00-21417. Harmonization With the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions
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AGENCY:
Research and Special Programs Administration (RSPA), DOT.
ACTION:
Notice of proposed rulemaking (NPRM).
SUMMARY:
RSPA proposes to amend the Hazardous Materials Regulations (HMR) to maintain alignment with international standards by incorporating various changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. In addition, RSPA proposes to revise the requirements for intermediate bulk containers and UN portable tanks for alignment with international requirements. Because of recent changes to the International Maritime Dangerous Goods Code (IMDG Code), the International Civil Aviation Organization's Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), and the United Nations Recommendations on the Transport of Dangerous Goods (UN Recommendations), these proposed revisions are necessary to facilitate the transport of hazardous materials in international commerce.
DATES:
Comments must be received by December 22, 2000.
ADDRESSES:
Address comments to the Dockets Management System, U.S. Department of Transportation, Room PL 401, 400 Seventh St., SW., Washington, DC 20590-0001. Comments should identify the docket number RSPA-00-7702 (HM-215D) and be submitted in two copies. If you wish to receive confirmation of receipt of your comments, include a self-addressed stamped postcard. You may also submit and review all comments by accessing the Docket Management System website at http://dms.dot.gov. Click on “Help and Information” to obtain instructions for filing a document electronically. The Dockets Unit is located on the Plaza Level of the Nassif Building at U.S. DOT at the above address. Public dockets may be reviewed between the hours of 10 a.m. and 5 p.m., Monday through Friday, except on Federal holidays.
Start Further InfoFOR FURTHER INFORMATION CONTACT:
Joan McIntyre, Office of Hazardous Materials Standards, telephone (202) 366-8553, or Bob Richard, Assistant International Standards Coordinator, telephone (202) 366-0656, Research and Special Programs Administration, U.S. Department of Transportation, 400 Seventh Street, SW., Washington, DC 20590-0001.
End Further Info End Preamble Start Supplemental InformationSUPPLEMENTARY INFORMATION:
I. Background
On December 21, 1990, the Research and Special Programs Administration (RSPA) (hereafter, “we” and “our” means “RSPA”) published a final rule based on the UN Recommendations [Docket HM-181; 55 FR 52402] which comprehensively revised the Hazardous Materials Regulations (HMR), 49 CFR parts 171 to 180, with respect to hazard communication, classification, and packaging requirements. The intended effect of the rule was to facilitate the international transportation of hazardous materials by ensuring a basic consistency between the HMR and international regulations, while at the same time ensuring the safe transportation of hazardous materials.
The UN Recommendations are not regulations, but are recommendations issued by the UN Committee of Experts on the Transport of Dangerous Goods. These recommendations are amended and updated biennially by the UN Committee of Experts. They serve as the basis for national, regional, and international modal regulations (specifically, the IMDG Code, issued by the International Maritime Organization (IMO), and the ICAO Technical Instructions, issued by the ICAO Dangerous Goods Panel). In 49 CFR 171.12, the HMR authorize hazardous materials shipments prepared in accordance with the IMDG Code if all or part of the transportation is by vessel, subject to certain conditions and limitations. Offering, accepting and transporting hazardous materials by aircraft, in conformance with the ICAO Technical Instructions, and by motor vehicle either before or after being transported by aircraft, are authorized in § 171.11, subject to certain conditions and limitations.
Since publication of the 1990 final rule, we have issued three additional international harmonization final rules, (Dockets HM-215A, 59 FR 67390; HM-215B, 62 FR 24690; and HM-215C, 64 FR 10742). The rules provided additional harmonization with international air and sea transportation requirements by more fully aligning the HMR with the corresponding biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions.
The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation and at the same time ensures the safety of people, property and the environment. Therefore, in our efforts to continue the alignment of the HMR with international requirements, this NPRM proposes changes to the HMR based on the eleventh revised edition of the UN Recommendations, the 2001-2002 ICAO Technical Instructions and Amendment 30 to the IMDG Code, all of which become effective January 1, 2001. Petitions for rulemaking pertinent to harmonization with international standards and the facilitation of international transportation are also addressed in this NPRM and serve as the basis of certain proposed changes. Other proposed changes are based on feedback from the regulated industry, RSPA and other DOT modal administrations, including a few proposed editorial clarifications and a Class 1 (explosives) placarding allowance for certain compatibility groups. Unless otherwise stated, the revisions are proposed for harmonization with international standards.
II. Overview of Proposed Changes in this NPRM
Proposed amendments to the HMR in this NPRM include:
—Incorporation by reference of the updated ICAO Technical Instructions, IMDG Code and UN Recommendations and addition of incorporation by reference of six current standards which include an International Atomic Energy Agency (IAEA) safety standard, an IMO safety standard, three International Organization for Standardization (ISO) standards and one American Society for Testing Materials (ASTM) standard.
—Amendments to the Hazardous Materials Table (HMT) which would add, revise or remove certain proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, bulk packaging requirements, and passenger and cargo aircraft maximum quantity limitations. Proper Start Printed Page 63295shipping name amendments include the proposal to replace the word “inhibited” with “stabilized.” Entry removals include certain domestic entries for which corresponding UN entries are included in the HMT.
—Revision of vessel stowage category definitions and codes for Class 1 (explosive) materials.
—Revision of shipping paper requirements for sea transport.
—Addition, removal and revision of certain entries to the List of Marine Pollutants.
—Addition, removal and revision of special provisions, including removal of current T codes and IBC bulk provisions and addition of UN portable tank codes and IBC special packing provisions, consistent with those in the UN Recommendations.
—Removal of the requirement to distinguish between primary and subsidiary risk labels and placards.
—Addition and revision to the list of organic peroxides and the list of self-reactive substances.
—Revision of the requirements pertaining to the transportation of samples.
—Revision of intermediate bulk container (IBC) requirements including amendments to the IBC commodity sections in §§ 173.240, 173.241, 173.242, 173.243 and 173.247, and addition of UN IBC packing instructions and special IBC packing provisions in part 172.
—Incorporation of the design, construction and use requirements for UN portable tanks.
—Consolidation of current portable tank maintenance, approval and use requirements.
—Inclusion of flexible grandfather provisions for the continued use of IM 101, IM102 and DOT 51 portable tanks.
—Removal of specifications for DOT 52 and 53 portable tanks and the provisions for their continued use.
—Incorporation of a provision for the use of the “W” mark for IBCs.
—Inclusion of a 12 mm minimum marking size for IBCs.
—Revision of minimum thickness requirements for metal IBCs.
—Revision of several explosives packing methods to allow a broader selection of authorized packagings.
—Revision of provisions for cigarette lighters and alcoholic beverages carried aboard aircraft.
—Allowance of the display of one placard when certain explosive compatibility groups are transported together.
—Revision of lithium battery requirements.
III. Summary of Regulatory Changes by Section
Part 171
Section 171.7. We propose to update the incorporation by reference for the ICAO Technical Instructions, the IMDG Code, the UN Recommendations and the UN Manual of Tests and Criteria. In addition, we propose to add an ASTM standard, the current edition of the IAEA safety standard, an IMO standard, and three ISO standards.
All of the updated incorporation by reference material will become effective January 1, 2001 and would be updated as follows:
—The ICAO Technical Instructions—2001-2002 edition.
—The IMDG Code—Amendment 30.
—The UN Recommendations—eleventh revised edition.
—The UN Manual of Tests and Criteria—third revised edition.
Additionally, all of the proposed added incorporation by reference material would become effective January 1, 2001 and would be added as follows:
—ASTM's “E 112-96 Standard for Test Methods for Determining Average Grain Size” would be added to define “fine grain steel” as included in the proposed incorporation of the UN portable tank specifications in § 178.274.
—IAEA's current “Regulations for the Safe Transport of Radioactive Material, No. ST-1,” 1996 edition would be added while retaining the previous edition entitled, “Regulations for the Safe Transport of Radioactive Material, Safety Series No. 6.” The ST-1 requirements were incorporated in the IMDG Code and the ICAO Technical Instructions which will both be effective January 1, 2001. Adding the updated ST-1 edition and retaining Safety Series No. 6 would afford the flexibility necessary in an interim period when international shipments are required to be in accordance with the ST-1 edition. Domestic shipments would remain subject to the HMR requirements, which are based on Safety Series No. 6 pending amendment of these requirements under a separate rulemaking.
—IMO'S current “International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships' (INF Code) would be added. The IMO Maritime Safety Committee adopted the INF Code for incorporation into the IMDG Code. In addition, the INF Code is being made mandatory for international transportation effective January 1, 2001, through an amendment to Chapter VII of the International Convention for the Safety of Life at Sea, 1974 (SOLAS 1974, as amended). The incorporation by reference and inclusion of the proposed new § 176.720 requirement for a vessel carrying irradiated nuclear fuel, plutonium and high-level radioactive wastes would align the HMR with these international standards. (Also, see § 176.2. and § 176.720.)
—Finally, we are proposing to add three ISO standards to coincide with the proposed incorporation of the UN portable tank requirements. The standards are as follows: “ISO 1496-3 Series 1 freight containers—Specification and testing,” 1996 edition; “ISO 4126-1 Safety valves-Part 1: General Requirements,” 1991 edition; and, “ISO 6892 Metallic materials—Tensile testing,” 1984 edition.
Section 171.8. We would add four new definitions to § 171.8. “Large packaging” would be added to correspond with the proposed addition of an approval provision that would allow the use of large packagings which comply with requirements in the UN Recommendations (see § 178.801). Large packagings are UN-marked bulk packagings which are very similar to IBCs, with the exception that they contain inner packagings. “Liner” would be added for clarification purposes. “Stabilized” would be added in conjunction with the proposal to replace the word “inhibited” with “stabilized” in proper shipping names (see § 172.101). Finally, “UN portable tank” would be added in conjunction with the proposal to include requirements for the design, construction and use of UN portable tanks (see §§ 178.274, 178.275, 178.276, 178.277).
Section 171.10. To correspond with the proposed incorporation of the UN portable tank specifications, we would add the unit of measure for “Newton” into the Table of Conversion Factors in paragraph (c)(2).
Section 171.11. We propose to add a new paragraph (d)(17) to ensure conformance with the current approval provision in § 173.128(d) which requires an approval from the Associate Administrator for the offering for transportation or transport of organic peroxides that are not identified by technical name in the § 173.225(b) Organic Peroxide Table. (We also propose to add the new paragraph under §§ 171.12 and 171.12a.) Start Printed Page 63296
Section 171.12. Paragraph (b)(3) would be revised by adding a limitation to the use of the IMDG Code by requiring that viscous flammable liquids, which are excepted from the IMDG Code when in a packaging of less than 450 liters (118.9 gallons) capacity, are subject to the HMR. We do not agree that the IMDG Code exception provides an adequate level of safety and opposed its incorporation in the ICAO Technical Instructions, the IMDG Code and UN Recommendations. We believe this requirement is necessary to ensure that importers and exporters are aware that these viscous flammable liquids are regulated in the United States. We also propose to add a new paragraph (b)(19) to ensure conformance with the current approval provision in § 173.128(d), which requires an approval from the Associate Administrator for the offering for transportation or transport of organic peroxides that are not identified by technical name in the § 173.225(b) Organic Peroxide Table. Finally, we proposed to revise paragraph (d) to reflect the addition of the current edition of the IAEA “Regulations for the Safe Transport of Radioactive Material, No. ST-1,” 1996 edition. (See § 171.7 for discussion concerning the addition of the updated ST-1 standards.)
Section 171.12a. We propose to add a new paragraph (b)(18) to ensure conformance with the current approval provision in § 173.128(d) which requires an approval from the Associate Administrator for the offering for transportation or transport of organic peroxides that are not identified by technical name in the § 173.225(b) Organic Peroxide Table.
Section 171.14. We propose to revise paragraphs (d) and (d)(1) to authorize a delayed implementation date for the amendments adopted in the HM-215D final rule. The effective date of this final rule would be October 1, 2001. However, we would authorize a voluntary compliance date of January 1, 2001. This authorization would allow shippers to prepare their international shipments in accordance with the new ICAO Technical Instructions, the IMDG Code and the HMR provisions. We also would authorize a delayed mandatory compliance date comparable to the transition provisions provided in the final rule under Docket HM-215C. The delayed mandatory compliance date would offer sufficient time to implement the new provisions and deplete current stocks of shipping papers, labels, placards and packagings affected by the new requirements.
We would revise paragraph (d)(2) to permit intermixing old and new (HM-215D) hazard communication requirements until October 1, 2002.
We would add a new paragraph (d)(4) to allow the use of the T code special provisions (proposed to be assigned to a hazardous material in Column (7) of the HMT) in effect on December 31, 2000 until January 1, 2010 for hazardous materials offered for transportation in IM and IMO portable tanks. This proposal is consistent the IMDG Code and would minimize any undue regulatory burden.
Part 172
Section 172.101. For alignment with international standards, we would revise paragraph (c)(11) and add new paragraphs (k)(6) through (k)(20). Consistent with the eleventh revised edition of the UN Recommendations, we would revise paragraph (c)(11) for materials transported as samples which are assigned a tentative proper shipping name, hazard class, identification number and packing group. We would revise the requirements by requiring the word “SAMPLE” to be included in association with the proper shipping name and by prohibiting the samples from being packaged together with other hazardous materials. We also would add a new paragraph (c)(16) to allow for the inclusion of the qualifying words “liquid,” “solid” or “molten,” as applicable, to a proper shipping name.
Consistent with the new stowage categories and terminology contained in Amendment 30 of the IMDG Code, we would add new paragraphs (k)(6) through (k)(20) to include the IMDG vessel stowage category definitions for Class 1 (explosive) materials. (Also see preamble discussion under “The Hazardous Materials Table” and § 176.63.)
The Hazardous Materials Table (HMT). Proposed amendments to the HMT for the purpose of harmonizing with the eleventh revised edition of the UN Recommendations (unless otherwise stated) would include the following:
—For the entries, “Other regulated substances, liquid, n.o.s.” and “Other regulated substances, solid, n.o.s.,” we would add the letter “G” to Column (1). The letter “G,” which denotes the n.o.s. and generic proper shipping names which are required to be supplemented with the technical names of the hazardous material (in parentheses and in association with the basic description), was inadvertently omitted in Docket HM-215C (64 FR 10742).
—We would add the following new entries: “Nitroglycerin mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin by mass,” UN3357; “Propellant, solid,” UN0501; “Refrigerating machines containing flammable, non-toxic, liquefied gas,” UN3358; “Rockets with inert head,” UN0502; and “1H-Tetrazole,” UN0504.
—We would revise the entry, “Dangerous Goods in Machinery or Dangerous Goods in Apparatus” by replacing the identification number NA8001 with UN3363, designating a Class 9 assignment and revising Special Provision 136 (see § 172.102). These proposed changes reflect the adoption of the entry by the UN Committee of Experts and amendments agreed to by the ICAO Dangerous Goods Panel. The entry was added to the HMT under Docket HM-215C as NA8001 and assigned Special Provision 136 to prescribe the appropriate hazard class assignment. As explained in HM-215C, the entry was adopted in the ICAO Technical Instructions to provide an exception from the UN packaging performance tests for equipment, machinery or apparatus containing small quantities of hazardous materials. For machinery or apparatus not specifically listed in the HMT, the entry provides a practical means of describing and transporting machinery or apparatus containing small quantities of hazardous materials. In HM-215C, we stated that upon the assignment of a UN identification number, we would revise the entry accordingly. This was accomplished in the eleventh revised edition of the UN Recommendations in which UN3363 was assigned and this entry was assigned to Class 9. The ICAO Technical Instructions were amended consistent with this UN decision. Therefore, based on the above discussion, we are proposing to revise the entry, “Dangerous Goods in Machinery or Dangerous Goods in Apparatus” by assigning it to Class 9, replacing the domestic identification number with an international identification number, and revising Special Provision 136.
—We are proposing to revise all proper shipping names containing the word “inhibited” by replacing “inhibited” with the word “stabilized.” (Also, see proposed definition for “stabilized” in § 171.8.) Replacing the word “inhibited” with “stabilized” would recognize that, in addition to inhibition, other means of controlling self-reaction would be acceptable. The proposed allowance of additional means of stabilization and the proposed removal of certain domestic entries from the HMT (see domestic entry removals later in this section) would also address a petition for Start Printed Page 63297rulemaking (P-1304) requesting that we add a new domestic entry, “Methyl methacrylate monomer, uninhibited,” Class 3, NA1247, PG II to the HMT.
—We would revise the following proper shipping names: “Lithium hypochlorite, dry or Lithium hypochlorite mixtures, dry,” UN1471; “Printing ink, flammable,” UN1210; and “Nitrocellulose membrane filters,” UN3270.
—For the entry, “Methacrylic acid, inhibited,” UN2531, we would replace Packing Group III with Packing Group II.
—We propose to remove various domestic entries that have assigned “NA” identification numbers. After reviewing the domestic entries, we determined that the HMR includes “UN” identification numbers assigned to entries that are equally appropriate in a number of instances, and in these instances the NA numbers are no longer necessary. Included in the proposed removals are seven domestic pesticide proper shipping names identified by the pesticide industry as no longer being used. These entries are: “Aldrin, liquid,” NA2762; “Aldrin, solid,” NA2761; “Dieldrin,” NA2761; “Methyl parathion liquid,” NA3018; “Methyl parathion solid, NA2783; “Parathion,” NA2783 and “Tetraethyl pyrophosphate solid,” NA3018.
—We would add radioactive material (Class 7) entries consistent with new entries introduced in the UN Recommendations and IAEA's “Regulations for the Safe Transport of Radioactive Material, No. ST-1” and revise the current radioactive material entries in the HMR to allow for domestic shipment only.
—For Class 1 (explosive) entries, we would revise Columns (10A) and (10B) to reflect the vessel stowage codes as they are presented in Amendment 30 to the IMDG Code. (See § 172.101(k) and § 176.63.)
—For the international entry “Methanol,” we would add a plus mark (+) in Column (1) of the HMT to indicate that this entry is classified with a subsidiary hazard of Class 6.1 on the basis of human experience.
—We would remove the entry “Isobutyric anhydride,” UN2530.
—For the entry “Morpholine,” UN2054, we would replace Class 3 with Class 8, replace Packing Group III with Packing Group I , and add Class 3 as the subsidiary hazard.
—For “Organic peroxide type F, solid, temperature controlled,” (UN3120), we would remove the Packing Group III entry that was due to a printing error in 49 CFR. The PG II entry would remain.
—For approximately 14 Zone A and B toxic-by-inhalation entries, we would revise the quantity limits for transport by air to “forbidden.” These revisions would be consistent with other toxic-by-inhalation entries in the HMT.
—For the entry “Fire extinguishers containing compressed or liquefied gas” we would add Special Provision 110 to Column (7).
—Based on a petition for rulemaking (P-1338) that we received from the Aluminum Company of America (Alcoa), we propose to add Special Provisions 128 and B115 to the entry, “Magnesium granules, coated, particle size not less than 149 microns,” UN2950. Special Provision 128 allows material meeting the Class 8 definition to be classed as a Division 4.3 with a Class 8 subsidiary hazard. Special Provision B115 authorizes the use of certain non-specification bulk packagings when the material being transported is loaded dry. Special Provisions 128 and B115 are currently assigned to “Aluminum smelting by-products or Aluminum remelting by-products.” Alcoa states that magnesium granules exhibit the same hazard properties as aluminum smelting and remelting by-products and behave similarly to these materials by occasionally meeting the criteria for both Division 4.3 and Class 8 materials. We agree with the petitioner and propose to add Special Provisions 128 and B115 to the entry “Magnesium granules, coated, particle size not less than 149 microns,” UN2950. (Also, see § 172.102, Special Provision 128.)
—For approximately 1,600 entries, we would revise Column (7) by harmonizing the HMR authorizations for IBCs with those contained in the UN Recommendations. In most cases, the UN Recommendations provide for greater flexibility in the use of different types of IBCs. However, in a few instances, the incorporation of the UN IBC requirements would further restrict the types of IBCs that are currently authorized for certain hazardous materials. For example, some Packing Group II liquid hazardous materials of Class 3, Division 6.1 and Class 8 that are currently authorized to be transported in composite IBCs with flexible inner receptacles (such as 31HZ2) would not be authorized in these types of IBCs if the UN provisions are adopted. For the benefit of the reader and to facilitate a review of the proposed amendments, we have included a table identifying all of the affected hazardous materials and indicating the current bulk assignments and the proposed IBC assignments. We would set out the IBC packaging requirements in a newly-created IBC Table under the Special Provisions section in § 172.102(c)(4). The table would consist of IBC Codes (using the designations 1B1-1B99) corresponding to the UN IBC packing instructions, and BB Codes corresponding to the UN IBC special packing provisions. We would assign the IBC packing instructions and the BB codes to specific hazardous materials in Column (7) of the § 172.101 HMT consistent with assignments in the UN Recommendations. In addition, we believe that consolidating the IBC requirements into one table would make it easier for readers to identify the authorized IBCs for specific hazardous materials and would enhance safety and international harmonization. As a result of this proposal, we would revise the bulk special provisions in § 172.102 (c)(3) to remove the current bulk codes relevant to the use of IBCs. We would also revise the current IBC packaging authorizations under §§ 173.240(d), 173.241(d), 173.242(d) and 173.243(d).
This proposal also addresses a petition we received from the Rigid Intermediate Bulk Container Association (RIBCA) (P-1395) requesting that we amend the HMR to expand the use of IBCs consistent with new UN provisions. Specifically, the petitioner requested uniformity with the UN Recommendations by requesting that the HMR allow the use of rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle for certain liquids. We are in agreement with RIBCA's request; however, in the interest of harmonization, we believe it would be more beneficial to adopt the UN Recommendations' IBC packing instructions in totality, and, as such, present the proposal as discussed above.
For purposes of the Government Printing Office's typesetting procedures, readers should be aware that for certain entries in the HMT, such as those with revised proper shipping names, the change may appear as a removal and addition, as opposed to a revision of the regulatory text in the Column (2) changes. Readers should review all changes appearing in the § 172.101 regulatory text for a complete view of the proposed changes.
Appendix B to § 172.101. For the readers' convenience, in Appendix B to § 172.101, List of Marine Pollutants, we Start Printed Page 63298would revise paragraph “1” by referencing § 171.4, which contains the applicability and exceptions for offering for transportation or transporting marine pollutants. We would revise paragraph “2” to reflect the IMDG Code's provision for the use of two Class 9 proper shipping names when a marine pollutant is not listed by name or by synonym in the HMT and does not meet the definitions of Class 1 through 8. In addition, a number of materials would be added, removed or amended in the List of Marine Pollutants. Included is the proposed removal of the entry “EPTC (ISO)” which also was the subject of a petition for rulemaking (P-1360) requesting removal of the entry based on its removal from the IMDG Code. Various other entries previously identified as marine pollutants are proposed to be removed. All of the proposed amendments to the List of Marine Pollutants are consistent with the marine pollutants provided in Amendment 30 of the IMDG Code.
Section 172.102. We propose to revise, add and remove special provisions as follows:
—Special Provision 43 would be revised to include a provision which would except “Nitrocellulose membrane filters,” UN3270 from the HMR requirements if shown not to meet the criteria for a Division 4.1 hazardous material, according to burn rate tests in Sub-section 33.2.1. of the UN Manual of Tests and Criteria, Part III.
—Special Provision 110 would be revised to more fully identify fire extinguishers that may be assigned to certain proper shipping names. The proposal would also provide for harmonization with the ICAO Technical Instructions. (We also propose to add the special provision to the entry, “Fire extinguishers containing compressed or liquefied gas.” See § 172.101 proposed HMT changes.)
—Special Provision 128 would be revised based on the proposal to assign it to “Magnesium granules, coated, particle size not less than 149 microns.” (See § 172.101, proposed Column (7) changes.)
—Special Provision 136 would be revised to reflect the changes adopted by the UN Committee of Experts and the ICAO Dangerous Goods Panel for the entry “Dangerous Goods in Machinery or Dangerous Goods in Apparatus.” (Also see § 172.101.) We would revise the special provision by removing the text specific to the determination of the hazard class based on the UN Committee of Experts' decision that items under this entry should be assigned to Class 9.
—A new Special Provision 139 would be added for two new proposed entries, “Radioactive material, transported under special arrangement, fissile” and “Radioactive material, transported under special arrangement non-fissile or fissile-excepted.” The special provision requires international shipments using the two entries to be made under an IAEA Certificate of Competent Authority to be issued by the U.S. Competent Authority. Domestic shipments transported under the two entries would be allowed only under a DOT exemption.
—A new Special Provision 142 would be assigned for the new entry “Nitroglycerin mixture, desensitized, liquid, n.o.s.” The special provision would require the material to be approved by the Associate Administrator.
—A new Special Provision 143 would be added for the entry “Life-saving appliances, not self-inflating, containing dangerous goods as equipment.” The special provision would clarify which articles may be transported under this entry.
— In conjunction with the proposal to revise and consolidate the IBC requirements (see § 172.101, Column (7) changes), we would make the following changes: revise the special provisions for bulk packagings in paragraph (c)(3) to exclude IBCs by revising Special Provisions B53 and B69 and removing Special Provisions B100, B101, B103 through B106 and B108 through B110, and a new paragraph (c)(4) would be added for special provisions specific to IBCs (BB Codes).
—The current T codes in paragraph (c)(7) would be revised to reflect the proposed incorporation of requirements for UN portable tanks and would apply to hazardous materials of Classes 2 through 9. The revised T codes would be consistent with those in the UN Recommendations and the IMDG Code and would supersede the current HMR IM portable tank T codes. The T code provisions would be required in addition to the proposed requirements in part 178. The codes specify the types of authorized portable tanks according to the specific hazardous material transported in the portable tank. Portable tank assignments for Zone A and Zone B toxic-by-inhalation liquids would remain consistent with their current assignments in the HMR. In instances where the UN requires a competent authority approval for transportation in portable tanks (such as when TP9 is assigned in the UN Recommendations), we have removed the approval provision. A transition period would be provided for the continued use of the existing T codes for IM portable tanks (see § 171.14(d)(5)).
—A new Special Provision W7 would be added for seven proposed new Class 7 entries and would assign the vessel stowage category “D,” as defined in § 172.101(k)(4), to uranyl nitrate hexahydrate solution.
—A new Special Provision W8 would be added for four proposed new Class 7 entries and would assign the vessel stowage category “D,” as defined in § 172.101(k)(4), to pyrophoric thorium metal or pyrophoric uranium metal.
—Finally, a new Special Provision W9 would be added for assignment to the entries, “Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen,” UN1748; “Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures with not less than 5.5 percent but not more than 10 percent water,” UN2880; and “Calcium hypochlorite mixtures, dry, with more than 10 percent but not more than 39 percent available chlorine.” UN2208. This proposed action would align the packaging requirements for these entries with those contained in Amendment 30 to the IMDG Code by authorizing certain packagings only when approved by the Associate Administrator.
Section 172.203. We are proposing to revise paragraphs (d)(11), (i) and (n). In paragraph (d)(11), we propose to allow an exception from the requirement to add the appropriate group notation to the shipping description for a shipment of low specific activity material or surface contaminated objects provided the symbols are contained in the proper shipping name.
In paragraph (i), we would add two additional shipping paper description requirements for transportation by vessel. The first amendment would be added as new paragraph (i)(5) and would require the flashpoint for a liquid hazardous material with a flashpoint of 61 °C or below to be included on shipping papers when transported by water. We received a petition (P-1402) from the Vessel Operators Hazardous Materials Association (VOHMA) requesting that we add an additional shipping paper description requirement to include the minimum flashpoint in degrees Celsius for Class 3 (flammable) Start Printed Page 63299or combustible liquid hazardous materials. VOHMA stated that the amendment would help support compliance with the current stowage requirements in § 176.305(c) and the segregation requirements (Code 22 and 23, see § 176.84) as designated in Column (10B) of the § 172.101 Hazardous Materials Table. We agree with the petitioner's reasoning; however, for consistency with the IMDG Code, we propose to add the requirement to specify the flashpoint when it is 61 °C or below for all such liquid hazardous materials whether or not the primary hazard is Class 3. The second amendment to the additional shipping paper description requirements for transportation by vessel would be added as new paragraph (i)(6) and is based on comments from the USCG regarding further harmonization with the IMDG Code. The amendment would require subsidiary risks of a hazardous material that are not reflected in the proper shipping name to be included on shipping papers.
Finally, in paragraph (n), we are proposing to clarify that the shipping paper requirement for the word “HOT” to be placed immediately preceding the proper shipping names of hazardous materials that are transported as elevated temperature materials, is not required for proper shipping names containing the words “Molten” or “Elevated temperature.”
Sections 172.402, 172.405 and 172.411. Consistent with the eleventh revised edition of the UN Recommendations, we are removing the requirement to differentiate between primary and subsidiary labels. Currently, primary labels are required to display the hazard class or division number in the lower corner of the label, while subsidiary labels may not display these numbers. We are proposing to amend the requirement which provides for two label specifications (one for primary hazards and one for subsidiary hazards) by removing the subsidiary hazard label specification. Upon adoption of this proposal, labels used to convey both primary and subsidiary hazards would display the appropriate hazard class or division number at the bottom of the label. This proposed change would provide relief by eliminating the need for shippers to stock two sets of labels. We also propose to allow labels meeting the current label specifications to continue to be displayed until October 1, 2005.
Section 172.504. Based on comments and our own initiative, we are proposing to allow the display of only one placard displaying one compatibility letter when certain Class 1 materials (explosives) of different compatibility groups are transported together in a single transport vehicle or container. This proposal is consistent with the mixed packaging allowances in § 173.61.
Section 172.519. Consistent with the proposal to eliminate the distinction between primary and subsidiary labels, we would revise paragraph (b)(4) to eliminate the requirement for placards. In addition, we would incorporate a new paragraph (b)(4)(i) to permit subsidiary placards meeting the current placarding specifications (such as placards without the hazard class or division number displayed in the lower corner of the placard) to continue to be displayed provided they were permanently affixed before January 1, 2001. Non-permanently affixed subsidiary placards meeting the current placarding specifications would be allowed to be displayed until October 1, 2005 or until current stocks are depleted, whichever occurs first.
Part 173
Section 173.2a. Consistent with the eleventh revised edition of the UN Recommendations, we would revise Note 2 to exclude liquid and solid desensitized explosives. In addition, we would add the revised Note 2 to Class 3, PG I, II and III.
Section 173.4. Based on a request for clarification, we would revise paragraph (a) to clarify that the small quantity exceptions apply to packagings containing articles, as well as inner receptacles.
Section 173.24b. We would add a new paragraph (e) to address acceptance of foreign manufactured UN portable tanks that conform to the applicable provisions in the UN Recommendations on the Transport of Dangerous Goods and are manufactured in countries that provide reciprocal treatment for UN portable tanks manufactured in the United States.
Section 173.28. We would correct a reference in paragraph (d)(1)(ii). The paragraph currently references “§ 173.225(c)(5)” and would be corrected to read § 173.225(c)(3).”
Section 173.32. We are proposing to revise this section to provide requirements for all portable tanks by consolidating the requirements for the use of IM portable tanks currently in § 173.32(c) into a single section. We are proposing to consolidate the qualification and maintenance requirements in § 173.32(c) and move them to part 180, subpart G, with the qualification and maintenance requirements for IBCs, cargo tanks and tank cars. We are also proposing to include a grandfather clause in this section (§ 173.32) to allow IM 101, 102 and DOT 51 portable tanks to continue to be constructed in accordance with the HMR until January 1, 2003. IM 101, 102 and DOT 51 portable tanks which are certified and approved prior to this date would be authorized for continued use provided they meet the applicable periodic inspection and test requirements proposed in part 180, subpart G. These requirements are currently in § 173.32b. On January 1, 2003, all newly manufactured portable tanks would be required to conform to the requirements for the design, construction and approval of UN portable tanks (see §§ 178.274, 178.275, 178.276 and 178.277). In addition, we are proposing to remove the provisions for the continued use of DOT Specification 52 and 53 portable tanks and ICC Specification portable tanks based on information we received that these portable tanks are no longer used. We specifically request comments with regard to removing these provisions.
Section 173.32a. We are proposing to remove § 173.32a and move its approval requirements for Specification portable tanks to proposed § 178.273. We believe that part 178 is a more appropriate location for these requirements and that the new section will prove to be more convenient for users of the HMR. We also propose to include similar requirements for the proposed incorporation of requirements for UN portable tanks.
Section 173.32b. We are proposing to remove § 173.32b and relocate the test requirements to part 180, subpart G, as discussed in § 173.32.
Section 173.32c. We are proposing to remove § 173.32c. The requirements for the use of all Specification portable tanks would be included in § 173.32, thereby precluding the need for this section.
Section 173.61. Based on our own initiative, for Class 1 (explosives) mixed packaging requirements, we would revise paragraph (e)(3) to allow explosives of compatibility group S that are allowed to be packaged with explosives of all other compatibility groups, except A and L, to be treated as belonging to any of the packaged compatibility groups except S. In addition, we would add a new paragraph (e)(8) to allow explosive articles of compatibility groups C, D, E and G, except for fireworks and articles requiring special packaging, to be treated as belonging to compatibility group E. This proposed revision corresponds with the current allowance contained in § 177.848(g).Start Printed Page 63300
Section 173.62. In paragraph (c), we would revise the Explosives Packing Instructions Table to authorize additional types of outer packagings in the following packing instructions: 112(a), 112(b), 112(c), 113, 115, 116, 130, 131, 134, 135, 136, 138, 140, 141,142 and 144.
Section 173.150. We would revise paragraph (d) by clarifying that alcoholic beverages containing over 24% alcohol by volume are not excepted from regulation when transported by a passenger or crewmember on passenger-carrying aircraft. (See preamble discussion under § 175.10.)
Section 173.162. We would revise paragraph (a)(1) by clarifying that the types of packagings specified in the paragraph are combination packagings and that the glass, earthenware or rigid plastics are inner packagings. In addition, for these packagings, we would increase the net mass of 10 kg (22 pounds) for each packaging to15 kg (33 pounds). This is consistent with Packing Instruction 800 in the UN Recommendations.
Section 173.185. We would revise § 173.185 to include a definition for equivalent lithium content for lithium ion cells and batteries and to provide the applicable aggregate lithium quantities relevant to excepting lithium ion cells and batteries from the requirements of the HMR.
Section 173.224. Consistent with the UN Recommendations, we would add the entry “2,2'-Azodi(isobutyronitrile) as a water-based paste” to the Self-Reactive Substances Table for substances that are not subject to the approval provisions of § 173.124(a)(2)(iii), provided all applicable provisions in the table are met. Finally, we would revise paragraph (b)(4) and remove paragraph (d) to allow Type F self-reaction substances to be transported in portable tanks under conditions specified in § 173.225(e) (see preamble discussion under § 173.225).
Section 173.225. We are proposing to amend the paragraph (b) Organic Peroxide Table by making various changes, such as revising several technical names, packing method authorizations and control temperatures. These proposed changes are consistent with the UN Recommendations. We are proposing to remove Notes “7” and “10” consistent with our proposed adoption of UN IBC 520 and add Notes “26” and “27” to specify the available oxygen content limitations for certain new organic peroxides formulations. We would revise paragraph (e) to incorporate the requirements from the eleventh revised edition of the UN Recommendations relevant to the emergency venting devices for portable tanks used for the transportation of organic peroxides and self-reactive substances. This responds to NTSB recommendation (I-92-2) that asked us to “revise the requirements for pressure relief venting on DOT specification 57 portable tanks used to transport dicumyl peroxides and other products with similar rapid decomposition characteristics to ensure that the pressure relief systems prevent overpressure rupture of tanks from a rapid product decomposition reaction.” We propose to apply the recommended venting requirements to all portable tanks and IBCs, rather than just DOT Specification portable tanks. Additionally, the types of portable tanks authorized for type F organic peroxide and self-reactive substances would be expanded to include UN portable tanks. We propose to adopt the requirements in Portable Tank Instruction T23 and IBC Special Provision , IBC 520.
Sections 173.240, 173.241, 173.242 and 173.243. In each section's paragraph (c), we would remove Specification DOT 52 and 53 portable tanks as authorized packagings (see § 173.32 ) because we believe that these portable tanks are no longer used. In addition, we would authorize UN portable tanks. In conjunction with the proposal to revise the requirements for IBCs for alignment with international standards, we would revise paragraph (d) which specifies authorized IBCs in §§ 173.240, 173.241, 173.242 and 173.243 to reflect the proposed incorporation of IBC packing instructions and BB codes (see § 172.101, Column (7)).
Section 173.247. In paragraph (c), we would remove Specification DOT 52 and 53 portable tanks as authorized packagings (see § 173.32).
Section 173.306. Consistent with Packing Instruction P201 in the UN Recommendations, we would amend the paragraph (a)(4)(iii) conditions for transporting flammable, non-pressurized gas samples by revising the inner packagings limit from 2.5 L (0.66 gallons) to 5 L (1.3 gallons).
Section 173.315. We would revise paragraphs (a) and (i) to incorporate provisions for the use of UN portable tanks for the transportation of liquefied compressed gases, in addition to the requirements for DOT Specification 51 portable tanks. Revisions would refer to tank instruction T50 (see UN T Codes under § 172.102) for the transportation of liquefied compressed gases in UN portable tanks and would include minor differences in pressure relief device requirements applicable to UN portable tanks.
Part 175
Section 175.10. For consistency with the ICAO Technical Instructions, we are proposing to revise paragraph (a)(10) to clarify that lighters containing “unabsorbed liquid fuel” are prohibited on one's person or in checked or carry-on baggage. We are proposing to revise exclusions for alcoholic beverages as carry-on and checked baggage to impose a per passenger quantity limit and to restrict the exceptions to alcoholic beverages in retail packagings containing not more than 70% alcohol. We are proposing to revise paragraph (a)(16) to exclude alcoholic beverages. Also, we are proposing to add new paragraph (a)(17) to specify that alcoholic beverages containing more than 24% and not more than 70% alcohol by volume, when carried by passengers or crew in checked or carry-on baggage, are not subject to the HMR if in retail packagings not exceeding 5 liters (1.3 gallons) with a total net quantity per person of 5 liters (1.3 gallons). These proposed changes are consistent with the ICAO Technical Instructions.
Section 175.33. For harmonization with the ICAO Technical Instructions, we would revise paragraph (a) introductory text to add a requirement that the written pilot notification must be accurate and legible.
Section 175.78. We would revise this section to update and align segregation requirements with recent changes adopted in the ICAO Technical Instructions which were based on a UN decision to remove the distinction between primary and subsidiary risk labels. Separate rows and columns would be provided for Divisions 5.1 and 5.2. We would add a new provision to clarify that packages with multiple risks would not need to be segregated from other packages bearing the same UN number.
Section 175.85. Consistent with a new provision adopted in the ICAO Technical Instructions, we would revise paragraph (a) to authorize main deck Class C cargo compartments. Currently, hazardous materials may be carried in a main deck cargo compartment of a passenger aircraft provided the compartment is inaccessible to passengers and it meets certification requirements for a Class B cargo compartment. (Class C cargo compartments differ from Class B cargo compartments in that Class C compartments are required to have a built-in fire extinguishing system, in Start Printed Page 63301addition to smoke or fire detection systems.)
Part 176
Section 176.2. In conjunction with the proposal to incorporate a requirement for vessel cargo to be in compliance with the INF Code (see § 176.720), we would add a definition for “INF cargo” under the § 176.2 definitions.
Section 176.63. For the stowage of Class 1 (explosive) materials on board a vessel, we would add a stowage location definition for “closed cargo transport unit.” This proposed addition coincides with the proposed addition of the vessel stowage category definitions contained in Amendment 30 to the IMDG Code. (See § 172.101(k).)
Section 176.84. Consistent with the IMDG Code we would revise paragraph (b) Table of provisions and paragraph (c)(2) stowage provisions. In the paragraph (b) Table of provisions, we would add two new stowage provisions for assignment to the entries, “Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen),” “Calcium hypochlorite, hydrated or Calcium hypochlorite hydrated mixtures with not less than 5.5 percent but not more than 10 percent water,” and “Calcium hypochlorite mixtures, dry with more than 10 percent but not more than 39 percent available chlorine.” In the paragraph (c)(2), we would revise the list of notes for the stowage of Class 1 (explosive) material provisions.
Section 176.128. We would make an editorial change in § 176.128(c) by correcting an identification number.
Section 176.136. We would make an editorial change in § 176.136 by removing the word “portable.”
Section 176.142. Based on a comment from the National Cargo Bureau, Inc., in § 176.142, paragraph (a), we would revise the list of hazardous materials that may not be transported in a vessel carrying Class 1 (explosive) materials to reflect the most current proper shipping names and to add one extremely flammable material, “Methyl phosphonous dichloride, pyrophoric liquid,” NA2845.
Section 176.720. We would add a new section to require a vessel carrying INF cargo in international transportation to comply with the “International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships,” (INF Code, 1998, English edition). The INF Code was adopted by the International Maritime Safety Committee and will be effective January 1, 2001 under the IMDG Code.
Part 177
Section 177.848. In paragraph (g)(3)(vi), we inadvertently added the terms “special stowage” and “stowed” from the corresponding vessel section of the HMR (§ 174.81) under HM-215C (64 FR 10742). In this NPRM, we propose to correct the wording by removing “special stowage,” which is not applicable to this section, and replacing “stowed” with “loaded, transported and stored.” We received a joint petition from the American Trucking Associations (ATA) and the Institute of Makers of Explosives (IME) (P-1396) requesting additional clarification of this paragraph. The paragraph reads:
“(vi) “6” means explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of compatibility groups C, D and E, provided no explosive substances are carried in the same vehicle.”
In this paragraph and the corresponding paragraph in § 174.81, the petitioners request that the word “other” be inserted before the wording “explosive substances.” However, there is a distinction between the words “articles” and “substances.” This paragraph pertains to certain explosive articles allowed to be stowed if no explosive substances (not articles) are carried on the same vehicle.
Part 178
Section 178.273. We are proposing to add a new section by moving the current requirements for the approval of Specification portable tanks from § 173.32a to the proposed § 178.273. These current approval provisions will precede the requirements for UN portable tanks (as proposed in §§ 178.274 through 178.277).
Sections 178.274, 178.275, 178.276 and 178.277. Based on the eleventh revised edition of the UN Recommendations, we are proposing to incorporate four new sections into the HMR for the UN portable tank requirements. This proposed action is based on our own initiative and responds to a petition for rulemaking (P-1373). The requirements apply to the design and construction of portable tanks. The IMO Dangerous Goods, Solid Cargoes and Containers (DSC) Sub-Committee agreed to incorporate the new harmonized UN multimodal portable tank requirements into the reformatted IMDG Code, Amendment 30. The reformatted IMDG Code is scheduled to become effective on January 1, 2001. The IMDG Code also includes a provision to allow for the continued use of portable tanks designed and constructed under the current requirements (those in Amendments 29 or previous amendments to the IMDG Code as applicable, depending on the date of construction).
The IMO intends to allow construction under the new requirements on January 1, 2001, on a voluntary compliance basis, with a mandatory compliance date of January 1, 2003. On January 1, 2003, all new portable tanks will be required to be manufactured in accordance with the new requirements. For purposes of harmonization, we are proposing to incorporate the corresponding design, construction and use requirements for UN portable tanks in the HMR. In addition, in § 173.32 we are proposing to provide for the continued use of IM 101, 102 and DOT Specification 51 portable tanks, which is consistent with the provisions adopted by the IMO.
The design and construction requirements for UN portable tanks do not differ significantly from the existing IM 101 and 102 portable tanks and the DOT Specification 51 requirements. In general, the UN requirements are less restrictive. For example, 6 mm (0.2 inches) minimum thickness is required for most portable tanks, as opposed to the current minimum thickness of 6.35 mm (0.3 inches) for IM 101 and 102 portable tanks. While the majority of the proposed changes involve relaxations of the regulatory requirements, there would be implications for portable tank manufacturers, shippers and operators who transport hazardous materials in portable tanks, and efforts would need to be undertaken to familiarize those affected with the differences. For example, we would require UN portable tanks used for the transportation of liquefied compressed gases to be approved by a DOT-designated approval agency, and we would require all UN portable tanks to meet a 4 g impact test. In addition to portable tanks for liquids and liquefied compressed gases, we propose to incorporate requirements for portable tanks that are used to transport refrigerated liquified gases (cryogenic liquids). Currently, requirements for portable tanks used for refrigerated liquefied gases are not specified in the HMR, and we authorize their use only under DOT exemptions. The differences between UN portable tanks and the current portable tank requirements include, but are not limited to the following:
—The proposed definition for portable tank includes multimodal tanks with a capacity of more than 450 liters (118.9 gallons). Previously, IMO Type Start Printed Page 633025 and DOT Specification 51 tanks intended for the transport of liquefied compressed gases were limited to a capacity of more than 1000 liters (264.2 gallons).
—The proposed design temperature range is defined as −40 °C to 50 °C (−40 °F to 122.0 °F). This NPRM also proposes design temperatures to be considered for portable tanks subjected to severe climatic conditions. Current regulations specify −20 °C to 50 °C (−4.0 °F to 122.0 °F).
—The proposed UN leakage test for liquids specifies a test pressure not less than 25% of Maximum Allowable Working Pressure (MAWP). The current HMR requirements specify an internal pressure equivalent to MAWP, but not less than 0.2 bar (20.0 kPa) for liquids.
—The proposed test requires that the design and construction of portable tanks must take into account the effects of fatigue during normal conditions of transport. Currently, this is not required in the HMR.
—The proposed requirements specify an absolute minimum thickness of 3 mm (0.1 inches), regardless of the material used and regardless of whether additional protection is provided.
—A rail impact test of 4 g would be required for all portable tanks meeting the definition of “Container” in the International Convention for Safe Containers (CSC).
—The proposed requirements specify that the test pressure be 1.3 times the design pressure. Currently, under the HMR, DOT 51 portable tanks are required to have a test pressure of 1.5 times the design pressure; however, this is based on the vapor pressure of the hazardous material at 115 °F (46.1 °C), whereas the UN calculates the vapor pressure at 65 °C (149 °F). Therefore, the differences between 1.5 at 46 °C and 1.3 at 65 °C would not be significant.
—The proposed requirements include a figure for thermal conductance for the thermal insulation systems of shells intended for the transport of liquefied compressed gases.
—The proposed requirements include a definition for “Holding time” relevant to portable tanks used for the transportation of refrigerated liquefied gases. This is consistent with current HMR requirements in § 178.338-9 for cargo tanks.
—The proposed requirements specify the effectiveness of the insulation system (heat influx in watts) based on a test using the portable tank.
—The proposal allows the specified minimum values for austenitic steels to be increased by 15% according to recognized material standards when greater values are provided in the material inspection certificates.
—The proposed requirements allow the combined capacity of all pressure relief devices to be sufficient to limit the pressure to 120% of the MAWP for liquefied compressed gases.
—The proposed requirements include a new filling limit for the transport of helium.
Based on the above discussion (§§ 178.273 through 178.277), five new sections are proposed to be added as follows: § 178.273 would be added by moving the current requirements for the approval of Specification portable tanks from § 173.32a and introducing similar requirements for UN portable tanks; § 178.274 would be added for the UN portable tank general design and construction requirements; § 178.275 would be added for the additional specifications for UN portable tanks intended for the transportation of liquid and solid materials of Classes 3 through 9; § 178.276 would be added for the additional requirements for UN portable tanks intended for the transportation of liquefied compressed gases; and § 178.277 would be added for the additional requirements for the design, construction, inspection and testing of UN portable tanks intended for the transport of refrigerated liquefied gases.
Section 178.703. Paragraph (a)(1) would be revised by incorporating a minimum height of 12 mm (0.5 inches) for IBC markings and by adding a requirement to allow use of the “W” mark for approval of equivalent IBC packagings, as provided for in § 178.801(i).
Section 178.705. We are proposing to revise the minimum wall thickness requirements to take into account the capacity of the IBC, as well as the IBC design type.
Section 178.801. In paragraph (i), we are proposing to add an approval provision for the use of large packagings, as defined in § 171.8 of this NPRM, provided the large packagings conform to the construction standards, performance testing and packaging marking as specified in UN Recommendations.
Section 178.812. Based on our own initiative, we would revise paragraph (c)(1) and add a new paragraph (c)(3) to add an alternate method for conducting the top lift test for flexible IBCs. Currently, the proposed alternate method is authorized in several approvals issued by the Associate Administrator.
Part 180
Sections 180.601, 180.603, 180.605. We propose to move the qualification and maintenance requirements for portable tanks to part 180. We believe that these requirements would be more appropriately placed in part 180 along with the qualification and maintenance requirements for cargo tanks, IBCs and tank cars. Therefore, we propose to add a new subpart, subpart G, to part 180 for the qualification and maintenance of portable tanks, and to include the incorporation of UN portable tanks as proposed in this NPRM.
IV. Rulemaking Analyses and Notices
A. Executive Order 12866 and DOT Regulatory Policies and Procedures
This proposed rule is not considered a significant regulatory action under section 3(f) of Executive Order 12866 and, therefore, was not reviewed by the Office of Management and Budget. The proposed rule is not considered a significant rule under the Regulatory Policies and Procedures of the Department of Transportation [44 FR 11034]. Because of the minimal economic impact of this proposed rule, preparation of a regulatory impact analysis or regulatory evaluation is not warranted.
B. Executive Order 13132
This proposed rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13132 (“Federalism”). This proposed rule would preempt State, local and Indian tribe requirements but does not propose any regulation that has substantial direct effects on the States, the relationship between the national government and the States, or the distribution of power and responsibilities among the various levels of government. Therefore, the consultation and funding requirements of Executive Order 13132 do not apply.
The Federal hazardous material transportation law, 49 U.S.C. 5101-5127, contains an express preemption provision (49 U.S.C. 5125(b)) that preempts State, local, and Indian tribe requirements on certain covered subjects. Covered subjects are:
(1) The designation, description, and classification of hazardous materials;
(2) The packing, repacking, handling, labeling, marking, and placarding of hazardous materials;
(3) The preparation, execution, and use of shipping documents related to hazardous materials and requirements related to the number, contents, and placement of those documents; Start Printed Page 63303
(4) The written notification, recording, and reporting of the unintentional release in transportation of hazardous; or
(5) The design, manufacture, fabrication, marking, maintenance, recondition, repair, or testing of a packaging or container represented, marked, certified, or sold as qualified for use in transporting hazardous material.
This proposed rule addresses covered subject items (1), (2), (3), and (5) above and would preempt State, local, and Indian tribe requirements not meeting the “substantively the same” standard. This proposed rule is necessary to incorporate changes already adopted in international standards. If the changes proposed in this NPRM are not adopted in the HMR, U.S. companies, including numerous small entities competing in foreign markets, will be at an economic disadvantage. These companies would be forced to comply with a dual system of regulation. The proposed changes are intended to avoid this result.
Federal hazardous materials transportation law provides at 5125(b)(2) that, if DOT issues a regulation concerning any of the covered subjects, DOT must determine and publish in the Federal Register the effective date of Federal preemption. The effective date may not be earlier than the 90th day following the date of issuance of the final rule and not later than two years after the date of issuance. Thus, RSPA lacks discretion in this area. RSPA proposes that the effective date of Federal preemption will be 180 days from publication of a final rule in this matter in the Federal Register.
C. Executive Order 13084
This proposed rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13084 (“Consultation and Coordination with Indian Tribal Governments”). Because this proposed rule does not significantly or uniquely affect the communities of the Indian tribal governments and does not impose substantial direct compliance costs, the funding and consultation requirements of Executive Order 13084 do not apply.
D. Regulatory Flexibility Act
This proposed rule would incorporate changes introduced in the eleventh revised edition of the UN Recommendations, the 2001-2002 ICAO Technical Instructions, and Amendment 30 to the IMDG Code. It would apply to offerors and carriers of hazardous materials and would facilitate the transportation of hazardous materials in international commerce by providing consistency with international requirements.
The costs associated with this proposed rule are considered to be so minimal as to not warrant preparation of a regulatory impact analysis or regulatory evaluation. The majority of amendments should result in cost savings and would ease the regulatory compliance burden for shippers engaged in international commerce, including trans-border shipments within North America. For example, cost savings will be realized by shippers and carriers as a result of eliminating the differences between primary and subsidiary labels. As a result of this change, it will no longer be necessary to stock two sets of labels for each hazard class. To ease any burden associated with this change, we are proposing a reasonable transition period where labels meeting current and proposed requirements may be used. Other cost savings include: revising minimum thickness requirements for metal IBCs; providing greater harmonization with international regulations and flexibility for IBCs and portable tanks that may be used for the transportation of hazardous materials; authorizing the use of UN portable tanks while retaining current IM 101, 102 and DOT Specification 51 portable tank requirements and authorizations for their use; numerous deletions from the hazardous materials table and the marine pollutant list; more flexible requirements for transporting samples of hazardous materials; authorization to use a single explosives placard when explosives of several compatibility groups are transported in a single freight container or vehicle; several clarifications of existing regulatory requirements; and revised requirements for large lithium batteries which will simplify the regulatory requirements applicable to batteries used in high energy efficient hybrid vehicles. We are proposing immediate voluntary compliance (as of January 1, 2001 or the date of publication of the final rule, whichever occurs first), a delayed effective date and a one-year transition period to allow for training of employees and to ease any burden on entities affected by the proposed amendments. Many companies involved in domestic, as well as global operations, will realize economic benefits as a result of the proposed amendments in this rulemaking. Therefore, I certify that this proposed rule will not, if promulgated, have a significant economic impact on a substantial number of small entities. This certification is subject to modification as a result of a review of comments received in response to this proposal.
E. Paperwork Reduction Act
We have current information collection approvals under OMB No. 2137-0557, Approvals for Hazardous Materials, which expires March 31, 2002, with 18,302 burden hours and $413,737.40 annual costs, and OMB No. 2137-0018, Inspection and Testing of Portable Tanks and Intermediate Bulk Containers, which expires March 31, 2002, with 51,340 burden hours and $10,235,000 annual costs. We believe that this proposed rule may result in minor incremental increases in the annual burden hours and costs. If these proposals are finalized, the current approvals would be revised and resubmitted to OMB for extension and re-approval.
Section 1320.8(d), Title 5, Code of Federal Regulations requires that RSPA provide interested members of the public and affected agencies an opportunity to comment on information collection and recordkeeping requests. This notice identifies information collections that we may submit to OMB for extension and re-approval based on the requirements in this proposed rule. We have revised burden estimates, where appropriate, to reflect current reporting levels or adjustments based on changes in this proposed rule since the information collections were last approved. We estimate that the total information collection and recordkeeping burdens as proposed in this rule would be revised as follows:
OMB No. 2137-0557:
Number of Respondents: 3,518.
Total Annual Responses: 3,869.
Total Annual Burden Hours: 18,381.
Total Annual Burden Cost: $413,737.40.
One-time Annual Start Up Burden Hours: 168.
One-time Annual Start Up Cost: $11,758.50.
Total Responses for First Year: 4,005.
Total Annual Burden Hours for First Year: 18,549.
Total Annual Burden Cost for First Year: $425,495.90.
We specifically request comments on the information collection and recordkeeping burdens associated with developing, implementing, and maintaining these requirements for approval under this proposed rule.
Requests for a copy of the information collection approvals, requests and data should be directed to Deborah Boothe, Office of Hazardous Materials Standards (DHM-10), Research and Special Programs Administration, Room 8102, 400 Seventh Street, SW, Washington, Start Printed Page 63304DC 20590-0001, Telephone (202) 366-8553.
Written comments should be addressed to the Dockets Management System as identified in the ADDRESSES section of this rulemaking. Comments should be received prior to the close of comment period identified in the DATES section of this rulemaking. Under the Paperwork Reduction Act of 1995, no person is required to respond to an information collection unless it displays a valid OMB control number. If these proposed requirements are adopted in a final rule, we will submit the revised information collection and recordkeeping requirements to the Office of Management and Budget for approval.
F. Regulation Identifier Number (RIN)
A regulation identifier number (RIN) is assigned to each regulatory action listed in the Unified Agenda of Federal Regulations. The Regulatory Information Service Center publishes the Unified Agenda in April and October of each year. The RIN number contained in the heading of this document can be used to cross-reference this action with the Unified Agenda.
G. Unfunded Mandates Reform Act
This proposed rule does not impose unfunded mandates under the Unfunded Mandates Reform Act of 1995. It does not result in costs of $100 million or more to either State, local or tribal governments, in the aggregate, or to the private sector, and is the least burdensome alternative that achieves the objective of the rule.
Start List of SubjectsList of Subjects
49 CFR Part 171
- Exports
- Hazardous materials transportation
- Hazardous waste
- Imports
- Incorporation by reference
- Reporting and recordkeeping requirements
49 CFR Part 172
- Education
- Hazardous materials transportation
- Hazardous waste
- Labeling
- Markings
- Packaging and containers
- Reporting and recordkeeping requirements
49 CFR Part 173
- Hazardous materials transportation
- Packaging and containers
- Radioactive materials
- Reporting and recordkeeping requirements
- Uranium
49 CFR Part 174
- Hazardous materials transportation
- Radioactive materials
- Railroad safety
49 CFR Part 175
- Air carriers
- Hazardous materials transportation
- Radioactive materials
- Reporting and recordkeeping requirements
49 CFR Part 176
- Hazardous materials transportation
- Maritime carriers
- Radioactive materials
- Reporting and recordkeeping requirements
49 CFR Part 177
- Hazardous materials transportation
- Motor carriers
- Radioactive materials
- Reporting and recordkeeping requirements
49 CFR Part 178
- Hazardous materials transportation
- Motor vehicle safety
- Packaging and containers
- Reporting and recordkeeping requirements
49 CFR Part 180
- Hazardous materials transportation
- Motor carriers
- Motor vehicle safety
- Packaging and containers
- Railroad safety
- Reporting and recordkeeping requirements
In consideration of the foregoing, 49 CFR Chapter I is proposed to be amended as follows:
Start PartPART 171—GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS
1. The authority citation for part 171 would continue to read as follows:
2. In § 171.7, in the paragraph (a)(3) table:
a. Under the entry “American Society for Testing and Materials”, a new entry would be added in alpha-numeric order;
b. Under the entry “International Atomic Energy Agency (IAEA)”, a new entry would be added in alhabetical order;
c. Under the entry “International Civil Aviation Organization (ICAO)”, the existing entry would be revised;
d. Under the entry “International Maritime Organization (IMO)”, the existing entry would be revised and a new entry would be added in appropriate alphabetical order;
e. Under the entry “International Organization for Standardization”, three new entries would added in appropriate alphabetical/numerical order; and
f. Under the entry “United Nations”, the existing entries would be revised.
