the definition set 
    forth in 40 CFR 122.29(b)(1), but with the additional reference to 
    certain process changes that, in and of themselves, would not cause a 
    mill to become a new source. See 40 CFR 430.01(j)(2). EPA intends that 
    permit writers will consult the specific ``new source'' criteria in 
    Part 430, rather than the more general criteria set forth in 40 CFR 
    122.29(b)(1) and 403 when determining whether pulp and paper mills 
    subject to subparts B or E are new sources. The other provisions of 40 
    CFR 122.29 continue to apply to these subparts, as do 40 CFR 122.2 and 
    40 CFR 403.3(k). The definition of ``new source'' in Part 430 does not 
    affect the definition of ``new source'' for purposes of the NESHAP 
    portion of these integrated rules.
        EPA is aware that application of the definitions in Part 122 to 
    pulp and paper mills in the Bleached Papergrade Kraft and Soda and 
    Papergrade Sulfite subcategories has sometimes caused controversy, 
    leading to disagreement between the permitting authority and the 
    facility whether a particular change at the mill triggers NSPS or PSNS. 
    EPA is promulgating a definition of ``new source'' specifically for 
    subparts B and E in order to set forth the specific factors relevant to 
    a new source determination for covered mills and thus, EPA hopes, to 
    end the disputes regarding a mill's
    
    [[Page 18567]]
    
    new source status. Indeed, the decision to promulgate subcategory-
    specific criteria in this rule is specifically contemplated by the 
    general criteria codified at 40 CFR 122.29(b)(1). EPA believes this 
    tailored definition is particularly important in view of the Voluntary 
    Advanced Technology Incentives Program EPA is also promulgating today 
    for subpart B mills. Through the Voluntary Advanced Technology 
    Incentives Program, EPA is encouraging mills to install new process 
    technologies and even to redesign bleach plant operations in order to 
    achieve effluent reductions beyond those required at the baseline BAT 
    level. EPA does not want existing mills that voluntarily choose to 
    participate in the Voluntary Advanced Technology Incentives Program to 
    be required to meet NSPS simply as a consequence of that election. 
    Therefore, by promulgating a definition of ``new source'' specifically 
    for subparts B and E, EPA hopes not only to clarify application of the 
    Part 122 definitions but also to provide certainty to subpart B mills 
    choosing to participate in the Voluntary Advanced Technology Incentives 
    Program that they will not inadvertently become a new source, which 
    would subject them to compulsory NSPS.
        For the convenience of the permit writer, the definition of new 
    source being codified in part 430 restates the three criteria already 
    codified in Sec. 122.29(b)(1). The first criterion provides that a 
    source is a new source if it is constructed at a site at which no other 
    source is located. Section 430.01 (j)(1)(i); see 40 CFR 
    122.29(b)(1)(i). As applied to part 430, this criterion is intended to 
    ensure that a greenfield mill is characterized as a new source and 
    hence is subject to NSPS or PSNS.
        The second criterion specified in today's definition of new source 
    incorporates the language of 40 CFR 122.29(b)(1)(ii) with two 
    additions. First, it provides that a fiber line that totally replaces 
    an existing fiber line is a new source (unless that fiber line is 
    enrolled in the Voluntary Advanced Technology Incentives Program). 
    Second, it includes a list of modifications that would not trigger the 
    new source definition if made by subpart B or E mills. See 40 CFR 
    430.01(j)(1)(ii) and (2). This criterion provides essentially that a 
    fiber line that is modified to comply with baseline BAT effluent 
    limitations or that is totally rebuilt to comply with Advanced 
    Technology BAT limitations is not a new source. (A fiber line is a 
    series of operations employed to convert wood or other fibrous raw 
    material into pulp. If the final product is bleached pulp, the fiber 
    line encompasses pulping, de-knotting, brownstock washing, pulp 
    screening, centrifugal cleaning, and multiple bleaching and washing 
    stages.)
        Among the changes specified in the regulation that alone do not 
    cause an existing fiber line at a mill to be considered a new source 
    are: Upgrades of existing pulping operations; upgrades or replacement 
    of pulp screening and washing operations; installation of extended 
    cooking and/or oxygen delignification systems or other post-digester, 
    pre-bleaching delignification systems; and bleach plant modifications 
    including changes in methods or amounts of chemical applications, new 
    chemical applications, installation of new bleaching towers to 
    facilitate replacement of sodium or calcium hypochlorite, and 
    installation of new pulp washing systems. 40 CFR 430.01(j)(2)(i)-(iv). 
    By expressly excluding these process modifications from the new source 
    definition, EPA thus allows a mill to implement the baseline BAT/PSES 
    technologies without triggering NSPS or PSNS. EPA believes that 
    interpreting process modifications that are designed to achieve 
    compliance with baseline BAT/PSES limitations as an existing source 
    modification is consistent with Congress' intentions in the Clean Water 
    Act concerning the respective roles of standards for existing and new 
    sources.
        As discussed in more detail below in connection with the third new 
    source criterion, EPA believes it is appropriate to define a new fiber 
    line as a new source because the construction of the new fiber line 
    (whether to supplement or replace an existing fiber line) presents the 
    type of pollution prevention opportunities customarily represented by 
    NSPS. However, EPA believes it is also appropriate to treat the 
    replacement fiber line as an existing source if that fiber line is 
    enrolled in the Voluntary Advanced Technology Incentives Program. See 
    40 CFR 430.01(j)(2)(v). EPA has decided to do this because requiring 
    the new fiber line to meet baseline NSPS requirements would defeat the 
    purpose of the Voluntary Advanced Technology Incentives Program by 
    undercutting the more environmentally protective pollution prevention 
    opportunities and limitations associated with that program. In the 
    first place, Advanced Technology BAT limitations at the Tier II and 
    Tier III levels are more stringent than the baseline NSPS requirements; 
    EPA's definition of new source thus is intended to allow mills to 
    commit to greater pollutant reductions than EPA could otherwise compel 
    and to do so incrementally while maintaining use of the existing fiber 
    line in the interim. Similarly, the Advanced Technology BAT limitations 
    at the Tier I level promote pollution prevention opportunities not 
    necessarily assured by NSPS, even though the technology bases for NSPS 
    and Tier I are similar. EPA has established different limitations for 
    Tier I than for NSPS because the regulations are intended to achieve 
    different objectives. The new source performance standards for AOX are 
    more stringent because, as a statistical matter, EPA determined that 
    this performance level reflects the best demonstrated performance by 
    mills using the NSPS technology. The Tier I limitations for AOX, in 
    contrast, are intended to reflect a more inclusive performance level 
    that EPA believes existing mills employing extended delignification can 
    achieve, in order to encourage more mills to implement extended 
    delignification technologies. The Tier I limitations also require the 
    recycle of filtrates to the recovery systems and impose limitations on 
    the lignin content of unbleached pulp, which EPA hopes will promote the 
    use of particular pollution prevention technologies and, in turn, 
    encourage mills to look beyond Tier I to the Tier II and Tier III 
    levels. This goal contrasts with the objective of NSPS, which simply is 
    to compel mills to achieve certain discharge levels by any combination 
    of technologies the mill selects, and would be defeated if the 
    definition of new source would have the effect of moving Tier I mills 
    into NSPS. Therefore, EPA has decided that, on balance, imposing NSPS 
    on mills that replace fiber lines for the purpose of participating in 
    the Voluntary Advanced Technology Incentives Program would discourage 
    rather than encourage the long-term goal of achieving even greater 
    environmental performance.
        The third criterion appearing in the definition of new source in 
    Sec. 430.01(j)(1)(iii) is identical to the third criterion at 
    Sec. 122.29(b)(1)(iii), and provides that a source is a new source if 
    its processes are substantially independent of an existing source at 
    the same site. In determining whether processes are substantially 
    independent, the permitting or pretreatment authority is directed to 
    consider such factors as the extent to which the new facility is 
    integrated with the existing plant, and the extent to which the new 
    facility is engaged in the same general type of activity as the 
    existing source. For example, if a mill operating in the Bleached 
    Papergrade Kraft and Soda subcategory builds and operates an entirely 
    new fiber line that permanently
    
    [[Page 18568]]
    
    supplements the capacity of an existing fiber line (and also, 
    incidentally, increases the total quantity of pollutants discharged by 
    the mill), the new fiber line would be considered a new source subject 
    to NSPS.
        EPA believes it is appropriate to subject a new fiber line that is 
    substantially independent of an existing fiber line to new source 
    performance standards because a mill designing that new fiber line has 
    pollution prevention opportunities akin to those available to 
    greenfield mills. For example, a mill would have the opportunity to 
    incorporate pollution prevention principles when designing a new fiber 
    line, including a new flow scheme and water balance. This new fiber 
    line would provide the opportunity to take advantage of pollution 
    prevention savings attributable to reduced chemical needs (and costs), 
    increased energy recovery, the possibility of improving yield, and 
    other operation and maintenance improvements.
        EPA notes that a fiber line that is substantially independent of an 
    existing fiber line is a new source even if the new fiber line is 
    enrolled in the Voluntary Advanced Technology Incentives Program. EPA 
    believes that this is appropriate because the supplemental fiber line 
    increases both the mill's production capacity and its discharge of 
    pollution to the environment. However, the fiber line could qualify for 
    incentives if it is enrolled in the Voluntary Advanced Technology 
    Incentives Program for NSPS at the Tier II or Tier III level.
        As reflected in the July 1996 Notice, 61 FR at 36848, EPA had 
    considered excluding from the definition of new source those mills that 
    renovated existing fiber lines but remained at existing production 
    levels. In response to comments, EPA has decided not to introduce 
    production levels as a factor in determining new source status. First, 
    taking production levels into account in determining whether an 
    existing source becomes a new source would be a departure from current 
    practice that EPA believes is not justified in this case. EPA believes 
    that the new source status of a subpart B or E mill should be 
    determined by the degree of process and production changes made at a 
    mill's fiber lines--such as the replacement of existing digesters and 
    bleach plants with new equipment--because those changes, not production 
    levels, present the real opportunities for pollution prevention 
    represented by NSPS or PSNS. Moreover, EPA agrees with comments stating 
    that mills subject to subpart B or E frequently undergo changes in 
    various degrees to increase production levels and that many of these 
    changes do not result in or from substantially independent facilities 
    or the total replacement of existing facilities. See DCN 25538 at 70-
    72. Therefore, the mere fact that a mill increases its production 
    levels does not mean that it concurrently has the opportunity to 
    install the type of advanced pollution prevention technologies 
    represented by NSPS.
        (3) Non-Continuous Discharger. EPA is changing the regulatory 
    language defining non-continuous dischargers as it applies to subparts 
    B and E. See 40 CFR 430.01(k)(2). EPA is also republishing, without 
    change, the current definition of non-continuous dischargers because it 
    continues to apply to the other subparts in part 430 and to the 
    determination of technology-based effluent limitations on conventional 
    pollutants for existing dischargers subject to subpart B or E. See 40 
    CFR 430.01(k)(1).
        EPA had proposed a new definition that would have defined as a non-
    continuous discharger a mill that stored wastewaters for periods of at 
    least 24 hours and that released that wastewater on a batch basis. In 
    the final definition applicable to subparts B and E, EPA is retaining 
    the storage component of the proposed (and existing) regulation but is 
    not specifying a minimum 24-hour storage period because EPA determined 
    that it had no particular significance for these subparts. However, as 
    indicated in the July 1996 Notice, 61 FR at 36842, EPA is adding 
    language defining as a non-continuous discharger a discharger that 
    releases stored wastewater on a variable flow or a pollutant loading 
    rate basis. Finally, in this new definition, EPA is clarifying that it 
    applies to storage or release of wastewaters required by the permitting 
    authority for the purpose of protecting receiving water quality, among 
    other purposes. See 40 CFR 430.01(k)(2). For subparts B and E only, EPA 
    also is eliminating the requirement in the existing regulation, at 40 
    CFR 430.01(c) (1996 ed.), for the NPDES authority to include maximum 
    day and maximum 30-day average concentration limitations consistent 
    with BPT, BCT, or NSPS limitations as appropriate. See 40 CFR 
    430.01(k). EPA will defer to the NPDES authority to establish maximum 
    day and maximum 30-day average limitations that are necessary to 
    protect receiving water quality. In later final rulemaking phases (see 
    section II, table II-2), EPA intends to adopt for remaining 
    subcategories the same definition for non-continuous dischargers as is 
    being promulgated today for subparts B and E.
        (4) Retention of Previously Promulgated Effluent Limitations 
    Guidelines and Standards. As discussed in more detail in Section 
    VI.B.2, EPA is not revising BPT or BCT effluent limitations for 
    conventional pollutants for subparts B and E. Therefore, EPA is 
    retaining the previously promulgated limitations for these pollutants 
    and subparts. See 40 CFR 430.22, 430.23, 430.52, 430.53.
        EPA is also retaining previously promulgated NSPS for subparts B 
    and E because new sources that commenced operation prior to the 
    effective date of today's NSPS remain subject to the earlier standards 
    for ten years beginning on the date construction of the new source was 
    completed. CWA section 306(d); see 40 CFR 430.25(a), 430.55(a).
        Finally, as discussed in more detail in Section VI.B.3.f, subparts 
    B and E include previously promulgated end-of-pipe effluent limitations 
    guidelines and standards for pentachlorophenol and trichlorophenol. EPA 
    is also retaining the accompanying provisions authorizing mills that do 
    not use those chemicals as biocides to certify this fact to the 
    permitting or pretreatment authority with the result that they would 
    not be subject to those limitations or standards. Id.
        In addition to today's new regulations for subparts B and E, EPA is 
    recodifying the previously promulgated BPT, BCT, BAT, NSPS, PSES and 
    PSNS for the other subparts of the pulp, paper, and paperboard 
    category. These limitations regulate the discharges of BOD5, 
    TSS, zinc, and other analytes. Although EPA is reorganizing the former 
    subcategories in accordance with the new subcategory designations, EPA 
    is not changing these limitations and standards. See Section VI.B.1.
        b. Determination of Effluent Limitations for Permits. (1) 
    Definition of Production and Production-Normalizing Parameters. The 
    Agency has based some of the effluent limitations guidelines and 
    standards promulgated today on pollutant concentrations. Others are 
    mass-based, that is, normalized on the basis of an appropriate measure 
    of production. Limitations and standards for AOX, chloroform, 
    BOD5, and TSS fall into this category.
        This appropriate measure of production is known as the 
    ``production-normalizing parameter.'' The current definition of 
    ``production-normalizing parameter'' is annual off-the-machine 
    production (including off-the-machine coating, where applicable) of 
    pulp, paper, and/or paperboard, divided by the number of operating days 
    that year. Most paper and paperboard production is measured at the off-
    the-
    
    [[Page 18569]]
    
    machine moisture content, while market pulp is measured as air-dry 
    metric tons (10 percent moisture). EPA is not changing this definition 
    of production as it applies to the effluent limitations and standards 
    for any subcategory in Part 430 other than subparts B and E. EPA is 
    also retaining the existing definition of production for the NSPS for 
    conventional pollutants being promulgated today for subpart B and 
    subpart E. See 40 CFR 430.01(n)(1).
        However, EPA is codifying a new definition of production for the 
    AOX and chloroform limitations being promulgated today for subparts B 
    and E. See 40 CFR 430.01(n)(2). Under the new specialized definition, 
    the production-normalizing parameter to be used by permit writers in 
    calculating mass-based limitations for chloroform and AOX is air-dried 
    metric tons of brownstock pulp (10 percent moisture) entering the 
    bleach plant at the stage during which chlorine or chlorine-containing 
    compounds are first applied to the pulp. In the case of bleach plants 
    that use totally chlorine-free bleaching, the production-normalizing 
    parameter used to calculate mass-based limitations shall be air-dried 
    metric tons of brownstock pulp (10 percent moisture) entering the first 
    stage of the bleach plant from which wastewater is discharged. Id. 
    Production, in turn, is defined as the annual unbleached pulp 
    production that enters the bleach plant (at ten percent moisture) 
    divided by the number of operating days of the bleach plant. Id.
        The Agency had proposed to change the current definition of 
    production in part 430 by adding the following statement: ``Production 
    in each of the foregoing cases shall be determined for each mill based 
    upon the highest annual production in the past five years divided by 
    the number of operating days that year.'' See 58 FR at 66189. EPA has 
    decided not to revise the definition to include a new time basis 
    because EPA is not revising the current BPT and BCT effluent 
    limitations guidelines at this time for subparts B and E. Codifying a 
    new time basis for determining production of AOX and chloroform would 
    have required permit writers to apply different time bases for 
    determining production for purposes of calculating BAT limitations and 
    limitations for conventional pollutants. In EPA's view, this would have 
    unduly complicated the permitting process. In addition, for NSPS, 
    introducing a time basis would be illogical because new sources do not 
    have five years of data from which to determine the one highest year.
        (2) Determination of Permit Limitations for Multiple Subcategory 
    Mills. For facilities with multiple point source categories, 
    subcategories, and segments, the appropriate guidelines for each 
    category, subcategory (or subpart), and segment are used to determine a 
    single permit limit for each pollutant. Chapter 5 of the U.S. EPA NPDES 
    Permit Writers' Manual (EPA-833-B-96-003, December 1996) provides 
    guidance in determining permit limits in situations when the effluent 
    guidelines for one subcategory regulates a different set of pollutants 
    than the effluent guidelines applicable to another subcategory. For 
    mill subject to today's rule, this situation may arise in setting 
    permit limits for AOX when the mill has production in multiple 
    subcategories.
        For pollutants regulated today at the bleach plant (i.e., dioxin, 
    furan, chlorinated phenolic pollutants, and chloroform, and, for 
    subpart B PSES/PSNS, AOX), EPA does not believe that multiple 
    guidelines will be relevant. The bleach plant is unlikely to be used 
    for more than one subcategory (or segment in subpart E), and thus, the 
    permit limit will be determined by the limitations and standards for a 
    single subcategory (or segment).
        There may be instances where a pollutant is regulated under the 
    limitations and standards promulgated today and the permitting 
    authority also wishes to establish limits for that particular pollutant 
    have yet to be established. For example, the permitting authority might 
    need to use best professional judgment to determine end-of-pipe limits 
    for AOX for a mill with production not only in subpart B or E (for 
    which AOX limitations are being promulgated today) but also in another 
    subpart (for which no AOX limitations have been promulgated) that 
    generates AOX. In these instances, the permitting authority would use 
    best professional judgment to develop pollutant limits for wastestreams 
    and pollutants not covered by today's rulemaking and apply those limits 
    to determine a proper permit limitation for the mill.
        Following promulgation of today's rules, EPA will develop and 
    publish additional guidance for the pulp and paper industry for 
    determining permit limitations for facilities with production in 
    multiple categories, subcategories, and segments.
        c. Compliance With Effluent Limitations. (1) Compliance 
    Demonstration for In-Plant Limitations. The effluent limitations and 
    standards that the Agency is promulgating today for dioxin, furan, 
    chloroform, the 12 chlorinated phenolic pollutants and AOX will be 
    applied (depending on the subcategory and segment) to the total 
    discharge from each physical bleach line operated at the mill. At most 
    mills, wastewaters from acid and alkaline bleaching stages are 
    discharged to separate sewers. At some mills, however, bleach plant 
    wastewaters are discharged to a combined sewer containing both acid and 
    alkaline wastewaters.
        For dioxin, furan, and chlorinated phenolic compounds, compliance 
    with the effluent limitations and standards can be demonstrated by 
    collecting separate samples of the acid and alkaline discharges and 
    preparing a flow-proportioned composite of these samples, resulting in 
    one sample of bleach plant effluent for analysis. However, in 
    determining the limitations, EPA used data from acid and alkaline 
    bleach plant effluents that had been analyzed separately. (EPA also 
    used data from combined sewers.) In a comment on Method 1653 (DCN 20095 
    A8), the commenter reported problems in achieving the Minimum Level in 
    Method 1653 for samples of composited acid and alkaline filtrates. If 
    necessary to achieve the Minimum Level, EPA recommends that the 
    facility test the effluents separately for reliable determination of 
    the chlorophenolics, TCDD, and TCDF.
        For chloroform, however, separate samples and analyses of all 
    bleach plant filtrates discharged separately are required to prevent 
    the loss of chloroform through air stripping as the samples are 
    collected, measured, and composited or through chemical reaction when 
    the acid and alkaline samples are combined. If separate acid and 
    alkaline sewers do not exist, compliance samples must be collected from 
    the point closest to the bleach plant that is or can be made physically 
    accessible.
        (2) Compliance with ML Limitations. In today's rulemaking for the 
    Bleached Papergrade Kraft and Soda subcategory, EPA is establishing 
    limitations and standards for 12 chlorinated phenolic pollutants and 
    dioxin, and alternative TCF limitations and standards for AOX, that are 
    expressed as less than the Minimum Level (``<5 ppq.....................="" yes.......................=""><5 ppq="" is="" less="" than="" the="" ml="" of="" 10="" ppq="" specified="" in="" sec.="" 430.01.="" non-detected...............=""><10 ppq....................="" yes.......................="" compliance="" is="" demonstrated="" for="" all="" values="" less="" than="" the="" ml="" specified="" in="" sec.="" 430.01.="" non-detected...............=""><11 ppq....................="" no........................="" the="" sample-specific="" ml="" must="" be="" less="" than="" the="" ml="" of="" 10="" ppq="" specified="" in="" sec.="" 430.01.="" ----------------------------------------------------------------------------------------------------------------="" (3)="" aox="" at="" calcium-,="" magnesium-,="" or="" sodium-based="" sulfite="" mills.="" the="" aox="" limitation="" for="" calcium-,="" magnesium-,="" or="" sodium-based="" papergrade="" sulfite="" mills="" is="" expressed="" as="" less="" than="" the="" minimum="" level="" (ml)="" of="" the="" analytical="" method.="" as="" discussed="" in="" section="" vi.b.6,="" this="" aox="" limitation="" is="" based="" on="" transfer="" of="" data="" collected="" at="" the="" bleach="" plant="" effluent="" to="" the="" end-of-pipe="" for="" bat.="" epa="" received="" comments="" asserting="" that="" this="" transfer="" of="" data="" does="" not="" account="" for="" potential="" sources="" of="" aox="" other="" than="" the="" bleach="" plant.="" examples="" of="" these="" potential="" sources="" of="" aox="" include="" the="" release="" of="" aox="" from="" purchased="" pulp="" used="" in="" papermaking,="" the="" use="" of="" chlorinated="" compounds="" for="" control="" of="" biological="" growth="" on="" paper="" machines,="" chlorine="" use="" in="" water="" treatment,="" and="" bleaching="" colored="" broke="" in="" the="" stock="" preparation="" area.="" hypochlorite="" is="" also="" used="" in="" deinking="" processes="" to="" strip="" color="" from="" post-consumer="" waste.="" aox="" contributions="" from="" deinking="" operations="" are="" not="" covered="" by="" this="" rule="" and="" would="" be="" addressed="" in="" developing="" appropriate="" permit="" limitations="" as="" described="" in="" vi.b.8.b(2)="" above.="" aox="" contributions="" due="" to="" chlorine="" use="" in="" treating="" process="" water="" supplies="" are="" not="" taken="" into="" account="" in="" the="" development="" of="" limitations="" and="" standards="" for="" the="" calcium-,="" magnesium-,="" or="" sodium-based="" [[page="" 18571]]="" sulfite="" pulp="" segment.="" in="" cases="" where="" other="" sources="" of="" aox,="" such="" as="" paper="" machines,="" make="" the="" end-of-pipe="" aox="" limitations="" in="" this="" rule="" impractical="" or="" infeasible="" for="" the="" purpose="" of="" assessing="" the="" contribution="" of="" aox="" from="" bleach="" plant="" sources,="" the="" aox="" limitation="" may="" be="" imposed="" on="" internal="" waste="" streams="" (i.e.,="" bleach="" plant="" effluent)="" before="" mixing="" with="" other="" waste="" streams="" containing="" aox.="" see="" 40="" cfr="" 122.45(h).="" (4)="" minimum="" monitoring="" frequencies.="" (a)="" rationale="" for="" establishing="" minimum="" monitoring="" frequencies.="" epa="" proposed="" specific="" minimum="" monitoring="" frequencies="" for="" pollutants="" in="" bleach="" plant="" and="" end-of-pipe="" effluent="" discharges.="" see="" 58="" fr="" at="" 66189.="" although="" epa="" proposed="" minimum="" monitoring="" requirements="" for="">5 and TSS limitations 
    established as part of NSPS, EPA is not specifying such requirements in 
    the final rule because permit authorities have ample experience 
    regulating these pollutants and can determine the appropriate 
    monitoring frequencies. See Section VI.A.3 for a discussion of 
    BOD5 monitoring requirements under today's air rule. See 
    also Section VI.B.7 for a discussion of monitoring requirements 
    associated with BMPs.
        The final rule specifies minimum monitoring frequencies for AOX, 
    dioxin, furan, chloroform, and chlorinated phenolic pollutants for non-
    TCF mills because of the nature and composition of the discharges from 
    non-TCF bleached papergrade kraft and soda and papergrade sulfite 
    mills. See 40 CFR 430.02 (a) and (b). Wastewaters from these mills have 
    been found to contain chlorinated organic compounds that are highly 
    toxic and bioaccumulative (e.g., dioxin, furan, and chlorinated 
    phenolic pollutants). Process-related variability in generating these 
    pollutants is clearly reflected in available data. Therefore, given the 
    environmental significance of these pollutants, minimum monitoring is 
    both necessary and appropriate to ensure that data are available to 
    permitting authorities to have an adequate basis to verify compliance 
    with the technology-based effluent limitations and standards. In 
    contrast to discharges of BOD5 and TSS, receiving water 
    effects from discharges of these chlorinated pollutants are not as 
    easily detected, are not as well understood, and do not manifest 
    themselves in a manner that enables a mill to quickly become aware of 
    and react to releases that may be harmful to the environment.
        The monitoring requirements imposed in 40 CFR 430.02 will not take 
    effect until EPA has obtained approval of these information collection 
    requirements from the Office of Management and Budget (OMB) under the 
    Paperwork Reduction Act, 44 U.S.C. 3501, et seq. For monitoring 
    requirements applicable to direct dischargers, EPA will seek to amend 
    the NPDES Discharge Monitoring Report ICR No. 229, OMB approval number 
    2040-0004, prior to its expiration on May 31, 1998. For indirect 
    dischargers, EPA will seek to add specified monitoring requirements for 
    indirect dischargers to the National Pretreatment Program ICR No. 2, 
    OMB approval number 2040-0009, when it expires on October 31, 1999. EPA 
    will not seek to amend this ICR prior to its expiration date because 
    the monitoring requirements for indirect dischargers do not become 
    effective until April 16, 2001 for existing indirect dischargers, and 
    EPA anticipates no new indirect dischargers commencing discharge prior 
    to the ICR expiration date.
        (b) Duration of Minimum Monitoring Frequency. The final rule 
    includes minimum monitoring frequency requirements for demonstrating 
    compliance with limitations and standards for dioxin, furan, 
    chloroform, the 12 chlorinated phenolic pollutants, and AOX for non-TCF 
    mills. See 40 CFR 430.02(a). Permitting and pretreatment authorities 
    retain authority to specify more frequent monitoring on a case-by-case 
    basis and must specify AOX monitoring frequency for TCF mills on a best 
    professional judgment basis. The minimum monitoring frequencies are 
    applicable to mills in Subparts B and E for a duration of five years 
    after inclusion in NPDES permits for direct dischargers. See 40 CFR 
    430.02(b). For existing indirect dischargers, the minimum monitoring 
    requirements apply until April 17, 2006 which reflects a five-year 
    monitoring period following the termination of the three-year 
    compliance period authorized by CWA Section 307(b)(1). Id. For new 
    indirect dischargers, the five year minimum monitoring period commences 
    upon operation. Id.
        EPA has determined the minimum monitoring frequencies established 
    by this rule are necessary to demonstrate compliance with the effluent 
    limitations guidelines and standards promulgated today, particularly 
    considering the degree of change that is expected to occur to pulping 
    and bleaching processes as this rule is implemented. In establishing 
    the minimum monitoring frequencies for the regulated pollutants, the 
    Agency has struck a balance between the cost of the monitoring regimen 
    and the need to ensure that sufficient data are consistently available 
    to permitting authorities to provide an adequate basis to verify 
    compliance with the effluent limitations and standards and to mills to 
    quickly become aware of and react to releases that may be harmful to 
    the environment.
        The Agency has selected a minimum monitoring frequency of once per 
    month for dioxin, furan, and chlorinated phenolic pollutants. See 40 
    CFR 430.02(a). These pollutants are the most toxic and bioaccumulative 
    among those regulated yet also are the most costly to analyze (total 
    cost of approximately $1,325 per sample; $825 per sample for dioxin, 
    furan, and $500 per sample for all 12 chlorinated phenolic analytes). 
    EPA expects that 12 data points for each pollutant per year, together 
    with daily end-of-pipe AOX data and information on process conditions 
    from detailed mill logs (e.g., unbleached pulp kappa numbers, bleach 
    plant kappa factors, bleached pulp brightness, etc.) that are 
    reviewable upon request, will yield a meaningful basis for establishing 
    compliance with the promulgated limitations through long-term trends 
    and short-term variability in dioxin, furan, and chlorinated phenolic 
    pollutant discharge loading patterns.
        The Agency has selected a minimum monitoring frequency of once per 
    week for chloroform. See 40 CFR 430.02(a). This minimum monitoring 
    frequency has been selected because data available indicate there can 
    be considerable temporal variability of this pollutant in bleach plant 
    wastewaters. Therefore, more data are required to adequately assess 
    compliance with the promulgated limitations and standards on both a 
    long-term and short-term basis. While the cost for laboratory analysis 
    of chloroform (approximately $270 per sample) is much lower than for 
    dioxin, furan, and chlorinated phenolic pollutants, chloroform sampling 
    requirements are more extensive and rigorous (e.g., sampling of all 
    bleach plant filtrates using special equipment and containers to 
    prevent volatilization). Weekly data (52 data points) and information 
    on process conditions from detailed mill logs that are reviewable upon 
    request are expected to yield an adequate basis for establishing long-
    term compliance trends in chloroform discharge loadings and developing 
    process control strategies to ensure the short-term compliance in 
    chloroform discharge loadings.
        The Agency has selected a minimum monitoring frequency of once 
    every day for AOX for non-TCF mills. See 40 CFR 430.02(a). This minimum 
    monitoring frequency has been selected because there can be 
    considerable daily variability in chlorinated organic discharge 
    loadings to receiving streams
    
    [[Page 18572]]
    
    reflecting both bleach plant discharge patterns and secondary 
    biological treatment system performance that is readily measured at 
    reasonable cost. At this time, AOX analysis costs $120 per sample. This 
    cost is likely to decrease after this regulation is promulgated with 
    increased capacity at commercial laboratories and analytical 
    laboratories on-site at many mills. While this bulk parameter measures 
    all chlorinated organic constituents in wastewater and not individual 
    pollutants, daily monitoring will provide an essentially continuous 
    data stream on a quick turnaround basis to mill operating personnel and 
    permit compliance authorities to assess and control process 
    technologies and manage the performance of end-of-pipe biological 
    treatment systems.
        The minimum monitoring frequencies in this rule as described above 
    will provide sufficient information to evaluate mill compliance with 
    the promulgated limitations over the long term and allow permitting and 
    pretreatment authorities to judge whether a different frequency of 
    monitoring is warranted after the initial compulsory period of minimum 
    monitoring has been completed. These data will prove useful to 
    permitting authorities and also to mill operators in developing a 
    robust mill-specific compliance data base with which to analyze the 
    effects of mill processes on effluent trends. The five-year duration of 
    the minimum monitoring requirements is consistent with permit issuance 
    cycles, will ease administrative burdens on operators and permitting 
    authorities, and will provide data useful for establishing appropriate 
    monitoring requirements during future permit renewals.
        Following completion of the compulsory five-year monitoring period 
    set forth by this rule, the permitting or pretreatment authority has 
    discretion to adjust monitoring requirements as deemed appropriate on a 
    case-by-case basis. For those mills consistently demonstrating 
    reductions superior to those required merely to comply with their 
    permit requirements, EPA believes that it may be appropriate to allow 
    less frequent monitoring to reduce the regulatory burden. EPA expects 
    the permitting or pretreatment authority also to consider the mill's 
    compliance and enforcement history in determining monitoring 
    frequencies. This avenue for relief provides incentives for voluntary 
    reductions of pollutant discharges through such means as reuse and 
    recycling. EPA also expects permitting and pretreatment authorities to 
    consider whether poor performance, compliance or enforcement history, 
    or other site-specific factors indicate a need to impose more frequent 
    monitoring than that specified in this rule.
        EPA has issued interim guidance for performance-based reductions of 
    NPDES permit monitoring frequencies, which may be useful for permit 
    writers and pretreatment authorities in determining alternative 
    monitoring frequencies at the close of the compulsory five-year period 
    imposed by this rule. (See Interim Guidance for Performance-Based 
    Reductions of NPDES Permit Monitoring Frequencies, April 1996, EPA-833-
    B-96-001). This document provides guidance to permit writers on 
    implementing EPA's NPDES regulations regarding appropriate monitoring 
    in permits and describes the conditions under which reduced monitoring 
    would be justified. Pretreatment control authorities also may find this 
    guidance useful in setting monitoring frequencies for industrial users 
    of POTWs. The current guidance applicable to all industrial point 
    sources is dated April 19, 1996, and is subject to revision.
        (c) Certification for TCF Bleaching. Mills certifying in their 
    permit application process that all bleaching processes are totally 
    chlorine-free are exempted from the minimum monitoring frequencies 
    established in this rule, provided that analytical data routinely 
    submitted as part of the permit application confirm the absence of 
    chlorinated compounds. See 40 CFR 430.02. EPA believes it is 
    appropriate to exclude TCF mills from the minimum monitoring 
    frequencies for chlorinated compounds since any process change that 
    introduces chlorinated compounds to the bleaching process requires 
    notification to the permitting authority and would result in reopening 
    the permit for modification. See, e.g., 40 CFR 122.21(g)(3), 
    122.21(g)(7), and 122.41(l).
        (d) ECF Certification in Lieu of Monitoring. In response to 
    comments, EPA has considered whether certification of ECF bleaching 
    processes can be used in lieu of monitoring. Because of the effect that 
    operation and control of pulping and bleach plant processes have on 
    generation of chlorinated pollutants, EPA has determined that the 
    information available at this time does not demonstrate that ECF 
    certification alone is sufficient to ensure compliance with the 
    regulations promulgated today. Therefore, this rule does not allow 
    certification of ECF bleaching to replace monitoring. (See DCN 14497, 
    Vol. I, and section VI.B.5 of this preamble for a discussion of factors 
    affecting chlorinated pollutant generation.)
        Elsewhere in today's Federal Register, however, EPA is proposing to 
    allow mills to demonstrate compliance with chloroform limitations by 
    certifying that they use ECF bleaching processes and that these 
    processes are operated in a manner consistent with certain process and 
    related factors. In this notice, EPA also is seeking additional 
    chloroform data, along with corresponding process data, to determine 
    whether an ECF certification process for chloroform should require 
    certification of certain process factors; for example, factors relating 
    to residual lignin content, chemical application rates, and other 
    process variables.
        d. Intake Credits, Upsets, and Bypasses. An intake credit is an 
    adjustment made to an effluent limitation to reflect the presence of a 
    pollutant in the discharger's intake water beyond what is removed by an 
    installed technology that would otherwise meet the technology-based 
    effluent limitation or standard. EPA's regulations concerning intake 
    credits are set forth at 40 CFR 122.45 and 40 CFR 403.15.
        A ``bypass'' is an intentional diversion of waste streams from any 
    portion of a treatment facility. An ``upset'' is an exceptional 
    incident in which there is unintentional non-compliance with 
    technology-based permit effluent limitations because of factors beyond 
    the reasonable control of the permittee. EPA's regulations concerning 
    bypasses and upsets are set forth at 40 CFR 122.41 (m) and (n).
        e. Variances and Modifications to Permits. (1) Variances. 
    Dischargers subject to the BAT and PSES limitations promulgated in 
    these final regulations may apply for a Fundamentally Different Factors 
    (FDF) variance under the provisions of section 301(n) of the CWA. The 
    FDF variance considers those facility-specific factors that a permittee 
    believes to be uniquely different from the factors considered by EPA in 
    developing an effluent guideline to determine whether the effluent 
    guidelines limitations should be inapplicable to the permittee's 
    facility. An FDF variance is based only on information submitted to EPA 
    during the rulemaking establishing the effluent limitations, or on 
    information the applicant did not have a reasonable opportunity to 
    submit during the rulemaking process. See CWA section 301(n)(1)(B). If 
    fundamentally different factors are determined to exist, the 
    alternative effluent limitations for the petitioner must be no less 
    stringent than those justified by the fundamental difference. See CWA 
    section 301(n)(1)(C). The alternative effluent
    
    [[Page 18573]]
    
    limitation must not result in non-water quality environmental impacts 
    significantly greater than those accepted by EPA in promulgating the 
    effluent limitations guidelines or pretreatment standards. See CWA 
    section 301(n)(1)(D). FDF variance requests, along with all supporting 
    information and data, must be received by the permitting authority 
    within 180 days after publication of the final effluent limitations 
    guideline or standard. See CWA section 301(n)(a). The specific 
    regulations covering FDF variance requirements and administration are 
    found at 40 CFR 122.21(m)(1), 40 CFR Part 125, Subpart D, and 40 CFR 
    403.13.
        Dischargers may also apply for a variance from the BAT limitations 
    on non-conventional pollutants in these final regulations under CWA 
    section 301(c) (for economic reasons) and 301(g) (for water quality 
    reasons). Regulations for the administration of these variances are 
    specified in 40 CFR 122.21(m)(2).
        New sources subject to NSPS or PSNS are not eligible for variances. 
    See E.I. DuPont v. Train, 430 U.S. 112 (1977).
        (2) Permit Modifications. It may be necessary to modify a permit at 
    some point after it has been issued. In a permit modification, only the 
    conditions subject to change are reconsidered. All other permit 
    conditions remain in effect unchanged. A permit modification may be 
    triggered in several ways, such as when the regulatory agency inspects 
    the facility and finds a need for the modification, or when information 
    submitted by the permittee suggests a need for a modification. Any 
    interested person may request that a permit modification be made. There 
    are two classifications of modifications: major and minor. From a 
    procedural standpoint, they differ primarily with respect to the public 
    notice requirements. Major modifications require public notice while 
    minor modifications do not. See 40 CFR 122.63. Virtually all 
    modifications that result in less stringent conditions are treated as a 
    major modification, with provisions for public notice and comment. 
    Conditions that would necessitate a major modification of a permit are 
    described in 40 CFR 122.62. Minor modifications are generally non-
    substantive changes. The conditions for minor modification are 
    described in 40 CFR 122.63.
    
    VII. Environmental Impacts
    
        This section of the preamble describes the environmental impacts of 
    the air and water regulations being promulgated today, and the 
    environmental impacts of the MACT II regulations being proposed today. 
    These impacts are described in terms of reductions in air pollution 
    emissions expected as a result of the final MACT I and proposed MACT II 
    rules, as well as the reduction in water pollution (effluent) 
    discharges expected as a result of today's effluent limitations 
    guidelines and standards for Subparts B and E. (In this section, all 
    references to MACT I include MACT III unless expressly noted.) The 
    emissions and effluent reductions described in this section generate 
    the quantified and monetized benefits described in Section VIII of this 
    preamble. This section also discusses the non-water quality 
    environmental impacts of the effluent limitations guidelines and 
    standards promulgated today, including air emissions, energy 
    requirements, solid waste generation, water use, and wood consumption. 
    Sections II.B.2 and VII.A describe air and water pollution control 
    technologies for each subcategory regulated today: Kraft, Soda, 
    Sulfite, and Semi-chemical mills that are subject to MACT I and MACT 
    III standards; and bleached papergrade kraft and soda and papergrade 
    sulfite mills that are subject to effluent limitations guidelines and 
    standards. EPA estimates that the application of these technologies by 
    the 155 mills regulated by today's air rules, including 96 of those 
    mills also regulated by today's water rules, will substantially reduce 
    air emissions and water pollution discharges, as described in Section 
    VII.B.
    
    A. Summary of Sources and Level of Control
    
        Table VII-1 shows a summary of sources and technology bases/level 
    of control for the final BAT/PSES effluent limitations guidelines and 
    standards, and the final MACT I standards. The summary of sources and 
    level of control for MACT II are discussed in the preamble for the 
    proposed MACT standards elsewhere in today's Federal Register.
    
    [[Page 18574]]
    
    
    
                                                            Table VII-1.--Final Cluster Rules--Sources and Technology Bases/Level of Control                                                        
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
        Toxic and nonconventional pollutant effluent control (BAT, PSES, and BMP technology bases) by subcategory      Hazardous air pollutant emission control (MACT I and III  levels of control) 
    -----------------------------------------------------------------------------------------------------------------                                 by subcategory                                
                                                          Papergrade sulfite                                         -------------------------------------------------------------------------------
                                     ------------------------------------------------------------   Best Management                                                                  Secondary and  
      Bleached papergrade kraft and        Calcium,                                                Practices (BMP),                         Soda and semi-                        nonwood fiber, and
                  soda                  magnesium, and     Ammonium sulfite     Specialty grade   (Subparts B and E)         Kraft             chemical             Sulfite         mechanical wood 
                                        sodium sulfite                                                                                                                                   fiber      
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                                                                                                                    
    (2) Selected BAT/PSES             Spent Pulping                                                                                                                                                 
                                       Liquor Spill                                                                                                                                                 
                                       Prevention and                                                                                                                                               
                                       Control.                                                                                                                                                     
    (2)Control LVHC System Vents      See Bleach Plant                                                                                                                                              
                                       Block Below.                                                                                                                                                 
    ECF: 100% Substitution of         TCF: Oxygen- and    ECF: 100%           ECF: 100%           ..................  Control Selected    Control Pulp        Control Pulp                          
     Chlorine with Chlorine Dioxide;   peroxide-enhanced   Substitution of     Substitution of                         HVLC Vents and      Washing System      Washing System                       
     effective brownstock washing;     extraction;         Chlorine with       Chlorine with                           Named High HAP      Vents at New        Vents, and                           
     elimination of hypochlorite;      peroxide            Chlorine Dioxide;   Chlorine Dioxide;                       Concentrated        Sources.            Control Liquor                       
     oxygen-and peroxide-enhanced      bleaching;          peroxide-enhanced   oxygen- and                             Condensate                              and Acid Tank                        
     extraction; closed brown-stock    elimination of      extraction;         peroxide-enhanced                       Streams.                                Vents at New                         
     screening; and other processes    all chlorine-       elimination of      extraction;                                                                     Sources.                             
     discussed at Section              containing          hypo-chlorite;      elimination of                                                                                                       
     VI.B.5.a(1).                      compounds; and      and use of dioxin-  hypochlorite; and                                                                                                    
                                       improved pulp       and furan-          use of dioxin and                                                                                                    
                                       cleaning.           precursor-free      furan precursor-                                                                                                     
                                                           defoamers.          free defoamers.                                                                                                      
                                                                                                                                                                                                    
    (3)Bleach Plant: Control                                                                                                                                                                        
     Chlorinated HAP from Vents at                                                                                                                                                                  
     Stages That Use Chlorinated                                                                                                                                                                    
     Bleaching Chemicals, and                                                                                                                                                                       
     Control Chloroform Emissions by                                                                                                                                                                
     Complying with BAT codified at                                                                                                                                                                 
     40 CFR 430.24(a) and (e) and 40                                                                                                                                                                
     CFR 430.54(a) and (c) or by                                                                                                                                                                    
     100% substitution of chlorine                                                                                                                                                                  
     with chlorine dioxide and                                                                                                                                                                      
     elimination of hypochlorite.                                                                                                                                                                   
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
    
    B. Air Emissions and Water Effluent Reductions
    
    1. Air Emissions Reductions
        The reductions described in this section are derived from estimated 
    air emissions reductions at all 155 pulp and paper mills in the CAA 
    kraft, soda, sulfite and semichemical subcategories that are subject to 
    MACT I and MACT II standards. These mills include the 96 mills subject 
    to the effluent limitations guidelines and standards promulgated today. 
    All references in this section to MACT I air emissions refer to the 
    expected effects of implementing both the air and water portion of the 
    final Cluster Rules.
        Implementation of the MACT portion of the Cluster Rules is expected 
    to significantly decrease HAP emissions. Table VII-2 presents the 
    environmental impacts of the Final Cluster Rules (BAT, PSES, BMPs, and 
    MACT I) and the Final Cluster Rules in combination with the MACT II 
    proposed standards.
        The air emission impacts presented in Table VII-2 are calculated 
    based on mill-specific processes and emission control information, 
    emission factors, and control levels summarized in Table VII-1. A more 
    detailed discussion of the calculation of the environmental impacts for 
    the final MACT standards is presented in Chapter 20 of the Background 
    Information Document described in Section XI of this preamble. A 
    detailed discussion of the environmental impacts of the proposed MACT 
    II is contained in the docket for the proposed MACT II standard. As 
    shown in Table VII-2, these final Cluster Rules not only reduce HAP 
    emissions from all CAA and CWA subcategories regulated, but they also 
    result in decreases of volatile organic compounds and total reduced 
    sulfur using industry data updated to 1996. Emissions of particulate 
    and carbon monoxide are estimated to increase under the final rules, 
    but are expected to decrease when combined with the proposed MACT II 
    standards. Emissions of sulfur dioxides, and, to a lesser degree, 
    nitrogen oxides are estimated to increase. Sulfur dioxide emissions are 
    generated primarily from the combustion of sulfur-containing compounds, 
    such as TRS, in the vent streams at kraft mills. The increases in 
    carbon monoxide, nitrogen oxide, and particulate matter air emissions 
    are primarily from the combustion of air vents in the pulping area and 
    increased energy to produce additional steam for steam strippers and 
    chlorine dioxide for the bleaching system. However, these emission 
    increase estimates are likely overstated because they do not account 
    for the fact that some mills in sensitive areas for sulfur dioxide 
    already have sulfur dioxide controls in place or may choose alternative 
    controls available in the final MACT rule that mitigate these
    
    [[Page 18575]]
    
    increases. The health effects and benefits of these emission reductions 
    and increases are discussed in Section VIII.G.1 of this notice.
    
                   Table VII-2.--Air Emission Impacts of Pulp and Paper Rules (All CAA Subcategories)               
    ----------------------------------------------------------------------------------------------------------------
                                                                                      Air emission reductions  (Mg/ 
                                                                                                  year)             
                                                                     Baseline air  ---------------------------------
                            Air pollutants                          emissions (Mg/                    Final cluster 
                                                                         year)       Final cluster      rules and   
                                                                                         rules        proposed MACT 
                                                                                                            II      
    ----------------------------------------------------------------------------------------------------------------
    Hazardous Air Pollutants......................................         240,000         139,000          142,000 
    Volatile Organic Compounds....................................         900,000         409,000          440,000 
    Total Reduced Sulfur..........................................         150,000          79,000           79,000 
    Particulate...................................................             aNA            b(83)          24,000 
    Carbon Monoxide...............................................              NA          (8,700)          49,000 
    Nitrogen Oxides...............................................              NA          (5,200)          (5,700)
    Sulfur Dioxides...............................................              NA         (94,500)         (94,400)
    ----------------------------------------------------------------------------------------------------------------
    a Industry process data was not collected to calculate emissions for these pollutants increases and decreases   
      for these pollutants reflected in columns to the right are increases or decreases of these pollutants caused  
      by projected installation of MACT control equipment and secondary air emission impacts of BAT, PSES, and BMPs.
    b Values in (  ) are estimated emission increases over baseline air emissions.                                  
    
    2. Water Pollutant Reductions
        Table VII-3 shows the estimated baseline (as of mid-1995) and the 
    reductions from baseline expected from the BMP requirements being 
    promulgated today for the Bleached Papergrade Kraft and Soda and 
    Papergrade Sulfite subcategories. (Hereafter, references to BAT/PSES 
    impacts include impacts associated with today's BMP requirements.) 
    Calculation of these pollutant reductions is discussed in Sections 
    VI.B.5.a(3) and VI.B.6.b(5). For a discussion of the estimated effluent 
    reduction benefits associated with the BAT limitations promulgated for 
    the Voluntary Advanced Technology Incentives Program for the Bleached 
    Papergrade Kraft and Soda subcategory, see Section IX. A.6 and Table 
    IX-1.
    
                         Table VII-3.--Estimated Pollutant Reductions From Baseline for BAT/PSES                    
    ----------------------------------------------------------------------------------------------------------------
                                                                              Estimated                   Estimated 
                                                                  Baseline   reductions:    Baseline     reductions:
             Pollutant parameter                  Units          discharge    Final BAT/    discharge    Final BAT/ 
                                                                  for BPK      PSES for   for PS mills   PSES for PS
                                                                   mills      BPK mills                     mills   
    ----------------------------------------------------------------------------------------------------------------
    2,3,7,8-TCDD........................  g/yr................           15           11          0.78          0.65
    2,3,7,8-TCDF........................  g/yr................          115          107          6.7           6.4 
    Chloroform..........................  kkg/yr..............           48           40          5.4           5.2 
    Chlorinated Phenolics...............  kkg/yr..............           55           45          2.0           1.8 
    AOX.................................  kkg/yr..............       36,300       24,200      4,380        4,010    
    ----------------------------------------------------------------------------------------------------------------
    BPK--Bleached Papergrade Kraft and Soda subcategory.                                                            
    PS--Papergrade Sulfite subcategory.                                                                             
    g--grams.                                                                                                       
    kkg--metric ton (1,000 kilograms or 1 megagram (Mg)).                                                           
    
        The air quality impacts shown in Table VII-2 and the water 
    pollutant effluent reductions shown above are used in the following 
    section to estimate reduced human health and environmental risk 
    attributable to today's rules. These estimates also form the basis for 
    estimating monetized benefits in the following section.
    
    C. Non-Water Quality Environmental Impacts of Effluent Limitations 
    Guidelines and Standards (BAT, PSES, and BMPs)
    
        Sections 304(b)(2)(B) and 306(b)(1)(B) of the Clean Water Act 
    require EPA to consider the non-water quality environmental impacts of 
    effluent limitations guidelines and standards. To address these 
    statutory requirements, EPA analyzed the air emissions, energy 
    requirements, solid waste generation impacts, and other environmental 
    impacts of the compulsory BAT, PSES, and BMPs being promulgated today 
    for the Bleached Papergrade Kraft and Soda and Papergrade Sulfite 
    subcategories. The results of this analysis are presented below. In 
    performing the analysis, EPA assumed that each mill in the regulated 
    subcategory would install the model technologies upon which today's 
    limitations and standards are based.
    1. Air Emissions
        The air emissions reductions of BAT, PSES, BMPs, and MACT I, in 
    combination, are presented in Section VII.B.1 above. This section 
    presents the estimated air emission impacts of BAT, PSES, and BMPs on 
    the 86 mills with production in the Bleached Papergrade Kraft and Soda 
    subcategory and the 11 mills with production in the Papergrade Sulfite 
    subcategory. (One mill has co-located operations in both subcategories 
    that separately contribute to the number of mills in each subcategory.)
        The control technologies that form the basis of effluent guidelines 
    and standards promulgated today involve changes in the processes used 
    to produce bleached pulp. These changes affect the rate at which air 
    pollutants, including HAPs, are emitted from the pulping and bleaching 
    processes that are subsequently controlled by MACT I. As shown in Table 
    VII-4, the process changes at bleached papergrade kraft
    
    [[Page 18576]]
    
    and soda and papergrade sulfite facilities subject to BAT, PSES, and 
    BMPs decrease the emissions of some HAPs but have little impact on 
    others. For example, the elimination of chlorine and hypochlorite from 
    bleaching processes, part of the basis for BAT and PSES, will reduce 
    the emission of chloroform in the Bleached Papergrade Kraft and Soda 
    subcategory by 66 percent [but will have a much smaller impact on the 
    emission of methanol.] The application of the BAT, PSES, and BMPs 
    promulgated today for the Bleached Papergrade Kraft and Soda 
    subcategory will reduce the emission of total HAPs from the sources 
    controlled by MACT I from 149,000 Mg/year to 139,000 Mg/yr (7 percent 
    reduction) without taking into account further reductions achieved by 
    MACT I controls.
    
     Table VII-4.--Impact of BAT, PSES, and BMP: Bleached Papergrade Kraft and Soda and Papergrade Sulfite Mills Air
                                   Emissions From Sources Subject to Control by MACT I                              
    ----------------------------------------------------------------------------------------------------------------
                                                                     Bleached papergrade     Papergrade sulfite (all
                                                                  kraft and soda [Mg/year]     segments) [Mg/year]  
                                                                 ---------------------------------------------------
                           Air pollutants                                        Emission                  Emission 
                                                                    Baseline    reductions    Baseline    reductions
                                                                   emissions    from BAT/    emissions    from BAT/ 
                                                                                PSES/BMPs                 PSES/BMPs 
    ----------------------------------------------------------------------------------------------------------------
    Total Hazardous Air Pollutants..............................      149,000       10,000        5,190        1,930
    Chloroform..................................................        9,510        6,060           13            8
    Volatile Organic Compounds..................................      569,000       11,000        6,020        2,270
    Total Reduced Sulfur........................................      100,000        1,300            0            0
    ----------------------------------------------------------------------------------------------------------------
    
        The process changes that form the basis of BAT, PSES, and BMP's 
    increase by approximately 1.5 percent the amount of spent pulping 
    liquor combusted by bleached papergrade kraft mills and papergrade 
    sulfite mills. See the Supplemental Technical Development Document, DCN 
    14487. HAPs and criteria air pollutants (volatile organic compounds, 
    particulate matter, carbon monoxide, nitrogen oxides, and sulfur 
    dioxides) are generated from combustion of spent pulping liquor by 
    bleached papergrade kraft and sulfite mills. As a result, as shown in 
    Tables VII-5a and VII-5b, the emission of total HAPs from spent pulping 
    liquor combustion sources (i.e., recovery boilers) will increase by 1.1 
    percent at bleached papergrade kraft and soda facilities and 1.9 
    percent at papergrade sulfite facilities above the 1995 baseline. 
    However, the net increase in HAP emissions from these combustion 
    sources (235 Mg/yr) represents 1.1 percent of the HAP emissions from 
    all sources subject to control by MACT I, II, and III. Although BAT, 
    PSES, and BMPs result in a small increase in HAP emissions from 
    recovery boilers, the combined effect of the Cluster Rules (including 
    proposed MACT II) is a net decrease of 60 percent in total HAP 
    emissions from all controlled sources. See Table VII-2.
    
       Table VII-5a.--Impact of BAT, PSES, and BMP: Bleached Papergrade Kraft and Soda Air Emissions From Recovery  
                Boilers at Bleached Papergrade Kraft and Soda Mills Subject to Proposed MACT II [Mg/year]           
    ----------------------------------------------------------------------------------------------------------------
                                                                                Emission                            
                                                                     1995      increases     MACT II     Net change 
                                                                   baseline    from BAT/     emission    after MACT 
                                                                   emission    PSES/BMPs    reductions       IIa    
    ----------------------------------------------------------------------------------------------------------------
    Hazardous Air Pollutants...................................       19,900          220           25          195 
    Volatile Organic Compounds.................................       19,500          213            0          213 
    Total Reduced Sulfur.......................................        2,650           27            0           27 
    Particulate Matter.........................................       31,400          360       12,900      (12,540)
    Carbon Monoxide............................................      124,000        1,440            0        1,440 
    Nitrogen Oxides............................................       36,100          423            0          423 
    Sulfur Dioxides............................................       67,800          784            0         784  
    ----------------------------------------------------------------------------------------------------------------
    a Parentheses indicate emissions decreases below baseline.                                                      
    
    
      Table VII-5b.--Impact of BAT, PSES, AND BMP: Air Emissions From Recovery Boilers at Papergrade Sulfite Mills  
                                          Subject to Proposed MACT II [Mg/year]                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                Emission                            
                                                                     1995      increases      MACT II     Net change
                                                                   baseline    from BAT/     emission     after MACT
                                                                   emission    PSES/BMPs    reductions        II    
    ----------------------------------------------------------------------------------------------------------------
    Hazardous Air Pollutants...................................        2,110           40        N/S             40 
    ----------------------------------------------------------------------------------------------------------------
    N/S--Not Significant.                                                                                           
    
    
    [[Page 18577]]
    
        Increases in the emission of criteria pollutants are also listed in 
    Table VII-5a. The emission of total criteria air pollutants from spent 
    pulping liquor combustion sources (i.e., recovery boilers) at mills in 
    the Bleached Papergrade Kraft and Soda subcategory will increase by 1.2 
    percent as a result of BAT, PSES, and BMPs and will be only slightly 
    mitigated by MACT II controls. The increases in nitrogen oxides (423 
    Mg/yr), sulfur dioxides (784 Mg/yr), and carbon monoxide (1440 Mg/yr) 
    emissions are minor relative to nationwide emissions, which are 19.8 
    million Mg/yr for nitrogen oxides, 16.6 million Mg/yr for sulfur 
    dioxides, and 83.6 million Mg/yr for carbon monoxide (OAQPS, 1995).
        EPA concludes that the technologies that form the basis of BAT, 
    PSES, and BMPs for bleached papergrade kraft and soda and papergrade 
    sulfite mills pose no significant adverse impacts to and indeed have 
    some benefits for air quality. EPA bases this determination on the 
    following:
    
    --Total HAP emissions from the sources subject to control by MACT I and 
    proposed MACT II from kraft and sulfite pulping and bleaching processes 
    decrease as a result of BAT, PSES, and BMPs;
    --HAP emissions would increase by less than one percent from bleached 
    kraft combustion sources and increase by less than two percent from 
    papergrade sulfite combustion sources; and
    --The increase in criteria air pollutants for the Bleached Papergrade 
    Kraft and Soda and Papergrade Sulfite subcategories is minor relative 
    to current national industrial emissions.
    
        EPA examined the effect of BAT combined with BMPs on the generation 
    of CO2 by considering the overall mill carbon balance and 
    the energy balance. Anthropogenic generation of water vapor is 
    minuscule relative to atmospheric recycling and is normally ignored in 
    greenhouse gas analysis. Therefore, water vapor is ignored here. EPA 
    concluded that neither option would have an impact on the total 
    emission of greenhouse gasses from mills due to pulping processing. 
    There, EPA concludes that the increased CO2 emissions 
    attributable to BAT pose no significant adverse non-water quality 
    environmental impact.
    2. Energy Impacts
        The impacts of BAT, PSES, and BMPs on the energy use of the 86 
    mills with production in the Bleached Papergrade Kraft and Soda 
    subcategory and the 11 mills with production in the Papergrade Sulfite 
    subcategory are summarized in Table VII-6. The process changes that 
    form the basis of the regulations promulgated today are estimated to 
    result in an increased energy requirement of 3.70 trillion Btu/yr in 
    oil equivalent at the 96 affected pulp and paper mills. This represents 
    a 0.82 percent increase from the current total Bleached Papergrade 
    Kraft and Soda subcategories energy consumption (papergrade sulfite 
    total energy consumption is minor relative to bleached papergrade 
    kraft) of 499.4 trillion Btu/yr in oil equivalent (DCN 14510). The 
    increased energy use is due to the increased off-site chemical 
    manufacturing electrical demand (met by off-site electric generating 
    stations) and on-site electrical demand (also met by off-site electric 
    generating stations, and commonly referred to as ``purchased energy''). 
    These increased demands are partially offset by the decreased steam 
    demand (met by on-site power boilers and recovery furnaces). Oil 
    equivalent is used to express the combined effects of changes in 
    thermal energy and electric power. It is based on the assumption that 
    marginal changes in electric power demand caused by the regulation will 
    be supplied by conventional condensing-type oil-fired power stations. 
    See DCN 14487.
    
      Table VII-6.--Energy Impacts of Bat, PSES, and BMP: Bleached Papergrade Kraft and Soda and Papergrade Sulfite 
                                                          Mills                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                              Bleached     Papergrade               
                Energy impacts                           Units               papergrade   sulfite (all    Combined  
                                                                                Kraft       segments)       total   
    ----------------------------------------------------------------------------------------------------------------
    On-Site Electricity Demand*...........  Trillion Btu/yr in oil                (2.37)      (0.0381)        (2.41)
                                             equivalent.                                                            
    Off-Site Electricity Demand*..........  Trillion Btu/yr in oil                 10.0         (1.05)         8.95 
                                             equivalent.                                                            
    Steam Demand..........................  Trillion Btu/yr in oil                (2.88)       (0.010)        (2.89)
                                             equivalent.                                                            
    Total Energy Demand**.................  Trillion Btu/yr in oil                 4.78         (1.08)         3.70 
                                             equivalent.                                                            
    Total Energy Equivalent...............  Number of Households***.......       46,100       (10,400)      35,700  
    ----------------------------------------------------------------------------------------------------------------
    Parentheses indicate energy savings.                                                                            
    * Assumes an overall electrical generating efficiency of 25 percent. (DCN 14797).                               
    * * Totals do not equal the sum of each line item due to rounding. Refer to Section 11 of the Supplemental      
      Technical Development Document which presents detailed energy estimates.                                      
    * * * Assumes 103.6 million Btu/household/yr (Energy Information Administration (DOE) 1993).                    
    
        The manufacture of sodium chlorate, the raw material used at pulp 
    mills to manufacture chlorine dioxide, requires much more electrical 
    energy than the manufacture of chlorine or other commonly used 
    bleaching chemicals. As a result, off-site electrical demand increases 
    by 8.95 trillion Btu/yr (2.61 million MWhr/yr) because of the effluent 
    limitations guidelines and standards promulgated today. EPA estimates 
    of changes in energy demand as mills install advanced technologies can 
    be found in DCN 14488.
        The total increase in energy demand resulting from this rule is 
    equivalent to the energy required for 35,700 households. Compared to 
    the most recent data for total national energy consumption, the rule 
    represents a 0.004 percent increase in energy demand. EPA concludes 
    that the technologies that form the basis of BAT, PSES, and BMPs for 
    bleached papergrade kraft and soda and papergrade sulfite mills do not 
    pose significant adverse impacts in nation-wide energy demand.
    3. Incidental BOD5 Removal and Sludge
        The process changes that form the basis for BAT, PSES, and BMP 
    increase by approximately 1.5 percent the amount of spent pulping 
    liquor collected and combusted by bleached papergrade kraft and soda 
    mills. Spent pulping liquor is a significant source of BOD5 
    loadings at these mills. The collection and combustion of this spent 
    pulping liquor results in an approximately 20 percent decrease in 
    BOD5 load into treatment. (EPA expects that papergrade 
    sulfite mills will have similar trends, but lacks data to calculate 
    residuals.)
        Sludge is generated as a byproduct of the wastewater treatment 
    systems used at pulp and paper mills. Primary sludge
    
    [[Page 18578]]
    
    (i.e., solids removed during physical wastewater treatment processes 
    such as sedimentation prior to biological treatment) is high in wood 
    fiber and volatile solids. Secondary sludge is the product of 
    biological treatment in which microorganisms consume organic matter 
    (BOD5) in the wastewater. Secondary sludge is a gelatinous 
    mixture of bacterial and fungal organisms. Because of the reduction in 
    BOD5 load into treatment, the combined application of BAT 
    limitations, PSES, and BMPs promulgated today will decrease sludge 
    generation by 35,900 kkg/yr (39,600 short tons/yr), which represents a 
    2 percent reduction from the mid-1995 baseline for subpart B and E 
    mills.
        Sludge generated at bleached papergrade kraft and soda and 
    papergrade sulfite mills may contain dioxin and furan if these 
    pollutants contaminate the wastewater treated at these mills. At 
    proposal, the Agency estimated that the mills in these two 
    subcategories generated 177 g/yr TEQ dioxin and furan in their 
    wastewater treatment sludge. Since the proposal, industry has 
    significantly reduced the level of dioxin and furan in its wastewater. 
    The Agency estimates that the dioxin and furan content of the sludge 
    has decreased similarly, to approximately 50 g/yr TEQ. See the 
    Supplemental Technical Development Document, DCN 14487.
        The process changes that form the basis of the BAT limitations and 
    PSES promulgated today limit the concentration of dioxin and furan 
    allowed to be discharged to the wastewater treatment system. As a 
    result, the Agency estimates that when fully implemented, the combined 
    application of BAT limitations and PSES will reduce the present sludge 
    loading of dioxin and furan TEQ by 43 g/yr, approximately an 85 percent 
    reduction from current levels. The period of time before individual 
    mills have reached this level will vary somewhat depending on the 
    compliance schedule incorporated in the permit and the type of 
    treatment system in place at each mill. See the Supplemental Technical 
    Development Document, DCN 14487.
        EPA concludes that the technologies that form the basis of BAT, 
    PSES, and BMPs for the Bleached Papergrade Kraft and Soda and 
    Papergrade Sulfite subcategories are beneficial from the standpoint of 
    solid waste generation. The technologies both reduce the quantity of 
    solid waste generated and also improve its quality by reducing the 
    pollutant loading in the sludge generated.
    4. Other Environmental Impacts
        Wood consumption at the bleached papergrade kraft and soda mills 
    will be reduced by up to 0.3 percent by the final BAT limitations and 
    PSES promulgated today. The wood savings results from a reduction in 
    losses of useful fiber associated with the recovery of liquor spills 
    and improvements in brownstock washing and screening of pulp. EPA 
    estimates no change in wood consumption at mills in the Papergrade 
    Sulfite subcategory.
        The control technologies that form the basis of the effluent 
    limitations guidelines and standards promulgated today will reduce 
    bleached papergrade kraft and soda mill effluent wastewater flows. The 
    greatest reductions would be realized in mills presently discharging 
    the highest flows. In 1995, the average bleached kraft mill discharged 
    approximately 95 m\3\/metric ton effluent (23,000 gallons/metric ton). 
    For a 1,000 metric ton/day mill, the average effluent flow is similar 
    to that from a city of 250,000 people. The effluent limitations 
    guidelines and standards will reduce total effluent flow in two ways: 
    (1) Closure of brownstock screening systems, and (2) BMPs. At a mill 
    with open screening, closure could reduce total effluent flow by 25 
    percent. BMP implementation could result in further effluent flow 
    decreases of two percent. EPA estimates a small reduction in wastewater 
    effluent flow from mills in the Papergrade Sulfite subcategory.
        EPA concludes that the technologies that form the basis of BAT, 
    PSES, and BMPs for the Bleached Papergrade Kraft and Soda and 
    Papergrade Sulfite subcategories are beneficial from the standpoint of 
    wood use and wastewater generation, and will not produce significant 
    adverse non-water quality environmental impacts.
    
    D. Non-Water Quality Environmental Impacts of New Source Performance 
    Standards and Pretreatment Standards for New Source (NSPS and PSNS)
    
        EPA analyzed the projected non-water quality environmental impacts 
    of BAT for the Bleached Papergrade Kraft and Soda subcategory for BAT, 
    PSES, and BMPs based on complete substitution of chlorine dioxide for 
    chlorine and other technology elements. This section presents the non-
    water quality environmental impacts of a second technology 
    configuration (NSPS and PSNS) which is equivalent to BAT, PSES, and 
    BMPs with the addition of extended delignification (oxygen 
    delignification or extended cooking) on a new 1000 tpd bleached 
    papergrade kraft fiber line.
        Table VII-7 presents the non-water quality environmental impacts of 
    the selected technology basis for NSPS and PSNS, compared to 
    conventional pulping and bleaching technology. These estimates are 
    based on the same calculational methodology described under BAT and 
    PSES, applied to a 1000 tpd model mill. Based on these estimates, EPA 
    concludes that the process technologies that form the basis for NSPS 
    and PSNS for the Bleached Papergrade Kraft and Soda subcategory pose no 
    significant adverse non-water quality environmental impacts.
    
     Table VII-7.--Non-Water Quality Environmental Impacts of NSPS/PSNS for 
               the Bleached Papergrade Kraft and Soda Subcategory           
    ------------------------------------------------------------------------
                                                   1000 tpd fiber line      
    ------------------------------------------------------------------------
    Wood Consumption.......................  No Difference.                 
    Effluent Flow..........................  Moderate Decrease.\1\          
    BOD to Treatment.......................  Decrease by 11,300 kg/day.     
    Sludge Generation......................  Decrease by 890 kg/day.        
    Carbon Dioxide.........................  Decrease by 21,700 Mg/year.    
    Energy Impacts:                                                         
        Total Electricity Demand...........  Decrease by 222,600 million BTU/
                                              year in oil equivalent.       
        Total Steam Demand.................  Increase by 60,180 million BTU/
                                              year in oil equivalent.       
        Total Energy Demand................  Decrease by 162,400 million BTU/
                                              year in oil equivalent.       
    Air Emissions:                                                          
        Hazardous Air Pollutants...........  Increase by 407 Mg/year.       
        Chloroform.........................  No Difference.                 
        Volatile Organic Compounds.........  Increase by 707 Mg/year.       
    
    [[Page 18579]]
    
                                                                            
        Total Reduced Sulfur...............  Increase by 28 Mg/year.        
        Particulate Matter.................  Decrease by 12 kg/year.        
        Carbon Monoxide....................  Decrease by 3 Mg/year.         
        Nitrogen Oxides....................  Decrease by 28 Mg/year.        
        Sulfur Dioxides....................  Decrease by 56 Mg/year.        
    ------------------------------------------------------------------------
    1 See Section 11.4.1.3 of the Supplemental Technical Development        
      Document, DCN 14487.                                                  
    
        NSPS and PSNS that EPA is promulgating today for the Papergrade 
    Sulfite subcategory are equivalent to BAT and PSES. Therefore, the NSPS 
    and PSNS present no additional non-water quality environmental impacts.
    
    VIII. Analysis of Costs, Economic Impacts, and Benefits
    
    A. Summary of Costs and Economic Impacts
    
        This section presents a summary of EPA's evaluation of the costs, 
    economic impacts, and benefits of the Cluster Rules. A more detailed 
    analysis is contained in the Economic Analysis for the National 
    Emission Standards for Hazardous Air Pollutants for Source Category: 
    Pulp and Paper Production; Effluent Limitations Guidelines, 
    Pretreatment Standards, and New Source Performance Standards: Pulp, 
    Paper, and Paperboard Category--Phase 1 (DCN 14649; hereafter, the 
    Economic Analysis).
        Today's action is a significant departure from prior EPA 
    rulemakings in that, for one industry, EPA is considering the 
    ramifications of implementing two major environmental statutes with 
    respect to pollution control, industrial technology and operations, 
    environmental impacts, costs, and economic impacts. As noted in Section 
    II of this preamble, today's rulemaking establishes regulations that 
    implement elements of both the CAA and CWA. The objective of this 
    economic analysis is to provide the most accurate portrayal possible of 
    the aggregate costs that the industry will face by implementing these 
    regulations, as well as the economic, financial, and social impacts 
    that EPA estimates will result from these costs. The economic impacts 
    of the combined, or joint, costs of the final CWA (BAT, NSPS, PSES, 
    PSNS, and BMP) requirements and the final and proposed CAA requirements 
    (MACT I, MACT III, and proposed MACT II) are different than the impacts 
    that would result from the costs of the CWA or CAA requirements 
    considered separately. While EPA presents separately the CWA and CAA 
    compliance costs and the economic impacts of those costs in this 
    section, the Agency believes the most accurate estimation of the 
    economic impacts that the pulp and paper industry will experience is 
    derived by considering total (combined) compliance costs of both the 
    CAA and CWA rules. Under the CWA, EPA considered the economic impacts 
    of each option by subcategory, combining indirect and direct 
    dischargers. EPA combined these groups because there are no differences 
    between direct and indirect dischargers in each subcategory with 
    respect to characteristics of wastewater generated or the model process 
    technologies considered.
        The compliance costs described in this section are EPA's best 
    estimates of the actual costs facilities will incur to comply with the 
    promulgated and proposed rules.
        The total annualized and operation and maintenance (O&M) costs 
    differ somewhat from the engineering cost estimates shown in Section 
    VI. The annual O&M costs shown in this section include a general and 
    administrative cost of four percent of capital costs, which makes these 
    O&M costs significantly higher than the engineering O&M cost estimates 
    shown in Section VI. The annualized costs shown in Section VIII are 
    both pre-tax and post-tax. Pre-tax costs, because they capture total 
    economic losses to society, are considered the social costs of the rule 
    and are used for examining cost-effectiveness (Sections VIII.D.4 and 
    VIII.F.1) and for comparing the costs and benefits of the rule (Section 
    VIII.H). Post-tax costs, which represent the projected costs to a firm 
    after tax shields for depreciation and other factors are accounted for, 
    are used in the economic achievability determination under the Clean 
    Water Act to evaluate facility closures, firm failures, and related 
    impacts. Post-tax costs are used in Sections VIII.A, VIII.B, VIII.C, 
    VIII.E, VIII.J, and most of Sections VIII.D and VIII.F.
        EPA's financial and economic analyses reflect as accurately as 
    possible the information that pulp and paper industry managers will 
    consider in making financial decisions. The economic impacts described 
    in this section (such as facility closures, job losses, and reduced 
    shipments) result from the total costs that a facility will bear 
    (including environmental compliance costs) compared to the facility's 
    expected revenues. EPA also evaluated the aggregate costs for all 
    facilities borne by each company to determine if each company will be 
    in jeopardy of bankruptcy as a result of aggregate compliance costs.
        In this section, EPA also describes the qualitative, quantitative, 
    and monetized benefits of environmental improvements expected to result 
    from compliance with these rules, and compares these benefits to the 
    costs of the rules. EPA identified 158 mills at proposal with kraft, 
    soda, sulfite or semi-chemical pulping processes. Of these, EPA now 
    projects that 155 mills will bear costs under the final MACT I and 149 
    mills will bear costs under the proposed MACT II (six mills do not 
    practice chemical recovery). These numbers could change over time as 
    mills change processes or close operations.
        EPA separately evaluated the compliance costs and economic impacts 
    of: (1) MACT I for the 155 mills that pulp wood using kraft, soda, 
    sulfite, or semi-chemical pulping processes; (2) combined final MACT I 
    and proposed MACT II for those mills; and (3) proposed MACT II for 
    combustion sources at the 149 mills. Although all of the regulatory 
    options and alternatives under consideration for MACT II are evaluated 
    in the EA, only the economic impacts related to the proposed regulatory 
    alternative are presented here. EPA estimates that there will be no 
    economic impacts associated with the MACT III regulations, which are 
    promulgated for mills that practice mechanical, secondary fiber, or 
    non-wood pulping or that produce paper or paperboard from purchased 
    pulp, because EPA believes that compliance with MACT III requirements 
    will neither impose costs nor result in additional emissions 
    reductions. For this reason, Section VIII presents no
    
    [[Page 18580]]
    
    further analysis of the MACT III regulations.
        EPA separately evaluated the impacts of the BAT, PSES, NSPS, PSNS, 
    and BMP requirements for the 86 mills currently in the Bleached 
    Papergrade Kraft and Soda subcategory and the 11 mills currently in 
    three segments of the Papergrade Sulfite subcategory. (One mill is in 
    both CWA subcategories.) Both direct and indirect discharging mills are 
    subject to BMPs. Hereafter, EPA's reference to BAT/PSES costs includes 
    the costs of complying with the final BMP requirements.
        EPA also evaluated the costs and impacts for the combination of 
    MACT I and BAT/PSES for the 96 bleached papergrade kraft and soda and 
    papergrade sulfite mills that are affected by both rules. EPA also 
    provides an estimate of the economic impacts when the proposed MACT II 
    costs are combined with the MACT I and BAT/PSES costs for these 96 
    mills. Finally, the economic impacts and costs for all 155 kraft, soda, 
    sulfite, and semi-chemical mills affected by air and/or water 
    regulations are reported.
        EPA also evaluated the impacts of NSPS or PSNS costs for new 
    sources, both singly and in combination with MACT I and proposed MACT 
    II costs.
        EPA evaluated economic achievability based on the relative 
    magnitude of compliance costs (in the form of total annualized costs) 
    and the resulting potential facility closures, potential job losses, 
    firm failures (potential bankruptcies), reduced value of shipments, 
    balance of trade effects, and indirect effects (reduced regional and 
    national output and employment which reflect the fact that impacts on 
    the pulp and paper industry will resonate throughout the economy). 
    Table VIII-1 presents a summary of annualized costs and projected mill 
    closures for the various rules and rule combinations. The level of 
    detail for reporting results in the preamble (and in the EA) is 
    sometimes constrained in order to protect confidential business 
    information. For that reason facility closures and job losses, for 
    example, are not identified for certain combinations of rules. All of 
    the results are contained in the confidential portion of the rulemaking 
    record.
    
                         Table VIII-1.--Summary: Costs and Economic Impacts of CAA and CWA Rules                    
    ----------------------------------------------------------------------------------------------------------------
                                                                            Rules                                   
                                       -----------------------------------------------------------------------------
                                                                                MACT I and  MACT I, BAT/ MACT I, BAT/
             Costs and impacts             MACT I      MACT II      BAT/PSES     BAT/PSES     PSES and     PSES and 
                                          (final)     (proposed)    (final)      (final)      MACT II      MACT II  
                                        (all mills)  (all mills)    (BPK&PS)     (BPK&PS)     (BPK&PS)   (all mills)
    ------------------------------------------------------------------\1\-------------------------------------------
    Pre-Tax Annualized Costs ($ MM)                                                                                 
     \2\..............................          125           32          263          351          366          420
    Post-Tax Annualized Costs($ MM)...           82           23          172          229          240          277
    Mill Closures.....................            0            0            1            2            3            3
    Firm Failures.....................            0            0            0            0            0           0 
    ----------------------------------------------------------------------------------------------------------------
    \1\ BPK: Bleached Papergrade Kraft and Soda subcategory PS: Papergrade Sulfite subcategory.                     
    \2\ Pre-Tax costs are not used in determining economic achievability.                                           
    
        MACT Costs: Total annualized MACT I costs for 155 facilities in all 
    subcategories regulated today are $82 million (all annualized costs 
    presented in Section VIII are post-tax costs in 1995 dollars, except 
    where noted). These costs differ from the engineering MACT control cost 
    estimates presented in Section VI, as noted above and in Section 
    VIII.B.1.c. Total annualized proposed MACT II costs for all 
    subcategories that EPA proposes to regulate are $23 million. No mill 
    closures, job losses, or firm failures are projected when either MACT I 
    or proposed MACT II costs are analyzed individually. When the costs for 
    final MACT I and proposed MACT II are combined, the (post-tax) 
    annualized costs are $105 million and result in one estimated mill 
    closure and losses of up to 700 jobs. No firm failures are predicted as 
    a result of the combined costs of MACT I and MACT II.
        BAT/PSES Costs: EPA estimated economic impacts for three BAT/PSES 
    options (Option A, Option B, and TCF) for all bleached papergrade kraft 
    and soda mills. Section VI.B.5.a(1) of this preamble contains a 
    description of each option. The naming conventions of Option A, Option 
    B, and TCF, which EPA introduced in that section, are also used here. 
    EPA selected Option A as the technology basis for BAT/PSES for the 
    Bleached Papergrade Kraft and Soda subcategory (see Section 
    VI.B.5.a(5)). For the 11 mills in three segments of the Papergrade 
    Sulfite subcategory, the Agency estimated the economic impacts of one 
    technology for each segment. EPA selected those technologies as the 
    bases for BAT/PSES for this subcategory (see Sections VI.B.6.b and d). 
    EPA presents a summary of the economic impacts of the selected BAT/PSES 
    technology bases immediately below. A summary of the economic impacts 
    for the rejected BAT/PSES options in the Bleached Papergrade Kraft and 
    Soda subcategory is presented in Section VIII.F.
        Total annualized costs for the selected BAT/PSES for the 96 mills 
    in the Bleached Papergrade Kraft and Soda and Papergrade Sulfite 
    subcategories are $172 million. One mill closure is predicted for the 
    Bleached Papergrade Kraft and Soda subcategory as a result of 
    compliance costs. Estimates of job losses are not presented in order to 
    protect confidential business information. EPA estimates no closures 
    for the Papergrade Sulfite subcategory as a result of compliance costs. 
    EPA estimates that no firm failures will result from BAT/PSES in these 
    subcategories. Based on current information, EPA projects that there 
    may be some new sources, most likely new fiber lines at existing pulp 
    and paper mills. EPA has identified the per plant NSPS/PSNS costs for 
    the Bleached Papergrade Kraft and Soda and the Papergrade Sulfite 
    subcategories. EPA did not have sufficient information to reliably 
    project the likely number of new sources (see Section VIII.D). EPA also 
    expects that many replacement fiber lines constructed at Subpart B 
    mills will be enrolled in the Voluntary Advanced Technology Incentives 
    Program and will therefore be existing sources rather than new sources. 
    40 CFR 430.01(j)(2). EPA also conducted a barrier to entry analysis for 
    new sources, discussed below.
        Combined Costs: The combined annualized costs for MACT I and BAT/
    PSES, affecting 96 bleached papergrade kraft and soda and papergrade 
    sulfite mills, are $229 million. As a result of these costs, two mills 
    in the Bleached Papergrade Kraft and Soda subcategory are projected to 
    close with an associated loss of 900 jobs. See Table VIII-3. No
    
    [[Page 18581]]
    
    mills are projected to close in the Papergrade Sulfite subcategory as a 
    result of compliance costs. No firm failures are predicted.
        The combined annualized costs for the proposed and final rules 
    (MACT I, BAT/PSES, and proposed MACT II) affecting the 96 bleached 
    papergrade kraft and soda and papergrade sulfite mills are $240 
    million. With these combined costs, three mills are projected to close. 
    The associated job losses increase with the additional projected 
    closure, but the estimate is not reported here in order to protect 
    confidential business information. No firm failures are expected to 
    result from the combined costs of MACT I, BAT/PSES, and proposed MACT 
    II for these mills.
        The annualized costs for the proposed and final rules (MACT I, BAT/
    PSES, and MACT II) applicable to all 155 kraft, soda, sulfite, and 
    semi-chemical mills are $277 million. With these combined costs for all 
    rules and all 155 mills, the impacts are unchanged; i.e., three mills 
    are projected to close, job losses exceed 900, and no firm failures are 
    expected.
    
    B. Overview of Economic Analysis
    
    1. Revisions in Analysis From Proposal
        a. Subcategories. Based on the subcategorization described in 
    Sections II.C.1, VI.A and VI.B.1, EPA estimated impacts for four CAA 
    subcategories--Kraft, Sulfite, Soda, and Semi-Chemical Process--and two 
    CWA subcategories--Papergrade Sulfite and Bleached Papergrade Kraft and 
    Soda. The economic analysis addresses 155 mills in the CAA 
    subcategories and 96 mills in the CWA subcategories. The 96 CWA mills 
    are a subset of the 155 CAA mills.
        b. Options. (1) Air Emissions Standards. The selected technology 
    bases for the MACT I & III standards are discussed fully in Section 
    II.B.2 of this preamble. Regulatory options and alternatives for MACT 
    II are discussed in Section IV.F of the preamble to the proposed MACT 
    II standards, which appears elsewhere in today's Federal Register, and 
    in the Economic Analysis (DCN 14649). EPA's economic analysis presents 
    results for eight regulatory alternatives. The summary presented here 
    pertains only to the final MACT I standard and proposed MACT II 
    standard.
        (2) Effluent Limitations Guidelines and Standards. For the BAT/PSES 
    analyses for the Bleached Papergrade Kraft and Soda subcategory, EPA's 
    economic analysis addresses three technology options. The summary 
    presented in this section of the preamble focuses on Option A, the 
    selected BAT/PSES option, but a brief discussion of the impacts for the 
    rejected options appears below in Section VIII.F. For the Papergrade 
    Sulfite subcategory, EPA's economic analysis (and the summary presented 
    here) analyzes only the technologies selected as the bases for the BAT/
    PSES for each segment. This is because EPA identified no technically 
    available options for the three papergrade sulfite segments other than 
    those considered and selected.
        NSPS/PSNS costs for new sources are presented in Section VIII.D.
        c. Methodology. The methodologies used by EPA to evaluate economic 
    impacts at the time of proposal are fully discussed in the Economic 
    Impact and Regulatory Flexibility Analysis of the Proposed Effluent 
    Limitations Guidelines and NESHAP for the Pulp, Paper, and Paperboard 
    Industry (EPA-821-R-93-021, November, 1993). Revisions to these 
    methodologies are discussed below and more fully in Chapters 3 and 4 of 
    the Economic Analysis (DCN 14649).
        As discussed or referenced in the July 15, 1996 Notice, EPA revised 
    components of the economic methodology to account for recent changes 
    that have occurred in the pulp and paper industry, including: (1) 
    revision of the discount rate; (2) integration of market (price change) 
    effects into the financial closure model; (3) incorporation of new 
    industry cycle data into the forecasting methodology; (4) adjustment of 
    the starting year for the analysis to 1996; (5) incorporation of 
    updated mill ownership data in the firm failure model; and (6) a 
    revised method for calculating annual costs. See 61 FR at 36843-44. 
    Each of these methodology revisions is briefly discussed below.
        At proposal, EPA used a facility-specific cost of capital (an 
    average of nine percent real cost of capital) derived from responses to 
    a 1989 industry survey) that reflected financing costs in 1989. Real 
    (inflation-adjusted) financing costs declined considerably between 1989 
    and 1995. For the final rule, EPA primarily used an inflation-adjusted 
    seven percent cost of capital or discount rate in the economic analysis 
    because this rate better reflects real industry financing costs from 
    1995 to 1997, and the Agency does not have accurate information on 
    current facility-specific financing costs. Additionally, the Office of 
    Management and Budget recommends a seven percent discount rate to 
    evaluate the social costs of federal regulations. In Chapter 6 of the 
    Economic Analysis (DCN 14649), EPA presents a sensitivity analysis of 
    results using alternative discount rates.
        At proposal, EPA used both a financial model and a comprehensive 
    market model to assess economic effects. Much of the information in the 
    market model was derived from the 1989 survey. A number of substantial 
    changes have occurred in pulp and paper markets since 1989 that the 
    market model does not reflect. EPA decided not to update the market 
    model (which estimated price increases), because an update would have 
    required a new survey of every mill and all product lines, which would 
    have been unnecessarily costly and burdensome to mill operators. EPA 
    was also concerned that the amount of time required for conducting and 
    analyzing a second survey would unnecessarily delay the final rule. 
    This would further extend the industry's inability to plan and make 
    capital investments with certainty regarding regulatory requirements. 
    Instead, EPA modified the financial model to incorporate product supply 
    and demand elasticities, which are estimates of changes in demand or 
    supply in response to price changes. The summary of results presented 
    in this preamble does not reflect the effects of price increases, 
    because such changes did not materially affect EPA decisions. Chapter 6 
    of the Economic Analysis (DCN 14649) presents all of the results.
        The last year of price information available at proposal was 1988. 
    Between 1988 and 1995, the pulp and paper industry completed a full 
    industry revenue cycle, with revenues peaking in 1988, falling through 
    1992, and reaching historic heights in 1995. For the final rule, this 
    newer information was incorporated into the forecasting methods for the 
    financial closure model, which assumes this seven-year cycle (a six-
    year cycle was used at proposal) of falling and rising prices will 
    continue into the future. Additionally, the starting year for the 
    analysis was adjusted to 1996 (from 1989, which was used at proposal).
        To identify potential firm failures (i.e., bankruptcies) using the 
    Altman's Z financial ratio analysis, EPA obtained updated financial 
    information, including mill ownership data, for publicly held 
    companies. Because updated information for privately held companies was 
    not available from public sources, EPA did not evaluate possible 
    failures among private firms. To include these companies would have 
    required a new industry survey.
        A facility-level financial analysis that was conducted at proposal 
    was discontinued because EPA was also unable to update facility-level 
    financial information without a new survey. The facility-level analysis 
    is not a
    
    [[Page 18582]]
    
    component of the Altman's Z analysis, on which EPA has relied to 
    identify firm failures for this final rule. While providing some useful 
    information, the facility financial analysis was not used to identify 
    firm-level bankruptcies at proposal and did not provide the basis at 
    proposal for making determinations of economic achievability.
        As noted in Section VIII.A., EPA considers general and 
    administrative as well as variable annual costs in the cost 
    annualization calculation. At proposal, general and administrative 
    costs (GAC) had been calculated as 4 percent of capital costs plus 60 
    percent of variable annual costs. Subsequent analysis indicated that 
    the engineering estimates for effluent control already included the 60 
    percent of variable annual costs. To remove this double-counting, GAC 
    is now calculated as four percent of capital costs for effluent control 
    (see DCN 14086). GAC is added after the engineering estimates prior to 
    cost annualization; this explains the differences between engineering 
    and economic estimates of operating and maintenance costs.
        All of the previously discussed revisions were made in an effort to 
    conduct an economic analysis of the air and water regulations that is 
    more representative of current economic conditions in the pulp and 
    paper industry and that provides more accurate economic impact results.
    
    C. Costs and Economic Impacts for Air Emissions Standards
    
        Table VIII-2 presents the engineering control cost estimates for 
    MACT I and for the regulatory alternative proposed for MACT II: $755 
    million in total capital costs and $172 million in annualized costs. A 
    more detailed discussion of the control costs for the final MACT 
    standard, including emission reductions and cost-effectiveness, is 
    provided in Chapter 20 of the Background Information Document. Table 
    VIII-2 also presents the capital costs and pre-tax and post-tax 
    annualized costs used in the economic analysis. EPA has determined that 
    the MACT III standards will impose no costs; therefore, none is 
    presented here or in Table VIII-2.
        As noted in Section VIII.A. and Chapter 5 of the Economic Analysis, 
    the engineering control cost estimates of the cost of MACT regulations 
    differ from the costs used in EPA's economic impact analysis of those 
    standards. The economic analysis also differentiates between pre-tax 
    annualized costs and post-tax annualized costs as discussed in Section 
    VIII.A.
    
                                 Table VIII-2.--Estimates of the Cost of Air Regulations                            
                                                  [Millions of dollars]                                             
    ----------------------------------------------------------------------------------------------------------------
                                                         MACT control cost     Economic analysis MACT cost estimates
                                                             estimates        --------------------------------------
                       Regulation                   --------------------------                  Annualized costs    
                                                       Capital     Annualized    Capital   -------------------------
                                                        costs         cost         cost       Pre-tax      Post-tax 
    ----------------------------------------------------------------------------------------------------------------
    MACT I.........................................         $496         $130         $501         $125          $82
    MACT II........................................          259           42          258           32           23
    Total Air......................................          755          172          759          157          105
    ----------------------------------------------------------------------------------------------------------------
    
        Based on the economic analysis, EPA predicts no firm failures, mill 
    closures, or associated job losses as a result of the costs of the MACT 
    rules considered individually. When the costs of the MACT rules are 
    combined, EPA projects one mill closure with up to 700 job losses. No 
    firm failures are anticipated for the combined MACT rules.
    
    D. Costs and Economic Impacts for Effluent Limitations Guidelines and 
    Standards
    
    1. BPT and BCT
        As explained in Section VI.B.2, EPA is exercising its discretion 
    not to revise BPT limitations for conventional pollutants at this time 
    for Subparts B and E. In addition, candidate BCT technologies do not 
    pass the two-part BCT cost reasonableness test. Therefore, EPA is not 
    revising the current BCT limitations for Subparts B and E mills; as a 
    result, these mills will incur no incremental BPT or BCT costs.
    2. Bleached Papergrade Kraft and Soda Subcategory
        a. BAT/PSES. For the selected BAT/PSES (Option A), capital costs 
    are $966 million, O&M costs are $151 million, and annualized costs are 
    $162 million. When considering these costs alone, the economic analysis 
    predicts closure of one mill as a result of this rule and no firm 
    failures. Other economic impacts (e.g., job losses) are reported in the 
    CBI portion of the rulemaking record.
        b. NSPS and PSNS. EPA considered the cost of NSPS and PSNS 
    technology for new source mills in the Bleached Papergrade Kraft and 
    Soda subcategory. EPA expects few new source mills or fiber lines to be 
    constructed that will be subject to NSPS/PSNS. Even if new source mills 
    or fiber lines are constructed that are subject to NSPS/PSNS, EPA 
    estimates that the selected NSPS/PSNS would not present a barrier to 
    entry. EPA estimated the average incremental capital costs of NSPS/PSNS 
    compliance (compared to Option A technology) to be approximately 0.50 
    to 2.0 percent of the capital cost of constructing a new source mill or 
    fiber line and concluded that this cost was not sufficient to present a 
    barrier to entry for proposed entrants, particularly considering the 
    lower operating costs of Option B.
    3. Papergrade Sulfite Subcategory
        a. BAT/PSES. As explained in Section VI.B.6.a, EPA is dividing the 
    Papergrade Sulfite subcategory into three segments. For BAT/PSES for 
    all three segments combined, capital costs are $73.8 million, O&M costs 
    are $7 million, and annualized costs are $9.8 million. No mills are 
    projected to close as a result of these compliance costs, and no firms 
    are projected to fail. There is no expected loss of jobs, shipments, or 
    exports.
        b. NSPS/PSNS. EPA considered the costs of NSPS/PSNS for new source 
    mills in the Papergrade Sulfite subcategory. Because NSPS/PSNS equals 
    BAT/PSES, EPA concluded that such costs were not sufficient to present 
    a barrier to entry. First, the cost of the NSPS/PSNS technology is an 
    insignificant fraction of the capital cost of a new source mill or 
    fiber line (less than one percent). Also, the costs of including the 
    selected NSPS/PSNS technology at a new source mill are substantially 
    less on a per ton basis than the costs of retrofitting existing mills. 
    Moreover, the increased chemical recovery and reduced operating costs 
    for the NSPS/PSNS option allow firms to
    
    [[Page 18583]]
    
    recover the capital cost associated with the NSPS/PSNS technology.
    4. Cost-Effectiveness
        EPA uses a cost-effectiveness ratio of dollars per toxic pound 
    equivalent removed (see Economic Analysis (DCN 14649), Chapter 5) to 
    evaluate the relative efficiency of a technology option in removing 
    toxic pollutants. The results reported below are expressed in 1981 
    dollars, as prescribed by EPA's cost-effectiveness methodology (DCN 
    14649). For the Bleached Papergrade Kraft and Soda subcategory, the 
    cost-effectiveness ratio for both BAT and PSES is $14 per toxic pound 
    equivalent removed. The cost-effectiveness ratios for the Papergrade 
    Sulfite subcategory are $13 per toxic pound equivalent removed for BAT 
    and $45 per toxic pound equivalent for PSES. EPA considers the selected 
    technology bases for the BAT/PSES limits for both subcategories to be 
    cost-effective.
    
    E. Costs and Impacts for the Integrated Rules
    
        EPA estimates that 155 kraft, soda, sulfite, and semi-chemical 
    mills will incur costs to comply with the CAA rules; 96 bleached 
    papergrade kraft and soda and papergrade sulfite mills will incur costs 
    to comply with the CWA rule, and the same 96 mills will incur both CAA 
    and CWA rule costs. Table VIII-3 is a summary of the expected costs and 
    impacts for various combinations of CAA and CWA rules. The losses of 
    jobs, shipments, exports, and indirect effects reported in Table VIII-3 
    are the impacts derived from mill closures. Some results are not 
    disclosed where confidentiality might be compromised.
    
                             Table VIII-3.--Costs and Economic Impacts of CAA and CWA Rules                         
    ----------------------------------------------------------------------------------------------------------------
                                                                            Rules                                   
                                       -----------------------------------------------------------------------------
                                                                                            MACT I, BAT/ MACT I, BAT/
             Costs and Impacts             MACT I      MACT II      BAT/PSES     MACT I &   PSES & MACT  PSES & MACT
                                          (final)     (proposed)  (BPK&PS)\1\    BAT/PSES   II (BPK&PS)    II (155  
                                                                                (96 mills)   (96 mills)     mills)  
    ----------------------------------------------------------------------------------------------------------------
    Capital Costs ($MM)...............          501          258        1,039        1,394        1,524        1,799
    Post-Tax Annualized Costs ($MM)...           82           23          172          229          240          277
    Mill Closures.....................            0            0            1            2            3            3
    Firm Failures.....................            0            0            0            0            0            0
    Job Losses (from mill closures)...            0            0          400          900        1,700        1,700
    Decreased Shipments ($MM).........            0            0          150          273          479          479
    Decreased Exports ($MM)...........            0            0           19           19           22           22
    Direct and Indirect Effects ($MM).  ...........  ...........          430          795        1,393       1,393 
    ----------------------------------------------------------------------------------------------------------------
    \1\ BPK: Bleached Papergrade Kraft and Soda subcategory.                                                        
    PS: Papergrade Sulfite subcategory.                                                                             
    
        While no mills are predicted to close due to MACT I costs alone, 
    and one mill in the Bleached Papergrade Kraft and Soda subcategory is 
    predicted to close due to BAT/PSES costs alone, EPA estimates that two 
    mills in the Bleached Papergrade Kraft and Soda subcategory may close 
    as a result of the combined costs imposed by these rules. The two 
    predicted closures represent approximately 2.3 percent of the 86 
    bleached papergrade kraft and soda mills and 1.3 percent of all 155 
    kraft, sulfite, soda, and semi-chemical mills affected by this 
    rulemaking. As a result of these two closures, 900 jobs could be lost. 
    These jobs represent 0.9 percent of the jobs in the Bleached Papergrade 
    Kraft and Soda subcategory. These costs generate a maximum estimated 
    price increase of 1.5 percent for any product (pulp, paper or 
    paperboard). Estimated losses in the value of shipments are 
    approximately $273 million, or 0.8 percent of bleached papergrade kraft 
    and soda shipments, while losses in the value of bleached papergrade 
    kraft and soda exports are approximately $19 million, or 0.5 percent of 
    subcategory exports.
        No mills are projected to close in the CWA Papergrade Sulfite 
    subcategory, or the CAA soda, sulfite, or semi-chemical subcategories 
    as a result of either the promulgated CAA or CWA regulations or a 
    combination of both.
        EPA examined the indirect effects of the final regulations (MACT I, 
    MACT III and BAT/PSES) on employment and output using a national-level 
    input-output model developed by the U.S. Department of Commerce. The 
    model provides multipliers that enable EPA to estimate national-level 
    impacts based on the loss of employment and output from closing mills. 
    Total projected effects on the U.S. economy of the combined MACT I and 
    BAT/PSES are approximately 5,700 jobs lost and $795 million in lost 
    economic output. While some local communities could experience some 
    economic dislocation as a result of closures, overall national impacts 
    would be insignificant. For comparison, the 1995 U.S. gross domestic 
    product was $7.3 trillion. The loss is approximately one-tenth of 1 
    percent of the gross domestic product for 1995. EPA also evaluated 
    regional (county-level) economic impacts when determining the economic 
    achievability of the regulation. For the final MACT I and BAT/PSES, in 
    the two counties where mills are projected to close, the unemployment 
    rate would increase by 0.4 percent and 0.7 percent respectively.
        In response to public comments, EPA also estimated the economic 
    impacts associated with the combined costs of promulgated and proposed 
    rules. When the MACT I, BAT/PSES, and MACT II costs are considered 
    jointly, EPA projects an additional mill closure with 800 additional 
    jobs lost and further decreases of $206 million in shipments and $3 
    million in exports. The total projected effects of the combined MACT 1, 
    BAT/PSES, and MACT II costs are approximately 10,000 jobs lost and $1.4 
    billion in lost economic output.
    
    F. Costs and Impacts of Rejected BAT/PSES Options for the Bleached 
    Papergrade Kraft and Soda Subcategory
    
    1. Summary of Results
        Table VIII-4 presents costs and impacts for two options (Option B 
    and TCF) that EPA evaluated, but did not select, as the basis for BAT/
    PSES for the Bleached Papergrade Kraft and Soda subcategory. EPA's 
    rationale for selecting Option A for BAT/PSES for this subcategory is 
    presented in Section VI.B.5.a(5). Table VIII-4 presents results in 
    three ways: considering CWA costs and impacts alone; considering the 
    costs and impacts of the rejected BAT/PSES options and MACT I; and 
    considering
    
    [[Page 18584]]
    
    the costs and impacts of the rejected BAT/PSES options, MACT I, and 
    MACT II.
    
      Table VIII-4.--Costs and Economic Impacts of Rejected BAT/PSES Options for the Bleached Papergrade Kraft and  
                                                    Soda Subcategory                                                
    ----------------------------------------------------------------------------------------------------------------
                                                                            Rules                                   
                                       -----------------------------------------------------------------------------
                                                                                              Option B              
              Costs & Impacts             Option B    TCF (BAT/     Option B   TCF + (BAT/   (BAT/PSES)   TCF, (BAT/
                                         (BAT/PSES)     PSES)     (BAT/PSES)+   PSES) MACT    MACT I &    PSES) MACT
                                                                     MACT I         I         MACT II    I & MACT II
    ----------------------------------------------------------------------------------------------------------------
    Capital Costs ($MM)...............        2,100        3,100        2,600        3,600        2,700        3,700
    Post-Tax Annualized Costs ($MM)...          216          688          292          764          300          772
    Mill Closures.....................            2            7            4            9        ND\1\            9
    Firm Failures.....................        (\3\)        (\3\)        (\3\)        (\3\)        (\3\)        (\3\)
    Job Losses (from mill closures)...          900        7,100        4,800       10,200           ND       10,200
    Decreased Shipments ($MM).........          273        2,300        1,300        3,200           ND        3,200
    Decreased Exports ($MM)...........           19          308           24          310           ND          310
    Direct and Indirect Effects ($MM).          795           NR        3,850           NR           ND          NR 
    ----------------------------------------------------------------------------------------------------------------
    \1\ ND: not disclosed to protect confidential business information.                                             
    \2\ NR: not reported.                                                                                           
    \3\ 1 or more.                                                                                                  
    
        Option B: The BAT/PSES capital costs for Option B for the Bleached 
    Papergrade Kraft and Soda subcategory are estimated at $2.1 billion; 
    O&M costs are $87 million; and annualized costs are $216 million. These 
    costs result in two projected mill closures, with direct impacts of at 
    least 900 jobs lost, $273 million in decreased shipments, $19 million 
    in decreased exports, and one or more potential firm failures. The firm 
    failures may also result in thousands of additional jobs lost (see 
    Section VI.B.5.a(5) and Chapter 6 of the Economic Analysis, DCN 14649). 
    Indirect and direct economic loss (i.e., losses throughout the economy 
    as a result of the closed mills) would be approximately $795 million. 
    The mill closures are projected to increase county unemployment rates 
    for the affected counties by 0.4 percent and 0.7 percent, respectively.
        EPA also calculated cost-effectiveness ratios for Option B for this 
    subcategory (for Option A results, see Section VIII.D.4, above). For 
    direct dischargers, the average and incremental (compared to Option A) 
    cost-effectiveness ratios are $15 per toxic pound-equivalent and $36 
    per toxic pound-equivalent, respectively (1981 dollars). For indirect 
    dischargers, the incremental cost-effectiveness (compared to Option A), 
    is $115 per toxic pound-equivalent.
        Option B and MACT I: The combined capital costs for Option B and 
    MACT I for mills in this subcategory are estimated at $2.6 billion; O&M 
    costs are $154 million; and annualized costs are $292 million. MACT I 
    annualized costs are greater under Option B than under Option A due to 
    the additions of MACT controls for oxygen delignification equipment 
    installed to comply with Option B. With the combined costs of Option B 
    and MACT I, the number of projected mill closures increases to four, 
    and the estimated number of firm failures remains unchanged at one or 
    more. The four closures cause losses of approximately 4,800 jobs, $1.3 
    billion in shipments, and $24 million of exports. Direct and indirect 
    losses would total nearly $4 billion. The mill closures are also 
    projected to increase county unemployment rates; the range of increased 
    unemployment for the affected counties is from less than 0.5 percentage 
    points to nearly 10 percentage points (as a hypothetical example, from 
    a baseline county unemployment rate of 10 percent to 10.5 percent after 
    a closure in County X and from a baseline of 10 percent to 20 percent 
    after a closure in County Y).
        Option B, MACT I, and MACT II: The combined capital costs for 
    Option B, MACT I, and proposed MACT II for mills in this subcategory 
    are estimated at $2.7 billion; O&M costs are $153 million; and 
    annualized costs are $300 million. With the combined costs of Option B, 
    MACT I, and MACT II, the number of projected mill closures increases 
    (number not disclosed), and the estimated number of firm failures 
    remains unchanged at one or more. The analysis projects additional 
    losses to jobs, shipments, and exports from the additional mill 
    closures (amounts not disclosed). Direct and indirect losses would also 
    increase, as would the unemployment rates in the counties in which the 
    mill closures are located.
        TCF: The capital costs for retrofitting mills in this subcategory 
    for TCF technology are estimated at $3.1 billion for TCF based on 
    peroxide bleaching and $5.6 billion for TCF based on ozone and peroxide 
    bleaching, respectively. EPA evaluated mill closures for the TCF option 
    with the lower capital costs. O&M costs for this option are $783 
    million, and annualized costs are $688 million. (TCF annualized costs 
    appear lower than annual O&M costs because of tax shields.) EPA 
    estimates that these costs would result in seven mill closures, which 
    are associated with approximately 7,100 job losses. EPA did not conduct 
    a firm failure analysis or calculate combined direct and indirect 
    impacts for this option because the closures and job losses alone are 
    more than sufficient indication that the option is not economically 
    achievable. EPA estimates, however, that a greater number of firms 
    would be placed in financial jeopardy with the costs of this option, 
    compared to Option B, which EPA has already determined is not 
    economically achievable (See Section VI.B.5.a(5)).
        TCF and MACT I: The combined capital costs for TCF and MACT I for 
    mills in this subcategory are estimated at $3.6 billion; O&M costs are 
    $851 million, and annualized costs are $764 million. EPA estimates that 
    these costs would result in nine mill closures and an associated loss 
    of 10,200 jobs, $3.2 billion in shipments, and $310 million in exports. 
    EPA conducted no additional economic analysis for this combination of 
    costs.
        TCF, MACT I, and MACT II: The combined capital costs for TCF, MACT 
    I, and MACT II for mills in this subcategory are estimated at $3.7 
    billion; O&M costs are $849 million; and annualized costs are $772 
    million. With the combined costs of TCF, MACT I, and MACT II, EPA 
    estimates that the number of mill closures, job losses, and
    
    [[Page 18585]]
    
    other impacts remain unchanged. EPA conducted no additional economic 
    analysis for this combination of costs.
    2. Implications of Results
        The costs of either Option B or TCF are projected to cause one or 
    more firm failures (bankruptcies). This is true even when the BAT/PSES 
    costs are considered without the compliance costs associated with MACT 
    I and/or MACT II. Although EPA cannot determine the actual outcome of 
    the projected failures in terms of lost production, closed facilities, 
    and lost jobs, the level of displacement would almost certainly cause 
    detrimental impacts to the U.S. pulp and paper industry. Section 
    VI.B.5.a(5) discusses EPA's reaction to these projected impacts in 
    terms of regulatory decisions. See also Chapter 6 of the Economic 
    Analysis, DCN 14649. That discussion also includes the Agency's 
    findings that the rejected BAT/PSES options are not economically 
    achievable.
    
