2024-22966. Addition of Certain Per- and Polyfluoroalkyl Substances (PFAS) to the Toxics Release Inventory (TRI)  

  • Table 1 to Paragraph ( a )(1)

    Chemical name CAS No. Reporting threshold (in pounds)
    *         *         *         *         *         *         *
    Per- and polyfluoroalkyl substances (Individually listed chemicals added by 15 U.S.C. 8921(b)(1) and (c)(1) and pursuant to 42 U.S.C. 11023(d)(2)). (EPA periodically updates the lists of covered chemicals at § 372.65(d) and (e) to reflect chemicals that have been added by 15 U.S.C. 8921) see § 372.65(d) and (e). 100
    *         *         *         *         *         *         *

    (2) * * *

    Table 2 to Paragraph ( a )(2)

    Category name Reporting threshold (in pounds)
    *         *         *         *         *         *         *
    Per- and polyfluoroalkyl substances (Chemical categories added by 15 U.S.C. 8921 (b)(1) and (c)(1) and pursuant to 42 U.S.C. 11023(d)(2)). (EPA periodically updates the lists of covered chemicals at § 372.65(f) to reflect chemical categories that have been added by 15 U.S.C. 8921) 100
    *         *         *         *         *         *         *

    3. Amend § 372.65 by:

    a. Revising the introductory text;

    b. In table 4 to paragraph (d):

    i. Removing the entries for “Ammonium perfluorobutanoate”; “Ammonium perfluorooctanoate”; “Chromium(III) perfluorooctanoate”; “Ethanaminium, N,N,N-triethyl-, salt with 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-1-octanesulfonic acid (1:1)”; “Hexafluoropropylene oxide dimer acid”; “Hexafluoropropylene oxide dimer acid ammonium salt”; “1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, ammonium salt”; “1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, potassium salt”; “1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, compd. with 2,2'-iminobis[ethanol] (1:1)”; “Lithium (perfluorooctane)sulfonate”; “1-Octanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ammonium salt”; “Octanoyl fluoride, pentadecafluoro-”; “Perfluorobutane sulfonic acid”; “Perfluorobutanesulfonate”; “Perfluorobutanoate”; “Perfluorobutanoic acid”; “Perfluorodecanoic acid”; “Perfluorododecanoic acid”; “Perfluorohexanesulfonic acid”; “Perfluorononanoic acid”; “Perfluorooctane sulfonic acid”; and “Perfluorooctanoic acid”; “Perfluorooctylsulfonyl fluoride”; “Potassium heptafluorobutanoate”; “Potassium perfluorobutane sulfonate”; “Potassium perfluorooctanesulfonate”; “Potassium perfluorooctanoate”; “Silver(I) perfluorooctanoate”; “Sodium perfluorobutanoate”; and “Sodium perfluorooctanoate”;

    ii. Adding, in alphabetical order, entries for “Broflanilide”; “1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(2-hydroxyethyl)-N-methyl-”; “1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl-”; “Cyclopentene, 1,3,3,4,4,5,5-heptafluoro-”; “Ethanesulfonamide, 1,1,2,2,2-pentafluoro-N-[(pentafluoroethyl)sulfonyl]-, lithium salt”; “6:2 Fluorotelomer alcohol”; “Fulvestrant”; “Hexaflumuron”; “Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-”; “Perfluorotridecanoic acid”; “Perfluoro(2-ethoxy-2-fluoroethoxy)acetic acid ammonium salt”; “2-Propenoic acid, 2-[methyl[(nonafluorobutyl)sulfonyl]amino]ethyl ester”; “Pyrifluquinazon”; “Tetraconazole”; “Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tri-deca-fluorooctyl)silane”; and “Trifluoro(trifluoromethyl) oxirane”;

    c. In table 5 to paragraph (e):

    i. Removing the entries for “307-35-7”; “307-55-1”; “335-66-0”; “335-67-1”; “335-76-2”; “335-93-3”; “335-95-5”; “355-46-4”; “375-22-4”; “375-73-5”; “375-95-1”; “1763-23-1”; “2218-54-4”; “2395-00-8”; “2795-39-3”; “2966-54-3”; “3825-26-1”; “3871-99-6”; “10495-86-0”; “13252-13-6”; “29081-56-9”; “29420-49-3”; “29457-72-5”; “45048-62-2”; “45187-15-3”; “56773-42-3”; “62037-80-3”; “68141-02-6”; “68259-08-5”; and “70225-16-0”;

