98-30272. National Recommended Water Quality Criteria; Republication  

  • [Federal Register Volume 63, Number 237 (Thursday, December 10, 1998)]
    [Notices]
    [Pages 68354-68364]
    From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
    [FR Doc No: 98-30272]
    
    
    
    [[Page 68353]]
    
    _______________________________________________________________________
    
    Part IV
    
    
    
    
    
    Environmental Protection Agency
    
    
    
    
    
    _______________________________________________________________________
    
    
    
    National Recommended Water Quality Criteria; Notice; Republication
    
    Federal Register / Vol. 63, No. 237 / Thursday, December 10, 1998 / 
    Notices
    
    [[Page 68354]]
    
    
    
    ENVIRONMENTAL PROTECTION AGENCY
    
    [FRL-OW-6186-6a]
    
    
    National Recommended Water Quality Criteria; Republication
    
        Editorial Note: FR Doc. 98-30272 was originally published as 
    Part IV (63 FR 67548-67558) in the issue of Monday, December 7, 
    1998. At the request of the agency, due to incorrect footnote 
    identifiers in the tables, the corrected document is being 
    republished in its entirety.
    AGENCY: Environmental Protection Agency (EPA).
    
    ACTION: Compilation of recommended water quality criteria and notice of 
    process for new and revised criteria.
    
    -----------------------------------------------------------------------
    
    SUMMARY: EPA is publishing a compilation of its national recommended 
    water quality criteria for 157 pollutants, developed pursuant to 
    section 304(a) of the Clean Water Act (CWA or the Act). These 
    recommended criteria provide guidance for States and Tribes in adopting 
    water quality standards under section 303(c) of the CWA. Such standards 
    are used in implementing a number of environmental programs, including 
    setting discharge limits in National Pollutant Discharge Elimination 
    System (NPDES) permits. These water quality criteria are not 
    regulations, and do not impose legally binding requirements on EPA, 
    States, Tribes or the public.
        This document also describes changes in EPA's process for deriving 
    new and revised 304(a) criteria. Comments provided to the Agency about 
    the content of this Notice will be considered in future publications of 
    water quality criteria and in carrying out the process for deriving 
    water quality criteria. With this improved process the public will have 
    more opportunity to provide data and views for consideration by EPA. 
    The public may send any comments or observations regarding the 
    compilation format or the process for deriving new or revised water 
    quality criteria to the Agency now, or anytime while the process is 
    being implemented.
    
    ADDRESSES: A copy of the document, ``National Recommended Water Quality 
    Criteria'' is available from the U.S. EPA, National Center for 
    Environmental Publications and Information, 11029 Kenwood Road, 
    Cincinnati, Ohio 45242, phone (513) 489-8190. The publication is also 
    available electronically at: http://www.epa.gov/ost. Send an original 
    and 3 copies of written comments to W-98-24 Comment Clerk, Water 
    Docket, MC 4104, US EPA, 401 M Street, S.W., Washington, D.C. 20460. 
    Comments may also be submitted electronically to OW-
    Docket@epamail.epa.gov. Comments should be submitted as a WP5.1, 6.1 or 
    an ASCII file with no form of encryption. The documents cited in the 
    compilation of recommended criteria are available for inspection from 9 
    to 4 p.m., Monday through Friday, excluding legal holidays, at the 
    Water Docket, EB57, East Tower Basement, USEPA, 401 M St., S.W., 
    Washington, D.C. 20460. For access to these materials, please call 
    (202) 260-3027 to schedule an appointment.
    
    FOR FURTHER INFORMATION CONTACT: Cindy A. Roberts, Health and 
    Ecological Criteria Division (4304), U.S. EPA, 401 M. Street, S.W., 
    Washington, D.C. 20460; (202) 260-2787; roberts.cindy@epamail.epa.gov.
    
    SUPPLEMENTARY INFORMATION:
    
    I. What Are Water Quality Criteria?
    
        Section 304(a)(1) of the Clean Water Act requires EPA to develop 
    and publish, and from time to time revise, criteria for water quality 
    accurately reflecting the latest scientific knowledge. Water quality 
    criteria developed under section 304(a) are based solely on data and 
    scientific judgments on the relationship between pollutant 
    concentrations and environmental and human health effects. Section 
    304(a) criteria do not reflect consideration of economic impacts or the 
    technological feasibility of meeting the chemical concentrations in 
    ambient water. Section 304(a) criteria provide guidance to States and 
    Tribes in adopting water quality standards that ultimately provide a 
    basis for controlling discharges or releases of pollutants. The 
    criteria also provide guidance to EPA when promulgating federal 
    regulations under section 303(c) when such action is necessary.
    
    II. What is in the Compilation Published Today?
    
        EPA is today publishing a compilation of its national recommended 
    water quality criteria for 157 pollutants. This compilation is also 
    available in hard copy at the address given above.
        The compilation is presented as a summary table containing EPA's 
    water quality criteria for 147 pollutants, and for an additional 10 
    pollutants, criteria solely for organoleptic effects. For each set of 
    criteria, EPA lists a Federal Register citation, EPA document number or 
    Integrated Risk Information System (IRIS) entry (www.epa.gov/ngispgm3/
    iris/irisdat). Specific information pertinent to the derivation of 
    individual criteria may be found in cited references. If no criteria 
    are listed for a pollutant, EPA does not have any national recommended 
    water quality criteria.
        These water quality criteria are the Agency's current recommended 
    304(a) criteria, reflecting the latest scientific knowledge. They are 
    generally applicable to the waters of the United States. EPA recommends 
    that States and Tribes use these water quality criteria as guidance in 
    adopting water quality standards pursuant to section 303(c) of the Act 
    and the implementing of federal regulations at 40 CFR part 131. Water 
    quality criteria derived to address site-specific situations are not 
    included; EPA recommends that States and Tribes follow EPA's technical 
    guidance in the ``Water Quality Standards Handbook--2nd Edition,'' EPA, 
    August 1994, in deriving such site-specific criteria. EPA recognizes 
    that in limited circumstances there may be regulatory voids in the 
    absence of State or Tribal water quality standards for specific 
    pollutants. However, States and Tribes should utilize the existing 
    State and Tribal narrative criteria to address such situations; States 
    and Tribes may consult EPA criteria documents and cites in the summary 
    table for additional information.
        The national recommended water quality criteria include: previously 
    published criteria that are unchanged; criteria that have been 
    recalculated from earlier criteria; and newly calculated criteria, 
    based on peer-reviewed assessments, methodologies and data, that have 
    not been previously published.
        The information used to calculate the water quality criteria is not 
    included in the summary table. Most information has been previously 
    published by the Agency in a variety of sources, and the summary table 
    cites those sources.
        When using these 304(a) criteria as guidance in adopting water 
    quality standards, EPA recommends States and Tribes consult the 
    citations referenced in the summary table for additional information 
    regarding the derivation of individual criteria.
        The Agency intends to revise the compilation of national 
    recommended water quality criteria from time to time to keep States and 
    Tribes informed as to the most current recommended water quality 
    criteria.
    
    III. How Are National Recommended Water Quality Criteria Used?
    
        Once new or revised 304(a) criteria are published by EPA, the 
    Agency expects States and Tribes to adopt promptly new or revised 
    numeric water quality criteria into their standards consistent with one 
    of the three options
    
    [[Page 68355]]
    
    in 40 CFR 131.11. These options are: (1) Adopt the recommended section 
    304(a) criteria; (2) adopt section 304(a) criteria modified to reflect 
    site-specific conditions; or, (3) adopt criteria derived using other 
    scientifically defensible methods. In adopting criteria under option 
    (2) or (3), States and Tribes must adopt water quality criteria 
    sufficient to protect the designated uses of their waters. When 
    establishing a numerical value based on 304(a) criteria, States and 
    Tribes may reflect site specific conditions or use other scientifically 
    defensible methods. However, States and Tribes should not selectively 
    apply data or selectively use endpoints, species, risk levels, or 
    exposure parameters in deriving criteria; this would not accurately 
    characterize risk and would not result in criteria protective of 
    designated uses.
        EPA emphasizes that, in the course of carrying out its 
    responsibilities under section 303(c), it reviews State and Tribal 
    water quality standards to assess the need for new or revised water 
    quality criteria. EPA generally believes that five years from the date 
    of EPA's publication of new or revised water quality criteria is a 
    reasonable time by which States and Tribes should take action to adopt 
    new or revised water quality criteria necessary to protect the 
    designated uses of their waters. This period is intended to accommodate 
    those States and Tribes that have begun a triennial review and wish to 
    complete the actions they have underway, deferring initiating adoption 
    of new or revised section 304(a) criteria until the next triennial 
    review.
    
    IV. What is the Status of Existing Criteria While They Are Under 
    Revision?
    
        The question of the status of the existing section 304(a) criteria 
    often arises when EPA announces that it is beginning a reassessment of 
    existing criteria. The general answer is that water quality criteria 
    published by EPA remain the Agency's recommended water quality criteria 
    until EPA revises or withdraws the criteria. For example, while 
    undertaking recent reassessments of dioxin, PCBs, and other chemicals, 
    EPA has consistently upheld the use of the current section 304(a) 
    criteria for these chemicals and considers them to be scientifically 
    sound until new, peer reviewed, scientific assessments indicate changes 
    are needed. Therefore, the criteria in today's notice are and will 
    continue to be the Agency's national recommended water quality criteria 
    for States and Tribes to use in adopting or revising their water 
    quality standards until superseded by the publication of revised 
    criteria, or withdrawn by notice in the Federal Register.
    