    G. Benefits
    
        In addition to costs and impacts, EPA also estimated the 
    environmental and human health benefits of implementing the CAA and CWA 
    requirements. Section VII of this preamble describes the estimated 
    reductions in air emissions and effluent discharges. The incremental 
    environmental improvements noted in Section VII.B. are derived compared 
    to a baseline of current emissions and discharges. Because current 
    emissions and discharges are a function of current technology, this is 
    the same baseline that was used to establish the costs of complying 
    with the rules. To the extent the total benefits of the rule can be 
    measured, costs can be directly compared to benefits.
        EPA is confident that its estimation of compliance costs is a full 
    and accurate account of such costs; EPA is less confident that the 
    estimation of benefits is similarly complete. EPA is not currently able 
    to quantitatively evaluate all human and ecosystem benefits associated 
    with air and water quality improvements. EPA is even more limited in 
    its ability to assign monetary values to these benefits and therefore 
    to be able to compare them to costs in a standard cost-benefit 
    framework. A comparison of costs to only the limited monetized subset 
    of benefits severely underestimates the true benefits of environmental 
    quality improvement and compromises the validity of a cost-benefit 
    analysis. The economic benefit values described below and in the 
    Economic Analysis (DCN 14649) should be considered a limited subset of 
    the total benefits of these rules, and should be evaluated along with 
    descriptive assessments of benefits and the acknowledgment that even 
    these may fall short of the real-world benefits that will result from 
    the rule.
    1. Air Quality Benefits
        Section VII.B.1 of this preamble describes the emissions reductions 
    expected as a result of implementing MACT I and MACT II standards. 
    Implementation of the final MACT I standard is expected to reduce 
    emissions of HAPs, VOCs, and TRS, but increase emissions of PM, 
    SO2, CO, and NOX. The proposed alternative for 
    MACT II is expected to reduce emissions for HAPs, VOCs, PM, TRS, CO, 
    and SO2, while it is expected to create a slight increase in 
    NOx emissions. The technology bases for BAT/PSES have secondary impacts 
    on the level of air emissions. The combined effect of MACT I and MACT 
    II for all subcategories regulated under the CAA is to decrease 
    emissions for all of the above mentioned pollutants except 
    NOX and SO2. See Table VIII-5 below. EPA 
    performed an evaluation of the benefits associated with the air 
    regulations based on the emission reductions estimated in Section 
    VII.B.1. The net change in air benefits expected to result from the 
    changes in emissions will be a change in adverse health effects 
    associated with inhalation of the above pollutants as well as changes 
    in welfare effects such as improved visibility and crop yields, and 
    reduced materials soiling and corrosion. Chapter 4 of the EA presents a 
    detailed description of the methodology used to monetize the benefits.
        a. Qualitative Description of Pollutant Effects. The air rules are 
    designed to reduce the emission of HAPs as defined in Section 112 of 
    the CAA. Several of these HAPs are classified as probable or possible 
    human carcinogens. Reducing the emissions of these pollutants is 
    expected to reduce the cancer risk of the exposed population. Other 
    HAPs are not classified as carcinogens; however, they have been shown 
    to cause other adverse health effects such as damage to the eye, 
    central nervous system, liver, kidney, and respiratory system when the 
    concentration of these emissions is above the health reference 
    benchmark for human exposure.
        Total reduced sulfur (TRS) emissions cause the malodorous smell 
    often associated with areas near pulp and paper mills. The MACT 
    standards will reduce these effects significantly. Odorant stimulants 
    of the nasal receptors that are associated with TRS emissions have been 
    associated with marked respiratory and cardiovascular responses, 
    however, the association is not direct because the perception of the 
    odor does not necessarily cause toxic effects. The threshold for odor 
    detections may occur before the onset of toxic effects. However, the 
    absence of odor does not guarantee safety since some components of TRS 
    emissions can cause fatigue of the olfactory senses, so individuals may 
    not perceive an odor on some occasions when toxic effects can occur. 
    There are numerous anecdotal reports of adverse reactions related to 
    odors associated with TRS, including headaches, shortness of breath, 
    nasal irritation, and, in some cases, nausea and sinus congestion.
        VOC and NOX emissions interact in the presence of 
    sunlight to create ground-level ozone. Recent scientific evidence shows 
    an association between elevated ozone concentrations and increases in 
    hospital admissions for a variety of respiratory illnesses and 
    indicates that ground-level ozone not only affects people with impaired 
    respiratory systems (such as asthmatics), but healthy adults and 
    children as well. Adverse welfare effects of ozone exposure include 
    damage to crops, tree seedlings, ornamentals (shrubs, grass, etc.), and 
    forested ecosystems. The reactions between VOCs and NOX to 
    form ozone depend on the balance in concentrations of each pollutant 
    found in the ambient air. For example, when the concentration of 
    NOX is high relative to the concentration of VOCs, VOC 
    reductions are effective in limiting ozone formation, while 
    NOX reductions in that situation are ineffective. The 
    integrated rule is expected to increase NOX emissions, but 
    decrease VOC emissions. The increase in NOX is not expected 
    to cause significant adverse health or environmental impacts because 
    the magnitude of this increase is much less than the magnitude of the 
    VOC emission reduction. The VOC reductions are expected to contribute 
    to the decrease in ozone concentrations.
        The adverse human health effects associated with PM include: 
    premature mortality; aggravation of respiratory and cardiovascular 
    disease (as indicated by increased hospital admissions and emergency 
    room visits, school absences, work loss days, and restricted activity 
    days); changes in lung function and increased respiratory symptoms; 
    alterations in lung tissue and structure; and altered respiratory tract 
    defense mechanisms. Populations at greater risk from exposure are: 
    individuals with respiratory disease and cardiovascular disease, 
    individuals with infectious disease, elderly individuals, asthmatic 
    individuals, and children. Reduced
    
    [[Page 18586]]
    
    welfare is associated with elevated concentrations of fine particles 
    which reduce visibility, damage materials, and cause soiling. The 
    integrated rule will decrease the adverse effects of PM.
        CO is a colorless, odorless gas that is toxic to mammals. When 
    inhaled, it combines with hemoglobin, which reduces the oxygen-carrying 
    capacity of blood and results in less oxygen being transported to vital 
    organs of the body. This can have detrimental effects on the 
    cardiovascular, central nervous, and pulmonary systems. The reduction 
    of CO emissions will diminish these potential effects.
        SO2 oxidizes in water to form both sulfurous and 
    sulfuric acids. When SO2 dissolves in the water of the 
    respiratory tract of humans, the resulting acidity is irritating to the 
    pulmonary tissues, causing nasal irritation and breathing difficulties 
    (especially to individuals with respiratory diseases such as asthma). 
    When SO2 dissolves in the atmosphere in rain, fog, or snow, 
    the acidity of the deposition can corrode various materials and cause 
    damage to both aquatic and terrestrial ecosystems. SO2 can 
    also transform into PM2.5, the effects of which are 
    discussed above.
        b. Monetized Air Quality Benefits. Table VIII-5 below presents both 
    the health and welfare benefits described in this section as well as 
    the emission reductions identified in Section VII.B.1 that are not 
    monetized but are considered in the evaluation of benefits.
        The benefit transfer method is utilized to value a subset of the 
    pollutants discussed above (VOC, SO2, and PM). This method 
    relies on previous benefit studies that have been conducted for the 
    same pollutants that are impacted by the pulp and paper rulemaking. 
    These studies provide useful data that can be transferred across 
    contexts in order to approximate the benefits of the pulp and paper 
    emission reductions.
    
                                               Table VIII-5.--Emissions Reductions and Annual Air Quality Benefits                                          
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                             Standard                                       
                                                                    ----------------------------------------------------------------------------------------
                                                                                 MACT I                      MACT II                      Combined          
                               Pollutant                            ----------------------------------------------------------------------------------------
                                                                       Decrease                       Decrease       Value       Decrease                   
                                                                         (Mg)        Value  ($MM)       (Mg)         ($MM)         (Mg)        Value  ($MM) 
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    HAPs...........................................................      139,000                NE        2,600            NE      142,000                NE
    TRS............................................................       79,000                NE           --            NE       79,000                NE
    NOX............................................................       (5,200)               NE         (500)           NE       (5,700)               NE
    VOC............................................................      409,000          24-1,055       32,600          2-84      441,000          26-1,139
    PM.............................................................          (83)              (1)       24,000           300       24,000               299
    CO.............................................................       (8,700)               NE       58,000            NE       49,000                NE
    SO2............................................................      (94,500)        (1,064)-0           30       0.1-0.3      (94,400)      (1,064)-0.3
    Total..........................................................  ............    (1,040)-1,054  ............      302-384  ............     (739)-1,438 
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    NE = not estimated.                                                                                                                                     
    Numbers in parentheses ( ) indicate emissions increases or negative benefits values.                                                                    
    Numbers in table rounded.                                                                                                                               
    
        For VOCs, benefits are valued using estimates of a range of the 
    average benefit per Megagram (Mg) derived from a recent benefit 
    analysis conducted by EPA in the process of revising the ozone national 
    ambient air quality standard (NAAQS) (see docket no. A-95-58: 
    Regulatory Impact Analysis for the Particulate Matter and Ozone NAAQS 
    and proposed Regional Haze Rule; July 1997). EPA values a range of VOC 
    benefits reflecting (1) an assumption that the transfer of benefits 
    must correlate with the areas that violate the ozone standard, and (2) 
    an assumption that recognizes that reductions outside areas of 
    violation of the ozone standard can have a positive benefit. Therefore, 
    the range of values reflects the application of a range of values for 
    the average benefit per Mg as they are applied to (1) the subset of VOC 
    emission reductions in areas of violation, and (2) to all VOC emission 
    reductions expected to be achieved by the integrated rule. The true 
    value is likely to fall within this range. Using the range of values of 
    the average benefit per Mg for ozone, monetized annual VOC benefits of 
    MACT I emission reductions range from $24 million to $1,055 million. 
    The lower-end of this range reflects an assumption of zero mortality 
    effects associated with ozone exposure and assumes morbidity benefits 
    occur only in areas predicted to violate the ozone standard, while the 
    upper-end includes mortality estimates as are calculated for the upper-
    end of the range of ozone benefits is included in the NAAQS RIA and 
    assumes morbidity benefits occur in all areas. For the proposed MACT II 
    alternative, total annual VOC benefits range in value from 
    approximately $2 million to $84 million. Therefore, total monetized VOC 
    benefits of the integrated rule are approximately $26 million to $1,139 
    million.
        For PM, a benefit transfer estimate is obtained from a benefit 
    analysis of PM10 that was prepared to support the evaluation 
    of the revised PM NAAQS (see Appendix C of the Regulatory Impact 
    Analysis for the Particulate Matter and Ozone NAAQS and proposed 
    Regional Haze Rule; July 1997). The average benefit per Mg derived from 
    this study is applied to all changes in emissions of PM that result 
    from the integrated rule. Using this value, the loss in total monetized 
    annual PM benefits associated with MACT I is approximately $1 million. 
    The proposed MACT II alternative achieves a positive benefit 
    approximately equal to $300 million. Thus the combined value of PM 
    benefits for the final and proposed pulp and paper air standards is 
    $299 million.
        For SO2, the EPA transfers a benefit estimate from a 
    national SO2 strategy analysis conducted for the evaluation 
    of the revised PM NAAQS (see docket no. A-95-54: Regulatory Impact 
    Analysis for the Particulate Matter and Ozone NAAQS and proposed 
    Regional Haze Rule; July 1997). This analysis shows that benefit values 
    are higher in the eastern regions of the country when compared to the 
    western regions. Therefore, EPA derives a range of benefit per Mg 
    values for each segment of the country. In addition, EPA takes into 
    consideration the uncertainty inherent in the estimate of MACT I 
    SO2 emission increases that may result from the rulemaking. 
    Therefore for MACT I, EPA values all SO2 emission increases 
    to obtain a lower bound estimate of (negative) benefits and assumes 
    zero emission increases due to the likely effects of mitigating 
    behavior to obtain an upper bound estimate of zero
    
    [[Page 18587]]
    
    disbenefits. For MACT II, all emission reductions are valued. Using the 
    range of values for the average benefit per Mg for SO2 and 
    the assumptions for the changes in emissions, monetized annual 
    SO2 disbenefits of MACT I range from $1,064 million down to 
    $0. For the proposed MACT II alternative, total annual SO2 
    benefits are from approximately $0.1 to $0.3 million. Therefore, total 
    monetized SO2 benefits (disbenefits) of the integrated rule 
    are approximately ($1,064) million to $0.3 million.
        Summing the monetized benefits and disbenefits for VOC, PM, and 
    SO2 emission changes provides a range of total annual 
    benefits (disbenefits) for MACT I of approximately ($1,040) million to 
    $1,054 million. Aggregate annual benefits attributed to MACT II range 
    in value from $302 million to $384 million. Combining the benefits of 
    the final and proposed air standards yields a range of total annual 
    benefits from approximately ($739) million to $1,438 million.
        These benefits are incomplete due to EPA's inability to quantify 
    many benefit and disbenefit categories including individual health and 
    welfare endpoints as well as the benefits and disbenefits of 
    controlling entire pollutant categories. Pollutant categories that are 
    not monetized are HAPs, TRS, CO, and NOX.
        c. Uncertainties Associated With Air Quality Benefits. Benefit per 
    Mg estimates used to monetize PM and VOC emission reductions are 
    uncertain because average benefit per Mg values do not take into 
    account location-specific information such as the population exposed. 
    The location-specific information is expected to have a significant 
    effect on the estimated benefits associated with these emission 
    reductions. Also, lack of information for several benefit categories 
    precludes a complete quantification of all benefit categories (or 
    disbenefits for pollutant increases).
    2. Water Quality Benefits
        This section describes environmental and human health benefits 
    expected as a result of implementing new BAT/PSES limits at 92 of the 
    96 mills in the Bleached Papergrade Kraft and Soda and Papergrade 
    Sulfite subcategories. (EPA estimated benefits for 92 mills because it 
    did not have effluent discharge information from 3 mills and did not 
    have receiving stream flow data for 1 mill). Because EPA was not able 
    to project the number of new sources, EPA attributes no benefits to the 
    final NSPS or PSNS regulations. Discharge of toxic, nonconventional, 
    and conventional pollutants into freshwater, estuarine, and marine 
    ecosystems may alter aquatic habitats, affect aquatic life, and 
    adversely impact human health. See Section VII.B.2. Chlorinated organic 
    compounds from chlorine bleaching, particularly 2,3,7,8-
    tetrachlorodibenzo-p-dioxin (TCDD) and 2,3,7,8-tetrachlorodibenzofuran 
    (TCDF) are human carcinogens and human systemic toxicants and are toxic 
    to aquatic life. These pollutants are persistent, resistant to 
    biodegradation, and bioaccumulative in aquatic organisms. As of 
    December 1995, states have issued 19 dioxin/furan-related fish 
    consumption advisories near 18 papergrade sulfite and bleached 
    papergrade kraft and soda mills (EPA, National Listing of Fish 
    Consumption Advisories, June 1996).
        EPA's analysis of these environmental and human health risk 
    concerns and the water-related benefits resulting from the final 
    effluent limitations guidelines and standards for these two 
    subcategories is contained in the ``Water Quality Assessment of Final 
    Effluent Limitations Guidelines for the Papergrade Sulfite and Bleached 
    Papergrade Kraft and Soda Subcategories of the Pulp, Paper, and 
    Paperboard Industry'' (WQA) (DCN 14650).
        a. Qualitative Description of Water-Related Benefits. The final BAT 
    limitations and PSES promulgated today for Subparts B and E will 
    benefit aquatic life by reducing the pulp and paper industry's 
    discharge of toxic and nonconventional pollutants, including a 91 
    percent reduction in TCDD and TCDF, a 69 percent reduction in AOX, an 
    83 percent reduction in chloroform, and an 82 percent reduction in 
    chlorinated phenolic pollutants compared to mid-1995 discharge levels. 
    Toxic and nonconventional pollutants will be reduced to levels below 
    those considered to impact biota in many receiving waters. Pollution 
    reduction numbers are provided in Section VII.B.2. Such impacts include 
    acute and chronic toxicity, sublethal effects on metabolic and 
    reproductive functions, and loss of prey organisms. Chemical 
    contamination of aquatic biota may also directly and indirectly impact 
    local pescivorous wildlife and birds.
        b. Quantitative Estimates of Water-Related Benefits. EPA has 
    quantified human health and aquatic life benefits using a site-specific 
    analysis for baseline conditions and for the conditions that would 
    result from pollutant removals under the rule. The final BAT 
    limitations and PSES for Subparts B and E would result in a significant 
    reduction of dioxins and furans in fish tissues. As a result, the 
    largest quantifiable and monetizable water benefit is a reduction in 
    number of potential excess cancer cases from the consumption of 
    contaminated fish by recreational and subsistence anglers. The next 
    largest category of monetized benefits includes recreational fishing 
    benefits derived from lifting of all 19 existing dioxin/furan-related 
    fish consumption advisories in waters downstream from mills in the 
    Bleached Papergrade Kraft and Soda and Papergrade Sulfite 
    subcategories. Removing fish consumption advisories would be expected 
    to increase the number of recreational anglers at sites where 
    advisories are lifted and to increase fishing enjoyment by existing 
    anglers. Three of the 19 receiving streams with dioxin/furan-related 
    fish consumption advisories also have advisories in place for other 
    contaminants (from other sources) that will not be affected by this 
    rule. No monetized benefits are expected to accrue for these streams at 
    this time. Quantified, non-monetized benefits include reduction in 
    exceedances of aquatic life and health-based ambient water quality 
    concentrations.
        (1) Fish Consumption Cancer Risks and Non-cancer Hazards. Upper-
    bound individual cancer risk, aggregate risk, and non-cancer hazards 
    from consuming contaminated fish are estimated for recreational, 
    subsistence, and Native American subsistence anglers. At proposal, 
    concentrations of carcinogenic and systemic toxicants in fish were 
    estimated using two site-specific models--a simple dilution model and 
    EPA's draft Dioxin Reassessment Evaluation model (DRE)(DCN 14650). For 
    the final rule, EPA used only the DRE model to estimate TCDD and TCDF 
    levels in fish below 92 mills discharging into 73 receiving streams, as 
    well as individual cancer risks and non-cancer hazards. Of these mills, 
    two in the Bleached Papergrade Kraft and Soda subcategory discharge 
    through the same pipe and therefore were treated as a single 
    discharger. As a result, a total of 91 discharges from 92 mills were 
    evaluated for the water quality assessment. EPA continues to use the 
    simple dilution model to evaluate other chlorinated organics (i.e., 
    three carcinogens and four systemic toxicants). EPA believes the DRE 
    approach provides more reliable estimates of dioxin and furan fate and 
    transport in the environment for use in human health assessments. The 
    reasons for relying exclusively on the DRE for assessing impacts due to 
    dioxin and furan are explained in greater detail in
    
    [[Page 18588]]
    
    Chapters 4 and 8 of the Economic Analysis (DCN 14649).
        EPA is also updating fish consumption rates used to estimate cancer 
    and non-cancer hazards. At proposal, EPA used 25 g/day for recreational 
    anglers, and 145 g/day for subsistence anglers. The revised estimates 
    are 21 g/day for recreational anglers and 48 g/day for subsistence 
    anglers, based on data provided by the nationally based ``Continuing 
    Survey of Food Intake by Individuals'' (CSFII), conducted by the U.S. 
    Department of Agriculture. EPA is also using an updated fish 
    consumption rate for Native American subsistence populations of 70 g/
    day, based on two studies (CRIFTC, 1994; Wolfe and Walker, 1989, in 
    rulemaking record). This consumption rate represents an average fish 
    consumption rate for Native Americans. (See Environmental Justice 
    Analysis in Chapter 8 of the Economic Analysis, DCN 14649).
        Projected individual cancer risks differ among the evaluated mills 
    and among recreational, subsistence, and Native American subsistence 
    fishermen due to the differences in consumption rates. TCDD and TCDF 
    contribute most of the estimated cancer risks. The final BAT/PSES for 
    the papergrade sulfite and Bleached Papergrade Kraft and Soda 
    subcategories are projected to reduce average baseline individual 
    cancer risks up to about one order of magnitude for each affected 
    group--recreational, subsistence, and Native American subsistence 
    populations. At both baseline and post-compliance, Native American 
    subsistence populations are at about one order of magnitude higher risk 
    than recreational anglers and less than one order of magnitude higher 
    risk than subsistence fishermen in this assessment because of their 
    comparatively higher fish consumption rates.
        At proposal, EPA estimated exposed recreational and subsistence 
    fishermen based on a comparison of creel survey results to licensed 
    anglers in counties adjoining pulp mill streams. Based on these 
    surveys, EPA estimated that 29 percent of county fishermen would use 
    affected stream reaches and therefore could be exposed to contaminated 
    fish. Since proposal, EPA has considered additional recreational angler 
    survey information and has determined that a range of 10 percent to 33 
    percent of adjacent county-licensed anglers provides effective upper 
    and lower bounds to the fishing effort expected on most affected stream 
    segments. EPA's benefit estimation methodology is described in Chapter 
    4 of the Economic Analysis (DCN 14649).
        EPA estimated the reduced annual cancer cases for combined 
    recreational and subsistence angler populations as a result of the 
    final BAT/PSES for the Papergrade Sulfite and Bleached Papergrade Kraft 
    and Soda subcategories. The projected number of increased cancer cases 
    for this population under baseline conditions due to pulp and paper 
    discharges is 0.83 to 2.76 annual cancer cases. EPA estimates this 
    number would decline to 0.1 to 0.35 excess cancer cases per year after 
    implementation of the final BAT/PSES, thus eliminating approximately 
    0.73 to 2.41 annual cancer cases.
        For Native American subsistence fishermen, EPA evaluated an upper 
    bound total risk at baseline and post-compliance with the selected BAT/
    PSES. EPA assumed that the total population of the tribes with treaty-
    ceded fishing rights near pulp and paper mills consumed an average of 
    70 g/person/day of TCDD/TCDF contaminated fish. The projected number of 
    increased cancer cases for this population under baseline conditions 
    due to pulp and paper discharges is 0.14 annual cancer cases. EPA 
    estimates this number would decline to 0.008 excess cancer cases per 
    year after implementation of the final BAT/PSES.
        With respect to non-cancer benefits, EPA examined the current 
    discharge of four pollutants that have reference doses (RfDs) contained 
    in EPA's Integrated Risk Information System (IRIS). The four pollutants 
    are chloroform, pentachlorophenol, 2,3,4,6-tetrachlorophenol, and 
    2,4,5-trichlorophenol. The RfD represents an estimate, with uncertainty 
    spanning perhaps an order of magnitude, of daily exposure--expressed in 
    milligrams per kilogram of body weight per day (mg/kg/day)--that is 
    likely to be without an appreciable risk of deleterious effects to a 
    given population during a lifetime. (EPA notes that this analysis 
    considers only the contribution of Subpart B and E pulp and paper 
    current discharge effluent to the RfD; the contribution from other 
    sources (background level of exposure) is not evaluated.)
        For the four pollutants with RfDs in IRIS, EPA used the simple 
    dilution model to determine fish tissue concentrations. EPA then 
    estimated whether human consumption of fish by recreational, 
    subsistence, and Native American subsistence populations exposed to the 
    pollutants below pulp and paper mills would exceed a chemical-specific 
    noncancer hazard quotient of 1.0. Hazard quotients are based on the 
    relationship between fish tissue concentrations, fish consumption, and 
    RfDs. If a hazard quotient exceeds 1.0, adverse effects might occur. 
    None of the four pollutants with RfDs in IRIS is estimated to exceed a 
    non-cancer hazard quotient of 1.0 under baseline or BAT/PSES conditions 
    for recreational, subsistence, or Native American subsistence anglers.
        EPA did not use the reference dose (RfD) approach to evaluate 
    potential noncancer effects associated with dioxin/furan. The use of an 
    RfD for dioxin/furan presents special problems. If EPA were to 
    establish an RfD for dioxin/furan using the standard conventions of 
    uncertainty, the RfD value would likely be one to two orders of 
    magnitude below average background population exposure. As stated 
    above, the RfD is a level that is likely to be without an appreciable 
    risk; it is not an ``action level'' or exposure level where non-cancer 
    effects are predicted. Where the RfD is below background levels, and 
    where effects are not readily apparent at background levels, it is not 
    appropriate to use the RfD for quantifying benefits.
        As an alternative to using the RfD, EPA evaluated potential 
    noncancer effects of dioxin/furan by comparing the modeled incremental 
    exposure of dioxin/furan from fish consumption (based on results from 
    the DRE model) to estimated ambient background levels (i.e., 120 
    picograms of toxic equivalents/day (pgTEQ/day)). EPA estimates that 
    adverse impacts associated with dioxin/furan exposures may occur at or 
    within one order of magnitude of average background exposures. As 
    exposures increase within and above this range, the probability and 
    severity of human noncancer effects most likely increases. EPA's 
    analysis shows that the estimated dioxin/furan exposure from pulp and 
    paper effluent at baseline exceeded estimated ambient background 
    exposure by an order of magnitude for two mills, with the size of the 
    exposed population ranging from 4,910 to 16,205 recreational and 
    subsistence anglers. The selected BAT/PSES are projected to reduce the 
    incremental exposure from fish consumption to a level that was not 
    significantly different from estimated ambient background exposure. The 
    size of the recreational and subsistence angler population exposed to 
    dioxin/furan doses exceeding one order of magnitude greater than the 
    background level would be zero under the selected BAT/PSES.
        For Native American subsistence populations with treaty-ceded 
    fishing rights, the maximum dioxin/furan exposure under baseline 
    conditions is projected to be 803 pgTEQ/day. Under the selected BAT/
    PSES, the maximum exposure is reduced to 39 pgTEQ/day,
    
    [[Page 18589]]
    
    which is less than estimated background levels for the United States.
        (2) Impact of BAT/PSES Controls on Dioxin/Furan-Related Fish 
    Consumption Advisories. EPA estimates that all 19 dioxin/furan-related 
    fish consumption advisories in place downstream of papergrade sulfite 
    and bleached papergrade kraft and soda mills as of December 1995 would 
    be lifted some time after the rule is implemented. Recent evidence 
    indicates that dioxin/furan fish tissue concentrations decline within 
    several years of removing dioxin/furan discharges, which is more 
    rapidly than previously thought (see Chapter 9 of the Economic 
    Analysis, DCN 14649). EPA accounts for potential latent dioxin/furan 
    contributions from sediment to fish tissue by assuming a three-year lag 
    before cancers from fish tissue consumption are reduced or dioxin/
    furan-related fish tissue advisories are lifted.
        (3) Exceedances of Human Health-Based Ambient Water Quality 
    Concentrations (AWQCs). EPA also has compared the modeled in-stream 
    pollutant concentrations to human health water quality criteria or 
    other toxic effect values, which are referred to as health-based AWQCs. 
    Exceedances of health-based AWQCs indicate existing human health-based 
    water quality problems.
        EPA has analyzed the health-based AWQCs for the ingestion of 
    organisms and the ingestion of water and organisms based on the simple 
    dilution model. EPA estimates that no mills exceed the health-based 
    AWQCs for ingestion of organisms only under baseline conditions or 
    under the final rule. With respect to the ingestion of water and 
    organisms, at baseline, three mills exceed AWQCs for two pollutants, 
    chloroform and pentachlorophenol (a total of four exceedances). Under 
    the rule, only one mill exceeds AWQCs (for pentachlorophenol).
        EPA did not estimate exceedances of AWQCs for dioxin and furan 
    because the simple dilution model is not well-suited for use in 
    estimating human health effects associated with water column 
    concentrations of hydrophobic chemicals like dioxin and furan. EPA did 
    not use the DRE model for this analysis for dioxin/furan because 
    results of the DRE model would not be comparable with AWQCs.
        (4) Aquatic Life Benefits. EPA used the simple dilution approach to 
    estimate exceedances of aquatic life AWQCs. This is a conservative 
    approach that assumes all pollutants (including dioxin and furan) 
    discharged to receiving streams are available to the biota. Although 
    hydrophobic chemicals such as dioxins and furans will be associated 
    primarily with suspended particulates and sediments, some 
    concentrations will also be found in the water column near the 
    discharge point. This is particularly true if discharges are assumed to 
    be continuous because even though the pollutants might eventually 
    become associated with suspended solids and sediment, they would also 
    be present in the water column in the vicinity of the discharge on an 
    ongoing basis prior to partitioning. Therefore, although it is 
    conservative, EPA believes that the simple dilution approach provides a 
    reasonable estimate of impacts to aquatic life.
        EPA compared modeled in-stream concentrations of toxic discharges 
    to EPA's aquatic life AWQCs. EPA's modeling results show that receiving 
    water concentrations for up to four pollutants (of 15 pollutants with 
    chronic aquatic life AWQCs) at 19 mills exceed aquatic life criteria at 
    baseline discharge levels (up to 25 total exceedances). The final BAT/
    PSES for the papergrade sulfite and Bleached Papergrade Kraft and Soda 
    subcategories are projected to reduce these exceedances to one 
    pollutant (TCDD) at six mills (six total exceedances). On average, the 
    selected BAT/PSES will reduce color of effluent by approximately 2.5 
    percent compared to current discharges. This color reduction may have 
    some aquatic life or recreational benefits depending on the natural 
    color of the receiving water, but they are not quantifiable or 
    monetizable at this time.
        c. Monetization of Water Quality Benefits. Monetized benefits of 
    the final BAT/PSES for mills in the Bleached Papergrade Kraft and Soda 
    and Papergrade Sulfite subcategories are presented in Table VIII-6. EPA 
    has monetized the human health benefits resulting from elimination of 
    0.73 to 2.41 cancer cases per year for the nation as a whole (see 
    Section VIII.F.2.b.(1)). The projected benefits range from $2 million 
    to $22 million.
        EPA estimates the value to anglers of contaminant-free fisheries as 
    a result of lifting 16 of the 19 dioxin/furan-related fish consumption 
    advisories to be $2 million to $19 million. (Because these values are 
    based on a benefits transfer from a study of contamination of the Great 
    Lakes trout and salmon fishery, which may differ greatly from some of 
    the areas affected by this rule, these values provide only a general 
    sense of the magnitude of the benefits of the rule.) Because non-
    dioxin/furan fish consumption advisories (PCBs and mercury) will remain 
    in place on three streams, EPA did not monetize the benefits of 
    removing the dioxin/furan fish consumption advisories on these streams. 
    EPA also estimates that recreational fishing would increase on the 16 
    streams by 115,000 angling days to 379,000 angling days post-
    compliance. However, the monetary value of this increase is not 
    estimated because of the difficulty of determining the extent to which 
    this increased participation reflects a net increase in fishing 
    activity or merely a shift from other locations (see the Economic 
    Analysis, DCN 14649, Chapter 4).
        Because of dioxin/furan removals due to compliance with BAT 
    limitations and PSES, sludge from pulp and paper mills may be disposed 
    of through land application, instead of more costly landfilling or 
    incineration. (Pursuant to a January 1994 Memorandum of Agreement 
    between EPA and the American Forest and Paper Association (AF&PA), a 
    maximum dioxin/furan concentration of 50 ppt is allowed for land 
    application of sludge or a sludge-derived product. See DCN 14399). Mill 
    sludge disposal costs could be expected to decline by $8 million to $16 
    million. EPA estimated these values based on the reduced tonnage of 
    expected dioxin/furan-contaminated sludge, which in turn was based on 
    the proportional reduction of dioxin/furan in effluent (see the 
    Economic Analysis, DCN 14649, Chapter 8).
        Total monetized water-related benefits for all the above categories 
    range from $12 million to $57 million.
        As noted previously, the above estimates do not include the 
    benefits that have been identified but not monetized, such as health 
    effects for Native American subsistence fishermen, reduction in AWQC 
    exceedances, reduction of projected non-cancer effects and improvements 
    in fish and wildlife habitat.
    
    [[Page 18590]]
    
    
    
      Table VIII-6.--Monetized Water Quality Benefits of Final BAT/PSES for 
         Bleached Papergrade Kraft and Soda and Papergrade Sulfite Mills    
    ------------------------------------------------------------------------
                                                            Final BAT/PSES  
                      Benefit category                     (millions 1995$) 
    ------------------------------------------------------------------------
    Water-related Benefits                                                  
        Human health (recreational fish consumption)....              $2-$22
        Recreational angling                                                
            ``Contaminant-free'' fishery................              $2-$19
            Increased participation.....................                   +
        Reduced Sludge Disposal Costs...................              $8-$16
          Total Water-related Benefits..................            $12-$57 
    ------------------------------------------------------------------------
    + Positive benefits expected but not estimated.                         
    
    H. Comparison of Costs and Benefits
    
        This section provides the individual and combined costs, economic 
    impacts, and benefits of the proposed and final CAA and CWA pulp and 
    paper regulations described in earlier sections. See Table VIII-7. The 
    costs and benefits of the CAA (MACT) rules apply to all 155 kraft, 
    soda, sulfite and semi-chemical mills subject to final or proposed MACT 
    requirements, while the costs and benefits for the final CWA (BAT/PSES) 
    regulations apply to the 96 mills in the Papergrade Sulfite and 
    Bleached Papergrade Kraft and Soda subcategories.
        Using the pre-tax annualized cost estimates reported in Section 
    VIII.C, net monetized air-related benefits are estimated to range 
    between net costs of $1,165 million to net benefits of $929 million per 
    year for the final MACT I rule considered in combination with the pre-
    tax annualized cost estimates for the final BAT/PSES. Pre-tax 
    annualized cost estimates are used as a proxy for the social costs of 
    the rules. Net benefits of the proposed regulatory alternative for MACT 
    II are $270 million to $352 million. Thus, the range of net benefits 
    (disbenefits) of the final and proposed air quality standards is ($896) 
    million to $1,281 million.
        EPA did not estimate annual net benefits for the final BAT/PSES for 
    the Papergrade Sulfite and Bleached Papergrade Kraft and Soda 
    subcategories because so many categories of benefits are unmonetized 
    that the comparison would be misleading.
    
                                                 Table VIII-7.--Summary of Costs, Economic Impacts and Benefits                                             
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                                                      MACT I,      MACT I,  
                                                                                                                        MACT I and    MACT II,     MACT II, 
                                                                      MACT I      MACT II      Combined    Final BAT/   final BAT/   and final    and final 
                                                                                              air rules       PSES       PSES (96     BAT/PSES     BAT/PSES 
                                                                                                                          mills)     (96 mills)  (155 mills)
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Capital Costs................................................         $501         $258         $759       $1,039       $1,394       $1,524       $1,799
    Pre-Tax Annualized Costs *...................................         $125          $32         $157         $263         $351         $366         $420
    Monetized Annual Benefits....................................  ($1,040)-$1                                                                              
                                                                          ,054    $302-$384  ($739)-$1,4                                                    
                                                                                                      38      $12-$57  ($1,028)-$1                          
                                                                                                                              ,111           NE  ($727)-$1,4
                                                                                                                                                          95
    Net Annual Benefits (Benefits-Costs).........................  ($1,165)-$9                                                                              
                                                                            29    $270-$352  ($896)-$1,2                                                    
                                                                                                      81           NE           NE           NE           NE
    Projected Mill Closures......................................            0            0            1            1            2            3            3
    Potential Job Losses (due to mill closures)..................            0            0           ND           ND          900           ND           ND
    Projected Firm Failures......................................            0            0            0            0            0            0           0 
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    * Pre-tax costs are greater than the post-tax annualized costs shown in Tables VIII-1 and VIII-3.                                                       
    Net costs (where costs exceed benefits) are shown in parentheses.                                                                                       
    NE = not estimated.                                                                                                                                     
    ND = not disclosed to protect confidentiality.                                                                                                          
    Figures in table reflect rounding.                                                                                                                      
    
    I. Costs and Benefits of Rejected Options for the Bleached Papergrade 
    Kraft and Soda Subcategory--Option B and TCF
    
    1. Air Benefits
        As noted in Section VIII.F.1, the oxygen delignification technology 
    used as a component of Option B and TCF increases emissions of certain 
    pollutants and, hence compliance costs to meet MACT I standards; the 
    implementation of additional MACT controls, however, also increases 
    MACT-related removals. As a result, both MACT I costs and benefits 
    increase where oxygen delignification is utilized. (As noted above, 
    only VOC, PM, and SO2 benefits are monetized here.) However, 
    because the MACT I technologies control all of the increased emissions 
    associated with oxygen delignification, there is no increased net 
    benefit of the CWA and CAA technologies to ambient air quality. Rather, 
    the net monetized benefits of MACT I in combination with Option B or 
    TCF are equivalent to the monetized benefits of MACT I in combination 
    with the final BAT/PSES. Thus, MACT I benefits associated with reducing 
    VOCs under either Option B or TCF range from $29 million to $1,050 
    million. MACT II VOC reduction benefits range from $2 million to $84 
    million. Therefore, total monetized VOC benefits of the air quality 
    standards under either Option B or TCF are $31 million to $1,134 
    million. PM related disbenefits for MACT I are $1 million, while MACT 
    II PM benefits are $300 million for a total PM benefit of approximately 
    $299 million, for either Option B or TCF. SO2 related 
    disbenefits for MACT I are from $1,043 million down to $0, while MACT 
    II SO2 benefits are from $0.1 to $0.3 million.
        Total monetized benefits (disbenefits) for MACT I are ($1,015) 
    million to $1,049 million under BAT/PSES Option
    
    [[Page 18591]]
    
    B or TCF (see the Economic Analysis, DCN 14649, Chapter 8). Aggregate 
    annual benefits attributed to MACT II range in value from $302 million 
    to $384 million. Combining the benefits of the final and proposed air 
    quality standards yields a range of total annual air quality benefits 
    (damages) from ($713) million to $1,433 million.
    2. Water Benefits
        The water quality benefits described in this section include 
    benefits for rejected BAT/PSES options for the Bleached Papergrade 
    Kraft and Soda subcategory in combination with benefits for the 
    selected BAT/PSES for the Papergrade Sulfite subcategory. (Benefits for 
    the two CWA subcategories were also combined in Section VIII.G.2 for 
    the selected BAT/PSES.) EPA estimated the human health benefits that 
    could be expected if either of the rejected BAT/PSES options for the 
    Bleached Papergrade Kraft and Soda subcategory--Option B or TCF--were 
    implemented. For combined recreational and (non-Native American) 
    subsistence angler populations using the same fish consumption rates 
    EPA used for the selected BAT/PSES, Option B is projected to eliminate 
    approximately 0.75 to 2.50 annual cancer cases from the baseline of 
    0.83 to 2.76 annual cancer cases projected to result from the mills' 
    discharges at [mid-1995] levels, leaving a residual of 0.08 to 0.26 
    excess cancer cases per year. Here, as in Section VIII.G.2.b(1), excess 
    cancer cases refers to cancer cases attributable solely to pulp and 
    paper dioxin/furan discharges. This represents a reduction of 90 
    percent from baseline. The monetized value of this reduction is $2 to 
    $23 million. TCF is projected to result in a reduction from the mid-
    1995 discharge baseline of 0.83 to 2.76 cases to 0.0 cases, which 
    increases the benefits from TCF by $0.1 million to $2.7 million, 
    compared to Option B. Because chlorine or chlorinated compounds are not 
    used for bleaching, no dioxin formation was attributed to the mills 
    under this option. Although some background dioxin cancer risk would 
    remain that is attributable to sources other than current pulp and 
    paper discharges, no residual cancer risk would remain from bleached 
    papergrade kraft and soda mills.
        For Native American subsistence fishermen, EPA evaluated cancer 
    risks at baseline and under Option B. To estimate the maximum potential 
    risk, EPA assumed that the entire population of the tribes with treaty-
    ceded fishing rights near pulp and paper mills would consume an average 
    of 70g/person/day of TCDD/TCDF contaminated fish. With this level of 
    consumption, the projected increased number of cancer cases for this 
    population at baseline would be 0.14 cancer cases/year. EPA estimates 
    that this number would decline to 0.007 cancer cases/year if BAT/PSES 
    based on Option B were promulgated and to 0.0 cases/year if BAT/PSES 
    based on TCF were promulgated.
        Both Option B and TCF would result in the removal of 19 dioxin/
    furan-related fish consumption advisories on streams downstream from 
    bleached papergrade kraft and soda mills. EPA estimates that non-dioxin 
    advisories will remain on three of those streams. Therefore, here as in 
    Section VIII.G.2.c, EPA did not monetize the benefits of removing the 
    dioxin/furan fish consumption advisories on these streams. EPA 
    estimates the value to anglers of the 16 ``contaminant-free'' fisheries 
    as a result of removing these advisories to be $2 million to $19 
    million. EPA also estimates that recreational fishing would increase on 
    these 16 streams by an estimated 115,000 angling days to 379,000 
    angling days post-compliance. However, the monetary value of this 
    increase is not estimated because of the difficulty of determining the 
    extent to which this increased participation reflects a net increase in 
    fishing activity or merely a shift from other locations. These results 
    are the same as those presented for the selected BAT/PSES. Because of 
    dioxin removals, sludge disposal costs for both Option B and TCF could 
    be expected to decline by $8 million to $16 million (see the Economic 
    Analysis, DCN 14649, Chapter 8).
        With respect to non-cancer human health benefits, none of the four 
    pollutants with RfDs is estimated to exceed a non-cancer hazard 
    quotient of 1.0 under baseline or under conditions associated with 
    rejected Option B for recreational, subsistence, or Native American 
    subsistence anglers. The same is true for the selected BAT/PSES. 
    Similarly, Option B would reduce projected health-based AWQC 
    exceedances to one facility for one pollutant (pentachlorophenol). 
    Under TCF, EPA estimates that there would be no exceedances of health-
    based AWQCs. For dioxin, EPA estimates that Option B would reduce 
    incremental exposure from fish consumption to a level that is not 
    significantly different from ambient background exposure. Under TCF, 
    chlorine and chlorinated compounds are not used for bleaching, and 
    therefore no dioxin was attributed to mills under this option.
        With respect to aquatic life benefits, EPA's modeling results show 
    that, for the four pollutants exceeding chronic aquatic life criteria 
    at 19 mills (up to 25 total exceedances), rejected Option B would 
    reduce these exceedences to one pollutant (TCDD) at three mills (three 
    total exceedences). TCF would reduce these exceedances to zero.
        In addition to the benefits of reducing dioxin in fish, EPA 
    investigated other potential benefits associated with Option B and TCF, 
    including color, COD, AOX, and chronic sub-lethal toxicity.
        Increased color in a receiving water can decrease light penetration 
    there, thus resulting in shifts of phytoplankton community structure to 
    undesirable species, reduced primary productivity (which can alter the 
    trophic structure of fish communities), and elevated receiving stream 
    temperatures. However, the actual impact on the receiving water of 
    reducing color in mill effluent is highly site-specific and depends in 
    particular on the natural color of the receiving water and other 
    factors. Therefore, the monetized benefits will also be site-specific, 
    to the extent that they can be determined at all. EPA is not 
    promulgating national technology-based limitations or standards for 
    color, but rather has determined that the potential aesthetic or 
    aquatic impacts are best addressed on a site-specific basis by the 
    permitting or pretreatment authority where necessary. See Section 
    VI.B.3.e. Indeed, EPA notes that about eight mills currently have 
    limitations for color in their NPDES permits, and an additional two 
    mills have current color monitoring requirements where stream water 
    quality requires such measures.
        Lowering COD can protect the receiving water against oxygen 
    depletion and is likely to reduce non-chlorinated organic compounds 
    that cause chronic sub-lethal effects on aquatic life. Evidence 
    indicates that this toxicity is associated at least in part with 
    families of non-chlorinated organic materials. Several studies indicate 
    that, as wastewater COD is reduced, indices of these chronic toxicity 
    effects also are reduced. EPA is deferring regulation of COD to the 
    individual permitting process for the time being, although EPA intends 
    to promulgate effluent limitations guidelines and standards for COD for 
    Subpart B mills in the future. See Section VI.B.3.d.
        Although a statistically significant relationship between AOX and 
    adverse environmental effects has not been established, EPA believes 
    that reduction of AOX (a valid measure of the total chlorinated organic 
    matter) will result in water quality benefits. See Section VI.B.3.c. 
    However, these cannot be quantified at this time.
    
    [[Page 18592]]
    
        Compared to current discharges, the incremental benefits associated 
    with OD (Option B) include: reduction of color (by 40 percent); COD (by 
    40 percent); AOX (by 84 percent); and chronic sub-lethal aquatic 
    toxicity. TCF would also reduce color discharges (by 40 percent), COD 
    (by 40 percent), AOX (by 96 percent) and chronic sub-lethal aquatic 
    toxicity. The water quality benefits of the rejected options are shown 
    in Table VIII-8.
    
      Table VIII-8.--Monetized Water Quality Benefits of Rejected BAT/PSES  
       Options for Bleached Papergrade Kraft and Soda & Papergrade Sulfite  
                                      Mills                                 
    ------------------------------------------------------------------------
                                                      Option B       TCF    
                   Benefit category                  (millions    (millions 
                                                       1995$)       1995$)  
    ------------------------------------------------------------------------
    Water-related Benefits                                                  
        Human health (Recreational fish                                     
         consumption)                                    $2-$23       $2-$25
        Recreational angling                                                
            ``Contaminant-free'' fishery..........       $2-$19       $2-$19
            Increased participation...............            +            +
        Reduced Sludge Disposal Costs.............       $8-$16       $8-$16
          Total Monetized Water-related Benefits..      $12-$58      $12-$60
    ------------------------------------------------------------------------
    + Positive benefits expected but not estimated.                         
    
        Combined annual air and water benefits related to Option B for all 
    155 mills regulated by today's rule, including final MACT I, proposed 
    MACT II and BAT/PSES based on Option B, would total ($701) million to 
    $1,491 million. Combined annual air and water benefits related to TCF, 
    including final MACT I, proposed MACT II and BAT/PSES based on TCF 
    would total ($701) million to $1,493 million.
    
    J. Benefit-Cost Comparison Using Case Studies
    
        Many benefits are highly site-specific. At proposal, EPA estimated 
    the costs and benefits of the pulp and paper rule at three sites using 
    a case study approach. EPA has expanded the case study analysis to 
    incorporate additional sites. The case studies focus on water quality 
    benefits, resulting from installation of BAT/PSES technologies, with 
    air quality benefits modeled for case study mills as they are at the 
    national level (see Section VIII.G.1, above). The three case studies at 
    proposal were (1) the Penobscot River in Maine, (2) the Wisconsin River 
    in central Wisconsin, and (3) the lower Columbia River in Washington 
    and Oregon. In addition, a qualitative retrospective case study was 
    conducted of the Leaf River in Mississippi. These case studies were 
    selected to provide geographic representation of the impacts of the 
    proposed rule, taking data availability into consideration.
        For the final rule, the three quantitative case studies were 
    updated to reflect EPA's revised analysis of costs, loadings, and human 
    health risks to sport anglers. In consideration of environmental 
    justice, EPA also evaluated health risks to Native American anglers in 
    the Penobscot and Columbia River case study areas.
        The four new case studies of monetized benefits analyze: (4) the 
    Lower Tombigbee and Mobile River watersheds in Alabama, (5) the Pigeon 
    River in North Carolina, (6) the Samoa Peninsula in California, and (7) 
    the upper Columbia River in Washington State and British Columbia, 
    Canada. These new case studies provide EPA with the first real 
    empirical evidence of already-realized benefits that can be expected 
    from adoption of the final BAT/PSES limits. Although a portion of the 
    water-related benefits estimates in these newer case studies are based 
    on actual outcomes from installing pollution control equipment (i.e., a 
    retrospective analysis), estimates of the benefits of MACT standards in 
    these case studies are prospective, based on expected future benefits.
        The case studies compare costs and benefits at specific bleached 
    papergrade kraft and soda mills in these seven areas across the 
    country, some of which have not installed technologies comparable to 
    the bases for BAT/PSES and some of which have installed such 
    technologies, thereby allowing the retrospective assessment of BAT/PSES 
    costs and benefits. Where mills have installed BAT-like technologies, 
    capital investments may include: 70 percent to 100 percent 
    substitution; oxygen delignification plus 100 percent substitution; 
    and/or totally chlorine-free technologies.
        EPA evaluated control cost estimates and air benefits for emission 
    controls necessary to meet the MACT I and II standards on a prospective 
    basis, assuming the level of controls currently existing at mills in 
    the case study areas as a baseline.
        As with the national-level analysis, significant water-related 
    benefits are derived from removal of dioxin/furan from fish, and air-
    related benefits from improved agriculture and health from reduced 
    ozone emissions. However, the case studies also address a wider range 
    of water-related benefits, including some site-specific recreational 
    benefits such as surfing, boating, white water rafting, non-consumptive 
    uses and non-use benefits that result from improved color in the 
    receiving water, improved odor and removal of health advisories. The 
    case studies provide a more complete picture of the range of water-
    related benefits that may be expected from the rule, although a number 
    of identifiable benefits, including improvements in ecological 
    conditions and reductions of non-cancer health effects remain 
    unquantified and unmonetized.
        Benefits and costs for the case studies are summarized and compared 
    in Table VIII-9. The monetized benefits range from two percent to 387 
    percent of BAT/PSES compliance costs. The case study results indicate 
    that monetized benefits may be of the same order of magnitude as costs 
    at individual sites.
        From a water quality perspective, the case studies provide a cross-
    section of mills and receiving waters nationwide, including fast- and 
    slow-moving streams, lakes and ocean waters.
        Using receiving water and population characteristics, EPA 
    attributed benefits from the case study sites to all bleached 
    papergrade kraft and soda and papergrade sulfite mills. As a 
    sensitivity analysis, EPA used the water quality benefits from the case 
    studies to estimate the national level water quality benefits of the 
    integrated final and proposed rule for the Bleached Papergrade Kraft 
    and Soda and Papergrade Sulfite subcategories. Based on the case 
    studies, monetized benefits from the water rules (Option A) would be 
    expected to range from $91 million to $451 million per year, or from 35
    
    [[Page 18593]]
    
    percent to 170 percent of water-related costs.
        The case studies were not selected to be, and are not necessarily, 
    representative of national benefits with respect to air quality.
    
                         Table VIII-9.--Comparison of Potential Annual Benefits to Potential Annualized Costs for Seven Case Study Sites                    
                                                                   [Millions of 1995 dollars]                                                               
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                               Air-related benefits b                             Total     
                                    Site                                  Water-related  ---------------------------------- Total monetized     compliance  
                                                                             benefits          MACT I          MACT II          benefits         costs a    
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                      ORIGINAL CASE STUDIES                                                                 
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Penobscot River....................................................        $0.7-$2.3       ($9.5)-7.7             $0.1      ($8.7)-10.1              (c)
    Wisconsin River....................................................        $0.1-$1.5     ($16.9)-15.6             $2.1     ($14.7)-19.2             $9.3
    Lower Columbia River...............................................        $1.5-$8.6     ($26.9)-56.2             $0.7     ($24.7)-65.5            $16.6
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                        NEWER CASE STUDIES                                                                  
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Lower Tombigbee and Mobile Rivers..................................       $1.1-$12.0   ($136.8)-113.2            $81.7   ($54.0)-$206.9            $32.5
    Pigeon River.......................................................        $2.7-$8.7      ($5.8)-$5.7             $2.1     ($1.0)-$16.5           c $7.1
    Samoa Peninsula....................................................        $0.1-$1.4      ($5.0)-10.1             $0.0     ($4.9)-$11.5           d $5.0
    Upper Columbia River/Lake Roosevelt................................       $1.5-$11.6               NA               NA       $1.5-$11.6            $3.0 
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    a The total compliance costs shown in this Table (for BAT/PSES, MACT I and proposed MACT II Option #1) differ from compliance costs used to determine   
      economic achievability. The cost estimates for the case studies were based on custom analysis of technology in-place corresponding to the case study  
      timeframes. In contrast, estimates used to determine economic achievability used a standard mid-1995 baseline for technology in-place                 
    b Based on implementation of technologies consistent with Option A.                                                                                     
    c Confidentiality agreements preclude disclosure of total costs for this site.                                                                          
    d This mill has indicated EPA's cost estimate is too high because EPA did not fully account for technology in-place.                                    
    NA = Not applicable.                                                                                                                                    
    
    IX. Incentives for Further Environmental Improvements
    
    A. The Voluntary Advanced Technology Incentives Program
    
    1. Introduction
        EPA is promulgating BAT limitations today that will achieve 
    significant pollutant reductions using technologies within the economic 
    capability of the subcategory as a whole. At the same time, EPA wants 
    to encourage the widespread use and perfection of technologies such as 
    extended delignification and to promote the development of even more 
    advanced technologies, such as those aimed at reducing bleach plant 
    flow. EPA also wants to encourage the widespread use and perfection of 
    TCF processes. These technologies and processes have the ability to 
    surpass the environmental protection that would be provided by 
    compliance with the baseline BAT. Indeed, EPA's vision of long-term 
    environmental goals for the pulp and paper industry includes continuing 
    research and progress toward such environmental improvement. The Agency 
    believes that individual mills can be encouraged to make substantial 
    environmental progress beyond the base level compelled by law. This 
    industry's participation in the 33/50 program, its progress toward 
    reducing toxic discharges in advance of the proposed BAT revisions, its 
    joint initiative with the U.S. Department of Energy to reduce future 
    energy demands, and its development and implementation of the 
    Sustainable Forestry Initiative, among other voluntary environmental 
    undertakings, indicate that an incentives program may be widely 
    accepted and utilized by individual mills.
        For this reason, EPA is establishing a Voluntary Advanced 
    Technology Incentives Program to encourage mills in the Bleached 
    Papergrade Kraft and Soda subcategory to move beyond today's baseline 
    BAT technologies toward the ``mill of the future,'' which EPA believes 
    will have a minimum impact on the environment. EPA also intends the 
    program to serve as a pilot program for determining the effectiveness 
    of regulatory incentives as a means of stimulating development of 
    environmentally beneficial technologies. As a result of the Voluntary 
    Advanced Technology Incentives Program, EPA hopes to achieve within 
    sixteen years greater pollutant reductions than it could achieve solely 
    by establishing a technological floor. Indeed, the development of 
    increasingly more advanced bleach plant process technologies is a 
    critical step toward the Clean Water Act's ultimate goal of eliminating 
    the discharge of pollutants into the Nation's waters. See CWA Section 
    101(a)(1).
        The BAT program under the Clean Water Act is widely and justifiably 
    applauded as a critical tool in forcing the development and 
    installation of environmentally beneficial technologies. The statute 
    demands progress toward the goal of eliminating the discharge of all 
    pollutants, CWA Section 301(b)(2)(A), but emphasizes that that progress 
    must be ``reasonable.'' Id. This Voluntary Advanced Technology 
    Incentives Program marries the twin objectives embodied in Section 
    301(b)(2)(A): compelling the industry to go as far as it reasonably can 
    go, through the achievement of limits that are technically and 
    economically achievable, while holding out through the Voluntary 
    Advanced Technology Incentives Program an array of alternative effluent 
    limits that EPA believes will lead to zero discharge. The baseline BAT 
    limitations discharge EPA's statutory mandate: to promulgate 
    limitations based on the best available technology economically 
    achievable. The Voluntary Advanced Technology Incentives Program, in 
    turn, promotes EPA's statutory goal: to establish limitations that act 
    as a beacon to show what is possible.
        EPA is codifying three tiers of Voluntary Advanced Technology BAT 
    effluent limitations and two tiers of Voluntary Advanced Technology 
    NSPS, which together form the backbone of the Voluntary Advanced 
    Technology Incentives Program for mills in the Bleached Papergrade 
    Kraft and Soda subcategory. The three BAT tiers are
    
    [[Page 18594]]
    
    labeled Tier I, Tier II and Tier III; the two NSPS tiers are labeled 
    Tier II and Tier III. Tier III is the most stringent of the tiers. Each 
    BAT tier is made up of an array of increasingly more stringent 
    enforceable effluent limitations, culminating in the ultimate 
    performance requirements for that particular tier. The NSPS tiers 
    consist entirely of the ultimate performance requirements for each 
    tier. In addition to the Voluntary Advanced Technology effluent 
    limitations and NSPS codified today, EPA has also assembled a number of 
    incentives relating to permitting and enforcement matters and public 
    recognition. EPA hopes these incentives will encourage many mills to 
    develop and install advanced and even innovative technologies that will 
    lead the industry as a whole toward the elimination of pollutant 
    discharges.
        EPA believes it is appropriate as a matter of policy to offer mills 
    incentives to reach beyond the baseline BAT and NSPS process 
    technologies. Capital costs associated with the Tier I technology are 
    substantially greater than the capital costs of Option A, which is the 
    technology basis for the baseline BAT limits. Although over ten years a 
    mill employing Tier I technologies will likely save money in operating 
    costs, the capital outlay involved may discourage mills from doing more 
    than the regulatory minimum. For Tiers II and III, the costs and risks 
    are even more acute, when one considers the cost of research, 
    development, and full scale commercial trials of technologies in the 
    early stages of development and implementation, as well as the 
    associated uncertainties concerning possible product impacts. EPA is 
    interested in encouraging research, development and installation of 
    emerging technologies in order to motivate the development of these 
    technologies for broader commercial applications. As these technologies 
    become proven and their efficiencies publicized, EPA hopes that they 
    will become--in effect if not as a matter of law--the industry floor. 
    Thus, EPA believes it is in the public interest to encourage mills 
    today to develop environmentally beneficial technology and to reward 
    mills that are innovative and forward-looking in their use of new and 
    more environmentally effective technology despite its greater cost.
        EPA received suggestions for an incentives program from a number of 
    stakeholders. From these and other stakeholder suggestions, EPA has 
    developed a program, presented below, that is intended to provide 
    incentives for further long term environmental improvements. EPA is 
    incorporating several types of incentives in this program. In addition, 
    because mill-specific factors, including product specifications and 
    existing equipment, will affect the technical approach taken and the 
    environmental goal attainable by an individual mill, EPA is 
    establishing several tiers of Advanced Technology performance 
    objectives, each with limitations and standards specific to the model 
    technology EPA is positing. In order to promote ambitious use of 
    Advanced Technologies, EPA is offering greater incentives for greater 
    reductions in pollutant discharge.
        EPA recognizes that some mills in the Bleached Papergrade Kraft and 
    Soda subcategory have already installed or have committed to install 
    Advanced Technologies that are achieving or have the potential to 
    achieve effluent limitations equivalent to the ultimate performance 
    requirements of one or more of the Voluntary Advanced Technology 
    Incentive Tiers. If these mills accept enforceable NPDES permit 
    limitations at one of the Tier levels, they will qualify for the 
    incentives program at that level. In some instances, therefore, the 
    incentives will actually serve as rewards for effluent reductions 
    already achieved.
    2. Mechanics of the Incentives Program
        The Voluntary Advanced Technology Incentives Program for the 
    Bleached Papergrade Kraft and Soda subcategory will supplement the 
    otherwise compulsory baseline BAT and NSPS program. EPA emphasizes that 
    the Voluntary Advanced Technology Incentives Program is entirely 
    voluntary; no mill in Subpart B is required to participate. Rather, 
    mills subject to the baseline BAT limits and NSPS contained in Subpart 
    B may enroll in the incentives program and thus subject themselves to 
    more stringent technology-based limitations corresponding to the 
    Incentives Tier they select. For example, a mill that determines that 
    it can achieve Tier II limits may designate itself as a BAT Tier II 
    mill. A mill with more than one fiber line subject to Subpart B may 
    choose to enroll all or some of its fiber lines in the Voluntary 
    Advanced Technology Incentives Program. A mill wishing to experiment 
    with advanced or even innovative bleaching technologies also may choose 
    different Tiers for different fiber lines. After the mill enrolls in 
    the Voluntary Advanced Technology Incentives Program, the permit writer 
    must place the corresponding BAT limitations in the mill's permit. 
    Achievement of the Advanced Technology BAT limitations thereafter would 
    be compulsory for that mill. A mill that chooses not to participate in 
    the program will receive the baseline BAT limitations or NSPS; 
    similarly, a mill that chooses to enroll some but not all of its 
    Subpart B fiber lines in the Voluntary Advanced Technology Incentives 
    Program will receive baseline BAT limitations or NSPS for its non-
    participating fiber lines.
        EPA expects that an interested mill would formally enroll in the 
    Voluntary Advanced Technology Incentives Program prior to issuance of 
    its next NPDES discharge permit. Enrollment can be made by indicating 
    the mill's intent on its permit application or through separate 
    correspondence to the permitting authority as long as the signatory 
    requirements of 40 CFR 122.22 are met. However, as discussed in more 
    detail in Section IX.A.7 below, EPA assumes that most mills, for 
    practical purposes, will decide whether to participate in the Voluntary 
    Advanced Technology Incentives Program in the next year in order to 
    assure that they will have the maximum amount of time to achieve the 
    various Tier limitations and to receive the additional compliance time 
    for MACT, established under these rules for mills enrolled in the 
    Voluntary Advanced Technology Incentives Program. Any mill can 
    voluntarily enter at any tier appropriate to its individual 
    circumstances. Further, mills that enter either at Tier I or Tier II 
    may decide, after making such a commitment in permits but before 
    termination of the appropriate compliance period (i.e., not later than 
    six years after publication of these rules--Tier I, or not later than 
    11 years after publication of these rules--Tier II), to commit to the 
    requirements of a more stringent tier (i.e., Tier II or Tier III). Such 
    mills will be subject to the deadlines specified in the regulation for 
    the newly chosen tier.
        Existing dischargers volunteering to participate in the incentives 
    program would receive BAT limitations that become progressively more 
    stringent over time. Although applied in stages, the limitations 
    represent a continuum of progress that a participating mill commits, 
    and is required, to achieve. At the first stage in the continuum are 
    limitations for the enrolled fiber line that reflect either a mill's 
    existing effluent quality or its current technology-based permit limits 
    for the BAT parameters, whichever are more stringent. See 40 CFR 
    430.24(b)(1). For the bleach plant parameters, such as dioxin, existing 
    effluent quality would be determined at the bleach plant, while 
    existing effluent quality for AOX would be determined at the end of the 
    pipe based on loadings attributable to that
    
    [[Page 18595]]
    
    fiber line. Id. The next stage in the continuum consists of enforceable 
    interim milestones. Under one set of milestones, existing dischargers 
    enrolled in Tiers II or III are required to meet interim BAT 
    limitations equivalent to the baseline BAT limitations by April 15, 
    2004. 40 CFR 430.24(b)(3). (By that date, dischargers enrolled are 
    required to meet the baseline BAT limitations for all pollutants, 
    except for Tier I; the AOX limitation for mills enrolled in Tier I is 
    the ultimate performance requirement for Tier I. Id.) Under the second 
    set of milestones, existing dischargers enrolled in any tier are 
    required to meet enforceable requirements determined by the permitting 
    authority based on best professional judgment; these milestones would 
    be expressed as narrative or numeric conditions in the mill's NPDES 
    permit. 40 CFR 430.24(b)(2). EPA intends the milestones to reflect each 
    step in a mill's progress toward achievement of the Tier's ultimate 
    performance requirements. Elsewhere in today's Federal Register, EPA is 
    proposing to require each participating mill to submit to its 
    permitting authority a plan detailing the steps it plans to take (with 
    corresponding dates) in order to meet its applicable BAT Tier 
    limitations. Under the proposed regulation, permit writers would be 
    authorized to use the information in the milestone plan as a basis for 
    setting milestone limitations. The final stage in the BAT continuum 
    represents the ultimate Advanced Technology performance levels for the 
    Tier selected. 40 CFR 430.24(b)(4)(i). As noted above, the Voluntary 
    Advanced Technology Incentives Program is also available for new 
    sources that elect to exceed baseline NSPS requirements. See 40 CFR 
    430.25(c). For new sources (as defined at 430.01(j)), the incentives 
    program begins at Tier II. The ultimate Tier II and Tier III 
    performance requirements constitute NSPS for such mills, with the 
    addition of standards for conventional pollutants at the baseline NSPS 
    level. See 40 CFR 430.25(c)(1) and (2). The NSPS Tier II and Tier III 
    performance requirements are the same as the ultimate BAT Tier II and 
    Tier III performance requirements for BAT. As required by CWA Section 
    306, new sources must comply with the applicable NSPS upon commencing 
    operation; therefore, the incremental approach of achieving 
    progressively more stringent performance levels discussed above for 
    existing sources would not apply to new sources enrolled in the 
    incentives program.
        In addition to Voluntary Advanced Technology BAT limitations and 
    NSPS, the NPDES permit of a mill enrolled in the Voluntary Advanced 
    Technology Incentives Program will need to contain all other permit 
    limitations and conditions otherwise applicable to the mill, including 
    any conventional pollutant limitations and standards, any water 
    quality-based effluent limitations required under CWA Section 
    301(b)(1)(C), and best management practices provisions, including those 
    promulgated today. Schedules for complying with those requirements, if 
    any, are determined by the applicable law; nothing in this incentives 
    program alters in any way those compliance deadlines.
        Because mills enrolling in the Voluntary Advanced Technology 
    Incentives Program are subject to more stringent BAT limitations and 
    NSPS than EPA could otherwise compel through national effluent 
    limitations guidelines, EPA has assembled a package of rewards and 
    incentives for participating mills. The public recognition incentive is 
    available as soon as a mill accepts Voluntary Advanced Technology BAT 
    limitations in its NPDES permit. The reduced monitoring incentive 
    applicable to dioxin, furan, chloroform and the 12 chlorinated phenolic 
    pollutants is available as soon as participating mills achieve those 
    limitations. See 40 CFR 430.02(c). The reduced monitoring incentive 
    applicable to AOX is available only after the ultimate Advanced 
    Technology performance level for that pollutant is achieved. See 40 CFR 
    430.02(d) and (e). The remaining incentives, including greater permit 
    certainty, reduced inspections, and reduced penalties, are available 
    only after the mill achieves all of the ultimate Advanced Technology 
    performance levels.
        EPA has decided not to make the Voluntary Advanced Technology 
    Incentives Program available to indirect discharges at this time 
    because it would be much more difficult to administer than the baseline 
    PSES program and therefore would impose substantial burden on local 
    governments. Further, EPA does not believe that commitments by indirect 
    dischargers to reduce AOX or flow levels warrants any delay in 
    compliance with limitations on dioxin and furan due to POTW pass-
    through and biosolids contamination concerns. Similarly, EPA has not 
    identified feasible technologies beyond BAT that can significantly 
    reduce pollutant discharges from mills in the Papergrade Sulfite 
    subcategory at this time, and so is not able to develop an incentives 
    program for this subcategory. Moreover, stakeholders have offered no 
    specific suggestions or supporting information and data upon which EPA 
    reasonably could develop a program for the Papergrade Sulfite 
    subcategory. However, EPA will consider developing incentive programs 
    for other subcategories as BAT limitations are promulgated for those 
    subcategories.
    3. The Technology Bases for the Voluntary Advanced Technology BAT 
    Limitations and NSPS
        In order to determine the appropriate Voluntary Advanced Technology 
    BAT limitations and NSPS, EPA first selected a model technology for 
    each Tier. For Tier I, which applies only to BAT, EPA determined that 
    the most appropriate technology was extended delignification with 
    complete substitution of chlorine dioxide for elemental chlorine, 
    closing up wastewater discharges from the fiber line prior to 
    bleaching, and efficient biological wastewater treatment. EPA selected 
    this technology basis because it is available today (see discussion of 
    BAT Option B and NSPS technology in Section VI.B.5.(a) and (b)), 
    because it is economically achievable for mills voluntarily choosing to 
    implement it (see Section IX.A.6), and because it represents an 
    important step in the direction of a minimum impact mill.
        The model technology for Tier II Voluntary Advanced Technology BAT 
    limitations and NSPS consists of extended delignification with complete 
    substitution of chlorine dioxide for elemental chlorine, supplemented 
    with increased use of water conservation practices, water reuse 
    practices, bleach plant filtrate recycling practices, and efficient 
    biological wastewater treatment. EPA anticipates that Tier II mills 
    will maximize the capability of extended delignification technology, 
    thereby reducing the amount of chlorine dioxide used in bleaching. The 
    model Tier II mill also will have highly effective pulping liquor spill 
    prevention and control and will have evaporators that minimize the 
    amount of black liquor carryover, to allow for extensive condensate 
    reuse. EPA expects that Tier II mills also will employ a closed fiber 
    line prior to bleaching improved water reuse within the bleach plant, 
    and will recycle a portion of bleach plant filtrate back through the 
    fiber line to the recovery cycle. The Tier II Advanced Technology BAT 
    limitations and NSPS represent the performance demonstrated by mills 
    that minimize effluent flow and reduce the formation of chlorinated 
    organic compounds using these technologies and practices. Three mills 
    in the United States are approaching the reduced wastewater flow levels 
    equivalent to Tier II, which leads EPA
    
    [[Page 18596]]
    
    to conclude that flow reduction technologies are emerging. Although the 
    flow volume projected or reported by these mills excludes pulping area 
    or evaporator condensates, which EPA includes within its Tier II flow 
    limitation, EPA expects that over the next ten or eleven years 
    condensate reuse strategies and discharge flow reduction technologies 
    will mature to allow mills to achieve the pulping area condensate, 
    evaporator condensate and bleach plant wastewater flow level being 
    codified today as part of Tier II. For further discussion of EPA's 
    rationale for selecting this technology as the basis for Voluntary 
    Advanced Technology BAT limitations and NSPS at the Tier II level, see 
    Section IX.A.6.
        The model technology for the Tier III Voluntary Advanced Technology 
    BAT limitations and NSPS represents what EPA believes can be achieved 
    in 15 or 16 years by mills on the cutting edge of minimum effluent 
    technology. In EPA's view, such mills will fully reuse pulping area and 
    evaporator system condensates, have a closed fiber line prior to 
    bleaching, and recycle the majority of bleach plant filtrates back to 
    the recovery cycle. EPA expects that these mills will also operate 
    efficient biological treatment systems. To achieve this degree of mill 
    closure, in addition to the level of technology described under Tier 
    II, EPA expects the model Tier III mill will have ``kidney'' technology 
    to remove metals from bleach filtrate and chloride from the mill liquor 
    cycle, and may perform extensive steam stripping or other treatment of 
    condensates to allow for full reuse. Mills that choose to use ozone 
    delignification may avoid the need for a chloride removal system. EPA 
    also expects that the Tier III mills will have advanced process control 
    systems and negligible losses of black liquor through leaks and spills. 
    Finally, the model Tier III mill will likely have extended liquid 
    storage capacity as part of its water recycle and liquor management 
    systems to help maintain the good hydraulic balance required for low 
    discharge flow operation. While no U.S. mill today is achieving these 
    limitations, EPA believes that the continuing progress being made by 
    mills toward closed-loop processing will lead to greater innovation 
    regarding technologies and practices necessary to achieve the Tier III 
    limitations. For further discussion of EPA's rationale for selecting 
    this technology as the basis for Voluntary Advanced Technology BAT 
    limitations and NSPS at the Tier III level, see Section IX.A.6. For a 
    more detailed discussion of the technology bases for the Voluntary 
    Advanced Technology BAT Limitations and NSPS, see Voluntary Advanced 
    Technology Incentives Program Technical Support Document (DCN 14488).
    4. Pollutants Regulated by Voluntary Advanced Technology BAT and NSPS 
    Limitations
        Except for TCF-based processes, each Advanced Technology tier 
    consists of limitations for dioxin, furan, chloroform, and 12 
    chlorinated phenolic pollutants monitored at the bleach plant. EPA is 
    not codifying limits for these pollutants for TCF processes. As 
    discussed in more detail below, each Tier also includes AOX limitations 
    monitored at the end of the pipe and, depending on the Tier, 
    limitations on lignin content or wastewater flow. In addition, each BAT 
    Tier includes limitations on pentachlorophenol and trichlorophenol 
    (when used as biocides), see 40 CFR 430.24(d), and each NSPS Tier 
    includes limitations on BOD5, TSS and pH, as well as 
    biocides. See 40 CFR 430.25(c) and (d).
        EPA has chosen to use AOX as a performance standard for each of the 
    three Voluntary Advanced Technology BAT tiers because AOX is a measure 
    of progress in reducing the total chlorinated organic matter in 
    wastewaters resulting from the bleaching of pulps. In addition, the use 
    of AOX rather than other measures of organic matter (e.g., 
    BOD5) will further encourage a pollution prevention approach 
    instead of end-of-pipe treatment technologies. The final rule 
    establishes minimum monitoring frequencies for AOX for each of the 
    Tiers, except for TCF fiber lines. See 40 CFR 430.02(d) and (e). For 
    TCF fiber lines, permit writers should determine the appropriate 
    monitoring frequency to assure continued compliance with the AOX 
    limitation.
        In addition to the AOX criterion, EPA is establishing BAT 
    limitations requirements for Tier I that include kappa numbers measured 
    prior to bleaching and a narrative limitation calling for recycling of 
    all filtrates generated prior to the point at which that kappa number 
    is measured. See 40 CFR 430.24(b)(4)(i). The kappa number is a measure 
    of lignin content in unbleached pulp, and is routinely determined by 
    mills. EPA is not establishing minimum monitoring requirements for 
    kappa numbers in this regulation. Permit writers maintain the authority 
    to establish monitoring frequencies on a best professional judgment 
    basis.
        By meeting the kappa number limitations, Tier I mills will achieve 
    substantial reductions in precursors for chlorinated organic pollutants 
    found in lignin beyond reductions achieved by mills with conventional 
    pulping processes. See DCN 14488. Some industry commenters suggested 
    that EPA simply specify qualifying Advanced Technologies and require 
    participating mills to employ one or more of those technologies in 
    order to receive incentives. EPA rejected this approach because it 
    would inhibit development of equivalent technologies that EPA cannot 
    foresee today and is inconsistent with the traditional performance-
    based structure of technology-based effluent limitations under the 
    Clean Water Act. Nevertheless, EPA agrees with these commenters that 
    Tier I mills will in all likelihood employ extended delignification 
    technologies or other technologies that similarly reduce the kappa 
    number prior to bleaching; EPA, therefore, is requiring Tier I mills to 
    achieve specified kappa numbers that reflect the performance 
    capabilities of well-operated, extended delignification systems. In 
    addition, EPA's Tier I limits reflect EPA's expectation that Tier I 
    mills will be bleaching pulps with less lignin and, hence, will realize 
    significant reductions in the amount of unrecoverable bleaching 
    chemicals required to achieve their target brightness. By using less 
    bleaching chemical, Tier I mills will further reduce the formation and 
    discharge of chlorinated organic pollutants generated by bleaching 
    pulps with chlorine-containing compounds, including chlorine dioxide. 
    By recycling the pulping area filtrates, Tier I mills also will be 
    implementing an important building block for long-term flow reduction 
    goals, and eliminating an important source of weak black liquor 
    discharge that would otherwise go to the mill's wastewater treatment 
    plant. See DCN 14488.
        By defining Tier I with parameter values (AOX, kappa numbers) and 
    recycle requirements as presented above, EPA intends to provide maximum 
    encouragement to as many mills as possible to achieve the performance 
    of at least the initial threshold of the Advanced Technology program. 
    Adopting threshold performance criteria that are too stringent could 
    discourage mills from making additional capital investments beyond 
    those necessary to achieve the baseline BAT. This could undermine one 
    goal of the incentives program, which is to achieve the greatest 
    environmental results possible consistent with mills' capital
    
    [[Page 18597]]
    
    investment cycles. Conversely, setting threshold criteria at levels 
    that could be met by some mills that comply only with the baseline BAT 
    limitations and that do not employ Advanced Technologies could serve as 
    a disincentive to invest in Advanced Technologies that achieve dramatic 
    reductions in pollutant loadings and flow. The kappa numbers defined 
    above for Tier I, while at the upper end of the range of values 
    achieved by extended delignification technologies, nonetheless appear 
    to separate mills that employ them from mills that would use 
    conventional pulping technologies to achieve the BAT limitations. See 
    DCN 14488.
        EPA is setting the Voluntary Advanced Technology BAT limitations 
    and NSPS for Tier II and Tier III based on a different philosophy than 
    for Tier I. EPA believes that Tiers II and III should reflect a 
    movement toward the long-term goal of minimizing impacts of mills in 
    all environmental media through partially or fully closed loop 
    processes. For Tier II, EPA is setting an AOX limit based on a long-
    term average (0.10 kg/kkg) that is currently being achieved by some of 
    the best mills in the industry. See DCN 14488. See 40 CFR 
    430.24(b)(4)(i) and 430.25(c)(2). For Tier III, EPA is setting an AOX 
    limit based on a long-term average (0.05 kg/kkg) that is being achieved 
    by only a very few mills, including one ECF mill. SeDCN 14488. Id. This 
    ECF mill achieved the AOX limit only with hardwood furnish; moreover, 
    it did so without the level of flow reduction anticipated for Tier III. 
    See DCN 14488. It is the Agency's judgment, based on trends in ECF 
    technology development to date, that with recycle of pulping and 
    evaporator condensates and bleach plant filtrates necessary to achieve 
    a wastewater flow of 5 m3/kkg, and removal of chlorides from 
    the liquor cycle, commensurate reductions in the mass of chlorinated 
    organic pollutants contained in wastewaters discharged also are likely 
    to occur. For this reason, it is EPA's judgment that the Tier III AOX 
    limit will be achievable by advanced ECF mills for both hardwood and 
    softwood furnishes as well as advanced TCF mills.
        The Tier II and Tier III BAT limitations and NSPS also include 
    restrictions on wastewater flow and a requirement that all pulping-area 
    filtrates be recycled to chemical recovery prior to bleaching. See 40 
    CFR 430.24(b)(4)(i) and 430.25(c)(2). As discussed above for Tier I, 
    the filtrates recycle requirement is an important step toward long-term 
    flow reduction. Flow reduction and progress toward closed loop mill 
    operations, in turn, are very important long-term environmental goals 
    because pollutant releases to all environmental media would be 
    minimized.
        While mills currently measure end-of-pipe flow at the point of 
    permitted discharges, Tier II and Tier III mills will be required to 
    establish and maintain flow measurement equipment to verify compliance 
    with the annual average reduced flow limits for those tiers for bleach 
    plant and pulping area and evaporator condensates. EPA is not 
    establishing minimum monitoring frequencies for flow in this 
    regulation. Permit writers maintain the authority to establish 
    monitoring frequencies on a best professional judgment basis. See 40 
    CFR 430.02.
        Review of currently available data and literature indicates that 
    the numerical values for flow set forth to define Tiers II (10 
    m3/kkg) and III (5 m3/kkg) are appropriately 
    stringent reduced flow targets by comparison to current wastewater flow 
    for mills with extended delignification technologies. See DCN 14488. 
    EPA believes it is appropriate to include condensates as part of the 
    specified wastewater flow volume because technologies are available 
    today that allow for their recycle and reuse; use of these technologies 
    therefore ensures that the cumulative volume of wastewater flow is 
    reduced to the greatest extent possible. See DCN 14488. One technology 
    in particular is the ``clean condensate alternative,'' which is a 
    viable MACT compliance alternative. See 40 CFR 63.447. This alternative 
    facilitates the segregation, treatment, and reuse of condensates and 
    thus will assist mills in achieving the wastewater flow objectives. 
    Inclusion of pulping and evaporator condensates in these reduced flow 
    targets therefore is consistent with the ``clean condensate'' MACT 
    compliance alternative and will promote flow reduction through recycle 
    and reuse of the greatest possible volume of process wastewater.
        EPA has the legal authority to establish Advanced Technology 
    effluent limitations for non-chemical parameters, such as lignin 
    content measurements and flow, and to do so where appropriate in 
    narrative form. For Tier I, these limitations take the form of kappa 
    numbers to measure lignin content in unbleached pulp and a narrative 
    requirement to recycle pulping area filtrates; for Tiers II and III, 
    they take the form of numerical limitations on process wastewater 
    flows, as well as the narrative requirement to recycle pulping area 
    filtrates. EPA has the authority to establish limits for lignin content 
    in unbleached pulp, for recycle of filtrates, and for reduced process 
    wastewater flows because each of these parameters functions as a 
    restriction on the quantities, rates or concentrations of chlorinated 
    organic pollutants and other pollutants in a mill's wastestream. See 
    CWA Section 502(11). Restrictions on lignin content of unbleached pulp, 
    measured as a kappa number, can be used to reduce the presence of 
    precursors for chlorinated organic pollutants in a mill's wastewater. 
    In addition, lignin itself is a material that includes polynuclear 
    aromatic hydrocarbons; a number of polynuclear aromatic hydrocarbons 
    are included in EPA's list of priority pollutants. See Appendix A to 
    Part 403 (reprinted after 40 CFR 423.17). Recycling pulping area 
    filtrates to the chemical recovery cycle prevents the discharge of weak 
    black liquor, which includes inorganic pulping chemicals and dissolved 
    wood substances. The dissolved wood substances include polynuclear 
    aromatic materials, degraded carbohydrates, low-molecular weight 
    organic acids, and wood extractives (resins and fatty acids). The 
    toxicity of the materials contained in black liquor is well documented; 
    see the BMP Technical Support Document (DCN 14489). Limits for process 
    wastewater flow, in this case pertaining to total pulping area and 
    evaporator condensate and bleach plant wastewater, move mills toward 
    closed loop operations. Reductions in flow will have the effect of 
    dramatically reducing mass loadings--and discharges--of non-chlorinated 
    organics such as lignin and a variety of chlorinated organics in 
    addition to dioxin, furan and the chlorinated phenolic pollutants 
    specifically regulated today. Because those pollutants are far too 
    numerous to measure individually (and some have not been specifically 
    isolated and identified), EPA determined that it was impracticable to 
    set mass-based limits for all of those pollutants. See DCN 14488. EPA 
    judged that establishing flow levels for Tiers II and III would be the 
    best way to control the discharge of these pollutants.
        For the foregoing reasons, all of these Advanced Technology 
    performance objectives qualify as effluent limitations under CWA 
    section 502(11). As noted above, the filtrates recycle limitation is a 
    narrative limitation. Nothing in the definition of effluent limitation 
    in CWA section 502(11) or elsewhere in the CWA compels that 
    restrictions on the discharge of pollutants be expressed in numeric 
    form. See NRDC v. Costle, 568 F.2d 1369, 1380 (D.C. Cir. 1977). In this 
    instance, EPA determined that the
    
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    restriction on filtrates (and hence the prevention of discharge of 
    toxic materials) could not be expressed as a numeric limitation and 
    therefore expressed that restriction in narrative form instead.
        For further discussion of the effluent reductions and environmental 
    benefits associated with the Advanced Technology BAT limitations and 
    standards promulgated for these parameters, see DCN 14488.
    5. Voluntary Advanced Technology BAT Limitations and NSPS
        The Voluntary Advanced Technology BAT limitations consist of three 
    separate components, which together comprise BAT for the particular 
    Tier. See 40 CFR 430.24(b). The first and third components consist of 
    numeric effluent limitations for the pollutants regulated by the 
    Voluntary Advanced Technology Incentives Program. The second component 
    consists of enforceable interim milestones. Under one set of 
    milestones, existing dischargers enrolled in Tiers II or III are 
    required to meet interim BAT limitations equivalent to the baseline BAT 
    limitations by April 15, 2004. Under the second set of milestones, 
    existing dischargers enrolled in any tier are required to meet 
    enforceable requirements that are developed on a best professional 
    judgment basis by the permitting authority; these milestones are 
    expressed in either narrative or numeric form. Taken together, these 
    three components constitute reasonable further progress toward the 
    national goal of eliminating the discharge of all pollutants and for 
    this reason represent BAT.
        The Voluntary Advanced Technology NSPS consist of only one stage--
    the ultimate performance objectives for the Tier in question, with the 
    addition of conventional limitations at the baseline NSPS level. See 40 
    CFR 430.25(c). This is because new sources, unlike existing sources 
    subject to BAT, must design and construct their facilities to achieve 
    NSPS upon commencing operation; sequencing limitations to achieve 
    continuing progress would be inconsistent with this statutory mandate.
        a. ``Stage 1'' BAT Limitations. In the regulation, EPA has codified 
    the first set of numeric BAT effluent limitations as ``stage 1'' 
    limitations to be applied in the absence of more stringent WQBELs. See 
    40 CFR 430.24(b)(1). Although expressed in this regulation in narrative 
    form, EPA intends that the permitting authority will express that 
    limitation in numeric form for each participating mill on a case-by-
    case basis. The ``stage 1'' limitations thus will be numeric values on 
    dioxin, furan, chloroform, AOX, and 12 chlorinated phenolic pollutants 
    that, for each pollutant, are equivalent to the more stringent of 
    either the technology-based limit on that pollutant in the mill's last 
    permit or the mill's current effluent quality with respect to that 
    pollutant. Id. Existing effluent quality for AOX would be determined at 
    the end of the pipe based on loadings attributable to that fiber line; 
    for all other pollutants covered by the Advanced Technology BAT 
    limitations, such as dioxin, existing effluent quality would be 
    determined at the point where the wastewater containing those 
    pollutants leaves the bleach plant. Id. These ``stage 1'' BAT limits 
    represent the first step in the Advanced Technology BAT continuum and 
    are enforceable against the participating mill as soon as they are 
    placed in the mill's NPDES permit.
        The purpose of the ``stage 1'' BAT limits is to ensure that, at a 
    minimum, existing effluent quality is maintained while the mill moves 
    toward achieving the ultimate Voluntary Advanced Technology BAT 
    performance requirements for the Tier selected by the mill. As Advanced 
    Technology permits are reissued for Tier II or Tier III mills, in 
    particular, new ``stage 1'' limitations must be established to reflect 
    the improving effluent quality of that mill. Id. Allowing a mill to 
    degrade its effluent quality during development and installation of 
    Advanced Technologies would be inconsistent with the statute's 
    direction that BAT limitations achieve reasonable further progress 
    toward the Clean Water Act's national goals. EPA's ``stage 1'' 
    limitations, thus, are intended to capture continuously improving 
    effluent quality.
        EPA had considered, but rejected, attempting to codify the ``stage 
    1'' limits in numeric form. First, EPA has no way on this record to 
    quantify and hence codify the existing effluent quality of each mill 
    that is potentially eligible to participate in this program. Nor would 
    such an attempt be wise, because EPA expects that mills considering 
    participating in the Voluntary Advanced Technology Incentives Program 
    will continue to improve their effluent quality up to and beyond the 
    promulgation date of this regulation and, most likely, up to and beyond 
    the dates that their existing effluent quality is translated into 
    enforceable permit limits. Therefore, even if EPA could codify such 
    ``stage 1'' limitations today, doing so would likely establish a less 
    stringent technological floor than the permitting authority would be 
    able to establish each time an Advanced Technology permit is issued 
    prior to achievement of the ultimate Advanced Technology performance 
    requirements.
        Because the ``stage 1'' limitations reflect a level of technology 
    that the mill is already employing or that was previously determined to 
    be BAT for that mill, EPA has determined that the technology bases for 
    the ``stage 1'' limits are both technically available and economically 
    achievable. EPA has also determined that they would not impose any 
    adverse non-water quality environmental impacts. EPA has determined 
    that these ``stage 1'' limitations are the ``best'' available 
    technology economically achievable for mills participating in the 
    Voluntary Advanced Technology Incentives Program because they allow 
    those mills to focus their resources on the research, development, 
    testing, and installation of the technologies ultimately needed to 
    achieve the Advanced Technology performance levels. Thus, ``stage 1'' 
    limitations reflect ``reasonable further progress toward the national 
    goal of eliminating the discharge of all pollutants,'' as called for by 
    CWA section 301(b)(2)(A). EPA also considered all of the other 
    statutory factors specified in CWA section 304(b)(2)(B) and concluded 
    that nothing in EPA's analysis of those factors justifies selecting a 
    different set of ``stage 1'' BAT limitations. For these reasons, EPA 
    determined that the ``stage 1'' BAT limitations promulgated today 
    represent the appropriate first rung of the Advanced Technology BAT 
    ladder that participating mills will have committed to ascend.
        EPA did not set ``stage 1'' limits at the baseline BAT level 
    because baseline BAT limits are not a logical first step to meeting the 
    ultimate Advanced Technology BAT limitations for the reasons set forth 
    below. See DCN 14488. First, as a technical matter, mills subject to 
    such interim limits most likely would need to install more chlorine 
    dioxide generator capacity than they ultimately would use to achieve 
    the Advanced Technology performance requirements. (EPA believes most 
    Advanced Technology mills ultimately will employ complete substitution 
    of chlorine dioxide for elemental chlorine, preceded by extended 
    delignification processes--a sequence that calls for approximately 30 
    to 75 percent less chlorine dioxide than a mill would use to achieve 
    the baseline BAT requirements depending on the degree of extended 
    delignification used.) Second, as an economic matter, interim 
    limitations driving a mill to over-design its chlorine dioxide 
    generator would cause the mill to divert capital away
    
    [[Page 18599]]
    
    from the processes needed to achieve the ultimate Voluntary Advanced 
    Technology BAT limitations. That diversion of resources undercuts one 
    of EPA's principal assumptions regarding the economic achievability of 
    the ultimate Voluntary Advanced Technology BAT limitations: that mills 
    would be able to focus their capital and other resources entirely on 
    those superior performance levels. Thus, EPA was concerned that by 
    compelling achievement of baseline BAT limitations as ``stage 1'' 
    limitations, EPA would unnecessarily inflate the overall cost of 
    achieving the ultimate Advanced Technology limitations. This would 
    likely cause some mills to conclude that they cannot sustain the 
    overall costs of achieving the Voluntary Advanced Technology BAT 
    limitations in an economically achievable manner. Other mills, in turn, 
    might decide to absorb the additional costs by diverting resources from 
    other environmentally beneficial projects that they might have 
    voluntarily undertaken. The Clean Water Act authorizes EPA to consider 
    non-water quality environmental impacts and other factors EPA deems 
    appropriate in setting BAT limitations. See CWA Section 304(b)(2)(B). 
    For these reasons, EPA believes that compelling achievement of the 
    baseline BAT limits in the first instance would have had the 
    contradictory and unintended effect of discouraging participation in 
    the program, with the result that fewer mills ultimately would be 
    motivated to achieve superior environmental performance. Finally, as 
    discussed in more detail below, EPA is requiring mills at the Tier II 
    and Tier III levels to achieve interim limitations equivalent to 
    baseline BAT by April 15, 2004. See 40 CFR 430.24(b)(3).
        b. Interim Milestones. As the second component of the Voluntary 
    Advanced Technology BAT for the three Incentives Tiers, EPA is 
    requiring the establishment of enforceable interim milestones. See 40 
    CFR 430.24(b) (2) and (3). EPA believes that interim milestones would 
    incrementally benefit the environment during the period prior to 
    achievement of the ultimate Advanced Technology performance levels and 
    will ensure that participating mills make reasonable progress toward 
    achieving the superior performance represented by the various Advanced 
    Technology BAT Tiers.
        EPA is promulgating two sets of enforceable interim milestones. The 
    first set requires mills enrolled at the Tier II or the Tier III level 
    to achieve limitations equivalent to baseline BAT limitations by April 
    15, 2004. 40 CFR 430.24(b)(3). (Mills enrolled at the Tier I level are 
    required to achieve those limitations as well as the ultimate Advanced 
    Technology limitations by that date. 40 CFR 430.24(b) (3) and (4).) EPA 
    believes that this is a reasonable requirement not only because it 
    ensures significant environmental progress consistent with CWA section 
    301(b)(2), but it also reflects the technology performance Tier II and 
    Tier III mills are likely to be achieving by that date. Mills enrolled 
    in Tier II and Tier III are expected to substantially modify pulping 
    and bleaching processes (e.g., install extended delignification, ECF, 
    or TCF bleaching) to comply with the Advanced Technology limitations. 
    EPA expects that all Tier II or Tier III mills will install extended 
    delignification and complete substitution (ECF) or TCF bleaching 
    processes well in advance of achieving their wastewater flow objectives 
    in order to allow sufficient time to design, install, test and adjust 
    their other flow-related processes. In EPA's judgment, process changes 
    sufficient to achieve baseline BAT limitations will occur by April 15, 
    2004. Once these processes are installed, the mill will be achieving or 
    exceeding the baseline BAT limitations being required by that date. See 
    DCN 14488.
        EPA notes that mills required to achieve water quality-based or 
    other effluent limitations equivalent to one or more of the Voluntary 
    Advanced Technology BAT limitations are still eligible to enroll in the 
    Voluntary Advanced Technology Incentives Program and to receive 
    incentives for achieving the remaining Voluntary Advanced Technology 
    limitations. However, the time for complying with water quality-based 
    or other equivalent effluent limitations would be determined by 
    applicable law, not by this Voluntary Advanced Technology Incentives 
    Program. Therefore, for example, if a mill's NPDES permit compels 
    immediate compliance with a dioxin limitation equivalent to the 
    Voluntary Advanced (BAT) Technology limitation on dioxin because of 
    water quality concerns or other requirements of state or federal law, 
    this six-year milestone would not be available for that dioxin 
    limitation. See CWA section 301(b)(1)(C).
        The second set of enforceable interim milestones promulgated today 
    applies to all mills enrolled in the Advanced Technology Incentives 
    Program. Although today's rule leaves the type and frequency of these 
    milestones to the permit writer's best professional judgment, see 40 
    CFR 430.24(b)(2), milestones should include intermediate pollutant load 
    and wastewater flow reductions (for Tier II and Tier III mills) in 
    addition to research schedules, construction schedules, mill trial 
    schedules, or other milestones appropriate to the advanced technology 
    and the participating mill. Interim milestones should be tailored to 
    circumstances and process technologies at individual mills.
        In order to facilitate the development of appropriate interim 
    milestones on a case-by-case basis, EPA proposes elsewhere in today's 
    Federal Register to require all mills enrolling in the incentives 
    program to submit plans detailing the strategy the mill will follow to 
    develop and implement the technology required to achieve the chosen 
    incentive tier, as well as the interim numeric limitations for Tiers II 
    and III. The plan should describe each envisioned new technology 
    component or process modification the mill will need to achieve the 
    Voluntary Advanced Technology BAT limits. A master schedule should be 
    included in the plan showing the sequence of implementing the new 
    technologies and process modifications and identifying critical path 
    relationships within the sequence. For each individual technology or 
    process modification, a schedule should be provided that lists the 
    anticipated date that associated construction, installation, or process 
    changes will be initiated, the anticipated date that those steps will 
    be completed, and the anticipated date that the full Advanced 
    Technology process or individual component will be fully operational. 
    For those technologies or process modifications that are not 
    commercially available or demonstrated on a full scale basis at the 
    time the plan is developed, the plan should include a schedule for 
    research (if necessary), process development, and mill trials. The 
    schedule for research, process development, and mill trials should show 
    major milestone dates and the anticipated date the technology or 
    process change will be available for mill implementation. The plan also 
    would need to include contingency plans in the event that any of the 
    technologies or processes specified in the Milestones Plan need to be 
    adjusted or alternative approaches developed to ensure that the 
    ultimate tier limits are achieved by the dates in the master schedule. 
    EPA expects the permitting authority to use the information contained 
    in those plans, as well as its own best professional judgment, to 
    establish enforceable interim milestones applying all statutory 
    factors. EPA also expects permit writers to include reopener clauses in 
    the permits to adjust these milestones including dates to reflect the
    