    ii. Adding, in numerical order, the entries for “428-59-1”; “647-42-7”; “1892-03-1”; “34454-97-2”; “51851-37-7”; “67584-55-8”; “68298-12-4”; “72629-94-8”; “86479-06-3”; “112281-77-3”; “129453-61-8”; “132182-92-4”; “132843-44-8”; “337458-27-2”;“908020-52-0”; and “1207727-04-5”; and

    d. Adding paragraph (f).

    The revisions and additions read as follows:

    Chemicals and chemical categories to which this part applies.

    The requirements of this part apply to the chemicals and chemical categories listed in this section. This section contains six listings. Paragraph (a) of this section is an alphabetical order listing of those chemicals that have an associated Chemical Abstracts Service (CAS) Registry number. Paragraph (b) of this section contains a CAS number order list of the same chemicals listed in paragraph (a) of this section. Paragraph (c) of this section contains the chemical categories for which reporting is required. These chemical categories are listed in alphabetical order and do not have CAS numbers. Paragraph (d) of this section is an alphabetical order listing of the per- and polyfluoroalkyl substances and their associated CAS Registry number. Paragraph (e) of this ( print page 81811) section contains a CAS number order list of the same chemicals listed in paragraph (d) of this section. Each listing identifies the effective date for reporting under § 372.30. Paragraph (f) of this section is an alphabetical order listing of the per- and polyfluoroalkyl substances chemical categories for which reporting is required. Per- and polyfluoroalkyl substances automatically added to the list of chemicals for which reporting is required pursuant to the Fiscal Year 2020 National Defense Authorization Act, section 7321(c), shall be incorporated as chemical categories to include the acid and associated salts, acyl/sulfonyl halides, and anhydride of that acid if added pursuant to a published final toxicity value that provides toxicity values for an acid and associated salts and/or acyl/sulfonyl halides and/or anhydride.

    * * * * *

    (d) * * *

    Table 4 to Paragraph ( d )

    Chemical name CAS No. Effective date
    *         *         *         *         *         *         *
    Broflanilide 1207727-04-5 1/1/2025
    *         *         *         *         *         *         *
    1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(2-hydroxyethyl)-N-methyl- 34454-97-2 1/1/2025
    *         *         *         *         *         *         *
    1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl- 68298-12-4 1/1/2025
    *         *         *         *         *         *         *
    Cyclopentene, 1,3,3,4,4,5,5-heptafluoro- 1892-03-1 1/1/2025
    *         *         *         *         *         *         *
    Ethanesulfonamide, 1,1,2,2,2-pentafluoro-N-[(pentafluoroethyl)sulfonyl]-, lithium salt 132843-44-8 1/1/2025
    *         *         *         *         *         *         *
    6:2 Fluorotelomer alcohol 647-42-7 1/1/2025
    *         *         *         *         *         *         *
    Fulvestrant 129453-61-8 1/1/2025
    *         *         *         *         *         *         *
    Hexaflumuron 86479-06-3 1/1/2025
    *         *         *         *         *         *         *
    Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)- 132182-92-4 1/1/2025
    *         *         *         *         *         *         *
    Perfluorotridecanoic acid 72629-94-8 1/1/2025
    *         *         *         *         *         *         *
    Perfluoro(2-ethoxy-2-fluoroethoxy)acetic acid ammonium salt 908020-52-0 1/1/2025
    *         *         *         *         *         *         *
    2-Propenoic acid, 2-[methyl[(nonafluorobutyl)sulfonyl]amino]ethyl ester 67584-55-8 1/1/2025
    *         *         *         *         *         *         *
    Pyrifluquinazon 337458-27-2 1/1/2025
    *         *         *         *         *         *         *
    Tetraconazole 112281-77-3 1/1/2025
    *         *         *         *         *         *         *
    Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-tri-deca-fluorooctyl)silane 51851-37-7 1/1/2025
    *         *         *         *         *         *         *
    Trifluoro(trifluoromethyl) oxirane 428-59-1 1/1/2025
    *         *         *         *         *         *         *