    V. What is the Process for Developing New or Revised Criteria?
    
        Section 304(a)(1) of the CWA requires the Agency to develop and 
    publish, and from time to time revise, criteria for water quality 
    accurately reflecting the latest scientific knowledge. The Agency has 
    developed an improved process that it intends to use when deriving new 
    criteria or conducting a major reassessment of existing criteria. The 
    purpose of the improved process is to provide expanded opportunities 
    for public input, and to make the process more efficient.
        When deriving new criteria, or when initiating a major reassessment 
    of existing criteria, EPA will take the following steps.
        1. EPA will first undertake a comprehensive review of available 
    data and information.
        2. EPA will publish a notice in the Federal Register and on the 
    Internet announcing its assessment or reassessment of the pollutant. 
    The notice will describe the data available to the Agency, and will 
    solicit any additional pertinent data or views that may be useful in 
    deriving new or revised criteria. EPA is especially interested in 
    hearing from the public regarding new data or information that was 
    unavailable to the Agency, and scientific views as to the application 
    of the relevant Agency methodology for deriving water quality criteria.
        3. After public input is received and evaluated, EPA will then 
    utilize information obtained from both the Agency's literature review 
    and the public to develop draft recommended water quality criteria.
        4. EPA will initiate a peer review of the draft criteria. Agency 
    peer review consists of a documented critical review by qualified 
    independent experts. Information about EPA peer review practices may be 
    found in the Science Policy Council's Peer Review Handbook (EPA 100-B-
    98-001, www.epa.gov).
        5. Concurrent with the peer review in step four, EPA will publish a 
    notice in the Federal Register and on the Internet, of the availability 
    of the draft water quality criteria and solicit views from the public 
    on issues of science pertaining to the information used in deriving the 
    draft criteria. The Agency believes it is important to provide the 
    public with the opportunity to provide scientific views on the draft 
    criteria even though we are not required to invite and respond to 
    written comments.
        6. EPA will evaluate the results of the peer review, and prepare a 
    response document for the record in accordance with EPA's Peer Review 
    Handbook. EPA at the same time will consider views provided by the 
    public on issues of science. Major scientific issues will be addressed 
    in the record whether from the peer review or the public.
        7. EPA will then revise the draft criteria as necessary, and 
    announce the availability of the final water quality criteria in the 
    Federal Register and on the Internet.
    
    VI. What is the Process for Minor Revisions to Criteria?
    
        In addition to developing new criteria, and conducting major 
    reassessments of existing criteria, EPA also from time to time 
    recalculates criteria based on new information pertaining to individual 
    components of the criteria. For example, in today's notice, EPA has 
    recalculated a number of criteria based on new, peer-reviewed data 
    contained in EPA's IRIS. Because such recalculations normally result in 
    only minor changes to the criteria, do not ordinarily involve a change 
    in the underlying scientific methodologies, and reflect peer-reviewed 
    data, EPA will typically publish such recalculated criteria directly as 
    the Agency's recommended water quality criteria. If it appears that a 
    recalculation results in a significant change EPA will follow the 
    process of peer review and public input outlined above. Further, when 
    EPA recalculates national water quality criteria in the course of 
    proposing or promulgating state-specific federal water quality 
    standards pursuant to section 303(c), EPA will offer an opportunity for 
    national public input on the recalculated criteria.
    
    VII. How Does the Process Outlined Above Improve Public Input and 
    Efficiency?
    
        In the past, EPA developed draft criteria documents and announced 
    their availability for public comment in the Federal Register. This led 
    to new data and views coming to EPA's attention after draft criteria 
    had already been developed. Responding to new data would sometimes lead 
    to extensive revisions.
        The steps outlined above improve the criteria development process 
    in the following ways.
        1. The new process is Internet-based which is in line with EPA 
    policy for public access and dissemination of information gathered by 
    EPA. Use of the Internet will allow the public to be more engaged in 
    the criteria development process than previously and to more
    
    [[Page 68356]]
    
    knowledgeably follow criteria development. For new criteria or major 
    revisions, EPA will announce its intentions to derive the new or 
    revised criteria on the Internet and include a list of the available 
    literature. This will give the public an opportunity to provide 
    additional data that might not otherwise be identified by the Agency.
        2. The public now has two opportunities to contribute data and 
    views, before development and during development, instead of a single 
    opportunity after development.
        3. EPA has instituted broader and more formal peer review 
    procedures. This independent scientific review is a more rigorous 
    disciplinary practice to ensure technical improvements in Agency 
    decision making. Previously, EPA used the public comment process 
    outlined above to obtain peer review. The new process allows for both 
    public input and a formal peer review, resulting in a more thorough and 
    complete evaluation of the criteria.
        4. Announcing the availability of the draft water quality criteria 
    on the Internet will give the public an opportunity to provide input on 
    issues of science in a more timely manner.
    
    VIII. Where Can I Find More Information About Water Quality 
    Criteria and Water Quality Standards?
    
        For more information about water quality criteria and Water Quality 
    Standards refer to the following: Water Quality Standards Handbook (EPA 
    823-B94-005a); Advanced Notice of Proposed Rule Making (ANPRM), (63 FR 
    36742); Water Quality Criteria and Standards Plan--Priorities for the 
    Future (EPA 822-R-98-003); Guidelines and Methodologies Used in the 
    Preparation of Health Effects Assessment Chapters of the Consent Decree 
    Water Criteria Documents (45 FR 79347); Draft Water Quality Criteria 
    Methodology Revisions: Human Health (63 FR 43755, EPA 822-Z-98-001); 
    and Guidelines for Deriving Numerical National Water Quality Criteria 
    for the Protection of Aquatic Organisms and Their Uses (EPA 822/R-85-
    100); National Strategy for the Development of Regional Nutrient 
    Criteria (EPA 822-R-98-002).
        These publications may also be accessed through EPA's National 
    Center for Environmental Publications and Information (NCEPI) or on the 
    Office of Science and Technology's Home-page (www.epa.gov/OST).
    
    IX. What Are the National Recommended Water Quality Criteria?
    
        The following compilation and its associated footnotes and notes 
    presents the national recommended water quality criteria.
    
    [[Page 68357]]
    
    
    