    [[Page 18600]]
    
    results of research (if necessary), process development, and mill 
    trials.
        Section 402(a) of the Clean Water Act authorizes permit writers to 
    establish permit conditions and limitations on the basis of best 
    professional judgment as necessary to achieve the objectives of the 
    Act. Although EPA is promulgating BAT limitations under CWA sections 
    301 and 304, EPA is not--nor could it today--codify the particular 
    process development, construction, and testing milestones that will 
    lead each participating mill to achieve the ultimate Voluntary Advanced 
    Technology performance requirements. Identifying those milestones is 
    best left to the judgment of the permit writer, who will have access to 
    far more mill-specific information than EPA has today.
        c. ``Stage 2'' limitations. The third component of the Voluntary 
    Advanced Technology BAT limitations consists of the ``stage 2'' 
    limitations. See 40 CFR 430.24(b)(4)(i). These are the only standards 
    applicable to Voluntary Advanced Technology NSPS and must be achieved 
    upon commencing operation. See 40 CFR 430.25(c). Also included in the 
    Voluntary Advanced Technology NSPS are standards for dioxin, furan, 
    chloroform, 12 chlorinated phenolic compounds, BOD5, TSS, 
    and pH at the baseline NSPS level. See 40 CFR 430.25(c)(1). In 
    addition, standards for pentachlorophenol and trichlorophenol, when 
    used as biocides, are part of the Voluntary Advanced Technology NSPS. 
    See 40 CFR 430.25(d).
        These limitations and standards represent the ultimate performance 
    requirements for each Tier. The ``stage 2'' limitations are as follows:
        (1) Tier I Voluntary Advanced Technology BAT Limitations (``stage 
    2''). For Tier I, the ultimate performance requirement for AOX is a 
    long-term average (LTA) of 0.26 kg/kkg, measured at the end of the 
    pipe. 40 CFR 430.24(b)(4)(i). Under this Tier, Advanced Technology 
    fiber lines at participating mills must also achieve reduced lignin 
    content in unbleached pulps as measured by a kappa number of 20 for 
    softwoods and 13 for hardwoods and reported as an annual average. Id. 
    Finally, Tier I Advanced Technology fiber lines must recycle to 
    recovery systems all filtrates up to the point at which the unbleached 
    pulp kappa numbers are measured (e.g., brownstock into bleaching). Tier 
    I also includes limitations for dioxin, furan, chloroform and 12 
    chlorinated phenolic pollutants, see 40 CFR 430.24(b)(3). Limitations 
    on these parameters are established at the baseline BAT levels because 
    application of Advanced Technologies does not appear on this record to 
    justify more stringent limitations.
        (2) Tier II Voluntary Advanced Technology BAT Limitations (``stage 
    2'') and NSPS. For Tier II, the ultimate performance requirement for 
    AOX is an LTA of less than 0.10 kg/kkg, measured at the end of the 
    pipe. 40 CFR 430.24(b)(4)(i) and 430.25(c)(2). In addition, Tier II 
    Advanced Technology fiber lines must recycle to chemical recovery 
    systems all pulping-area filtrates prior to bleaching. Id. Finally, 
    Tier II Advanced Technology fiber lines must also achieve total pulping 
    area condensate, evaporator condensate, and bleach plant wastewater 
    flow of 10 m\3\/kkg or less reported as an annual average. Id. Tier II 
    mills must also meet (or, in the case of existing dischargers, must 
    continue to meet) limitations for dioxin, furan, chloroform, and the 12 
    chlorinated phenolic pollutants. See 40 CFR 430.24(b)(3) and 
    430.25(c)(1). Application of the Tier II Technologies does not appear 
    to justify more stringent limitations for these parameters.
        (3) Tier III Voluntary Advanced Technology BAT Limitations (``stage 
    2'') and NSPS. For Tier III, the ultimate performance requirement for 
    AOX is an LTA of less than 0.05 kg/kkg, measured at the end of the 
    pipe. See 40 CFR 430.24(b)(4)(i) and 430.25(c)(2). In addition, Tier 
    III Advanced Technology fiber lines must recycle to chemical recovery 
    systems all pulping-area filtrates prior to bleaching. Id. Finally, 
    Tier III Advanced Technology fiber lines must also achieve total 
    pulping area condensate, evaporator condensate, and bleach plant 
    wastewater flow of 5 m\3\/kkg or less reported as an annual average. 
    Id. Tier III mills must also meet (or, in the case of existing 
    dischargers, must continue to meet) limitations for dioxin, furan, 
    chloroform, and the 12 chlorinated phenolic pollutants. See 40 CFR 
    430.24(b)(3) and 430.25(c)(1). Application of the Tier III Technologies 
    does not appear to justify more stringent limitations for these 
    parameters.
        d. Voluntary Advanced Technology BAT Limitations and NSPS for Mills 
    Employing TCF Processes. In order to encourage mills to employ Advanced 
    Technologies founded on TCF processes, EPA is opening today's 
    incentives program to fiber lines that employ or commit to employ such 
    processes. Existing dischargers that choose to employ TCF processes are 
    subject to the ``stage 1'' limitations, interim milestones (including 
    the baseline BAT limitations), and the ``stage 2'' limitations 
    applicable to the selected tier. 40 CFR 430.24(b) and 430.25(c). These 
    limitations are discussed above. However, recently gathered data from 
    TCF mills indicate that all TCF mills will be able to achieve the AOX 
    performance requirements at any Tier level because end-of-pipe AOX 
    levels are being reported at below minimum level. See DCN 14488. 
    Consequently, the AOX limitations for TCF fiber lines are expressed as 
    ``5 
    loads associated with the Advanced Technologies. The technology basis 
    of each of the Incentives Tiers will lead to overall decreases in 
    energy consumption, primarily because of replacement of chlorine 
    dioxide with oxygen-based delignification and bleaching chemicals. EPA 
    expects a slight increase in air emissions (<2 percent)="" due="" to="" increased="" recovery="" of="" black="" liquor="" that="" will="" occur="" under="" the="" incentives="" tiers.="" however,="" these="" are="" offset="" by="" reductions="" in="" air="" pollution="" that="" derive="" from="" the="" reductions="" in="" overall="" energy="" consumption.="" epa="" considered="" the="" potential="" for="" cross-media="" transfer="" of="" pollutants="" through="" implementation="" of="" the="" advanced="" technologies="" that="" form="" the="" basis="" of="" the="" incentives="" tiers.="" epa="" found="" no="" basis="" to="" conclude="" that="" cross-="" media="" transfer="" of="" pollutants="" would="" occur.="" see="" dcn="" 14488="" and="" dcn="" 14492.="" however,="" much="" of="" the="" tier="" ii="" and="" tier="" iii="" technology="" bases="" focus="" on="" closing="" mill="" process="" cycles,="" which="" has="" not="" yet="" been="" fully="" demonstrated.="" as="" these="" technologies="" are="" fully="" developed="" and="" implemented,="" sufficient="" engineering="" analyses="" and="" testing="" should="" be="" performed="" to="" assess="" whether="" unacceptable="" cross="" media="" transfer="" of="" pollutants="" are="" occurring,="" and="" whether="" modifications="" need="" to="" be="" made="" to="" avoid="" any="" unacceptable="" transfers="" identified.="" for="" nsps,="" epa="" has="" determined="" that="" tier="" ii="" and="" tier="" iii="" technologies="" constitute="" the="" best="" demonstrated="" control="" technologies="" for="" mills="" enrolling="" in="" those="" tiers.="" although="" epa="" cannot="" say="" today="" that="" either="" of="" these="" technology="" sequences="" is="" the="" best="" demonstrated="" control="" technology="" for="" new="" sources="" in="" the="" bleached="" papergrade="" kraft="" and="" soda="" subcategory="" as="" a="" whole,="" epa="" does="" believe="" that="" new="" sources="" emerging="" within="" the="" next="" 16="" years="" may="" characterize="" them="" as="" such="" based="" on="" their="" own="" sense="" of="" their="" economic="" and="" technical="" capabilities.="" therefore,="" as="" with="" existing="" sources,="" epa="" is="" promulgating="" this="" additional="" array="" of="" nsps="" in="" order="" to="" provide="" such="" mills="" the="" opportunity="" to="" pursue="" voluntarily="" pollution="" prevention="" technologies--and="" to="" accept="" correspondingly="" more="" stringent="" effluent="" limitations--if="" business="" circumstances="" warrant.="" epa="" notes="" that="" a="" mill="" subjecting="" itself="" to="" the="" advanced="" technology="" nsps="" will="" be="" shielded="" from="" more="" stringent="" technology-based="" effluent="" limitations="" for="" ten="" years="" beginning="" on="" the="" date="" that="" construction="" is="" completed.="" see="" cwa="" section="" 306(d).="" because="" these="" standards="" are="" entirely="" voluntary,="" their="" promulgation="" today="" presents="" no="" barrier="" to="" entry.="" in="" addition,="" epa="" has="" determined="" that="" achievement="" of="" these="" standards="" will="" not="" result="" in="" any="" significant="" non-water="" quality="" environmental="" impacts="" or="" significant="" additional="" energy="" requirements.="" see="" dcn="" 14488.="" nothing="" in="" epa's="" analysis="" of="" the="" other="" statutory="" factors="" applicable="" to="" nsps="" justified="" selecting="" different="" nsps="" technologies.="" epa="" also="" believes="" it="" is="" appropriate="" to="" promulgate="" limitations="" for="" all="" three="" tiers="" at="" the="" same="" time="" it="" promulgates="" the="" baseline="" bat="" limitations.="" (the="" same="" rationale="" applies="" for="" today's="" voluntary="" advanced="" technology="" nsps.)="" by="" promulgating="" all="" three="" voluntary="" advanced="" technology="" bat="" tiers="" today,="" rather="" than="" in="" five-year="" increments,="" epa="" hopes="" to="" encourage="" as="" many="" mills="" as="" possible="" to="" develop="" and="" install="" advanced="" technologies.="" on="" this="" record,="" epa="" has="" determined="" that="" its="" customary="" practice="" of="" promulgating="" a="" single="" bat="" for="" similarly="" situated="" mills--represented="" here="" by="" the="" baseline="" bat="" limitations--would="" have="" the="" unintended="" effect="" of="" impeding="" some="" mills'="" progress="" toward="" even="" greater="" environmental="" objectives="" than="" epa="" can="" compel="" at="" this="" time.="" thus,="" if="" epa="" were="" to="" promulgate="" only="" baseline="" bat="" limitations="" today="" and="" not="" establish="" a="" parallel="" track="" for="" mills="" converting="" to="" advanced="" technologies,="" epa="" is="" concerned="" that="" mills="" might="" abandon="" their="" voluntary="" long-term="" strategies="" of="" superior="" environmental="" performance="" in="" favor="" of="" compulsory="" short-term="" compliance="" strategies="" focused="" on="" the="" baseline="" bat.="" instead,="" by="" promulgating="" voluntary="" advanced="" technology="" bat="" limitations="" at="" the="" same="" time="" as="" baseline="" bat="" limitations,="" epa="" allows="" interested="" mills="" to="" consider="" all="" technology="" options="" at="" the="" outset="" before="" they="" make="" their="" investment="" decisions="" and="" to="" design="" and="" install="" precisely="" the="" technologies="" and="" [[page="" 18603]]="" processes="" they="" will="" need="" to="" meet="" their="" long-term="" advanced="" technology="" objectives.="" therefore,="" epa="" has="" decided="" to="" promulgate="" all="" of="" the="" voluntary="" advanced="" technology="" bat="" limitations="" today="" in="" order="" to="" provide="" mills="" with="" an="" opportunity="" to="" push="" their="" environmental="" performance="" beyond="" the="" minimum="" prescribed="" by="" the="" baseline="" bat="" and="" on="" toward="" the="" statutory="" goal="" of="" zero="" discharge.="" promulgating="" the="" various="" voluntary="" advanced="" technology="" tiers="" today="" rather="" than="" in="" five-year="" increments="" also="" provides="" some="" predictability="" regarding="" the="" progress="" expected="" of="" advanced="" technology="" mills="" over="" time.="" epa="" hopes="" that="" this="" predictability="" will="" encourage="" greater="" participation="" in="" the="" program="" and="" thus="" lead="" to="" superior="" effluent="" quality.="" finally,="" promulgating="" all="" three="" tiers="" of="" advanced="" technology="" bat="" limitations="" today="" makes="" sense="" because="" it="" reflects="" epa's="" regulatory="" approach="" for="" promoting="" successively="" greater="" environmental="" achievements="" for="" this="" industry,="" and="" because="" companies="" willing="" to="" commit="" to="" achieve="" the="" increased="" environmental="" controls="" will="" be="" able="" to="" avoid="" the="" uncertainties="" inherent="" in="" a="" succession="" of="" later="" rulemakings.="" epa="" has="" the="" authority="" to="" promulgate="" the="" three="" tiers="" of="" voluntary="" advanced="" technology="" bat="" limitations="" today="" even="" though="" their="" ultimate="" performance="" requirements="" will="" not="" be="" attained="" until="" a="" future="" date.="" epa="" has="" the="" authority="" under="" cwa="" section="" 304(b)(2)="" and="" 304(m)="" to="" revise="" the="" baseline="" bat="" limitations="" for="" the="" bleached="" papergrade="" kraft="" and="" soda="" subcategory="" whenever="" the="" administrator="" deems="" it="" is="" appropriate.="" thus,="" epa="" would="" be="" free="" in="" 5,="" 10="" or="" 15="" years="" to="" codify="" the="" voluntary="" advanced="" technology="" limitations="" as="" bat.="" however,="" by="" then,="" mills="" potentially="" interested="" in="" pursuing="" advanced="" technologies="" would="" already="" have="" been="" required="" to="" meet="" baseline="" bat="" limitations,="" perhaps="" using="" technologies="" not="" fully="" compatible="" with="" more="" advanced="" processes.="" the="" costs="" of="" retrofitting,="" or="" in="" some="" cases="" replacing,="" newly="" installed="" process="" technologies="" to="" achieve="" more="" stringent="" limits="" might="" prevent="" epa="" from="" finding="" that="" these="" technologies="" are="" economically="" achievable.="" in="" addition,="" participating="" mills="" would="" lose="" a="" long-term="" planning="" horizon,="" which="" is="" very="" important="" because="" of="" the="" significant="" capital="" outlays="" involved.="" as="" a="" result,="" epa="" was="" concerned="" that="" failure="" to="" promulgate="" these="" voluntary="" advanced="" technology="" bat="" limitations="" today="" might="" compromise="" future="" pollution="" prevention="" opportunities.="" epa="" is="" authorized="" to="" consider="" those="" opportunities="" when="" promulgating="" bat="" limitations.="" epa="" therefore="" believes="" it="" is="" appropriate="" to="" consider="" these="" barriers="" to="" pollution="" prevention="" as="" factors="" relevant="" to="" the="" definition="" of="" bat="" limitations="" and="" the="" timing="" of="" their="" promulgation,="" see="" cwa="" section="" 304(b)(2)(b);="" especially="" since="" failure="" to="" promulgate="" a="" voluntary="" advanced="" technology="" incentives="" program="" at="" this="" time="" might="" impede="" reasonable="" further="" progress="" toward="" the="" national="" goal="" of="" eliminating="" discharges="" of="" all="" pollutants.="" see="" cwa="" section="" 301(b)(2).="" an="" important="" component="" of="" this="" incentives="" program="" is="" the="" element="" of="" choice.="" direct="" discharging="" mills="" subject="" to="" subpart="" b="" may="" choose="" whether="" to="" enroll="" in="" the="" program="" and,="" once="" enrolled,="" may="" choose="" the="" tier,="" or="" performance="" level,="" that="" they="" will="" achieve.="" in="" order="" to="" codify="" this="" structure,="" epa="" has="" promulgated="" three="" sets="" of="" voluntary="" advanced="" technology="" bat="" limitations="" for="" bleached="" papergrade="" kraft="" and="" soda="" mills="" and="" two="" sets="" of="" nsps="" in="" addition="" to="" the="" baseline="" bat="" and="" nsps.="" in="" effect,="" epa="" has="" divided="" subpart="" b="" into="" segments="" based="" on="" the="" types="" of="" bleach="" plant="" processes="" mills="" choose="" to="" employ.="" epa="" has="" considerable="" authority="" to="" establish="" segments="" within="" an="" industrial="" subcategory="" for="" the="" purpose="" of="" promulgating="" bat="" limitations="" unique="" to="" those="" mills.="" much="" like="" mill-specific="" variances="" based="" on="" fundamentally="" different="" factors,="" segments="" reflect="" epa's="" authority="" to="" take="" into="" account="" the="" diversity="" within="" each="" industry.="" see="" chemical="" mrfs.="" ass'n="" v.="" nrdc,="" 470="" u.s.="" 116,="" 130,="" 105="" s.ct="" 1102,="" 1110="" (1985).="" thus,="" segmentation,="" like="" variances,="" is="" not="" an="" exception="" to="" the="" standard-setting="" process,="" but="" rather="" a="" more="" fine-tuned="" application="" of="" it.="" id.="" for="" bat,="" epa="" has="" essentially="" established="" four="" segments="" for="" the="" bleached="" papergrade="" kraft="" and="" soda="" subcategory="" (and,="" similarly,="" three="" segments="" for="" nsps).="" one="" segment="" codifies="" the="" baseline="" bat="" limitations;="" the="" other="" three="" segments="" codify="" tiers="" i,="" ii="" and="" iii="" of="" the="" voluntary="" advanced="" technology="" bat="" incentives="" program.="" epa="" defined="" the="" advanced="" technology="" segments="" to="" reflect="" the="" various="" types="" of="" process="" changes="" and="" control="" techniques="" that="" mills="" might="" employ="" to="" achieve="" environmental="" performance="" beyond="" the="" baseline="" bat="" level.="" the="" advanced="" technology="" segments="" also="" reflect="" the="" cost="" of="" achieving="" progressively="" greater="" environmental="" effluent="" reductions.="" any="" one="" of="" those="" factors="" is="" sufficient="" under="" cwa="" section="" 304(b)(2)="" to="" justify="" a="" segment="" for="" affected="" mills.="" each="" mill="" in="" subpart="" b="" must="" comply="" with="" the="" baseline="" bat="" limitations="" unless="" it="" designates="" itself="" as="" an="" advanced="" technology="" mill,="" in="" which="" case="" it="" must="" meet="" the="" bat="" limitations="" corresponding="" to="" the="" tier--and="" segment--it="" chooses.="" although="" epa="" has="" identified="" an="" array="" of="" process="" changes="" that,="" if="" employed,="" could="" distinguish="" one="" subpart="" b="" mill="" from="" another="" and="" has="" based="" its="" advanced="" technology="" limitations="" on="" those="" potential="" changes,="" epa="" has="" made="" the="" advanced="" technology="" segments="" voluntary.="" this="" is="" because="" the="" decision="" whether="" advanced="" technology="" process="" changes="" are="" technically="" feasible="" and="" economically="" achievable="" for="" a="" particular="" mill="" depends="" on="" many="" factors="" unique="" to="" that="" mill="" that="" epa,="" on="" the="" record="" available="" today,="" cannot="" readily="" discern="" or="" forecast.="" among="" the="" more="" significant="" factors="" appear="" to="" be="" the="" mill's="" current="" bleaching="" sequence,="" the="" physical="" configuration="" of="" equipment,="" the="" age="" of="" equipment="" (and,="" thus,="" end-of-life="" issues),="" the="" available="" capacity="" in="" chlorine="" dioxide="" generation="" and="" in="" the="" recovery="" boiler,="" and="" whether="" the="" mill="" uses="" hardwood="" or="" softwood.="" see="" dcn="" 14488.="" see="" also="" paper="" task="" force,="" technical="" supplement="" white="" papers,="" record="" section="" 20.2.8,="" dcn="" 14794,="" dcn="" 14795,="" and="" dcn="" 14796.="" epa="" also="" has="" important="" policy="" reasons="" for="" making="" the="" advanced="" technology="" bat="" limitations="" voluntary,="" both="" in="" terms="" of="" the="" decision="" to="" participate="" and="" in="" terms="" of="" the="" level="" of="" environmental="" performance="" to="" be="" achieved.="" as="" discussed="" in="" greater="" detail="" above,="" epa="" believes="" that="" mills="" willing="" and="" able="" to="" employ="" technologies="" and="" processes="" superior="" to="" the="" ``baseline''="" promulgated="" as="" bat--and="" willing="" to="" guarantee="" that="" effort="" in="" the="" form="" of="" enforceable="" technology-based="" permit="" limitations--="" should="" have="" the="" opportunity="" to="" do="" so.="" by="" giving="" mills="" a="" choice="" to="" exceed="" baseline="" compliance="" levels,="" epa="" implements="" cwa="" section="" 301(b)(2)'s="" direction="" that="" bat="" limitations="" ``result="" in="" reasonable="" further="" progress="" toward="" the="" national="" goal="" of="" eliminating="" the="" discharge="" of="" all="" pollutants,''="" to="" the="" extent="" consistent="" with="" epa's="" findings="" of="" economic="" achievability,="" among="" other="" factors.="" by="" allowing="" mills="" to="" choose="" between="" baseline="" bat="" limitations="" and="" voluntary="" advanced="" technology="" bat="" limitations="" at="" the="" outset,="" epa="" also="" wants="" to="" encourage="" mills="" to="" consider="" all="" possible="" process="" configurations="" before="" investing="" in="" the="" baseline="" bat="" technology.="" thus,="" by="" codifying="" multiple="" expressions="" of="" bat,="" epa="" has="" established="" a="" regulatory="" mechanism="" that="" allows="" mills="" to="" choose="" greater="" environmental="" performance="" than="" epa="" could="" require="" on="" this="" record="" and="" also="" authorizes="" permit="" writers="" to="" [[page="" 18604]]="" memorialize="" that="" choice="" in="" the="" form="" of="" enforceable="" permit="" limits.="" although="" applied="" here="" for="" the="" first="" time="" to="" codify="" a="" voluntary="" advanced="" technology="" incentives="" program,="" the="" notion="" of="" using="" segmentation="" to="" determine="" applicable="" technology-based="" limitations="" is="" not="" new.="" indeed,="" effluent="" limitations="" guidelines="" and="" standards="" routinely="" base="" applicability="" of="" technology-based="" limitations="" on="" a="" discharger's="" particular="" process="" or="" treatment="" technologies.="" for="" example,="" elsewhere="" in="" today's="" rule="" epa="" is="" segmenting="" the="" papergrade="" sulfite="" subcategory="" to="" reflect,="" among="" other="" things,="" the="" type="" of="" product="" the="" mill="" produces.="" thus,="" a="" papergrade="" sulfite="" mill="" choosing="" to="" produce="" specialty="" products="" subjects="" itself="" to="" a="" different="" set="" of="" limitations="" than="" other="" mills="" in="" its="" subcategory="" simply="" by="" making="" that="" business="" decision.="" epa="" also="" used="" segmentation="" to="" account="" for="" different="" treatment="" configurations="" when="" it="" promulgated="" bat="" for="" the="" organic="" chemicals,="" plastics="" and="" synthetic="" fibers="" category.="" see="" 40="" cfr="" 414.91,="" 414.101;="" 58="" fr="" 36872,="" 36881-85="" (july="" 9,="" 1993).="" in="" that="" rule,="" epa="" established="" two="" sets="" of="" bat="" limitations="" for="" a="" subcategory="" of="" plants,="" one="" set="" applicable="" to="" plants="" using="" end-of-pipe="" biological="" treatment="" and="" the="" other="" set="" applicable="" to="" plants="" using="" some="" other="" treatment="" technology,="" including="" in-plant="" waste="" management="" practices.="" in="" this="" rule,="" the="" advanced="" technology="" segments="" are="" intended="" to="" anticipate="" a="" mill's="" business="" decision="" to="" change="" its="" cooking,="" washing,="" bleaching,="" wastewater="" recycle,="" and="" recovery="" processes="" to="" achieve="" greater="" pollutant="" reductions="" than="" epa="" can="" require="" as="" baseline="" bat.="" indeed,="" by="" establishing="" these="" segments,="" epa="" hopes="" to="" encourage="" many="" mills="" to="" choose="" advanced="" technologies,="" especially="" those="" mills="" that="" would="" need="" to="" change="" their="" bleaching="" and="" washing="" processes="" in="" any="" event="" to="" comply="" with="" the="" baseline="" bat.="" epa="" also="" notes="" that="" it="" could="" have="" accomplished="" the="" same="" result="" for="" existing="" sources="" on="" a="" case-by-case="" basis="" through="" the="" clean="" water="" act's="" variance="" processes.="" see="" chemical="" mrfs.="" ass'n="" v.="" nrdc,="" 470="" u.s.="" at="" 130,="" 105="" s.ct="" at="" 1110.="" advanced="" technology="" mills="" could="" have="" sought="" fundamentally="" different="" factors="" variances="" under="" cwa="" section="" 301(n);="" for="" non-conventional="" pollutants,="" these="" mills="" could="" have="" pursued="" a="" variance="" under="" section="" 301(c).="" under="" either="" section,="" mills="" could="" have="" obtained="" bat="" effluent="" limitations="" that="" are="" more="" or="" less="" stringent="" than="" the="" baseline="" bat.="" see="" chemical="" mrfs.="" ass'n="" v.="" nrdc,="" 470="" u.s.="" at="" 116,="" 105="" s.ct="" at="" 1105-06="" (fdf="" variances);="" epa="" v.="" national="" crushed="" stone="" ass'n,="" 449="" u.s.="" 64,="" 79="" n.18="" (1980)="" (sec.="" 301(c)="" variances).="" however,="" epa="" rejected="" implementing="" the="" voluntary="" advanced="" technology="" incentives="" program="" through="" variances="" for="" several="" reasons.="" first,="" the="" clean="" water="" act="" and="" its="" legislative="" history="" indicate="" a="" clear="" congressional="" preference="" for="" the="" use="" of="" subcategories,="" rather="" than="" variances,="" to="" address="" discernible="" differences="" among="" regulated="" entities.="" by="" requiring="" applications="" for="" fdf="" variances="" to="" be="" based="" on="" information="" submitted="" during="" the="" rulemaking="" process="" (unless="" the="" applicant="" lacked="" a="" reasonable="" opportunity="" to="" make="" such="" submission),="" see="" section="" 301(n)(1)(b),="" congress="" stressed="" the="" need="" for="" companies="" to="" participate="" fully="" in="" the="" guideline="" development="" process="" to="" assure="" that="" adequate="" information="" is="" available="" to="" epa="" to="" develop="" appropriate="" subcategories.="" see="" 131="" cong.="" rec.="" s="" 8013="" (june="" 12,="" 1985)="" (sen.="" bentsen);="" see="" also="" 133="" cong.="" rec.="" h="" 131,="" 136-37="" (jan.="" 7,="" 1987)="" (rep.="" howard)="" (provision="" assures="" that="" effluent="" guidelines="" ``are="" as="" comprehensive="" as="" possible'');="" 133="" cong.="" rec.="" s="" 733,="" 739="" (jan.="" 14,="" 1987)="" (sen.="" mitchell)="" (epa="" should="" accommodate="" fundamental="" differences="" among="" facilities="" through="" the="" establishment="" of="" subcategories).="" in="" this="" rulemaking,="" many="" commenters="" supplied="" vast="" amounts="" of="" information="" concerning="" the="" special="" circumstances="" of="" facilities="" aspiring="" to="" become="" minimum="" impact="" mills.="" as="" congress="" intended,="" epa="" established="" the="" three="" voluntary="" advanced="" technology="" segments="" in="" response="" to="" that="" information="" rather="" than="" deferring="" consideration="" of="" the="" issue="" to="" the="" post-rulemaking="" variance="" process.="" second,="" as="" a="" matter="" of="" policy,="" epa="" believes="" it="" is="" reasonable="" to="" employ="" its="" subcategorization,="" rather="" than="" its="" variance,="" authority="" to="" implement="" the="" voluntary="" advanced="" technology="" incentives="" program.="" by="" establishing="" the="" voluntary="" advanced="" technology="" bat="" limitations="" by="" rulemaking="" at="" the="" same="" time="" it="" codifies="" the="" baseline="" bat="" limitations,="" epa="" intends="" to="" provide="" all="" direct="" discharging="" mills="" within="" subpart="" b="" the="" immediate="" opportunity="" to="" push="" beyond="" base="" level="" environmental="" performance="" and="" also="" to="" provide="" with="" certainty="" regarding="" the="" stringency="" and="" timing="" of="" the="" limits="" they="" would="" be="" expected="" to="" meet.="" in="" this="" way,="" epa="" hopes="" to="" encourage="" many="" mills="" to="" participate="" in="" the="" program.="" use="" of="" case-by-case="" variance="" procedures,="" in="" contrast,="" would="" introduce="" delay="" and="" uncertainty="" into="" the="" process,="" which="" epa="" believes="" would="" discourage="" industry="" participation.="" in="" summary,="" epa="" has="" discretion="" in="" determining="" whether="" to="" account="" for="" industry="" characteristics="" through="" subcategorization="" or="" through="" the="" variance="" process.="" like="" variances,="" the="" voluntary="" advanced="" technology="" segments="" apply="" only="" to="" mills="" that="" on="" their="" own="" initiative="" seek="" different="" bat="" limitations.="" unlike="" variances,="" however,="" the="" subcategorization="" scheme="" promulgated="" by="" epa="" assures="" consistent="" and="" timely="" implementation="" of="" the="" voluntary="" advanced="" technology="" incentives="" program,="" which="" epa="" believes="" is="" critical="" to="" its="" success.="" therefore,="" for="" the="" reasons="" explained,="" epa's="" decision="" to="" subcategorize="" subpart="" b="" was="" rational="" and="" within="" its="" discretion.="" 7.="" time="" frames="" for="" achieving="" voluntary="" advanced="" technology="" bat="" limitations="" in="" order="" to="" promote="" the="" pollution="" prevention="" objectives="" of="" the="" voluntary="" advanced="" technology="" incentives="" program,="" epa="" has="" determined="" that="" existing="" mills="" choosing="" to="" participate="" in="" that="" program="" should="" receive="" a="" reasonable="" amount="" of="" time="" to="" achieve="" the="" advanced="" tier="" performance="" levels="" they="" select.="" see="" 40="" cfr="" 430.24(b)(4)(ii).="" (these="" performance="" levels="" are="" codified="" in="" this="" rule="" as="" ``stage="" 2''="" bat="" limitations.)="" the="" extended="" timeframes="" discussed="" below="" are="" not="" available="" for="" new="" sources="" enrolled="" in="" the="" advanced="" technology="" incentives="" program="" because="" the="" clean="" water="" act="" requires="" new="" sources="" to="" comply="" with="" applicable="" nsps="" upon="" commencing="" operation.="" cwa="" section="" 306(e).="" however,="" new="" sources="" interested="" in="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" after="" commencing="" operation="" may="" nevertheless="" do="" so,="" for="" example,="" by="" achieving="" the="" baseline="" nsps="" requirements="" at="" the="" time="" discharges="" commence="" and="" later="" installing="" additional="" technologies="" necessary="" to="" achieve="" the="" more="" stringent="" aox="" and="" flow="" requirements="" of="" tiers="" ii="" or="" iii.="" once="" limitations="" equivalent="" to="" the="" selected="" advanced="" tier="" performance="" levels="" are="" placed="" in="" the="" mill's="" permit="" and="" the="" mill="" achieves="" those="" limits,="" it="" is="" eligible="" to="" receive="" the="" regulatory="" and="" enforcement="" relief="" described="" as="" incentives="" in="" section="" ix.b.="" below.="" epa="" has="" determined="" that="" reasonable="" dates="" by="" which="" existing="" sources="" can="" achieve="" advanced="" technology="" performance="" requirements="" are="" [april="" 15,="" 2004]="" for="" tier="" i,="" april="" 15,="" 2009="" for="" tier="" ii,="" and="" april="" 15,="" 2014="" for="" tier="" iii.="" see="" 40="" cfr="" 430.24(b)(4)(ii).="" as="" discussed="" in="" more="" detail="" below,="" these="" dates="" assume="" an="" initial="" start-up="" year="" during="" which="" mills="" subject="" to="" subpart="" b="" would="" decide="" whether="" to="" enroll="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" and="" develop="" a="" plan="" for="" complying="" with="" the="" ultimate="" incentives="" [[page="" 18605]]="" bat="" limitations.="" the="" remaining="" additional="" time,="" calculated="" as="" 5="" years="" for="" tier="" i,="" 10="" years="" for="" tier="" ii,="" and="" 15="" years="" for="" tier="" iii,="" corresponds="" to="" the="" time="" epa="" believes="" a="" mill="" would="" need="" in="" order="" to="" arrange="" its="" financing="" and="" to="" develop,="" install,="" test,="" and="" implement="" the="" chosen="" advanced="" technologies="" at="" full="" scale="" to="" comply="" with="" the="" ultimate="" tier="" limits.="" epa="" regards="" five="" years="" as="" a="" reasonable="" time="" frame="" to="" achieve="" the="" voluntary="" advanced="" technology="" bat="" limitations="" corresponding="" to="" tier="" i="" (including="" the="" bleach="" plant="" bat="" effluent="" limitations).="" when="" spread="" over="" five="" years,="" the="" capital="" costs="" of="" those="" technologies="" become="" more="" manageable="" (although="" they="" are="" still="" significantly="" higher="" than="" the="" capital="" costs="" associated="" with="" the="" baseline="" bat).="" in="" addition,="" the="" five="" year="" period="" gives="" mills="" increased="" flexibility="" to="" schedule="" the="" significant="" capital="" investment="" within="" the="" mill's="" normal="" capital="" investment="" cycle,="" i.e.,="" to="" purchase="" and="" install="" the="" necessary="" equipment="" when="" capital="" is="" available.="" therefore,="" epa="" believes="" the="" five="" year="" period="" will="" enable="" mills="" to="" participate="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" that="" otherwise="" might="" not="" have="" the="" financial="" resources="" to="" make="" the="" necessary="" capital="" investment.="" epa="" regards="" ten="" years="" as="" a="" reasonable="" timeframe="" to="" achieve="" the="" voluntary="" advanced="" technology="" bat="" limitations="" corresponding="" to="" tier="" ii="" because="" the="" development="" and="" implementation="" of="" technologies="" to="" reduce="" bleach="" plant="" flow="" to="" 10="" m\3\/kkg="" pose="" technical="" and="" economic="" difficulties="" that="" epa="" believes="" would="" take="" mills="" up="" to="" ten="" years="" to="" resolve.="" (once="" flow="" levels="" are="" reduced,="" epa="" expects="" that="" mills="" also="" will="" be="" able="" to="" achieve="" the="" tier="" ii="" aox="" limitations.)="" recycling="" a="" substantial="" portion="" of="" pulping="" and="" evaporator="" condensates="" and="" bleach="" plant="" filtrates,="" with="" the="" attendant="" complexities="" of="" total="" mill="" water,="" chemical,="" and="" energy="" balances,="" requires="" considerable="" time="" before="" it="" can="" be="" implemented="" successfully="" at="" mill-scale.="" for="" example,="" when="" bleach="" plant="" filtrates="" are="" recycled,="" problems="" with="" scale="" and="" corrosion="" can="" take="" many="" months="" to="" over="" a="" year="" to="" develop="" and="" be="" observed.="" once="" identified,="" fully="" correcting="" such="" problems="" can="" take="" significant="" additional="" time="" because="" of="" the="" time="" lag="" between="" action="" and="" observed="" effect="" in="" nearly="" closed="" systems.="" in="" addition="" to="" problems="" with="" scale="" and="" corrosion,="" mills="" pursuing="" tier="" ii="" performance="" levels="" may="" have="" to="" solve="" challenges="" associated="" with="" reusing="" condensates,="" such="" as="" for="" bleached="" pulp="" washing.="" there="" are="" a="" few="" mills="" currently="" doing="" this,="" but="" not="" broad="" operating="" experience.="" consequently,="" epa="" expects="" that="" tier="" ii="" mills="" will="" need="" to="" invest="" considerable="" time="" and="" effort="" to="" research="" and="" develop="" solutions="" to="" those="" technical="" problems.="" in="" addition="" to="" these="" technical="" challenges,="" significant="" capital="" costs="" may="" be="" involved="" in="" achieving="" tier="" ii="" limits,="" notably="" as="" a="" result="" of="" upgrading="" full="" pulping="" and="" bleaching="" lines="" and="" associated="" evaporator="" equipment.="" providing="" an="" extended="" timeframe="" that="" allows="" a="" mill="" to="" make="" such="" capital="" expenditures="" on="" a="" schedule="" consistent="" with="" its="" planned="" investment="" cycle="" can="" make="" such="" large="" investments="" economically="" achievable.="" for="" example,="" one="" u.s.="" mill="" currently="" approaching="" the="" tier="" ii="" flow="" and="" aox="" levels="" installed="" many="" of="" the="" relevant="" technologies="" in="" stages="" over="" what="" probably="" will="" be="" a="" ten-="" year="" period,="" with="" the="" last="" three="" years="" used="" for="" testing="" and="" fine-tuning="" its="" reduced="" flow="" processes.="" yet="" even="" this="" mill="" still="" needs="" to="" address="" the="" technical="" challenges="" of="" further="" reducing="" condensate="" discharge="" flow="" before="" it="" is="" fully="" able="" to="" achieve="" the="" tier="" ii="" bat="" limits.="" that="" mill="" needed="" ten="" years="" to="" plan="" its="" multi-hundred="" million="" dollar="" renovation="" and="" pollution="" prevention="" investment,="" to="" arrange="" appropriate="" financing,="" to="" install="" supporting="" technologies="" at="" appropriate="" intervals="" and="" to="" research,="" develop,="" test,="" and="" refine="" its="" innovative="" flow-reducing="" processes.="" epa="" believes="" that="" this="" mill's="" experience="" is="" representative="" of="" what="" other="" tier="" ii="" mills="" may="" encounter="" as="" they="" work="" to="" achieve="" the="" tier="" ii="" limitations.="" see="" the="" voluntary="" advanced="" technology="" incentives="" program="" technical="" support="" document="" (dcn="" 14488)="" for="" additional="" examples="" of="" why="" the="" ten-year="" timeframe="" is="" appropriate.="" based="" on="" these="" experiences,="" epa="" believes="" that="" the="" package="" of="" technologies="" underlying="" the="" tier="" ii="" voluntary="" advanced="" technology="" bat="" limitations="" will="" not="" be="" technically="" and="" economically="" achievable="" for="" mills="" aspiring="" to="" those="" performance="" levels="" until="" april="" 15,="" 2009.="" however,="" epa="" believes="" that="" mills="" will="" be="" able="" to="" achieve="" the="" baseline="" bat="" limitations="" by="" april="" 15,="" 2004,="" and="" enforceable="" interim="" milestones="" reflecting="" intermediate="" levels="" of="" flow="" reduction="" (determined="" on="" a="" case-by-case="" basis)="" in="" a="" period="" shorter="" than="" eleven="" years.="" epa="" regards="" 15="" years="" as="" a="" reasonable="" timeframe="" to="" achieve="" the="" voluntary="" advanced="" technology="" bat="" limitations="" corresponding="" to="" tier="" iii.="" as="" for="" tier="" ii,="" flow="" reduction="" again="" is="" the="" most="" difficult="" and="" time-consuming="" task.="" however,="" because="" reducing="" flow="" for="" pulping="" and="" evaporator="" condensates="" and="" bleach="" plant="" filtrates="" to="" 5="" m\3\/kkg="" or="" even="" lower="" approaches="" a="" closed="" mill="" configuration,="" even="" more="" technically="" difficult="" and="" time-consuming="" tasks="" must="" be="" successfully="" completed,="" necessitating="" five="" additional="" years="" beyond="" the="" tier="" ii="" timeframe.="" for="" example,="" mills="" would="" probably="" need="" to="" install="" ``kidney''="" technologies="" to="" remove="" metals="" and="" chlorides="" in="" order="" to="" control="" system="" scaling="" and="" corrosion="" problems="" while="" maintaining="" product="" quality="" and="" minimizing="" cross-media="" impacts.="" successful="" completion="" of="" these="" tasks="" at="" individual="" mills="" may="" involve="" research,="" extensive="" process="" development,="" and="" mill="" trials.="" the="" types="" of="" corrosion="" and="" scaling="" problems="" epa="" anticipates="" could="" take="" over="" a="" year="" of="" nearly="" closed-loop="" operation="" to="" identify="" and="" several="" more="" years="" of="" experimental="" modifications="" to="" mill="" operations="" to="" solve.="" extensive="" time="" is="" required="" for="" such="" modifications="" because="" of="" the="" time="" lag="" in="" nearly="" closed-mill="" systems="" from="" changing="" process="" conditions="" and="" observing="" the="" steady="" state="" impact="" on="" hydraulic="" systems,="" liquor="" systems,="" and="" associated="" mill="" equipment.="" mills="" may="" also="" need="" to="" embark="" on="" process="" development="" and="" mill="" trials="" to="" achieve="" treated="" condensate="" quality="" that="" is="" sufficient="" to="" extensively="" reuse="" condensates,="" as="" well="" as="" to="" reestablish="" complex="" mill="" water="" and="" energy="" balances.="" for="" these="" reasons,="" epa="" believes="" that="" 15="" years="" is="" a="" reasonable="" amount="" of="" time="" for="" a="" tier="" iii="" mill="" to="" perfect="" existing="" technologies="" or="" invent="" or="" develop="" new="" ones="" as="" necessary="" to="" achieve="" the="" tier="" iii="" performance="" levels.="" however,="" epa="" believes="" that="" all="" mills="" will="" be="" able="" to="" achieve="" the="" baseline="" bat="" limitations="" by="" [april="" 15,="" 2004],="" and="" enforceable="" interim="" milestones="" reflecting="" intermediate="" levels="" of="" flow="" reduction="" (determined="" on="" a="" case-by-case="" basis)="" in="" a="" period="" shorter="" than="" 15="" years.="" in="" short,="" epa="" believes="" that="" the="" additional="" 5,="" 10="" and="" 15="" year="" periods="" provided="" by="" the="" rule="" are="" necessary="" to="" foster="" investment,="" research,="" development,="" and="" mill="" trials="" of="" advanced="" technologies="" envisioned="" by="" the="" specified="" performance="" levels.="" epa="" further="" believes="" that,="" by="" the="" dates="" specified="" in="" the="" rule,="" technologies="" necessary="" to="" achieve="" those="" performance="" levels="" will="" indeed="" be="" available.="" see="" dcn="" 14488.="" epa="" has="" concluded="" that="" it="" is="" reasonable="" to="" measure="" the="" extended="" time="" periods="" from="" the="" publication="" date="" of="" the="" cluster="" rules="" rather="" than="" from="" the="" date="" a="" participating="" mill's="" npdes="" permit="" is="" issued,="" with="" the="" addition="" of="" one="" year="" at="" the="" beginning="" to="" afford="" mills="" a="" meaningful="" opportunity="" to="" consider="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program.="" epa="" recognizes="" that="" the="" decision="" whether="" to="" commit="" to="" the="" advanced="" technology="" goals="" cannot="" be="" undertaken="" lightly.="" this="" is="" especially="" so="" in="" view="" of="" the="" significant="" [[page="" 18606]]="" capital="" costs="" involved="" and="" in="" view="" of="" possible="" uncertainties="" regarding="" the="" availability="" of="" appropriate="" cost-effective="" technologies="" and="" a="" mill's="" ability="" to="" maintain="" product="" quality.="" accordingly,="" epa="" expects="" the="" decision="" would="" need="" to="" be="" made="" at="" the="" corporate="" rather="" than="" the="" facility="" level,="" which="" would="" probably="" require="" corporate-wide="" consideration="" of="" the="" firm's="" financial="" health,="" its="" environmental="" objectives="" and="" future="" marketing="" strategies,="" and="" its="" overall="" long-term="" plans.="" because="" epa="" believes="" that="" many="" firms="" in="" subpart="" b="" have="" been="" pondering="" these="" strategic="" questions="" since="" publication="" of="" the="" proposed="" rule="" in="" december="" 1993="" and="" the="" notice="" regarding="" a="" possible="" incentives="" program="" in="" july="" 1996,="" epa="" has="" concluded="" that="" one="" year="" is="" sufficient="" to="" allow="" firms="" to="" make="" a="" decision="" whether="" to="" participate="" in="" the="" voluntary="" advanced="" technology="" incentives="" program.="" if="" a="" mill's="" permit="" expires="" and="" is="" reissued="" before="" april="" 15,="" 1999,="" the="" permitting="" authority="" should="" incorporate="" voluntary="" advanced="" technology="" bat="" limitations="" into="" that="" permit="" at="" the="" mill's="" request.="" if="" the="" mill="" has="" not="" yet="" decided="" whether="" to="" participate="" in="" the="" voluntary="" advanced="" technology="" incentives="" program,="" the="" permit="" writer="" should="" incorporate="" bat="" limitations="" based="" on="" the="" bat="" baseline="" and="" should="" include="" a="" reopener="" clause="" so="" that="" the="" permit="" can="" be="" modified="" as="" necessary="" to="" reflect="" the="" mill's="" decision="" to="" participate="" in="" the="" incentives="" program.="" in="" order="" to="" afford="" that="" mill="" a="" full="" year="" to="" decide="" whether="" to="" enroll="" in="" the="" incentives="" program,="" epa="" believes="" it="" would="" be="" appropriate="" for="" the="" permitting="" authority="" to="" issue="" a="" compliance="" order="" expiring="" april="" 15,="" 1999="" so="" that="" the="" mill="" would="" not="" be="" required="" to="" comply="" with="" the="" baseline="" bat="" limitations="" until="" after="" the="" election="" date="" has="" passed.="" some="" commenters="" suggested="" that="" epa="" measure="" the="" advanced="" technology="" time="" periods="" from="" the="" date="" the="" first="" permit="" reflecting="" voluntary="" advanced="" technology="" bat="" limitations="" is="" issued.="" epa="" rejected="" that="" approach="" and="" instead="" is="" measuring="" the="" time="" periods="" from="" the="" publication="" date="" of="" this="" rule="" (plus="" one="" year)="" for="" the="" following="" reasons.="" first,="" these="" timeframes="" reflect="" epa's="" conclusions="" regarding="" the="" amount="" of="" time="" that="" mills="" would="" need="" in="" order="" to="" achieve="" the="" various="" voluntary="" advanced="" technology="" tier="" performance="" levels,="" once="" they="" have="" committed="" to="" those="" goals.="" as="" discussed="" in="" more="" detail="" above,="" epa="" based="" these="" conclusions="" on="" record="" information="" concerning="" the="" availability="" of="" technologies="" and="" capital,="" among="" other="" factors.="" these="" factors="" have="" nothing="" to="" do="" with="" the="" permitting="" cycle.="" second,="" as="" a="" matter="" of="" policy,="" epa="" wants="" to="" promote="" implementation="" of="" advanced="" technologies="" as="" soon="" as="" possible;="" if="" epa="" were="" to="" measure="" the="" advanced="" technology="" time="" periods="" from="" the="" date="" of="" permit="" re-issuance,="" achievement="" of="" the="" ultimate="" tier="" i="" performance="" requirements="" and="" the="" interim="" baseline="" bat="" limitations="" for="" tiers="" ii="" and="" iii,="" for="" example,="" could="" be="" deferred="" at="" some="" mills="" by="" as="" much="" as="" ten="" years="" from="" the="" date="" of="" promulgation.="" third,="" epa="" was="" concerned="" that="" tying="" the="" advanced="" technology="" time="" periods="" to="" highly="" variable="" permit="" issuance="" dates="" would="" mean="" that="" mills="" with="" later="" permits="" would="" realize="" a="" competitive="" advantage="" over="" similarly="" situated="" mills="" that,="" merely="" because="" of="" their="" particular="" permit="" cycle,="" would="" need="" to="" achieve="" the="" voluntary="" advanced="" technology="" bat="" limitations="" sooner.="" such="" inequities--whether="" perceived="" or="" real--could="" discourage="" some="" mills="" from="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program.="" finally,="" mills="" in="" the="" bleached="" papergrade="" kraft="" and="" soda="" subcategory="" have="" been="" on="" notice="" since="" at="" least="" 1993="" that="" epa="" was="" considering="" basing="" some="" portion="" of="" its="" cluster="" rules="" on="" extended="" delignification="" technologies.="" (in="" its="" 1993="" proposal,="" epa="" proposed="" to="" base="" bat="" limitations="" on="" a="" process="" that="" included="" oxygen="" delignification="" and="" 100="" percent="" substitution="" of="" chlorine="" dioxide="" for="" elemental="" chlorine.)="" in="" some="" cases,="" that="" proposal="" has="" already="" influenced="" investment="" decisions="" at="" some="" mills.="" epa="" acknowledges="" that="" a="" mill="" choosing="" not="" to="" participate="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" could="" seek="" a="" compliance="" schedule="" in="" an="" enforcement="" order="" that,="" depending="" on="" the="" date="" its="" permit="" was="" reissued,="" could="" allow="" that="" mill="" to="" achieve="" bat="" limits="" (including="" a="" less="" stringent="" aox="" limit)="" at="" a="" later="" date="" than="" tier="" i="" advanced="" technology="" mills="" would="" be="" required="" to="" achieve="" a="" more="" stringent="" aox="" limit="" and="" reduced="" kappa="" numbers="" and="" pulping="" area="" filtrate="" recycling.="" while="" epa="" agrees="" with="" comments="" characterizing="" this="" as="" unfair="" to="" those="" facilities="" making="" the="" significant="" commitment="" to="" install="" advanced="" technologies,="" epa="" believes="" that="" the="" likelihood="" of="" such="" inequities="" is="" small="" for="" the="" following="" reasons.="" first,="" epa="" has="" determined="" that="" this="" is="" likely="" to="" happen="" in="" comparatively="" few="" cases.="" more="" than="" 80="" percent="" of="" the="" permits="" issued="" to="" mills="" in="" the="" bleached="" papergrade="" kraft="" and="" soda="" subcategory="" will="" expire="" before="" 2000.="" see="" record="" section="" 21.8.1,="" dcn="" 14652.="" consequently,="" epa="" believes="" that="" most="" advanced="" technology="" mills="" will="" receive="" more="" time="" to="" achieve="" tier="" i="" limits="" than="" other="" mills="" would="" receive="" to="" achieve="" baseline="" bat="" limits,="" even="" with="" an="" enforcement="" compliance="" schedule.="" second,="" when="" epa="" is="" the="" permitting="" authority,="" epa="" will="" exercise="" its="" enforcement="" discretion="" to="" refrain="" from="" issuing="" enforcement="" compliance="" schedules="" after="" april="" 15,="" 1999="" to="" mills="" not="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program.="" this="" means="" that="" a="" mill="" not="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" would="" be="" expected="" to="" comply="" with="" its="" baseline="" bat="" limits="" by="" the="" date="" its="" permit="" containing="" those="" limits="" is="" issued,="" or="" by="" [april="" 15,="" 1999],="" whichever="" is="" later.="" epa="" will="" also="" publish="" guidance="" urging="" state="" enforcement="" authorities="" to="" do="" the="" same.="" by="" limiting="" the="" discretionary="" enforcement-related="" compliance="" schedules="" available="" to="" baseline="" bat="" mills,="" epa="" hopes="" that="" the="" additional="" time="" periods="" specified="" for="" advanced="" technology="" mills="" will="" become="" a="" more="" meaningful="" incentive="" and="" perhaps="" may="" persuade="" some="" mills="" to="" participate="" in="" the="" incentives="" program="" rather="" than="" comply="" immediately="" with="" the="" baseline="" bat="" limitations.="" 8.="" legal="" authority="" to="" promulgate="" a="" package="" of="" progressively="" more="" stringent="" voluntary="" advanced="" technology="" bat="" limitations="" as="" described="" in="" more="" detail="" above,="" the="" advanced="" technology="" bat="" guidelines="" for="" each="" tier="" consists="" of="" a="" range="" of="" successively="" more="" stringent="" limitations="" and="" permit="" conditions="" that="" represent="" a="" mill's="" progress="" toward="" the="" tier's="" ultimate="" advanced="" technology="" performance="" requirements.="" based="" on="" its="" analysis="" of="" today's="" advanced="" and,="" in="" some="" cases,="" innovative="" technologies="" and="" its="" judgment="" regarding="" the="" historically="" rapid="" advance="" of="" pollution="" prevention="" processes="" in="" this="" industry,="" epa="" has="" determined="" that="" those="" performance="" requirements="" are="" achievable,="" as="" a="" technical="" matter,="" by="" the="" dates="" specified="" in="" each="" tier,="" and="" that="" none="" of="" the="" other="" statutory="" factors="" in="" cwa="" section="" 304(b)(2)(b)="" justify="" selecting="" different="" technology="" bases="" for="" advanced="" technology="" bat.="" epa="" has="" also="" determined="" that="" those="" advanced="" technology="" performance="" requirements="" are="" within="" the="" economic="" capability="" of="" mills="" choosing="" today="" to="" meet="" them="" and="" hence="" are="" economically="" achievable="" for="" those="" mills.="" epa="" bases="" that="" determination="" primarily="" on="" two="" factors.="" first,="" no="" mill="" is="" compelled="" to="" enroll="" in="" the="" voluntary="" advanced="" technology="" incentives="" program;="" accordingly,="" epa="" assumes="" that="" mills="" that="" choose="" to="" enroll--and="" voluntarily="" subject="" themselves="" to="" a="" progression="" of="" [[page="" 18607]]="" successively="" more="" stringent,="" enforceable="" permit="" limits--do="" so="" with="" the="" knowledge="" that="" they="" have="" the="" economic="" as="" well="" as="" technical="" ability="" to="" meet="" those="" limits.="" second,="" the="" experience="" of="" other="" mills="" that="" voluntarily="" undertook="" major="" pollution="" prevention="" projects="" informs="" epa="" that="" the="" ambitious="" performance="" requirements="" are="" indeed="" achievable="" for="" participating="" mills="" if="" the="" incremental="" improvements="" are="" staggered="" over="" time.="" this="" incremental="" approach="" is="" authorized="" by="" cwa="" section="" 301(b)(2)(a),="" which="" expressly="" requires="" bat="" to="" result="" in="" reasonable="" further="" progress="" toward="" the="" national="" goal="" of="" eliminating="" pollutant="" discharges.="" epa="" believes="" that="" each="" of="" the="" steps="" comprising="" the="" three="" tiers="" of="" voluntary="" advanced="" technology="" bat="" limitations="" moves="" participating="" mills="" toward="" that="" national="" goal.="" once="" a="" mill="" enrolls="" in="" the="" voluntary="" advanced="" technology="" incentives="" program,="" it="" accepts="" and="" must="" begin="" immediately="" to="" implement="" a="" bat="" package="" consisting="" of="" successively="" more="" stringent="" permit="" limits="" and="" conditions.="" although="" environmental="" improvements="" are="" realized="" only="" incrementally,="" the="" mill="" is="" subject="" to="" the="" total="" set="" of="" limits--including="" the="" ultimate="" performance="" requirements--as="" soon="" as="" its="" advanced="" technology="" permit="" is="" written="" based="" on="" the="" first="" increment="" of="" that="" bat="" package.="" thus,="" the="" mill="" is="" continuously="" subject="" to="" and="" must="" comply="" immediately="" with="" the="" advanced="" technology="" bat="" package="" as="" it="" progressively="" unfolds,="" including="" each="" interim="" bat="" limitation="" or="" permit="" condition="" representing="" that="" progress.="" epa's="" promulgation="" of="" bat="" as="" a="" package="" of="" progressively="" more="" stringent="" limitations="" and="" conditions="" is="" also="" consistent="" with="" the="" use="" of="" bat="" as="" a="" ``beacon="" to="" show="" what="" is="" possible.''="" kennecott="" v.="" epa,="" 780="" f.2d="" 445,="" 448="" (4th="" cir.="" 1985).="" thus,="" while="" the="" compulsory="" bat="" in="" this="" rule="" functions="" as="" the="" ``base="" level''="" for="" the="" subcategory="" as="" a="" whole,="" see="" e.i.="" du="" pont="" de="" nemours="" &="" co.="" v.="" train,="" 430="" u.s.="" 112,="" 129="" (1977),="" epa="" expects="" the="" voluntary="" advanced="" technology="" bat="" limitations="" to="" drive="" technologies="" and="" mills="" beyond="" that="" base="" level="" toward="" achievement="" of="" the="" goals="" of="" the="" clean="" water="" act.="" by="" holding="" out="" the="" advanced="" technologies="" as="" beacons="" of="" progress,="" epa="" believes="" that="" today's="" rule="" will="" encourage="" more="" mills="" to="" strive="" toward="" epa's="" pollution="" prevention="" and="" reduced="" flow="" objectives="" than="" might="" otherwise="" do="" so="" if="" epa="" promulgated="" nothing="" more="" than="" a="" ``base="" level''="" bat.="" moreover,="" by="" codifying="" progressively="" more="" stringent="" limitations="" in="" today's="" advanced="" technology="" bat="" package,="" epa="" promotes="" a="" form="" of="" technological="" progress="" that="" is="" consistent="" with="" congressional="" intent="" that="" bat="" should="" aspire="" to="" ``increasingly="" higher="" levels="" of="" control.''="" see,="" e.g.,="" statement="" of="" sen.="" muskie="" (oct.="" 4,="" 1972),="" reprinted="" in="" a="" legislative="" history="" of="" the="" water="" pollution="" control="" act="" amendments="" of="" 1972="" (``1972="" leg.="" hist.''),="" at="" 170.="" it="" is="" also="" consistent="" with="" the="" overall="" goals="" of="" the="" act.="" see="" cwa="" section="" 101(a).="" agencies="" have="" considerable="" discretion="" to="" interpret="" their="" statutes="" to="" promote="" congressional="" objectives.="" ``="" `[t]he="" breadth="" of="" agency="" discretion="" is,="" if="" anything,="" at="" zenith="" when="" the="" action="" *="" *="" *="" relates="" primarily="" to="" *="" *="" *="" the="" fashioning="" of="" policies,="" remedies="" and="" sanctions,="" including="" enforcement="" and="" voluntary="" compliance="" programs[,]="" in="" order="" to="" arrive="" at="" maximum="" effectuation="" of="" congressional="" objectives.'="" ''="" u.s.="" steelworkers="" of="" america="" v.="" marshall,="" 647="" f.2d="" 1189,="" 1230-31="" n.64="" (d.c.="" cir.="" 1980)="" (upholding="" osha="" rule="" staggering="" lead="" requirements="" over="" 10="" years)="" (quoting="" niagara="" mohawk="" power="" corp.="" v.="" fpc,="" 379="" f.2d="" 153,="" 159="" (d.c.="" cir.="" 1967)),="" cert.="" denied,="" 453="" u.s.="" 9113="" (1981).="" in="" this="" case,="" the="" codification="" of="" progressively="" more="" stringent="" bat="" limitations="" advances="" not="" only="" the="" general="" goal="" of="" the="" clean="" water="" act,="" but="" also="" the="" explicit="" goal="" of="" the="" bat="" program.="" see="" chevron,="" u.s.a.,="" inc.="" v.="" nrdc,="" 467="" u.s.="" 837,="" 843-44="" (1984).="" moving="" toward="" the="" elimination="" of="" pollutant="" discharges="" in="" stages="" is="" also="" consistent="" with="" overarching="" structure="" of="" the="" effluent="" limitations="" guidelines="" program.="" congress="" originally="" envisioned="" that="" the="" sequence="" of="" attaining="" bpt="" limits="" in="" 1977="" and="" bat="" limits="" in="" 1983="" would="" result="" in="" ``levels="" of="" control="" which="" approach="" and="" achieve="" the="" elimination="" of="" the="" discharge="" of="" pollutants.''="" statement="" of="" sen.="" muskie="" (oct.="" 4,="" 1972),="" reprinted="" in="" 1972="" legislative="" history,="" at="" 170.="" this="" two-step="" approach="" produced="" dramatic="" improvements="" in="" water="" quality,="" but="" did="" not="" achieve="" the="" elimination="" of="" pollutant="" discharges.="" therefore,="" epa="" periodically="" revisits="" and="" revises="" its="" effluent="" limitations="" guidelines="" with="" the="" intention="" each="" time="" of="" making="" further="" progress="" toward="" the="" national="" goal.="" (this="" is="" the="" sixth="" effluent="" limitations="" guideline="" promulgated="" for="" the="" pulp="" and="" paper="" industry,="" and="" the="" fourth="" applicable="" to="" bleached="" papergrade="" kraft="" and="" soda="" mills.)="" achieving="" these="" incremental="" improvements="" through="" successive="" rulemakings="" carries="" a="" substantial="" cost,="" however.="" the="" effluent="" guideline="" rulemaking="" process="" is="" highly="" complex,="" in="" large="" part="" because="" of="" the="" massive="" record="" compiled="" to="" inform="" the="" agency's="" decisions="" and="" because="" of="" the="" substantial="" costs="" associated="" with="" achieving="" each="" additional="" increment="" of="" environmental="" improvement.="" by="" promulgating="" these="" voluntary="" advanced="" technology="" bat="" limitations="" today="" as="" a="" package="" of="" incremental="" environmental="" improvements,="" epa="" hopes="" to="" achieve="" the="" goals="" that="" congress="" envisioned="" for="" the="" bat="" program="" at="" considerably="" less="" cost:="" one="" rulemaking="" that="" looks="" both="" at="" the="" present="" and="" well="" into="" the="" future.="" mills="" willing="" to="" surpass="" today's="" compulsory="" bat="" requirements="" have="" a="" framework="" to="" anticipate="" what="" could="" be="" tomorrow's="" subcategory-wide="" bat="" and="" to="" make="" today's="" environmental,="" financial="" and="" engineering="" judgments="" accordingly.="" thus,="" the="" three-tiered="" incentives="" program="" itself="" represents="" reasonable="" further="" progress="" toward="" the="" goal="" of="" eliminating="" pollutant="" discharges.="" at="" the="" same="" time,="" within="" each="" tier,="" mills="" must="" make="" incremental="" improvements="" that="" also="" represent="" reasonable="" further="" progress="" toward="" that="" national="" goal.="" in="" short,="" each="" bat="" increment,="" whether="" in="" the="" form="" of="" the="" tiers="" themselves="" or="" the="" progressively="" more="" stringent="" limitations="" comprising="" them,="" gives="" contemporary="" meaning="" to="" the="" staging="" process="" originally="" envisioned="" by="" congress="" as="" the="" means="" to="" achieve="" the="" goal="" of="" eliminating="" discharge="" of="" pollutants="" to="" the="" nation's="" waters.="" finally,="" like="" other="" agencies,="" epa="" has="" inherent="" authority="" to="" phase="" in="" regulatory="" requirements="" in="" appropriate="" cases.="" epa="" has="" employed="" this="" authority="" in="" other="" contexts.="" for="" example,="" epa="" recently="" phased="" in,="" over="" two="" years,="" tsca="" rules="" pertaining="" to="" lead-based="" paint="" activities.="" see="" 40="" cfr="" 746.239="" and="" 61="" fr="" 45788,="" 45803="" (aug.="" 29,="" 1996).="" similarly,="" the="" occupational="" safety="" and="" health="" administration="" phased="" in,="" over="" 10="" years,="" a="" series="" of="" progressively="" more="" stringent="" lead-related="" controls.="" see="" 29="" cfr="" 1910.1025="" (1979="" ed.).="" indeed,="" in="" upholding="" that="" rule,="" the="" u.s.="" court="" of="" appeals="" for="" the="" d.c.="" circuit="" noted="" that="" ``the="" extremely="" remote="" deadline="" at="" which="" the="" [sources]="" are="" to="" meet="" the="" final="" [permissible="" exposure="" limits]="" is="" perhaps="" the="" single="" most="" important="" factor="" supporting="" the="" feasibility="" of="" the="" standard.''="" united="" steelworkers="" of="" america="" v.="" marshall,="" 647="" f.2d="" at="" 1278.="" epa="" is="" aware="" that="" cwa="" sections="" 301(b)(2)(c)="" &="" (d)="" require="" bat="" limits="" to="" be="" achieved="" ``in="" no="" case="" later="" than="" three="" years="" after="" the="" date="" such="" limits="" are="" promulgated="" under="" section="" 304(b),="" and="" in="" no="" case="" later="" than="" march="" 31,="" 1989.''="" (section="" 301(b)(2)(f),="" which="" refers="" to="" bat="" limitations="" for="" nonconventional="" pollutants,="" also="" contains="" the="" march="" 31,="" 1989="" date,="" but="" uses="" as="" its="" starting="" point="" the="" date="" the="" limitations="" are="" ``established.'')="" this="" language="" does="" not="" speak="" to="" the="" precise="" question="" epa="" confronts="" here:="" whether="" epa="" can="" [[page="" 18608]]="" promulgate="" voluntary="" advanced="" technology="" bat="" limitations="" that="" are="" phased="" in="" over="" time,="" so="" that="" a="" direct="" discharger="" at="" all="" times="" is="" subject="" to="" and="" must="" comply="" immediately="" with="" the="" particular="" bat="" limitations="" applicable="" to="" them="" at="" any="" given="" point="" in="" time.="" section="" 301(b)(2)="" provides="" no="" clear="" direction.="" epa="" therefore="" is="" charged="" with="" making="" a="" reasonable="" interpretation="" of="" the="" statute="" to="" fill="" the="" gap.="" see="" chevron,="" u.s.a.,="" inc.="" v.="" nrdc,="" 467="" u.s.="" at="" 843-44.="" epa="" believes="" that="" subjecting="" mills="" who="" voluntarily="" enroll="" in="" the="" voluntary="" advance="" technology="" incentives="" program="" to="" progressively="" more="" stringent="" bat="" limitations="" over="" time="" best="" serves="" congress'="" intent="" of="" pushing="" mills="" to="" achieve="" reasonable="" further="" progress="" toward="" eliminating="" all="" pollutant="" discharges.="" it="" also="" ensures="" that="" mills="" achieve="" these="" superior="" performance="" requirements="" at="" a="" pace="" that="" makes="" technical="" and="" economic="" sense.="" finally,="" by="" phasing="" in="" these="" highly="" stringent--but="" elected--="" controls,="" epa="" hopes="" to="" encourage="" more="" mills="" to="" surpass="" the="" bat="" baseline,="" with="" the="" result="" that="" the="" environment="" realizes="" a="" far="" greater="" improvement="" than="" epa="" could="" expect="" to="" see="" without="" this="" phased="" approach.="" for="" these="" reasons,="" epa="" believes="" it="" is="" entitled="" to="" deference="" in="" its="" decision="" to="" promulgate="" voluntary="" advanced="" technology="" bat="" limits="" in="" this="" manner.="" several="" commenters="" supported="" the="" idea="" of="" phasing="" in="" compliance="" with="" bat="" limitations="" for="" the="" purpose="" of="" minimizing="" short-term="" economic="" impacts="" on="" mills,="" but="" urged="" epa="" to="" adopt="" this="" approach="" to="" set="" baseline="" bat="" limits="" based="" on="" the="" model="" tier="" i="" advanced="" technology="" (i.e.,="" bat="" option="" b).="" in="" other="" words,="" these="" commenters="" argued="" that="" more="" stringent="" baseline="" bat="" limits="" based="" on="" the="" tier="" i="" technology="" would="" be="" economically="" achievable="" for="" the="" entire="" subcategory="" because="" affected="" mills="" would="" have="" five="" years="" to="" achieve="" full="" compliance.="" as="" noted="" above,="" epa="" agrees="" that="" the="" advanced="" technologies="" that="" are="" not="" economically="" achievable="" at="" present="" can="" become="" economically="" achievable="" for="" individual="" mills="" that="" voluntarily="" participate="" as="" time="" passes.="" indeed,="" congress="" recognized="" as="" much="" in="" requiring="" epa="" to="" review="" its="" effluent="" guidelines="" and="" to="" revise="" them="" as="" appropriate.="" see="" cwa="" section="" 304(b).="" however,="" epa="" disagrees="" that="" it="" currently="" has="" sufficient="" basis="" on="" the="" record="" available="" today="" to="" compel="" all="" mills="" in="" the="" bleached="" papergrade="" kraft="" and="" soda="" subcategory="" to="" meet="" the="" more="" stringent="" limits="" five="" years="" from="" now.="" in="" this="" rulemaking,="" the="" economic="" achievability="" of="" those="" more="" stringent="" (tier="" i)="" limits="" is="" determined="" by="" the="" voluntary="" investment="" decisions="" of="" the="" affected="" mills;="" because="" of="" the="" voluntary="" nature="" of="" the="" advanced="" technology="" incentives="" program,="" it="" is="" the="" mills,="" not="" epa,="" that="" determine="" that="" particular="" advanced="" technologies="" are="" available="" and="" economically="" achievable="" for="" them="" within="" the="" time="" frames="" provided="" in="" this="" program.="" in="" order="" for="" epa="" to="" impose="" advanced="" technology="" limits="" on="" the="" entire="" subcategory="" as="" the="" commenter="" suggests,="" epa="" would="" need="" to="" find="" adequate="" support="" in="" the="" rulemaking="" record="" today="" that="" compulsory="" bat="" limits="" will="" be="" economically="" achievable="" for="" their="" entire="" subcategory="" five="" years="" from="" now.="" epa="" cannot="" make="" that="" determination="" based="" on="" the="" information="" available="" today.="" at="" best,="" epa="" could="" only="" speculate="" whether="" some="" or="" all="" of="" the="" mills="" projected="" to="" sustain="" the="" most="" severe="" economic="" impacts="" if="" bat="" option="" b="" is="" selected="" would="" be="" able="" to="" avoid="" those="" impacts="" if="" compliance="" with="" that="" bat="" is="" deferred.="" epa="" does="" not="" believe="" that="" this="" type="" of="" speculation="" is="" a="" sufficient="" basis="" for="" compelling="" compliance="" with="" bat="" limits="" that="" are="" not="" economically="" achievable="" today="" for="" the="" subcategory="" as="" a="" whole.="" moreover,="" when="" epa="" estimated="" the="" effects="" of="" deferring="" compliance,="" subcategory-wide,="" for="" five="" years="" in="" response="" to="" these="" comments,="" epa="" concluded="" that="" the="" projected="" impacts="" were="" such="" that,="" even="" then,="" bat="" option="" b="" would="" not="" be="" economically="" achievable="" for="" the="" subcategory="" as="" a="" whole.="" see="" section="" vi.b.5.a(5).="" for="" these="" reasons,="" epa="" concludes="" that="" it="" does="" not="" have="" a="" sufficient="" record="" basis="" today="" to="" make="" tier="" i="" (or="" bat="" option="" b)="" limitations="" the="" compulsory="" baseline="" bat="" even="" if="" such="" limits="" would="" not="" be="" effective="" until="" 2002.="" see="" dcn="" 14392,="" and="" cbi="" documents="" dcn="" 14390="" and="" dcn="" 14391.="" epa="" could="" have="" accomplished="" the="" same="" results="" in="" this="" rulemaking="" simply="" by="" deferring="" the="" effective="" dates="" of="" the="" ultimate="" advanced="" technology="" performance="" objectives="" until="" the="" dates="" specified="" in="" the="" rule="" for="" achievement="" of="" the="" ``stage="" 2''="" limitations.="" epa="" has="" the="" legal="" authority="" to="" defer="" the="" effective="" dates="" of="" the="" ``stage="" 2''="" portion="" of="" the="" advanced="" technology="" bat="" limitations="" in="" this="" manner.="" subject="" to="" the="" minimum="" delays="" imposed="" by="" the="" apa,="" 5="" u.s.c.="" sec.="" 553(d),="" and="" the="" small="" business="" regulatory="" enforcement="" fairness="" act="" (sbrefa),="" 5="" u.s.c.="" sec.="" 801,="" epa="" has="" inherent="" authority="" to="" determine="" the="" effective="" date="" of="" a="" rule="" and="" to="" defer="" the="" effective="" date="" in="" appropriate="" cases.="" see="" asg="" industries,="" inc.="" v.="" consumer="" products="" safety="" comm'n,="" 593="" f.2d="" 1323,="" 1335="" (d.c.="" cir.="" 1979).="" nothing="" in="" the="" clean="" water="" act="" limits="" this="" authority="" with="" respect="" to="" bat="" effluent="" limitations="" guidelines.="" in="" contrast="" to="" section="" 306(b)(1)(b),="" where="" congress="" explicitly="" stated="" that="" new="" source="" performance="" standards,="" ``or="" revisions="" thereof,="" shall="" become="" effective="" upon="" promulgation,''="" the="" cwa="" is="" silent="" regarding="" the="" effective="" date="" of="" bat="" effluent="" limitations="" guidelines.="" having="" failed="" to="" prescribe="" when="" bat="" guidelines="" become="" effective,="" congress="" therefore="" has="" delegated="" to="" the="" agency="" the="" authority="" to="" choose="" the="" appropriate="" effective="" date="" of="" the="" bat="" effluent="" guideline="" limitations="" it="" promulgates,="" so="" long="" as="" the="" agency's="" choice="" is="" consistent="" with="" the="" goals="" and="" purposes="" of="" the="" act.="" see="" chevron,="" u.s.a.,="" inc.="" v.="" nrdc,="" 467="" u.s.="" at="" 843-44,="" 861.="" under="" this="" approach,="" the="" ``stage="" 1''="" limitations="" would="" be="" effective="" immediately,="" and="" the="" ``stage="" 2''="" limitations="" would="" become="" effective="" by="" the="" dates="" specified="" in="" the="" regulation.="" b.="" incentives="" available="" after="" achievement="" of="" advanced="" technology="" bat="" limitations="" and="" nsps="" 1.="" greater="" certainty="" regarding="" permit="" limits="" and="" requirements="" industry="" stakeholders="" have="" suggested="" to="" epa="" that="" mills="" could="" be="" encouraged="" to="" implement="" advanced="" technologies="" if="" they="" had="" a="" reasonable="" assurance="" that="" all="" limitations="" and="" conditions="" in="" their="" permits="" would="" remain="" constant="" over="" a="" specified="" period="" of="" time,="" once="" compliance="" with="" the="" advanced="" technology="" limits="" and="" standards="" is="" achieved.="" under="" this="" incentive,="" epa="" will="" issue="" guidance="" to="" states="" regarding="" the="" reissuance="" of="" npdes="" permits="" held="" by="" mills="" that="" achieve="" all="" of="" their="" advanced="" technology="" bat="" limitations="" or="" nsps.="" (epa="" notes="" that="" new="" sources="" that="" accept="" permit="" limitations="" based="" on,="" and="" commence="" operation="" in="" compliance="" with,="" tier="" ii="" or="" tier="" iii="" nsps="" automatically="" possess="" a="" shield="" against="" more="" stringent="" standards="" of="" performance="" for="" ten="" years="" from="" the="" completion="" of="" construction.)="" in="" its="" forthcoming="" guidance,="" epa="" will="" address="" the="" timing="" of="" reissuing="" advanced="" technology="" npdes="" permits="" and="" the="" limitations="" those="" reissued="" permits="" should="" contain.="" regarding="" the="" reissuance="" of="" advanced="" technology="" npdes="" permits,="" epa="" believes="" that="" permitting="" authorities="" could="" reasonably="" conclude="" that="" an="" advanced="" technology="" npdes="" permit="" held="" by="" a="" mill="" meeting="" all="" of="" its="" tier="" limits="" is="" a="" low="" priority="" for="" permit="" reissuance,="" if="" there="" is="" no="" new="" water="" quality-="" or="" facility-related="" data="" or="" information="" that="" would="" justify="" new="" or="" different="" limits.="" under="" these="" circumstances,="" epa="" believes="" it="" would="" be="" reasonable="" for="" a="" permitting="" authority="" to="" [[page="" 18609]]="" conclude="" that="" that="" permit="" is="" a="" lower="" priority="" for="" reissuance="" because="" the="" mill="" is="" voluntarily="" achieving="" reductions="" greater="" than="" otherwise="" required="" by="" the="" baseline="" bat="" and="" hence="" presents="" a="" lower="" risk="" to="" water="" quality="" than="" other="" mills.="" in="" its="" guidance,="" however,="" epa="" will="" emphasize="" that="" an="" advanced="" technology="" npdes="" permit="" should="" be="" administratively="" extended="" only="" if="" the="" permitting="" authority="" had="" provided="" the="" public="" with="" notice="" (the="" last="" time="" the="" permit="" was="" reissued)="" that="" it="" might="" choose="" to="" extend="" the="" permit="" administratively="" when="" it="" expires.="" thus,="" epa="" expects="" the="" permitting="" authority="" to="" notify="" the="" public="" as="" part="" of="" the="" preceding="" permitting="" process="" of="" the="" circumstances="" under="" which="" it="" would="" regard="" the="" advanced="" technology="" npdes="" permit="" as="" a="" low="" priority="" for="" reissuance="" in="" the="" next="" permitting="" cycle.="" for="" example,="" epa="" expects="" the="" permitting="" authority="" to="" inform="" the="" public="" that="" the="" permit="" probably="" would="" be="" administratively="" extended="" if="" the="" permittee="" has="" achieved="" all="" of="" its="" advanced="" technology="" limitations,="" if="" it="" has="" filed="" a="" timely="" permit="" application,="" and="" if="" the="" permitting="" authority="" possesses="" no="" new="" water="" quality="" or="" facility-related="" data="" that="" would="" justify="" new="" or="" different="" permit="" conditions="" and="" limits.="" in="" addition,="" epa="" expects="" that="" the="" permit="" eligible="" for="" an="" administrative="" extension="" would="" contain="" bmps="" and="" any="" water="" quality-based="" effluent="" limits="" necessary="" to="" achieve="" applicable="" water="" quality="" standards.="" thus,="" epa="" would="" not="" expect="" any="" adverse="" effect="" on="" the="" environment="" during="" the="" period="" the="" permit="" is="" administratively="" extended,="" in="" the="" absence="" of="" specific="" information="" indicating="" that="" more="" stringent="" water="" quality="" effluent="" limits="" need="" to="" be="" imposed.="" the="" forthcoming="" guidance="" will="" also="" address="" the="" types="" of="" limitations="" an="" advanced="" technology="" npdes="" permit="" should="" contain="" when="" it="" is="" reissued="" after="" achievement="" of="" the="" tier="" limitations.="" as="" a="" threshold="" matter,="" the="" permitting="" authority="" will="" need="" to="" determine="" if="" there="" is="" a="" need="" for="" new="" or="" revised="" water="" quality-based="" effluent="" limitations.="" if="" there="" is="" none,="" epa="" encourages="" permitting="" authorities="" to="" promptly="" reissue="" the="" npdes="" permit="" with="" the="" existing="" water="" quality-based="" effluent="" limitations,="" if="" any,="" and="" the="" appropriate="" limitations="" found="" in="" 40="" cfr="" part="" 430.="" in="" some="" cases,="" the="" permitting="" authority="" may="" receive="" new="" facility-="" or="" watershed-="" specific="" information="" indicating="" that="" load="" reductions="" and,="" consequently,="" more="" stringent="" effluent="" limits="" on="" a="" pollutant="" in="" the="" mill's="" wastewater="" are="" necessary="" to="" achieve="" applicable="" water="" quality="" standards="" for="" that="" pollutant.="" under="" these="" circumstances,="" epa="" would="" urge="" states="" to="" develop="" priorities="" for="" allocating="" the="" necessary="" load="" reductions="" in="" a="" way="" that="" gives="" preference="" to="" advanced="" technology="" mills="" over="" all="" other="" subpart="" b="" mills,="" particularly="" where="" advanced="" technology="" mills="" contribute="" a="" small="" portion="" of="" the="" total="" pollutant="" loads="" to="" the="" stream.="" moreover,="" where="" more="" than="" one="" advanced="" technology="" mill="" discharges="" in="" a="" watershed,="" these="" priorities="" would="" further="" give="" preference="" first="" to="" tier="" iii="" mills,="" then="" to="" tier="" ii,="" and="" finally="" to="" tier="" i="" mills.="" 2.="" reduced="" effluent="" monitoring="" epa="" believes="" that="" reduced="" monitoring="" provisions="" are="" appropriate="" for="" ecf="" and="" tcf="" mills="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" and="" is="" including="" them="" in="" the="" today's="" regulation="" for="" mills="" that="" achieve="" voluntary="" advanced="" technology="" bat="" limitations="" or="" nsps,="" as="" appropriate.="" see="" 40="" cfr="" 430.02(c),="" (d)="" and="" (e).="" in="" epa's="" view,="" consistent="" and="" successful="" implementation="" of="" the="" advanced="" technologies="" through="" ecf="" or="" tcf="" processes="" will="" make="" it="" increasingly="" less="" likely="" that="" the="" pollutants="" controlled="" by="" the="" baseline="" bat="" will="" be="" present="" in="" the="" wastewater="" from="" advanced="" technology="" fiber="" lines="" in="" levels="" of="" concern.="" because="" of="" these="" reductions="" and="" because="" monitoring="" for="" these="" pollutants="" tends="" to="" be="" costly,="" epa="" believes="" it="" is="" reasonable="" to="" allow="" mills="" achieving="" the="" voluntary="" advanced="" technology="" bat="" limitations="" or="" nsps="" through="" ecf="" or="" tcf="" processes="" to="" monitor="" less="" frequently="" for="" those="" pollutant="" parameters="" over="" time="" after="" establishing="" a="" reliable="" baseline="" of="" consistent="" achievement="" of="" those="" advanced="" technology="" bat="" limitations="" or="" nsps.="" see="" 40="" cfr="" 430.02(c)-(e).="" to="" qualify="" for="" a="" monitoring="" incentive,="" the="" mill="" must="" certify="" that="" the="" fiber="" line="" is="" tcf="" or="" advanced="" ecf="" either="" as="" part="" of="" their="" permit="" application="" or="" as="" part="" of="" a="" report="" of="" progress="" on="" compliance="" with="" milestones="" established="" to="" achieve="" their="" ultimate="" tier="" limits.="" 40="" cfr="" 430.02(c).="" no="" monitoring="" incentive="" is="" available="" for="" kappa="" number="" or="" flow="" because="" no="" minimum="" monitoring="" frequencies="" are="" being="" established="" by="" this="" regulation.="" epa="" encourages="" permitting="" authorities="" to="" consider="" factors="" such="" as="" the="" reliability="" of="" the="" advanced="" technology="" to="" consistently="" achieve="" or="" exceed="" the="" applicable="" limitations="" and="" performance="" variability="" in="" establishing="" monitoring="" frequencies="" for="" kappa="" number="" and="" flow="" on="" a="" best="" professional="" judgment="" basis.="" the="" monitoring="" incentive="" for="" aox="" applies="" only="" when="" the="" entire="" mill="" is="" ecf="" or="" tcf.="" see="" 40="" cfr="" 430.02(c)="" and="" (d).="" since="" compliance="" with="" aox="" most="" likely="" will="" be="" determined="" at="" the="" end="" of="" the="" pipe,="" the="" monitoring="" requirement="" would="" be="" governed="" by="" the="" fiber="" line="" for="" which="" most="" frequent="" monitoring="" is="" required.="" epa="" retains="" the="" authority="" to="" request="" or="" obtain="" specific="" information="" that="" may="" be="" needed="" to="" determine="" compliance="" with="" the="" requirements="" of="" this="" rule.="" because="" monitoring="" relief="" is="" specified="" to="" be="" available="" by="" the="" date="" compliance="" is="" required,="" even="" if="" the="" limits="" have="" not="" been="" achieved,="" epa="" anticipates="" that="" permitting="" authorities="" will="" exercise="" their="" section="" 308="" authority="" to="" extend="" more="" frequent="" monitoring="" for="" mills="" that="" do="" not="" achieve="" compliance="" with="" their="" limitations.="" epa="" relies="" on="" section="" 308(a)="" of="" the="" clean="" water="" act="" for="" authority="" to="" promulgate="" this="" incentive.="" the="" reduced="" monitoring="" for="" this="" effluent="" limitations="" guideline="" incentive="" program="" is="" being="" incorporated="" in="" the="" code="" of="" federal="" regulations,="" and="" is="" summarized="" as="" follows:="" a.="" for="" tcf="" fiber="" lines="" under="" tiers="" i,="" ii,="" and="" iii,="" no="" monitoring="" incentive="" is="" available="" because="" no="" existing="" tcf="" fiber="" line="" is="" subject="" to="" minimum="" monitoring="" frequencies="" established="" by="" this="" rule.="" see="" 40="" cfr="" 430.02(a).="" epa="" anticipates="" that="" permitting="" authorities="" will="" consider="" the="" monitoring="" for="" aox="" being="" imposed="" on="" mills="" in="" comparable="" tiers,="" and="" the="" additional="" assurance="" of="" compliance="" that="" tcf="" process="" technologies="" afford="" relative="" to="" aox,="" in="" establishing="" monitoring="" frequencies="" on="" a="" best="" professional="" judgment="" basis.="" for="" mills="" that="" use="" tcf="" processes="" part="" of="" the="" time="" and="" ecf="" processes="" for="" the="" remainder,="" epa="" would="" apply="" the="" reduced="" monitoring="" incentive="" applicable="" to="" an="" ecf="" process.="" see="" 40="" cfr="" 430.02(c),="" (d)="" and="" (e).="" b.="" for="" any="" fiber="" line="" enrolled="" under="" tier="" i,="" ii,="" or="" iii="" for="" which="" the="" mill="" certifies="" in="" its="" npdes="" permit="" application="" or="" other="" communication="" to="" the="" permitting="" authority="" that="" it="" employs="" exclusively="" advanced="" ecf="" technologies="" (i.e.,="" extended="" delignification="" or="" other="" technologies="" that="" achieve="" at="" least="" the="" tier="" i="" performance="" levels="" specified="" in="" section="" 430.24(b)(4)(i)),="" the="" minimum="" monitoring="" requirements="" for="" dioxin,="" furan,="" chloroform="" and="" the="" 12="" chlorinated="" phenolic="" pollutants="" will="" be="" suspended="" after="" one="" year="" of="" monitoring="" following="" achievement="" of="" those="" limitations="" and="" standards.="" see="" 40="" cfr="" 430.02(c).="" (these="" limitations="" and="" standards="" must="" be="" achieved="" no="" later="" than="" april="" 15,="" 2004.="" see="" 40="" cfr="" 430.24(b)(3).)="" for="" aox,="" a="" certifying="" advanced="" ecf="" mill="" also="" would="" be="" permitted="" to="" perform="" weekly="" instead="" of="" daily="" monitoring="" for="" one="" year="" after="" achievement="" of="" the="" ultimate="" tier="" bat="" limit="" or="" nsps="" for="" that="" pollutant.="" see="" 40="" [[page="" 18610]]="" cfr="" 430.02(d).="" monitoring="" for="" aox="" once="" per="" month="" would="" be="" permitted="" for="" tier="" i="" ecf="" mills="" for="" four="" years="" beyond="" the="" completion="" of="" that="" one="" year="" period.="" see="" 40="" cfr="" 430.02(e).="" tier="" ii="" ecf="" mills="" would="" be="" permitted="" to="" monitor="" for="" aox="" once="" per="" quarter="" for="" four="" years="" beyond="" the="" completion="" of="" that="" one="" year="" period,="" and="" tier="" iii="" ecf="" mills="" would="" be="" permitted="" to="" monitor="" for="" aox="" once="" per="" year="" for="" four="" years="" beyond="" the="" completion="" of="" that="" one="" year="" period.="" id.="" 3.="" reduced="" inspections="" epa="" will="" issue="" guidance="" to="" epa="" regional="" offices="" indicating="" that="" fiber="" lines="" enrolled="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" and="" achieving="" voluntary="" advanced="" technology="" bat="" limitations="" or="" nsps="" should="" be="" a="" lower="" priority="" than="" other="" npdes="" facilities="" for="" routine="" inspections="" under="" the="" cwa.="" under="" this="" incentive,="" the="" guidance="" would="" recommend="" that="" fiber="" lines="" achieving="" tier="" i="" limits="" receive="" routine="" epa="" inspections="" not="" more="" than="" once="" every="" two="" years;="" fiber="" lines="" achieving="" tier="" ii="" limits="" receive="" routine="" epa="" inspections="" not="" more="" than="" twice="" every="" five="" years;="" and="" fiber="" lines="" achieving="" tier="" iii="" limits="" receive="" routine="" epa="" inspections="" not="" more="" than="" once="" every="" five="" years.="" this="" incentive="" reflects="" epa's="" view="" that="" mills="" installing="" and="" operating="" advanced="" technologies="" at="" levels="" to="" meet="" the="" appropriate="" tier="" effluent="" limitations="" and="" standards="" are="" likely="" to="" be="" complying="" with="" the="" other="" permit="" requirements="" applicable="" to="" that="" fiber="" line.="" furthermore,="" the="" substantial="" reductions="" in="" pollutants="" and="" wastewater="" volumes="" discharged,="" particularly="" by="" mills="" achieving="" tier="" ii="" and="" tier="" iii="" limitations="" and="" standards,="" will="" have="" commensurately="" reduced="" environmental="" impacts.="" epa="" already="" has="" redirected="" federal="" npdes="" inspections="" away="" from="" annual="" inspections="" of="" all="" major="" dischargers="" to="" focus="" on="" high="" risk="" facilities="" in="" priority="" watersheds.="" targeted="" efforts="" in="" these="" priority="" watersheds="" focus="" on="" such="" factors="" as="" facility="" compliance="" status="" and="" rates,="" location="" and="" affected="" population,="" citizen="" complaints,="" etc.="" nonetheless,="" under="" this="" incentive,="" epa="" reserves="" the="" authority="" to="" conduct="" multi-media="" inspections="" without="" prior="" notice,="" and="" to="" inspect="" advanced="" technology="" fiber="" lines="" for="" cause,="" whether="" or="" not="" there="" is="" an="" ongoing="" violation.="" epa="" also="" reserves="" its="" right="" to="" inspect="" an="" advanced="" technology="" mill="" in="" connection="" with="" specific="" watershed="" or="" airshed="" concerns.="" 4.="" public="" recognition="" programs="" epa="" is="" pleased="" to="" have="" the="" opportunity="" to="" implement="" a="" program="" in="" which="" it="" can="" recognize="" facilities="" for="" voluntary="" activities="" that="" achieve="" further="" environmental="" improvements="" beyond="" those="" required="" by="" the="" baseline="" bat="" limitations="" and="" nsps="" promulgated="" today.="" epa's="" intention="" is="" to="" provide="" for="" easily="" administered="" and="" meaningful="" public="" recognition="" for="" mills="" that="" participate="" in="" the="" voluntary="" advanced="" technology="" incentives="" program.="" epa="" will="" accord="" public="" recognition="" to="" mills="" when="" they="" formally="" enroll="" in="" the="" program,="" when="" they="" achieve="" major="" interim="" milestones,="" and="" when="" they="" achieve="" the="" ultimate="" tier="" performance="" requirements.="" the="" applicable="" state="" permitting="" authority="" also="" may="" choose="" to="" separately="" recognize="" a="" pulp="" and="" paper="" mill="" for="" its="" commitments="" and="" achievements="" toward="" further="" environmental="" improvements.="" the="" following="" paragraphs="" describe="" the="" steps="" for="" public="" recognition.="" epa="" will="" issue="" additional="" guidance="" to="" facilitate="" implementation="" of="" this="" incentive.="" a.="" enrolling="" in="" the="" voluntary="" advanced="" technology="" incentives="" program.="" once="" a="" mill="" has="" enrolled="" in="" the="" voluntary="" advanced="" technology="" incentives="" program,="" epa="" will="" issue="" a="" letter="" to="" each="" facility="" acknowledging="" its="" participation="" and="" identifying="" the="" tier="" limits="" (and="" fiber="" line(s)="" as="" appropriate)="" to="" which="" the="" mill="" has="" committed.="" each="" year="" epa="" will="" publish="" a="" federal="" register="" notice="" identifying="" mills="" that="" have="" committed="" to="" the="" program="" within="" the="" previous="" year.="" the="" self-="" selected="" tier="" will="" be="" clearly="" identified,="" as="" will="" any="" other="" pertinent="" information.="" the="" federal="" register="" notice="" will="" be="" made="" available="" on="" the="" epa="" internet="" web="" site.="" b.="" achievement="" of="" milestones.="" each="" time="" a="" mill="" achieves="" a="" major="" milestone="" (particularly="" those="" which="" achieve="" reduction="" in="" effluent="" pollutant="" loadings),="" epa="" will="" recognize="" that="" mill="" in="" its="" annual="" federal="" register="" notice.="" in="" order="" to="" qualify="" for="" this="" recognition,="" each="" mill="" must="" notify="" its="" permitting="" authority="" and="" provide="" supporting="" monitoring="" data="" or="" other="" relevant="" documentation.="" the="" permitting="" authority="" may="" choose="" to="" visit="" the="" site="" for="" verification.="" epa,="" in="" concert="" with="" the="" relevant="" state="" npdes="" programs,="" also="" will="" then="" ascertain="" the="" status="" of="" clean="" water="" act="" compliance="" and="" any="" other="" enforcement="" actions="" prior="" to="" public="" recognition="" activities.="" any="" criminal="" enforcement="" activities,="" particularly="" convictions,="" also="" will="" be="" ascertained.="" this="" information="" on="" compliance="" and="" enforcement="" status="" will="" be="" available="" for="" consideration="" by="" epa="" senior="" management="" prior="" to="" initiation="" of="" public="" recognition="" activities.="" relevant="" information="" on="" enforcement="" and="" compliance="" status="" also="" may="" be="" shared="" as="" appropriate="" with="" senior="" management="" of="" state="" permitting="" agencies="" that="" initiate="" separate="" public="" recognition="" activities.="" public="" recognition="" for="" achieving="" milestones="" will="" continue="" until="" the="" date="" participating="" mills="" are="" required="" to="" achieve="" the="" ultimate="" tier="" performance="" requirements.="" c.="" achievement="" of="" voluntary="" advanced="" technologies="" bat="" limitations="" or="" nsps.="" mills="" that="" achieve="" their="" advanced="" technology="" bat="" limitations="" or="" nsps="" will="" notify="" the="" permitting="" authority="" and="" submit="" supporting="" monitoring="" data="" and="" other="" relevant="" documentation.="" the="" permitting="" authority="" will="" verify="" that="" the="" advanced="" technology="" bat="" limitations="" or="" nsps="" have="" been="" achieved.="" the="" annual="" federal="" register="" notice="" will="" identify="" these="" facilities="" as="" reaching="" their="" goal.="" epa="" also="" will="" participate="" in="" an="" award="" ceremony="" at="" an="" appropriate="" venue="" (e.g.,="" tappi="" environmental="" conference).="" 5.="" reduced="" penalties="" in="" recognition="" of="" the="" considerable="" capital="" expenditures="" that="" mills="" participating="" in="" the="" voluntary="" advanced="" technology="" incentives="" program="" will="" make="" to="" implement="" advanced="" technologies="" and="" to="" achieve="" pollutant="" reductions="" superior="" to="" those="" achievable="" through="" the="" baseline="" bat="" or="" nsps,="" epa="" will="" encourage="" enforcement="" authorities="" to="" take="" into="" account="" those="" investments="" as="" appropriate="" when="" assessing="" penalties="" against="" these="" mills="" for="" violations="" relating="" to="" those="" advanced="" technologies.="" existing="" epa="" settlement="" policies="" provide="" consideration="" of="" advanced="" technology="" investments="" in="" this="" manner.="" in="" epa's="" view,="" if="" a="" facility="" has="" installed="" and="" is="" operating="" the="" advanced="" technology="" in="" good="" faith,="" reports="" violations="" in="" a="" prompt="" manner="" to="" epa="" or="" the="" state,="" and="" either="" corrects="" the="" violations="" in="" a="" timely="" manner="" or="" agrees="" to="" and="" complies="" with="" reasonable="" remedial="" measures="" concurred="" on="" by="" the="" primary="" enforcement="" authority,="" then="" the="" enforcement="" authority="" would="" be="" justified="" in="" taking="" the="" advanced="" technology="" investment="" into="" account="" in="" determining="" economic="" benefit="" and="" in="" reducing="" the="" gravity="" portion="" of="" the="" penalty="" by="" up="" to="" 100="" percent.="" where="" the="" installation="" and="" operation="" of="" any="" advanced="" technology="" was="" more="" expensive="" than="" the="" installation="" and="" operation="" of="" the="" technology="" underlying="" the="" baseline="" bat,="" the="" advanced="" technology="" facilities="" would="" derive="" no="" economic="" benefit="" (i.e.,="" zero="" ben)="" from="" the="" violation="" associated="" with="" the="" advanced="" technology.="" this="" would="" be="" the="" case="" even="" when="" the="" advanced="" technology="" fails,="" as="" long="" as="" the="" design,="" operation="" and="" installation="" are="" within="" [[page="" 18611]]="" applicable="" engineering="" standards="" and="" operational="" procedures="" are="" within="" industry="" norms.="" the="" decision="" whether="" to="" take="" such="" advanced="" technology="" investments="" into="" account="" in="" determining="" economic="" benefit="" would="" be="" left="" to="" the="" state's="" discretion="" when="" the="" state="" is="" the="" enforcing="" authority.="" epa="" will="" issue="" guidance="" to="" clarify="" application="" of="" this="" incentive.="" mills="" also="" can="" take="" advantage="" of="" the="" recently="" issued="" audit="" policy="" providing="" they="" meet="" the="" criteria="" specified="" in="" that="" policy.="" see="" 60="" fr="" 66706="" (dec.="" 22,="" 1995).="" x.="" administrative="" requirements="" and="" related="" government="" acts="" or="" initiatives="" a.="" dockets="" the="" docket="" is="" an="" organized="" and="" complete="" file="" of="" all="" the="" information="" submitted="" to="" or="" otherwise="" considered="" by="" epa="" in="" the="" development="" of="" the="" final="" regulations.="" the="" principal="" purposes="" of="" the="" docket="" are:="" (1)="" to="" allow="" interested="" parties="" to="" readily="" identify="" and="" locate="" documents="" so="" that="" they="" can="" intelligently="" and="" effectively="" participate="" in="" the="" rulemaking="" process;="" and="" (2)="" to="" serve="" as="" the="" record="" in="" case="" of="" judicial="" review,="" except="" for="" intra-agency="" review="" materials="" as="" provided="" for="" in="" section="" 307(d)(7)(a).="" 1.="" air="" dockets="" air="" docket="" no.="" a-92-40="" contains="" information="" considered="" by="" epa="" in="" development="" of="" the="" neshap="" for="" the="" chemical="" wood="" pulping="" mills.="" air="" docket="" no.="" a-95-31="" contains="" information="" considered="" in="" developing="" the="" neshap="" for="" mechanical="" pulping="" processes,="" secondary="" fiber="" pulping="" processes,="" and="" nonwood="" fiber="" pulping="" processes.="" the="" air="" dockets="" are="" available="" for="" public="" inspection="" between="" 8="" a.m.="" and="" 4="" p.m.,="" monday="" through="" friday="" except="" for="" federal="" holidays,="" at="" the="" following="" address:="" u.s.="" environmental="" protection="" agency,="" air="" and="" radiation="" docket="" and="" information="" center="" (mc-6102),="" 401="" m="" street="" sw,="" washington,="" dc="" 20460;="" telephone:="" (202)="" 260-7548.="" the="" dockets="" are="" located="" at="" the="" above="" address="" in="" room="" m-1500,="" waterside="" mall="" (ground="" floor).="" all="" comments="" received="" during="" the="" public="" comment="" period="" on="" the="" 1993="" proposed="" neshap="" are="" contained="" in="" the="" pulp="" and="" paper="" water="" docket="" (see="" following="" paragraph="" for="" location).="" comments="" received="" on="" the="" march="" 8,="" 1996,="" supplemental="" neshap="" notice="" at="" 61="" fr="" 9383="" are="" contained="" in="" air="" dockets="" a-92-40="" and="" a-="" 95-31.="" 2.="" water="" docket="" the="" complete="" public="" record="" for="" the="" effluent="" limitations="" guidelines="" and="" standards="" rulemaking,="" including="" epa's="" responses="" to="" comments="" received="" during="" the="" rulemaking,="" is="" available="" for="" review="" at="" epa's="" water="" docket,="" room="" m2616,="" 401="" m="" street="" sw,="" washington,="" dc="" 20460.="" for="" access="" to="" docket="" materials,="" call="" (202)="" 260-3027.="" the="" docket="" staff="" requests="" that="" interested="" parties="" call="" between="" 9:00="" am="" and="" 3:30="" pm="" for="" an="" appointment="" before="" visiting="" the="" docket.="" the="" epa="" regulations="" at="" 40="" cfr="" part="" 2="" provide="" that="" a="" reasonable="" fee="" may="" be="" charged="" for="" copying="" materials="" from="" the="" air="" and="" water="" dockets.="" epa="" notes="" that="" many="" documents="" in="" the="" record="" supporting="" these="" final="" rules="" have="" been="" claimed="" as="" confidential="" business="" information="" (cbi)="" and,="" therefore,="" are="" not="" included="" in="" the="" record="" that="" is="" available="" to="" the="" public="" in="" the="" air="" and="" water="" dockets.="" to="" support="" the="" rulemaking,="" epa="" is="" presenting="" certain="" information="" in="" aggregated="" form="" or="" is="" masking="" facility="" identities="" to="" preserve="" confidentiality="" claims.="" further,="" the="" agency="" has="" withheld="" from="" disclosure="" some="" data="" not="" claimed="" as="" confidential="" business="" information="" because="" release="" of="" this="" information="" could="" indirectly="" reveal="" information="" claimed="" to="" be="" confidential.="" b.="" executive="" order="" 12866="" and="" omb="" review="" under="" executive="" order="" 12866,="" (58="" fr="" 51735,="" october="" 4,="" 1993),="" the="" agency="" must="" determine="" whether="" the="" regulatory="" action="" is="" ``significant''="" and="" therefore="" subject="" to="" omb="" review="" and="" the="" requirements="" of="" the="" executive="" order.="" the="" order="" defines="" ``significant="" regulatory="" action''="" as="" one="" that="" ``is="" likely="" to="" result="" in="" a="" rule="" that="" may:="" (1)="" have="" an="" annual="" effect="" on="" the="" economy="" of="" $100="" million="" or="" more="" or="" adversely="" affect="" in="" a="" material="" way="" the="" economy,="" a="" sector="" of="" the="" economy,="" productivity,="" competition,="" jobs,="" the="" environment,="" public="" health="" or="" safety,="" or="" state,="" local,="" or="" tribal="" governments="" or="" communities;="" (2)="" create="" a="" serious="" inconsistency="" or="" otherwise="" interfere="" with="" an="" action="" taken="" or="" planned="" by="" another="" agency;="" (3)="" materially="" alter="" the="" budgetary="" impact="" of="" entitlements,="" grants,="" user="" fees,="" or="" loan="" programs="" or="" the="" rights="" and="" obligations="" of="" recipients="" thereof;="" or="" (4)="" raise="" novel="" legal="" or="" policy="" issues="" arising="" out="" of="" legal="" mandates,="" the="" president's="" priorities,="" or="" the="" principles="" set="" forth="" in="" the="" executive="" order.''="" pursuant="" to="" the="" terms="" of="" executive="" order="" 12866,="" it="" has="" been="" determined="" that="" the="" cluster="" rules="" are="" a="" ``significant="" regulatory="" action''="" because="" they="" will="" have="" an="" annual="" effect="" on="" the="" economy="" of="" $100="" million="" or="" more.="" as="" such,="" this="" action="" was="" submitted="" to="" omb="" for="" review.="" changes="" made="" in="" response="" to="" omb="" suggestions="" or="" recommendations="" are="" documented="" in="" the="" public="" record.="" c.="" regulatory="" flexibility="" act="" and="" the="" small="" business="" regulatory="" enforcement="" fairness="" act="" of="" 1996="" (sbrefa)="" under="" the="" regulatory="" flexibility="" act="" (rfa),="" 5="" u.s.c.="" 601="" et="" seq.,="" as="" amended="" by="" sbrefa,="" epa="" generally="" is="" required="" to="" conduct="" a="" regulatory="" flexibility="" analysis="" describing="" the="" impact="" of="" the="" rule="" on="" small="" entities.="" however,="" under="" section="" 605(b)="" of="" the="" rfa,="" epa="" is="" not="" required="" to="" prepare="" the="" regulatory="" flexibility="" analysis="" if="" epa="" certifies="" that="" the="" rule="" will="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" pursuant="" to="" section="" 605(b)="" of="" the="" rfa,="" the="" agency="" certifies="" that="" today's="" final="" cwa="" rule="" will="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" in="" addition,="" epa="" also="" finds="" that="" the="" final="" caa="" rule="" will="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" small="" entities,="" as="" defined,="" include="" small="" businesses,="" small="" governments,="" and="" small="" organizations.="" this="" rulemaking="" does="" not="" affect="" small="" organizations.="" for="" small="" governments,="" these="" rules="" could="" directly="" affect="" administration="" or="" operating="" costs,="" but="" are="" not="" expected="" to="" result="" in="" significant="" impacts="" (see="" section="" x.e.).="" small="" businesses="" are="" the="" remaining="" class="" of="" small="" entity="" affected="" by="" this="" rulemaking.="" for="" small="" businesses,="" epa="" examined="" the="" economic="" impacts="" of="" these="" rules="" in="" detail="" and="" the="" results="" of="" its="" analysis="" are="" found="" in="" the="" ``economic="" analysis''="" (see="" dcn="" 14649).="" the="" following="" is="" a="" brief="" summary="" of="" the="" analysis.="" today's="" cwa="" final="" rule="" will="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities,="" because="" of="" those="" companies="" affected="" by="" the="" cwa="" rule,="" only="" four="" are="" ``a="" small="" business="" concern''="" as="" defined="" by="" sba="" regulations.="" (the="" rfa,="" in="" general,="" requires="" use="" of="" sba="" definitions="" of="" small="" businesses;="" for="" this="" regulation,="" small="" businesses="" are="" defined="" as="" firms="" employing="" no="" more="" than="" 750="" workers.)="" epa="" does="" not="" believe="" this="" is="" a="" substantial="" number="" of="" small="" entities="" as="" that="" term="" is="" used="" in="" the="" rfa.="" moreover,="" while="" all="" four="" small="" business="" concerns="" would="" experience="" increased="" costs="" of="" operation="" as="" a="" result="" of="" today's="" rule,="" the="" costs="" of="" complying="" with="" the="" rule="" are="" also="" not="" significant.="" as="" a="" measure="" of="" the="" economic="" impact="" of="" today's="" requirements="" on="" a="" small="" entity,="" epa="" evaluated="" the="" costs="" of="" the="" rule="" relative="" to="" the="" company's="" annual="" revenues.="" the="" cost="" of="" the="" rule="" only="" exceeded="" one="" percent="" of="" revenues="" for="" one="" of="" the="" facilities="" and="" in="" no="" case="" did="" it="" exceed="" three="" percent.="" [[page="" 18612]]="" when="" the="" costs="" of="" the="" cwa="" rule="" are="" considered="" in="" combination="" with="" the="" costs="" of="" the="" final="" caa="" mact="" i="" and="" mact="" iii="" rules,="" epa's="" conclusion="" does="" not="" change.="" epa's="" analysis="" showed="" that="" the="" combined="" costs="" of="" achieving="" compliance="" with="" the="" final="" air="" and="" water="" rules="" will="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" as="" noted="" above,="" the="" cwa="" rule="" affects="" only="" four="" small="" entities.="" further,="" the="" combined="" costs="" of="" the="" rules="" only="" exceeded="" one="" percent="" of="" revenues="" for="" one="" of="" the="" four="" small="" entities="" covered="" by="" both="" the="" final="" air="" and="" water="" rules,="" and="" for="" no="" small="" entity="" did="" it="" exceed="" three="" percent.="" even="" though="" this="" is="" a="" small="" cost,="" because="" of="" the="" poor="" pre-existing="" economic="" conditions="" at="" one="" facility,="" epa="" projects="" that="" one="" facility="" owned="" by="" one="" of="" the="" small="" firms="" may="" close="" as="" a="" result="" of="" the="" combined="" final="" cwa="" and="" caa="" rules.="" epa="" has="" determined="" that="" one="" closure="" is="" not="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" business="" concerns.="" though="" not="" required="" by="" the="" rfa,="" epa="" also="" examined="" the="" costs="" of="" the="" final="" cwa="" rule="" in="" combination="" with="" the="" costs="" of="" the="" final="" mact="" i="" and="" mact="" iii="" and="" proposed="" mact="" ii="" rules.="" epa's="" analysis="" showed="" that="" the="" combined="" costs="" of="" achieving="" compliance="" with="" the="" final="" air="" and="" water="" rules="" and="" the="" proposed="" mact="" ii="" rule="" would="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" as="" stated="" before,="" only="" four="" small="" entities="" would="" be="" affected.="" the="" combined="" cost="" of="" the="" rules="" would="" only="" exceed="" one="" percent="" of="" revenues="" for="" two="" small="" entities="" and="" for="" no="" small="" entity="" covered="" by="" both="" the="" final="" air="" and="" water="" rules="" and="" the="" proposed="" air="" rule="" would="" it="" exceed="" three="" percent.="" even="" though="" this="" is="" a="" small="" cost,="" because="" of="" the="" poor="" pre-existing="" economic="" conditions="" at="" one="" facility,="" epa="" projects="" that="" one="" facility="" owned="" by="" one="" of="" the="" small="" firms="" may="" close="" as="" a="" result="" of="" the="" final="" cwa="" and="" final="" and="" proposed="" caa="" rules.="" epa's="" assessment="" of="" the="" impacts="" on="" small="" businesses="" subject="" to="" the="" final="" caa="" rules="" yields="" similar="" results.="" epa="" evaluated="" the="" impacts="" of="" the="" costs="" of="" the="" final="" mact="" i="" and="" mact="" iii="" rules="" on="" small="" businesses.="" of="" the="" companies="" affected="" by="" the="" two="" caa="" rules,="" only="" 11="" meet="" the="" sba="" definition="" of="" ``a="" small="" business="" concern.''="" epa="" does="" not="" believe="" this="" is="" a="" substantial="" number="" of="" small="" entities="" as="" that="" term="" is="" used="" in="" the="" rfa.="" epa="" has="" also="" examined="" the="" extent="" of="" the="" impact="" on="" those="" 11="" companies="" and="" finds="" that="" the="" costs="" of="" complying="" with="" the="" final="" mact="" i="" rule="" and="" the="" final="" mact="" iii="" rule="" will="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" in="" evaluating="" the="" costs="" of="" the="" rules="" relative="" to="" the="" company's="" annual="" revenues,="" epa's="" analysis="" shows="" that="" no="" company="" is="" estimated="" to="" incur="" costs="" in="" excess="" of="" one="" percent="" of="" its="" revenues="" as="" a="" result="" of="" implementing="" the="" final="" mact="" i="" and="" mact="" iii="" rules.="" as="" a="" consequence,="" epa="" finds="" that="" the="" caa="" rule="" does="" not="" have="" a="" significant="" economic="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" when="" the="" costs="" of="" the="" final="" mact="" i="" and="" mact="" iii="" rules="" are="" considered="" in="" combination="" with="" the="" costs="" of="" the="" final="" cwa="" rule,="" epa's="" analysis="" shows="" that="" the="" combined="" costs="" of="" achieving="" compliance="" with="" the="" final="" air="" and="" water="" rules="" is="" still="" not="" a="" significant="" impact="" on="" a="" substantial="" number="" of="" small="" entities.="" as="" discussed,="" only="" 11="" small="" business="" concerns="" must="" comply="" with="" the="" caa="" rule.="" of="" these,="" only="" four="" will="" experience="" additional="" costs="" due="" to="" the="" cwa="" rule.="" the="" combined="" costs="" of="" the="" rules="" only="" exceeded="" one="" percent="" of="" revenues="" for="" one="" small="" entity="" covered="" by="" both="" the="" air="" and="" water="" rules,="" and="" for="" no="" small="" entity="" did="" it="" exceed="" three="" percent.="" even="" though="" this="" is="" a="" small="" cost,="" because="" of="" the="" poor="" pre-existing="" economic="" conditions="" at="" one="" facility,="" epa="" projects="" that="" one="" facility="" owned="" by="" one="" of="" the="" small="" firms="" may="" close="" as="" a="" result="" of="" the="" combined="" final="" cwa="" and="" caa="" rules.="" though="" not="" required="" by="" the="" rfa,="" epa="" also="" assessed="" the="" cumulative="" economic="" effect="" on="" small="" entities="" if="" the="" proposed="" mact="" rule="" is="" adopted.="" epa's="" conclusion="" that="" costs="" to="" small="" entities="" are="" not="" great="" does="" not="" change="" when="" the="" costs="" of="" the="" final="" and="" proposed="" mact="" rules="" are="" combined="" with="" the="" costs="" of="" the="" final="" cwa="" rule.="" the="" combined="" cost="" of="" the="" rules="" would="" only="" exceed="" one="" percent="" of="" revenues="" for="" two="" small="" entities="" covered="" by="" both="" the="" final="" air="" and="" water="" rules="" and="" the="" proposed="" air="" rule,="" and="" for="" no="" small="" entity="" would="" it="" exceed="" three="" percent.="" even="" though="" this="" is="" a="" small="" cost,="" because="" of="" the="" poor="" pre-existing="" economic="" conditions="" at="" one="" facility,="" epa="" projects="" that="" one="" facility="" owned="" by="" one="" of="" the="" small="" firms="" may="" close="" as="" a="" result="" of="" the="" combined="" final="" cwa="" and="" caa="" rules.="" d.="" paperwork="" reduction="" act="" the="" information="" collection="" requirements="" in="" the="" air="" emissions="" rules="" have="" been="" submitted="" for="" approval="" to="" the="" office="" of="" management="" and="" budget="" (omb)="" under="" the="" paperwork="" reduction="" act,="" 44="" u.s.c.="" 3501="" et="" seq.="" an="" information="" collection="" request="" (icr)="" document="" has="" been="" prepared="" by="" epa="" (icr="" no.="" 1657.02),="" and="" a="" copy="" may="" be="" obtained="" from="" sandy="" farmer,="" oppe="" regulatory="" information="" division;="" u.s.="" environmental="" protection="" agency="" (2137);="" 401="" m="" st.,="" sw.;="" washington,="" dc="" 20460="" or="" by="" calling="" (202)="" 260-="" 2740.="" the="" information="" requirements="" are="" not="" effective="" until="" omb="" approves="" them.="" the="" information="" required="" to="" be="" collected="" by="" the="" air="" emission="" rules="" is="" needed="" as="" part="" of="" the="" overall="" compliance="" and="" enforcement="" program.="" it="" is="" necessary="" to="" identify="" the="" regulated="" entities="" who="" are="" subject="" to="" the="" rule="" and="" ensure="" their="" compliance="" with="" the="" rule.="" the="" recordkeeping="" and="" reporting="" requirements="" are="" mandatory="" and="" are="" being="" established="" under="" section="" 114="" of="" the="" clean="" air="" act.="" there="" are="" approximately="" 490="" respondents="" that="" are="" potentially="" affected="" by="" the="" air="" emission="" rules.="" all="" 490="" respondents="" must="" submit="" an="" initial="" applicability="" notification.="" of="" the="" 490="" affected="" respondents,="" there="" would="" be="" an="" estimated="" 155="" respondents="" required="" to="" perform="" additional="" information="" collection.="" for="" the="" 155="" respondents,="" this="" collection="" of="" information="" has="" an="" estimated="" total="" annual="" recordkeeping="" and="" reporting="" burden="" averaging="" 320="" hours="" per="" respondent="" during="" the="" first="" three="" years="" after="" promulgation.="" for="" the="" 155="" respondents,="" the="" average="" annualized="" cost="" of="" the="" reporting="" and="" recordkeeping="" burden="" per="" respondent="" is="" $29,600="" for="" the="" first="" three="" years="" following="" promulgation.="" the="" recordkeeping="" and="" reporting="" burden="" means="" the="" total="" time,="" effort,="" or="" financial="" resources="" expended="" by="" persons="" to="" generate,="" maintain,="" retain,="" or="" disclose="" or="" provide="" information="" to="" or="" for="" a="" federal="" agency.="" this="" includes="" the="" time="" needed="" to="" review="" instructions;="" develop,="" acquire,="" install,="" and="" utilize="" technology="" and="" systems="" for="" the="" purposes="" of="" collecting,="" validating,="" and="" verifying="" information,="" processing="" and="" maintaining="" information,="" and="" disclosing="" and="" providing="" information;="" adjust="" the="" existing="" ways="" to="" comply="" with="" any="" previously="" applicable="" instructions="" and="" requirements;="" train="" personnel="" to="" be="" able="" to="" respond="" to="" a="" collection="" of="" information;="" search="" data="" sources;="" complete="" and="" review="" the="" collection="" of="" information;="" and="" transmit="" or="" otherwise="" disclose="" the="" information.="" specifically,="" the="" estimated="" 155="" respondents="" must="" submit="" performance="" test="" notifications,="" statements="" of="" compliance,="" and="" semi-annual="" reports="" of="" monitored="" parameters.="" the="" 155="" respondents="" must="" also="" conduct="" performance="" tests.="" if="" compliance="" exceedances="" occur,="" respondents="" must="" submit="" quarterly="" excess="" emissions="" reports.="" this="" information="" will="" be="" used="" to="" demonstrate="" compliance="" with="" the="" neshap.="" send="" comments="" on="" the="" agency's="" need="" for="" this="" information,="" the="" accuracy="" of="" the="" [[page="" 18613]]="" provided="" burden="" estimates,="" and="" any="" suggested="" methods="" for="" minimizing="" respondent="" burden,="" including="" through="" the="" use="" of="" automated="" collection="" techniques="" to="" the="" director,="" oppe="" regulatory="" information="" division;="" u.s.="" environmental="" protection="" agency="" (2137);="" 401="" m="" st.,="" sw;="" washington,="" dc="" 20460;="" and="" to="" the="" office="" of="" information="" and="" regulatory="" affairs,="" office="" of="" management="" and="" budget,="" 725="" 17th="" st.,="" nw,="" washington,="" dc="" 20503,="" marked="" ``attention:="" desk="" officer="" for="" epa.''="" include="" the="" icr="" number="" in="" any="" correspondence.="" the="" effluent="" limitation="" guidelines="" and="" standards="" promulgated="" today="" contain="" two="" distinct="" information="" collection="" activities,="" i.e.,="" specified="" monitoring="" requirements,="" see="" 40="" cfr="" 430.02,="" and="" development="" of="" bmp="" plans="" and="" related="" monitoring,="" see="" 40="" cfr="" 430.03(c)(4),="" (c)(5),="" (c)(10),="" (d),="" (e),="" (f),="" (g),="" (h)="" and="" (i)(4).="" epa="" will="" seek="" approval="" of="" these="" information="" collection="" requirements="" from="" the="" office="" of="" management="" and="" budget="" (omb)="" under="" the="" paperwork="" reduction="" act,="" 44="" u.s.c.="" 3501="" et="" seq.,="" as="" follows.="" epa="" will="" seek="" to="" amend="" the="" npdes="" discharge="" monitoring="" report="" icr="" no.="" 229,="" omb="" approval="" number="" 2040-0004,="" expiration="" may="" 31,="" 1998,="" to="" add="" specified="" monitoring="" requirements="" for="" direct="" dischargers.="" epa="" will="" seek="" to="" add="" the="" specified="" monitoring="" requirements="" for="" indirect="" dischargers="" by="" amending="" the="" national="" pretreatment="" program="" icr="" no.="" 2,="" omb="" approval="" number="" 2040-0009,="" prior="" to="" its="" expiration="" on="" october="" 31,="" 1999.="" epa="" will="" seek="" approval="" of="" the="" best="" management="" practices="" icr="" no.="" 1829.01="" for="" the="" requirements="" pertaining="" to="" bmp="" plans="" and="" associated="" monitoring.="" epa's="" burden="" estimates="" for="" the="" bmp="" icr="" are="" presented="" for="" comment="" in="" a="" document="" published="" elsewhere="" in="" today's="" federal="" register.="" an="" agency="" may="" not="" conduct="" or="" sponsor,="" and="" a="" person="" is="" not="" required="" to="" respond="" to,="" a="" collection="" of="" information="" unless="" it="" displays="" a="" currently="" valid="" omb="" control="" number.="" the="" omb="" control="" numbers="" for="" epa's="" regulations="" are="" listed="" in="" 40="" cfr="" parts="" 9="" and="" 48="" cfr="" chapter="" 15.="" in="" addition,="" direct="" discharging="" mills="" continue="" to="" be="" required,="" under="" 40="" cfr="" 122.21,="" to="" submit="" certain="" information="" as="" part="" of="" their="" application="" for="" an="" npdes="" permit.="" indirect="" discharging="" mills,="" in="" turn,="" must="" submit="" industrial="" user="" reports="" and="" periodic="" reports="" regarding="" compliance="" with="" categorical="" pretreatment="" standards="" under="" 40="" cfr="" 403.12(b),="" (d),="" and="" (e).="" the="" effluent="" limitations="" guidelines="" and="" standards="" being="" promulgated="" today="" do="" not="" change="" those="" requirements.="" epa="" notes="" that="" mills="" that="" describe="" their="" process="" as="" tcf="" or="" ecf="" under="" 40="" cfr="" 122.21(g)(3)="" or="" 40="" cfr="" 403.12(b),="" (d),="" or="" (e)="" as="" applicable,="" supply="" corroborating="" data="" if="" requested="" by="" the="" permitting="" authority="" under="" 40="" cfr="" 122.21(g)(13),="" and="" comply="" with="" the="" signatory="" and="" certification="" requirements="" in="" 40="" cfr="" 122.22="" or="" 40="" cfr="" 403.12(l)="" as="" applicable="" will="" be="" deemed="" to="" have="" certified="" their="" process="" as="" tcf="" or="" ecf.="" in="" addition,="" direct="" discharging="" mills="" that="" indicate="" under="" 40="" cfr="" 122.21(g)(3)="" and="" (g)(13)="" their="" desire="" to="" participate="" in="" the="" advanced="" technology="" incentives="" program="" and="" comply="" with="" the="" signatory="" and="" certification="" requirements="" in="" 40="" cfr="" 122.22="" or="" 40="" cfr="" 122.23,="" whichever="" is="" applicable,="" will="" be="" deemed="" to="" have="" enrolled="" in="" the="" advanced="" technology="" incentives="" program.="" in="" both="" cases,="" this="" information="" will="" determine="" the="" types="" of="" technology-based="" effluent="" limitations="" and="" standards="" and="" the="" types="" of="" monitoring="" requirements,="" if="" any,="" they="" will="" receive.="" omb="" has="" approved="" the="" existing="" information="" collection="" requirements="" associated="" with="" npdes="" discharge="" permit="" applications="" and="" industrial="" user="" reports="" under="" the="" paperwork="" reduction="" act,="" 44="" u.s.c.="" 3501,="" et="" seq.="" omb="" has="" assigned="" omb="" control="" number="" 2040-0086="" to="" the="" npdes="" permit="" application="" activity="" and="" omb="" control="" numbers="" 2040-0009="" and="" 2040-0150="" to="" the="" reporting="" and="" certification="" requirements="" for="" industrial="" users.="" nothing="" in="" today's="" rule="" changes="" the="" burden="" estimates="" for="" these="" icrs.="" all="" information="" submitted="" to="" the="" epa="" for="" which="" a="" claim="" of="" confidentiality="" is="" made="" will="" be="" safeguarded="" according="" to="" the="" epa="" policies="" set="" forth="" in="" title="" 40,="" chapter="" 1,="" part="" 2,="" subpart="" b--="" confidentiality="" of="" information="" (see="" 40="" cfr="" part="" 2;="" 41="" fr="" 36902,="" september="" 1,="" 1976;="" amended="" by="" 43="" fr="" 39999,="" september="" 8,="" 1978;="" 43="" fr="" 42241,="" september="" 28,="" 1978;="" 44="" fr="" 17674,="" march="" 23,="" 1979).="" e.="" unfunded="" mandates="" reform="" act="" title="" ii="" of="" the="" unfunded="" mandates="" reform="" act="" of="" 1995="" (umra),="" p.l.="" 104-4,="" establishes="" requirements="" for="" federal="" agencies="" to="" assess="" the="" effects="" of="" their="" regulatory="" actions="" on="" state,="" local,="" and="" tribal="" governments="" and="" the="" private="" sector.="" under="" section="" 202="" of="" the="" umra,="" epa="" generally="" must="" prepare="" a="" written="" statement,="" including="" a="" cost-benefit="" analysis,="" for="" proposed="" and="" final="" rules="" with="" ``federal="" mandates''="" that="" may="" result="" in="" expenditures="" to="" state,="" local,="" and="" tribal="" governments,="" in="" the="" aggregate,="" or="" to="" the="" private="" sector,="" of="" $100="" million="" or="" more="" in="" any="" one="" year.="" before="" promulgating="" an="" epa="" rule="" for="" which="" a="" written="" statement="" is="" needed,="" section="" 205="" of="" the="" umra="" generally="" requires="" epa="" to="" identify="" and="" consider="" a="" reasonable="" number="" of="" regulatory="" alternatives="" and="" adopt="" the="" least="" costly,="" most="" cost-effective="" or="" least="" burdensome="" alternative="" that="" achieves="" the="" objectives="" of="" the="" rule.="" the="" provisions="" of="" section="" 205="" do="" not="" apply="" when="" they="" are="" inconsistent="" with="" applicable="" law.="" moreover,="" section="" 205="" allows="" epa="" to="" adopt="" an="" alternative="" other="" than="" the="" least="" costly,="" most="" cost-effective="" or="" least="" burdensome="" alternative="" if="" the="" administrator="" publishes="" with="" the="" final="" rule="" an="" explanation="" why="" that="" alternative="" was="" not="" adopted.="" before="" epa="" establishes="" any="" regulatory="" requirements="" that="" may="" significantly="" or="" uniquely="" affect="" small="" governments,="" including="" tribal="" governments,="" it="" must="" have="" developed="" under="" section="" 203="" of="" the="" umra="" a="" small="" government="" agency="" plan.="" the="" plan="" must="" provide="" for="" notifying="" potentially="" affected="" small="" governments,="" enabling="" officials="" of="" affected="" small="" governments="" to="" have="" meaningful="" and="" timely="" input="" in="" the="" development="" of="" epa="" regulatory="" proposals="" with="" significant="" federal="" intergovernmental="" mandates,="" and="" informing,="" educating,="" and="" advising="" small="" governments="" on="" compliance="" with="" the="" regulatory="" requirements.="" epa="" has="" determined="" that="" today's="" final="" rules="" contain="" a="" federal="" mandate="" that="" may="" result="" in="" expenditures="" of="" $100="" million="" or="" more="" for="" the="" private="" sector="" in="" any="" one="" year.="" accordingly,="" epa="" has="" prepared="" the="" written="" statement="" required="" by="" section="" 202="" of="" the="" umra.="" this="" statement="" is="" contained="" in="" the="" economic="" analysis="" for="" the="" rule="" (dcn="" 14649)="" and="" other="" support="" documents="" and="" is="" summarized="" below.="" in="" addition,="" epa="" has="" determined="" that="" the="" rules="" contain="" no="" regulatory="" requirements="" that="" might="" significantly="" or="" uniquely="" affect="" small="" governments="" and="" therefore="" are="" not="" subject="" to="" the="" requirement="" of="" section="" 203="" of="" the="" umra.="" the="" reasons="" for="" this="" finding="" are="" set="" forth="" below.="" epa="" prepared="" several="" supporting="" analyses="" for="" the="" final="" rules.="" throughout="" this="" preamble="" and="" in="" those="" supporting="" analyses,="" epa="" has="" responded="" to="" the="" umra="" section="" 202="" requirements.="" considerations="" with="" respect="" to="" costs,="" benefits,="" and="" regulatory="" alternatives="" are="" addressed="" in="" the="" economic="" analysis="" (dcn="" 14649),="" which="" is="" summarized="" in="" section="" viii="" of="" this="" preamble.="" a="" very="" brief="" summary="" follows.="" the="" statutory="" authorities="" for="" these="" rules="" are="" found="" in="" section="" 112="" of="" the="" caa="" and="" multiple="" sections="" of="" the="" cwa="" (see="" section="" i="" for="" a="" list).="" in="" part,="" these="" sections="" of="" the="" statutes="" authorize="" and="" direct="" epa="" to="" issue="" regulations="" and="" standards="" to="" address="" air="" emissions="" and="" effluent="" discharges.="" epa="" prepared="" a="" qualitative="" and="" quantitative="" cost-benefit="" assessment="" of="" [[page="" 18614]]="" the="" federal="" requirements="" imposed="" by="" today's="" final="" rules.="" in="" large="" part,="" the="" private="" sector,="" not="" other="" governments,="" will="" incur="" the="" costs.="" specifically,="" the="" costs="" of="" this="" federal="" mandate="" are="" compliance="" costs="" to="" be="" borne="" by="" the="" regulated="" pulp="" and="" paper="" mills.="" in="" addition,="" although="" some="" states="" and="" local="" governments="" will="" incur="" costs="" to="" implement="" the="" standards,="" these="" costs="" to="" governments="" will="" not="" exceed="" the="" thresholds="" established="" by="" umra.="" the="" final="" rules="" are="" not="" expected="" to="" result="" in="" significant="" or="" unique="" impacts="" to="" small="" governments;="" the="" requirements="" are="" consistent="" with="" established="" and="" already-operating="" implementation="" programs.="" epa="" estimates="" that="" the="" total="" annualized="" costs="" for="" the="" private="" sector="" to="" comply="" with="" the="" federal="" mandate="" are="" $351="" million="" (pre-tax)/="" $229="" million="" (post-tax).="" the="" mandate's="" benefits="" are="" primarily="" in="" the="" areas="" of="" reduced="" health="" risks="" and="" improved="" air="" and="" water="" quality.="" the="" economic="" analysis="" (dcn="" 14649)="" describes,="" qualitatively,="" many="" such="" benefits.="" the="" analysis="" then="" quantifies="" a="" subset="" of="" the="" benefits="" and,="" for="" a="" subset="" of="" the="" quantified="" benefits,="" epa="" monetizes="" (i.e.,="" places="" a="" dollar="" value="" on)="" selected="" benefits.="" epa's="" estimates="" of="" the="" monetized="" benefits="" for="" the="" final="" rules="" are="" in="" the="" range="" of="" $39="" to="" $403="" million.="" epa="" does="" not="" believe="" that="" there="" will="" be="" any="" disproportionate="" budgetary="" effects="" of="" the="" rules="" on="" any="" particular="" areas="" of="" the="" country,="" particular="" types="" of="" communities,="" or="" particular="" industry="" segments.="" epa's="" basis="" for="" this="" finding="" is="" its="" analysis="" of="" economic="" impacts,="" which="" is="" summarized="" in="" section="" viii="" of="" the="" preamble="" and="" in="" the="" economic="" analysis="" (dcn="" 14649).="" a="" key="" feature="" of="" that="" analysis="" is="" the="" estimation="" of="" financial="" impacts="" for="" each="" facility="" incurring="" compliance="" costs.="" epa="" considered="" the="" costs,="" impacts,="" and="" other="" effects="" for="" specific="" regions="" and="" individual="" communities,="" and="" found="" no="" disproportionate="" budgetary="" effects.="" although="" these="" final="" rules="" apply="" only="" to="" one="" industry="" segment,="" epa="" found="" no="" disproportionate="" budgetary="" effect.="" (the="" term="" segment="" as="" used="" in="" this="" context="" refers="" to="" the="" industrial="" category="" of="" pulp,="" paper,="" and="" paperboard,="" and="" not="" to="" individual="" subcategories="" within="" that="" category;="" it="" is="" used="" differently="" in="" other="" sections="" of="" this="" preamble.)="" the="" economic="" analysis="" (dcn="" 14649)="" also="" describes="" the="" rules'="" effect="" on="" the="" national="" economy="" in="" terms="" of="" effects="" on="" productivity,="" economic="" growth,="" and="" international="" competitiveness;="" epa="" found="" such="" effects="" to="" be="" minimal.="" although="" epa="" has="" determined="" that="" these="" rules="" do="" not="" contain="" requirements="" that="" might="" significantly="" or="" uniquely="" affect="" any="" state,="" local,="" or="" tribal="" governments="" (see="" chapter="" 7),="" epa="" consulted="" with="" state="" and="" local="" air="" and="" water="" pollution="" control="" officials.="" these="" consultations="" primarily="" pertained="" to="" implementation="" issues="" for="" states="" and="" local="" governments.="" epa's="" evaluation="" of="" their="" comments="" is="" reflected="" in="" the="" final="" rules.="" for="" each="" regulatory="" decision="" in="" today's="" rules,="" epa="" has="" selected="" the="" ``least="" costly,="" most="" cost="" effective,="" or="" least="" burdensome="" alternative''="" that="" was="" consistent="" with="" the="" requirements="" of="" the="" caa="" and="" cwa.="" this="" satisfies="" section="" 205="" of="" the="" umra.="" as="" part="" of="" this="" rulemaking,="" epa="" had="" identified="" and="" considered="" a="" reasonable="" number="" of="" regulatory="" alternatives.="" primarily,="" the="" regulatory="" alternatives="" are="" manufacturing="" processes,="" air="" emission="" controls,="" wastewater="" discharge="" controls,="" and="" other="" technologies.="" many="" of="" the="" alternatives="" are="" described="" above="" in="" section="" vi;="" others="" are="" described="" in="" supporting="" documents.="" the="" agency's="" consideration="" of="" alternatives="" also="" included="" an="" incentives="" program="" to="" encourage="" bleached="" papergrade="" kraft="" and="" soda="" mills="" to="" commit="" to="" pollution="" prevention="" advances="" beyond="" the="" requirements="" of="" the="" federal="" mandate.="" see="" section="" ix.="" the="" agency's="" selection="" from="" among="" these="" alternatives="" is="" consistent="" with="" the="" requirements="" of="" umra,="" in="" terms="" of="" cost,="" cost-effectiveness,="" and="" burden.="" several="" sections="" of="" the="" preamble="" are="" devoted="" to="" describing="" the="" agency's="" rationale="" for="" each="" regulatory="" decision="" (e.g.,="" sections="" vi.b.5.a(5)="" and="" vi.b.6.b(2)).="" finally,="" epa="" has="" considered="" the="" purpose="" and="" intent="" of="" the="" unfunded="" mandates="" reform="" act="" and="" has="" determined="" that="" these="" rules="" are="" needed,="" not="" only="" because="" of="" the="" significant="" pollutant="" reductions="" these="" rules="" will="" achieve,="" see="" section="" vii,="" but="" also="" to="" satisfy="" epa's="" obligations="" under="" the="" consent="" decree="" in="" environmental="" defense="" fund="" and="" natural="" wildlife="" federation="" v.="" thomas,="" see="" section="" ii.c.1.a,="" and="" epa's="" caa="" obligations.="" f.="" pollution="" prevention="" act="" in="" the="" pollution="" prevention="" act="" of="" 1990="" (42="" u.s.c.="" 13101="" et="" seq.,="" public="" law="" 101-508,="" november="" 5,="" 1990),="" congress="" declared="" pollution="" prevention="" the="" national="" policy="" of="" the="" united="" states.="" the="" pollution="" prevention="" act="" declares="" that="" pollution="" should="" be="" prevented="" or="" reduced="" whenever="" feasible;="" pollution="" that="" cannot="" be="" prevented="" or="" reduced="" should="" be="" recycled="" or="" reused="" in="" an="" environmentally="" safe="" manner="" wherever="" feasible;="" pollution="" that="" cannot="" be="" recycled="" should="" be="" treated;="" and="" disposal="" or="" release="" into="" the="" environment="" should="" be="" chosen="" only="" as="" a="" last="" resort.="" today's="" rules="" are="" consistent="" with="" this="" policy.="" as="" described="" in="" section="" vi,="" development="" of="" today's="" rules="" focused="" on="" the="" pollution-="" preventing="" technologies="" that="" some="" segments="" of="" the="" industry="" have="" already="" adopted.="" thus,="" a="" critical="" component="" of="" the="" technology="" bases="" for="" today's="" effluent="" limitations="" guidelines="" and="" standards="" are="" process="" changes="" that="" eliminate="" or="" substantially="" reduce="" the="" formation="" of="" certain="" toxic="" chemicals.="" epa="" also="" employs="" process="" changes="" as="" the="" technology="" basis="" for="" the="" emission="" standards.="" g.="" common="" sense="" initiative="" on="" august="" 19,="" 1994,="" the="" administrator="" established="" the="" common="" sense="" initiative="" (csi)="" council="" in="" accordance="" with="" the="" federal="" advisory="" committee="" act="" (5="" u.s.c.="" appendix="" 2,="" section="" 9="" (c))="" requirements.="" a="" principal="" goal="" of="" the="" csi="" includes="" developing="" recommendations="" for="" optimal="" approaches="" to="" multimedia="" controls="" for="" industrial="" sectors="" including="" petroleum="" refining,="" metal="" plating="" and="" finishing,="" printing,="" electronics="" and="" computers,="" auto="" manufacturing,="" and="" iron="" and="" steel="" manufacturing.="" the="" pulp="" and="" paper="" regulations="" were="" not="" among="" the="" rulemaking="" efforts="" included="" in="" the="" common="" sense="" initiative.="" however,="" many="" of="" the="" csi="" objectives="" have="" been="" incorporated="" into="" these="" final="" rules,="" and="" the="" agency="" intends="" to="" continue="" to="" pursue="" these="" objectives.="" h.="" executive="" order="" 12875="" to="" reduce="" the="" burden="" of="" federal="" regulations="" on="" states="" and="" small="" governments,="" the="" president="" issued="" executive="" order="" 12875="" on="" october="" 28,="" 1993,="" entitled="" enhancing="" the="" intergovernmental="" partnership="" (58="" fr="" 58093).="" in="" particular,="" this="" executive="" order="" requires="" epa="" to="" consult="" with="" representatives="" of="" affected="" state,="" local,="" or="" tribal="" governments.="" while="" these="" rules="" do="" not="" create="" mandates="" upon="" state,="" local,="" or="" tribal="" governments,="" epa="" involved="" state="" and="" local="" governments="" in="" their="" development.="" because="" this="" regulation="" imposes="" costs="" to="" the="" private="" sector="" in="" excess="" of="" $100="" million,="" the="" epa="" pursued="" the="" preparation="" of="" an="" unfunded="" mandates="" statement="" and="" the="" other="" requirements="" of="" the="" unfunded="" mandates="" reform="" act.="" the="" requirements="" are="" met="" as="" presented="" in="" the="" unfunded="" mandate="" s="" section="" above.="" i.="" executive="" order="" 12898="" executive="" order="" 12898="" directs="" federal="" agencies="" to="" ``determine="" whether="" their="" programs,="" policies,="" and="" activities="" have="" [[page="" 18615]]="" disproportionally="" high="" adverse="" human="" health="" or="" environmental="" effects="" on="" minority="" populations="" and="" low-income="" populations.''="" (sec.3-301="" and="" sec.="" 3-302).="" in="" developing="" the="" cluster="" rules,="" epa="" analyzed="" the="" environmental="" justice="" questions="" raised="" by="" these="" rules.="" epa="" conducted="" two="" analyses="" in="" 1996="" to="" comply="" with="" executive="" order="" 12898="" and="" to="" determine="" human="" health="" effects="" on="" minority="" and="" low-income="" populations.="" first,="" in="" a="" comparison="" of="" demographic="" characteristics,="" epa="" found="" that="" there="" is="" no="" significant="" difference="" in="" ethnic="" makeup="" or="" income="" level="" of="" counties="" where="" bleached="" papergrade="" kraft="" and="" soda="" mills="" are="" located="" when="" compared="" to="" the="" states="" in="" which="" they="" are="" located.="" in="" fact,="" of="" the="" twenty-six="" states="" with="" bleached="" papergrade="" kraft="" and="" soda="" mills,="" fifteen="" states="" actually="" have="" lower="" minority="" populations="" (as="" a="" percentage="" of="" overall="" population)="" in="" mill="" counties="" than="" in="" the="" state="" as="" a="" whole,="" and="" sixteen="" states="" have="" a="" lower="" percent="" african-american="" population="" in="" mill="" counties="" than="" in="" their="" respective="" states.="" fifteen="" states="" have="" a="" slightly="" larger="" portion="" of="" the="" population="" living="" below="" the="" poverty="" line="" in="" mill="" counties="" (15="" percent="" average)="" when="" compared="" to="" the="" state="" as="" a="" whole="" (14.1="" percent="" average);="" however,="" when="" epa="" examined="" the="" results="" statistically,="" differences="" examined="" between="" mill="" counties="" and="" total="" state="" populations="" were="" not="" significant.="" therefore,="" epa="" has="" concluded="" that="" the="" regulatory="" decisions="" reflected="" in="" today's="" rules="" will="" not="" have="" a="" disproportionately="" high="" adverse="" human="" health="" or="" environmental="" effect="" on="" minority="" populations="" or="" low-income="" populations.="" second,="" epa="" investigated="" the="" fish="" consumption="" characteristics="" of="" native="" american="" populations="" downstream="" from="" pulp="" and="" paper="" mills.="" of="" the="" 48="" native="" american="" tribes="" downstream="" from="" pulp="" mills,="" eight="" have="" special="" subsistence="" fishing="" rights.="" one="" finding="" from="" epa's="" analysis="" is="" that="" members="" of="" five="" of="" these="" tribes="" have="" elevated="" risks="" of="" contracting="" cancer="" from="" consuming="" fish="" contaminated="" by="" dioxin,="" when="" compared="" to="" the="" general="" population="" and="" recreational="" anglers,="" because="" they="" consume="" fish="" at="" higher="" levels.="" epa="" expects="" the="" final="" rule="" to="" reduce="" substantially="" the="" cancer="" risks="" to="" these="" tribal="" populations,="" as="" discussed="" in="" chapter="" 8="" of="" the="" economic="" analysis="" (dcn="" 14649).="" j.="" submission="" to="" congress="" and="" the="" general="" accounting="" office="" under="" 5="" u.s.c.="" 801(a)(1)(a)="" as="" amended="" by="" the="" small="" business="" regulatory="" enforcement="" fairness="" act="" of="" 1996="" (sbrefa),="" epa="" submitted="" a="" report="" containing="" this="" rule="" and="" other="" required="" information="" to="" the="" u.s.="" senate,="" the="" u.s.="" house="" of="" representatives="" and="" the="" comptroller="" general="" of="" the="" general="" accounting="" office="" prior="" to="" publication="" of="" the="" rule="" in="" today's="" federal="" register.="" this="" rule="" is="" a="" ``major="" rule''="" as="" defined="" by="" 5="" u.s.c.="" 804(2).="" k.="" national="" technology="" transfer="" and="" advancement="" act="" under="" section="" 12(d)="" of="" the="" national="" technology="" transfer="" and="" advancement="" act,="" the="" agency="" is="" required="" to="" use="" voluntary="" consensus="" standards="" in="" its="" regulatory="" and="" procurement="" activities="" unless="" to="" do="" so="" would="" be="" inconsistent="" with="" applicable="" law="" or="" otherwise="" impractical.="" voluntary="" consensus="" standards="" are="" technical="" standards="" (e.g.,="" materials="" specifications,="" test="" methods,="" sampling="" procedures,="" business="" practices,="" etc.)="" which="" are="" developed="" or="" adopted="" by="" voluntary="" consensus="" standards="" bodies.="" where="" available="" and="" potentially="" applicable="" voluntary="" consensus="" standards="" are="" not="" used="" by="" epa,="" the="" act="" requires="" the="" agency="" to="" provide="" congress,="" through="" the="" office="" of="" management="" and="" budget,="" an="" explanation="" of="" the="" reasons="" for="" not="" using="" such="" standards.="" this="" section="" summarizes="" epa's="" response="" to="" the="" requirements="" of="" the="" nttaa="" for="" the="" analytical="" test="" methods="" promulgated="" as="" part="" of="" today's="" effluent="" limitations="" guidelines="" and="" standards.="" epa's="" analytical="" test="" method="" development="" is="" consistent="" with="" the="" requirements="" of="" the="" nttaa.="" although="" the="" agency="" initiated="" data="" collection="" for="" these="" effluent="" guidelines="" many="" years="" prior="" to="" enactment="" of="" the="" nttaa,="" traditionally,="" analytical="" test="" method="" development="" has="" been="" analogous="" to="" the="" act's="" requirements="" for="" consideration="" and="" use="" of="" voluntary="" consensus="" standards.="" epa="" performed="" extensive="" literature="" searches="" to="" identify="" any="" analytical="" methods="" from="" industry,="" academia,="" voluntary="" consensus="" standards="" bodies="" and="" other="" parties="" that="" could="" be="" used="" to="" measure="" the="" analytes="" in="" today's="" rulemaking.="" the="" results="" of="" this="" search="" formed="" the="" basis="" for="" epa's="" analytical="" method="" development="" and="" validation="" in="" support="" of="" this="" rulemaking.="" two="" new="" analytical="" test="" methods="" are="" being="" promulgated="" in="" today's="" final="" rule="" (see="" section="" vi.b.4).="" the="" first="" method="" is="" epa="" method="" 1650="" for="" determination="" of="" adsorbable="" organic="" halides="" (aox).="" development="" of="" method="" 1650="" began="" in="" 1989="" to="" support="" data="" gathering="" for="" regulation="" of="" pulp="" and="" paper="" industry="" discharges.="" this="" method="" was="" developed="" by="" combining="" various="" procedures="" contained="" in="" methods="" from="" voluntary="" consensus="" standards="" bodies="" and="" other="" standards="" developing="" organizations="" such="" as="" german="" din="" standard="" 38="" 409,="" international="" standard="" organization="" (iso)="" method="" 9562,="" scandinavian="" method="" scan-w="" 9:89,="" standard="" method="" 5320="" (published="" jointly="" by="" the="" american="" public="" health="" association,="" the="" american="" water="" works="" association="" and="" the="" water="" environment="" federation),="" a="" method="" published="" by="" environment="" canada,="" epa's="" method="" 9020="" and="" epa's="" interim="" method="" 450.1.="" the="" foreign="" and="" international="" methods="" all="" employed="" the="" batch="" adsorption="" technique="" for="" determination="" of="" aox;="" the="" u.s.="" methods="" all="" employed="" the="" column="" technique.="" nearly="" all="" data="" collected="" by="" the="" paper="" industry="" and="" others="" prior="" to="" development="" of="" method="" 1650="" were="" gathered="" using="" the="" column="" technique.="" method="" 1650="" allows="" use="" of="" both="" the="" batch="" and="" column="" techniques="" but="" contains="" restrictions="" on="" the="" batch="" technique="" specific="" to="" paper="" industry="" wastewaters,="" as="" detailed="" in="" the="" method="" and="" as="" described="" above="" in="" section="" vi.b.4="" and="" in="" epa's="" responses="" to="" public="" comments="" (dcn="" 14497,="" vol.="" vii).="" in="" addition="" to="" the="" differences="" between="" adsorption="" techniques,="" none="" of="" the="" existing="" methods,="" including="" those="" in="" voluntary="" consensus="" standards,="" contained="" the="" standardized="" quality="" control="" (qc)="" and="" qc="" acceptance="" criteria="" that="" epa="" requires="" for="" data="" verification="" and="" validation="" in="" its="" water="" programs.="" epa="" is="" therefore="" promulgating="" the="" new="" epa="" method="" 1650.="" epa="" is="" also="" promulgating="" epa="" method="" 1653="" for="" determination="" of="" chlorinated="" phenolics.="" development="" of="" method="" 1653="" also="" began="" in="" 1989="" to="" support="" data="" gathering="" for="" regulation="" of="" pulp="" and="" paper="" industry="" discharges.="" this="" method="" was="" developed="" using="" national="" council="" of="" the="" paper="" industry="" for="" air="" and="" stream="" improvement="" (ncasi)="" methods="" cp85.01="" and="" cp86.01="" as="" a="" starting="" point="" and="" adding="" the="" necessary="" standardized="" qc="" and="" qc="" acceptance="" criteria.="" epa="" method="" 1653="" and="" the="" ncasi="" methods="" employ="" in-situ="" derivatization="" to="" assure="" that="" only="" chlorophenolics="" are="" derivatized="" and="" measured.="" the="" in-situ="" derivatization="" technique="" allows="" only="" chlorophenolics="" to="" be="" derivatized="" in="" the="" effluent="" and="" leaves="" behind="" interfering="" analytes.="" this="" condition="" is="" necessary="" for="" accurate="" measurement="" of="" the="" relevant="" analytes.="" voluntary="" consensus="" standards="" methods="" were="" not="" available="" for="" chlorophenolics="" by="" in-situ="" derivatization.="" epa="" is="" therefore="" promulgating="" the="" new="" epa="" method="" 1653.="" dischargers="" are="" also="" required="" to="" monitor="" for="" 2,3,7,8-="" tetrachlorodibenzo-p-dioxin="" (dioxin;="" tcdd;="" 2,3,7,8-tcdd),="" 2,3,7,8-="" tetrachlorodibenzofuran="" (tcdf;="" [[page="" 18616]]="" 2,3,7,8-tcdf),="" chloroform,="" biochemical="" oxygen="" demand="" (bod),="" and="" total="" suspended="" solids="" (tss).="" methods="" for="" monitoring="" these="" pollutants="" are="" specified="" in="" tables="" at="" 40="" cfr="" part="" 136.="" when="" available,="" methods="" published="" by="" voluntary="" consensus="" standards="" bodies="" are="" included="" in="" the="" list="" of="" approved="" methods="" in="" these="" tables.="" specifically,="" voluntary="" consensus="" standards="" are="" approved="" for="" the="" determination="" of="" chloroform,="" bod,="" and="" tss="" (from="" the="" 18th="" edition="" of="" standard="" methods).="" in="" addition,="" usgs="" methods="" are="" approved="" for="" bod="" and="" tss.="" for="" tcdd="" and="" tcdf,="" epa="" is="" specifying="" the="" use="" of="" epa="" method="" 1613,="" promulgated="" at="" 62="" fr="" 48394="" (september="" 15,="" 1997).="" this="" method="" was="" developed="" to="" support="" data="" gathering="" for="" regulation="" of="" pulp="" and="" paper="" industry="" discharges="" and="" incorporates="" procedures="" from="" epa,="" academia,="" industry="" (ncasi="" and="" the="" dow="" chemical="" co.)="" and="" a="" commercial="" laboratory.="" there="" were="" no="" voluntary="" consensus="" standards="" methods="" available="" for="" these="" pollutants="" by="" high="" resolution="" gas="" chromatography="" (hrgc)="" coupled="" with="" high="" resolution="" mass="" spectrometry="" (hrms)="" at="" the="" time="" epa="" method="" 1613="" was="" developed.="" both="" hrgc="" and="" hrms="" are="" required="" to="" separately="" detect="" and="" measure="" dioxin="" and="" furan="" isomers="" at="" low="" concentrations="" (i.e.,="" low="" parts="" per="" quadrillion="" (ppq)).="" high="" resolution="" techniques="" are="" necessary="" to="" conduct="" the="" assay="" in="" the="" presence="" of="" interfering="" analytes.="" epa="" is="" unaware="" of="" the="" existence="" of="" an="" hrgc/hrms="" method="" from="" a="" voluntary="" consensus="" standards="" body="" for="" determination="" of="" tcdd="" and="" tcdf="" in="" the="" low="" ppq="" range="" in="" pulp="" and="" paper="" industry="" discharges.="" xi.="" background="" documents="" the="" summary="" of="" public="" comments="" and="" agency="" responses="" and="" the="" environmental="" impacts="" statement="" for="" the="" neshap="" are="" contained="" in="" the="" final="" background="" information="" document="" (bid).="" a="" paper="" copy="" of="" the="" final="" background="" information="" document="" for="" the="" neshap="" may="" be="" obtained="" from="" the="" u.s.="" epa="" library="" (md-35),="" research="" triangle="" park,="" north="" carolina="" 27711,="" telephone="" (919)="" 541-2777;="" or="" from="" the="" national="" technical="" information="" services,="" 5285="" port="" royal="" road,="" springfield,="" virginia="" 22151,="" telephone="" (703)="" 487-4650.="" to="" obtain="" the="" final="" background="" information="" document,="" please="" refer="" to="" ``pulp,="" paper,="" and="" paperboard="" industry--background="" information="" for="" promulgated="" air="" emission="" standards,="" manufacturing="" processes="" at="" kraft,="" sulfite,="" soda,="" semi-chemical,="" mechanical,="" and="" secondary="" and="" non-wood="" fiber="" mills,="" final="" eis''="" (epa-453/r-93-050b).="" an="" electronic="" copy="" of="" the="" final="" background="" information="" document="" is="" available="" from="" the="" technology="" transfer="" network="" described="" in="" the="" supplementary="" information="" section="" of="" this="" document.="" documents="" supporting="" the="" effluent="" limitations="" guidelines="" and="" standards="" may="" be="" obtained="" by="" contacting="" the="" national="" technical="" information="" services,="" 5285="" port="" royal="" road,="" springfield,="" virginia="" 22151,="" telephone="" (703)="" 487-4650.="" epa's="" technical="" conclusions="" concerning="" the="" wastewater="" regulations="" are="" detailed="" in="" the="" ``supplemental="" technical="" development="" document="" for="" effluent="" limitations="" guidelines="" and="" standards="" for="" the="" pulp,="" paper,="" and="" paperboard="" point="" source="" category''="" (epa-821-r-97-011,="" dcn="" 14487).="" the="" agency's="" economic="" analysis="" is="" found="" in="" the="" ``economic="" analysis="" for="" the="" national="" emissions="" standards="" for="" hazardous="" air="" pollutants="" for="" source="" category:="" pulp="" and="" paper="" production;="" effluent="" limitations="" guidelines,="" pretreatment="" standards,="" and="" new="" source="" performance="" standards="" for="" the="" pulp,="" paper,="" and="" paperboard="" industry--phase="" i,''="" referred="" to="" as="" the="" economic="" analysis="" (epa-821-r-97-012,="" dcn="" 14649).="" this="" document="" also="" includes="" an="" analysis="" of="" the="" incremental="" costs="" and="" pollutant="" removals="" for="" the="" effluent="" regulations.="" analytical="" methods="" used="" in="" the="" development="" of="" the="" effluent="" guidelines="" are="" found="" in="" ``analytical="" methods="" for="" the="" determination="" of="" pollutants="" in="" pulp="" and="" paper="" industry="" wastewater,''="" a="" compendium="" of="" analytical="" methods="" (epa="" 821-b-97-00).="" the="" environmental="" assessment="" is="" presented="" in="" the="" ``water="" quality="" assessment="" of="" final="" effluent="" limitations="" guidelines="" for="" the="" papergrade="" sulfite="" and="" bleached="" papergrade="" kraft="" and="" soda="" subcategories="" of="" the="" pulp,="" paper,="" and="" paperboard="" industry''="" (epa-823-r-97-009,="" dcn="" 14650).="" the="" statistical="" analyses="" used="" in="" this="" rulemaking="" are="" detailed="" in="" the="" ``statistical="" support="" document="" for="" the="" pulp="" and="" paper="" industry:="" subpart="" b''="" (dcn="" 14496).="" the="" best="" management="" practices="" program="" is="" presented="" in="" ``technical="" support="" document="" for="" best="" management="" practices="" for="" spent="" pulping="" liquor="" management,="" spill="" prevention,="" and="" control="" (dcn="" 14489),="" also="" referred="" to="" as="" the="" bmp="" technical="" support="" document.="" the="" advanced="" technology="" incentives="" program="" is="" presented="" in="" the="" ``technical="" support="" document="" for="" the="" voluntary="" advanced="" technology="" incentives="" program,''="" (epa-821-r-97-014,="" dcn="" 14488).="" list="" of="" subjects="" 40="" cfr="" part="" 63="" environmental="" protection,="" air="" pollution="" control,="" hazardous="" substances,="" reporting="" and="" recordkeeping="" requirements.="" 40="" cfr="" part="" 261="" hazardous="" waste,="" recycling,="" reporting="" and="" recordkeeping="" requirements.="" 40="" cfr="" part="" 430="" paper="" and="" paper="" products="" industry,="" reporting="" and="" recordkeeping="" requirements,="" waste="" treatment="" and="" disposal,="" water="" pollution="" control.="" dated:="" november="" 14,="" 1997.="" carol="" m.="" browner,="" administrator.="" for="" the="" reasons="" set="" out="" in="" the="" preamble,="" title="" 40,="" chapter="" i="" of="" the="" code="" of="" federal="" regulations="" is="" amended="" as="" follows:="" part="" 63--national="" emission="" standards="" for="" hazardous="" air="" pollutants="" for="" source="" categories="" 1.="" the="" authority="" citation="" for="" part="" 63="" continues="" to="" read="" as="" follows:="" authority:="" 42="" u.s.c.="" 7401,="" et="" seq.="" 2.="" part="" 63="" is="" amended="" by="" adding="" subpart="" s="" to="" read="" as="" follows:="" subpart="" s--national="" emission="" standards="" for="" hazardous="" air="" pollutants="" from="" the="" pulp="" and="" paper="" industry="" sec.="" 63.440="" applicability.="" 63.441="" definitions.="" 63.442="" [reserved]="" 63.443="" standards="" for="" the="" pulping="" system="" at="" kraft,="" soda,="" and="" semi-="" chemical="" processes.="" 63.444="" standards="" for="" the="" pulping="" system="" at="" sulfite="" processes.="" 63.445="" standards="" for="" the="" bleaching="" system.="" 63.446="" standards="" for="" kraft="" pulping="" process="" condensates.="" 63.447="" clean="" condensate="" alternative.="" 63.448-63.449="" [reserved]="" 63.450="" standards="" for="" enclosures="" and="" closed-vent="" systems.="" 63.451-63.452="" [reserved]="" 63.453="" monitoring="" requirements.="" 63.454="" recordkeeping="" requirements.="" 63.455="" reporting="" requirements.="" 63.456="" [reserved]="" 63.457="" test="" methods="" and="" procedures.="" 63.458="" delegation="" of="" authority.="" 63.459="" [reserved]="" [[page="" 18617]]="" table="" 1="" to="" subpart="" s.--general="" provisions="" applicability="" to="" subpart="" s="" subpart="" s--national="" emission="" standards="" for="" hazardous="" air="" pollutants="" from="" the="" pulp="" and="" paper="" industry="" sec.="" 63.440="" applicability.="" (a)="" the="" provisions="" of="" this="" subpart="" apply="" to="" the="" owner="" or="" operator="" of="" processes="" that="" produce="" pulp,="" paper,="" or="" paperboard;="" that="" are="" located="" at="" a="" plant="" site="" that="" is="" a="" major="" source="" as="" defined="" in="" sec.="" 63.2="" of="" subpart="" a="" of="" this="" part;="" and="" that="" use="" the="" following="" processes="" and="" materials:="" (1)="" kraft,="" soda,="" sulfite,="" or="" semi-chemical="" pulping="" processes="" using="" wood;="" or="" (2)="" mechanical="" pulping="" processes="" using="" wood;="" or="" (3)="" any="" process="" using="" secondary="" or="" non-wood="" fibers.="" (b)="" the="" affected="" source="" to="" which="" the="" existing="" source="" provisions="" of="" this="" subpart="" apply="" is="" as="" follows:="" (1)="" for="" the="" processes="" specified="" in="" paragraph="" (a)(1)="" of="" this="" section,="" the="" affected="" source="" is="" the="" total="" of="" all="" hap="" emission="" points="" in="" the="" pulping="" and="" bleaching="" systems;="" or="" (2)="" for="" the="" processes="" specified="" in="" paragraphs="" (a)(2)="" or="" (a)(3)="" of="" this="" section,="" the="" affected="" source="" is="" the="" total="" of="" all="" hap="" emission="" points="" in="" the="" bleaching="" system.="" (c)="" the="" new="" source="" provisions="" of="" this="" subpart="" apply="" to="" the="" total="" of="" all="" hap="" emission="" points="" at="" new="" or="" existing="" sources="" as="" follows:="" (1)="" each="" affected="" source="" defined="" in="" paragraph="" (b)(1)="" of="" this="" section="" that="" commences="" construction="" or="" reconstruction="" after="" december="" 17,="" 1993;="" (2)="" each="" pulping="" system="" or="" bleaching="" system="" for="" the="" processes="" specified="" in="" paragraph="" (a)(1)="" of="" this="" section="" that="" commences="" construction="" or="" reconstruction="" after="" december="" 17,="" 1993;="" (3)="" each="" additional="" pulping="" or="" bleaching="" line="" at="" the="" processes="" specified="" in="" paragraph="" (a)(1)="" of="" this="" section,="" that="" commences="" construction="" after="" december="" 17,="" 1993;="" (4)="" each="" affected="" source="" defined="" in="" paragraph="" (b)(2)="" of="" this="" section="" that="" commences="" construction="" or="" reconstruction="" after="" march="" 8,="" 1996;="" or="" (5)="" each="" additional="" bleaching="" line="" at="" the="" processes="" specified="" in="" paragraphs="" (a)(2)="" or="" (a)(3)="" of="" this="" section,="" that="" commences="" construction="" after="" march="" 8,="" 1996.="" (d)="" each="" existing="" source="" shall="" achieve="" compliance="" no="" later="" than="" april="" 16,="" 2001,="" except="" as="" provided="" in="" paragraphs="" (d)(1)="" through="" (d)(3)="" of="" this="" section.="" (1)="" each="" kraft="" pulping="" system="" shall="" achieve="" compliance="" with="" the="" pulping="" system="" provisions="" of="" sec.="" 63.443="" for="" the="" equipment="" listed="" in="" sec.="" 63.443(a)(1)(ii)="" through="" (a)(1)(v)="" as="" expeditiously="" as="" practicable,="" but="" in="" no="" event="" later="" than="" april="" 17,="" 2006="" and="" the="" owners="" and="" operators="" shall="" establish="" dates,="" update="" dates,="" and="" report="" the="" dates="" for="" the="" milestones="" specified="" in="" sec.="" 63.455(b).="" (2)="" each="" dissolving-grade="" bleaching="" system="" at="" either="" kraft="" or="" sulfite="" pulping="" mills="" shall="" achieve="" compliance="" with="" the="" bleach="" plant="" provisions="" of="" sec.="" 63.445="" of="" this="" subpart="" as="" expeditiously="" as="" practicable,="" but="" in="" no="" event="" later="" than="" 3="" years="" after="" the="" promulgation="" of="" the="" revised="" effluent="" limitation="" guidelines="" and="" standards="" under="" 40="" cfr="" 430.14="" through="" 430.17="" and="" 40="" cfr="" 430.44="" through="" 430.47.="" (3)="" each="" bleaching="" system="" complying="" with="" the="" voluntary="" advanced="" technology="" incentives="" program="" for="" effluent="" limitation="" guidelines="" in="" 40="" cfr="" 430.24,="" shall="" comply="" with="" the="" requirements="" specified="" in="" either="" paragraph="" (d)(3)(i)="" or="" (d)(3)(ii)="" of="" this="" section="" for="" the="" effluent="" limitation="" guidelines="" and="" standards="" in="" 40="" cfr="" 430.24.="" (i)="" comply="" with="" the="" bleach="" plant="" provisions="" of="" sec.="" 63.445="" of="" this="" subpart="" as="" expeditiously="" as="" practicable,="" but="" in="" no="" event="" later="" than="" april="" 16,="" 2001.="" (ii)="" comply="" with="" all="" of="" the="" following:="" (a)="" the="" owner="" or="" operator="" of="" a="" bleaching="" system="" shall="" comply="" with="" the="" bleach="" plant="" provisions="" of="" sec.="" 63.445="" of="" this="" subpart="" as="" expeditiously="" as="" practicable,="" but="" in="" no="" event="" later="" than="" april="" 15,="" 2004.="" (b)="" the="" owner="" or="" operator="" of="" a="" bleaching="" system="" shall="" not="" increase="" the="" application="" rate="" of="" chlorine="" or="" hypochlorite="" in="" kg="" of="" bleaching="" agent="" per="" megagram="" of="" odp,="" in="" the="" bleaching="" system="" above="" the="" average="" daily="" rates="" used="" over="" the="" three="" months="" prior="" to="" june="" 15,="" 1998="" until="" the="" requirements="" of="" paragraph="" (d)(3)(ii)(a)="" of="" this="" section="" are="" met="" and="" record="" application="" rates="" as="" specified="" in="" sec.="" 63.454(c).="" (c)="" owners="" and="" operators="" shall="" establish="" dates,="" update="" dates,="" and="" report="" the="" dates="" for="" the="" milestones="" specified="" in="" sec.="" 63.455(b).="" (e)="" each="" new="" source,="" specified="" as="" the="" total="" of="" all="" hap="" emission="" points="" for="" the="" sources="" specified="" in="" paragraph="" (c)="" of="" this="" section,="" shall="" achieve="" compliance="" upon="" start-up="" or="" june="" 15,="" 1998,="" whichever="" is="" later,="" as="" provided="" in="" sec.="" 63.6(b)="" of="" subpart="" a="" of="" this="" part.="" (f)="" each="" owner="" or="" operator="" of="" an="" affected="" source="" with="" affected="" process="" equipment="" shared="" by="" more="" than="" one="" type="" of="" pulping="" process,="" shall="" comply="" with="" the="" applicable="" requirement="" in="" this="" subpart="" that="" achieves="" the="" maximum="" degree="" of="" reduction="" in="" hap="" emissions.="" (g)="" each="" owner="" or="" operator="" of="" an="" affected="" source="" specified="" in="" paragraphs="" (a)="" through="" (c)="" of="" this="" section="" must="" comply="" with="" the="" requirements="" of="" subpart="" a--general="" provisions="" of="" this="" part,="" as="" indicated="" in="" table="" 1="" to="" this="" subpart.="" sec.="" 63.441="" definitions.="" all="" terms="" used="" in="" this="" subpart="" shall="" have="" the="" meaning="" given="" them="" in="" the="" caa,="" in="" subpart="" a="" of="" this="" part,="" and="" in="" this="" section="" as="" follows:="" acid="" condensate="" storage="" tank="" means="" any="" storage="" tank="" containing="" cooking="" acid="" following="" the="" sulfur="" dioxide="" gas="" fortification="" process.="" black="" liquor="" means="" spent="" cooking="" liquor="" that="" has="" been="" separated="" from="" the="" pulp="" produced="" by="" the="" kraft,="" soda,="" or="" semi-chemical="" pulping="" process.="" bleaching="" means="" brightening="" of="" pulp="" by="" the="" addition="" of="" oxidizing="" chemicals="" or="" reducing="" chemicals.="" bleaching="" line="" means="" a="" group="" of="" bleaching="" stages="" arranged="" in="" series="" such="" that="" bleaching="" of="" the="" pulp="" progresses="" as="" the="" pulp="" moves="" from="" one="" stage="" to="" the="" next.="" bleaching="" stage="" means="" all="" process="" equipment="" associated="" with="" a="" discrete="" step="" of="" chemical="" application="" and="" removal="" in="" the="" bleaching="" process="" including="" chemical="" and="" steam="" mixers,="" bleaching="" towers,="" washers,="" seal="" (filtrate)="" tanks,="" vacuum="" pumps,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" bleaching="" system="" means="" all="" process="" equipment="" after="" high-density="" pulp="" storage="" prior="" to="" the="" first="" application="" of="" oxidizing="" chemicals="" or="" reducing="" chemicals="" following="" the="" pulping="" system,="" up="" to="" and="" including="" the="" final="" bleaching="" stage.="" boiler="" means="" any="" enclosed="" combustion="" device="" that="" extracts="" useful="" energy="" in="" the="" form="" of="" steam.="" a="" boiler="" is="" not="" considered="" a="" thermal="" oxidizer.="" chip="" steamer="" means="" a="" vessel="" used="" for="" the="" purpose="" of="" preheating="" or="" pretreating="" wood="" chips="" prior="" to="" the="" digester,="" using="" flash="" steam="" from="" the="" digester="" or="" live="" steam.="" closed-vent="" system="" means="" a="" system="" that="" is="" not="" open="" to="" the="" atmosphere="" and="" is="" composed="" of="" piping,="" ductwork,="" connections,="" and,="" if="" necessary,="" flow-inducing="" devices="" that="" transport="" gas="" or="" vapor="" from="" an="" emission="" point="" to="" a="" control="" device.="" combustion="" device="" means="" an="" individual="" unit="" of="" equipment,="" including="" but="" not="" limited="" to,="" a="" thermal="" oxidizer,="" lime="" kiln,="" recovery="" furnace,="" process="" heater,="" or="" boiler,="" used="" for="" the="" thermal="" oxidation="" of="" organic="" hazardous="" air="" pollutant="" vapors.="" [[page="" 18618]]="" decker="" system="" means="" all="" equipment="" used="" to="" thicken="" the="" pulp="" slurry="" or="" reduce="" its="" liquid="" content="" after="" the="" pulp="" washing="" system="" and="" prior="" to="" high-density="" pulp="" storage.="" the="" decker="" system="" includes="" decker="" vents,="" filtrate="" tanks,="" associated="" vacuum="" pumps,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" digester="" system="" means="" each="" continuous="" digester="" or="" each="" batch="" digester="" used="" for="" the="" chemical="" treatment="" of="" wood="" or="" non-wood="" fibers.="" the="" digester="" system="" equipment="" includes="" associated="" flash="" tank(s),="" blow="" tank(s),="" chip="" steamer(s)="" not="" using="" fresh="" steam,="" blow="" heat="" recovery="" accumulator(s),="" relief="" gas="" condenser(s),="" prehydrolysis="" unit(s)="" preceding="" the="" pulp="" washing="" system,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" the="" digester="" system="" includes="" any="" of="" the="" liquid="" streams="" or="" condensates="" associated="" with="" batch="" or="" continuous="" digester="" relief,="" blow,="" or="" flash="" steam="" processes.="" emission="" point="" means="" any="" part="" of="" a="" stationary="" source="" that="" emits="" hazardous="" air="" pollutants="" regulated="" under="" this="" subpart,="" including="" emissions="" from="" individual="" process="" vents,="" stacks,="" open="" pieces="" of="" process="" equipment,="" equipment="" leaks,="" wastewater="" and="" condensate="" collection="" and="" treatment="" system="" units,="" and="" those="" emissions="" that="" could="" reasonably="" be="" conveyed="" through="" a="" stack,="" chimney,="" or="" duct="" where="" such="" emissions="" first="" reach="" the="" environment.="" evaporator="" system="" means="" all="" equipment="" associated="" with="" increasing="" the="" solids="" content="" and/or="" concentrating="" spent="" cooking="" liquor="" from="" the="" pulp="" washing="" system="" including="" pre-evaporators,="" multi-effect="" evaporators,="" concentrators,="" and="" vacuum="" systems,="" as="" well="" as="" associated="" condensers,="" hotwells,="" and="" condensate="" streams,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" flow="" indicator="" means="" any="" device="" that="" indicates="" gas="" or="" liquid="" flow="" in="" an="" enclosed="" system.="" hap="" means="" a="" hazardous="" air="" pollutant="" as="" defined="" in="" sec.="" 63.2="" of="" subpart="" a="" of="" this="" part.="" high="" volume,="" low="" concentration="" or="" hvlc="" collection="" system="" means="" the="" gas="" collection="" and="" transport="" system="" used="" to="" convey="" gases="" from="" the="" hvlc="" system="" to="" a="" control="" device.="" high="" volume,="" low="" concentration="" or="" hvlc="" system="" means="" the="" collection="" of="" equipment="" including="" the="" pulp="" washing,="" knotter,="" screen,="" decker,="" and="" oxygen="" delignification="" systems,="" weak="" liquor="" storage="" tanks,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" knotter="" system="" means="" equipment="" where="" knots,="" oversized="" material,="" or="" pieces="" of="" uncooked="" wood="" are="" removed="" from="" the="" pulp="" slurry="" after="" the="" digester="" system="" and="" prior="" to="" the="" pulp="" washing="" system.="" the="" knotter="" system="" equipment="" includes="" the="" knotter,="" knot="" drainer="" tanks,="" ancillary="" tanks,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" kraft="" pulping="" means="" a="" chemical="" pulping="" process="" that="" uses="" a="" mixture="" of="" sodium="" hydroxide="" and="" sodium="" sulfide="" as="" the="" cooking="" liquor.="" lime="" kiln="" means="" an="" enclosed="" combustion="" device="" used="" to="" calcine="" lime="" mud,="" which="" consists="" primarily="" of="" calcium="" carbonate,="" into="" calcium="" oxide.="" low="" volume,="" high="" concentration="" or="" lvhc="" collection="" system="" means="" the="" gas="" collection="" and="" transport="" system="" used="" to="" convey="" gases="" from="" the="" lvhc="" system="" to="" a="" control="" device.="" low="" volume,="" high="" concentration="" or="" lvhc="" system="" means="" the="" collection="" of="" equipment="" including="" the="" digester,="" turpentine="" recovery,="" evaporator,="" steam="" stripper="" systems,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" mechanical="" pulping="" means="" a="" pulping="" process="" that="" only="" uses="" mechanical="" and="" thermo-mechanical="" processes="" to="" reduce="" wood="" to="" a="" fibrous="" mass.="" the="" mechanical="" pulping="" processes="" include,="" but="" are="" not="" limited="" to,="" stone="" groundwood,="" pressurized="" groundwood,="" refiner="" mechanical,="" thermal="" refiner="" mechanical,="" thermo-mechanical,="" and="" tandem="" thermo-mechanical.="" non-wood="" pulping="" means="" the="" production="" of="" pulp="" from="" fiber="" sources="" other="" than="" trees.="" the="" non-wood="" fiber="" sources="" include,="" but="" are="" not="" limited="" to,="" bagasse,="" cereal="" straw,="" cotton,="" flax="" straw,="" hemp,="" jute,="" kenaf,="" and="" leaf="" fibers.="" oven-dried="" pulp="" or="" odp="" means="" a="" pulp="" sample="" at="" zero="" percent="" moisture="" content="" by="" weight.="" pulp="" samples="" for="" applicability="" or="" compliance="" determinations="" for="" both="" the="" pulping="" and="" bleaching="" systems="" shall="" be="" unbleached="" pulp.="" for="" purposes="" of="" complying="" with="" mass="" emission="" limits="" in="" this="" subpart,="" megagram="" of="" odp="" shall="" be="" measured="" to="" represent="" the="" amount="" of="" pulp="" entering="" and="" processed="" by="" the="" equipment="" system="" under="" the="" specified="" mass="" limit.="" for="" equipment="" that="" does="" not="" process="" pulp,="" megagram="" of="" odp="" shall="" be="" measured="" to="" represent="" the="" amount="" of="" pulp="" that="" was="" processed="" to="" produce="" the="" gas="" and="" liquid="" streams.="" oxygen="" delignification="" system="" means="" the="" equipment="" that="" uses="" oxygen="" to="" remove="" lignin="" from="" pulp="" after="" high-density="" stock="" storage="" and="" prior="" to="" the="" bleaching="" system.="" the="" oxygen="" delignification="" system="" equipment="" includes="" the="" blow="" tank,="" washers,="" filtrate="" tanks,="" any="" interstage="" pulp="" storage="" tanks,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" primary="" fuel="" means="" the="" fuel="" that="" provides="" the="" principal="" heat="" input="" to="" the="" combustion="" device.="" to="" be="" considered="" primary,="" the="" fuel="" must="" be="" able="" to="" sustain="" operation="" of="" the="" combustion="" device="" without="" the="" addition="" of="" other="" fuels.="" process="" wastewater="" treatment="" system="" means="" a="" collection="" of="" equipment,="" a="" process,="" or="" specific="" technique="" that="" removes="" or="" destroys="" the="" hap's="" in="" a="" process="" wastewater="" stream.="" examples="" include,="" but="" are="" not="" limited="" to,="" a="" steam="" stripping="" unit,="" wastewater="" thermal="" oxidizer,="" or="" biological="" treatment="" unit.="" pulp="" washing="" system="" means="" all="" equipment="" used="" to="" wash="" pulp="" and="" separate="" spent="" cooking="" chemicals="" following="" the="" digester="" system="" and="" prior="" to="" the="" bleaching="" system,="" oxygen="" delignification="" system,="" or="" paper="" machine="" system="" (at="" unbleached="" mills).="" the="" pulp="" washing="" system="" equipment="" includes="" vacuum="" drum="" washers,="" diffusion="" washers,="" rotary="" pressure="" washers,="" horizontal="" belt="" filters,="" intermediate="" stock="" chests,="" and="" their="" associated="" vacuum="" pumps,="" filtrate="" tanks,="" foam="" breakers="" or="" tanks,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" the="" pulp="" washing="" system="" does="" not="" include="" deckers,="" screens,="" knotters,="" stock="" chests,="" or="" pulp="" storage="" tanks="" following="" the="" last="" stage="" of="" pulp="" washing.="" pulping="" line="" means="" a="" group="" of="" equipment="" arranged="" in="" series="" such="" that="" the="" wood="" chips="" are="" digested="" and="" the="" resulting="" pulp="" progresses="" through="" a="" sequence="" of="" steps="" that="" may="" include="" knotting,="" refining,="" washing,="" thickening,="" blending,="" storing,="" oxygen="" delignification,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" pulping="" process="" condensates="" means="" any="" hap-containing="" liquid="" that="" results="" from="" contact="" of="" water="" with="" organic="" compounds="" in="" the="" pulping="" process.="" examples="" of="" process="" condensates="" include="" digester="" system="" condensates,="" turpentine="" recovery="" system="" condensates,="" evaporator="" system="" condensates,="" lvhc="" system="" condensates,="" hvlc="" system="" condensates,="" and="" any="" other="" condensates="" from="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" liquid="" streams="" that="" are="" intended="" for="" byproduct="" recovery="" are="" not="" considered="" process="" condensate="" streams.="" pulping="" system="" means="" all="" process="" equipment,="" beginning="" with="" the="" digester="" system,="" and="" up="" to="" and="" including="" the="" last="" piece="" of="" pulp="" conditioning="" equipment="" prior="" to="" the="" bleaching="" system,="" including="" [[page="" 18619]]="" treatment="" with="" ozone,="" oxygen,="" or="" peroxide="" before="" the="" first="" application="" of="" a="" chemical="" bleaching="" agent="" intended="" to="" brighten="" pulp.="" the="" pulping="" system="" includes="" pulping="" process="" condensates="" and="" can="" include="" multiple="" pulping="" lines.="" recovery="" furnace="" means="" an="" enclosed="" combustion="" device="" where="" concentrated="" spent="" liquor="" is="" burned="" to="" recover="" sodium="" and="" sulfur,="" produce="" steam,="" and="" dispose="" of="" unwanted="" dissolved="" wood="" components="" in="" the="" liquor.="" screen="" system="" means="" equipment="" in="" which="" oversized="" particles="" are="" removed="" from="" the="" pulp="" slurry="" prior="" to="" the="" bleaching="" or="" papermaking="" system="" washed="" stock="" storage.="" secondary="" fiber="" pulping="" means="" a="" pulping="" process="" that="" converts="" a="" fibrous="" material,="" that="" has="" previously="" undergone="" a="" manufacturing="" process,="" into="" pulp="" stock="" through="" the="" addition="" of="" water="" and="" mechanical="" energy.="" the="" mill="" then="" uses="" that="" pulp="" as="" the="" raw="" material="" in="" another="" manufactured="" product.="" these="" mills="" may="" also="" utilize="" chemical,="" heat,="" and="" mechanical="" processes="" to="" remove="" ink="" particles="" from="" the="" fiber="" stock.="" semi-chemical="" pulping="" means="" a="" pulping="" process="" that="" combines="" both="" chemical="" and="" mechanical="" pulping="" processes.="" the="" semi-chemical="" pulping="" process="" produces="" intermediate="" yields="" ranging="" from="" 55="" to="" 90="" percent.="" soda="" pulping="" means="" a="" chemical="" pulping="" process="" that="" uses="" sodium="" hydroxide="" as="" the="" active="" chemical="" in="" the="" cooking="" liquor.="" spent="" liquor="" means="" process="" liquid="" generated="" from="" the="" separation="" of="" cooking="" liquor="" from="" pulp="" by="" the="" pulp="" washing="" system="" containing="" dissolved="" organic="" wood="" materials="" and="" residual="" cooking="" compounds.="" steam="" stripper="" system="" means="" a="" column="" (including="" associated="" stripper="" feed="" tanks,="" condensers,="" or="" heat="" exchangers)="" used="" to="" remove="" compounds="" from="" wastewater="" or="" condensates="" using="" steam.="" the="" steam="" stripper="" system="" also="" contains="" all="" equipment="" associated="" with="" a="" methanol="" rectification="" process="" including="" rectifiers,="" condensers,="" decanters,="" storage="" tanks,="" and="" any="" other="" equipment="" serving="" the="" same="" function="" as="" those="" previously="" listed.="" strong="" liquor="" storage="" tanks="" means="" all="" storage="" tanks="" containing="" liquor="" that="" has="" been="" concentrated="" in="" preparation="" for="" combustion="" or="" oxidation="" in="" the="" recovery="" process.="" sulfite="" pulping="" means="" a="" chemical="" pulping="" process="" that="" uses="" a="" mixture="" of="" sulfurous="" acid="" and="" bisulfite="" ion="" as="" the="" cooking="" liquor.="" temperature="" monitoring="" device="" means="" a="" piece="" of="" equipment="" used="" to="" monitor="" temperature="" and="" having="" an="" accuracy="" of="">1.0 percent 
    of the temperature being monitored expressed in degrees Celsius or 
    0.5 degrees Celsius ( deg.C), whichever is greater.
        Thermal oxidizer means an enclosed device that destroys organic 
    compounds by thermal oxidation.
        Turpentine recovery system means all equipment associated with 
    recovering turpentine from digester system gases including condensers, 
    decanters, storage tanks, and any other equipment serving the same 
    function as those previously listed. The turpentine recovery system 
    includes any liquid streams associated with the turpentine recovery 
    process such as turpentine decanter underflow. Liquid streams that are 
    intended for byproduct recovery are not considered turpentine recovery 
    system condensate streams.
        Weak liquor storage tank means any storage tank except washer 
    filtrate tanks containing spent liquor recovered from the pulping 
    process and prior to the evaporator system.
    