The revisions and additions read as follows:
Reference material.(a) Matter incorporated by reference. * * *
(3) Table of material incorporated by reference. * * *
Source and name of material 49 CFR reference * * * * * * * American Society for Testing and Materials * * * * * * * ASTM E 112-96 Standard Test Methods for Determining Average Grain Size, 1996 Edition 178.274 * * * * * * * International Atomic Energy Agency (IAEA) * * * * * * * IAEA, Regulations for the Safe Transport of Radioactive Material, No. ST-1, 1996 Edition 171.12(d) * * * * * * * International Civil Aviation Organization (ICAO) * * * * * * * Technical Instructions for the Safe Transport of Dangerous Goods by Air, DOC 9284-AN/905, 2001-2002 Edition 171.11; 172.191; 172.202; 172.401; 172.512; 172.519; 172.602 Start Printed Page 63305 International Maritime Organization (IMO) * * * * * * * International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes On Board Ships (INF Code) 176.720 International Maritime Dangerous Goods (IMDG) Code, as amended by Amendment 30 (2000 edition) 171.12; 172.401; 172.407; 173.21; 176.2; 176.5; 176.11; 176.27; 176.30. International Organization for Standardization * * * * * * * ISO 1496-3 Series 1 freight containers—Specification and testing, 1996 edition 178.274 * * * * * * * ISO 4126-1 Safety valves Part 1: Safety valves,1991 edition 178.274 * * * * * * * ISO 6892 Metallic materials—Tensile testing, 1984 edition 178.274 * * * * * * * United Nations * * * * * * * UN Recommendations on the Transport of Dangerous Goods, Eleventh Revised Edition (1999) 172.102; 172.401; 172.407; 172.502; 173.1; 173.3; 173.21; 173.22; 173.24; 173.56; 173.57; 173.124; 173.166; 178.500; 178.700. UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Third Revised Edition (1999) 172.102; 173.21; 173.57; 173.58; 173.124; 173.128; 173.166; 173.185. * * * * *3. In § 171.8, the following definitions would be added in appropriate alphabetical order to read as follows:
Definitions and abbreviations.* * * * *Large packaging means a packaging that—
(1) Consists of an outer packaging which contains articles or inner packagings; and
(2) Is designed for mechanical handling; and
(3) Exceeds 400 kg net mass or 450 liters (118.9 gallons) capacity and has a volume of not more than 3 m3. (See § 178.801(i) of this subchapter); and.
(4) Conforms to the requirements for the construction, testing and marking of large packagings as specified in the UN Recommendations.
* * * * *Liner means a separate tube or bag inserted into a packaging, (including IBCs and large packagings) but not forming an integral part of the packaging, including the closures of the packaging's openings.
* * * * *Stabilized means that the hazardous material is in a condition that precludes uncontrolled reaction. This may be achieved by methods such as adding an inhibiting chemical, degassing the hazardous material to remove dissolved oxygen and inerting the air space in the package, or maintaining the hazardous material under temperature control.
* * * * *UN portable tank means a multimodal tank having a capacity of more than 450 liters (118.9 gallons). It includes a shell fitted with service equipment and structural equipment, including stabilizing members external to the shell and skids, mountings or accessories to facilitate mechanical handling. The UN portable tank must be capable of being filled and discharged without the removal of its structural equipment and must be capable of being lifted when full. Cargo tanks, rail tank car tanks, non-metallic tanks and IBCs and packagings made to cylinder specifications are not UN portable tanks.
* * * * *4. In § 171.10, in the paragraph (c)(2) Table of Conversion Factors for SI Units, a unit of measure would be added as the last entry to read as follows:
Units of measure.* * * * *(c) * * *
(2) * * *
Table of Conversion Factors for SI Units
Measurement SI to U.S. standard U.S. standard to SI * * * * * * * Force 1 Newton = 9.807 pound-force 1 Pound-force = 0.1020N. * * * * *5. In § 171.11, a new paragraph (d)(17) would be added to read as follows:
Use of ICAO Technical Instructions.* * * * *(d) * * *
(17) An organic peroxide that is not identified by technical name in the Organic Peroxide Table in § 173.225(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
6. In § 171.12, in paragraph (b)(3), a sentence would be added at the end of the paragraph, a new paragraph (b)(19) would be added, and paragraphs (d) Start Printed Page 63306heading and introductory text and (d)(4) would be revised to read as follows:
Import and export shipments.* * * * *(b) * * *
(3) * * * A viscous flammable liquid which is excepted from the requirements of the IMDG Code based on having a flash point of 23 °C (73.4 °F) or greater and less than or equal to 60.5 °C (140.9 °F), not meeting the toxic or corrosive definitions, not containing more than 20% nitrocellulose, and being packed in receptacles of less than 450 liters (118.9 gallons) capacity, may not be transported under the provisions of this section and is subject to the requirements of this subchapter.
* * * * *(19) An organic peroxide that is not identified by technical name in the Organic Peroxide Table in § 173.225(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
* * * * *(d) Use of International Atomic Energy Agency (IAEA) regulations for Class 7 (radioactive) materials. Class 7 (radioactive) materials being imported into or exported from the United States, or passing through the United States in the course of being shipped between places outside the United States, may be offered and accepted for transportation when packaged, marked, labeled, and otherwise prepared for shipment in accordance with IAEA “Regulations for the Safe Transport of Radioactive Material,” Safety Series No. 6, 1985 edition, or ST-1, 1996 edition (incorporated by reference, see § 171.7), if:
* * * * *(4) The country of origin for the shipment has adopted the corresponding edition (Safety Series No. 6, 1985 Edition, or ST-1, 1996 Edition) of the IAEA “Regulations for the Safe Transport of Radioactive Material”;
* * * * *7. In § 171.12a, a new paragraph (b)(18) would be added to read as follows:
Canadian shipments and packagings.* * * * *(b) * * *
(18) An organic peroxide that is not identified by technical name in the Organic Peroxide Table in § 173.225(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
8. In § 171.14, paragraphs (d) introductory text, (d)(1) and (d)(2) introductory text would be revised and a new paragraph (d)(4) would be added to read as follows:
Transitional provisions for implementing certain requirements.* * * * *(d) A final rule published in the Federal Register on [publication date of final rule], effective October 1, 2001, resulted in revisions to this subchapter. During the transition period provided in paragraph (d)(1) of this section, a person may elect to comply with either the applicable requirements of this subchapter in effect on September 30, 2001, or the requirements published in the [publication date of final rule] final rule.
(1) Transition dates. The effective date of the [publication date of final rule] final rule is October 1, 2001. A delayed compliance date of October 1, 2002 is authorized. On October 1, 2002, all applicable regulatory requirements adopted in the [publication date of final rule] final rule must be met.
(2) Intermixing old and new requirements. Prior to the transition date in paragraph (d)(1) of this section, it is recommended that the hazard communication requirements be consistent where practicable. Marking, labeling, placarding, and shipping paper descriptions should conform to either the old requirements of this subchapter in effect on September 30, 2001, or the new requirements of this subchapter in the [publication date of final rule] final rule without intermixing communication elements. However, intermixing is permitted, during the applicable transition period, for packaging, hazard communication, and handling provisions, as follows:
* * * * *(4) Until January 1, 2010, a hazardous material may be transported in an IM or IMO portable tank in accordance with the T Codes (special provisions) assigned to a hazardous material in Column (7) of the HMT in effect on September 30, 2000.
PART 172—HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND TRAINING REQUIREMENTS
9. The authority citation for part 172 would continue to read as follows:
10. In § 172.101, paragraph (c)(11) would be revised and new paragraphs (c)(16) and (k)(6) through (k)(20) would be added to read as follows:
Purpose and use of hazardous materials table.* * * * *(c) * * *
(11) Except for a material subject to § 173.21, § 173.54, § 173.56(d), § 173.56(e)(1), § 173.124(a)(2)(iii) or § 173.128(c) of this subchapter, a hazardous waste or a sample of a material for which the hazard class is uncertain and must be determined by testing, may be assigned a tentative proper shipping name, hazard class/division, identification number, and packing group, if applicable, based on the shipper's tentative determination according to: Defining criteria in this subchapter; the hazard precedence prescribed in § 173.2a of this subchapter; and the shippers knowledge of the material. In addition, a sample of material that is to be tested is subject to the following requirements:
(i) A sample may not be an explosive, infectious substance, or radioactive material;
(ii) Except when the word “Sample” already appears in the proper shipping name, the word “Sample” must appear before the proper shipping name for the sample;
(iii) If the proper shipping description for a sample is assigned a “G” in Column (1) of the HMT, the provisions requiring a technical name for the constituent(s) do not apply;
(iv) A sample must be transported in a combination packaging which conforms to the requirements of this subchapter that are applicable to the tentative Packing Group assigned, and may not exceed a net mass of 2.5 kg. (5.5 pounds) per package;
(v) A sample may not be packed together with any other hazardous material;
(vi) For a sample that is a self-reactive material, the requirements in § 173.224(c)(3) apply; and
(vii) For a sample that is an organic peroxide, the requirements in § 173.225(c)(2) must be met.
* * * * *(16) Unless it is already included in the proper shipping name in the Table, the qualifying words “liquid” or “solid” may be added in association with the proper shipping name when a hazardous material specifically listed by name in the Table may, due to the differing physical states of the various isomers of the material, be either a liquid or a solid (for example “Dinitrotoluenes, liquid” and “Dinitrotoluenes, solid”). Use of the words “liquid” or “solid” is subject to Start Printed Page 63307the limitations specified for the use of the words “mixture” or “solution” in paragraph § 172.101(c)(10) of this section. The qualifying word “molten” may be added in association with the proper shipping name when a hazardous material, which is a solid in accordance with the definition in § 171.8 of this subchapter, is offered for transportation in the molten state (for example, “Alkylphenols, solid, n.o.s., molten”).
* * * * *(k) * * *
(6) Stowage category “01” means the material may be stowed “on deck” or “under deck” on a cargo vessel (up to 12 passengers) and on a passenger vessel.
(7) Stowage category “02” means the material may be stowed “on deck” or “under deck” on a cargo vessel (up to 12 passengers) and “on deck” in closed cargo transport units or “under deck” in closed cargo transport units on a passenger vessel.
(8) Stowage category “03” means the material may be stowed “on deck” or “under deck” on a cargo vessel (up to 12 passengers) and “on deck” in closed cargo transport units on a passenger vessel.
(9) Stowage category “04” means the material may be stowed “on deck” or “under deck” on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel.
(10) Stowage category “05” means the material may be stowed “on deck” in closed cargo transport units or “under deck” on a cargo vessel (up to 12 passengers) and on a passenger vessel.
(11) Stowage category “06” means the material may be stowed “on deck” in closed cargo transport units or “under deck” on a cargo vessel (up to 12 passengers) and “on deck” in closed cargo transport units or “under deck” in closed cargo transport units on a passenger vessel.
(12) Stowage category “07” means the material may be stowed “on deck” in closed cargo transport units or “under deck” on a cargo vessel (up to 12 passengers) and “on deck” only in closed cargo transport units on a passenger vessel.
(13) Stowage category “08” means the material may be stowed “on deck” in closed cargo transport units or “under deck” on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel.
(14) Stowage category “09” means the material may be stowed “on deck” in closed cargo transport units or “under deck” in closed cargo transport units on a cargo vessel (up to 12 passengers) and on a passenger vessel.
(15) Stowage category “10” means the material may be stowed “on deck” in closed cargo transport units or “under deck” in closed cargo transport units on a cargo vessel (up to 12 passengers) and “on deck” only in closed cargo transport units on a passenger vessel.
(16) Stowage category “11” means the material may be stowed “on deck” in closed cargo transport units or “under deck” in magazine stowage type “c” on a cargo vessel (up to 12 passengers) and “on deck” only in closed cargo transport units on a passenger vessel.
(17) Stowage category “12” means the material may be stowed “on deck” in closed cargo transport units or “under deck” in magazine stowage type “c” on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel.
(18) Stowage category “13” means the material may be stowed “on deck” in closed cargo transport units or “under deck” in magazine stowage type “A” on a cargo vessel (up to 12 passengers) and “on deck” only in closed cargo transport units on a passenger vessel.
(19) Stowage category “14” means the material may be stowed “on deck” in closed cargo transport units on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel.
(20) Stowage category “15” means the material may be stowed “on deck” in closed cargo transport units or “under deck” in closed cargo transport units on a cargo vessel (up to 12 passengers) but the material is prohibited on a passenger vessel.
* * * * *11. In § 172.101, the Hazardous Materials Table would be amended by removing, adding, or revising, in appropriate alphabetical sequence, the following entries to read as follows:
Purpose and use of hazardous materials table.* * * * *Start Printed Page 63308§ 172.101 Hazardous Materials Table
Symbols Hazardous materials descriptions and proper shipping names Hazard class or division Identification Nos. PG Label codes Special provisions (8) Packaging (§ 173.***) (9) Quantity limitations (10) Vessel stowage Exceptions Non-bulk Bulk Passenger aircraft/rail Cargo aircraft only Location Other (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B) * * * * * * * [REMOVE:] Accumulators, pressurized, pneumatic or hydraulic (containing non-flammable gas.) NA1956 Aldrin, liquid (PG II) NA2762 Aldrin, solid (PG II) NA2761 Antimony tribromide, solids (PG II) NA1549 Antimony tribromide, solution (PG II) NA1549 Antimony trifluoride, solution (PG II) NA1549 Antimony trifluoride, solution (PG) NA1549 Arsenic sulfide (PG II) NA1557 Arsenic trisulfide (PG II) NA1557 Barium styphnate (PG II) NA0473 Calcium arsenite, solid (PG II) NA1574 Start Printed Page 63309 Chromic acid, solid (PG II) NA1463 Denatured alcohol (PG I, II, III) NA1986 Denatured alcohol (PG I, II, III) NA1987 Dichlorobutene (PG I) NA2920 D Dieldrin (PG II) NA2761 D Diesel fuel NA1993 Dodecylbenzene-sulfonic acid (PG II) NA2584 Gasohol gasoline mixed with ethyl alcohol, with not more than 20 percent alcohol. (PG II) NA1203 Grenades, empty primed (PG II) NA0349 Insecticide gases flammable n.o.s NA1954 Isobutyric anhydride (PG III) UN2530 Lead mono-nitroresorcinate (PG II) NA0473 Lighters for cigars, cigarettes, etc., with lighter fluids. (PG II) NA1226 Maleic acid (PG III) NA2215 Start Printed Page 63310 Medicines, corrosive, liquid, n.o.s. (PG II, III) NA1760 Medicines, corrosive, solid, n.o.s. (PG II, III) NA1759 Medicines, flammable, liquid, n.o.s. (PG I, II, III) NA1993 Medicines, flammable, solids, n.o.s. (PG II) NA1325 Medicines, oxidizing substance, solid, n.o.s. (PG II) NA1479 Metal alkyl, solution, n.o.s. (PG II) NA9195 Methacrylic acid, inhibited (PG III) UN2531 Methyl parathion liquid (PG II) NA3018 Methyl parathion solid (PG II) NA2783 Start Printed Page 63311 Organic perioxide type F, solid temperature controlled. (PG III only) UN3120 Parathion (PG I, II) NA2783 Picric acide, wet, with not less than 10 percent water. (PG I) NA1344 Propargyl alcohol (PG II) NA1986 Refrigerating machine (PG III) NA1993 Refrigerating machines, containing flammable, non-poisonous, liquefied gas NA1954 Selenium oxide (PG I) NA2811 Sodium hydrosulfide, solution (PG II) NA2922 Sodium selenite (PG II) NA2630 Sulfur trioxide, uninhibited (PG I) NA1829 Tetraethyl lead, liquid (PG I) NA1649 Tetraethyl pyrophosphate, liquid (PG I) NA3018 Start Printed Page 63312 Tetraethyl pyrophosphate solid (PG II) NA1707 Titanium sulfate solution (PG II) NA1760 mon-(Trichloro) tetra- (monopotassium dichloro)-panta-s-triazinetrione, dry (with more than 39 percent available chlorine). (PG II) NA2468 Oxygen generator, checmical UN3356 Zirconium sulfate (PG III) NA9163 * * * * * * * [ADD:] * * * * * * * Aircraft engines (including turbines), see Engines, internal combustion * * * * * * * Diesel fuel, see Gas oil 3 NA1883 III None B1 150 203 242 60 L 220 L A Start Printed Page 63313 * * * * * * * Fuel system components (including fuel control units (FCU), carburetor, fuel lines, fuel pumps) see Dangerous Goods in Apparatus or Dangerous Goods in Machinery * * * * * * * Methacrylic acid, stabilized 8 UN2531 II 8 T14 154 202 242 1 L 30 L A * * * * * * * Nitroglycerin mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin, by mass 3 UA3357 II 3 142 None 202 243 5 L 60 L E Start Printed Page 63314 * * * * * * * Oxygen generator, chemical (including when contained in associated equipment, e.g., passenger service units (PSUs), portable breathing equipment (PBE), etc.) 5.1 UN3356 II 5.1 60.A51 None 212 None Forbidden 25 kg gross D 56, 58, 69, 106 Propellant, solid 1.4C UN0501 1.4C None 62 None Forbidden Forbidden A 24E * * * * * * * I Radioactive material, excepted package—articles manufactured from natural uranium or depleted uranium or natural thorium 7 UN2909 None 422, 426 422, 426 422, 426 A * * * * * * * I Radioactive material, excepted package—empty packaging 7 UN2908 Empty 422, 428 422, 428 422, 428 A Start Printed Page 63315 * * * * * * * I Radioactive material, excepted package—instruments or articles 7 UN2911 None 422, 424 422, 424 422, 424 A * * * * * * * I Radioactive material, low specific activity (LSA-I) non fissile or fissile-excepted 7 UN2912 7 W7 421, 422, 428 427 427 A 95 * * * * * * * I Radioactive material, low specific activity (LSA-II) non fissile or fissile-excepted 7 UN3321 7 W7 421, 422, 428 427 427 A 95 * * * * * * * I Radioactive material, low specific activity (LSA-III) non fissile or fissile excepted 7 UN3322 7 W7 421, 422, 428 427 427 A 95 * * * * * * * I Radioactive material, surface contaminated objects (SCO-I or SCO-II) non fissile or fissile-excepted 7 UN2913 7 421, 422, 428 427 427 A 95 Start Printed Page 63316 * * * * * * * I Radioactive material, transported under special arrangement, fissile 7 UN3331 7 139 * * * * * * * I Radioactive material, transported under special arrangement non fissile or fissile-excepted 7 UN2919 7 139 * * * * * * * I Radioactive material, Type A package, fissile non-special form 7 UN3327 7 W7, W8 453 417 417 A 95 * * * * * * * I Radioactive material, Type A package non-special form, non fissile or fissile-excepted 7 UN2915 7 W7, W8 415 415 A 95 Start Printed Page 63317 * * * * * * * I Radioactive material, Type A package, special form non fissile or fissile-excepted 7 UN3332 7 W7, W8 415, 476 415, 476 A 95 * * * * * * * I Radioactive material, Type A package, special form, fissile 7 UN3333 7 W7, W8 453 417, 476 417, 476 A * * * * * * * I Radioactive material, Type B(M) package, fissile 7 UN3329 7 453 417 417 A * * * * * * * I Radioactive material, Type B(M) package non fissile or fissile-excepted 7 UN2917 7 416 416 A 95 * * * * * * * I Radioactive material, Type B(U) package, fissile 7 UN3328 7 453 417 417 A * * * * * * * I Radioactive material, Type B(U) package non fissile or fissile-excepted 7 UN2916 7 416 416 A 95 I Radioactive material, uranium hexafluoride non fissile or fissile-excepted 7 UN2978 7,8 423 420, 427 420, 427 A 95 Start Printed Page 63318 * * * * * * * I Radioactive material, uranium hexafluoride, fissile 7 UN2977 7,8 453 417, 420 417, 420 A * * * * * * * Refrigerating Machines containing flammable, nontoxic, liquefied gas 2.1 UN3358 2.1 306 306 306 Forbidden Forbidden C 40 * * * * * * * Rockets with inert head 1.2C UN0502 1.2 None 62 None Forbidden Forbidden B 1E, 5E * * * * * * * 1H-Tetrazole 1.1D UN0504 1.1D None 62 None Forbidden Forbidden B 1E, 5E * * * * * * * [REVISE:] * * * * * * * Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen) 5.1 UN1748 ll 5.1 A7, A9, N34, W9 152 212 None 5 kg 25 kg D 4, 5, 25, 48, 56, 58, 69 Start Printed Page 63319 Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not less than 5.5 percent but not more than 10 percent water 5.1 UN2880 ll 5.1 W9 152 212 240 5 kg 25 kg D 4, 5, 25, 48, 56, 58, 69 Calcium hypochlorite mixtures, dry with more than 10 percent but not more than 39 percent available chlorine 5.1 UN2208 lll 5.1 A1, A29, N34, W9 152 213 240 25 kg 100 kg D 4, 5, 25, 48, 56, 58, 69 * * * * * * * Dangerous Goods in Machinery or Dangerous Goods in Apparatus 9 UN3363 136 None 222 None No limit No limit A * * * * * * * Fire extinguishers containing 2.2 UN1044 2.2 18, 110 309 309 None 75 kg 150 kg A Magnesium granules, coated, particle size not less than 149 4.3 UN295- lll 4.3 128, A1, A19, B108, B115 151 213 240 25 kg 100 kg A * * * * * * * +, l Methanol 3 UN1230 ll 3, 6.1 T8 150 202 242 1 L 60 L B 40 * * * * * * * Morpholine 8 UN2054 l 8, 3 T17 None 201 243 .5L 2.5L C 25, 40 Start Printed Page 63320 * * * * * * * G Pyrophoric organometallic compound, water-reactive, n.o.s 4.2 UN3203 l 4.2, 4.3 T28, T40 None 187 242 Forbidden Forbidden D 18 * * * * * * * D Radioactive material, excepted package—articles manufactured from natural or depleted uranium or natural thorium 7 UN2910 None 422, 426 422, 426 422, 426 A * * * * * * * D Radioactive material, excepted package—empty package or empty packaging 7 UN2910 empty 428 428 428 A * * * * * * * D Radioactive material, excepted package—instruments or articles 7 UN2910 None 422, 424 422, 424 422, 424 A * * * * * * * D Radioactive material, fissile, n.o.s 7 UN2918 7 453 417 417 A 40, 95 Start Printed Page 63321 * * * * * * * D Radioactive material, low specific activity, n.o.s. or Radioactive material, LSA, n.o.s. 7 UN2912 7 421, 428 427 427 A * * * * * * * D Radioactive material, n.o.s 7 UN2982 7 421, 428 415, 416 415, 416 A 40, 95 * * * * * * * D Radioactive material, special form n.o.s 7 UN2974 7 421, 424 415, 416 415, 416 A * * * * * * * Regulated medical waste 6.2 UN3291 II 6.2 A13, A14 134 197 None No limit No limit E * * * * * * * D Radioactive material, surface contaminated object or Radioactive material SCO 7 UN2913 7 421, 424, 426 427 427 A * * * * * * * D Thorium metal, pyrophoric 7 UN2975 7,4.2 None 418 None Forbidden Forbidden D * * * * * * * D Thorium nitrate, solid 7 UN2976 7,5.1 None 419 None Forbidden 15 kg A * * * * * * * D Uranium hexafluoride, fissile excepted or non-fissile 7 UN2978 7,8 423 420, 427 420, 427 Start Printed Page 63322 * * * * * * * D Uranium, hexafluoride, fissile (with more than 1 percent U-235) 7 UN2977 7, 8 453 417, 420 417, 420 A * * * * * * * D Uranium metal, pyrophoric 7 UN2979 7,4.2 None 418 None D * * * * * * * D Uranyl nitrate hexahydrate solution 7 UN2980 7, 8 421, 427 415, 416, 417 415, 416, 417 D * * * * * * * D Uranyl nitrate, solid 7 UN2981 7,5.1 None 419 None Forbidden 15 kg A * * * * * * * Start Printed Page 63323End Part[Amended]12. In addition, in the § 172.101 Hazardous Materials Table, the following changes would be made:
a. In Column (1), a “G” would be added for the entries, “Other regulated substances, liquid, n.o.s.” and “Other regulated substances, solid, n.o.s.”
b. In Column (2), the following proper shipping names would be revised as follows:
Current column 2 entry Revise to read: Lithium hypochlorite, dry or Lithium hypochlorite mixtures, dry Lithium hypochlorite, dry with more than 39% available chlorine (8.8% available oxygen) or Lithium hypochlorite mixtures, dry with more than 39% available chlorine (8.8% available oxygen). Nitrocellulose membrane filters Nitrocellulose membrane filters, with not more than 12.6% nitrogen, by dry mass. Printing ink, flammable Printing ink, flammable or Printing ink related material (including printing ink thinning or reducing compound), flammable. c. In Column (2), for the following entries, the word “inhibited” would be revised to read “stabilized”:
Acrolein, inhibited Acrylic acid, inhibited Acrylonitrile, inhibited Bicyclo [2,2,1] hepta-2, 5-diene, inhibited or 2,5-Norbornadiene, inhibited. Butadienes, inhibited Butyl acrylates, inhibited n-Butyl methacrylates, inhibited. Butyl vinyl ether, inhibited Chloral, anhydrous, inhibited Chloroprene, inhibited Cyanogen chloride, inhibited Diketene, inhibited Divinyl ether, inhibited Ethyl acrylate, inhibited Ethylacetylene, inhibited Ethyleneimine, inhibited Isobutyl acrylate, inhibited Isobutyl methacrylate, inhibited Isoprene, inhibited Methacrylaldehyde, inhibited Methacrylic acid, inhibited Methacrylonitrile, inhibited Methyl acrylate, inhibited Methyl isopropenyl ketone, inhibited. Methyl methacrylate monomer, inhibited. Propadiene, inhibited Propyleneimine, inhibited Styrene monomer, inhibited Tetrafluoroethylene, inhibited Trifluorochloroethylene, inhibited Vinyl acetate, inhibited Vinyl bromide, inhibited Vinyl butyrate, inhibited Vinyl ethyl ether, inhibited Vinyl fluoride, inhibited Vinyl isobutyl ether, inhibited Vinyl methyl ether, inhibited Vinyl chloride, inhibited or Vinyl chloride, stabilized Vinylidene chloride, inhibited Vinylpyridines, inhibited Vinyltoluene, inhibited Vinyltrichlorosilane, inhibited d. In Column (7), the following entry would be revised as follows:
Column (2) entry Column (7) entry Revise to read Life-saving appliances, not self inflating containing dangerous goods as equipment 143 e. In Column (7), the following entries would be revised as follows:
Note to reader:
The following Table is listed in numerical order according to the UN identification number. Columns 10 and 11 are proposed special provisions for IBCs. Columns 8 and 9 are proposed special provisions for portable tanks. If adopted, these four columns would appear in the Special Provisions column (Column (7)) of the § 172.101 Hazardous Materials Table.
Start Printed Page 63324Start Printed Page 63391Table Showing Proposed Portable Tank and IBC Authorizations
UN No. Name/Description Class PG Label(s) Special provisions Bulk section 173.xxx Portable tank instruction Port.Tank special provisions IBC code IBC special provisions 1003 Air, refrigerated liquid, (cryogenic liquid) non-pressurized 2.2 2.2, 5.1 318, 319 T75 TP22 1003 Air, refrigerated liquid, (cryogenic liquid) 2.2 2.2, 5.1 318, 319 T75 TP22 1005 Ammonia, anhydrous 2.2 2.2 13 314, 315 T50 1005 Ammonia, anhydrous 2.3 2.3, 8 4 314, 315 T50 1009 Bromotrifluoromethane or Refrigerant gas, R 13B1 2.2 2.2 314, 315 T50 1010 Butadienes, inhibited 2.1 2.1 314, 315 T50 1011 Butane see also Petroleum gases, liquefied 2.1 2.1 19 314, 315 T50 1012 Butylene see also Petroleum gases, liquefied 2.1 2.1 19 314, 315 T50 1017 Chlorine 2.3 2.3, 8 2, B9, B14 314, 315 T50 TP19 1018 Chlorodifluoromethane or Refrigerant gas R 22 2.2 2.2 314, 315 T50 1020 Chloropentafluoroethane or Refrigerant gas R 115 2.2 2.2 314, 315 T50 1021 1-Chloro-1,2,2,-tetrafluoroethane or Refrigerant gas R 124 2.2 2.2 314, 315 T50 1027 Cyclopropane 2.1 2.1 314, 315 T50 1028 Dichlorodifluoromethane or Refrigerant gas R 12 2.2 2.2 314, 315 T50 1029 Dichlorofluoromethane or Refrigerant gas R 21 2.2 2.2 314, 315 T50 1030 1,1-Difluoroethane or Refrigerant gas R 152a 2.1 2.1 314, 315 T50 1032 Dimethylamine, anhydrous 2.1 2.1 314, 315 T50 1033 Dimethyl ether 2.1 2.1 314, 315 T50 1036 Ethylamine 2.1 2.1 B77 314, 315 T50 1037 Ethyl chloride 2.1 2.1 B43, B77 314, 315 T50 1038 Ethylene, refrigerated liquid (cryogenic liquid) 2.1 2.1 318, 319 T75 1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C 2.3 2.3, 2.1 4 323 T50 TP20 1041 Ethylene oxide and carbon dioxide mixtures with more than 9 percent but not more than 87 percent ethylene oxide 2.1 2.1 314, 315 T50 1052 Hydrogen fluoride, anhydrous 8 l 8, 6.1 3, B7, B46, B71, B77, T24, T27 243 T10 TP2 1055 Isobutylene see also Petroleum gases, liquefied 2.1 2.1 19 314, 315 T50 1060 Methyl acetylene and propadiene mixtures, stabilized 2.1 2.1 314, 315 T50 1061 Methylamine, anhydrous 2.1 2.1 314, 315 T50 1062 Methyl bromide 2.3 2.3 3, B14 314, 315 T50 1063 Methyl chloride or Refrigerant gas R 40 2.1 2.1 314, 315 T50 Start Printed Page 63325 1064 Methyl mercaptan 2.3 2.3, 2.1 3, B7, B9, B14 314, 315 T50 1067 Dinitrogen tetroxide 2.3 2.3, 5.1, 8 1, B7, B14, B45, B46, B61, B66, B67, B77 314 T50 TP21 1073 Oxygen, refrigerated liquid (cryogenic liquid) 2.2 2.2, 5.1 318 T75 TP22 1075 Petroleum gases, liquefied or Liquefied petroleum gas 2.1 2.1 314, 315 T50 1077 Propylene see also Petroleum gases, liquefied 2.1 2.1 19 314, 315 T50 1078 Refrigerant gases, n.o.s. 2.2 2.2 314, 315 T50 1079 Sulfur dioxide 2.3 2.3, 8 3, B14 314, 315 T50 TP19 1082 Trifluorochloroethylene, inhibited 2.3 2.3, 2.1 3, B14 314, 315 T50 1083 Trimethylamine, anhydrous 2.1 2.1 314, 315 T50 1085 Vinyl bromide, inhibited 2.1 2.1 314, 315 T50 1086 Vinyl chloride, inhibited or Vinyl chloride, stabilized 2.1 2.1 21, B44 314, 315 T50 1087 Vinyl methyl ether, inhibited 2.1 2.1 B44 314, 315 T50 1088 Acetal 3 ll 3 T7 242 T4 TP1 lB2 1089 Acetaldehyde 3 l 3 A3, B16, T20, T26, T29 243 T11 TP2 TP7 1090 Acetone 3 ll 3 T8 242 T4 TP1 lB2 1091 Acetone oils 3 ll 3 T7, T30 242 T4 TP1 TP8 lB2 1092 Acrolein, inhibited 6.1 l 6.1, 3 1, B9, B14, B30, B42, B72, B77, T38, T43, T44 244 T22 TP2 TP7 TP13 TP38 TP44 1093 Acrylonitrile, inhibited 3 l 3, 6.1 B9, T18, T26 243 T14 TP2 TP13 1098 Allyl alcohol 6.1 l 6.1, 3 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1099 Allyl bromide 3 l 3, 6.1 T18 243 T14 TP2 TP13 1100 Allyl chloride 3 l 3, 6.1 T18, T26 243 T14 TP2 TP13 1104 Amyl acetates 3 lll 3 B1, T1 242 T2 TP1 lB3 1105 Pentanols 3 ll 3 T1 242 T4 TP1 TP29 lB2 1105 Pentanols 3 lll 3 B1, B3, T1 242 T2 TP1 lB3 1106 Amylamines 3 ll 3, 8 T1 243 T7 TP1 lB2 1106 Amylamines 3 lll 3, 8 B1 242 T4 TP1 lB3 1107 Amyl chlorides 3 ll 3 T1 242 T4 TP1 lB2 1108 1-Pentene (n-amylene) 3 l 3 T14 243 T11 TP2 1109 Amyl formates 3 lll 3 B1, T1 242 T2 TP1 lB3 1110 n-Amyl methyl ketone 3 lll 3 B1, T1 242 T2 TP1 lB3 1111 Amyl mercaptans 3 ll 3 A3, T8 242 T4 TP1 lB2 1112 Amyl nitrate 3 lll 3 B1, T1 242 T2 TP1 lB3 1113 Amyl nitrites 3 ll 3 T8 242 T4 TP1 lB2 1114 Benzene 3 ll 3 B101, T8 242 T4 TP1 lB2 1120 Butanols 3 II 3 T1 242 T4 TP1 TP29 IB2 1120 Butanols 3 III 3 B1, T1 242 T2 TP1 IB3 1123 Butyl acetates 3 II 3 T1 242 T4 TP1 IB2 1123 Butyl acetates 3 III 3 B1, T1 242 T2 TP1 IB3 1125 n-Butylamine 3 II 3, 8 B101, T8 242 T7 TP1 IB2 Start Printed Page 63326 1126 1-Bromobutane 3 II 3 T1 242 T4 TP1 IB2 1127 Chlorobutanes 3 II 3 B101, T8 242 T4 TP1 IB2 1128 n-Butyl formate 3 II 3 T1 242 T4 TP1 IB2 1129 Butyraldehyde 3 II 3 T8 242 T4 TP1 IB2 1130 Camphor oil 3 III 3 B1, T1 242 T2 TP1 IB3 1131 Carbon disulfide 3 I 3, 6.1 B16, T18, T26, T29 243 T14 TP2 TP7 TP13 1133 Adhesives, containing a flammable liquid 3 I 3 B42, T7, T30 243 T11 TP1 TP8 TP27 1133 Adhesives, containing a flammable liquid 3 II 3 B52, T7, T30 242 T4 TP1 TP8 IB2 1133 Adhesives, containing a flammable liquid 3 III 3 B1, B52, T7, T30 242 T2 TP1 IB3 1134 Chlorobenzene 3 III 3 B1, T1 242 T2 TP1 IB3 1135 Ethylene chlorohydrin 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1136 Coal tar distillates, flammable 3 II 3 T8, T31 242 T4 TP1 IB2 1136 Coal tar distillates, flammable 3 III 3 B1, T7, T30 242 T4 TP1 TP29 IB3 1139 Coating solution (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 3 I 3 T42 243 T11 TP1 TP8 TP27 1139 Coating solution (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1139 Coating solution (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1143 Crotonaldehyde, stabilized 6.1 I 6.1, 3 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1144 Crotonylene 3 I 3 T20 243 T11 TP2 1145 Cyclohexane 3 II 3 B101, T8 242 T4 TP1 IB2 1146 Cyclopentane 3 II 3 B101, T14 242 T7 TP1 IB2 1147 Decahydronaphthalene 3 III 3 B1, T1 242 T2 TP1 IB3 1148 Diacetone alcohol 3 II 3 T1 242 T4 TP1 IB2 1148 Diacetone alcohol 3 III 3 B1, T1 242 T2 TP1 IB3 1149 Dibutyl ethers 3 III 3 B1, T1 242 T2 TP1 IB3 1150 1,2-Dichloroethylene 3 II 3 T14 242 T7 TP2 IB2 1152 Dichloropentanes 3 III 3 B1, T1 242 T2 TP1 IB3 1153 Ethylene glycol diethyl ether 3 III 3 B1, T1 242 T2 TP1 IB3 1154 Diethylamine 3 II 3, 8 B101, N34, T8 243 T7 TP1 IB2 1155 Diethyl ether or Ethyl ether 3 I 3 T21 243 T11 TP2 1156 Diethyl ketone 3 II 3 T1 242 T4 TP1 IB2 1157 Diisobutyl ketone 3 III 3 B1, T1 242 T2 TP1 IB3 Start Printed Page 63327 1158 Diisopropylamine 3 II 3, 8 B101, T8 243 T7 TP1 IB2 1159 Diisopropyl ether 3 II 3 B101, T8 242 T4 TP1 IB2 1160 Dimethylamine solution 3 II 3, 8 T8, T34 243 T7 TP1 IB2 1161 Dimethyl carbonate 3 II 3 T8 242 T4 TP1 IB2 1162 Dimethyldichlorosilane 3 II 3, 8 B77, T15, T26 243 T7 TP2 TP13 IB2 1163 Dimethylhydrazine, unsymmetrical 6.1 I 6.1, 3, 8 2, B7, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP 45 1164 Dimethyl sulfide 3 II 3 B100, T14 242 T7 TP2 IB1 BB8 1165 Dioxane 3 II 3 T8 242 T4 TP1 IB2 1166 Dioxolane 3 II 3 T8 242 T4 TP1 IB2 1167 Divinyl ether, inhibited 3 I 3 T14 243 T11 TP2 1169 Extracts, aromatic, liquid 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1169 Extracts, aromatic, liquid 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1170 Ethanol or Ethyl alcohol Ethanol solutions or Ethyl alcohol solutions 3 II 3 24, T1 242 T4 TP1 IB2 1170 Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl alcohol solutions 3 III 3 24, B1, T1 242 T2 TP1 IB3 1171 Ethylene glycol monoethyl ether 3 III 3 B1, T1 242 T2 TP1 IB3 1172 Ethylene glycol monoethyl ether 3 III 3 B1, T1 242 T2 TP1 IB3 1173 Ethyl acetate 3 II 3 T2 242 T4 TP1 IB2 1175 Ethylbenzene 3 II 3 T1 242 T4 TP1 IB2 1176 Ethyl borate 3 II 3 T8 242 T4 TP1 IB2 1177 Ethylbutyl acetate 3 III 3 B1, T1 242 T2 TP1 IB3 1178 2-Ethylbutyraldehyde 3 II 3 B1, T1 242 T4 TP1 IB2 1179 Ethyl butyl ether 3 II 3 B1, B101, T1 242 T4 TP1 IB2 1180 Ethyl butyrate 3 III 3 B1, T1 242 T2 TP1 IB3 1181 Ethyl chloroacetate 6.1 II 6.1, 3 T14 243 T7 TP2 IB2 1182 Ethyl chloroformate 6.1 I 6.1, 3. 8 2, A3, A6, A7, B9, B14, B32, B74, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1183 Ethyldichlorosilane 4.3 I 4.3, 8, 3 A2, A3, A7, N34, T18, T26 244 T10 TP2 TP7 TP13 1184 Ethylene dichloride 3 II 3, 6.1 T14 243 T7 TP1 IB2 1185 Ethyleneimine, inhibited 6.1 I 6.1, 3 1, B9, B14, B30, B72, B77, N25, N32, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 1188 Ethylene glycol monomethyl ether 3 III 3 B1, T1 242 T2 TP1 IB3 1189 Ethylene glycol monomethyl ether acetate 3 III 3 B1, T1 242 T2 TP1 IB3 1190 Ethyl formate 3 II 3 T8 242 T4 TP1 IB2 1191 Octyl aldehydes 3 III 3 B1, T1 242 T2 TP1 IB3 1192 Ethyl lactate 3 III 3 B1, T1 242 T2 TP1 IB3 1193 Ethyl methyl ketone or Methyl ethyl ketone 3 II 3 T8 242 T4 TP1 IB2 1195 Ethyl propionate 3 II 3 T1 242 T4 TP1 IB2 1196 Ethyltrichlorosilane 3 II 3, 8 A7, B100, N34, T15, T26 243 T7 TP2 TP13 IB1 1197 Extracts, flavoring, liquid 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 Start Printed Page 63328 1197 Extracts, flavoring, liquid 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1198 Formaldehyde, solutions, flammable 3 III 3, 8 B1, T8 242 T4 TP1 IB3 1199 Furaldehydes 6.1 II 6.1, 3 T15 243 T7 TP2 IB2 1201 Fusel oil 3 II 3 T1 242 T4 TP1 IB2 1201 Fusel oil 3 III 3 B1, T1 242 T2 TP1 IB3 1202 Gas oil or Diesel fuel or Heating oil, light 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1203 Gasoline 3 II 3 B33, B101, T8 242 T4 TP1 IB2 1204 Nitroglycerin solution in alcohol with not more than 1 percent nitroglycerin 3 II 3 N34, T25 None IB2 1206 Heptanes 3 II 3 T2 242 T4 TP1 IB2 1207 Hexaldehyde 3 III 3 B1, T1 242 T2 TP1 IB3 1208 Hexanes 3 II 3 B101, T8 242 T4 TP1 IB2 1210 Printing ink, flammable 3 I 3 T8, T31 243 T11 TP1 TP8 1210 Printing ink, flammable 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1210 Printing ink, flammable 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1212 Isobutanol or Isobutyl alcohol 3 III 3 B1, T1 242 T2 TP1 IB3 1213 Isobutyl acetate 3 II 3 T1 242 T4 TP1 IB2 1214 Isobutylamine 3 II 3, 8 B101, T8 243 T7 TP1 IB2 1216 Isooctenes 3 II 3 T8 242 T4 TP1 IB2 1218 Isoprene, inhibited 3 I 3 T20 243 T11 TP2 1219 Isopropanol or Isopropyl alcohol 3 II 3 T1 242 T4 TP1 IB2 1220 Isopropyl acetate 3 II 3 T1 242 T4 TP1 IB2 1221 Isopropylamine 3 I 3, 8 T20 243 T11 TP2 1222 Isopropyl nitrate 3 II 3 T25 None IB2 BB7 1223 Kerosene 3 III 3 B1, T1 242 T2 TP2 IB3 1224 Ketones, liquid, n.o.s. 3 I 3 T8, T31 243 T11 TP1 TP8 TP27 1224 Ketones, liquid, n.o.s. 3 II 3 T8, T31 242 T7 TP1 TP8 TP28 IB2 1224 Ketones, liquid, n.o.s. 3 III 3 B1, T7, T30 242 T4 TP1 TP29 IB3 1228 Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s 3 II 3, 6.1 T13 243 T11 TP2 TP27 IB2 1228 Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s 3 III 3, 6.1 B1, T8 242 T7 TP1 TP28 IB3 1229 Mesityl oxide 3 III 3 B1, T1 242 T2 TP1 IB3 1230 Methanol 3 II 3 T8 242 T7 TP2 IB2 1230 Methanol 3 II 3, 6.1 T8 242 T7 TP2 IB2 1231 Methyl acetate 3 II 3 B101, T8 242 T4 TP1 IB2 1233 Methylamyl acetate 3 III 3 B1, T1 242 T2 TP1 IB3 1234 Methylal 3 II 3 T14 242 T7 TP2 IB2 BB8 1235 Methylamine, aqueous solution 3 II 3, 8 B1, T8 243 T7 TP1 IB2 1237 Methyl butyrate 3 II 3 T1 242 T4 TP1 IB2 1238 Methyl chloroformate 6.1 I 6.1, 3, 8 1, B9, B14, B30, B72, N34, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 1239 Methyl chloromethyl ether 6.1 I 6.1, 3 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP38 TP44 Start Printed Page 63329 1242 Methyldichlorosilane 4.3 I 4.3, 8, 3 A2, A3, A7, B6, B77, N34, T16, T26 243 T10 TP2 TP7 TP13 1243 Methyl formate 3 I 3 T20 243 T11 TP2 1244 Methylhydrazine 6.1 I 6.1, 3, 8 1, B7, B9, B14, B30, B72, B77, N34, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 1245 Methyl isobutyl ketone 3 II 3 T1 242 T4 TP1 IB2 1246 Methyl isopropenyl ketone, inhibited 3 II 3 T7 242 T4 TP1 IB2 1247 Methyl methacrylate monomer, inhibited 3 II 3 T8 242 T4 TP1 IB2 1248 Methyl propionate 3 II 3 B101, T2 242 T4 TP1 IB2 1249 Methyl propyl ketone 3 II 3 T1 242 T4 TP1 IB2 1250 Methyltrichlorosilane 3 I 3, 8 A7, B6, B77, N34, T14, T26 243 T11 TP2 TP13 1251 Methyl vinyl ketone, stabilized 6.1 I 6.1, 3, 8 1, 25, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 1262 Octanes 3 II 3 T1 242 T4 TP1 IB2 1263 Paint including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base 3 I 3 T8, T31 243 T11 TP1 TP8 1263 Paint related material including paint thinning, drying, removing, or reducing compound 3 I 3 T8, T31 243 T11 TP1 TP8 1263 Paint including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base 3 II 3 B52, T7, T30 242 T4 TP1 TP8 IB2 1263 Paint related material including paint thinning, drying, removing, or reducing compound 3 II 3 B52, T7, T30 242 T4 TP1 TP8 IB2 1263 Paint including paint, lacquer,enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base 3 III 3 B1, B52, T7, T30 242 T2 TP1 IB3 1263 Paint related material including paint thinning, drying, removing, or reducing compound 3 III 3 B1, B52, T7, T30 242 T2 TP1 IB3 1264 Paraldehyde 3 III 3 B1, T1 242 T2 TP1 IB3 1265 Pentanes 3 I 3 T20 243 T11 TP2 1265 Pentanes 3 II 3 T20 242 T4 TP1 IB2 BB8 1266 Perfumery products with flammable solvents 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1266 Perfumery products with flammable solvents 3 III 3 B1, T7, T30 242 T2 TP1 IB3 Start Printed Page 63330 1267 Petroleum crude oil 3 I 3 T8, T31 243 T11 TP1 TP8 1267 Petroleum crude oil 3 II 3 T8, T31 242 T4 TP1 TP8 IB2 1267 Petroleum crude oil 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1268 Petroleum distillates, n.o.s. or Petroleum products, n.o.s 3 I 3 T8, T31 243 T11 TP1 TP8 1268 Petroleum distillates, n.o.s. or Petroleum products, n.o.s 3 II 3 T8, T31 242 T7 TP1 TP8 TP28 IB2 1268 Petroleum distillates, n.o.s. or Petroleum products, n.o.s 3 III 3 B1, T7, T30 242 T4 TP1 TP29 IB3 1272 Pine oil 3 III3 B1, T1 242 T2 TP1 IB3 1274 n-Propanol or Propyl alcohol, normal 3 II 3 B1, T1 242 T4 TP1 IB2 1274 n-Propanol or Propyl alcohol, normal 3 III 3 B1, T1 242 T2 TP1 IB3 1275 Propionaldehyde 3 II 3 T14 242 T7 TP1 IB2 1276 n-Propyl acetate 3 II 3 T1 242 T4 TP1 IB2 1277 Propylamine 3 II 3, 8 N34, T14 243 T7 TP1 IB2 1278 Propyl chloride 3 II 3 N34, T14 242 T7 TP2 IB2 BB8 1279 1,2-Dichloropropane 3 II 3 N36, T1 242 T4 TP1 IB2 1280 Propylene oxide 3 I 3 A3, N34, 243 T11 TP2 TP7 1281 Propyl formates 3 II 3 T8 242 T4 TP1 IB2 1282 Pyridine 3 II 3 T8 242 T4 TP2 IB2 1286 Rosin oil 3 II 3 T7 242 T4 TP1 IB2 1286 Rosin oil 3 III 3 B1, T1 242 T2 TP1 IB3 1287 Rubber solution 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1287 Rubber solution 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1288 Shale oil 3 I 3 T7 243 T11 TP1 TP8 TP27 1288 Shale oil 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1288 Shale oil 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1289 Sodium methylate solutions in alcohol 3 II 3, 8 T8, T31 243 T7 TP1 TP8 IB2 1289 Sodium methylate solutions in alcohol 3 III 3, 8 B1, T7, T30 242 T4 TP1 IB3 1292 Tetraethyl silicate 3 III 3 B1, T1 242 T2 TP1 IB3 1293 Tinctures, medicinal 3 II 3 T8, T31 242 T4 TP1 TP8 IB2 1293 Tinctures, medicinal 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1294 