    (e) * * *

    ( print page 81812)

    Table 5 to Paragraph ( e )

    CAS No. Chemical name Effective date
    *         *         *         *         *         *         *
    428-59-1 Trifluoro(trifluoromethyl) oxirane 1/1/2025
    *         *         *         *         *         *         *
    647-42-7 6:2 Fluorotelomer alcohol 1/1/2025
    *         *         *         *         *         *         *
    1892-03-1 Cyclopentene, 1,3,3,4,4,5,5-heptafluoro- 1/1/2025
    *         *         *         *         *         *         *
    34454-97-2 1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-(2-hydroxyethyl)-N-methyl- 1/1/2025
    *         *         *         *         *         *         *
    51851-37-7 Triethoxy(3,3,4,4,5,5,6,6,7,7,8,8,8-trideca-fluorooctyl)silane 1/1/2025
    *         *         *         *         *         *         *
    67584-55-8 2-Propenoic acid, 2-[methyl[(nonafluorobutyl)sulfonyl]amino]ethyl ester 1/1/2025
    *         *         *         *         *         *         *
    68298-12-4 1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-nonafluoro-N-methyl- 1/1/2025
    *         *         *         *         *         *         *
    72629-94-8 Perfluorotridecanoic acid 1/1/2025
    *         *         *         *         *         *         *
    86479-06-3 Hexaflumuron 1/1/2025
    *         *         *         *         *         *         *
    112281-77-3 Tetraconazole 1/1/2025
    *         *         *         *         *         *         *
    129453-61-8 Fulvestrant 1/1/2025
    *         *         *         *         *         *         *
    132182-92-4 Pentane, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)- 1/1/2025
    *         *         *         *         *         *         *
    132843-44-8 Ethanesulfonamide, 1,1,2,2,2-pentafluoro-N-[(pentafluoroethyl)sulfonyl]-, lithium salt 1/1/2025
    *         *         *         *         *         *         *
    337458-27-2 Pyrifluquinazon 1/1/2025
    *         *         *         *         *         *         *
    908020-52-0 Perfluoro(2-ethoxy-2-fluoroethoxy)acetic acid ammonium salt 1/1/2025
    *         *         *         *         *         *         *
    1207727-04-5 Broflanilide 1/1/2025
    *         *         *         *         *         *         *

    (f) Per- and polyfluoroalkyl chemical category listing.

    Table 6 to Paragraph ( f )