    
    Sec. 63.442  [Reserved]
    
    
    Sec. 63.443  Standards for the pulping system at kraft, soda, and semi-
    chemical processes.
    
        (a) The owner or operator of each pulping system using the kraft 
    process subject to the requirements of this subpart shall control the 
    total HAP emissions from the following equipment systems, as specified 
    in paragraphs (c) and (d) of this section.
        (1) At existing affected sources, the total HAP emissions from the 
    following equipment systems shall be controlled:
        (i) Each LVHC system;
        (ii) Each knotter or screen system with total HAP mass emission 
    rates greater than or equal to the rates specified in paragraphs 
    (a)(1)(ii)(A) or (a)(1)(ii)(B) of this section or the combined rate 
    specified in paragraph (a)(1)(ii)(C) of this section.
        (A) Each knotter system with emissions of 0.05 kilograms or more of 
    total HAP per megagram of ODP (0.1 pounds per ton).
        (B) Each screen system with emissions of 0.10 kilograms or more of 
    total HAP per megagram of ODP (0.2 pounds per ton).
        (C) Each knotter and screen system with emissions of 0.15 kilograms 
    or more of total HAP per megagram of ODP (0.3 pounds per ton).
        (iii) Each pulp washing system;
        (iv) Each decker system that:
        (A) Uses any process water other than fresh water or paper machine 
    white water; or
        (B) Uses any process water with a total HAP concentration greater 
    than 400 parts per million by weight; and
        (v) Each oxygen delignification system.
        (2) At new affected sources, the total HAP emissions from the 
    equipment systems listed in paragraphs (a)(1)(i), (a)(1)(iii), and 
    (a)(1)(v) of this section and the following equipment systems shall be 
    controlled:
        (i) Each knotter system;
        (ii) Each screen system;
        (iii) Each decker system; and
        (iv) Each weak liquor storage tank.
        (b) The owner or operator of each pulping system using a semi-
    chemical or soda process subject to the requirements of this subpart 
    shall control the total HAP emissions from the following equipment 
    systems as specified in paragraphs (c) and (d) of this section.
        (1) At each existing affected sources, the total HAP emissions from 
    each LVHC system shall be controlled.
        (2) At each new affected source, the total HAP emissions from each 
    LVHC system and each pulp washing system shall be controlled.
        (c) Equipment systems listed in paragraphs (a) and (b) of this 
    section shall be enclosed and vented into a closed-vent system and 
    routed to a control device that meets the requirements specified in 
    paragraph (d) of this section. The enclosures and closed-vent system 
    shall meet the requirements specified in Sec. 63.450.
        (d) The control device used to reduce total HAP emissions from each 
    equipment system listed in paragraphs (a) and (b) of this section 
    shall:
        (1) Reduce total HAP emissions by 98 percent or more by weight; or
        (2) Reduce the total HAP concentration at the outlet of the thermal 
    oxidizer to 20 parts per million or less by volume, corrected to 10 
    percent oxygen on a dry basis; or
        (3) Reduce total HAP emissions using a thermal oxidizer designed 
    and operated at a minimum temperature of 871  deg.C (1600  deg.F) and a 
    minimum residence time of 0.75 seconds; or
        (4) Reduce total HAP emissions using a boiler, lime kiln, or 
    recovery furnace by introducing the HAP emission stream with the 
    primary fuel or into the flame zone.
        (e) Periods of excess emissions reported under Sec. 63.455 shall 
    not be a violation of Sec. 63.443 (c) and (d) provided that the time of 
    excess emissions (excluding periods of startup, shutdown, or 
    malfunction) divided by the total process operating time in a semi-
    annual reporting period does not exceed the following levels:
        (1) One percent for control devices used to reduce the total HAP 
    emissions from the LVHC system; and
    
    [[Page 18620]]
    
        (2) Four percent for control devices used to reduce the total HAP 
    emissions from the HVLC system; and
        (3) Four percent for control devices used to reduce the total HAP 
    emissions from both the LVHC and HVLC systems.
    
    
    Sec. 63.444  Standards for the pulping system at sulfite processes.
    
        (a) The owner or operator of each sulfite process subject to the 
    requirements of this subpart shall control the total HAP emissions from 
    the following equipment systems as specified in paragraphs (b) and (c) 
    of this section.
        (1) At existing sulfite affected sources, the total HAP emissions 
    from the following equipment systems shall be controlled:
        (i) Each digester system vent;
        (ii) Each evaporator system vent; and
        (iii) Each pulp washing system.
        (2) At new affected sources, the total HAP emissions from the 
    equipment systems listed in paragraph (a)(1) of this section and the 
    following equipment shall be controlled:
        (i) Each weak liquor storage tank;
        (ii) Each strong liquor storage tank; and
        (iii) Each acid condensate storage tank.
        (b) Equipment listed in paragraph (a) of this section shall be 
    enclosed and vented into a closed-vent system and routed to a control 
    device that meets the requirements specified in paragraph (c) of this 
    section. The enclosures and closed-vent system shall meet the 
    requirements specified in Sec. 63.450. Emissions from equipment listed 
    in paragraph (a) of this section that is not necessary to be reduced to 
    meet paragraph (c) of this section is not required to be routed to a 
    control device.
        (c) The total HAP emissions from both the equipment systems listed 
    in paragraph (a) of this section and the vents, wastewater, and 
    condensate streams from the control device used to reduce HAP 
    emissions, shall be controlled as follows.
        (1) Each calcium-based or sodium-based sulfite pulping process 
    shall:
        (i) Emit no more than 0.44 kilograms of total HAP or methanol per 
    megagram (0.89 pounds per ton) of ODP; or
        (ii) Remove 92 percent or more by weight of the total HAP or 
    methanol.
        (2) Each magnesium-based or ammonium-based sulfite pulping process 
    shall:
        (i) Emit no more than 1.1 kilograms of total HAP or methanol per 
    megagram (2.2 pounds per ton) of ODP; or
        (ii) Remove 87 percent or more by weight of the total HAP or 
    methanol.
    
    
    Sec. 63.445  Standards for the bleaching system.
    
        (a) Each bleaching system that does not use any chlorine or 
    chlorinated compounds for bleaching is exempt from the requirements of 
    this section. Owners or operators of the following bleaching systems 
    shall meet all the provisions of this section:
        (1) Bleaching systems that use chlorine;
        (2) Bleaching systems bleaching pulp from kraft, sulfite, or soda 
    pulping processes that uses any chlorinated compounds; or
        (3) Bleaching systems bleaching pulp from mechanical pulping 
    processes using wood or from any process using secondary or non-wood 
    fibers, that use chlorine dioxide.
        (b) The equipment at each bleaching stage, of the bleaching systems 
    listed in paragraph (a) of this section, where chlorinated compounds 
    are introduced shall be enclosed and vented into a closed-vent system 
    and routed to a control device that meets the requirements specified in 
    paragraph (c) of this section. The enclosures and closed-vent system 
    shall meet the requirements specified in Sec. 63.450.
        (c) The control device used to reduce chlorinated HAP emissions 
    (not including chloroform) from the equipment specified in paragraph 
    (b) of this section shall:
        (1) Reduce the total chlorinated HAP mass in the vent stream 
    entering the control device by 99 percent or more by weight;
        (2) Achieve a treatment device outlet concentration of 10 parts per 
    million or less by volume of total chlorinated HAP; or
        (3) Achieve a treatment device outlet mass emission rate of 0.001 
    kg of total chlorinated HAP mass per megagram (0.002 pounds per ton) of 
    ODP.
        (d) The owner or operator of each bleaching system subject to 
    paragraph (a)(2) of this section shall comply with paragraph (d)(1) or 
    (d)(2) of this section to reduce chloroform air emissions to the 
    atmosphere, except the owner or operator of each bleaching system 
    complying with extended compliance under Sec. 63.440(d)(3)(ii) shall 
    comply with paragraph (d)(1) of this section.
        (1) Comply with the following applicable effluent limitation 
    guidelines and standards specified in 40 CFR part 430:
        (i) Dissolving-grade kraft bleaching systems and lines, 40 CFR 
    430.14 through 430.17;
        (ii) Paper-grade kraft and soda bleaching systems and lines, 40 CFR 
    430.24(a)(1) and (e), and 40 CFR 430.26 (a) and (c);
        (iii) Dissolving-grade sulfite bleaching systems and lines, 40 CFR 
    430.44 through 430.47; or
        (iv) Paper-grade sulfite bleaching systems and lines, 40 CFR 
    430.54(a) and (c), and 430.56(a) and (c).
        (2) Use no hypochlorite or chlorine for bleaching in the bleaching 
    system or line.
    
    
    Sec. 63.446  Standards for kraft pulping process condensates.
    
        (a) The requirements of this section apply to owners or operators 
    of kraft processes subject to the requirements of this subpart.
        (b) The pulping process condensates from the following equipment 
    systems shall be treated to meet the requirements specified in 
    paragraphs (c), (d), and (e) of this section:
        (1) Each digester system;
        (2) Each turpentine recovery system;
        (3) Each evaporator stage where weak liquor is introduced (feed 
    stages) in the evaporator system;
        (4) Each HVLC collection system; and
        (5) Each LVHC collection system.
        (c) One of the following combinations of HAP-containing pulping 
    process condensates generated, produced, or associated with the 
    equipment systems listed in paragraph (b) of this section shall be 
    subject to the requirements of paragraphs (d) and (e) of this section:
        (1) All pulping process condensates from the equipment systems 
    specified in paragraphs (b)(1) through (b)(5) of this section.
        (2) The combined pulping process condensates from the equipment 
    systems specified in paragraphs (b)(4) and (b)(5) of this section, plus 
    pulping process condensate stream(s) that in total contain at least 65 
    percent of the total HAP mass from the pulping process condensates from 
    equipment systems listed in paragraphs (b)(1) through (b)(3) of this 
    section.
        (3) The pulping process condensates from equipment systems listed 
    in paragraphs (b)(1) through (b)(5) of this section that in total 
    contain a total HAP mass of 3.6 kilograms or more of total HAP per 
    megagram (7.2 pounds per ton) of ODP for mills that do not perform 
    bleaching or 5.5 kilograms or more of total HAP per megagram (11.1 
    pounds per ton) of ODP for mills that perform bleaching.
        (d) The pulping process condensates from the equipment systems 
    listed in paragraph (b) of this section shall be conveyed in a closed 
    collection system that is designed and operated to meet the 
    requirements specified in paragraphs (d)(1) and (d)(2) of this section.
        (1) Each closed collection system shall meet the individual drain 
    system
    
    [[Page 18621]]
    
    requirements specified in Sec. 63.960, 63.961, and 63.962 of subpart RR 
    of this part, except for closed vent systems and control devices shall 
    be designed and operated in accordance with Secs. 63.443(d) and 63.450, 
    instead of in accordance with Sec. 63.693 as specified in Sec. 63.962 
    (a)(3)(ii), (b)(3)(ii)(A), and (b)(3)(ii)(B)(5)(iii); and
        (2) If a condensate tank is used in the closed collection system, 
    the tank shall meet the following requirements:
        (i) The fixed roof and all openings (e.g., access hatches, sampling 
    ports, gauge wells) shall be designed and operated with no detectable 
    leaks as indicated by an instrument reading of less than 500 parts per 
    million above background, and vented into a closed-vent system that 
    meets the requirements in Sec. 63.450 and routed to a control device 
    that meets the requirements in Sec. 63.443(d); and
        (ii) Each opening shall be maintained in a closed, sealed position 
    (e.g., covered by a lid that is gasketed and latched) at all times that 
    the tank contains pulping process condensates or any HAP removed from a 
    pulping process condensate stream except when it is necessary to use 
    the opening for sampling, removal, or for equipment inspection, 
    maintenance, or repair.
        (e) Each pulping process condensate from the equipment systems 
    listed in paragraph (b) of this section shall be treated according to 
    one of the following options:
        (1) Recycle the pulping process condensate to an equipment system 
    specified in Sec. 63.443(a) meeting the requirements specified in 
    Sec. 63.443(c) and (d); or
        (2) Discharge the pulping process condensate below the liquid 
    surface of a biological treatment system meeting the requirement 
    specified in paragraph (e)(3) of this section; or
        (3) Treat the pulping process condensates to reduce or destroy the 
    total HAP's by at least 92 percent or more by weight; or
        (4) At mills that do not perform bleaching, treat the pulping 
    process condensates to remove 3.3 kilograms or more of total HAP per 
    megagram (6.6 pounds per ton) of ODP, or achieve a total HAP 
    concentration of 210 parts per million or less by weight at the outlet 
    of the control device; or
        (5) At mills that perform bleaching, treat the pulping process 
    condensates to remove 5.1 kilograms or more of total HAP per megagram 
    (10.2 pounds per ton) of ODP, or achieve a total HAP concentration of 
    330 parts per million or less by weight at the outlet of the control 
    device.
        (f) Each HAP removed from a pulping process condensate stream 
    during treatment and handling under paragraphs (d) or (e) of this 
    section, except for those treated according to paragraph (e)(2) of this 
    section, shall be controlled as specified in Sec. 63.443(c) and (d).
        (g) For each steam stripper system used to comply with the 
    requirements specified in paragraph (e)(3) of this section, periods of 
    excess emissions reported under Sec. 63.455 shall not be a violation of 
    paragraphs (d), (e), and (f) of this section provided that the time of 
    excess emissions (including periods of startup, shutdown, or 
    malfunction) divided by the total process operating time in a semi-
    annual reporting period does not exceed 10 percent.
        (h) Each owner or operator of a new or existing affected source 
    subject to the requirements of this section shall evaluate all new or 
    modified pulping process condensates or changes in the annual bleached 
    or non-bleached ODP used to comply with paragraph (i) of this section, 
    to determine if they meet the applicable requirements of this section.
        (i) For the purposes of meeting the requirements in paragraphs 
    (c)(2), (e)(4), or (e)(5) of this section at mills producing both 
    bleached and unbleached pulp products, owners and operators may meet a 
    prorated mass standard that is calculated by prorating the applicable 
    mass standards (kilograms of total HAP per megagram of ODP) for 
    bleached and unbleached specified in paragraphs (c)(2), (e)(4), or 
    (e)(5) of this section by the ratio of annual megagrams of bleached and 
    unbleached ODP.
    
    
    Sec. 63.447  Clean condensate alternative.
    
        As an alternative to the requirements specified in 
    Sec. 63.443(a)(1)(ii) through (a)(1)(v) for the control of HAP 
    emissions from pulping systems using the kraft process, an owner or 
    operator must demonstrate to the satisfaction of the Administrator, by 
    meeting all the requirements below, that the total HAP emissions 
    reductions achieved by this clean condensate alternative technology are 
    equal to or greater than the total HAP emission reductions that would 
    have been achieved by compliance with Sec. 63.443(a)(1)(ii) through 
    (a)(1)(v).
        (a) For the purposes of this section only the following additional 
    definitions apply.
        (1) Clean condensate alternative affected source means the total of 
    all HAP emission points in the pulping, bleaching, causticizing, and 
    papermaking systems (exclusive of HAP emissions attributable to 
    additives to paper machines and HAP emission points in the LVHC 
    system).
        (2) Causticizing system means all equipment associated with 
    converting sodium carbonate into active sodium hydroxide. The equipment 
    includes smelt dissolving tanks, lime mud washers and storage tanks, 
    white and mud liquor clarifiers and storage tanks, slakers, slaker grit 
    washers, lime kilns, green liquor clarifiers and storage tanks, and 
    dreg washers ending with the white liquor storage tanks prior to the 
    digester system, and any other equipment serving the same function as 
    those previously listed.
        (3) Papermaking system means all equipment used to convert pulp 
    into paper, paperboard, or market pulp, including the stock storage and 
    preparation systems, the paper or paperboard machines, and the paper 
    machine white water system, broke recovery systems, and the systems 
    involved in calendering, drying, on-machine coating, slitting, winding, 
    and cutting.
        (b) Each owner or operator shall install and operate a clean 
    condensate alternative technology with a continuous monitoring system 
    to reduce total HAP emissions by treating and reducing HAP 
    concentrations in the pulping process water used within the clean 
    condensate alternative affected source.
        (c) Each owner or operator shall calculate HAP emissions on a 
    kilogram per megagram of ODP basis and measure HAP emissions according 
    to the appropriate procedures contained in Sec. 63.457.
        (d) Each owner or operator shall determine the baseline HAP 
    emissions for each equipment system and the total of all equipment 
    systems in the clean condensate alternative affected source based on 
    the following:
        (1) Process and air pollution control equipment installed and 
    operating on or after December 17, 1993, and
        (2) Compliance with the following requirements that affect the 
    level of HAP emissions from the clean condensate alternative affected 
    source:
        (i) The pulping process condensates requirements in Sec. 63.446;
        (ii) The applicable effluent limitation guidelines and standards in 
    40 CFR part 430, subparts A, B, D, and E; and
        (iii) All other applicable requirements of local, State, or Federal 
    agencies or statutes.
        (e) Each owner or operator shall determine the following HAP 
    emission reductions from the baseline HAP emissions determined in 
    paragraph (d) of this section for each equipment system and the total 
    of all equipment
    
    [[Page 18622]]
    
    systems in the clean condensate alternative affected source:
        (1) The HAP emission reduction occurring by complying with the 
    requirements of Sec. 63.443(a)(1)(ii) through (a)(1)(v); and
        (2) The HAP emissions reduction that occurring by complying with 
    the clean condensate alternative technology.
        (f) For the purposes of all requirements in this section, each 
    owner or operator may use as an alternative, individual equipment 
    systems (instead of total of all equipment systems) within the clean 
    condensate alternative affected source to determine emissions and 
    reductions to demonstrate equal or greater than the reductions that 
    would have been achieved by compliance with Sec. 63.443(a)(1)(ii) 
    through (a)(1)(v).
        (g) The initial and updates to the control strategy report 
    specified in Sec. 63.455(b) shall include to the extent possible the 
    following information:
        (1) A detailed description of:
        (i) The equipment systems and emission points that comprise the 
    clean condensate alternative affected source;
        (ii) The air pollution control technologies that would be used to 
    meet the requirements of Sec. 63.443(a)(1)(ii) through (a)(1)(v);
        (iii) The clean condensate alternative technology to be used.
        (2) Estimates and basis for the estimates of total HAP emissions 
    and emissions reductions to fulfill the requirements paragraphs (d), 
    (e), and (f) of this section.
        (h) Each owner or operator shall report to the Administrator by the 
    applicable compliance date specified in Sec. 63.440(d) or (e) the 
    rationale, calculations, test procedures, and data documentation used 
    to demonstrate compliance with all the requirements of this section.
    
    
    Secs. 63.448-63.449  [Reserved]
    
    
    Sec. 63.450  Standards for enclosures and closed-vent systems.
    
        (a) Each enclosure and closed-vent system specified in 
    Secs. 63.443(c), 63.444(b), and 63.445(b) for capturing and 
    transporting vent streams that contain HAP shall meet the requirements 
    specified in paragraphs (b) through (d) of this section.
        (b) Each enclosure shall maintain negative pressure at each 
    enclosure or hood opening as demonstrated by the procedures specified 
    Sec. 63.457(e). Each enclosure or hood opening closed during the 
    initial performance test specified in Sec. 63.457(a) shall be 
    maintained in the same closed and sealed position as during the 
    performance test at all times except when necessary to use the opening 
    for sampling, inspection, maintenance, or repairs.
        (c) Each component of the closed-vent system used to comply with 
    Secs. 63.443(c), 63.444(b), and 63.445(b) that is operated at positive 
    pressure and located prior to a control device shall be designed for 
    and operated with no detectable leaks as indicated by an instrument 
    reading of less than 500 parts per million by volume above background, 
    as measured by the procedures specified in Sec. 63.457(d).
        (d) Each bypass line in the closed-vent system that could divert 
    vent streams containing HAP to the atmosphere without meeting the 
    emission limitations in Secs. 63.443, 63.444, or 63.445 shall comply 
    with either of the following requirements:
        (1) On each bypass line, the owner or operator shall install, 
    calibrate, maintain, and operate according to manufacturer's 
    specifications a flow indicator that provides a record of the presence 
    of gas stream flow in the bypass line at least once every 15 minutes. 
    The flow indicator shall be installed in the bypass line in such a way 
    as to indicate flow in the bypass line; or
        (2) For bypass line valves that are not computer controlled, the 
    owner or operator shall maintain the bypass line valve in the closed 
    position with a car seal or a seal placed on the valve or closure 
    mechanism in such a way that valve or closure mechanism cannot be 
    opened without breaking the seal.
    
    
    Secs. 63.451-63.452  [Reserved]
    
    
    Sec. 63.453  Monitoring requirements.
    
        (a) Each owner or operator subject to the standards specified in 
    Secs. 63.443(c) and (d), 63.444(b) and (c), 63.445(b) and (c), 
    63.446(c), (d), and (e), 63.447(b) or Sec. 63.450(d), shall install, 
    calibrate, certify, operate, and maintain according to the 
    manufacturer's specifications, a continuous monitoring system (CMS, as 
    defined in Sec. 63.2 of this part) as specified in paragraphs (b) 
    through (m) of this section, except as allowed in paragraph (m) of this 
    section. The CMS shall include a continuous recorder.
        (b) A CMS shall be operated to measure the temperature in the 
    firebox or in the ductwork immediately downstream of the firebox and 
    before any substantial heat exchange occurs for each thermal oxidizer 
    used to comply with the requirements of Sec. 63.443(d)(1) through 
    (d)(3). Owners and operators complying with the requirements in 
    Sec. 63.443(d)(2) or (d)(3) shall monitor the parameter specified and 
    for the temperature and concentration limits specified.
        (c) A CMS shall be operated to measure the following parameters for 
    each gas scrubber used to comply with the bleaching system requirements 
    of Sec. 63.445(c) or the sulfite pulping system requirements of 
    Sec. 63.444(c).
        (1) The pH or the oxidation/reduction potential of the gas scrubber 
    effluent;
        (2) The gas scrubber vent gas inlet flow rate; and
        (3) The gas scrubber liquid influent flow rate.
        (d) As an option to the requirements specified in paragraph (c) of 
    this section, a CMS shall be operated to measure the chlorine outlet 
    concentration of each gas scrubber used to comply with the bleaching 
    system outlet concentration requirement specified in Sec. 63.445(c)(2).
        (e) The owner or operator of a bleaching system complying with 40 
    CFR 430.24, shall monitor the chlorine and hypochlorite application 
    rates, in kg of bleaching agent per megagram of ODP, of the bleaching 
    system during the extended compliance period specified in 
    Sec. 63.440(d)(3).
        (f) A CMS shall be operated to measure the gas scrubber parameters 
    specified in paragraphs (c)(1) through (c)(3) of this section or those 
    site specific parameters determined according to the procedures 
    specified in paragraph (n) of this section to comply with the sulfite 
    pulping system requirements specified in Sec. 63.444(c).
        (g) A CMS shall be operated to measure the following parameters for 
    each steam stripper used to comply with the treatment requirements in 
    Sec. 63.446(e) (3), (4), or (5):
        (1) The process wastewater feed rate;
        (2) The steam feed rate; and
        (3) The process wastewater column feed temperature.
        (h) As an option to the requirements specified in paragraph (g) of 
    this section, a CMS shall be operated to measure the methanol outlet 
    concentration to comply with the steam stripper outlet concentration 
    requirement specified in Sec. 63.446 (e)(4) or (e)(5).
        (i) A CMS shall be operated to measure the appropriate parameters 
    determined according to the procedures specified in paragraph (n) of 
    this section to comply with the condensate applicability requirements 
    specified in Sec. 63.446(c).
        (j) Each owner or operator using a biological treatment system to 
    comply with Sec. 63.446(e)(2) shall perform the following monitoring 
    procedures.
    
    [[Page 18623]]
    
        (1) On a daily basis, monitor the following parameters for each 
    biological treatment unit:
        (i) Composite daily sample of outlet soluble BOD5 
    concentration to monitor for maximum daily and maximum monthly average;
        (ii) Mixed liquor volatile suspended solids;
        (iii) Horsepower of aerator unit(s);
        (iv) Inlet liquid flow; and
        (v) Liquid temperature.
        (2) Obtain daily inlet and outlet liquid grab samples from each 
    biological treatment unit to have HAP data available to perform 
    quarterly percent reduction tests specified in paragraph (j)(2)(ii) of 
    this section and the compliance percent reduction tests specified in 
    paragraph (p)(1)(i) of this section. Perform the following procedures 
    with the liquid samples:
        (i) Store the samples for 5 days as specified in Sec. 63.457(n). 
    The 5 day storage requirement is required since the soluble 
    BOD5 test requires 5 days to obtain results. If the results 
    of the soluble BOD5 test are outside of the range 
    established during the initial performance test, then the archive 
    sample shall be used to perform the percent reduction test specified in 
    Sec. 63.457(1).
        (ii) Perform the percent reduction test procedures specified in 
    Sec. 63.457(l) within 45 days after the beginning of each quarter as 
    follows.
        (A) The percent reduction test performed in the first quarter 
    (annually) shall be performed for total HAP and the percent reduction 
    obtained from the test shall be at least as great as the total HAP 
    reduction specified in Sec. 63.446(e)(2).
        (B) The remaining quarterly percent reduction tests shall be 
    performed for methanol and the percent reduction obtained from the test 
    shall be at least as great as the methanol reduction determined in the 
    previous first-quarter test specified in paragraph (j)(2)(ii)(A) of 
    this section.
        (C) The parameter values used to calculate the percent reductions 
    required in paragraphs (j)(2)(ii)(A) and (j)(2)(ii)(B) of this section 
    shall be parameter values measured and samples taken in paragraph 
    (j)(1) of this section.
        (k) Each enclosure and closed-vent system used to comply with 
    Sec. 63.450(a) shall comply with the requirements specified in 
    paragraphs (k)(1) through (k)(6) of this section.
        (1) For each enclosure opening, a visual inspection of the closure 
    mechanism specified in Sec. 63.450(b) shall be performed at least once 
    every 30 days to ensure the opening is maintained in the closed 
    position and sealed.
        (2) Each closed-vent system required by Sec. 63.450(a) shall be 
    visually inspected every 30 days and at other times as requested by the 
    Administrator. The visual inspection shall include inspection of 
    ductwork, piping, enclosures, and connections to covers for visible 
    evidence of defects.
        (3) For positive pressure closed-vent systems or portions of 
    closed-vent systems, demonstrate no detectable leaks as specified in 
    Sec. 63.450(c) measured initially and annually by the procedures in 
    Sec. 63.457(d).
        (4) Demonstrate initially and annually that each enclosure opening 
    is maintained at negative pressure as specified in Sec. 63.457(e).
        (5) The valve or closure mechanism specified in Sec. 63.450(d)(2) 
    shall be inspected at least once every 30 days to ensure that the valve 
    is maintained in the closed position and the emission point gas stream 
    is not diverted through the bypass line.
        (6) If an inspection required by paragraphs (k)(1) through (k)(5) 
    of this section identifies visible defects in ductwork, piping, 
    enclosures or connections to covers required by Sec. 63.450, or if an 
    instrument reading of 500 parts per million by volume or greater above 
    background is measured, or if enclosure openings are not maintained at 
    negative pressure, then the following corrective actions shall be taken 
    as soon as practicable.
        (i) A first effort to repair or correct the closed-vent system 
    shall be made as soon as practicable but no later than 5 calendar days 
    after the problem is identified.
        (ii) The repair or corrective action shall be completed no later 
    than 15 calendar days after the problem is identified.
        (l) Each pulping process condensate closed collection system used 
    to comply with Sec. 63.446(d) shall be visually inspected every 30 days 
    and shall comply with the inspection and monitoring requirements 
    specified in Sec. 63.964 of subpart RR of this part, except for the 
    closed-vent system and control device inspection and monitoring 
    requirements specified in Sec. 63.964(a)(2) of subpart RR of this part, 
    the closed-vent system and the control device shall meet the 
    requirements specified in paragraphs (a) and (k) of this section.
        (m) Each owner or operator using a control device, technique or an 
    alternative parameter other than those specified in paragraphs (b) 
    through (l) of this section shall install a CMS and establish 
    appropriate operating parameters to be monitored that demonstrate, to 
    the Administrator's satisfaction, continuous compliance with the 
    applicable control requirements.
        (n) To establish or reestablish, the value for each operating 
    parameter required to be monitored under paragraphs (b) through (j), 
    (l), and (m) of this section or to establish appropriate parameters for 
    paragraphs (f), (i), and (m) of this section, each owner or operator 
    shall use the following procedures:
        (1) During the initial performance test required in Sec. 63.457(a) 
    or any subsequent performance test, continuously record the operating 
    parameter;
        (2) Determinations shall be based on the control performance and 
    parameter data monitored during the performance test, supplemented if 
    necessary by engineering assessments and the manufacturer's 
    recommendations;
        (3) The owner or operator shall provide for the Administrator's 
    approval the rationale for selecting the monitoring parameters 
    necessary to comply with paragraphs (f), (i), and (m) of this section; 
    and
        (4) Provide for the Administrator's approval the rationale for the 
    selected operating parameter value, and monitoring frequency, and 
    averaging time. Include all data and calculations used to develop the 
    value and a description of why the value, monitoring frequency, and 
    averaging time demonstrate continuous compliance with the applicable 
    emission standard.
        (o) Each owner or operator of a control device subject to the 
    monitoring provisions of this section shall operate the control device 
    in a manner consistent with the minimum or maximum (as appropriate) 
    operating parameter value or procedure required to be monitored under 
    paragraphs (a) through (n) of this section and established under this 
    subpart. Except as provided in paragraph (p) of this section, 
    Sec. 63.443(e), or Sec. 63.446(g), operation of the control device 
    below minimum operating parameter values or above maximum operating 
    parameter values established under this subpart or failure to perform 
    procedures required by this subpart shall constitute a violation of the 
    applicable emission standard of this subpart and be reported as a 
    period of excess emissions.
        (p) Each owner or operator of a biological treatment system 
    complying with paragraph (j) of this section shall perform all the 
    following requirements when the monitoring parameters specified in 
    paragraphs (j)(1)(i) through (j)(1)(iii) of this section are below 
    minimum operating parameter values or
    
    [[Page 18624]]
    
    above maximum operating parameter values established in paragraph (n) 
    of this section.
        (1) The following shall occur and be recorded as soon as practical:
        (i) Determine compliance with Sec. 63.446(e)(2) using the percent 
    reduction test procedures specified in Sec. 63.457(l) and the 
    monitoring data specified in paragraph (j)(1) of this section that 
    coincide with the time period of the parameter excursion;
        (ii) Steps shall be taken to repair or adjust the operation of the 
    process to end the parameter excursion period; and
        (iii) Steps shall be taken to minimize total HAP emissions to the 
    atmosphere during the parameter excursion period.
        (2) A parameter excursion is not a violation of the applicable 
    emission standard if the percent reduction test specified in paragraph 
    (p)(1)(i) of this section demonstrates compliance with 
    Sec. 63.446(e)(2), and no maintenance or changes have been made to the 
    process or control device after the beginning of a parameter excursion 
    that would influence the results of the determination.
    
    
    Sec. 63.454  Recordkeeping requirements.
    
        (a) The owner or operator of each affected source subject to the 
    requirements of this subpart shall comply with the recordkeeping 
    requirements of Sec. 63.10 of subpart A of this part, as shown in table 
    1, and the requirements specified in paragraphs (b) through (d) of this 
    section for the monitoring parameters specified in Sec. 63.453.
        (b) For each applicable enclosure opening, closed-vent system, and 
    closed collection system, the owner or operator shall prepare and 
    maintain a site-specific inspection plan including a drawing or 
    schematic of the components of applicable affected equipment and shall 
    record the following information for each inspection:
        (1) Date of inspection;
        (2) The equipment type and identification;
        (3) Results of negative pressure tests for enclosures;
        (4) Results of leak detection tests;
        (5) The nature of the defect or leak and the method of detection 
    (i.e., visual inspection or instrument detection);
        (6) The date the defect or leak was detected and the date of each 
    attempt to repair the defect or leak;
        (7) Repair methods applied in each attempt to repair the defect or 
    leak;
        (8) The reason for the delay if the defect or leak is not repaired 
    within 15 days after discovery;
        (9) The expected date of successful repair of the defect or leak if 
    the repair is not completed within 15 days;
        (10) The date of successful repair of the defect or leak;
        (11) The position and duration of opening of bypass line valves and 
    the condition of any valve seals; and
        (12) The duration of the use of bypass valves on computer 
    controlled valves.
        (c) The owner or operator of a bleaching system complying with 
    Sec. 63.440(d)(3)(ii)(B) shall record the daily average chlorine and 
    hypochlorite application rates, in kg of bleaching agent per megagram 
    of ODP, of the bleaching system until the requirements specified in 
    Sec. 63.440(d)(3)(ii)(A) are met.
        (d) The owner or operator shall record the CMS parameters specified 
    in Sec. 63.453 and meet the requirements specified in paragraph (a) of 
    this section for any new affected process equipment or pulping process 
    condensate stream that becomes subject to the standards in this subpart 
    due to a process change or modification.
    
    
    Sec. 63.455  Reporting requirements.
    