Toluene 3 II 3 T1 242 T4 TP1 IB2 1295 Trichlorosilane 4.3 I 4.3, A7, N34, T24 T26 244 T14 TP2 TP7 1296 Triethylamine 3 II 3, 8 B101, T8 243 T7 TP1 IB2 1297 Trimethylamine, aqueous solutions with not more than 50 percent trimethylamine by mass 3 I 3, 8 T42 243 T11 TP1 1297 Trimethylamine, aqueous solutions with not more than 50 percent trimethylamine by mass 3 II 3, 8 B1, T14 243 T7 TP1 IB2 1297 Trimethylamine, aqueous solutions with not more than 50 percent trimethylamine by mass 3 III 3, 8 B1 242 T7 TP1 IB3 1298 Trimethylchlorosilane 3 II 3, 8 A3, A7, B77, N34, T14, T26 243 T7 TP2 TP13 IB2 1299 Turpentine 3 III 3 B1, T1 242 T2 TP1 IB3 1300 Turpentine substitute 3 I 3 T1 243 T11 TP1 TP1 TP27 1300 Turpentine substitute 3 II 3 T1 242 T4 TP1 IB2 1300 Turpentine substitute 3 III 3 B1, T1 242 T2 TP1 IB3 1301 Vinyl acetate, inhibited 3 II 3 T8 242 T4 TP1 IB2 1302 Vinyl ethyl ether, inhibited 3 I 3 A3, B100, T14 243 T11 TP2 Start Printed Page 63331 1303 Vinylidene chloride, inhibited 3 I 3 T23, T29 243 T12 TP2 TP7 1304 Vinyl isobutyl ether, inhibited 3 II 3 T8 242 T4 TP1 IB2 1305 Vinyltrichlorosilane, inhibited 3 I 3, 8 A3, A7, B6, N34, T14, T26 243 T11 TP2 TP13 1306 Wood preservatives, liquid 3 II 3 T7, T30 242 T4 TP1 TP8 IB2 1306 Wood preservatives, liquid 3 III 3 B1, T7, T30 242 T2 TP1 IB3 1307 Xylenes 3 II 3 T1 242 T4 TP1 IB2 1307 Xylenes 3 III 3 B1, T1 242 T2 TP1 IB3 1308 Zirconium suspended in a liquid 3 II 3 242 IB2 1308 Zirconium suspended in a liquid 3 III 3 B1 242 IB2 1309 Aluminum powder, coated 4.1 II 4.1 240 IB8 BB2, BB4 1309 Aluminum powder, coated 4.1 III 4.1 240 IB8 BB3 1312 Borneol 4.1 III 4.1 A1 240 IB8 BB3 1313 Calcium resinate 4.1 III 4.1 A1, A19 240 IB6 1314 Calcium resinate, fused 4.1 III 4.1 A1, A19 240 IB4 1318 Cobalt resinate, precipitated 4.1 III 4.1 A1, A19 240 IB6 1323 Ferrocerium 4.1 II 4.1 59, A19 240 IB8 BB2, BB4 1325 Flammable solids, organic, n.o.s 4.1 II 4.1 A1 240 T3 TP1 IB8 BB2, BB4 1325 Flammable solids, organic, n.o.s 4.1 III 4.1 A1 240 T1 TP1 IB8 BB3 1326 Hafnium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns 4.1 II 4.1 A6, A19, A20 N34 241 IB6 BB2 1328 Hexamethylenetetramine 4.1 III 4.1 A1 240 IB8 BB3 1330 Manganese resinate 4.1 III 4.1 A1 240 IB6 1332 Metaldehyde 4.1 III 4.1 A1 240 IB8 BB3 1333 Cerium, slabs, ingots, or rods 4.1 II 4.1 N34 240 IB8 BB2, BB4 1334 Naphthalene, crude or Naphthalene, refined 4.1 III 4.1 A1 240 IB8 BB3 1338 Phosphorus, amorphous 4.1 III 4.1 A1, A19, B1, B9, B26 243 IB8 BB3 1339 Phosphorus heptasulfide, free from yellow or white phosphorus 4.1 II 4.1 A20, N34 240 IB4 1340 Phosphorus pentasulfide, free from yellow or white phosphorus 4.3 II 4.3, 4.1 A20, B59, B101, B106 242 IB4 1341 Phosphorus sesquisulfide, free from yellow or white phosphorus 4.1 II 4.1 A20, N34 240 IB4 1343 Phosphorus trisulfide, free from yellow or white phosphorus 4.1 II 4.1 A20, N34 240 IB4 1346 Silicon powder, amorphous 4.1 III 4.1 A1 240 IB8 BB3 1350 Sulfur 4.1 III 4.1 30, T1 240 T1 TP1 IB8 BB3 Start Printed Page 63332 1352 Titanium powder, wetted with not less than 25 percent water (a visible excess of water must be present (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns 4.1 II 4.1 A19, A20, N34 240 IB6 BB2 1353 Fibers of Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s. 4.1 III 4.1 A1 240 IB8 BB3 1358 Zirconium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns 4.1 II 4.1 A19, A20, N34 241 IB6 BB2 1361 Carbon, animal or vegetable origin 4.2 II 4.2 242 IB6 1361 Carbon, animal or vegetable origin 4.2 III 4.2 241 IB8 BB3 1362 Carbon, activated 4.2 III 4.2 241 IB8 BB3 1363 Copra 4.2 III 4.2 241 IB8 BB3, BB6 1364 Cotton waste, oily 4.2 III 4.2 None IB8 BB6 1365 Cotton, wet 4.2 III 4.2 241 IB8 BB6 1366 Diethylzinc 4.2 I 4.2, 4.3 B11, T28, T40 244 T21 TP2 TP7 1369 p-Nitrosodimethylaniline 4.2 II 4.2 A19, A20, B101, N34 241 IB6 BB2 1370 Dimethylzinc 4.2 I 4.2, 4.3 B11, B16, T28, T29, T40 244 T21 TP2 TP7 1373 Fibers or Fabrics, animal or vegetable or Synthentic, n.o.s. with animal or vegetable oil 4.2 III 4.2 137 241 IB8 BB3 1374 Fish meal, unstablized or Fish scrap, unstabilized 4.2 II 4.2 A1, A19 241 IB8 BB2 1376 Iron oxide, spent, or Iron sponge, spent obtained from coal gas purification 4.2 III 4.2 B18 240 IB8 BB3 1378 Metal catalyst, wetted with a visible excess of liquid 4.2 II 4.2 A2, A8, N34 None IB1 1379 Paper, unsaturated oil treated incompletely dried (including carbon paper) 4.2 III 4.2 B101, B106 241 IB8 BB3 1381 Phosphorus, white dry or Phosphorus, white, under water or Phosphorus white, in solution or Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution 4.2 I 4.2, 6.1 B9, B26, N34, T15, T26, T33 243 T9 TP3 Start Printed Page 63333 1382 Potassium sulfide, anhydrous or Potassium sulfide with less than 30 percent water of crystallization 4.2 II 4.2 A19, A20, B16, B106, N34 241 IB6 BB2 1384 Sodium dithionite or Sodium hydrosulfite 4.2 II 4.2 A19, A20, B106 241 IB6 BB2 1385 Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization 4.2 II 4.2 A19, A20, B106, N34 241 IB6 BB2 1386 Seed cake with more than 1.5 percent oil and not more than 11 percent moisture 4.2 III None N7 241 IB8 BB3, BB6 1386 Seed cake, containing vegetable oil solvent extractions and expelled seeds, with not more than 10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined 4.2 III None N7 241 IB8 BB3, BB6 1390 Alkali metal amides 4.3 II 4.3 A6, A7, A8, A19, A20, B106 241 IB7 BB2 1392 Alkaline earth metal amalgams 4.3 I 4.3 A19, B101, B106, N34, N40 242 IB4 BB1 1393 Alkaline earth metal alloys, n.o.s 4.3 II 4.3 A19, B101, B106 241 IB7 BB2 1394 Aluminum carbide 4.3 II 4.3 A20, B101, B106, N41 242 IB7 BB2 1395 Aluminum ferrosilicon powder 4.3 II 4.3, 6.1 A19, B106, B108 242 IB5 BB2 1395 Aluminum ferrosilicon powder 4.3 III 4.3, 6.1 A19, A20, B106, B108 241 IB4 1396 Aluminum powder, uncoated 4.3 II 4.3 A19, A20, B106, B108 242 IB7 BB2 1396 Aluminum powder, uncoated 4.3 III 4.3 A19, A20, B106, B108 241 IB8 BB4 1398 Aluminum silicon powder, uncoated 4.3 III 4.3 A1, A19, B108 241 IB8 BB4 1400 Barium 4.3 II 4.3 A19, B101, B106 241 IB7 BB2 1401 Calcium 4.3 II 4.3 B101, B106 241 IB7 BB2 1402 Calcium carbide 4.3 I 4.3 A1, A8, B55, B101, B106, N34 242 IB4 BB1 Start Printed Page 63334 1402 Calcium carbide 4.3 II 4.3 A1, A8, B55, B59, B101, B106, N34 241 IB7 BB2 1403 Calcium cyanamide with more than 0.1 percent of calcium carbide 4.3 III 4.3 A1, A19, B105 241 IB8 BB4 1405 Calcium silicide 4.3 II 4.3 A19, B105, B106 241 IB7 BB2 1405 Calcium silicide 4.3 III 4.3 A1, A19, B106, B108 241 IB8 BB4 1407 Cesium or Caesium 4.3 I 4.3 A19, B100, N34, N40 242 IB1 BB1 1408 Ferrosilicon, with 30 percent or more but less than 90 percent silicon 4.3 III 4.3, 6.1 A1, A19 240 IB8 BB4 1409 Metal hydrides, water-reactive, n.o.s 4.3 II 4.3 A19, B101, B106, N34, N40 242 IB4 1415 Lithium 4.3 I 4.3 A7, A19, B100, N45 244 IB1 BB1 1417 Lithium silicon 4.3 II 4.3 A19, A20, B105, B106 241 IB7 BB2 1418 Magnesium, powder or Magnesium alloys, powder 4.3 II 4.3, 4.2 A19, B56, B101, B106 241 IB5 BB2 1418 Magnesium, powder or Magnesium alloys, powder 4.3 III 4.3, 4.2 A19, B56, B106, B108 241 IB8 BB4 1420 Potassium, metal alloys 4.3 I 4.3 A19, A20, B27 244 IB4 BB1 1422 Potassium sodium alloys 4.3 I 4.3 A19, B27, N34, N40, T15, T26 244 T9 TP3 TP7 IB4 BB1 1423 Rubidium 4.3 I 4.3 22, A7, A19, B100, N34, N40, N45 242 IB1 BB1 1428 Sodium 4.3 I 4.3 A7, A8, A19, A20, B9, B48, B68, N34, T15, T29, T46 244 T9 TP3 TP7 TP46 IB4 BB1 1431 Sodium methylate 4.2 II 4.2, 8 A19 242 IB5 BB2 1435 Zinc ashes 4.3 III 4.3 A1, A19, B108 241 IB8 BB4 1436 Zinc powder or Zinc dust 4.3 II 4.3, 4.2 A19, B109 242 IB7 BB2 1436 Zinc powder or Zinc dust 4.3 III 4.3, 4.2 B108 242 IB8 BB4 1437 Zirconium hydride 4.1 II 4.1 A19, A20, N34 240 IB4 1438 Aluminum nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 1439 Ammonium dichromate 5.1 II 5.1 242 IB8 BB2, BB4 1442 Ammonium perchlorate 5.1 II 5.1 107, A9 242 IB6 BB2 1444 Ammonium persulfate 5.1 III 5.1 A1, A29 240 IB8 BB3 Start Printed Page 63335 1445 Barium chlorate 5.1 II 5.1, 6.1 A9, N34, T8 242 T4 TP1 IB6 BB2 1446 Barium nitrate 5.1 II 5.1, 6.1 242 IB8 BB2, BB4 1447 Barium perchlorate 5.1 II 5.1, 6.1 T8 242 T4 TP1 IB6 BB2 1448 Barium permanganate 5.1 II 5.1, 6.1 242 IB6 BB2 1449 Barium peroxide 5.1 II 5.1, 6.1 242 IB6 BB2 1450 Bromates, inorganic, n.o.s 5.1 II 5.1 242 IB8 BB2, BB4 1451 Cesium nitrate or Caesium nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 1452 Calcium chlorate 5.1 II 5.1 N34 242 IB8 BB2, BB4 1453 Calcium chlorite 5.1 II 5.1 A9, N34 242 IB8 BB2, BB4 1454 Calcium nitrate 5.1 III 5.1 34 240 IB8 BB3 1455 Calcium perchlorate 5.1 II 5.1 242 IB6 BB2 1456 Calcium permanganate 5.1 II 5.1 242 IB6 BB2 1457 Calcium peroxide 5.1 II 5.1 242 IB6 BB2 1458 Chlorate and borate mixtures 5.1 II 5.1 A9, N34 240 IB8 BB2, BB4 1458 Chlorate and borate mixtures 5.1 III 5.1 A9, N34 240 IB8 BB3 1459 Chlorate and magnesium chloride mixtures 5.1 II 5.1 A9, N34, T8 240 T4 TP1 IB8 BB2, BB4 1459 Chlorate and magnesium chloride mixtures 5.1 III 5.1 A9, N34, T8 240 T4 TP1 IB8 BB3 1461 Chlorates, inorganic, n.o.s 5.1 II 5.1 A9, N34 242 IB6 BB2 1462 Chlorites, inorganic, n.o.s 5.1 II 5.1 A7, N34 242 IB6 BB2 1463 Chromium trioxide, anhydrous 5.1 II 5.1, 8 B106 242 IB8 BB4 1465 Didymium nitrate 5.1 III 5.1 A1 240 IB8 BB3 1466 Ferric nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 1467 Guanidine nitrate 5.1 III 5.1 A1 240 IB8 BB3 1469 Lead nitrate 5.1 II 5.1, 6.1 242 IB8 BB2, BB4 1470 Lead perchlorate, solid 5.1 II 5.1, 6.1 T8 242 T4 TP1 IB6 BB2 1470 Lead perchlorate, solution 5.1 II 5.1, 6.1 T8 243 T4 TP1 IB1 1471 Lithium hypochlorite, dry or Lithium hypochlorite mixtures, dry 5.1 II 5.1 A9, N34 240 IB8 BB2, BB4 1472 Lithium peroxide 5.1 II 5.1 A9, N34 None IB6 BB2 1473 Magnesium bromate 5.1 II 5.1 A1 242 IB8 BB4 1474 Magnesium nitrate 5.1 III 5.1 A1 240 IB8 BB3 1475 Magnesium perchlorate 5.1 II 5.1 242 IB6 BB2 1476 Magnesium peroxide 5.1 II 5.1 242 IB6 BB2 1477 Nitrates, inorganic, n.o.s 5.1 II 5.1 240 IB8 BB2, BB4 1477 Nitrates, inorganic, n.o.s 5.1 III 5.1 240 IB8 BB3 1479 Oxidizing solid, n.o.s. 5.1 I 5.1 242 IB6 BB1 1479 Oxidizing solid, n.o.s. 5.1 II 5.1 240 IB8 BB2, BB4 1479 Oxidizing solid, n.o.s. 5.1 III 5.1 240 IB8 BB3 1481 Perchlorates, inorganic, n.o.s. 5.1 II 5.1 242 IB6 BB2 1481 Perchlorates, inorganic, n.o.s 5.1 III 5.1 240 IB8 BB3 1482 Permanganates, inorganic, n.o.s 5.1 II 5.1 26, A30 242 IB6 BB2 1482 Permanganates, inorganic, n.o.s. 5.1 III 5.1 A26, A30 240 IB8 BB3 1483 Peroxides, inorganic, n.o.s 5.1 II 5.1 A7, A20, N34 242 IB6 BB2 1483 Peroxides, inorganic, n.o.s 5.1 III 5.1 A7, A20, N34 240 IB8 BB3 1484 Potassium bromate 5.1 II 5.1 242 IB8 BB4 1485 Potassium chlorate 5.1 II 5.1 A9, N34 242 IB8 BB4 1486 Potassium nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 1487 Potassium nitrate and sodium nitrite mixtures 5.1 II 5.1 B78 240 IB8 BB4 1488 Potassium nitrite 5.1 II 5.1 242 IB8 BB4 1489 Potassium perchlorate, solid 5.1 II 5.1 242 IB6 BB2 Start Printed Page 63336 1489 Potassium perchlorate, solution 5.1 II 5.1 242 T4 TP1 IB2 1490 Potassium permanganate 5.1 II 5.1 240 IB8 BB4 1491 Potassium peroxide 5.1 I 5.1 A20, N34 None IB6 BB1 1492 Potassium persulfate 5.1 III 5.1 A1, A29 240 IB8 BB3 1493 Silver nitrate 5.1 II 5.1 242 IB8 BB4 1494 Sodium bromate 5.1 II 5.1 242 IB8 BB4 1495 Sodium chlorate 5.1 II 5.1 A9, N34, T8 240 T4 TP1 IB8 BB4 1496 Sodium chlorite 5.1 II 5.1 A9, N34, T8 242 T4 TP1 IB8 BB2, BB4 1498 Sodium nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 1499 Sodium nitrate and potassium nitrate mixtures 5.1 III 5.1 A1, A29 240 IB8 BB3 1500 Sodium nitrite 5.1 III 5.1, 6.1 A1, A29 240 IB8 BB3 1502 Sodium perchlorate 5.1 II 5.1 242 IB6 BB2 1503 Sodium permanganate 5.1 II 5.1 242 IB6 BB2 1504 Sodium peroxide 5.1 I 5.1 A20, N34 None IB6 BB1 1505 Sodium persulfate 5.1 III 5.1 A1 240 IB8 BB3 1506 Strontium chlorate 5.1 II 5.1 A1, A9, N34 242 IB8 BB2, BB4 1507 Strontium nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 1508 Strontium perchlorate 5.1 II 5.1 242 IB6 BB2 1509 Strontium peroxide 5.1 II 5.1 242 IB6 BB2 1510 Tetranitromethane 5.1 I 5.1, 6.1 2, B9, B14, B32, B74, T38, T43, T45 None T20 TP2 TP13 TP38 TP44 1511 Urea hydrogen peroxide 5.1 III 5.1, 8 A1, A7, A29 240 IB8 BB3 1512 Zinc ammonium nitrite 5.1 II 5.1 242 IB8 BB4 1513 Zinc chlorate 5.1 II 5.1 A9, N34 242 IB8 BB2, BB4 1514 Zinc nitrate 5.1 II 5.1 240 IB8 BB4 1515 Zinc permanganate 5.1 II 5.1 242 IB6B B2 1516 Zinc peroxide 5.1 II 5.1 242 IB6 BB2 1541 Acetone cyanohydrin, stabilized 6.1 I 6.1 2, A3, B9, B14, B32, B76, B77, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1544 Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous 6.1 I 6.1 242 IB7 BB1 1544 Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous 6.1 II 6.1 242 IB8 BB2, BB4 1544 Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. poisonous 6.1 III 6.1 240 IB8 BB3 1545 Allyl isothiocyanate, stabilized 6.1 II 6.1, 3 A3, A7 243 T7 TP2 IB2 1546 Ammonium arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1547 Aniline 6.1 II 6.1 T8 243 T7 TP2 IB2 1548 Aniline hydrochloride 6.1 III 6.1 240 IB8 BB3 1549 Antimony compounds, inorganic, solid, n.o.s 6.1 III 6.1 35 240 IB8 BB3 1550 Antimony lactate 6.1 III 6.1 240 IB8 BB3 1551 Antimony potassium tartrate 6.1 III 6.1 240 IB8 BB3 1553 Arsenic acid, liquid 6.1 I 6.1 T18, T27 243 T20 TP2 TP7 TP13 1554 Arsenic acid, solid 6.1 II 6.1 242 IB8 BB2, BB4 1555 Arsenic bromide 6.1 II 6.1 242 IB8 BB2, BB4 Start Printed Page 63337 1556 Arsenic compounds, liquid, n.o.s. inorganic, including arsenates n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s 6.1 II 6.1 243 IB2 1556 Arsenic compounds, liquid, n.o.s. inorganic, including arsenates n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s 6.1 III 6.1 241 IB3 1557 Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s 6.1 I 6.1 242 IB7 BB1 1557 Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 1557 Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s 6.1 III 6.1 240 IB8 BB3 1558 Arsenic 6.1 II 6.1 242 IB8 BB2, BB4 1559 Arsenic pentoxide 6.1 II 6.1 242 IB8 BB2, BB4 1560 Arsenic trichloride 6.1 I 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1561 Arsenic trioxide 6.1 II 6.1 242 IB8 BB2, BB4 1562 Arsenical dust 6.1 II 6.1 242 IB8 BB2, BB4 1564 Barium compounds, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 1564 Barium compounds, n.o.s 6.1 III 6.1 240 IB8 BB3 1565 Barium cyanide 6.1 I 6.1 N74, N75 242 IB7 BB1 1566 Beryllium compounds, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 1566 Beryllium compounds, n.o.s 6.1 III 6.1 240 IB8 BB3 1567 Beryllium, powder 6.1 II 6.1, 4.1 242 IB8 BB2, BB4 1569 Bromoacetone 6.1 II 6.1, 3 2 245 T20 TP2 TP13 1570 Brucine 6.1 I 6.1 242 IB7 BB1 1572 Cacodylic acid 6.1 II 6.1 242 IB8 BB2, BB4 1573 Calcium arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1574 Calcium arsenate and calcium arsenite, mixtures, solid 6.1 II 6.1 242 IB8 BB2, BB4 1575 Calcium cyanide 6.1 I 6.1 N79, N80 242 IB7 BB1 1577 Chlorodinitrobenzenes 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1578 Chloronitrobenzenes meta or para, solid 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 Start Printed Page 63338 1578 Chloronitrobenzene, ortho, liquid 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 1579 4-Chloro-o-toluidine hydrochloride 6.1 III 6.1 240 IB8 BB3 1580 Chloropicrin 6.1 I 6.1 2, B7, B9, B14, B32, B46, B74, T38, T43, TP45 244 T20 TP2 TP13 TP38 T45 1581 Chloropicrin and methyl bromide mixtures 2.3 2.3 2, B9, B14 314, 315 T50 1582 Chloropicrin and methyl chloride mixtures 2.3 2.3 2 245 T50 1583 Chloropicrin mixtures, n.o.s 6.1 II 6.1 243 IB2 1583 Chloropicrin mixtures, n.o.s 6.1 III 6.1 241 IB3 1585 Copper acetoarsenite 6.1 II 6.1 242 IB8 BB2, BB4 1586 Copper arsenite 6.1 II 6.1 242 IB8 BB2, BB4 1587 Copper cyanide 6.1 II 6.1 242 IB8 BB2, BB4 1588 Cyanides, inorganic, solid, n.o.s 6.1 I 6.1 N74, N75 242 IB7 BB1 1588 Cyanides, inorganic, solid, n.o.s 6.1 II 6.1 N74, N75 242 IB8 BB2, BB4 1588 Cyanides, inorganic, solid, n.o.s 6.1 III 6.1 N74, N75 240 IB8 BB3 1590 Dichloroanilines, liquid 6.1 II 6.1 T14 243 T7 TP2 IB2 1590 Dichloroanilines, solid 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1591 o-Dichlorobenzene 6.1 III 6.1 T7 241 T4 TP1 IB3 1593 Dichloromethane 6.1 III 6.1 N36, T13 241 T7 TP2 IB3 BB8 1594 Diethyl sulfate 6.1 II 6.1 B101, T14 243 T7 TP2 IB2 1595 Dimethyl sulfate 6.1 I 6.1, 8 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1596 Dinitroanilines 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1597 Dinitrobenzenes, liquid 6.1 II 6.1 11, T14 243 T7 TP2 IB2 1597 Dinitrobenzenes, solid 6.1 II 6.1 11 242 IB8 BB2, BB4 1598 Dinitro-o-cresol, solid 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1598 Dinitro-o-cresol, solution 6.1 II 6.1 T14 243 T7 TP2 IB2 BB2, BB4 1599 Dinitrophenol solutions 6.1 II 6.1 T8 243 T7 TP2 IB2 1599 Dinitrophenol solutions 6.1 III 6.1 T7 241 T4 TP1 IB3 1600 Dinitrotoluenes, molten 6.1 II 6.1 B100, T14 243 T7 TP3 1601 Disinfectants, solid, toxic, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 1601 Disinfectants, solid, toxic, n.o.s 6.1 III 6.1 240 IB8 BB3 1602 Dyes, liquid, toxic, n.o.s or Dye intermediates, liquid, toxic, n.o.s 6.1 II 6.1 243 IB2 1602 Dyes, liquid, toxic, n.o.s or Dye intermediates, liquid, toxic, n.o.s 6.1 III 6.1 241 IB3 1603 Ethyl bromoacetate 6.1 II 6.1, 3 T14 243 T7 TP2 IB2 1604 Ethylenediamine 8 II 8, 3 T14 243 T7 TP2 IB2 Start Printed Page 63339 1605 Ethylene dibromide 6.1 I 6.1 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1606 Ferric arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1607 Ferric arsenite 6.1 II 6.1 242 IB8 BB2, BB4 1608 Ferrous arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1611 Hexaethyl tetraphosphate, solid 6.1 II 6.1 N76 242 IB8 BB2, BB4 1611 Hexaethyl tetraphosphate liquid 6.1 II 6.1 N76 243 IB2 BB2, BB4 1613 Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, aqueous solutions with not more than 20 percent hydrogen cyanide 6.1 I 6.1 2, B61, B65, B77, B82 244 T20 TP2 TP13 1616 Lead acetate 6.1 III 6.1 240 IB8 BB3 1617 Lead arsenates 6.1 II 6.1 242 IB8 BB2, BB4 1618 Lead arsenites 6.1 II 6.1 242 IB8 BB2, BB4 1620 Lead cyanide 6.1 II 6.1 242 IB8BB2, BB4 1621 London purple 6.1 II 6.1 242 IB8 BB2, BB4 1622 Magnesium arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1623 Mercuric arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1624 Mercuric chloride 6.1 II 6.1 242 IB8 BB2, BB4 1625 Mercuric nitrate 6.1 II 6.1 N73 242 IB8 BB2, BB4 1626 Mercuric potassium cyanide 6.1 I 6.1 N74, N75 242 IB7 BB1 1627 Mercurous nitrate 6.1 II 6.1 242 IB8 BB2, BB4 1629 Mercury acetate 6.1 II 6.1 242 IB8 BB2, BB4 1630 Mercury ammonium chloride 6.1 II 6.1 242 IB8 BB2, BB4 1631 Mercury benzoate 6.1 II 6.1 242 IB8 BB2, BB4 1634 Mercury bromides 6.1 II 6.1 242 IB8 BB2, BB4 1636 Mercury cyanide 6.1 II 6.1 N74, N75 242 IB8 BB2, BB4 1637 Mercury gluconate 6.1 II 6.1 242 IB8 BB2, BB4 1638 Mercury iodide, solution 6.1 II 6.1 243 IB8 BB2, BB4 1638 Mercury iodide, solid 6.1 II 6.1 242 IB2 BB2, BB4 1639 Mercury nucleate 6.1 II 6.1 242 IB8 BB2, BB4 1640 Mercury oleate 6.1 II 6.1 242 IB8 BB2, BB4 1641 Mercury oxide 6.1 II 6.1 242 IB8 BB2, BB4 1642 Mercury oxycyanide, desensitized 6.1 II 6.1 242 IB8 BB2, BB4 1643 Mercury potassium iodide 6.1 II 6.1 242 IB8 BB2, BB4 1644 Mercury salicylate 6.1 II 6.1 242 IB8 BB2, BB4 1645 Mercury sulfates 6.1 II 6.1 242 IB8 BB2, BB4 1646 Mercury thiocyanate 6.1 II 6.1 242 IB8 BB2, BB4 1647 Methyl bromide and ethylene dibromide mixtures, liquid 6.1 I 6.1 2, B9, B14, B32, B74, N65, T38, T43, T45 244 T20 TP2 TP13 TP38 TP44 1648 Acetonitrile 3 II 3 T14 242 T7 TP2 IB2 1649 Motor fuel anti-knock mixtures 6.1 I 6.1, 3 14, B9, B90, T26, T39 244 T14 TP2 TP13 1650 beta-Naphthylamine 6.1 II 6.1 T12, T26 242 T7 TP2 IB8 BB2, BB4 1651 Naphthylthiourea 6.1 II 6.1 242 IB8 BB2, BB4 1652 Naphthylurea 6.1 II 6.1 242 IB8 BB2, BB4 1653 Nickel cyanide 6.1 II 6.1 N74, N75 242 IB8 BB2, BB4 1654 Nicotine 6.1 II 6.1 243 IB2 1655 Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s. 6.1 I 6.1 242 IB7 BB1 Start Printed Page 63340 1655 Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 1655 Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s. 6.1 III 6.1 240 IB8 BB3 1656 Nicotine hydrochloride or Nicotine hydrochloride solution 6.1 II 6.1 243 IB2 BB2, BB4 1657 Nicotine salicylate 6.1 II 6.1 242 IB8 BB2, BB4 1658 Nicotine sulfate, solid 6.1 II 6.1 242 IB8 BB2, BB4 1658 Nicotine sulfate, solution 6.1 II 6.1 T14 243 T7 TP2 IB2 1659 Nicotine tartrate 6.1 II 6.1 242 IB8 BB2, BB4 1661 Nitroanilines (o-; m-; p-;) 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1662 Nitrobenzene 6.1 II 6.1 T14 243 T7 TP2 IB2 1663 Nitrophenols (o-; m-; p-;) 6.1 III 6.1 T8, T38 240 T4 TP3 TP38 IB8 BB3 1664 Nitrotoluenes, solid m-, or p- 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1664 Nitrotoluenes, liquid o-; m-; p-; 6.1 II 6.1 T14 243 T7 TP2 IB2 BB2, BB4 1665 Nitroxylenes, (o-; m-; p-) 6.1 II 6.1 T14 243 T7 TP2 IB2 BB2, BB4 1669 Pentachloroethane 6.1 II 6.1 T14 243 T7 TP2 IB2 1670 Perchloromethyl mercaptan 6.1 I 6.1 2, A3, A7, B9, B14, B32, B74, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 T45 1671 Phenol, solid 6.1 II 6.1 N78, T14 242 T6 TP2 IB8 BB2, BB4 1672 Phenylcarbylamine chloride 6.1 I 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1673 Phenylenediamines (o-; m-; p-;) 6.1 III 6.1 240 T7 TP1 IB8 BB3 1674 Phenylmercuric acetate 6.1 II 6.1 242 IB8 BB2, BB4 1677 Potassium arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1678 Potassium arsenite 6.1 II 6.1 242 IB8 BB2, BB4 1679 Potassium cuprocyanide 6.1 II 6.1 242 IB8 BB2, BB4 1680 Potassium cyanide 6.1 I 6.1 B69, B77, N74, N75, T18, T26 242 T14 TP2 TP13 IB7 BB1 1683 Silver arsenite 6.1 II 6.1 242 IB8 BB2, BB4 1684 Silver cyanide 6.1 II 6.1 242 IB8 BB2, BB4 1685 Sodium arsenate 6.1 II 6.1 242 IB8 BB2, BB4 1686 Sodium arsenite, aqueous solutions 6.1 II 6.1 T15 243 T7 TP2 IB2 1686 Sodium arsenite, aqueous solutions 6.1 III 6.1 T15 241 T4 TP2 IB3 1687 Sodium azide 6.1 II 6.1 B28 242 IB8 BB2, BB4 1688 Sodium cacodylate 6.1 II 6.1 242 IB8 BB2, BB4 1689 Sodium cyanide 6.1 I 6.1 B69, B77, N74, N75, T42 242 T14 TP2 TP13 IB7 BB1 1690 Sodium fluoride 6.1 III 6.1 T8 240 T4 TP1 IB8 BB3 1691 Strontium arsenite 6.1 II 6.1 242 IB8 BB2, BB4 1692 Strychnine or Strychnine salts 6.1 I 6.1 242 IB7 BB1 1693 Tear gas substances, liquid, n.o.s 6.1 II 6.1 None IB2 1693 Tear gas substances, solid, n.o.s 6.1 II 6.1 None IB8 BB2, BB4 Start Printed Page 63341 1694 Bromobenzyl cyanides, solid 6.1 I 6.1 T18 242 T14 TP2 TP13 1694 Bromobenzyl cyanides, liquid 6.1 I 6.1 T18 243 T14 TP2 TP13 1695 Chloroacetone, stabilized 6.1 I 6.1, 3, 8 2, B9, B14, B32, B74, N12, N32, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1697 Chloroacetophenone (CN), liquid 6.1 II 6.1 A3, N12, N32, N33 243 T11 TP2 TP13 TP27 IB2 1697 Chloroacetophenone (CN), solid 6.1 II 6.1 A3, N12, N32, N33, N34 None T7 TP2 TP13 IB8 BB2, BB4 1699 Diphenylchloroarsine, solid 6.1 I 6.1 A8, B14, B32, N33, N34 242 IB7 BB1 1699 Diphenylchloroarsine, liquid 6.1 I 6.1 A8, B14, B32, N33, N34 243 T14 TP2 TP13 TP27 1701 Xylyl bromide 6.1 II 6.1 A3, A6, A7, N33 None T7 TP2 TP13 IB2 1702 Tetrachloroethane 6.1 II 6.1 N36, T14 243 T7 TP2 IB2 1704 Tetraethyl dithiopyrophosphate 6.1 II 6.1 242 IB8 BB2, BB4 1707 Thallium compounds, n.o.s. 6.1 II 6.1 242 IB8 BB2, BB4 1708 Toluidines liquid 6.1 II 6.1 T14 243 T7 TP2 IB2 1708 Toluidines solid 6.1 II 6.1 242 T7 TP2 IB8 BB2, BB4 1709 2,4-Toluylenediamine or 2,4-Toluenediamine 6.1 III 6.1 T7 240 T4 TP1 IB8 BB3 1710 Trichloroethylene 6.1 III 6.1 N36, T1 241 T4 TP1 IB3 1711 Xylidines, solution 6.1 II 6.1 T14 243 T7 TP2 IB2 1711 Xylidines, solid 6.1 II 6.1 T14 242 T7 TP2 IB8 BB2, BB4 1712 Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc arsenite mixtures 6.1 II 6.1 242 IB8 BB2, BB4 1713 Zinc cyanide 6.1 I 6.1 242 IB7 BB1 1715 Acetic anhydride 8 II 8, 3 A3, A6, A7, A10, B2, T8 243 T7 TP2 IB2 1716 Acetyl bromide 8 II 8 B2, T12, T26 242 T8 TP2 TP12 IB2 1717 Acetyl chloride 3 II 3, 8 A3, A6, A7, B100, N34, T18, T26 243 T8 TP2 TP12 IB1 1718 Butyl acid phosphate 8 III 8 T7 241 T4 TP1 IB3 1719 Caustic alkali liquids, n.o.s 8 II 8 B2, T14 242 T11 TP2 TP27 IB2 1719 Caustic alkali liquids, n.o.s 8 III 8 T7 241 T7 TP1 TP28 IB3 1722 Allyl chloroformate 6.1 I 6.1, 3, 8 2, B9, B14, B32, B74, N41, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1723 Allyl iodide 3 II 3, 8 A3, A6, B100, N34, T18 243 T7 TP2 TP13 IB1 Start Printed Page 63342 1724 Allyltrichlorosilane, stablized 8 II 8, 3 A7, B2, B6, N34, T8, T26 243 T7 TP2 TP13 IB2 1725 Aluminum bromide, anhydrous 8 II 8 B106 240 IB8 BB2, BB4 1726 Aluminum chloride, anhydrous 8 II 8 B106 240 IB8 BB2, BB4 1727 Ammonium hydrogendifluoride, solid 8 II 8 B106, N34 240 IB8 BB2, BB4 1728 Amyltrichlorosilane 8 II 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 TP13 IB2 1729 Anisoyl chloride 8 II 8 B2, T8 242 T7 TP2 IB2 1730 Antimony pentachloride, liquid 8 II 8 B2, T8, T26 242 T7 TP2 IB2 1731 Antimony pentachloride, solutions 8 II 8 B2, T8, T27 242 T7 TP2 IB2 1731 Antimony pentachloride, solutions 8 III 8 T7, T26 241 T4 TP1 IB3 1732 Antimony pentafluoride 8 II 8, 6.1 A3, A6, A7, A10, N3, T12, T26 243 T7 TP2 IB2 1733 Antimony trichloride, liquid 8 II 8 B2 242 IB2 1733 Antimony trichloride, solid 8 II 8 B106 240 IB8 BB2, BB4 1736 Benzoyl chloride 8 II 8 B2, T9, T26 242 T8 TP2 TP12 IB2 1737 Benzyl bromide 6.1 II 6.1, 8 A3, A7, N33, N34, T12, T26 243 T8 TP2 TP12 TP13 IB2 1738 Benzyl chloride 6.1 II 6.1, 8 A3, A7, B70, N33, N42, T12, T26 243 T8 TP2 TP12 TP13 IB2 1738 Benzyl chloride unstabilized 6.1 II 6.1, 8 A3, A7, B8, B11, N33, N34, N43, T12, T26 243 T8 TP2 TP12 TP13 IB2 1739 Benzyl chloroformate 8 I 8 A3, A6, B4, N41, T18, T26 243 T10 TP2 TP12 TP13 1740 Hydrogendifluorides, n.o.s. solutions 8 II 8 N3, N34 242 IB2 1740 Hydrogendifluorides, n.o.s. solutions 8 II 8 N3, N34 240 IB5 BB2, BB4 1740 Hydrogendifluorides, n.o.s. solutions 8 III 8 N3, N34 241 IB3 BB3 1740 Hydrogendifluorides, n.o.s. solutions 8 III 8 N3, N34 240 IB8 BB3 1742 Boron trifluoride acetic acid complex 8 II 8 B2, B6, T9, T27 242 T8 TP2 TP12 IB2 1743 Boron trifluoride propionic acid complex 8 II 8 B2, T9, T27 242 T8 TP2 TP12 IB2 D 1744 Bromine or Bromine solutions 8 I 8, 6.1 1, A3, A6, B9, B64, B85, N34, N43, T18, T41 249 T22 TP2 TP10 TP12 TP13 Start Printed Page 63343 1745 Bromine pentafluoride 5.1 I 5.1, 6.1, 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP12 TP13, TP38 1746 Bromine trifluoride 5.1 I 5.1, 6.1, 8 2, B9, B14, B32, B74, T38, T43, T45 244 T22 TP2 TP12 TP13, TP38 1747 Butyltrichlorosilane 8 II 8, 3 A7, B2, B6, N34, T8, T26 243 T7 TP2 TP13 IB2 1748 Calcium hypochlorite, dry or Calcium hypochlorite 5.1 II 5.1 A7, A9, N34 None IB8 BB2, BB4 1750 Chloroacetic acid, solution 6.1 II 6.1, 8 A7, N34, T8, T27 243 T7 TP2 IB2 1751 Chloroacetic acid, solid 6.1 II 6.1, 8 A3, A7, N34 242 IB8 BB4 1752 Chloroacetyl chloride 6.1 I 6.1, 8 2, A3, A6, A7, B3 B8, B9, B14, B32, B74, B77, N34, N43, T38, T43, T45 244 T20 TP2 TP13, TP38, TP45 1753 Chlorophenyltrichlorosilane 8 II 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 IB2 1754 Chlorosulfonic acid (with or without sulfur trioxide) 8 I 8, 6.1 2, A3, A6, A10, B9, B10, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP12 TP38, TP45 1755 Chromic acid solution 8 II 8 B2, T9, T27 242 T8 TP2 TP12 IB2 1755 Chromic acid solution 8 III 8 T8, T26 241 T4 TP1 TP12 IB3 1756 Chromic fluoride, solid 8 II 8 240 IB8 BB2, BB4 1757 Chromic fluoride, solution 8 II 8 B2, T8 242 T7 TP2 IB2 1757 Chronic fluoride, solution 8 III 8 T7 241 T4 TP1 IB3 1758 Chromium oxychloride 8 I 8 A3, A6, A7, B10, N34, T12, T26 243 DT10 TP2 TP12 1759 Corrosive solids, n.o.s 8 I 8 242 IB7 BB1 1759 Corrosive solids, n.o.s 8 II 8 128 240 IB8 BB2, BB4 1759 Corrosive solids, n.o.s 8 III 8 128 240 IB8 BB3 1760 Corrosive liquids, n.o.s 8 I 8 A7, B10, T42 243 T14 TP2 TP27 1760 Corrosive liquids, n.o.s 8 II 8 B2, T14 242 T11 TP2 TP27 IB2 1760 Corrosive liquids, n.o.s 8 III 8 T7 241 T7 TP1 TP28 IB3 1761 Cupriethylenediamine solution 8 II 8, 8, T26 243 T7 TP2 IB2 Start Printed Page 63344 1761 Cupriethylenediamine solution 8 III 8, T7 242 T7 TP1 TP28 IB3 1762 Cyclohexenyltrichlorosilane 8 II 8 A7, B2, N34, T8. T26 242 T7 TP2 TP13 IB2 1763 Cyclohexyltrichlorosilane 8 II 8 A7, B2, N34, T8, T26 242 T7 TP2 TP13 IB2 1764 Dichloroacetic acid 8 II 8 A3, A6, A7, B2, N34, T9, T27 242 T8 TP2 TP12 IB2 1765 Dichloroacetyl chloride 8 II 8 A3, A6, A7, B2, N34, T8, T26 242 T7 TP2 IB2 1766 Dichlorophenyltrichlorosilane 8 II 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 TP13 IB2 1767 Diethyldichlorosilane 8 II 8, 3 A7, B6, B100, N34, T8, T26 243 T7 TP2 TP13 IB2 1768 Difluorophosphoric acid, anhydrous 8 II 8 A6, A7, B2, N5, N34, T9, T27 242 T8 TP2 TP12 IB2 1769 Diphenyldichlorosilane 8 II 8 A7, B2, N34, T8, T26 242 T7 TP2 TP13 IB2 1770 Diphenylmethyl bromide 8 II 8 240 IB8 BB2, BB4 1771 Dodecyltrichlorosilane 8 II 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 TP13 IB2 1773 Ferric chloride, anhydrous 8 III 8 240 IB8 BB3 1775 Fluoroboric acid 8 II 8 A6, A7, B2, B15, N3, N34, T15, T27 242 T7 TP2 IB2 1776 Fluorophosphoric acid anhydrous 8 ll 8 A6, A7, B2, N3, N34, T9, T27 242 T8 TP2 TP12 1B2 1777 Fluorosulfonic acid 8 l 8 A3, A6, A7, A10, B6, B10, N3, T9, T27 243 T10 TP2 TP12 1778 Fluorosilicic acid 8 ll 8 A6, A7, B2, B15, N3, N34, T12, T27 242 T8 TP2 TP12 1B2 1779 Formic acid 8 ll 8 B2, B28, T8 242 T7 TP2 lB2 1780 Fumaryl chloride 8 ll 8 B2, T8, T26 242 T7 TP2 1B2 1781 Hexadecyltrichlorosilane 8 II 8 A7, B2, B6, N34, T8 242 T7 TP2 1B2 1782 Hexafluorophosphoric acid 8 II 8 A6, A7, B2, N3, N34, T9, T27 242 T8 TP2 TP12 1B2 1783 Hexamethylenediamine solution 8 II 8 T8 242 T7 TP2 1B2 1783 Hexamethylenediamine solution 8 III 8 T7 241 T4 TP1 1B3 1784 Hexyltrichlorosilane 8 ll 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 TP13 lB2 Start Printed Page 63345 1786 Hydrofluoric acid and Sulfuric acid mixtures 8 l 8, 6.1 A6, A7, B15, B23, N5, N34, T18, T27 243 T10 TP2 TP12 TP13 1787 Hydriodic acid 8 II 8 A3, A6, B2, N41, T9, T27 242 T7 TP2 lB2 1787 Hydriodic acid 8 III 8 T8, T26 241 T4 TP1 lB3 1788 Hydrobromic acid, with not more than 49 percent hydrobromic acid 8 ll 8 A3, A6, B2, B15, N41, T9, T27 242 T7 TP2 lB2 1788 Hydrobromic acid, with more than 49 percent hydrobromic acid 8 ll 8 B2, B15, N41, T9, T27 242 T7 TP2 lB2 1788 Hydrobromic acid, with more than 49 percent hydrobromic acid 8 lll 8 T8, T26 241 T4 TP1 lB3 1788 Hydrobromic acid, with not more than 49 percent hydrobromic acid 8 lll 8 T8, T26 241 T4 TP1 lB3 1789 Hydrochloric acid 8 ll 8 A3, A6, B3, B15, N41, T9, T27 242 T8 TP2 TP12 lB2 1789 Hydrochloric acid 8 lll 8 T8, T26 241 T4 TP1 TP12 lB3 1790 Hydrofluoric acid, with more than 60 percent strength 8 l 8, 6.1 A6, A7, B4, B15, B23, N5, N34, T18, T27 243 T10 TP2 TP12 TP13 1790 Hydrofluoric acid, with not more than 60 percent strength 8 ll 8, 6.1 A6, A7, B15, B110, N5, N34, T18, T27 243 T8 TP2 TP12 lB2 1791 Hypochlorite solutions 8 ll 8 A7, B2, B15, N34, T7 242 T7 TP2 TP24 lB2 BB5 1791 Hypochlorite solutions 8 lll 8 B104, N34, T7 241 T4 TP2 TP24 lB3 1792 Iodine monochloride 8 ll 8 B6, N41, T8, T26 240 T7 TP2 lB8 BB2, BB4 1793 Isopropyl acid phosphate 8 lll 8 T7 240 T4 TP1 lB8 BB3 1794 Lead sulfate with more than 3 percent free acid 8 ll 8 240 lB8 BB2, BB4 1796 Nitrating acid mixtures with more than 50 percent nitric acid 8 l 8, 5.1 T12, T27 243 T10 TP2 TP12 TP13 1796 Nitrating acid mixtures with not more than 50 percent nitric acid 8 ll 8 B2, T12, T27 242 T8 TP2 TP12 TP13 lB2 1798 Nitrohydrochloric acid 8 l 8 A3, B10, N41, T18, T27 243 T10 TP2 TP12 TP13 1799 Nonytrichlorosilane 8 ll 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 TP13 lB2 1800 Octadecyltrichlorosilane 8 ll 8 A7, B2, B6, T8, N34 242 T7 TP2 TP13 lB2 Start Printed Page 63346 1801 Octyltrichlorosilane 8 ll 8 A7, B2, B6, N34, T8, T26 242 T7 TP2 TP13 lB2 1802 Perchloric acid with not more than 50 percent acid by mass 8 ll 8, 5.1 N41, T9 243 T7 TP2 lB2 1803 Phenolsulfonic acid, liquid 8 ll 8 B2, N41, T8 242 T7 TP2 lB2 1804 Phenyltrichlorosilane 8 ll 8 A7, B6, N34, T8 242 T7 TP2 lB2 1805 Phosphoric acid 8 lll 8 A7, N34, T7 241 T4 TP1 lB3 BB3 1806 Phosphorus pentachloride 8 ll 8 A7, B106, N34 240 lB8 BB2, BB4 1807 Phosphorus pentoxide 8 ll 8 A7, N34 240 lB8 BB2, BB4 1808 Phosphorus tribromide 8 ll 8 A3, A6, A7, B2, B25, N34, N43, T8 242 T7 TP2 lB2 1809 Phosphorus trichloride 6.1 l 6.1, 8 2, B9, B14, B15, B32, B74, B77, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1810 Phosphorus oxychloride 8 ll 8, 6.1 2, A7, B9, B14, B32, B74, B77, N34, T38, T43, T45 244 T20 TP2 TP38 TP45 1811 Potassium hydrogendifluoride, solution 8 ll 8, 6.1 N3, N34, T8 243 T7 TP2 lB8 BB2, BB4 1811 Potassium hydrogendifluoride, solid 8 ll 8, 6.1 B106, N3, N34, T8 240 T7 TP2 lB2 BB2, BB4 1812 Potassium fluoride 6.1 lll 6.1 T8 240 T4 TP1 lB8 BB3 1813 Potassium hydroxide, solid 8 ll 8 240 lB8 BB2, BB4 1814 Potassium hydroxide, solution 8 ll 8 B2, T8 242 T7 TP2 lB2 1814 Potassium hydroxide, solution 8 lll 8 T7 241 T4 TP1 lB3 1815 Propionyl chloride 3 ll 3, 8 B100, T8, T26 243 T7 TP1 lB1 1816 Propyltrichlorosilane 8 II 8, 3 A7, B2, B6, N34, T8, T26 243 T7 TP2 TP13 IB2 1817 Pyrosulfuryl chloride 8 II 8 B2, T9, T27 242 T8 TP2 TP12 IB2 1818 Silicon tetrachloride 8 II 8 A3, A6, B2, B6, T18, T26, T29 242 T7 TP2 TP7 IB2 1819 Sodium aluminate, solution 8 II 8 B2, T8 242 T7 TP2 IB2 1819 Sodium aluminate, solution 8 III 8 T7 241 T4 TP1 IB3 1823 Sodium hydroxide, solid 8 II 8 240 IB8 BB2, BB4 1824 Sodium hydroxide solution 8 II 8 B2, N34, T8 242 T7 TP2 IB2 1824 Sodium hydroxide solution 8 III 8 N34, T7 241 T4 TP1 IB3 1825 Sodium monoxide 8 II 8 240 IB8 BB2, BB4 Start Printed Page 63347 1826 Nitrating acid mixtures, spent with more than 50 percent nitric acid 8 I 8, 5.1 T12, T27 243 T10 TP2 TP12 TP13 1826 Nitrating acid mixtures spent with not more than 50 percent nitric acid 8 II 8 B2, B100, T12, T27 242 T8 TP2 TP12 IB2 1827 Stannic chloride, anhydrous 8 II 8 B2, T8, T26 242 T7 TP2 IB2 1828 Sulfur chlorides 8 I 8 5, A3, B10, B77, N34, T18, T27 243 T20 TP2 TP12 1829 Sulfur trioxide, inhibited or Sulfur trioxide, stabilized 8 I 8, 6.1 2, A7, B9, B14, B32, B49, B74, B77, N34, T38, T43, T45 244 T20 TP4 TP12 TP13 TP25 TP26 TP38 TP45 1830 Sulfuric acid with more than 51 percent acid 8 II 8 A3, A7, B3, B83, B84, N34, T9, T27 242 T8 TP2 TP12 IB2 1831 Sulfuric acid, fuming with less than 30 percent free sulfur trioxide 8 I 8 A3, A7, B84, N34, T18, T27 243 T20 TP2 TP12 TP13 1831 Sulfuric acid, fuming with 30 percent or more free sulfur trioxide 8 I 8, 6.1 2, B9, B14, B32, B74, B77, B84, N34, T38, T43, T45 244 T20 TP2 TP12 TP13 1832 Sulfuric acid, spent 8 II 8 A3, A7, B2, B83, B84, N34, T9, T27 242 T8 TP2 TP12 IB2 1833 Sulfurous acid 8 II 8 B3, T8 242 T7 TP2 IB2 1834 Sulfuryl chloride 8 I 8, 6.1 1, A3, B6, B9, B10, B14, B30, B74, B77, N34, T38, T43, T44 244 T22 TP2 TP12 TP38 TP44 1835 Tetra- methyl- ammonium hydroxide 8 II 8 B2, T8 242 T7 TP2 IB2 1836 Thionyl chloride 8 I 8 A7, B6, B10, N34, T18, T27 243 T10 TP2 TP12 TP13 1837 Thiophosphoryl chloride 8 II 8 A3, A7, B2, B8, B25, B101, N34, T12 242 T7 TP2 IB2 Start Printed Page 63348 1838 Titanium tetrachloride 8 II 8, 6.1 2, A3, A6, B7, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1839 Trichloroacetic acid 8 II 8 A7, N34 240 IB8 BB2, BB4 1840 Zinc chloride, solution 8 III 8 T7 241 T4 TP1 IB3 1841 Acetaldehyde ammonia 9 III 9 240 IB8 BB6 1843 Ammonium dinitro-o-cresolate 6.1 II 6.1 T8 242 T7 TP2 IB8 BB2, BB4 1846 Carbon tetrachloride 6.1 II 6.1 N36, T8 243 T7 TP2 IB2 1847 Potassium sulfide, hydrated with not less than 30 percent water of crystallization 8 II 8 240 IB8 BB2, BB4 1848 Propionic acid 8 III 8 T7 241 T4 TP1 IB3 1849 Sodium sulfide, hydrated with not less than 30 percent water 8 II 8 T8 240 T7 TP2 IB8 BB2, BB4 1858 Hexafluoropropylene, compressed or Refrigerant gas R 1216 2.2 2.2 314, 315 T50 1862 Ethyl crotonate 3 II 3 T1 242 T4 TP2 IB2 1863 Fuel, aviation, turbine engine 3 I 3 T7 243 T11 TP1 TP8 1863 Fuel, aviation, turbine engine 3 II 3 T1 242 T4 TP1 TP8 IB2 1863 Fuel, aviation, turbine engine 3 III 3 B1, T1 242 T2 TP1 IB3 1865 n-Propyl nitrate 3 II 3 T25 None IB2 BB7 1866 Resin solution, flammable 3 I 3 B52, T8, T31 243 T11 TP1 TP8 1866 Resin solution, flammable 3 II 3 B52, T7, T30 242 T4 TP1 TP8 IB2 1866 Resin solution, flammable 3 III 3 B1, B52, T7, T30 242 T2 TP1 IB3 1868 Decaborane 4.1 II 4.1, 6.1 A19, A20 None IB6 BB2 1869 Magnesium or Magnesium alloys with more than 50 percent magnesium in pellets, turnings or ribbons 4.1 III 4.1 A1 240 IB8 BB3 1871 Titanium hydride 4.1 II 4.1 A19, A20, N34 241 IB4 1872 Lead dioxide 5.1 III 5.1 A1 240 IB8 BB3 1873 Perchloric acid with more than 50 percent but not more than 72 percent acid, by mass 5.1 I 5.1, 8 A2, A3, N41, T9, T27 243 T10 TP1 TP12 1884 Barium oxide 6.1 III 6.1 240 IB8 BB3 1885 Benzidine 6.1 II 6.1 242 IB8 BB2, BB4 1886 Benzylidene chloride 6.1 II 6.1 T8 243 T7 TP2 IB2 1887 Bromochloromethane 6.1 III 6.1 T7 241 T4 TP1 IB3 1888 Chloroform 6.1 III 6.1 N36, T14 241 T7 TP2 IB3 1891 Ethyl bromide 6.1 II 6.1 B100, T17 243 T7 TP2 TP13 IB2 BB8 1892 Ethyldichloroarsine 6.1 I 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 1894 Phenylmercuric hydroxide 6.1 II 6.1 242 IB8 BB2, BB4 1895 Phenylmercuric nitrate 6.1 II 6.1 242 IB8 BB2, BB4 1897 Tetrachloroethylene 6.1 III 6.1 N36, T1 241 T4 TP1 IB3 1898 Acetyl iodide 8 II 8 B2, B101, T9 242 T7 TP2 TP13 IB2 Start Printed Page 63349 1902 Diisooctyl acid phosphate 8 III 8 T7 241 T4 TP1 IB3 1903 Disinfectant, liquid, corrosive, n.o.s 8 I 8 A7, B10, T42 243 T14 TP2 TP27 1903 Disinfectants, liquid, corrosive n.o.s 8 II 8 B2 242 T7 TP2 IB2 1903 Disinfectants, liquid, corrosive n.o.s 8 III 8 241 T4 TP1 IB3 1905 Selenic acid 8 I 8 N34 242 IB7 BB1 1906 Sludge, acid 8 II 8 A3, A7, B2, N34, T9, T27 242 T8 TP2 TP12 IB2 1907 Soda lime with more than 4 percent sodium hydroxide 8 III 8 240 IB8 BB3 1908 Chlorite solution 8 II 8 A3, A6, A7,B2, N34, T8 242 T7 TP2 TP24 IB2 1908 Chlorite solution 8 III 8 A3, A6, A7, B2, N34, T8 241 T4 TP2 TP24 IB3 1910 Calcium oxide 8 III 8 240 IB8 BB3 1912 Methyl chloride and methylene chloride mixtures 2.1 2.1 314, 315 T50 1913 Neon, refrigerated liquid (cryogenic liquid) 2.2 2.2 None T75 1914 Butyl propionates 3 III 3 B1, T1 242 T2 TP1 IB3 1915 Cyclohexanone 3 III 3 B1, T1 242 T2 TP1 IB3 1916 2,2'-Dichlorodiethyl ether 6.1 II 6.1, 3 N33, N34, T8 243 T7 TP2 IB2 1917 Ethyl acrylate, inhibited 3 II 3 T8 242 T4 TP1 TP13 IB2 1918 Isopropylbenzene 3 III 3 B1, T1 242 T2 TP1 IB3 1919 Methyl acrylate, inhibited 3 II 3 T8 242 T4 TP1 TP13 IB2 1920 Nonanes 3 III 3 B1, T1 242 T2 TP1 IB3 1921 Propyleneimine, inhibited 3 I 3, 6.1 A3, N34, T25 243 T14 TP2 TP13 1922 Pyrrolidine 3 II 3, 8 T1 243 T7 TP1 IB2 1923 Calcium dithionite or Calcium hydrosulfite 4.2 II 4.2 A19, A20 241 IB6 BB2 1929 Potassium dithionite or Potassium hydrosulfite 4.2 II 4.2 A8, A19, A20 241 IB6 BB2 1931 Zinc dithionite or Zinc hydrosulfite 9 III None 240 IB8 1932 Zirconium scrap 4.2 III 4.2 N34 240 IB8 BB3 1935 Cyanide solutions, n.o.s 6.1 I 6.1 B37, T18, T26 243 T14 TP2 TP13 TP27 1935 Cyanide solutions, n.o.s 6.1 II 6.1 T18, T26 243 T11 TP2 TP13 TP27 IB2 1935 Cyanide solutions, n.o.s 6.1 III 6.1 T18, T26 241 T7 TP2 TP13 TP28 IB3 1938 Bromoacetic acid, solid 8 II 8 A7, N34, T9 240 T7 IB8 BB2, BB4 1938 Bromoacetic acid, solution 8 II 8 B2, T9 242 T7 TP2 IB2 1939 Phosphorus oxybromide 8 II 8 B8, B106, N41, N43 240 T7 TP2 IB8 BB2, BB4 1940 Thioglycolic acid 8 II 8 A7, B2, N34, T8 242 T7 TP2 IB2 1941 Dibromodifluoromethane, R12B2 9 III None T22 241 T11 TP2 1942 Ammonium nitrate, with not more than 0.2 percent of combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 5.1 III 5.1 A1, A29 240 IB8 BB3 Start Printed Page 63350 1951 Argon, refrigerated liquid (cryogenic liquid) 2.2 2.2 318 T75 1958 1,2-Dichloro-1,1,2,2-Tetrafluoroethane or Refrigerant gas R114 2.2 2.2 314, 315 T50 1961 Ethane, refrigerated liquid 2.1 2.1 315 T75 1963 Helium, refrigerated liquid (cryogenic liquid) 2.2 2.2 318 T75 1965 Hydrocarbon gas mixture, liquefied, n.o.s 2.1 2.1 314, 315 T50 1966 Hydrogen, refrigerated liquid (cryogenic liquid) 2.1 2.1 318, 319 T75 1969 Isobutane see also Petroleum gases, 315 liquefied 2.1 2.1 19 314, 315 T50 1970 Krypton, refrigerated liquid (cryogenic liquid) 2.2 2.2 None T75 1972 Methane, refrigerated liquid (cryogenic liquid) or Natural gas, refrigerated liquid (cryogenic liquid), with high methane content) 2.1 2.1 318 T75 1973 Chlorodifluoromethane and chloropentafluoroethane mixture or Refrigerant gas R 502 with fixed boiling point, with approximately 49 percent chlorodifluoromethane R502 2.2 2.2 314, 315 T50 1974 Chlorodifluorobromomethane or Refrigerant gas R 12B1 2.2 2.2 314, 315 T50 1976 Octafluorocyclobutane or Refrigerant gas RC318 2.2 2.2 314, 315 T50 1977 Nitrogen, refrigerated liquid cryogenic liquid 2.2 2.2 318 T75 1978 Propane see also Petroleum gases, liquefied 2.1 2.1 19 314, 315 T50 1983 1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a 2.2 2.2 314, 315 T50 1986 Alcohols, flammable, toxic, n.o.s 3 I 3, 6.1 T8, T31 243 T14 TP2 TP13 TP27 1986 Alcohols, flammable, toxic, n.o.s 3 II 3, 6.1 T8, T31 243 T11 TP2 TP27 IB2 1986 Alcohols, flammable, toxic, n.o.s 3 III 3, 6.1 B1, T8, T31 242 T7 TP1 TP28 IB3 1987 Alcohols, n.o.s 3 I 3 T8, T31 243 T11 TP1 TP8 TP27 1987 Alcohols, n.o.s 3 II 3 T8, T31 242 T7 TP1 TP8 TP28 IB2 1987 Alcohols, n.o.s 3 III 3 B1, T7, T30 242 T4 TP1 TP29 IB3 1988 Aldehydes, flammable, toxic, n.o.s 3 I 3, 6.1 T8, T31 243 T14 TP2 TP13 TP27 1988 Aldehydes, flammable, toxic, n.o.s 3 II 3, 6.1 T8, T31 243 T11 TP2 TP27 IB2 1988 Aldehydes, flammable, toxic, n.o.s 3 III 3, 6.1 B1, T8, T31 242 T7 TP1 TP28 IB3 1989 Aldehydes, n.o.s 3 I 3 T8, T31 243 T11 TP1 TP27 Start Printed Page 63351 1989 Aldehydes, n.o.s 3 II 3 T8, T31 242 T7 TP1 TP8 TP 28 IB2 1989 Aldehydes, n.o.s 3 III 3 B1, T7, T30 242 T4 TP1 TP29 IB3 1990 Benzaldehyde 9 III 9 T1 241 T2 TP1 IB3 1991 Chloroprene, inhibited 3 I 3, 6.1 B57, T15 243 T14 TP2 TP6 TP13 1992 Flammable liquids, toxic, n.o.s 3 I 3, 6.1 T42 243 T14 TP2 TP13 TP27 1992 Flammable liquids, toxic, n.o.s 3 II 3, 6.1 T18 243 T7 TP2 TP13 IB2 1992 Flammable liquids, toxic, n.o.s 3 III 3, 6.1 B1, T18 242 T7 TP1 TP28 IB3 1993 Flammable