    Category name Effective date
    9-chlorohexadecafluoro-3-oxanone-1-sulfonic acid (9Cl-PF3ONS) (CASRN 756426-58-1), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following): 1/1/2025
    73606-19-6: potassium 9-chlorohexadecafluoro-3-oxanonane-1 sulfonate
    11-chloroeicosafluoro-3-oxaundecane-1-sulfonic acid (11Cl-PF3OUdS) (CASRN 763051-92-9), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following): 1/1/2025
    83329-89-9: potassium 11-chloroeicosafluoro-3-oxaundecane-1-sulfonate
    Hexafluoropropylene oxide dimer acid (HFPO-DA, GenX) (CASRN 13252-13-6), salts, and acyl halides (includes all associated salts and acyl halides, including the following): 1/1/2025
    2062-98-8: propanoyl fluoride, 2,3,3,3-tetrafluoro-2 (heptafluoropropoxy)-]
    62037-80-3: ammonium perfluoro-2-methyl-3-oxahexanoate
    67118-55-2: potassium 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy)propanoate
    ( print page 81813)
    67963-75-1: sodium 2,3,3,3-tetrafluoro-2(heptafluoropropoxy)propanoate
    Perfluorobutanesulfonic acid (PFBS), salts, sulfonyl halides, and anhydride (CASRN 375-73-5) (includes all associated salts and sulfonyl halides, including the following): 1/1/2025
    375-72-4: perfluorobutanesulfonyl fluoride
    29420-49-3: potassium perfluorobutane sulfonate
    36913-91-4: perfluorobutanesulfonic anhydride
    60453-92-1: sodium nonafluorobutane-1-sulfonate
    68259-10-9: ammonium perfluorobutanesulfonate
    70225-18-2: bis(2-hydroxyethyl)ammonium perfluorobutanesulfonate
    131651-65-5: lithium nonafluorobutane-1-sulfonate
    220689-12-3: tetrabutylphosphonium perfluorobutanesulfonate
    507453-86-3: magnesium nonafluorobutanesulfonate
    Perfluorobutanoic acid (PFBA) (CASRN 375-22-4), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    335-42-2: perfluorobutanoyl fluoride
    336-59-4: perfluorobutanoic anhydride
    375-16-6: heptafluorobutyryl chloride
    2218-54-4: sodium perfluorobutanoate
    2966-54-3: potassium perfluorobutanoate
    3794-64-7: silver heptafluorobutyrate
    10495-86-0: ammonium perfluorobutanoate
    73755-28-9: rhodium(II) perfluorobutyrate dimer
    Perfluorodecanoic acid (PFDA) (CASRN 335-76-2), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    307-38-0: perfluorodecanoyl chloride
    3108-42-7: ammonium Perfluorodecanoate
    3830-45-3: sodium Perfluorodecanoate
    942199-24-8: perfluorodecanoic anhydride
    Perfluorododecanoic acid (PFDoA) (CASRN 307-55-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    3793-74-6: ammonium tricosafluorododecanoate
    1456735-80-0: perfluorododecanoic anhydride
    Perfluorohexanesulfonic acid (PFHxS) (CASRN 355-46-4), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following): 1/1/2025
    423-50-7: perfluorohexanesulfonyl fluoride
    3871-99-6: potassium perfluorohexanesulfonate
    55120-77-9: lithium perfluorohexanesulfonate
    68259-08-5: ammonium perfluorohexanesulfonate
    70225-16-0: bis(2-hydroxyethyl)ammonium perfluorohexanesulfonate
    82382-12-5: sodium perfluorohexanesulfonate
    109065-55-6: perfluorohexanesulfonic anhydride
    Perfluorohexanoic acid (PFHxA) (CASRN 307-24-4), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    308-13-4: perfluorohexanoic anhydride
    336-02-7: silver perfluorohexanoate
    355-38-4: perfluorohexanoyl fluoride
    335-53-5: perfluorohexanoyl chloride
    2923-26-4: sodium perfluorohexanoate
    3109-94-2: potassium undecafluorohexanoate
    21615-47-4: ammonium perfluorohexanoate
    Perfluorononanoic acid (PFNA) (CASRN 375-95-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    558-95-2: heptadecafluorononanoyl fluoride
    4149-60-4: ammonium perfluorononanoate
    21049-38-7: potassium perfluorononanoate
    21049-39-8: sodium heptadecafluorononanoate
    52447-23-1: heptadecafluorononanoyl chloride
    228407-54-3: perfluorononanoic anhydride
    1H,1H, 2H, 2H-Perfluorooctane sulfonic acid (6:2 FTS) (CASRN 27619-97-2), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following): 1/1/2025
    2043-57-4: 1H,1H,2H,2H-Perfluorooctyl iodide
    27619-89-2: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonyl chloride
    27619-94-9: sodium 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctane-1-sulfonate
    59587-38-1: potassium 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulfonate
    59587-39-2: 6:2 fluorotelomer sulfonate ammonium
    1807944-82-6: 1-octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-, barium salt (2:1)
    Perfluorooctanoic acid (PFOA) (CASRN 335-67-1), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    335-64-8: pentadecafluorooctanoyl chloride
    335-66-0: pentadecafluorooctanoyl fluoride
    335-93-3: silver perfluorooctanoate
    335-95-5: sodium perfluorooctanoate
    ( print page 81814)
    2395-00-8: potassium perfluorooctanoate
    3825-26-1: ammonium perfluorooctanoate
    17125-58-5: lithium perfluorooctanoate
    17125-60-9: cesium perfluorooctanoate
    33496-48-9: perfluorooctanoic anhydride
    68141-02-6: chromium perfluorooctanoate
    98065-31-7: potassium pentadecafluorooctanoate—water (1:1:2)
    Perfluorooctanesulfonic acid (PFOS) (CASRN 1763-23-1), salts, sulfonyl halides, and anhydride (includes all associated salts and sulfonyl halides, including the following): 1/1/2025
    307-35-7: perfluorooctylsulfonyl fluoride
    423-92-7: perfluorooctanesulfonic anhydride
    2795-39-3: potassium perfluorooctanesulfonate
    4021-47-0: sodium perfluorooctanesulfonate
    29081-56-9: ammonium perfluorooctanesulfonate
    29457-72-5: lithium perfluorooctanesulfonate
    56773-42-3: tetraethylammonium perfluorooctanesulfonate
    70225-14-8: 1-octanesulfonic acid,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, compd with 2,2'-iminobis[ethanol] (1:1)
    91036-71-4: magnesium bis(heptadecafluorooctanesulfonate)
    111873-33-7: tetrabutylammonium perfluorooctanesulfonate
    Perfluoropropanoic acid (PFPrA) (CASRN 422-64-0), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    356-42-3: pentafluoropropanoic anhydride
    378-76-7: potassium perfluoropropanoate
    378-77-8: sodium perfluoropropanoate
    422-59-3: perfluoropropanoyl chloride
    422-61-7: perfluoropropanoyl fluoride
    Perfluoroundecanoic acid (PFUnA) (CASRN 2058-94-8), salts, acyl halides, and anhydride (includes all associated salts and acyl halides, including the following): 1/1/2025
    4234-23-5: ammonium perfluoroundecanoate
    30377-53-8: potassium perfluoroundecanoate
    60871-96-7: sodium perfluoroundecanoate
    97163-17-2: calcium perfluoroundecanoate
    942199-03-3: perfluoroundecanoic anhydride