        (a) Each owner or operator of a source subject to this subpart 
    shall comply with the reporting requirements of subpart A of this part 
    as specified in table 1 and all the following requirements in this 
    section. The initial notification report specified under 
    Sec. 63.9(b)(2) of subpart A of this part shall be submitted by April 
    15, 1999.
        (b) Each owner or operator of a kraft pulping system specified in 
    Sec. 63.440(d)(1) or a bleaching system specified in 
    Sec. 63.440(d)(3)(ii) shall submit, with the initial notification 
    report specified under Sec. 63.9(b)(2) of subpart A of this part and 
    paragraph (a) of this section and update every two years thereafter, a 
    non-binding control strategy report containing, at a minimum, the 
    information specified in paragraphs (b)(1) through (b)(3) of this 
    section in addition to the information required in Sec. 63.9(b)(2) of 
    subpart A of this part.
        (1) A description of the emission controls or process modifications 
    selected for compliance with the control requirements in this standard.
        (2) A compliance schedule, including the dates by which each step 
    toward compliance will be reached for each emission point or sets of 
    emission points. At a minimum, the list of dates shall include:
        (i) The date by which the major study(s) for determining the 
    compliance strategy will be completed;
        (ii) The date by which contracts for emission controls or process 
    modifications will be awarded, or the date by which orders will be 
    issued for the purchase of major components to accomplish emission 
    controls or process changes;
        (iii) The date by which on-site construction, installation of 
    emission control equipment, or a process change is to be initiated;
        (iv) The date by which on-site construction, installation of 
    emissions control equipment, or a process change is to be completed;
        (v) The date by which final compliance is to be achieved;
        (vi) For compliance with paragraph Sec. 63.440(d)(3)(ii), the 
    tentative dates by which compliance with effluent limitation guidelines 
    and standards intermediate pollutant load effluent reductions and as 
    available, all the dates for the best available technology's milestones 
    reported in the National Pollutant Discharge Elimination System 
    authorized under section 402 of the Clean Water Act and for the best 
    professional milestones in the Voluntary Advanced Technology Incentives 
    Program under 40 CFR 430.24 (b)(2); and
        (vii) The date by which the final compliance tests will be 
    performed.
        (3) Until compliance is achieved, revisions or updates shall be 
    made to the control strategy report required by paragraph (b) of this 
    section indicating the progress made towards completing the 
    installation of the emission controls or process modifications during 
    the 2-year period.
        (c) The owner or operator of each bleaching system complying with 
    Sec. 63.440(d)(3)(ii)(B) shall certify in the report specified under 
    Sec. 63.10(e)(3) of subpart A of this part that the daily application 
    rates of chlorine and hypochlorite for that bleaching system have not 
    increased as specified in Sec. 63.440(d)(3)(ii)(B) until the 
    requirements of Sec. 63.440(d)(3)(ii)(A) are met.
        (d) The owner or operator shall meet the requirements specified in 
    paragraph (a) of this section upon startup of any new affected process 
    equipment or pulping process condensate stream that becomes subject to 
    the standards of this subpart due to a process change or modification.
    
    
    Sec. 63.456  [Reserved]
    
    
    Sec. 63.457  Test methods and procedures.
    
        (a) Initial performance test. An initial performance test is 
    required for all emission sources subject to the limitations in 
    Secs. 63.443, 63.444, 63.445, 63.446, and 63.447, except those 
    controlled by a combustion device that is designed and operated as 
    specified in Sec. 63.443(d)(3) or (d)(4).
        (b) Vent sampling port locations and gas stream properties. For 
    purposes of
    
    [[Page 18625]]
    
    selecting vent sampling port locations and determining vent gas stream 
    properties, required in Secs. 63.443, 63.444, 63.445, and 63.447, each 
    owner or operator shall comply with the applicable procedures in 
    paragraphs (b)(1) through (b)(6) of this section.
        (1) Method 1 or 1A of part 60, appendix A, as appropriate, shall be 
    used for selection of the sampling site as follows:
        (i) To sample for vent gas concentrations and volumetric flow 
    rates, the sampling site shall be located prior to dilution of the vent 
    gas stream and prior to release to the atmosphere;
        (ii) For determining compliance with percent reduction 
    requirements, sampling sites shall be located prior to the inlet of the 
    control device and at the outlet of the control device; measurements 
    shall be performed simultaneously at the two sampling sites; and
        (iii) For determining compliance with concentration limits or mass 
    emission rate limits, the sampling site shall be located at the outlet 
    of the control device.
        (2) No traverse site selection method is needed for vents smaller 
    than 0.10 meter (4.0 inches) in diameter.
        (3) The vent gas volumetric flow rate shall be determined using 
    Method 2, 2A, 2C, or 2D of part 60, appendix A, as appropriate.
        (4) The moisture content of the vent gas shall be measured using 
    Method 4 of part 60, appendix A.
        (5) To determine vent gas concentrations, the owner or operator 
    shall collect a minimum of three samples that are representative of 
    normal conditions and average the resulting pollutant concentrations 
    using the following procedures.
        (i) Method 308 in Appendix A of this part shall be used to 
    determine the methanol concentration.
        (ii) Except for the modifications specified in paragraphs 
    (b)(5)(ii)(A) through (b)(5)(ii)(K) of this section, Method 26A of part 
    60, appendix A shall be used to determine chlorine concentration in the 
    vent stream.
        (A) Probe/Sampling Line. A separate probe is not required. The 
    sampling line shall be an appropriate length of 0.64 cm (0.25 in) OD 
    Teflon tubing. The sample inlet end of the sampling line 
    shall be inserted into the stack in such a way as to not entrain liquid 
    condensation from the vent gases. The other end shall be connected to 
    the impingers. The length of the tubing may vary from one sampling site 
    to another, but shall be as short as possible in each situation. If 
    sampling is conducted in sunlight, opaque tubing shall be used. 
    Alternatively, if transparent tubing is used, it shall be covered with 
    opaque tape.
        (B) Impinger Train. Three 30 milliliter (ml) capacity midget 
    impingers shall be connected in series to the sampling line. The 
    impingers shall have regular tapered stems. Silica gel shall be placed 
    in the third impinger as a desiccant. All impinger train connectors 
    shall be glass and/or Teflon.
        (C) Critical Orifice. The critical orifice shall have a flow rate 
    of 200 to 250 ml/min and shall be followed by a vacuum pump capable of 
    providing a vacuum of 640 millimeters of mercury (mm Hg). A 45 
    millimeter diameter in-line Teflon 0.8 micrometer filter 
    shall follow the impingers to project the critical orifice and vacuum 
    pump.
        (D) The following are necessary for the analysis apparatus:
        (1) Wash bottle filled with deionized water;
        (2) 25 or 50 ml graduated burette and stand;
        (3) Magnetic stirring apparatus and stir bar;
        (4) Calibrated pH Meter;
        (5) 150-250 ml beaker or flask; and
        (6) A 5 ml pipette.
        (E) The procedures listed in paragraphs (b)(5)(ii)(E)(1) through 
    (b)(5)(ii)(E)(7) of this section shall be used to prepare the reagents.
        (1) To prepare the 1 molarity (M) potassium dihydrogen phosphate 
    solution, dissolve 13.61 grams (g) of potassium dihydrogen phosphate in 
    water and dilute to 100 ml.
        (2) To prepare the 1 M sodium hydroxide solution (NaOH), dissolve 
    4.0 g of sodium hydroxide in water and dilute to 100 ml.
        (3) To prepare the buffered 2 percent potassium iodide solution, 
    dissolve 20 g of potassium iodide in 900 ml water. Add 50 ml of the 1 M 
    potassium dihydrogen phosphate solution and 30 ml of the 1 M sodium 
    hydroxide solution. While stirring solution, measure the pH of solution 
    electrometrically and add the 1 M sodium hydroxide solution to bring pH 
    to between 6.95 and 7.05.
        (4) To prepare the 0.1 normality (N) sodium thiosulfate solution, 
    dissolve 25 g of sodium thiosulfate, pentahydrate, in 800 ml of freshly 
    boiled and cooled distilled water in a 1-liter volumetric flask. Dilute 
    to volume. To prepare the 0.01 N sodium thiosulfate solution, add 10.0 
    ml standardized 0.1 N sodium thiosulfate solution to a 100 ml 
    volumetric flask, and dilute to volume with water.
        (5) To standardize the 0.1 N sodium thiosulfate solution, dissolve 
    3.249 g of anhydrous potassium bi-iodate, primary standard quality, or 
    3.567 g potassium iodate dried at 103 +/-2 degrees Centigrade for 1 
    hour, in distilled water and dilute to 1000 ml to yield a 0.1000 N 
    solution. Store in a glass-stoppered bottle. To 80 ml distilled water, 
    add, with constant stirring, 1 ml concentrated sulfuric acid, 10.00 ml 
    0.1000 N anhydrous potassium bi-iodate, and 1 g potassium iodide. 
    Titrate immediately with 0.1 n sodium thiosulfate titrant until the 
    yellow color of the liberated iodine is almost discharged. Add 1 ml 
    starch indicator solution and continue titrating until the blue color 
    disappears. The normality of the sodium thiosulfate solution is 
    inversely proportional to the ml of sodium thiosulfate solution 
    consumed:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.000
    
        (6) To prepare the starch indicator solution, add a small amount of 
    cold water to 5 g starch and grind in a mortar to obtain a thin paste. 
    Pour paste into 1 L of boiling distilled water, stir, and let settle 
    overnight. Use clear supernate for starch indicator solution.
        (7) To prepare the 10 percent sulfuric acid solution, add 10 ml of 
    concentrated sulfuric acid to 80 ml water in an 100 ml volumetric 
    flask. Dilute to volume.
        (F) The procedures specified in paragraphs (b)(5)(ii)(F)(1) through 
    (b)(5)(ii)(F)(5) of this section shall be used to perform the sampling.
        (1) Preparation of Collection Train. Measure 20 ml buffered 
    potassium iodide solution into each of the first two impingers and 
    connect probe, impingers, filter, critical orifice, and pump. The 
    sampling line and the impingers shall be shielded from sunlight.
        (2) Leak and Flow Check Procedure. Plug sampling line inlet tip and 
    turn on pump. If a flow of bubbles is visible in either of the liquid 
    impingers, tighten fittings and adjust connections and
    
    [[Page 18626]]
    
    impingers. A leakage rate not in excess of 2 percent of the sampling 
    rate is acceptable. Carefully remove the plug from the end of the 
    probe. Check the flow rate at the probe inlet with a bubble tube flow 
    meter. The flow should be comparable or slightly less than the flow 
    rate of the critical orifice with the impingers off-line. Record the 
    flow and turn off the pump.
        (3) Sample Collection. Insert the sampling line into the stack and 
    secure it with the tip slightly lower than the port height. Start the 
    pump, recording the time. End the sampling after 60 minutes, or after 
    yellow color is observed in the second in-line impinger. Record time 
    and remove the tubing from the vent. Recheck flow rate at sampling line 
    inlet and turn off pump. If the flow rate has changed significantly, 
    redo sampling with fresh capture solution. A slight variation (less 
    than 5 percent) in flow may be averaged. With the inlet end of the line 
    elevated above the impingers, add about 5 ml water into the inlet tip 
    to rinse the line into the first impinger.
        (4) Sample Analysis. Fill the burette with 0.01 N sodium 
    thiosulfate solution to the zero mark. Combine the contents of the 
    impingers in the beaker or flask. Stir the solution and titrate with 
    thiosulfate until the solution is colorless. Record the volume of the 
    first endpoint (TN, ml). Add 5 ml of the 10 percent sulfuric acid 
    solution, and continue the titration until the contents of the flask 
    are again colorless. Record the total volume of titrant required to go 
    through the first and to the second endpoint (TA, ml). If the volume of 
    neutral titer is less than 0.5 ml, repeat the testing for a longer 
    period of time. It is important that sufficient lighting be present to 
    clearly see the endpoints, which are determined when the solution turns 
    from pale yellow to colorless. A lighted stirring plate and a white 
    background are useful for this purpose.
        (5) Interferences. Known interfering agents of this method are 
    sulfur dioxide and hydrogen peroxide. Sulfur dioxide, which is used to 
    reduce oxidant residuals in some bleaching systems, reduces formed 
    iodine to iodide in the capture solution. It is therefore a negative 
    interference for chlorine, and in some cases could result in erroneous 
    negative chlorine concentrations. Any agent capable of reducing iodine 
    to iodide could interfere in this manner. A chromium trioxide 
    impregnated filter will capture sulfur dioxide and pass chlorine and 
    chlorine dioxide. Hydrogen peroxide, which is commonly used as a 
    bleaching agent in modern bleaching systems, reacts with iodide to form 
    iodine and thus can cause a positive interference in the chlorine 
    measurement. Due to the chemistry involved, the precision of the 
    chlorine analysis will decrease as the ratio of chlorine dioxide to 
    chlorine increases. Slightly negative calculated concentrations of 
    chlorine may occur when sampling a vent gas with high concentrations of 
    chlorine dioxide and very low concentrations of chlorine.
        (G) The following calculation shall be performed to determine the 
    corrected sampling flow rate:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.001
    
    Where:
    
    SC=Corrected (dry standard) sampling flow rate, liters 
    per minute;
    SU=Uncorrected sampling flow rate, L/min;
    BP=Barometric pressure at time of sampling;
    PW=Saturated partial pressure of water vapor, mm Hg at temperature; 
    and
    t=Ambient temperature,  deg.C.
    
        (H) The following calculation shall be performed to determine the 
    moles of chlorine in the sample:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.002
    
    Where:
    
    TN=Volume neutral titer, ml;
    TA=Volume acid titer (total), ml; and
    NThio=Normality of sodium thiosulfate titrant.
    
        (I) The following calculation shall be performed to determine the 
    concentration of chlorine in the sample:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.003
    
    Where:
    
    SC=Corrected (dry standard) sampling flow rate, liters 
    per minute;
    tS=Time sampled, minutes;
    TN=Volume neutral titer, ml;
    TA=Volume acid titer (total), ml; and
    NThio=Normality of sodium thiosulfate titrant.
    
        (J) The following calculation shall be performed to determine the 
    moles of chlorine dioxide in the sample:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.004
    
    Where:
    
    TA=Volume acid titer (total), ml;
    TN=Volume neutral titer, ml; and
    NThio=Normality of sodium thiosulfate titrant.
    
        (K) The following calculation shall be performed to determine the 
    concentration of chlorine dioxide in the sample:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.005
    
    Where:
    
    SC=Corrected (dry standard) sampling flow rate, liters 
    per minute;
    tS=Time sampled, minutes;
    TA=Volume acid titer (total), ml;
    TN=Volume neutral titer, ml; and
    NThio=Normality of sodium thiosulfate titrant.
    
        (iii) Any other method that measures the total HAP or methanol 
    concentration that has been demonstrated to the Administrator's 
    satisfaction.
        (6) The minimum sampling time for each of the three runs per method 
    shall be 1 hour in which either an integrated sample or four grab 
    samples shall be taken. If grab sampling is used, then the samples 
    shall be taken at approximately equal intervals in time, such as 15 
    minute intervals during the run.
        (c) Liquid sampling locations and properties. For purposes of 
    selecting liquid sampling locations and for determining properties of 
    liquid streams such as wastewaters, process waters, and condensates 
    required in Secs. 63.444, 63.446, and 63.447, the owner or operator 
    shall comply with the following procedures:
        (1) Samples shall be collected using the sampling procedures 
    specified in Method 305 of part 60, appendix A;
        (i) Where feasible, samples shall be taken from an enclosed pipe 
    prior to the liquid stream being exposed to the atmosphere; and
        (ii) When sampling from an enclosed pipe is not feasible, samples 
    shall be collected in a manner to minimize exposure of the sample to 
    the atmosphere and loss of HAP compounds prior to sampling.
        (2) The volumetric flow rate of the entering and exiting liquid 
    streams shall be determined using the inlet and outlet flow meters or 
    other methods demonstrated to the Administrator's satisfaction. The 
    volumetric flow rate measurements to determine actual mass removal 
    shall be taken at the same time as the concentration measurements;
        (3) To determine liquid stream total HAP or methanol 
    concentrations, the owner or operator shall collect a minimum of three 
    samples that are representative of normal conditions and average the 
    resulting pollutant concentrations using one of the following:
        (i) Method 305 in Appendix A of this part, adjusted using the 
    following equation:
    
    [GRAPHIC] [TIFF OMITTED] TR15AP98.006
    
    Where:
    
    C=Pollutant concentration for the liquid stream, parts per million 
    by weight.
    
    [[Page 18627]]
    
    Ci=Measured concentration of pollutant i in the liquid 
    stream sample determined using Method 305, parts per million by 
    weight.
    fmi=Pollutant-specific constant that adjusts 
    concentration measured by Method 305 to actual liquid concentration; 
    the fm for methanol is 0.85. Additional pollutant fm values can be 
    found in table 34, subpart G of this part.
    n=Number of individual pollutants, i, summed to calculate total HAP.
    
        (ii) Any other method that measures total HAP concentration that 
    has been demonstrated to the Administrator's satisfaction.
        (4) To determine soluble BOD5 in the effluent stream 
    from a biological treatment unit used to comply with Secs. 63.446(e)(2) 
    and 63.453(j), the owner or operator shall use Method 405.1, of part 
    136, with the following modifications:
        (i) Filter the sample through the filter paper, into Erlenmeyer 
    flask by applying a vacuum to the flask sidearm. Minimize the time for 
    which vacuum is applied to prevent stripping of volatile organics from 
    the sample. Replace filter paper as often as needed in order to 
    maintain filter times of less than approximately 30 seconds per filter 
    paper. No rinsing of sample container or filter bowl into the 
    Erlenmeyer flask is allowed.
        (ii) Perform Method 405.1 on the filtrate obtained in paragraph 
    (c)(4) of this section. Dilution water shall be seeded with 1 
    milliliter of final effluent per liter of dilution water. Dilution 
    ratios may require adjustment to reflect the lower oxygen demand of the 
    filtered sample in comparison to the total BOD5. Three BOD 
    bottles and different dilutions shall be used for each sample.
        (d) Detectable leak procedures. To measure detectable leaks for 
    closed-vent systems as specified in Sec. 63.450 or for pulping process 
    wastewater collection systems as specified in Sec. 63.446(d)(2)(i), the 
    owner or operator shall comply with the following:
        (1) Method 21, of part 60, appendix A; and
        (2) The instrument specified in Method 21 shall be calibrated 
    before use according to the procedures specified in Method 21 on each 
    day that leak checks are performed. The following calibration gases 
    shall be used:
        (i) Zero air (less than 10 parts per million by volume of 
    hydrocarbon in air); and
        (ii) A mixture of methane or n-hexane and air at a concentration of 
    approximately, but less than, 10,000 parts per million by volume 
    methane or n-hexane.
        (e) Negative pressure procedures. To demonstrate negative pressure 
    at process equipment enclosure openings as specified in Sec. 63.450(b), 
    the owner or operator shall use one of the following procedures:
        (1) An anemometer to demonstrate flow into the enclosure opening;
        (2) Measure the static pressure across the opening;
        (3) Smoke tubes to demonstrate flow into the enclosure opening; or
        (4) Any other industrial ventilation test method demonstrated to 
    the Administrator's satisfaction.
        (f) HAP concentration measurements. For purposes of complying with 
    the requirements in Secs. 63.443, 63.444, and 63.447, the owner or 
    operator shall measure the total HAP concentration as one of the 
    following:
        (1) As the sum of all individual HAP's; or
        (2) As methanol.
        (g) Condensate HAP concentration measurement. For purposes of 
    complying with the kraft pulping condensate requirements in 
    Sec. 63.446, the owner or operator shall measure the total HAP 
    concentration as methanol except for the purposes of complying with the 
    initial performance test specified in Sec. 63.457(a) for 
    Sec. 63.446(e)(2) and as specified in Sec. 63.453(j)(2)(ii).
        (h) Bleaching HAP concentration measurement. For purposes of 
    complying with the bleaching system requirements in Sec. 63.445, the 
    owner or operator shall measure the total HAP concentration as the sum 
    of all individual chlorinated HAP's or as chlorine.
        (i) Vent gas stream calculations. To demonstrate compliance with 
    the mass emission rate, mass emission rate per megagram of ODP, and 
    percent reduction requirements for vent gas streams specified in 
    Secs. 63.443, 63.444, 63.445, and 63.447, the owner or operator shall 
    use the following:
        (1) The total HAP mass emission rate shall be calculated using the 
    following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.007
    
    Where:
    
    E=Mass emission rate of total HAP from the sampled vent, kilograms 
    per hour.
    K2=Constant, 2.494 x 10-6 (parts per million 
    by volume)-1 (gram-mole per standard cubic meter) 
    (kilogram/gram) (minutes/hour), where standard temperature for 
    (gram-mole per standard cubic meter) is 20  deg.C.
    Cj=Concentration on a dry basis of pollutant j in parts 
    per million by volume as measured by the test methods specified in 
    paragraph (b) of this section.
    Mj=Molecular weight of pollutant j, gram/gram-mole.
    Qs=Vent gas stream flow rate (dry standard cubic meter 
    per minute) at a temperature of 20  deg.C as indicated in paragraph 
    (b) of this section.
    n=Number of individual pollutants, i, summed to calculate total HAP.
    
        (2) The total HAP mass emission rate per megagram of ODP shall be 
    calculated using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.008
    
    Where:
    
    F=Mass emission rate of total HAP from the sampled vent, in 
    kilograms per megagram of ODP.
    E=Mass emission rate of total HAP from the sampled vent, in 
    kilograms per hour determined as specified in paragraph (i)(1) of 
    this section.
    P=The production rate of pulp during the sampling period, in 
    megagrams of ODP per hour.
    
        (3) The total HAP percent reduction shall be calculated using the 
    following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.009
    
    Where:
    
    R=Efficiency of control device, percent.
    Ei=Inlet mass emission rate of total HAP from the sampled vent, in 
    kilograms of pollutant per hour, determined as specified in 
    paragraph (i)(1) of this section.
    Eo=Outlet mass emission rate of total HAP from the 
    sampled vent, in kilograms of pollutant per hour, determined as 
    specified in paragraph (i)(1) of this section.
    
        (j) Liquid stream calculations. To demonstrate compliance with the 
    mass flow rate, mass per megagram of ODP, and percent reduction 
    requirements for liquid streams specified in Sec. 63.446, the owner or 
    operator shall use the following:
        (1) The mass flow rates of total HAP or methanol entering and 
    exiting the treatment process shall be calculated using the following 
    equations:
          
        [GRAPHIC] [TIFF OMITTED] TR15AP98.010
        
    Where:
    
    Eb=Mass flow rate of total HAP or methanol in the liquid 
    stream entering the treatment process, kilograms per hour.
    Ea=Mass flow rate of total HAP or methanol in the liquid 
    exiting the treatment process, kilograms per hour.
    
    [[Page 18628]]
    
    K=Density of the liquid stream, kilograms per cubic meter.
    Vbi=Volumetric flow rate of liquid stream entering the 
    treatment process during each run i, cubic meters per hour, 
    determined as specified in paragraph (c) of this section.
    Vai=Volumetric flow rate of liquid stream exiting the 
    treatment process during each run i, cubic meters per hour, 
    determined as specified in paragraph (c) of this section.
    Cbi=Concentration of total HAP or methanol in the stream 
    entering the treatment process during each run i, parts per million 
    by weight, determined as specified in paragraph (c) of this section.
    Cai=Concentration of total HAP or methanol in the stream 
    exiting the treatment process during each run i, parts per million 
    by weight, determined as specified in paragraph (c) of this section.
    n=Number of runs.
    
        (2) The mass of total HAP or methanol per megagram ODP shall be 
    calculated using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.011
    
    Where:
    
    F=Mass loading of total HAP or methanol in the sample, in kilograms 
    per megagram of ODP.
    Ea=Mass flow rate of total HAP or methanol in the 
    wastewater stream in kilograms per hour as determined using the 
    procedures in paragraph (j)(1) of this section.
    P=The production rate of pulp during the sampling period in 
    megagrams of ODP per hour.
    
        (3) The percent reduction of total HAP across the applicable 
    treatment process shall be calculated using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.012
    
    Where:
    
    R=Control efficiency of the treatment process, percent.
    Eb=Mass flow rate of total HAP in the stream entering the 
    treatment process, kilograms per hour, as determined in paragraph 
    (j)(1) of this section.
    Ea=Mass flow rate of total HAP in the stream exiting the 
    treatment process, kilograms per hour, as determined in paragraph 
    (j)(1) of this section.
    
        (4) Compounds that meet the requirements specified in paragraphs 
    (j)(4)(i) or (4)(ii) of this section are not required to be included in 
    the mass flow rate, mass per megagram of ODP, or the mass percent 
    reduction determinations.
        (i) Compounds with concentrations at the point of determination 
    that are below 1 part per million by weight; or
        (ii) Compounds with concentrations at the point of determination 
    that are below the lower detection limit where the lower detection 
    limit is greater than 1 part per million by weight.
        (k) Oxygen concentration correction procedures. To demonstrate 
    compliance with the total HAP concentration limit of 20 ppmv in 
    Sec. 63.443(d)(2), the concentration measured using the methods 
    specified in paragraph (b)(5) of this section shall be corrected to 10 
    percent oxygen using the following procedures:
        (1) The emission rate correction factor and excess air integrated 
    sampling and analysis procedures of Methods 3A or 3B of part 60, 
    appendix A shall be used to determine the oxygen concentration. The 
    samples shall be taken at the same time that the HAP samples are taken.
        (2) The concentration corrected to 10 percent oxygen shall be 
    computed using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.013
    
    Where:
    
    Cc=Concentration of total HAP corrected to 10 percent 
    oxygen, dry basis, parts per million by volume.
    Cm=Concentration of total HAP dry basis, parts per 
    million by volume, as specified in paragraph (b) of this section.
    %02d=Concentration of oxygen, dry basis, percent by 
    volume.
    
        (1) Biological treatment system percent reduction calculation. To 
    determine compliance with an open biological treatment system option 
    specified in Sec. 63.446(e)(2) and the monitoring requirements 
    specified in Sec. 63.453(j)(2), the percent reduction due to 
    destruction in the biological treatment system shall be calculated 
    using the following equation:
    
    R=fbio x 100
    
    Where:
    
    R=Destruction of total HAP or methanol in the biological treatment 
    process, percent.
    fbio=The fraction of total HAP or methanol removed in the 
    biological treatment system. The site-specific biorate constants 
    shall be determined using the procedures specified and as limited in 
    appendix C of part 63.
    
        (m) Condensate segregation procedures. The following procedures 
    shall be used to demonstrate compliance with the condensate segregation 
    requirements specified in Sec. 63.446(c).
        (1) To demonstrate compliance with the percent mass requirements 
    specified in Sec. 63.446(c)(1), the procedures specified in paragraphs 
    (m)(1)(i) through (m)(1)(iii) of this section shall be performed.
        (i) Determine the total HAP mass of all condensates from each 
    equipment system listed in Sec. 63.446 (b)(1) through (b)(3) using the 
    procedures specified in paragraphs (c) and (j) of this section.
        (ii) Multiply the total HAP mass determine in paragraph (m)(1)(i) 
    of this section by 0.65 to determine the target HAP mass for the high-
    HAP fraction condensate stream or streams.
        (iii) Compliance with the segregation requirements specified in 
    Sec. 63.446(c)(1) is demonstrated if the condensate stream or streams 
    from each equipment system listed in Sec. 63.446 (b)(1) through (b)(3) 
    being treated as specified in Sec. 63.446(e) contain at least as much 
    total HAP mass as the target total HAP mass determined in paragraph 
    (m)(1)(ii) of this section.
        (2) To demonstrate compliance with the percent mass requirements 
    specified in Sec. 63.446(c)(2), the procedures specified in paragraphs 
    (m)(2)(i) through (m)(2)(ii) of this section shall be performed.
        (i) Determine the total HAP mass contained in the high-HAP fraction 
    condensates from each equipment system listed in Sec. 63.446(b)(1) 
    through (b)(3) and the total condensates streams from the equipment 
    systems listed in Sec. 63.446(b)(4) and (b)(5), using the procedures 
    specified in paragraphs (c) and (j) of this section.
        (ii) Compliance with the segregation requirements specified in 
    Sec. 63.446(c)(2) is demonstrated if the total HAP mass determined in 
    paragraph (m)(2)(i) of this section is equal to or greater than the 
    appropriate mass requirements specified in Sec. 63.446(c)(2).
        (n) Biological treatment system monitoring sampling storage. The 
    inlet and outlet grab samples required to be collected in 
    Sec. 63.453(j)(2) shall be stored at 4 deg. C (40 deg. F) to minimize 
    the biodegradation of the organic compounds in the samples.
    
    
    Sec. 63.458  Delegation of authority.
    
        (a) In delegating implementation and enforcement authority to a 
    State under section 112(d) of the CAA, the authorities contained in 
    paragraph (b) of this section shall be retained by the Administrator 
    and not transferred to a State.
        (b) Authorities which will not be delegated to States:
        (1) Section 63.6(g)--Use of an alternative nonopacity emission 
    standard;
        (2) Section 63.453(m)--Use of an alternative monitoring parameter;
        (3) Section 63.457(b)(5)(iii)--Use of an alternative test method 
    for total HAP or methanol in vents; and
        (4) Section 63.457(c)(3)(ii)--Use of an alternative test method for 
    total HAP or methanol in wastewater.
    
    [[Page 18629]]
    
    Sec. 63.459  [Reserved]
    
      Table 1 to Subpart S--General Provisions Applicability to Subpart S a 
    ------------------------------------------------------------------------
                                  Applies to Subpart                        
              Reference                    S                  Comment       
    ------------------------------------------------------------------------
    63.1(a)(1)-(3)..............  Yes...............                        
    63.1(a)(4)..................  Yes...............  Subpart S (this table)
                                                       specifies            
                                                       applicability of each
                                                       paragraph in subpart 
                                                       A to subpart S.      
    63.1(a)(5)..................  No................  Section reserved.     
    63.1(a)(6)-(8)..............  Yes...............                        
    63.1(a)(9)..................  No................  Section reserved.     
    63.1(a)(10).................  No................  Subpart S and other   
                                                       cross-referenced     
                                                       subparts specify     
                                                       calendar or operating
                                                       day.                 
    63.1(a)(11)-(14)............  Yes...............                        
    63.1(b)(1)..................  No................  Subpart S specifies   
                                                       its own              
                                                       applicability.       
    63.1(b)(2)-(3)..............  Yes...............                        
    63.1(c)(1)-(2)..............  Yes...............                        
    63.1(c)(3)..................  No................  Section reserved.     
    63.1(c)(4)-(5)..............  Yes...............                        
    63.1(d).....................  No................  Section reserved.     
    63.1(e).....................  Yes...............                        
    63.2........................  Yes...............                        
    63.3........................  Yes...............                        
    63.4(a)(1)..................  Yes...............                        
    63.4(a)(3)..................                                            
    63.4(a)(4)..................  No................  Section reserved.     
    63.4(a)(5)..................  Yes...............                        
    63.4(b).....................  Yes...............                        
    63.4(c).....................  Yes...............                        
    63.5(a).....................  Yes...............                        
    63.5(b)(1)..................  Yes...............                        
    63.5(b)(2)..................  No................  Section reserved.     
    63.5(b)(3)..................  Yes...............                        
    63.5(b)(4)-(6)..............  Yes...............                        
    63.5(c).....................  No................  Section reserved.     
    63.5(d).....................  Yes...............                        
    63.5(e).....................  Yes...............                        
    63.5(f).....................  Yes...............                        
    63.6(a).....................  Yes...............                        
    63.6(b).....................  No................  Subpart S specifies   
                                                       compliance dates for 
                                                       sources subject to   
                                                       subpart S.           
    63.6(c).....................  No................  Subpart S specifies   
                                                       compliance dates for 
                                                       sources subject to   
                                                       subpart S.           
    63.6(d).....................  No................  Section reserved.     
    63.6(e).....................  Yes...............                        
    63.6(f).....................  Yes...............                        
    63.6(g).....................  Yes...............                        
    63.6(h).....................  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    63.6(i).....................  Yes...............                        
    63.6(j).....................  Yes...............                        
    63.7........................  Yes...............                        
    63.8(a)(1)..................  Yes...............                        
    63.8(a)(2)..................  Yes...............                        
    63.8(a)(3)..................  No................  Section reserved.     
    63.8(a)(4)..................  Yes...............                        
    63.8(b)(1)..................  Yes...............                        
    63.8(b)(2)..................  No................  Subpart S specifies   
                                                       locations to conduct 
                                                       monitoring.          
    63.8(b)(3)..................  Yes...............                        
    63.8(c)(1)..................  Yes...............                        
    63.8(c)(2)..................  Yes...............                        
    63.8(c)(3)..................  Yes...............                        
    63.8(c)(4)..................  No................  Subpart S allows site 
                                                       specific             
                                                       determination of     
                                                       monitoring frequency 
                                                       in Sec.              
                                                       63.453(n)(4).        
    63.8(c)(5)..................  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    63.8(c)(6)..................  Yes...............                        
    63.8(c)(7)..................  Yes...............                        
    63.8(c)(8)..................  Yes...............                        
    63.8(d).....................  Yes...............                        
    63.8(e).....................  Yes...............                        
    63.8(f)(1)-(5)..............  Yes...............                        
    63.8(f)(6)..................  No................  Subpart S does not    
                                                       specify relative     
                                                       accuracy test for    
                                                       CEM's.               
    63.8(g).....................  Yes...............                        
    63.9(a).....................  Yes...............                        
    63.9(b).....................  Yes...............  Initial notifications 
                                                       must be submitted    
                                                       within one year after
                                                       the source becomes   
                                                       subject to the       
                                                       relevant standard.   
    63.9(c).....................  Yes...............                        
    63.9(d).....................  No................  Special compliance    
                                                       requirements are only
                                                       applicable to kraft  
                                                       mills.               
    63.9(e).....................  Yes...............                        
    63.9(f).....................  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    
    [[Page 18630]]
    
                                                                            
    63.9(g)(1)..................  Yes...............                        
    63.9(g)(2)..................  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    63.9(g)(3)..................  No................  Subpart S does not    
                                                       specify relative     
                                                       accuracy tests,      
                                                       therefore no         
                                                       notification is      
                                                       required for an      
                                                       alternative.         
    63.9(h).....................  Yes...............                        
    63.9(i).....................  Yes...............                        
    63.9(j).....................  Yes...............                        
    63.10(a)....................  Yes...............                        
    63.10(b)....................  Yes...............                        
    63.10(c)....................  Yes...............                        
    63.10(d)(1).................  Yes...............                        
    63.10(d)(2).................  Yes...............                        
    63.10(d)(3).................  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    63.10(d)(4).................  Yes...............                        
    63.10(d)(5).................  Yes...............                        
    63.10(e)(1).................  Yes...............                        
    63.10(e)(2)(i)..............  Yes...............                        
    63.10(e)(2)(ii).............  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    63.10(e)(3).................  Yes...............                        
    63.10(e)(4).................  No................  Pertains to continuous
                                                       opacity monitors that
                                                       are not part of this 
                                                       standard.            
    63.10(f)....................  Yes...............                        
    63.11-63.15.................  Yes...............                        
    ------------------------------------------------------------------------
    a Wherever subpart A specifies ``postmark'' dates, submittals may be    
      sent by methods other than the U.S. Mail (e.g., by fax or courier).   
      Submittals shall be sent by the specified dates, but a postmark is not
      required.                                                             
    
        3. Appendix A of part 63 is amended by adding Method 308 in 
    numerical order to read as follows:
    
    Appendix A to Part 63--Test Methods
    
    * * * * *
    
    Method 308--Procedure for Determination of Methanol Emission From 
    Stationary Sources
    
    1.0  Scope and Application
    
        1.1  Analyte. Methanol. Chemical Abstract Service (CAS) No. 67-56-
    1.
        1.2  Applicability. This method applies to the measurement of 
    methanol emissions from specified stationary sources.
    
    2.0  Summary of Method
    
        A gas sample is extracted from the sampling point in the stack. The 
    methanol is collected in deionized distilled water and adsorbed on 
    silica gel. The sample is returned to the laboratory where the methanol 
    in the water fraction is separated from other organic compounds with a 
    gas chromatograph (GC) and is then measured by a flame ionization 
    detector (FID). The fraction adsorbed on silica gel is extracted with 
    an aqueous solution of n-propanol and is then separated and measured by 
    GC/FID.
    
    3.0  Definitions [Reserved]
    
    4.0  Interferences [Reserved]
    
    5.0  Safety
    
        5.1  Disclaimer. This method may involve hazardous materials, 
    operations, and equipment. This test method does not purport to address 
    all of the safety problems associated with its use. It is the 
    responsibility of the user of this test method to establish appropriate 
    safety and health practices and to determine the applicability of 
    regulatory limitations before performing this test method.
        5.2  Methanol Characteristics. Methanol is flammable and a 
    dangerous fire and explosion risk. It is moderately toxic by ingestion 
    and inhalation.
    
    6.0  Equipment and Supplies
    
        6.1  Sample Collection. The following items are required for sample 
    collection:
        6.1.1  Sampling Train. The sampling train is shown in Figure 308-1 
    and component parts are discussed below.
        6.1.1.1  Probe. Teflon, approximately 6-millimeter (mm) 
    (0.24 inch) outside diameter.
        6.1.1.2  Impinger. A 30-milliliter (ml) midget impinger. The 
    impinger must be connected with leak-free glass connectors. Silicone 
    grease may not be used to lubricate the connectors.
        6.1.1.3  Adsorbent Tube. Glass tubes packed with the required 
    amount of the specified adsorbent.
        6.1.1.4  Valve. Needle valve, to regulate sample gas flow rate.
        6.1.1.5  Pump. Leak-free diaphragm pump, or equivalent, to pull gas 
    through the sampling train. Install a small surge tank between the pump 
    and rate meter to eliminate the pulsation effect of the diaphragm pump 
    on the rotameter.
        6.1.1.6  Rate Meter. Rotameter, or equivalent, capable of measuring 
    flow rate to within 2 percent of the selected flow rate of up to 1000 
    milliliter per minute (ml/min). Alternatively, the tester may use a 
    critical orifice to set the flow rate.
        6.1.1.7  Volume Meter. Dry gas meter (DGM), sufficiently accurate 
    to measure the sample volume to within 2 percent, calibrated at the 
    selected flow rate and conditions actually encountered during sampling, 
    and equipped with a temperature sensor (dial thermometer, or 
    equivalent) capable of measuring temperature accurately to within 3 
    deg.C (5.4  deg.F).
        6.1.1.8  Barometer. Mercury (Hg), aneroid, or other barometer 
    capable of measuring atmospheric pressure to within 2.5 mm (0.1 inch) 
    Hg. See the NOTE in Method 5 (40 CFR part 60, appendix A), section 
    6.1.2.
        6.1.1.9  Vacuum Gauge and Rotameter. At least 760-mm (30-inch) Hg 
    gauge and 0- to 40-ml/min rotameter, to be used for leak-check of the 
    sampling train.
        6.2  Sample Recovery. The following items are required for sample 
    recovery:
        6.2.1  Wash Bottles. Polyethylene or glass, 500-ml, two.
        6.2.2  Sample Vials. Glass, 40-ml, with Teflon-lined 
    septa, to store impinger samples (one per sample).
        6.2.3  Graduated Cylinder. 100-ml size.
        6.3  Analysis. The following are required for analysis:
        6.3.1  Gas Chromatograph. GC with an FID, programmable temperature 
    control, and heated liquid injection port.
    
    [[Page 18631]]
    
        6.3.2  Pump. Capable of pumping 100 ml/min. For flushing sample 
    loop.
        6.3.3  Flow Meter. To monitor accurately sample loop flow rate of 
    100 ml/min.
        6.3.4  Regulators. Two-stage regulators used on gas cylinders for 
    GC and for cylinder standards.
        6.3.5  Recorder. To record, integrate, and store chromatograms.
        6.3.6  Syringes. 1.0- and 10-microliter (l) size, calibrated, for 
    injecting samples.
        6.3.7  Tubing Fittings. Stainless steel, to plumb GC and gas 
    cylinders.
        6.3.8  Vials. Two 5.0-ml glass vials with screw caps fitted with 
    Teflon-lined septa for each sample.
        6.3.9  Pipettes. Volumetric type, assorted sizes for preparing 
    calibration standards.
        6.3.10  Volumetric Flasks. Assorted sizes for preparing calibration 
    standards.
        6.3.11  Vials. Glass 40-ml with Teflon-lined septa, to 
    store calibration standards (one per standard).
    
    7.0  Reagents and Standards
    
        Note: Unless otherwise indicated, all reagents must conform to 
    the specifications established by the Committee on Analytical 
    Reagents of the American Chemical Society. Where such specifications 
    are not available, use the best available grade.
    
        7.1  Sampling. The following are required for sampling:
        7.1.1  Water. Deionized distilled to conform to the American 
    Society for Testing and Materials (ASTM) Specification D 1193-77, Type 
    3. At the option of the analyst, the potassium permanganate 
    (KMnO4) test for oxidizable organic matter may be omitted 
    when high concentrations of organic matter are not expected to be 
    present.
        7.1.2  Silica Gel. Deactivated chromatographic grade 20/40 mesh 
    silica gel packed in glass adsorbent tubes. The silica gel is packed in 
    two sections. The front section contains 520 milligrams (mg) of silica 
    gel, and the back section contains 260 mg.
        7.2  Analysis. The following are required for analysis:
        7.2.1  Water. Same as specified in section 7.1.1.
        7.2.2  n-Propanol, 3 Percent. Mix 3 ml of n-propanol with 97 ml of 
    water.
        7.2.3  Methanol Stock Standard. Prepare a methanol stock standard 
    by weighing 1 gram of methanol into a 100-ml volumetric flask. Dilute 
    to 100 ml with water.
        7.2.3.1  Methanol Working Standard. Prepare a methanol working 
    standard by pipetting 1 ml of the methanol stock standard into a 100-ml 
    volumetric flask. Dilute the solution to 100 ml with water.
        7.2.3.2  Methanol Standards For Impinger Samples. Prepare a series 
    of methanol standards by pipetting 1, 2, 5, 10, and 25 ml of methanol 
    working standard solution respectively into five 50-ml volumetric 
    flasks. Dilute the solutions to 50 ml with water. These standards will 
    have 2, 4, 10, 20, and 50 g/ml of methanol, respectively. 
    After preparation, transfer the solutions to 40-ml glass vials capped 
    with Teflon septa and store the vials under refrigeration. 
    Discard any excess solution.
        7.2.3.3  Methanol Standards for Adsorbent Tube Samples. Prepare a 
    series of methanol standards by first pipetting 10 ml of the methanol 
    working standard into a 100-ml volumetric flask and diluting the 
    contents to exactly 100 ml with 3 percent n-propanol solution. This 
    standard will contain 10 g/ml of methanol. Pipette 5, 15, and 
    25 ml of this standard, respectively, into four 50-ml volumetric 
    flasks. Dilute each solution to 50 ml with 3 percent n-propanol 
    solution. These standards will have 1, 3, and 5 g/ml of 
    methanol, respectively. Transfer all four standards into 40-ml glass 
    vials capped with Teflon-lined septa and store under 
    refrigeration. Discard any excess solution.
        7.2.4  GC Column. Capillary column, 30 meters (100 feet) long with 
    an inside diameter (ID) of 0.53 mm (0.02 inch), coated with DB 624 to a 
    film thickness of 3.0 micrometers, (m) or an equivalent 
    column. Alternatively, a 30-meter capillary column coated with 
    polyethylene glycol to a film thickness of 1 m such as AT-WAX 
    or its equivalent.
        7.2.5  Helium. Ultra high purity.
        7.2.6  Hydrogen. Zero grade.
        7.2.7  Oxygen. Zero grade.
    
    8.0  Procedure
    
        8.1  Sampling. The following items are required for sampling:
        8.1.1  Preparation of Collection Train. Measure 20 ml of water into 
    the midget impinger. The adsorbent tube must contain 520 mg of silica 
    gel in the front section and 260 mg of silica gel in the backup 
    section. Assemble the train as shown in Figure 308-1. An optional, 
    second impinger that is left empty may be placed in front of the water-
    containing impinger to act as a condensate trap. Place crushed ice and 
    water around the impinger.
    
    BILLING CODE 6560-50-P
    
    [[Page 18632]]
    
    [GRAPHIC] [TIFF OMITTED] TR15AP98.014
    
    
    
    BILLING CODE 6560-50-C
    
    [[Page 18633]]
    
        8.1.2  Leak Check. A leak check prior to the sampling run is 
    optional; however, a leak check after the sampling run is mandatory. 
    The leak-check procedure is as follows:
        Temporarily attach a suitable (e.g., 0-to 40-ml/min) rotameter to 
    the outlet of the DGM, and place a vacuum gauge at or near the probe 
    inlet. Plug the probe inlet, pull a vacuum of at least 250 mm (10 inch) 
    Hg, and note the flow rate as indicated by the rotameter. A leakage 
    rate not in excess of 2 percent of the average sampling rate is 
    acceptable.
    
        Note: Carefully release the probe inlet plug before turning off 
    the pump.
    
        8.1.3  Sample Collection. Record the initial DGM reading and 
    barometric pressure. To begin sampling, position the tip of the 
    Teflon tubing at the sampling point, connect the tubing to 
    the impinger, and start the pump. Adjust the sample flow to a constant 
    rate between 200 and 1000 ml/min as indicated by the rotameter. 
    Maintain this constant rate (10 percent) during the entire 
    sampling run. Take readings (DGM, temperatures at DGM and at impinger 
    outlet, and rate meter) at least every 5 minutes. Add more ice during 
    the run to keep the temperature of the gases leaving the last impinger 
    at 20  deg.C (68  deg.F) or less. At the conclusion of each run, turn 
    off the pump, remove the Teflon tubing from the stack, and 
    record the final readings. Conduct a leak check as in section 8.1.2. 
    (This leak check is mandatory.) If a leak is found, void the test run 
    or use procedures acceptable to the Administrator to adjust the sample 
    volume for the leakage.
        8.2  Sample Recovery. The following items are required for sample 
    recovery:
        8.2.1  Impinger. Disconnect the impinger. Pour the contents of the 
    midget impinger into a graduated cylinder. Rinse the midget impinger 
    and the connecting tubes with water, and add the rinses to the 
    graduated cylinder. Record the sample volume. Transfer the sample to a 
    glass vial and cap with a Teflon septum. Discard any excess 
    sample. Place the samples in an ice chest for shipment to the 
    laboratory.
        8.2.2.  Adsorbent Tubes. Seal the silica gel adsorbent tubes and 
    place them in an ice chest for shipment to the laboratory.
    
    9.0  Quality Control
    
        9.1  Miscellaneous Quality Control Measures. The following quality 
    control measures are required:
    
    ------------------------------------------------------------------------
           Section         Quality control measure           Effect         
    ------------------------------------------------------------------------
    8.1.2, 8.1.3, 10.1..  Sampling equipment leak   Ensures accurate        
                           check and calibration.    measurement of sample  
                                                     volume.                
    10.2................  GC calibration..........  Ensures precision of GC 
                                                     analysis.              
    ------------------------------------------------------------------------
    
        9.2  Applicability. When the method is used to analyze samples to 
    demonstrate compliance with a source emission regulation, an audit 
    sample must be analyzed, subject to availability.
        9.3  Audit Procedure. Analyze an audit sample with each set of 
    compliance samples. Concurrently analyze the audit sample and a set of 
    compliance samples in the same manner to evaluate the technique of the 
    analyst and the standards preparation. The same analyst, analytical 
    reagents, and analytical system shall be used both for the compliance 
    samples and the EPA audit sample.
        9.4  Audit Sample Availability. Audit samples will be supplied only 
    to enforcement agencies for compliance tests. Audit samples may be 
    obtained by writing: Source Test Audit Coordinator (MD-77B), Air 
    Measurement Research Division, National Exposure Research Laboratory, 
    U.S. Environmental Protection Agency, Research Triangle Park, NC 27711; 
    or by calling the Source Test Audit Coordinator (STAC) at (919) 541-
    7834. The audit sample request must be made at least 30 days prior to 
    the scheduled compliance sample analysis.
        9.5  Audit Results. Calculate the audit sample concentration 
    according to the calculation procedure provided in the audit 
    instructions included with the audit sample. Fill in the audit sample 
    concentration and the analyst's name on the audit response form 
    included with the audit instructions. Send one copy to the EPA Regional 
    Office or the appropriate enforcement agency and a second copy to the 
    STAC. The EPA Regional office or the appropriate enforcement agency 
    will report the results of the audit to the laboratory being audited. 
    Include this response with the results of the compliance samples in 
    relevant reports to the EPA Regional Office or the appropriate 
    enforcement agency.
    
    10.0  Calibration and Standardization
    
        10.1  Metering System. The following items are required for the 
    metering system:
        10.1.1  Initial Calibration.
        10.1.1.1  Before its initial use in the field, first leak-check the 
    metering system (drying tube, needle valve, pump, rotameter, and DGM) 
    as follows: Place a vacuum gauge at the inlet to the drying tube, and 
    pull a vacuum of 250 mm (10 inch) Hg; plug or pinch off the outlet of 
    the flow meter, and then turn off the pump. The vacuum shall remain 
    stable for at least 30 seconds. Carefully release the vacuum gauge 
    before releasing the flow meter end.
        10.1.1.2  Next, remove the drying tube, and calibrate the metering 
    system (at the sampling flow rate specified by the method) as follows: 
    Connect an appropriately sized wet test meter (e.g., 1 liter per 
    revolution (0.035 cubic feet per revolution)) to the inlet of the 
    drying tube. Make three independent calibrations runs, using at least 
    five revolutions of the DGM per run. Calculate the calibration factor, 
    Y (wet test meter calibration volume divided by the DGM volume, both 
    volumes adjusted to the same reference temperature and pressure), for 
    each run, and average the results. If any Y-value deviates by more than 
    2 percent from the average, the metering system is unacceptable for 
    use. Otherwise, use the average as the calibration factor for 
    subsequent test runs.
        10.1.2  Posttest Calibration Check. After each field test series, 
    conduct a calibration check as in section 10.1.1 above, except for the 
    following variations: (a) The leak check is not to be conducted, (b) 
    three, or more revolutions of the DGM may be used, and (c) only two 
    independent runs need be made. If the calibration factor does not 
    deviate by more than 5 percent from the initial calibration factor 
    (determined in section 10.1.1), then the DGM volumes obtained during 
    the test series are acceptable. If the calibration factor deviates by 
    more than 5 percent, recalibrate the metering system as in section 
    10.1.1, and for the calculations, use the calibration factor (initial 
    or recalibration) that yields the lower gas volume for each test run.
        10.1.3  Temperature Sensors. Calibrate against mercury-in-glass 
    thermometers.
        10.1.4  Rotameter. The rotameter need not be calibrated, but should 
    be cleaned and maintained according to the manufacturer's instruction.
        10.1.5  Barometer. Calibrate against a mercury barometer.
        10.2  Gas Chromatograph. The following procedures are required for 
    the gas chromatograph:
        10.2.1  Initial Calibration. Inject 1 l of each of the 
    standards prepared in sections 7.2.3.3 and 7.2.3.4 into the GC and 
    record the response. Repeat the injections for each standard until two 
    successive injections agree within 5 percent. Using the mean response 
    for
    
    [[Page 18634]]
    
    each calibration standard, prepare a linear least squares equation 
    relating the response to the mass of methanol in the sample. Perform 
    the calibration before analyzing each set of samples.
        10.2.2  Continuing Calibration. At the beginning of each day, 
    analyze the mid level calibration standard as described in section 
    10.5.1. The response from the daily analysis must agree with the 
    response from the initial calibration within 10 percent. If it does 
    not, the initial calibration must be repeated.
    
    11.0  Analytical Procedure
    
        11.1  Gas Chromatograph Operating Conditions. The following 
    operating conditions are required for the GC:
        11.1.1  Injector. Configured for capillary column, splitless, 200 
    deg.C (392  deg.F).
        11.1.2  Carrier. Helium at 10 ml/min.
        11.1.3  Oven. Initially at 45  deg.C for 3 minutes; then raise by 
    10  deg.C to 70  deg.C; then raise by 70  deg.C/min to 200  deg.C.
        11.2  Impinger Sample. Inject 1 l of the stored sample 
    into the GC. Repeat the injection and average the results. If the 
    sample response is above that of the highest calibration standard, 
    either dilute the sample until it is in the measurement range of the 
    calibration line or prepare additional calibration standards. If the 
    sample response is below that of the lowest calibration standard, 
    prepare additional calibration standards. If additional calibration 
    standards are prepared, there shall be at least two that bracket the 
    response of the sample. These standards should produce approximately 50 
    percent and 150 percent of the response of the sample.
        11.3  Silica Gel Adsorbent Sample. The following items are required 
    for the silica gel adsorbent samples:
        11.3.1  Preparation of Samples. Extract the front and backup 
    sections of the adsorbent tube separately. With a file, score the glass 
    adsorbent tube in front of the first section of silica gel. Break the 
    tube open. Remove and discard the glass wool. Transfer the first 
    section of the silica gel to a 5-ml glass vial and stopper the vial. 
    Remove the spacer between the first and second section of the adsorbent 
    tube and discard it. Transfer the second section of silica gel to a 
    separate 5-ml glass vial and stopper the vial.
        11.3.2  Desorption of Samples. Add 3 ml of the 10 percent n-
    propanol solution to each of the stoppered vials and shake or vibrate 
    the vials for 30 minutes.
        11.3.3  Inject a 1-l aliquot of the diluted sample from 
    each vial into the GC. Repeat the injection and average the results. If 
    the sample response is above that of the highest calibration standard, 
    either dilute the sample until it is in the measurement range of the 
    calibration line or prepare additional calibration standards. If the 
    sample response is below that of the lowest calibration standard, 
    prepare additional calibration standards. If additional calibration 
    standards are prepared, there shall be at least two that bracket the 
    response of the sample. These standards should produce approximately 50 
    percent and 150 percent of the response of the sample.
    
    12.0  Data Analysis and Calculations
    
        12.1  Nomenclature.
    
    Caf=Concentration of methanol in the front of the adsorbent 
    tube, g/ml.
    Cab=Concentration of methanol in the back of the adsorbent 
    tube, g/ml.
    Ci=Concentration of methanol in the impinger portion of the 
    sample train, g/ml.
    E=Mass emission rate of methanol, g/hr (lb/hr).
    Mtot=Total mass of methanol collected in the sample train, 
    g.
    Pbar=Barometric pressure at the exit orifice of the DGM, mm 
    Hg (in. Hg).
    Pstd=Standard absolute pressure, 760 mm Hg (29.92 in. Hg).
    Qstd=Dry volumetric stack gas flow rate corrected to 
    standard conditions, dscm/hr (dscf/hr).
    Tm=Average DGM absolute temperature, degrees K ( deg.R).
    Tstd=Standard absolute temperature, 293 degrees K (528 
    deg.R).
    Vaf=Volume of front half adsorbent sample, ml.
    Vab=Volume of back half adsorbent sample, ml.
    Vi=Volume of impinger sample, ml.
    Vm=Dry gas volume as measured by the DGM, dry cubic meters 
    (dcm), dry cubic feet (dcf).
    Vm(std)=Dry gas volume measured by the DGM, corrected to 
    standard conditions, dry standard cubic meters (dscm), dry standard 
    cubic feet (dscf).
    
        12.2  Mass of Methanol. Calculate the total mass of methanol 
    collected in the sampling train using Equation 308-1.
    [GRAPHIC] [TIFF OMITTED] TR15AP98.015
    
        12.3  Dry Sample Gas Volume, Corrected to Standard Conditions. 
    Calculate the volume of gas sampled at standard conditions using 
    Equation 308-2.
    [GRAPHIC] [TIFF OMITTED] TR15AP98.016
    
        12.4  Mass Emission Rate of Methanol. Calculate the mass emission 
    rate of methanol using Equation 308-3.
    [GRAPHIC] [TIFF OMITTED] TR15AP98.017
    
    13.0  Method Performance [Reserved]
    
    14.0  Pollution Prevention [Reserved]
    
    15.0  Waste Management [Reserved]
    
    16.0  Bibliography
    
        1. Rom, J.J. ``Maintenance, Calibration, and Operation of 
    Isokinetic Source Sampling Equipment.'' Office of Air Programs, 
    Environmental Protection Agency. Research Triangle Park, NC. APTD-0576 
    March 1972.
        2. Annual Book of ASTM Standards. Part 31; Water, Atmospheric 
    Analysis. American Society for Testing and Materials. Philadelphia, PA. 
    1974. pp. 40-42.
        3. Westlin, P.R. and R.T. Shigehara. ``Procedure for Calibrating 
    and Using Dry Gas Volume Meters as Calibration Standards.'' Source 
    Evaluation Society Newsletter. 3(1) :17-30. February 1978.
        4. Yu, K.K. ``Evaluation of Moisture Effect on Dry Gas Meter 
    Calibration.'' Source Evaluation Society Newsletter. 5(1) :24-28. 
    February 1980.
        5. NIOSH Manual of Analytical Methods, Volume 2. U.S. Department of 
    Health and Human Services National Institute for Occupational Safety 
    and Health. Center for Disease Control. 4676
    
    [[Page 18635]]
    
    Columbia Parkway, Cincinnati, OH 45226. (available from the 
    Superintendent of Documents, Government Printing Office, Washington, DC 
    20402.)
        6. Pinkerton, J.E. ``Method for Measuring Methanol in Pulp Mill 
    Vent Gases.'' National Council of the Pulp and Paper Industry for Air 
    and Stream Improvement, Inc., New York, NY.
    
    17.0  Tables, Diagrams, Flowcharts, and Validation Data
    
        [Reserved].
    * * * * *
    
    PART 261--[AMENDED]
    
        1. The authority citation of part 261 continues to read as follows:
    
        Authority: 42 U.S.C. 6905, 6912(a), 6921, 6922, and 6938.
    
        2. Section 261.4 is amended by adding paragraph (a) (15) to read as 
    follows:
    
    
    Sec. 261.4  Exclusions.
    
        (a) * * *
        (15) Condensates derived from the overhead gases from kraft mill 
    steam strippers that are used to comply with 40 CFR 63.446(e). The 
    exemption applies only to combustion at the mill generating the 
    condensates.
    * * * * *
        1. Part 430 is revised to read as follows:
    
    PART 430--THE PULP, PAPER, AND PAPERBOARD POINT SOURCE CATEGORY
    
    General Provisions
    
    Sec.
    430.00  Applicability.
    430.01  General definitions.
    430.02  Monitoring requirements.
    430.03  Best management practices (BMPs) for spent pulping liquor, 
    soap, and turpentine management, spill prevention, and control.
    
    Subpart A--Dissolving Kraft Subcategory
    
    Sec.
    430.10  Applicability; description of the dissolving kraft 
    subcategory.
    430.11  Specialized definitions.
    430.12  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.13  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the best conventional pollutant 
    control technology (BCT).
    430.14  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.15  New source performance standards (NSPS).
    430.16  Pretreatment standards for existing sources (PSES).
    430.17  Pretreatment standards for new sources (PSNS).
    
    Subpart B--Bleached Papergrade Kraft and Soda Subcategory
    
    Sec.
    430.20  Applicability; description of the bleached papergrade kraft 
    and soda subcategory.
    430.21  Specialized definitions.
    430.22  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.23  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.24  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.25  New source performance standards (NSPS).
    430.26  Pretreatment standards for existing sources (PSES).
    430.27  Pretreatment standards for new sources (PSNS).
    430.28  Best management practices (BMPs).
    
    Subpart C--Unbleached Kraft Subcategory
    
    Sec.
    430.30  Applicability; description of the unbleached kraft 
    subcategory.
    430.31  Specialized definitions.
    430.32  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.33  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.34  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.35  New source performance standards (NSPS).
    430.36  Pretreatment standards for existing (PSES).
    430.37  Pretreatment standards for new sources (PSNS).
    
    Subpart D--Dissolving Sulfite Subcategory
    
    Sec.
    430.40  Applicability; description of the dissolving sulfite 
    subcategory.
    430.41  Specialized definitions.
    430.42  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.43  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.44  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.45  New source performance standards (NSPS).
    430.46  Pretreatment standards for existing sources (PSES).
    430.47  Pretreatment standards for new sources (PSNS).
    
    Subpart E--Papergrade Sulfite Subcategory
    
    Sec.
    430.50  Applicability; description of the papergrade sulfite 
    subcategory.
    430.51  Specialized definitions.
    430.52  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.53  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.54  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.55  New source performance standards (NSPS).
    430.56  Pretreatment standards for existing sources (PSES).
    430.57  Pretreatment standards for new sources (PSNS).
    430.58  Best management practices (BMPs).
    
    Subpart F--Semi-Chemical Subcategory
    
    Sec.
    430.60  Applicability; description of the semi-chemical subcategory.
    430.61  Specialized definitions.
    430.62  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.63  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.64  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.65  New source performance standards (NSPS).
    430.66  Pretreatment standards for existing sources (PSES).
    430.67  Pretreatment standards for new sources (PSNS).
    
    Subpart G--Mechanical Pulp Subcategory
    
    Sec.
    430.70  Applicability; description of the mechanical pulp 
    subcategory.
    430.71  Specialized definitions.
    430.72  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    
    [[Page 18636]]
    
    430.73  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.74  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.75  New source performance standards (NSPS).
    430.76  Pretreatment standards for existing sources (PSES).
    430.77  Pretreatment standards for new sources (PSNS).
    
    Subpart H--Non-Wood Chemical Pulp Subcategory
    
    Sec.
    430.80  Applicability; description of the non-wood chemical pulp 
    subcategory.
    430.81  Specialized definitions.
    430.82  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT). [Reserved]
    430.83  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT). [Reserved]
    430.84  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT). [Reserved]
    430.85  New source performance standards (NSPS). [Reserved]
    430.86  Pretreatment standards for existing sources (PSES). 
    [Reserved]
    430.87  Pretreatment standards for new sources (PSNS). [Reserved]
    
    Subpart I--Secondary Fiber Deink Subcategory
    
    Sec.
    430.90  Applicability; description of the secondary fiber deink 
    subcategory.
    430.91  Specialized definitions.
    430.92  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.93  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.94  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.95  New source performance standards (NSPS).
    430.96  Pretreatment standards for existing sources (PSES).
    430.97  Pretreatment standards for new sources (PSNS).
    
    Subpart J--Secondary Fiber Non-Deink Subcategory
    
    Sec.
    430.100  Applicability; description of the secondary fiber non-deink 
    subcategory.
    430.101  Specialized definitions.
    430.102  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.103  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.104  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.105  New source performance standards (NSPS).
    430.106  Pretreatment standards for existing sources (PSES).
    430.107  Pretreatment standards for new sources (PSNS).
    
    Subpart K--Fine and Lightweight Papers From Purchased Pulp Subcategory
    
    Sec.
    430.110  Applicability; description of the fine and lightweight 
    papers from purchased pulp subcategory.
    430.111  Specialized definitions.
    430.112  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.113  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.114  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.115  New source performance standards (NSPS).
    430.116  Pretreatment standards for existing sources (PSES).
    430.117  Pretreatment standards for new sources (PSNS).
    Subpart L--Tissue, Filter, Non-Woven, and Paperboard From Purchased 
    Pulp Subcategory
    Sec.
    430.120  Applicability; description of the tissue, filter, non-
    woven, and paperboard from purchased pulp subcategory.
    430.121  Specialized definitions.
    430.122  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT).
    430.123  Effluent limitations representing the degree of effluent 
    reduction attainable by the best conventional pollutant control 
    technology (BCT).
    430.124  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    430.125  New source performance standards (NSPS).
    430.126  Pretreatment standards for existing sources (PSES).
    430.127  Pretreatment standards for new sources (PSNS).
    
    Appendix A to Part 430--Methods 1650 and 1653
    
        Authority: Sections 301, 304, 306, 307, 308, 402, and 501 of the 
    Clean Water Act, as amended, (33 U.S.C. 1311, 1314, 1316, 1317, 
    1318, 1342, and 1361), and Section 112 of the Clean Air Act, as 
    amended (42 U.S.C. 7412).
    
    General Provisions
    
    
    Sec. 430.00  Applicability.
    
        (a) This part applies to any pulp, paper, or paperboard mill that 
    discharges or may discharge process wastewater pollutants to the waters 
    of the United States, or that introduces or may introduce process 
    wastewater pollutants into a publicly owned treatment works.
        (b) The following table presents the subcategorization scheme 
    codified in this part, with references to former subpart designations 
    contained in the 1997 edition of 40 CFR parts 425 through 699:
    
    [[Page 18637]]
    
    
    
       Subcategorization Scheme With References to Former Subparts Contained in the July 1, 1997 Edition of 40 CFR  
                                                  Parts 425 Through 699                                             
    ----------------------------------------------------------------------------------------------------------------
      Final codified subpart    Final subcategorization scheme        Types of products covered in the subpart      
    ----------------------------------------------------------------------------------------------------------------
    A.........................  Dissolving Kraft..............  Dissolving pulp at kraft mills (Fa)                 
    B.........................  Bleached Papergrade Kraft and   Market pulp at bleached kraft mills (Ga);           
                                 Soda.                           paperboard, coarse paper, and tissue paper at      
                                                                 bleached kraft mills (Ha); pulp and fine papers at 
                                                                 bleached kraft mills (Ia); and pulp and paper at   
                                                                 soda mills (Pa).                                   
    C.........................  Unbleached Kraft..............  Pulp and paper at unbleached kraft mills including  
                                                                 linerboard or bag paper and other mixed products   
                                                                 (Aa); pulp and paper using the unbleached kraft-   
                                                                 neutral sulfite semi-chemical (cross recovery)     
                                                                 process (Da); and pulp and paper at combined       
                                                                 unbleached kraft and semi-chemical mills, wherein  
                                                                 the spent semi-chemical cooking liquor is burned   
                                                                 within the unbleached kraft chemical recovery      
                                                                 system (Va).                                       
    D.........................  Dissolving Sulfite............  Pulp at dissolving sulfite mills for the following  
                                                                 grades: nitration, viscose, cellophane, and acetate
                                                                 (Ka).                                              
    E.........................  Papergrade Sulfite............  Pulp and paper at papergrade sulfite mills where    
                                --Calcium-, Magnesium-, or       blow pit pulp washing techniques are used (Ja) and 
                                 Sodium-based pulps.             pulp and paper at papergrade sulfite mills where   
                                --Ammonium-based pulps.          vacuum or pressure drums are used to wash pulp     
                                --Specialty grade pulps.         (Ua).                                              
    F.........................  Semi-Chemical.................  Pulp and paper at semi-chemical mills using an      
                                                                 ammonia base or a sodium base (Ba).                
    G.........................  Mechanical Pulp...............  Pulp and paper at groundwood chemi-mechanical mills 
                                                                 (La); pulp and paper at groundwood mills through   
                                                                 the application of the thermo-mechanical process   
                                                                 (Ma); pulp and coarse paper, molded pulp products, 
                                                                 and newsprint at groundwood mills (Na); and pulp   
                                                                 and fine paper at groundwood mills (Oa).           
    H.........................  Non-Wood Chemical Pulp........  Pulp and paper at non-wood chemical pulp mills.     
    I.........................  Secondary Fiber Deink.........  Pulp and paper at deink mills including fine papers,
                                                                 tissue papers, or newsprint (Qa).                  
    J.........................  Secondary Fiber Non-Deink.....  Paperboard from wastepaper from noncorrugating      
                                                                 medium furnish or from corrugating medium furnish  
                                                                 (Ea); tissue paper from wastepaper without deinking
                                                                 at secondary fiber mills (Ta); molded products from
                                                                 wastepaper without deinking (Wa); and builders'    
                                                                 paper and roofing felt from wastepaper (40 CFR Part
                                                                 431, Subpart Aa).                                  
    K.........................  Fine and Lightweight Papers     Fine Papers at nonintegrated mills using wood fiber 
                                 from Purchased Pulp.            furnish or cotton fiber furnish (Ra); and          
                                                                 lightweight papers at nonintegrated mills or       
                                                                 lightweight electrical papers at nonintegrated     
                                                                 mills (Xa).                                        
    L.........................  Tissue, Filter, Non-woven, and  Tissue papers at nonintegrated mills (Sa); filter   
                                 Paperboard from Purchased       and non-woven papers at nonintegrated mills (Ya);  
                                 Pulp.                           and paperboard at nonintegrated mills (Za).        
    ----------------------------------------------------------------------------------------------------------------
    a This subpart is contained in the 40 CFR parts 425 through 699, edition revised as of July 1, 1997.            
    
    Sec. 430.01  General definitions.
    
        In addition to the definitions set forth in 40 CFR part 401 and 40 
    CFR 403.3, the following definitions apply to this part:
        (a) Adsorbable organic halides (AOX). A bulk parameter that 
    measures the total mass of chlorinated organic matter in water and 
    wastewater.
        (b) Annual average. The mean concentration, mass loading or 
    production-normalized mass loading of a pollutant over a period of 365 
    consecutive days (or such other period of time determined by the 
    permitting authority to be sufficiently long to encompass expected 
    variability of the concentration, mass loading, or production-
    normalized mass loading at the relevant point of measurement).
        (c) Bleach plant. All process equipment used for bleaching 
    beginning with the first application of bleaching agents (e.g., 
    chlorine, chlorine dioxide, ozone, sodium or calcium hypochlorite, or 
    peroxide), each subsequent extraction stage, and each subsequent stage 
    where bleaching agents are applied to the pulp. For mills in Subpart E 
    of this part producing specialty grades of pulp, the bleach plant 
    includes process equipment used for the hydrolysis or extraction stages 
    prior to the first application of bleaching agents. Process equipment 
    used for oxygen delignification prior to the application of bleaching 
    agents is not part of the bleach plant.
        (d) Bleach plant effluent. The total discharge of process 
    wastewaters from the bleach plant from each physical bleach line 
    operated at the mill, comprising separate acid and alkaline filtrates 
    or the combination thereof.
        (e) Chemical oxygen demand (COD). A bulk parameter that measures 
    the oxygen-consuming capacity of organic and inorganic matter present 
    in water or wastewater. It is expressed as the amount of oxygen 
    consumed from a chemical oxidant in a specific test.
        (f) Elemental chlorine-free (ECF). Any process for bleaching pulps 
    in the absence of elemental chlorine and hypochlorite that uses 
    exclusively chlorine dioxide as the only chlorine-containing bleaching 
    agent.
        (g) End of the pipe. The point at which final mill effluent is 
    discharged to waters of the United States or introduced to a POTW.
        (h) Fiber line. A series of operations employed to convert wood or 
    other fibrous raw material into pulp. If the final product is bleached 
    pulp, the fiber line encompasses pulping, de-knotting, brownstock 
    washing, pulp screening, centrifugal cleaning, and multiple bleaching 
    and washing stages.
        (i) Minimum level (ML). The level at which the analytical system 
    gives recognizable signals and an acceptable calibration point. The 
    following minimum levels apply to pollutants in this part.
    
    [[Page 18638]]
    
    
    
    ------------------------------------------------------------------------
                 Pollutant                Method          Minimum level     
    ------------------------------------------------------------------------
    2,3,7,8-TCDD......................        1613  10 pg/L a               
    2,3,7,8-TCDF......................        1613  10 pg/L a               
    Trichlorosyringol.................        1653  2.5 ug/L b              
    3,4,5-Trichlorocatechol...........        1653  5.0 ug/L b              
    3,4,6-Trichlorocatechol...........        1653  5.0 ug/L b              
    3,4,5-Trichloroguaiacol...........        1653  2.5 ug/L b              
    3,4,6-Trichloroguaiacol...........        1653  2.5 ug/L b              
    4,5,6-Trichloroguaiacol...........        1653  2.5 ug/L b              
    2,4,5-Trichlorophenol.............        1653  2.5 ug/L b              
    2,4,6-Trichlorophenol.............        1653  2.5 ug/L b              
    Tetrachlorocatechol...............        1653  5.0 ug/L b              
    Tetrachloroguaiacol...............        1653  5.0 ug/L b              
    2,3,4,6-Tetrachlorophenol.........        1653  2.5 ug/L b              
    Pentachlorophenol.................        1653  5.0 ug/L b              
    AOX...............................        1650  20 ug/L b               
    ------------------------------------------------------------------------
    a Picograms per liter.                                                  
    b Micrograms per liter.                                                 
    
        (j) New source. (1) Notwithstanding the criteria codified at 40 CFR 
    122.29(b)(1), a source subject to subpart B or E of this part is a 
    ``new source'' if it meets the definition of ``new source'' at 40 CFR 
    122.2 and:
        (i) It is constructed at a site at which no other source is 
    located; or
        (ii) It totally replaces the process or production equipment that 
    causes the discharge of pollutants at an existing source, including the 
    total replacement of a fiber line that causes the discharge of 
    pollutants at an existing source, except as provided in paragraph 
    (j)(2) of this section; or
        (iii) Its processes are substantially independent of an existing 
    source at the same site. In determining whether these processes are 
    substantially independent, the Director shall consider such factors as 
    the extent to which the new facility is integrated with the existing 
    plant; and the extent to which the new facility is engaged in the same 
    general type of activity as the existing source.
        (2) The following are examples of changes made by mills subject to 
    subparts B or E of this part that alone do not cause an existing mill 
    to become a ``new source'':
        (i) Upgrades of existing pulping operations;
        (ii) Upgrades or replacement of pulp screening and washing 
    operations;
        (iii) Installation of extended cooking and/or oxygen 
    delignification systems or other post-digester, pre-bleaching 
    delignification systems;
        (iv) Bleach plant modifications including changes in methods or 
    amounts of chemical applications, new chemical applications, 
    installation of new bleaching towers to facilitate replacement of 
    sodium or calcium hypochlorite, and installation of new pulp washing 
    systems; or
        (v) Total replacement of process or production equipment that 
    causes the discharge of pollutants at an existing source (including a 
    replacement fiber line), but only if such replacement is performed for 
    the purpose of achieving limitations that have been included in the 
    discharger's NPDES permit pursuant to Sec. 430.24(b).
        (k) Non-continuous discharger. (1) Except as provided in paragraph 
    (k)(2) of this section, a non-continuous discharger is a mill which is 
    prohibited by the NPDES authority from discharging pollutants during 
    specific periods of time for reasons other than treatment plant upset 
    control, such periods being at least 24 hours in duration. A mill shall 
    not be deemed a non-continuous discharger unless its permit, in 
    addition to setting forth the prohibition described above, requires 
    compliance with the effluent limitations established for non-continuous 
    dischargers and also requires compliance with maximum day and average 
    of 30 consecutive days effluent limitations. Such maximum day and 
    average of 30 consecutive days effluent limitations for non-continuous 
    dischargers shall be established by the NPDES authority in the form of 
    concentrations which reflect wastewater treatment levels that are 
    representative of the application of the best practicable control 
    technology currently available, the best conventional pollutant control 
    technology, or new source performance standards in lieu of the maximum 
    day and average of 30 consecutive days effluent limitations for 
    conventional pollutants set forth in each subpart.
        (2) A mill is a non-continuous discharger for the purposes of 
    determining applicable effluent limitations under subpart B or E of 
    this part (other than conventional limits for existing sources) if, for 
    reasons other than treatment plant upset control (e.g., protecting 
    receiving water quality), the mill is prohibited by the NPDES authority 
    from discharging pollutants during specific periods of time or if it is 
    required to release its discharge on a variable flow or pollutant 
    loading rate basis.
        (l) POTW. Publicly owned treatment works as defined at 40 CFR 
    403.3(o).
        (m) Process wastewater. For subparts B and E only, process 
    wastewater is any water that, during manufacturing or processing, comes 
    into direct contact with or results from the production or use of any 
    raw material, intermediate product, finished product, byproduct, or 
    waste product. For purposes of subparts B and E of this part, process 
    wastewater includes boiler blowdown; wastewaters from water treatment 
    and other utility operations; blowdowns from high rate (e.g., greater 
    than 98 percent) recycled non-contact cooling water systems to the 
    extent they are mixed and co-treated with other process wastewaters; 
    wastewater, including leachates, from landfills owned by pulp and paper 
    mills subject to subpart B or E of this part if the wastewater is 
    commingled with wastewater from the mill's manufacturing or processing 
    facility; and storm waters from the immediate process areas to the 
    extent they are mixed and co-treated with other process wastewaters. 
    For purposes of this part, contaminated groundwaters from on-site or 
    off-site groundwater remediation projects are not process wastewater.
        (n) Production. (1) For all limitations and standards specified in 
    this part except those pertaining to AOX and chloroform: Production 
    shall be defined as the annual off-the-machine production (including 
    off-the-machine coating where applicable) divided by the number of 
    operating days during that year. Paper and paperboard production shall 
    be measured at the off-the-machine moisture content, except for subpart 
    C of this part (as it pertains to pulp and paperboard production at
    
    [[Page 18639]]
    
    unbleached kraft mills including linerboard or bag paper and other 
    mixed products, and to pulp and paperboard production using the 
    unbleached kraft neutral sulfite semi-chemical (cross recovery) 
    process), and subparts F and J of this part (as they pertain to 
    paperboard production from wastepaper from noncorrugating medium 
    furnish or from corrugating medium furnish) where paper and paperboard 
    production shall be measured in air-dry-tons (10% moisture content). 
    Market pulp shall be measured in air-dry tons (10% moisture). 
    Production shall be determined for each mill based upon past production 
    practices, present trends, or committed growth.
        (2) For AOX and chloroform limitations and standards specified in 
    subparts B and E of this part: Production shall be defined as the 
    annual unbleached pulp production entering the first stage of the 
    bleach plant divided by the number of operating days during that year. 
    Unbleached pulp production shall be measured in air-dried-metric-tons 
    (10% moisture) of brownstock pulp entering the bleach plant at the 
    stage during which chlorine or chlorine-containing compounds are first 
    applied to the pulp. In the case of bleach plants that use totally 
    chlorine free bleaching processes, unbleached pulp production shall be 
    measured in air-dried-metric tons (10% moisture) of brownstock pulp 
    entering the first stage of the bleach plant from which wastewater is 
    discharged. Production shall be determined for each mill based upon 
    past production practices, present trends, or committed growth.
        (o) TCDD. 2,3,7,8-tetrachlorodibenzo-p-dioxin.
        (p) TCDF. 2,3,7,8-tetrachlorodibenzo-p-furan.
        (q) Totally chlorine-free (TCF) bleaching. Pulp bleaching 
    operations that are performed without the use of chlorine, sodium 
    hypochlorite, calcium hypochlorite, chlorine dioxide, chlorine 
    monoxide, or any other chlorine-containing compound.
        (r) Wet Barking. Wet barking operations shall be defined to include 
    hydraulic barking operations and wet drum barking operations which are 
    those drum barking operations that use substantial quantities of water 
    in either water sprays in the barking drums or in a partial submersion 
    of the drums in a ``tub'' of water.
    
    
    Sec. 430.02  Monitoring requirements.
    
        This section establishes minimum monitoring frequencies for certain 
    pollutants. Where no monitoring frequency is specified in this section 
    or where the duration of the minimum monitoring frequency has expired 
    under paragraphs (b) through (e) of this section, the permit writer or 
    pretreatment control authority shall determine the appropriate 
    monitoring frequency in accordance with 40 CFR 122.44(i) or 40 CFR part 
    403, as applicable.
        (a) BAT, NSPS, PSES, and PSNS monitoring frequency for chlorinated 
    organic pollutants. The following monitoring frequencies apply to 
    discharges subject to subpart B or subpart E of this part:
    
    ----------------------------------------------------------------------------------------------------------------
                                                                         Minimum monitoring frequency               
            CAS number                 Pollutant        ------------------------------------------------------------
                                                                    Non-TCFa                        TCFb            
    ----------------------------------------------------------------------------------------------------------------
    1198556..................  Tetrachlorocatechol.....  Monthly......................  (c)                         
    2539175..................  Tetrachloroguaiacol.....  Monthly......................  (c)                         
    2539266..................  Trichlorosyringol.......  Monthly......................  (c)                         
    2668248..................  4,5,6-trichloroguaiacol.  Monthly......................  (c)                         
    32139723.................  3,4,6-trichlorocatechol.  Monthly......................  (c)                         
    56961207.................  3,4,5-trichlorocatechol.  Monthly......................  (c)                         
    57057837.................  3,4,5-trichloroguaiacol.  Monthly......................  (c)                         
    58902....................  2,3,4,6-                  Monthly......................  (c)                         
                                tetrachlorophenol.                                                                  
    60712449.................  3,4,6-trichloroguaiacol.  Monthly......................  (c)                         
    87865....................  Pentachlorophenold......  Monthly......................  (c)                         
    88062....................  2,4,6-trichlorophenold..  Monthly......................  (c)                         
    95954....................  2,4,5-trichlorophenold..  Monthly......................  (c)                         
    1746016..................  2,3,7,8-TCDD............  Monthly......................  (c)                         
    51207319.................  2,3,7,8-TCDF............  Monthly......................  (c)                         
    67663....................  chloroforme.............  Weekly.......................  (c)                         
    59473040.................  AOXf....................  Daily........................  None specified.             
    ----------------------------------------------------------------------------------------------------------------
    a Non-TCF: Pertains to any fiber line that does not use exclusively TCF bleaching processes.                    
    b TCF: Pertains to any fiber line that uses exclusively TCF bleaching processes, as disclosed by the discharger 
      in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22 or, for indirect        
      dischargers, as reported to the pretreatment control authority under 40 CFR 403.12 (b), (d), or (e).          
    c This regulation does not specify a limit for this pollutant for TCF bleaching processes.                      
    d Monitoring frequency does not apply to this compound when used as a biocide. The permitting or pretreatment   
      control authority must determine the appropriate monitoring frequency for this compound, when used as a       
      biocide, under 40 CFR 122.44(i) or 40 CFR Part 403, as applicable.                                            
    e This regulation does not specify a limit for this pollutant for Subpart E mills.                              
    f This regulation does not specify a limit for this pollutant for the ammonium-based or specialty grade sulfite 
      pulp segments of Subpart E.                                                                                   
    
        (b) Duration of required monitoring for BAT, NSPS, PSES, and PSNS. 
    The monitoring frequencies specified in paragraph (a) of this section 
    apply for the following time periods:
        (1) For direct dischargers, a duration of five years commencing on 
    the date the applicable limitations or standards from subpart B or 
    subpart E of this part are first included in the discharger's NPDES 
    permit;
        (2) For existing indirect dischargers, until April 17, 2006;
        (3) For new indirect dischargers, a duration of five years 
    commencing on the date the indirect discharger commences operation.
        (c) Reduced monitoring frequencies for bleach plant pollutants 
    under the Voluntary Advanced Technology Incentives Program. The 
    following monitoring frequencies apply to mills enrolled in the 
    Voluntary Advanced Technology Incentives Program established under 
    subpart B of this part for a duration of five years commencing after 
    achievement of the applicable BAT limitations specified in 
    Sec. 430.24(b)(3) or NSPS specified in Sec. 430.25(c)(1) for the 
    following pollutants, except as noted in footnote f:
    
    [[Page 18640]]
    
    
    
    ----------------------------------------------------------------------------------------------------------------
                                                                  Minimum monitoring frequency                      
       CAS  number          Pollutant     --------------------------------------------------------------------------
                                                  Non-ECF a            Advanced  ECF b,f              TCF c         
    ----------------------------------------------------------------------------------------------------------------
    1198556..........  Tetrachlorocatecho  Monthly................  Monthly                  (d)                    
                        l.                                                                                          
    2539175..........  Tetrachloroguiacol  Monthly................  Monthly                  (d)                    
    2539266..........  Trichlorosyringol.  Monthly................  Monthly                  (d)                    
    2668248..........  4,5,6-              Monthly................  Monthly                  (d)                    
                        trichloroguaiacol.                                                                          
    32139723.........  3,4,6-              Monthly................  Monthly                  (d)                    
                        trichlorocatechol.                                                                          
    56961207.........  3,4,5-              Monthly................  Monthly                  (d)                    
                        trichlorocatechol.                                                                          
    57057837.........  3,4,5-              Monthly................  Monthly                  (d)                    
                        trichloroguaiacol.                                                                          
    58902............  2,3,4,6-            Monthly................  Monthly                  (d)                    
                        tetrachlorophenol.                                                                          
    60712449.........  3,4,6-              Monthly................  Monthly                  (d)                    
                        trichloroguaiacol.                                                                          
    87865............  Pentachlorophenol   Monthly................  Monthly                  (d)                    
                        e.                                                                                          
    88062............  2,4,6-              Monthly................  Monthly                  (d)                    
                        trichlorophenol e.                                                                          
    95954............  2,4,5-              Monthly................  Monthly                  (d)                    
                        trichlorophenol e.                                                                          
    1746016..........  2,3,7,8-TCDD......  Monthly................  Monthly                  (d)                    
    51207319.........  2,3,7,8-TCDF......  Monthly................  Monthly                  (d)                    
    67663............  Chloroform........  Weekly.................  Monthly                  (d)                    
    ----------------------------------------------------------------------------------------------------------------
    a Non-ECF: Pertains to any fiber line that does not use exclusively ECF or TCF bleaching processes.             
    b Advanced ECF: Pertains to any fiber line that uses exclusively Advanced ECF bleaching processes, or           
      exclusively ECF and TCF bleaching processes as disclosed by the discharger in its permit application under 40 
      CFR 122.21(g)(3) and certified under 40 CFR 122.22. Advanced ECF consists of the use of extended              
      delignification or other technologies that achieve at least the Tier I performance levels specified in Sec.   
      430.24(b)(4)(i).                                                                                              
    c TCF: Pertains to any fiber line that uses exclusively TCF bleaching processes, as disclosed by the discharger 
      in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22.                        
    d This regulation does not specify a limit for this pollutant for TCF bleaching processes.                      
    e Monitoring frequency does not apply to this compound when used as a biocide. The permitting authority must    
      determine the appropriate monitoring frequency for this compound, when used as a biocide, under 40 CFR        
      122.44(i).                                                                                                    
    f Monitoring requirements for these pollutants by mills certifying as Advanced ECF in their NPDES permit        
      application or other communication to the permitting authority will be suspended after one year of monitoring.
      The permitting authority must determine the appropriate monitoring frequency for these pollutants beyond that 
      time under 40 CFR 122.44(i).                                                                                  
    
        (d) Reduced monitoring frequencies for AOX under the Voluntary 
    Advanced Technology Incentives Program (year one). The following 
    monitoring frequencies apply to direct dischargers enrolled in the 
    Voluntary Advanced Technology Incentives Program established under 
    Subpart B of this part for a duration of one year after achievement of 
    the applicable BAT limitations specified in Sec. 430.24(b)(4)(i) or 
    NSPS specified in Sec. 430.25(c)(2):
    
    ----------------------------------------------------------------------------------------------------------------
                                                                    Advanced ECF,  any tier                         
       CAS  number          Pollutant        Non-ECF,  any tier a              b                 TCF,  any tier c   
    ----------------------------------------------------------------------------------------------------------------
    59473040.........  AOX...............  Daily..................  Weekly.................  None specified.        
    ----------------------------------------------------------------------------------------------------------------
    a Non-ECF: Pertains to any fiber line that does not use exclusively ECF or TCF bleaching processes.             
    b Advanced ECF: Pertains to any fiber line that uses exclusively Advanced ECF bleaching processes or exclusively
      ECF and TCF bleaching processes, as disclosed by the discharger in its permit application under 40 CFR        
      122.21(g)(3) and certified under 40 CFR 122.22. Advanced ECF consists of the use of extended delignification  
      or other technologies that achieve at least the Tier I performance levels specified in Sec.  430.24(b)(4)(i). 
    c TCF: Pertains to any fiber line that uses exclusively TCF bleaching processes, as disclosed by the discharger 
      in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22.                        
    
        (e) Reduced monitoring frequencies for AOX under the Voluntary 
    Advanced Technology Incentives Program (years two through five). The 
    following monitoring frequencies apply to mills enrolled in the 
    Voluntary Advanced Technology Incentives Program established under 
    Subpart B of this part for a duration of four years starting one year 
    after achievement of the applicable BAT limitations specified in 
    Sec. 430.24(b)(4)(i) or NSPS specified in Sec. 430.25(c)(2):
    
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                      Advanced ECF--tier I   Advanced ECF--tier    Advanced ECF--tier                       
        CAS number            Pollutant         Non-ECF  any tier a             b                   II b                  III b           TCF-- any tier c  
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    59473040..........  AOX..................  Daily................  Monthly.............  Quarterly...........  Annually............  None specified.     
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    a Non-ECF: Pertains to any fiber line that does not use exclusively ECF or TCF bleaching processes.                                                     
    b Advanced ECF: Pertains to any fiber line that uses exclusively Advanced ECF bleaching processes or exclusively ECF and TCF bleaching processes, as    
      disclosed by the discharger in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22. Advanced ECF consists of the use of
      extended delignification or other technologies that achieve at least the Tier I performance levels specified in Sec.  430.24(b)(4)(i).                
    c TCF: Pertains to any fiber line that uses exclusively TCF bleaching processes, as disclosed by the discharger in its permit application under 40 CFR  
      122.21(g)(3) and certified under 40 CFR 122.22.                                                                                                       
    
    
    [[Page 18641]]
    
    Sec. 430.03  Best management practices (BMPs) for spent pulping liquor, 
    soap, and turpentine management, spill prevention, and control.
    
        (a) Applicability. This section applies to direct and indirect 
    discharging pulp, paper, and paperboard mills with pulp production in 
    subparts B (Bleached Papergrade Kraft and Soda) and E (Papergrade 
    Sulfite).
        (b) Specialized definitions. (1) Action Level: A daily pollutant 
    loading that when exceeded triggers investigative or corrective action. 
    Mills determine action levels by a statistical analysis of six months 
    of daily measurements collected at the mill. For example, the lower 
    action level may be the 75th percentile of the running seven-day 
    averages (that value exceeded by 25 percent of the running seven-day 
    averages) and the upper action level may be the 90th percentile of the 
    running seven-day averages (that value exceeded by 10 percent of the 
    running seven-day averages).
        (2) Equipment Items in Spent Pulping Liquor, Soap, and Turpentine 
    Service: Any process vessel, storage tank, pumping system, evaporator, 
    heat exchanger, recovery furnace or boiler, pipeline, valve, fitting, 
    or other device that contains, processes, transports, or comes into 
    contact with spent pulping liquor, soap, or turpentine. Sometimes 
    referred to as ``equipment items.''
        (3) Immediate Process Area: The location at the mill where pulping, 
    screening, knotting, pulp washing, pulping liquor concentration, 
    pulping liquor processing, and chemical recovery facilities are 
    located, generally the battery limits of the aforementioned processes. 
    ``Immediate process area'' includes spent pulping liquor storage and 
    spill control tanks located at the mill, whether or not they are 
    located in the immediate process area.
        (4) Intentional Diversion: The planned removal of spent pulping 
    liquor, soap, or turpentine from equipment items in spent pulping 
    liquor, soap, or turpentine service by the mill for any purpose 
    including, but not limited to, maintenance, grade changes, or process 
    shutdowns.
        (5) Mill: The owner or operator of a direct or indirect discharging 
    pulp, paper, or paperboard manufacturing facility subject to this 
    section.
        (6) Senior Technical Manager: The person designated by the mill 
    manager to review the BMP Plan. The senior technical manager shall be 
    the chief engineer at the mill, the manager of pulping and chemical 
    recovery operations, or other such responsible person designated by the 
    mill manager who has knowledge of and responsibility for pulping and 
    chemical recovery operations.
        (7) Soap: The product of reaction between the alkali in kraft 
    pulping liquor and fatty acid portions of the wood, which precipitate 
    out when water is evaporated from the spent pulping liquor.
        (8) Spent Pulping Liquor: For kraft and soda mills ``spent pulping 
    liquor'' means black liquor that is used, generated, stored, or 
    processed at any point in the pulping and chemical recovery processes. 
    For sulfite mills ``spent pulping liquor'' means any intermediate, 
    final, or used chemical solution that is used, generated, stored, or 
    processed at any point in the sulfite pulping and chemical recovery 
    processes (e.g., ammonium-, calcium-, magnesium-, or sodium-based 
    sulfite liquors).
        (9) Turpentine: A mixture of terpenes, principally pinene, obtained 
    by the steam distillation of pine gum recovered from the condensation 
    of digester relief gases from the cooking of softwoods by the kraft 
    pulping process. Sometimes referred to as sulfate turpentine.
        (c) Requirement to implement Best Management Practices. Each mill 
    subject to this section must implement the Best Management Practices 
    (BMPs) specified in paragraphs (c)(1) through (10) of this section. The 
    primary objective of the BMPs is to prevent leaks and spills of spent 
    pulping liquors, soap, and turpentine. The secondary objective is to 
    contain, collect, and recover at the immediate process area, or 
    otherwise control, those leaks, spills, and intentional diversions of 
    spent pulping liquor, soap, and turpentine that do occur. BMPs must be 
    developed according to best engineering practices and must be 
    implemented in a manner that takes into account the specific 
    circumstances at each mill. The BMPs are as follows:
        (1) The mill must return spilled or diverted spent pulping liquors, 
    soap, and turpentine to the process to the maximum extent practicable 
    as determined by the mill, recover such materials outside the process, 
    or discharge spilled or diverted material at a rate that does not 
    disrupt the receiving wastewater treatment system.
        (2) The mill must establish a program to identify and repair 
    leaking equipment items. This program must include:
        (i) Regular visual inspections (e.g., once per day) of process 
    areas with equipment items in spent pulping liquor, soap, and 
    turpentine service;
        (ii) Immediate repairs of leaking equipment items, when possible. 
    Leaking equipment items that cannot be repaired during normal 
    operations must be identified, temporary means for mitigating the leaks 
    must be provided, and the leaking equipment items repaired during the 
    next maintenance outage;
        (iii) Identification of conditions under which production will be 
    curtailed or halted to repair leaking equipment items or to prevent 
    pulping liquor, soap, and turpentine leaks and spills; and
        (iv) A means for tracking repairs over time to identify those 
    equipment items where upgrade or replacement may be warranted based on 
    frequency and severity of leaks, spills, or failures.
        (3) The mill must operate continuous, automatic monitoring systems 
    that the mill determines are necessary to detect and control leaks, 
    spills, and intentional diversions of spent pulping liquor, soap, and 
    turpentine. These monitoring systems should be integrated with the mill 
    process control system and may include, e.g., high level monitors and 
    alarms on storage tanks; process area conductivity (or pH) monitors and 
    alarms; and process area sewer, process wastewater, and wastewater 
    treatment plant conductivity (or pH) monitors and alarms.
        (4) The mill must establish a program of initial and refresher 
    training of operators, maintenance personnel, and other technical and 
    supervisory personnel who have responsibility for operating, 
    maintaining, or supervising the operation and maintenance of equipment 
    items in spent pulping liquor, soap, and turpentine service. The 
    refresher training must be conducted at least annually and the training 
    program must be documented.
        (5) The mill must prepare a brief report that evaluates each spill 
    of spent pulping liquor, soap, or turpentine that is not contained at 
    the immediate process area and any intentional diversion of spent 
    pulping liquor, soap, or turpentine that is not contained at the 
    immediate process area. The report must describe the equipment items 
    involved, the circumstances leading to the incident, the effectiveness 
    of the corrective actions taken to contain and recover the spill or 
    intentional diversion, and plans to develop changes to equipment and 
    operating and maintenance practices as necessary to prevent recurrence. 
    Discussion of the reports must be included as part of the annual 
    refresher training.
        (6) The mill must establish a program to review any planned 
    modifications to the pulping and chemical recovery facilities and any 
    construction activities in the pulping and chemical recovery areas 
    before these activities commence. The purpose of such review is to 
    prevent leaks and spills of spent
    
    [[Page 18642]]
    
    pulping liquor, soap, and turpentine during the planned modifications, 
    and to ensure that construction and supervisory personnel are aware of 
    possible liquor diversions and of the requirement to prevent leaks and 
    spills of spent pulping liquors, soap, and turpentine during 
    construction.
        (7) The mill must install and maintain secondary containment (i.e., 
    containment constructed of materials impervious to pulping liquors) for 
    spent pulping liquor bulk storage tanks equivalent to the volume of the 
    largest tank plus sufficient freeboard for precipitation. An annual 
    tank integrity testing program, if coupled with other containment or 
    diversion structures, may be substituted for secondary containment for 
    spent pulping liquor bulk storage tanks.
        (8) The mill must install and maintain secondary containment for 
    turpentine bulk storage tanks.
        (9) The mill must install and maintain curbing, diking or other 
    means of isolating soap and turpentine processing and loading areas 
    from the wastewater treatment facilities.
        (10) The mill must conduct wastewater monitoring to detect leaks 
    and spills, to track the effectiveness of the BMPs, and to detect 
    trends in spent pulping liquor losses. Such monitoring must be 
    performed in accordance with paragraph (i) of this section.
        (d) Requirement to develop a BMP Plan. (1) Each mill subject to 
    this section must prepare and implement a BMP Plan. The BMP Plan must 
    be based on a detailed engineering review as described in paragraphs 
    (d)(2) and (3) of this section. The BMP Plan must specify the 
    procedures and the practices required for each mill to meet the 
    requirements of paragraph (c) of this section, the construction the 
    mill determines is necessary to meet those requirements including a 
    schedule for such construction, and the monitoring program (including 
    the statistically derived action levels) that will be used to meet the 
    requirements of paragraph (i) of this section. The BMP Plan also must 
    specify the period of time that the mill determines the action levels 
    established under paragraph (h) of this section may be exceeded without 
    triggering the responses specified in paragraph (i) of this section.
        (2) Each mill subject to this section must conduct a detailed 
    engineering review of the pulping and chemical recovery operations--
    including but not limited to process equipment, storage tanks, 
    pipelines and pumping systems, loading and unloading facilities, and 
    other appurtenant pulping and chemical recovery equipment items in 
    spent pulping liquor, soap, and turpentine service--for the purpose of 
    determining the magnitude and routing of potential leaks, spills, and 
    intentional diversions of spent pulping liquors, soap, and turpentine 
    during the following periods of operation:
        (i) Process start-ups and shut downs;
        (ii) Maintenance;
        (iii) Production grade changes;
        (iv) Storm or other weather events;
        (v) Power failures; and
        (vi) Normal operations.
        (3) As part of the engineering review, the mill must determine 
    whether existing spent pulping liquor containment facilities are of 
    adequate capacity for collection and storage of anticipated intentional 
    liquor diversions with sufficient contingency for collection and 
    containment of spills. The engineering review must also consider:
        (i) The need for continuous, automatic monitoring systems to detect 
    and control leaks and spills of spent pulping liquor, soap, and 
    turpentine;
        (ii) The need for process wastewater diversion facilities to 
    protect end-of-pipe wastewater treatment facilities from adverse 
    effects of spills and diversions of spent pulping liquors, soap, and 
    turpentine;
        (iii) The potential for contamination of storm water from the 
    immediate process areas; and
        (iv) The extent to which segregation and/or collection and 
    treatment of contaminated storm water from the immediate process areas 
    is appropriate.
        (e) Amendment of BMP Plan. (1) Each mill subject to this section 
    must amend its BMP Plan whenever there is a change in mill design, 
    construction, operation, or maintenance that materially affects the 
    potential for leaks or spills of spent pulping liquor, turpentine, or 
    soap from the immediate process areas.
        (2) Each mill subject to this section must complete a review and 
    evaluation of the BMP Plan five years after the first BMP Plan is 
    prepared and, except as provided in paragraph (e)(1) of this section, 
    once every five years thereafter. As a result of this review and 
    evaluation, the mill must amend the BMP Plan within three months of the 
    review if the mill determines that any new or modified management 
    practices and engineered controls are necessary to reduce significantly 
    the likelihood of spent pulping liquor, soap, and turpentine leaks, 
    spills, or intentional diversions from the immediate process areas, 
    including a schedule for implementation of such practices and controls.
        (f) Review and certification of BMP Plan. The BMP Plan, and any 
    amendments thereto, must be reviewed by the senior technical manager at 
    the mill and approved and signed by the mill manager. Any person 
    signing the BMP Plan or its amendments must certify to the permitting 
    or pretreatment control authority under penalty of law that the BMP 
    Plan (or its amendments) has been prepared in accordance with good 
    engineering practices and in accordance with this regulation. The mill 
    is not required to obtain approval from the permitting or pretreatment 
    control authority of the BMP Plan or any amendments thereto.
        (g) Record keeping requirements. (1) Each mill subject to this 
    section must maintain on its premises a complete copy of the current 
    BMP Plan and the records specified in paragraph (g)(2) of this section 
    and must make such BMP Plan and records available to the permitting or 
    pretreatment control authority and the Regional Administrator or his or 
    her designee for review upon request.
        (2) The mill must maintain the following records for three years 
    from the date they are created:
        (i) Records tracking the repairs performed in accordance with the 
    repair program described in paragraph (c)(2) of this section;
        (ii) Records of initial and refresher training conducted in 
    accordance with paragraph (c)(4) of this section;
        (iii) Reports prepared in accordance with paragraph (c)(5) of this 
    section; and
        (iv) Records of monitoring required by paragraphs (c)(10) and (i) 
    of this section.
        (h) Establishment of wastewater treatment system influent action 
    levels. (1) Each mill subject to this section must conduct a monitoring 
    program, described in paragraph (h)(2) of this section, for the purpose 
    of defining wastewater treatment system influent characteristics (or 
    action levels), described in paragraph (h)(3) of this section, that 
    will trigger requirements to initiate investigations on BMP 
    effectiveness and to take corrective action.
        (2) Each mill subject to this section must employ the following 
    procedures in order to develop the action levels required by paragraph 
    (h) of this section:
        (i) Monitoring parameters. The mill must collect 24-hour composite 
    samples and analyze the samples for a measure of organic content (e.g., 
    Chemical Oxygen Demand (COD) or Total Organic Carbon (TOC)). 
    Alternatively, the mill may use a measure related to spent pulping 
    liquor losses measured continuously and averaged over 24 hours (e.g., 
    specific conductivity or color).
    
    [[Page 18643]]
    
        (ii) Monitoring locations. For direct dischargers, monitoring must 
    be conducted at the point influent enters the wastewater treatment 
    system. For indirect dischargers monitoring must be conducted at the 
    point of discharge to the POTW. For the purposes of this requirement, 
    the mill may select alternate monitoring point(s) in order to isolate 
    possible sources of spent pulping liquor, soap, or turpentine from 
    other possible sources of organic wastewaters that are tributary to the 
    wastewater treatment facilities (e.g., bleach plants, paper machines 
    and secondary fiber operations).
        (3) By the date prescribed in paragraph (j)(1)(iii) of this 
    section, each existing discharger subject to this section must complete 
    an initial six-month monitoring program using the procedures specified 
    in paragraph (h)(2) of this section and must establish initial action 
    levels based on the results of that program. A wastewater treatment 
    influent action level is a statistically determined pollutant loading 
    determined by a statistical analysis of six months of daily 
    measurements. The action levels must consist of a lower action level, 
    which if exceeded will trigger the investigation requirements described 
    in paragraph (i) of this section, and an upper action level, which if 
    exceeded will trigger the corrective action requirements described in 
    paragraph (i) of this section.
        (4) By the date prescribed in paragraph (j)(1)(vi) of this section, 
    each existing discharger must complete a second six-month monitoring 
    program using the procedures specified in paragraph (h)(2) of this 
    section and must establish revised action levels based on the results 
    of that program. The initial action levels shall remain in effect until 
    replaced by revised action levels.
        (5) By the date prescribed in paragraph (j)(2) of this section, 
    each new source subject to this section must complete a six-month 
    monitoring program using the procedures specified in paragraph (h)(2) 
    of this section and must develop a lower action level and an upper 
    action level based on the results of that program.
        (6) Action levels developed under this paragraph must be revised 
    using six months of monitoring data after any change in mill design, 
    construction, operation, or maintenance that materially affects the 
    potential for leaks or spills of spent pulping liquor, soap, or 
    turpentine from the immediate process areas.
        (i) Monitoring, corrective action, and reporting requirements. (1) 
    Each mill subject to this section must conduct daily monitoring of the 
    influent to the wastewater treatment system in accordance with the 
    procedures described in paragraph (h)(2) of this section for the 
    purpose of detecting leaks and spills, tracking the effectiveness of 
    the BMPs, and detecting trends in spent pulping liquor losses.
        (2) Whenever monitoring results exceed the lower action level for 
    the period of time specified in the BMP Plan, the mill must conduct an 
    investigation to determine the cause of such exceedance. Whenever 
    monitoring results exceed the upper action level for the period of time 
    specified in the BMP Plan, the mill must complete corrective action to 
    bring the wastewater treatment system influent mass loading below the 
    lower action level as soon as practicable.
        (3) Although exceedances of the action levels will not constitute 
    violations of an NPDES permit or pretreatment standard, failure to take 
    the actions required by paragraph (i)(2) of this section as soon as 
    practicable will be a permit or pretreatment standard violation.
        (4) Each mill subject to this section must report to the NPDES 
    permitting or pretreatment control authority the results of the daily 
    monitoring conducted pursuant to paragraph (i)(1) of this section. Such 
    reports must include a summary of the monitoring results, the number 
    and dates of exceedances of the applicable action levels, and brief 
    descriptions of any corrective actions taken to respond to such 
    exceedances. Submission of such reports shall be at the frequency 
    established by the NPDES permitting or pretreatment control authority, 
    but in no case less than once per year.
        (j) Compliance deadlines. (1) Existing direct and indirect 
    dischargers. Except as provided in paragraph (j)(2) of this section for 
    new sources, indirect discharging mills subject to this section must 
    meet the deadlines set forth below. Except as provided in paragraph 
    (j)(2) of this section for new sources, NPDES permits must require 
    direct discharging mills subject to this section to meet the deadlines 
    set forth below. If a deadline set forth below has passed at the time 
    the NPDES permit containing the BMP requirement is issued, the NPDES 
    permit must require immediate compliance with such BMP requirement(s).
        (i) Prepare BMP Plans and certify to the permitting or pretreatment 
    authority that the BMP Plan has been prepared in accordance with this 
    regulation not later than April 15, 1999;
        (ii) Implement all BMPs specified in paragraph (c) of this section 
    that do not require the construction of containment or diversion 
    structures or the installation of monitoring and alarm systems not 
    later than April 15, 1999.
        (iii) Establish initial action levels required by paragraph (h)(3) 
    of this section not later than April 15, 1999.
        (iv) Commence operation of any new or upgraded continuous, 
    automatic monitoring systems that the mill determines to be necessary 
    under paragraph (c)(3) of this section (other than those associated 
    with construction of containment or diversion structures) not later 
    than April 17, 2000. 
        (v) Complete construction and commence operation of any spent 
    pulping liquor, collection, containment, diversion, or other 
    facilities, including any associated continuous monitoring systems, 
    necessary to fully implement BMPs specified in paragraph (c) of this 
    section not later than April 16, 2001.
        (vi) Establish revised action levels required by paragraph (h)(4) 
    of this section as soon as possible after fully implementing the BMPs 
    specified in paragraph (c) of this section, but not later than January 
    15, 2002.
        (2) New Sources. Upon commencing discharge, new sources subject to 
    this section must implement all of the BMPs specified in paragraph (c) 
    of this section, prepare the BMP Plan required by paragraph (d) of this 
    section, and certify to the permitting or pretreatment authority that 
    the BMP Plan has been prepared in accordance with this regulation as 
    required by paragraph (f) of this section, except that the action 
    levels required by paragraph (h)(5) of this section must be established 
    not later than 12 months after commencement of discharge, based on six 
    months of monitoring data obtained prior to that date in accordance 
    with the procedures specified in paragraph (h)(2) of this section.
    