liquids, n.o.s 3 I 3 T42 243 T11 TP1 1993 Flammable liquids, n.o.s 3 II 3 T8, T31 242 T7 TP1 TP8 TP28 IB2 1993 Flammable liquids, n.o.s 3 III 3 B1, B52, T7, T30 242 T4 TP1 TP29 IB3 1994 Iron pentacarbonyl 6.1 I 6.1, 3 1, B9, B14, B30, B72, B77, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 1999 Tars, liquid including road asphalt and oils, bitumen and cut backs 3 II 3 B13, T7, T30 242 T3 TP3 TP29 IB2 1999 Tars, liquid including road asphalt and oils, bitumen and cut backs 3 III 3 B1, B13, T7, T30 242 T1 TP3 IB3 2001 Cobalt naphthenates, powder 4.1 III 4.1 A19 240 IB8 BB3 2002 Celluloid, scrap 4.2 III 4.2 241 IB8 BB3 2003 Metal alkyls water-reactive, n.o.s. or Metal aryls water-reactive, n.o.s 4.2 I 4.2, 4.3 B11, T42 244 T21 TP2 TP7 2004 Magnesium diamide 4.2 II 4.2 A8, A19, A20 241 IB6 2008 Zirconium powder, dry 4.2 II 4.2 A19, A20, N5, N34 241 IB6 BB2 2008 Zirconium powder, dry 4.2 III 4.2 241 IB8 BB3 2009 Zirconium, dry, finished sheets, strip or coiled wire 4.2 III 4.2 A1, A19 240 IB8 2014 Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary) 5.1 II 5.1, 8 12, A3, A6, B53, B80, B81, B85, B104, B110, T14, T37 243 T7 TP2 TP6 TP24 TP37 IB2 BB5 2014 Hydrogen peroxide, aqueous solutions with not less than 20 percent but not more than 40 percent hydrogen peroxide (stabilized as necessary) 5.1 II 5.1, 8 A2, A3, A6, B53, B104, B110, T14, TP37 243 T7 TP2 TP6 TP24 T37 IB2 BB5 2015 Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more than 60 percent hydrogen peroxide 5.1 I 5.1, 8 12, B53, B80, B81, B85, T15, T37 243 T10 TP2 TP6 TP24 TP37 2018 Chloroanilines, solid 6.1 II 6.1 T14, T38 242 T7 TP2 TP38 IB8 BB2, BB4 2019 Chloroanilines, liquid 6.1 II 6.1 T14 243 T7 TP2 IB2 2020 Chlorophenols, solid 6.1 III 6.1 T7 240 T4 TP1 IB8 BB3 2021 Chlorophenols, liquid 6.1 III 6.1 T7 241 T4 TP1 IB3 Start Printed Page 63352 2022 Cresylic acid 6.1 II 6.1, 8 B110, T8 243 T7 TP2 TP13 IB2 2023 Epichlorohydrin 6.1 II 6.1, 3 T14 243 T7 TP2 TP13 IB2 2024 Mercury compounds, liquid, n.o.s 6.1 II 6.1 243 IB2 2024 Mercury compounds, liquid, n.o.s 6.1 III 6.1 241 IB3 2025 Mercury compounds, solid, n.o.s 6.1 I 6.1 242 IB7 BB1 2025 Mercury compounds, solid, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 2025 Mercury compounds, solid, n.o.s 6.1 III 6.1 240 IB8 BB3 2026 Phenylmercuric compounds, n.o.s 6.1 I 6.1 242 IB7 BB1 2026 Phenylmercuric compounds, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 2026 Phenylmercuric compounds, n.o.s 6.1 III 6.1 240 IB8 BB3 2027 Sodium arsenite, solid 6.1 II 6.1 242 IB8 BB2, BB4 2030 Hydrazine hydrate or Hydrazine aqueous solutions, with not less than 37 percent but not more than 64 percent hydrazine, by mass 8 II 8, 6.1 B16, B53, B110, T15 243 T7 TP2 TP13 IB2 2031 Nitric acid other than red fuming, with more than 70 percent nitric acid 8 I 8, 5.1 B47, B53, T9, T27 243 T10 TP2 TP12 TP13 2031 Nitric acid other than red fuming, with not more than 70 percent nitric acid 8 II 8 B2, B47, B53, T9, T27 242 T8 TP2 TP12 IB2 2032 Nitric acid, red fuming 8 I 8, 5.1, 6.1 2, B9, B32, B74, T38, T43, T45 244 T20 TP2 TP12 TP13 TP38 TP45 2033 Potassium monoxide 8 II 8 240 IB8 BB2, BB4 2035 1,1,1-Trifluoroethane, compressed or Refrigerant gas R 143a 2.1 2.1 314, 315 T50 2038 Dinitrotoluenes, liquid 6.1 II 6.1 T8 243 T7 TP2 IB2 2038 Dinitrotoluenes, solid 6.1 II 6.1 T8 242 T7 TP2 IB8 BB2, BB4 2045 Isobutyraldehyde or Isobutyl aldehyde 3 II 3 T8 242 T4 TP1 IB2 2046 Cymenes 3 III 3 B1, T1 242 T2 TP1 IB3 2047 Dichloropropenes 3 II 3 T8 242 T4 TP1 IB2 2047 Dichloropropenes 3 III 3 B1, T8 242 T2 TP1 IB3 2048 Dicyclopentadiene 3 III 3 B1, T1 242 T2 TP1 IB3 2049 Diethylbenzene 3 III 3 B1, T1 242 T2 TP1 IB3 2050 Diisobutylene, isomeric compounds 3 II 3 T1 242 T4 TP1 IB2 2051 2-Dimethylaminoethanol 8 II 8, 3 B2, T8 243 T7 TP2 IB2 2052 Dipentene 3 III 3 B1, T1 242 T2 TP1 IB3 2053 Methyl isobutyl carbinol 3 III 3 B1, T1 242 T2 TP1 IB3 2054 Morpholine 3 III 3 B1, T1 242 T10 TP2 2055 Styrene monomer, inhibited 3 III 3 B1, T1 242 T2 TP1 IB3 2056 Tetrahydrofuran 3 II 3 T8 242 T4 TP1 IB2 2057 Tripropylene 3 II 3 T1 242 T4 TP1 IB2 2057 Tripropylene 3 III 3 B1, T1 242 T2 TP1 IB3 2058 Valeraldehyde 3 II 3 T1 242 T4 TP1 IB2 2059 Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose 3 II 3 T8, T31 242 T4 TP1 TP8 IB2 Start Printed Page 63353 2059 Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose 3 III 3 B1, T7, T30 242 T2 TP1 IB3 2067 Ammonium nitrate fertilizers; uniform non-segregating mixtures of ammonium nitrate with added matter which is inorganic and chemically inert towards ammonium nitrate, with not less than 90 percent ammonium nitrate and not more than 0.2 percent 5.1 III 5.1 52 240 IB8 BB3 2071 Ammonium nitrate fertilizers: uniform non-segregating mixtures of nitrogen/phosphate or nitrogen/potash types or complete fertilizers of nitrogen/phosphate/potash type, with not more than 70 percent ammonium nitrate and not more than 0.4 percent total 9 III 9 132 240 IB8 2074 Acrylamide 6.1 III 6.1 T8 240 T4 TP1 IB8 BB3 2075 Chloral, anhydrous, inhibited 6.1 II 6.1 B101, T14 243 T7 TP2 IB2 2076 Cresols 6.1 II 6.1, 8 B110, T8 243 T7 TP2 IB8 BB2, BB4 2077 alpha-Naphthylamine 6.1 III 6.1 T7 240 T3 TP1 IB8 BB3 2078 Toluene diisocyanate 6.1 II 6.1 B110, T14 243 T7 TP2 TP13 IB2 2079 Diethylenetriamine 8 II 8 B2, T8 242 T7 TP2 IB2 2187 Carbon dioxide, refrigerated liquid 2.2 2.2 314, 315 T75 2201 Nitrous oxide, refrigerated liquid 2.2 2.2, 5.1 B6 314, 315 T75 TP22 2205 Adiponitrile 6.1 III 6.1 T1 241 T3 TP1 IB3 2206 Isocyanates, toxic, n.o.s. or Isocyanate, solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C 6.1 II 6.1 T15 243 T11 TP2 TP13 TP27 IB2 2206 Isocyanates, toxic, n.o.s. or Isocyanate, solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C 6.1 III 6.1 T8 241 T7 TP1 TP13 TP28 IB3 2208 Calcium hypochlorite mixtures, dry, with more than 10 percent but not more than 39 percent available chlorine 5.1 III 5.1 A1, A29, B103, N34 240 IB8 BB3 2209 Formaldehyde, solutions, with not less than 25 percent formaldehyde 8 III 8 T1 241 T4 TP1 IB3 Start Printed Page 63354 2210 Maneb or Maneb preparations with not less than 60 percent maneb 4.2 III 4.2, 4.3 57, A1, A19, B105 242 IB6 2211 Polymeric beads, expandable, evolving flammable vapor 9 III None 32 221 IB8 BB6 2212 Blue asbestos (Crocidolite) or Brown asbestos (amosite, mysorite) 9 II 9 240 IB8 BB2, BB4 2213 Paraformaldehyde 4.1 III 4.1 A1 240 IB8 BB3 2214 Phthalic anhydride with more than .05 percent maleic anhydride 8 III 8 T7 240 T4 TP3 IB8 BB3 2215 Maleic anhydride 8 III 8 T7 240 T4 TP1 IB8 BB3 2215 Maleic anhydride 8 III 8 T7 240 T4 TP3 2216 Fish meal, stabilized or Fish scrap, stabilized 9 III None 218 IB8 2217 Seed cake with not more than 1.5 percent oil and not more than 11 percent moisture 4.2 III None N7 241 IB8 BB3, BB6 2218 Acrylic acid, inhibited 8 II 8, 3 B2, T8 243 T7 TP2 IB2 2219 Allyl glycidyl ether 3 III 3 B1, T7 242 T2 TP1 IB3 2222 Anisole 3 III 3 B1, T1 242 T2 TP1 IB3 2224 Benzonitrile 6.1 II 6.1 T14 243 T7 TP2 IB2 2225 Benzene sulfonyl chloride 8 III 8 T8 241 T4 TP1 IB3 2226 Benzotrichloride 8 II 8 B2, B101, T15 242 T7 TP2 IB2 2227 n-Butyl methacrylate, inhibited 3 III 3 B1, T1 242 T2 TP1 IB3 2232 2-Chloroethanal 6.1 I 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2233 Chloroanisidines 6.1 III 6.1 240 IB8 BB3 2234 Chlorobenzotrifluorides 3 III 3 B1, T1 242 T2 TP1 IB3 2235 Chlorobenzyl chlorides 6.1 III 6.1 T8 241 T4 TP1 IB3 2236 3-Chloro-4-methylphenyl isocyanate 6.1 II 6.1 243 IB2 2237 Chloronitroanilines 6.1 III 6.1 240 IB8 BB3 2238 Chlorotoluenes 3 III 3 B1, T1 242 T2 TP1 IB3 2239 Chlorotoluidines solid 6.1 III 6.1 240 T4 TP1 IB8 BB3 2239 Chlorotoluidines liquid 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 2240 Chromosulfuric acid 8 I 8 A3, A6, A7, B4, B6, N34, T12, T27 243 T10 TP2 TP12 TP13 2241 Cycloheptane 3 II 3 T1 242 T4 TP1 IB2 2242 Cycloheptene 3 II 3 B1, T7 242 T4 TP1 IB2 2243 Cyclohexyl acetate 3 III 3 B1, T1 242 T2 TP1 IB3 2244 Cyclopentanol 3 III 3 B1, T1 242 T2 TP1 IB3 2245 Cyclopentanone 3 III 3 B1, T1 242 T2 TP1 IB3 2246 Cyclopentene 3 II 3 B101, T13 242 T7 TP2 IB2 BB8 2247 n-Decane 3 III 3 B1, T1 242 T2 TP1 IB3 2248 Di-n-butylamine 8 II 8, 3 T8 243 T7 TP2 IB2 2250 Dichlorophenyl isocyanates 6.1 II 6.1 242 T7 TP2 IB8 BB2, BB4 2251 Bicyclo(2,2,1)hepta-2,5-diene, inhibited or 2,5-Norbornadiene, inhibited 3 II 3 242 T7 TP2 IB2 2252 1,2-Dimethoxyethane 3 II 3 T1 242 T4 TP1 IB2 2253 N,N-Dimethylaniline 6.1 II 6.1 T8 243 T7 TP2 IB1 2256 Cyclohexene 3 II 3 B101, T7 242 T4 TP1 IB2 Start Printed Page 63355 2257 Potassium 4.3 I 4.3 A19, A20, B27, B100, N6, N34, T15, T26 244 T9 TP3 TP7 IB1 BB1 2258 1,2-Propylenediamine 8 II 8, 3 A3, A6, N34, T8 243 T7 TP2 IB2 2259 Triethylenetetramine 8 II 8 B2, T8 242 T7 TP2 IB2 2260 Tripropylamine 3 III 3, 8 B1, T8 242 T4 TP1 IB3 2261 Xylenols 6.1 II 6.1 T8 242 T7 TP2 IB8 BB2, BB4 2262 Dimethylcarbamoyl chloride 8 II 8 B2, T8 242 T7 TP2 IB2 2263 Dimethylcyclohexanes 3 II 3 T1 242 T4 TP1 IB2 2264 Dimethylcyclohexylamine 8 II 8, 3 B2, T8 243 T7 TP2 IB2 2265 N,N-Dimethylformamide 3 III 3 B1, T1 242 T2 TP2 IB3 2266 Dimethyl-N-propylamine 3 II 3,8 T14, T26 243 T7 TP2 TP13 IB2 2267 Dimethyl thiophosphoryl chloride 6.1 II 6.1, 8 T7 243 T7 TP2 IB2 2269 3,3′-Iminodipropylamine 8 III 8 T8 241 T4 TP2 IB3 2270 Ethylamine, aqueous solution with not less than 50 percent but not more than 70 percent ethylamine 3 II 3, 8 T14 243 T7 TP1 IB2 2271 Ethyl amyl ketone 3 III 3 B1, T1 242 T2 TP1 IB3 2272 N-Ethylaniline 6.1 III 6.1 T2 241 T4 TP1 IB3 2273 2-Ethylaniline 6.1 III 6.1 T2 241 T4 TP1 IB3 2274 N-Ethyl-N-benzylaniline 6.1 III 6.1 T2 241 T4 TP1 IB3 2275 2-Ethylbutanol 3 III 3 B1, T1 242 T2 TP1 IB3 2276 2-Ethylhexylamine 3 III 3, 8 B1, T2 242 T4 TP1 IB3 2277 Ethyl methacrylate 3 II 3 T1 242 T4 TP1 IB2 2278 n-Heptene 3 II 3 B101, T8 242 T4 TP1 IB2 2279 Hexachlorobutadiene 6.1 III 6.1 T7 241 T4 TP1 IB3 2280 Hexamethylenediamine, solid 8 III 8 240 T4 TP1 IB8 BB3 2281 Hexamethylene diisocyanate 6.1 II 6.1 B101, T14 243 T7 TP2 TP13 IB2 2282 Hexanols 3 III 3 B1, T1 242 T2 TP1 IB3 2283 Isobutyl methacrylate, inhibited 3 III 3 B1, T1 242 T2 TP1 IB3 2284 Isobutyronitrile 3 II 3, 6.1 T17 243 T7 TP2 TP13 IB2 2285 Isocyanatobenzotrifluorides 6.1 II 6.1, 3 5, B101, T14 243 T7 TP2 IB2 2286 Pentamethylheptane 3 III 3 B1, T1 242 T2 TP1 IB3 2287 Isoheptenes 3 II 3 T7 242 T4 TP1 IB2 2288 Isohexenes 3 II 3 T7 242 T11 TP1 IB2 BB8 2289 Isophoronediamine 8 III 8 T8 241 T4 TP1 IB3 2290 Isophorone diisocyanate 6.1 III 6.1 T7 241 T4 TP2 IB3 2291 Lead compounds, soluble, n.o.s. 6.1 III 6.1 138 240 IB8 BB3 2293 4-Methoxy-4-methylpentan-2-one 3 III 3 B1, T1 242 T2 TP1 IB3 2294 N-Methylaniline 6.1 III 6.1 T7 241 T4 TP1 IB3 2295 Methyl chloroacetate 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 2296 Methylcyclohexane 3 II 3 B1, T1 242 T4 TP1 IB2 2297 Methylcyclohexanone 3 III 3 B1, T1 242 T2 TP1 IB3 2298 Methylcyclopentane 3 II 3 T8 242 T4 TP1 IB2 2299 Methyl dichloroacetate 6.1 III 6.1 T1 241 T4 TP1 IB3 2300 2-Methyl-5-ethylpyridine 6.1 III 6.1 T7 241 T4 TP1 IB3 2301 2-Methylfuran 3 II 3 T7 242 T4 TP1 IB2 2302 5-Methylhexan-2-one 3 III 3 B1, T1 242 T2 TP1 IB3 2303 Isopropenylbenzene 3 III 3 B1, T1 242 T2 TP1 IB3 2304 Naphthalene, molten 4.1 III 4.1 A1,T8 241 T1 TP3 IB1 2305 Nitrobenzenesulfonic acid 8 II 8 242 IB2 2306 Nitrobenzotrifluorides 6.1 II 6.1 T8 243 T7 TP2 IB2 Start Printed Page 63356 2307 3-Nitro-4-chlorobenzotrifluoride 6.1 II 6.1 T8 243 T7 TP2 IB2 2308 Nitrosylsulfuric acid 8 II 8 A3, A6, A7, B2, N34, T9, T27 242 T8 TP2 TP12 IB2 2309 Octadiene 3 II 3 B1, T1 242 T4 TP1 IB2 2310 Pentane-2,4-dione 3 III 3, 6.1 B1, T1 242 T4 TP1 IB3 2311 Phenetidines 6.1 III 6.1 T7 241 T4 TP1 IB3 2312 Phenol, molten 6.1 II 6.1 B14, B100, T8 243 T7 TP3 2313 Picolines 3 III 3 B1, T8 242 T4 TP1 IB3 2315 Polychlorinated biphenyls, liquid 9 II 9 9, 81 241 T4 TP1 IB3 2315 Polychlorinated biphenyls, solid 9 II 9 9, 81 240 IB7 2316 Sodium cuprocyanide, solid 6.1 I 6.1 242 IB7 BB1 2317 Sodium cuprocyanide, solution 6.1 I 6.1 T8, T26 243 T14 TP2 TP13 2318 Sodium hydrosulfide, with less than 25 percent water of crystallization 4.2 II 4.2 A7, A19, A20 241 IB6 BB2 2319 Terpene hydrocarbons, n.o.s 3 III 3 B1 T1 242 T4 TP1 TP29 IB3 2320 Tetraethylenepentamine 8 III 8 T2 241 T4 TP1 IB3 2321 Trichlorobenzenes, liquid 6.1 III 6.1 T7 241 T4 TP1 IB3 2322 Trichlorobutene 6.1 II 6.1 T8 243 T7 TP2 IB2 2323 Triethyl phosphite 3 III 3 B1, T1 242 T2 TP1 IB3 2324 Triisobutylene 3 III 3 B1, T7, T30 242 T4 TP1 IB3 2325 1,3,5-Trimethylbenzene 3 III 3 B1, T1 242 T2 TP1 IB3 2326 Trimethylcyclohexylamine 8 III 8 T2 241 T4 TP1 IB3 2327 Trimethylhexamethyl- enediamines 8 III 8 T7 241 T4 TP1 IB3 2328 Trimethylhexamethylene diisocyanate 6.1 III 6.1 T8 241 T4 TP2 TP13 IB3 2329 Trimethyl phosphite 3 III 3 B1, T1 242 T2 TP1 IB3 2330 Undecane 3 III 3 B1, T1 242 T2 TP1 IB3 2331 Zinc chloride, anhydrous 8 III 8 240 IB8 BB3 2332 Acetaldehyde oxime 3 III 3 B1 T8 242 T4 TP1 IB3 2333 Allyl acetate 3 II 3, 6.1 T8 243 T7 TP1 TP13 IB2 2334 Allylamine 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2335 Allyl Dethyl ether 3 II 3, 6.1 T8 243 T7 TP1 TP13 IB2 2336 Allyl formate 3 I 3, 6.1 T18, T26 243 T14 TP2 TP13 2337 Phenyl mercaptan 6.1 I 6.1, 3 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2338 Benzotrifluoride 3 II 3 T2 242 T4 TP1 IB2 2339 2-Bromobutane 3 II 3 B1, T1 242 T4 TP1 IB2 2340 2-Bromoethyl ethyl ether 3 II 3 T7 242 T4 TP1 IB2 2341 1-Bromo-3-methylbutane 3 III 3 B1, T7, T30 242 T2 TP1 IB3 2342 Bromomethylpropanes 3 II 3 T7, T30 242 T4 TP1 IB2 2343 2-Bromopentane 3 II 3 T1 242 T4 TP1 IB2 2344 Bromopropanes 3 II 3 T7 242 T4 TP1 IB2 2344 Bromopropanes 3 III 3 T2 242 T2 TP1 IB3 2345 3-Bromopropyne 3 II 3 T8 242 T4 TP1 IB2 2346 Butanedione 3 II 3 T1 242 T4 TP1 IB2 Start Printed Page 63357 2347 Butyl mercaptans 3 II 3 A3, T8 242 T4 TP1 IB2 2348 Butyl acrylates, inhibited 3 III 3 B1, T8, T31 242 T2 TP1 IB3 2350 Butyl methyl ether 3 II 3 T8 242 T4 TP1 IB2 2351 Butyl nitrites 3 I 3 T8 243 T11 TP1 TP8 TP27 2351 Butyl nitrites 3 II 3 T8 242 T4 TP1 IB2 2351 Butyl nitrites 3 III 3 B1, T8 242 T2 TP1 IB3 2352 Butyl vinyl ether, inhibited 3 II 3 B101, T7 242 T4 TP1 IB2 2353 Butyryl chloride 3 II 3, 8 B100, T9, T26 243 T8 TP2 TP12 TP13 IB2 2354 Chloromethyl ethyl ether 3 II 3, 61 T8 243 T7 TP1 IB2 2356 2-Chloropropane 3 I 3 N36, T14 243 T11 TP2 TP13 2357 Cyclohexylamine 8 II 8, 3 B101, T8, T26 243 T7 TP2 IB2 2358 Cyclooctatetraene 3 II 3 T8 242 T4 TP1 IB2 2359 Diallylamine 3 II 3, 6.1, 8 T8 243 T7 TP1 IB2 2360 Diallylether 3 II 3, 6.1 N12, T8 243 T7 TP1 TP13 IB2 2361 Diisobutylamine 3 III 3, 8 B1, T1 242 T4 TP1 IB3 2362 1,1-Dichloroethane 3 II 3 B101, T7 242 T4 TP1 IB2 2363 Ethyl mercaptan 3 I 3 T21 243 T11 TP2 TP13 2364 n-Propyl benzene 3 III 3 B1, T1 242 T2 TP1 IB3 2366 Diethyl carbonate 3 III 3 B1, T1 242 T2 TP1 IB3 2367 alpha-Methylvaleraldehyde 3 II 3 B1, T1 242 T4 TP1 IB2 2368 alpha-Pinene 3 III 3 B1, T1 242 T2 TP1 IB3 2370 1-Hexene 3 II 3 B101, T8 242 T4 TP1 IB2 2371 Isopentenes 3 I 3 T20 243 T11 TP2 2372 1,2-Di-(dimethylamino)ethane 3 II 3 T8 242 T4 TP1 IB2 2373 Diethoxymethane 3 II 3 T8 242 T4 TP1 IB2 2374 3,3-Diethoxypropene 3 II 3 T1 242 T4 TP1 IB2 2375 Diethyl sulfide 3 II 3 B101, T14 243 T7 TP1 TP13 IB2 2376 2,3-Dihydropyran 3 II 3 T7 242 T4 TP1 IB2 2377 1,1-Dimethoxyethane 3 II 3 T13 242 T7 TP1 IB2 2378 2-Dimethylaminoacetonitrile 3 II 3, 6.1 T8 243 T7 TP1 IB2 2379 1,3-Dimethylbutylamine 3 II 3, 8 T8 243 T7 TP1 IB2 2380 Dimethyl diethoxysilane 3 II 3 T8 242 T4 TP1 IB2 2381 Dimethyl disulfide 3 II 3 T8 242 T4 TP1 IB2 2382 Dimethyl hydrazine, symmetrical 6.1 I 6.1, 3 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2383 Dipropyl amine 3 II 3, 8 T8 243 T7 TP1 IB2 2384 Di-n-propyl ether 3 II 3 T1 242 T4 TP1 IB2 2385 Ethyl isobutyrate 3 II 3 T1 242 T4 TP1 IB2 2386 1-Ethylpiperidine 3 II 3, 8 T8 243 T7 TP1 IB2 2387 Fluorobenzene 3 II 3 B101, T8 242 T4 TP1 IB2 2388 Fluorotoluenes 3 II 3 T8 242 T4 TP1 IB2 2389 Furan 3 I 3 T18 243 T12 TP2 TP13 2390 2-Iodobutane 3 II 3 T8 242 T4 TP1 IB2 2391 Iodomethylpropanes 3 II 3 T8 242 T4 TP1 IB2 2392 Iodopropanes 3 III 3 B1, T8 242 T2 TP1 IB3 2393 Isobutyl formate 3 II 3 T1 242 T4 TP1 IB2 2394 Isobutyl propionate 3 III 3 B1, T1 242 T2 TP1 IB3 2395 Isobutyryl chloride 3 II 3, 8 B100, T9, T26 243 T7 TP2 IB1 2396 Methacrylaldehyde, inhibited 3 II 3, 6.1 45, T8 243 T7 TP1 TP13 IB2 2397 3-Methylbutan-2-one 3 II 3 T1 242 T4 TP1 IB2 2398 Methyl tert-butyl ether 3 II 3 B101, T14 242 T7 TP1 IB2 2399 1-Methylpiperidine 3 II 3, 8 T8 243 T7 TP1 IB2 2400 Methyl isovalerate 3 II 3 T1 242 T4 TP1 IB2 2401 Piperidine 8 I 3, 88, 3 T2, T17 243 T10 TP2 2402 Propanethiols 3 II 3 T8 242 T4 TP1 TP13 IB2 2403 Isopropenyl acetate 3 II 3 T1 242 T4 TP1 IB2 2404 Propionitrile 3 II 3, 6.1 T14 243 T7 TP1 TP13 IB2 2405 Isopropyl butyrate 3 III 3 B1, T1 242 T2 TP1 IB3 Start Printed Page 63358 2406 Isopropyl isobutyrate 3 II 3 T1 242 T4 TP1 IB2 2407 Isopropyl chloroformate 6.1 I 6.1, 3, 8 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP44 2409 Isopropyl propionate 3 II 3 T1 242 T4 TP1 IB2 2410 1,2,3,6-Tetrahydropyridine 3 II 3 T8 242 T4 TP1 IB2 2411 Butyronitrile 3 II 3, 6.1 T14 243 T7 TP1 TP13 IB2 2412 Tetrahydrothiophene 3 II 3 T7 242 T4 TP1 IB2 2413 Tetrapropylorthotitanate 3 III 3 B1, T8 242 T4 TP1 IB3 2414 Thiophene 3 II 3 B101, T2 242 T4 TP1 IB2 2416 Trimethyl borate 3 II 3 T14 242 T7 TP1 IB2 2424 Octafluoropropane or Refrigerant gas R 218 2.2 2.2 314, 315 T50 2426 Ammonium nitrate, liquid (hot concentrated solution) 5.1 5.1 B5, B100, T25 243 T7 2427 Potassium chlorate, aqueous solution 5.1 II 5.1 A2, T8 241 T4 TP1 IB2 2427 Potassium chlorate, aqueous solution 5.1 III 5.1 A2, T8 241 T4 TP1 IB2 2428 Sodium chlorate, aqueous solution 5.1 II 5.1 A2, B6, T8 241 T4 TP1 IB2 2428 Sodium chlorate, aqueous solution 5.1 III 5.1 A2, T8 241 T4 TP1 IB2 2429 Calcium chlorate aqueous solution 5.1 II 5.1 A2, N41, T8 242 T4 TP1 IB2 2429 Calcium chlorate aqueous solution 5.1 III 5.1 A2, N41, T8 241 T4 TP1 IB2 2430 Alkylphenols, solid, n.o.s. (including C2-C12 homologues) 8 I 8 T8 242 T10 TP2 TP28 IB7 BB1 2430 Alkylphenols, solid, n.o.s. (including C2-C12 homologues) 8 II 8 T8 240 T3 TP2 IB8 BB2, BB4 2430 Alkylphenols, solid, n.o.s. (including C2-C12 homologues) 8 III 8 T8 240 T3 TP1 IB8 BB3 2431 Anisidines 6.1 III 6.1 T1 241 T4 TP1 IB3 2432 N,N-Diethylaniline 6.1 III 6.1 T2 241 T4 TP1 IB3 2433 Chloronitrotoluenes, solid 6.1 III 6.1 240 IB8 BB3 2433 Chloronitrotoluenes liquid 6.1 III 6.1 241 T4 TP1 IB3 2434 Dibenzyldichlorosilane 8 II 8 B2, T8, T26 242 T7 TP2 TP13 IB2 2435 Ethylphenyldichlorosilane 8 II 8 A7, B2, N34, T8, T26 242 T7 TP2 TP13 IB2 2436 Thioacetic acid 3 II 3 T8 242 T4 TP1 IB2 2437 Methylphenyldichlorosilane 8 II 8 T8, T26 242 T7 TP2 TP13 IB2 2438 Trimethylacetyl chloride 6.1 I 6.1, 8, 3 2, A3, A6, A7, B3, B9, B14, B32, B74, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2439 Sodium hydrogendifluoride solution 8 II 8 N3, N34 242 IB8 BB2, BB4 2439 Sodium hydrogendifluoride, solid 8 II 8 B106, N3, N34 240 IB8 BB2, BB4 s 2440 Stannic chloride, pentahydrate 8 III 8 240 IB8 BB3 Start Printed Page 63359 2442 Trichloroacetyl chloride 8 II 8, 6.1 2, A3, A7, B9, B14, B32, B74, N34, T38, T43, T45 244 T20 TP2 TP38, TP45 2443 Vanadium oxytrichloride 8 II 8 A3, A6, A7, B2, B16, N34, T8, T26 242 T7 TP2 IB2 2444 Vanadium tetrachloride 8 I 8 A3, A6, A7, B4, N34, T8, T26 243 T10 TP2 2445 Lithium alkyls 4.2 I 4.2, 4.3 B11, T28, T40 244 T21 TP2 TP7 2446 Nitrocresols 6.1 III 6.1 240 IB8 BB3 2447 Phosphorus white, molten 4.2 I 4.2, 6.1 B9, B26, N34, T15, T26, T29 243 T21 TP3 TP7 TP26 2448 Sulfur, molten 4.1 III 4.1 T9, T38 247 T1 TP3 TP38 IB1 2456 2-Chloropropene 3 I 3 A3, N36, T20 243 T11 TP2 2457 2,3-Dimethylbutane 3 II 3 T13 242 T7 TP1 IB2 2458 Hexadienes 3 II 3 B101, T7 242 T4 TP1 IB2 2459 2-Methyl-1-butene 3 I 3 T14 243 T11 TP2 2460 2-Methyl-2-butene 3 II 3 T14 242 T7 TP1 IB2 BB8 2461 Methylpentadienes 3 II 3 T7 242 T4 TP1 IB2 2464 Berylium nitrate 5.1 II 5.1, 6.1 242 IB8 BB2, BB4 2465 Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts 5.1 II 5.1 28 240 IB8 BB4 2466 Potassium superoxide 5.1 I 5.1 A20 None IB6 BB1 2468 Trichloroisocyanuric acid, dry 5.1 II 5.1 240 IB8 BB4 2469 Zinc bromate 5.1 III 5.1 A1, A29 240 IB8 BB3 2470 Phenylacetonitrile, liquid 6.1 III 6.1 T8 241 T4 TP1 IB3 2471 Osmium tetroxide 6.1 I 6.1 A8, B100, N33, N34 242 IB7 BB1 2473 Sodium arsanilate 6.1 III 6.1 240 IB8 BB3 2474 Thiophosgene 6.1 II 6.1 2, A7, B9, B14, B32, B74, N33, N34, T38, T43, T45 244 T20 TP2 TP38 TP45 2475 Vanadium trichloride 8 III 8 240 IB8 BB3 2477 Methyl isothiocyanate 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2478 Isocyanates, flammable, toxic, n.o.s. or Isocyanate solutions, flammable, toxic, n.o.s. flashpoint less than 23 degrees C 3 II 3, 6.1 5, A3, A7, T15 243 T11 TP2 TP13 TP27 IB2 Start Printed Page 63360 2480 Methyl isocyanate 6.1 I 6.1, 3 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 2481 Ethyl isocyanate 3 I 3, 6.1 1, A7, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 2482 n-Propyl isocyanate 6.1 I 6.1, 3 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 2483 Isopropyl isocyanate 3 I 3, 6.1 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 2484 tert-Butyl isocyanate 6.1 I 6.1, 3 1, A7, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 2485 n-Butyl isocyanate 6.1 I 6.1, 3 2, A7, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2486 Isobutyl isocyanate 3 I 3, 6.1 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP27 2487 Phenyl isocyanate 6.1 I 6.1, 3 2, B9, B14, B32, B74, B77, N33, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2488 Cyclohexyl isocyanate 6.1 I 6.1, 3 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2490 Dichloroisopropyl ether 6.1 II 6.1 T8 243 T7 TP2 IB2 2491 Ethanolamine or Ethanolamine solutions 8 III 8 T7 241 T4 TP1 IB3 2493 Hexamethyleneimine 3 II 3, 8 B101, T8 243 T7 TP1 IB2 2496 Propionic anhydride 8 III 8 T2 241 T4 TP1 IB3 2498 1, 2, 3, 6-Tetrahydrobenzaldehyde 3 III 3 B1, T1 242 T2 TP1 IB3 Start Printed Page 63361 2501 Tris-(1-aziridinyl)phosphine oxide, solution 6.1 II 6.1 T8 243 T7 TP2 IB2 2501 Tris-(1-aziridinyl)phosphine oxide, solution 6.1 III 6.1 T7 241 T4 TP1 IB3 2502 Valeryl chloride 8 II 8, 3 A3, A6, A7, B2, N34, T8 243 T7 TP2 IB2 2503 Zirconium tetrachloride 8 III 8 240 IB8 BB3 2504 Tetrabromoethane 6.1 III 6.1 T7 241 T4 TP1 IB3 2505 Ammonium fluoride 6.1 III 6.1 240 IB8 BB3 2506 Ammonium hydrogen sulfate 8 II 8 240 IB8 BB2, BB4 2507 Chloroplatinic acid, solid 8 III 8 240 IB8 BB3 2508 Molybdenum pentachloride 8 III 8 T8, T26 240 T4 TP1 IB8 BB3 2509 Potassium hydrogen sulfate 8 II 8 A7, N34 240 IB8 BB2, BB4 2511 2-Chloropropionic acid 8 III 8 T8 241 TP2 IB3 2512 Aminophenols (o-; m-; p-) 6.1 III 6.1 T1 240 T4 TP1 IB8 BB3 2513 Bromoacetyl bromide 8 II 8 B2, T9, T26 242 T8 TP2 TP12 IB2 2514 Bromobenzene 3 III 3 B1, T1 242 T2 TP1 IB3 2515 Bromoform 6.1 III 6.1 T7 241 T4 TP1 IB3 2516 Carbon tetrabromide 6.1 III 6.1 240 IB8 BB3 2517 1-Chloro-1,1-difluoroethanes or Refrigerant gas R 142b 2.1 2.1 314, 315 T50 2518 1,5,9-Cyclododecatriene 6.1 III 6.1 T7 241 T4 TP1 IB3 2520 Cyclooctadienes 3 III 3 B1, T1 242 T2 TP1 IB3 2521 Diketene, inhibited 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2522 2-Dimethylaminoethyl methacrylate 6.1 II 6.1 T8 243 T7 TP2 IB2 2524 Ethyl orthoformate 3 III 3 B1, T7 242 T2 TP1 IB3 2525 Ethyl oxalate 6.1 III 6.1 T1 241 T4 TP1 IB3 2526 Furfurylamine 3 III 3, 8 B1, T1 242 T4 TP1 IB3 2527 Isobutyl acrylate, inhibited 3 III 3 B1, T1 242 T2 TP1 IB3 2528 Isobutyl isobutyrate 3 III 3 B1, T1 242 T2 TP1 IB3 2529 Isobutyric acid 3 III 3, 8 B1, T1 242 T4 TP1 IB3 2531 Methacrylic acid, inhibited 8 III 8 T8, T47 241 T4 TP1 TP18 IB3 2533 Methyl trichloroacetate 6.1 III 6.1 T1 241 T4 TP1 IB3 2535 4-Methylmorpholine or n-methylmorpholine 3 II 3, 8 B6, T8 243 T7 TP1 IB2 2536 Methyltetrahydrofuran 3 II 3 B101, T7 242 T4 TP1 IB2 2538 Nitronaphthalene 4.1 III 4.1 A1 240 IB8 BB3 2541 Terpinolene 3 III 3 B1, T1 242 T2 TP1 IB3 2542 Tributylamine 6.1 II 6.1 B110, T14 243 T7 TP2 IB2 2545 Hafnium powder, dry 4.2 II 4.2 A19, A20, B101, B106, N34 241 IB6 BB2 2545 Hafnium powder, dry 4.2 III 4.2 B100, B106 241 IB8 BB3 2546 Titanium powder, dry 4.2 II 4.2 A19, A20, N5, N34 241 IB6 BB2 2546 Titanium powder, dry 4.2 III 4.2 241 IB8 BB3 2547 Sodium superoxide 5.1 I 5.1 A20, N34 None IB6 BB1 2552 Hexafluoroacetone hydrate 6.1 II 6.1 T14 243 T7 TP2 IB2 2554 Methyl allyl chloride 3 II 3 B101, T8 242 T4 TP1 TP13 IB2 2558 Epibromohydrin 6.1 I 6.1, 3 T18, T26 243 T14 TP2 TP13 Start Printed Page 63362 2560 2-Methylpentan-2-ol 3 III 3 B1, T1 242 T2 TP1 IB3 2561 3-Methyl-1-butene 3 I 3 T20 243 T11 TP2 2564 Trichloroacetic acid, solution 8 II 8 A3, A6, A7, B2, N34, T8 242 T7 TP2 IB2 2564 Trichloroacetic acid, solution 8 III 8 A3, A6, A7, N34, T7 241 T4 TP1 IB3 2565 Dicyclohexylamine 8 III 8 T8 241 T4 TP1 IB3 2567 Sodium pentachlorophenate 6.1 II 6.1 242 IB8 BB2, BB4 2570 Cadmium compounds 6.1 I 6.1 242 IB7 BB1 2570 Cadmium compounds 6.1 II 6.1 242 IB8 BB2, BB4 2570 Cadmium compounds 6.1 III 6.1 240 IB8 BB3 2571 Alkylsulfuric acids 8 II 8 B2, T9, T27 242 T8 TP2 TP12 TP13 IB2 2572 Phenylhydrazine 6.1 II 6.1 T8 243 T7 TP2 IB2 2573 Thallium chlorate 5.1 II 5.1, 6.1 242 IB6 BB2 2574 Tricresyl phosphate with more than 3 percent ortho isomer 6.1 II 6.1 A3, N33, N34, T8 243 T7 TP2 IB2 2576 Phosphorus oxybromide, molten 8 II 8 B2, B8, N41, N43, T8, T27 242 T7 TP3 TP13 IB1 2577 Phenylacetyl chloride 8 II 8 B2, T8, T26 242 T7 TP2 IB2 2578 Phosphorus trioxide 8 III 8 240 IB8 BB3 2579 Piperazine 8 III 8 T7 240 T4 TP1 IB8 BB3 2580 Aluminum bromide, solution 8 III 8 T8 241 T4 TP1 IB3 2581 Aluminum chloride, solution 8 III 8 T8 241 T4 TP1 IB3 2582 Ferric chloride, solution 8 III 8 B15, T8 241 T4 TP1 IB3 2583 Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric acid 8 II 8 240 IB8 BB2, BB4 2584 Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid 8 II 8 B2, T8, T27 242 T8 TP2 TP12 TP13 IB2 2585 Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid 8 III 8 240 IB8 BB3 2586 Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid 8 III 8 T8 241 T4 TP1 IB3 2587 Benzoquinone 6.1 II 6.1 242 IB8 BB2, BB4 2588 Pesticides, solid, toxic, n.o.s. 6.1 I 6.1 242 IB7 2588 Pesticides, solid, toxic, n.o.s. 6.1 II 6.1 242 IB8 BB2, BB4 2588 Pesticides, solid, toxic, n.o.s. 6.1 III 6.1 240 IB8 BB3 2589 Vinyl chloroacetate 6.1 II 6.1, 3 T14 243 T7 TP2 IB2 2590 White asbestos (chrysotile, actinolite, anthophyllite, tremolite) 9 III 9 240 IB8 BB2, BB3 2591 Xenon, refrigerated liquid (cryogenic liquids) 2.2 2.2 None T75 Start Printed Page 63363 2602 Dichlorodifluoromethane and difluoroethane azeotropic mixture or Refrigerant gas R 500 with approximately 74 percent dichlorodifluoromethane 2.2 2.2 314, 315 T50 2603 Cycloheptatriene 3 II 3, 6.1 T14 243 T7 TP1 TP13 IB2 2604 Boron trifluoride diethyl etherate 8 I 8, 3 A19, T8, T26 243 T10 TP2 2605 Methoxymethyl isocyanate 3 I 3, 6.1 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 2606 Methyl orthosilicate 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2607 Acrolein dimer, stabilized 3 III 3 B1, T1 242 T2 TP1 IB3 2608 Nitropropanes 3 III 3 B1, T1 242 T2 TP1 IB3 2609 Triallyl borate 6.1 III 6.1 241 IB3 2610 Triallylamine 3 III 3, 8 B1, T1 242 T4 TP1 IB3 2611 Propylene chlorohydrin 6.1 II 6.1, 3 T9 243 T7 TP2 TP13 IB2 2612 Methyl propyl ether 3 II 3 T14 242 T7 TP2 IB2 BB8 2614 Methallyl alcohol 3 III 3 B1, T1 242 T2 TP1 IB3 2615 Ethyl propyl ether 3 II 3 B101, T8 242 T4 TP1 IB2 2616 Triisopropyl borate 3 II 3 T8, T31 242 T4 TP1 IB2 2616 Triisopropyl borate 3 III 3 B1, T8, T31 242 T2 TP1 IB3 2617 Methylcyclohexanols, flammable 3 III 3 B1, T2 242 T2 TP1 IB3 2618 Vinyltoluenes, inhibited 3 III 3 B1, T1 242 T2 TP1 IB3 2619 Benzyldimethylamine 8 II 8, 3 B2, T1 243 T7 TP2 IB2 2620 Amyl butyrates 3 III 3 B1, T1 242 T2 TP1 IB3 2621 Acetyl methyl carbinol 3 III 3 B1, T1 242 T2 TP1 IB3 2622 Glycidaldehyde 3 II 3, 6.1 T8 243 T7 TP1 IB2 BB8 2624 Magnesium silicide 4.3 II 4.3 A19, A20, B105, B106 241 IB7 BB2 2626 Chloric acid aqueous solution, with not more than 10 percent chloric acid 5.1 II 5.1 T25 None IB2 2627 Nitrites, inorganic, n.o.s. 5.1 II 5.1 33 None IB8 BB4 2628 Potassium fluoroacetate 6.1 I 6.1 242 IB7 BB1 2629 Sodium fluoroacetate 6.1 I 6.1 242 IB7 BB1 2630 Selenates or Selenites 6.1 I 6.1 242 IB7 BB1 2642 Fluoroacetic acid 6.1 I 6.1 B100 242 IB7 BB1 2643 Methyl bromoacetate 6.1 II 6.1 B100, T8 243 T7 TP2 IB2 2644 Methyl iodide 6.1 I 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2645 Phenacyl bromide 6.1 II 6.1 B106 242 IB8 BB2, BB4 Start Printed Page 63364 2646 Hexachlorocyclopentadiene 6.1 I 6.1 2, B9, B14, B32, B74, B77, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2647 Malononitrile 6.1 II 6.1 242 IB8 BB2, BB4 2648 1,2-Dibromobutan-3-one 6.1 II 6.1 243 IB2 2649 1,3-Dichloroacetone 6.1 II 6.1 242 IB8 BB2, BB4 2650 1,1-Dichloro-1-nitroethane 6.1 II 6.1 T8 243 T7 TP2 IB2 2651 4,4'-Diaminodiphenyl methane 6.1 III 6.1 240 T4 TP1 IB8 BB3 2653 Benzyl iodide 6.1 II 6.1 T8 243 T7 TP2 IB2 2655 Potassium fluorosilicate 6.1 III 6.1 240 IB8 BB3 2656 Quinoline 6.1 III 6.1 T8 241 T4 TP1 IB3 2657 Selenium disulfide 6.1 II 6.1 242 IB8 BB2, BB4 2659 Sodium chloroacetate 6.1 III 6.1 240 IB8 BB3 2660 Nitrotoluidines (mono) 6.1 III 6.1 240 IB8 BB3 2661 Hexachloroacetone 6.1 III 6.1 T8 241 T4 TP1 IB3 2662 Hydroquinone 6.1 III 6.1 240 T4 TP1 IB8 BB3 2664 Dibromomethane 6.1 III 6.1 T7 241 T4 TP1 IB3 2667 Butyltoluenes 6.1 III 6.1 T2 241 T4 TP1 IB3 2668 Chloroacetonitrile 6.1 II 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP38 TP45 IBC99 2669 Chlorocresols, solid 6.1 II 6.1 242 T7 IB8 BB2, BB3 2669 Chlorocresols, liquid 6.1 II 6.1 T8 243 T7 TP2 IB2 2670 Cyanuric chloride 8 II 8 240 IB8 BB2, BB4 2671 Aminopyridines (o-; m-; p-) 6.1 II 6.1 T7 242 T7 TP2 IB8 BB2, BB4 2672 Ammonia solutions, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia 8 III 8 T14 241 T7 TP1 IB3 2673 2-Amino-4-chlorophenol 6.1 II 6.1 242 IB8 BB2, BB4 2674 Sodium fluorosilicate 6.1 III 6.1 240 IB8 BB3 2677 Rubidium hydroxide solution 8 II 8 B2, T8 242 T7 TP2 IB2 2677 Rubidium hydroxide solution 8 III 8 T7 241 T4 TP1 IB3 2678 Rubidium hydroxide 8 II 8 T8 240 T7 TP2 IB8 BB2, BB4 2679 Lithium hydroxide, solution 8 II 8 B2, T8 242 T7 TP2 IB2 2679 Lithium hydroxide, solution 8 III 8 T8 241 T4 TP2 IB3 2680 Lithium hydroxide, monohydrate or Lithium hydroxide, solid 8 II 8 240 IB8 BB2, BB4 2681 Caesium hydroxide solution or Cesium hydroxide solution 8 II 8 B2, T8 242 T7 TP2 IB2 2681 Caesium hydroxide solution or Cesium hydroxide solution 8 III 8 T7 241 T4 TP1 IB3 2682 Caesium hydroxide or Cesium hydroxide 8 II 8 240 IB8 BB2, BB4 2683 Ammonium sulfide solution 8 II 8, 6.1, 3 T14 243 T7 TP2 TP13 IB1 2684 Diethylaminopropylamine 3 III 3, 8 B1, T8 242 T4 TP1 IB3 Start Printed Page 63365 2685 N,N-Diethylethylenediamine 8 II 8, 3 T8 243 T7 TP2 IB2 2686 2-Diethylaminoethanol 8 II 8, 3 B2, T15, T26 243 T7 TP2 IB2 2687 Dicyclohexylammonium nitrite 4.1 III 4.1 240 IB8 BB3 2688 1-Chloro-3-bromopropane 6.1 III 6.1 T2 241 T4 TP1 IB3 2689 Glycerol alpha- monochlorohydrin 6.1 III 6.1 T2 241 T4 TP1 IB3 2690 N-n-Butyl imidazole 6.1 II 6.1 T8 243 T7 TP2 IB2 2691 Phosphorus pentabromide 8 II 8 A7, B106, N34 240 IB8 BB2, BB4 2692 Boron tribromide 8 I 8, 6.1 2, A3, A7, B9, B14, B32, B74, N34, T38, T43, T45 244 T20 TP2 TP12 TP13 TP38 TP45 2693 Bisulfites, aqueous solutions, n.o.s 8 III 8 T8 241 T7 TP1 TP28 IB3 2698 Tetrahydrophthalic anhydrides with more than 0.05 percent of maleic anhydride 8 III 8 240 IB8 BB3 2699 Trifluoroacetic acid 8 I 8 A3, A6, A7, B4, N3, N34, T18, T27 243 T10 TP2 TP12 2705 1-Pentol 8 II 8 B2, T8 242 T7 TP2 IB2 2707 Dimethyldioxanes 3 II 3 T8, T31 242 T4 TP1 IB2 2707 Dimethyldioxanes 3 III 3 B1, T7, T30 242 T2 TP1 IB3 2709 Butyl benzenes 3 III 3 B1, T1 242 T2 TP1 IB3 2710 Dipropyl ketone 3 III 3 B1, T1 242 T2 TP1 IB3 2713 Acridine 6.1 III 6.1 240 IB8 BB3 2714 Zinc resinate 4.1 III 4.1 A1 240 IB6 2715 Aluminum resinate 4.1 III 4.1 240 IB6 2716 1,4-Butynediol 6.1 III 6.1 A1 240 IB8 BB3 2717 Camphor, synthetic 4.1 III 4.1 A1 240 IB8 BB3 2719 Barium bromate 5.1 II 5.1, 6.1 242 IB8 BB2, BB4 2720 Chromium nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 2721 Copper chlorate 5.1 II 5.1 A1 242 IB8 BB2, BB4 2722 Lithium nitrate 5.1 III 5.1 A1 240 IB8 BB3 2723 Magnesium chlorate 5.1 II 5.1 242 IB8 BB2, BB4 2724 Manganese nitrate 5.1 III 5.1 A1 240 IB8 BB3 2725 Nickel nitrate 5.1 III 5.1 A1 240 IB8 BB3 2726 Nickel nitrite 5.1 III 5.1 A1 240 IB8 BB3 2727 Thallium nitrate 6.1 II 6.1, 5.1 242 IB6 BB2 2728 Zirconium nitrate 5.1 III 5.1 A1, A29 240 IB8 BB3 2729 Hexachlorobenzene 6.1 III 6.1 241 IB3 2730 Nitroanisole 6.1 III 6.1 T8 240 T4 TP1 IB8 BB3 2732 Nitrobromobenzenes solid 6.1 III 6.1 240 T4 TP1 IB8 BB3 2732 Nitrobromobenzenes liquid 6.1 III 6.1 T8, T38 241 T4 TP1 TP38 IB3 2733 Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s 3 I 3, 8 T42 243 T14 TP1 TP27 2733 Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s 3 II 3, 8 T8, T31 243 T11 TP1 TP27 IB2 2733 Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s 3 III 3, 8 B1, T8, T31 242 T7 TP1 TP28 IB3 Start Printed Page 63366 2734 Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s 8 I 8, 3 A3, A6, N34, T8, T31 243 T14 TP2 TP27 2734 Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s 8 II 8, 3 T8, T31 243 T11 TP2 TP27 IB2 2735 Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s 8 I 8 A3, A6, B10, N34, T42 243 T14 TP2 TP27 2735 Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s 8 II 8 B2, T8 242 T11 TP1 TP27 IB2 2735 Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, corrosive, n.o.s 8 III 8 T8 241 T7 TP1 TP28 IB3 2738 N-Butylaniline 6.1 II 6.1 T8 243 T7 TP2 IB2 2739 Butyric anhydride 8 III 8 T2 241 T4 TP1 IB3 2740 n-Propyl chloroformate 6.1 I 6.1, 3, 8 2, A3, A6, A7, B9, B14, B32, B74, B77, N34, T38, T43, T45 244 T20 TP2 TP13 TP38 TP44 2741 Barium hypochlorite with more than 22 percent available chlorine 5.1 II 5.1, 6.1 A7, A9, N34 None IB8 BB2, BB4 2742 Chloroformates, toxic, corrosive, flammable, n.o.s 6.1 II 6.1, 8, 3 5 243 T7 TP2 IB1 2743 n-Butyl chloroformate 6.1 I 6.1, 8, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 2744 Cyclobutyl chloroformate 6.1 II 6.1, 8, 3 T18 243 T7 TP2 TP13 IB1 2745 Chloromethyl chloroformate 6.1 II 6.1, 8 T18 243 T7 TP2 TP13 IB2 2746 Phenyl chloroformate 6.1 II 6.1, 8 T12 243 T7 TP2 TP13 IB2 2747 tert-Butylcyclohexylchloroformate 6.1 III 6.1 T8 241 T4 TP1 IB3 2748 2-Ethylhexyl chloroformate 6.1 II 6.1, 8 T12 243 T7 TP2 TP13 IB2 2749 Tetramethylsilane 3 I 3 T21, T26 243 T14 TP2 2750 1,3-Dichloropropanol-2 6.1 II 6.1 T8 243 T7 TP2 IB2 2751 Diethylthiophosphoryl chloride 8 II 8 B2, T8 240 T7 TP2 IB8 BB2, BB4 2752 1,2-Epoxy-3-ethoxypropane 3 III 3 B1, T1 242 T2 TP1 IB3 2753 N-Ethylbenzyltoluidines solid 6.1 III 6.1 240 T7 TP1 IB8 BB3 2753 N-Ethylbenzyltoluidines liquid 6.1 III 6.1 T14 241 T7 TP1 IB3 2754 N-Ethyltoluidines 6.1 II 6.1 T14 243 T7 TP2 IB2 2757 Carbamate pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2757 Carbamate pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 Start Printed Page 63367 2757 Carbamate pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2758 Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2758 Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2759 Arsenical pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2759 Arsenical pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2759 Arsenical pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2760 Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2760 Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2761 Organochlorine pesticides, solid toxic 6.1 I 6.1 242 IB7 BB1 2761 Organochlorine pesticides, solid toxic 6.1 II 6.1 242 IB8 BB2, BB4 2761 Organochlorine pesticides, solid toxic 6.1 III 6.1 240 IB8 BB3 2762 Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2762 Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2763 Triazine pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2763 Triazine pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2763 Triazine pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2764 Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2764 Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2771 Thiocarbamate pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2771 Thiocarbamate pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2771 Thiocarbamate pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2772 Thiocarbomate pesticide, liquid, flammable, toxic, flashpoint less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2772 Thiocarbomate pesticide, liquid, flammable, toxic, flashpoint less than 23 degrees C. 