                                                                National Recommended Water Quality Criteria for Priority Toxic Pollutants
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
                                                              Freshwater                               Saltwater                   Human health for consumption of:
                                               ------------------------------------------------------------------------------------------------------------------------
           Priority pollutant         CAS No.    CMC  (g/   CCC  (g/   CMC  (g/   CCC  (g/   Water + organism      Organism only           FR cite/source
                                                        L)                  L)                  L)                  L)            (g/L)      (g/L)
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
    1  Antimony....................    7440360  ..................  ..................  ..................  ..................  14 B,\\Z..........  4300 B............  57 FR 60848
    2  Arsenic.....................    7440382  340 A,D,K.........  150 A,D,K.........  69 A,D,bb.........  36A,D,bb..........  ..................  ..................  62 FR 42160
                                                                                                                                0.018 C,M,S.......  0.14 C,M,S........  57 FR 60848
    3  Beryllium...................    7440417  ..................  ..................  ..................  ..................  J,\\Z.............  J.................  62 FR 42160
    4  Cadmium.....................    7440439  4.3 D,\\E,\\K.....  2.2 D,\\E,\\K.....  42 D,\\bb.........  9.3 D,\\bb........  J,\\Z.............  J.................  62 FR 42160
    5a  Chromium III...............   16065831  570 D,\\E,\\K.....  74 D,E,K..........  ..................  ..................  ..................  ..................  EPA 820/B-96-001
                                                                                                                                J,\\Z Total.......  J.................  62 FR 42160
    5b  Chromium VI................   18540299  16 D,\\K..........  11 D,\\K..........  1,100 D,\\bb......  50 D,\\bb.........  J,\\Z Total.......  J.................  62 FR 42160
    6  Copper......................    7440508  13 D,\\E,\\K,\\cc.  9.0 D,\\E,\\K,\\cc  4.8 D,\\cc,\\ff...  3.1 D,\\cc,\\ff...  1,300 U...........  ..................  62 FR 42160
    7  Lead........................    7439921  65 D,\\E,\\bb,\\gg  2.5 D,\\E,\\bb,\\g  210 D,\\bb........  8.1 D,\\bb........  J.................  J.................  62 FR 42160
                                                                     g.
    8  Mercury.....................    7439976  1.4 D,\\K,\\hh....  0.77 D,\\K,\\hh...  1.8 D,\\ee,\\hh...  0.94 D,\\ee,\\hh..  0.050 B...........  0.051 B...........  62 FR 42160
    9  Nickel......................    7440020  470 D,\\E,\\K.....  52 D,\\E,\\K......  74 D,\\bb.........  8.2 D,\\bb........  610 B.............  4,600 B...........  62 FR 42160
    10  Selenium...................    7782492  L,\\R,\\T.........  5.0 T.............  290 D,\\bb,\\dd...  71 D,\\bb,\\dd....  ..................  ..................  62 FR 42160
                                                                                                                                170 Z.............  11,000............  IRIS 09/01/91
    11  Silver.....................    7440224  3.4 D,\\E,\\G.....  ..................  1.9 D,\\G.........  ..................  ..................  ..................  62 FR 42160
    12  Thallium...................    7440280  ..................  ..................  ..................  ..................  1.7 B.............  6.3 B.............  57 FR 60848
    13  Zinc.......................    7440666  120 D,\\E,\\K.....  120 D,\\E,\\K.....  90 D,\\bb.........  81 D,\\bb.........  ..................  ..................  62 FR 42160
                                                                                                                                9,100 U...........  69,000 U..........  IRIS 10/01/92
    14  Cyanide....................      57125  22 K,\\Q..........  5.2 K,\\Q.........  ..................  ..................  ..................  ..................  EPA 820/B-96-001
                                                                                        1 Q,\\bb..........  1 Q,\\bb..........  700 B,\\Z.........  220,000 B,\\H.....  57 FR 60848
    15  Asbestos...................    1332214  ..................  ..................  ..................  ..................  7 million fibers/L  ..................  57 FR 60848
                                                                                                                                 I.
    16  2, 3, 7, 8-TCDD Dioxin.....    1746016  ..................  ..................  ..................  ..................  1.3E-8 C..........  1.4E-8 C..........  62 FR 42160
    17  Acrolein...................     107028  ..................  ..................  ..................  ..................  320...............  780...............  57 FR 60848
    18  Acrylonitrile..............     107131  ..................  ..................  ..................  ..................  0.059 B,C.........  0.66 B,C..........  57 FR 60848
    19  Benzene....................      71432  ..................  ..................  ..................  ..................  1.2 B,C...........  71 B,C............  62 FR 42160
    20  Bromoform..................      75252  ..................  ..................  ..................  ..................  4.3 B,C...........  360 B,C...........  62 FR 42160
    21  Carbon Tetrachloride.......      56235  ..................  ..................  ..................  ..................  0.25 B,C..........  4.4 B,C...........  57 FR 60848
    22  Chlorobenzene..............     108907  ..................  ..................  ..................  ..................  680 B,Z...........  21,000 B,H........  57 FR 60848
    23  Chlorodibromomethane.......     124481  ..................  ..................  ..................  ..................  0.41 B,C..........  34 B,C............  62 FR 42160
    24  Chloroethane...............      75003                                                                                                                          ............................
    25  2-Chloroethylvinyl Ether...     110758                                                                                                                          ............................
    26  Chloroform.................      67663  ..................  ..................  ..................  ..................  5.7 B,C...........  470 B,C...........  62 FR 42160
    27  Dichlorobromomethane.......      75274  ..................  ..................  ..................  ..................  0.56 B,C..........  46 B,C............  62 FR 42160
    28  1,1-Dichloroethane.........      75343                                                                                                                          ............................
    29  1,2-Dichloroethane.........     107062  ..................  ..................  ..................  ..................  0.38 B,C..........  99 B,C............  57 FR 60848
    30  1,1-Dichloroethylene.......      75354  ..................  ..................  ..................  ..................  0.057 B,C.........  3.2 B,C...........  57 FR 60848
    31  1,2-Dichloropropane........      78875  ..................  ..................  ..................  ..................  0.52 B,C..........  39 B,C............  62 FR 42160
    32  1,3-Dichloropropene........     542756  ..................  ..................  ..................  ..................  10 B..............  1,700 B...........  57 FR 60848
    33  Ethylbenzene...............     100414  ..................  ..................  ..................  ..................  3,100 B,Z.........  29,000 B..........  62 FR 42160
    34  Methyl Bromide.............      74839  ..................  ..................  ..................  ..................  48 B..............  4000 B............  62 FR 42160
    35  Methyl Chloride............      74873  ..................  ..................  ..................  ..................  J.................  J.................  62 FR 42160
    36  Methylene Chloride.........      75092  ..................  ..................  ..................  ..................  4.7 B,C...........  1600 B,C..........  62 FR 42160
    37  1,1,2,2-Tetrachloroethane..      79345  ..................  ..................  ..................  ..................  0.17 B,C..........  11B,C.............  57 FR 60848
    38  Tetrachloroethylene........     127184  ..................  ..................  ..................  ..................  0.8 C.............  8.85 C............  57 FR 60848
    39  Toluene....................     108883  ..................  ..................  ..................  ..................  6,800 B,Z.........  200,000 B.........  62 FR 42160
    40  1,2-Trans-Dichloroethylene.     156605  ..................  ..................  ..................  ..................  700 B,Z...........  140,000 B.........  62 FR 42160
    41  1,1,1-Trichloroethane......      71556  ..................  ..................  ..................  ..................   J,Z..............   J................  62 FR 42160
    42  1,1,2-Trichloroethane......      79005  ..................  ..................  ..................  ..................  0.60 B,C..........  42 B,C............  57 FR 60848
    43  Trichloroethylene..........      79016  ..................  ..................  ..................  ..................  2.7 C.............  81 C..............  57 FR 60848
    44  Vinyl Chloride.............      75014  ..................  ..................  ..................  ..................  2.0 C.............  525 C.............  57 FR 60848
    45  2-Chlorophenol.............      95578  ..................  ..................  ..................  ..................  120 B,U...........  400 B,U...........  62 FR 42160
    46  2,4-Dichlorophenol.........     120832  ..................  ..................  ..................  ..................  93 B,U............  790 B,U...........  57 FR 60848
    47  2,4-Dimethylphenol.........     105679  ..................  ..................  ..................  ..................  540 B,U...........  2,300 B,U.........  62 FR 42160
    48  2-Methyl-4,6-Dinitrophenol.     534521  ..................  ..................  ..................  ..................  13.4..............  765...............  57 FR 60848
    49  2,4-Dinitrophenol..........      51285  ..................  ..................  ..................  ..................  70 B..............  14,000 B..........  57 FR 60848
    50  2-Nitrophenol..............      88755                                                                                                                          ............................
    51  4-Nitrophenol..............     100027                                                                                                                          ............................
    52  3-Methyl-4-Chlorophenol....      59507  ..................  ..................  ..................  ..................   U................   U.
    
    [[Page 68358]]
    