    Subpart A--Dissolving Kraft Subcategory
    
    
    Sec. 430.10  Applicability; description of the dissolving kraft 
    subcategory.
    
        The provisions of this subpart apply to discharges resulting from 
    the production of dissolving pulp at kraft mills.
    
    
    Sec. 430.11  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    [[Page 18644]]
    
    Sec. 430.12  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
                                    Subpart A                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of             
                                                       daily         Non-   
                                       Maximum for   values for   continuous
                                        any 1 day        30      dischargers
                                                    consecutive             
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         23.6        12.25         6.88
    TSS..............................         37.3        20.05        11.02
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (b) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of wet barking operations, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days 
    limitations, but shall be subject to annual average effluent 
    limitations:
    
                                    Subpart A                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ---------------------------     Non-    
    Pollutant or pollutant property                Average of    continuous 
                                                  daily values   dischargers
                                     Maximum for     for 30        (annual  
                                      any 1 day    consecutive    average)  
                                                      days                  
    ------------------------------------------------------------------------
    BOD5...........................          3.2          1.7           0.95
    TSS............................          6.9          3.75          2.0 
    pH.............................        (\1\)      (\1\)         (\1\)   
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (c) The following limitations establish the quantity or quality of 
    pollutants or pollutant parameters, controlled by this section, 
    resulting from the use of log washing or chip washing operations, which 
    may be discharged by a point source subject to the provisions of this 
    subpart. These limitations are in addition to the limitations set forth 
    in paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs and/or 
    chips which are subject to such operations. Non-continuous dischargers 
    shall not be subject to the maximum day and average of 30 consecutive 
    days limitations, but shall be subject to the annual average effluent 
    limitations:
    
    [[Page 18645]]
    
    
    
                                    Subpart A                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         0.35          0.2          0.1
    TSS..............................         0.70          0.4          0.2
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (d) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of log flumes or log ponds, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days 
    limitations but shall be subject to the annual average effluent 
    limitations:
    
                                    Subpart A                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.6           0.35          0.2
    TSS............................          1.45          0.8           0.4
    pH.............................      (\1\)         (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    Sec. 430.13  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT): The limitations shall be the same as those 
    specified for conventional pollutants (which are defined in 40 CFR 
    401.16) in Sec. 430.12 of this subpart for the best practicable control 
    technology currently available (BPT).
    
    
    Sec. 430.14  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb) but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
    [[Page 18646]]
    
    
    
                                    Subpart A                               
                           [BAT effluent limitations]                       
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      Kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0025  (0.011)(55.1)/y            
    Trichlorophenol..............        0.016   (0.068)(55.1)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    Sec. 430.15  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides:
    
                                    Subpart A                               
                                     [NSPS]                                 
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         15.6          8.4          4.4
    TSS..............................         27.3         14.3          7.5
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                          Maximum for any 1 day                     
                                                    ----------------------------------------------------------------
                                                      Kg/kkg (or                                                    
                                                      pounds per                                                    
                                                      1,000 lb)                    Milligrams/liter                 
                                                      of product                                                    
    Pentachlorophenol..............................       0.0025  (0.012)(50.7)/y                                   
    Trichlorophenol................................       0.016   (0.074)(50.7)/y                                   
    y = wastewater discharged in kgal per ton at                                                                    
     all times.                                                                                                     
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.16  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides. PSES must be attained 
    on or before July 1, 1984:
    
    [[Page 18647]]
    
    
    
                                                        Subpart A                                                   
                                                         [PSES]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                         Kg/kkg (or 
            Pollutant or pollutant property                                                              pounds per 
                                                                  Milligrams/liter (mg/l)               1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.............................  (0.011)(55.1)/y...................................        0.0025
    Trichlorophenol...............................  (0.082)(55.1)/y...................................        0.019 
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Sec. 430.17  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart A                                                   
                                                         [PSNS]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                         Kg/kkg (or 
            Pollutant or pollutant property                                                              pounds per 
                                                                  Milligrams/liter (mg/l)               1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.............................  (0.012)(50.7)/y...................................        0.0025
    Trichlorophenol...............................  (0.089)(50.7)/y...................................        0.019 
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Subpart B--Bleached Papergrade Kraft and Soda Subcategory
    
    
    Sec. 430.20  Applicability; description of the bleached papergrade 
    kraft and soda subcategory.
    
        The provisions of this subpart apply to discharges resulting from: 
    the production of market pulp at bleached kraft mills; the integrated 
    production of paperboard, coarse paper, and tissue paper at bleached 
    kraft mills; the integrated production of pulp and fine papers at 
    bleached kraft mills; and the integrated production of pulp and paper 
    at soda mills.
    
    
    Sec. 430.21  Specialized definitions.
    
        (a) The general definitions, abbreviations, and methods of analysis 
    set forth in 40 CFR part 401 and Sec. 430.01 of this part apply to this 
    subpart.
        (b) Baseline BAT limitations or NSPS means the BAT limitations 
    specified in Sec. 430.24(a) (1) or (2), as applicable, and the NSPS 
    specified in Sec. 430.25(b) (1) or (2), as applicable, that apply to 
    any direct discharger that is not ``enrolled'' in the ``Voluntary 
    Advanced Technology Incentives Program.''
        (c) Enroll means to notify the permitting authority that a mill 
    intends to participate in the ``Voluntary Advanced Technology 
    Incentives Program.'' A mill can enroll by indicating its intention to 
    participate in the program either as part of its application for a 
    National Pollutant Discharge Elimination System (NPDES) permit, or 
    through separate correspondence to the permitting authority as long as 
    the mill signs the correspondence in accordance with 40 CFR 122.22.
        (d) Existing effluent quality means the level at which the 
    pollutants identified in Sec. 430.24(a)(1) are present in the effluent 
    of a mill ``enrolled'' in the ``Voluntary Advanced Technology 
    Incentives Program.''
        (e) Kappa number is a measure of the lignin content in unbleached 
    pulp, determined after pulping and prior to bleaching.
        (f) Voluntary Advanced Technology Incentives Program is the program 
    established under Sec. 430.24(b) (for existing direct dischargers) and 
    Sec. 430.25(c) (for new direct dischargers) whereby participating mills 
    agree to accept enforceable effluent limitations and conditions in 
    their NPDES permits that are more stringent than the ``baseline BAT 
    limitations or NSPS'' that would otherwise apply, in exchange for 
    regulatory- and enforcement-related rewards and incentives.
    
    
    Sec. 430.22  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT):
    
    [[Page 18648]]
    
    
    
                                    Subpart B                               
      [BPT effluent limitations for bleached kraft facilities where market  
                                pulp is produced]                           
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................         15.45          8.05         4.52
    TSS............................         30.4          16.4          9.01
    pH.............................      (\1\)         (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
          [BPT effluent limitations for bleached kraft facilities where     
            paperboard, coarse paper, and tissue paper are produced]        
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------            
    Pollutant or pollutant parameter                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5............................         13.65          7.1         3.99
    TSS.............................         24.0          12.9         7.09
    pH..............................      (\1\)           (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for bleached kraft facilities where pulp and 
                            fine papers are produced]                       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant parameter                Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         10.6          5.5         3.09
    TSS..............................        22.15         11.9         6.54
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for soda facilities where pulp and paper are 
                                    produced]                               
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant parameter                Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         13.7          7.1         3.99
    TSS..............................         24.5         13.2         7.25
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
    [[Page 18649]]
    
        (b) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of wet barking operations, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations:
    
                                    Subpart B                               
      [BPT effluent limitations for bleached kraft facilities where market  
                                pulp is produced]                           
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------     Non-   
    Pollutant or pollutant parameter                Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................          2.3          1.2          0.70
    TSS.............................          5.3          2.85         1.55
    pH..............................        (\1\)      (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
          [BPT effluent limitations for bleached kraft facilities where     
            paperboard, coarse paper, and tissue paper are produced]        
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant parameter                Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         2.25          1.2         0.65
    TSS..............................         5.75          3.1         1.70
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\1 Within the range of 5.0 to 9.0 at all times.                       
    
    
                                    Subpart B                               
     [BPT effluent limitations for bleached kraft facilities where pulp and 
                            fine papers are produced]                       
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          1.95          1.0          0.55
    TSS............................          5.3           2.85         1.55
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for soda facilities where pulp and papers are
                                    produced]                               
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          2.05          1.1          0.60
    
    [[Page 18650]]
    
                                                                            
    TSS............................          5.25          2.8          1.55
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (c) The following limitations establish the quantity or quality of 
    pollutants or pollutant parameters, controlled by this section, 
    resulting from the use of log washing or chip washing operations, which 
    may be discharged by a point source subject to the provisions of this 
    subpart. These limitations are in addition to the limitations set forth 
    in paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs and/or 
    chips which are subject to such operations:
    
                                    Subpart B                               
      [BPT effluent limitations for bleached kraft facilities where market  
                                pulp is produced]                           
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.2           0.1           0.1
    TSS............................          0.6           0.3          0.15
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times..                       
    
    
                                    Subpart B                               
          [BPT effluent limitations for bleached kraft facilities where     
            paperboard, coarse paper, and tissue paper are produced]        
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.25          0.15         0.05
    TSS............................          0.65          0.35         0.20
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for bleached kraft facilities where pulp and 
                            fine papers are produced]                       
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.2           0.1          0.05
    TSS............................          0.55          0.3          0.15
    
    [[Page 18651]]
    
                                                                            
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for soda facilities where pulp and papers are
                                    produced]                               
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.15          0.1          0.05
    TSS............................          0.5           0.25         0.15
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (d) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of log flumes or log ponds, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations:
    
                                    Subpart B                               
      [BPT effluent limitations for bleached kraft facilities where market  
                                pulp is produced]                           
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.4           0.2          0.15
    TSS............................          1.15          0.6          0.35
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
          [BPT effluent limitations for bleached kraft facilities where     
            paperboard, coarse paper, and tissue paper are produced]        
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
         Pollutant or pollutant     ----------------------------     Non-   
               parameter                            Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.45          0.25         0.10
    TSS............................          1.25          0.7          0.35
    
    [[Page 18652]]
    
                                                                            
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for bleached kraft facilities where pulp and 
                            fine papers are produced]                       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant parameter                Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         0.35          0.2         0.10
    TSS..............................         1.15          0.6         0.30
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
     [BPT effluent limitations for soda facilities where pulp and papers are
                                    produced]                               
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant parameter                Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................          0.3          0.2         0.10
    TSS..............................          1.1         0.55         0.35
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\Within the range of 5.0 to 9.0 at all times.                         
    
    Sec. 430.23  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best conventional 
    pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT). The limitations shall be the same as those 
    specified in Sec. 430.22 of this subpart for the best practicable 
    control technology currently available (BPT).
    
    
    Sec. 430.24  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best available technology 
    economically achievable (BAT).
        (a) Except as provided in paragraph (b) of this section--
        (1) The following effluent limitations apply with respect to each 
    fiber line that does not use an exclusively TCF bleaching process, as 
    disclosed by the discharger in its NPDES permit application under 40 
    CFR 122.21(g)(3) and certified under 40 CFR 122.22:
    
    [[Page 18653]]
    
    
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                               BAT effluent limitations             
                                                                ----------------------------------------------------
                  Pollutant or pollutant property                                                          Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    TCDD.......................................................  a                                           (b)
    TCDF.......................................................  31.9 c                                          (b)
    Chloroform.................................................  6.92 d                                     4.14 (d)
    Trichlorosyringol..........................................  a                                           (b)
    3,4,5-trichlorocatechol....................................  a                                           (b)
    3,4,6-trichlorocatechol....................................  a                                           (b)
    3,4,5-trichloroguaiacol....................................  a                                           (b)
    3,4,6-trichloroguaiacol....................................  a                                           (b)
    4,5,6-trichloroguaiacol....................................  a                                           (b)
    2,4,5-trichlorophenol......................................  a                                           (b)
    2,4,6-trichlorophenol......................................  a                                           (b)
    Tetrachlorocatechol........................................  a                                           (b)
    Tetrachloroguaiacol........................................  a                                           (b)
    2,3,4,6-tetrachlorophenol..................................  a                                           (b)
    Pentachlorophenol..........................................  a                                           (b)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                            
                                        Continuous dischargers       Non-   
                                      --------------------------  continuous
                                                                 dischargers
                                       Maximum for    Monthly   ------------
                                        any 1 day   average (kg/    Annual  
                                         (kg/kkg)       kkg)     average (kg/
                                                                     kkg)   
    AOX..............................        0.951        0.623        0.512
    COD..............................          (e)          (e)         (e) 
    ------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this     
      pollutant; however, permitting authorities may do so as appropriate.  
    c Picograms per liter.                                                  
    d Grams per 1,000 kilograms (g/kkg).                                    
    e [Reserved].                                                           
    
        (2) The following effluent limitations apply with respect to each 
    fiber line that uses exclusively TCF bleaching processes, as disclosed 
    by the discharger in its NPDES permit application under 40 CFR 
    122.21(g)(3) and certified under 40 CFR 122.22:
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                             BAT effluent limitations (TCF)                         
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3) kg/kkg(or pounds per                                                                                        
     1,000 lb) of product                                                                                           
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  a                  (b)                    a                  (b)         
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
        (b) The following limitations apply with respect to each fiber line 
    enrolled in the Voluntary Advanced Technology Incentives Program:
        (1) Stage 1 Limitations: Numeric limitations that are equivalent to 
    the discharger's existing effluent quality or the discharger's current 
    effluent limitations established under CWA section 301(b)(2), whichever 
    are more stringent, for the pollutants identified in paragraph (a)(1) 
    of this section (with the exception of COD). For AOX, the permitting 
    authority must determine existing effluent quality for each fiber line 
    enrolled in the Voluntary Advanced Technology Incentives Program at the 
    end of the pipe based on loadings attributable to that fiber line. For 
    the remaining pollutants, with the exception of COD, the permitting 
    authority must determine existing effluent quality for each fiber line 
    enrolled in the Voluntary Advanced Technology Incentives Program at the 
    point where the wastewater containing those pollutants leaves the 
    bleach plant. These limitations must be recalculated each time the 
    NPDES permit of a discharger enrolled in the Voluntary Advanced 
    Technology Incentives Program is reissued, up to:
        (i) April 15, 2004 for all pollutants in paragraph (a)(1) of this 
    section except AOX; and
        (ii) The date specified in paragraph (b)(4)(ii) of this section for 
    achieving the applicable AOX limitation specified in paragraph 
    (b)(4)(i).
    
    [[Page 18654]]
    
        (2) Best Professional Judgment Milestones: Narrative or numeric 
    limitations and/or special permit conditions, as appropriate, 
    established by the permitting authority on the basis of his or her best 
    professional judgment that reflect reasonable interim milestones toward 
    achievement of the effluent limitations specified in paragraphs (b)(3) 
    and (b)(4) of this section, as applicable.
        (3) Six-year Milestones: By April 15, 2004 all dischargers enrolled 
    in the Voluntary Advanced Technology Incentives Program must achieve 
    the following:
        (i) The effluent limitations specified in paragraph (a)(1) of this 
    section, except that, with respect to AOX, dischargers subject to Tier 
    I effluent limitations specified in paragraph (b)(4)(i) of this section 
    must achieve the AOX limitation specified in that paragraph; or
        (ii) For dischargers that use exclusively TCF bleaching processes 
    as of April 15, 2004, the effluent limitations specified in paragraph 
    (a)(2) of this section.
        (4)(i) Stage 2 Limitations:
    
                                                                Ultimate Voluntary Advanced Technology Incentives Program BAT Limitations                                                           
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                                                                                  AOX (kg/kkg)                      
                                                                                                                                           ---------------------------------------------------------
                                                                                                           Total pulping area condensate,         Non-TCF a                       TCF               
                   Tier                        Kappa number (annual average)               Filtrate      evaporator condensate, and bleach ---------------------------------------------------------
                                                                                          recycling        plant wastewater flow (annual     Maximum                                                
                                                                                                                      average)              for any 1    Annual    Maximum for any   Annual average 
                                                                                                                                               day      average         1 day                       
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
    Tier I...........................  20 (softwood furnish)........................  (b)..............  N/A..............................       0.58       0.26  c             (d)             
                                       13 (Hardwood furnish)                                                                                                                                        
    Tier II..........................  NA...........................................  (b)..............  10 cubic meters/kkg..............       0.23       0.10  c             (d)             
    Tier III.........................  N/A..........................................  (b)..............  5 cubic meters/kkg...............       0.11        0.5  c             (d)             
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
    a Non-TCF: Pertains to any fiber line that does not use exclusively TCF bleaching processes.                                                                                                    
    b Complete recycling to the chemical recovery system of all filtrates generated prior to bleaching. Under Tier I, this includes all filtrates up to the point where kappa number is measures.   
    c ``d This regulation does not specify this type of limitation for this pollutant; however, permitting authorities may do so as appropriate.                                                        
     AN/A means ``not applicable.''                                                                                                                                                                 
    
        (ii) Deadlines. (A) A discharger enrolled in Tier I of the 
    Voluntary Advanced Technology Incentives Program must achieve for Tier 
    I limitations in paragraph (b)(4)(i) of this section by April 15, 2004.
        (B) A discharger enrolled in Tier II of the Voluntary Advanced 
    Technology Incentives Program must achieve the Tier II limitations in 
    paragraph (b)(4)(i) of this section by April 15, 2009.
        (C) A discharger enrolled in Tier III of the Voluntary Advanced 
    Technology Incentives Program must achieve the Tier III limitations in 
    paragraph (b)(4)(i) of this section by April 15, 2014.
        (c) [RESERVED].
        (d) The following additional effluent limitations apply to all 
    dischargers subject to this section in accordance with the previous 
    subcategorization scheme unless the discharger certifies to the 
    permitting authority that it is not using these compounds as biocides. 
    Also, for non-continuous dischargers, concentration limitation (mg/l) 
    shall apply. Concentration limitations will only apply to non-
    continuous dischargers:
    
                                    Subpart B                               
      [Supplemental BAT effluent limitations for bleached kraft facilities  
                         where market pulp is produced]                     
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pullutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0019  (0.011)(41.6)/y            
    Trichlorophenol..............        0.012   (0.068)(41.6)/y            
    y = wastewater discharged in                                            
     kgal per ton product.                                                  
    ------------------------------------------------------------------------
    
    
                                    Subpart B                               
      [Supplemental BAT effluent limitations for bleached kraft facilities  
         where paperboard, coarse paper, and tissue paper are produced]     
    ------------------------------------------------------------------------
                                             Maximun for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0016  (0.11)(35.4)/y             
    Trichlorophenol..............        0.010   (0.068)(35.4)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
    [[Page 18655]]
    
    
                                    Subpart B                               
      [Supplemental BAT effluent limitations for bleached kraft facilities  
     where pulp and fine papers are produced and soda facilities where pulp 
                             and paper are produced]                        
    ------------------------------------------------------------------------
                                              Maximum for any 1 day         
                                   -----------------------------------------
        Pollutant or pollutant       kg/kkg (or                             
               property              pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    ------------------------------------------------------------------------
    Pentachlorophenol.............       0.0014  (0.011) (30.9)/y           
    Trichlorophenol...............       0.0088  (0.068) (30.9)/y           
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
        (e) Pursuant to 40 CFR 122.44(i) and 122.45(h), a discharger must 
    demonstrate compliance with the effluent limitations in paragraph 
    (a)(1) or (b)(3) of this section, as applicable, by monitoring for all 
    pollutants (except for AOX and COD) at the point where the wastewater 
    containing those pollutants leaves the bleach plant. The permitting 
    authority may impose effluent limitations and/or monitoring 
    requirements on internal wastestreams for any other pollutants covered 
    in this section as appropriate under 40 CFR 122.44(i) and 122.45(h). In 
    addition, a discharger subject to a limitation on total pulping area 
    condensate, evaporator condensate, and bleach plant wastewater flow 
    under paragraph (b)(4)(i) of this section, for Tier II and Tier III, 
    must demonstrate compliance with that limitation by establishing and 
    maintaining flow measurement equipment to monitor these flows at the 
    point or points where they leave the pulping area, evaporator area, and 
    bleach plant.
    
    
    Sec. 430.25  New source performance standards (NSPS).
    
        New sources subject to this subpart must achieve the following new 
    source performance standards (NSPS), as applicable.
        (a) The following standards apply to each new source that commenced 
    discharge after June 15, 1988 and before June 15, 1998, provided that 
    the new source was constructed to meet these standards:
    
                                    Subpart B                               
      [1982 New Source Performance Standards for bleached kraft facilities  
                         where market pulp is produced]                     
    ------------------------------------------------------------------------
                                        Continuous dischargers       Non-   
                                      --------------------------  continuous
                                                     Average of  dischargers
                                                       daily    ------------
     Pollutant or pollutant property   Maximum for   values for             
                                        any 1 day        30         Annual  
                                                    consecutive    average  
                                                        days                
    ------------------------------------------------------------------------
                                                                            
    (2) kg/kkg (or pounds per 1,000                                         
     lb) of product                                                         
    ------------------------------------------------------------------------
    BOD5.............................         10.3          5.5         2.88
    TSS..............................         18.2          9.5         5.00
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart B                               
      [1982 New Source Performance Standards for bleached kraft facilities  
         where paperboard, coarse paper, and tissue paper are produced]     
    ------------------------------------------------------------------------
                                        Continuous dischargers       Non-   
                                      --------------------------  continuous
                                                     Average of  dischargers
                                                       daily    ------------
     Pollutant or pollutant property   Maximum for   values for             
                                        any 1 day        30         Annual  
                                                    consecutive    average  
                                                        days                
    ------------------------------------------------------------------------
                                                                            
    (2) kg/kkg (or pounds per 1,000                                         
     lb) of product                                                         
    ------------------------------------------------------------------------
    BOD5.............................          8.5          4.6         2.41
    TSS..............................         14.6          7.6         4.00
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
    [[Page 18656]]
    
    
                                    Subpart B                               
      [1982 New Source Performance Standards for bleached kraft facilities  
     where pulp and fine papers are produced and soda facilities where pulp 
                             and paper are produced]                        
    ------------------------------------------------------------------------
                                        Continuous dischargers       Non-   
                                      --------------------------  continuous
                                                     Average of  dischargers
                                                       daily    ------------
     Pollutant or pollutant property   Maximum for   values for             
                                        any 1 day        30         Annual  
                                                    consecutive    average  
                                                        days                
    ------------------------------------------------------------------------
                                                                            
    (2) kg/kkg (or pounds per 1,000                                         
     lb) of product                                                         
    ------------------------------------------------------------------------
    BOD5.............................          5.7          3.1         1.62
    TSS..............................          9.1          4.8         2.53
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (b) Except as provided in paragraph (c) of this section--
        (1) The following standards apply with respect to each new source 
    fiber line that does not use an exclusively TCF bleaching process, as 
    disclosed by the discharger in its NPDES permit application under 40 
    CFR 122.21(g)(3) and certified under 40 CFR 122.22, and that commences 
    discharge after June 15, 1998:
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                         NSPS                       
                                                                ----------------------------------------------------
                  Pollutant or pollutant property                                                          Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    TCDD.......................................................  a                                           (b)
    TCDF.......................................................  31.9 c                                          (b)
    Chloroform.................................................  6.92 d                                       4.14 d
    Trichlorosyringol..........................................  a                                           (b)
    3,4,5-trichlorocatechol....................................  a                                           (b)
    3,4,6-trichlorocatechol....................................  a                                           (b)
    3,4,5-trichloroguaiacol....................................  a                                           (b)
    3,4,6-trichloroguaiacol....................................  a                                           (b)
    4,5,6-trichloroguaiacol....................................  a                                           (b)
    2,4,5-trichlorophenol......................................  a                                           (b)
    2,4,6-trichlorophenol......................................  a                                           (b)
    Tetrachlorocatechol........................................  a                                           (b)
    Tetrachloroguaiacol........................................  a                                           (b)
    2,3,4,6-tetrachlorophenol..................................  a                                           (b)
    Pentachlorophenol..........................................  a                                           (b)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                            
                                      Continuous dischargers        Non-    
                                   ----------------------------  continuous 
                                                                 dischargers
                                     Maximum for     Monthly   -------------
                                      any 1 day   average (kg/     Annual   
                                      (kg/kkg)        kkg)      average (kg/
                                                                    kkg)    
    AOX...........................         0.476         0.272         0.208
    BOD5..........................         4.52          2.41          1.73 
    TSS...........................         8.47          3.86          2.72 
    pH............................     (\1\)         (\1\)         (\1\)    
    COD...........................       (e)           (e)           (e)    
    ------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this     
      pollutant; however, permitting authorities may do so as appropriate.  
    c Picograms per liter.                                                  
    d Grams per 1,000 kilograms(g/kkg).                                     
    e [Reserved].                                                           
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (2) The following standards apply with respect to each new source 
    fiber line that uses exclusively TCF bleaching processes, as disclosed 
    by the discharger in its NPDES permit application under 40 CFR 
    122.21(g)(3) and certified under 40 CFR 122.22, and that commences 
    discharge after June 15, 1998:
    
    [[Page 18657]]
    
    
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                          NSPS (TCF)                                
                                         ---------------------------------------------------------------------------
                                                 Continuous dischargers              Non-continuous  dischargers    
       Pollutant or pollutant property   ---------------------------------------------------------------------------
                                                                     Monthly                                Annual  
                                           Maximum for any 1 day     average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
    AOX d...............................  a                            (b)  a                            (b)
    BOD5 d..............................  4.52                            2.41  N/A                             1.73
    TSS d...............................  8.47                            3.86  N/A                             2.72
    pH..................................  (\1\)                          (\1\)  (\1\)                          (\1\)
    COD.................................  (c)                              (c)  (c)                              (c)
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    d Kilograms per 1,000 kilograms (kg/kkg).                                                                       
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
        (c) With respect to each new source fiber line that is enrolled in 
    the Voluntary Advanced Technology Incentives Program, dischargers 
    subject to this section must achieve:
        (1) The standards specified in paragraph (b)(1) of this section 
    (except for AOX) or paragraph (b)(2) of this section, as applicable; 
    and
        (2) Standards for filtrates, flow, and AOX:
    
                                                 Ultimate Voluntary Advanced Technology Incentives Program NSPS                                             
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                                         AOX (kg/kkg)                       
                                                                                                 -----------------------------------------------------------
                                                              Total pulping area condensate,            Non-TCF a                        TCF                
                   Tier                     Filtrate         evaporator condensate, and bleach   -----------------------------------------------------------
                                           recycling      plant wastewater flow (annual average)   Maximum                                                  
                                                                                                  for any 1    Annual   Maximum for any 1    Annual average 
                                                                                                     day      average          day                          
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Tier II..........................  (b)..............  10 cubic meters/kkg...................       0.23       0.10  c              (d)              
    Tier III.........................  (b)..............  5 cubic meters/kkg....................       0.11       0.05  c              (d)              
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    a Non-TCF: Pertains to any fiber line that does not use exclusively TCF bleaching processes.                                                            
    b Complete recycling to the chemical recovery system of all filtrates generated prior to bleaching.                                                     
    c ``d This regulation does not specify this type of limitation for this pollutant; however, permitting authorities may do so as appropriate.                
    
        (d) These additional standards apply to all new sources, regardless 
    of when they commenced discharge, in accordance with the previous 
    subcategorization scheme unless the discharger certifies to the 
    permitting authority that it is not using these compounds as biocides. 
    Also, for non-continuous dischargers, concentration limitations (mg/l) 
    shall apply. Concentration limitations will only apply to non-
    continuous dischargers:
    
                                    Subpart B                               
      [Supplemental NSPS for bleached kraft facilities where market pulp is 
                                    produced]                               
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0019  (0.013)(36.6)/y            
    Trichlorophenol..............        0.012   (0.077)(36.6)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart B                               
       [Supplemental NSPS for bleached kraft facilities where paperboard,   
                  coarse paper, and tissue paper are produced]              
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0016  (0.012)(31.7)/y            
    
    [[Page 18658]]
    
                                                                            
    Trichlorophenol..............        0.010   (0.076)(31.7)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart B                               
      [Supplemental NSPS for bleached kraft facilities where pulp and fine  
        papers are produced and soda facilities where pulp and paper are    
                                    produced]                               
    ------------------------------------------------------------------------
                                              Maximum for any 1 day         
                                   -----------------------------------------
        Pollutant or pollutant       kg/kkg (or                             
               property              pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    ------------------------------------------------------------------------
    Pentachlorophenol.............       0.0014  (0.014)(25.1)/y            
    Trichlorophenol...............       0.0088  (0.084)(25.1)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
        (e) Pursuant to 40 CFR 122.44(i) and 122.45(h), a discharger must 
    demonstrate compliance with the limitations in paragraph (b)(1) or 
    (c)(1) of this section, as applicable, by monitoring for all pollutants 
    (except for AOX, COD, BOD5, TSS, and pH) at the point where the 
    wastewater containing those pollutants leaves the bleach plant. The 
    permitting authority may impose effluent limitations and/or monitoring 
    requirements on internal wastestreams for any other pollutants covered 
    in this section as appropriate under 40 CFR 122.44(i) and 122.45(h). In 
    addition, a discharger subject to a limitation on total pulping area 
    condensate, evaporator condensate, and bleach plant wastewater flow 
    under paragraph (c)(2) of this section must demonstrate compliance with 
    that limitation by establishing and maintaining flow measurement 
    equipment monitoring these flows at the point or points where they 
    leave the pulping area, evaporator area, and the bleach plant.
    
    
    Sec. 430.26  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES).
        (a)(1) The following pretreatment standards apply with respect to 
    each fiber line operated by an indirect discharger subject to this 
    section, unless the indirect discharger discloses to the pretreatment 
    control authority in a report submitted under 40 CFR 403.12(b) that it 
    uses exclusively TCF bleaching processes at that fiber line. These 
    pretreatment standards must be attained on or before April 16, 2001:
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                         PSES                       
                                                                ----------------------------------------------------
                  Pollutant or pollutant property                                                          Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    TCDD.......................................................  a                                           (b)
    TCDF.......................................................  31.9 c                                          (b)
    Chloroform.................................................  6.92 d                                       d 4.14
    Trichlorosyringol..........................................  a                                           (b)
    3,4,5-trichlorocatechol....................................  a                                           (b)
    3,4,6-trichlorocatechol....................................  a                                           (b)
    3,4,5-trichloroguaiacol....................................  a                                           (b)
    3,4,6-trichloroguaiacol....................................  a                                           (b)
    4,5,6-trichloroguaiacol....................................  a                                           (b)
    2,4,5-trichlorophenol......................................  a                                           (b)
    2,4,6-trichlorophenol......................................  a                                           (b)
    Tetrachlorocatechol........................................  a                                           (b)
    Tetrachloroguaiacol........................................  a                                           (b)
    2,3,4,6-tetrachlorophenol..................................  a                                           (b)
    Pentachlorophenol..........................................  a                                           (b)
    AOX........................................................  2.64 e                                       e 1.41
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    c Picograms per liter.                                                                                          
    d Grams per 1,000 kilograms (g/kkg).                                                                            
    
    [[Page 18659]]
    
                                                                                                                    
    e Kilograms per 1,000 kilograms (kg/kkg).                                                                       
    
        (2) The following pretreatment standards apply with respect to each 
    fiber line operated by an indirect discharger subject to this section 
    if the indirect discharger discloses to the pretreatment control 
    authority in a report submitted under 40 CFR 403.12(b) that it uses 
    exclusively TCF bleaching processes at that fiber line. These 
    pretreatment standards must be attained on or before April 16, 2001:
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                      PSES (TCF)                    
                                                                ----------------------------------------------------
                  Pollutant or pollutant parameter                                                         Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    AOX........................................................  a                                           (b)
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (b) The following pretreatment standards apply to all indirect 
    dischargers, in accordance with the previous subcategorization scheme. 
    An indirect discharger is not required to meet these pretreatment 
    standards if it certifies to the pretreatment control authority that it 
    is not using these compounds as biocides. In cases when POTWs find it 
    necessary to impose mass effluent limitations, equivalent mass 
    limitations are provided as guidance:
    
                                    Subpart B                               
      [Supplemental PSES for bleached kraft facilities where market pulp is 
                                    produced]                               
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0019  (0.011)(41.6)/y            
    Trichlorophenol..............        0.014   (0.082)(41.6)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart B                               
       [Supplemental PSES for bleached kraft facilities where paperboard,   
                  coarse paper, and tissue paper are produced]              
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0016  (0.011)(35.4)/y            
    Trichlorophenol..............        0.012   (0.082)(35.4)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart B                               
      [Supplemental PSES for bleached kraft facilities where pulp and fine  
        papers are produced and soda facilities where pulp and paper are    
                                    produced]                               
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0014  (0.011)(30.9)/y            
    Trichlorophenol..............        0.011   (0.082)(30.9)/y            
    y = wastewater discharged in                                            
     kgal per ton of product                                                
    ------------------------------------------------------------------------
    
        (c) An indirect discharger must demonstrate compliance with the 
    pretreatment standards in paragraph (a)(1) of this section by 
    monitoring at the point where the wastewater containing those 
    pollutants leaves the bleach plant.
    
    
    Sec. 430.27  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must:
    
    [[Page 18660]]
    
    comply with 40 CFR part 403; and achieve the following pretreatment 
    standards for new sources (PSNS).
        (a)(1) The following pretreatment standards apply with respect to 
    each fiber line that is a new source, unless the indirect discharger 
    discloses to the pretreatment control authority in a report submitted 
    under 40 CFR 403.12 that it uses exclusively TCF bleaching processes at 
    that fiber line:
    
                                                        Subpart B                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                         PSNS                       
                                                                ----------------------------------------------------
                  Pollutant or pollutant property                                                          Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    TCDD.......................................................  a                                           (b)
    TCDF.......................................................  31.9 c                                          (b)
    Chloroform.................................................  6.92 d                                       4.14 d
    Trichlorosyringol..........................................  a                                           (b)
    3,4,5-trichlorocatechol....................................  a                                           (b)
    3,4,6-trichlorocatechol....................................  a                                           (b)
    3,4,5-trichloroguaiacol....................................  a                                           (b)
    3,4,6-trichloroguaiacol....................................  a                                           (b)
    4,5,6-trichloroguaiacol....................................  a                                           (b)
    2,4,5-trichlorophenol......................................  a                                           (b)
    2,4,6-trichlorophenol......................................  a                                           (b)
    Tetrachlorocatechol........................................  a                                           (b)
    Tetrachloroguaiacol........................................  a                                           (b)
    2,3,4,6-tetrachlorophenol..................................  a                                           (b)
    Pentachlorophenol..........................................  a                                           (b)
    AOX........................................................  1.16 e                                      0.814 e
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    c Picograms per liter.                                                                                          
    d Grams per 1,000 kilograms (g/kkg).                                                                            
    e Kilograms per 1,000 kilograms (kg/kkg).                                                                       
    
        (2) The following pretreatment standards apply with respect to each 
    new source fiber line operated by an indirect discharger subject to 
    this section if the indirect discharger discloses to the pretreatment 
    control authority in a report submitted under 40 CFR 403.12(b) that it 
    uses exclusively TCF bleaching processes at that fiber line:
    
                                                        Subpart B                                                   
                                                                                                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                                      PSNS (TCF)                    
                                                                ----------------------------------------------------
                  Pollutant or pollutant parameter                                                         Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    AOX........................................................  a                                          (b) 
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (b) The following pretreatment standards apply to all new source 
    indirect dischargers, regardless of when they commenced discharge, in 
    accordance with the previous subcategorization scheme. An indirect 
    discharger is not required to meet these pretreatment standards if it 
    certifies to the pretreatment control authority that it is not using 
    these compounds as biocides. In cases when POTWs find it necessary to 
    impose mass-based effluent limitations, equivalent mass limitations are 
    provided as guidance:
    
                                    Subpart B                               
      [Supplemental PSNS for bleached kraft facilities where market pulp is 
                                    produced]                               
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0019  (0.013)(36.6)/y            
    Trichlorophenol..............        0.014   (0.093)(36.6)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
    [[Page 18661]]
    
    
                                    Subpart B                               
       [Supplemental PSNS for bleached kraft facilities where paperboard,   
                  coarse paper, and tissue paper are produced]              
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0016  (0.012)(31.7)/y            
    Trichlorophenol..............        0.012   (0.092)(31.7)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart B                               
      [Supplemental PSNS for bleached kraft facilities where pulp and fine  
        papers are produced and soda facilities where pulp and paper are    
                                    produced]                               
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      kg/kkg (or                              
              parameter             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0014  (0.014)(25.1)/y            
    Trichlorophenol..............        0.011   (0.101)(25.1)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
        (c) An indirect discharger must demonstrate compliance with the 
    pretreatment standards in paragraph (a)(1) of this section by 
    monitoring at the point where the wastewater containing those 
    pollutants leaves the bleach plant.
    
    
    Sec. 430.28  Best management practices (BMPs).
    
        The definitions and requirements set forth in 40 CFR 430.03 apply 
    to facilities in this subpart.
    
    Subpart C--Unbleached Kraft Subcategory
    
    
    Sec. 430.30  Applicability; description of the unbleached kraft 
    subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from: the production of pulp and paper at unbleached kraft 
    mills; the production of pulp and paper at unbleached kraft-neutral 
    sulfite semi-chemical (cross recovery) mills; and the production of 
    pulp and paper at combined unbleached kraft and semi-chemical mills, 
    wherein the spent semi-chemical cooking liquor is burned within the 
    unbleached kraft chemical recovery system.
    
    
    Sec. 430.31  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    
    Sec. 430.32  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best practicable control 
    technology currently available (BPT):
    
                                    Subpart C                               
           [BPT effluent limitations for unbleached kraft facilities]       
    ------------------------------------------------------------------------
                                                Kg/kkg (or pounds per 1,000 
                                                      lb) of product        
                                             -------------------------------
                                                                Average of  
         Pollutant or pollutant property                       daily values 
                                                Maximum for       for 30    
                                                 any 1 day      consecutive 
                                                                   days     
    ------------------------------------------------------------------------
    BOD5....................................             5.6             2.8
    TSS.....................................            12.0             6.0
    pH......................................           (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                        
    
    
    [[Page 18662]]
    
    
                                    Subpart C                               
    [BPT effluent limitations for unbleached kraft facilities producing pulp
       and paper using the unbleached kraft-neutral sulfite semi-chemical   
                            (cross recovery) process]                       
    ------------------------------------------------------------------------
                                                Kg/kkg (or pounds per 1,000 
                                                      lb) of product        
                                             -------------------------------
                                                                Average of  
         Pollutant or pollutant property                       daily values 
                                                Maximum for       for 30    
                                                 any 1 day      consecutive 
                                                                   days     
    ------------------------------------------------------------------------
    BOD5....................................             8.0            4.0 
    TSS.....................................            12.5            6.25
    pH......................................           (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                        
    
    
                                    Subpart C                               
    [BPT effluent limitations for unbleached kraft facilities where pulp and
     paper are produced using a combined unbleached kraft and semi-chemical 
    process, wherein the spent semi-chemical cooking liquor is burned within
                 the unbleached kraft chemical recovery system]             
    ------------------------------------------------------------------------
                                                Kg/kkg (or pounds per 1,000 
                                                      lb) of product        
                                             -------------------------------
                                                                Average of  
         Pollutant or pollutant property                       daily values 
                                                Maximum for       for 30    
                                                 any 1 day      consecutive 
                                                                   days     
    ------------------------------------------------------------------------
    BOD5....................................             (a)             (a)
    TSS.....................................             (a)             (a)
    pH......................................             (a)             (a)
    ------------------------------------------------------------------------
    a [Reserved].                                                           
    
    Sec. 430.33  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT), except that non-continuous dischargers shall 
    not be subject to the maximum day and average-of-30-consecutive-days 
    limitations, but shall be subject to annual average effluent 
    limitations:
    
                                    Subpart C                               
           [BCT effluent limitations for unbleached kraft facilities]       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                                         Non-continuous     
                                                       dischargers (annual  
                                                            average)        
     Pollutant or pollutant property               -------------------------
                                        Continuous                Average of
                                       dischargers                  daily   
                                                    Maximum for   values for
                                                     any 1 day        30    
                                                                 consecutive
                                                                     days   
    ------------------------------------------------------------------------
    BOD5.............................          5.6          2.8          1.9
    TSS..............................         12.0          6.0          3.6
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                        
    
    
    [[Page 18663]]
    
    
                                    Subpart C                               
      [BCT effluent limitations for unbleached kraft-neutral sulfite semi-  
    chemical (cross recovery) process and/or a combined unbleached kraft and
    semi-chemical process, wherein the spent semi-chemical cooking liquor is
          burned within the unbleached kraft chemical recovery system]      
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ---------------------------     Non-    
    Pollutant or pollutant property                Average of    continuous 
                                                  daily values      dis-    
                                     Maximum for     for 30       chargers  
                                      any 1 day    consecutive     (annual  
                                                      days        average)  
    ------------------------------------------------------------------------
    BOD5...........................          8.0          4.0           2.9 
    TSS............................         12.5          6.25          3.57
    pH.............................        (\1\)      (\1\)         (\1\)   
    ------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                        
    
    Sec. 430.34  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb), but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                    Subpart C                               
           [BAT effluent limitations for unbleached kraft facilities]       
    ------------------------------------------------------------------------
                                              Maximum for any 1 day         
                                   -----------------------------------------
        Pollutant or pollutant       Kg/kkg (or                             
               property              pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    ------------------------------------------------------------------------
    Pentachlorophenol.............      0.00058  (0.011)(12.6)/y            
    Trichlorophenol...............      0.00053  (0.010)(12.6)/y            
    y=wastewater discharged in                                              
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart C                               
    [BAT effluent limitations for unbleached kraft facilities where pulp and
       paper are produced using the unbleached kraft-neutral sulfite semi-  
    chemical (cross recovery) process and/or a combined unbleached kraft and
    semi-chemical process, wherein the spent semi-chemical cooking liquor is
          burned within the unbleached kraft chemical recovery system]      
    ------------------------------------------------------------------------
                                              Maximum for any 1 day         
                                   -----------------------------------------
        Pollutant or pollutant       Kg/kkg (or                             
               property              pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    ------------------------------------------------------------------------
    Pentachlorophenol.............      0.00064  (0.011)(14.0)/y            
    Trichlorophenol...............      0.00059  (0.010)(14.0)/y            
    y=wastewater discharged in                                              
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    Sec. 430.35  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides:
    
    [[Page 18664]]
    
    
    
                                    Subpart C                               
       [NSPS for unbleached kraft facilities where linerboard is produced]  
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                       Continuous dischargers               
                                     --------------------------     Non-    
     Pollutant or pollutant property                Average of   continuous 
                                                      daily         dis-    
                                      Maximum for   values for    chargers  
                                       any 1 day        30         (annual  
                                                   consecutive    average)  
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................          3.4          1.8          0.94
    TSS.............................          5.8          3.0          1.6 
    pH..............................        (\1\)        (\1\)      (\1\)   
    ------------------------------------------------------------------------
    
    
                                                                            
                                              Maximum for any 1 day         
                                   -----------------------------------------
                                     Kg/kkg (or                             
                                     pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    Pentachlorophenol.............      0.00058  (0.015)(9.4)/y             
    Trichlorophenol...............      0.00053  (0.013)(9.4)/y             
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart C                               
      [NSPS for unbleached kraft facilities where bag paper and other mixed 
                             products are produced]                         
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------     Non-   
     Pollutant or pollutant property                 Average of   continuous
                                                       daily         dis-   
                                       Maximum for   values for    chargers 
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................          5.0         2.71          1.4
    TSS..............................          9.1          4.8          2.5
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    
    
                                                                            
                                              Maximum for any 1 day         
                                   -----------------------------------------
                                     Kg/kkg (or                             
                                     pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    Pentachlorophenol.............      0.00058  (0.012)(11.4)/y            
    Trichlorophenol...............      0.00053  (0.011)(11.4)/y            
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart C                               
     [NSPS for unbleached kraft facilities where pulp and paper are produced
         using the unbleached kraft-neutral sulfite semi-chemical (cross    
     recovery) process and/or a combined unbleached kraft and semi-chemical 
    process, wherein the spent semi-chemical cooking liquor is burned within
                 the unbleached kraft chemical recovery system]             
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................          3.9          2.1          1.1
    
    [[Page 18665]]
    
                                                                            
    TSS..............................          7.3          3.8          1.9
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    
    
                                                                            
                                              Maximum for any 1 day         
                                   -----------------------------------------
                                     Kg/kkg (or                             
                                     pounds per                             
                                     1,000 lb)         Milligrams/liter     
                                     of product                             
    Pentachlorophenol.............      0.00064  (0.013)(11.5)/y            
    Trichlorophenol...............      0.00059  (0.012)(11.5)/y            
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    Sec. 430.36  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using those biocides. PSES must be attained 
    on or before July 1, 1984:
    
                                                        Subpart C                                                   
                                         [PSES for unbleached kraft facilities]                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                          Kg/kkg (or
            Pollutant or pollutant property                                                               pounds per
                                                                      Milligrams/liter                    1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol.............................  (0.011)(12.6)/y....................................      0.00058
    Trichlorophenol...............................  (0.010)(12.6)/y....................................      0.00053
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to  
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart C                                                   
       [PSES for unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral   
      sulfite semi-chemical (cross recovery) process and/or a combined unbleached kraft and semi-chemical process,  
     wherein the spent semi-chemical cooking liquor is burned within the unbleached kraft chemical recovery system] 
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                          Kg/kkg (or
            Pollutant or pollutant property                                                               pounds per
                                                                      Milligrams/liter                    1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol.............................  (0.011)(14.0)/y....................................      0.00064
    Trichlorophenol...............................  (0.010)(14.0)/y....................................      0.00059
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to  
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18666]]
    
    Sec. 430.37  Pretreatment standards for new sources (PSNS).
    
        (a) Except as provided in 40 CFR 403.7, any new source subject to 
    this subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart C                                                   
                           [PSNS for unbleached kraft facilities where linerboard is produced]                      
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                          Kg/kkg (or
            Pollutant or pollutant property                                                               pounds per
                                                                      Milligrams/liter                    1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol.............................  (0.015)(9.4)/y.....................................      0.00058
    Trichlorophenol...............................  (0.013)(9.4)/y.....................................      0.00053
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to  
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart C                                                   
              [PSNS for unbleached kraft facilities where bag paper and other mixed products are produced]          
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                          Kg/kkg (or
            Pollutant or pollutant property                                                               pounds per
                                                                      Milligrams/liter                    1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol.............................  (0.012)(11.4)/y....................................      0.00058
    Trichlorophenol...............................  (0.011)(11.4)/y....................................      0.00053
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to  
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart C                                                   
       [PSNS for unbleached kraft facilities where pulp and paper are produced using the unbleached kraft-neutral   
      sulfite semi-chemical (cross recovery) process and/or a combined unbleached kraft and semi-chemical process,  
     wherein the spent semi-chemical cooking liquor is burned within the unbleached kraft chemical recovery system] 
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                          Kg/kkg (or
            Pollutant or pollutant property                                                               pounds per
                                                                      Milligrams/liter                    1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol.............................  (0.013)(11.5)/y....................................      0.00064
    Trichlorophenol...............................  (0.012)(11.5)/y....................................      0.00059
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases where POTWs find it necessary to  
      impose mass effluent limitations.                                                                             
    
    Subpart D--Dissolving Sulfite Subcategory
    
    
    Sec. 430.40  Applicability; description of the dissolving sulfite 
    subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the production of pulp at dissolving sulfite mills.
    
    
    Sec. 430.41  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    
    Sec. 430.42  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
    [[Page 18667]]
    
    
    
                                    Subpart D                               
     [BPT effluent limitations for dissolving sulfite pulp facilities where 
                        nitration grade pulp is produced]                   
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................         41.4          21.5          12.1
    TSS............................         70.65         38.05         20.9
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                          
    
    
                                    Subpart D                               
     [BPT effluent limitations for dissolving sulfite pulp facilities where 
                         viscose grade pulp is produced]                    
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................         44.3          23.0          12.9
    TSS............................         70.65         38.05         20.9
    pH.............................        (1)           (1)             (1)
    ------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                          
    
    
                                    Subpart D                               
     [BPT effluent limitations for dissolving sulfite pulp facilities where 
                       cellophane grade pulp is produced]                   
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................        48.05        24.95         14.0
    TSS..............................        70.65        38.05         20.9
    pH...............................          (1)          (1)          (1)
    ------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                          
    
    
                                    Subpart D                               
     [BPT effluent limitations for dissolving sulfite pulp facilities where 
                         acetate grade pulp is produced]                    
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................       150.80       126.40       114.83
    TSS..............................        70.65        38.05         20.9
    pH...............................          (2)          (2)          (2)
    ------------------------------------------------------------------------
    1 BOD5 effluent limitations were remanded (Weyerhaeuser Company, et al  
      v. Costle, 590 F. 2nd 1011; D.C. Circuit 1978).                       
    2 Within the range of 5.0 to 9.0 at all times.                          
    
    
    [[Page 18668]]
    
        (b) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of wet barking operations, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days 
    limitations, but shall be subject to annual average effluent 
    limitations:
    
                                    Subpart D                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                       Kg/kkg (or pounds per 1,000 lb) of   
                                                     product                
                                   -----------------------------------------
                                      Continuous dischargers                
        Pollutant or pollutant     ----------------------------     Non-    
               property                            Average of    continuous 
                                                  daily values      dis-    
                                     Maximum for     for 30       chargers  
                                      any 1 day    consecutive     (annual  
                                                      days        average)  
    ------------------------------------------------------------------------
    BOD5..........................          0.7           0.35          0.2 
    TSS...........................          0.15          0.1           0.05
    pH............................        (1)           (1)           (1)   
    ------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                          
    
        (c) The following limitations establish the quantity or quality of 
    pollutants or pollutant parameters, controlled by this section, 
    resulting from the use of log washing or chip washing operations, which 
    may be discharged by a point source subject to the provisions of this 
    subpart. These limitations are in addition to the limitations set forth 
    in paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs and/or 
    chips which are subject to such operations. Non-continuous dischargers 
    shall not be subject to the maximum day and average of 30 consecutive 
    days limitations, but shall be subject to the annual average effluent 
    limitations:
    
                                    Subpart D                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         0.15          0.1         0.05
    TSS..............................         0.15          0.1         0.05
    pH...............................          (1)          (1)          (1)
    ------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                          
    
        (d) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of log flumes or log ponds, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days 
    limitations but shall be subject to the annual average effluent 
    limitations:
    
    [[Page 18669]]
    
    
    
                                    Subpart D                               
                           [BPT effluent limitations]                       
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         0.15          0.1         0.05
    TSS..............................         0.15          0.1         0.05
    pH...............................          (1)          (1)          (1)
    ------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                          
    
    Sec. 430.43  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT): The limitations shall be the same as those 
    specified for conventional pollutants (which are defined in 40 CFR 
    401.16) in Sec. 430.42 of this subpart for the best practicable control 
    technology currently available (BPT).
    
    
    Sec. 430.44  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb) but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                    Subpart D                               
     [BAT effluent limitations for dissolving sulfite pulp facilities where 
              nitration, viscose, or cellophane pulps are produced]         
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      Kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0030  (0.011)(66.0)/y            
    Trichlorophenol..............        0.019   (0.068)(66.0)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    
                                    Subpart D                               
     [BAT effluent limitations for dissolving sulfite pulp facilities where 
                         acetate grade pulp is produced]                    
    ------------------------------------------------------------------------
                                             Maximum for any 1 day          
                                  ------------------------------------------
        Pollutant or pollutant      Kg/kkg (or                              
               property             pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    ------------------------------------------------------------------------
    Pentachlorophenol............        0.0033  (0.011)(72.7)/y            
    Trichlorophenol..............        0.021   (0.068)(72.7)/y            
    y = wastewater discharged in                                            
     kgal per ton of product.                                               
    ------------------------------------------------------------------------
    
    Sec. 430.45  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides
    
    [[Page 18670]]
    
    must certify to the permit-issuing authority that they are not using 
    these biocides:
    
                                    Subpart D                               
     [NSPS for dissolving sulfite pulp facilities where nitration grade pulp
                                  is produced]                              
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                       Continuous dischargers               
                                     --------------------------     Non-    
     Pollutant or pollutant property                Average of   continuous 
                                                      daily         dis-    
                                      Maximum for   values for    chargers  
                                       any 1 day        30         (annual  
                                                   consecutive    average)  
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................         26.9         14.5          7.59
    TSS.............................         40.8         21.3         11.2 
    pH..............................        (\1\)        (\1\)      (\1\)   
    ------------------------------------------------------------------------
    
    
                                                                            
                                             Maximum for any 1 day          
                                  ------------------------------------------
                                    Kg/kkg (or                              
                                    pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    Pentachlorophenol............        0.0030  (0.012)(59.0)/y            
    Trichlorophenol..............        0.019   (0.012)(59.0)/y            
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart D                               
    [NSPS for dissolving sulfite pulp facilities where viscose grade pulp is
                                    produced]                               
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                       Continuous dischargers               
                                     --------------------------     Non-    
     Pollutant or pollutant property                Average of   continuous 
                                                      daily         dis-    
                                      Maximum for   values for    chargers  
                                       any 1 day        30         (annual  
                                                   consecutive    average)  
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................         28.7         15.5          8.12
    TSS.............................         40.8         21.3         11.2 
    pH..............................        (\1\)        (\1\)      (\1\)   
    ------------------------------------------------------------------------
    
    
                                                                            
                                             Maximum for any 1 day          
                                  ------------------------------------------
                                    Kg/kkg (or                              
                                    pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    Pentachlorophenol............        0.0030  (0.012)(59.0)/y            
    Trichlorophenol..............        0.019   (0.012)(59.0)/y            
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
    [[Page 18671]]
    
    
                                    Subpart D                               
    [NSPS for dissolving sulfite pulp facilities where cellophane grade pulp
                                  is produced]                              
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                       Continuous dischargers               
                                     --------------------------             
     Pollutant or pollutant property                Average of   Non-contin-
                                                      daily         uous    
                                      Maximum for   values for   dischargers
                                       any 1 day        30         (annual  
                                                   consecutive    average)  
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................         31.2         16.8          8.80
    TSS.............................         40.8         21.3         11.2 
    pH..............................        (\1\)        (\1\)      (\1\)   
    ------------------------------------------------------------------------
    
    
                                                                            
                                             Maximum for any 1 day          
                                  ------------------------------------------
                                    Kg/kkg (or                              
                                    pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    Pentachlorophenol............        0.0030  (0.012)(59.0)/y            
    Trichlorophenol..............        0.019   (0.076)(59.0)/y            
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart D                               
    [NSPS for dissolving sulfite pulp facilities where acetate grade pulp is
                                    produced]                               
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         39.6         21.4         11.2
    TSS..............................         41.1         21.5         11.3
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    
    
                                                                            
                                             Maximum for any 1 day          
                                  ------------------------------------------
                                    Kg/kkg (or                              
                                    pounds per                              
                                   1,000 lb) of        Milligrams/liter     
                                      product                               
    Pentachlorophenol............        0.0033  (0.012)(65.7)/y            
    Trichlorophenol..............        0.021   (0.075)(65.7)/y            
    y = wastewater discharged in                                            
     kgal per ton at all times.                                             
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    Sec. 430.46  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides. PSES must be attained 
    on or before July 1, 1984:
    
    [[Page 18672]]
    
    
    
                                                        Subpart D                                                   
     [PSES for dissolving sulfite pulp facilities where nitration, viscose, or cellophane grade pulps are produced] 
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                         Kg/kkg (or 
            Pollutant or pollutant property                                                              pounds per 
                                                                  Milligrams/liter (mg/l)               1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.............................  (0.011)(66.0)/y...................................        0.0030
    Trichlorophenol...............................  (0.082)(66.0)/y...................................        0.023 
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart D                                                   
                   [PSES for dissolving sulfite pulp facilities where acetate grade pulp is produced]               
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                         Kg/kkg (or 
            Pollutant or pollutant property                                                              pounds per 
                                                                  Milligrams/liter (mg/l)               1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.............................  (0.011)(72.7)/y...................................        0.0033
    Trichlorophenol...............................  (0.082)(72.7)/y...................................        0.025 
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Sec. 430.47  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart D                                                   
     [PSNS for dissolving sulfite pulp facilities where nitration, viscose, or cellophane grade pulps are produced] 
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                         Kg/kkg (or 
            Pollutant or pollutant property                                                              pounds per 
                                                                  Milligrams/liter (mg/l)               1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.............................  (0.012)(59.0)/y...................................        0.0030
    Trichlorophenol...............................  (0.092)(59.0)/y...................................        0.023 
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart D                                                   
                   [PSNS for dissolving sulfite pulp facilities where acetate grade pulp is produced]               
    ----------------------------------------------------------------------------------------------------------------
                                                                          Maximum for any 1 day                     
                                                   -----------------------------------------------------------------
                                                                                                         Kg/kkg (or 
            Pollutant or pollutant property                                                              pounds per 
                                                                  Milligrams/liter (mg/l)               1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.............................  (0.012)(65.7)/y...................................        0.0033
    Trichlorophenol...............................  (0.091)(65.7)/y...................................        0.025 
    y=wastewater discharged in kgal per ton of                                                                      
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18673]]
    
    Subpart E--Papergrade Sulfite Subcategory
    
    
    Sec. 430.50  Applicability; description of the papergrade sulfite 
    subcategory.
    
        The provisions of this subpart apply to discharges resulting from 
    the: integrated production of pulp and paper at papergrade sulfite 
    mills, where blow pit pulp washing techniques are used; and the 
    integrated production of pulp and paper at papergrade sulfite mills 
    where vacuum or pressure drums are used to wash pulp.
    
    
    Sec. 430.51  Specialized definitions.
    
        (a) Except as provided in paragraphs (b) and (c) of this section, 
    the general definitions, abbreviations, and methods of analysis set 
    forth in 40 CFR part 401 and Sec. 430.01 of this part apply to this 
    subpart.
        (b) Sulfite cooking liquor is defined as bisulfite cooking liquor 
    when the pH of the liquor is between 3.0 and 6.0 and as acid sulfite 
    cooking liquor when the pH is less than 3.0.
        (c) For this subpart, the segments for the papergrade sulfite 
    subcategory are defined as follows:
        (1) The calcium-, magnesium-, or sodium-based sulfite pulp segment 
    consists of papergrade sulfite mills where pulp and paper are produced 
    using an acidic cooking liquor of calcium, magnesium, or sodium 
    sulfite, unless those mills are specialty grade sulfite mills;
        (2) The ammonium-based sulfite pulp segment consists of papergrade 
    sulfite mills where pulp and paper are produced using an acidic cooking 
    liquor of ammonium sulfite, unless those mills are specialty grade 
    sulfite mills;
        (3) The specialty grade sulfite pulp segment consists of those 
    papergrade sulfite mills where a significant portion of production is 
    characterized by pulp with a high percentage of alpha cellulose and 
    high brightness sufficent to produce end products such as plastic 
    molding compounds, saturating and laminating products, and photographic 
    papers. The specialty grade segment also includes those mills where a 
    major portion of production is 91 ISO brightness and above.
    
    
    Sec. 430.52  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT):
    
                                    Subpart E                               
       [Bisulfite liquor/surface condensers; BPT effluent limitations for   
       papergrade sulfite facilities where blow pit washing techniques are  
                                      used]                                 
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5............................         31.8         16.55         9.30
    TSS.............................         43.95        23.65        12.99
    pH..............................      (\1\)           (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart E                               
      [Bisulfite liquor/barometric condensers; BPT effluent limitations for 
       papergrade sulfite facilities where blow pit washing techniques are  
                                      used]                                 
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------     Non-   
     Pollutant or pollutant property                Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................         34.7         18.05        10.14
    TSS.............................         52.2         28.1         15.44
    pH..............................        (\1\)      (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
    [[Page 18674]]
    
    
                                    Subpart E                               
      [Acid sulfite liquor/surface condensers; BPT effluent limitations for 
       papergrade sulfite facilities where blow pit washing techniques are  
                                      used]                                 
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................         32.3          16.8          9.44
    TSS............................         43.95         23.65        12.99
    pH.............................      (\1\)         (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart E                               
    [Acid sulfite liquor/barometric condensers; BPT effluent limitations for
       papergrade sulfite facilities where blow pit washing techniques are  
                                      used]                                 
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5............................         35.55         18.5        10.39
    TSS.............................         52.2          28.1        15.44
    pH..............................      (\1\)           (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart E                               
       [Bisulfite liquor/surface condensers; BPT effluent limitations for   
    papergrade sulfite facilities where vacuum or pressure drums are used to
                                   wash pulp]                               
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................         26.7          13.9          7.81
    TSS............................         43.95         23.65        12.99
    pH.............................      (\1\)         (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    Note: Limitations above do not apply to mills using continuous          
      digesters.                                                            
    
    
                                    Subpart E                               
      [Bisulfite liquor/barometric condensers; BPT effluent limitations for 
    papergrade sulfite facilities where vacuum or pressure drums are used to
                                   wash pulp]                               
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         29.4         15.3         8.60
    TSS..............................         52.2         28.1        15.44
    
    [[Page 18675]]
    
                                                                            
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    Note: Limitations above do not apply to mills using continuous          
      digesters.                                                            
    
    
                                    Subpart E                               
      [Acid sulfite liquor/surface condensers; BPT effluent limitations for 
    papergrade sulfite facilities where vacuum or pressure drums are used to
                                   wash pulp]                               
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------     Non-   
     Pollutant or pollutant property                Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................        29.75         15.5          8.71
    TSS.............................        43.95         23.65        12.99
    pH..............................        (\1\)      (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    Note: Limitations above do not apply to mills using continuous          
      digesters.                                                            
    
    
                                    Subpart E                               
    [Acid sulfite liquor/barometric condensers; BPT effluent limitations for
    papergrade sulfite facilities where vacuum or pressure drums are used to
                                   wash pulp]                               
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................         32.5         16.9         9.49
    TSS..............................         52.2         28.1        15.44
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    Note: Limitations above do not apply to mills using continuous          
      digesters.                                                            
    
    
                                    Subpart E                               
     [Continuous digesters; BPT effluent limitations for papergrade sulfite 
        facilities where vacuum or pressure drums are used to wash pulp]    
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................        38.15        19.85        11.15
    TSS..............................        53.75        28.95        15.91
    
    [[Page 18676]]
    
                                                                            
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (b) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of wet barking operations, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations:
    
                                    Subpart E                               
     [BPT effluent limitations for papergrade sulfite facilities where blow 
                        pit washing techniques are used]                    
    ------------------------------------------------------------------------
                                         Kg/kkg (or pounds per 1,000 lb) of 
                                                      product               
                                      --------------------------------------
                                        Continuous dischargers              
                                      --------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5.............................          2.7         1.45         0.80
    TSS..............................          7.5         3.95         2.19
    pH...............................        (\1\)        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart E                               
    [BPT effluent limitations for papergrade sulfite facilities where vacuum
                    or pressure drums are used to wash pulp]                
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          3.05          1.6          0.90
    TSS............................          7.5           3.95         2.19
    pH.............................      (\1\)         (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (c) The following limitations establish the quantity or quality of 
    pollutants or pollutant parameters, controlled by this section, 
    resulting from the use of log washing or chip washing operations, which 
    may be discharged by a point source subject to the provisions of this 
    subpart. These limitations are in addition to the limitations set forth 
    in paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs and/or 
    chips which are subject to such operations:
    
    [[Page 18677]]
    
    
    
                                    Subpart E                               
     [BPT effluent limitations for papergrade sulfite facilities where blow 
                        pit washing techniques are used]                    
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------     Non-   
     Pollutant or pollutant property                Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5............................         0.15          0.1          0.05
    TSS.............................         2.55          1.35         0.75
    pH..............................        (\1\)      (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
                                    Subpart E                               
    [BPT effluent limitations for papergrade sulfite facilities where vacuum
                    or pressure drums are used to wash pulp]                
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ---------------------------     Non-    
    Pollutant or pollutant property                Average of    continuous 
                                                  daily values   dischargers
                                     Maximum for     for 30        (annual  
                                      any 1 day    consecutive    average)  
                                                      days                  
    ------------------------------------------------------------------------
    BOD5...........................         0.35          0.2           0.1 
    TSS............................         2.55          1.35          0.75
    pH.............................        (\1\)      (\1\)         (\1\)   
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
        (d) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of log flumes or log ponds, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations:
    
                                    Subpart E                               
     [BPT effluent limitations for papergrade sulfite facilities where blow 
                        pit washing techniques are used]                    
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                      product               
                                     ---------------------------------------
                                        Continuous dischargers              
                                     ---------------------------            
     Pollutant or pollutant property                 Average of      Non-   
                                                       daily      continuous
                                       Maximum for   values for  dischargers
                                        any 1 day        30        (annual  
                                                    consecutive    average) 
                                                        days                
    ------------------------------------------------------------------------
    BOD5............................          0.35          0.2          0.1
    TSS.............................          1.7           0.9          0.5
    pH..............................      (\1\)           (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    
    [[Page 18678]]
    
    
                                    Subpart E                               
    [BPT effluent limitations for papergrade sulfite facilities where vacuum
                    or pressure drums are used to wash pulp]                
    ------------------------------------------------------------------------
                                        Kg/kkg (or pounds per 1,000 lb) of  
                                                     product                
                                    ----------------------------------------
                                       Continuous dischargers               
                                    ----------------------------     Non-   
    Pollutant or pollutant property                 Average of    continuous
                                                   daily values  dischargers
                                      Maximum for     for 30       (annual  
                                       any 1 day    consecutive    average) 
                                                       days                 
    ------------------------------------------------------------------------
    BOD5...........................          0.7           0.35          0.2
    TSS............................          1.70          0.9           0.5
    pH.............................      (\1\)         (\1\)           (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                        
    
    Sec. 430.53  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best conventional 
    pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT). The limitations shall be the same as those 
    specified for conventional pollutants in Sec. 430.52 of this subpart 
    for the best practicable control technology currently available (BCT).
    
    
    Sec. 430.54  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best available technology 
    economically achievable (BAT).
        (a) (1) The following effluent limitations apply to all dischargers 
    in the calcium-, magnesium-, or sodium-based sulfite pulp segment:
    
                                                        Subpart E                                                   
                           [Production of Calcium-, Magnesium-, or Sodium-based Sulfite Pulps]                      
    ----------------------------------------------------------------------------------------------------------------
                                                                BAT effluent limitations                            
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3)kg/kkg (or pounds per                                                                                        
     1,000 lb) of product                                                                                           
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  <>a                   (b)                    <>a                   (b)         
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
        (2)(i) The following effluent limitations apply to all dischargers 
    in the ammonium-based sulfite pulp segment:
    
                                  Subpart E--Production of Ammonium-Based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                           BAT effluent limitations                 
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day            Monthly average    
    ----------------------------------------------------------------------------------------------------------------
    TCDD a..............................................  b                             (c)                     
    TCDF a..............................................  b                             (c)                     
    Chloroform a........................................  (d)                               (c)                     
    Trichlorosyringol a.................................  b                             (c)                     
    3,4,5-trichlorocatechol a...........................  b                             (c)                     
    3,4,6-trichlorocatechol a...........................  b                             (c)                     
    3,4,5-trichloroguaiacol a...........................  b                             (c)                     
    3,4,6-trichloroguaiacol a...........................  b                             (c)                     
    4,5,6-trichloroguaiacol a...........................  b                             (c)                     
    2,4,5-trichlorophenol a.............................  b                             (c)                     
    2,4,6-trichlorophenol a.............................  b                             (c)                     
    Tetrachlorocatechol a...............................  b                             (c)                     
    Tetrachloroguaiacol a...............................  b                             (c)                     
    2,3,4,6-tetrachlorophenol a.........................  b                             (c)                     
    Pentachlorophenol a.................................  b                             (c)                     
    ----------------------------------------------------------------------------------------------------------------
    
    
    [[Page 18679]]
    
    
                                                                                                                    
                                                                   Continuous dischargers        Non-continuous     
                                                                 --------------------------        dischargers      
                                                                                           -------------------------
                                                                  Maximum for    Monthly    Maximum for     Annual  
                                                                   any 1 day     average     any 1 day     average  
                                                                                                                    
    (3) kg/kkg (or pounds per 1,000 lb) of product                                                                  
    ----------------------------------------------------------------------------------------------------------------
    AOX.........................................................          (d)          (d)          (d)          (d)
    COD.........................................................          (d)          (d)          (d)          (d)
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines that use a TCF bleaching process as disclosed by   
      the discharger in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22.         
    b ``c This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    d [Reserved].                                                                                                   
    
        (ii) The following effluent limitations apply to all dischargers in 
    the ammonium-based sulfite pulp segment with respect to each fiber line 
    that uses exclusively TCF bleaching processes, as disclosed by the 
    discharger in its NPDES permit application under 40 CFR 122.21(g)(3) 
    and certified under 40 CFR 122.22:
    
                                  Subpart E--Production of Ammonium-Based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                             BAT effluent limitations (TCF)                         
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3) kg/kkg (or pounds per                                                                                       
     1000 lb) of product                                                                                            
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  a                  (b)                    a                  (b)         
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
        (3)(i) The following effluent limitations apply to all dischargers 
    in the specialty grade pulp segment:
    
             Subpart E--Production of Specialty Grade Sulfite Pulps         
    ------------------------------------------------------------------------
                                             BAT effluent limitations       
                                    ----------------------------------------
    Pollutant or pollutant property                               Monthly   
                                      Maximum for any 1 day       Average   
    ------------------------------------------------------------------------
    TCDD a.........................  b                    (c)           
    TCDF a.........................  b                    (c)           
    Chloroform a...................  (d)                      (c)           
    Trichlorosyringol a............  b                    (c)           
    3,4,5-trichlorocatechol a......  b                    (c)           
    3,4,6-trichlorocatechol a......  b                    (c)           
    3,4,5-trichloroguaiacol a......  b                    (c)           
    3,4,6-trichloroguaiacol a......  b                    (c)           
    4,5,6-trichloroguaiacol a......  b                    (c)           
    2,4,5-trichlorophenol a........  b                    (c)           
    2,4,6-trichlorophenol a........  b                    (c)           
    Tetrachlorocatechol a..........  b                    (c)           
    Tetrachloroguaiacol a..........  b                    (c)           
    2,3,4,6-tetrachlorophenol a....  b                    (c)           
    Pentachlorophenol a............  b                    (c)           
    ------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                   Continuous dischargers        Non-continuous     
                                                                 --------------------------        dischargers      
                                                                                           -------------------------
                                                                  Maximum for    Monthly    Maximum for     Annual  
                                                                   any 1 day     average     any 1 day     average  
                                                                                                                    
    (3)kg/kkg (or pounds per 1,000 lb) of product                                                                   
    ----------------------------------------------------------------------------------------------------------------
    AOX.........................................................          (d)          (d)          (d)          (d)
    COD.........................................................          (d)          (d)          (d)          (d)
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines that use a TCF bleaching process as disclosed by   
      the discharger in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22.         
    b ``c This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    
    [[Page 18680]]
    
                                                                                                                    
    d [Reserved].                                                                                                   
    
        (ii) The following effluent limitations apply to dischargers in the 
    specialty grade pulp segment with respect to each fiber line that uses 
    exclusively TCF bleaching processes, as disclosed by the discharger in 
    its NPDES permit application under 40 CFR 122.21(g)(3) and certified 
    under 40 CFR 122.22:
    
                                     Subpart E--Production of Specialty Grade Pulps                                 
    ----------------------------------------------------------------------------------------------------------------
                                                             BAT effluent limitations (TCF)                         
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3)kg/kkg (or pounds per 1000                                                                                   
     lb) of product                                                                                                 
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  a                  (b)                    a                  (b)         
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
        (b) The following additional effluent limitations apply to each 
    discharger subject to this section in accordance with the previous 
    subcatgorization scheme unless it certifies to the permitting authority 
    that it is not using these compounds as biocides. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply. 
    Concentration limitations will only apply to non-continuous 
    dischargers:
    
                                                        Subpart E                                                   
                                         [Supplemental BAT effluent limitations]                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                 Maximum for any 1 day                              
        Pollutant or pollutant    ----------------------------------------------------------------------------------
               property             kg/kkg (or pounds per 1,000 lb)                                                 
                                               of product                            Milligrams/liter               
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol............  0.00058exp(0.017x)...............  ((0.011)(12.67)exp(0.017x))/y                 
    Trichlorophenol..............  0.0036exp(0.017x)................  ((0.068)(12.67)exp(0.017x))/y                 
    x = percent sulfite pulp in                                                                                     
     final product.                                                                                                 
    y = wastewater discharged in                                                                                    
     kgal per ton of product.                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    
        (c) Pursuant to 40 CFR 122.44(i) and 122.45(h), a discharger must 
    demonstrate compliance with the limitations in paragraphs (a)(2) or 
    (a)(3) of this section, as applicable, by monitoring for all pollutants 
    (except for AOX and COD) at the point where the wastewater containing 
    those pollutants leaves the bleach plant. The permitting authority may 
    impose effluent limitations and/or monitoring requirements on internal 
    wastestreams for any other pollutants covered in this section as 
    appropriate under 40 CFR 122.44(i) and 122.45(h).
    
    
    Sec. 430.55  New source performance standards (NSPS).
    
        New sources subject to this subpart must achieve the following new 
    source performance standards (NSPS), as applicable.
        (a) The following standards apply to each new source regardless of 
    when it commenced discharge:
    
                                                                            Subpart E                                                                       
                                                                           [1982 NSPS]                                                                      
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                              Kg/kkg (or pounds per 1,000 lb) of product                                    
                                         -------------------------------------------------------------------------------------------------------------------
                                                                         Continuous dischargers                                                             
      Pollutant or pollutant  property   --------------------------------------------------------------------------------------  Non-continuous dischargers 
                                                                                           Average of daily values for 30             (annual average)      
                                                    Maximum for any 1 day                         consecutive days                                          
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    BOD5................................  4.38exp(0.017x)..........................  2.36exp(0.017x)..........................  Average of daily values for 
                                                                                                                                 30 consecutive days divided
                                                                                                                                 by 1.91.                   
    TSS.................................  5.81exp(0.017x)..........................  3.03exp(0.017x)..........................  Average of daily values for 
                                                                                                                                 30 consecutive days divided
                                                                                                                                 by 1.90.                   
    pH..................................  (1)......................................  (1)......................................  (1)                         
    x = percent sulfite pulp in final product.                                                                                                              
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                                                                                                          
    
        (b) The following standards apply with respect to each new source 
    fiber line that commences discharge after June 15, 1998.
        (1) The following standards apply to all new sources in the 
    calcium-, magnesium-, or sodium-based sulfite pulp segment:
    
    [[Page 18681]]
    
    
    
                                                        Subpart E                                                   
                           [Production of Calcium-, Magnesium-, or Sodium-based Sulfite Pulps]                      
    ----------------------------------------------------------------------------------------------------------------
                                                                          NSPS                                      
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3)kg/kkg (or pounds per                                                                                        
     1,000 lb) of product                                                                                           
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  a                  (b)                    a                  (b)         
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
        (2)(i) The following standards apply to all new sources in the 
    ammonium-based sulfite pulp segment:
    
              Subpart E--Production of Ammonium-based Sulfite Pulps         
    ------------------------------------------------------------------------
                                                       NSPS                 
                                    ----------------------------------------
    Pollutant or pollutant property                               Monthly   
                                      Maximum for any 1 day       average   
    ------------------------------------------------------------------------
    TCDD a.........................  b                    (c)           
    TCDF a.........................  b                    (c)           
    Chloroform a...................  (d)                      (d)           
    Trichlorosyringol a............  b                    (c)           
    3,4,5-trichlorocatechol a......  b                    (c)           
    3,4,6-trichlorocatechol a......  b                    (c)           
    3,4,5-trichloroguaiacol a......  b                    (c)           
    3,4,6-trichloroguaiacol a......  b                    (c)           
    4,5,6-trichloroguaiacol a......  b                    (c)           
    2,4,5-trichlorophenol a........  b                    (c)           
    2,4,6-trichlorophenol a........  b                    (c)           
    Tetrachlorocatechol a..........  b                    (c)           
    Tetrachloroguaiacol a..........  b                    (c)           
    2,3,4,6-tetrachlorophenol a....  b                    (c)           
    Pentachlorophenol a............  b                    (c)           
    ------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                   Continuous dischargers        Non-continuous     
                                                                 --------------------------        dischargers      
                                                                                           -------------------------
                                                                  Maximum for    Monthly    Maximum for     Annual  
                                                                   any 1 day     average     any 1 day     average  
                                                                                                                    
    (3)kg/kkg (or pounds per 1,000 lb) of product                                                                   
    ----------------------------------------------------------------------------------------------------------------
    AOX.........................................................          (d)          (d)          (d)          (d)
    COD.........................................................          (d)          (d)          (d)          (d)
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines that use a TCF bleaching process as disclosed by   
      the discharger in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22.         
    b ``c This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    d [Reserved].                                                                                                   
    
        (ii) The following standards apply to all new sources in the 
    ammonium-based sulfite pulp segment with respect to each fiber line 
    that uses exclusively TCF bleaching processes, as disclosed by the 
    discharger in its NPDES permit application under 40 CFR 122.21(g)(3) 
    and certified under 40 CFR 122.22:
    
                                  Subpart E--Production of Ammonium-based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                       NSPS (TCF)                                   
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3)kg/kkg (or pounds per 1000                                                                                   
     lb) of product                                                                                                 
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  a                  (b)                    a                  (b)         
    
    [[Page 18682]]
    
                                                                                                                    
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
        (3)(i) The following standards apply to all new sources in the 
    specialty grade sulfite pulp segment:
    
                                 Subpart E--Production of Specialty Grade Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                                     NSPS                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day            Monthly average    
    ----------------------------------------------------------------------------------------------------------------
    TCDD a..............................................  b                             (c)                     
    TCDF a..............................................  b                             (c)                     
    Chloroform a........................................  (d)                               (d)                     
    Trichlorosyringol a.................................  b                             (c)                     
    3,4,5-trichlorocatechol a...........................  b                             (c)                     
    3,4,6-trichlorocatechol a...........................  b                             (c)                     
    3,4,5-trichloroguaiacol a...........................  b                             (c)                     
    3,4,6-trichloroguaiacol a...........................  b                             (c)                     
    4,5,6-trichloroguaiacol a...........................  b                             (c)                     
    2,4,5-trichlorophenol a.............................  b                             (c)                     
    2,4,6-trichlorophenol a.............................  b                             (c)                     
    Tetrachlorocatechol a...............................  b                             (c)                     
    Tetrachloroguaiacol.................................  b                             (c)                     
    2,3,4,6-tetrachlorophenol a.........................  b                             (c)                     
    Pentachlorophenol a.................................  b                             (c)                     
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                   Continuous dischargers        Non-continuous     
                                                                 --------------------------        dischargers      
                                                                                           -------------------------
                                                                  Maximum for    Monthly    Maximum for     Annual  
                                                                   any 1 day     average     any 1 day     average  
                                                                                                                    
    (3)kg/kkg (or pounds per 1,000 lb) of product                                                                   
    ----------------------------------------------------------------------------------------------------------------
    AOX.........................................................          (d)          (d)          (d)          (d)
    COD.........................................................          (d)          (d)          (d)          (d)
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines that use a TCF bleaching process as disclosed by   
      the discharger in its permit application under 40 CFR 122.21(g)(3) and certified under 40 CFR 122.22.         
    b ``c This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    d [Reserved].                                                                                                   
    
        (ii) The following standards apply to all new sources within the 
    specialty grade sulfite pulp segment with respect to each fiber line 
    that uses exclusively TCF bleaching processes, as disclosed by the 
    discharger in its NPDES permit application under 40 CFR 122.21(g)(3) 
    and certified under 40 CFR 122.22:
    
                                 Subpart E--Production of Specialty Grade Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                       NSPS (TCF)                                   
                                  ----------------------------------------------------------------------------------
        Pollutant or pollutant                Continuous dischargers                  Non-continuous dischargers    
               property           ----------------------------------------------------------------------------------
                                                                                                           Annual   
                                   Maximum for any 1 day     Monthly average     Maximum for any 1 day     average  
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (3)kg/kkg (or pounds per 1000                                                                                   
     lb) of product                                                                                                 
    ----------------------------------------------------------------------------------------------------------------
    AOX..........................  a                  (b)                    a                  (b)         
    COD..........................  (c)                    (c)                    (c)                    (c)         
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, permitting authorities  
      may do so as appropriate.                                                                                     
    c [Reserved].                                                                                                   
    
    
    [[Page 18683]]
    
        (c) The following standards apply to each new source regardless of 
    when it commenced discharge, unless it certifies to the permitting 
    authority that it is not using these compounds as biocides. Also, for 
    non-continuous dischargers, concentration limitations (mg/l) shall 
    apply. Concentration limitations will only apply to non-continuous 
    dischargers:
    
                                                        Subpart E                                                   
                                                   [Supplemental NSPS]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                 Maximum for any 1 day                              
        Pollutant or pollutant    ----------------------------------------------------------------------------------
               property             kg/kkg (or pounds per 1,000 lb)                                                 
                                               of product                            Milligrams/liter               
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol............  0.00058exp(0.017x)...............  ((0.015)(9.12)exp(0.017x))/y                  
    Trichlorophenol..............  0.0036exp(0.017x)................  ((0.094)(9.12)exp(0.017x))/y                  
    x = percent sulfite pulp in                                                                                     
     final product.                                                                                                 
    y = wastewater discharged in                                                                                    
     kgal per ton of product.                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    
        (d) Pursuant to 40 CFR 122.44(i) and 122.45(h), a discharger must 
    demonstrate compliance with the standards in paragraphs (b)(2) or 
    (b)(3) of this section, as applicable, by monitoring for all pollutants 
    (except for AOX, COD, BOD5, TSS, and pH) at the point where the 
    wastewater containing those pollutants leaves the bleach plant. The 
    permitting authority may impose effluent limitations and/or monitoring 
    requirements on internal wastestreams for any other pollutants covered 
    in this section as appropriate under 40 CFR 122.44(i) and 122.45(h).
    
    
    Sec. 430.56  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES).
        (a) The following pretreatment standards must be attained on or 
    before April 16, 2001.
        (1) The following pretreatment standards apply to all indirect dis- 
    chargers in the calcium-, magnesium-, or sodium-based sulfite pulp 
    segment:
    
                                                        Subpart E                                                   
                           [Production of Calcium-, Magnesium-, or Sodium-based Sulfite Pulps]                      
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSES                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
                                                                                                                    
    (1) kg/kkg (or pounds per 1,000 lb) of product                                                                  
    ----------------------------------------------------------------------------------------------------------------
    AOX.................................................  >ML a                             (b)                     
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (2)(i) The following pretreatment standards apply to all indirect 
    dischargers in the ammonium-based sulfite pulp segment:
    
                                  Subpart E--Production of Ammonium-Based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSES                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day            Monthly average    
    ----------------------------------------------------------------------------------------------------------------
    TCDD a..............................................  b                             (c)                     
    TCDF a..............................................  b                             (c)                     
    Trichlorosyringol a.................................  b                             (c)                     
    3,4,5-trichlorocatechol a...........................  b                             (c)                     
    3,4,6-trichlorocatechol a...........................  b                             (c)                     
    3,4,5-trichloroguaiacol a...........................  b                             (c)                     
    3,4,6-trichloroguaiacol a...........................  b                             (c)                     
    4,5,6-trichloroguaiacol a...........................  b                             (c)                     
    2,4,5-trichlorophenol a.............................  b                             (c)                     
    2,4,6-trichlorophenol a.............................  b                             (c)                     
    Tetrachlorocatechol a...............................  b                             (c)                     
    Tetrachloroguaiacol a...............................  b                             (c)                     
    2,3,4,6-tetrachlorophenol a.........................  b                             (c)                     
    Pentachlorophenol a.................................  b                             (c)                     
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines operated by any indirect discharger that discloses 
      to the pretreatment control authority, at the time it submits the report required under 40 CFR 403.12(b), (d),
      or (e), that it uses a TCF bleaching process at that fiber line.                                              
    b ``c This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
    
    [[Page 18684]]
    
        (ii) The following pretreatment standards apply with respect to 
    each new source fiber line operated by an indirect discharger producing 
    ammonium-based sulfite pulps if the indirect discharger discloses to 
    the pretreatment control authority in a report submitted under 40 CFR 
    403.12(b) that it uses exclusively TCF bleaching processes at that 
    fiber line:
    
                                  Subpart E--Production of Ammonium-Based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                                  PSNS (TCF)                        
              Pollutant or pollutant parameter           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
    AOX.................................................  a                             (b)                     
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (3)(i) The following pretreatment standards apply to all indirect 
    dischargers in the specialty grade sulfite pulp segment:
    
                                 Subpart E--Production of Specialty Grade Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSES                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day            Monthly average    
    ----------------------------------------------------------------------------------------------------------------
    TCDD a..............................................  b                             (c)                     
    TCDF a..............................................  b                             (c)                     
    Trichlorosyringol a.................................  b                             (c)                     
    3,4,5-trichlorocatechol a...........................  b                             (c)                     
    3,4,6-trichlorocatechol a...........................  b                             (c)                     
    3,4,5-trichloroguaiacol a...........................  b                             (c)                     
    3,4,6-trichloroguaiacol a...........................  b                             (c)                     
    4,5,6-trichloroguaiacol a...........................  b                             (c)                     
    2,4,5-trichlorophenol a.............................  b                             (c)                     
    2,4,6-Trichlorophenol a.............................  b                             (c)                     
    Tetrachlorocatechol a...............................  b                             (c)                     
    Tetrachloroguaiacol a...............................  b                             (c)                     
    2,3,4,6-tetrachlorophenol a.........................  b                             (c)                     
    Pentachlorophenol a.................................  b                             (c)                     
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines operated by any indirect discharger that discloses 
      to the pretreatment control authority, at the time it submits the report required under 40 CFR 403.12(b), (d),
      or (e), that it uses a TCF bleaching process at that fiber line.                                              
    b ``c This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (ii) The following pretreatment standards apply with respect to 
    each fiber line operated by an indirect discharger producing specialty 
    grade sulfite pulps if the indirect discharger discloses to the 
    pretreatment control authority in a report submitted under 40 CFR 
    403.12(b) that it uses exclusively TCF bleaching processes at that 
    fiber line. These pretreatment standards must be attained on or before 
    April 16, 2001:
    
                                                        Subpart E                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                  PSES (TCF)                        
              Pollutant or pollutant parameter           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
    AOX.................................................  a                             (b)                     
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (b) The following pretreatment standards apply to each indirect 
    discharger, in accordance with the previous subcategorization scheme, 
    unless it certifies to the pretreatment control authority that it is 
    not using these compounds as biocides. In cases when POTWs find it 
    necessary to impose mass effluent limitations, equivalent mass 
    limitations are provided as guidance:
    
                                                                            Subpart E                                                                       
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                  Supplemental PSES                                         
                                                        ----------------------------------------------------------------------------------------------------
              Pollutant or pollutant property                                                   Maximum for any 1 day                                       
                                                        ----------------------------------------------------------------------------------------------------
                                                          kg/kkg (or pounds per 1,000 lb) of product                      Milligrams/liter                  
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Pentachlorophenol..................................  0.00058exp(0.017x)..........................  ((0.011)(12.67)exp(0.017x))/y                        
    
    [[Page 18685]]
    
                                                                                                                                                            
    Trichlorophenol....................................  0.0043exp(0.017x)...........................  ((0.082)(12.67)exp(0.017x))/y                        
    x = percent sulfite pulp in final product.                                                                                                              
    y = wastewater discharged in kgal per ton of                                                                                                            
     product.                                                                                                                                               
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    
        (c) An indirect discharger must demonstrate compliance with the 
    pretreatment standards in paragraphs (a)(2) or (a)(3) of this section, 
    as applicable, by monitoring for all pollutants at the point where the 
    wastewater containing those pollutants leaves the bleach plant.
    
    
    Sec. 430.57  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS).
        (a) (1) The following pretreatment standards apply to each indirect 
    discharger in the calcium-,
    magnesium-, or sodium-based sulfite pulp segment that is a new source:
    
                                                        Subpart E                                                   
                           [Production of Calcium-, Magnesium-, or Sodium-Based Sulfite Pulps]                      
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
                                                                  kg/kkg (or pounds per 1,000 lb) of product        
                                                         -----------------------------------------------------------
    AOX.................................................  a                             (b)                     
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (2)(i) The following standards apply to each indirect discharger in 
    the ammonium-based sulfite pulp segment that is a new source:
    
                                 Subpart E.--Production of Ammonium-Based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
    TCDD a..............................................  b                             (c)                     
    TCDF a..............................................  b                             (c)                     
    Trichlorosyringol a.................................  b                             (c)                     
    3,4,5-trichlorocatechol a...........................  b                             (c)                     
    3,4,6-trichlorocatechol a...........................  b                             (c)                     
    3,4,5-trichloroguaiacol a...........................  b                             (c)                     
    3,4,6-trichloroguaiacol a...........................  b                             (c)                     
    4,5,6-trichloroguaiacol a...........................  b                             (c)                     
    2,4,5-trichlorophenol a.............................  b                             (c)                     
    2,4,6-trichlorophenol a.............................  b                             (c)                     
    Tetrachlorocatechol a...............................  b                             (c)                     
    Tetrachloroguaiacol a...............................  b                             (c)                     
    2,3,4,6-tetrachlorophenol a.........................  b                             (c)                     
    Pentachlorophenol a.................................  b                             (c)                     
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines operated by any indirect discharger that discloses 
      to the pretreatment control authority, at the time it submits the report required under 40 CFR 403.12 (b),    
      (d), or (e), that it uses a TCF bleaching process at that fiber line.                                         
    b ``c This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (ii) The following pretreatment standards apply with respect to 
    each new source fiber line operated by an indirect discharger producing 
    ammonium-based sulfite pulps if the indirect discharger discloses to 
    the pretreatment control authority in a report submitted under 40 CFR 
    403.12(b) that it uses exclusively TCF bleaching processes at that 
    fiber line:
    
    [[Page 18686]]
    
    
    
                                 Subpart E.--Production of Ammonium-Based Sulfite Pulps                             
    ----------------------------------------------------------------------------------------------------------------
                                                                                  PSNS (TCF)                        
              Pollutant or pollutant parameter           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
    AOX.................................................  a                             (b)                     
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (3)(i) The following pretreatment standards apply to each indirect 
    discharger in the specialty grade sulfite pulp segment that is a new 
    source:
    
                                 Subpart E.--Production of Specialty Grade Sulfite Pulps                            
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
               Pollutant or pollutant property           -----------------------------------------------------------
                                                                Maximum for any 1 day           Monthly  average    
    ----------------------------------------------------------------------------------------------------------------
    TCDD a..............................................  b                             (c)                     
    TCDF a..............................................  b                             (c)                     
    Trichlorosyringol a.................................  b                             (c)                     
    3,4,5-trichlorocatechol a...........................  b                             (c)                     
    3,4,6-trichlorocatechol a...........................  b                             (c)                     
    3,4,5-trichloroguaiacol a...........................  b                             (c)                     
    3,4,6-trichloroguaiacol a...........................  b                             (c)                     
    4,5,6-trichloroguaiacol a...........................  b                             (c)                     
    2,4,5-trichlorophenol a.............................  b                             (c)                     
    2,4,6-trichlorophenol a.............................  b                             (c)                     
    Tetrachlorocatechol a...............................  b                             (c)                     
    Tetrachloroguaiacol a...............................  b                             (c)                     
    2,3,4,6-tetrachlorophenol a.........................  b                             (c)                     
    Pentachlorophenol a.................................  b                             (c)                     
    ----------------------------------------------------------------------------------------------------------------
    a These limitations do not apply with respect to fiber lines operated by any indirect discharger that discloses 
      to the pretreatment control authority, at the time it submits the report required under 40 CFR 403.12 (b),    
      (d), or (e), that it uses a TCF bleaching process at that fiber line.                                         
    b ``c This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (ii) The following pretreatment standards apply with respect to 
    each new source fiber line operated by an indirect discharger producing 
    specialty grade sulfite pulps if the indirect discharger discloses to 
    the pretreatment control authority in a report submitted under 40 CFR 
    403.12(b) that it uses exclusively TCF bleaching processes at that 
    fiber line:
    
                                 Subpart E.--Production of Specialty Grade Sulfite Pulps                            
    ----------------------------------------------------------------------------------------------------------------
                                                                                      PSNS (TCF)                    
                                                                ----------------------------------------------------
                  Pollutant or pollutant parameter                                                         Monthly  
                                                                          Maximum for any 1 day            average  
    ----------------------------------------------------------------------------------------------------------------
    AOX........................................................  a                                           (b)
    ----------------------------------------------------------------------------------------------------------------
    a ``b This regulation does not specify this type of limitation for this pollutant; however, pretreatment control    
      authorities may do so as appropriate.                                                                         
    
        (b) The following pretreatment standards shall apply to each new 
    source indirect dischargers unless the indirect discharger certifies to 
    the pretreatment control authority that it is not using these compounds 
    as biocides. In cases when POTWs find it necessary to impose mass 
    effluent standards, equivalent mass standards are provided as guidance:
    
                                                        Subpart E                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                          Supplemental PSNS                         
                                               ---------------------------------------------------------------------
                                                                        Maximum for any 1 day                       
          Pollutant or pollutant property      ---------------------------------------------------------------------
                                                 kg/kkg (or pounds per                                              
                                                 1,000 lb) of product                 Milligrams/liter              
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................  0.00058exp (0.017x)...  ((0.015)(9.12)exp(0.017x))/y                
    Trichlorophenol...........................  0.0043exp (0.017x)....  ((0.114)(9.12)exp(0.017x))/y                
    x = percent sulfite pulp in final product.                                                                      
    y = wastewater discharged in kgal per ton                                                                       
     of product.                                                                                                    
    ----------------------------------------------------------------------------------------------------------------
    
    
    [[Page 18687]]
    
        (c) An indirect discharger must demonstrate compliance with the 
    pretreatment standards in paragraphs (a)(2) or (a)(3) of this section, 
    as applicable, by monitoring for all pollutants at the point where the 
    wastewater containing those pollutants leaves the bleach plant.
    
    
    Sec. 430.58  Best management practices (BMPs).
    
        The definitions and requirements set forth in 40 CFR 430.03 apply 
    to facilities in this subpart.
    
    Subpart F--Semi-Chemical Subcategory
    
    
    Sec. 430.60  Applicability; description of the semi-chemical 
    subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the integrated production of pulp and paper at semi-
    chemical mills.
    
    
    Sec. 430.61  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    
    Sec. 430.62  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best practicable control 
    technology currently available (BPT):
    
                                                        Subpart F                                                   
                                    [BPT effluent limitations for ammonia base mills]                               
    ----------------------------------------------------------------------------------------------------------------
                                                                  Kg/kkg (or pounds per 1,000 lb) of product        
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                               Average of daily values
                                                                Maximum for any 1 day        for 30 consecutive days
    ----------------------------------------------------------------------------------------------------------------
    BOD5................................................   8.0                              4.0                     
    TSS.................................................  10.0                              5.0                     
    pH..................................................  (\1\)                             (\1\)                   
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart F                                                   
                                    [BPT effluent limitations for sodium base mills]                                
    ----------------------------------------------------------------------------------------------------------------
                                                                  Kg/kkg (or pounds per 1,000 lb) of product        
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                               Average of daily values
                                                                Maximum for any 1 day        for 30 consecutive days
    ----------------------------------------------------------------------------------------------------------------
    BOD5................................................   8.7                              4.35                    
    TSS.................................................  11.0                              5.5                     
    pH..................................................  (\1\)                             (\1\)                   
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                                                                
    
    Sec. 430.63  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT): The limitations shall be the same as those 
    specified for conventional pollutants (which are defined in 40 CFR 
    401.16) in Sec. 430.62 of this subpart for the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average-of-30-
    consecutive-days limitations, but shall be subject to annual average 
    effluent limitations determined by dividing the average-of-30-
    consecutive-days limitations for BOD5 by 1.36 and TSS by 1.36.
    
    
    Sec. 430.64  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1,000 lb), but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
    [[Page 18688]]
    
    
    
                                                        Subpart F                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                              BAT effluent limitations              
                                                               -----------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                  Pollutant or pollutant property                Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0012   (0.029)(10.3)/y                       
    Trichlorophenol...........................................       0.00043  (0.010)(10.3)/y                       
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    Sec. 430.65  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides:
    
                                                        Subpart F                                                   
                                                         [NSPS]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                Kg/kkg (or pounds per 1,000 lb) of  
                                                                                              product               
                                                                             ---------------------------------------
                                                                               Continuous dischargers               
                                                                             --------------------------     Non-    
                         Pollutant or pollutant property                                    Average of   continuous 
                                                                                              daily         dis-    
                                                                              Maximum for   values for    chargers  
                                                                               any 1 day        30         (annual  
                                                                                           consecutive    average)  
                                                                                               days                 
    ----------------------------------------------------------------------------------------------------------------
    BOD5....................................................................          3.0          1.6          0.84
    TSS.....................................................................          5.8          3.0          1.6 
    pH......................................................................        (\1\)        (\1\)      (\1\)   
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                              Maximum for any 1 day                 
                                                            --------------------------------------------------------
                                                              Kg/kkg (or                                            
                                                              pounds per                                            
                                                             1,000 lb) of               Milligrams/liter            
                                                                product                                             
    Pentachlorophenol......................................       0.0012   (0.041)(7.3)/y                           
    Trichlorophenol........................................       0.00043  (0.014)(7.3)/y                           
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.66  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides. PSES must be attained 
    on or before July 1, 1984:
    
                                                        Subpart F                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSES                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                           Kg/kkg (or 
                                                                                                         pounds per 
                                                                        Milligrams/liter                1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(10.3)/y.............................       0.0014 
    
    [[Page 18689]]
    
                                                                                                                    
    Trichlorophenol.....................................  (0.010)(10.3)/y.............................       0.00043
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    Sec. 430.67  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart F                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                           Kg/kkg (or 
                                                                                                         pounds per 
                                                                        Milligrams/liter                1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.045)(7.3)/y..............................       0.0014 
    Trichlorophenol.....................................  (0.014)(7.3)/y..............................       0.00043
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    Subpart G--Mechanical Pulp Subcategory
    
    
    Sec. 430.70  Applicability; description of the mechanical pulp 
    subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from: the production of pulp and paper at groundwood chemi-
    mechanical mills; the production of pulp and paper at groundwood mills 
    through the application of the thermo-mechanical process; the 
    integrated production of pulp and coarse paper, molded pulp products, 
    and newsprint at groundwood mills; and the integrated production of 
    pulp and fine paper at groundwood mills.
    