Document Information

Published:
10/08/2024
Department:
Environmental Protection Agency
Entry Type:
Proposed Rule
Action:
Proposed rule.
Document Number:
2024-22966
Dates:
Comments must be received on or before December 9, 2024. Comments on the information collection provisions submitted to the Office of Management and Budget (OMB) under the Paperwork Reduction Act (PRA) are best assured of consideration by OMB if OMB receives a copy of your comments on or before November 7, 2024.
Pages:
81776-81814 (39 pages)
Docket Numbers:
EPA-HQ-OPPT-2023-0538, FRL-9313-01-OCSPP
RINs:
2070-AL03: Addition of Certain Per- and Polyfluoroalkyl Substances (PFAS) to the Toxics Release Inventory (TRI)
RIN Links:
https://www.federalregister.gov/regulations/2070-AL03/addition-of-certain-per-and-polyfluoroalkyl-substances-pfas-to-the-toxics-release-inventory-tri-
Topics:
Environmental protection, Reporting and recordkeeping requirements
PDF File:
2024-22966.pdf
Supporting Documents:
» PFAS Explained US EPA website
» Health Effects Support Document for Perfluorooctane Sulfonate (PFOS)
» The ECOTOXicology Knowledgebase: A Curated Database of Ecologically Relevant Toxicity Tests to Support Environmental Research and Risk Assessment
» Human Health Hazard TRI Listing Support Document for Perfluoroundecanoic Acid (PFUnA; CASRN 2058-94-8)
» Chronic exposure to 6:2 chlorinated polyfluorinated ether sulfonate acid (F-53B) induced hepatotoxic effects in adult zebrafish and disrupted the PPAR signaling pathway in their offspring
» Yi et al. Probing the Hepatotoxicity Mechanisms of Novel Chlorinated Polyfluoroalkyl Sulfonates to Zebrafish Larvae: Implication of Structural Specificity
» Prediction of Aqueous Solubility, Vapor Pressure and Critical Micelle Concentration for Aquatic Partitioning of Perfluorinated Chemicals
» Japanese patent
» Background document to the Opinion on the Annex XV dossier proposing restrictions on Perfluorooctanoic acid (PFOA), PFOA salts and PFOA-related substances
» A Review of bioconcentration and bioaccumulation assessments for organic chemicals in aquatic organisms