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2775 Copper based pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 Start Printed Page 63368 2775 Copper based pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2775 Copper based pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2776 Copper based pesticides, liquid, flammable, tox, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2776 Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2777 Mercury based pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2777 Mercury based pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2777 Mercury based pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2778 Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2778 Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2779 Substituted nitrophenol pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2779 Substituted nitrophenol pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2779 Substituted nitrophenol pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2780 Substituted nitrophenol pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 T27 2780 Substituted nitrophenol pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2781 Bipyridilium pesticides, solid, toxic 6.1 I 6.1 242 IB7 BB1 2781 Bipyridilium pesticides, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 2781 Bipyridilium pesticides, solid, toxic 6.1 III 6.1 240 IB8 BB3 2782 Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 2782 Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 2783 Organophosphorus pesticides, solid, toxic 6.1 I 6.1 N77 242 IB7 BB1 2783 Organophosphorus pesticides, solid, toxic 6.1 II 6.1 N77 242 IB8 BB2, BB4 2783 Organophosphorus pesticides, solid, toxic 6.1 III 6.1 N77 240 IB8 BB3 Start Printed Page 63369 2784 Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 l 3, 6.1 T42 243 T14 TP2 TP13 TP27 2784 Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 ll 3, 6.1 T18 243 T11 TP2 TP13 TP27 lB2 2785 4-Thiapentanal 6.1 lll 6.1 T8 241 T4 TP1 lB3 2786 Organotin pesticides, solid, toxic 6.1 l 6.1 242 lB7 BBl 2786 Organotin pesticides, solid, toxic 6.1 ll 6.1 242 lB8 BB2, BB4 2786 Organotin pesticides, solid, toxic 6.1 lll 6.1 240 lB8 BB3 2787 Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 l 3, 6.1 243 T14 TP2 TP13 TP27 2787 Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 ll 3, 6.1 243 T11 TP2 TP13 TP27 lB2 2788 Organotin compounds, liquid, n.o.s 6.1 l 6.1 A3, N33, N34, T42 243 T14 TP2 TP13 TP27 2788 Organotin compounds, liquid, n.o.s 6.1 ll 6.1 A3, N33, N34, T14 243 T11 TP2 TP13 TP27 lB2 2788 Organotin compounds, liquid, n.o.s 6.1 lll 6.1 T14 241 T7 TP2 TP28 lB3 2789 Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass 8 ll 8, 3 A3, A6, A7, A10, B2, T8 243 T7 TP2 lB2 2790 Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by mass 8 ll 8 A3, A6, A7, A10, B2, T8 242 T7 TP2 lB2 2790 Acetic acid solution, with more than 10 percent and less than 50 percent acid by mass 8 lll 8 T8 242 T4 TP1 lB3 2793 Ferrous metal borings or Ferrous metal shavings or Ferrous metal turnings or Ferrous metal cuttings in a form liable to self-heating 4.2 lll 4.2 A1, A19, B101 241 lB8 BB3, BB6 2796 Battery fluid, acid 8 ll 8 A3, A7, B2, B15, N6, N34, T9, T27 242 T8 TP2 TP12 lB2 2796 Sulfuric acid with not more than 51% acid 8 ll 8 A3, A7, B2, B15, N6, N34, T9, T27 242 T8 TP2 TP12 lB2 2797 Battery fluid, alkali 8 ll 8 B2, N6, T8 242 T7 TP2 lB2 2798 Phenyl phosphorus dichloride 8 ll 8 B2, B15, T8, T26 242 T7 TP2 lB2 2799 Phenyl phosphorus thiodichloride 8 ll 8 B2, B15, T8, T26 242 T7 TP2 lB2 2801 Dyes, liquid, corrosive, n.o.s. or Dye intermediates liquid, corrosive, n.o.s 8 l 8 11, B10 243 T14 TP2 TP27 Start Printed Page 63370 2801 Dyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid, corrosive, n.o.s 8 ll 8 11, B2, T14 242 T11 TP2 TP27 lB2 2801 Dyes, liquid, corrosive, n.o.s. or Dye intermediates liquid, corrosive, n.o.s 8 lll 8 11, T7 241 T7 TP1 TP28 lB3 2802 Copper chloride 8 lll 8 240 lB8 BB3 2805 Lithium hydride, fused solid 4.3 ll 4.3 A8, A19, A20, B101, B106 241 lB4 2806 Lithium nitride 4.3 l 4.3 A19, B101, B106, N40 242 lB4 BB1 2810 Toxic, liquids, organic, n.o.s. Inhalation hazard, Packing Group I, Zone A 6.1 l 6.1 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP27 TP38 TP44 2810 Toxic, liquids, organic, n.o.s. Inhalation hazard, Packing Group I, Zone B 6.1 l 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP27 TP38 TP45 2810 Toxic, liquids, organic, n.o.s 6.1 l 6.1 T42 243 T14 TP2 TP13 TP27 2810 Toxic, liquids, organic, n.o.s 6.1 ll 6.1 B110, T14 243 T11 TP2 TP13 TP27 lB2 2810 Toxic, liquids, organic, n.o.s 6.1 lll 6.1 T7 241 T7 TP1 TP28 lB3 2811 Toxic solids, organic, n.o.s 6.1 l 6.1 242 lB7 2811 Toxic solids, organic, n.o.s 6.1 ll 6.1 242 lB8 BB2, BB4 2811 Toxic solids, organic, n.o.s 6.1 lll 6.1 240 lB8 BB3 2812 Sodium aluminate, solid 8 lll 8 240 lB8 BB3 2813 Water reactive solid, n.o.s 4.3 1 4.3 B101, B106, N40 240 IB4 2813 Water-reactive solid, n.o.s 4.3 ll 4.3 B101, B106 242 lB7 BB2 2813 Water-reactive solid, n.o.s 4.3 lll 4.3 B105, B106 T7 241 lB8 BB4 2815 N-Aminoethylpiperazine 8 lll 8 T7 241 T4 TP1 lB3 2817 Ammonium hydrogendifluoride, solution 8 ll 8, 6.1 N34, T15 243 T8 TP2 TP12 TP13 lB2 2817 Ammonium hydrogendifluoride, solution 8 lll 8, 6.1 T8 241 T4 TP1 TP12 TP13 lB3 2818 Ammonium polysulfide, solution 8 ll 8, 6.1 T14 243 T7 TP2 TP13 lB2 2818 Ammonium polysulfide, solution 8 lll 8, 6.1 T7 241 T4 TP1 TP13 lB3 2819 Amyl acid phosphate 8 lll 8 T7 241 T4 TP1 lB3 2820 Butyric acid 8 lll 8 T1 241 T4 TP1 lB3 2821 Phenol solutions 6.1 ll 6.1 T14 243 T7 TP2 lB2 2821 Phenol solutions 6.1 lll 6.1 T7 241 T4 TP1 lB3 2822 2-Chloropyridine 6.1 ll 6.1 T14 243 T7 TP2 lB2 2823 Crotonic acid, solid 8 lll 8 240 lB8 BB3 2823 Crotonic acid liquid 8 lll 8 241 T4 TP1 lB3 2826 Ethyl chlorothioformate 8 II 8, 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP38 TP45 Start Printed Page 63371 2829 Caproic acid 8 III 8 T1 241 T4 TP1 IB3 2830 Lithium ferrosilicon 4.3 II 4.3 A19, B105, B106 241 IB7 BB2 2831 1,1,1-Trichloroethane 6.1 III 6.1 N36, T7 241 T4 TP1 IB3 2834 Phosphorous acid 8 III 8 T7 240 T3 TP1 IB8 BB3 2835 Sodium aluminum hydride 4.3 II 4.3 A8, A19, A20, B100 242 IB1 2837 Bisulfate, aqueous solution 8 II 8 A7, B2, N34, T8, T26 242 T7 TP2 IB2 2837 Bisulfate, aqueous solution 8 III 8 A7, N34, T7, T26 241 T4 TP1 IB3 2838 Vinyl butyrate, inhibited 3 II 3 T7 242 T4 TP1 IB2 2839 Aldol 6.1 II 6.1 T8 243 T7 TP2 IB2 2840 Butyraldoxime 3 III 3 B1, T1 242 T2 TP1 IB3 2841 Di-n-amylamine 3 III 3, 6.1 B1, T8 242 T4 TP1 IB3 2842 Nitroethane 3 III 3 B1, T8 242 T2 TP1 IB3 2844 Calcium manganese silicon 4.3 III 4.3 A1, A19, B105, B106 241 IB8 BB2, BB4 2845 Pyrophoric liquids, organic, n.o.s 4.2 I 4.2 B11, T42 244 T22 TP2 TP7 TP38 TP45 2849 3-Chloropropanol-1 6.1 III 6.1 T8 241 T4 TP1 IB3 2850 Propylene tetramer 3 III 3 B1, T1 242 T2 TP1 IB3 2851 Boron trifluoride dihydrate 8 II 8 T9, T27 240 T7 TP2 IB8 BB2, BB4 2853 Magnesium fluorosilicate 6.1 III 6.1 240 IB8 BB3 2854 Ammonium fluorosilicate 6.1 III 6.1 240 IB8 BB3 2855 Zinc fluorosilicate 6.1 III 6.1 240 IB8 BB3 2856 Fluorosilicates, n.o.s 6.1 III 6.1 240 IB8 BB3 2858 Zirconium, dry, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) 4.1 III 4.1 A1 240 IB8 2859 Ammonium metavanadate 6.1 II 6.1 242 IB8 BB2, BB4 2861 Ammonium polyvanadate 6.1 II 6.1 242 IB8 BB2, BB4 2862 Vanadium pentoxide, non-fused form 6.1 III 6.1 240 IB8 BB3 2863 Sodium ammonium vanadate 6.1 II 6.1 242 IB8 BB2, BB4 2864 Potassium metavanadate 6.1 II 6.1 242 IB8 BB2, BB4 2865 Hydroxylamine sulfate 8 III 8 240 IB8 BB3 2869 Titanium trichloride mixtures 8 II 8 A7, B106, N34 240 IB8 BB2, BB4 2869 Titanium trichloride mixtures 8 III 8 A7, N34 240 IB8 BB3 2871 Antimony powder 6.1 III 6.1 240 IB8 BB3 2872 Dibromochloropropane 6.1 III 6.1 T7 241 T4 TP1 IB3 2873 Dibutylaminoethanol 6.1 III 6.1 T1 241 T4 TP1 IB3 2874 Furfuryl alcohol 6.1 III 6.1 T2 241 T4 TP1 IB3 2875 Hexachlorophene 6.1 III 6.1 240 IB8 BB3 2876 Resorcinol 6.1 III 6.1 240 IB8 BB3 2878 Titanium sponge granules or Titanium sponge powders 4.1 III 4.1 A1 240 IB8 BB3 2879 Selenium oxychloride 8 I 8, 6.1 A3, A6, A7, N34, T12, T27 243 T10 TP2 TP12 TP13 Start Printed Page 63372 2880 Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not less than 5.5 percent but not more than 10 percent water 5.1 II 5.1 240 IB8 BB2, BB4 2881 Metal catalyst, dry 4.2 II 4.2 N34 242 IB6 BB2 2881 Metal catalyst, dry 4.2 III 4.2 N34 241 IB8 BB3 2902 Pesticides, liquid, toxic, n.o.s 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 2902 Pesticides, liquid, toxic, n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 2902 Pesticides, liquid, toxic, n.o.s 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 2903 Pesticides, liquid, toxic, flammable, n.o.s flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 2903 Pesticides, liquid, toxic, flammable, n.o.s flashpoint not less than 23 degrees C 6.1 II 6.1,3 T14 243 T11 TP2 TP13 TP27 IB2 2903 Pesticides, liquid, toxic, flammable, n.o.s flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 IB3 2904 Chlorophenolates, liquid or Phenolates, liquid 8 III 8 241 IB3 2905 Chlorophenolates, solid or Phenolates, solid 8 III 8 240 IB8 BB3 2907 Isosorbide dinitrate mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate 4.1 II 4.1 None IB6 BB2 2912 Radioactive material, low specific activity, n.o.s or Radioactive material, LSA, n.o.s 7 7 427 T5 TP4 2913 Radioactive material, surface contaminated object, n.o.s or Radioactive material, SCO 7 7 427 T5 TP4 2920 Corrosive liquids, flammable, n.o.s 8 I 8, 3 B10, T42 243 T14 TP2 TP27 2920 Corrosive liquids, flammable, n.o.s 8 II 8, 3 B2, T15, T26 243 T11 TP2 TP27 IB2 2921 Corrosive solids, flammable, n.o.s 8 I 8, 4.1 B106 242 IB6 2921 Corrosive solids, flammable, n.o.s 8 II 8, 4.1 242 IB8 BB2, BB4 2922 Corrosive liquids, toxic, n.o.s 8 I 8, 6.1 A7, B10, T18, T27 243 T14 TP2 TP13 TP27 2922 Corrosive liquids, toxic, n.o.s 8 II 8, 6.1 B3, T18, T26 243 T7 TP2 IB2 2922 Corrosive liquids, toxic, n.o.s 8 III 8, 6.1 T8 241 T7 TP1 TP28 IB3 2923 Corrosive solids, toxic, n.o.s 8 I 8, 6.1 242 IB7 2923 Corrosive solids, toxic, n.o.s 8 II 8, 6.1 240 IB8 2923 Corrosive solids, toxic, n.o.s 8 III 8, 6.1 240 IB8 BB3 2924 Flammable liquids, corrosive, n.o.s 3 I 3, 8 T42 243 T14 TP2 2924 Flammable liquids, corrosive, n.o.s 3 II 3, 8 T15, T26 243 T11 TP2 TP27 IB2 Start Printed Page 63373 2924 Flammable liquids, corrosive, n.o.s 3 III 3, 8 B1, T15, T26 242 T7 TP1 TP28 IB3 2925 Flammable solids, corrosive, organic, n.o.s 4.1 II 4.1, 8 A1, B106 242 IB6 BB2 2925 Flammable solids, corrosive, organic, n.o.s 4.1 III 4.1, 8 A1, B106 242 IB6 2926 Flammable solids, toxic, organic, n.o.s 4.1 II 4.1, 6.1 A1, B106 242 IB6 BB2 2926 Flammable solids, toxic, organic, n.o.s 4.1 III 4.1, 6.1 A1, B106 242 IB6 2927 Toxic liquids, corrosive, organic, n.o.s, inhalation hazard, Packing Group I, Zone B 6.1 I 6.1, 8 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP27 TP38 TP45 2927 Toxic liquids, corrosive, organic, n.o.s 6.1 I 6.1, 8 T42 243 T14 TP2 TP13 TP27 2927 Toxic liquids, corrosive, organic, n.o.s, inhalation hazard, Packing Group I, Zone A 6.1 I 6.1, 8 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP27 TP38 TP44 2927 Toxic liquids, corrosive, organic, n.o.s 6.1 II 6.1, 8 T42 243 T11 TP2 TP27 IB2 2928 Toxic solids, corrosive, organic, n.o.s 6.1 I 6.1, 8 242 IB7 2928 Toxic solids, corrosive, organic, n.o.s 6.1 II 6.1, 8 242 IB6 BB2 2929 Toxic liquids, flammable, organic, n.o.s, inhalation hazard, Packing Group I, Zone B 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP27 TP38 TP45 2929 Toxic liquids, flammable, organic, n.o.s 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 2929 Toxic liquids, flammable, organic, n.o.s, inhalation hazard, Packing Group I, Zone A 6.1 I 6.1, 3 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP27 TP38 TP44 2929 Toxic liquids, flammable, organic, n.o.s 6.1 II 6.1, 3 T15 243 T11 TP2 TP13 TP27 IB2 2930 Toxic solids, flammable, organic, n.o.s 6.1 I 6.1, 4.1 B106 242 IB6 2930 Toxic solids, flammable, organic, n.o.s 6.1 II 6.1, 4.1 B106 242 IB8 BB2, BB4 2931 Vanadyl sulfate 6.1 II 6.1 242 IB8 BB2, BB4 2933 Methyl 2-chloropropionate 3 III 3 B1, T7 242 T2 TP1 IB3 2934 Isopropyl 2-chloropropionate 3 III 3 B1, T1 242 T2 TP1 IB3 2935 Ethyl 2-chloropropionate 3 III 3 B1, T1 242 T2 TP1 IB3 2936 Thiolactic acid 6.1 II 6.1 T8 242 T7 TP2 IB8 BB2, BB4 2937 alpha-Methylbenzyl alcohol 6.1 III 6.1 T1 241 T4 TP1 IB3 2940 9-Phosphabicyclononanes or Cyclooctadiene phosphines 4.2 II 4.2 A19 241 IB6 BB2 2941 Fluoroanilines 6.1 III 6.1 T8 241 T4 TP1 IB3 Start Printed Page 63374 2942 2-Trifluoromethylaniline 6.1 III 6.1 241 IB3 2943 Tetrahydrofurfurylamine 3 III 3 B1, T1 242 T2 TP1 IB3 2945 N-Methylbutylamine 3 II 3, 8 T8 243 T7 TP1 IB2 2946 2-Amino-5-diethylaminopentane 6.1 III 6.1 T1 241 T4 TP1 IB3 2947 Isopropyl chloroacetate 3 III 3 B1, T1 242 T2 TP1 IB3 2948 3-Trifluoromethylaniline 6.1 II 6.1 T14 243 T7 TP2 IB2 2949 Sodium hydrosulfide with not less than 25 percent water of crystallization 8 II 8 A7 240 T7 TP2 IB8 BB2, BB4 2950 Magnesium granules, coated particle size not less than 149 microns 4.3 III 4.3 A1, A19, B108 240 IB8 BB4 2965 Boron trifluoride dimethyl etherate 4.3 I 4.3, 8, 3 A19, T12, T26 243 T10 TP2 TP7 2966 Thioglycol 6.1 II 6.1 T8 243 T7 TP2 IB2 2967 Sulfamic acid 8 III 8 240 IB8 BB3 2968 Maneb stabilized or Maneb preparations, stabilized against self-heating 4.3 III 4.3 54, A1, A19, B108 242 IB8 BB4 2969 Castor beans or Castor meal or Castor pomace or Castor flake 9 II None 240 IB8 BB2, BB4 2983 Ethyene oxide and propylene oxide mixtures, with not more than 30 percent ethylene oxide 3 I 3, 6.1 5, A11, N4, N34, T24, T29 243 T14 TP2 TP7 TP13 2984 Hydrogen peroxide, aqueous solutions with not less than 8 percent but less than 20 percent hydrogen peroxide (stabilized as necessary) 5.1 III 5.1 17, A1, B104, T8, T37 241 T4 TP1 TP6 TP24 TP37 IB2 BB5 2985 Chlorosilanes, flammable, corrosive, n.o.s 3 II 3, 8 B100, T17, T26 243 T11 TP2 TP13 TP27 IB1 2986 Chlorosilanes, corrosive, flammable, n.o.s 8 II 8, 3 B100, T18, T26 243 T11 TP2 TP27 IB2 2987 Chlorosilanes, corrosive, n.o.s 8 II 8 B2, T14, T26 242 T14 TP2 TP27 IB2 2988 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s 4.3 I 4.3, 3, 8 A2, T24, T26 244 T10 TP2 TP7 TP13 2989 Lead phosphite, dibasic 4.1 II 4.1 240 IB8 BB2, BB4 2989 Lead phosphite, dibasic 4.1 III 4.1 240 IB8 BB3 2991 Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 2991 Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 2991 Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 TP28 IB3 Start Printed Page 63375 2992 Carbamate pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 2992 Carbamate pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 2992 Carbamate pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 2993 Arsenical pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 2993 Arsenical pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 2993 Arsenical pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 TP28 IB3 2994 Arsenical pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 2994 Arsenical pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 2994 Arsenical pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 2995 Organochlorine pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 2995 Organochlorine pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 2995 Organochlorine pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 TP28 IB3 2996 Organochlorine pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 2996 Organochlorine pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 2996 Organochlorine pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 2997 Triazine pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T42 243 T14 TP2 TP13 TP27 2997 Triazine pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 2997 Triazine pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 III 6.1, 3 T14 242 T7 TP2 TP28 IB3 2998 Triazine pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 2998 Triazine pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 2998 Triazine pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3002 Phenyl urea pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP27 3002 Phenyl urea pesticides, liquid, toxic 6.1 II 6.1 T14 243 T7 TP2 3002 Phenyl urea pesticides, liquid, toxic 6.1 III 6.1 T14 241 T4 TP1 Start Printed Page 63376 3005 Thiocarbamate pesticides, liquid, flammable, toxic, flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 3005 Thiocarbamate pesticides, liquid, flammable, toxic, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3005 Thiocarbamate pesticides, liquid, flammable, toxic, flashpoint not less than 23 degrees C 6.1 III 6.1, 3 T14 242 T7 TP2 TP28 IB3 3006 Thiocarbamate pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 3006 Thiocarbamate pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3006 Thiocarbamate pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3009 Copper based pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 3009 Copper based pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3009 Copper based pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 TP28 IB3 3010 Copper based pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 3010 Copper based pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3010 Copper based pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3011 Mercury based pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 3011 Mercury based pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3011 Mercury based pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 III 6.1, 3 T14 242 T7 TP2 TP28 IB3 3012 Mercury based pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 3012 Mercury based pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3012 Mercury based pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3013 Substituted nitrophenol pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 3013 Substituted nitrophenol pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 Start Printed Page 63377 3013 Substituted nitrophenol pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 TP28 IB3 3014 Substituted nitrophenol pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 3014 Substituted nitrophenol pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3014 Substituted nitrophenol pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3015 Bipyridilium pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 I 6.1, T42 243 T14 TP2 TP13 TP27 3015 Bipyridilium pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 4 T14 243 T11 TP2 TP13 TP27 IB2 3015 Bipyridilium pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 III 6.1, B1, T14 242 T7 TP2 TP28 IB3 3016 Bipyridilium pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 3016 Bipyridilium pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3016 Bipyridilium pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3017 Organophosphorus pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 I 6.1, 3 N76, T42 243 T14 TP2 TP13 TP27 3017 Organophosphorus pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 N76, T14 243 T11 TP2 TP13 TP27 IB2 3017 Organophosphorus pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, N76, T14 242 T7 TP2 TP28 IB3 3018 Organophosphorus pesticides, liquid, toxic 6.1 I 6.1 N76, T42 243 T14 TP2 TP13 TP27 3018 Organophosphorus pesticides, liquid, toxic 6.1 II 6.1 N76, T14 243 T11 TP2 TP13 TP27 IB2 3018 Organophosphorus pesticides, liquid, toxic 6.1 III 6.1 N76, T14 241 T7 TP2 TP28 IB3 3019 Organotin pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 I 6.1, 3 T42 243 T14 TP2 TP13 TP27 3019 Organotin pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3019 Organotin pesticides, liquid, toxic, flammable, flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1, T14 242 T7 TP2 TP28 IB3 3020 Organotin pesticides, liquid, toxic 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 3020 Organotin pesticides, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP13 TP27 IB2 Start Printed Page 63378 3020 Organotin pesticides, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3021 Pesticides, liquid, flammable, toxic, flashpoint less than 23 degrees C 3 I 3, 6.1 B5 243 T14 TP2 TP13 TP27 3021 Pesticides, liquid, flammable, toxic, flashpoint less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 3022 1,2-Butylene oxide, stabilized 3 II 3 T8 242 T4 TP1 IB2 3023 2-Methyl-2-heptanethiol 6.1 I 6.1, 3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 3024 Coumarin derivative pesticides, liquid, flammable, toxic, flashpoint less than 23 degrees C 3 I 3, 6.1 243 T14 TP2 TP13 TP27 3024 Coumarin derivative pesticides, liquid, flammable, toxic, flashpoint less than 23 degrees C 3 II 3, 6.1 243 T11 TP2 TP13 TP27 IB2 3025 Coumarin derivative pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 I 6.1, 3 243 T14 TP2 TP13 TP27 3025 Coumarin derivative pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 II 6.1, 3 243 T11 TP2 TP13 TP27 IB2 3025 Coumarin derivative pesticides, liquid, toxic, flammable flashpoint not less than 23 degrees C 6.1 III 6.1, 3 B1 242 T7 TP1 TP28 IB3 3026 Coumarin derivative pesticides, liquid, toxic 6.1 I 6.1 243 T14 TP2 TP13 TP27 3026 Coumarin derivative pesticides, liquid, toxic 6.1 II 6.1 243 T11 TP2 TP27 IB2 3026 Coumarin derivative pesticides, liquid, toxic 6.1 III 6.1 241 T7 TP1 TP28 IB3 3027 Coumarin derivative pesticides, solid, toxic 6.1 I 6.1 242 T14 TP2 TP27 IB7 BB1 3027 Coumarin derivative pesticides, solid, toxic 6.1 II 6.1 242 T11 TP2 TP27 IB8 BB2, BB4 3027 Coumarin derivative pesticides, solid, toxic 6.1 III 6.1 240 T7 TP1 TP28 IB8 BB3 3048 Aluminum phosphide pesticides 6.1 I 6.1 A8 242 IB7 BB1 3049 Metal alkyl halides water-reactive, n.o.s. or Metal aryl halides water-reactive, n.o.s 4.2 I 4.2, 4.3 B9, B11, T28, T29, T40 244 T21 TP2 TP7 3050 Metal alkyl hydrides water-reactive, n.o.s. or Metal aryl hydrides water-reactive, n.o.s 4.2 I 4.2, 4.3 B9, B11, T28, T29, T40 244 T21 TP2 TP7 3051 Aluminum alkyls 4.2 I 4.2, 4.3 B9, B11, T28, T29, T40 244 T21 TP2 TP7 Start Printed Page 63379 3052 Aluminum alkyl halides 4.2 I 4.2, 4.3 B9, B11, T28, T29, T40 244 T21 TP2 TP7 3052 Aluminum alkyl halides 4.2 I 4.2, 4.3 B9, B11, T28, T29, T40 244 T21 TP2 TP7 3053 Magnesium alkyls 4.2 I 4.2, 4.3 B11, T28, T29, T40 244 T21 TP2 TP7 3054 Cyclohexyl mercaptan 3 III 3 B1, T1 242 T2 TP1 IB3 3055 2-(2-Aminoethoxy) ethanol 8 III 8 T2 241 T4 TP1 IB3 3056 n-Heptaldehyde 3 III 3 B1, T1 242 T2 TP1 IB3 3057 Trifluoroacetyl chloride 2.3, 8 2.3, 8 2, B7, B9, B14 314, 315 T50 TP21 3065 Alcoholic beverages 3 II 3 24, B1, T1 242 T4 TP1 IB2 3065 Alcoholic beverages 3 III 3 24, B1, N11, T1 242 T2 TP1 IB3 3066 Paint or Paint related material 8 II 8 B2, T14 242 T7 TP2 IB2 3066 Paint or Paint related material 8 III 8 B52, T7 241 T4 TP1 IB3 3070 Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5 percent ethylene oxide 2.2 2.2 314, 315 T50 3071 Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan mixtures, liquid, toxic, flammable, n.o.s., flash point not less than 23 degrees C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3073 Vinylpyridines, inhibited 6.1 II 6.1, 3, 8 B100, T8 243 T7 TP2 TP13 IB1 3076 Aluminum alkyl hydrides 4.2 I 4.2, 4.3 B9, B11, T28, T29, T40 244 T21 TP2 TP7 3077 Environmentally hazardous substances, solid, n.o.s 9 III 9 8, B54, N20 240 IB8 3078 Cerium, turnings or gritty powder 4.3 II 4.3 A1, B106, B109 242 IB7 BB2 3079 Methacrylonitrile, inhibited 3 I 3, 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 3080 Isocyanates, toxic, flammable, n.o.s. or Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C 6.1 II 6.1, 3 T15 243 T11 TP2 TP13 TP27 IB2 3082 Environmentally hazardous substances, liquid, n.o.s 9 III 9 8, T1 241 T4 TP1 TP29 IB3 3084 Corrosive solids, oxidizing, n.o.s 8 II 8, 5.1 B100 242 IB6 BB2 3085 Oxidizing solid, corrosive, n.o.s 5.1 II 5.1, 8 242 IB6 BB2 3085 Oxidizing solid, corrosive, n.o.s 5.1 III 5.1, 8 240 IB8 BB3 Start Printed Page 63380 3086 Toxic solids, oxidizing, n.o.s 6.1 II 6.1, 5.1 242 IB6 BB2 3087 Oxidizing solid, toxic, n.o.s 5.1 II 5.1, 6.1 242 IB6 BB2 3087 Oxidizing solid, toxic, n.o.s 5.1 III 5.1, 6.1 240 IB8 BB3 3088 Self-heating, solid, organic, n.o.s 4.2 II 4.2 B101 241 IB6 BB2 3088 Self-heating, solid, organic, n.o.s 4.2 III 4.2 B101 241 IB8 BB3 3089 Metal powders, flammable, n.o.s 4.1 II 4.1 240 IB8 BB2, BB4 3089 Metal powders, flammable, n.o.s 4.1 III 4.1 240 IB6 3092 1-Methoxy-2-propanol 3 III 3 B1, T1 242 T2 TP1 IB3 3093 Corrosive liquids, oxidizing, n.o.s 8 II 8, 5.1 243 IB2 3095 Corrosive solids, self-heating, n.o.s 8 II 8, 4.2 242 IB6 BB2 3096 Corrosive solids, water-reactive, n.o.s 8 II 8, 4.3 B105 242 IB6 BB2 3098 Oxidizing liquid, corrosive, n.o.s 5.1 II 5.1, 8 243 IB1 3098 Oxidizing liquid, corrosive, n.o.s 5.1 III 5.1, 8 242 IB2 3099 Oxidizing liquid, toxic, n.o.s 5.1 II 5.1, 6.1 243 IB1 3099 Oxidizing liquid, toxic, n.o.s 5.1 III 5.1, 6.1 242 IB2 3109 Organic peroxide type F, liquid 5.2 II 5.2 225 T23 IB52 BB5 3110 Organic peroxide type F, solid 5.2 II 5.2 T42 225 T23 3119 Organic peroxide type F, liquid, temperature controlled 5.2 II 5.2 225 T23 IB52 BB5 3120 Organic peroxide type F, solid, temperature controlled 5.2 II 5.2 225 T23 3122 Toxic liquids, oxidizing, n.o.s. Inhalation Hazard, Packing Group I, Zone B 6.1 I 6.1, 5.1 2, B9, B14, B32, T38, T43, T45 244 T20 TP2 TP13 TP38 TP44 3122 Toxic liquids, oxidizing, n.o.s. Inhalation hazard, Packing Group I, Zone A 6.1 I 6.1, 5.1 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 3122 Toxic liquids, oxidizing, n.o.s 6.1 II 6.1, 5.1 243 IB2 3123 Toxic liquids, water-reactive, n.o.s. Inhalation hazard, packing group I, Zone A 6.1 I 6.1, 4.3 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP38 TP44 3123 Toxic liquids, water-reactive, n.o.s. Inhalation hazard, Packing group I, Zone B 6.1 I 6.1, 4.3 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP44 3123 Toxic liquids, water-reactive, n.o.s 6.1 II 6.1, 4.3 243 IB2 3124 Toxic solids, self-heating, n.o.s 6.1 II 6.1, 4.2 242 IB6 BB2 3125 Toxic solids, water-reactive, n.o.s 6.1 II 6.1, 4.3 B101 242 IB6 BB2 3126 Self-heating, solid, corrosive, organic, n.o.s 4.2 II 4.2, 8 242 IB5 BB2 Start Printed Page 63381 3126 Self-heating, solid, corrosive, organic, n.o.s 4.2 III 4.2, 8 242 IB8 BB3 3128 Self-heating, solid, toxic, organic, n.o.s 4.2 II 4.2, 6.1 242 IB5 BB2 3128 Self-heating, solid, toxic, organic, n.o.s 4.2 III 4.2, 6.1 242 IB8 BB3 3129 Water-reactive liquid, corrosive, n.o.s 4.3 II 4.3, 8 B106 243 IB1 3129 Water-reactive liquid, corrosive, n.o.s 4.3 III 4.3, 8 B106 242 IB2 3130 Water-reactive liquid, toxic, n.o.s 4.3 II 4.3, 6.1 B106 243 IB1 3130 Water-reactive liquid, toxic, n.o.s 4.3 III 4.3, 6.1 B106 242 IB2 3131 Water-reactive solid, corrosive, n.o.s 4.3 II 4.3, 8 B101, B106 242 IB6 BB2 3131 Water-reactive solid, corrosive, n.o.s 4.3 III 4.3, 8 B105, B106 241 IB8 BB4 3132 Water-reactive solid, flammable, n.o.s 4.3 I 4.3, 4.1 B101, B106, N40 242 IB4 3132 Water-reactive solid, flammable, n.o.s 4.3 II 4.3, 4.1 B101, B106 242 IB4 3132 Water-reactive solid, flammable, n.o.s 4.3 III 4.3, 4.1 B105, B106 241 IB6 3134 Water-reactive solid, toxic, n.o.s 4.3 II 4.3, 6.1 B105, B106 242 IB5 BB2 3134 Water-reactive solid, toxic, n.o.s 4.3 III 4.3, 6.1 B105, B106 241 IB8 BB4 3135 Water-reactive solid, self-heating, n.o.s 4.3 II 4.3, 4.2 B101, B106 242 IB5 BB2 3135 Water-reactive solid, self-heating, n.o.s 4.3 III 4.3, 4.2 B101, B106 241 IB8 BB4 3136 Trifluoromethane, refrigerated liquid 2.2 2.2 314, 315 T75 3138 Ethylene, acetylene and propylene mixture, refrigerated liquid with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene 2.1 2.1 314, 315 T75 3139 Oxidizing liquid, n.o.s 5.1 II 5.1 127, A2 242 IB2 3139 Oxidizing liquid, n.o.s 5.1 III 5.1 127, A2 241 IB2 3140 Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s 6.1 I 6.1 A4, T42 243 T14 TP2 TP27 3140 Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 3140 Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3141 Atimony compounds, inorganic, liquid, n.o.s 6.1 III 6.1 35, T7 241 T7 TP1 TP28 IB3 3142 Disinfectants, liquid, toxic, n.o.s 6.1 I 6.1 A4, T42 243 T14 TP2 TP27 3142 Disinfectants, liquid, toxic, n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 3142 Disinfectants, liquid, toxic, n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s 6.1 I 6.1 A5 242 T14 TP2 TP27 IB7 BB1 3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s 6.1 III 6.1 240 IB8 BB3 Start Printed Page 63382 3144 Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 3144 Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3145 Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) 8 I 8 T8 243 T14 TP2 3145 Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) 8 II 8 T8 242 T11 TP2 TP27 IB2 3145 Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) 8 III 8 T7 241 T7 TP1 TP28 IB3 3146 Organotin compounds, solid, n.o.s 6.1 I 6.1 A5 242 IB7 BB1 3146 Organotin compounds, solid, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 3146 Organotin compounds, solid, n.o.s 6.1 III 6.1 240 IB8 BB3 3147 Dyes, solid, corrosive, n.o.s or Dye intermediates corrosive, n.o.s solid 8 I 8 242 IB7 BB1 3147 Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s 8 II 8 240 IB8 BB2, BB4 3147 Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s 8 III 8 240 IB8 BB3 3148 Water-reactive liquid, n.o.s 4.3 II 4.3 B106 243 IB1 3148 Water-reactive liquid, n.o.s 4.3 III 4.3 B106 242 IB2 3149 Hydrogen peroxide and peroxyacetic acid mixtures, stabilized with acids, water and not more than 5 percent peroxyacetic acid 5.1 II 5.1, 8 A2, A3, A6, B53, B104, B110, T14 243 T7 TP2 TP6 TP24 IB2 BB5 3151 Polyhalogenated biphenyls, liquid or Polyhalogenated terphenyls liquid 9 II 9 241 IB3 3152 Polyhalogenated biphenyls, solid or Polyhalogenated terphenyls, solid 9 II 9 241 IB8 BB2, BB4 3153 Perfluoro(methyl vinyl ether) 2.1 2.1 314, 315 T50 3155 Pentachlorophenol 6.1 II 6.1 242 IB8 BB2, BB4 3158 Gas, refrigerated liquid, n.o.s. (cryogenic liquid) 2.2 2.2 318 T75 3159 1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a 2.2 2.2 314, 315 T50 3161 Liquefied gas, flammable, n.o.s 2.1 2.1 314, 315 T50 3163 Liquefied gas, n.o.s 2.2 2.2 314, 315 T50 3170 Aluminum smelting by-products or Aluminum remelting by-products 4.3 II 4.3 128, B106, B115 242 IB7 BB2 Start Printed Page 63383 3170 Aluminum smelting by-products or Aluminum remelting by-products 4.3 III 4.3 128, B106, B115 241 IB8 BB4 3174 Titanium disulphide 4.2 III 4.2 241 IB8 BB3 3175 Solids containing flammable liquid, n.o.s 4.1 II 4.1 47 240 IB6 BB2 3176 Flammable solid, organic, molten, n.o.s 4.1 II 4.1 T9 240 T3 TP3 TP26 IB1 3176 Flammable solid, organic, molten, n.o.s 4.1 III 4.1 T9 240 T1 TP3 TP26 IB1 3178 Flammable solid, inorganic, n.o.s 4.1 II 4.1 A1 240 IB8 BB2, BB4 3178 Flammable solid, inorganic, n.o.s 4.1 III 4.1 A1 240 IB8 BB3 3179 Flammable solid, toxic, inorganic, n.o.s 4.1 II 4.1, 6.1 A1, B106 242 IB6 BB2 3179 Flammable solid, toxic, inorganic, n.o.s 4.1 III 4.1, 6.1 A1, B106 242 IB6 3180 Flammable solid, corrosive, inorganic, n.o.s 4.1 II 4.1, 8 A1, B106 242 IB6 BB2 3180 Flammable solid, corrosive, inorganic, n.o.s 4.1 III 4.1, 8 A1, B106 242 IB6 3181 Metal salts of organic compounds, flammable, n.o.s 4.1 II 4.1 A1 240 IB8 BB2, BB4 3181 Metal salts of organic compounds, flammable, n.o.s 4.1 III 4.1 A1 240 IB8 BB3 3182 Metal hydrides, flammable, n.o.s 4.1 II 4.1 A1 240 IB4 3182 Metal hydrides, flammable, n.o.s 4.1 III 4.1 A1 240 IB4 3183 Self-heating liquid, organic, n.o.s 4.2 II 4.2 242 IB2 3183 Self-heating liquid, organic, n.o.s. 4.2 III 4.2 241 IB2 3184 Self-heating liquid, toxic, organic, n.o.s 4.2 II 4.2, 6.1 243 IB2 3184 Self-heating liquid, toxic, organic, n.o.s 4.2 III 4.2, 6.1 241 IB2 3185 Self-heating liquid, corrosive, organic, n.o.s 4.2 II 4.2, 8 243 IB2 3185 Self-heating liquid, corrosive, organic, n.o.s 4.2 III 4.2, 8 241 IB2 3186 Self-heating liquid, inorganic, n.o.s 4.2 II 4.2 242 IB2 3186 Self-heating liquid, inorganic, n.o.s 4.2 III 4.2 241 IB2 3187 Self-heating liquid, toxic, inorganic, n.o.s 4.2 II 4.2, 6.1 243 IB2 3187 Self-heating liquid, toxic, inorganic, n.o.s 4.2 III 4.2, 6.1 241 IB2 3188 Self-heating liquid, corrosive, inorganic, n.o.s 4.2 II 4.2, 8 243 IB2 3188 Self-heating liquid, corrosive, inorganic, n.o.s 4.2 III 4.2, 8 241 IB2 3189 Metal powder, self-heating, n.o.s 4.2 II 4.2 241 IB6 BB2 3189 Metal powder, self-heating, n.o.s 4.2 III 4.2 241 IB8 BB3 3190 Self-heating solid, inorganic, n.o.s 4.2 II 4.2 241 IB6 BB2 3190 Self-heating solid, inorganic, n.o.s 4.2 III 4.2 241 IB8 BB3 3191 Self-heating solid, toxic, inorganic, n.o.s 4.2 II 4.2, 6.1 242 IB5 BB2 Start Printed Page 63384 3191 Self-heating solid, toxic, inorganic, n.o.s 4.2 III 4.2, 6.1 242 IB8 BB3 3192 Self-heating solid, corrosive, inorganic, n.o.s 4.2 II 4.2, 8 242 IB5 BB2 3192 Self-heating solid, corrosive, inorganic, n.o.s 4.2 III 4.2, 8 242 IB8 BB3 3203 Pyrophoric organometallic compound, water-reactive, n.o.s 4.2 I 4.2, 4.3 T28, T40 242 T21 TP2 TP7 3203 Pyrophoric organometallic compound, water-reactive, n.o.s 4.2 I 4.2, 4.3 T28, T40 242 T21 TP2 TP7 3205 Alkaline earth metal alcoholates, n.o.s 4.2 II 4.2 65 241 IB6 BB2 3205 Alkaline earth metal alcoholates, n.o.s 4.2 III 4.2 65 241 IB8 BB3 3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s 4.2 II 4.2, 8 64 242 IB5 BB2 3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s 4.2 III 4.2, 8 64 242 IB8 BB3 3207 Organometallic compound or Compound solution or Compound dispersion, water-reactive, flammable, n.o.s 4.3 I 4.3, 3 T28 244 T13 TP2 TP7 3207 Organometallic compound or Compound solution or Compound dispersion, water-reactive, flammable, n.o.s 4.3 II 4.3, 3 T28 243 T7 TP2 TP7 IB1 BB2 3207 Organometallic compound or Compound solution or Compound dispersion, water-reactive, flammable, n.o.s 4.3 III 4.3, 3 T28, B101, B106 242 T7 TP2 TP7 IB2 BB4 3208 Metallic substance, water-reactive, n.o.s 4.3 I 4.3 B101, B106 242 IB4 3208 Metallic substance, water-reactive, n.o.s 4.3 II 4.3 B101, B106 242 IB7 BB2 3208 Metallic substance, water-reactive, n.o.s 4.3 III 4.3 B105, B108 241 IB8 BB4 3209 Metallic substance, water-reactive, self-heating, n.o.s 4.3 II 4.3, 4.2 B101, B106 242 IB5 BB2 3209 Metallic substance, water-reactive, self-heating, n.o.s 4.3 III 4.3, 4.2 B101, B106 242 IB8 BB4 3210 Chlorates, inorganic, aqueous solution, n.o.s 5.1 II 5.1 T8 242 T4 TP1 IB2 3211 Perchlorates, inorganic, aqueous solution, n.o.s 5.1 II 5.1 T8 242 T4 TP1 IB2 3211 Perchlorates, inorganic, aqueous solution, n.o.s 5.1 III 5.1 T8 241 T4 TP1 IB2 3212 Hypochlorites, inorganic, n.o.s 5.1 II 5.1 240 IB8 BB2, BB4 3213 Bromates, inorganic, aqueous solution, n.o.s 5.1 II 5.1 T8 242 T4 TP1 IB2 Start Printed Page 63385 3214 Permanganates, inorganic, aqueous solution, n.o.s 5.1 II 5.1 26, T8 242 T4 TP1 IB2 3215 Persulfates, inorganic, n.o.s 5.1 III 5.1 240 IB8 BB3 3216 Persulfates, inorganic, aqueous solution, n.o.s 5.1 III 5.1 T2 241 T4 TP1 TP29 IB2 3218 Nitrates, inorganic, aqueous solution, n.o.s 5.1 II 5.1 58, T8 242 T4 TP1 IB2 3218 Nitrates, inorganic, aqueous solution, n.o.s 5.1 III 5.1 58, T8 241 T4 TP1 IB2 3219 Nitrites, inorganic, aqueous solution, n.o.s 5.1 II 5.1 T8 242 T4 TP1 IB1 3219 Nitrites, inorganic, aqueous solution, n.o.s 5.1 III 5.1 T8 241 T4 TP1 IB2 3220 Pentafluoroethane or Refrigerant gas R 125 2.2 2.2 314, 315 T50 3241 2-Bromo-2-nitropropane-1,3-diol 4.1 III 4.1 46 None IB8 BB3 3242 Azodicarbonamide 4.1 II 4.1 38 240 IB8 3243 Solids containing toxic liquid, n.o.s 6.1 II 6.1 48 240 IB2 3244 Solids containing corrosive liquid, n.o.s 8 II 8 49 240 IB5 3246 Methanesulfonyl chloride 6.1 I 6.1, 8 2, 25, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP12 TP13 TP38 TP45 3247 Sodium peroxoborate, anhydrous 5.1 II 5.1 240 IB8 BB4 3248 Medicine, liquid, flammable, toxic, n.o.s 3 II 3, 6.1 36 None IB2 3248 Medicine, liquid, flammable, toxic, n.o.s 3 III 3, 6.1 36 None IB3 3250 Chloroacetic acid, molten 6.1 II 6.1, 8 T9 243 T7 TP3 IB1 3251 Isosorbide-5-mononitrate 4.1 III 4.1 66 240 IB8 3252 Difluoromethane or Refrigerant gas R 32 2.1 2.1 314, 315 T50 3253 Disodium trioxosilicate 8 III 8 240 IB8 BB3 3256 Elevated temperature liquid, flammable, n.o.s, with flash point above 37.8 C, at or above its flash point 3 III 3 T1 247 T3 TP3 TP29 IB1 3257 Elevated temperature liquid, n.o.s, at or above 100 C and below its flash point (including molten metals, molten salts, etc.) 9 III 9 T1 247 T3 TP3 TP29 IB1 3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive n.o.s 8 I 8 242 IB7 BB1 3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive n.o.s 8 II 8 240 IB8 BB2, BB4 3259 Amines, solid, corrosive, n.o.s, or Polyamines, solid, corrosive n.o.s 8 III 8 240 IB8 BB3 Start Printed Page 63386 3260 Corrosive solid, acidic, inorganic, n.o.s 8 I 8 242 IB7 BB1 3260 Corrosive solid, acidic, inorganic, n.o.s 8 II 8 240 IB8 BB2, BB4 3260 Corrosive solid, acidic, inorganic, n.o.s 8 III 8 240 IB8 BB3 3261 Corrosive solid, acidic, organic, n.o.s 8 I 8 242 IB7 BB1 3261 Corrosive solid, acidic, organic, n.o.s 8 II 8 240 IB8 BB2, BB4 3261 Corrosive solid, acidic, organic, n.o.s 8 III 8 240 IB8 BB3 3262 Corrosive solid, basic, inorganic, n.o.s 8 I 8 242 IB7 BB1 3262 Corrosive solid, basic, inorganic, n.o.s 8 II 8 240 IB8 BB2, BB4 3262 Corrosive solid, basic, inorganic, n.o.s 8 III 8 240 IB8 BB3 3263 Corrosive solid, basic, organic, n.o.s 8 I 8 242 IB7 BB1 3263 Corrosive solid, basic, organic, n.o.s 8 II 8 240 IB8 BB2, BB4 3263 Corrosive solid, basic, organic, n.o.s 8 III 8 240 IB8 BB3 3264 Corrosive liquid, acidic, inorganic, n.o.s 8 I 8 B10 243 T14 TP2 TP27 3264 Corrosive liquid, acidic, inorganic, n.o.s 8 II 8 B2, T14 242 T11 TP2 TP27 IB2 3264 Corrosive liquid, acidic, inorganic, n.o.s 8 III 8 T7 241 T7 TP1 TP28 IB3 3265 Corrosive liquid, acidic, organic, n.o.s 8 I 8 B10 243 T14 TP2 TP27 3265 Corrosive liquid, acidic, organic, n.o.s 8 II 8 B2, T14 242 T11 TP2 TP27 IB2 3265 Corrosive liquid, acidic, organic, n.o.s 8 III 8 T7 241 T7 TP1 TP28 IB3 3266 Corrosive liquid, basic, inorganic, n.o.s 8 I 8 B10 243 T14 TP2 TP27 3266 Corrosive liquid, basic, inorganic, n.o.s 8 II 8 B2, T14 242 T11 TP2 TP27 IB2 3266 Corrosive liquid, basic, inorganic, n.o.s 8 III 8 T7 241 T7 TP1 TP28 IB3 3267 Corrosive liquid, basic, organic, n.o.s 8 I 8 B10 243 T14 TP2 TP27 3267 Corrosive liquid, basic, organic, n.o.s 8 II 8 B2, T14 242 T11 TP2 TP27 IB2 3267 Corrosive liquid, basic, organic, n.o.s 8 III 8 T7 241 T7 TP1 TP28 IB3 3271 Ethers, n.o.s 3 II 3 T8 242 T7 TP1 TP8 TP28 IB2 3271 Ethers, n.o.s 3 III 3 B1, T7 242 T4 TP1 TP29 IB3 3272 Esters, n.o.s 3 II 3 T8 242 T7 TP1 TP8 TP28 IB2 3272 Esters, n.o.s 3 III 3 B1, T7 242 T4 TP1 TP29 IB3 3273 Nitriles, flammable, toxic, n.o.s 3 I 3, 6.1 243 T14 TP2 TP13 TP27 3273 Nitriles, flammable, toxic, n.o.s 3 II 3, 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3274 Alcoholates solution, n.o.s, in alcohol 3 II 3, 8 243 IB2 3275 Nitriles, toxic, flammable, n.o.s 6.1 I 6.1, 3 5 243 T14 TP2 TP13 TP27 3275 Nitriles, toxic, flammable, n.o.s 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3276 Nitriles, toxic, n.o.s 6.1 I 6.1 5 243 T14 TP2 TP13 TP27 3276 Nitriles, toxic, n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 Start Printed Page 63387 3276 Nitriles, toxic, n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3277 Chloroformates, toxic, corrosive, n.o.s 6.1 II 6.1, 8 T12, T26 243 T8 TP2 TP13 TP28 IB2 3278 Organophosphorus compound, toxic n.o.s 6.1 I 6.1 5 243 T14 TP2 TP13 TP27 IB7 3278 Organophosphorus compound, toxic n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 3278 Organophosphorus compound, toxic n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3279 Organophosphorus compound, toxic, flammable, n.o.s 6.1 I 6.1, 3 5 243 T14 TP2 TP13 3279 Organophosphorus compound, toxic, flammable, n.o.s 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3280 Organoarsenic compound, n.o.s 6.1 I 6.1 5 242 T14 TP2 TP27 IB7 BB1 3280 Organoarsenic compound, n.o.s 6.1 II 6.1 T14 242 T11 TP2 TP27 IB8 BB2, BB4 3280 Organoarsenic compound, n.o.s 6.1 III 6.1 T7 240 T7 TP1 TP28 IB8 BB3 3281 Metal carbonyls, n.o.s 6.1 I 6.1 5 243 T14 TP2 TP13 TP27 3281 Metal carbonyls, n.o.s 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 3281 Metal carbonyls, n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3282 Organometallic compound, toxic n.o.s 6.1 I 6.1 B106 242 T14 TP2 TP27 IB7 BB1 3282 Organometallic compound, toxic n.o.s 6.1 II 6.1 T14 242 T11 TP2 TP27 IB8 BB2, BB4 3282 Organometallic compound, toxic n.o.s 6.1 III 6.1 T7 240 T7 TP1 TP28 IB8 BB3 3283 Selenium compound, n.o.s 6.1 I 6.1 242 T14 TP2 TP27 IB7 BB1 3283 Selenium compound, n.o.s 6.1 II 6.1 T14 242 T11 TP2 TP27 IB8 BB2, BB4 3283 Selenium compound, n.o.s 6.1 III 6.1 T7 240 T7 TP1 TP28 IB8 BB3 3284 Tellurium compound, n.o.s 6.1 I 6.1 242 T14 TP2 TP27 IB7 BB1 3284 Tellurium compound, n.o.s 6.1 II 6.1 T14 242 T11 TP2 TP27 IB8 BB2, BB4 3284 Tellurium compound, n.o.s 6.1 III 6.1 T7 240 T7 TP1 TP28 IB8 BB3 3285 Vanadium compound, n.o.s 6.1 I 6.1 242 T14 TP2 TP27 IB7 BB1 3285 Vanadium compound, n.o.s 6.1 II 6.1 T14 242 T11 TP2 TP27 IB8 BB2, BB4 3285 Vanadium compound, n.o.s 6.1 III 6.1 T7 240 T7 TP1 TP28 IB8 BB3 3286 Flammable liquid, toxic, corrosive, n.o.s 3 I 3, 6.1, 8 243 T14 TP2 TP13 TP27 3286 Flammable liquid, toxic, corrosive, n.o.s 3 II 3, 6.1, 8 T14 243 T11 TP2 TP13 TP27 IB2 3287 Toxic liquid, inorganic, n.o.s 6.1 I 6.1 T42 243 T14 TP2 TP13 TP27 3287 Toxic liquid, inorganic, n.o.s Inhalation Hazard, Packing Group I, Zone A 6.1 I 6.1 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP27 T38 T44 3287 Toxic liquid, inorganic, n.o.s Inhalation Hazard, Packing Group I, Zone B 6.1 I 6.1 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP27 T38, T45 3287 Toxic liquid, inorganic, n.o.s 6.1 II 6.1 B110, T14 243 T11 TP2 TP27 IB2 Start Printed Page 63388 3287 Toxic liquid, inorganic, n.o.s 6.1 III 6.1 T7 241 T7 TP1 TP28 IB3 3288 Toxic solid, inorganic, n.o.s 6.1 I 6.1 242 IB7 3288 Toxic solid, inorganic, n.o.s 6.1 II 6.1 242 IB8 BB2, BB4 3288 Toxic solid, inorganic, n.o.s 6.1 III 6.1 240 IB8 BB3 3289 Toxic liquid, corrosive, inorganic, n.o.s 6.1 I 6.1, 8 T42 243 T14 TP2 TP13 TP27 3289 Toxic liquid, corrosive, inorganic, n.o.s Inhalation Hazard, Packing Group I, Zone B 6.1 I 6.1, 8 2, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP27 TP38 TP45 3289 Toxic liquid, corrosive, inorganic, n.o.s inhalation Hazard, Packing Group I, Zone A 6.1 I 6.1, 8 1, B9, B14, B30, B72, T38, T43, T44 244 T22 TP2 TP13 TP27 TP38 TP44 3289 Toxic liquid, corrosive, inorganic, n.o.s 6.1 II 6.1, 8 T14 243 T11 TP2 TP27 IB2 3290 Toxic solid, corrosive, inorganic, n.o.s 6.1 I 6.1, 8 242 IB7 3290 Toxic solid, corrosive, inorganic, n.o.s 6.1 II 6.1, 8 242 IB6 BB2 3293 Hydrazine, aqueous solution with not more than 37 percent hydrazine, by mass 6.1 III 6.1 T7 241 T4 TP1 IB3 3294 Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide 6.1 I 6.1, 3 2, 25, B9, B14, B32, B74, T38, T43, T45 244 T20 TP2 TP13 TP38 TP45 3295 Hydrocarbons, liquid, n.o.s 3 I 3 T8, T31 243 T11 TP1 TP8 3295 Hydrocarbons, liquid, n.o.s 3 II 3 T8, T31 242 T7 TP1 TP8 TP28 IB2 3295 Hydrocarbons, liquid, n.o.s 3 III 3 B1, T7, T30 242 T4 TP1 TP29 IB3 3296 Heptafluoropropane or Refrigerant gas R 227 2.2 2.2 314, 315 T50 3297 Ethylene oxide and chlorotetrafluoroethane mixture with not more than 8.8 percent 2.2 2.2 314, 315 T50 3298 Ethylene oxide and pentafluoroethane mixture with not more than 7.9 percent ethylene oxide 2.2 2.2 314, 315 T50 3299 Ethylene oxide and tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide 2.2 2.2 314, 315 T50 3301 Corrosive liquid, self-heating, n.o.s 8 II 8, 4.2 B2 242 IB1 3302 2-Dimethylaminoethyl acrylate 6.1 II 6.1 T8 243 T7 TP2 IB2 3311 Gas, refrigerated liquid, flammable, n.o.s (crygoenic liquid) 2.2 2.2, 5.1 318 T75 Start Printed Page 63389 3312 Gas, refrigerated liquid, flammable, n.o.s (cryogenic liquid) 2.1 2.1 318 T75 3313 Organic pigments, self-heating 4.2 II 4.2 241 IB8 BB4 3313 Organic pigments, self-heating 4.2 III 4.2 B101 241 IB8 BB3 3314 Plastic molding compound in dough, sheet or extruded rope form evolving flammable vapor 9 III 9 32 221 IB8 BB6 3318 Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia 2.2 2.2 13 314, 315 T50 3318 Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia 2.3 2.3, 8 4 314, 315 T50 3320 Sodium borohydride and sodium hydroxide solution, with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass 8 II 8 B2, N34, T8 242 T7 TP2 IB2 3320 Sodium borohydride and sodium hydroxide solution, with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass 8 III 8 B2, N34, T7 241 T4 TP2 IB3 3336 Mercaptans, liquid, flammable, n.o.s., or Mercaptan mixture, liquid, flammable, n.o.s 3 I 3 T23 243 T11 TP2 3336 Mercaptans, liquid, flammable, n.o.s., or Mercaptan mixture, liquid, flammable, n.o.s 3 II 3 T8, T31 242 T7 TP1 TP8 TP28 IB2 3336 Mercaptans, liquid, flammable, n.o.s., or Mercaptan mixture, liquid, flammable, n.o.s 3 III 3 B1, B52, T7, T30 241 T4 TP1 TP29 IB3 3337 Refrigerant gas R 404A 2.2 314, 315 T50 3338 Refrigerant gas R 407A 2.2 314, 315 T50 3339 Refrigerant gas R 407B 2.2 314, 315 T50 3340 Refrigerant gas R 407C 2.2 314, 315 T50 3341 Thiourea dioxide 4.2 II 4.2 241 IB6 BB2 3341 Thiourea dioxide 4.2 III 4.2 241 IB8 BB3 3342 Xanthates 4.2 II 4.2 241 IB6 BB2 3342 Xanthates 4.2 III 4.2 241 IB8 BB3 3345 Phenoxyacetic acid derivative pesticide, solid, toxic 6.1 I 6.1 242 IB7 BB1 3345 Phenoxyacetic acid derivative pesticide, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 Start Printed Page 63390 3345 Phenoxyacetic acid derivative pesticide, solid, toxic 6.1 III 6.1 240 IB8 BB3 3346 Phenoxyacetic acid derivative pesticide, liquid flammable, toxic flashpoint less than 23° C 3 I 3, 6.1 T23 243 T14 TP2 TP13 TP27 3346 Phenoxyacetic acid derivative pesticide, liquid flammable, toxic flashpoint less than 23° C 3 II 3, 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3347 Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flashpoint not less than 23° C 6.1 I 6.1, 3 T24, T26 243 T14 TP2 TP13 TP27 3347 Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flashpoint not less than 23° C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3347 Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flashpoint not less than 23° C 6.1 III 6.1, 3 T14 241 T7 TP2 TP28 IB3 3348 Phenoxyacetic acid derivative pesticide, liquid, toxic 6.1 I 6.1 T24, T26 243 T14 TP2 TP13 TP27 3348 Phenoxyacetic acid derivative pesticide, liquid, toxic 6.1 II 6.1 T14 243 T11 TP2 TP27 IB2 3348 Phenoxyacetic acid derivative pesticide, liquid, toxic 6.1 III 6.1 T14 241 T7 TP2 TP28 IB3 3349 Pyrethroid pesticide, solid, toxic 6.1 I 6.1 242 IB7 BB1 3349 Pyrethroid pesticide, solid, toxic 6.1 II 6.1 242 IB8 BB2, BB4 3349 Pyrethroid pesticide, solid, toxic 6.1 III 6.1 230 IB8 BB3 3350 Pyrethroid pesticide, liquid, flammable, toxic, flashpoint less than 23° C 3 I 3, 6.1 T24, T26 243 T14 TP2 TP13 TP27 3350 Pyrethroid pesticide, liquid, flammable, toxic, flashpoint less than 23° C 3 II 3, 6.1 T14 243 T11 TP2 TP13 TP27 IB2 3351 Pyrethroid pesticide, liquid, flammable, toxic, flashpoint not less than 23° C 6.1 I 6.1, 3 T24, T26 243 T14 TP2 TP13 TP27 3351 Pyrethroid pesticide, liquid, flammable, toxic, flashpoint not less than 23° C 6.1 II 6.1, 3 T14 243 T11 TP2 TP13 TP27 IB2 3351 Pyrethroid pesticide, liquid, flammable, toxic, flashpoint not less than 23° C 6.1 III 6.1, 3 T14 241 T7 TP2 TP28 IB3 3352 Pyrethroid pesticide, liquid toxic 6.1 I 6.1 242 T14 TP2 TP13 TP27 3352 Pyrethroid pesticide, liquid toxic 6.1 II 6.1 242 T11 TP2 TP27 IB2 3352 Pyrethroid pesticide, liquid toxic 6.1 III 6.1 240 T7 TP2 TP28 IB3 f. In Columns (9A) and (9B), the following entries would be revised as follows:
Note to readers:
*** means no change to current limit.
Column (2) Column (4) Column (5) Column (9A) Revise to read: Column (9B) Revise to read: Acetone cyanohydrin, stabilized UN1541 I *** Forbidden. Boron tribromide UN2692 I *** Forbidden. n-Butyl chloroformate UN2743 I Forbidden Forbidden. n-Butyl isocyanate UN2485 I *** Forbidden. Bisulfites, aqueous solutions, n.o.s UN2693 III 5 L 60 L. Cells, containing sodium UN3292 II 25 kg gross Chloroacetonitrile UN2668 II *** Forbidden. Chloroform UN1888 III 60 L 220 L. Crotonaldehyde, stabilized UN1143 I Forbidden. Diethyl sulfide UN2375 II 5 L Divinyl ether, inhibited UN1167 I 30 L. Lithium battery UN3090 II 5 kg gross *** Methacrylonitrile, inhibited UN3079 I *** Forbidden. Methyl bromide and ethylene dibromide mixtures, liquid UN1647 I *** Forbidden. Methyl orthosilicate UN2606 I *** Forbidden. Nitrogen trifluoride, compressed UN2451 75 kg 150 kg. Nitrous oxide, refrigerated liquid UN2201 Forbidden Forbidden. Nitromethane UN1261 II *** Forbidden. Phosphorus oxychloride UN1810 II *** Forbidden. n-Propyl chloroformate UN2740 I *** Forbidden. Sulfur trioxide, inhibited or Sulfur trioxide, stabilized UN1829 I *** Forbidden. Tear gas substances, solid, n.o.s. UN1693 I *** 15 kg. Titanium tetrachloride UN1838 II *** Forbidden. Thiophosgene UN2474 II *** Forbidden. g. In Columns (10A) and (10B), the following entries would be revised as follows:
Column (2) entry Column (4) entry Column (10a) revise to read: Column (10b) revise to read: Ammonium nitrate-fuel oil mixture containing only prilled ammonium nitrate and fuel oil NA0331 10 19E Ammonium nitrate, with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance UN0222 10 19E Ammonium perchlorate UN0402 10 19E Ammonium picrate, dry or wetted with less than 10 percent water, by mass UN0004 10 5E, 19E Ammunition, illuminating with or without burster, expelling charge or propelling charge UN0171 03 Ammunition, illuminating with or without burster, expelling charge or propelling charge UN0254 03 Ammunition, illuminating with or without burster, expelling charge or propelling charge UN0297 02 Ammunition, incendiary liquid or gel, with burster, expelling charge or propelling charge UN0247 04 23E Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge UN0243 08 8E, 14E, 15E, 17E Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge UN0244 08 8E, 14E, 15E, 17E Ammunition, incendiary with or without burster, expelling charge or propelling charge UN0009 03 Ammunition, incendiary with or without burster, expelling charge, or propelling charge UN0010 03 Ammunition, incendiary with or without burster, expelling charge, or propelling charge UN0300 02 Ammunition, practice UN0362 02 Ammunition, practice UN0488 03 Ammunition, proof UN0363 02 Ammunition, smoke, white phosphorus with burster,expelling charge, or propelling charge UN0245 08 8E, 14E, 15E, 17E Ammunition, smoke, white phosphorus with burster, expelling charge, or propelling charge UN0246 08 8E, 14E, 15E, 17E Ammunition, smoke with or without burster, expelling charge or propelling charge UN0015 8E, 17E, 20E Ammunition, smoke with or without burster, expelling charge or propelling charge UN0016 8E, 17E, 20E Ammunition, smoke with or without burster, expelling charge or propelling charge UN0303 7E, 8E, 14E, 15E, 17E Ammunition, tear-producing with burster, expelling charge or propelling charge UN0018 8E, 17E, 20E Ammunition, tear-producing with burster, expelling charge or propelling charge UN0019 8E, 17E, 20E Ammunition, tear-producing with burster, expelling charge or propelling charge UN0301 7E, 8E, 14E, 15E, 17E Ammunition, toxic with burster, expelling charge, or propelling charge UN0020 08 8E, 14E, 15E, 17E Ammunition, toxic with burster, expelling charge, or propelling charge UN0021 08 8E, 14E, 15E, 17E Articles, explosive, extremely insensitive or Articles, EEI UN0486 07 Articles, explosive, n.o.s UN0349 05 Articles, explosive, n.o.s UN0350 06 Start Printed Page 63392 Articles, explosive, n.o.s UN0351 06 Articles, explosive, n.o.s UN0352 06 Articles, explosive, n.o.s UN0353 06 Articles, explosive, n.o.s UN0354 08 8E, 14E, 15E, 17E Articles, explosive, n.o.s UN0355 08 8E, 14E, 15E, 17E Articles, explosive, n.o.s UN0356 08 8E, 14E, 15E, 17E Articles, explosive, n.o.s UN0462 07 Articles, explosive, n.o.s UN0463 07 Articles, explosive, n.o.s UN0464 07 Articles, explosive, n.o.s UN0465 08 Articles, explosive, n.o.s UN0466 07 Articles, explosive, n.o.s UN0467 07 Articles, explosive, n.o.s UN0468 07 Articles, explosive, n.o.s UN0469 08 Articles, explosive, n.o.s UN0470 07 Articles, explosive, n.o.s UN0471 06 Articles, explosive, n.o.s UN0472 08 Articles, pyrophoric UN0380 08 8E, 14E, 15E, 17E Articles, pyrotechnic for technical purposes UN0428 07 Articles, pyrotechnic for technical purposes UN0429 07 Articles, pyrotechnic for technical purposes UN0430 07 Articles, pyrotechnic for technical purposes UN0431 06 Articles, pyrotechnic for technical purposes UN0432 05 Barium azide, dry or wetted with less than 50 percent water, by mass. UN0224 12 Barium styphnate NA0473 Black powder, compressed or Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets UN0028 10 Black powder or Gunpowder, granular or as a meal UN0027 10 Bombs, photo-flash UN0037 08 Bombs, photo-flash UN0038 03 Bombs, photo-flash UN0039 03 Bombs, photo-flash UN0299 03 Bombs, with bursting charge UN0033 08 Bombs, with bursting charge UN0034 03 Bombs, with bursting charge UN0035 03 Bombs, with bursting charge UN0291 08 Bombs with flammable liquid, with bursting charge UN0399 04 23E Bombs with flammable liquid, with bursting charge UN0400 04 23E Boosters with detonator UN0225 11 Boosters with detonator UN0268 07 Boosters, without detonator UN0042 07 Boosters, without detonator UN0283 07 Bursters, explosive UN0043 07 Cartridges, flash UN0049 07 Cartridges, flash UN0050 07 Cartridges for weapons, blank UN0326 07 Cartridges for weapons, blank UN0413 07 Cartridges for weapons, blank or Cartridges, small arms, blank UN0014 05 Cartridges for weapons, blank or Cartridges, small arms, blank UN0327 07 Cartridges for weapons, blank or Cartridges, small arms, blank UN0338 06 Cartridges for weapons, inert projectile UN0328 03 Cartridges for weapons, inert projectile or Cartridges, small arms UN0012 05 Cartridges for weapons, inert projectile or Cartridges, small arms UN0339 06 Cartridges for weapons, inert projectile or Cartridges, small arms UN0417 06 Cartridges for weapons, with bursting charge UN0005 08 Cartridges for weapons, with bursting charge UN0006 03 Cartridges for weapons, with bursting charge UN0007 08 Cartridges for weapons, with bursting charge UN0321 03 Cartridges for weapons, with bursting charge UN0348 08 Cartridges for weapons, with bursting charge UN0412 02 Cartridges, oil well UN0277 07 Cartridges, oil well UN0278 06 Cartridges, power device UN0275 07 Cartridges, power device UN0276 06 Cartridges, power device UN0323 05 Cartridges, power device UN0381 07 Cartridges, signal UN0054 07 Cartridges, signal UN0312 06 Cartridges, signal UN0405 05 Cases, cartridge, empty with primer UN0055 05 Cases, cartridges, empty with primer UN0379 06 Cases, combustible, empty, without primer UN0446 06 Cases, combustible, empty, without primer UN0447 07 Start Printed Page 63393 Charges, bursting, plastics bonded UN0457 07 Charges, bursting, plastics bonded UN0458 07 Charges, bursting, plastics bonded UN0459 06 Charges, bursting, plastics bonded UN0460 05 Charges, demolition UN0048 03 Charges, depth UN0056 03 Charges, explosive, commercial without detonator UN0442 07 Charges, explosive, commercial without detonator UN0443 07 Charges, explosive, commercial without detonator UN0444 06 Charges, explosive, commercial without detonator UN0445 05 Charges, propelling UN0271 07 Charges, propelling UN0272 07 Charges, propelling UN0415 07 Charges, propelling UN0491 06 Charges, propelling, for cannon UN0242 10 Charges, propelling, for cannon UN0279 10 Charges, propelling, for cannon UN0414 10 Charges, shaped, flexible, linear UN0237 06 Charges, shaped, flexible, linear UN0288 07 Charges, shaped, without detonator UN0059 07 Charges, shaped, without detonator UN0439 07 Charges, shaped, without detonator UN0440 06 Charges, shaped, without detonator UN0441 05 Charges, supplementary explosive UN0060 10 Components, explosive train, n.o.s UN0382 11 Components, explosive train, n.o.s UN0383 06 Components, explosive train, n.o.s UN0384 05 Components, explosive train, n.o.s UN0461 11 Contrivances, water-activated, with burster, expelling charge or propelling charge UN0248 08 8E, 14E, 15E, 17E Contrivances, water-activated, with burster, expelling charge or propelling charge UN0249 08 8E, 14E, 15E, 17E Cord, detonating, flexible UN0065 07 Cord, detonating, flexible UN0289 06 Cord detonating or Fuse detonating metal clad UN0102 07 Cord, detonating or Fuse, detonating metal clad UN0290 07 Cord, detonating, mild effect or Fuse, detonating, mild effect metal clad UN0104 06 Cord, igniter UN0066 06 Cutters, cable, explosive UN0070 05 Cyclotetramethylenetetranitramine, desensitized or Octogen, desensitized or HMX, desensitized UN0484 10 Cyclotetramethylenetetranitramine, wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass UN0226 10 Cyclotrimethylenetrinitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized UN0483 10 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass UN0072 10 Deflagrating metal salts of aromatic nitroderivatives, n.o.s UN0132 10 5E Detonator assemblies, non-electric for blasting UN0360 11 Detonator assemblies, non-electric for blasting UN0361 06 Detonator assemblies, non-electric for blasting UN0500 05 Detonators, electric, for blasting UN0030 11 Detonators, electric, for blasting UN0255 06 Detonators, electric for blasting UN0456 05 Detonators for ammunition UN0073 11 Detonators for ammunition UN0364 11 Detonators for ammunition UN0365 06 Detonators for ammunition UN0366 05 Detonators, non-electric, for blasting UN0029 11 Detonators, non-electric, for blasting UN0267 06 Detonators, non-electric for blasting UN0455 05 Diazodinitrophenol, wetted with not less than 40 percent water or mixture of alcohol and water, by mass UN0074 12 Diethyleneglycol dinitrate, desensitized with not less than 25 percent non-volatile, water-insoluble phlegmatizer, by mass UN0075 13 21E Dinitroglycoluril or Dingu UN0489 10 Dinitrophenol, dry or wetted with less than 15 percent water, by mass UN0076 10 5E Dinitrophenolates alkali metals, dry or wetted with less than 15 percent water, by mass UN0077 10 5E Dinitroresorcinol, dry or wetted with less than 15 percent water, by mass UN0078 10 5E Dinitrosobenzene UN0406 10 Dipicryl sulfide, dry or wetted with less than 10 percent water, by mass UN0401 10 Explosive, blasting, type A UN0081 10 21E Explosive, blasting, type B UN0082 10 Explosive, blasting, type B or Agent blasting, Type B UN0331 10 Explosive, blasting, type C UN0083 10 22E Start Printed Page 63394 Explosive, blasting, type D UN0084 10 Explosive, blasting, type E UN0241 10 19E Explosive, blasting, type E or Agent blasting, Type E UN0332 10 Fireworks UN0333 07 Fireworks UN0334 07 Fireworks UN0335 07 Fireworks UN0336 06 Fireworks UN0337 05 Flares, aerial UN0093 07 Flares, aerial UN0403 06 Flares, aerial UN0404 05 Flares, aerial UN0420 07 Flares, aerial UN0421 07 Flares, surface UN0092 07 Flares, surface UN0418 07 Flares, surface UN0419 07 Flash powder UN0094 15 Flash powder UN0305 15 Fracturing devices, explosive, without detonators for oil wells UN0099 07 Fuse, igniter tubular metal clad UN0103 06 Fuse, non-detonating instantaneous or quickmatch UN0101 07 Fuse, safety UN0105 05 Fuzes, detonating UN0106 11 Fuzes, detonating UN0107 11 Fuzes, detonating UN0257 06 Fuzes, detonating UN0367 05 Fuzes, detonating, with protective features UN0408 07 Fuzes, detonating, with protective features UN0409 07 Fuzes, detonating, with protective features UN0410 06 Fuzes, igniting UN0316 07 Fuzes, igniting UN0317 06 Fuzes, igniting UN0368 05 Grenades, empty primed NA0349 05 Grenades, hand or rifle, with bursting charge UN0284 07 Grenades, hand or rifle, with bursting charge UN0285 07 Grenades, hand or rifle, with bursting charge UN0292 08 Grenades, hand or rifle, with bursting charge UN0293 08 Grenades, practice, hand or rifle UN0110 05 Grenades, practice, hand or rifle UN0318 07 Grenades, practice, hand or rifle UN0372 07 Grenades, practice, Hand or rifle UN0452 06 Guanyl nitrosaminoguanylidene hydrazine, wetted with not less than 30 percent water, by mass UN0113 12 Guanyl nitrosaminoguanyltetrazene, wetted or Tetrazene, wetted with not less than 30 percent water or mixture of alcohol and water, by mass UN0114 12 Hexanitrodiphenylamine or Dipicrylamine or Hexyl UN0079 10 Hexanitrostilbene UN0392 10 Hexolite, or Hexotol dry or wetted with less than 15 percent water, by mass UN0118 10 Hexotonal UN0393 10 Igniters UN0121 07 Igniters UN0314 07 Igniters UN0315 07 Igniters UN0325 06 Igniters UN0454 05 Jet perforating guns, charged oil well, with detonator NA0124 07 Jet perforating guns, charged oil well, with detonator NA0494 06 Jet perforating guns, charged, oil well, without detonator UN0124 07 Jet perforating guns, charged, oil well, without detonator UN0494 06 Lead azide, wetted with not less than 20 percent water or mixture of alcohol and water, by mass UN0129 12 Lead mononitroresorcinate NA0473 12 Lead styphnate, wetted or Lead trinitroresorcinate, wetted with not less than 20 percent water or mixture of alcohol and water, by mass UN0130 12 Lighters, fuse UN0131 05 Mannitol hexanitrate, wetted or Nitromannite, wetted with not less than 40 percent water, or mixture of alcohol and water, by mass UN0133 10 5-Mercaptotertrazol-1-acetic acid UN0448 09 Mercury fulminate, wetted with not less than 20 percent water, or mixture of alcohol and water, by mass UN0135 12 Mines with bursting charge UN0136 08 Mines with bursting charge UN0137 03 Mines with bursting charge UN0138 03 Mines with bursting charge UN0294 08 Start Printed Page 63395 Model rocket motor NA0276 06 Model rocket motor NA0323 05 Nitro urea UN0147 10 5-Nitrobenzotriazol UN0385 10 Nitrocellulose, dry or wetted with less than 25 percent water (or alcohol), by mass UN0340 13 27E Nitrocellulose, plasticized with not less than 18 percent plasticizing substance, by mass UN0343 10 Nitrocellulose, unmodified or plasticized with less than 18 percent plasticizing substance, by mass UN0341 13 27E Nitrocellulose, wetted with not less than 25 percent alcohol, by mass UN0342 10 Nitroglycerin, desensitized with not less than 40 percent non-volatile water insoluble phlegmatizer, by mass UN0143 13 21E Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 10 percent nitrogylcerin UN0144 10 21E Nitroguanidine or Picrite, dry or wetted with less than 20 percent water, by mass UN0282 10 Nitrostarch, dry or wetted with less than 20 percent water, by mass UN0146 10 Nitrotriazolone or NTO UN0490 10 Octolite or Octol, dry or wetted with less than 15 percent water, by mass UN0266 10 Octonal UN0496 10 Pentaerythrite tetranitrate or Pentaerythritol tetranitrate or PETN, with not less than 7 percent wax by mass UN0411 10 Pentaerythrite tetranitrate, wetted or Pentaerythritol tetranitrate, wetted, or PETN, wetted with not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pentaerythritol tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass UN0150 10 Pentolite, dry or wetted with less than 15 percent water, by mass UN0151 10 Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass UN0433 10 Powder cake, wetted or Powder paste, wetted with not less than 25 percent water, by mass UN0159 10 Powder, smokeless UN0160 26E Powder, smokeless UN0161 26E Primers, cap type UN0044 05 Primers, cap type UN0377 11 Primers, cap type UN0378 06 Primers, tubular UN0319 07 Primers, tubular UN0320 06 Primers, tubular UN0376 05 Projectiles, inert with tracer UN0345 01 Projectiles, inert, with tracer UN0424 03 Projectiles, inert, with tracer UN0425 02 Projectiles, with burster or expelling charge UN0346 03 Projectiles, with burster or expelling charge UN0347 02 Projectiles, with burster or expelling charge UN0426 08 Projectiles, with burster or expelling charge UN0427 08 Projectiles, with burster or expelling charge UN0434 03 Projectiles, with burster or expelling charge UN0435 02 Projectiles, with bursting charge UN0167 08 Projectiles, with bursting charge UN0168 03 Projectiles, with bursting charge UN0169 03 Projectiles, with bursting charge UN0324 08 Projectiles, with bursting charge UN0344 02 Propellant, liquid UN0495 10 Propellant, liquid UN0497 10 Propellant, solid UN0498 26E Propellant, solid UN0499 26E RDX and HMX mixtures, wetted with not less than 15 percent water by mass or RDX and HMX mixtures, desensitized with not less than 10 percent phlegmatizer by mass UN0391 10 Release devices, explosive UN0173 05 Rivets, explosive UN0174 05 Rocket motors UN0186 03 Rocket motors UN0280 03 Rocket motors UN0281 03 Rocket motors, liquid fueled UN0395 04 23E Rocket motors, liquid fueled UN0396 04 23E Rocket motors with hypergolic liquids with or without an expelling charge UN0250 08 8E, 14E, 15E, Rocket motors with hypergolic liquids with or without an expelling charge UN0322 08 8E, 14E, 15E, Rockets, line-throwing UN0238 07 Rockets, line-throwing UN0240 07 Rockets, line-throwing UN0453 06 Rockets, liquid fueled with bursting charge UN0397 04 23E Rockets, liquid fueled with bursting charge UN0398 04 23E Rockets, with bursting charge UN0180 08 Rockets, with bursting charge UN0181 03 Start Printed Page 63396 Rockets, with bursting charge UN0182 03 Rockets, with bursting charge UN0295 08 Rockets, with expelling charge UN0436 03 Rockets, with expelling charge UN0437 03 Rockets, with expelling charge UN0438 02 Rockets, with inert head UN0183 03 Samples, explosive, other than initiating explosives UN0190 14 Signal devices, hand UN0191 06 Signal devices, hand UN0373 05 Signals, distress, ship UN0194 07 Signals, distress, ship UN0195 07 Signals, railway track, explosive UN0192 07 Signals, railway track, explosive UN0193 05 Signals, railway track, explosive UN0492 07 Signals, railway track, explosive UN0493 06 Signals, smoke UN0196 07 Signals, smoke UN0197 06 Signals, smoke UN0313 07 Signals, smoke UN0487 07 Sodium dinitro-o-cresolate, dry or wetted with less than 15 percent water, by mass UN0234 10 5E Sodium picramate, dry or wetted with less than 20 percent water, by mass UN0235 10 5E Sounding devices, explosive UN0204 08 Sounding devices, explosive UN0296 08 Sounding devices, explosive UN0374 07 Sounding devices, explosive UN0375 07 Substances, explosive, n.o.s UN0357 8E, 14E, 15E, 17E Substances, explosive, n.o.s UN0358 8E, 14E, 15E, 17E Substances, explosive, n.o.s UN0359 8E, 14E, 15E, 17E Substances, explosive, n.o.s UN0473 12 Substances, explosive, n.o.s UN0474 10 Substances, explosive, n.o.s UN0475 10 Substances, explosive, n.o.s UN0476 08 Substances, explosive, n.o.s UN0477 10 Substances, explosive, n.o.s UN0478 08 Substances, explosive, n.o.s UN0479 09 Substances, explosive, n.o.s UN0480 09 Substances, explosive, n.o.s UN0481 05 Substances, explosive, n.o.s UN0485 08 Substances, explosive, very insensitive, n.o.s., or Substances, EVI, n.o.s UN0482 10 Tetranitroaniline UN0207 10 Tetrazol-1-acetic acid UN0407 09 Torpedoes, liquid fueled, with inert head UN0450 04 23E Torpedoes, liquid fueled, with or without bursting charge UN0449 04 23E Torpedoes with bursting charge UN0329 03 Torpedoes with bursting charge UN0330 08 Torpedoes with bursting charge UN0451 03 Toy Caps NA0337 05 Tracers for ammunition UN0212 07 Tracers for ammunition UN0306 06 Trinitro-meta-cresol UN0216 10 5E Trinitroaniline or Picramide UN0153 10 Trinitroanisole UN0213 10 Trinitrobenzene, dry or wetted with less than 30 percent water, by mass UN0214 10 Trinitrobenzenesulfonic acid UN0386 10 5E Trinitrobenzoic acid, dry or wetted with less than 30 percent water, by mass UN0215 10 5E Trinitrochlorobenzene or Picryl chloride. UN0155 10 Trinitrofluorenone UN0387 10 Trinitronaphthalene UN0217 10 Trinitrophenetole UN0218 10 Trinitrophenol or Picric acid, dry or wetted with less than 30 percent water, by mass UN0154 10 5E Trinitrophenylmethylnitramine or Tetryl. UN0208 10 Trinitroresorcinol or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass UN0219 10 5E Trinitroresorcinol, wetted or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass UN0394 10 5E Trinitrotoluene and Trinitrobenzene mixtures or TNT and trinitrobenzene mixtures or TNT and hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures UN0388 10 Trinitrotoluene mixtures containing Trinitrobenzene and Hexanitrostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene UN0389 10 Trinitrotoluene or TNT, dry or wetted with less than 30 percent water, by mass UN0209 10 Tritonal UN0390 10 Urea nitrate, dry or wetted with less than 20 percent water, by mass UN0220 10 Warheads, rocket with burster or expelling charge UN0370 02 Start Printed Page 63397 Warheads, rocket with burster or expelling charge UN0371 08 Warheads, rocket with bursting charge UN0286 03 Warheads, rocket with bursting charge UN0287 03 Warheads, rocket with bursting charge UN0369 08 Warheads, torpedo with bursting charge UN0221 03 Zirconium picramate, dry or wetted with less than 20 percent water, by mass. UN0236 10 5E 13. In Appendix B to § 172.101, paragraphs 1. and 2. would be revised and the List of Marine Pollutants would be amended by removing 73 entries, adding 2 entries and revising 2 entries in appropriate alphabetical order to read as follows:
Appendix B to § 172.101—List of Marine Pollutants
1. See § 171.4 of this subchapter for applicability of marine pollutants. This appendix lists potential marine pollutants as defined in § 171.8 of this subchapter.
2. Marine pollutants listed in this appendix are not necessarily listed by name in the § 172.101 Table. If a marine pollutant not listed by name or by synonym in the § 172.101 Table meets the definition of any hazard Class 1 through 8, then you must determine the class and division of the material in accordance with § 173.2a of this subchapter. You must also select the most appropriate hazardous material description and proper shipping name. If a marine pollutant not listed by name or by synonym in the § 172.101 Table does not meet the definition of any Class 1 through 8, then you must offer it for transportation under the most appropriate of the following two Class 9 entries: “Environmentally hazardous substances, liquid, n.o.s.,” UN3082, or “Environmentally hazardous substances, solid, n.o.s.,” UN3077.
* * * * *List of Marine Pollutants
S.M.P. Marine pollutant (1) (2) [Remove:] Acetal Acetaldehyde Amyl mercaptans Anisole Benzaldehyde Butyl benzenes n-Butyl butyrate Butylphenols, liquid Butylphenols, solid Butyraldehyde Calcium naphthenate Camphor oil Chlorotoluenes (ortho-, meta-, para-) Coal tar Coal tar naphtha Creosote (coal tar) Creosote (wood tar) Cresols (o-; m-; p-) Cresylic acid Cresylic acid sodium salt normal-Decaldehyde normal-Decanol Decyl acrylate Dichlorobenzene (meta; ortho; para) Dichlorophenols, liquid Dichlorophenols, solid 2,4-Dichlorophenoxyacetic acid (see also 2,4D) 2,4 Dichlorophenoxyacetic acid diethanolamine salt 2,4 Dichlorophenoxyacetic acid dimethylamine salt 2,4-Dichlorophenoxyacetic acid triisopropylamine salt Diethybenzenes (mixed isomers) Diisopropylnaphthalene Dimethyl disulphide Dimethyl glyoxal (butanedione) Dimethyl sulphide Diphenyl ether Diphenyl ether/biphenyl phenyl ether mixtures Diphenyl/diphenyl ether (mixtures) EPTC (ISO) Ethyl acrylate, inhibited 2-Ethylbutyraldehyde 2-Ethylhexenal Ethyl chlorothioformate 2,4-Hexadiene aldehyde normal-Hexaldehyde Start Printed Page 63398 Iron oxide, spent Iron sponge, spent Isobutyl aldehyde Isobutyl isobutyrate Isobutyl priopionate Isobutyraldehyde Isodecaldehyde Isodecanol Isononanol Isooctanol Isopropylbenzene Isovaleraldehyde 1-Methyl-4-ethylbenzene 2-Methyl-5-ethylpyridine Methyl salicylate 2-Methylbutyraldehyde Methylnaphthalenes, liquid Methylnaphthalenes, solid Naphthalene, crude or refined Naphthalene, molten Naphthenic acids, liquid Naphthenic acids, solid Nitrocresols Nitrotolueunes (ortho-;meta-;para-), liquid Nitrotoluenes (ortho-;meta-;para-), solid 1-Nonanal 1-Nonanol 1-Octanol alpha-Pinene Propanethiols Propionaldehyde n-Propylbenzene Styrene monomer, inhibited n-Tetramethylbenzenes 4-Thiapentanal 1,2,3-Trimethylbenzene 1,2,4-Trimethyl benzene 1,3,5-Trimethyl benzene Turpentine 1-Undecanol normal-Valeraldehyde Vinyltoluenes, inhibited mixed isomers Xylenols [Add:] * * * * * * * Chlorotoluenes (meta-;para-) * * * * * * * Desmedipham * * * * * * * PP Diclofop-methyl * * * * * * * Dichlorobenzene (para) * * * * * * * Diisopropylnaphthalenes, mixed isomers * * * * * * * PP Fenchlorazole-ethyl * * * * * * * PP Fenoxapro-ethyl * * * * * * * PP Fenoxaprop-P-ethyl * * * * * * * Linuron Start Printed Page 63399 * * * * * * * PP Silafluofen * * * * * * * PP 1,2,3-Trichlorobenzene * * * * * * * [Revise:] * * * * * * * PP Dodecyl hydroxypropyl sulfide * * * * * * * 14. In § 172.102, in paragraph (c)(1), Special Provisions 43, 110, 128 and 136 would be revised and Special Provisions 139, 142 and 143 would be added; paragraph (c)(3) introductory text, Special Provisions B53 and B69 and paragraphs (c)(4) and (c)(7) would be revised; and in paragraph (c)(8), Specials Provisions W7, W8 and W9 would be added in numerical order to read as follows:
Special provisions.* * * * *(c) * * *
(1) * * *
Code/Special Provisions
* * * * *43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a). On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1, nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of this subchapter when contained individually in an article or a sealed packet.
* * * * *110 Fire extinguishers transported under UN1044 may include installed actuating cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per extinguishing unit.
* * * * *128 Regardless of the provisions of § 172.101(c)(12), aluminum smelting by-products, aluminum remelting by-products and coated magnesium granules described under these entries meeting the definition of Class 8, Packing Group II or III, may be classed as a Division 4.3 material and transported under this entry. The presence of a Class 8 hazard must be communicated as required by this part for subsidiary hazards.
* * * * *136 This entry only applies to machinery and apparatus containing hazardous materials as in integral element of the machinery or apparatus. It may not be used to describe machinery or apparatus for which a proper shipping name exists in the § 172.101 Table. Except when approved by the Associate Administrator, machinery or apparatus may only contain hazardous materials for which exceptions are referenced in Column (8) of the § 172.101 Table and are provided in part 173, subpart D, of this subchapter. Hazardous materials shipped under this entry are excepted from the labeling requirements of this subchapter unless offered for transportation or transported by aircraft and are not subject to the placarding requirements of subpart F of part 173 of this subchapter. Orientation markings as described in § 172.312 (a)(2) are required when liquid hazardous materials may escape due to incorrect orientation. The machinery or apparatus, if unpackaged, or the packaging in which it is contained shall be marked “Dangerous goods in machinery” or “Dangerous goods in apparatus”, as appropriate, with the identification number UN3363. For transportation by aircraft, machinery or apparatus may not contain any material forbidden for transportation by passenger or cargo aircraft. The Associate Administrator may except from the requirements of this subchapter, equipment, machinery and apparatus provided:
a. It is shown that it does not pose a significant risk in transportation;
b. The quantities of hazardous materials do not exceed those specified in § 173.4 of this subchapter; and
c. The equipment, machinery or apparatus conforms with § 173.222 of this subchapter.
* * * * *139 Use of the “special arrangement” proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the U.S. Competent Authority in accordance with the requirements in § 173.471, § 173.472, or § 173.473 of this subchapter. Use of these proper shipping names for domestic shipments may be made only under a DOT exemption, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter.
* * * * *142 These hazardous materials may not be classified and transported unless authorized by the Associate Administrator. The Associate Administrator will base the authorization on results from Series 2 tests and a Series 6(c) test from the UN Manual of Tests and Criteria on packages as prepared for transport in accordance with the requirements of this subchapter.
143 These articles may contain:
a. Division 2.2 compressed gases, including oxygen;
b. Signal devices (Class 1) which may include smoke and illumination signal flares. Signal devices must be packed in plastic or fiberboard inner packagings;
c. Electric storage batteries;
d. First aid kits; or
e. Strike anywhere matches.
* * * * *(3) “B” codes. These provisions apply only to bulk packagings, other than IBCs:
Code/Special Provisions
* * * * *B53 Packagings must be made of either aluminum or steel.
* * * * *B69 Dry sodium cyanide or potassium cyanide may be shipped in sift-proof weather-resistant metal covered hopper cars, covered motor vehicles, portable tanks or non-specification bins. Bins must be approved by the Associate Administrator.
* * * * *(4) Table 1—IBC Codes and BB Special IBC Packing Provisions. These Start Printed Page 63400provisions apply only to transportation in IBCs:
Table 1.—IBC Codes1
IBC Code Authorized IBCs IB1 Authorized IBCs: Metal (31A, 31B and 31N). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. IB2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130kPa at 55 °C (1.3 bar at 131 °F) are authorized. IB3 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. IB4 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N). IB5 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1). IB6 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport. IB7 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F). Additional Requirement: Liners of wooden IBCs must be sift-proof. IB8 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IB99 IBCs are only authorized if approved by the Associate Administrator. 1 1 IBCs may be used for the transportation of hazardous materials when no IBC code is assigned in the § 172.101 Hazardous Materials Table for the specific material if approved by the Associate Administrator. Table 2.—Organic Peroxide IBC Code (IB52)1
UN No. Organic peroxide Type of IBC Maximum quantity (liters) Control temperature (°C) Emergency temperature (°C) 3109 ORGANIC PEROXIDE, TYPE F, LIQUID tert-Butyl hydroperoxide, not more than 72% with water 31A 1250 tert-Butyl peroxyacetate, not more than 32% in diluent type A 31A 31HA1 1250 1000 tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 32% in diluent type A 31A 31HA1 1250 1000 Cumyl hydroperoxide, not more than 90% in diluent type A 31HA1 1250 Dibenzoyl peroxide, not more than 42% as a stable dispersion 31H1 1000 Di-tert-butyl peroxide, not more than 52% in diluent type A 31A 31HA1 1250 1000 1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A 31H1 1000 Dilauroyl peroxide, not more than 42%, stable dispersion, in water 31HA1 1000 Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A 31HA1 1250 p-Menthyl hydroperoxide, not more than 72% in diluent type A 31HA1 1250 Peroxyacetic acid, stabilized, not more than 17% 31H1 31HA1 31A 1500 1500 1500 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B 31HA1 31A 1000 1250 +30 +30 +35 +35 tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A 31A 1250 0 +10 Start Printed Page 63401 tert-Butyl peroxyneodecanoate, not more than 42% stable dispersion, in water 31A 1250 −5 +5 tert-Butyl peroxypivalate, not more than 27% in diluent type B 31HA1 31A 1000 1250 +10 +10 +15 +15 Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1250 −15 −5 Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1000 +30 +35 Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1000 +30 +35 Di-(2-ethylhexyl) peroxydicarbonate, not more than 52%, stable dispersion, in water 31A 1250 −20 −10 Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1000 +15 +20 Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 38% in diluent type A 31HA1 31A 1000 1250 +10 C +10 C +15 +15 Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water 31A 1250 +10 +15 1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1250 −5 +5 1 This IBC Code applies to organic peroxides of type F. For formulations not listed in this table, only IBCs that are approved by the Associate Administrator may be used. Table 3.—BB Codes
BB1 IBCs must be packed in closed freight containers or a closed transport vehicle. BB2 When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. BB3 Flexible IBCs shall be sift-proof and water-resistant or shall be fitted with a sift-proof and water-resistant liner. BB4 Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. BB5 IBCs must be provided with a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. BB6 Non-specification bulk bins are authorized. BB7 For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178 of this subchapter. * * * * *(7) “T” codes. (i) These provisions apply to the transportation of UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. In T23, the organic peroxides and self-reactive substances which are authorized to be transported in portable tanks are listed along with the applicable control and emergency temperatures. Liquefied compressed gases are assigned to portable tank instruction T50. T50 provides the maximum allowable working pressures, bottom opening requirements, pressure relief requirements and degree of filling requirements for liquefied compressed gases permitted for transport in portable tanks. Refrigerated liquefied gases which are authorized to be transported in portable tanks are specified in tank instruction T75.
(ii) The following table specifies the portable tank requirements applicable to T Codes T1 through T22. Column 1 specifies the T Code. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by § 173.32b of this subchapter must be conducted. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of § 178.275(f)(3) of this subchapter for the pressure relief devices. When the word “Normal” is indicated, § 178.275(f)(3) of this subchapter does not apply. Column 5 either references the applicable requirements for bottom openings in part 178 of this subchapter, or references “Prohibited” which means bottom openings are prohibited. The table follows:Start Printed Page 63402
Table of Portable Tank T Codes
[Portable Tank Instructions: T1-T22—Portable tank instructions. T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.]
Portable tank instruction Minimum test pressure (bar) Minimum shell thickness (in mm-reference steel) (See § 178.274(d)) Pressure-relief requirements (See § 178.275(f)) Bottom opening requirements (See § 178.275(c)) (1) (2) (3) (4) (5) T1 1.5 § 178.274(d)(2) Normal § 178.274(c)(2). T2 1.5 § 178.274(d)(2) Normal § 178.275(c)(3). T3 2.65 § 178.274(d)(2) Normal § 178.275(c)(2). T4 2.65 § 178.274(d)(2) Normal § 178.275(c)(3). T5 2.65 § 178.274(d)(2) § 178.275(f)(3) Prohibited. T6 4 § 178.274(d)(2) Normal § 178.275(c)(2). T7 4 § 178.274(d)(2) Normal § 178.275(c)(3). T8 4 § 178.274(d)(2) Normal Prohibited. T9 4 6 mm Normal Prohibited. T10 4 6 mm § 178.275(f)(3) Prohibited. T11 6 § 178.274(d)(2) Normal § 178.275(c)(3). T12 6 § 178.274(d)(2) § 178.275(f)(3) § 178.275(c)(3). T13 6 6 mm Normal Prohibited. T14 6 6 mm § 178.275(f)(3) Prohibited. T15 10 § 178.274(d)(2) Normal § 178.275(c)(3). T16 10 § 178.274(d)(2) § 178.275(f)(3) § 178.275(c)(3). T17 10 6 mm Normal § 178.275(c)(3). T18 10 6 mm § 178.275(f)(3) § 178.275(c)(3). T19 10 6 mm § 178.275(f)(3) Prohibited. T20 10 8 mm § 178.275(f)(3) Prohibited. T21 10 10 mm Normal Prohibited. T22 10 10 mm § 178.275(f)(3) Prohibited. (iii) The following table specifies the portable tank requirements applicable to T23 for self-reactive substances of Division 4.1 and organic peroxides of Division 5.2 which are authorized to be transported in portable tanks:
Portable Tank Instruction
[T23—Portable tank instruction. T23 applies to self-reactive substances of Division 4.1 and organic peroxides of Division 5.2.]
UN No. Hazardous material Minimum test pressure (bar) Minimum shell thickness (mm-reference steel) Bottom opening requirements Pressure-relief requirements Filling limits Control temperature (°C) Emergency temperature (°C) 3109 Organic peroxide, Type F, liquid 444444 See § 178.274(d)(2) See § 178.275(c)(3) See § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) tert-Butyl hydroperoxide not more than 72% water. (Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water.) § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) Cumyl hydro-peroxide, not more than 90% in diluent type A § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) Di-tert-butyl peroxide, not more than 32% in diluent type A § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) Isopropyl cumyl hydro-peroxide, not more than 72% in diluent type A § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) p-Menthyl hydro-peroxide, not more than 72% in diluent type A § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) Pinanyl hydro-peroxide, not more than 50% in diluent type A § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) 3110 Organic peroxide, Type F, solid 4 § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) Dicumyl peroxide. Maximum quantity per portable tank 2,000 kg 3119 Organic peroxide, Type F, liquid, temperature controlled 444444 See § 178.274(d)(2) See § 178.275(c)(3) See § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) As approved by Assoc. Admin. for HMS As approved by Assoc. Admin. for HMS. Start Printed Page 63403 tert-Butyl peroxyacetate, not more than 32% in diluent type B § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) +30 +35 tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) +15 +20 tert-Butyl peroxypivalate, not more than 27% in diluent type B § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) −5 +10 tert-Butyl peroxy-3,5,5-trimethyl-hexanoate, not more than 32% in diluent type B § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) +35 +40 Di-(3,5,-trimethyl-hexanoyl) peroxide, not more than 38% in diluent type A § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) 0 +5 3120 Organic peroxide, Type F, solid, temperature controlled 4 § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) As approved by Assoc. Admin. for HMS As approved by Assoc. Admin. for HMS. 3229 Self-reactive liquid Type F 4 § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) 3230 Self-Reactive solid Type F 4 § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) 3239 Self-reactive liquid Type F, temperature controlled 4 § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) As approved by Assoc. Admin. for HMS As approved by Assoc. Admin. for HMS. 3240 Self-reactive solid Type F, temperature controlled 4 § 178.274(d)(2) § 178.275(c)(3) § 178.275(j)(1) Not more than 90% at 59 °F (15 °C) As approved by Assoc. Admin. for HMS As approved by Assoc. Admin. for HMS. (iv) The following portable tank instruction applies to portable tanks used for the transportation of liquefied compressed gases. The T50 table provides the UN identification number and proper shipping name for each liquefied compressed gas authorized to be transported in a T50 portable tank. The following table provides maximum allowable working pressures, bottom opening requirements, pressure relief device requirements and degree of filling requirements for each liquefied compressed gases permitted for transportation in a T50 portable tank:
Note to reader:
We are proposing to revise the word “stabilized” in the proper shipping names below to read “inhibited” (see preamble discussion under § 172.101).
Portable Tank Instruction
[T50—Portable tank instruction 50 applies to liquefied compressed gases.]
UN No. Non-refrigerated liquefied compressed gasses Max. allowable working pressure (bar) Small; Bare; Sunshield Insulated Openings below liquid level Pressure relief requirements (See § 178.276(e)) Maximum filing density (kg/l) 1005 Ammonia, anhydrous 29.0 25.7 22.0 19.7 Allowed § 178.276(e) 0.53 1009 Bromotrifluoromethane or Refrigerant gas R 13B1 38.0 34.0 30.0 27.5 ......do Normal 1.13 1010 Butadienes, stabilized 7.5 7.0 7.0 7.0 ......do ......do 0.55 1011 Butane 7.0 7.0 7.0 7.0 ......do ......do 0.51 Start Printed Page 63404 1012 Butylene 8.0 7.0 7.0 7.0 ......do ......do 0.53 017 Chlorine 19.0 17.0 15.0 13.5 Not allowed § 178.276(e) 1.25 1018 Chlorodifluoromethane or Refrigerant gas R 22 26.0 24.0 21.0 19.0 Allowed Normal 1.03 1020 Chloropentafluoroethane or Refrigerant gas R 115 23.0 20.0 18.0 16.0 ......do ......do 1.06 1021 1-Chloro-1,2,2,2-tetrafluoroethane or Refrigerant gas R 124 10.3 9.8 7.9 7.0 ......do ......do 1.2 1027 Cyclopropane 18.0 16.0 14.5 13.0 ......do ......do 0.53 1028 Dichlorodifluoromethane or Refrigerant gas R 12 16.0 15.0 13.0 11.5 ......do ......do 1.15 1029 Dichlorofluoromethane or Refrigerant gas R 21 7.0 7.0 7.0 7.0 ......do ......do 1.23 1030 1,1-Difluoroethane or Refrigerant gas R 152a 16.0 14.0 12.4 11.0 ......do ......do 0.79 1032 Dimethylamine, anhydrous 7.0 7.0 7.0 7.0 ......do ......do 0.59 1033 Dimethyl ether 15.5 13.8 12.0 10.6 ......do ......do 0.58 1036 Thylamine 7.0 7.0 7.0 7.0 ......do ......do 0.61 1037 Ethyl chloride 7.0 7.0 7.0 7.0 ......do ......do 0.8 1040 Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 °C −10 Not allowed § 178.276(e) .078 1041 Ethylene oxide and carbon dioxide mixture with more than 9% but no more than 87% ethylene oxide 1 Allowed Normal See § 173.32(f) 1055 Isobutylene 8.1 7.0 7.0 7.0 ......do ......do 0.52 1060 Methyl acetylene and propadiene mixture, stabilized 28.0 24.5 22.0 20.0 ......do ......do Start Printed Page 63405 1061 Methylamine, anhydrous 10.8 9.6 7.8 7.0 ......do ......do 0.58 1062 Methyl bromide 7.0 7.0 7.0 7.0 Not allowed § 178.276(e) 1.51 1063 Methyl chloride or Refrigerant gas R 40 14.5 12.7 11.3 10.0 Allowed Normal .081 1064 Methyl mercaptan 7.0 7.0 7.0 7.0 Not allowed § 178.276(e) 0.78 1067 Dinitrogen tetroxide 7.0 7.0 7.0 7.0 ....do § 178.276(e) 1.3 1075 Petroleum gas, liquefied (1) Allowed Normal See § 173.32(f) 1077 Propylene 28.0 24.5 22.0 20.0 ......do ......do 0.43 1078 Refrigerant gas, n.o.s (1) ......do ......do See § 173.32(f) 1079 Sulphur dioxide 11.6 10.3 8.5 7.6 Not Allowed § 178.276(e) 1.23 1082 Trifluorochloroethylene, stabilized or Refrigerant gas R 1113 17.0 15.0 13.1 11.6 ......do § 178.276(e) 1.13 1083 Trimethylamine, anhydrous 7.0 7.0 7.0 7.0 Allowed Normal 0.56 1085 Vinyl bromide, stabilized 7.0 7.0 7.0 7.0 ......do ......do 1.37 1086 Vinyl chloride, stabilized 10.6 9.3 8.0 7.0 ......do ......do 0.81 1087 Vinyl methyl ether, stabilized 7.0 7.0 7.0 7.0 ......do ......do 0.67 1581 Chloropicrin and methyl bromide mixture 7.0 7.0 7.0 7.0 Not allowed § 178.276(e) 1.51 1582 Chloropicrin and methyl chloride mixture 19.2 16.9 15.1 13.1 ......do § 178.276(e) 0.81 1858 Hexafluoropropylene compressed or Refrigerant gas R 1216 19.2 16.9 15.1 13.1 Allowed Normal 1.11 Start Printed Page 63406 1912 Methyl chloride and methylene chloride mixture 15.2 13.0 11.6 10.1 ......do ......do 0.81 1958 1,2-Dichloro-1,1,2,2-tetrafluoroethane or Refrigerant gas R 114 7.0 7.0 7.0 7.0 ......do ......do 1.3 1965 Hydrocarbon gas, mixture liquefied, n.o.s (1) ......do ......do See § 173.32(f) 1969 Isobutane 8.5 7.5 7.0 7.0 ......do ......do 0.49 1973 Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% chlorodifluoromethane or Refrigerant gas R 502 28.3 25.3 22.8 20.3 ......do ......do 1.05 1974 Chlorodifluorobromomethane or Refrigerant gas R 12B1 7.4 7.0 7.0 7.0 ......do ......do 1.61 1976 Octafluorocyclobutane or Refrigerant gas RC 318 8.8 7.8 7.0 7.0 ......do ......do 1.34 1978 Propane 22.5 20.4 18.0 16.5 ......do ......do 0.42 1983 1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a 7.0 7.0 7.0 7.0 ......do ......do 1.18 2035 1,1,1-Trifluoroethane compressed or Refrigerant gas R 143a 31.0 27.5 24.2 21.8 ......do ......do 0.76 2424 Octafluoropropane or Refrigerant gas R 218 23.1 20.8 18.6 16.6 ......do ......do 1.07 2517 1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b 8.9 7.8 7.0 7.0 ......do ......do 0.99 2602 Dichlorodifluoromethane and difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane or Refrigerant gas R 500 20.0 18.0 16.0 14.5 ......do ......do 1.01 3057 Trifluoroacetyl chloride 14.6 12.9 11.3 9.9 Not allowed § 178.276(e) 1.17 3070 Ethylene oxide and dichlorodifluoromethane mixture with not more than 12.5% ethylene oxide 14.0 12.0 11.0 9.0 Allowed § 178.276(e) 1.09 3153 Perfluoro (methyl vinyl ether) 14.3 13.4 11.2 10.2 ......do Normal 1.14 3159 1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a 17.7 15.7 13.8 12.1 ......do ......do 1.04 Start Printed Page 63407 3161 Liquefied gas, flammable, n.o.s. (1) ......do ......do See § 173.32(f) 3163 Liquefied gas, n.o.s. (1) ......do ......do See § 173.32(f) 3220 Pentafluoroethane or Refrigerant gas R 125 34.4 30.8 27.5 24.5 ......do ......do 0.95 3252 Difluoromethane or Refrigerant gas R 32 43.0 39.0 34.4 30.5 ......do ......do 0.78 3296 Heptafluoropropane or Refrigerant gas R 227 16.0 14.0 12.5 11.0 ......do ......do 1.2 3297 Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide 8.1 7.0 7.0 7.0 ......do ......do 1.16 3298 Ethylene oxide and pentafluoroethane mixture, with not more than 7.9% ethylene oxide 25.9 23.4 20.9 18.6 ......do ......do 1.02 3299 Ethylene oxide and tetrafluoroethane mixture, with not more than 5.6% ethylene oxide 16.7 14.7 12.9 11.2 ......do ......do 1.03 3318 Ammonia solution, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia (1) .....do § 178.276(e) § 173.32(f) 3337 Refrigerant gas R 404A 31.6 28.3 25.3 22.5 ......do Normal 0.84 3338 Refrigerant gas R 407A 31.3 28.1 25.1 22.4 ......do ......do 0.95 3339 Refrigerant gas R 407B 33.0 29.6 26.5 23.6 ......do ......do 0.95 3340 Refrigerant gas R 407C 29.9 26.8 23.9 21.3 ......do ......do 0.95 1 See MAWP definition in § 178.276(a). (v) When portable tank instruction T75 is referenced in Column (7) of the § 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of § 178.277 of this subchapter.
(vi) When a specific portable tank instruction is specified by a T Code in Column (7) of the § 172.101 Table for a specific hazardous material, a Specification portable tank conforming to an alternative tank instruction may be used if:
(A) the portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified);
(B) the portable tank has greater or equivalent wall thickness (for example, 10 bar when 6 bar is specified);
(C) the portable tank has a pressure relief device as specified in the T Code or is preceded by a frangible disc when no frangible disc is required. If a frangible disc is required in series with the pressure relief device, the alternative portable tank must be fitted with a frangible disc; and
(D) the portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings when two effective means of closure are specified; or the portable tank has no bottom openings or three effective means of closure when three effective means of closure are specified. If no bottom openings are authorized, the alternative portable tank must not have bottom openings. Start Printed Page 63408
(vii) When a hazardous material is not assigned a portable tank T Code or TP 9 is referenced in Column (7) of the § 172.101 Table, the hazardous material may only be transported in a portable tank if approved by the Associate Administrator.
(viii) Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the § 172.101 Table. The following is a list of the portable tank special provisions:
Code/Special Provisions
TP1 The maximum degree of filling must not exceed the degree of filling determined by the following (see Note 1 following TP3 for an explanation of the coefficients):
TP2 The maximum degree of filling must not exceed the degree of filling determined by the following (see Note 1 following TP3):
TP3 a. For liquids transported under elevated temperature, the maximum degree of filling is determined by the following:
Where: α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
Where: d15 and d50 are the densities of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.
TP4 The maximum degree of filling for portable tanks must not exceed 90%.
TP5 [Reserved.]
TP6 To prevent the tank from bursting in an event, including fire engulfment under the conditions prescribed in CGA pamphlet S-1.2 (see § 171.7 of this subchapter), it must be equipped with pressure relief devices that are adequate in relation to the capacity of the tank and the nature of the hazardous material transported.
TP7 The vapor space must be purged of air by nitrogen or other means.
TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flashpoint of the hazardous material transported is greater than 0 °C (32 °F).
TP9 A hazardous material assigned to special provision TP9 in Column (7) of the § 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator.
TP10 The portable tank must be fitted with a lead lining at least 5 mm (0.2 inches) thick. The lead lining must be tested annually to ensure that it is intact and functional. Another suitable lining material may be used if approved by the Associate Administrator.
TP12 This material is considered highly corrosive to steel.
TP13 Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.
TP16 The tank must be protected against over and under pressurization which may be experienced during transportation. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in subpart E, part 107 of this subchapter. The pressure relief device must be preceded by a frangible disk in accordance with the requirements of § 178.275(f)(3) of this subchapter to prevent crystallization of the product in the pressure relief device.
TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank.
TP18 The temperature of this material must be maintained between 18 °C (64.4 °F) and 40 °C (104 °F) while in transportation. Portable tanks containing solidified methacrylic acid must not be reheated during transportation.
TP19 The calculated wall thickness must be increased by 3 mm at the time of construction. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). The portable tank must not be used if the wall thickness is less than that prescribed by the applicable T code in Column (7) of the Table for this material.
TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket.
TP21 The wall thickness must not be less than 8 mm. Tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years.
TP22 Lubricants for portable tank fittings must be oxygen compatible.
TP24 The portable tank may be fitted with a device to prevent the build up of excess pressure due to the slow decomposition of the hazardous material being transported. The device must be in the vapor space when the tank is filled under maximum filling conditions. This device must also prevent an unacceptable amount of leakage of liquid in the case of overturning.
TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 °C (90.5 °F).
TP26 The heating device must be exterior to the shell. For UN 3176, this requirement only applies when the hazardous material reacts dangerously with water.
TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in § 178.275, where the test pressure is 1.5 times the MAWP.
TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.
TP29 A portable tank having a minimum test pressure of 1.5 bar (150.0 kPa) may be used provided the calculated test pressure is 1.5 bar or less based on the MAWP of the hazardous materials, as defined in § 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP.
TP30 This hazardous material may only be transported in insulated tanks.
TP31 This hazardous material may only be transported in tanks in the solid state.
TP37 IM portable tanks are only authorized for the shipment of hydrogen peroxide solutions in water containing 72% or less hydrogen peroxide by weight. Pressure relief devices shall be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure. In addition, the portable tank must be designed so that internal surfaces may be effectively cleaned and passivated. Each tank must be equipped with pressure relief devices conforming to the following requirements:
Concentration of hydrogen peroxide solution Total venting capacity in standard cubic feet per hour (S.C.F.H.) per pound of hydrogen peroxide solution 52% or less 11 Over 52%, but not greater than 60% 22 Over 60%, but not greater than 72% 32 TP38 Each tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 °C (60 °F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials may not promote corrosion to steel when wet.
TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of § 173.24b(b) of this Start Printed Page 63409subchapter. Thickness of stainless steel for tank shell and heads must be the greater of 7.62 mm (0.300 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.5 times the vapor pressure of the hazardous material at 46 °C (115 °F).
TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. Thickness of stainless steel for portable tank shells and heads must be the greater of 6.35 mm (0.250 inch) or the thickness required for a portable tank with a design pressure at least equal to 1.3 times the vapor pressure of the hazardous material at 46 °C (115 °F).
TP46 Portable tanks in sodium metal service are not required to be hydrostatically retested.
TP47 This hazardous material is not permitted for transport in IM portable tanks.
* * * * *(8) * * *
Code/Special Provisions
W7 Vessel stowage category for uranyl nitrate hexahydrate solution is “D” as defined in § 172.101(k)(4).
W8 Vessel stowage category for pyrophoric thorium metal or pyrophoric uranium metal is “D” as defined in § 172.101(k)(4).
W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: Woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings.
* * * * *13. In addition, in § 172.102, in paragraph (c)(3), Special Provisions B100, B101, B103, B104, B105, B106, B108, B109 and B110 would be removed.
14. In § 172.203, paragraph (d)(11) would be revised, new paragraphs (i)(5) and (i)(6) would be added, and paragraph (n) would be revised to read as follows:
Additional description requirements.* * * * *(d) * * *
(11) For a shipment of low specific activity material or surface contaminated objects, the appropriate group notation of LSA-I, LSA-II, LSA-III, SCO-I, or SCO-II, unless these symbols are contained in the proper shipping name.
* * * * *(i) * * *
(5) Minimum flashpoint if 61°C or below (in °C closed cup (c.c.).
(6) Subsidiary hazards not communicated in the proper shipping name.
* * * * *(n) Elevated temperature materials. If a liquid material in a package meets the definition of an elevated temperature material in § 171.8 of this subchapter, and the fact that it is an elevated temperature material is not disclosed in the proper shipping name (for example, when the words “Molten” or “Elevated temperature” are part of the proper shipping name), the word “HOT” must immediately precede the proper shipping name of the material on the shipping paper.
* * * * *15. In § 172.402, paragraph (b) would be revised to read as follows:
Additional labeling requirements.* * * * *(b) Display of hazard class on labels. The appropriate hazard class or division number must be displayed in the lower corner of a primary hazard label and a subsidiary hazard label. A subsidiary label meeting the specifications of this section which were in effect on [Date of publication of final rule] (such as, a label without the hazard class or division number displayed in the lower corner of the label) may continue to be used as a subsidiary label in domestic transportation by rail or highway until October 1, 2005, provided the color tolerances are maintained and are in accordance with the display requirements in this subchapter.
* * * * *[Amended]16. In § 172.405, the following changes would be made:
a. In paragraph (a) introductory text, the wording “subsidiary label when—” would be removed and “subsidiary label.” would be added in its place.
b. Paragraphs (a)(1) and (a)(2) would be removed.
17. In § 172.411, the section heading, the text of paragraph (c) preceding the labels, and paragraph (d) would be revised to read as follows:
EXPLOSIVE 1.1, 1.2, 1.3, 1.4, 1.5 and 1.6 labels.* * * * *(c) Except for size and color, the EXPLOSIVE 1.4, EXPLOSIVE 1.5 and EXPLOSIVE 1.6 labels must be as follows:
* * * * *(d) In addition to complying with § 172.407, the background color on the EXPLOSIVE 1.4, EXPLOSIVE 1.5, EXPLOSIVE 1.6 and EXPLOSIVE subsidiary label must be orange. The “*” shall be replaced with the appropriate compatibility group. The compatibility group letter must be shown as a capitalized Roman letter. Division numerals must measure at least 30 mm (1.2 inches) in height and at least 5 mm (0.2 inches) in width.
18. In addition, in § 172.411, in paragraph (c), the wording “EXPLOSIVE SUBSIDIARY LABEL:” and the label following it would be removed.
19. In § 172.504, in paragraph (g), a sentence would be added at the end of the existing text and paragraphs (g)(1) through (g)(4) would be added to read as follows:
General placarding requirements.* * * * *(g) * * * When more than one compatibility group placard is required for Class 1 materials, only one placard is required to be displayed as follows:
(1) Explosive articles of compatibility groups C, D or E may be placarded displaying compatibility group E.
(2) Explosive articles of compatibility groups C, D, E or N may be placarded displaying compatibility group D.
(3) Explosive substances of compatibility groups C and D may be placarded displaying compatibility group D.
(4) Explosive articles of compatibility groups C, D, E or G, except for fireworks, may be placarded displaying compatibility group E.
20. In § 172.519, paragraph (b)(4) would be revised to read as follows:
General specifications for placards.* * * * *(b) * * *
(4) For a placard corresponding to the primary or subsidiary hazard class of a material, the hazard class or division number must be displayed in the lower corner of the placard. A permanently affixed subsidiary placard meeting the specifications of this section which were in effect on [date of publication of final rule] (such as, a placard without the hazard class or division number displayed in the lower corner of the placard) and which was installed prior to October 1, 2001, may continue to be used as a subsidiary placard in domestic transportation by rail or highway, provided the color tolerances are maintained and are in accordance with the display requirements in this subchapter. Stocks of non-permanently affixed subsidiary placards in compliance with the requirements in effect on [date of publication of final rule], may continue to be used in domestic transportation by rail or highway until October 1, 2005, or until current stocks are depleted, whichever occurs first.
* * * * *PART 173—SHIPPERS—GENERAL REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS
21. The authority citation for part 173 would continue to read as follows:
22. In § 173.2a, in paragraph (b), in the Precedence of Hazard Table, in the first column, the first three entries would be amended by adding a footnote reference “2” immediately following “I”, “II”, and “III”, respectively, and in footnote 2 at the end of the table would be revised to read as follows:
Classification of a material having more than one hazard.* * * * *(b) * * *
Precedence of Hazard Table
2 Materials of Division 4.1 other than self-reactive substances and solid desensitized explosives, and materials of Class 3 other than liquid desensitized explosives. * * * * *23. In § 173.4, paragraph (a)(1) introductory text is revised to read as follows:
Small quantity exceptions.(a) * * *
(1) The maximum quantity of material per inner receptacle or article is limited to:
* * * * *24. In § 173.24b, paragraph (e) would be added to read as follows:
Additional general requirements for bulk packagings.* * * * *(e) Specification packagings and UN standard packagings manufactured outside the United States— (1) UN portable tanks. A UN portable tank manufactured in the United States must conform in all details to the applicable requirements in this part, the specification requirements in part 178 of this subchapter and the retest requirements in part 180 of this subchapter.
(2) UN portable tanks manufactured outside the United States. A UN portable tank manufactured outside the United States, in accordance with national or international regulations based on the UN Recommendations on the Transport of Dangerous Goods and is an authorized packaging, it may be filled, offered and transported in the United States, if the § 172.101 Table of this subchapter authorizes the hazardous material and it conforms to the applicable T code and tank provision codes assigned to the hazardous material in Column (7) of the Table. In addition, the portable tank must be in accordance with the following:
(i) Conform to applicable provisions in the UN Recommendations on the Transport of Dangerous Goods (Incorporated by reference, see § 171.7 of this subchapter) and the requirements of this subpart;
(ii) Be capable of passing the prescribed tests in part 178 of this subchapter applicable to the UN portable tank specification;
(iii) Be designed and manufactured according to the ASME Code (Incorporated by reference, see § 171.7 of this subchapter) or a pressure vessel design code approved by the Associate Administrator;
(iv) Be approved by the Associate Administrator when the portable tank is designed and constructed under the provisions of an alternative arrangement (see § 178.274(a)(2) of this subchapter); and
(v) When manufactured in a country other than the United States, the competent authority of the country of manufacture must provide reciprocal treatment for UN portable tanks manufactured in the United States.
25. Section 173.32 would be revised to read as follows:
Requirements for the use of portable tanks.(a) General requirements. No person may offer a hazardous material for transportation in a portable tank except as authorized by this subchapter.
(1) Except as otherwise provided in this subpart, a portable tank may not be used for the transportation of a hazardous material unless it meets the requirements of this subchapter.
(2) No person may fill and offer for transportation a portable tank when the prescribed periodic test or inspection under subpart G of part 180 of this subchapter has become due until the test or inspection has been successfully completed. This requirement does not apply to any portable tank filled prior to the test or inspection due date.
(3) When a portable tank is used as a cargo tank container, it shall conform to all the requirements prescribed for cargo tank containers. (See § 173.33.)
(b) Substitute packagings. A particular Specification portable tank may be substituted for another portable tank as follows:
(1) An IM or UN portable tank may be used whenever an IM or UN portable tank having less stringent requirements is authorized provided the portable tank meets or exceeds the requirements for pressure-relief devices, bottom outlets and any other special provisions specified in § 172.102(c)(7)(vi) of this subchapter.
(2) Where a Specification IM101 or IM102 portable tank is prescribed, a Specification 51 portable tank otherwise conforming to the special commodity requirements of § 172.102(c)(7) of this subchapter may be used.
(3) A DOT Specification 51 portable tank may be used whenever a DOT Specification 56, 57, or 60 portable tank is authorized. A DOT Specification 60 portable tank may be used whenever a DOT Specification 56 or 57 portable tank is authorized. A higher integrity tank used instead of a specified portable tank must meet the same design profile; for example, a DOT Specification 51 portable tank must be lined if used instead of a lined DOT Specification 60 portable tank.
(c) Grandfather provisions for portable tanks— (1) Continued use of specification 56 and 57 portable tanks. Continued use of an existing portable tank constructed to DOT Specification 56 or 57 is authorized only for a tank constructed before October 1, 1996. A stainless steel portable tank internally lined with polyethylene that was constructed on or before October 1, 1996, and that meets all requirements of DOT Specification 57 except for being equipped with a polypropylene discharge ball valve and polypropylene secondary discharge opening closure, may be marked as a Specification 57 portable tank and used in accordance with the provisions of this section.
(2) A DOT Specification 51 and IM 101 or IM 102 portable tank may not be manufactured after January 1, 2003 may continue to be used for the transportation of a hazardous material provided they fulfill the requirements of Start Printed Page 63411this subchapter, including the specification requirements and the requirements of this subchapter for the transportation of the particular hazardous material (see § 171.14(d)(5) of this subchapter), and provided it conforms to the periodic inspection and tests specified for the particular portable tank in subpart G of part 180 of this subchapter. On and after January 1, 2003, all newly manufactured portable tanks must conform to the requirements for the design, construction and approval of UN portable tanks as specified in §§ 178.273, 178.274, 178.275, 178.276 and 178.277 of this subchapter.
(3) A DOT Specification portable tank manufactured prior to January 1, 1992 that is equipped with a non-reclosable pressure relief device may continue in service for the hazardous materials for which it is authorized. Except for a DOT Specification 56 or 57 portable tank, a DOT Specification portable tank manufactured after January 1, 1992, used for materials meeting the definition for Division 6.1 liquids, Packing Group I or II, Class 2 gases, or Class 3 or 4 liquids, must be equipped with a re-closing pressure relief valve having adequately sized venting capacity.
(d) Maximum Allowable Working Pressure. (1) Prior to filling and offering a portable tank for transportation, the shipper must confirm that the portable tank conforms to the specification required for the hazardous material and that the maximum allowable working pressure (MAWP) of the portable tank is greater than or equal to the highest pressure obtained under the following conditions:
(i) For compressed gases and certain refrigerated liquids that are not cryogenic liquids and that are not transported in a UN portable tank, the pressure prescribed in § 173.315. For liquefied compressed gases transported in a UN portable tank, the pressures prescribed in T50 in § 172.102 of this subchapter.
(ii) For liquid hazardous materials the pressures specified in § 178.275(a) of this subchapter used for determining the MAWP.
(iii) The maximum pressure used to load or unload the hazardous material.
(2) Unless otherwise specified, where a portable tank is authorized, the minimum tank design pressure is 172 kPa (25 psig) for any Packing Group I or Packing Group II liquid hazardous material that meets more than one hazard class definition.
(e) External inspection prior to filling. Each portable tank must be given a complete external inspection. Any unsafe condition must be corrected prior to its being offered for transportation. The external inspection shall include a visual inspection of:
(1) The shell, piping, valves and other appurtenances for corroded areas, dents, defects in welds and other defects such as missing, damaged, or leaking gaskets;
(2) All flanged connections or blank flanges for missing or loose nuts and bolts;
(3) All emergency devices for corrosion, distortion, or any damage or defect that could prevent their normal operation;
(4) All required markings on the tank for legibility; and
(5) Any device for tightening manhole covers to ensure such devices are operative and adequate to prevent leakage at the manhole cover.
(f) Loading requirements. (1) A hazardous material may not be loaded in a portable tank if the part of the tank or any of its appurtenances having contact with the material during transportation would be damaged, would cause a dangerous reaction with the material or would compromise the ability of the portable tank to retain the hazardous material.
(2) A hazardous material may not be loaded in a portable tank unless it has pressure relief devices providing total relieving capacity meeting the requirements of this subchapter.
(3) Except during a hydrostatic test, a portable tank may not be subjected to a pressure greater than its maximum allowable working pressure.
(4) A portable tank may not be loaded to a gross weight greater than the maximum allowable gross weight specified on its identification plate.
(5) Except for a non-flowable solid or a liquid with a viscosity of 2,680 centistokes (millimeters squared per second) or greater at 20°C (68 °F), a portable tank or compartment thereof having a volume greater than 7,500 L (1,980 gallons) may not be loaded to a filling density of more than 20% and less than 80% by volume. This filling restriction does not apply if a portable tank is divided by partitions or surge plates into compartments of not more than 7,500 L (1,980) capacity. Portable tanks must not be offered for transportation in an ullage condition liable to produce an unacceptable hydraulic force due to surge.
(6) The outage for a portable tank may not be less than 2% at a temperature of 50 °C (122 °F). For UN portable tanks, the applicable maximum filling limits apply as specified according to the assigned TP codes in Column (7) of the § 172.101 Table of this subchapter except when transported domestically.
(7) Each tell-tale indicator for the space between a frangible disc and a safety relief valve mounted in series must be checked after the tank is filled and prior to transportation to ensure that the frangible disc is leak free. Any leakage through the frangible disc must be corrected prior to offering the tank for transportation. The tell-tale device must be designed to prevent the loss of any hazardous material through the device itself while the tank is in transportation.
(8) During filling, the temperature of the hazardous materials shall not exceed the limits of the design temperature range of the portable tank.
(9) The maximum mass of liquefied compressed gas per liter (gallon) of shell capacity (kg/L or lbs./gal.) may not exceed the density of the liquefied compressed gas at 50 °C (122 °F). The portable tank must not be liquid full at 60 °C (140 °F).
(g) Relief system. Any DOT Specification portable tank manufactured prior to January 1, 1992 that is equipped with a non-reclosable pressure relief device may continue in service for the hazardous materials for which it it is authorized. Except for DOT Specification 56 and 57 portable tanks, any DOT Specification portable tank manufactured after January 1, 1992 used for materials meeting the definition for Division 6.1 liquids Packing Group I or II, Class 2 gases, or Class 3 or 4 liquids must be equipped with a reclosing pressure relief valve having adequately sized venting capacity.
(h) Additional requirements for specific modal transport. In addition to other applicable requirements, the following apply:
(1) A portable tank containing a hazardous material may not be loaded on a highway or rail transport vehicle unless loaded entirely within the horizontal outline thereof, without overhang or projection of any part of the tank assembly. In addition, for unloading a portable tank, see § 177.834(h) of this subchapter.
(2) A portable tank used for the transportation of flammable liquids by rail may not be fitted with non-reclosing pressure relief devices except in series with reclosing pressure relief valves.
(3) A portable tank or Specification 106A or 110A multi-unit tank car containing a hazardous material may not be offered for transportation aboard a passenger vessel unless:
(i) The vessel is operating under a change to its character of vessel certification as defined in § 171.8 of this subchapter; and Start Printed Page 63412
(ii) The material is permitted to be transported aboard a passenger vessel in the § 172.101 Table of this subchapter.
(i) Additional general commodity specific requirements. In addition to other applicable requirements, the following requirements apply:
(1) Each uninsulated portable tank used for the transportation of liquefied compressed gases must have an exterior surface finish that is significantly reflective, such as a light-reflecting color if painted, or a bright reflective metal or other material if unpainted.
(2) If a hazardous material is being transported in a molten state, the portable tank must be thermally insulated with suitable insulation material of sufficient thickness that the overall thermal conductance is not more than 0.080 Btu per hour per square foot per degree Fahrenheit differential.
(j) Additional requirements for portable tanks other than IM specification and UN portable tanks. (1) The bursting strength of any piping and fittings must be at least four times the design pressure of the tank, and at least four times the pressure to which, in any instance, it may be subjected in service by the action of a pump or other device (not including safety relief valves) that may subject piping to pressures greater than the design pressure of the tank.