    
    Sec. 430.71  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    
    Sec. 430.72  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
                                                        Subpart G                                                   
      [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical  
                                                   mills are produced]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         13.5         7.05         3.96
    TSS......................................................................        19.75        10.65         5.85
    
    [[Page 18690]]
    
                                                                                                                    
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced 
                                through the application of the thermo-mechanical process]                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         10.6         5.55         3.12
    TSS......................................................................        15.55         8.35         4.59
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
       [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse  
                         paper, molded pulp products, and newsprint at groundwood mills occurs]                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         7.45          3.9         2.19
    TSS......................................................................        12.75         6.85         3.76
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper
                                               at groundwood mills occurs]                                          
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         6.85          3.6          2.0
    TSS......................................................................        11.75          6.3          3.5
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
    [[Page 18691]]
    
        (b) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of wet barking operations, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days 
    limitations, but shall be subject to annual average effluent 
    limitations:
    
                                                        Subpart G                                                   
      [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical  
                                                   mills are produced]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          0.9         0.45         0.25
    TSS......................................................................          2.6         1.45         0.80
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced 
                                through the application of the thermo-mechanical process]                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          0.9         0.45         0.3 
    TSS......................................................................          2.7         1.45         0.75
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
       [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse  
                         paper, molded pulp products, and newsprint at groundwood mills occurs]                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         1.15         0.55         0.30
    TSS......................................................................         2.0          1.1          0.60
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
    [[Page 18692]]
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper
                                               at groundwood mills occurs]                                          
    ----------------------------------------------------------------------------------------------------------------
                                                                                Kg/kkg (or pounds per 1,000 lb) of  
                                                                                             product                
                                                                            ----------------------------------------
                                                                               Continuous dischargers               
                                                                            ---------------------------     Non-    
                        Pollutant or pollutant property                                    Average of    continuous 
                                                                                          daily values      dis-    
                                                                             Maximum for     for 30       chargers  
                                                                              any 1 day    consecutive     (annual  
                                                                                              days        average)  
    ----------------------------------------------------------------------------------------------------------------
    BOD5...................................................................         1.1           0.55          0.35
    TSS....................................................................         1.95          1.1           0.60
    pH.....................................................................        (\1\)      (\1\)         (\1\)   
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
        (c) The following limitations establish the quantity or quality of 
    pollutants or pollutant parameters, controlled by this section, 
    resulting from the use of log washing or chip washing operations, which 
    may be discharged by a point source subject to the provisions of this 
    subpart. These limitations are in addition to the limitations set forth 
    in paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs and/or 
    chips which are subject to such operations. Non-continuous dischargers 
    shall not be subject to the maximum day and average of 30 consecutive 
    days limitations, but shall be subject to the annual average effluent 
    limitations:
    
                                                        Subpart G                                                   
      [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical  
                                                   mills are produced]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.05         0.05         0.05
    TSS......................................................................         0.25         0.15         0.10
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced 
                                through the application of the thermo-mechanical process]                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.05         0.05         0.05
    TSS......................................................................         0.30         0.15         0.05
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
    [[Page 18693]]
    
    
                                                        Subpart G                                                   
       [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse  
                         paper, molded pulp products, and newsprint at groundwood mills occurs]                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.15         0.05         0.05
    TSS......................................................................         0.20         0.15         0.10
    pH.......................................................................        (\1\)        (\1\)       (\1\) 
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper
                                               at groundwood mills occurs]                                          
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.15         0.05         0.05
    TSS......................................................................          0.2         0.15         0.10
    pH.......................................................................        (\1\)        (\1\)       (\1\) 
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
        (d) The following limitations establish the quantity or quality of 
    pollutants or pollutant properties, controlled by this section, 
    resulting from the use of log flumes or log ponds, which may be 
    discharged by a point source subject to the provisions of this subpart. 
    These limitations are in addition to the limitations set forth in 
    paragraph (a) of this section and shall be calculated using the 
    proportion of the mill's total production due to use of logs which are 
    subject to such operations. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days 
    limitations but shall be subject to the annual average effluent 
    limitations:
    
                                                        Subpart G                                                   
      [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical  
                                                   mills are produced]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.15         0.05         0.05
    TSS......................................................................         0.55          0.3         0.15
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
    [[Page 18694]]
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced 
                                through the application of the thermo-mechanical process]                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.15         0.15         0.05
    TSS......................................................................         0.60         0.35         0.15
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
       [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse  
                         paper, molded pulp products, and newsprint at groundwood mills occurs]                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         0.25         0.1          0.05
    TSS......................................................................         0.45         0.25         0.15
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper
                                               at groundwood mills occurs]                                          
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          0.2         0.05         0.05
    TSS......................................................................          0.4         0.25         0.15
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
        (e) For those mills using zinc hydrosulfite as a bleaching agent in 
    the manufacturing process, the following effluent limitations are to be 
    added to the base limitations set forth in paragraph (a) of this 
    section. Permittees not using zinc hydrosulfite as a bleaching agent 
    must certify to the permit issuing authority that they are not using 
    this bleaching compound. Non-continuous dischargers shall not be 
    subject to the maximum day and average of 30 consecutive days effluent 
    limitations, but shall be subject to annual average effluent 
    limitations:
    
    [[Page 18695]]
    
    
    
                                                        Subpart G                                                   
      [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood chemi-mechanical  
                                                   mills are produced]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                               Kg/kkg (or pounds per 1,000 lb) of   
                                                                                             product                
                                                                           -----------------------------------------
                                                                              Continuous dischargers                
                                                                           ----------------------------     Non-    
                        Pollutant or pollutant property                                    Average of    continuous 
                                                                                          daily values   dischargers
                                                                             Maximum for     for 30        (annual  
                                                                              any 1 day    consecutive    average)  
                                                                                              days                  
    ----------------------------------------------------------------------------------------------------------------
    Zinc..................................................................         0.34          0.17          0.11 
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced 
                                through the application of the thermo-mechanical process]                           
    ----------------------------------------------------------------------------------------------------------------
                                                                               Kg/kkg (or pounds per 1,000 lb) of   
                                                                                             product                
                                                                           -----------------------------------------
                                                                              Continuous dischargers                
                                                                           ----------------------------     Non-    
                        Pollutant or pollutant property                                    Average of    continuous 
                                                                                          daily values   dischargers
                                                                             Maximum for     for 30        (annual  
                                                                              any 1 day    consecutive    average)  
                                                                                              days                  
    ----------------------------------------------------------------------------------------------------------------
    Zinc..................................................................         0.26          0.13          0.09 
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart G                                                   
       [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse  
                         paper, molded pulp products, and newsprint at groundwood mills occurs]                     
    ----------------------------------------------------------------------------------------------------------------
                                                                               Kg/kkg (or pounds per 1,000 lb) of   
                                                                                             product                
                                                                           -----------------------------------------
                                                                              Continuous dischargers                
                                                                           ----------------------------     Non-    
                        Pollutant or pollutant property                                    Average of    continuous 
                                                                                          daily values   dischargers
                                                                             Maximum for     for 30        (annual  
                                                                              any 1 day    consecutive    average)  
                                                                                              days                  
    ----------------------------------------------------------------------------------------------------------------
    Zinc..................................................................         0.30          0.15          0.10 
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart G                                                   
     [BPT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper
                                               at groundwood mills occurs]                                          
    ----------------------------------------------------------------------------------------------------------------
                                                                               Kg/kkg (or pounds per 1,000 lb) of   
                                                                                             product                
                                                                           -----------------------------------------
                                                                              Continuous dischargers                
                                                                           ----------------------------     Non-    
                        Pollutant or pollutant property                                    Average of    continuous 
                                                                                          daily values   dischargers
                                                                             Maximum for     for 30        (annual  
                                                                              any 1 day    consecutive    average)  
                                                                                              days                  
    ----------------------------------------------------------------------------------------------------------------
    Zinc..................................................................        0.275         0.135         0.090 
    ----------------------------------------------------------------------------------------------------------------
    
    Sec. 430.73  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        (a)(1) The following applies to: mechanical pulp facilities where 
    the integrated production of pulp and coarse paper, molded pulp 
    products, and newsprint at groundwood mills occurs; and mechanical pulp 
    facilities where the integrated production of pulp and fine paper at 
    groundwood mills occurs:
        (2) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart shall achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best conventional
    
    [[Page 18696]]
    
    pollutant control technology (BCT): The limitations shall be the same 
    as those specified for conventional pollutants (which are defined in 40 
    CFR 401.16) in Sec. 430.72 of this subpart for the best practicable 
    control technology currently available (BPT).
        (b) [Reserved]
    
    
    Sec. 430.74  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        (a) The following applies to mechanical pulp facilities where pulp 
    and paper at groundwood mills are produced through the application of 
    the thermo-mechanical process; mechanical pulp facilities where the 
    integrated production of pulp and coarse paper, molded pulp products, 
    and newsprint at groundwood mills occurs; and mechanical pulp 
    facilities where the integrated production of pulp and fine paper at 
    groundwood mills occurs: except as provided in 40 CFR 125.30 through 
    125.32, any existing point source subject to this subpart must achieve 
    the following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT), except that non-continuous 
    dischargers shall not be subject to the maximum day mass limitations in 
    kg/kkg (lb/1000 lb), but shall be subject to concentration limitations. 
    Concentration limitations are only applicable to non-continuous 
    dischargers. Pentachlorophenol and trichlorophenol limitations are only 
    applicable at facilities where chlorophenolic-containing biocides are 
    used. Permittees not using chlorophenolic-containing biocides must 
    certify to the permit-issuing authority that they are not using these 
    biocides. Zinc limitations are only applicable at facilities where zinc 
    hydrosulfite is used as a bleaching agent. Permittees not using zinc 
    hydrosulfite as a bleaching agent must certify to the permit issuing 
    authority that they are not using this bleaching compound:
    
                                                        Subpart G                                                   
     [BAT effluent limitations for mechanical pulp facilities where pulp and paper at groundwood mills are produced 
                                through the application of the thermo-mechanical process]                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.00097  (0.011)(21.1)/y                       
    Trichlorophenol...........................................       0.00088  (0.010)(21.1)/y                       
    Zinc......................................................       0.26     (3.0)(21.1)/y                         
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart G                                                   
       [BAT effluent limitations for mechanical pulp facilities where the integrated production of pulp and coarse  
                         paper, molded pulp products, and newsprint at groundwood mills occurs]                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0011   (0.011)(23.8)/y                       
    Trichlorophenol...........................................       0.00099  (0.010)(23.8)/y                       
    Zinc......................................................       0.30     (3.0)(23.8)/y                         
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart G                                                   
     [BAT effluent limitations for mechanical pulp facilities where the integrated production of pulp and fine paper
                                               at groundwood mills occurs                                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0010   (0.011)(21.9)/y                       
    Trichlorophenol...........................................       0.00092  (0.010)(21.9)/y                       
    Zinc......................................................       0.27     (3.0)(21.9)/y                         
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
        (b) [Reserved]
    
    
    Sec. 430.75  New source performance standards (NSPS).
    
        (a) The following applies to mechanical pulp facilities where pulp 
    and paper at groundwood mills are produced through the application of 
    the thermo-mechanical process; mechanical pulp facilities where the 
    integrated
    
    [[Page 18697]]
    
    production of pulp and coarse paper, molded pulp products, and 
    newsprint at groundwood mills occurs; and mechanical pulp facilities 
    where the integrated production of pulp and fine paper at groundwood 
    mills occurs: any new source subject to this subpart must achieve the 
    following new source performance standards (NSPS), except that non-
    continuous dischargers shall not be subject to the maximum day and 
    average of 30 consecutive days effluent limitations for BOD5 and TSS, 
    but shall be subject to annual average effluent limitations. Also, for 
    non-continuous dischargers, concentration limitations (mg/l) shall 
    apply, where provided. Concentration limitations will only apply to 
    non-continuous dischargers. Pentachlorophenol and trichlorophenol 
    limitations are only applicable at facilities where chlorophenolic-
    containing biocides are used. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides. Zinc limitations are only applicable 
    at facilities where zinc hydrosulfite is used as a bleaching agent. 
    Permittees not using zinc hydrosulfite as a bleaching agent must 
    certify to the permit issuing authority that they are not using this 
    bleaching compound:
    
                                                        Subpart G                                                   
         [NSPS for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the     
                                      application of the thermo-mechanical process]                                 
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          4.6          2.5          1.3
    TSS......................................................................          8.7          4.6          2.4
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                              Maximum for any 1 day                 
                                                            --------------------------------------------------------
                                                              Kg/kkg (or                                            
                                                              pounds per                                            
                                                             1,000 lb) of               Milligrams/liter            
                                                                product                                             
    Pentachlorophenol......................................       0.00097  (0.017)(13.8)/y                          
    Trichlorophenol........................................       0.00088  (0.015)(13.8)/y                          
    Zinc...................................................       0.17     (3.0)(13.8)/y                            
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart G                                                   
       [NSPS for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp   
                                   products, and newsprint at groundwood mills occurs]                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          4.6          2.5          1.3
    TSS......................................................................          7.3          3.8          2.0
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                              Maximum for any 1 day                 
                                                            --------------------------------------------------------
                                                              Kg/kkg (or                                            
                                                              pounds per                                            
                                                             1,000 lb) of               Milligrams/liter            
                                                                product                                             
    Pentachlorophenol......................................       0.0011   (0.016)(16.8)/y                          
    Trichlorophenol........................................       0.00099  (0.014)(16.8)/y                          
    Zinc...................................................       0.21     (3.0)(16.8)/y                            
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
    [[Page 18698]]
    
    
                                                        Subpart G                                                   
       [NSPS mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills  
                                                         occurs]                                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          3.5          1.9         0.99
    TSS......................................................................          5.8          3.0         1.58
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                               Maximum for any 1 day                
                                                             -------------------------------------------------------
                                                               Kg/kkg (or                                           
                                                               pounds per                                           
                                                               1,000 lb)                Milligrams/liter            
                                                               of product                                           
    Pentachlorophenol.......................................      0.0010   (0.016) (15.4)/y                         
    Trichlorophenol.........................................      0.00092  (0.014) (15.4)/y                         
    Zinc....................................................      0.19     (3.0) (15.4)/y                           
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
        (b) [Reserved]
    
    
    Sec. 430.76  Pretreatment standards for existing sources (PSES).
    
        (a) The following applies to mechanical pulp facilities where pulp 
    and paper at groundwood mills are produced through the application of 
    the thermo-mechanical process; mechanical pulp facilities where the 
    integrated production of pulp and coarse paper, molded pulp products, 
    and newsprint at groundwood mills occurs; and mechanical pulp 
    facilities where the integrated production of pulp and fine paper at 
    groundwood mills occurs: except as provided in 40 CFR 403.7 and 403.13, 
    any existing source subject to this subpart that introduces pollutants 
    into a publicly owned treatment works must comply with 40 CFR part 403 
    and achieve the following pretreatment standards for existing sources 
    (PSES). Pentachlorophenol and trichlorophenol limitations are only 
    applicable at facilities where chlorophenolic-containing biocides are 
    used. Permittees not using chlorophenolic-containing biocides must 
    certify to the permit-issuing authority that they are not using these 
    biocides. Zinc limitations are only applicable at facilities where zinc 
    hydrosulfite is used as a bleaching agent. Permittees not using zinc 
    hydrosulfite as a bleaching agent must certify to the permit-issuing 
    authority that they are not using this bleaching compound. PSES must be 
    attained on or before July 1, 1984:
    
                                                        Subpart G                                                   
         [PSES for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the     
                                      application of the thermo-mechanical process]                                 
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/1)            1,000 1b) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.011) (21.1)/y............................       0.00097
    Trichlorophenol.....................................  (0.010) (21.1)/y............................       0.00088
    Zinc................................................  (3.0) (21.1)/y..............................       0.26   
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18699]]
    
    
                                                        Subpart G                                                   
       [PSES for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp   
                                   products, and newsprint at groundwood mills occurs]                              
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/1)            1,000 1b) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.011) (23.8)/y............................       0.0011 
    Trichlorophenol.....................................  (0.010) (23.8)/y............................       0.00099
    Zinc................................................  (3.0) (23.8)/y..............................       0.30   
    y = wasterwater discharged in kgal per ton of                                                                   
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart G                                                   
     [PSNS for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills
                                                         occurs]                                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          producta  
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.011)(21.9)/y.............................       0.0010 
    Trichlorophenol.....................................  (0.010)(21.9)/y.............................       0.00092
    Zinc................................................  (3.0)(21.9)/y...............................       0.27   
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
        (b) [Reserved]
    
    
    Sec. 430.77  Pretreatment standards for new sources (PSNS).
    
        (a) The following applies to mechanical pulp facilities where pulp 
    and paper at groundwood mills are produced through the application of 
    the thermo-mechanical process; mechanical pulp facilities where the 
    integrated production of pulp and coarse paper, molded pulp products, 
    and newsprint at groundwood mills occurs; and mechanical pulp 
    facilities where the integrated production of pulp and fine paper at 
    groundwood mills occurs: except as provided in 40 CFR 403.7, any new 
    source subject to this subpart that introduces pollutants into a 
    publicly owned treatment works must comply with 40 CFR part 403 and 
    achieve the following pretreatment standards for new sources (PSNS). 
    Pentachlorophenol and trichlorophenol limitations are only applicable 
    at facilities where chlorophenolic-containing biocides are used. 
    Permittees not using chlorophenolic-containing biocides must certify to 
    the permit-issuing authority that they are not using these biocides. 
    Zinc limitations are only applicable at facilities where zinc 
    hydrosulfite is used as a bleaching agent. Permittees not using zinc 
    hydrosulfite as a bleaching agent must certify to the permit issuing 
    authority that they are not using this bleaching compound:
    
                                                        Subpart G                                                   
         [PSNS for mechanical pulp facilities where pulp and paper at groundwood mills are produced through the     
                                      application of the thermo-mechanical process]                                 
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          producta  
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.017)(13.8)/y.............................       0.00097
    Trichlorophenol.....................................  (0.015)(13.8)/y.............................       0.00088
    Zinc................................................  (3.0)(13.8)/y...............................       0.17   
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18700]]
    
    
                                                        Subpart G                                                   
       [PSNS for mechanical pulp facilities where the integrated production of pulp and coarse paper, molded pulp   
                                   products, and newsprint at groundwood mills occurs]                              
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          producta  
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.016)(16.8)/y.............................       0.0011 
    Trichlorophenol.....................................  (0.014)(16.8)/y.............................       0.00099
    Zinc................................................  (3.0)(16.8)/y...............................       0.21   
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart G                                                   
     [PSNS for mechanical pulp facilities where the integrated production of pulp and fine paper at groundwood mills
                                                         occurs]                                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          producta  
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.016)(15.4)/y.............................       0.0010 
    Trichlorophenol.....................................  (0.014)(15.4)/y.............................       0.00092
    Zinc................................................  (3.0)(15.4)/y...............................       0.19   
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
        (b) [Reserved]
    
    Subpart H--Non-Wood Chemical Pulp Subcategory
    
    
    Sec. 430.80  Applicability; description of the non-wood chemical pulp 
    subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the production of pulp and paper at non-wood chemical 
    pulp mills. This subcategory includes, but is not limited to, mills 
    producing non-wood pulps from chemical pulping processes such as kraft, 
    sulfite, or soda.
    
    
    Sec. 430.81  Specialized definitions.
    
        The general definitions, abbreviations, and methods of analysis set 
    forth in 40 CFR 401 and Sec. 430.01 of this part shall apply to this 
    subpart.
    
    
    Sec. 430.82  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best practicable control 
    technology currently available (BPT). [Reserved]
    
    
    Sec. 430.83  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best conventional pollutant 
    control technology (BCT). [Reserved]
    
    
    Sec. 430.84  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of best available technology 
    economically achievable (BAT). [Reserved]
    
    
    Sec. 430.85  New source performance standards (NSPS). [Reserved]
    
    
    Sec. 430.86  Pretreatment standards for existing sources (PSES). 
    [Reserved]
    
    
    Sec. 430.87  Pretreatment standards for new sources (PSNS). [Reserved]
    
    Subpart I--Secondary Fiber Deink Subcategory
    
    
    Sec. 430.90  Applicability; description of the secondary fiber deink 
    subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the integrated production of pulp and paper at deink 
    mills.
    
    
    Sec. 430.91  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    
    Sec. 430.92  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
    [[Page 18701]]
    
    
    
                                                        Subpart I                                                   
                                               [BPT effluent limitations]                                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................        18.1          9.4          5.3 
    TSS......................................................................        24.05        12.95         7.12
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.93  Effluent limitations guidelines representing the degree of 
    effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT): The limitations shall be the same as those 
    specified for conventional pollutants (which are defined in 40 CFR 
    401.16) in Sec. 430.92 of this subpart for the best practicable control 
    technology currently available (BPT).
    
    
    Sec. 430.94  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb) but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart I                                                   
                                   [Facilities where fine or tissue paper is produced]                              
    ----------------------------------------------------------------------------------------------------------------
                                                                              BAT effluent limitations              
                                                               -----------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                  Pollutant or pollutant property                Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0030  (0.029)(24.4)/y                        
    Trichlorophenol...........................................       0.0069  (0.068)(24.4)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart I                                                   
                                        [Facilities where newsprint is produced]                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                              BAT effluent limitations              
                                                               -----------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                  Pollutant or pollutant property                Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0030  (0.029)(24.4)/y                        
    Trichlorophenol...........................................       0.0010  (0.010)(24.4)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    Sec. 430.95  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration
    
    [[Page 18702]]
    
    limitations (mg/l) shall apply, where provided. Concentration 
    limitations will only apply to non-continuous dischargers. Only 
    facilities where chlorophenolic-containing biocides are used shall be 
    subject to pentachlorophenol and trichlorophenol limitations. 
    Permittees not using chlorophenolic-containing biocides must certify to 
    the permit-issuing authority that they are not using these biocides:
    
                                                        Subpart I                                                   
                                        [Facilities where fine paper is produced]                                   
                                                         [NSPS]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          5.7          3.1          1.6
     TSS.....................................................................          8.7          4.6          2.4
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0030  (0.045)(15.9)/y                        
    Trichlorophenol...........................................       0.0069  (0.104)(15.9)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart I                                                   
                                       [Facilities where tissue paper is produced]                                  
                                                         [NSPS]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          9.6          5.2         2.72
    TSS......................................................................         13.1          6.8         3.58
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0030  (0.036)(19.5)/y                        
    Trichlorophenol...........................................       0.0069  (0.085)(19.5)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
    [[Page 18703]]
    
    
                                                        Subpart I                                                   
                                        [Facilities where newsprint is produced]                                    
                                                         [NSPS]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          6.0          3.2          1.7
    TSS......................................................................         12.0          6.3          3.3
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0030  (0.044)(16.2)/y                        
    Trichlorophenol...........................................       0.0010  (0.015)(16.2)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.96  Pretreatment standards for existing sources (PSES).
    
        (a) Except as provided in 40 CFR 403.7 and 403.13, any existing 
    source subject to this subpart that introduces pollutants into a 
    publicly owned treatment works must comply with 40 CFR part 403 and 
    achieve the following pretreatment standards for existing sources 
    (PSES) if it uses chlorophenolic-containing biocides. Permittees not 
    using chlorophenolic-containing biocides must certify to the permit-
    issuing authority that they are not using these biocides. PSES must be 
    attained on or before July 1, 1984:
    
                                                        Subpart I                                                   
                                   [Facilities where fine or tissue paper is produced]                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSES                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                            Kg/kkg (or
                                                                                                          pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.032)(24.4)/y..............................       0.0033
    Trichlorophenol.....................................  (0.082)(24.4)/y..............................       0.0084
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    
                                                        Subpart I                                                   
                                        [Facilities where newsprint is produced]                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSES                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                            Kg/kkg (or
                                                                                                          pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.032)(24.4)/y..............................       0.0033
    Trichlorophenol.....................................  (0.010)(24.4)/y..............................       0.0010
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    
    [[Page 18704]]
    
    Sec. 430.97  Pretreatment standards for new sources (PSNS).
    
        (a) Except as provided in 40 CFR 403.7, any new source subject to 
    this subpart that introduces pollutants into a publicly owned treatment 
    works must comply with 40 CFR part 403 and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart I                                                   
                                        [Facilities where fine paper is produced]                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                            Kg/kkg (or
                                                                                                          pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.049)(15.9)/y..............................       0.0033
    Trichlorophenol.....................................  (0.126)(15.9)/y..............................       0.0084
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    
                                                        Subpart I                                                   
                                       [Facilities where tissue paper is produced]                                  
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                            Kg/kkg (or
                                                                                                          pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.040)(19.5)/y..............................       0.0033
    Trichlorophenol.....................................  (0.103)(19.5)/y..............................       0.0084
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    
                                                        Subpart I                                                   
                                        [Facilities where newsprint is produced]                                    
    ----------------------------------------------------------------------------------------------------------------
                                                                                     PSNS                           
                                                         -----------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
               Pollutant or pollutant property                                                           Kg/kkg ( or
                                                                                                          pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.048)(16.2)/y..............................       0.0033
    Trichlorophenol.....................................  (0.015)(16.2)/y..............................       0.0010
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass equivalent limitations.                                                                           
    
    Subpart J--Secondary Fiber Non-Deink Subcategory
    
    
    Sec. 430.100  Applicability; description of the secondary fiber non-
    deink subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the production of: paperboard from wastepaper; tissue 
    paper from wastepaper without deinking at secondary fiber mills; molded 
    products from wastepaper without deinking at secondary fiber mills; and 
    builders' paper and roofing felt from wastepaper.
    
    
    Sec. 430.101  Specialized definitions.
    
        For the purpose of this subpart:
        (a) Except as provided below, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
        (b) Noncorrugating medium furnish subdivision mills are mills where 
    recycled corrugating medium is not used in the production of 
    paperboard.
        (c) Corrugating medium furnish subdivision mills are mills where 
    only recycled corrugating medium is used in the production of 
    paperboard.
    
    [[Page 18705]]
    
    Sec. 430.102  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT):
    
                                    Subpart J                               
    [BPT effluent limitations for secondary fiber non-deink facilities where
      paperboard from wastepaper is produced--noncorrugating medium finish  
                                  subdivision]                              
    ------------------------------------------------------------------------
                                                      Kg/kkg (or pounds per 
                                                      1,000 lb) of product  
                                                   -------------------------
                                                                  Average of
            Pollutant or pollutant property                         daily   
                                                    Maximum for   values for
                                                     any 1 day        30    
                                                                 consecutive
                                                                     days   
    ------------------------------------------------------------------------
    BOD5..........................................          3.0          1.5
    TSS...........................................          5.0          2.5
    pH............................................        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ 1Within the range of 6.0 to 9.0 at all times.                       
    
    
                                    Subpart J                               
    [BPT effluent limitations for secondary fiber non-deink facilities where
        paperboard from wastepaper is produced--corrugating medium finish   
                                  subdivision]                              
    ------------------------------------------------------------------------
                                                      Kg/kkg (or pounds per 
                                                      1,000 lb) of product  
                                                   -------------------------
                                                                  Average of
            Pollutant or pollutant property                         daily   
                                                    Maximum for   values for
                                                     any 1 day        30    
                                                                 consecutive
                                                                     days   
    ------------------------------------------------------------------------
    BOD5..........................................          5.7          2.8
    TSS...........................................          9.2          4.6
    pH............................................        (\1\)        (\1\)
    ------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                        
    
    
                                    Subpart J                               
    [BPT effluent limitations for secondary fiber non-deink facilities where
         builders' paper and roofing felt from wastepaper are produced]     
    ------------------------------------------------------------------------
                                                      Kg/kkg (or pounds per 
                                                      1,000 lb) of product  
                                                   -------------------------
                                                                  Average of
            Pollutant or pollutant property                         daily   
                                                    Maximum for   values for
                                                     any 1 day        30    
                                                                 consecutive
                                                                     days   
    ------------------------------------------------------------------------
    BOD5..........................................          5.0          3.0
    TSS...........................................          5.0          3.0
    pH............................................        (\1\)        (\1\)
    Setteable Solids..............................        (\2\)        (\2\)
    ------------------------------------------------------------------------
    \1\ Within the range of 6.0 to 9.0 at all times.                        
    \2\ Not to exceed 0.2 ml/l.                                             
    
        (b) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart must achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
    [[Page 18706]]
    
    
    
                                                        Subpart J                                                   
       [BPT effluent limitations for secondary fiber non-deink facilities where tissue from wastepaper is produced  
                                                    without deinking]                                               
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------     Non-   
                         Pollutant or pollutant property                                     Average of   continuous
                                                                                               daily     dischargers
                                                                               Maximum for   values for    (annual  
                                                                                any 1 day        30        average  
                                                                                            consecutive     days)   
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................        13.7           7.1          4.0
    TSS......................................................................        17.05          9.2          5.1
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart J                                                   
      [BPT effluent limitations for secondary fiber non-deink facilities where molded products from wastepaper are  
                                               produced without deinking]                                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------     Non-   
                         Pollutant or pollutant property                                     Average of   continuous
                                                                                               daily     dischargers
                                                                               Maximum for   values for    (annual  
                                                                                any 1 day        30        average  
                                                                                            consecutive     days)   
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          4.4          2.3          1.3
    TSS......................................................................         10.8          5.8          3.2
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.103  Effluent limitations guidelines representing the degree 
    of effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        (a) Except as provided in 40 CFR 125.30 through 125.32, any 
    existing point source subject to this subpart shall achieve the 
    following effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best conventional 
    pollutant control technology (BCT): The limitations shall be the same 
    as those specified for conventional pollutants (which are defined in 40 
    CFR 401.16) in Sec. 430.102 of this subpart for the best practicable 
    control technology currently available (BPT).
        (b) For secondary fiber non-deink facilities where paperboard from 
    wastepaper is produced, non-continuous dischargers shall not be subject 
    to the maximum day and average-of-30-consecutive-days limitations, but 
    shall be subject to annual average effluent limitations determined by 
    dividing the average-of-30-consecutive-days limitations for BOD5 and 
    TSS by 1.77 and 2.18.
        (c) For secondary fiber non-deink facilities where builders' paper 
    and roofing felt from wastepaper are produced, non-continuous 
    dischargers shall not be subject to the maximum day and average-of-30-
    consecutive-days limitations, but shall be subject to annual average 
    effluent limitations determined by dividing the average-of-30-
    consecutive-days limitations for BOD5 and TSS by 1.90 and 1.90.
    
    
    Sec. 430.104  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb) but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
    [[Page 18707]]
    
    
    
                                                        Subpart J                                                   
    [BAT effluent limitations for secondary fiber non-deink facilities where paperboard from wastepaper is produced]
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................      0.00087  (0.029)(7.2)/y                         
    Trichlorophenol...........................................      0.00030  (0.010)(7.2)/y                         
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart J                                                   
     [BAT effluent limitations for secondary fiber non-deink facilities where builders' paper and roofing felt from 
                                                wastepaper are produced]                                            
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................      0.0017   (0.029)(14.4)/y                        
    Trichlorophenol...........................................      0.00060  (0.010)(14.4)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart J                                                   
       [BAT effluent limitations for secondary fiber non-deink facilities where tissue from wastepaper is produced  
                                                    without deinking]                                               
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0030  (0.029)(25.2)/y                        
    Trichlorophenol...........................................       0.0011  (0.010)(25.2)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart J                                                   
      [BAT effluent limitations for secondary fiber non-deink facilities where molded products from wastepaper are  
                                               produced without deinking]                                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................      0.0026   (0.029)(21.1)/y                        
    Trichlorophenol...........................................      0.00088  (0.010)(21.1)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    Sec. 430.105  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides:
    
    [[Page 18708]]
    
    
    
                                                        Subpart J                                                   
       [NSPS for secondary fiber non-deink facilities where paperboard from wastepaper is produced--noncorrugating  
                                               medium furnish subdivision]                                          
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          2.6          1.4         0.73
    TSS......................................................................          3.5          1.8         0.95
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................      0.00087  (0.065)(3.2)/y                         
    Trichlorophenol...........................................      0.00030  (0.023)(3.2)/y                         
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart J                                                   
     [NSPS for secondary fiber non-deink facilities where paperboard from wastepaper is produced--corrugating medium
                                                   finish subdivision]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          3.9          2.1          1.1
    TSS......................................................................          4.4          2.3          1.2
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................      0.00087  (0.065)(3.2)/y                         
    Trichlorophenol...........................................      0.00030  (0.023)(3.2)/y                         
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart J                                                   
        [NSPS for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are   
                                                        produced]                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          1.7         0.94         0.49
    TSS......................................................................          2.7         1.40         0.74
    
    [[Page 18709]]
    
                                                                                                                    
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................      0.0017   (0.155)(2.7)/y                         
    Trichlorophenol...........................................      0.00060  (0.053)(2.7)/y                         
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart J                                                   
        [NSPS for secondary fiber non-deink facilities where tissue from wastepaper is produced without deinking]   
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          4.6          2.5          1.3
    TSS......................................................................         10.2          5.3          2.8
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0030  (0.045)(16.3)/y                        
    Trichlorophenol...........................................       0.0011  (0.015)(16.3)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart J                                                   
        [NSPS for secondary fiber non-deink facilities where molded products from wastepaper are produced without   
                                                        deinking]                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          2.1          1.1         0.58
    TSS......................................................................          4.4          2.3         1.21
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
    [[Page 18710]]
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................      0.0026   (0.107)(5.7)/y                         
    Trichlorophenol...........................................      0.00088  (0.037)(5.7)/y                         
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.106  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides. PSES must be attained 
    on or before July 1, 1984:
    
                                                        Subpart J                                                   
              [PSES for secondary fiber non-deink facilities where paperboard from wastepaper is produced]          
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                         of producta
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(7.2)/y...............................      0.00096
    Trichlorophenol.....................................  (0.010)(7.2)/y...............................      0.00030
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart J                                                   
        [PSES for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are   
                                                        produced]                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(14.4)y..............................       0.0019 
    Trichlorophenol.....................................  (0.010)(14.4)y..............................       0.00060
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart J                                                   
        [PSES for secondary fiber non-deink facilities where tissue from wastepaper is produced without deinking]   
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
                                                                                                              a     
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(25.2)y...............................       0.0034
    Trichlorophenol.....................................  (0.010)(25.2)/y..............................       0.0011
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18711]]
    
    
                                                        Subpart J                                                   
        [PSES for secondary fiber non-deink facilities where molded products from wastepaper are produced without   
                                                        deinking]                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.032)(21.1)y...............................      0.0028 
    Trichlorophenol.....................................  (0.010)(21.1)y...............................      0.00088
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Sec. 430.107  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart J                                                   
              [PSNS for secondary fiber non-deink facilities where paperboard from wastepaper is produced]          
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.072)(3.2)/y...............................      0.00096
    Trichlorophenol.....................................  (0.023)(3.2)/y...............................      0.00030
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart J                                                   
        [PSNS for secondary fiber non-deink facilities where builders' paper and roofing felt from wastepaper are   
                                                        produced]                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.171)(2.7)/y..............................       0.0019 
    Trichlorophenol.....................................  (0.053)(2.7)/y..............................       0.00060
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart J                                                   
        [PSNS for secondary fiber non-deink facilities where tissue from wastepaper is produced without deinking]   
    ----------------------------------------------------------------------------------------------------------------
                                                                                        Maximum for any 1 day       
                                                                               -------------------------------------
                                                                                                          Kg/kkg (or
                          Pollutant or pollutant property                                                 pounds per
                                                                                Milligrams/liter (mg/l)   1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol.........................................................          (0.049)(16.3)/y       0.0034
    Trichlorophenol...........................................................          (0.015)(16.3)/y       0.0011
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18712]]
    
    
                                                        Subpart J                                                   
        [PSNS for secondary fiber non-deink facilities where molded products from wastepaper are produced without   
                                                        deinking]                                                   
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.118)(5.7)/y..............................       0.0028 
    Trichlorophenol.....................................  (0.037)(5.7)/y..............................       0.00088
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Subpart K--Fine and Lightweight Papers from Purchased Pulp 
    Subcategory
    
    
    Sec. 430.110  Applicability; description of the fine and lightweight 
    papers from purchased pulp subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the production of: fine paper at nonintegrated mills; 
    and lightweight paper at nonintegrated mills.
    
    
    Sec. 430.111  Specialized definitions.
    
        For the purpose of this subpart:
        (a) Except as provided in paragraphs (b) and (c) of this section, 
    the general definitions, abbreviations, and methods of analysis set 
    forth in 40 CFR part 401 and Sec. 430.01 of this part shall apply to 
    this subpart.
        (b) Cotton fiber furnish subdivision mills are those mills where 
    significant quantities of cotton fibers (equal to or greater than 4 
    percent of the total product) are used in the production of fine 
    papers.
        (c) Wood fiber furnish subdivision mills are those mills where 
    cotton fibers are not used in the production of fine papers.
    
    
    Sec. 430.112  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
                                                        Subpart K                                                   
     [BPT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp--wood fiber
                                                  furnish subdivision]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          8.2         4.25          2.4
    TSS......................................................................         11.0          5.9          3.2
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart K                                                   
       [BPT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp--cotton  
                                               fiber furnish subdivision]                                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         17.4          9.1          5.1
    TSS......................................................................         24.3         13.1          7.2
    
    [[Page 18713]]
    
                                                                                                                    
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart K                                                   
      [BPT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp] 
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         24.1         13.2         7.37
    TSS......................................................................         21.6         10.6         6.0 
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart K                                                   
     [BPT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp-- 
                                           electrical grade papers subdivision                                      
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         38.0         20.9         11.7
    TSS......................................................................         34.2         16.7          9.5
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.113  Effluent limitations guidelines representing the degree 
    of effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT): The limitations shall be the same as those 
    specified for conventional pollutants (which are defined in 40 CFR 
    401.16) in Sec. 430.102 of this subpart for the best practicable 
    control technology currently available (BPT).
    
    
    Sec. 430.114  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb) but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
    [[Page 18714]]
    
    
    
                                                        Subpart K                                                   
     [BAT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp--wood fiber
                                                  furnish subdivision]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0018   (0.029)(15.2)/y                       
    Trichlorophenol...........................................       0.00064  (0.010)(15.2)/y                       
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart K                                                   
       [BAT effluent limitations for non-integrated mills where fine paper is produced from purchased pulp--cotton  
                                               fiber furnish subdivision]                                           
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0051  (0.029)(42.3)/y                        
    Trichlorophenol...........................................       0.0018  (0.010)(42.3)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart K                                                   
      [BAT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp] 
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0059  (0.029)(48.7)/y                        
    Trichlorophenol...........................................       0.0020  (0.010)(48.7)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart K                                                   
     [BAT effluent limitations for non-integrated mills where lightweight papers are produced from purchased pulp-- 
                                          electrical grade papers subdivision]                                      
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0093  (0.029)(76.9)/y                        
    Trichlorophenol...........................................       0.0032  (0.010)(76.9)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    Sec. 430.115  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides:
    
    [[Page 18715]]
    
    
    
                                                        Subpart K                                                   
    [NSPS for non-integrated mills where fine paper is produced from purchased pulp--wood fiber furnish subdivision]
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (Annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          3.5          1.9          1.0
    TSS......................................................................          4.4          2.3          1.2
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    Pentachlorophenol.........................................       0.0018   (0.047)(9.4)/y                        
    Trichlorophenol...........................................       0.00064  (0.016)(9.4)/y                        
    y=wastewater discharged in kgal per ton at all times.                                                           
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart K                                                   
          [NSPS for non-integrated mills where fine paper is produced from purchased pulp--cotton fiber furnish     
                                                      subdivision]                                                  
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          7.8          4.2          2.2
    TSS......................................................................          9.5          4.9          2.6
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0051  (0.039)(31.1)/y                        
    Trichlorophenol...........................................       0.0018  (0.014)(31.1)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart K                                                   
                [NSPS for non-integrated mills where lightweight papers are produced from purchased pulp]           
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         13.7          6.7          4.5
    TSS......................................................................         12.0          5.2          3.2
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
    [[Page 18716]]
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0059  (0.037)(38.2)/y                        
    Trichlorophenol...........................................       0.0020  (0.013)(38.2)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart K                                                   
       [NSPS for non-integrated mills where lightweight papers are produced from purchased pulp--electrical grade   
                                                   papers subdivision]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         24.1         11.7          7.9
    TSS......................................................................         21.1          9.2          5.6
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0093  (0.033)(66.8)/y                        
    Trichlorophenol...........................................       0.0032  (0.012)(66.8)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.116  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides. PSES must be attained 
    on or before July 1, 1984:
    
                                                        Subpart K                                                   
    [PSES for non-integrated mills where fine paper is produced from purchased pulp--wood fiber furnish subdivision]
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          producta  
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(15.2)/y.............................       0.0020 
    Trichlorophenol.....................................  (0.010)(15.2)/y.............................       0.00064
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart K                                                   
          [PSES for non-integrated mills where fine paper is produced from purchased pulp--cotton fiber furnish     
                                                      subdivision]                                                  
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          producta  
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(42.3)/y.............................       0.0056 
    
    [[Page 18717]]
    
                                                                                                                    
    Trichlorophenol.....................................  (0.010)(42.3)/y.............................       0.0018 
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart K                                                   
                [PSES for non-integrated mills where lightweight papers are produced from purchased pulp]           
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.032)(48.7)/y..............................       0.0065
    Trichlorophenol.....................................  (0.010)(48.7)/y..............................       0.0032
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart K                                                   
       [PSES for non-integrated mills where lightweight papers are produced from purchased pulp--electrical grade   
                                                   papers subdivision]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(76.9)/y.............................        0.010 
    Trichlorophenol.....................................  (0.010)(76.9)/y.............................        0.0032
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Sec. 430.117  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart K                                                   
    [PSNS for non-integrated mills where fine paper is produced from purchased pulp--wood fiber furnish subdivision]
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.052)(9.4)/y..............................        0.0020
    Trichlorophenol.....................................  (0.016)(9.4)/y..............................        0.0064
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18718]]
    
    
                                                        Subpart K                                                   
          [PSNS for non-integrated mills where fine paper is produced from purchased pulp--cotton fiber furnish     
                                                      subdivision]                                                  
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.044)(31.1)/y..............................       0.0056
    Trichlorophenol.....................................  (0.014)(31.1)/y..............................       0.0018
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart K                                                   
                [PSNS for non-integrated mills where lightweight papers are produced from purchased pulp]           
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.041)(38.2)/y..............................       0.0065
    Trichlorophenol.....................................  (0.013)(38.2)/y..............................       0.0020
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart K                                                   
       [PSNS for non-integrated mills where lightweight papers are produced from purchased pulp--electrical grade   
                                                   papers subdivision]                                              
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.037)(66.8)/y.............................        0.010 
    Trichlorophenol.....................................  (0.012)(66.8)/y.............................        0.0032
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Subpart L--Tissue, Filter, Non-Woven, and Paperboard From Purchased 
    Pulp Subcategory
    
    
    Sec. 430.120  Applicability; description of the tissue, filter, non-
    woven, and paperboard from purchased pulp subcategory.
    
        The provisions of this subpart are applicable to discharges 
    resulting from the production of tissue papers at non-integrated mills, 
    filter and non-woven papers at non-integrated mills, and paperboard at 
    non-integrated mills. The production of electrical grades of board and 
    matrix board is not included in this subpart.
    
    
    Sec. 430.121  Specialized definitions.
    
        For the purpose of this subpart, the general definitions, 
    abbreviations, and methods of analysis set forth in 40 CFR part 401 and 
    Sec. 430.01 of this part shall apply to this subpart.
    
    
    Sec. 430.122  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best practicable control 
    technology currently available (BPT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart must achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best practicable control 
    technology currently available (BPT), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days limitations but shall be subject to annual average 
    effluent limitations:
    
    [[Page 18719]]
    
    
    
                                                        Subpart L                                                   
        [BPT effluent limitations for non-integrated mills where tissue papers are produced from purchased pulp]    
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................        11.4          6.25         3.49
    TSS......................................................................        10.25         5.0          2.84
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart L                                                   
    [BPT effluent limitations for non-integrated mills where filter and non-woven papers are produced from purchased
                                                          pulp]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         29.6         16.3          9.1
    TSS......................................................................         26.6         13.0          7.4
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart L                                                   
          [BPT effluent limitations for non-integrated mills where paperboard is produced from purchased pulp]      
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                                 Non-continuous     
                                                                                               dischargers (Annual  
                                                                                                    average)        
                         Pollutant or pollutant property                                   -------------------------
                                                                                Continuous                Average of
                                                                               dischargers                  daily   
                                                                                            Maximum for   values for
                                                                                             any 1 day        30    
                                                                                                         consecutive
                                                                                                             days   
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          6.5          3.6          2.0
    TSS......................................................................          5.8          2.8          1.6
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.123  Effluent limitations guidelines representing the degree 
    of effluent reduction attainable by the application of the best 
    conventional pollutant control technology (BCT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart shall achieve the following 
    effluent limitations representing the degree of effluent reduction 
    attainable by the application of the best conventional pollutant 
    control technology (BCT): The limitations shall be the same as those 
    specified for conventional pollutants (which are defined in 40 CFR 
    401.16) in Sec. 430.122 of this subpart for the best practicable 
    control technology currently available (BPT).
    
    
    Sec. 430.124  Effluent limitations representing the degree of effluent 
    reduction attainable by the application of the best available 
    technology economically achievable (BAT).
    
        Except as provided in 40 CFR 125.30 through 125.32, any existing 
    point source subject to this subpart where chlorophenolic-containing 
    biocides are used must achieve the following effluent limitations 
    representing the degree of effluent reduction attainable by the 
    application of the best available technology economically achievable 
    (BAT). Non-continuous dischargers shall not be subject to the maximum 
    day mass limitations in kg/kkg (lb/1000 lb) but shall be subject to 
    concentration limitations. Concentration limitations are only 
    applicable to non-continuous dischargers. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
    [[Page 18720]]
    
    
    
                                                        Subpart L                                                   
        [BAT effluent limitations for non-integrated mills where tissue papers are produced from purchased pulp]    
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0028   (0.029)(22.9)/y                       
    Trichlorophenol...........................................       0.00096  (0.010)(22.9)/y                       
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart L                                                   
    [BAT effluent limitations for non-integrated mills where filter and non-woven papers are produced from purchased
                                                          pulp]                                                     
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0072  (0.029)(59.9)/y                        
    Trichlorophenol...........................................       0.0025  (0.010)(59.9)/y                        
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                        Subpart L                                                   
          [BAT effluent limitations for non-integrated mills where paperboard is produced from purchased pulp]      
    ----------------------------------------------------------------------------------------------------------------
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                  Pollutant or pollutant property                pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol.........................................       0.0016   (0.029)(12.9)/y                       
    Trichlorophenol...........................................       0.00054  (0.010)(12.9)/y                       
    y = wastewater discharged in kgal per ton of product.                                                           
    ----------------------------------------------------------------------------------------------------------------
    
    Sec. 430.125  New source performance standards (NSPS).
    
        Any new source subject to this subpart must achieve the following 
    new source performance standards (NSPS), except that non-continuous 
    dischargers shall not be subject to the maximum day and average of 30 
    consecutive days effluent limitations for BOD5 and TSS, but shall be 
    subject to annual average effluent limitations. Also, for non-
    continuous dischargers, concentration limitations (mg/l) shall apply, 
    where provided. Concentration limitations will only apply to non-
    continuous dischargers. Only facilities where chlorophenolic-containing 
    biocides are used shall be subject to pentachlorophenol and 
    trichlorophenol limitations. Permittees not using chlorophenolic-
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides:
    
                                                        Subpart L                                                   
                  [NSPS for non-integrated mills where tissue papers are produced from purchased pulp]              
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          7.0          3.4          2.3
    TSS......................................................................          6.0          2.6          1.6
    pH.......................................................................        (\1\)        (\1\)        (\1\)
    ----------------------------------------------------------------------------------------------------------------
    
    
    [[Page 18721]]
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    Pentachlorophenol.........................................       0.0028   (0.035)(19.1)/y                       
    Trichlorophenol...........................................       0.00096  (0.012)(19.1)/y                       
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Within the range of 5.0 to 9.0 at all times.                                                                
    
    
                                                        Subpart L                                                   
           [NSPS for non-integrated mills where filter and non-woven papers are produced from purchased pulp]       
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................         17.1          8.3          5.6
    TSS......................................................................         15.0          6.6          4.0
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                 1,000 lb)               Milligrams/liter           
                                                                 of product                                         
    Pentachlorophenol.........................................       0.0072  (0.037)(47.5)/y                        
    Trichlorophenol...........................................       0.0025  (0.013)(47.5)/y                        
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    1 Within the range of 5.0 to 9.0 at all times.                                                                  
    
    
                                                        Subpart L                                                   
                    [NSPS for non-integrated mills where paperboard is produced from purchased pulp]                
    ----------------------------------------------------------------------------------------------------------------
                                                                                 Kg/kkg (or pounds per 1,000 lb) of 
                                                                                              product               
                                                                              --------------------------------------
                                                                                Continuous dischargers              
                                                                              --------------------------            
                         Pollutant or pollutant property                                     Average of      Non-   
                                                                                               daily      continuous
                                                                               Maximum for   values for  dischargers
                                                                                any 1 day        30        (annual  
                                                                                            consecutive    average) 
                                                                                                days                
    ----------------------------------------------------------------------------------------------------------------
    BOD5.....................................................................          4.0          1.9          1.3
    TSS......................................................................          3.5          1.5          0.9
    pH.......................................................................          (1)          (1)          (1)
    ----------------------------------------------------------------------------------------------------------------
    
    
                                                                                                                    
                                                                                Maximum for any 1 day               
                                                               -----------------------------------------------------
                                                                 Kg/kkg (or                                         
                                                                 pounds per                                         
                                                                1,000 lb) of             Milligrams/liter           
                                                                   product                                          
    Pentachlorophenol.........................................       0.0016   (0.033)(11.2)/y                       
    Trichlorophenol...........................................       0.00054  (0.012)(11.2)/y                       
    y = wastewater discharged in kgal per ton at all times.                                                         
    ----------------------------------------------------------------------------------------------------------------
    (1) Within the range of 5.0 to 9.0 at all times.                                                                
    
    Sec. 430.126  Pretreatment standards for existing sources (PSES).
    
        Except as provided in 40 CFR 403.7 and 403.13, any existing source 
    subject to this subpart that introduces pollutants into a publicly 
    owned treatment works must: comply with 40 CFR part 403; and achieve 
    the following pretreatment standards for existing sources (PSES) if it 
    uses chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-
    
    [[Page 18722]]
    
    containing biocides must certify to the permit-issuing authority that 
    they are not using these biocides. PSES must be attained on or before 
    July 1, 1984:
    
                                                        Subpart L                                                   
                  [PSES for non-integrated mills where tissue papers are produced from purchased pulp]              
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(22.9)/y.............................       0.0031 
    Trichlorophenol.....................................  (0.010)(22.9)/y.............................       0.00096
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart L                                                   
           [PSES for non-integrated mills where filter and non-woven papers are produced from purchased pulp]       
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.032)(59.9)/y..............................       0.0080
    Trichlorophenol.....................................  (0.010)(59.9)/y..............................       0.0025
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart L                                                   
                    [PSES for non-integrated mills where paperboard is produced from purchased pulp]                
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.032)(12.9)/y.............................       0.0017 
    Trichlorophenol.....................................  (0.010)(12.9)/y.............................       0.00054
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Sec. 430.127  Pretreatment standards for new sources (PSNS).
    
        Except as provided in 40 CFR 403.7, any new source subject to this 
    subpart that introduces pollutants into a publicly owned treatment 
    works must: comply with 40 CFR part 403; and achieve the following 
    pretreatment standards for new sources (PSNS) if it uses 
    chlorophenolic-containing biocides. Permittees not using 
    chlorophenolic-containing biocides must certify to the permit-issuing 
    authority that they are not using these biocides:
    
                                                        Subpart L                                                   
                  [PSNS for non-integrated mills where tissue papers are produced from purchased pulp]              
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.038)(19.1)/y.............................       0.0031 
    Trichlorophenol.....................................  (0.012)(19.1)/y.............................       0.00096
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
    [[Page 18723]]
    
    
                                                        Subpart L                                                   
           [PSNS for non-integrated mills where filter and non-woven papers are produced from purchased pulp]       
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                          Kg/kkg (or
               Pollutant or pollutant property                                                            pounds per
                                                                     Milligrams/liter (mg/l)              1,000 lb) 
                                                                                                          of product
    ----------------------------------------------------------------------------------------------------------a-----
    Pentachlorophenol...................................  (0.040)(47.5)/y..............................       0.0080
    Trichlorophenol.....................................  (0.013)(47.5)/y..............................       0.0025
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    
                                                        Subpart L                                                   
                    [PSNS for non-integrated mills where paperboard is produced from purchased pulp]                
    ----------------------------------------------------------------------------------------------------------------
                                                                             Maximum for any 1 day                  
                                                         -----------------------------------------------------------
                                                                                                         Kg/kkg (or 
               Pollutant or pollutant property                                                           pounds per 
                                                                     Milligrams/liter (mg/l)            1,000 lb) of
                                                                                                          product a 
    ----------------------------------------------------------------------------------------------------------------
    Pentachlorophenol...................................  (0.037)(11.2)/y.............................       0.0017 
    Trichlorophenol.....................................  (0.012)(11.2)/y.............................       0.00054
    y = wastewater discharged in kgal per ton of                                                                    
     product.                                                                                                       
    ----------------------------------------------------------------------------------------------------------------
    a The following equivalent mass limitations are provided as guidance in cases when POTWs find it necessary to   
      impose mass effluent limitations.                                                                             
    
    Appendix A to Part 430--Methods 1650 and 1653
    
    Method 1650--Adsorbable Organic Halides by Adsorption and Coulometric 
    Titration
    
    1.0  Scope and Application
    
        1.1  This method is for determination of adsorbable organic 
    halides (AOX) associated with the Clean Water Act; the Resource 
    Conservation and Recovery Act; the Comprehensive Environmental 
    Response, Compensation, and Liability Act; and other organic halides 
    amenable to combustion and coulometric titration. The method is 
    designed to meet the survey and monitoring requirements of the 
    Environmental Protection Agency (EPA).
        1.2  The method is applicable to the determination of AOX in 
    water and wastewater. This method is a combination of several 
    existing methods for organic halide measurements (References 1 
    through 7).
        1.3  The method can be used to measure organically-bound halides 
    (chlorine, bromine, iodine) present in dissolved or suspended form. 
    Results are reported as organic chloride (Cl-). The 
    detection limit of the method is usually dependent on interferences 
    rather than instrumental limitations. A method detection limit (MDL; 
    Reference 8) of 6.6 g/L, and a minimum level (ML; Section 
    18) of 20 g/L, can be achieved with no interferences 
    present.
        1.4  This method is for use by or under the supervision of 
    analysts experienced in the use of a combustion/micro-coulometer. 
    Each laboratory that uses this method must demonstrate the ability 
    to generate acceptable results using the procedures described in 
    Section 9.2.
        1.5  Any modification of the method beyond those expressly 
    permitted (Section 9.1.2) is subject to application and approval of 
    an alternate test procedure under 40 CFR 136.4 and 136.5.
    
    2.0  Summary of Method
    
        2.1  Sample preservation: Residual chlorine that may be present 
    is removed by the addition of sodium thiosulfate. Samples are 
    adjusted to a pH < 2="" and="" maintained="" at="" 0="" to="" 4="" deg.c="" until="" analysis.="" 2.2="" sample="" analysis:="" organic="" halide="" in="" water="" is="" determined="" by="" adsorption="" onto="" granular="" activated="" carbon="" (gac),="" washing="" the="" adsorbed="" sample="" and="" gac="" to="" remove="" inorganic="" halide,="" combustion="" of="" the="" sample="" and="" gac="" to="" form="" the="" hydrogen="" halide,="" and="" titration="" of="" the="" hydrogen="" halide="" with="" a="" micro-coulometer,="" as="" shown="" in="" figure="" 1.="" 2.3="" micro-coulometer.="" 2.3.1="" this="" detector="" operates="" by="" maintaining="" a="" constant="" silver-="" ion="" concentration="" in="" a="" titration="" cell.="" an="" electric="" potential="" is="" applied="" to="" a="" solid="" silver="" electrode="" to="" produce="" silver="" ions="" in="" the="" cell.="" as="" hydrogen="" halide="" produced="" from="" the="" combustion="" of="" organic="" halide="" enters="" the="" cell,="" it="" is="" partitioned="" into="" an="" acetic="" acid="" electrolyte="" where="" it="" precipitates="" as="" silver="" halide.="" the="" current="" produced="" is="" integrated="" over="" the="" combustion="" period.="" the="" electric="" charge="" is="" proportional="" to="" the="" number="" of="" moles="" of="" halogen="" captured="" in="" the="" cell="" (reference="" 6).="" 2.3.2="" the="" mass="" concentration="" of="" organic="" halides="" is="" reported="" as="" an="" equivalent="" concentration="" of="" organically="" bound="" chloride="">-).
    
    3.0  Definitions
    
        3.1  Adsorbable organic halides is defined as the analyte 
    measured by this method. The nature of the organo-halides and the 
    presence of semi-extractable material will influence the amount 
    measured and interpretation of results.
        3.2  Definitions for terms used in this method are given in the 
    glossary at the end of the method (Section 18).
    
    4.0  Interferences
    
        4.1  Solvents, reagents, glassware, and other sample processing 
    hardware may yield elevated readings from the micro-coulometer. All 
    materials used in the analysis shall be demonstrated to be free from 
    interferences under the conditions of analysis by running method 
    blanks initially and with each sample batch (samples started through 
    the adsorption process in a given eight-hour shift, to a maximum of 
    20 samples). Specific selection of reagents and purification of 
    solvents may be required.
        4.2  Glassware is cleaned by detergent washing in hot water, 
    rinsing with tap water and distilled water, capping with aluminum 
    foil, and baking at 450 deg.C for at least one hour. For some 
    glassware, immersion in a chromate cleaning solution prior to 
    detergent washing may be required. If blanks from glassware without 
    cleaning or with fewer cleaning steps show no detectable organic 
    halide, the cleaning steps that do not eliminate organic halide may 
    be omitted.
        4.3  Most often, contamination results from methylene chloride 
    vapors in laboratories that perform organic extractions. Heating, 
    ventilating, and air conditioning systems that are shared between 
    the extraction laboratory and the laboratory in which organic halide 
    measurements are performed transfer the methylene chloride vapors to 
    the air in the organic halide laboratory. Exposure of the activated 
    carbon
    
    [[Page 18724]]
    
    used in the analysis results in contamination. Separate air handling 
    systems, charcoal filters, and glove boxes can be used to minimize 
    this exposure.
        4.4  Activated carbon.
        4.4.1  The purity of each lot of activated carbon must be 
    verified before each use by measuring the adsorption capacity and 
    the background level of halogen (Section 9.5). The stock of 
    activated carbon should be stored in its granular form in a glass 
    container that is capped tightly. Protect carbon at all times from 
    sources of halogen vapors.
        4.4.2  Inorganic substances such as chloride, chlorite, bromide, 
    and iodide will adsorb on activated carbon to an extent dependent on 
    their original concentration in the aqueous solution and the volume 
    of sample adsorbed. Treating the activated carbon with a solution of 
    nitrate causes competitive desorption of inorganic halide species. 
    However, if the inorganic halide concentration is greater than 2,000 
    times the organic halide concentration, artificially high results 
    may be obtained.
        4.4.3  Halogenated organic compounds that are weakly adsorbed on 
    activated carbon are only partially recovered from the sample. These 
    include certain alcohols and acids such as chloroethanol and 
    chloroacetic acid that can be removed from activated carbon by the 
    nitrate wash.
        4.5  Polyethylene gloves should be worn when handling equipment 
    surfaces in contact with the sample to prevent transfer of 
    contaminants that may be present on the hands.
    
    5.0  Safety
    
        5.1  The toxicity or carcinogenicity of each reagent used in 
    this method has not been precisely determined; however, each 
    chemical substance should be treated as a potential health hazard. 
    Exposure to these substances should be reduced to the lowest 
    possible level. The laboratory is responsible for maintaining a 
    current awareness file of OSHA regulations regarding the safe 
    handling of the chemicals specified in this method. A reference file 
    of material safety data sheets (MSDSs) should be made available to 
    all personnel involved in the chemical analysis. Additional 
    information on laboratory safety can be found in References 9 
    through 11.
        5.2  This method employs strong acids. Appropriate clothing, 
    gloves, and eye protection should be worn when handling these 
    substances.
        5.3  Field samples may contain high concentrations of toxic 
    volatile compounds. Sample containers should be opened in a hood and 
    handled with gloves that will prevent exposure.
    
    6.0  Equipment and Supplies
    
        Note: Brand names, suppliers, and part numbers are for 
    illustrative purposes only. No endorsement is implied. Equivalent 
    performance may be achieved using apparatus and materials other than 
    those specified here, but demonstration of equivalent performance 
    that meets the requirements of this method is the responsibility of 
    the laboratory.
        6.1  Sampling equipment.
        6.1.1  Bottles: 100- to 4000-mL, amber glass, sufficient for all 
    testing (Section 8.2). Detergent water wash, chromic acid rinse, 
    rinse with tap and distilled water, cover with aluminum foil, and 
    heat to 450 deg.C for at least one hour before use.
        6.1.2  PTFE liner: Cleaned as above and baked at 100 to 
    200 deg.C for at least one hour.
        6.1.3  Bottles and liners must be lot certified to be free of 
    organic halide by running blanks according to this method.
        6.2  Scoop for granular activated carbon (GAC): Capable of 
    precisely measuring 40 mg (5 mg) GAC (Dohrmann Measuring 
    Cup 521-021, or equivalent).
        6.3  Batch adsorption and filtration system.
        6.3.1  Adsorption system: Rotary shaker, wrist action shaker, 
    ultrasonic system, or other system for assuring thorough contact of 
    sample with activated carbon. Systems different from the one 
    described below must be demonstrated to meet the performance 
    requirements in Section 9 of this method.
        6.3.1.1  Erlenmeyer flasks: 250- to 1500-mL with ground-glass 
    stopper, for use with rotary shaker.
        6.3.1.2  Shake table: Sybron Thermolyne Model LE ``Big Bill'' 
    rotator/shaker, or equivalent.
        6.3.1.3  Rack attached to shake table to permit agitation of 16 
    to 25 samples simultaneously.
        6.3.2  Filtration system (Figure 2).
        6.3.2.1  Vacuum filter holder: Glass, with fritted-glass support 
    (Fisher Model 09-753E, or equivalent).
        6.3.2.2  Polycarbonate filter: 0.40 to 0.45 micron, 25-mm 
    diameter (Micro Separations Inc, Model K04CP02500, or equivalent).
        6.3.2.3  Filter forceps: Fisher Model 09-753-50, or equivalent, 
    for handling filters. Two forceps may better aid in handling 
    filters. Clean by washing with detergent and water, rinsing with tap 
    and deionized water, and air drying on aluminum foil.
        6.3.2.4  Vacuum flask: 500- to 1500-mL (Fisher 10-1800, or 
    equivalent).
        6.3.2.5  Vacuum Source: A pressure/vacuum pump, rotary vacuum 
    pump, or other vacuum source capable of providing at least 610 mm 
    (24 in.) Hg vacuum at 30 L/min free air displacement.
        6.3.2.6  Stopper and tubing to mate the filter holder to the 
    flask and the flask to the pump.
        6.3.2.7  Polyethylene gloves: (Fisher 11-394-110-B, or 
    equivalent).
        6.4  Column adsorption system.
        6.4.1  Adsorption module: Dohrmann AD-2, Mitsubishi TXA-2, or 
    equivalent with pressurized sample and nitrate-wash reservoirs, 
    adsorption columns, column housings, gas and gas pressure 
    regulators, and receiving vessels. For each sample reservoir, there 
    are two adsorption columns connected in series. A small steel funnel 
    for filling the columns and a rod for pushing out the carbon are 
    also required. A schematic of the column adsorption system is shown 
    in Figure 3.
        6.4.2  Adsorption columns: Pyrex, 5  0.2 cm long  x  
    2 mm ID, to hold 40 mg of granular activated carbon (GAC).
        6.4.3  Cerafelt: Johns-Manville, or equivalent, formed into 
    plugs using stainless steel borer (2 mm ID) with ejection rod 
    (available from Dohrmann or Mitsubishi) to hold 40 mg of granular 
    activated carbon (GAC). Caution: Handle Cerafelt with gloves.
        6.4.4  Column holders: To support adsorption columns.
        6.5  Combustion/micro-coulometer system: Commercially available 
    as a single unit or assembled from parts. At the time of the writing 
    of this method, organic halide units were commercially available 
    from the Dohrmann Division of Rosemount Analytical, Santa Clara, 
    California; Euroglas BV, Delft, the Netherlands; and Mitsubishi 
    Chemical Industries, Ltd., Tokyo, Japan.
        6.5.1  Combustion system: Older systems may not have all of the 
    features shown in Figure 4. These older systems may be used provided 
    the performance requirements (Section 9) of this method are met.
        6.5.1.1  Combustion tube: Quartz, capable of being heated to 800 
    to 1000  deg.C and accommodating a boat sampler. The tube must 
    contain an air lock for introduction of a combustion boat, 
    connections for purge and combustion gas, and connection to the 
    micro-coulometer cell.
        6.5.1.2  Tube furnace capable of controlling combustion tube in 
    the range of 800 to 1000  deg.C.
        6.5.1.3  Boat sampler: Capable of holding 35 to 45 mg of 
    activated carbon and a polycarbonate filter, and fitting into the 
    combustion tube (Section 6.5.1.1). Some manufacturers offer an 
    enlarged boat and combustion tube for this purpose. Under a time-
    controlled sequence, the boat is first moved into an evaporation 
    zone where water and other volatiles are evaporated, and then into 
    the combustion zone where the carbon and all other organic material 
    in the boat are burned in a flowing oxygen stream. The evolved gases 
    are transported by a non-reactive carrier gas to the micro-
    coulometer cell.
        6.5.1.4  Motor driven boat sampler: Capable of advancing the 
    combustion boat into the furnace in a reproducible time sequence. A 
    suggested time sequence is as follows:
        A. Establish initial gas flow rates: 160 mL/min CO2; 
    40 mL/min O2.
        B. Sequence start.
        C. Hold boat in hatch for five seconds to allow integration for 
    baseline subtraction.
        D. Advance boat into vaporization zone.
        E. Hold boat in vaporization zone for 110 seconds.
        F. Establish gas flow rates for combustion: 200 mL/min 
    O2; 0 mL/min CO2; advance boat into pyrolysis 
    zone (800 deg.C).
        G. Hold boat in pyrolysis zone for six minutes.
        H. Return gas flow rates to initial values; retract boat into 
    hatch to cool and to allow remaining HX to be swept into detector 
    (approximately two minutes).
        I. Stop integration at 10 minutes after sequence start.
    
        Note: If the signal from the detector does not return to 
    baseline, it may be necessary to extend the pyrolysis time.The 
    sequence above may need to be optimized for each instrument.
    
        6.5.1.5  Absorber: Containing sulfuric acid to dry the gas 
    stream after combustion to
    
    [[Page 18725]]
    
    prevent backflush of electrolyte is highly recommended.
        6.5.2  Micro-coulometer system: Capable of detecting the 
    equivalent of 0.2 g of Cl- at a signal-to-noise 
    ratio of 2; capable of detecting the equivalent of 1 g of 
    Cl- with a relative standard deviation less than 10%, and 
    capable of accumulating a minimum of the equivalent of 500 
    g of Cl- before a change of electrolyte is 
    required.
        6.5.2.1  Micro-coulometer cell: The three cell designs presently 
    in use are shown in Figure 1. Cell operation is described in Section 
    2.
        6.5.2.2  Cell controller: Electronics capable of measuring the 
    small currents generated in the cell and accumulating and displaying 
    the charge produced by hydrogen halides entering the cell. A strip-
    chart recorder is desirable for display of accumulated charge.
        6.6  Miscellaneous glassware: nominal sizes are specified below; 
    other sizes may be used, as necessary.
        6.6.1  Volumetric flasks: 5-, 10-, 25-, 50-, 100-, and 1000-mL.
        6.6.2  Beakers: 100-, 500-, and 1000-mL.
        6.6.3  Volumetric pipets: 1- and 10-mL with pipet bulbs.
        6.6.4  Volumetric micro-pipets: 10-, 20-, 50-, 100-, 200-, and 
    500-L with pipet control (Hamilton 0010, or equivalent).
        6.6.5  Graduated cylinders: 10-, 100-, and 1000-mL.
        6.7  Micro-syringes: 10-, 50-, and 100-L.
        6.8  Balances.
        6.8.1  Top-loading, capable of weighing 0.1 g.
        6.8.2  Analytical, capable of weighing 0.1 mg.
        6.9  pH meter.
        6.10  Wash bottles: 500- to 1000-mL, PTFE or polyethylene.
        6.11  Strip-chart recorder: suggested but not required--useful 
    for determining end of integration (Section 11.4.2).
    
    7.0  Reagents and Standards
    
        7.1  Granular activated carbon (GAC): 75 to 150 m (100 
    to 200 mesh); (Dohrmann, Mitsubishi, Carbon Plus, or equivalent), 
    with chlorine content less than 1 g Cl- per 
    scoop (< 25="">g Cl- per gram), adsorption capacity 
    greater than 1000 g Cl- (as 2,4,6-
    trichlorophenol) per scoop (>25,000 g/g), inorganic halide 
    retention of less than 1 g Cl- per scoop in the 
    presence of 10 mg of inorganic halide (< 20="">g 
    Cl- per gram in the presence of 2500 mg of inorganic 
    halide), and that meets the other test criteria in this method.
        7.2  Reagent water: Water in which organic halide is not 
    detected by this method.
        7.2.1  Preparation: Reagent water may be generated by:
        7.2.1.1  Activated carbon: Pass tap water through a carbon bed 
    (Calgon Filtrasorb-300, or equivalent).
        7.2.1.2  Water purifier: Pass tap water through a purifier 
    (Millipore Super Q, or equivalent).
        7.2.2  pH adjustment: Adjust the pH of the reagent water to < 2="" with="" nitric="" acid="" for="" all="" reagent="" water="" used="" in="" this="" method,="" except="" for="" the="" acetic="" acid="" solution="" (section="" 7.13).="" 7.3="" nitric="" acid="">3): Concentrated, analytical 
    grade.
        7.4  Sodium chloride (NaCl) solution (100 g/mL of 
    Cl-): Dissolve 0.165g NaCl in 1000 mL reagent water. This 
    solution is used for cell testing and for the inorganic halide 
    rejection test.
        7.5  Ammonium chloride (NH4Cl) solution (100 
    g/mL of Cl-): Dissolve 0.1509 g NH4Cl 
    in 1000 mL reagent water.
        7.6  Sulfuric acid: Reagent grade (specific gravity 1.84).
        7.7  Oxygen: 99.9% purity.
        7.8  Carbon Dioxide: 99.9% purity.
        7.9  Nitrate stock solution: In a 1000-mL volumetric flask, 
    dissolve 17g of NaNO3 in approximately 100 mL of reagent 
    water, add 1.4 mL nitric acid (Section 7.3) and dilute to the mark 
    with reagent water.
        7.10  Nitrate wash solution: Dilute 50 mL of nitrate stock 
    solution (Section 7.9) to 1000 mL with reagent water.
        7.11  Sodium thiosulfate 
    (Na2S2O3) solution (1 N): Weigh 79 
    grams of Na2S2O3 in a 1-L 
    volumetric flask and dilute to the mark with reagent water.
        7.12  Trichlorophenol solutions.
    
        Note: The calibration solutions in this section employ 100-mL 
    volumes. For determinations requiring a larger or smaller volume, 
    increase or decrease the size of the volumetric flasks 
    commensurately. For example, if a 1-L sample is to be analyzed, use 
    1000-mL flasks (Sections 7.12.3.1 and 7.12.4) and 10 times the 
    volume of reagent water (Sections 7.12.3.1 and 7.12.4). The volume 
    of stock solution added to the calibration solutions and precision 
    and recovery (PAR) test solution remain as specified (Sections 
    7.12.3.2 and 7.12.4) so that the same amount of chloride is 
    delivered to the coulometric cell regardless of the volume of the 
    calibration and PAR solutions.
    
        7.12.1  Methanol: HPLC grade.
        7.12.2  Trichlorophenol stock solution (1.0 mg/mL of 
    Cl-): Dissolve 0.186 g of 2,4,6-trichlorophenol in 100 mL 
    of halide-free methanol.
        7.12.3  Trichlorophenol calibration solutions.
        7.12.3.1  Place approximately 90 mL of reagent water in each of 
    five 100-mL volumetric flasks.
        7.12.3.2  Using a calibrated micro-syringe or micro-pipets, add 
    2, 5, 10, 30, and 80 L of the trichlorophenol stock 
    solution (Section 7.12.2) to the volumetric flasks and dilute each 
    to the mark with reagent water to produce calibration solutions of 
    2, 5, 10, 30, and 80 g Cl- per 100 mL of 
    solution (20, 50, 100, 300, and 800 g/L).
        7.12.3.3  Some instruments may have a calibration range that 
    does not extend to 800 g/L (80 g of 
    Cl-). For those instruments, a narrower dynamic range may 
    be used. However, if the concentration of halide in a sample exceeds 
    that range, the sample must be diluted to bring the concentration 
    within the range calibrated.
        7.12.4  Trichlorophenol precision and recovery (PAR) test 
    solution (10 g/L of Cl-): Partially fill a 100-
    mL volumetric flask, add 10 L of the stock solution 
    (Section 7.12.2), and dilute to the mark with reagent water.
        7.13 Acetic acid solution: Containing 30 to 70% acetic acid in 
    deionized water, per the instrument manufacturer's instructions.
    
    8.0  Sample Collection, Preservation, and Storage
    
        8.1  Sample preservation.
        8.1.1  Residual chlorine: If the sample is known or suspected to 
    contain free chlorine, the chlorine must be reduced to eliminate 
    positive interference that may result from continued chlorination 
    reactions. A knowledge of the process from which the sample is 
    collected may be of value in determining whether dechlorination is 
    necessary. Immediately after sampling, test for residual chlorine 
    using the following method or an alternative EPA method (Reference 
    12):
        8.1.1.1  Dissolve a few crystals of potassium iodide in the 
    sample and add three to five drops of a 1% starch solution. A blue 
    color indicates the presence of residual chlorine.
        8.1.1.2  If residual chlorine is found, add 1 mL of sodium 
    thiosulfate solution (Section 7.11) for each 2.5 ppm of free 
    chlorine or until the blue color disappears. Do not add an excess of 
    sodium thiosulfate. Excess sodium thiosulfate may cause 
    decomposition of a small fraction of the OX.
        8.1.2  Acidification: Adjust the pH of aqueous samples to < 2="" with="" nitric="" acid.="" acidification="" inhibits="" biological="" activity="" and="" stabilizes="" chemical="" degradation,="" including="" possible="" dehalogenation="" reactions="" that="" may="" occur="" at="" high="" ph.="" acidification="" is="" necessary="" to="" facilitate="" thorough="" adsorption.="" 8.1.3="" refrigeration:="" maintain="" samples="" at="" a="" temperature="" of="" 0="" to="" 4="" deg.="" c="" from="" time="" of="" collection="" until="" analysis.="" 8.2="" collect="" the="" amount="" of="" sample="" necessary="" for="" analysis="" (section="" 11)="" and="" all="" qc="" tests="" (section="" 9)="" in="" an="" amber="" glass="" bottle="" of="" the="" appropriate="" size="" (section="" 6.1.1).="" 8.3="" analyze="" samples="" no="" less="" than="" three="" days="" nor="" more="" than="" six="" months="" after="" collection.="" 9.0="" quality="" control="" 9.1="" each="" laboratory="" that="" uses="" this="" method="" is="" required="" to="" operate="" a="" formal="" quality="" assurance="" program.="" the="" minimum="" requirements="" of="" this="" program="" consist="" of="" an="" initial="" demonstration="" of="" laboratory="" capability,="" an="" ongoing="" analysis="" of="" standards="" and="" blanks="" as="" tests="" of="" continued="" performance,="" and="" analysis="" of="" matrix="" spike="" and="" matrix="" spike="" duplicate="" (ms/msd)="" samples="" to="" assess="" accuracy="" and="" precision.="" laboratory="" performance="" is="" compared="" to="" established="" performance="" criteria="" to="" determine="" if="" the="" results="" of="" analyses="" meet="" the="" performance="" characteristics="" of="" the="" method.="" 9.1.1="" the="" laboratory="" shall="" make="" an="" initial="" demonstration="" of="" the="" ability="" to="" produce="" acceptable="" results="" with="" this="" method.="" this="" ability="" is="" demonstrated="" as="" described="" in="" section="" 9.2.="" 9.1.2="" the="" laboratory="" is="" permitted="" to="" modify="" this="" method="" to="" improve="" separations="" or="" lower="" the="" costs="" of="" measurements,="" provided="" that="" all="" performance="" specifications="" are="" met.="" each="" time="" a="" modification="" is="" made="" to="" the="" method,="" the="" laboratory="" is="" required="" to="" repeat="" the="" procedures="" in="" sections="" 9.2.2="" and="" 10="" to="" demonstrate="" continued="" method="" performance.="" if="" the="" detection="" limit="" of="" the="" method="" will="" be="" affected="" by="" the="" modification,="" the="" laboratory="" should="" demonstrate="" that="" the="" mdl="" (40="" cfr="" [[page="" 18726]]="" 136,="" appendix="" b)="" is="" less="" than="" or="" equal="" to="" the="" mdl="" in="" this="" method="" or="" one-third="" the="" regulatory="" compliance="" level,="" whichever="" is="" higher.="" 9.1.3="" the="" laboratory="" shall="" spike="" 10%="" of="" the="" samples="" with="" known="" concentrations="" of="" 2,4,6-trichlorophenol="" to="" monitor="" method="" performance="" and="" matrix="" interferences="" (interferences="" caused="" by="" the="" sample="" matrix).="" this="" test="" is="" described="" in="" section="" 9.3.="" when="" results="" of="" these="" spikes="" indicate="" atypical="" method="" performance="" for="" samples,="" the="" samples="" are="" diluted="" to="" bring="" method="" performance="" within="" acceptable="" limits.="" 9.1.4="" analyses="" of="" blanks="" are="" required="" to="" demonstrate="" freedom="" from="" contamination.="" the="" procedures="" and="" criteria="" for="" analysis="" of="" blanks="" are="" described="" in="" section="" 9.4.="" 9.1.5="" the="" laboratory="" shall,="" on="" an="" ongoing="" basis,="" demonstrate="" through="" the="" analysis="" of="" the="" precision="" and="" recovery="" (par)="" standard="" that="" the="" analysis="" system="" is="" in="" control.="" these="" procedures="" are="" described="" in="" section="" 9.10.="" 9.1.6="" the="" laboratory="" shall="" perform="" quality="" control="" tests="" on="" the="" granular="" activated="" carbon.="" these="" procedures="" are="" described="" in="" section="" 9.5.="" 9.1.7="" samples="" are="" analyzed="" in="" duplicate="" to="" demonstrate="" precision.="" these="" procedures="" are="" described="" in="" section="" 9.6.="" 9.2="" initial="" demonstration="" of="" laboratory="" capability.="" 9.2.1="" method="" detection="" limit="" (mdl):="" to="" establish="" the="" ability="" to="" detect="" aox,="" the="" laboratory="" should="" determine="" the="" mdl="" per="" the="" procedure="" in="" 40="" cfr="" 136,="" appendix="" b="" using="" the="" apparatus,="" reagents,="" and="" standards="" that="" will="" be="" used="" in="" the="" practice="" of="" this="" method.="" an="" mdl="" less="" than="" or="" equal="" to="" the="" mdl="" in="" section="" 1.3="" should="" be="" achieved="" prior="" to="" the="" practice="" of="" this="" method.="" 9.2.2="" initial="" precision="" and="" recovery="" (ipr):="" to="" establish="" the="" ability="" to="" generate="" acceptable="" precision="" and="" recovery,="" the="" laboratory="" shall="" perform="" the="" following="" operations:="" 9.2.2.1="" analyze="" four="" aliquots="" of="" the="" par="" standard="" (section="" 7.12.4)="" and="" a="" method="" blank="" according="" to="" the="" procedures="" in="" sections="" 9.4="" and="" 11.="" 9.2.2.2="" using="" the="" blank-subtracted="" results="" of="" the="" set="" of="" four="" analyses,="" compute="" the="" average="" percent="" recovery="" (x)="" and="" the="" standard="" deviation="" of="" the="" percent="" recovery="" (s)="" for="" the="" results.="" 9.2.2.3="" the="" average="" percent="" recovery="" shall="" be="" in="" the="" range="" of="" 81="" to="" 114="">g/L and the standard deviation shall be less than 
    8 g/L. If X and s meet these acceptance criteria, system 
    performance is acceptable and analysis of blanks and samples may 
    begin. If, however, s exceeds the precision limit or X falls outside 
    the range for recovery, system performance is unacceptable. In this 
    case, correct the problem and repeat the test.
        9.3  Matrix spikes: The laboratory shall spike a minimum of 10% 
    of samples from a given matrix type (e.g., C-stage filtrate, 
    produced water, treated effluent) in duplicate (MS/MSD). If only one 
    sample from a given matrix type is analyzed, an additional two 
    aliquots of that sample shall be spiked.
        9.3.1  The concentration of the analytes spiked into the MS/MSD 
    shall be determined as follows:
        9.3.1.1  If, as in compliance monitoring, the concentration of 
    OX is being checked against a regulatory concentration limit, the 
    spiking level shall be at that limit or at one to five times higher 
    than the background concentration determined in Section 9.3.2, 
    whichever concentration is higher.
        9.3.1.2  If the concentration of OX is not being checked against 
    a regulatory limit, the spike shall be at the concentration of the 
    precision and recovery standard (PAR; Section 7.12.4) or at one to 
    five times higher than the background concentration determined in 
    Section 9.3.2, whichever concentration is higher.
        9.3.2  Analyze one sample out of each batch of 10 samples from 
    each site to determine the background concentration of AOX. If 
    necessary, prepare a solution of 2,4,6-trichlorophenol appropriate 
    to produce a level in the sample one to five times the background 
    concentration. Spike two additional sample aliquots with spiking 
    solution and analyze them to determine the concentration after 
    spiking.
        9.3.2.1  Compute the percent recovery of each analyte in each 
    aliquot:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.018
    
        9.3.2.2  Compute the relative percent difference (RPD) between 
    the two results (not between the two recoveries) as described in 
    Section 12.4.
        9.3.2.3   If the RPD is less than 20%, and the recoveries for 
    the MS and MSD are within the range of 78 to 116%, the results are 
    acceptable.
        9.3.2.4  If the RPD is greater than 20%, analyze two aliquots of 
    the precision and recovery standard (PAR).
        9.3.2.4.1  If the RPD for the two aliquots of the PAR is greater 
    than 20%, the analytical system is out of control. In this case, 
    repair the problem and repeat the analysis of the sample batch, 
    including the MS/MSD.
        9.3.2.4.2  If, however, the RPD for the two aliquots of the PAR 
    is less than 20%, dilute the sample chosen for the MS/MSD by a 
    factor of 2-10 (to remain within the working range of the analytical 
    system) and repeat the MS/MSD test. If the RPD is still greater than 
    20%, the result may not be reported for regulatory compliance 
    purposes. In this case, choose another sample for the MS/MSD and 
    repeat analysis of the sample batch.
        9.3.2.5  If the percent recovery for both the MS and MSD are 
    less than 78% or greater than 116%, analyze the precision and 
    recovery (PAR) standard.
        9.3.2.5.1  If the recovery of the PAR is outside the 78 to 116% 
    range, the analytical system is out of control. In this case, repair 
    the problem and repeat the analysis of the sample batch, including 
    the MS/MSD.
        9.3.2.5.2  If the recovery of the PAR is within the range of 78 
    to 116%, dilute the sample, MS, and MSD by a factor of 2-10 (to 
    remain within the working range of the analytical system) and re-
    analyze. If the results of the dilute analyses remain outside of the 
    acceptable range, these results may not be reported for regulatory 
    compliance purposes. In this case, choose another sample for the MS/
    MSD and repeat the analysis of the sample batch.
        9.4  Blanks.
        9.4.1  Reagent water blanks: Analyzed to demonstrate freedom 
    from contamination.
        9.4.1.1  Analyze a reagent water blank with each batch of 
    samples. The blank must be analyzed immediately preceding 
    calibration verification to allow for blank subtraction and to 
    demonstrate freedom from contamination and memory effects, and must 
    include all details of the procedure to be followed when analyzing 
    samples.
        9.4.1.2   Prepare the reagent water blank using a volume of 
    reagent water equivalent to the volume used for sample preparation 
    (Section 11.1). If using the micro-column procedure, adsorb the 
    method blank using two columns, as described in Section 11. Combust 
    the GAC from each column separately, as described in Section 11.
        9.4.1.3  If the result from the blank from the batch method or 
    the sum of the results from two columns is more than 20 g/
    L, analysis of samples is halted until the source of contamination 
    is eliminated and a blank shows no evidence of contamination at this 
    level.
        9.4.2  Nitrate-washed GAC blanks: Analyzed daily to demonstrate 
    that the GAC is free from contamination.
        9.4.2.1  Nitrate-washed GAC blank for the batch procedure: 
    Analyze a batch nitrate-washed GAC blank by adding a scoop of dry 
    GAC to the assembled filter apparatus containing the polycarbonate 
    membrane and washing the GAC with the nitrate wash solution (Section 
    7.10) using the procedure in Section 11.2.6.
        9.4.2.2  Nitrate-washed GAC blank for the column procedure: 
    Analyze a column nitrate-washed GAC blank by assembling two carbon 
    columns in series and washing the columns with the nitrate wash 
    solution (Section 7.10) using the procedure in Section 11.3.4.2. 
    Analyze the GAC in each column separately. The results of the second 
    analysis must be within 0.2 g Cl- of 
    the first. A difference greater than 0.2 g Cl- 
    indicates a lack of homogeneity in the GAC that could introduce 
    unacceptable variability. If the difference exceeds this amount, the 
    GAC should be replaced.
        9.4.3  The result for the reagent water blank (Section 9.4.1) 
    shall not exceed the result for the nitrate wash blank (Section 
    9.4.2.1 or 9.4.2.2) by more than 0.5 g Cl-.
        9.5  Granular activated carbon (GAC) batch testing: Each lot 
    number or batch of activated carbon received from a supplier is 
    tested once before use to ensure adequate quality. Use only GAC that 
    meets the test criteria below.
        9.5.1  Contamination test: Analyze a scoop of GAC. Reject carbon 
    if the amount of OX exceeds 1 g (25 g 
    Cl-/g).
        9.5.2  Inorganic chloride adsorption test: Attempt to adsorb 
    NaCl from 100 mL of a solution containing 100 mg/L in reagent water. 
    Wash with nitrate solution and analyze. The amount of halide should 
    be less than 1 g Cl- larger than the blank. A 
    larger amount indicates significant uptake of inorganic chloride by 
    the carbon. Reject carbon if the 1 g level is exceeded.
        9.6  Samples that are being used for regulatory compliance 
    purposes shall be analyzed in duplicate.
    
    [[Page 18727]]
    
        9.6.1  The procedure for preparing duplicate sample aliquots is 
    described in Section 11.5.
        9.6.2  Calculate the RPD by following the same procedure 
    described in Section 12.4.
        9.6.3  If the RPD is greater than 20%, the analyses must be 
    repeated.
        9.6.4  If the RPD remains greater than 20%, the result may not 
    be reported for regulatory compliance purposes.
        9.7  The specifications in this method can be met if the 
    apparatus used is calibrated properly and maintained in a calibrated 
    state. The standards used for calibration (Section 10), calibration 
    verification (Section 9.9), and for initial (Section 9.2.2) and 
    ongoing (Section 9.10) precision and recovery should be identical, 
    so that the most precise results will be obtained.
        9.8  Depending on specific program requirements, field 
    duplicates may be collected to determine the precision of the 
    sampling technique.
        9.9  At the beginning and end of each eight-hour shift during 
    which analyses are performed, system performance and calibration are 
    verified. Verification of system performance and calibration may be 
    performed more frequently, if desired.
        9.9.1  If performance and calibration are verified at the 
    beginning and end of each shift (or more frequently), samples 
    analyzed during that period are considered valid.
        9.9.2  If performance and calibration are not verified at both 
    the beginning and end of a shift (or more frequently), samples 
    analyzed during that period must be reanalyzed.
        9.9.3  If calibration is verified at the beginning of a shift, 
    recalibration using the five standards described in Section 10.6 is 
    not necessary; otherwise, the instrument must be recalibrated prior 
    to analyzing samples (Section 10).
        9.9.4  Cell maintenance and other changes to the analytical 
    system that can affect system performance may not be performed 
    during the eight-hour (or shorter) shift.
        9.10  Calibration verification and ongoing precision and 
    recovery: Calibration and system performance are verified by the 
    analysis of the 100 g/L PAR standard.
        9.10.1  Analyze a blank (Section 9.4) and analyze the PAR 
    standard (Section 7.12.4) immediately thereafter at the beginning 
    and end of each shift. Compute the concentration of organic halide 
    in the blank and in the PAR standard using the procedures in Section 
    12. The blank shall be less than 2 g Cl- (20 
    g/L equivalent).
        9.10.2  Subtract the result for the blank from the result of the 
    PAR standard using the procedures in Section 12, and compute the 
    percent recovery of the blank-subtracted PAR standard. The percent 
    recovery shall be in the range of 78 to 116%.
        9.10.3  If the recovery is within this range, the analytical 
    process is in control and analysis of blanks and samples may 
    proceed. If, however, the recovery is not within the acceptable 
    range, the analytical process is not in control. In this event, 
    correct the problem and repeat the ongoing precision and recovery 
    test (Section 9.10), or recalibrate (Sections 10.5 through 10.6).
        9.10.4  If the recovery is not within the acceptable range for 
    the PAR standard analyzed at the end of the eight-hour shift, 
    correct the problem, repeat the ongoing precision and recovery test 
    (Section 9.10), or recalibrate (Sections 10.5 through 10.6), and 
    reanalyze the sample batch that was analyzed during the eight-hour 
    shift.
        9.10.5  If the recovery is within the acceptable range at the 
    end of the shift, and samples are to be analyzed during the next 
    eight-hour shift, the end of shift verification may be used as the 
    beginning of shift verification for the subsequent shift, provided 
    the next eight-hour shift begins as the first shift ends.
        9.11  It is suggested but not required that the laboratory 
    develop a statement of data quality for AOX and develop QC charts to 
    form a graphic demonstration of method performance. Add results that 
    pass the specification in Section 9.10.2 to initial and previous 
    ongoing data. Develop a statement of data quality by calculating the 
    average percent recovery (R) and the standard deviation of percent 
    recovery (sr). Express the accuracy as a recovery 
    interval from R - 2sr to R + 2sr. For example, 
    if R=95% and sr=5%, the accuracy is 85 to 105%.
    
    10.0  Calibration and Standardization
    
        10.1  Assemble the OX system and establish the operating 
    conditions necessary for analysis. Differences between various makes 
    and models of instruments will require different operating 
    procedures. Laboratories should follow the operating instructions 
    provided by the manufacturer of their particular instrument. 
    Sensitivity, instrument detection limit, precision, linear range, 
    and interference effects must be investigated and established for 
    each particular instrument. Calibration is performed when the 
    instrument is first set up and when calibration cannot be verified 
    (Section 9.9).
        10.2  Cell performance test: Inject 100 L of the sodium 
    chloride solution (10 g Cl-; Section 7.4) 
    directly into the titration cell electrolyte. Adjust the instrument 
    to produce a reading of 10 g Cl-.
        10.3  Combustion system test: This test can be used to assure 
    that the combustion/micro-coulometer systems are performing properly 
    without introduction of carbon. This test should be used during 
    initial instrument setup and when instrument performance indicates a 
    problem with the combustion system.
        10.3.1  Designate a quartz boat for use with the ammonium 
    chloride (NH4Cl) solution only.
        10.3.2  Inject 100 L of the NH4Cl solution 
    (Section 7.5) into this boat and proceed with the analysis.
        10.3.3  The result shall be between 9.5 and 10.5 g 
    Cl-. If the recovery is not between these limits, the 
    combustion or micro-coulometer systems are not performing properly. 
    Check the temperature of the combustion system, verify that there 
    are no leaks in the combustion system, confirm that the cell is 
    performing properly (Section 10.2), and then repeat the test.
        10.4  Trichlorophenol combustion test: This test can be used to 
    assure that the combustion/micro-coulometer systems are performing 
    properly when carbon is introduced. It should be used during 
    instrument setup and when it is necessary to isolate the adsorption 
    and combustion steps.
        10.4.1  Inject 10 L of the 1 mg/mL trichlorophenol 
    stock solution (Section 7.12.2) onto one level scoop of GAC in a 
    quartz boat.
        10.4.2  Immediately proceed with the analysis to prevent loss of 
    trichlorophenol and to prevent contamination of the carbon.
        10.4.3  The result shall be between 9.0 and 11.0 g 
    Cl-. If the recovery is not between these limits, the 
    combustion/micro-coulometer system shall be adjusted and the test 
    repeated until the result falls within these limits.
        10.5  Background level of Cl-: Determine the average 
    background level of Cl- for the entire analytical system 
    as follows:
        10.5.1  Using the procedure in Section 11 (batch or column) that 
    will be used for the analysis of samples, determine the background 
    level of Cl- in each of three portions of reagent water. 
    The volume of reagent water used shall be the same as the volume 
    used for analysis of samples.
        10.5.2  Calculate the average (mean) concentration of 
    Cl- and the standard deviation of the concentration.
        10.5.3  The sum of the average concentration plus two times the 
    standard deviation of the concentration shall be less than 20 
    g/L. If not, the water or carbon shall be replaced, or the 
    adsorption system moved to an area free of organic halide vapors, 
    and the test (Section 10.5) shall be repeated. Only after this test 
    is passed may calibration proceed.
        10.6  Calibration by external standard: A calibration line 
    encompassing the calibration range is developed using solutions of 
    2,4,6-trichlorophenol.
        10.6.1  Analyze each of the five calibration solutions (Section 
    7.12.3) using the procedure in Section 11 (batch or column) that 
    will be used for the analysis of samples, and the same procedure 
    that was used for determination of the system background (Section 
    10.5). Analyze these solutions beginning with the lowest 
    concentration and proceeding to the highest. Record the response of 
    the micro-coulometer to each calibration solution.
        10.6.2  Prepare a method blank as described in Section 9.4. 
    Subtract the value of the blank from each of the five calibration 
    results, as described in Section 12.
        10.6.3  Calibration factor (ratio of response to concentration) 
    Using the blank subtracted results, compute the calibration factor 
    at each calibration point, and compute the average calibration 
    factor and the relative standard deviation (coefficient of 
    variation; Cv) of the calibration factor over the calibration range.
        10.6.4  Linearity: The Cv of the calibration factor shall be 
    less than 20%; otherwise, the calibration shall be repeated after 
    adjustment of the combustion/micro-coulometer system and/or 
    preparation of fresh calibration standards.
        10.6.5  Using the average calibration factor, compute the 
    percent recovery at each calibration point. The recovery at each 
    calibration point shall be within the range of 80 to 111%. If any 
    point is not within this range, a fresh calibration standard shall 
    be
    
    [[Page 18728]]
    
    prepared for that point, this standard shall be analyzed, and the 
    calibration factor (Section 10.6.3) and calibration linearity 
    (Section 10.6.4) shall be computed using the new calibration point. 
    All points used in the calibration must meet the 80 to 111% recovery 
    specification.
    
    11.0 Procedure
    
        11.1  Sample dilution: Many samples will contain high 
    concentrations of halide. If analyzed without dilution, the micro-
    coulometer can be overloaded, resulting in frequent cell cleaning 
    and downtime. The following guidance is provided to assist in 
    estimating dilution levels.
        11.1.1  Paper and pulp mills that employ chlorine bleaching: 
    Samples from pulp mills that use a chlorine bleaching process may 
    overload the micro-coulometer. To prevent system overload, the 
    maximum volume suggested for paper industry samples that employ 
    halide in the bleaching process is 100 mL. An adsorption volume as 
    small as 25 mL may be used, provided the concentration of AOX in the 
    sample can be measured reliably, as defined by the requirements in 
    Section 9.11. To minimize volumetric error, an adsorption volume 
    less than 25 mL may not be used. If AOX cannot be measured reliably 
    in a 100-mL sample volume, a sample volume to a maximum of 1000 mL 
    must be used. The sample and adsorption volumes are suggested for 
    paper industry samples employing chlorine compounds in the bleaching 
    process:
    
    ------------------------------------------------------------------------
                                                      Sample                
              Paper or pulp mill stream               volume      Adsorption
                                                       (mL)*     volume (mL)
    ------------------------------------------------------------------------
    Evaporator condensate........................         100.0          100
    Process water................................         100.0          100
    Pulp mill effluent...........................          30.0           50
    Paper mill effluent..........................          10.0           25
    Combined mill effluent.......................           5.0           25
    Combined bleach effluent.....................           1.0           25
    C-stage filtrate.............................           0.5           25
    E-stage filtrate.............................           0.5           25
    ------------------------------------------------------------------------
    * Assumes dilution to final volume of 100 mL. All sample aliquots       
      (replicates, diluted samples) must be analyzed using the same fixed   
      final volume (sample volume plus reagent water, as needed).           
    
        11.1.2  Sample dilution procedure.
        11.1.2.1  Partially fill a precleaned volumetric flask with pH < 2="" reagent="" water,="" allowing="" for="" the="" volume="" of="" sample="" to="" be="" added.="" 11.1.2.2="" mix="" sample="" thoroughly="" by="" tumbling="" or="" shaking="" vigorously.="" 11.1.2.3="" immediately="" withdraw="" the="" required="" sample="" aliquot="" using="" a="" pipet="" or="" micro-syringe.="" note:="" because="" it="" will="" be="" necessary="" to="" rinse="" the="" pipet="" or="" micro-="" syringe="" (section="" 11.1.2.5),="" it="" may="" be="" necessary="" to="" pre-calibrate="" the="" pipet="" or="" micro-syringe="" to="" assure="" that="" the="" exact="" volume="" desired="" will="" be="" delivered.="" 11.1.2.4="" dispense="" or="" inject="" the="" aliquot="" into="" the="" volumetric="" flask.="" 11.1.2.5="" rinse="" the="" pipet="" or="" syringe="" with="" small="" portions="" of="" reagent="" water="" and="" add="" to="" the="" flask.="" 11.1.2.6="" dilute="" to="" the="" mark="" with="" ph="">< 2="" reagent="" water.="" 11.1.3="" all="" samples="" to="" be="" reported="" for="" regulatory="" compliance="" monitoring="" purposes="" must="" be="" analyzed="" in="" duplicate,="" as="" described="" in="" section="" 11.5.="" 11.1.4="" pulp="" and="" paper="" in-process="" samples:="" the="" concentration="" of="" organic="" halide="" in="" in-process="" samples="" has="" been="" shown="" to="" be="" 20="" to="" 30%="" greater="" using="" the="" micro-column="" adsorption="" technique="" than="" using="" the="" batch="" adsorption="" technique.="" for="" this="" reason,="" the="" micro-column="" technique="" shall="" be="" used="" for="" monitoring="" in-process="" samples.="" examples="" of="" in-process="" samples="" include:="" combined="" bleach="" plant="" effluent,="" c-="" stage="" filtrate,="" and="" e-stage="" filtrate.="" 11.2="" batch="" adsorption="" and="" filtration.="" 11.2.1="" place="" the="" appropriate="" volume="" of="" sample="" (diluted="" if="" necessary),="" preserved="" as="" described="" in="" section="" 8,="" into="" an="" erlenmeyer="" flask.="" 11.2.2="" add="" 5="" ml="" of="" nitrate="" stock="" solution="" to="" the="" sample="" aliquot.="" 11.2.3="" add="" one="" level="" scoop="" of="" activated="" carbon="" that="" has="" passed="" the="" quality="" control="" tests="" in="" section="" 9.="" 11.2.4="" shake="" the="" suspension="" for="" at="" least="" one="" hour="" in="" a="" mechanical="" shaker.="" 11.2.5="" filter="" the="" suspension="" through="" a="" polycarbonate="" membrane="" filter.="" filter="" by="" suction="" until="" the="" liquid="" level="" reaches="" the="" top="" of="" the="" carbon.="" 11.2.6="" wash="" the="" inside="" surface="" of="" the="" filter="" funnel="" with="" 25="" ml="">5 mL) of nitrate wash solution in several portions. 
    After the level of the final wash reaches the top of the GAC, filter 
    by suction until the cake is barely dry. The time required for 
    drying should be minimized to prevent exposure of the GAC to halogen 
    vapors in the air, but should be sufficient to permit drying of the 
    cake so that excess water is not introduced into the combustion 
    apparatus. A drying time of approximately 10 seconds under vacuum 
    has been shown to be effective for this operation.
        11.2.7  Carefully remove the top of the filter holder, making 
    sure that no carbon is lost. This operation is most successfully 
    performed by removing the clamp, tilting the top of the filter 
    holder (the funnel portion) to one side, and lifting upward.
        11.2.8  Using a squeeze bottle or micro-syringe, rapidly rinse 
    the carbon from the inside of the filter holder onto the filter cake 
    using small portions of wash solution. Allow the cake to dry under 
    vacuum for no more than 10 seconds after the final rinse. 
    Immediately turn the vacuum off.
        11.2.9  Using tweezers, carefully fold the polycarbonate filter 
    in half, then in fourths, making sure that no carbon is lost.
        11.3  Column adsorption.
        11.3.1  Column preparation: Prepare a sufficient number of 
    columns for one day's operation as follows:
        11.3.1.1  In a glove box or area free from halide vapors, place 
    a plug of Cerafelt into the end of a clean glass column.
        11.3.1.2  Fill the glass column with one level scoop 
    (approximately 40 mg) of granular activated carbon that has passed 
    the quality control tests in Section 9.
        11.3.1.3  Insert a Cerafelt plug into the open end of the column 
    to hold the carbon in place.
        11.3.1.4  Store the columns in a glass jar with PTFE lined 
    screw-cap to prevent infiltration of halide vapors from the air.
        11.3.2  Column setup.
        11.3.2.1  Install two columns in series in the adsorption 
    module.
        11.3.2.2  If the sample is known or expected to contain 
    particulates that could prevent free flow of sample through the 
    micro-columns, a Cerafelt plug is placed in the tubing ahead of the 
    columns. If a measurement of the OX content of the particulates is 
    desired, the Cerafelt plug can be washed with nitrate solution, 
    placed in a combustion boat, and processed as a separate sample.
        11.3.3  Adjusting sample flow rate: Because the flow rate used 
    to load the sample onto the columns can affect the ability of the 
    GAC to adsorb organic halides, the flow rate of the method blank is 
    measured, and the gas pressure used to process samples is adjusted 
    accordingly. The flow rate of the blank, which is composed of 
    acidified reagent water and contains no particulate matter, should 
    be greater than the flow rate of any sample containing even small 
    amounts of particulate matter.
        11.3.3.1  Fill the sample reservoir with the volume of reagent 
    water chosen for the analysis (Section 9.4.1.2) that has been 
    preserved and acidified as described in Section 8. Cap the 
    reservoir.
        11.3.3.2  Adjust the gas pressure per the manufacturer's 
    instructions. Record the time required for the entire volume of 
    reagent water to pass through both columns. The flow rate must not 
    exceed 3 mL/min over the duration of the time required to adsorb the 
    volume. If this flow rate is exceeded, adjust gas pressure, prepare 
    another blank, and repeat the adsorption.
    
    [[Page 18729]]
    
        11.3.3.3  Once the flow rate for the blank has been established, 
    the same adsorption conditions must be applied to all subsequent 
    samples during that eight-hour shift, or until another method blank 
    is processed, whichever comes first. To aid in overcoming 
    breakthrough problems, a lower gas pressure (and, therefore, flow 
    rate) may be used for processing of samples, if desired. If the 
    sample adsorption unit is disassembled or cleaned, the flow rate 
    must be checked before processing additional samples.
        11.3.3.4  Elute the pair of columns with 2 mL of nitrate wash 
    solution. The flow rate of nitrate wash solution must not exceed 3 
    mL/min.
        11.3.3.5  Separate the columns and mark for subsequent analysis.
        11.3.4  The adsorption of sample volumes is performed in a 
    similar fashion. Fill the sample reservoir with the sample volume 
    chosen for the analysis (Section 11.1), that has been preserved as 
    described in Section 8. All analyses must be performed with this 
    volume (sample volume plus reagent water, as needed) in order to 
    maintain a flow rate no greater than that determined for the blank 
    (see Section 11.3.3).
        11.3.4.1  Use the same gas pressure for sample adsorption as is 
    used for the blank.
        11.3.4.2  Elute the columns with 2 mL of the nitrate wash 
    solution.
        11.3.4.3  Separate the columns and mark for subsequent analysis.
        11.3.5  If it is desirable to make measurements at levels lower 
    than can be achieved with the sample volume chosen, or if the 
    instrument response of an undiluted sample is less than three times 
    the instrument response of the blank (Section 12.6.3), a larger 
    sample volume must be used.
        11.4  Combustion and titration.
        11.4.1  Polycarbonate filter and GAC from batch adsorption.
        11.4.1.1  Place the folded polycarbonate filter containing the 
    GAC in a quartz combustion boat, close the airlock, and proceed with 
    the automated sequence.
        11.4.1.2  Record the signal from the micro-coulometer for a 
    minimum integration time of 10 minutes and determine the 
    concentration of Cl- from calibration data, per Section 
    12.
        11.4.2  Columns from column adsorption.
        11.4.2.1  Using the push rod, push the carbon and the Cerafelt 
    plug(s) from the first column into a combustion boat. Proceed with 
    the automated sequence.
        11.4.2.2  Record the signal from the micro-coulometer for a 
    minimum integration time of 10 minutes and determine the 
    concentration of Cl- for the first column from 
    calibration data, per Section 12.
        11.4.2.3  Repeat the automated sequence with the second column.
        11.4.2.4  Determine the extent of breakthrough of organic 
    halides from the first column to the second column, as described in 
    Section 12.
        11.4.3  The two columns that are used for the method blank must 
    be combusted separately, as is done for samples. 11.5 Duplicate 
    sample analysis: All samples to be reported for regulatory 
    compliance purposes must be analyzed in duplicate. This requirement 
    applies to both the batch and column adsorption procedures. In 
    addition, if it is necessary to dilute the sample for the purposes 
    of reducing breakthrough or maintaining the concentration within the 
    calibration range, a more or less dilute sample must be analyzed. 
    The adsorption volumes used for analysis of undiluted samples, 
    diluted samples, and all replicates must be the same as the volume 
    used for QC tests and calibration (Sections 9 and 10).
        11.5.1  Using results from analysis of one sample volume 
    (Section 11.4) and the procedure in Section 11.1.2, determine if the 
    dilution used was within the calibration range of the instrument 
    and/or if breakthrough exceeded the specification in Section 12.3.1. 
    If the breakthrough criterion was exceeded or the sample was not 
    within the calibration range, adjust the dilution volume as needed. 
    If the breakthrough criterion was not exceeded and the sample 
    dilution was within the calibration range, a second volume at the 
    same dilution level may be used.
        11.5.2  Adsorb the sample using the same technique (batch or 
    column) used for the first sample volume. Combust the GAC from the 
    second volume as described in Section 11.4, and calculate the 
    results as described in Section 12. Compare the results of the two 
    analyses as described in Section 12.4.
        11.5.3  Duplicate analyses are not required for method blanks, 
    as different dilution levels are not possible.
        11.5.4  Duplicate analyses of the PAR standard used for 
    calibration verification (Section 9.10) are not required.
    