     
    53  Pentachlorophenol..........      87865  19 F,K............  15 F,K............  13 bb.............  7.9 bb............  0.28 B,C..........  8.2 B,C,H.........  62 FR 42160
    54  Phenol.....................     108952  ..................  ..................  ..................  ..................  21,000 B,U........  ..................  62 FR 42160
                                                                                                                                                    4,600,000 B,H,U...  57 FR 60848
    55  2,4,6-Trichlorophenol......      88062  ..................  ..................  ..................  ..................  2.1 B,C,U.........  6.5 B,C...........  62 FR 42160
    56  Acenaphthene...............      83329  ..................  ..................  ..................  ..................  1,200 B,U.........  2,700 B,U.........  62 FR 42160
    57  Acenaphthylene.............     208968
    58  Anthracene.................     120127  ..................  ..................  ..................  ..................  9,600 B...........  110,000 B.........  62 FR 42160
    59  Benzidine..................      92875  ..................  ..................  ..................  ..................  0.00012 B,C.......  0.00054 B,C.......  57 FR 60848
    60  BenzoaAnthracene...........      56553  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    61  BenzoaPyrene...............      50328  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    62  BenzobFluoranthene.........     205992  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    63  BenzoghiPerylene...........     191242                                                                                                                          ............................
    64  BenzokFluoranthene.........     207089  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    65  Bis2-ChloroethoxyMethane...     111911                                                                                                                          ............................
    66  Bis2-ChloroethylEther......     111444  ..................  ..................  ..................  ..................  0.031 B,C.........  1.4 B,C...........  57 FR 60848
    67  Bis2-ChloroisopropylEther..   39638329  ..................  ..................  ..................  ..................  1,400 B...........  ..................  62 FR 42160
                                                                                                                                                    170,000 B.........  57 FR 60848
    68  Bis2-EthylhexylPhthalate X.     117817  ..................  ..................  ..................  ..................  1.8 B,C...........  5.9 B,C...........  57 FR 60848
    69  4-Bromophenyl Phenyl Ether.     101553                                                                                                                          ............................
    70  Butylbenzyl PhthalateW.....      85687  ..................  ..................  ..................  ..................  3,000 B...........  5,200 B...........  62 FR 42160
    71  2-Chloronaphthalene........      91587  ..................  ..................  ..................  ..................  1,700 B...........  4,300 B...........  62 FR 42160
    72  4-Chlorophenyl Phenyl Ether    7005723                                                                                                                          ............................
    73  Chrysene...................     218019  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    74  Dibenzoa,hAnthracene.......      53703  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    75  1,2-Dichlorobenzene........      95501  ..................  ..................  ..................  ..................  2,700 B,Z.........  17,000 B..........  62 FR 42160
    76  1,3-Dichlorobenzene........     541731  ..................  ..................  ..................  ..................  400...............  2,600.............  62 FR 42160
    77  1,4-Dichlorobenzene........     106467  ..................  ..................  ..................  ..................  400 Z.............  2,600.............  62 FR 42160
    78  3,3'-Dichlorobenzidine.....      91941  ..................  ..................  ..................  ..................  0.04 B,C..........  0.077 B,C.........  57 FR 60848
    79  Diethyl Phthalate W........      84662  ..................  ..................  ..................  ..................  23,000 B..........  120,000 B.........  57 FR 60848
    80  Dimethyl Phthalate W.......     131113  ..................  ..................  ..................  ..................  313,000...........  2,900,000.........  57 FR 60848
    81  Di-n-Butyl Phthalate W.....      84742  ..................  ..................  ..................  ..................  2,700 B...........  12,000 B..........  57 FR 60848
    82  2,4-Dinitrotoluene.........     121142  ..................  ..................  ..................  ..................  0.11 C............  9.1 C.............  57 FR 60848
    83  2,6-Dinitrotoluene.........     606202                                                                                                                          ............................
    84  Di-n-Octyl Phthalate.......     117840                                                                                                                          ............................
    85  1,2-Diphenylhydrazine......     122667  ..................  ..................  ..................  ..................  0.040 B,C.........  0.54 B,C..........  57 FR 60848
    86  Fluoranthene...............     206440  ..................  ..................  ..................  ..................  300 B.............  370 B.............  62 FR 42160
    87  Fluorene...................      86737  ..................  ..................  ..................  ..................  1,300 B...........  14,000 B..........  62 FR 42160
    88  Hexachlorobenzene..........     118741  ..................  ..................  ..................  ..................  0.00075 B,C.......  0.00077 B,C.......  62 FR 42160
    89  Hexachlorobutadiene........      87683  ..................  ..................  ..................  ..................  0.44 B,C..........  50 B,C............  57 FR 60848
    90  Hexachlorocyclopentadiene..      77474  ..................  ..................  ..................  ..................  240 B,U,Z.........  17,000 B,H,U......  57 FR 60848
    91  Hexachloroethane...........      67721  ..................  ..................  ..................  ..................  1.9 B,C...........  8.9 B,C...........  57 FR 60848
    92  Ideno 1,2,3-cdPyrene.......     193395  ..................  ..................  ..................  ..................  0.0044 B,C........  0.049 B,C.........  62 FR 42160
    93  Isophorone.................      78591  ..................  ..................  ..................  ..................  36 B,C............  2,600 B,C.........  IRIS 11/01/97
    94  Naphthalene................      91203                                                                                                                          ............................
    95  Nitrobenzene...............      98953  ..................  ..................  ..................  ..................  17 B..............  1,900 B,H,U.......  57 FR 60848
    96  N-Nitrosodimethylamine.....      62759  ..................  ..................  ..................  ..................  0.00069 B,C.......  8.1 B,C...........  57 FR 60848
    97  N-Nitrosodi-n-Propylamine..     621647  ..................  ..................  ..................  ..................  0.005 B,C.........  1.4 B,C...........  62 FR 42160
    98  N-Nitrosodiphenylamine.....      86306  ..................  ..................  ..................  ..................  5.0 B,C...........  16 B,C............  57 FR 60848
    99  Phenanthrene...............      85018                                                                                                                          ............................
    100  Pyrene....................     129000  ..................  ..................  ..................  ..................  960 B.............  11,000 B..........  62 FR 42160
    101  1,2,4-Trichlorobenzene....     120821  ..................  ..................  ..................  ..................  260 Z.............  940...............  IRIS 11/01/96
    102  Aldrin....................     309002  3.0 G.............  ..................  1.3 G.............  ..................  0.00013 B,C.......  0.00014 B,C.......  62 FR 42160
    103  alpha-BHC.................     319846  ..................  ..................  ..................  ..................  0.0039 B,C........  0.013 B,C.........  62 FR 42160
    104  beta-BHC..................     319857  ..................  ..................  ..................  ..................  0.014 B,C.........  0.046 B,C.........  62 FR 42160
    105  gamma-BHC (Lindane).......      58899  0.95 K............  ..................  0.16 G............  ..................  0.019 C...........  0.063 C...........  62 FR 42160
    106  delta-BHC.................     319868
    107  Chlordane.................      57749  2.4 G.............  0.0043 G,aa.......  0.09 G............  0.004 G,aa........  ..................  ..................  62 FR 42160
                                                                                                                                0.0021 B,C........  0.0022 B,C........  IRIS 02/07/98
    
    [[Page 68359]]
    
     
    108  4,4'-DDT..................      50293  1.1 G.............  0.001 G,aa........  0.13 G............  0.001 G,aa........  0.00059 B,C.......  0.00059 B,C.......  62 FR 42160
    109  4,4'-DDE..................      72559  ..................  ..................  ..................  ..................  0.00059 B,C.......  0.00059 B,C.......  62 FR 42160
    110  4,4'-DDD..................      72548  ..................  ..................  ..................  ..................  0.00083 B,C.......  0.00084 B,C.......  62 FR 42160
    111  Dieldrin..................      60571  0.24 K............  0.056 K,O.........  0.71 G............  0.0019 G,aa.......  0.00014 B,C.......  0.00014 B,C.......  62 FR 42160
    112  alpha-Endosulfan..........     959988  0.22 G,Y..........  0.056 G,Y.........  0.034 G,Y.........  0.0087 G,Y........  110 B.............  240 B.............  62 FR 42160
    113  beta-Endosulfan...........   33213659  0.22 G,Y..........  0.056 G,Y.........  0.034 G,Y.........  0.0087 G,Y........  110 B.............  240 B.............  62 FR 42160
    114  Endosulfan Sulfate........    1031078  ..................  ..................  ..................  ..................  110 B.............  240 B.............  62 FR 42160
    115  Endrin....................      72208  0.086 K...........  0.036 K,O.........  0.037 G...........  0.0023 G,aa.......  0.76 B............  0.81 B,H..........  62 FR 42160
    116  Endrin Aldehyde...........    7421934  ..................  ..................  ..................  ..................  0.76 B............  0.81 B,H..........  62 FR 42160
    117  Heptachlor................      76448  0.52 G............  0.0038 G,aa.......  0.053 G...........  0.0036 G,aa.......  0.00021 B,C.......  0.00021 B,C.......  62 FR 42160
    118  Heptachlor Epoxide........    1024573  0.52 G,V..........  0.0038 G,V,aa.....  0.053 G,V.........  0.0036 G,V,aa.....  0.00010 B,C.......  0.00011 B,C.......  62 FR 42160
    119  Polychlorinated Biphenyls   .........  ..................  0.014 N,aa........  ..................  0.03 N,aa.........  ..................  ..................  62 FR 42160
      PCBs                                                                                                                      0.00017 B,C,P.....  0.00017 B,C,P.....  63 FR 16182
    120  Toxaphene.................    8001352  0.73..............  0.0002 aa.........  0.21..............  0.0002 aa.........  0.00073 B,C.......  0.00075 B,C.......  62 FR 42160
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
    Footnotes:
    A This recommended water quality criterion was derived from data for arsenic (III), but is applied here to total arsenic, which might imply that arsenic (III) and arsenic (V) are equally toxic
      to aquatic life and that their toxicities are additive. In the arsenic criteria document (EPA 440/5-84-033, January 1985), Species Mean Acute Values are given for both arsenic (III) and
      arsenic (V) for five species and the ratios of the SMAVs for each species range from 0.6 to 1.7. Chronic values are available for both arsenic (III) and arsenic (V) for one species; for the
      fathead minnow, the chronic value for arsenic (V) is 0.29 times the chronic value for arsenic (III). No data are known to be available concerning whether the toxicities of the forms of
      arsenic to aquatic organisms are additive.
    B This criterion has been revised to reflect The Environmental Protection Agency's q1* or RfD, as contained in the Integrated Risk Information System (IRIS) as of April 8, 1998. The fish
      tissue bioconcentration factor (BCF) from the 1980 Ambient Water Quality Criteria document was retained in each case.
    C This criterion is based on carcinogenicity of 10 -6 risk. Alternate risk levels may be obtained by moving the decimal point (e.g., for a risk level of 10 -5, move the decimal point in the
      recommended criterion one place to the right).
    D Freshwater and saltwater criteria for metals are expressed in terms of the dissolved metal in the water column. The recommended water quality criteria value was calculated by using the
      previous 304(a) aquatic life criteria expressed in terms of total recoverable metal, and multiplying it by a conversion factor (CF). The term ``Conversion Factor'' (CF) represents the
      recommended conversion factor for converting a metal criterion expressed as the total recoverable fraction in the water column to a criterion expressed as the dissolved fraction in the water
      column. (Conversion Factors for saltwater CCCs are not currently available. Conversion factors derived for saltwater CMCs have been used for both saltwater CMCs and CCCs.) See ``Office of
      Water Policy and Technical Guidance on Interpretation and Implementation of Aquatic Life Metals Criteria,'' October 1, 1993, by Martha G. Prothro, Acting Assistant Administrator for Water,
      available from the Water Resource center, USEPA, 401 M St., SW, mall code RC4100, Washington, DC 20460; and 40 CFRSec.  131.36(b)(1). Conversion Factors applied in the table can be found in
      Appendix A to the Preamble--Conversion Factors for Dissolved Metals.
    E The freshwater criterion for this metal is expressed as a function of hardness (mg/L) in the water column. The value given here corresponds to a hardness of 100 mg/L. Criteria values for
      other hardness may be calculated from the following: CMC (dissolved) = exp {m A [ln(hardness)]+b A} (CF), or CCC (dissolved) = exp {m C [ln (hardness)]+b C} (CF) and the parameters specified
      in Appendix B to the Preamble--Parameters for Calculating Freshwater Dissolved Metals Criteria That Are Hardness-Dependent.
    F Freshwater aquatic life values for pentachlorophenol are expressed as a function of pH, and are calculated as follows: CMD=exp(1.005(pH)-4.869); CCC=exp(1.005 (pH)-5.134). Values displayed
      in table correspond to a pH of 7.8.
    G This Criterion is based on 304(a) aquatic life criterion issued in 1980, and was issued in one of the following documents: Aldrin/Dieldrin (EPA 440/5-80-019), Chlordane (EPA 440/5-80-027),
      DDT (EPA 440/5-80-038), Endosulfan (EPA 440/5-80-046), Endrin (EPA 440/5-80-047), Heptachlor (440/5-80-052), Hexachlorocyclohexane (EPA 440/5-80-054), Silver (EPA 440/5-80-071). The Minimum
      Data Requirements and derivation procedures were different in the 1980 Guidelines than in the 1985 Guidelines. For example, a ``CMC'' derived using the 1980 Guidelines was derived to be used
      as an instantaneous maximum. If assessment is to be done using an averaging period, the values given should be divided by 2 to obtain a value that is more comparable to a CMC derived using
      the 1985 Guidelines.
    H No criterion for protection of human health from consumption of aquatic organisms excluding water was presented in the 1980 criteria document or in the 1986 Quality Criteria for Water.
      Nevertheless, sufficient information was presented in the 1980 document to allow the calculation of a criterion, even though the results of such a calculation were not shown in the document.
    I This criterion for asbestos is the Maximum Contaminant Level (MCL) developed under the Safe Drinking Water Act (SDWA).
    J EPA has not calculated human health criterion for this contaminant. However, permit authorities should address this contaminant in NPDES permit actions using the State's existing narrative
      criteria for toxics.
    K This recommended criterion is based on a 304(a) aquatic life criterion that was issued in the 1995 Updates: Water Quality Criteria Documents for the Protection of Aquatic Life in Ambient
      Water, (EPA-820-B-96-011, September 1996). This value was derived using the GLI Guidelines (60 FR 15393-15399, March 23, 1995; 40 CFR 132 Appendix A); the difference between the 1985
      Guidelines and the GLI Guidelines are explained on page iv of the 1995 Updates. None of the decisions concerning the derivation of this criterion were affected by any considerations that are
      specific to the Great Lakes.
    L The CMC=1/[(f1/CMC1)=(f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated as selenite and selenate, respectively, and CMC1 and CMC2 are 185.9 g/l and
      12.83 g/l, respectively.
    M EPA is currently reassessing the criteria for arsenic. Upon completion of the reassessment the Agency will publish revised criteria as appropriate.
    N PCBs are a class of chemicals which include aroclors, 1242, 1254, 1221, 1232, 1248, 1260, and 1016, CAS numbers 53469219, 11097691, 11104282, 11141165, 12672296, 11096825 and 12674112
      respectively. The aquatic life criteria apply to this set of PCBs.
    O The derivation of the CCC for this pollutant did not consider exposure through the diet, which is probably important for aquatic life occupying upper trophic levels.
    P This criterion applies to total pcbs, i.e., the sum of all congener or all isomer analyses.
    Q This recommended water quality criterion is expressed as g free cyanide (as CN)/L.
    R This value was announced (61 FR 58444-58449, November 14, 1996) as a proposed GLI 303(c) aquatic life criterion. EPA is currently working on this criterion and so this value might change
      substantially in the near future.
    S This recommended water quality criterion refers to the inorganic form only.
    T This recommended water quality criterion is expressed in terms of total recoverable metal in the water column. It is scientifically acceptable to use the conversion factor of 0.922 that was
      used in the GLI to convert this to a value that is expressed in terms of dissolved metal.
    U The organoleptic effect criterion is more stringent than the value for priority toxic pollutants.
    