(2) Pipe joints must be threaded, welded or flanged. If threaded pipe is used, the pipe and pipe fittings must not be lighter than (Schedule 80) weight. Non-malleable metals must not be used in the construction of valves or fittings. Where copper tubing is permitted, joints must be brazed or be of equally strong metal union type. The melting point of brazing material may not be lower than 1,000 °F (537.8°C). The method of joining tubing must not decrease the strength of the tubing such as by the cutting of threads.
(3) Non-malleable metals may not be used in the construction of valves or fittings.
(4) Suitable provision must be made in every case to allow for expansion, contraction, jarring and vibration of all pipe. Slip joints may not be used for this purpose.
(5) Piping and fittings must be grouped in the smallest practicable space and must be protected from damage as required by the specification.
(6) All piping, valves and fittings on every portable tank must be leakage tested with gas or air after installation and proved tight at not less than the design pressure of the portable tank on which they are used. In the event of replacement, all such piping, valves, or fittings so replaced must be tested in accordance with the requirements of this section before the portable tank is returned to transportation service. The requirements of this section apply to all hoses used on portable tanks, except that hoses may be tested either before or after installation on the portable tank.
(7) All materials used in the construction of portable tanks and their appurtenances may not be subject to destructive attack by the contents of the tank.
(8) All parts of the portable tanks and appurtenances for anhydrous ammonia must be steel. No aluminum, copper, silver, zinc, nor their alloys may be used. Brazed joints may not be used.
(9) Each outlet of a portable tank used for the transportation of liquefied compressed gases, except carbon dioxide, must be provided with a suitable automatic excess-flow valve (see definition in § 178.337-1(g) of this subchapter). These valves must be located inside the portable tank or at a point outside the portable tank where the line enters or leaves the portable tank. The valve seat must be located inside the portable tank or may be located within a welded flange or its companion flange, or within a nozzle or within a coupling. The installation must be made in such a manner as to reasonably assure that any undue strain which causes failure requiring functioning of the valve shall cause failure in such a manner that it will not impair the operation of the valve.
(i) Safety device connections and liquid level gauging devices that are constructed so that the outward flow of tank contents willl not exceed that passed by an opening of 0.1397 cm (0.0550 inches) are not required to be equipped with excess-flow valves.
(ii) An excess-flow valve must close automatically if the flow reaches the rated flow of gas or liquid specified by the original valve manufacturer when piping mounted directly on the valve is sheared off before the first valve, pump, or fitting downstream from the excess flow valve.
(iii) An excess-flow valve may be designed with a by-pass, not to exceed a 0.1016 cm (0.040 inches) diameter opening to allow equalization of pressure.
(iv) Filling and discharge lines must be provided with manually operated shut-off valves located as close to the tank as practical. The use of “Stop-Check” valves to satisfy with one valve the requirements of this section is forbidden.
(10) Each portable tank used for carbon dioxide and nitrous oxide must be lagged with a suitable insulation material of such thickness that the overall thermal conductance is not more than 0.08 Btu per square foot per degree Fahrenheit differential in temperature per hour. The conductance must be determined at 60° Fahrenheit. Insulation material used on portable tanks for nitrous oxide must be noncombustible.
(11) A refrigerating and/or heating coil or coils must be installed in portable tanks used for carbon dioxide and nitrous oxide. Such coils must be tested externally to at least the same pressure as the test pressure of the portable tank. The coils must also be tested internally to at least twice the working pressure of the heating or refrigerating system to be used, but in no case less than the test pressure of the portable tank. Such coils must be securely anchored. The refrigerant or heating medium to be circulated through the coil or coils must be such as to cause no adverse chemical reaction with the portable tank or its contents in the event of leakage.
[Removed]28. § 173.32c would be removed.
29. In § 173.61, paragraph (e)(3) would be revised and a new paragraph (e)(8) would be added to read as follows:
Mixed packaging requirements.* * * * *(e) * * *
(3) Explosives of compatibility group S may be packaged together with explosives of all other compatibility groups except A and L, and the entire package shall be treated as belonging to any of the packaged compatibility groups except S.
* * * * *(8) Explosive articles of compatibility groups C, D, E and G, except for fireworks and articles requiring special packaging, may be packaged together and the entire package shall be treated as belonging to compatibility group E.
[Amended]30. In § 173.62, in paragraph (c), in the Explosives Packing Instructions Table, in the fourth column, the following changes would be made in appropriate packaging specification number order:
a. For packing instruction entries, 112(a), 112(b), 112(c), 113, 115, 116, 130, 131, 134, 135, 136, 138, 140, 141, 142 and 144, under the word “Drums”, the wording “plywood (1D)” would be added in the alpha-numeric order of the parenthetical. Start Printed Page 63413
b. For the packing instruction entries, 112(c), 113, 115, 134, 138 and 140, under the word “Drums”, the wording “plastics, removable head (1H2)” would be added in the alpha-numeric order of the parenthetical.
c. For the packing instruction entries, 134 and 138, under the word “Drums”, the wording “fiberboard (1G)” would be added in the alpha-numeric order of the parenthetical.
d. For the packing instruction entry, 144, under the wording “plastics, expanded (4H1)”, the word “Drums.” would be added and under the new word “Drums.”, the wording, “steel, removable head (1A2)”, “Aluminum, removable head (1B2)” and “plastics, removable head (1H2)” would be added in the alpha-numeric order of the parenthetical.
e. For the packing instruction entry, 144, under the word “Boxes”, the wording “plastics, solid (4H2)” would be added in the alpha-numeric order of the parenthetical.
f. For the packing instruction entries, 112(c) and 113, under the word “Boxes”, the wording “aluminum (4B)” would be added in the alpha-numeric order of the parenthetical.
31. In § 173.128, paragraph (d)(1)(ii) would be revised to read as follows:
Class 5, Division 5.2—Definitions and types.* * * * *(a) * * *
(1) * * *
(ii) A mixture of organic peroxides prepared according to § 173.225(c)(3); or
* * * * *32. In § 173.150, paragraph (d)(2) is revised to read as follows:
Exceptions for Class 3 (flammable) and combustible liquids.* * * * *(d) * * *
(2) Is in an inner packaging of five liters (1.3 gallons) or less, and is not transported as checked or carry-on baggage by passenger aircraft, except as provided in § 175.10(a)(17) of this subchapter; or
* * * * *33. In § 173.162, paragraph (a) introductory text and (a)(1) would be revised to read as follows:
Gallium.(a) Except when packaged in cylinders or steel flasks, gallium must be packaged in packagings which meet the requirements of part 178 of this subchapter at the Packing Group I performance level for transportation by aircraft, and at the Packing Group III performance level for transport by highway, rail or vessel, as follows:
(1) In combination packagings intended to contain liquids consisting of glass, earthenware or rigid plastic inner packagings with a maximum net mass of 15 kg (33 pounds) each. The inner packagings must be packed in wood boxes (4C1, 4C2, 4D, 4F), fiberboard boxes (4G), plastic boxes (4H1, 4H2), fiber drums (1G) or removable head steel and plastic drums or jerricans (1A2, 1H2, 3A2 or 3H2) with sufficient cushioning materials to prevent breakage. Either the inner packagings or the outer packagings must have inner liners or bags of strong leakproof and puncture-resistant material impervious to the contents and completely surrounding the contents to prevent it from escaping from the package, irrespective of its position.
* * * * *34. In § 173.185, a new sentence would be added at the end of paragraph (a), paragraphs (b) introductory text, (b)(1), (b)(2), (b)(5), (c)(1), (c)(2), and (c)(3) would be revised, and a heading would be added to paragraph (c) to read as follows:
Lithium batteries and cells.(a) * * * For the purposes of this subchapter, “lithium content” means the mass of lithium in the anode of a lithium metal or lithium alloy cell, except in the case of a lithium ion cell where the “equivalent lithium content” in grams is calculated to be 0.3 times the rated capacity in ampere-hours.
(b) Exceptions. Cells and batteries are not subject to the requirements of this subchapter if they meet the following requirements:
(1) Each cell with a liquid cathode may contain no more than 0.5 g of lithium content. Each cell with a solid cathode may contain no more than 1.0 g lithium content. Each lithium ion cell may contain no more than 1.5 g of equivalent lithium content;
(2) Each battery with a liquid cathode may contain an aggregate quantity of no more than 1.0 g lithium content. Each battery with a solid cathode may contain an aggregate quantity of no more than 2.0 g of lithium content. Each lithium-ion battery may contain an aggregate quantity of no more than 8.0 grams of equivalent lithium content;
* * * * *(5) If when fully charged, the aggregate lithium content of the anodes in a liquid cathode battery is more than 0.5 g, or the aggregate lithium content of the anodes in a solid cathode battery is more than 1.0 g, then the battery may not contain a liquid or gas that is a hazardous material according to this subchapter unless the liquid or gas, if free, would be completely absorbed or neutralized by other materials in the battery.
(c) Additional exceptions. * * *
(1) The lithium content of the anode of each cell, when fully charged, is not more than 5 g;
(2) The aggregate lithium content of the anodes of each battery, when fully charged, is not more than 25 g;
(3) Each cell or battery is of the type proven to be non-dangerous by testing in accordance with tests in the UN Manual of Tests and Criteria (incorporated by reference, see § 171.7 of this subchapter). Such testing must be carried out on each type of cell or battery prior to the initial transport of that type; and
* * * * *35. In § 173.224, paragraph (b)(4) would be revised; in the table following paragraph (b)(7), the following entry would be added in the appropriate alphabetical order; and paragraph (d) would be removed, to read as follows:
Packaging and control and emergency temperatures for self-reactive materials.* * * * *(b) * * *
(4) Packing method. Column 4 specifies the highest packing method which is authorized for the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in § 173.225(d) defines the packing methods. Bulk packagings are authorized as specified in § 173.225(d) for Type F self-reactive substances. Additional bulk packagings are authorized if approved by the Associate Administrator.
* * * * *(7) * * *Start Printed Page 63414
Self-Reactive Substances
Self-reactive substance Identification No. Concentration—(%) Packing method Control temperature—(°C) Emergency temperature Notes (1) (2) (3) (4) (5) (6) (7) * * * * * * * 2,2′-Azodi(isobutyronitrile) as a water based paste 3224 ≤50% OP6 * * * * * * * * * * * *36. In § 173.225, in paragraph (b), in the Organic Peroxide Table, the following entries would be removed and added in the appropriate alphabetical order; in Column (8), “7” and “10” would be removed each place they appear; and in the “NOTES” immediately following the Table, Notes “7” and “10” would be removed and reserved and Notes “26” and “27” would be added in the appropriate numerical order; and paragraphs (e) introductory text, (e)(3), and (e)(5) would be revised to read as follows:
Packaging requirements and other provisions for organic peroxides.* * * * *(b) * * *
Organic Peroxide Table
Technical name ID number Concentration (mass %) Diluent (mass %) Water (mass %) Packing method Temperature (°C) Note A B I Control Emergency (1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) * * * * * * * [REMOVE:] tert-Amyl peroxybenzoate UN3105 ≤96 ≥4 OP7 * * * * * * * tert-Butyl peroxy-2-ethylhexanoate UN3119 ≤32 ≥68 Bulk 10 15 14 * * * * * * * tert-Butyl peroxyneodecanoate [as a stable dispersion in water] UN3117 ≤42 OP8 0 10 * * * * * * * tert-Butyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 10 15 * * * * * * * tert-Butyl peroxypivalate UN3119 ≤27 ≥73 Bulk −5 5 14 * * * * * * * Cumyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 0 10 * * * * * * * Cyclohexanone peroxide(s) UN3105 ≤72 ≥28 OP7 5 * * * * * * * 1,1-Di-(tert-butylperoxy)-3,5,5- trimethylcyclohexane UN3101 >90-100 OP5 1,1-Di-(tert-butylperoxy)-3,5,5- trimethylcyclohexane UN3103 >57-90 ≥10 OP5 1,1-Di-(tert-butylperoxy)-3,5,5-trimethylcyclohexane UN3106 ≤57 ≥43 OP7. 1,1-Di-(tert-butylperoxy)-3,5,5-trimethylcyclohexane UN3107 ≤57 ≥43 OP8 1,1-Di-(tert-butylperoxy)-3,5,5-trimethylcyclohexane UN3107 ≤32 ≥26 ≥42 OP8 * * * * * * * Di-(2-ethylhexyl) peroxydicarbonate UN3115 ≤77 ≥23 OP7 −15 −5 * * * * * * * Diisopropyl peroxydicarbonate UN3115 ≤52 ≥48 OP7 −10 0 * * * * * * * 2,5-Dimethyl-2,5-di-(2-ethylhexanoylperoxy)hexane UN3115 ≤100 OP7 20 25 * * * * * * * Dimyristyl peroxydicarbonate [as a stable dispersion in water] UN3119 ≤42 IBC 15 25 10 * * * * * * * − Di-n-propyl peroxydicarbonate UN3113 ≤100 OP4 −25 −15 * * * * * * * Di-(3,5,5-trimethylhexanoyl) peroxide UN3119 ≤38 ≥62 Bulk −10 0 14 * * * * * * * Isopropyl sec-butyl peroxydicarbonate [and] Di-sec-butyl peroxy-dicarbonate [and] Di-isopropyl peroxydicarbonate UN3115 ≤32 +≤15-18 +≤12-15 ≥38 OP7 −20 −10 * * * * * * * 2,4,4-Trimethylpentyl-2-peroxyneodecanoate UN3115 ≤72 ≥28 OP7 −5 5 2,4,4-Trimethylpentyl-2-peroxyneodecanoate [as a stable dispersion in water]. UN3119 ≤52 OP8 −5 5 2,4,4-Trimethylpentyl-2-peroxy phenoxyacetate UN3115 ≤37 ≥63 OP7 −10 0 Start Printed Page 63415 [ADD:] tert-Amyl peroxybenzoate UN3103 ≤100 OP5 * * * * * * * tert-Butyl peroxy-2-ethylhexanoate UN3119 ≤32 ≥68 Bulk 15 20 14 * * * * * * * tert-Butyl peroxyneodecanoate [as a stable dispersion in water] UN3117 ≤52 OP8 0 10 * * * * * * * tert-Butyl peroxyneodecanoate [as a stable dispersion in water] UN3119 ≤42 IBC −5 5 10 * * * * * * * tert-Butyl peroxyneodecanoate UN3119 ≤32 ≥68 IBC 0 10 10 * * * * * * * tert-Butyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 0 10 * * * * * * * tert-Butyl peroxypivalate UN3119 ≤27 ≥73 Bulk 5 10 14 * * * * * * * Cumyl peroxyneodecanoate [as a stable dispersion in water] UN3119 ≤52 IBC −15 −5 * * * * * * * Cumyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 −10 0 * * * * * * * Cyclohexanone peroxide(s) UN3105 ≤72 ≥28 OP7 5 * * * * * * * 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3101 >90-100 OP5 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3103 >57-90 ≥10 OP5 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3105 ≤77 ≥23 OP7 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3106 ≤57 ≥43 OP7 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3107 ≤57 ≥43 OP8 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3107 ≤32 ≥26 ≥42 OP8 * * * * * * * 2,2-Di-(4,4-di-(tert-butylperoxy cyclohexyl) propane UN3107 ≤ 22 ≥78 OP8 * * * * * * * Di-(2-ethylhexyl) peroydicarbonate [as a stable dispersion in water] UN3119 ≤52 IBC −20 −10 * * * * * * * Di-(2-ethoxyethyl) peroxydicarbonate UN3115 ≤52 ≥48 OP7 −10 0 * * * * * * * Di-(2-ethylhexyl) peroxydicarbonate UN3115 ≤77 ≥23 OP7 −15 −5 * * * * * * * Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water] UN3117 ≤ 62 OP8 −15 −5 * * * * * * * Diisopropyl peroxydicarbonate UN3115 ≤52 ≥48 OP7 −20 −10 * * * * * * * Di-(3-methoxybutyl) peroxydicarbonate UN3115 ≤ 52 ≥48 OP7 −5 5 * * * * * * * Di-(3-methylbenzoyl) peroxide+Benzoyl (3-methylbenzoyl) peroxide+Dibenzoyl peroxide UN3115 ≤ 20+ ≤18+ ≤4 ≥58 OP7 35 40 * * * * * * * 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3108 ≤77 ≥23 OP8 * * * * * * * 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3101 >86-100 OP5 * * * * * * * Dimyristyl peroxydicarbonate [as a stable dispersion in water] UN3119 ≤42 IBC 15 20 10 * * * * * * * Di-n-propyl peroxydicarbonate UN3113 ≤100 OP3 −25 −15 * * * * * * * Di-n-propyl peroxydicarbonate UN3113 ≤77 ≥23 OP5 −20 −10 * * * * * * * tert-Hexyl peroxyneodecanoate UN3115 ≤71 ≥29 OP7 0 10 * * * * * * * tert-Hexyl peroxypivalate UN3115 ≤72 ≥28 OP7 10 15 * * * * * * * Methyl ethyl ketone peroxide(s) UN3105 ≤37 ≥55 ≥8 OP7 26 Start Printed Page 63416 * * * * * * * 1,1,3,3-Tetramethylbutyl peroxyneodecanoate UN3115 ≤72 ≥28 OP7 −5 5 1,1,3,3-Tetramethylbutyl peroxyneodecanoate [as a stable dispersion in water] UN3119 ≤52 IBC −5 −5 −10 1,1,3,3-Tetramethylbutyl peroxy phenoxyacetate UN3115 ≤37 ≥63 OP7 −10 0 * * * * * * * 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane UN3105 ≤42 ≥58 OP7 27 * * * * * * * Notes:
* * * * *26. Available oxygen must be ≤ 10%.
27. Available oxygen must be ≤ 7.6%.
* * * * *(e) Bulk packagings for organic peroxides. The following bulk packagings are authorized:
* * * * *(3) Portable tanks. The following requirements apply to portable tanks intended for the transport of Type F organic peroxides or Type F self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of T23 (see § 172.102(c)(7) of this subchapter), when T23 is specified in Column (7) of the § 171.101 Table of this subchapter for the Type F organic peroxide or Type F self-reactive substance. Type F organic peroxide or self-reactive substance formulations other than those indicated in T23 may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply:
(i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4 bar).
(ii) Portable tanks must be fitted with temperature-sensing devices.
(iii) Portable tanks must be fitted with pressure relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell.
(iv) The pressure relief devices must consist of reclosing devices fitted to prevent significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 °C (122 °F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The start-to-discharge pressure must in no case be such that liquid would escape from the pressure relief devices if the portable tank were overturned.
(v)(A) The emergency-relief devices may be of the reclosing or frangible types, or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula:
Where:
q = heat absorption (W)
A = wetted area (m2)
(B) Insulation factor (F) in the formula in paragraph (e)(3)(v)(A) of this section equals 1 for non-insulated vessels and for insulated vessels F is calculated using the following formula:
Where:
U = K/L = heat transfer coefficient of the insulation (W·m−2·K−1); where K = heat conductivity of insulation layer (W·m−1·K−1), and L = thickness of insulation layer (m).
TPO = temperature of material at relieving conditions (K).
(vi) The start-to-discharge pressure of emergency-relief devices must be higher than that specified for the pressure relief devices in paragraph (e)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank.
Note to Paragraph (e)(3)(vi):
An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (incorporated by reference, see § 171.7 of this subchapter).
(vii) For insulated portable tanks, the capacity and setting of emergency-relief devices must be determined assuming a loss of insulation from 1 percent of the surface area.
(ix) Vacuum-relief devices and reclosing devices on portable tanks used for flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided.
(x) Service equipment such as devices and external piping must be designed and constructed so that no hazardous material remains in them after filling the portable tank.
(xi) Portable tanks may be either insulated or protected by a sun-shield. If the SADT of the hazardous material in the portable tank is 55 °C (131 °F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal.
(xii) The degree of filling must not exceed 90% at 15 °C (59 °F).
(xiii) DOT 57 metal portable tanks are authorized only for tert-butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s), dicumyl peroxide and mixtures of two or more of these peroxides.
* * * * *(5) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to IB52 (see 172.102(c)(4) of this subchapter), as applicable, and the IBC conforms to the requirements in part 178 of this subchapter at the Packing Group II performance level. The following additional requirements also apply:
(i) IBCs shall be provided with a device to allow venting during transportation. The inlet to the pressure Start Printed Page 63417relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation.
(ii) To prevent explosive rupture of metal IBCs or composite IBCs with complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (e)(3)(v) of this section. The control and emergency temperatures specified in IB52 are based on a non-insulated IBC.
37. In § 173.240, paragraphs (c) and (d) would be revised to read as follows:
Bulk packagings for certain low hazard solid materials.* * * * *(c) Portable tanks and closed bulk bins. DOT 51, 56, 57 and 60 portable tanks; IMO type 1, 2 and 5, and IM 101 and IM 102 portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and sift-proof non-DOT Specification portable tanks and closed bulk bins are authorized.
(d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the § 172.101 Table of this subchapter for the material being transported.
(1) IBCs may not be used for the following hazardous materials:
(i) Packing Group I liquids; and
(ii) Packing Group I solids that may become liquid during transportation.
(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation:
(i) Wooden: 11C, 11D and 11;
(ii) Fiberboard: 11G;
(iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and
(iv) Composite: 11HZ2 and 21HZ2.
38. In § 173.241, paragraphs (c) and (d) would be revised to read as follows:
Bulk packagings for certain low hazard liquid and solid materials.* * * * *(c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; IMO type 1, 2 and 5, and IM 101 and IM 102 portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; and non-DOT Specification portable tanks suitable for transport of liquids are authorized.
(d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the § 172.101 Table for the material being transported.
(1) IBCs may not be used for the following hazardous materials:
(i) Packing Group I liquids; and
(ii) Packing Group I solids that may become liquid during transportation.
(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation:
(i) Wooden: 11C, 11D and 11F;
(ii) Fiberboard: 11G;
(iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and
(iv) Composite: 11HZ2 and 21HZ2.
39. In § 173.242, paragraphs (c) introductory text and (d) would be revised to read as follows:
Bulk packagings for certain medium hazard liquids and solids, including solids with dual hazards.* * * * *(c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; Specification IM and UN portable tanks when a T Code is specified in Column (7) of the § 172.101 Hazardous Materials Table for a specific hazardous material; and marine portable tanks conforming to 46 CFR part 64 are authorized. DOT Specification 57 portable tanks used for the transport by vessel of Class 3, Packaging Group II materials must conform to the following:
* * * * *(d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the § 172.101 Table of this subchapter for the material being transported.
(1) IBCs may not be used for the following hazardous materials:
(i) Packing Group I liquids; and
(ii) Packing Group I solids that may become liquid during transportation.
(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation:
(i) Wooden: 11C, 11D and 11F;
(ii) Fiberboard: 11G;
(iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2; and
(iv) Composite: 11HZ2 and 21HZ2.
* * * * *40. In § 173.243, paragraphs (c) and (d) would be revised to read as follows:
Bulk packaging for certain high hazard liquids and dual hazard materials which pose a moderate hazard.* * * * *(c) Portable tanks. DOT Specification 51 and 60 portable tanks; UN portable tanks when a T code is specified in Column (7) of the § 172.101 Table of this subchapter for a specific hazardous material; and marine portable tanks conforming to 46 CFR part 64 with design pressure of at least 172.4 kPa (25 psig) are authorized.
(d) IBCs. IBCs are authorized subject to the conditions and limitations of this section provided the IBC type is authorized according to the IBC packaging code specified for the specific hazardous material in Column (7) of the § 172.101 Table of this subchapter and the IBC conforms to the requirements in part 178 of this subchapter at the Packing Group performance level as specified in Column (5) of the § 172.101 Table of this subchapter for the material being transported.
(1) IBCs may not be used for the following hazardous materials:
(i) Packing Group I liquids; and
(ii) Packing Group I solids that may become liquid during transportation.
(2) The following IBCs may not be used for Packing Group II and III solids that may become liquid during transportation:
(i) Wooden: 11C, 11D and 11F;
(ii) Fiberboard: 11G;
(iii) Flexible: 13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 and 13M2, and
(iv) Composite: 11HZ2 and 21HZ2.
* * * * *41. In § 173.247, paragraph (c) would be revised to read as follows:
Bulk packaging for certain elevated temperature materials (Class 9) and certain flammable elevated temperature materials (Class 3).* * * * *(c) Portable tanks. DOT Specification 51, 56, 57 and 60 portable tanks; IM 101, 102 portable tanks; UN portable tanks; marine portable tanks conforming to 46 CFR part 64; metal IBCs and non-Start Printed Page 63418specification portable tanks equivalent in structural design and accident damage resistance to specification packagings are authorized.
* * * * *42. In § 173.306, paragraph (a)(4)(iii) would be revised to read as follows:
Limited quantities of compressed gases.(a) * * *
(4) * * *
(iii) Non-pressurized gases, flammable must be packed in hermetically-sealed glass or metal inner packagings of not more than 5 L (1.3 gallons) overpacked in a strong outer packaging.
* * * * *43. In § 173.315, the text of paragraph (a) preceding the table and paragraphs (i)(1)((iii), (i)(3), (i)(4) and (i)(8) would be revised and paragraph (i)(7) would be removed and reserved to read as follows:
Compressed gases in cargo tanks and portable tanks.(a) Liquefied compressed gases that are transported in UN portable tanks must be loaded and offered for transportation in accordance with tank provision T50 in § 172.102 of this subchapter. A liquefied compressed gas offered for transportation in a cargo tank motor vehicle or a portable tank must be prepared in accordance with this section, § 173.32, § 173.33 and subpart E or subpart G of part 180 of this subchapter; for cryogenic liquids, also see § 173.326 and § 173.328. Except for UN portable tanks, a liquefied compressed gas must be loaded and offered for transportation in accordance with the following table:
* * * * *(i) * * *
(1) * * *
(iii) For an insulated tank, the required relieving capacity of the relief valves must be the same as for an uninsulated tank, unless the insulation will remain in place and will be effective under fire conditions. In this case, except for UN portable tanks, each insulated tank must be covered by a sheet metal jacket of not less than 16 gauge thickness. For UN portable tanks where the relieving capacity of the valves has been reduced on the basis of the insulation system, the insulation system must remain effective at all temperatures less than 649 °C (1200.2 °F) and be jacketed with a material having a melting point of 700 °C (1292.0 °F) or greater.
* * * * *(3) Each safety relief valve on a portable tank, other than a UN portable tank, must be set to start-to-discharge at pressure no higher than 110% of the tank design pressure and no lower than the design pressure specified in paragraph (a) of this section for the gas transported. For UN portable tanks used for liquefied compressed gases and constructed in accordance with the requirements of § 178.276 of this subchapter, the pressure relief device(s) must conform to § 178.276(e) of this subchapter.
(4) Except for UN portable tanks, each safety relief valve must be plainly and permanently marked with the pressure in p.s.i.g. at which it is set to discharge, with the actual rate of discharge of the device in cubic feet per minute of the gas or of air at 60 °F (15.6 °C) and 14.7 p.s.i.a., and with the manufacturer's name or trade name and catalog number. The start-to-discharge valve must be visible after the valve is installed. The rated discharge capacity of the device must be determined at a pressure of 120% of the design pressure of the tank. For UN portable tanks, each pressure relief device must be clearly and permanently marked as specified in § 178.274(f)(1) of this subchapter.
* * * * *(8) Each safety relief valve outlet must be provided with a protective device to prevent the entrance and accumulation of dirt and water. This device must not impede flow through the valve. Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure.
* * * * *PART 175—CARRIAGE BY AIRCRAFT
44. The authority citation for Part 175 would continue to read as follows:
45. In § 175.10, paragraphs (a)(10) and (a)(16) would be revised, and paragraph (a)(17) would be added to read as follows:
Exceptions.(a) * * *
(10) Safety matches or a lighter intended for use by an individual when carried on one's person. However, lighters containing unabsorbed liquid fuel (other than liquefied gas), lighter fuel, and lighter refills are not permitted on one's person or in checked or carry-on baggage.
* * * * *(16) Perfumes and colognes, purchased through duty-free sales, carried by passengers or crew in carry-on baggage.
(17) Alcoholic beverages containing—
(i) Not more than 24% alcohol by volume; or
(ii) More than 24% and not more than 70% alcohol by volume when in retail packagings not exceeding 5 liters (1.3 gallons) carried by a crewmember or passenger in checked or carry-on baggage, with a total net quantity per person of 5 liters (1.3 gallons) for such beverages.
* * * * *46. In § 175.33, paragraph (a) introductory text would be revised to read as follows:
Notification of pilot-in-command.(a) Except as provided in § 175.10, when a hazardous material subject to the provisions of this subchapter is carried in an aircraft, the operator of the aircraft must provide the pilot-in-command with accurate and legible written information as early as practicable before departure of the aircraft, which specifies at least the following:
* * * * *47. Section 175.78 would be revised to read as follows:
Stowage compatibility of cargo.(a) For stowage on an aircraft, in a cargo facility, or in any other area at an airport designated for the stowage of hazardous materials, packages containing hazardous materials which might react dangerously with one another may not be placed next to each other or in a position that would allow a dangerous interaction in the event of leakage.
(b) As a minimum, the segregation instructions prescribed in the following Segregation Table must be followed to maintain acceptable segregation between packages containing hazardous materials with different hazards. The Segregation Table instructions in paragraph (c) of this section apply whether or not the class or division is the primary or subsidiary risk. The Segregation Table follows:Start Printed Page 63419
Segregation Table
Hazard label Class or division 1 2 3 4.2 4.3 5.1 5.2 8 1 Note 1 Note 2 Note 2 Note 2 Note 2 Note 2 Note 2 Note 2 1 Note 2 2 Note 2 3 Note 2 X 4.2 Note 2 X 4.3 Note 2 X X 5.1 Note 2 X X 5.2 Note 2 8 Note 2 X (c) Instructions for using the Segregation Table are as follows:
(1) The dots at the intersection of a row and column indicate that no restrictions apply.
(2) The letter “X” at the intersection of a row and column indicates that packages containing these classes of hazardous materials may not be stowed next to or in contact with each other, or in a position which would allow interaction in the event of leakage of the contents.
(3) Note 1. “Note 1” at the intersection of a row and column means the following:
(i) For explosives in compatibility groups A through K and N—
(A) Packages bearing the same compatibility group letter and the same division number may be stowed together.
(B) Explosives of the same compatibility group, but different divisions may be stowed together provided the whole shipment is treated as belonging to the division having the smaller number. However, when explosives of Division 1.5 Compatibility Group D are stowed together with explosives of Division 1.2 Compatibility Group D, the whole shipment must be treated as Division 1.1, Compatibility Group D.
(C) Packages bearing different compatibility group letters may not be stowed , whether or not they belong to the same division, except as provided in paragraphs (c)(3)(ii) and (iii) of this section.
(ii) Explosives in Compatibility Group L may not be stowed with explosives in other compatibility groups. They may only be stowed with the same type of explosives in Compatibility Group L.
(iii) Explosives of Division 1.4, Compatibility Group S, may be stowed with explosives of all compatibility groups except for Compatibility Groups A and L.
(iv) Other than explosives of Division 1.4, Compatibility Group S (see paragraph (c)(3)(iii) of this section), and Compatibility Groups C, D and E that may be stowed together, explosives that do not belong in the same compatibility group may not be stowed together.
(A) Any combination of substances in Compatibility Groups C and D must be assigned to the most appropriate compatibility group shown in the § 172.101 Hazardous Materials Table.
(B) Explosives in Compatibility Group N may be stowed together with explosives in Compatibility Groups C, D and E when the combination is assigned Compatibility Group D.
(4) Note 2. “Note 2” at the intersection of a row and column means that other than explosives of Division 1.4, Compatibility Group S, explosives may not be stowed together with that class.
(5) Packages containing hazardous materials with multiple hazards in the class or divisions, which require segregation in accordance with the Segregation Table need not be segregated from other packages bearing the same UN number.
(6) A package labeled “BLASTING AGENT” may not be stowed next to or in a position that will allow contact with a package of special fireworks or railway torpedoes.
48. In § 175.85 paragraph (a) would be revised to read as follows:
Cargo location.(a) Except as provided in § 175.10, no person may carry a hazardous material subject to the requirements of this subchapter in the cabin of a passenger-carrying aircraft or on the flight deck of any aircraft. Hazardous materials may be carried in a main deck cargo compartment of a passenger aircraft provided that the compartment is inaccessible to passengers and that it meets all certification requirements for a Class B aircraft cargo compartment in 14 CFR 25.857(b) or for a Class C aircraft cargo compartment in 14 CFR 25.857(c).
* * * * *PART 176—CARRIAGE BY VESSEL
49. The authority citation for part 176 would continue to read as follows:
50. In § 176.2, the following definition would be added in appropriate alphabetical order to read as follows:
Definitions.* * * * *INF cargo means packaged irradiated nuclear fuel, plutonium or high-level radioactive wastes as those terms are defined in the “International Code for the Safe Carriage of Packaged Irradiated Nuclear Fuel, Plutonium and High-Level Radioactive Wastes on Board Ships” (incorporated by reference, see § 171.7 of this subchapter).
* * * * *51. In § 176.63, a new paragraph (e) would be added to read as follows:
Stowage locations.* * * * *(e) Closed cargo transport unit, for the purpose of stowage of Class 1 (explosive) materials on board a vessel, means a clean, substantial, weatherproof box structure which can be secured to the ship's structure and includes a closed freight container, a closed vehicle, a closed rail wagon or a portable magazine. When this stowage is specified, stowage in small compartments such as deckhouses and mast lockers or oversized weatherproof packages (overpacks) are acceptable alternatives. The floor of any closed cargo transport unit or compartment shall be constructed of wood, close boarded or arranged so that goods are stowed on sparred gratings, wooden pallets or dunnage. Provided that the necessary additional specifications are met, a closed cargo transport unit may be used for Class 1 (explosive) magazine stowage type “A,” “B” or “C,” but not as a portable magazine.
52. In § 176.84, in paragraph (b) Table of provisions, the entries “4” and “5” Start Printed Page 63420would be revised, paragraph (c)(1) would be revised, in paragraph (c)(2), the List of Notes would be revised and paragraph (c)(3) would be removed to read as follows:
Other requirements for stowage and segregation for cargo vessels and passenger vessels.* * * * *(b) Table of provisions:
Code Provisions * * * * * 4 Stow “Separated from” liquid organic materials. 5 Stow “Separated from” powdered metals and their compounds. * * * * * (c) * * *
(1) Explosive substances and explosive articles must be stowed in accordance with Column (10A) and Columm (10B) of the § 172.101 Table of this subchapter.
Notes Provisions 5E Stow “away from” lead and its compounds. 7E Stowage category “04” for projectiles or cartridges for guns, cannons or mortars; Stowage category “08” for other types. 8E When under deck, special stowage is required. 14E On deck, cargo transport unit must be steel. 15E On deck, cargo transport unit must be leakproof. 17E On deck stowage is recommended. 19E Substances which contain ammonium nitrate or other ammonium salts must be stowed “away from” Explosive, blasting, type C, UN0083. 20E Stowage category “03” for projectiles or cartridges for guns, cannons or mortars; Stowage category “07” for other types; magazines must be of steel construction that prevents leakage. 21E Cargo space ventilation must be carefully controlled to avoid excessive condensation. 22E May not be stowed together with explosive substances containing ammonium nitrate or other ammonium salts. Segregate from other Class 1 (explosive) materials in the same manner as is required for flammable liquids. 23E Stowage category “13” and, for on deck stowage, non-metallic lining of closed cargo transport unit is required when not in effectively sealed, sift-proof packages; Stowage category “10” permitted when in effectively sealed, sift-proof packages. 26E For closed cargo transport unit, a non-metallic lining is required. 27E Stow away from alkaline compounds. [Amended]53. In § 176.128, in paragraph (c), the word “UN 0600” would be revised to read “UN 0060”.
[Amended]54. In § 176.136, in paragraph (e), the word “portable” would be removed.
55. In § 176.142, paragraph (a) would be revised to read as follows:
Hazardous materials of extreme flammability.(a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials:
Carbon disulfide: UN1131, Class 3
Diethylzinc: UN1366, Division 4.2
Dimethylzinc: UN1370, Division 4.2
Magnesium alkyls: UN3053, Division 4.2
Methyl phosphorous dichloride: NA2845, Division 6.1
Nickel carbonyl: UN1259, Division 6.1
Pyrophoric liquid, inorganic, n.o.s.: UN3194, Division 4.2
Pyrophoric liquids, organic, n.o.s.: UN2845, Division 4.2
Pyrophoric organometallic compound, water-reactive, n.o.s.: UN3203, Division 4.2
* * * * *56. A new section § 176.720 would be added to subpart M to read as follows:
Requirements for carriage of INF cargo in international transportation.(a) A vessel carrying INF cargo in international transportation must meet the requirements of the INF Code (incorporated by reference, see § 171.7 of this subchapter) in addition to all other applicable requirements of this subchapter.
PART 177—CARRIAGE BY PUBLIC HIGHWAY
57. The authority citation for part 177 would continue to read as follows:
58. In § 177.848, paragraph (g)(3)(vi) would be revised to read as follows:
Segregation of hazardous materials.* * * * *(g) * * *
(3) * * *
(vi) “6” means explosive articles in compatibility group G, other than fireworks and those requiring special handling, may be loaded, transported and stored with articles of compatibility groups C, D and E, provided no explosive substances are carried in the same vehicle.
* * * * *PART 178—SPECIFICATIONS FOR PACKAGINGS
59. The authority citation for part 178 would continue to read as follows:
60. A new section § 178.273 would be added to subpart H to read as follows:
Approval of Specification IM portable tanks and UN portable tanks.(a) Application for approval. (1) An owner or manufacturer of a portable tank shall apply for approval to a designated approval agency authorized to approve the portable tank in accordance with the procedures in subpart E, part 107 of this subchapter.
(2) Each application for approval must contain the following information:
(i) Three complete copies of all engineering drawings, calculations, and Start Printed Page 63421test data necessary to ensure that the design meets the relevant specification.
(ii) The manufacturer's serial number that will be assigned to each portable tank.
(iii) A statement as to whether the design type has been examined by any approval agency previously and judged unacceptable. Affirmative statements must be documented with the name of the approval agency, reason for nonacceptance, and the nature of modifications made to the design type.
(b) Action by approval agency. The approval agency shall perform the following activities:
(1) Review the application for approval to determine whether it is complete and conforms with the requirements of paragraph (a) of this section. If an application is incomplete, it will be returned to the applicant and the applicant will be informed in what respects the application is incomplete.
(2) Review all drawings and calculations to ensure that the design is in compliance with all requirements of the relevant specification. If the application is approved, one set of the approved drawings, calculations, and test data shall be returned to the applicant. The second and third (inspector's copy) sets of approved drawings, calculations, and test data shall be retained by the approval agency. Maintain drawings and approval records for as long as the portable tank remains in service. The drawings and records must be provided to DOT upon request.
(3) Witness all tests required for the approval of the portable tank specified in § 178.273 and part 180, subpart G, of this subchapter.
(4) Ensure, through appropriate inspection that each portable tank is fabricated in all respects in conformance with the approved drawings, calculations, and test data.
(5) Determine and ensure that the portable tank is suitable for its intended use and that it conforms to the requirements of this subchapter.
(6) For UN portable tanks intended for liquefied compressed gases and Division 6.1 liquids which meet the inhalation toxicity criteria (Zone A or B) as defined in § 173.132 of this subchapter, or that are designated as toxic by inhalation materials in the § 172.101 Table of this subchapter, the approval agency must ensure that:
(i) The portable tank has been constructed in accordance with the ASME Code, Section VIII, Division 1 (incorporated by reference, see § 171.7 of this subchapter). ASME Code, Section VIII, Division II or other design code may be used if approved by the Associate Administrator (see § 178.274(b)(1));
(ii) All applicable provisions of the design and construction have been met to the satisfaction of the designated approval agency in accordance with the rules established in the ASME Code and that the portable tank meets the requirements of the ASME Code or other design code if approved by the Associate Administrator (see § 178.274(b)(1)), and all the applicable requirements specified in this subchapter;
(iii) The authorized inspector has carried out all the inspections specified by the rules established in the ASME Code; and
(iv) The portable tank is marked with a U stamp code symbol under the authority of an authorized independent inspector.
(7) For UN portable tanks the approval certificate must also include the following:
(i) The results of the applicable framework and rail impact test specified in part 180, subpart G, of this subchapter; and
(ii) The results of the initial inspection and test in § 180.605 of this subchapter.
(8) Upon successful completion of all requirements of this subpart, the approval agency shall:
(i) Apply its name, identifying mark or identifying number, and the date upon which the approval was issued, to the metal identification marking plate attached to the portable tank. Any approvals for UN portable tanks authorizing design or construction alternatives (Alternate Arrangements) approved by the Associate Administrator (see § 178.274(a)(2)) must be indicated on the plate as specified in § 178.274(i).
(ii) Issue an approval certificate for each portable tank or, in the case of a series of identical portable tanks manufactured to a single design type, for each series of portable tanks. The approval certificate must include all the information required to be displayed on the required metal identification plate required by § 178.270-14 for IM portable tanks, § 178.245-6 for specification 51 steel portable tanks, or § 178.274(i) for UN portable tanks. The approval certificate must attest that the approval agency designated to approve the portable tank has approved the portable tank in accordance with the procedures in subpart E, part 107 of this subchapter and that the portable tank is suitable for its intended purpose and meets the requirements of this subchapter. When a series of portable tanks is manufactured without change in the design type, the certificate may be valid for the entire series of portable tanks representing a single design type. For UN portable tanks, the certificate must refer to the prototype test report, the hazardous materials or group of hazardous materials allowed to be transported, the materials of construction of the shell and lining (when applicable) and an approval number. The approval number must consist of the distinguishing sign or mark of the country (“USA” for the United States of America) where the approval was granted and a registration number.
(iii) Retain a copy of each approval certificate.
(9) The approval agency must remain independent from the manufacturer. The approval agency and the authorized inspector may be the same entity.
(c) Manufacturers' responsibilities. The manufacturer is responsible for compliance with the applicable specifications for the design and construction of portable tanks. In addition to responsibility for compliance, manufacturers are responsible for ensuring that the contracted approval agency and authorized inspector, if applicable, are qualified, reputable and competent. The manufacturer of a portable tank must:
(1) Comply with all the applicable requirements of the ASME Code (incorporated by reference, see § 171.7 of this subchapter) and of this subpart including, but not limited to, ensuring that the quality control, design calculations and required tests are performed and that all aspects of the portable tank meet the applicable requirements.
(2) Obtain and use a designated approval agency, if applicable, and obtain and use a DOT-designated approval agency to approve the design, construction and certification of the portable tank.
(3) Provide a statement in the manufacturers' data report attesting that each portable tank that is manufactured complies with the relevant specification and all the applicable requirements of this subchapter.
(4) Maintain records of the qualification of portable tanks for at least 5 years and provide copies to the approval agency and the owner of the tank. Provide records to the U.S. DOT upon request.
(d) Denial of application for approval. If an approval agency finds that a portable tank cannot be approved for any reason, it shall so notify the applicant in writing and shall provide the applicant with the reasons for which the approval is denied. A copy of the Start Printed Page 63422notification letter shall be provided to the Associate Administrator. An applicant aggrieved by a decision of an approval agency may appeal the decision in writing within 90 days of receipt to the Associate Administrator.
(e) Modifications to approved portable tanks. (1) Prior to modification of any approved portable tank which may affect conformance of an IM or UN portable tank, which may involve a change to the design type or which may affect its ability to retain the hazardous material in transportation, the person desiring to make such modification shall inform the approval agency that issued the initial approval of the portable tank (or if unavailable another approval agency) of the nature of the modification and request approval of the modification. The owner or manufacturer shall supply the approval agency with three sets of all revised drawings, calculations, and test data relative to the intended modification.
(2) A statement as to whether the intended modification has been examined by any approval agency previously judged unacceptable. An affirmative statement must be documented with the name of the approving agency, the reason for nonacceptance, and the nature of changes made to the modification since its original rejection.
(3) The approval agency shall review the request for modification, and if it is determined that the proposed modification is in full compliance with the relevant DOT specification, including a UN portable tank, the request shall be approved and the approval agency shall perform the following activities:
(i) Return one set of the approved revised drawings, calculations, and test data to the applicant. The second and third sets of the approved revised drawings, calculations, and data shall be retained by the approval agency as required in § 107.404(a)(3) of this subchapter.
(ii) Ensure through appropriate inspection that all modifications conform to the revised drawings, calculations, and test data.
(iii) Determine the extent to which retesting of the modified tank is necessary based on the nature of the proposed modification, and ensure that all required retests are satisfactorily performed.
(iv) If modification to an approved tank alters any information on the approval certificate, issue a new approval certificate for the modified tank and ensure that any necessary changes are made to the metal identification plate. A copy of each newly issued approval certificate shall be retained by the approval agency and by the owner of each portable tank.
(4) If it determined that the proposed modification is not in compliance with the relevant DOT specification, the request shall be denied. The procedures of paragraph (d) of this section apply to such denial.
(f) Termination of Approval Certificate. (1) The Associate Administrator may terminate an approval issued under this section if he determines that:
(i) Information upon which the approval was based is fraudulent or substantially erroneous; or
(ii) Termination of the approval is necessary to adequately protect against risks to life and property; or
(iii) The approval was not issued by the approval agency in good faith; or
(iv) That the portable tank does not meet the specification.
(2) Before an approval is withdrawn, the Associate Administrator gives the interested party(ies):
(i) Written notice of the facts or conduct believed to warrant the withdrawal;
(ii) Opportunity to submit oral and written evidence; and
(iii) Opportunity to demonstrate or achieve compliance with the application requirement.
(3) If the Associate Administrator determines that a certificate of approval must be withdrawn to preclude a significant and imminent adverse affect on public safety, he shall withdraw the certificate of approval issued by a designated approval agency. In such circumstances, the procedures of paragraphs (f)(2) (ii) and (iii) of this section need not be provided prior to withdrawal of the approval, but shall be provided as soon as practicable thereafter.
61. Section 178.274 would be added to subpart H to read as follows:
Specifications for UN portable tanks.(a) General. (1) Each UN portable tank must meet the requirements of this section. In addition to the requirements of this section, requirements specific to UN portable tanks used for liquid and solid hazardous materials, liquefied compressed gases and refrigerated liquefied gases are provided in §§ 178.275, 178.276 and 178.277, respectively. Requirements for approval, maintenance, inspection, testing and use are provided in § 178.273 and part 180, subpart G, of this subchapter. Any portable tank which meets the definition of a “container” within the terms of the International Convention for Safe Containers (CSC) must meet the requirements of the CSC as amended and 49 CFR parts 450 through 453 and must have a CSC safety approval plate.
(2) In recognition of scientific and technological advances, the technical requirements applicable to UN portable tanks may be varied if approved by the Associate Administrator and the portable tank is shown to provide a level of safety equal to or exceeding the requirements of this subchapter with respect to the compatibility of the transported hazardous materials and the ability of the portable tank to withstand impact, loading and fire conditions. Portable tanks approved to alternative technical requirements must be marked “Alternative Arrangement” as specified in paragraph (i) of this section.
(3) Definitions. The following definitions apply for the purposes of design and construction of UN portable tanks under this subpart:
Alternate Arrangement portable tank means a UN portable tank that has been approved to alternative technical requirements or testing methods other than those specified for UN portable tanks in part 178 or part 180 of this subchapter.
Approval agency means the designated approval agency authorized to approve the portable tank in accordance with the procedures in subpart E, part 107 of this subchapter.
Design pressure is defined differently depending on the hazardous materials intended to be transported in the portable tank. See §§ 178.275, 178.276 and 178.277 as applicable.
Design type means a portable tank or series of portable tanks made of materials of the same material specifications and thicknesses, manufactured by a single manufacturer, using the same fabrication techniques (for example, welding procedures) and made with equivalent structural equipment, closures, and service equipment.
Fine grain steel means steel which has a ferritic grain size of 6 or finer when determined in accordance with ASTM E 112 (incorporated by reference, see § 171.7 of this subchapter).
Jacket means the outer insulation cover or cladding which may be part of the insulation system.
Leakage test means a test using gas to subject the shell and its service equipment to an effective internal pressure of not less than 25% of the MAWP. For portable tanks used for refrigerated liquefied gases the leakage test must be conducted at an effective internal pressure of not less than 90% of the MAWP. Start Printed Page 63423
Maximum allowable working pressure (MAWP) is defined differently depending on the hazardous materials intended to be transported in the portable tank. See §§ 178.275, 178.276 and 178.277, as applicable.
Maximum permissible gross mass (MPGM) means the sum of the tare mass of the portable tank and the heaviest hazardous material authorized for transportation.
Mild steel means a steel with a guaranteed minimum tensile strength of 360 N/mm2 to 440 N/mm2 and a guaranteed minimum elongation at fracture as specified in paragraph § 178.274(c)(11).
Offshore portable tank means a portable tank specially designed for repeated use in the transportation of hazardous materials to, from and between offshore facilities. An offshore portable tank is designed and constructed in accordance with the Guidelines for the Approval of Containers Handled in Open Seas specified in the IMDG Code (incorporated by reference, see § 171.7 of this subchapter).
Reference steel means a steel with a tensile strength of 370 N/mm2 and an elongation at fracture of 27%.
Service equipment means measuring instruments and filling, discharge, venting, safety, heating, cooling and insulating devices.
Shell means the part of the portable tank which retains the hazardous materials intended for transportation, including openings and their closures, but does not include service equipment or external structural equipment.
Structural equipment means the reinforcing, fastening, protective and stabilizing members external to the shell.
Test pressure means the maximum gauge pressure at the top of the shell during the hydraulic pressure test equal to not less than 1.5 times the design pressure for liquids and 1.3 for liquefied compressed gases. The minimum test pressure for portable tanks intended for specific hazardous materials is specified in the applicable portable tank T code assigned to a particular hazardous material in the § 172.101 Table of this subchapter.
(b) General design and construction requirements. (1) The design temperature range for the shell must be −40 °C to 50 °C (−40 °F to 122 °F) for hazardous materials transported under normal conditions of transportation, except for portable tanks used for refrigerated liquefied gases where the minimum design temperature must not be higher than the lowest (coldest) temperature (for example, service temperature) of the contents during filling, discharge or transportation. For hazardous materials handled under elevated temperature conditions, the design temperature must not be less than the maximum temperature of the hazardous material during filling, discharge or transportation. More severe design temperatures must be considered for portable tanks subjected to severe climatic conditions (for example, portable tanks transported in arctic regions). Shells must be designed and constructed in accordance with the requirements of the ASME Code, Section VIII, Division 1 (incorporated by reference, see § 171.7 of this subchapter), except as limited or modified in this subchapter. For portable tanks used for liquid or solid hazardous materials, a design code other than the ASME Code may be used if approved by the Associate Administrator. Portable tanks used for liquified compressed gases require an ASME certification and U stamp. Shells must be made of metallic materials suitable for forming. Non-metallic materials may be used for the attachments and supports between the shell and jacket, provided their material properties at the minimum and maximum design temperatures are proven to be sufficient. For welded shells, only a material whose weldability has been fully demonstrated may be used. Welds must be of high quality and conform to a level of integrity at least equivalent to the welding requirements specified in the ASME Code, Section VIII for the welding of pressure vessels. When the manufacturing process or the materials make it necessary, the shells must be suitably heat-treated to guarantee adequate toughness in the weld and in the heat affected zones. In choosing the material, the design temperature range must be taken into account with respect to risk of brittle fracture, stress corrosion cracking, resistance to impact, and suitability for the hazardous materials intended for transportation in the portable tank. When fine grain steel is used, the guaranteed value of the yield strength must be not more than 460 N/mm2 and the guaranteed value of the upper limit of the tensile strength must be not more than 725 N/mm2 according to the material specification. Aluminum may not be used as a construction material for the shell. Portable tank materials must be suitable for the external environment where they will be transported taking into account the determined design temperature range. Portable tanks must be designed to withstand, without loss of contents, at least the internal pressure due to the contents and the static, dynamic and thermal loads during normal conditions of handling and transportation. The design must take into account the effects of fatigue, caused by repeated application of these loads through the expected life of the portable tank.
(2) Portable tank shells, fittings, and pipework must be constructed from materials that are:
(i) Compatible with the hazardous materials intended to be transported; or
(ii) Properly passivated or neutralized by chemical reaction, if applicable; or
(iii) For portable tanks used for liquid and solid materials, lined with corrosion-resistant material directly bonded to the shell or attached by equivalent means.
(3) Gaskets and seals must be made of materials that are compatible with the hazardous materials intended to be transported.
(4) When shells are lined, the lining must be compatible with the hazardous materials intended to be transported, homogeneous, non-porous, free from perforations, sufficiently elastic and compatible with the thermal expansion characteristics of the shell. The lining of every shell, shell fittings and piping must be continuous and must extend around the face of any flange. Where external fittings are welded to the tank, the lining must be continuous through the fitting and around the face of external flanges. Joints and seams in the lining must be made by fusing the material together or by other equally effective means.
(5) Contact between dissimilar metals which could result in damage by galvanic action must be prevented by appropriate measures.
(6) The construction materials of the portable tank, including any devices, gaskets, linings and accessories, must not adversely affect or react with the hazardous materials intended to be transported in the portable tank.
(7) Portable tanks must be designed and constructed with supports that provide a secure base during transportation and with suitable lifting and tie-down attachments.
(c) Design criteria. (1) Portable tanks and their fastenings must, under the maximum permissible load, be capable of absorbing the following separately applied static forces (for calculation purposes, acceleration due to gravity (g) = 9.81m/s2):
(i) In the direction of travel: 2g (twice the MPGM multiplied by the acceleration due to gravity);
(ii) Horizontally at right angles to the direction of travel: 1g (the MPGM Start Printed Page 63424multiplied by the acceleration due to gravity);
(iii) Vertically upwards: 1g (the MPGM multiplied by the acceleration due to gravity); and
(iv) Vertically downwards: 2g (twice the MPGM multiplied by the acceleration due to gravity).
(2) Under each of the forces specified in paragraph (c)(1) of this section, the safety factor must be as follows:
(i) For metals having a clearly defined yield point, a design margin of 1.5 in relation to the guaranteed yield strength; or
(ii) For metals with no clearly defined yield point, a design margin of 1.5 in relation to the guaranteed 0.2% proof strength and, for austenitic steels, the 1% proof strength.
(3) The values of yield strength or proof strength must be the values according to recognized material standards. When austenitic steels are used, the specified minimum values of yield strength or proof strength according to the material standards may be increased by up to 15% when these greater values are attested in the material inspection certificate.
(4) Portable tanks must be capable of being electrically grounded to prevent dangerous electrostatic discharge when they are used for Class 2 flammable gases or Class 3 flammable liquids, including elevated temperature materials transported at or above their flash point.
(5) For shells of portable tanks used for liquefied compressed gases, the shell must consist of a circular cross section. Shells must be of a design capable of being stress-analysed mathematically or experimentally by resistance strain gauges as specified in UG-101 of the ASME Code (incorporated by reference, see § 171.7 of this subchapter), or other methods approved by the Associate Administrator.
(6) Shells must be designed and constructed to withstand a hydraulic test pressure of not less than 1.5 times the design pressure for portable tanks used for liquids and 1.3 times the design pressure for portable tanks used for liquefied compressed gases. Specific requirements are provided for each hazardous material in the applicable T Code or portable tank special provision specified in the § 172.101 Table of this subchapter. The minimum shell thickness requirements must also be taken into account.
(7) For metals exhibiting a clearly defined yield point or characterized by a guaranteed proof strength (0.2% proof strength, generally, or 1% proof strength for austenitic steels), the primary membrane stress (sigma) in the shell must not exceed 0.75 Re or 0.50 Rm, whichever is lower, at the test pressure, where:
Re = yield strength in N/mm2, or 0.2% proof strength or, for austenitic steels, 1% proof strength;
Rm = minimum tensile strength in N/mm2.
(8) The values of Re and Rm to be used must be the specified minimum values according to recognized material standards. When austenitic steels are used, the specified minimum values for Re and Rm according to the material standards may be increased by up to 15% when greater values are attested in the material inspection certificate.
(9) Steels which have a Re/Rm ratio of more than 0.85 are not allowed for the construction of welded shells. The values of Re and Rm to be used in determining this ratio must be the values specified in the material inspection certificate.
(10) Steels used in the construction of shells must have an elongation at fracture, in percentage, of not less than 10,000/Rm with an absolute minimum of 16% for fine grain steels and 20% for other steels.
(11) For the purpose of determining actual values for materials for sheet metal, the axis of the tensile test specimen must be at right angles (transversely) to the direction of rolling. The permanent elongation at fracture must be measured on test specimens of rectangular cross sections in accordance with ISO 6892 (see § 171.7 of this subchapter), using a 50 mm gauge length.
(d) Minimum shell thickness. (1) The minimum shell thickness must be the greatest thickness of the following:
(i) the minimum thickness determined in accordance with the requirements of paragraphs (d)(2) through (d)(10) of this section;
(ii) the minimum thickness determined in accordance with the ASME Code (incorporated by reference, see § 171.7 of this subchapter) or other approved pressure vessel code; or
(iii) the minimum thickness specified in the applicable T code or portable tank special provision indicated for each hazardous material in the § 172.101 Table of this subchapter.
(2) Shells (cylindrical portions, heads and manhole covers) not more than 1.80 m in diameter may not be less than 5 mm thick in the reference steel or of equivalent thickness in the metal to be used. Shells more than 1.80 m in diameter may not be less than 6 mm thick in the reference steel or of equivalent thickness in the metal to be used. For portable tanks used only for the transportation of powdered or granular solid hazardous materials of Packing Group II or III, the minimum thickness requirement may be reduced to 5 mm in the reference steel or of equivalent thickness in the metal to be used regardless of the shell diameter. For vacuum-insulated tanks, the aggregate thickness of the jacket and the shell must correspond to the minimum thickness prescribed in this paragraph, with the thickness of the shell itself not less than the minimum thickness prescribed in paragraph (d)(3) of this section.
(3) When additional protection against shell damage is provided in the case of portable tanks used for liquid and solid hazardous materials requiring test pressures less than 2.65 bar (265.0 kPa), subject to certain limitations specified in the UN Recommendations (incorporated by reference, see § 171.7 of this subchapter), the Associate Administrator may approve a reduced minimum shell thickness.
(4) The cylindrical portions, heads and manhole covers of all shells must not be less than 3 mm (0.1 inch) thick regardless of the material of construction, except for portable tanks used for liquefied compressed gases where the cylindrical portions, ends (heads) and manhole covers of all shells must not be less than 4 mm (0.2 inch) thick regardless of the material of construction.
(5) When steel that has characteristics other than that of reference steel is used, the equivalent thickness of the shell and heads must be determined according to the following formula:
Where:
e1 = required equivalent thickness (in mm) of the metal to be used;
e0 = minimum thickness (in mm) of the reference steel specified in the applicable T code or portable tank special provision indicated for each material in the § 172.101 Table of this subchapter;
d1 = 1.8m, unless the formula is used to determine the equivalent minimum thickness for a portable tank shell that is required to have a minimum thickness of 8mm or 10mm according to the applicable T code indicated in the § 172.101 Table of this subchapter. When reference steel thicknesses of 8mm or 10mm are specified, d1 is equal to the actual diameter of the shell but not less than 1.8m;
Rm1 = guaranteed minimum tensile strength (in N/mm2) of the metal to be used;
A1 = guaranteed minimum elongation at fracture (in %) of the metal to be used Start Printed Page 63425according to recognized material standards.