    12.0  Data Analysis and Calculations
    
        12.1  Batch Adsorption Method: Calculate the blank-subtracted 
    concentration of adsorbable organic halide detected in each sample 
    (in micrograms of chloride per liter) using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.019
    
    Where:
    
    C=g Cl- from micro-coulometer for the sample
    B=g Cl- from micro-coulometer for the reagent 
    water blank (Section 9.4.1)
    V = volume of sample in liters
    
        This calculation is performed for each of the two dilution 
    levels analyzed for each sample.
        12.2  Column Adsorption Method: Calculate the blank-subtracted 
    concentration of adsorbable organic halide detected in each sample 
    (in micrograms of chloride per liter) using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.020
    
    Where:
    
    C1=g C1- from micro-coulometer for 
    first column from the sample
    C2=g C1- from micro-coulometer for 
    second column from the sample
    B1=g from micro-coulometer for first column from 
    the reagent water blank (Section 9.4.1)
    B2=g C1- from micro-coulometer for 
    second column from the reagent water blank (Section 9.4.1)
    V=volume of sample in liters
    
        12.3  Percent breakthrough: For each sample analyzed by the 
    column method, calculate the percent breakthrough of halide from the 
    first column to the second column, using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.021
    
        12.3.1  For samples to be reported for regulatory compliance 
    purposes, the percent breakthrough must be less than or equal to 25% 
    for both of the two analyses performed on each sample (see Section 
    11.5).
        12.3.2  If the breakthrough exceeds 25%, dilute the affected 
    sample further, maintaining the amount of halide at least three 
    times higher than the level of blank, and reanalyze the sample. 
    Ensure that the sample is also analyzed at a second level of 
    dilution that is at least a factor of 2 different (and still higher 
    than three times the blank).
        12.4  Relative percent difference (RPD): Calculate the relative 
    percent difference between the results of the two analyses of each 
    sample, using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.022
    
        12.5  High concentrations of AOX: If the amount of halide from 
    either analysis exceeds the calibration range, dilute the sample and 
    reanalyze, maintaining at least a factor of 2 difference in the 
    dilution levels of the two portions of the sample used.
        12.6  Low concentrations of AOX: The blank-subtracted final 
    result from the batch procedure or the sum of the blank-subtracted 
    results from the two carbon columns should be significantly above 
    the level of the blank.
        12.6.1  If the instrument response for a sample exceeds the 
    instrument response for the blank by a factor of at least 3, the 
    result is acceptable.
        12.6.2  If the instrument response for a sample is less than 
    three times the instrument response for the blank, and the sample 
    has been diluted, analyze a less dilute aliquot of sample.
        12.6.3  If the instrument response of an undiluted sample 
    containing AOX above the minimum level is less than three times the 
    instrument response for the blank, the result is suspect and may not 
    be used for regulatory compliance purposes. In this case, find the 
    cause of contamination, correct the problem, and reanalyze the 
    sample under the corrected conditions.
        12.7  Report results that meet all of the specifications in this 
    method as the mean of the blank-subtracted values from Section 12.1 
    or 12.2 for the two analyses at different dilution levels, in 
    g/L of Cl- (not as 2,4,6-trichlorophenol), to 
    three significant figures. Report the RPD of the two analyses. For 
    samples analyzed by the column procedure, also report the percent 
    breakthrough.
    
    [[Page 18730]]
    
    13.0  Method Performance
    
        The specifications contained in this method are based on data 
    from a single laboratory and from a large-scale study of the pulp 
    and paper industry.
    
    14.0  Pollution Prevention
    
        14.1  The solvents used in this method pose little threat to the 
    environment when recycled and managed properly.
        14.2  Standards should be prepared in volumes consistent with 
    laboratory use to minimize the volume of expired standards to be 
    disposed.
    
    15.0  Waste Management
    
        15.1  It is the laboratory's responsibility to comply with all 
    federal, state, and local regulations governing waste management, 
    particularly the hazardous waste identification rules and land 
    disposal restrictions, and to protect the air, water, and land by 
    minimizing and controlling all releases from fume hoods and bench 
    operations. Compliance with all sewage discharge permits and 
    regulations is also required.
        15.2  Samples preserved with HCl or H2SO4 
    to pH <2 are="" hazardous="" and="" must="" be="" neutralized="" before="" being="" disposed,="" or="" must="" be="" handled="" as="" hazardous="" waste.="" acetic="" acid="" and="" silver="" acetate="" solutions="" resulting="" from="" cell="" flushing="" must="" be="" disposed="" of="" in="" accordance="" with="" all="" applicable="" federal,="" state,="" and="" local="" regulations.="" 15.3="" for="" further="" information="" on="" waste="" management,="" consult="" ``the="" waste="" management="" manual="" for="" laboratory="" personnel,''="" and="" ``less="" is="" better:="" laboratory="" chemical="" management="" for="" waste="" reduction,''="" both="" available="" from="" the="" american="" chemical="" society's="" department="" of="" government="" relations="" and="" science="" policy,="" 1155="" 16th="" street="" n.w.,="" washington,="" d.c.="" 20036.="" 16.0="" references="" 16.1="" ``total="" organic="" halide,="" methods="" 450.1--interim,''="" prepared="" by="" stephen="" billets="" and="" james="" j.="" lichtenberg,="" usepa,="" office="" of="" research="" and="" development,="" physical="" and="" chemical="" methods="" branch,="" emsl-cincinnati,="" cincinnati,="" oh="" 45268,="" epa="" 600/4-81-056="" (1981).="" 16.2="" method="" 9020,="" usepa="" office="" of="" solid="" waste,="" ``test="" methods="" for="" evaluating="" solid="" waste,="" sw-846,''="" third="" edition,="" 1987.="" 16.3="" ``determination="" of="" adsorbable="" organic="" halogens="" (aox),''="" ``german="" standard="" methods="" for="" the="" analysis="" of="" water,="" waste="" water="" and="" sludge--general="" parameters="" of="" effects="" and="" substances,''="" deutsche="" industrie="" norm="" (din)="" method="" 38="" 409,="" part="" 14,="" din="" german="" standards="" institute,="" beuth="" verlag,="" berlin,="" germany="" (1987).="" 16.4="" ``water="" quality:="" determination="" of="" adsorbable="" organic="" halogens="" (aox),''="" international="" organization="" for="" standard/draft="" international="" standardization="" (iso/dis)="" method="" 9562="" (1988).="" 16.5="" ``organically="" bound="" chlorine="" by="" the="" aox="" method,''="" scan-w="" 9:89,="" secretariat,="" scandinavian="" pulp,="" paper="" and="" board="" testing="" committee,="" box="" 5604,="" s-11486,="" stockholm,="" sweden="" (1989).="" 16.6="" method="" 5320,="" ``dissolved="" organic="" halogen,''="" from="" ``standard="" methods="" for="" the="" examination="" of="" water="" and="" wastewater,''="" 5320,="" american="" public="" health="" association,="" 1015="" 15th="" st.="" nw,="" washington,="" dc="" 20005="" (1989).="" 16.7="" ``canadian="" standard="" method="" for="" the="" determination="" of="" adsorbable="" organic="" halides="" (aox)="" in="" waters="" and="" wastewaters,''="" environment="" canada="" and="" the="" canadian="" pulp="" and="" paper="" association="" (1990).="" 16.8="" 40="" cfr="" part="" 136,="" appendix="" b.="" 16.9="" ``working="" with="" carcinogens,''="" dhew,="" phs,="" cdc,="" niosh,="" publication="" 77-206,="" (aug="" 1977).="" 16.10="" ``osha="" safety="" and="" health="" standards,="" general="" industry''="" osha="" 2206,="" 29="" cfr="" 1910="" (jan="" 1976).="" 16.11="" ``safety="" in="" academic="" chemistry="" laboratories,''="" acs="" committee="" on="" chemical="" safety="" (1979).="" 16.12="" ``methods="" 330.4="" and="" 330.5="" for="" total="" residual="" chlorine,''="" usepa,="" emsl-cincinnati,="" cincinnati,="" oh="" 45268,="" epa-4-79-020="" (march="" 1979).="" 16.13="" ``validation="" of="" method="" 1650:="" determination="" of="" organic="" halide,''="" analytical="" technologies="" inc.,="" erce="" contract="" 87-3410,="" november="" 15,="" 1990.="" available="" from="" the="" epa="" sample="" control="" center,="" dyncorp,="" 300="" n.="" lee="" st.,="" alexandria,="" va="" 22314="" (703-519-1140).="" 17.0="" figures="" billing="" code="" 6560-50-p="" [[page="" 18731]]="" [graphic]="" [tiff="" omitted]="" tr15ap98.023="" [[page="" 18732]]="" [graphic]="" [tiff="" omitted]="" tr15ap98.024="" [[page="" 18733]]="" [graphic]="" [tiff="" omitted]="" tr15ap98.025="" [[page="" 18734]]="" [graphic]="" [tiff="" omitted]="" tr15ap98.026="" billing="" code="" 6560-50-c="" [[page="" 18735]]="" 18.0="" glossary="" of="" definitions="" and="" purposes="" these="" definitions="" and="" purposes="" are="" specific="" to="" this="" method="" but="" have="" been="" conformed="" to="" common="" usage="" as="" much="" as="" possible.="" 18.1="" units="" of="" weight="" and="" measure="" and="" their="" abbreviations.="" 18.1.1="" symbols.="" deg.c="" degrees="" celsius="">g  microgram
    L  microliter
    < less="" than="">  greater than
    %  percent
    
        18.1.2  Alphabetical characters.
    
    cm  centimeter
    g  gram
    h  hour
    ID  inside diameter
    in  inch
    L  liter
    m  meter
    mg  milligram
    min  minute
    mL  milliliter
    mm  millimeter
    N  normal; gram molecular weight of solute divided by hydrogen 
    equivalent of solute, per liter of solution
    OD  outside diameter
    ppb  part-per-billion
    ppm  part-per-million
    ppt  part-per-trillion
    psig  pounds-per-square inch gauge
    v/v  volume per unit volume
    w/v  weight per unit volume
    
        18.2  Definitions and acronyms (in alphabetical order).
        Analyte: AOX tested for by this method.
        Calibration standard (CAL): A solution prepared from a secondary 
    standard and/or stock solution which is used to calibrate the 
    response of the instrument with respect to analyte concentration.
        Calibration verification standard (VER): The mid-point 
    calibration standard (CS3) that is used to verify calibration.
        Field blank: An aliquot of reagent water or other reference 
    matrix that is placed in a sample container in the laboratory or the 
    field, and treated as a sample in all respects, including exposure 
    to sampling site conditions, storage, preservation, and all 
    analytical procedures. The purpose of the field blank is to 
    determine if the field or sample transporting procedures and 
    environments have contaminated the sample.
        IPR: Initial precision and recovery; four aliquots of the 
    diluted PAR standard analyzed to establish the ability to generate 
    acceptable precision and accuracy. An IPR is performed prior to the 
    first time this method is used and any time the method or 
    instrumentation is modified.
        Laboratory blank: See Method blank.
        Laboratory control sample (LCS): See Ongoing precision and 
    recovery sample (OPR).
        Laboratory reagent blank: See Method blank.
        May: This action, activity, or procedural step is neither 
    required nor prohibited.
        May not: This action, activity, or procedural step is 
    prohibited.
        Method blank: An aliquot of reagent water that is treated 
    exactly as a sample including exposure to all glassware, equipment, 
    solvents, reagents, internal standards, and surrogates that are used 
    with samples. The method blank is used to determine if analytes or 
    interferences are present in the laboratory environment, the 
    reagents, or the apparatus.
        Minimum level (ML): The level at which the entire analytical 
    system must give a recognizable signal and acceptable calibration 
    point for the analyte. It is equivalent to the concentration of the 
    lowest calibration standard, assuming that all method-specified 
    sample weights, volumes, and cleanup procedures have been employed.
        Must: This action, activity, or procedural step is required.
        OPR: Ongoing precision and recovery standard; a laboratory blank 
    spiked with a known quantity of analyte. The OPR is analyzed exactly 
    like a sample. Its purpose is to assure that the results produced by 
    the laboratory remain within the limits specified in this method for 
    precision and recovery.
        PAR: Precision and recovery standard; secondary standard that is 
    diluted and spiked to form the IPR and OPR.
        Preparation blank: See Method blank.
        Primary dilution standard: A solution containing the specified 
    analytes that is purchased or prepared from stock solutions and 
    diluted as needed to prepare calibration solutions and other 
    solutions.
        Quality control check sample (QCS): A sample containing all or a 
    subset of the analytes at known concentrations. The QCS is obtained 
    from a source external to the laboratory or is prepared from a 
    source of standards different from the source of calibration 
    standards. It is used to check laboratory performance with test 
    materials prepared external to the normal preparation process.
        Reagent water: Water demonstrated to be free from the analyte of 
    interest and potentially interfering substances at the method 
    detection limit for the analyte.
        Relative standard deviation (RSD): The standard deviation 
    multiplied by 100, divided by the mean.
        RSD: See Relative standard deviation.
        Should: This action, activity, or procedural step is suggested 
    but not required.
        Stock solution: A solution containing an analyte that is 
    prepared using a reference material traceable to EPA, the National 
    Institute of Science and Technology (NIST), or a source that will 
    attest to the purity and authenticity of the reference material.
        VER: See Calibration verification standard.
    
    Method 1653--Chlorinated Phenolics in Wastewater by In Situ Acetylation 
    and GCMS
    
    1.0  Scope and Application
    
        1.1  This method is for determination of chlorinated phenolics 
    (chlorinated phenols, guaiacols, catechols, vanillins, 
    syringaldehydes) and other compounds associated with the Clean Water 
    Act; the Resource Conservation and Recovery Act; and the 
    Comprehensive Environmental Response, Compensation, and Liability 
    Act; and that are amenable to in situ acetylation, extraction, and 
    analysis by capillary column gas chromatography/mass spectrometry 
    (GCMS). This method is based on existing methods for determination 
    of chlorophenolics in pulp and paper industry wastewaters 
    (References 1 and 2).
        1.2  The chemical compounds listed in Table 1 may be determined 
    in waters and, specifically, in in-process streams and wastewaters 
    associated with the pulp and paper industry. The method is designed 
    to meet the survey and monitoring requirements of the Environmental 
    Protection Agency (EPA).
        1.3  The detection limit of this method is usually dependent on 
    the level of interferences rather than instrumental limitations. The 
    method detection limits (MDLs) in Table 2 typify the minimum 
    quantity that can be detected with no interferences present.
        1.4  The GCMS portions of this method are for use only by 
    persons experienced with GCMS or under the close supervision of such 
    qualified persons. Laboratories unfamiliar with analyses of 
    environmental samples by GCMS should run the performance tests in 
    Reference 3 before beginning.
        1.5  Any modification of the method beyond those expressly 
    permitted is subject to the application and approval of alternative 
    test procedures under 40 CFR Parts 136.4 and 136.5.
    
    2.0  Summary of Method
    
        2.1  A 1000-mL aliquot of water is spiked with stable 
    isotopically labeled analogs of the compounds of interest and an 
    internal standard. The solution is adjusted to neutral pH, potassium 
    carbonate buffer is added, and the pH is raised to 9-11.5. The 
    chlorophenolics are converted in situ to acetates by the addition of 
    acetic anhydride. After acetylation, the solution is extracted with 
    hexane. The hexane is concentrated to a final volume of 0.5 mL, an 
    instrument internal standard is added, and an aliquot of the 
    concentrated extract is injected into the gas chromatograph (GC). 
    The compounds are separated by GC and detected by a mass 
    spectrometer (MS). The labeled compounds and internal standard serve 
    to correct the variability of the analytical technique.
        2.2  Identification of a pollutant (qualitative analysis) is 
    performed by comparing the relative retention time and mass spectrum 
    to that of an authentic standard. A compound is identified when its 
    relative retention time and mass spectrum agree.
        2.3  Quantitative analysis is performed in one of two ways by 
    GCMS using extracted ion-current profile (EICP) areas: (1) For those 
    compounds listed in Table 1 for which standards and labeled analogs 
    are available, the GCMS system is calibrated and the compound 
    concentration is determined using an isotope dilution technique; (2) 
    for those compounds listed in Table 1 for which authentic standards 
    but no labeled compounds are available, the GCMS system is 
    calibrated and the compound concentration is determined using an 
    internal standard technique.
        2.4  Quality is assured through reproducible calibration and 
    testing of the extraction and GCMS systems.
    
    [[Page 18736]]
    
    3.0  Definitions
    
        3.1  Chlorinated phenolics are the chlorinated phenols, 
    guaiacols, catechols, vanillins, syringaldehydes and other compounds 
    amenable to in situ acetylation, extraction, and determination by 
    GCMS using this method.
        3.2  Definitions for other terms used in this method are given 
    in the glossary at the end of the method (Section 20.0).
    
    4.0  Interferences
    
        4.1  Solvents, reagents, glassware, and other sample processing 
    hardware may yield artifacts and/or elevated baselines, causing 
    misinterpretation of chromatograms and spectra. All materials used 
    in the analysis shall be demonstrated to be free from interferences 
    under the conditions of analysis by running method blanks initially 
    and with each sample batch (samples started through the extraction 
    process on a given eight-hour shift, to a maximum of 20). Specific 
    selection of reagents and purification of solvents by distillation 
    in all-glass systems may be required. Glassware and, where possible, 
    reagents are cleaned by using solvent rinse and baking at 450  deg.C 
    for a minimum of one hour.
        4.2  Interferences co-extracted from samples will vary 
    considerably from source to source, depending on the diversity of 
    the site being sampled. Industry experience suggests that high 
    levels of non-chlorinated phenols may cause poor recovery of the 
    compounds of interest, particularly in samples collected in the 
    vicinity of a source of creosote, such as a wood-preserving plant 
    (Reference 1).
        4.3  The internal standard, 3,4,5-trichlorophenol, has been 
    reported to be an anaerobic degradation product of 2,3,4,5-
    tetrachlorophenol and/or pentachlorophenol (Reference 1). When an 
    interference with this or another compound occurs, labeled 
    pentachlorophenol or another labeled compound may be used as an 
    alternative internal standard; otherwise, the internal standards and 
    reference compounds must be used as specified in this method.
        4.4  Blank contamination by pentachlorophenol has been reported 
    (Reference 1) to be traceable to potassium carbonate; it has also 
    been reported that this contamination may be removed by baking 
    overnight at 400 to 500  deg.C.
        4.5  Catechols are susceptible to degradation by active sites on 
    injection port liners and columns, and are subject to oxidation to 
    the corresponding chloro-o-benzoquinones (Reference 2). A small 
    amount of ascorbic acid may be added to samples to prevent auto-
    oxidation (Reference 2; also see Section 11.1.6). For pulp and paper 
    industry samples, ascorbic acid may be added to treated effluent 
    samples only.
    
    5.0  Safety
    
        5.1  The toxicity or carcinogenicity of each compound or reagent 
    used in this method has not been precisely determined; however, each 
    chemical compound should be treated as a potential health hazard. 
    Exposure to these compounds should be reduced to the lowest possible 
    level. The laboratory is responsible for maintaining a current 
    awareness file of OSHA regulations regarding the safe handling of 
    the chemicals specified in this method. A reference file of 
    materials safety data sheets (MSDSs) should be made available to all 
    personnel involved in these analyses. Additional information on 
    laboratory safety can be found in References 4 through 6.
        5.2  Samples may contain high concentrations of toxic compounds, 
    and should be handled with gloves and a hood opened to prevent 
    exposure.
    
    6.0  Equipment and Supplies
    
        Note: Brand names, suppliers, and part numbers are for 
    illustrative purposes only. No endorsement is implied. Equivalent 
    performance may be achieved using apparatus and materials other than 
    those specified here, but demonstration of equivalent performance 
    that meets the requirements of this method is the responsibility of 
    the laboratory.
    
        6.1  Sampling equipment for discrete or composite sampling.
        6.1.1  Sample bottles and caps.
        6.1.1.1  Sample bottle: Amber glass, 1000-mL minimum, with 
    screw-cap. If amber bottles are not available, samples shall be 
    protected from light.
        6.1.1.2  Bottle caps: Threaded to fit sample bottles. Caps shall 
    be lined with PTFE.
        6.1.1.3  Cleaning bottles: Detergent water wash, cap with 
    aluminum foil, and bake at 450 deg.C for a minimum of one hour 
    before use.
        6.1.1.4  Cleaning liners: Detergent water wash, reagent water 
    (Section 7.4) and solvent rinse, and bake at approximately 200 deg.C 
    for a minimum of 1 hour prior to use.
        6.1.1.5  Bottles and liners must be lot-certified to be free of 
    chlorophenolics by running blanks according to this method. If 
    blanks from bottles and/or liners without cleaning or with fewer 
    cleaning steps show no detectable chlorophenolics, the bottle and 
    liner cleaning steps that do not eliminate chlorophenolics may be 
    omitted.
        6.1.2  Compositing equipment: Automatic or manual compositing 
    system incorporating glass containers cleaned per bottle cleaning 
    procedure above. Sample containers are kept at 0 to 4  deg.C during 
    sampling. Glass or PTFE tubing only shall be used. If the sampler 
    uses a peristaltic pump, a minimum length of compressible silicone 
    rubber tubing may be used in the pump only. Before use, the tubing 
    shall be thoroughly rinsed with methanol, followed by repeated 
    rinsing with reagent water (Section 7.4) to minimize sample 
    contamination. An integrating flow meter is used to collect 
    proportional composite samples.
        6.2  Extraction apparatus.
        6.2.1  Bottle or beaker: 1500-to 2000-mL capacity.
        6.2.2  Separatory funnel: 500-to 2000-mL, glass, with PTFE 
    stopcock.
        6.2.3  Magnetic stirrer: Corning Model 320, or equivalent, with 
    stirring bar.
        6.3  Polyethylene gloves: For handling samples and extraction 
    equipment (Fisher 11-394-110-B, or equivalent).
        6.4  Graduated cylinders: 1000-mL, 100-mL, and 10-mL nominal.
        6.5  Centrifuge: Capable of accepting 50-mL centrifuge tubes and 
    achieving 3000 RPM.
        6.5.1  Centrifuge tubes.
        6.5.1.1  35-mL nominal, with PTFE-lined screw-cap.
        6.5.1.2  15-mL nominal, conical graduated, with ground-glass 
    stopper.
        6.6  Concentration apparatus.
        6.6.1    Kuderna-Danish (K-D) concentrator tube: 10-mL, 
    graduated (Kontes K-570050-1025, or equivalent) with calibration 
    verified. Ground-glass stopper (size 19/22 joint) is used to prevent 
    evaporation of extracts.
        6.6.2  Kuderna-Danish (K-D) evaporation flask: 1000-mL (Kontes 
    K-570001-1000, or equivalent), attached to concentrator tube with 
    springs (Kontes K-662750-0012).
        6.6.3  Snyder column: Three-ball macro (Kontes K-503000-0232, or 
    equivalent).
        6.6.4  Snyder column: Two-ball micro (Kontes K-469002-0219, or 
    equivalent).
        6.6.5  Boiling chips: Approximately 10/40 mesh, extracted with 
    methylene chloride and baked at 450  deg.C for a minimum of one 
    hour.
        6.6.6  Nitrogen evaporation apparatus: Equipped with a water 
    bath controlled at 35 to 40  deg.C (N-Evap, Organomation Associates, 
    Inc., South Berlin, MA, or equivalent), installed in a fume hood. 
    This device may be used in place of the micro-Snyder column 
    concentrator in Section 6.6.4 above.
        6.7   Water bath: Heated, with concentric ring  cover,  capable  
    of  temperature  control ( 2  deg.C), installed in a 
    fume hood.
        6.8  Sample vials: Amber glass, 1- to 3-mL, with PTFE-lined 
    screw-cap.
        6.9  Balances.
        6.9.1  Analytical: Capable of weighing 0.1 mg.
        6.9.2  Top loading: Capable of weighing 10 mg.
        6.10  pH meter.
        6.11  Gas chromatograph: Shall have splitless or on-column 
    injection port for capillary column, temperature program with 
    50 deg.C hold, and shall meet all of the performance specifications 
    in Section 9.
        6.12  Gas chromatographic column: 30 m (5 m)  x  
    0.25 mm (0.02 mm) I.D.  x  0.25 micron, 5% phenyl, 94% 
    methyl, 1% vinyl silicone bonded-phase fused-silica capillary column 
    (J & W DB-5, or equivalent).
        6.13  Mass spectrometer: 70 eV electron impact ionization, shall 
    repetitively scan from 42 to 450 amu in 0.95 to 1.00 second, and 
    shall produce a unit resolution (valleys between m/z 441-442 less 
    than 10% of the height of the 441 peak), background-corrected mass 
    spectrum from 50 ng decafluorotriphenylphosphine (DFTPP) introduced 
    through the GC inlet. The spectrum shall meet the mass-intensity 
    criteria in Table 3 (Reference 7). The mass spectrometer shall be 
    interfaced to the GC such that the end of the capillary column 
    terminates within 1 cm of the ion source, but does not intercept the 
    electron or ion beams. All portions of the column which connect the 
    GC to the ion source shall remain at or above the column temperature 
    during analysis to preclude condensation of less volatile compounds.
        6.14  Data system: Shall collect and record MS data, store mass-
    intensity data in spectral
    
    [[Page 18737]]
    
    libraries, process GCMS data, generate reports, and compute and 
    record response factors.
        6.14.1  Data acquisition: Mass spectra shall be collected 
    continuously throughout the analysis and stored on a mass storage 
    device.
        6.14.2  Mass spectral libraries: User-created libraries 
    containing mass spectra obtained from analysis of authentic 
    standards shall be employed to reverse search GCMS runs for the 
    compounds of interest (Section 10.2).
        6.14.3  Data processing: The data system shall be used to 
    search, locate, identify, and quantify the compounds of interest in 
    each GCMS analysis. Software routines shall be employed to compute 
    retention times, and to compute peak areas at the m/z's specified 
    (Table 4). Displays of spectra, mass chromatograms, and library 
    comparisons are required to verify results.
        6.14.4  Response factors and multi-point calibrations: The data 
    system shall be used to record and maintain lists of response 
    factors (response ratios for isotope dilution) and multi-point 
    calibration curves (Section 10). Computations of relative standard 
    deviation (coefficient of variation) are used for testing 
    calibration linearity. Statistics on initial (Section 9.3.2) and 
    ongoing (Section 9.6) performance shall be computed and maintained.
    
    7.0  Reagents and Standards
    
        7.1  Reagents for adjusting sample pH.
        7.1.1  Sodium hydroxide: Reagent grade, 6 N in reagent water.
        7.1.2  Sulfuric acid: Reagent grade, 6 N in reagent water.
        7.2  Reagents for sample preservation.
        7.2.1  Sodium thiosulfate 
    (Na2S2O3) solution (1 N): Weigh 79 
    g Na2S2O3 in a 1-L volumetric flask 
    and dilute to the mark with reagent water.
        7.2.2  Ascorbic acid solution: Prepare a solution of ascorbic 
    acid in reagent water at a concentration of 0.1 g/mL. This solution 
    must be prepared fresh on each day when derivatizations will be 
    performed. Therefore, do not prepare more than will be used that 
    day. (A 50-mL volume is sufficient for ten analyses).
        7.3  Solvents: Hexane, acetone, and methanol. Distilled in glass 
    (Burdick and Jackson, or equivalent).
        7.4  Reagent water: Water in which the compounds of interest and 
    interfering compounds are not detected by this method.
        7.5  Reagents for derivatization.
        7.5.1  Potassium carbonate (K2CO3).
        7.5.1.1  Purification: Spread in a shallow baking dish, heat 
    overnight at 400 to 500 deg.C.
        7.5.1.2  Solution: Dissolve 150 g purified 
    K2CO3 in 250 mL reagent water.
        7.5.2  Acetic anhydride: Redistilled reagent grade.
        7.6  Analytical standards.
        7.6.1  Derivatization: Because the chlorinated phenolics are 
    determined as their acetate derivatives after in situ acetylation, 
    the method requires that the calibration standards be prepared by 
    spiking the underivatized materials into reagent water and carrying 
    the spiked reagent water aliquot through the entire derivatization 
    and extraction procedure that is applied to the field samples.
        7.6.2  Standard solutions: Purchased as solutions or mixtures 
    with certification to their purity, concentration, and authenticity, 
    or prepared from materials of known purity and composition. If 
    chemical purity of a compound is 98% or greater, the weight may be 
    used without correction to compute the concentration of the 
    standard. When not being used, standards are stored in the dark at 
    -20 to -10  deg.C in screw-capped vials with PTFE-lined lids. A mark 
    is placed on the vial at the level of the solution so that solvent 
    evaporation loss can be detected. The vials are brought to room 
    temperature prior to use.
        7.6.3  If the chemical purity of any standard does not meet the 
    98% requirement above, the laboratory must correct all calculations, 
    calibrations, etc., for the difference in purity.
        7.7  Preparation of stock solutions: Prepare chlorovanillins and 
    chlorosyringaldehydes in acetone, as these compounds are subject to 
    degradation in methanol. Prepare the remaining chlorophenolics in 
    methanol. Prepare all standards per the steps below. Observe the 
    safety precautions in Section 5.
        7.7.1  Dissolve an appropriate amount of assayed reference 
    material in a suitable solvent. For example, weigh 50 mg 
    (0.1 mg) of pentachlorophenol in a 10-mL ground-glass-
    stoppered volumetric flask and fill to the mark with methanol. After 
    the pentachlorophenol is completely dissolved, transfer the solution 
    to a 15-mL vial with PTFE-lined cap.
        7.7.2  Stock solutions should be checked for signs of 
    degradation prior to the preparation of calibration or performance 
    test standards and shall be replaced after six months, or sooner if 
    comparison with quality control check standards indicates a change 
    in concentration.
        7.8  Labeled compound spiking solution: From stock solutions 
    prepared as above, or from mixtures, prepare one spiking solution to 
    contain the labeled chlorovanillin in acetone and a second spiking 
    solution to contain the remaining chlorophenolics, including the 
    3,4,5-trichlorophenol sample matrix internal standard (SMIS), in 
    methanol. The labeled compounds and SMIS are each at a concentration 
    of 12.5 g/mL.
        7.9  Secondary standards for calibration: Using stock solutions 
    (Section 7.7), prepare one secondary standard containing the 
    chlorovanillins and chlorsyringaldehydes listed in Table 1 in 
    acetone and a second secondary standard containing the remaining 
    chlorophenolics in methanol. The monochlorinated phenol, guaiacol, 
    and catechol are included at a concentration of 25 g/mL; 
    the trichlorinated catechols, tetrachlorinated guaiacol and 
    catechol, pentachlorophenol, 5,6-dichlorovanillin, and 2,6-
    dichlorosyringaldehyde are included at a concentration of 100 
    g/mL; and the remaining compounds are included at a 
    concentration of 50 g/mL, each in their respective 
    solutions.
        7.10  Instrument internal standard (IIS): Prepare a solution of 
    2,2'-difluorobiphenyl (DFB) at a concentration of 2.5 mg/mL in 
    hexane.
        7.11  DFTPP solution: Prepare a solution of DFTPP at 50 
    g/mL in acetone.
        7.12  Solutions for obtaining authentic mass spectra (Section 
    10.2): Prepare mixtures of compounds at concentrations which will 
    assure authentic spectra are obtained for storage in libraries.
        7.13  Preparation of calibration solutions.
        7.13.1  Into five 1000-mL aliquots of reagent water, spike 50, 
    100, 200, 500 and 1000 L of each of the two solutions in 
    Section 7.9. Spike 1.00 mL of each of the two labeled compound 
    spiking solutions (Section 7.8) into each of the five aliquots.
        7.13.2  Using the procedure in Section 11, derivatize and 
    extract each solution, and concentrate the extract to a final volume 
    of 0.50 mL. This will produce calibration solutions of nominal 5, 
    10, 20, 50, and 100 g/mL of the native chlorophenolics and 
    a constant concentration of 25 g/mL of each labeled 
    compound and the SMIS (assuming 100% derivatization and recovery). 
    As noted in Section 11.1.6, ascorbic acid is added to all samples of 
    final effluents to stabilize chlorocatechols, but is not added to 
    samples of pulp and paper in-process wastewaters. Therefore, it is 
    necessary to prepare separate sets of five initial calibration 
    standards with and without the addition of ascorbic acid. Also, in 
    the event that the laboratory is extracting final effluent samples 
    by both the stir-bar and separatory funnel procedures (see Section 
    11.3), initial calibration standards should be prepared by both 
    methods.
        7.13.3  These solutions permit the relative response (labeled to 
    unlabeled) and the response factor to be measured as a function of 
    concentration (Sections 10.4 and 10.5).
        7.13.4  The nominal 50 g/mL standard may also be used 
    as a calibration verification standard (see Section 9.6).
        7.14  Ongoing precision and recovery (OPR) standard: Used for 
    determination of initial (Section 9.3.2) and ongoing (Section 9.6) 
    precision and recovery. This solution is prepared by spiking 500 
    L of each the two solutions of the secondary calibration 
    standards (Section 7.9) and 1 mL of each of the two labeled compound 
    spiking solutions (Section 7.8) into 1000 mL of reagent water.
        7.15  Stability of solutions: All standard solutions (Sections 
    7.7 through 7.14) shall be analyzed within 48 hours of preparation 
    and on a monthly basis thereafter for signs of degradation. 
    Standards will remain acceptable if the peak area at the 
    quantitation m/z relative to the DFB internal standard remains 
    within 15% of the area obtained in the initial analysis 
    of the standard.
    
    8.0  Sample Collection, Preservation, and Storage
    
        8.1  Collect samples in glass containers (Section 6.1) following 
    conventional sampling practices (Reference 9). Aqueous samples are 
    collected in refrigerated bottles using automatic sampling 
    equipment.
        8.2  Sample preservation.
        8.2.1  Residual chlorine: If the sample contains residual 
    chlorine, the chlorine must be reduced to eliminate positive 
    interference resulting from continued chlorination reactions. 
    Immediately after sampling, test for residual chlorine using the 
    following
    
    [[Page 18738]]
    
    method or an alternative EPA method (Reference 10).
        8.2.1.1  Dissolve a few crystals of potassium iodide in the 
    sample and add three to five drops of a 1% starch solution. A blue 
    color indicates the presence of residual chlorine.
        8.2.1.2  If residual chlorine is found, add 1 mL of sodium 
    thiosulfate solution (Section 7.2.1) for each 2.5 ppm of free 
    chlorine or until the blue color disappears.
        8.2.2  Acidification: Adjust pH of all aqueous samples to <2 with="" sulfuric="" acid="" (section="" 7.1.2).="" failure="" to="" acidify="" samples="" may="" result="" in="" positive="" interferences="" from="" continued="" chlorination="" reactions.="" 8.2.3="" refrigeration:="" maintain="" sample="" temperature="" at="" 0="" to="" 4="" deg.c="" from="" time="" of="" collection="" until="" extraction,="" and="" maintain="" extracts="" at="" a="" temperature="" of="" 0="" to="" 4="" deg.="" c="" from="" time="" of="" extraction="" until="" analysis.="" 8.3="" collect="" a="" minimum="" of="" 2000="" ml="" of="" sample.="" this="" will="" provide="" a="" sufficient="" amount="" for="" all="" testing.="" smaller="" amounts="" may="" be="" collected="" if="" the="" stream="" is="" known="" to="" contain="" high="" levels="" of="" chlorophenolics.="" 8.4="" all="" samples="" must="" be="" acetylated="" and="" extracted="" within="" 30="" days="" of="" collection,="" and="" must="" be="" analyzed="" within="" 30="" days="" of="" acetylation.="" if="" labeled="" compound="" recoveries="" for="" a="" sample="" do="" not="" meet="" the="" acceptance="" criteria="" in="" table="" 5="" and="" the="" 30-day="" holding="" time="" is="" not="" met,="" a="" new="" sample="" must="" be="" collected.="" 9.0="" quality="" control="" 9.1="" each="" laboratory="" that="" uses="" this="" method="" is="" required="" to="" operate="" a="" formal="" quality="" assurance="" program="" (reference="" 8).="" the="" minimum="" requirements="" of="" this="" program="" consist="" of="" an="" initial="" demonstration="" of="" laboratory="" capability,="" analysis="" of="" samples="" spiked="" with="" labeled="" compounds="" to="" evaluate="" and="" document="" data="" quality,="" and="" analysis="" of="" standards="" and="" blanks="" as="" tests="" of="" continued="" performance.="" laboratory="" performance="" is="" compared="" to="" established="" performance="" criteria="" to="" determine="" if="" the="" results="" of="" analyses="" meet="" the="" performance="" characteristics="" of="" the="" method.="" 9.1.1="" dftpp="" spectrum="" validity="" shall="" be="" checked="" at="" the="" beginning="" of="" each="" eight-hour="" shift="" during="" which="" analyses="" are="" performed.="" this="" test="" is="" described="" in="" section="" 9.2.="" 9.1.2="" the="" laboratory="" shall="" make="" an="" initial="" demonstration="" of="" the="" ability="" to="" generate="" acceptable="" results="" with="" this="" method.="" this="" ability="" is="" established="" as="" described="" in="" section="" 9.3.="" 9.1.3="" the="" laboratory="" is="" permitted="" to="" modify="" this="" method="" to="" improve="" separations="" or="" lower="" the="" costs="" of="" measurements,="" provided="" all="" performance="" specifications="" are="" met.="" each="" time="" a="" modification="" is="" made="" to="" the="" method,="" the="" laboratory="" is="" required="" to="" repeat="" the="" procedures="" in="" sections="" 10.3="" and="" 9.3.2="" to="" demonstrate="" method="" performance.="" if="" the="" detection="" limits="" for="" the="" analytes="" in="" this="" method="" will="" be="" affected="" by="" the="" modification,="" the="" laboratory="" should="" demonstrate="" that="" each="" mdl="" (40="" cfr="" 136,="" appendix="" b)="" is="" less="" than="" or="" equal="" to="" the="" mdl="" in="" this="" method="" or="" one-third="" the="" regulatory="" compliance="" level,="" whichever="" is="" higher.="" 9.1.4="" the="" laboratory="" shall="" spike="" all="" samples="" with="" labeled="" compounds="" and="" the="" sample="" matrix="" internal="" standard="" (smis)="" to="" monitor="" method="" performance.="" this="" test="" is="" described="" in="" section="" 9.4.="" when="" results="" of="" these="" spikes="" indicate="" atypical="" method="" performance="" for="" samples,="" the="" samples="" are="" diluted="" to="" bring="" method="" performance="" within="" acceptable="" limits="" (section="" 13).="" 9.1.5="" analyses="" of="" blanks="" are="" required="" to="" demonstrate="" freedom="" from="" contamination.="" the="" procedures="" and="" criteria="" for="" analysis="" of="" a="" blank="" are="" described="" in="" section="" 9.5.="" 9.1.6="" the="" laboratory="" shall,="" on="" an="" ongoing="" basis,="" demonstrate="" through="" analysis="" of="" the="" ongoing="" precision="" and="" recovery="" standard="" (section="" 7.14)="" that="" the="" analysis="" system="" is="" in="" control.="" these="" procedures="" are="" described="" in="" section="" 9.6.="" 9.1.7="" the="" laboratory="" shall="" maintain="" records="" to="" define="" the="" quality="" of="" data="" that="" is="" generated.="" development="" of="" accuracy="" statements="" is="" described="" in="" section="" 9.4.4="" and="" 9.6.3.="" 9.2="" dftpp="" spectrum="" validity:="" inject="" 1="">L of the DFTPP 
    solution (Section 7.11) either separately or within a few seconds of 
    injection of the OPR standard (Section 9.6) analyzed at the 
    beginning of each shift. The criteria in Table 3 shall be met.
        9.3  Initial demonstration of laboratory capability.
        9.3.1  Method Detection Limit (MDL): To establish the ability to 
    detect the analytes in this method, the laboratory should determine 
    the MDL per the procedure in 40 CFR 136, Appendix B using the 
    apparatus, reagents, and standards that will be used in the practice 
    of this method. MDLs less than or equal to the MDLs in Table 2 
    should be achieved prior to the practice of this method.
        9.3.2  Initial precision and recovery (IPR): To establish the 
    ability to demonstrate control over the analysis system and to 
    generate acceptable precision and accuracy, the laboratory shall 
    perform the following operations:
        9.3.2.1  Derivatize, extract, concentrate, and analyze four 
    1000-mL aliquots of the ongoing precision and recovery standard 
    (OPR; Section 7.14), according to the procedure in Section 11. 
    Separate sets of IPR aliquots must be prepared with the addition of 
    ascorbic acid and without.
        9.3.2.2  Using results of the four analyses, compute the average 
    percent recovery (X) and the relative standard deviation of the 
    recovery (s) for each compound, by isotope dilution for pollutants 
    with a labeled analog, and by internal standard for pollutants with 
    no labeled analog and for the labeled compounds and the SMIS.
        9.3.2.3  For each compound, compare s and X with the 
    corresponding limits for initial precision and recovery in Table 5. 
    If s and X for all compounds meet the acceptance criteria, system 
    performance is acceptable and analysis of blanks and samples may 
    begin. If, however, any individual s exceeds the precision limit or 
    any individual X falls outside the range for recovery, system 
    performance is unacceptable for that compound. In this event, 
    correct the problem and repeat the test (Section 9.3.2).
        9.4  Labeled compound recovery: The laboratory shall spike all 
    samples with labeled compounds and the sample matrix internal 
    standard (SMIS) to assess method performance on the sample matrix.
        9.4.1  Analyze each sample according to the method beginning in 
    Section 11.
        9.4.2  Compute the percent recovery (P) of the labeled compounds 
    and the SMIS using the internal standard method (Section 14.3) with 
    2,2'-difluorobiphenyl as the reference compound.
        9.4.3  Compare the labeled compound and SMIS recovery for each 
    compound with the corresponding limits in Table 5. If the recovery 
    of any compound falls outside its warning limit, method performance 
    is unacceptable for that compound in that sample. Therefore, the 
    sample is complex. The sample is diluted and reanalyzed per Section 
    13.
        9.4.4  As part of the QA program for the laboratory, it is 
    suggested, but not required, that method accuracy for samples be 
    assessed and records maintained. After the analysis of five samples 
    for which the labeled compounds pass the tests in Section 9.4.3, 
    compute the average percent recovery (P) and the standard deviation 
    of the percent recovery (sp) for the labeled compounds only. Express 
    the accuracy assessment as a percent recovery interval from P-2sp to 
    P + 2sp for each matrix. For example, if P = 90% and sp = 10%, the 
    accuracy interval is expressed as 70 to 110%. Update the accuracy 
    assessment for each compound on a regular basis (e.g., after each 20 
    to 30 new accuracy measurements).
        9.5  Blanks: Reagent water blanks are analyzed to demonstrate 
    freedom from contamination.
        9.5.1  Extract and concentrate a 1000-mL reagent water blank 
    with each sample batch (samples started through the extraction 
    process on the same eight-hour shift, to a maximum of 20 samples). 
    Blanks associated with samples to which ascorbic acid is added must 
    be prepared with ascorbic acid, and blanks associated with samples 
    to which ascorbic acid is not added must be prepared without 
    ascorbic acid. Analyze the blank immediately after analysis of the 
    OPR (Section 7.14) to demonstrate freedom from contamination.
        9.5.2  If any of the compounds of interest (Table 1) or any 
    potentially interfering compound is found in an aqueous blank at 
    greater than 5g/L (assuming a response factor of one 
    relative to the sample matrix internal standard for compounds not 
    listed in Table 1), analysis of samples is halted until the source 
    of contamination is eliminated and a blank shows no evidence of 
    contamination at this level.
        9.6  Calibration verification and ongoing precision and 
    recovery: At the beginning of each eight-hour shift during which 
    analyses are performed, analytical system performance is verified 
    for all compounds. Analysis of DFTPP (Section 9.2) and the nominal 
    50g/mL OPR (Section 11.1.5) is used to verify all 
    performance criteria. Adjustment and/or recalibration, per Section 
    10, shall be performed until all performance criteria are met. Only 
    after all performance criteria are met may samples and blanks be 
    analyzed.
        9.6.1  Analyze the extract of the OPR (Section 11.1.5) at the 
    beginning of each eight-hour shift and prior to analysis of
    
    [[Page 18739]]
    
    samples from the same batch. Alternatively, a separate calibration 
    verification may be performed using an aliquot of the midpoint 
    calibration standard from Section 7.13 (with a nominal concentration 
    of 50 g/mL). This alternative may be used to check 
    instrument performance on failure of an OPR, or when samples 
    extracted with an OPR aliquot are not analyzed within the same 
    eight-hour analysis shift.
        9.6.1.1  Retention times: The absolute retention time of 2,2'-
    difluorobiphenyl shall be within the range of 765 to 885 seconds, 
    and the relative retention times of all pollutants and labeled 
    compounds shall fall within the limits given in Table 2.
        9.6.1.2  GC resolution: The valley height between 4,6-
    dichloroguaiacol and 3,4-dichloroguaiacol at m/z 192 shall not 
    exceed 10% of the height of the taller of the two peaks.
        9.6.1.3  Multiple peaks: Each compound injected shall give a 
    single, distinct GC peak.
        9.6.2  Compute the percent recovery of each pollutant (Table 1) 
    by isotope dilution (Section 10.4) for those compounds that have 
    labeled analogs. Compute the percent recovery of each pollutant that 
    has no labeled analog by the internal standard method (Section 
    10.5), using the 3,4,5-trichlorophenol (SMIS) as the internal 
    standard. Compute the percent recovery of the labeled compounds and 
    the SMIS by the internal standard method, using the 2,2'-
    difluorobiphenyl as the internal standard.
        9.6.2.1  For each compound, compare the recovery with the limits 
    for ongoing precision and recovery in Table 5. If all compounds meet 
    the acceptance criteria, system performance is acceptable and 
    analysis of blanks and samples may proceed. If, however, any 
    individual recovery falls outside of the range given, system 
    performance is unacceptable for that compound. In this event, there 
    may be a problem with the GCMS or with the derivatization/
    extraction/concentration systems.
        9.6.2.2  GCMS system: To determine if the failure of the OPR 
    test (Section 9.6.2.1) is due to instrument drift, analyze the 
    current calibration verification extract (Section 7.13.4), calculate 
    the percent recoveries of all compounds, and compare with the OPR 
    recovery limits in Table 5. If all compounds meet these criteria, 
    GCMS performance/stability is verified, and the failure of the OPR 
    analysis is attributed to problems in the derivatization/extraction/
    concentration of the OPR. In this case, analysis of the sample 
    extracts may proceed. However, failure of any of the recovery 
    criteria in the analysis of a sample extract requires 
    rederivatization of that sample (Sections 13.3.1 and 13.3.2). If, 
    however, the performance/stability of the GCMS is not verified by 
    analysis of the calibration verification extract, the GCMS requires 
    recalibration and all extracts associated with the failed OPR must 
    be reanalyzed.
        9.6.3  Add results that pass the specifications in Section 
    9.6.2.1 to initial and previous ongoing data for each compound. 
    Update QC charts to form a graphic representation of continued 
    laboratory performance. Develop a statement of laboratory accuracy 
    for each pollutant and labeled compound in each matrix type (reagent 
    water, C-stage filtrate, E-stage filtrate, final effluent, etc.) by 
    calculating the average percent recovery (R) and the standard 
    deviation of percent recovery (sr). Express the accuracy as a 
    recovery interval from R- 2sr to R + 2sr. For example, if R = 95% 
    and sr = 5%, the accuracy is 85 to 105%.
        9.7  The specifications contained in this method can be met if 
    the apparatus used is calibrated properly, then maintained in a 
    calibrated state. The standards used for calibration (Section 10) 
    and for initial (Section 9.3.2) and ongoing (Section 9.6) precision 
    and recovery should be identical, so that the most precise results 
    will be obtained. The GCMS instrument in particular will provide the 
    most reproducible results if dedicated to the settings and 
    conditions required for the analyses of chlorophenolics by this 
    method.
        9.8  Depending on specific program requirements, field 
    replicates may be collected to determine the precision of the 
    sampling technique, and spiked samples may be required to determine 
    the accuracy of the analysis when the internal standard method is 
    used.
    
    10.0  Calibration and Standardization
    
        10.1  Assemble the GCMS and establish the operating conditions 
    in Section 12. Analyze standards per the procedure in Section 12 to 
    demonstrate that the analytical system meets the minimum levels in 
    Table 2, and the mass-intensity criteria in Table 3 for 50 ng DFTPP.
        10.2  Mass-spectral libraries: Detection and identification of 
    compounds of interest are dependent upon spectra stored in user-
    created libraries.
        10.2.1  Obtain a mass spectrum of the acetyl derivative of each 
    chlorophenolic compound (pollutant, labeled compound, and the sample 
    matrix internal standard) by derivatizing and analyzing an authentic 
    standard either singly or as part of a mixture in which there is no 
    interference between closely eluting components. That only a single 
    compound is present is determined by examination of the spectrum. 
    Fragments not attributable to the compound under study indicate the 
    presence of an interfering compound.
        10.2.2  Adjust the analytical conditions and scan rate (for this 
    test only) to produce an undistorted spectrum at the GC peak 
    maximum. An undistorted spectrum will usually be obtained if five 
    complete spectra are collected across the upper half of the GC peak. 
    Software algorithms designed to ``enhance'' the spectrum may 
    eliminate distortion, but may also eliminate authentic m/z's or 
    introduce other distortion.
        10.2.3  The authentic reference spectrum is obtained under DFTPP 
    tuning conditions (Section 10.1 and Table 3) to normalize it to 
    spectra from other instruments.
        10.2.4  The spectrum is edited by removing all peaks in the m/z 
    42 to 45 range, and saving the five most intense mass spectral peaks 
    and all other mass spectral peaks greater than 10% of the base peak 
    (excluding the peaks in the m/z 42 to 45 range). The spectrum may be 
    further edited to remove common interfering m/z's. The spectrum 
    obtained is stored for reverse search and for compound confirmation. 
    10.3 Minimum level: Demonstrate that the chlorophenolics are 
    detectable at the minimum level (per all criteria in Section 14). 
    The nominal 5 g/mL calibration standard (Section 7.13) can 
    be used to demonstrate this performance.
        10.4  Calibration with isotope dilution: Isotope dilution is 
    used when (1) labeled compounds are available, (2) interferences do 
    not preclude its use, and (3) the quantitation m/z (Table 4) 
    extracted ion-current profile (EICP) area for the compound is in the 
    calibration range. Alternative labeled compounds and quantitation m/
    z's may be used based on availability. If any of the above 
    conditions preclude isotope dilution, the internal standard 
    calibration method (Section 10.5) is used.
        10.4.1  A calibration curve encompassing the concentration range 
    is prepared for each compound to be determined. The relative 
    response (pollutant to labeled) vs. concentration in standard 
    solutions is plotted or computed using a linear regression. The 
    example in Figure 1 shows a calibration curve for phenol using 
    phenol-d5 as the isotopic diluent. Also shown are the 
    10% error limits (dotted lines). Relative response (RR) 
    is determined according to the procedures described below. A minimum 
    of five data points are employed for calibration.
        10.4.2  The relative response of a pollutant to its labeled 
    analog is determined from isotope ratio values computed from 
    acquired data. Three isotope ratios are used in this process:
    
    Rx = the isotope ratio measured for the pure pollutant.
    Ry = the isotope ratio measured for the labeled compound.
    Rm = the isotope ratio of an analytical mixture of 
    pollutant and labeled compounds.
    
        The m/z's are selected such that Rx>Ry. If 
    Rm is not between 2Ry and 0.5Rx, 
    the method does not apply and the sample is analyzed by the internal 
    standard method.
    10.4.3  Capillary columns sometimes separate the pollutant-labeled 
    pair when deuterium labeled compounds are used, with the labeled 
    compound eluted first (Figure 2). For this case,
    
    [[Page 18740]]
    
    [GRAPHIC] [TIFF OMITTED] TR15AP98.028
    
    
        10.4.4  When the pollutant-labeled pair is not separated (as 
    occurs with carbon-13-labeled compounds), or when another labeled 
    compound with interfering spectral masses overlaps the pollutant (a 
    case which can occur with isomeric compounds), it is necessary to 
    determine the contributions of the pollutant and labeled compound to 
    the respective EICP areas. If the peaks are separated well enough to 
    permit the data system or operator to remove the contributions of 
    the compounds to each other, the equations in Section 10.4.3 apply. 
    This usually occurs when the height of the valley between the two GC 
    peaks at the same m/z is less than 70 to 90% of the height of the 
    shorter of the two peaks. If significant GC and spectral overlap 
    occur, RR is computed using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.029
    
    Where:
    
    Rx is measured as shown in figure 3A,
    Ry is measured as shown in figure 3B,
    Rm is measured as shown in figure 3C.
    
        For example, Rx = 46100/4780 = 9.644; Ry = 
    2650/43600 = 0.0608; Rm = 49200/48300 = 1.1019; thus, RR 
    = 1.114. 10.4.5 To calibrate the analytical system by isotope 
    dilution, analyze a 1-L aliquot of each of the calibration 
    standards (Section 7.13) using the procedure in Section 12. Compute 
    the RR at each concentration.
        10.4.6  Linearity: If the ratio of relative response to 
    concentration for any compound is constant (less than 20% 
    coefficient of variation) over the five-point calibration range, an 
    averaged relative response/concentration ratio may be used for that 
    compound; otherwise, the complete calibration curve for that 
    compound shall be used over the five-point calibration range.
        10.5  Calibration by internal standard: The method contains two 
    types of internal standards, the sample matrix internal standard 
    (SMIS) and the instrument internal standard (IIS), and they are used 
    for different quantitative purposes. The 3,4,5-trichlorophenol 
    sample matrix internal standard (SMIS) is used for measurement of 
    all pollutants with no labeled analog and when the criteria for 
    isotope dilution (Section 10.4) cannot be met. The 2,2'-
    difluorobiphenyl instrument internal standard (IIS) is used for 
    determination of the labeled compounds and the SMIS. The results are 
    used for intralaboratory statistics (Sections 9.4.4 and 9.6.3).
        10.5.1  Response factors: Calibration requires the determination 
    of response factors (RF) for both the pollutants with no labeled 
    analog and for the labeled compounds and the SMIS. The response 
    factor is defined by the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.030
    
    Where:
    
    As=the area of the characteristic mass for the compound 
    in the daily standard.
    Ais=the area of the characteristic mass for the internal 
    standard.
    Cis=the concentration of the internal standard 
    (g/mL).
    Cs=is the concentration of the compound in the 
    calibration standard (g/mL).
    
        When this equation is used to determine the response factors for 
    pollutant compounds without labeled analogs, use the area 
    (Ais) and concentration (Cis) of 3,4,5-
    trichlorophenol (SMIS) as the internal standard. When this equation 
    is used to determine the response factors for the labeled analogs 
    and the SMIS, use the area (Ais) and concentration 
    (Cis) of 2,2'-difluorobiphenyl as the internal standard.
        10.5.2  The response factor is determined for at least five 
    concentrations appropriate to the response of each compound (Section 
    7.13); nominally, 5, 10, 20, 50, and 100 g/mL. The amount 
    of SMIS added to each solution is the same (25 g/mL) so 
    that Cis remains constant. Likewise, the concentration of 
    IIS is constant in each solution. The area ratio (As/
    Ais) is plotted versus the concentration ratio 
    (Cs/Cis) for each compound in the standard to 
    produce a calibration curve.
        10.5.3  Linearity: If the response factor (RF) for any compound 
    is constant (less than 35% coefficient of variation) over the five-
    point calibration range, an averaged response factor may be used for 
    that compound; otherwise, the complete calibration curve for that 
    compound shall be used over the five-point range.
        10.6  Combined calibration: By using calibration solutions 
    (Section 7.13) containing the pollutants, labeled compounds, and the 
    internal standards, a single set of analyses can be used to produce 
    calibration curves for the isotope dilution and internal standard 
    methods. These curves are verified each shift (Section 9) by 
    analyzing the OPR standard, or an optional calibration verification 
    (VER) standard. Recalibration is required only if OPR criteria 
    (Section 9.6 and Table 5) cannot be met.
    
    11.0  Sample Derivatization, Extraction, and Concentration
    
        The procedure described in this section uses a stir-bar in a 
    beaker for the derivatization. The extraction procedures applied to 
    samples depend on the type of sample being analyzed. Extraction of 
    samples from in-process wastewaters is performed using a separatory 
    funnel procedure. All calibrations, IPR, OPR, and blank analyses 
    associated with in-process wastewater samples must be performed by 
    the separatory funnel procedure.
        Extraction of samples of final effluents and raw water may be 
    performed using either the stir-bar procedure or the separatory 
    funnel procedure. However, all calibrations, IPR, OPR, blank, and 
    sample analyses must be performed using the same procedure. Both 
    procedures are described below.
        11.1  Preparation of all sample types for stir-bar 
    derivatization.
        11.1.1  Allow sample to warm to room temperature.
        11.1.2  Immediately prior to measuring, shake sample vigorously 
    to insure homogeneity.
        11.1.3  Measure 1000 mL (10 mL) of sample into a 
    clean 2000-mL beaker. Label the beaker with the sample number.
        11.1.4  Dilute aliquot(s).
        11.1.4.1  Complex samples: For samples that are expected to be 
    difficult to derivatize, concentrate, or are expected to overload 
    the GC column or mass spectrometer, measure an additional 100 mL 
    (1 mL) into a clean 2000-mL beaker and dilute to a final 
    volume of 1000-mL (50 mL) with reagent water. Label with 
    the sample number and as the dilute aliquot. However, to ensure 
    adequate sensitivity, a 1000-mL aliquot must always be prepared and 
    analyzed.
        11.1.4.2  Pulp and paper industry samples: For in-process 
    streams such as E-stage and C-stage filtrates and other in-process 
    wastewaters, it may be necessary to prepare an aliquot at an 
    additional level of dilution. In this case, dilute 10 mL 
    (0.1 mL) of sample to 1000-mL (50 mL).
        11.1.5  QC aliquots: For a batch of samples of the same type to 
    be extracted at the same time (to a maximum of 20), place two 1000-
    mL (10 mL) aliquots of reagent water in clean 2000-mL 
    beakers. Label one beaker as the blank and the other as the ongoing 
    precision and recovery (OPR) aliquot. Because final effluent samples 
    are treated with ascorbic acid and in-process wastewater samples are 
    not (see Section 11.1.6), prepare an OPR aliquot and a blank for the 
    final effluent and a separate pair for the in-process samples. Treat 
    these QC aliquots in the same fashion as the associated samples, 
    adding
    
    [[Page 18741]]
    
    ascorbic acid to the pair associated with the final effluents, and 
    not adding ascorbic acid to the pair associated with the in-process 
    samples.
        11.1.6  Ascorbic acid: Added to stabilize chlorocatechols. 
    However, for pulp and paper industry in-process streams and other 
    in-process wastewaters, the addition of ascorbic acid may convert 
    chloro-o-quinones to catechols if these quinones are present. 
    Separate calibration curves must be prepared with and without the 
    addition of ascorbic acid (Section 7.13.2).
        11.1.6.1  Spike 5 to 6 mL of the ascorbic acid solution (Section 
    7.2.2) into each final effluent sample, and the associated 
    calibration standards, IPR and OPR aliquots, and blank.
        11.1.6.2  For pulp and paper industry C-stage filtrates, E-stage 
    filtrates, and untreated effluents, omit the ascorbic acid to 
    prevent the conversion of chloro-o-quinones to catechols. Prepare 
    calibration standards, IPR and OPR aliquots, and blanks associated 
    with these samples without ascorbic acid as well.
        11.1.7  Spike 1000 L of the labeled compound spiking 
    solution (Section 7.8) into the sample and QC aliquots.
        11.1.8  Spike 500 L of the nominal 50 g/mL 
    calibration solution (Section 7.13.4) into the OPR aliquot.
        11.1.9  Adjust the pH of the sample aliquots to between 7.0 and 
    7.1. For calibration standards, IPR and OPR aliquots, and blanks, pH 
    adjustment is not required.
        11.1.10  Equilibrate all sample and QC solutions for 
    approximately 15 minutes, with occasional stirring.
        11.2  Derivatization: Because derivatization must proceed 
    rapidly, particularly upon the addition of the 
    K2CO3 buffer, it is necessary to work with one 
    sample at a time until the derivatization step (Section 11.2.3) is 
    complete.
        11.2.1  Place a beaker containing a sample or QC aliquot on the 
    magnetic stirrer in a fume hood, drop a clean stirring bar into the 
    beaker, and increase the speed of the stirring bar until the vortex 
    is drawn to the bottom of the beaker.
        11.2.2  Measure 25 to 26 mL of 
    K2CO3 buffer into a graduated cylinder or 
    other container and 25 to 26 mL of acetic acid into another.
        11.2.3  Add the K2CO3 buffer to the sample 
    or QC aliquot, immediately (within one to three seconds) add the 
    acetic anhydride, and stir for three to five minutes to complete the 
    derivatization.
        11.3  Extraction: Two procedures are described below for the 
    extraction of derivatized samples. The choice of extraction 
    procedure will depend on the sample type. For final effluent 
    samples, either of two procedures may be utilized for extraction of 
    derivatized samples. For samples of in-process wastewaters, the 
    separatory funnel extraction procedure must be used.
    
        Note: Whichever procedure is employed, the same extraction 
    procedure must be used for calibration standards, IPR aliquots, OPR 
    aliquots, blanks, and the associated field samples.
    
        11.3.1  Stir-bar extraction of final effluents.
        11.3.1.1  Add 200 mL (20 mL) of hexane to the beaker 
    and stir for three to five minutes, drawing the vortex to the bottom 
    of the beaker.
        11.3.1.2  Stop the stirring and drain the hexane and a portion 
    of the water into a 500-to 1000-mL separatory funnel. Allow the 
    layers to separate.
        11.3.1.3  Drain the aqueous layer back into the beaker.
        11.3.1.4  The formation of emulsions can be expected in any 
    solvent extraction procedure. If an emulsion forms, the laboratory 
    must take steps to break the emulsion before proceeding. Mechanical 
    means of breaking the emulsion include the use of a glass stirring 
    rod, filtration through glass wool, and other techniques. For 
    emulsions that resist these techniques, centrifugation is nearly 
    100% effective.
        If centrifugation is employed to break the emulsion, drain the 
    organic layer into a centrifuge tube, cap the tube, and centrifuge 
    for two to three minutes or until the phases separate. If the 
    emulsion cannot be completely broken, collect as much of the organic 
    phase as possible, and measure and record the volume of the organic 
    phase collected.
        If all efforts to break the emulsion fail, including 
    centrifugation, and none of the organic phase can be collected, 
    proceed with the dilute aliquot (Section 11.1.4.2). However, use of 
    the dilute aliquot will sacrifice the sensitivity of the method, and 
    may not be appropriate in all cases.
        11.3.1.5  Drain the organic layer into a Kuderna-Danish (K-D) 
    apparatus equipped with a 10-mL concentrator tube. Label the K-D 
    apparatus. It may be necessary to pour the organic layer through a 
    funnel containing anhydrous sodium sulfate to remove any traces of 
    water from the extract.
        11.3.1.6  Repeat the extraction (Section 11.3.1.1 through 
    11.3.1.5) two more times using another 200-mL of hexane for each 
    extraction, combining the extracts in the K-D apparatus.
        11.3.1.7  Proceed with concentration of the extract, as 
    described in Section 11.4.
        11.3.2  Separatory funnel extraction of either final effluents 
    or in-process wastewaters.
        11.3.2.1  Transfer the derivatized sample or QC aliquot to a 2-L 
    separatory funnel.
        11.3.2.2  Add 200 mL (20 mL) of hexane to the 
    separatory funnel. Cap the funnel and extract the sample by shaking 
    the funnel for two to three minutes with periodic venting.
        11.3.2.3  Allow the organic layer to separate from the water 
    phase for a minimum of 10 minutes.
        11.3.2.4  Drain the lower aqueous layer into the beaker used for 
    derivatization (Section 11.2), or into a second clean 2-L separatory 
    funnel. Transfer the solvent to a 1000-mL K-D flask. It may be 
    necessary to pour the organic layer through a funnel containing 
    anhydrous sodium sulfate to remove any traces of water from the 
    extract.
        11.3.2.5  The formation of emulsions can be expected in any 
    solvent extraction procedure. If an emulsion forms, the laboratory 
    must take steps to break the emulsion before proceeding. Mechanical 
    means of breaking the emulsion include the use of a glass stirring 
    rod, filtration through glass wool, and other techniques. For 
    emulsions that resist these techniques, centrifugation may be 
    required.
        If centrifugation is employed to break the emulsion, drain the 
    organic layer into a centrifuge tube, cap the tube, and centrifuge 
    for two to three minutes or until the phases separate. If the 
    emulsion cannot be completely broken, collect as much of the organic 
    phase as possible, and measure and record the volume of the organic 
    phase collected. If all efforts to break the emulsion, including 
    centrifugation, fail and none of the organic phase can be collected, 
    proceed with the dilute aliquot (Section 11.1.4.2). However, use of 
    the dilute aliquot will sacrifice the sensitivity of the method, and 
    may not be appropriate in all cases.
        11.3.2.6  If drained into a beaker, transfer the aqueous layer 
    to the 2-L separatory funnel (Section 11.3.2.1). Perform a second 
    extraction using another 200 mL of fresh solvent.
        11.3.2.7  Transfer the extract to the 1000-mL K-D flask in 
    Section 11.3.2.4.
        11.3.2.8  Perform a third extraction in the same fashion as 
    above.
        11.3.2.9  Proceed with concentration of the extract, as 
    described in Section 11.4.
        11.4  Macro concentration: Concentrate the extracts in separate 
    1000-mL K-D flasks equipped with 10-mL concentrator tubes. Add one 
    to two clean boiling chips to the flask and attach a three-ball 
    macro-Snyder column. Prewet the column by adding approximately 1 mL 
    of hexane through the top. Place the K-D apparatus in a hot water 
    bath so that the entire lower rounded surface of the flask is bathed 
    with steam. Adjust the vertical position of the apparatus and the 
    water temperature as required to complete the concentration in 15 to 
    20 minutes. At the proper rate of distillation, the balls of the 
    column will actively chatter but the chambers will not flood. When 
    the liquid has reached an apparent volume of 1 mL, remove the K-D 
    apparatus from the bath and allow the solvent to drain and cool for 
    at least 10 minutes. Remove the Snyder column and rinse the flask 
    and its lower joint into the concentrator tube with 1 to 2 mL of 
    hexane. A 5-mL syringe is recommended for this operation.
        11.5  Micro-concentration: Final concentration of the extracts 
    may be accomplished using either a micro-Snyder column or nitrogen 
    evaporation.
        11.5.1  Micro-Snyder column: Add a clean boiling chip and attach 
    a two-ball micro-Snyder column to the concentrator tube. Prewet the 
    column by adding approximately 0.5 mL hexane through the top. Place 
    the apparatus in the hot water bath. Adjust the vertical position 
    and the water temperature as required to complete the concentration 
    in 5 to 10 minutes. At the proper rate of distillation, the balls of 
    the column will actively chatter but the chambers will not flood. 
    When the liquid reaches an apparent volume of approximately 0.2 mL, 
    remove the apparatus from the water bath and allow to drain and cool 
    for at least 10 minutes. Remove the micro-Snyder column and rinse 
    its lower joint into the concentrator tube with approximately 0.2 mL 
    of hexane. Adjust to a final volume of 0.5 mL.
        11.5.2  Nitrogen evaporation: Transfer the concentrator tube to 
    a nitrogen evaporation
    
    [[Page 18742]]
    
    device and direct a gentle stream of clean dry nitrogen into the 
    concentrator. Rinse the sides of the concentrator tube with small 
    volumes of hexane, and concentrate the extract to a final volume of 
    0.5 mL.
        11.6  Spike each extract with 10 L of the 2,2'-
    difluorobiphenyl IIS (Section 7.10) and transfer the concentrated 
    extract to a clean screw-cap vial using hexane to rinse the 
    concentrator tube. Seal the vial with a PTFE-lined lid, and mark the 
    level on the vial. Label with the sample number and store in the 
    dark at -20 to -10  deg.C until ready for analysis.
    
    12.0  GCMS Analysis
    
        12.1  Establish the following operating conditions:
    
    Carrier gas flow: Helium at 30 cm/sec at 50  deg.C
    Injector temperature: 300  deg.C
    Initial temperature: 50  deg.C
    Temperature program: 8  deg.C/min to 270  deg.C
    Final hold: Until after 2,6-dichlorosyringaldehyde elutes
    
        Adjust the GC conditions to meet the requirements in Section 
    9.6.1.1 and Table 2 for analyte separation and sensitivity. Once 
    optimized, the same GC conditions must be used for the analysis of 
    all standards, blanks, IPR and OPR aliquots, and samples.
        12.2  Bring the concentrated extract (Section 11.6) or standard 
    (Sections 7.13 and 7.14) to room temperature and verify that any 
    precipitate has redissolved. Verify the level on the extract 
    (Sections 7.13, 7.14, and 11.6) and bring to the mark with solvent 
    if required.
        12.3  Inject a 1-L volume of the standard solution or 
    extract using on-column or splitless injection. For 0.5 mL extracts, 
    this 1-L injection volume will contain 50 ng of the DFB 
    internal standard. If an injection volume other than 1 L is 
    used, that volume must contain 50 ng of DFB.
        12.4  Start the GC column temperature ramp upon injection. Start 
    MS data collection after the solvent peak elutes. Stop data 
    collection after the 2,6-dichlorosyringaldehyde peak elutes. Return 
    the column to the initial temperature for analysis of the next 
    sample.
    
    13.0  Analysis of Complex Samples
    
        Some samples may contain high levels (>1000 g/L) of the 
    compounds of interest, interfering compounds, and/or other phenolic 
    materials. Some samples will not concentrate to 0.5 mL (Section 
    11.5); others will overload the GC column and/or mass spectrometer; 
    others may contain amounts of phenols that may exceed the capacity 
    of the derivatizing agent.
        13.1  Analyze the dilute aliquot (Section 11.1.4) when the 
    sample will not concentrate to 0.5 mL. If a dilute aliquot was not 
    extracted, and the sample holding time (Section 8.4) has not been 
    exceeded, dilute an aliquot of sample with reagent water, and 
    derivatize and extract it (Section 11.1.4). Otherwise, dilute the 
    extract (Section 14.7.3) and quantitate it by the internal standard 
    method (Section 14.3).
        13.2  Recovery of the 2,2'-difluorobiphenyl instrument internal 
    standard: The EICP area of the internal standard should be within a 
    factor of two of the area in the OPR or VER standard (Section 9.6). 
    If the absolute areas of the labeled compounds and the SMIS are 
    within a factor of two of the respective areas in the OPR or VER 
    standard, and the DFB internal standard area is less than one-half 
    of its respective area, then internal standard loss in the extract 
    has occurred. In this case, analyze the extract from the dilute 
    aliquot (Section 11.1.4).
        13.3  Recovery of labeled compounds and the sample matrix 
    internal standard (SMIS): SMIS and labeled compound recovery 
    specifications have been developed for samples with and without the 
    addition of ascorbic acid. Compare the recoveries to the appropriate 
    limits in Table 5.
        13.3.1  If SMIS or labeled compound recoveries are outside the 
    limits given in Table 5 and the associated OPR analysis meets the 
    recovery criteria, the extract from the dilute aliquot (Section 
    11.1.4) is analyzed as in Section 14.7.
        13.3.2  If labeled compound or SMIS recovery is outside the 
    limits given in Table 5 and the associated OPR analysis did not meet 
    recovery criteria, a problem in the derivatization/extraction/
    concentration of the sample is indicated, and the sample must be 
    rederivatized and reanalyzed.
    
    14.0  Data Analysis and Calculations
    
        14.1  Qualitative determination: Identification is accomplished 
    by comparison of data from analysis of a sample or blank with data 
    stored in the mass spectral libraries. Identification of a compound 
    is confirmed when the following criteria are met:
        14.1.1  The signals for m/z 43 (to indicate the presence of the 
    acetyl derivative) and all characteristic m/z's stored in the 
    spectral library (Section 10.2.4) shall be present and shall 
    maximize within the same two consecutive scans.
        14.1.2  Either (1) the background corrected EICP areas, or (2) 
    the corrected relative intensities of the mass spectral peaks at the 
    GC peak maximum shall agree within a factor of two (0.5 to 2 times) 
    for all m/z's stored in the library.
        14.1.3  The relative retention time shall be within the window 
    specified in Table 2.
        14.1.4  The m/z's present in the mass spectrum from the 
    component in the sample that are not present in the reference mass 
    spectrum shall be accounted for by contaminant or background ions. 
    If the mass spectrum is contaminated, an experienced spectrometrist 
    (Section 1.4) shall determine the presence or absence of the 
    compound.
        14.2  Quantitative determination by isotope dilution: By adding 
    a known amount of a labeled compound to every sample prior to 
    derivatization and extraction, correction for recovery of the 
    pollutant can be made because the pollutant and its labeled analog 
    exhibit the same effects upon derivatization, extraction, 
    concentration, and gas chromatography. Relative response (RR) values 
    for sample mixtures are used in conjunction with calibration curves 
    described in Section 10.4 to determine concentrations directly, so 
    long as labeled compound spiking levels are constant. For the phenol 
    example given in Figure 1 (Section 10.4.1), RR would be equal to 
    1.114. For this RR value, the phenol calibration curve given in 
    Figure 1 indicates a concentration of 27 g/mL in the sample 
    extract (Cex).
        14.2.1  Compute the concentration in the extract using the 
    response ratio determined from calibration data (Section 10.4) and 
    the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.031
    
    Where:
    
    Cex = concentration of the pollutant in the extract.
    An = area of the characteristic m/z for the pollutant.
    Cl = concentration of the labeled compound in the 
    extract.
    Al = area of the characteristic m/z for the labeled 
    compound.
    RR = response ratio from the initial calibration.
    
    
        14.2.2  For the IPR (Section 9.3.2) and OPR (Section 9.6), 
    compute the percent recovery of each pollutant using the equation in 
    Section 14.6. The percent recovery is used for the evaluation of 
    method and laboratory performance, in the form of IPR (Section 
    9.3.2) and OPR (Section 9.6).
        14.3  Quantitative determination by internal standard: Compute 
    the concentration using the response factor determined from 
    calibration data (Section 10.5) and the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.032
    
    Where:
    
    Cex = concentration of the pollutant in the extract.
    As = area of the characteristic m/z for the pollutant.
    Cis = concentration of the internal standard in the 
    extract (see note below).
    Ais = area of the characteristic m/z for the internal 
    standard.
    RF = response factor from the initial calibration.
    
        Note: When this equation is used to compute the extract 
    concentrations of native compounds without labeled analogs, use the 
    area (Ais) and concentration (Cis) of 3,4,5-
    trichlorophenol (SMIS) as the internal standard.
    
        For the IPR (Section 9.3.2) and OPR (Section 9.6), compute the 
    percent recovery using the equation in Section 14.6.
    
        Note: Separate calibration curves will be required for samples 
    with and without the addition of ascorbic acid, and also for both 
    extraction procedures (stir-bar and separatory funnel) where 
    applicable.
    
        14.4  Compute the concentration of the labeled compounds and the 
    SMIS using the equation in Section 14.3, but using the area and 
    concentration of the 2,2'-difluorobiphenyl as the internal standard, 
    and the area of the labeled compound or SMIS as As.
        14.5  Compute the concentration of each pollutant compound in 
    the sample using the following equation:
    
    [[Page 18743]]
    
    [GRAPHIC] [TIFF OMITTED] TR15AP98.033
    
    
    Where:
    
    Cs = Concentration of the pollutant in the sample.
    Cex = Concentration of the pollutant in the extract.
    Vex = Volume of the concentrated extract (typically 0.5 
    mL).
    Vo = Volume of the original sample in liters.
    
        14.6  Compute the recovery of each labeled compound and the SMIS 
    as the ratio of concentration (or amount) found to the concentration 
    (or amount) spiked, using the following equation:
    [GRAPHIC] [TIFF OMITTED] TR15AP98.034
    
        These percent recoveries are used to assess method performance 
    according to Sections 9 and 13.
        14.7  If the EICP area at the quantitation m/z for any compound 
    exceeds the calibration range of the system, three approaches are 
    used to obtain results within the calibration range.
        14.7.1  If the recoveries of all the labeled compounds in the 
    original sample aliquot meet the limits in Table 5, then the extract 
    of the sample may be diluted by a maximum of a factor of 10, and the 
    diluted extract reanalyzed.
        14.7.2  If the recovery of any labeled compound is outside its 
    limits in Table 5, or if a tenfold dilution of the extract will not 
    bring the pollutant within the calibration range, then extract and 
    analyze a dilute aliquot of the sample (Section 11). Dilute 100 mL, 
    10 mL, or an appropriate volume of sample to 1000 mL with reagent 
    water and extract per Section 11.
        14.7.3  If the recoveries of all labeled compounds in the 
    original sample aliquot (Section 14.7.1) meet the limits in Table 5, 
    and if the sample holding time has been exceeded, then the original 
    sample extract is diluted by successive factors of 10, the DFB 
    internal standard is added to give a concentration of 50 g/
    mL in the diluted extract, and the diluted extract is analyzed. 
    Quantitation of all analytes is performed using the DFB internal 
    standard.
        14.7.4  If the recoveries of all labeled compounds in the 
    original sample aliquot (Section 14.7.1) or in the dilute aliquot 
    (Section 14.7.2) (if a dilute aliquot was analyzed) do not meet the 
    limits in Table 5, and if the holding time has been exceeded, re-
    sampling is required.
        14.8  Results are reported for all pollutants, labeled 
    compounds, and the sample matrix internal standard in standards, 
    blanks, and samples, in units of g/L.
        14.8.1  Results for samples which have been diluted are reported 
    at the least dilute level at which the area at the quantitation m/z 
    is within the calibration range (Section 14.7).
        14.8.2  For compounds having a labeled analog, results are 
    reported at the least dilute level at which the area at the 
    quantitation m/z is within the calibration range (Section 14.7) and 
    the labeled compound recovery is within the normal range for the 
    method (Section 13.3).
    
    15.0  Method Performance
    
        15.1  Single laboratory performance for this method is detailed 
    in References 1, 2, and 11. Acceptance criteria were established 
    from multiple laboratory use of the draft method.
        15.2  A chromatogram of the ongoing precision and recovery 
    standard (Section 7.14) is shown in Figure 4.
    
    16.0   Pollution Prevention
    
        16.1  The solvents used in this method pose little threat to the 
    environment when recycled and managed properly.
        16.2  Standards should be prepared in volumes consistent with 
    laboratory use to minimize the volume of expired standards to be 
    disposed.
    
    17.0  Waste Management
    
        17.1  It is the laboratory's responsibility to comply with all 
    federal, state, and local regulations governing waste management, 
    particularly the hazardous waste identification rules and land 
    disposal restrictions, and to protect the air, water, and land by 
    minimizing and controlling all releases from fume hoods and bench 
    operations. Compliance with all sewage discharge permits and 
    regulations is also required.
        17.2  Samples preserved with HCl or H2SO4 
    to pH < 2="" are="" hazardous="" and="" must="" be="" neutralized="" before="" being="" disposed,="" or="" must="" be="" handled="" as="" hazardous="" waste.="" 17.3="" for="" further="" information="" on="" waste="" management,="" consult="" ``the="" waste="" management="" manual="" for="" laboratory="" personnel'',="" and="" ``less="" is="" better:="" laboratory="" chemical="" management="" for="" waste="" reduction'',="" both="" available="" from="" the="" american="" chemical="" society's="" department="" of="" government="" relations="" and="" science="" policy,="" 1155="" 16th="" street="" n.w.,="" washington,="" d.c.="" 20036.="" 18.0="" references="" 18.1="" ``chlorinated="" phenolics="" in="" water="" by="" in="" situ="" acetylation/="" gc/ms="" determination,''="" method="" cp-86.01,="" national="" council="" of="" the="" paper="" industry="" for="" air="" and="" stream="" improvement,="" inc.,="" 260="" madison="" avenue,="" new="" york,="" ny="" 10016="" (july="" 1986).="" 18.2="" ``6240-chlorinated="" phenolics="" (interim="" standard),''="" draft="" version,="" u.s.="" environmental="" protection="" agency,="" manchester="" laboratory,="" manchester,="" washington.="" 18.3="" ``performance="" tests="" for="" the="" evaluation="" of="" computerized="" gas="" chromatography/mass="" spectrometry="" equipment="" and="" laboratories,''="" usepa,="" emsl="" cincinnati,="" oh="" 45268,="" epa-600/4-80-025="" (april="" 1980).="" 18.4="" ``working="" with="" carcinogens,''="" dhew,="" phs,="" cdc,="" niosh,="" publication="" 77-206="" (august="" 1977).="" 18.5="" ``osha="" safety="" and="" health="" standards,="" general="" industry,''="" osha="" 2206,="" 29="" cfr="" 1910="" (january="" 1976).="" 18.6="" ``safety="" in="" academic="" chemistry="" laboratories,''="" acs="" committee="" on="" chemical="" safety="" (1979).="" 18.7="" ``interlaboratory="" validation="" of="" u.="" s.="" environmental="" protection="" agency="" method="" 1625a,="" addendum="" report,''="" sri="" international,="" prepared="" for="" analysis="" and="" evaluation="" division="" (wh-="" 557),="" usepa,="" 401="" m="" st.="" sw,="" washington,="" dc="" 20460="" (january="" 1985).="" 18.8="" ``handbook="" of="" analytical="" quality="" control="" in="" water="" and="" wastewater="" laboratories,''="" usepa,="" emsl,="" cincinnati,="" oh="" 45268,="" epa-="" 600/4-79-019="" (march="" 1979).="" 18.9="" ``standard="" practice="" for="" sampling="" water,''="" astm="" annual="" book="" of="" standards,="" astm,="" philadelphia,="" pa,="" 76="" (1980).="" 18.10="" ``methods="" 330.4="" and="" 330.5="" for="" total="" residual="" chlorine,''="" usepa,="" emsl,="" cincinnati,="" oh="" 45268,="" epa="" 600/4-70-020="" (march="" 1979).="" 18.11="" ``determination="" of="" chlorophenolics,="" special="" analytical="" services="" contract="" 1047,="" episode="" 1886,''="" analytical="" technologies,="" inc.,="" prepared="" for="" w.="" a.="" telliard,="" industrial="" technology="" division="" (wh-552),="" usepa,="" 401="" m="" st.="" sw,="" washington,="" dc="" 20460="" (june="" 1990).="" 18.12="" ``determination="" of="" chlorophenolics="" by="" gcms,="" development="" of="" method="" 1653,''="" analytical="" technologies,="" inc.,="" prepared="" for="" w.="" a.="" telliard,="" industrial="" technology="" division="" (wh-552),="" usepa,="" 401="" m="" st.="" sw,="" washington,="" dc="" 20460="" (may="" 1991).="" 19.0="" tables="" and="" figures="" [[page="" 18744]]="" table="" 1.--chlorophenolic="" compounds="" determined="" by="" gcms="" using="" isotope="" dilution="" and="" internal="" standard="" techniques="" ----------------------------------------------------------------------------------------------------------------="" pollutant="" labeled="" compound="" compound="" -----------------------------------------------------------------------------="" cas="" registry="" epa-egd="" analog="" cas="" registry="" epa-egd="" ----------------------------------------------------------------------------------------------------------------="" 4-chlorophenol....................="" 106-48-9="" 1001="" 2,4-dichlorophenol................="" 120-83-2="" 1002="">3                      93951-74-7         1102
    2,6-dichlorophenol................         87-65-0         1003                                                 
    2,4,5-trichlorophenol.............         95-95-4         1004                                                 
    2,4,6-trichlorophenol.............         88-06-2         1005                                                 
    2,3,4,6-tetrachlorophenol.........         58-90-2         1006                                                 
    pentachlorophenol.................         87-86-5         1007  13C6                    85380-74-1         1107
    4-chloroguaiacol..................      16766-30-6         1008  13C6                   136955-39-0         1108
    3,4-dichloroguaiacol..............      77102-94-4         1009                                                 
    4,5-dichloroguaiacol..............       2460-49-3         1010                                                 
    4,6-dichloroguaiacol..............      16766-31-7         1011                                                 
    3,4,5-trichloroguaiacol...........      57057-83-7         1012                                                 
    3,4,6-trichloroguaiacol...........      60712-44-9         1013                                                 
    4,5,6-trichloroguaiacol...........       2668-24-8         1014  13C6                   136955-40-3         1114
    tetrachloroguaiacol...............       2539-17-5         1015  13C6                   136955-41-4         1115
    4-chlorocatechol..................       2138-22-9         1016                                                 
    3,4-dichlorocatechol..............       3978-67-4         1017                                                 
    3,6-dichlorocatechol..............       3938-16-7         1018                                                 
    4,5-dichlorocatechol..............       3428-24-8         1019  13C6                   136955-42-5         1119
    3,4,5-trichlorocatechol...........      56961-20-7         1020                                                 
    3,4,6-trichlorocatechol...........      32139-72-3         1021                                                 
    tetrachlorocatechol...............       1198-55-6         1022  13C6                   136955-43-6         1122
    5-chlorovanillin..................      19463-48-0         1023  13C6                   136955-44-7         1123
    6-chlorovanillin..................      18268-76-3         1024                                                 
    5,6-dichlorovanillin..............      18268-69-4         1025                                                 
    2-chlorosyringaldehyde............      76341-69-0         1026                                                 
    2,6-dichlorosyringaldehyde........      76330-06-8         1027                                                 
    trichlorosyringol.................       2539-26-6         1028                                                 
                                                                                                                    
      Sample matrix internal standard                                                                               
                  (SMIS)                                                                                            
                                                                                                                    
    3,4,5-trichlorophenol.............        609-19-8          184                                                 
                                                                                                                    
    Instrument internal standard (IIS)                                                                              
                                                                                                                    
    2,2'-difluorobiphenyl.............        388-82-9          164                                                 
    ----------------------------------------------------------------------------------------------------------------
    
    
                      Table 2.--Gas Chromatography and Method Detection Limits for Chlorophenolics                  
    ----------------------------------------------------------------------------------------------------------------
                                                                                             Minimum                
                                                 Retention     EGD  ref                     level \4\      MDL \5\  
        EGD No.\1\             Compound          time mean       No.        RRT  window   (g/  (g/
                                                 (sec) \2\                      \3\            L)            L)     
    ----------------------------------------------------------------------------------------------------------------
    1001..............  4-chlorophenol........          691          184     0.651-0.681          1.25          1.11
    1003..............  2,6-dichlorophenol....          796          184     0.757-0.779          2.5           1.39
    1102..............  2,4-dichlorophenol-d3.          818          164     0.986-0.998                            
    1202..............  2,4-dichlorophenol....          819         1102     0.997-1.006          2.5           0.15
    164...............  2,2'-difluorobiphenyl           825          164           1.000                            
                         (I.S.).                                                                                    
    1108..............  4-chloroguaiacol-13C6.          900          164     1.077-1.103                            
    1208..............  4-chloroguaiacol......          900         1108     0.998-1.002          1.25          0.09
    1005..............  2,4,6-trichlorophenol.          920          184     0.879-0.895          2.5           0.71
    1004..............  2,4,5-trichlorophenol.          979          184     0.936-0.952          2.5           0.57
    1016..............  4-chlorocatechol......         1004          184     0.961-0.975          1.25          0.59
    1011..............  4,6-dichloroguaiacol..         1021          184     0.979-0.991          2.5           0.45
    1009..............  3,4-dichloroguaiacol..         1029          184     0.986-0.998          2.5           0.52
    184...............  3,4,5-trichlorophenol          1037          164     1.242-1.272                            
                         (I.S.).                                                                                    
    1010..............  4,5-dichloroguaiacol..         1071          184     1.026-1.040          2.5           0.52
    1018..............  3,6-dichlorocatechol..         1084          184     1.037-1.053          2.5           0.57
    1006..............  2,3,4,6-                       1103          184     1.050-1.078          2.5           0.38
                         tetrachlorophenol.                                                                         
    1123..............  5-chlorovanillin-13C6.         1111          164     1.327-1.367                            
    1223..............  5-chlorovanillin......         1111         1123     0.998-1.001          2.5           1.01
    1013..............  3,4,6-                         1118          184     1.066-1.090          2.5           0.46
                         trichloroguaiacol.                                                                         
    1024..............  6-chlorovanillin......         1122          184     1.070-1.094          2.5           0.94
    1017..............  3,4-dichlorocatechol..         1136          184     1.083-1.105          2.5           0.60
    1119..............  4,5-dichlorocatechol-          1158          164     1.384-1.424                            
                         13C6.                                                                                      
    1219..............  4,5-dichlorocatechol..         1158         1119     0.998-1.001          2.5           0.24
    1012..............  3,4,5-                         1177          184     1.120-1.160          2.5           0.49
                         trichloroguaiacol.                                                                         
    1114..............  4,5,6-                         1208          164     1.444-1.484                            
                         trichloroguaiacol-                                                                         
                         13C6.                                                                                      
    1214..............  4,5,6-                         1208         1114     0.998-1.002          2.5           0.25
                         trichloroguaiacol.                                                                         
    1021..............  3,4,6-                         1213          184     1.155-1.185          5.0           0.44
                         trichlorocatechol.                                                                         
    1025..............  5,6-dichlorovanillin..         1246          184     1.182-1.222          5.0           0.80
    
    [[Page 18745]]
    
                                                                                                                    
    1026..............  2-chlorosyringaldehyde         1255          184     1.190-1.230          2.5           0.87
    1107..............  pentachlorophenol-13C6         1267          164     1.511-1.561                            
    1207..............  pentachlorophenol.....         1268         1107     0.998-1.002          5.0           0.28
    1020..............  3,4,5-                         1268          184     1.208-1.238          5.0           0.53
                         trichlorocatechol.                                                                         
    1115..............  tetrachloroguaiacol-           1289          164     1.537-1.587                            
                         13C6.                                                                                      
    1215..............  tetrachloroguaiacol...         1290         1115     0.998-1.002          5.0           0.23
    1028..............  trichlorosyringol.....         1301          184     1.240-1.270          2.5           0.64
    1122..............  tetrachlorocatechol-           1365          164     1.630-1.690                            
                         13C6.                                                                                      
    1222..............  tetrachlorocatechol...         1365         1122     0.998-1.002          5.0           0.76
    1027..............  2,6-                           1378          184     1.309-1.349          5.0          1.13 
                         dichlorosyringaldehyd                                                                      
                         e.                                                                                         
    ----------------------------------------------------------------------------------------------------------------
    \1\ Four digit numbers beginning with 10 indicate a pollutant quantified by the internal standard method; four  
      digit numbers beginning with 11 indicate a labeled compound quantified by the internal standard method; four  
      digit numbers beginning with 12 indicate a pollutant quantified by isotope dilution.                          
    \2\ The retention times in this column are based on data from a single laboratory (reference 12), utilizing the 
      GC conditions in Section 11.                                                                                  
    \3\ Relative retention time windows are estimated from EPA Method 1625.                                         
    \4\ The minimum level (ML) is defined as the level at which the entire analytical system must give a            
      recognizable signal and acceptable calibration point for the analyte. It is equivalent to the concentration of
      the lowest calibration standard, assuming that all method-specified sample weights, volumes, and cleanup      
      procedures have been employed.                                                                                
    \5\ 40 CFR Part 136, Appendix B; from reference 2.                                                              
    
    
                Table 3.--DFTPP Mass Intensity Specifications \1\           
    ------------------------------------------------------------------------
                 Mass                          Intensity required           
    ------------------------------------------------------------------------
    51...........................  8 to 82% of m/z 198.                     
    68...........................  Less than 2% of m/z 69.                  
    69...........................  11 to 91% of m/z 198.                    
    70...........................  Less than 2% of m/z 69.                  
    127..........................  32 to 59% of m/z 198.                    
    197..........................  Less than 1% of m/z 198.                 
    198..........................  Base peak, 100% abundance.               
    199..........................  4 to 9% of m/z 198.                      
    275..........................  11 to 30% of m/z 198.                    
    441..........................  44 to 110% of m/z 443.                   
    442..........................  30 to 86% of m/z 198.                    
    443..........................  14 to 24% of m/z 442.                    
    ------------------------------------------------------------------------
    \1\ Reference 7.                                                        
    
    
           Table 4.--Characteristic M/Z's of Chlorophenolic Compounds       
    ------------------------------------------------------------------------
                            Compound                            Primary m/z 
    ------------------------------------------------------------------------
    4-chlorophenol..........................................             128
    2,4-dichlorophenol......................................             162
    2,4-dichlorophenol-d3...................................             167
    2,6-dichlorophenol......................................             162
    2,4,5-trichlorophenol...................................             196
    2,4,6-trichlorophenol...................................             196
    2,3,4,6-tetrachlorophenol...............................             232
    pentachlorophenol.......................................             266
    pentachlorophenol-13C6..................................             272
    4-chloroguaiacol........................................             158
    4-chloroguaiacol-13C6...................................             164
    3,4-dichloroguaiacol....................................             192
    4,5-dichloroguaiacol....................................             192
    4,6-dichloroguaiacol....................................             192
    3,4,5-trichloroguaiacol.................................             226
    3,4,6-trichloroguaiacol.................................             226
    4,5,6-trichloroguaiacol.................................             226
    4,5,6-trichloroguaiacol-13C6............................             234
    tetrachloroguaiacol.....................................             262
    tetrachloroguaiacol-13C6................................             268
    4-chlorocatechol........................................             144
    3,4-dichlorocatechol....................................             178
    3,6-dichlorocatechol....................................             178
    4,5-dichlorocatechol....................................             178
    4,5-dichlorocatechol-13C6...............................             184
    3,4,5-trichlorocatechol.................................             212
    3,4,6-trichlorocatechol.................................             212
    
    [[Page 18746]]
    
                                                                            
    tetrachlorocatechol.....................................             248
    tetrachlorocatechol-13C6................................             254
    5-chlorovanillin........................................             186
    5-chlorovanillin-13C6...................................             192
    6-chlorovanillin........................................             186
    5,6-dichlorovanillin....................................             220
    2-chlorosyringaldehyde..................................             216
    2,6-dichlorosyringaldehyde..............................             250
    trichlorosyringol.......................................             256
                                                                            
             Sample Matrix Internal Standard (SMIS)                         
                                                                            
    3,4,5-trichlorophenol...................................             196
                                                                            
               Instrument Internal Standard (IIS)                           
                                                                            
    2,2'-difluorobiphenyl...................................             190
    ------------------------------------------------------------------------
    
    
                                 Table 5.--Acceptance Criteria for Performance Tests \1\                            
    ----------------------------------------------------------------------------------------------------------------
                                                                 Initial precision              Labeled compound and
                                                                 and recovery sec.               SMIS recovery sec. 
                                                     Test         9.3.2 (percent)     Ongoing       9.4 and 14.6    
                                                   conc.\3\   ----------------------  recovery ---------------------
         EGD No.\2\             Compound         (g/                         sec. 9.6     With     Without 
                                                      mL)                            (percent)   ascorbic   ascorbic
                                                                   s          X                   acid P     acid P 
                                                                                                   (%)        (%)   
    ----------------------------------------------------------------------------------------------------------------
    1001...............  4-chlorophenol........           25          64     72-144     40-236                      
    1202...............  2,4-dichlorophenol....           50          14     84-120     84-118                      
    1102...............  2,4-dichlorophenol-d3.           25          54     64-160     56-170     58-135     27-143
    1003...............  2,6-dichlorophenol....           50          20     66-148     58-170                      
    1004...............  2,4,5-trichlorophenol.           50          14     78-140     82-128                      
    1005...............  2,4,6-trichlorophenol.           50          20     72-142     72-146                      
    1006...............  2,3,4,6-                         50          14     80-132     82-132                      
                          tetrachlorophenol.                                                                        
    1207...............  pentachlorophenol.....          100           6     90-111     84-120                      
    1107...............  pentachlorophenol-               25          21     58-169     61-157      8-143     27-167
                          \13\C6.                                                                                   
    1208...............  4-chloroguaiacol......           25          20     88-120     88-120                      
    1108...............  4-chloroguaiacol-                25         104     68-148     64-152     59-121     43-168
                          \13\C6.                                                                                   
    1009...............  3,4-dichloroguaiaco\4\           50          18     80-126     82-126                      
    1010...............  4,5-dichloroguaiacol..           50          14     82-121     80-128                      
    1011...............  4,6-dichloroguaiacol..           50          16     82-126     86-120                      
    1012...............  3,4,5-                           50          16     78-130     80-134                      
                          trichloroguaiacol.                                                                        
    1013...............  3,4,6-                           50          16     64-152     74-140                      
                          trichloroguaiacol.                                                                        
    1214...............  4,5,6-                           50          14     92-106     88-116                      
                          trichloroguaiacol.                                                                        
    1114...............  4,5,6-                           25          48     66-146     74-140     48-131     51-139
                          trichloroguaiacol-                                                                        
                          \13\C6.                                                                                   
    1215...............  tetrachloroguaiacol...          100           7     84-115     81-126                      
    1115...............  tetrachloroguaiacol-             25          22     57-173     65-161     35-120     27-161
                          \13\C6.                                                                                   
    1016...............  4-chlorocatechol......           25          48     76-140     80-124                      
    1017...............  3,4-dichlorocatechol..           50          24     66-154     78-134                      
    1018...............  3,6-dichlorocatechol..           50          16     78-136     84-126                      
    1219...............  4,5-dichlorocatechol..           50           8     84-118     86-122                      
    1119...............  4,5-dichlorocatechol-            25          78     68-144     66-142     33-129      0-190
                          \13\C6.                                                                                   
    1020...............  3,4,5-                          100          17     60-166     72-128                      
                          trichlorocatechol.                                                                        
    1021...............  3,4,6-                          100          17     74-138     64-149                      
                          trichlorocatechol\4\.                                                                     
    1222...............  tetrachlorocatechol...          100          29     46-234     81-132                      
    1122...............  tetrachlorocatechol-             25          39     48-227     63-152     14-118      0-184
                          \13\C6.                                                                                   
    1223...............  5-chlorovanillin......           50          20     94-208     84-118                      
    1123...............  5-chlorovanillin-                25          84     68-160     70-144     51-126     32-254
                          \13\C6.                                                                                   
    1024...............  6-chlorovanillin......           50          22     82-128     80-126                      
    1025...............  5,6-dichlorovanillin..          100           9     67-146     77-140                      
    1026...............  2-chlorosyringaldehyde           50          28     76-130     72-156                      
    1027...............  2,6-                            100          14     82-129     60-183                      
                          dichlorosyringaldehyd                                                                     
                          e.                                                                                        
    1028...............  trichlorosyringol.....           50          18     76-136     66-174                      
    ----------------------------------------------------------------------------------------------------------------
                                             Sample Matrix Internal Standard                                        
    ----------------------------------------------------------------------------------------------------------------
    184................  3,4,5-trichlorophenol.          100          47     62-185     68-144     56-116     24-167
    ----------------------------------------------------------------------------------------------------------------
    \1\ Specifications derived from multi-laboratory testing of draft method.                                       
    \2\ Four-digit numbers beginning with 10 indicate a pollutant quantified by the internal standard method; four- 
      digit numbers beginning with 11 indicate a labeled compound quantified by the internal standard method; four- 
      digit numbers beginning with 12 indicate a pollutant quantified by isotope dilution.                          
    \3\ Test concentrations are in units of g/mL.                                                          
    \4\ Specification derived from isomer.                                                                          
    
    
    BILLING CODE 6560-50-P
    
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    BILLING CODE 6560-50-C
    
    [[Page 18751]]
    
    20.0  Glossary of Definitions and Purposes
    
        These definitions and purposes are specific to this method but 
    have been conformed to common usage as much as possible.
        20.1  Units of weight and measure and their abbreviations
        20.1.1  Symbols.
    
     deg.C  degrees Celsius
    L  microliter
    < less="" than="">  greater than
    %  percent
    
        20.1.2  Alphabetical characters.
    
    cm  centimeter
    g  gram
    h  hour
    ID  inside diameter
    in.  inch
    L  liter
    M  Molecular ion
    m  meter
    mg  milligram
    min  minute
    mL  milliliter
    mm  millimeter
    m/z  mass-to-charge ratio
    N  normal; gram molecular weight of solute divided by hydrogen 
    equivalent of solute, per liter of solution
    OD  outside diameter
    pg  picogram
    ppb  part-per-billion
    ppm  part-per-million
    ppt  part-per-trillion
    psig  pounds-per-square inch gauge
    v/v  volume per unit volume
    w/v  weight per unit volume
        20.2  Definitions and acronyms (in alphabetical order).
        Analyte: A chlorophenolic tested for by this method.
        The analytes are listed in Table 1.
        Calibration standard (CAL): A solution prepared from a secondary 
    standard and/or stock solutions and used to calibrate the response 
    of the instrument with respect to analyte concentration.
        Calibration verification standard (VER): The mid-point 
    calibration standard (CS3) that is used to verify calibration. See 
    Table 4.
        Chlorophenolics: collectively, the analytes listed in Table 1.
        CS1, CS2, CS3, CS4, CS5: See Calibration standards and Table 4.
        Field blank: An aliquot of reagent water or other reference 
    matrix that is placed in a sample container in the laboratory or the 
    field, and treated as a sample in all respects, including exposure 
    to sampling site conditions, storage, preservation, and all 
    analytical procedures. The purpose of the field blank is to 
    determine if the field or sample transporting procedures and 
    environments have contaminated the sample.
        GC: Gas chromatograph or gas chromatography.
        HRGC: High resolution GC.
        IPR: Initial precision and recovery; four aliquots of the 
    diluted PAR standard analyzed to establish the ability to generate 
    acceptable precision and accuracy. An IPR is performed prior to the 
    first time this method is used and any time the method or 
    instrumentation is modified.
        K-D: Kuderna-Danish concentrator; a device used to concentrate 
    the analytes in a solvent.
        Laboratory blank: See Method blank.
        Laboratory control sample (LCS): See Ongoing precision and 
    recovery standard (OPR).
        Laboratory reagent blank: See Method blank.
        May: This action, activity, or procedural step is neither 
    required nor prohibited.
        May not: This action, activity, or procedural step is 
    prohibited.
        Method blank: An aliquot of reagent water that is treated 
    exactly as a sample including exposure to all glassware, equipment, 
    solvents, reagents, internal standards, and surrogates that are used 
    with samples. The method blank is used to determine if analytes or 
    interferences are present in the laboratory environment, the 
    reagents, or the apparatus.
        Minimum level (ML): The level at which the entire analytical 
    system must give a recognizable signal and acceptable calibration 
    point for the analyte. It is equivalent to the concentration of the 
    lowest calibration standard, assuming that all method-specified 
    sample weights, volumes, and cleanup procedures have been employed.
        MS: Mass spectrometer or mass spectrometry.
        Must: This action, activity, or procedural step is required.
        OPR: Ongoing precision and recovery standard (OPR); a laboratory 
    blank spiked with known quantities of analytes. The OPR is analyzed 
    exactly like a sample. Its purpose is to assure that the results 
    produced by the laboratory remain within the limits specified in 
    this method for precision and recovery.
        PAR: Precision and recovery standard; secondary standard that is 
    diluted and spiked to form the IPR and OPR.
        Preparation blank: See Method blank.
        Primary dilution standard: A solution containing the specified 
    analytes that is purchased or prepared from stock solutions and 
    diluted as needed to prepare calibration solutions and other 
    solutions.
        Quality control check sample (QCS): A sample containing all or a 
    subset of the analytes at known concentrations. The QCS is obtained 
    from a source external to the laboratory or is prepared from a 
    source of standards different from the source of calibration 
    standards. It is used to check laboratory performance with test 
    materials prepared external to the normal preparation process.
        Reagent water: Water demonstrated to be free from the analytes 
    of interest and potentially interfering substances at the method 
    detection limit for the analyte.
        Relative standard deviation (RSD): The standard deviation times 
    100 divided by the mean.
        RF: Response factor. See Section 10.5.1.
        RR: Relative response. See Section 10.4.4.
        RSD: See Relative standard deviation.
        Should: This action, activity, or procedural step is suggested 
    but not required.
        Stock solution: A solution containing an analyte that is 
    prepared using a reference material traceable to EPA, the National 
    Institute of Science and Technology (NIST), or a source that will 
    attest to the purity and authenticity of the reference material.
        VER: See Calibration verification standard.
    
    [FR Doc. 98-9613 Filed 4-14-98; 8:45 am]
    BILLING CODE 6560-50-P
    
    
    

Document Information

Effective Date:
6/15/1998
Published:
04/15/1998
Department:
Environmental Protection Agency
Entry Type:
Rule
Action:
Final rules.
Document Number:
98-9613
Dates:
In accordance with the Small Business Regulatory Enforcement Fairness Act of 1996, the regulations shall become effective June 15, 1998. For compliance dates, see the SUPPLEMENTARY INFORMATION section under the heading ``Compliance Dates.''
Pages:
18504-18751 (248 pages)
Docket Numbers:
FRL-5924-8
RINs:
2040-AB53: Effluent Guidelines and Standards for the Pulp, Paper, and Paperboard Category
RIN Links:
https://www.federalregister.gov/regulations/2040-AB53/effluent-guidelines-and-standards-for-the-pulp-paper-and-paperboard-category
PDF File:
98-9613.pdf
CFR: (589)
40 CFR 63.457(1)
40 CFR 401.16)
40 CFR 7.12.4)
40 CFR 7.10)
40 CFR 7.12.3)
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