    [[Page 68360]]
    
     
    V This value was derived from data for heptachlor and the criteria document provides insufficient data to estimate the relative toxicities of heptachlor and heptachlor epoxide.
    W Although EPA has not published a final criteria document for this compound it is EPA's understanding that sufficient data exist to allow calculation of aquatic criteria. It is anticipated
      that industry intends to publish in the peer reviewed literature draft aquatic life criteria generated in accordance with EPA Guidelines. EPA will review such criteria for possible issuance
      as national WQC.
    X There is a full set of aquatic life toxicity data that show that DEHP is not toxic to aquatic organisms at or below its solubility limit.
    Y This value was derived from data for endosulfan and is most appropriately applied to the sum of alpha-endosulfan and beta-endosulfan.
    Z A more stringent MCL has been issued by EPA. Refer to drinking water regulations (40 CFR 141) or Safe Drinking Water Hotline (1-800-426-4791) for values.
    aa This CCC is based on the Final Residue Value procedure in the 1985 Guidelines. Since the publication of the Great Lakes Aquatic Life Criteria Guidelines in 1995 (60FR 15393-15399, March 23,
      1995), the Agency no longer uses the Final Residue Value procedure for deriving CCCs for new or revised 304(a) aquatic life criteria.
    bb This water quality criterion is based on 304(a) aquatic life criterion that was derived using the 1985 Guidelines (Guidelines for Deriving Numerical National Water Quality Criteria for the
      Protection of Aquatic Organisms and Their Uses, PB85-227049, January 1985) and was issued in one of the following criteria documents: Arsenic (EPA 440/5-84-033), Cadmium (EPA 440/5-84-032),
      Chromium (EPA 440/5-84-029), Copper (EPA 440/5-84-031), Cyanide (EPA 400/5-84-028), Lead (EPA 440/5-84-027), Nickel (EPA 440/5-86-004), Pentachlorophenol (EPA 440/5-86-009), Toxaphene (EPA
      440/5-86-006), Zinc (EPA 440/5-87-003).
    cc When the concentration of dissolved organic carbon is elevated, copper is substantially less toxic and use of Water-Effect Ratios might be appropriate.
    dd The selenium criteria document (EPA 440/5-87-006), September 1987) provides that if selenium is as toxic to saltwater fishes in the field as it is to freshwater fishes in the field, the
      status of the fish community should be monitored whenever the concentration of selenium exceeds 5.0 g/L in salt water because the saltwater CCC does not take into account uptake via
      the food chain.
    ee This recommended water quality criterion was derived on page 43 of the mercury criteria document (EPA 440/5-84-026, January 1985). The saltwater CCC of 0.025 g/L given on page 23
      of the criteria document is based on the Final Residue Value procedure in the 1985 Guidelines. Since the publication of the Great Lakes Aquatic Life Criteria Guidelines in 1995 (60FR15393-
      15399, March 23, 1995), the Agency no longer uses the Final Residue Value procedure for deriving CCCs for new or revised 304(a) aquatic life criteria.
    ff This recommended water quality criterion was derived in Ambient Water Quality Criteria Saltwater Copper Addendum (Draft, April 14, 1995) and was promulgated in the Interim Final National
      Toxics Rule (60FR22228-222237, May 4, 1995).
    gg EPA is actively working on this criterion and so this recommended water quality criterion may change substantially in the near future.
    hh This recommended water quality criterion was derived from data for inorganic mercury (II), but is applied here to total mercury. If a substantial portion of the mercury in the water column
      is methylmercury, this criterion will probably be under protective. In addition, even though inorganic mercury is converted to methylmercury and methylmercury bioaccumulates to a great
      extent, this criterion does not account for uptake via the food chain because sufficient data were not available when the criteria was derived.
    