(6) The wall and all parts of the shell may not have a thickness less than that prescribed in paragraphs (d)(2), (d)(3) and (d)(4) of this section. This thickness must be exclusive of any corrosion allowance.
(7) There must be no sudden change of plate thickness at the attachment of the heads to the cylindrical portion of the shell.
(e) Service equipment. (1) Service equipment must be arranged so that it is protected against the risk of mechanical damage by external forces during handling and transportation. When the connections between the frame and the shell allow relative movement between the sub-assemblies, the equipment must be fastened to allow such movement without risk of damage to working parts. The external discharge fittings (pipe sockets, shut-off devices) and the internal stop-valve and its seating must be protected against mechanical damage by external forces (for example, by using shear sections). The filling and discharge devices (including flanges or threaded plugs) and any protective caps must be capable of being secured against unintended opening.
(2) Each connection to a portable tank must be clearly marked to indicate its function.
(3) Each stop-valve or other means of closure must be designed and constructed to a rated pressure not less than the MAWP of the shell taking into account the temperatures expected during transport. All stop-valves with screwed spindles must close by a clockwise motion of the handwheel. For other stop-valves the position (open and closed) and direction of closure must be clearly indicated. All stop-valves must be designed to prevent unintentional opening.
(4) Piping must be designed, constructed and installed to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping must be of a suitable metallic material. Welded pipe joints must be used wherever possible.
(5) Joints in copper tubing must be brazed or have an equally strong metal union. The melting point of brazing materials must be no lower than 525 °C (977 °F). The joints must not decrease the strength of the tubing, such as may happen when cutting threads.
(6) The burst pressure of all piping and pipe fittings must be greater than the highest of four times the MAWP of the shell or four times the pressure to which it may be subjected in service by the action of a pump or other device (except pressure relief devices).
(7) External fittings must be grouped together. Filling and discharge connections may be installed below the normal liquid level of the tank if the tank design conforms to the following requirements:
(i) The portable tank must be permanently mounted in a full framework for containerized transport. For each portable tank design, a prototype portable tank, must fulfill the requirements of parts 450 through 453 of this title for compliance with the requirements of Annex II of the International Convention for Safe Containers.
(ii) Each filling and discharge connection must be equipped with an internal self-closing stop-valve capable of closing within 30 seconds of actuation. Each internal self-closing stop-valve must be protected by a shear section or sacrificial device located outboard of the valve. The shear section or sacrificial device must break at no more than 70 percent of the load that would cause failure of the internal self-closing stop-valve.
(iii) Each internal self-closing stop-valve must be provided with remote means of automatic closure, both thermal and mechanical. The thermal means of automatic closure must actuate at a temperature of not over 121 °C (250 °F).
(8) Ductile metals must be used in the construction of valves and accessories.
(f) Pressure relief devices.—(1) Marking of pressure relief devices. Every pressure relief device must be clearly and permanently marked with the following:
(i) the pressure (in bar or kPa) or temperature for fusible elements (in °C) at which it is set to discharge;
(ii) the allowable tolerance at the discharge pressure for reclosing devices;
(iii) the reference temperature corresponding to the rated pressure for frangible discs;
(iv) the allowable temperature tolerance for fusible elements;
(v) the rated flow capacity of the device in standard cubic meters of air per second (m3/s) determined according to ISO 4126-1 (incorporated by reference, see § 171.7 of this subchapter); and
(vi) when practicable, the device must show the manufacturer's name and product number.
(2) Connections to pressure relief devices. Connections to pressure relief devices must be of sufficient size to enable the required discharge to pass unrestricted to the safety device. No stop-valve may be installed between the shell and the pressure relief devices except where duplicate devices are provided for maintenance or other reasons and the stop-valves serving the devices actually in use are locked open or the stop-valves are interlocked so that at least one of the duplicate devices is always in use. There must be no obstruction in an opening leading to a vent or pressure relief device which might restrict or cut-off the flow from the shell to that device. Vents or pipes from the pressure relief device outlets, when used, must deliver the relieved vapor or liquid to the atmosphere in conditions of minimum back-pressure on the relieving devices.
(3) Location of pressure relief devices. (i) Each pressure relief device inlet must be situated on top of the shell in a position as near the longitudinal and transverse center of the shell as reasonably practicable. All pressure relief device inlets must, under maximum filling conditions, be situated in the vapor space of the shell and the devices must be so arranged as to ensure that escaping vapor is discharged unrestrictedly. For flammable hazardous materials, the escaping vapor must be directed away from the shell in such a manner that it cannot impinge upon the shell. For refrigerated liquefied gases, the escaping vapor must be directed away from the tank and in such a manner that it cannot impinge upon the tank. Protective devices which deflect the flow of vapor are permissible provided the required relief-device capacity is not reduced.
(ii) Arrangements must be made to prevent unauthorized persons from access to the pressure relief devices and to protect the devices from damage caused by the portable tank overturning.
(g) Gauging devices. Unless a portable tank is intended to be filled by weight, it must be equipped with one or more gauging devices. Glass level-gauges and gauges made of other fragile material, which are in direct communication with the contents of the tank are prohibited. A connection for a vacuum gauge must be provided in the jacket of a vacuum-insulated portable tank.
(h) Portable tank supports, frameworks, lifting and tie-down attachments. (1) Portable tanks must be designed and constructed with a support structure to provide a secure base during transport. The forces and safety factors specified in paragraphs (c)(1) and (c)(2) of this section, respectively, must be taken into account in this aspect of the design. Skids, frameworks, cradles or other similar structures are acceptable.
(2) The combined stresses caused by portable tank mountings (for example, Start Printed Page 63426cradles, framework, etc.) and portable tank lifting and tie-down attachments must not cause excessive stress in any portion of the shell. Permanent lifting and tie-down attachments must be fitted to all portable tanks. Preferably they should be fitted to the portable tank supports but may be secured to reinforcing plates located on the shell at the points of support. Each portable tank must be designed so that the center of gravity of the filled tank is approximately centered within the points of attachment for lifting devices.
(3) In the design of supports and frameworks, the effects of environmental corrosion must be taken into account.
(4) Forklift pockets must be capable of being closed off. The means of closing forklift pockets must be a permanent part of the framework or permanently attached to the framework. Single compartment portable tanks with a length less than 3.65 m need not have forklift pockets that are capable of being closed off provided that:
(i) The shell, including all the fittings, are well protected from being hit by the forklift blades; and
(ii) The distance between forklift pockets (measured from the center of each pocket) is at least half of the maximum length of the portable tank.
(5) During transport, portable tanks must be adequately protected against damage to the shell, and service equipment resulting from lateral and longitudinal impact and overturning on the shell and service equipment must be constructed to withstand impact or overturning. External fittings must be protected so as to preclude the release of the shell contents upon impact or overturning of the portable tank on its fittings. Examples of protection include:
(i) Protection against lateral impact which may consist of longitudinal bars protecting the shell on both sides at the level of the median line;
(ii) Protection of the portable tank against overturning which may consist of reinforcement rings or bars fixed across the frame;
(iii) Protection against rear impact which may consist of a bumper or frame;
(iv) Protection of the shell against damage from impact or overturning by use of an ISO frame in accordance with ISO 1496-3 (incorporated by reference, see § 171.7 of this subchapter); and
(v) Protection of the portable tank from impact or overturning by a vacuum insulation jacket.
(i) Marking. (1) Every portable tank must be fitted with a corrosion resistant metal plate permanently attached to the portable tank in a conspicuous place and readily accessible for inspection. When the plate cannot be permanently attached to the shell, the shell must be marked with at least the information required by the ASME Code (incorporated by reference, see § 171.7 of this subchapter). At a minimum, the following information must be marked on the plate by stamping or by any other similar method:
Country of manufacture
UN
Approval Country
Approval Number
Alternative Arrangements “AA” (see § 178.274(a)(2))
Manufacturer's name or mark
Manufacturer's serial number
Approval Agency (Authorized body for the design approval)
Owner's registration number
Year of manufacture
Pressure vessel code to which the shell is designed
Test pressure _____ bar gauge.
MAWP _____ bar gauge.
External design pressure (not required for portable tanks used for refrigerated liquefied gases) _____ bar/gauge.
Design temperature range _____ °C to _____ °C. (For portable tanks used for refrigerated liquefied gases, the minimum design temperature must be marked.)
Water capacity at 20 °C/ _____ liters.
Water capacity of each compartment at 20 °C _____ liters.
Initial pressure test date and witness identification.
MAWP for heating/cooling system _____ bar gauge.
Shell material(s) and material standard reference(s).
Equivalent thickness in reference steel _____ mm.
Lining material (when applicable).
Date and type of most recent periodic test(s).
Month _____ Year _____ Test pressure _____ bar/gauge.
Stamp of approval agency that performed or witnessed the most recent test.
For portable tanks used for refrigerated liquefied gases:
Either “thermally insulated” or “vacuum insulated” _____.
Effectiveness of the insulation system (heat influx) _____ Watts (W).
Reference holding time _____ days or hours and initial pressure _____ bar/kPa gauge and degree of filling _____ in kg for each refrigerated liquefied gas permitted for transportation.
(2) The following information must be marked either on the portable tank itself or on a metal plate firmly secured to the portable tank:
Name of the operator.
Name of hazardous materials being transported and maximum mean bulk temperature (except for refrigerated liquefied gases, the name and temperature are only required when the maximum mean bulk temperature is higher than 50 °C).
Maximum permissible gross mass (MPGM) _____ kg.
Unladen (tare) mass _____ kg.
Note to Paragraph (i)(2):
For the identification of the hazardous materials being transported refer to part 172 of this subchapter.
(3) If a portable tank is designed and approved for open seas operations, such as offshore oil exploration, in accordance with the IMDG Code, the words “OFFSHORE PORTABLE TANK” must be marked on the identification plate.
62. Section 178.275 would be added to subpart H to read as follows:
Specification for UN Portable Tanks intended for the transportation of liquid and solid hazardous materials.(a) In addition to the requirements of § 178.274, the following definitions and requirements apply to UN portable tanks intended for the transportation of liquid and solid hazardous materials:
(1) Design pressure means the pressure to be used in calculations required by the recognized pressure vessel code. The design pressure must not be less than the highest of the following pressures:
(i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or
(ii) The sum of:
(A) The absolute vapor pressure (in bar) of the hazardous material at 65 °C, minus 1 bar (149 °F, minus 100 kPa);
(B) The partial pressure (in bar) of air or other gases in the ullage space, resulting from their compression during filling without pressure relief by a maximum ullage temperature of 65 °C (149 °F) and a liquid expansion due to an increase in mean bulk temperature of 35 °C (95 °F); and
(C) A head pressure determined on the basis of the forces specified in § 178.274(c), but not less than 0.35 bar (35 kPa).
(2) Maximum allowable working pressure (MAWP) means a pressure that must not be less than the highest of the following pressures measured at the top of the shell while in operating position:
(i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or
(ii) The maximum effective gauge pressure to which the shell is designed which must be not less than the design pressure.
(b) Service equipment. (1) In addition to the requirements specified in § 178.274, for service equipment, all openings in the shell, intended for filling or discharging the portable tank must be fitted with a manually operated stop-valve located as close to the shell Start Printed Page 63427as reasonably practicable. Other openings, except for openings leading to venting or pressure relief devices, must be equipped with either a stop-valve or another suitable means of closure located as close to the shell as reasonably practicable.
(2) All portable tanks must be fitted with a manhole or other inspection openings of a suitable size to allow for internal inspection and adequate access for maintenance and repair of the interior. Compartmented portable tanks must have a manhole or other inspection openings for each compartment.
(3) For insulated portable tanks, top fittings must be surrounded by a spill collection reservoir with suitable drains.
(4) Piping must be designed, constructed and installed to avoid the risk of damage due to thermal expansion and contraction, mechanical shock and vibration. All piping must be of a suitable metallic material. Welded pipe joints must be used wherever possible.
(c) Bottom openings. (1) Certain hazardous materials may not be transported in portable tanks with bottom openings. When the applicable T code or portable tank special provision, as referenced for materials in the § 172.101 Table of this subchapter, specifies that bottom openings are prohibited, there must be no openings below the liquid level of the shell when it is filled to its maximum permissible filling limit. When an existing opening is closed, it must be accomplished by internally and externally welding one plate to the shell.
(2) Bottom discharge outlets for portable tanks carrying certain solid, crystallizable or highly viscous hazardous materials must be equipped with at least two serially fitted and mutually independent shut-off devices. Use of only two shut-off devices is only authorized when this paragraph is referenced in the applicable T Code indicated for each hazardous material in the § 172.101 Table of this subchapter. The design of the equipment must be to the satisfaction of the approval agency and must include:
(i) An external stop-valve fitted as close to the shell as reasonably practicable; and
(ii) A liquid tight closure at the end of the discharge pipe, which may be a bolted blank flange or a screw cap.
(3) Except as provided in paragraph (c)(2) of this section, every bottom discharge outlet must be equipped with three serially fitted and mutually independent shut-off devices. The design of the equipment must be to the satisfaction of the approval agency and must include:
(i) A self-closing internal stop-valve, which is a stop-valve within the shell or within a welded flange or its companion flange, such that:
(A) The control devices for the operation of the valve are designed to prevent any unintended opening through impact or other inadvertent act;
(B) The valve is operable from above or below;
(C) If possible, the setting of the valve (open or closed) must be capable of being verified from the ground;
(D) Except for portable tanks having a capacity less than 1,000 liters (264.2 gallons), it must be possible to close the valve from an accessible position of the portable tank that is remote from the valve itself; and
(E) The valve must continue to be effective in the event of damage to the external device for controlling the operation of the valve;
(ii) An external stop-valve fitted as close to the shell as reasonably practicable; and
(iii) A liquid tight closure at the end of the discharge pipe, which may be a bolted blank flange or a screw cap.
(4) For a lined shell, the internal stop-valve required by paragraph (c)(3)(i) of this section may be replaced by an additional external stop-valve.
(d) Pressure relief devices. All portable tanks must be fitted with at least one pressure relief device. All relief devices must be designed, constructed and marked in accordance with the requirements of this subchapter.
(e) Vacuum-relief devices. (1) A shell which is to be equipped with a vacuum-relief device must be designed to withstand, without permanent deformation, an external pressure of not less than 0.21 bar (21.0 kPa) above the internal pressure. The vacuum-relief device must be set to relieve at a vacuum setting not greater than minus (−) 0.21 bar (−21.0 kPa) unless the shell is designed for a higher external over pressure, in which case the vacuum-relief pressure of the device to be fitted must not be greater than the tank design vacuum pressure. A shell that is not fitted with a vacuum-relief device must be designed to withstand, without permanent deformation, an external pressure of not less than 0.4 bar (40.0 kPa) above the internal pressure.
(2) Vacuum-relief devices used on portable tanks intended for the transportation of hazardous materials meeting the criteria of Class 3, including elevated temperature hazardous materials transported at or above their flash point, must prevent the immediate passage of flame into the shell or the portable tank must have a shell capable of withstanding, without leakage, an internal explosion resulting from the passage of flame into the shell.
(f) Pressure relief devices. (1) Each portable tank with a capacity not less than 1,900 liters (501.9 gallons) and every independent compartment of a portable tank with a similar capacity, must be provided with one or more pressure relief devices of the reclosing type. Such portable tanks may, in addition, have a frangible disc or fusible element in parallel with the reclosing devices, except when the applicable T code assigned to a hazardous material requires that the frangible disc precede the pressure relief device, according to paragraph (f)(3) of this section, or when no bottom openings are allowed. The pressure relief devices must have sufficient capacity to prevent rupture of the shell due to over pressurization or vacuum resulting from filling, discharging, from heating of the contents or fire.
(2) Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of liquid and the development of any dangerous excess pressure.
(3) When required for certain hazardous materials by the applicable T code or portable tank special provision specified for a hazardous material in the § 172.101 Table of this subchapter, portable tanks must have a pressure relief device consistent with the requirements of this subchapter. Except for a portable tank in dedicated service that is fitted with an approved relief device constructed of materials compatible with the hazardous material, the relief device system must include a frangible disc preceding a reclosing pressure relief device. A pressure gauge or suitable tell-tale indicator for the detection of disc rupture, pin-holing or leakage must provide the space between the frangible disc and the pressure relief device. The frangible disc must rupture at a nominal pressure 10% above the start to discharge pressure of the relief device.
(4) Every portable tank with a capacity less than 1,900 liters (501.9 gallons) must be fitted with a pressure relief device, which may be a frangible disc when this disc is set to rupture at a nominal pressure equal to the test pressure at any temperature within the design temperature range.
(5) When the shell is fitted for pressure discharge, a suitable pressure relief device must provide the inlet line to the portable tank set to operate at a pressure not higher than the MAWP of the shell, and a stop-valve must be fitted as close to the shell to minimize the potential for damage. Start Printed Page 63428
(6) Setting of pressure relief devices. (i) Pressure relief devices must operate only in conditions of excessive rise in temperature, since the shell must not be subject to undue fluctuations of pressure during normal conditions of transportation.
(ii) The required pressure relief device must be set to start-to-discharge at a nominal pressure of five-sixths of the test pressure for shells having a test pressure of not more than 4.5 bar (450 kPa) and 110% of two-thirds of the test pressure for shells having a test pressure of more than 4.5 bar (450 kPa). A self-closing relief device must close at a pressure not more than 10% below the pressure at which the discharge starts. The device must remain closed at all lower pressures. This requirement does not prevent the use of vacuum-relief or combination pressure relief and vacuum-relief devices.
(g) Fusible elements. Fusible elements must operate at a temperature between 110 °C (230 °F) and 149 °C (300.2 °F) provided that the pressure in the shell at the fusing temperature will not exceed the test pressure. They must be placed at the top of the shell with their inlets in the vapor space and in no case may they be shielded from external heat. Fusible elements must not be utilized on portable tanks with a test pressure which exceeds 2.65 bar (265.0 kPa). Fusible elements used on portable tanks intended for the transport of elevated temperature hazardous materials must be designed to operate at a temperature higher than the maximum temperature that will be experienced during transport and must be to the satisfaction of the approval agency.
(h) Capacity of pressure relief devices. (1) The reclosing pressure relief device required by paragraph (f)(1) must have a minimum cross sectional flow area equivalent to an orifice of 31.75 mm (1.3 inches) diameter. Vacuum-relief devices, when used, must have a cross sectional flow area not less than 284 mm2 (11.2 inches2).
(2) Under conditions of complete fire engulfment of the portable tank, the combined delivery capacity of the relief devices must be sufficient to limit the pressure in the shell to 20% above the start-to-discharge pressure specified in paragraph(f)(6) of this section. Emergency pressure relief devices may be used to achieve the full relief capacity prescribed. The total required capacity of the relief devices may be determined using the formula in paragraph (h)(2)(i) of this section or the table in paragraph (h)(2)(iii) of this section.
(i)(A) To determine the total required capacity of the relief devices, which must be regarded as being the sum of the individual capacities of all the contributing devices, the following formula must be used:
Where:
Q = minimum required rate of discharge in cubic meters of air per second (m3/s) at standard conditions: 1 bar and 0 °C (273 K);
F = for uninsulated shells: 1; for insulated shells: U(649 − t)/13.6 but in no case is less than 0.25 where: U = thermal conductance of the insulation in kW·m−2·K−1, at 38 °C; and t = actual temperature of the hazardous material during filling (in °C) or when this temperature is unknown, let t = 15 °C. The value of F given above for insulated shells may only be used if the insulation is in conformance with paragraph (h)(2)(iv) of this section;
A = total external surface area of shell in square meters;
Z = the gas compressibility factor in the accumulating condition (when this factor is unknown, let Z equal 1.0);
T = absolute temperature in Kelvin (°C + 273) above the pressure relief devices in the accumulating condition;
L = the latent heat of vaporization of the liquid, in kJ/kg, in the accumulating condition;
M = molecular weight of the hazardous material.
(B) The constant C, as shown in the formula in paragraph (h)(2)(i)(A) of this section, is derived from one of the following formula as a function of the ratio k of specific heats:
Where:
cp is the specific heat at constant pressure; and
cv is the specific heat at constant volume.
(C) When k>1:
(D) When k = 1 or k is unknown, a value of 0.607 may be used for the constant C. C may also be taken from the following table:
C Constant Value Table
k C k C k C 1.00 0.607 1.26 0.660 1.52 0.704 1.02 0.611 1.28 0.664 1.54 0.707 1.04 0.615 1.30 0.667 1.56 0.710 1.06 0.620 1.32 0.671 1.58 0.713 1.08 0.624 1.34 0.674 1.60 0.716 1.10 0.628 1.36 0.678 1.62 0.719 1.12 0.633 1.38 0.681 1.64 0.722 1.14 0.637 1.40 0.685 1.66 0.725 1.16 0.641 1.42 0.688 1.68 0.728 1.18 0.645 1.44 0.691 1.70 0.731 1.20 0.649 1.46 0.695 2.00 0.770 1.22 0.652 1.48 0.698 2.20 0.793 1.24 0.656 1.50 0.701 (ii) As an alternative to the formula in paragraph (h)(2)(i) of this section, relief devices for shells used for transporting liquids may be sized in accordance with the table in paragraph (h)(2)(iii) of this section. The table in paragraph (h)(2)(iii) of this section assumes an insulation value of F = 1 and must be adjusted accordingly when the shell is insulated. Other values used in determining the table in paragraph (h)(2)(iii) of this section are: L = 334.94 kJ/kg; M = 86.7; T = 394 K; Z = 1; and C = 0.607.
(iii) Minimum emergency vent capacity, Q, in cubic meters per air per second at 1 bar and 0 °C (273 K), as shown in the following table: Start Printed Page 63429
Minimum Emergency Vent Capacity
[Q Values]
A Exposed area (square meters) Q (Cubic meters of air per second) A Exposed area (square meters) Q (Cubic meters of air per second) 2 0.230 37.5 2.539 3 0.320 40 2.677 4 0.405 42.5 2.814 5 0.487 45 2.949 6 0.565 47.5 3.082 7 0.641 50 3.215 8 0.715 52.5 3.346 9 0.788 55 3.476 10 0.859 57.5 3.605 12 0.998 60 3.733 14 1.132 62.5 3.860 16 1.263 65 3.987 18 1.391 67.5 4.112 20 1.517 70 4.236 22.5 1.670 75 4.483 25 1.821 80 4.726 27.5 1.969 85 4.967 30 2.115 90 5.206 32.5 2.258 95 5.442 35 2.400 100 5.676 (iv) Insulation systems, used for the purpose of reducing venting capacity, must be approved by the approval agency. In all cases, insulation systems approved for this purpose must:
(A) Remain effective at all temperatures up to 649 °C (1200.2 °F); and
(B) Be jacketed with a material having a melting point of 700 °C (1292 °F) or greater.
(i) Approval, inspection and testing. Approval procedures for UN portable tanks are specified in § 178.273. Inspection and testing requirements are specified in § 180.605 of this subchapter.
63. Section 178.276 would be added to subpart H to read as follows:
Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of liquefied compressed gases.(a) In addition to the requirements of § 178.274 applicable to UN portable tanks, the following requirements apply to UN portable tanks used for liquefied compressed gases. In addition to the definitions in § 178.274, the following definitions apply:
Design pressure means the pressure to be used in calculations required by the ASME Code (incorporated by reference, see § 171.7 of this subchapter). The design pressure must be not less than the highest of the following pressures:
(i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or
(ii) The sum of:
(A) The maximum effective gauge pressure to which the shell is designed as defined in this paragraph under “MAWP”; and
(B) A head pressure determined on the basis of the dynamic forces specified in paragraph (h) of this section, but not less than 0.35 bar (35 kPa).
Note to Paragraph (a)(1):
For the purpose of this section, the term “design pressure” as used in this specification is identical to the term “maximum allowable working pressure” as used in the ASME Code, Section VIII.
(2) Design reference temperature means the temperature at which the vapor pressure of the contents is determined for the purpose of calculating the MAWP. The value for each portable tank type is as follows:
(i) Shell with a diameter of 1.5 meters or less: 65 °C; or
(ii) Shell with a diameter of more than 1.5 meters:
(A) Without insulation or sun shield: 60 °C;
(B) With sun shield: 55 °C; and
(C) With insulation: 50 °C.
(3) Filling density means the average mass of liquefied compressed gas per liter of shell capacity (kg/l).
(4) Maximum allowable working pressure (MAWP) means a pressure that must be not less than the highest of the following pressures measured at the top of the shell while in operating position, but in no case less than 7 bar (700 kPa):
(i) The maximum effective gauge pressure allowed in the shell during filling or discharge; or
(ii) The maximum effective gauge pressure to which the shell is designed, which must be:
(A) Not less than the pressure specified for each liquefied compressed gas listed in portable tank special provision T50; and
(B) Not less than the sum of:
(1) The absolute vapor pressure (in bar) of the liquefied compressed gas at the design reference temperature minus 1 bar; and
(2) The partial pressure (in bar) of air or other gases in the ullage space which is determined by the design reference temperature and the liquid phase expansion due to the increase of the mean bulk temperature of tr-tf (tf = filling temperature, usually 15 °C, tr = 50 °C maximum mean bulk temperature);
(b) General design and construction requirements. (1) Tanks must be of seamless or welded steel construction, or combination of both, and have a water capacity greater than 450 liters (118.9 gallons). Tanks must be designed, constructed, certified and stamped in accordance with the ASME Code, Section VIII (incorporated by reference, see § 171.7 of this subchapter).
(2) Portable tanks must be postweld heat-treated and radiographed as prescribed in the ASME Code, except that each portable tank constructed in accordance with part UHT of the ASME Code must be postweld heat-treated. Where postweld heat treatment is required, the portable tank must be treated as a unit after completion of all the welds in and/or to the shell and heads. The method must be as prescribed in the ASME Code. Welded attachments to pads may be made after postweld heat treatment is made. A portable tank used for anhydrous ammonia must be postweld heat-treated. The postweld heat treatment must be as prescribed in the ASME Code, but in no event at less than 1050 °F tank metal temperature. Additionally, portable tanks constructed in accordance with part UHT of the ASME Code must conform to the following requirements:
(i) Welding procedure and welder performance tests must be made annually in accordance with section IX of the ASME Code. In addition to the essential variables named therein, the following must be considered to be essential variables: number of passes, thickness of plate, heat input per pass, and manufacturer's identification of rod and flux. The number of passes, thickness of plate and heat input per pass may not vary more than 25 percent from the procedure qualification. Records of the qualification must be retained for at least 5 years by the tank manufacturer and made available to duly identified representatives of the Department of Transportation or the owner of the tank.
(ii) Impact tests must be made on a lot basis. A lot is defined as 100 tons or less of the same heat and having a thickness variation no greater than plus or minus 25 percent. The minimum impact required for full-sized specimens shall be 20 foot-pounds (or 10 foot-pounds for half-sized specimens) at 0° F Charpy V-Notch in both the longitudinal and transverse direction. If the lot test does not pass this requirement, individual plates may be accepted if they individually meet this impact requirement.
(3) Welding procedures and welder performance tests must be made annually in accordance with Section IX of the ASME Code. In addition to the essential variables named therein, the following must be considered to be essential variables: number of passes, thickness of plate, heat input per pass, and manufacturer's identification of rod and flux. The number of passes, Start Printed Page 63430thickness of plate and heat input per pass may not vary more than 25% from the procedure qualification. Records of the qualification must be retained for at least 5 years by the portable tank manufacturer and made available to the approval agency and the owner of the tank as specified in § 178.273.
(4) Impact tests must be made on a lot basis. A lot is defined as 100 tons or less of raw material of the same heat and having a thickness variation no greater than plus or minus 25%. The minimum impact required for full-sized specimens must be 20 foot-pounds (or 10 foot-pounds for half-sized specimens) at 0° F Charpy V-Notch in both the longitudinal and transverse direction. If the lot test does not pass this requirement, individual plates may be accepted if they individually meet this impact requirement.
(5) When the shells intended for the transportation of liquefied compressed gases are equipped with thermal insulation, a device must be provided to prevent any dangerous pressure from developing in the insulating layer in the event of a leak, when the protective covering is so closed as to be gas-tight. The thermal insulation must not inhibit access to the fittings and discharge devices. In addition, the thermal insulation systems must satisfy the following requirements:
(i) Consist of a shield covering not less than the upper third, but not more than the upper half of the surface of the shell, and separated from the shell by an air space of approximately 40 mm across; or
(ii) Consist of a complete cladding of insulating materials. The insulation must be of adequate thickness and constructed to prevent the ingress of moisture and damage to the insulation. The insulation and cladding must have a thermal conductance of not more than 0.67 (W·m−2·K−1) under normal conditions of transportation.
(c) Service equipment. (1) All openings with a diameter of more than 1.5 mm (.1 inch) in shells of portable tanks, except openings for pressure-relief devices, inspection openings and closed bleed holes, must be fitted with at least three mutually independent shut-off devices in series: the first being an internal stop-valve, excess flow valve, integral excess flow valve, or excess flow feature device (see § 178.337-1(g)), the second being an external stop-valve and the third being a blank flange or equivalent device.
(2) When a portable tank is fitted with an excess flow valve, the excess flow valve must be so fitted that its seating is inside the shell or inside a welded flange or, when fitted externally, its mountings must be designed so that in the event of impact it must maintain its effectiveness. The excess flow valves must be selected and fitted so as to close automatically when the rated flow specified by the manufacturer is reached. Connections and accessories leading to or from such a valve must have a capacity for a flow more than the excess flow valve's rated flow.
(3) For filling and discharge openings, the first shut-off device must be an internal stop-valve and the second must be a stop-valve placed in an accessible position on each discharge and filling pipe.
(4) For filling and discharge bottom openings of portable tanks intended for the transportation of flammable and/or toxic liquefied compressed gases, the internal stop-valve must be a quick closing safety device that closes automatically in the event of unintended movement of the portable tank during filling or discharge or fire engulfment. Except for portable tanks having a capacity of not more than 1,000 liters (264.2 gallons), it must be possible to operate this device by remote control.
(5) In addition to filling, discharge and gas pressure equalizing orifices, shells may have openings in which gauges, thermometers and manometers can be fitted. Connections for such instruments must be made by suitable welded nozzles or pockets and may not be connected by screwed connections through the shell.
(6) All portable tanks must be fitted with manholes or other inspection openings of suitable size to allow for internal inspection and adequate access for maintenance and repair of the interior.
(d) Bottom openings. Bottom openings are prohibited on portable tanks when the portable tank special provision T50 in § 172.102(c)(7) of this subchapter indicates that bottom openings are not allowed. In this case, there may be no openings located below the liquid level of the shell when it is filled to its maximum permissible filling limit.
(e) Pressure relief devices. (1) Portable tanks must be provided with one or more reclosing pressure relief devices. The pressure relief devices must open automatically at a pressure not less than the MAWP and be fully open at a pressure equal to 110% of the MAWP. These devices must, after discharge, close at a pressure not less than 10% below the pressure at which discharge starts and must remain closed at all lower pressures. The pressure relief devices must be of a type that will resist dynamic forces including liquid surge. A frangible disc may only be used in series with a reclosing pressure relief device.
(2) Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure.
(3) Portable tanks intended for the transportation of certain liquefied compressed gases identified in portable tank special provision T50 in § 172.102 of this subchapter must have a pressure relief device which conforms to the requirements of this subchapter. Unless a portable tank in dedicated service is fitted with a relief device constructed of materials compatible with the hazardous material, the relief device must comprise a frangible disc preceded by a reclosing device. The space between the frangible disc and the device must be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement must facilitate the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible discs must rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device.
(4) In the case of portable tanks used for more than one gas, the pressure relief devices must open at a pressure indicated in paragraph (f) of this section for the gas having the highest maximum allowable pressure of the gases allowed to be transported in the portable tank.
(f) Capacity of relief devices. The combined delivery capacity of the relief devices must be sufficient so that, in the event of total fire engulfment, the pressure inside the shell cannot exceed 120% of the MAWP. Reclosing relief devices must be used to achieve the full relief capacity prescribed. In the case of portable tanks used for more than gas, the combined delivery capacity of the pressure relief devices must be taken for the liquefied compressed gas which requires the highest delivery capacity of the liquefied compressed gases allowed to be transported in the portable tank. The total required capacity of the relief devices must be determined according to the requirements in § 178.275(h). These requirements apply only to liquefied compressed gases which have critical temperatures well above the temperature at the accumulating condition. For gases which have critical temperatures near or below the temperature at the accumulating condition, the calculation of the pressure relief device delivery capacity must consider the additional thermodynamic properties of the gas (for example, CGA S-1.2-1995; Start Printed Page 63431incorporated by reference, see § 171.7 of this subchapter).
64. A new § 178.277 would be added to subpart H to read as follows:
Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of refrigerated liquefied gases.(a) In addition to the requirements of § 178.274 applicable to UN portable tanks, the following requirements and definitions apply to UN portable tanks used for refrigerated liquefied gases:
(1) Design pressure. For the purpose of this section the term design pressure is consistent with the definition for design pressure in the ASME Code, Section VIII (incorporated by reference, see § 171.7 of this subchapter).
(2) Holding time is the time, as determined by testing, that will elapse from loading until the pressure of the contents, under equilibrium conditions, reaches the lowest set pressure of the pressure limiting device(s) (for example, pressure control valve or pressure relief device). Holding time must be determined as specified in § 178.338-9.
(3) Maximum allowable working pressure (MAWP) means the maximum effective gauge pressure permissible at the top of the shell of a loaded portable tank in its operating position including the highest effective pressure during filling and discharge;
(4) Minimum design temperature means the temperature which is used for the design and construction of the shell not higher than the lowest (coldest) service temperature of the contents during normal conditions of filling, discharge and transportation.
(5) Shell means the part of the portable tank which retains the refrigerated liquefied gas intended for transport, including openings and their closures, but does not include service equipment or external structural equipment.
(6) Tank means a construction which normally consists of either :
(i) A jacket and one or more inner shells where the space between the shell(s) and the jacket is exhausted of air (vacuum insulation) and may incorporate a thermal insulation system; or
(ii) A jacket and an inner shell with an intermediate layer of solid thermally insulating material (for example, solid foam).
(b) General design and construction requirements. (1) Portable tanks must be of seamless or welded steel construction and have a water capacity of more than 450 liters (118.9 gallons). Portable tanks must be designed, constructed, certified and stamped in accordance with the ASME Code (incorporated by reference, see § 171.7 of this subchapter).
(2) Portable tanks must be postweld heat treated and radiographed as prescribed in the ASME Code except that each tank constructed in accordance with part UHT of the ASME Code must be postweld heat treated. Where postweld heat treatment is required, the tank must be treated as a unit after completion of all the welds to the shell and heads. The method must be as prescribed in the ASME Code. Welded attachments to pads may be made after postweld heat treatment is made. The postweld heat treatment must be as prescribed in the ASME Code, but in no event at less than 1050 °F tank metal temperature.
(3) Welding procedure and welder performance tests must be made annually in accordance with Section IX of the ASME Code (incorporated by reference, see § 171.7 of this subchapter). In addition to the essential variables named in the ASME Code, the following must be considered as essential variables: number of passes, thickness of plate, heat input per pass, and the specified rod and flux. The number of passes, thickness of plate and heat input per pass may not vary more than 25% from the procedure qualification. Records of the qualification must be retained for at least 5 years by the portable tank manufacturer and made available to the approval agency and the owner of the portable tank as specified in § 178.273.
(4) Impact tests must be made on a lot basis. A lot is defined as 100 tons or less of the same heat and having a thickness variation no greater than plus or minus 25%. The minimum impact required for full-sized specimens must be 20 foot-pounds (or 10 foot-pounds for half-sized specimens) at 0 °F Charpy V-Notch in both the longitudinal and transverse direction. If the lot test does not pass this requirement, individual plates may be accepted if they individually meet this impact requirement.
(5) Shells and jackets must be made of metallic materials suitable for forming. Jackets must be made of steel. Non-metallic materials may be used for the attachments and supports between the shell and jacket, provided their material properties at the minimum design temperature are proven to be sufficient. In choosing the material, the minimum design temperature must be taken into account with respect to risk of brittle fracture, to hydrogen embrittlement, to stress corrosion cracking and to resistance to impact.
(6) Any part of a portable tank, including fittings, gaskets and pipe-work, which can be expected normally to come into contact with the refrigerated liquefied gas transported must be compatible with that refrigerated liquefied gas.
(7) The thermal insulation system must include a complete covering of the shell with effective insulating materials. External insulation must be protected by a jacket so as to prevent the ingress of moisture and other damage under normal transport conditions.
(8) When a jacket is so closed as to be gas-tight, a device must be provided to prevent any dangerous pressure from developing in the insulation space.
(9) Materials which may react with oxygen or oxygen enriched atmospheres in a dangerous manner may not be used in portable tanks intended for the transport of refrigerated liquefied gases having a boiling point below minus 182 °C at atmospheric pressure in locations with the thermal insulation where there is a risk of contact with oxygen or with oxygen enriched fluid.
(10) Insulating materials must not deteriorate unduly in service.
(11) A reference holding time must be determined for each refrigerated liquefied gas intended for transport in a portable tank. The reference holding time must be determined by testing in accordance with the requirements of § 178.338-9, considering the following factors:
(i) The effectiveness of the insulation system, determined in accordance with paragraph (b)(12) of this section;
(ii) The lowest set pressure of the pressure limiting device;
(iii) The initial filling conditions;
(iv) An assumed ambient temperature of 30 °C (86 °F);
(v) The physical properties of the individual refrigerated liquefied gas intended to be transported.
(12) The effectiveness of the insulation system (heat influx in watts) may be determined by type testing the portable tank in accordance with a procedure specified in § 178.338-9(c) or by using the holding time test in § 178.338-9(b). This test must consist of either:
(i) A constant pressure test (for example, at atmospheric pressure) when the loss of refrigerated liquefied gas is measured over a period of time; or
(ii) A closed system test when the rise in pressure in the shell is measured over a period of time.
(13) When performing the constant pressure test, variations in atmospheric pressure must be taken into account. When performing either test, corrections must be made for any variation of the ambient temperature from the assumed Start Printed Page 63432ambient temperature reference value of 30 °C (86 °F).
(14) The jacket of a vacuum-insulated double-wall tank must have either an external design pressure not less than 100 kPa (1 bar) gauge pressure calculated in accordance with the ASME Code or a calculated critical collapsing pressure of not less than 200 kPa (2 bar) gauge pressure. Internal and external reinforcements may be included in calculating the ability of the jacket to resist the external pressure.
Note to paragraph (b):
For the determination of the actual holding time as indicated by paragraphs (b)(11), (12) and (13) of this section, before each journey, refer to § 178.338-9(b).
(c) Design criteria. For shells with vacuum insulation, the test pressure must not be less than 1.3 times the sum of the MAWP and 100 kPa (1 bar). In no case may the test pressure be less than 300 kPa (3 bar) gauge pressure.
(d) Service equipment. (1) Each filling and discharge opening in portable tanks used for the transport of flammable refrigerated liquefied gases must be fitted with at least three mutually independent shut-off devices in series: the first being a stop-valve situated as close as reasonably practicable to the jacket, the second being a stop-valve and the third being a blank flange or equivalent device. The shut-off device closest to the jacket must be a quick closing device, which closes automatically in the event of unintended movement of the portable tank during filling or discharge or fire engulfment. This device must be operable by remote control.
(2) Each filling and discharge opening in portable tanks used for the transport of non-flammable refrigerated liquefied gases must be fitted with at least two mutually independent shut-off devices in series: the first being a stop-valve situated as close as reasonably practicable to the jacket and the second a blank flange or equivalent device.
(3) For sections of piping which can be closed at both ends and where liquid product can be trapped, a method of automatic pressure relief must be provided to prevent excess pressure build-up within the piping.
(4) Each connection on a portable tank must be clearly marked to indicate its function.
(5) When pressure-building units are used, the liquid and vapor connections to that unit must be provided with a valve as close to the jacket as reasonably practicable to prevent the loss of contents in case of damage to the pressure-building unit.
(6) The materials of construction of valves and accessories must have satisfactory properties at the lowest operating temperature of the portable tank.
(e) Pressure relief devices. (1) Every shell must be provided with not less than two independent reclosing pressure relief devices. The pressure relief devices must open automatically at a pressure not less than the MAWP and be fully open at a pressure equal to 110% of the MAWP. These devices must, after discharge, close at a pressure not lower than 10% below the pressure at which discharge starts and must remain closed at all lower pressures. The pressure relief devices must be of the type that will resist dynamic forces including surge.
(2) Except for portable tanks used for oxygen, portable tanks for non-flammable refrigerated liquefied gases (except oxygen) and hydrogen may in addition have frangible discs in parallel with the reclosing devices as specified in paragraphs (e)(4)(ii) and (e)(4)(iii) of this section.
(3) Pressure relief devices must be designed to prevent the entry of foreign matter, the leakage of gas and the development of any dangerous excess pressure.
(4) Capacity and setting of pressure relief devices. (i) In the case of the loss of vacuum in a vacuum-insulated tank or of loss of 20% of the insulation of a tank insulated with solid materials, the combined capacity of all pressure relief devices installed must be sufficient so that the pressure (including accumulation) inside the shell does not exceed 120% of the MAWP.
(ii) For non-flammable refrigerated liquefied gases (except oxygen) and hydrogen, this capacity may be achieved by the use of frangible discs in parallel with the required safety-relief devices. Frangible discs must rupture at nominal pressure equal to the test pressure of the shell.
(iii) Under the circumstances described in paragraphs (e)(4)(i) and (e)(4)(ii) of this section, together with complete fire engulfment, the combined capacity of all pressure relief devices installed must be sufficient to limit the pressure in the shell to the test pressure.
(iv) The required capacity of the relief devices must be calculated in accordance with CGA Pamphlet S-1-1.2 (incorporated by reference, see § 171.7 of this subchapter).
65. In § 178.703, paragraph (a)(1) introductory text would be revised and in paragraph (a)(1)(ii), a new sentence would be added at the end of the paragraph to read as follows:
Marking of intermediate bulk containers.(a) * * *
(1) Mark every IBC in a durable and clearly visible manner (may be applied in a single line or in multiple lines provided the correct sequence is followed) with the following information in letters, numerals and symbols of at least 12 mm in height and in the sequence presented:
* * * * *(ii) * * * The letter “W” must follow the IBC design type identification code on an IBC when the IBC differs from the requirements in subpart N of this part, or is tested using methods other than those specified in this subpart, and is approved by the Associate Administrator in accordance with the provisions in § 178.801(i).
* * * * *66. In § 178.705, paragraph (c)(1)(iv)(A) would be revised and a new paragraph (c)(1)(iv)(C) would be added to read as follows:
Standards for metal intermediate bulk containers.* * * * *(c) * * *
(1) * * *
(iv) * * *
(A) For a reference steel having a product of Rm X Ao = 10,000, where Ao is the minimum elongation (as a percentage) of the reference steel to be used on fracture under tensile stress, (Rm X Ao = 10,000 X 145; if tensile strength is in U.S. Standard units of pounds per square inch) the wall thickness must not be less than:
Capacity (C) in liters1 Wall thickness (T) in mm Types 11A, 11B, 11N Types 21A, 21B, 21N, 31A, 31B, 31N Unprotected Protected Unprotected Protected C ≤ 1000 2.0 1.5 2.5 2.0 1000 < C ≤ 2000 T=C/2000 + 1.5 T=C/2000 + 1.0 T=C/2000 + 2.0 T=C/2000 + 1.5 Start Printed Page 63433 2000 < C ≤ 3000 T=C/2000 + 1.5 T=C/2000 + 1.0 T=C/1000 + 1.0 T=C/2000 + 1.5 1 Where: gallons = liters × 0.264. * * * * *(C) For purposes of the calculation described in paragraph (c)(1)(iv)(B) of this section, the guaranteed minimum tensile strength of the metal to be used (Rm1) must be the minimum value according to material standards. However, for austenitic (stainless) steels, the specified minimum value for Rm, according to the material standards, may be increased by up to 15% when a greater value is provided in the material inspection certificate. When no material standard exists for the material in question, the value of Rm must be the minimum value indicated in the material inspection certificate.
* * * * *67. In § 178.801, in paragraph (i), two sentences would be added at the end of the paragraph to read as follows:
General requirements.* * * * *(i) * * * A large packaging, as defined in § 171.8 of this subchapter, may be used if approved by the Associate Administrator. The large packaging must conform to the construction standards, performance testing and packaging marking requirements specified in the UN Recommendations (incorporated by reference, see § 171.7 of this subchapter)
* * * * *68. In § 178.812, paragraph (c)(1) would be revised and a new paragraph (c)(3) would be added to read as follows:
Top lift test.* * * * *(c) Test method. (1) A metal or flexible IBC must be lifted in the manner for which it is designed until clear of the floor and maintained in that position for a period of five minutes.
* * * * *(3) If not tested as indicated in paragraph (c)(1) of this section, a flexible IBC design type must be tested as follows:
(i) Fill the flexible IBC to 95% full with a material representative of the product to be shipped.
(ii) Suspend the flexible IBC by its lifting devices.
(iii) Apply a constant downward force through a specially designed platen. The platen will be a minimum of 60% and a maximum of 80% of the cross sectional surface area of the flexible IBC.
(iv) The combination of the mass of the filled flexible IBC and the force applied through the platen must be a minimum of six times the maximum net mass of the flexible IBC. The test must be conducted for a period of five minutes.
(v) Other equally effective methods of top lift testing and preparation may be used with approval of the Associate Administrator.
* * * * *PART 180—CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS
69. The authority citation for part 180 would continue to read as follows:
70. Subpart G would be added to part 180 to read as follows:
Subpart G—Qualification and Maintenance of Portable Tanks
180.601 180.603 180.605Subpart G—Qualification and Maintenance of Portable Tanks
Applicability.This subpart prescribes requirements, in addition to those contained in parts 107, 171, 172, 173, and 178 of this subchapter, applicable to any person responsible for the continuing qualification, maintenance or periodic retesting of a portable tank.
Qualification of portable tanks.(a) Each portable tank used for the transportation of hazardous materials must be an authorized packaging.
(b) To qualify as an authorized packaging, each portable tank must conform to the requirements of this subchapter or the applicable specification to which the portable tank was constructed.
(c) The following portable tanks are authorized for use provided they conform to all applicable safety requirements of this subchapter: 51, 56, 57, 60, IM 101, IM 102 and UN portable tanks.
(d) A portable tank that also meets the definition of “container” in 49 CFR 450.3(a)(3) must conform to the requirements in parts 450 through 453 of this tile for compliance with Annex II of the Convention for Safe Containers (CSC).
(e) Exemption portable tanks based on DOT 51 portable tanks. The owner of a portable tank constructed in accordance with and used under an exemption issued prior to August 31, 1996, which was in conformance with the requirements for Specification DOT 51 portable tanks with the exception of the location of fill and discharge outlets, shall examine the portable tank and its design to determine if it meets the outlet requirements in effect on October 1, 1999. If the owner determines that the portable tank is in compliance with all requirements of the DOT 51 specification, the exemption number stenciled on the portable tank shall be removed and the specification plate (or a plate placed adjacent to the specification plate) shall be durably marked “DOT 51-E*****” (where ***** is to be replaced by the exemption number). During the period the portable tank is in service, and for one year thereafter, the owner of the portable tank must retain on file at its principal place of business a copy of the last exemption in effect.
Requirements for retest, inspection or repair of portable tanks.(a) A portable tank constructed in accordance with a DOT specification for which a test or inspection specified in this section has become due, may not be filled and offered for transportation or transported until the test or inspection has been successfully completed. This paragraph (a) does not apply to any portable tank filled prior to the test or inspection due date.
(b) Conditions requiring test and inspection of portable tanks. Without regard to any other test or inspection requirements, a Specification or UN portable tank must be tested and inspected in accordance with this section prior to further use if any of the following conditions exist:
(1) The portable tank shows evidence of bad dents, corroded or abraded areas, Start Printed Page 63434leakage, or any other condition that might render it unsafe for transportation service.
(2) The portable tank has been in an accident and has been damaged to an extent that may adversely affect its ability to retain the hazardous material.
(3) The portable tank has been out of hazardous materials transportation service for a period of one year or more.
(4) The portable tank has been modified from its original design specification.
(5) The Department so requires based on the existence of probable cause that the portable tank is in an unsafe operating condition.
(c) Schedule for initial and periodic inspections and tests. Each Specification portable tank must be tested and inspected in accordance with the following schedule:
(1) Each IM or UN portable tank must be given an initial inspection and test before being placed into service, a periodic inspection and test at least once every five years, and an intermediate periodic inspection and test at least every 2.5 years following the last five-year periodic inspection and test.
(2) Each Specification 51 portable tank must be given a periodic inspection and test at least once every five years.
(3) Each Specification 56 or 57 portable tank must be given a periodic inspection and test at least once every 2.5 years.
(4) Each Specification 60 portable tank must be given a periodic inspection and test at the end of the first 4-year period after the original test; at least once every 2 years thereafter up to a total of 12 years of service; and at least once annually thereafter. Retesting is not required on a rubber-lined tank except before each relining.
(d) Initial inspection and test. The initial inspection and test of a portable tank must include the following:
(1) A check of the design characteristics;
(2) An internal and external examination of the portable tank and its fittings, taking into account the hazardous materials to be transported;
(3) A hydrostatic pressure test as specified in paragraph (i) of this section;
(4) A leakage test;
(5) A test of the satisfactory operation of all service equipment including pressure relief devices must also be performed. When the shell and its fittings have been pressure-tested separately, they must be subjected to a leakage test after reassembly. All welds subject to full stress level in the shell must be inspected during the initial test by radiographic, ultrasonic, or another suitable non-destructive test method. This does not apply to the jacket;
(6) A UN portable tank that meets the definition of “container” in the CSC (see 49 CFR 450.3(a)(2)) must be subjected to an impact test using a prototype representing each design type. The prototype portable tank must be shown to be capable of absorbing the forces resulting from an impact not less than 4 times (4 g) the maximum permissable gross mass of the fully loaded portable tank at a duration typical of the mechanical shocks experienced in rail transportation. A listing of standards describing methods acceptable for performing the impact test are provided in the UN Recommendations (incorporated by reference, see § 171.7 of this subchapter);
(7) The following tests must be completed on a portable tank that is also a CSC container without leakage or deformation that would render the tank unsuitable for transportation and use:
(i) Longitudinal inertia. The tank loaded to its maximum gross weight must be positioned with its longitudinal axis vertical. It shall be held in this position for five minutes by support at the lower end of the base structure providing vertical and lateral restraint and by support at the upper end of the base structure providing lateral restraint only.
(ii) Lateral inertia. The tank loaded to its maximum gross weight must be positioned for five minutes with its transverse axis vertical. It shall be held in this position for five minutes by support at the lower side of the base structure providing vertical and lateral restraint and by support at the upper side of the base structure providing lateral restraint only.
(e) Intermediate periodic inspection and test. The intermediate periodic inspection and test must include at least an internal and external examination of the portable tank and its fittings taking into account the hazardous materials intended to be transported; a leakage test; and a test of the satisfactory operation of all service equipment. Sheathing, thermal insulation, etc. need only to be removed to the extent required for reliable appraisal of the condition of the portable tank. For portable tanks intended for the transportation of a single hazardous material, the internal examination may be waived if it is leakage tested in accordance with the procedures in paragraph (i) of this section prior to each filling, or if approved by the Associate Administrator.
(f) Periodic inspection and test. The periodic inspection and test must include an internal and external examination and, unless excepted, a hydraulic pressure test as specified in this section. Sheathing, thermal insulation, etc. need only to be removed to the extent required for reliable appraisal of the condition of the portable tank. Reclosing pressure relief devices must be removed from the tank and tested separately. For portable tanks where the shell and equipment have been pressure-tested separately, after assembly they must be subjected together to a leakage test.
(g) Exceptional inspection and test. The exceptional inspection and test is necessary when a portable tank shows evidence of damaged or corroded areas, or leakage, or other conditions that indicate a deficiency that could affect the integrity of the portable tank. The extent of the exceptional inspection and test must depend on the amount of damage or deterioration of the portable tank. It must include at least the intermediate inspection and a hydrostatic test according paragraph (e) of this section. Pressure relief devices need not be tested or replaced unless there is reason to believe the relief devices have been affected by the damage or deterioration.
(h) Internal and external examination. The internal and external examinations must ensure that:
(1) The shell is inspected for pitting, corrosion, or abrasions, dents, distortions, defects in welds or any other conditions, including leakage, that might render the portable tank unsafe for transportation;
(2) The piping, valves, and gaskets are inspected for corroded areas, defects, and other conditions, including leakage, that might render the portable tank unsafe for filling, discharge or transportation;
(3) Devices for tightening manhole covers are operative and there is no leakage at manhole covers or gaskets;
(4) Missing or loose bolts or nuts on any flanged connection or blank flange are replaced or tightened;
(5) All emergency devices and valves are free from corrosion, distortion and any damage or defect that could prevent their normal operation. Remote closure devices and self-closing stop-valves must be operated to demonstrate proper operation;
(6) Required markings on the portable tank are legible and in accordance with the applicable requirements; and
(7) The framework, the supports and the arrangements for lifting the portable tank are in satisfactory condition.
(i) Pressure test procedures for specification 51, 57, 60, IM or UN portable tanks. (1) Each Specification 57 portable tank must be leak tested by a Start Printed Page 63435minimum sustained air pressure of at least three psig applied to the entire tank. Each Specification 51 or 56 portable tank must be tested by a minimum pressure (air or hydrostatic) of at least 2 psig or at least one and one-half times the design pressure (maximum allowable working pressure, or re-rated pressure) of the tank, whichever is greater. Leakage tests for all other portable tanks must be at a pressure of at least 25% of MAWP. During each air pressure test, the entire surface of all joints under pressure must be coated with or immersed in a solution of soap and water, heavy oil, or other material suitable for the purpose of detecting leaks, but in no case less than five minutes. The pressure must be held for a period of time sufficiently long to assure detection of leaks. During the air or hydrostatic test, relief devices may be removed, but all the closure fittings must be in place and the relief device openings plugged. Lagging need not be removed from a lagged tank if it is possible to maintain the required test pressure at constant temperature with the tank disconnected from the source of pressure.
(2) Each Specification 60 portable tank must be retested by completely filling the tank with water or other liquid having a similar viscosity, the temperature of which shall not exceed 100 °F during the test, and applying a pressure of 60 psig. The tank shall be capable of holding the prescribed pressure for at least 10 minutes without leakage, evidence of impending failure, or failure. All closures shall be in place while the test is made and the pressure shall be gauged at the top of the tank. Safety devices and/or vents shall be plugged during this test.
(3) Each Specification IM or UN portable tank, except for UN portable tanks used for liquefied compressed gases and all piping, valves and accessories, except pressure relief devices, must be hydrostatically tested with water, or other liquid of similar density and viscosity, to a pressure not less than 150% of its maximum allowable working pressure. UN portable tanks used for liquefied compressed gases must be hydrostatically tested with water, or other liquid of similar density and viscosity, to a pressure not less than 130% of its maximum allowable working pressure. The minimum test pressure for a portable tank is determined on the basis of the hazardous materials that are intended to be transported in the tanks. Minimum test pressure for specific hazardous materials are specified in the applicable T Codes assigned to a particular hazardous material in the § 172.101 Table of this subchapter. While under pressure the tank shall be inspected for leakage, distortion, or any other condition which might render the tank unsafe for service. A portable tank fails to meet the requirements of the pressure test if, during the test, there is permanent distortion of the tank exceeding that permitted by the applicable specification; if there is any leakage; or if there are any deficiencies. Any portable tank that fails must be rejected and may not be used again for the transportation of a hazardous material unless the tank is adequately repaired, and, thereafter, a successful test is conducted in accordance with the requirements of this paragraph. An approval agency shall witness the hydrostatic test. Any damage or deficiency that might render the portable tank unsafe for service shall be repaired to the satisfaction of the witnessing approval agency. The repaired tank must be hydrostatically retested. Upon successful completion of the hydrostatic test, the witnessing approval agency shall apply its name, identifying mark or identifying number in accordance with paragraph (l) of this section.
(j) Rejection criteria. When evidence of any unsafe condition is discovered, the portable tank may not be returned to service until it has been corrected and the pressure test is repeated and passed.
(k) Repair. The repair of a portable tank is authorized, provided such repairs are made in accordance with the requirements prescribed in the specification for the tank's original design and construction. In addition to any other provisions of the specification, no portable tank may be repaired so as to cause leakage or cracks or the likelihood of leakage or cracks near areas of stress concentration due to cooling metal shrinkage in welding operations, sharp fillets, reversal of stresses, or otherwise. No field welding may be done except to non-pressure parts. In all cases, when cutting, burning or welding operations on the shell have been affected, that work must be done with the approval of the approval agency and be done in accordance with the requirements of this subchapter, taking into account the pressure vessel code used for the construction of the shell. A pressure test to the original test pressure must be performed after the work is completed.
(l) Inspection and test markings. Each portable tank must be durably and legibly marked, in English, with the date (month and year) of the last hydrostatic test, the identification markings of the approval agency witnessing the test when required, and the date of the last visual inspection. The marking must be placed on or near the metal identification plate in letters not less than 3 mm (0.118 inches) high when on the metal identification plate and 32 mm (1.25 inches) high when on the portable tank.
(m) Record retention. The owner of each portable tank or his authorized agent shall retain a written record of the date and results of all required inspections and tests, and the name and address of the person performing the inspection or test, until the next retest has been satisfactorily completed and recorded. In addition, a manufacturer's data report of the portable tank must be procured and retained in the files of the owner during the time that such portable tank is used for such service, except for Specifications 56 and 57 portable tanks.
Issued in Washington, DC on August 16, 2000, under authority delegated in 49 CFR part 106.
Robert A. McGuire,
Associate Administrator for Hazardous Materials Safety.
[FR Doc. 00-21417 Filed 10-20-00; 8:45 am]
BILLING CODE 4910-60-P
Document Information
- Published:
- 10/23/2000
- Department:
- Research and Special Programs Administration
- Entry Type:
- Proposed Rule
- Action:
- Notice of proposed rulemaking (NPRM).
- Document Number:
- 00-21417
- Dates:
- Comments must be received by December 22, 2000.
- Pages:
- 63293-63435 (143 pages)
- Docket Numbers:
- Docket No. RSPA-2000-7702 (HM-215D)
- RINs:
- 2137-AD41: Harmonization With United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions
- RIN Links:
- https://www.federalregister.gov/regulations/2137-AD41/harmonization-with-united-nations-recommendations-international-maritime-dangerous-goods-code-and-in
- Topics:
- Air carriers, Education, Exports, Hazardous materials transportation, Hazardous waste, Imports, Incorporation by reference, Labeling, Maritime carriers, Motor carriers, Motor vehicle safety, Packaging and containers, Radioactive materials, Railroad safety, Reporting and recordkeeping requirements, Uranium
- PDF File:
- 00-21417.pdf
- CFR: (61)
- 49 CFR 171.7
- 49 CFR 171.8
- 49 CFR 171.10
- 49 CFR 171.11
- 49 CFR 171.12
- More ...