    
                                                                 National Recommended Water Quality Criteria for Non Priority Pollutants
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
                                                               Freshwater                               Saltwater                   Human health for consumption of:
                                                ------------------------------------------------------------------------------------------------------------------------
         Non priority pollutant        CAS No.    CMC  (g/   CCC  (g/   CMC  (g/   CCC  (g/   Water + organism      Organism only           FR cite/source
                                                         L)                  L)                  L)                  L)            (g/L)      (g/L)
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
     1  Alkalinity..................  .........  ..................  20000 F...........  ..................  ..................  ..................  ..................  Gold Book
     2  Aluminum pH 6.5-9.0.........    7429905  750 G,I...........  87 G,I,L..........  ..................  ..................  ..................  ..................  53 FR 33178
     3  Ammonia.....................    7664417                                    FRESHWATER CRITERIA ARE pH DEPENDENT--SEE DOCUMENT                                    EPA822-R-98-008
                                                                                  SALTWATER CRITERIA ARE pH AND TEMPERATURE DEPENDENT D                                  EPA440/5-88-004
     4  Aesthetic Qualities.........                                                        NARRATIVE STATEMENT--SEE DOCUMENT                                            Gold Book
     5  Bacteria....................  .........                                  FOR PRIMARY RECREATION AND SHELLFISH USES--SEE DOCUMENT                                 Gold Book
     6  Barium......................    7440393  ..................  ..................  ..................  ..................  1,000 A...........  ..................  Gold Book
     7  Boron.......................  .........                                             NARRATIVE STATEMENT--SEE DOCUMENT                                            Gold Book
     8  Chloride....................   16887006  860000 G..........  230000 G..........  ..................  ..................  ..................  ..................  53 FR 19028
     9  Chlorine....................    7782505  19................  11................  13................  7.5...............   C................  ..................  Gold Book
    10  Chlorophenoxy Herbicide           93721  ..................  ..................  ..................  ..................  10 A..............  ..................  Gold Book
     2,4,5,-TP.
    11  Chlorophenoxy Herbicide 2,4-      94757  ..................  ..................  ..................  ..................  100 A,C...........  ..................  Gold Book
     D.
    12  Chloropyrifos...............    2921882  0.083 G...........  0.041 G...........  0.011 G...........  0.0056 G..........  ..................  ..................  Gold Book
    13  Color.......................  .........                                            NARRATIVE STATEMENT--SEE DOCUMENT F                                           Gold Book
    14  Demeton.....................    8065483  ..................  0.1 F,H...........  ..................  0.1 F,H...........  ..................  ..................  Gold Book
    15  Ether, Bis Chloromethyl.....     542881  ..................  ..................  ..................  ..................  0.00013 E.........  0.00078 E.........  IRIS 01/01/91
    16  Gases, Total Dissolved......  .........                                            NARRATIVE STATEMENT--SEE DOCUMENT F                                           Gold Book
    17  Guthion.....................      86500  ..................  0.01 F,H..........  ..................  0.01 F,H..........  ..................  ..................  Gold Book
    18  Hardness....................  .........                                             NARRATIVE STATEMENT--SEE DOCUMENT                                            Gold Book
    19  Hexachlorocyclo-hexane-          319868  ..................  ..................  ..................  ..................  0.0123............  0.0414............  Gold Book
     Technical.
    20  Iron........................    7439896  ..................  1000 F............  ..................  ..................  300 A.............  ..................  Gold Book
    21  Malathion...................     121755  ..................  0.1 F,H...........  ..................  ..................  ..................  ..................  Gold Book
    22  Manganese...................    7439965  ..................  ..................  ..................  ..................  50 A..............  100 A.............  Gold Book
    23  Methoxychlor................      72435  ..................  0.03 F,H..........  ..................  0.03 F,H..........  100 A,C...........  ..................  Gold Book
    24  Mirex.......................    2385855  ..................  0.001 F,H.........  ..................  0.001 F,H.........  ..................  ..................  Gold Book
    25  Nitrates....................   14797558  ..................  ..................  ..................  ..................  10,000 A..........  ..................  Gold Book
    26  Nitrosamines................  .........  ..................  ..................  ..................  ..................  0.0008............  1.24..............  ...........................
    
    [[Page 68361]]
    
     
    27  Dinitrophenols..............   25550587  ..................  ..................  ..................  ..................  70................  14,000............  Gold Book
    28  Nitrosodibutylamine,N.......     924163  ..................  ..................  ..................  ..................  0.0064 A..........  0.587 A...........  Gold Book
    29  Nitrosodiethylamine,N.......      55185  ..................  ..................  ..................  ..................  0.0008 A..........  1.24 A............  Gold Book
    30  Nitrosopyrrolidine,N........     930552  ..................  ..................  ..................  ..................  0.016.............  91.9..............  Gold Book
    31  Oil and Grease..............  .........                                            NARRATIVE STATEMENT--SEE DOCUMENT F                                           Gold Book
    32  Oxygen, Dissolved...........    7782447                                      WARMWATER AND COLDWATER MATRIX--SEE DOCUMENT O                                      Gold Book
    33  Parathion...................      56382  0.065 J...........  0.013 J...........  ..................  ..................  ..................  ..................  Gold Book
    34  Pentachlorobenzene..........     608935  ..................  ..................  ..................  ..................  3.5 E.............  4.1 E.............  IRIS 03/01/88
    35  pH..........................  .........  ..................  6.5-9 F...........  ..................  6.5-8.5 F,K.......  5-9...............  ..................  Gold Book
    36  Phosphorus Elemental........    7723140  ..................  ..................  ..................  0.1 F,K...........  ..................  ..................  Gold Book
    37  Phosphate Phosphorus........  .........                                             NARRATIVE STATEMENT--SEE DOCUMENT                                            Gold Book
    38  Solids Dissolved and          .........  ..................  ..................  ..................  ..................  250,000 A.........  ..................  Gold Book
     Salinity.
    39  Solids Suspended and          .........                                            NARRATIVE STATEMENT--SEE DOCUMENT F                                           Gold Book
     Turbidity.
    40  Sulfide-Hydrogen Sulfide....    7783064  ..................  2.0 F,H...........  ..................  2.0 F,H...........  ..................  ..................  Gold Book
    41  Tainting Substances.........  .........                                             NARRATIVE STATEMENT--SEE DOCUMENT                                            Gold Book
    42  Temperature.................  .........                                        SPECIES DEPENDENT CRITERIA--SEE DOCUMENT M                                        Gold Book
    43  Tetrachlorobenzene,1,2,4,5-.      95943  ..................  ..................  ..................  ..................  2.3 E.............  2.9 E.............  IRIS03/01/91
    44  Tributyltin TBT.............  .........  0.46 N............  0.063 N...........  0.37 N............  0.010 N...........  ..................  ..................  62 FR 42554
    45  Trichlorophenol,2,4,5-......      95954  ..................  ..................  ..................  ..................  2,600 B,E.........  9,800 B,E.........  IRIS 03/01/88
    ------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
    Footnotes:
    A This human health criterion is the same as originally published in the Red Book which predates the 1980 methodology and did not utilize the fish ingestion BCF approach. This same criterion
      value is now published in the Gold Book
    B The organoleptic effect criterion is more stringent than the value presented in the non priority pollutants table.
    C A more stringent Maximum Contaminant Level (MCL) has been issued by EPA under the Safe Drinking Water Act. Refer to drinking water regulations 40 CFR 141 or Safe Drinking Water Hotline (1-
      800-426-4791) for values.
    D According to the procedures described in the Guidelines for Deriving Numerical National Water Quality Criteria for the Protection of Aquatic Organisms and Their Uses, except possibly where a
      very sensitive species is important at a site, freshwater aquatic life should be protected if both conditions specified in Appendix C to the Preamble--Calculation of Freshwater Ammonia
      Criterion are satisfied.
    E This criterion has been revised to reflect The Environmental Protection Agency's q1* or RfD, as contained in the Integrated Risk Information System (IRIS) as of April 8, 1998. The fish
      tissue bioconcentration factor (BCF) used to derive the original criterion was retained in each case.
    F The derivation of this value is presented in the Red Book (EPA 440/9-76-023, July, 1976).
    G This value is based on a 304(a) aquatic life criterion that was derived using the 1985 Guidelines (Guidelines for Deriving Numerical National Water Quality Criteria for the Protection of
      Aquatic Organisms and Their Uses, PB85-227049, January 1985) and was issued in one of the following criteria documents: Aluminum (EPA 440/5-86-008); Chloride (EPA 440/5-88-001);
      Chloropyrifos (EPA 440/5-86-005).
    H This CCC is based on the Final Residue Value procedure in the 1985 Guidelines. Since the publication of the Great Lakes Aquatic Life Criteria Guidelines in 1995 (60 FR 15393-15399, March 23,
      1995), the Agency no longer uses the Final Residue Value procedure for deriving CCCs for new or revised 304(a) aquatic life criteria.
    I This value is expressed in terms of total recoverable metal in the water column.
    J This value is based on a 304(a) aquatic life criterion that was issued in the 1995 Updates: Water Quality Criteria Documents for the Protection of Aquatic Life in Ambient Water (EPA-820-B-96-
      001). This value was derived using the GLI Guidelines (60 FR 15393-15399, March 23, 1995; 40 CFR 132 Appendix A); the differences between the 1985 Guidelines and the GLI Guidelines are
      explained on page iv of the 1995 Updates. No decision concerning this criterion was affected by any considerations that are specific to the Great Lakes.
    K According to page 181 of the Red Book: For open ocean waters where the depth is substantially greater than the euphotic zone, the pH should not be changed more than 0.2 units from the
      naturally occurring variation or any case outside the range of 6.5 to 8.5. For shallow, highly productive coastal and estuarine areas where naturally occurring pH variations approach the
      lethal limits of some species, changes in pH should be avoided but in any case should not exceed the limits established for fresh water, i.e., 6.5-9.0.
    L There are three major reasons why the use of Water-Effect Ratios might be appropriate. (1) The value of 87 g/l is based on a toxicity test with the striped bass in water with pH=6.5-
      6.6 and hardness <10 mg/l.="" data="" in="" ``aluminum="" water-effect="" ratio="" for="" the="" 3m="" plant="" effluent="" discharge,="" middleway,="" west="" virginia''="" (may="" 1994)="" indicate="" that="" aluminum="" is="" substantially="" less="" toxic="" at="" higher="" ph="" and="" hardness,="" but="" the="" effects="" of="" ph="" and="" hardness="" are="" not="" well="" quantified="" at="" this="" time.="" (2)="" in="" tests="" with="" the="" brook="" trout="" at="" low="" ph="" and="" hardness,="" effects="" increased="" with="" increasing="" concentrations="" of="" total="" aluminum="" even="" though="" the="" concentration="" of="" dissolved="" aluminum="" was="" constant,="" indicating="" that="" total="" recoverable="" is="" a="" more="" appropriate="" measurement="" than="" dissolved,="" at="" least="" when="" particulate="" aluminum="" is="" primarily="" aluminum="" hydroxide="" particles.="" in="" surface="" waters,="" however,="" the="" total="" recoverable="" procedure="" might="" measure="" aluminum="" associated="" with="" clay="" particles,="" which="" might="" be="" less="" toxic="" than="" aluminum="" associated="" with="" aluminum="" hydroxide.="" (3)="" epa="" is="" aware="" of="" field="" data="" indicating="" that="" many="" high="" quality="" waters="" in="" the="" u.s.="" contain="" more="" than="" 87="">g aluminum/L, when either total recoverable or dissolved is measured.
    M U.S. EPA. 1973. Water Quality Criteria 1972. EPA-R3-73-033. National Technical Information Service, Springfield, VA.; U.S. EPA. 1977. Temperature Criteria for Freshwater Fish: Protocol and
      Procedures. EPA-600/3-77-061. National Technical Information Service, Springfield, VA.
    N This value was announced (62 FR 42554, August 7, 1997) as a proposed 304(a) aquatic life criterion. Although EPA has not responded to public comment, EPA is publishing this as a 304(a)
      criterion in today's notice as guidance for States and Tribes to consider when adopting water quality criteria.
    O U.S. EPA. 1986. Ambient Water Quality Criteria for Dissolved Oxygen. EPA 440/5-86-003. National Technical Information Service, Springfield, VA.
    
    
    [[Page 68362]]
    
    
                          National Recommended Water Quality Criteria for Organoleptic Effects
    ----------------------------------------------------------------------------------------------------------------
                                                                  Organoleptic
                                                                     effect
                     Pollutant                       CAS No.        criteria                FR cite/source
                                                                 (g/L)
    ----------------------------------------------------------------------------------------------------------------
    1  Acenaphthene............................          208968           20     Gold Book
    2  Monochlorobenzene.......................          108907           20     Gold Book
    3  3-Chlorophenol..........................  ..............            0.1   Gold Book
    4  4-Chlorophenol..........................          106489            0.1   Gold Book
    5  2,3-Dichlorophenol......................  ..............            0.04  Gold Book
    6  2,5-Dichlorophenol......................  ..............            0.5   Gold Book
    7  2,6-Dichlorophenol......................  ..............            0.2   Gold Book
    8  3,4-Dichlorophenol......................  ..............            0.3   Gold Book
    9  2,4,5-Trichlorophenol...................           95954            1     Gold Book
    10  2,4,6-Trichlorophenol..................           88062            2     Gold Book
    11  2,3,4,6-Tetrachlorophenol..............  ..............            1     Gold Book
    12  2-Methyl-4-Chlorophenol................  ..............         1800     Gold Book
    13  3-Methyl-4-Chlorophenol................           59507         3000     Gold Book
    14  3-Methyl-6-Chlorophenol................  ..............           20     Gold Book
    15  2-Chlorophenol.........................           95578            0.1   Gold Book
    16  Copper.................................          744058         1000     Gold Book
    17  2,4-Dichlorophenol.....................          120832            0.3   Gold Book
    18  2,4-Dimethylphenol.....................          105679          400     Gold Book
    19  Hexachlorocyclopentadiene..............           77474            1     Gold Book
    20  Nitrobenzene...........................           98953           30     Gold Book
    21  Pentachlorophenol......................           87865           30     Gold Book
    22  Phenol.................................          108952          300     Gold Book
    23  Zinc...................................         7440666         5000     45 FR 79341
    ----------------------------------------------------------------------------------------------------------------
    General Notes:
    1. These criteria are based on organoleptic (taste and odor) effects. Because of variations in chemical
      nomenclature systems, this listing of pollutants does not duplicate the listing in Appendix A of 40 CFR Part
      423. Also listed are the Chemical Abstracts Service (CAS) registry numbers, which provide a unique
      identification for each chemical.
    
    National Recommended Water Quality Criteria
    
    Additional Notes
    
    1. Criteria Maximum Concentration and Criterion Continuous 
    Concentration
    
        The Criteria Maximum Concentration (CMC) is an estimate of the 
    highest concentration of a material in surface water to which an 
    aquatic community can be exposed briefly without resulting in an 
    unacceptable effect. The Criterion Continuous Concentration (CCC) is 
    an estimate of the highest concentration of a material in surface 
    water to which an aquatic community can be exposed indefinitely 
    without resulting in an unacceptable effect. The CMC and CCC are 
    just two of the six parts of a aquatic life criterion; the other 
    four parts are the acute averaging period, chronic averaging period, 
    acute frequency of allowed exceedence, and chronic frequency of 
    allowed exceedence. Because 304(a) aquatic life criteria are 
    national guidance, they are intended to be protective of the vast 
    majority of the aquatic communities in the United States.
    
    2. Criteria Recommendations for Priority Pollutants, Non Priority 
    Pollutants and Organoleptic Effects
    
        This compilation lists all priority toxic pollutants and some 
    non priority toxic pollutants, and both human health effect and 
    organoleptic effect criteria issued pursuant to CWA Sec. 304(a). 
    Blank spaces indicate that EPA has no CWA Sec. 304(a) criteria 
    recommendations. For a number of non-priority toxic pollutants not 
    listed, CWA Sec. 304(a) ``water + organism'' human health criteria 
    are not available, but, EPA has published MCLs under the SDWA that 
    may be used in establishing water quality standards to protect water 
    supply designated uses. Because of variations in chemical 
    nomenclature systems, this listing of toxic pollutants does not 
    duplicate the listing in Appendix A of 40 CFR Part 423. Also listed 
    are the Chemical Abstracts Service CAS registry numbers, which 
    provide a unique identification for each chemical.
    
    3. Human Health Risk
    
        The human health criteria for the priority and non priority 
    pollutants are based on carcinogenicity of 10-6 risk. 
    Alternate risk levels may be obtained by moving the decimal point 
    (e.g., for a risk level of 10-5, move the decimal point in the 
    recommended criterion one place to the right).
    
    4. Water Quality Criteria Published Pursuant to Section 304(a) or 
    Section 303(c) of the CWA
    
        Many of the values in the compilation were published in the 
    proposed California Toxics Rule (CTR, 62 FR 42160). Although such 
    values were published pursuant to Section 303(c) of the CWA, they 
    represent the Agency's most recent calculation of water quality 
    criteria and thus are published today as the Agency's 304(a) 
    criteria. Water quality criteria published in the proposed CTR may 
    be revised when EPA takes final action on the CTR.
    
    5. Calculation of Dissolved Metals Criteria
    
        The 304(a) criteria for metals, shown as dissolved metals, are 
    calculated in one of two ways. For freshwater metals criteria that 
    are hardness-dependent, the dissolved metal criteria were calculated 
    using a hardness of 100 mg/l as CaCO3 for illustrative 
    purposes only. Saltwater and freshwater metals' criteria that are 
    not hardness-dependent are calculated by multiplying the total 
    recoverable criteria before rounding by the appropriate conversion 
    factors. The final dissolved metals' criteria in the table are 
    rounded to two significant figures. Information regarding the 
    calculation of hardness dependent conversion factors are included in 
    the footnotes.
    
    6. Correction of Chemical Abstract Services Number
    
        The Chemical Abstract Services number (CAS) for Bis(2-
    Chloroisopropyl) Ether, has been corrected in the table. The correct 
    CAS number for this chemical is 39638-32-9. Previous publications 
    listed 108-60-1 as the CAS number for this chemical.
    
    [[Page 68363]]
    
    7. Maximum Contaminant Levels
    
        The compilation includes footnotes for pollutants with Maximum 
    Contaminant Levels (MCLs) more stringent than the recommended water 
    quality criteria in the compilation. MCLs for these pollutants are 
    not included in the compilation, but can be found in the appropriate 
    drinking water regulations (40 CFR 141.11-16 and 141.60-63), or can 
    be accessed through the Safe Drinking Water Hotline (800-426-4791) 
    or the Internet (http://www.epa.gov/ost/tools/dwstds-s.html).
    
    8. Organoleptic Effects
    
        The compilation contains 304(a) criteria for pollutants with 
    toxicity-based criteria as well as non-toxicity based criteria. The 
    basis for the non-toxicity based criteria are organoleptic effects 
    (e.g., taste and odor) which would make water and edible aquatic 
    life unpalatable but not toxic to humans. The table includes 
    criteria for organoleptic effects for 23 pollutants. Pollutants with 
    organoleptic effect criteria more stringent than the criteria based 
    on toxicity (e.g., included in both the priority and non-priority 
    pollutant tables) are footnoted as such.
    
    9. Category Criteria
    
        In the 1980 criteria documents, certain recommended water 
    quality criteria were published for categories of pollutants rather 
    than for individual pollutants within that category. Subsequently, 
    in a series of separate actions, the Agency derived criteria for 
    specific pollutants within a category. Therefore, in this 
    compilation EPA is replacing criteria representing categories with 
    individual pollutant criteria (e.g., 1,3-dichlorobenzene, 1,4-
    dichlorobenzene and 1,2-dichlorobenzene).
    
    10. Specific Chemical Calculations
    
    A. Selenium
    
    (1) Human Health
    
        In the 1980 Selenium document, a criterion for the protection of 
    human health from consumption of water and organisms was calculated 
    based on a BCF of 6.0 L/kg and a maximum water-related contribution 
    of 35 g Se/day. Subsequently, the EPA Office of Health and 
    Environmental Assessment issued an errata notice (February 23, 
    1982), revising the BCF for selenium to 4.8 L/kg. In 1988, EPA 
    issued an addendum (ECAO-CIN-668) revising the human health criteria 
    for selenium. Later in the final National Toxic Rule (NTR, 57 FR 
    60848), EPA withdrew previously published selenium human health 
    criteria, pending Agency review of new epidemiological data.
        This compilation includes human health criteria for selenium, 
    calculated using a BCF of 4.8 L/kg along with the current IRIS RfD 
    of 0.005 mg/kg/day. EPA included these recommended water quality 
    criteria in the compilation because the data necessary for 
    calculating a criteria in accordance with EPA's 1980 human health 
    methodology are available.
    
    (2) Aquatic Life
    
        This compilation contains aquatic life criteria for selenium 
    that are the same as those published in the proposed CTR. In the 
    CTR, EPA proposed an acute criterion for selenium based on the 
    criterion proposed for selenium in the Water Quality Guidance for 
    the Great Lakes System (61 FR 58444). The GLI and CTR proposals take 
    into account data showing that selenium's two most prevalent 
    oxidation states, selenite and selenate, present differing 
    potentials for aquatic toxicity, as well as new data indicating that 
    various forms of selenium are additive. The new approach produces a 
    different selenium acute criterion concentration, or CMC, depending 
    upon the relative proportions of selenite, selenate, and other forms 
    of selenium that are present.
        EPA notes it is currently undertaking a reassessment of 
    selenium, and expects the 304(a) criteria for selenium will be 
    revised based on the final reassessment (63 FR 26186). However, 
    until such time as revised water quality criteria for selenium are 
    published by the Agency, the recommended water quality criteria in 
    this compilation are EPA's current 304(a) criteria.
    
    B. 1,2,4-Trichlorobenzene and Zinc
    
        Human health criteria for 1,2,4-trichlorobenzene and zinc have 
    not been previously published. Sufficient information is now 
    available for calculating water quality criteria for the protection 
    of human health from the consumption of aquatic organisms and the 
    consumption of aquatic organisms and water for both these compounds. 
    Therefore, EPA is publishing criteria for these pollutants in this 
    compilation.
    
    C. Chromium (III)
    
        The recommended aquatic life water quality criteria for chromium 
    (III) included in the compilation are based on the values presented 
    in the document titled: 1995 Updates: Water Quality Criteria 
    Documents for the Protection of Aquatic Life in Ambient Water, 
    however, this document contains criteria based on the total 
    recoverable fraction. The chromium (III) criteria in this 
    compilation were calculated by applying the conversion factors used 
    in the Final Water Quality Guidance for the Great Lakes System (60 
    FR 15366) to the 1995 Update document values.
    
    D. Ether, Bis (Chloromethyl), Pentachlorobenzene, 
    Tetrachlorobenzene 1,2,4,5- Trichlorophenol
    
        Human health criteria for these pollutants were last published 
    in EPA's Quality Criteria for Water 1986 or ``Gold Book''. Some of 
    these criteria were calculated using Acceptable Daily Intake (ADIs) 
    rather than RfDs. Updated q1*s and RfDs are now available in IRIS 
    for ether, bis (chloromethyl), pentachlorobenzene, 
    tetrachlorobenzene 1,2,4,5-, and trichlorophenol, and were used to 
    revise the water quality criteria for these compounds. The 
    recommended water quality criteria for ether, bis (chloromethyl) 
    were revised using an updated q1*, while criteria for 
    pentachlorobenzene, and tetrachlorobenzene 1,2,4,5-, and 
    trichlorophenol were derived using an updated RfD value.
    
    E. PCBs
    
        In this compilation EPA is publishing aquatic life and human 
    health criteria based on total PCBs rather than individual 
    arochlors. These criteria replace the previous criteria for the 
    seven individual arochlors. Thus, there are criteria for a total of 
    102 of the 126 priority pollutants.
    
        Dated: October 26, 1998.
    J. Charles Fox,
    Assistant Administrator, Office of Water.
    
    [[Page 68364]]
    
    Appendix A--Conversion Factors for Dissolved Metals
    
    ----------------------------------------------------------------------------------------------------------------
                                                                                        Conversion      Conversion
                 Metal                  Conversion factor        Conversion factor        factor          factor
                                          freshwater CMC          freshwater CCC       saltwater CMC   saltwater CCC
    ----------------------------------------------------------------------------------------------------------------
    Arsenic........................  1.000..................  1.000.................           1.000           1.000
    Cadmium........................  1.138672-[(ln hardness)  1.101672-[(ln                    0.994           0.994
                                      (0.041838)]              hardness) (0.041838)]
    Chromium III...................  0.316..................  0.860
    Chromium VI....................  0.982..................  0.962.................           0.993           0.993
    Copper.........................  0.960..................  0.960.................           0.83            0.83
    Lead...........................  1.46203-[(ln hardness)   1.46203-[(ln hardness)           0.951           0.951
                                      (0.145712)]              (0.145712)]
    Mercury........................  0.85...................  0.85..................           0.85            0.85
    Nickel.........................  0.998..................  0.997.................           0.990           0.990
    Selenium.......................  .......................  ......................           0.998           0.998
    Silver.........................  0.85...................  ......................           0.85
    Zinc...........................  0.978..................  0.986.................           0.946           0.946
    ----------------------------------------------------------------------------------------------------------------
    
    Appendix B--Parameters for Calculating Freshwater Dissolved Metals 
    Criteria That Are Hardness-Dependent
    
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                                                                                                                Freshwater conversion factors (CF)
                    Chemical                       mA            bA            mC            bC      -------------------------------------------------------
                                                                                                                 Acute                      Chronic
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Cadmium.................................        1.128        -3.6867        0.7852       -2.715   1.136672-[ln                1.101672-[ln
                                                                                                       (hardness)(0.041838)]       (hardness)(0.041838)]
    Chromium III............................        0.8190        3.7256        0.8190        0.6848  0.316.....................  0.860
    Copper..................................        0.9422       -1.700         0.8545       -1.702   0.960.....................  0.960
    Lead....................................        1.273        -1.460         1.273        -4.705   1.46203-[ln                 1.46203-[ln
                                                                                                       (hardness)(0.145712)]       (hardness)(0.145712)]
    Nickel..................................        0.8460        2.255         0.8460        0.0584  0.998.....................  0.997
    Silver..................................        1.72         -6.52    ............  ............  0.85
    Zinc....................................        0.8473        0.884         0.8473        0.884   0.978.....................  0.986
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    
    Appendix C--Calculation of Freshwater Ammonia Criterion
    
        1. The one-hour average concentration of total ammonia nitrogen 
    (in mg N/L) does not exceed, more than once every three years on the 
    average, the CMC calculated using the following equation:
    [GRAPHIC] [TIFF OMITTED] TN10DE98.009
    
        In situations where salmonids do not occur, the CMC may be 
    calculated using the following equation:
    [GRAPHIC] [TIFF OMITTED] TN10DE98.010
    
        2. The thirty-day average concentration of total ammonia 
    nitrogen (in mg N/L) does not exceed, more than once every three 
    years on the average, the CCC calculated using the following 
    equation:
    
    [GRAPHIC] [TIFF OMITTED] TN10DE98.011
    
        Editorial Note: FR Doc. 98-30272 was originally published as 
    Part IV (63 FR 67548-67558) in the issue of Monday, December 7, 
    1998. At the request of the agency, due to incorrect footnote 
    identifiers in the tables, the corrected document is being 
    republished in its entirety.
    [FR Doc. 98-30272 Filed 12-4-98; 8:45 am]
    BILLING CODE 1505-01-D
    
    
    

Document Information

Published:
12/10/1998
Department:
Environmental Protection Agency
Entry Type:
Notice
Action:
Compilation of recommended water quality criteria and notice of process for new and revised criteria.
Document Number:
98-30272
Dates:
Water Quality Criteria Documents for the Protection of Aquatic Life in Ambient
Pages:
68354-68364 (11 pages)
Docket Numbers:
FRL-OW-6186-6a
PDF File:
98-30272.pdf