94-4555. Commonwealth Edison Company (Zion Nuclear Power Station, Unit Nos. 1 and 2)  

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    [Federal Register: March 1, 1994]
    
    
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    NUCLEAR REGULATORY COMMISSION
    [Docket Nos. 50-295 and 50-304]
    
     
    
    Commonwealth Edison Company (Zion Nuclear Power Station, Unit 
    Nos. 1 and 2)
    
    Exemption
    
    I
        The Commonwealth Edison Company (the licensee), is the holder of 
    Facility Operating License Nos. DPR-39 and DPR-48 which authorize 
    operation of Zion Nuclear Power Station, Units 1 and 2, at a steady-
    state power level not in excess of 3250 megawatts thermal. The facility 
    consists of two pressurized water reactors located at the licensee's 
    site in Lake County, Illinois. The licenses provide, among other 
    things, that they are subject to all rules, regulations and orders of 
    the Nuclear Regulatory Commission (the Commission) now and hereafter in 
    effect.
    II
        In a letter dated December 3, 1993, the licensee provided an 
    assessment of the reference temperature for pressurized thermal shock 
    (RTPTS) for the design life (32 effective full power years) for 
    the Zion Nuclear Power Station Units 1 and 2 (Zion 1 and 2) reactor 
    vessels and requested an exemption from determining the unirradiated 
    reference temperature (initial RTNDT) in accordance with NB-2331 
    of Section III of the ASME Boiler and Pressure Vessel Code (ASME Code), 
    as specified in 10 CFR 50.61(b)(2)(i). Prior correspondence commenced 
    with the licensee's letter dated December 13, 1991, that replied to the 
    amendment to 10 CFR 50.61 which was published in the Federal Register 
    on May 15, 1991, (56 FR 22300). In a letter dated March 13, 1992, the 
    licensee provided its flux reduction program to ensure the 
    intermediate-to-lower shell circumferential weld for Zion Unit 1 would 
    remain less than the screening criterion through 32 EFPY. In a letter 
    dated May 22, 1992, the licensee used data provided by the Babcock and 
    Wilcox Owners' Group (B&WOG) to address the initial RTNDT and 
    RTPTS for the Zion Unit 1 and 2 reactor pressure vessels (RPVs). 
    With this data, the licensee was able to show that the RPVs will 
    satisfy the pressurized thermal shock (PTS) screening criteria through 
    32 EFPY. After reviewing the licensee's submittals, the staff requested 
    additional information in a letter dated December 2, 1992. The licensee 
    responded in a letter dated January 28, 1993. On June 9, 1993, the 
    staff met with the licensee to discuss the performance of a modified 
    analysis utilizing improved analytical techniques. In a letter dated 
    September 1, 1993, the licensee provided a summary report demonstrating 
    that the Zion RPVs will not exceed the end of life PTS screening 
    criteria. In another letter dated October 5, 1993, the licensee 
    detailed the development of the methodology utilized in performing the 
    PTS evaluation for the Zion RPVs.
    III
        The Pressurized Thermal Shock (PTS) rule, 10 CFR 50.61, ``Fracture 
    toughness requirements for protection against pressurized thermal shock 
    events,'' adopted on July 23, 1985, establishes screening criteria that 
    define a limiting level of embrittlement beyond which operation cannot 
    continue without further plant-specific evaluation. The screening 
    criteria are given in terms of reference temperature, RTPTS. The 
    screening criteria are 270 deg.F for plates and axial welds and 
    300 deg.F for circumferential welds. The RTPTS is defined as the 
    sum of (a) the unirradiated reference temperature, (b) the margin to be 
    added to cover uncertainties in the initial properties, copper and 
    nickel contents, fluence, and calculation procedures, and (c) the 
    increase in RTPTS caused by irradiation. The amount of increase in 
    RTPTS is based on the amount of neutron irradiation and the amount 
    of copper and nickel in the material. The greater the amounts of 
    copper, nickel and neutron fluence, the greater the increase in 
    RTPTS for the material and the lower its fracture resistance. The 
    PTS rule requires that the unirradiated reference temperature be 
    determined from measurements as defined in the ASME Code, Section III, 
    Paragraph NB-2331. The amount of margin is dependent on whether: (a) 
    The material is a weld or a base metal, (b) the unirradiated reference 
    temperature is a generic value or a measured value, and (c) the 
    increase in RTPTS is from credible surveillance material or is 
    from the chemistry factor tables in the PTS rule.
        The PTS rule was amended on May 15, 1991. The amended rule changed 
    the method of calculating embrittlement to the method recommended in 
    Regulatory Guide (RG) 1.99, Revision 2, ``Radiation Embrittlement of 
    Reactor Vessel Materials'', and requires licensees to consider the 
    effect of reactor vessel operating temperature and surveillance results 
    on the calculated RTpts value. The licensee provided this 
    assessment in a letter dated July 2, 1992, which contained the 
    licensee's response to Generic Letter (GL) 92-01, Revision 1, ``Reactor 
    Vessel Structural Integrity, 10 CFR 50.54(f)''. The purpose of GL 92-01 
    was to obtain information needed to assess compliance with requirements 
    set forth in 10 CFR Part 50, Appendices G and H and commitments made in 
    response to GL 88-11 regarding reactor vessel structural integrity. The 
    licensee's responses to GL 92-01 are being evaluated and will be 
    resolved as an issue separate from this exemption request.
    
    Pressurized Thermal Shock (PTS) Evaluation
    
    Licensee's Evaluation
    
        The licensee reports that the beltline of each reactor vessel 
    consists of a forging, four plates, four longitudinal welds and three 
    circumferential welds. There are sufficient records to identify the 
    heat number and chemical composition (percentage copper and nickel) of 
    all beltline materials.
    
    Unirradiated Reference Temperature
    
        The unirradiated reference temperature for the beltline forgings 
    and plates was determined from test results from the materials. The 
    licensee used a generic value (-5 deg.F) for the unirradiated reference 
    temperature of all beltline weld metals, with the exception of the weld 
    metal identified as WF-70. The unirradiated reference temperature for 
    WF-70 weld metal was determined from drop weight tests and fracture 
    toughness tests from welds fabricated with WF-70 and WF-209-1 weld 
    metal. Since WF-70 and WF-209-1 welds were fabricated using the same 
    heat number of weld wire and the same type of flux, their material 
    properties are considered equivalent. The licensee's data will be 
    discussed in the Staff Evaluation of Unirradiated Reference Temperature 
    for WF-70.
        The unirradiated reference temperature that is defined in Section 
    III of the ASME Code, Paragraph NB-2331 is determined from Charpy V-
    notch (CVN) impact and drop weight tests. These tests have been 
    performed on WF-70 weld metal by the licensees for Zion and Oconee, the 
    B&WOG and Oak Ridge National Laboratory (ORNL). The test results 
    indicate that the unirradiated reference temperature varies from 
    -3 deg.F to +123 deg.F with a standard deviation of 43.1 deg.F and a 
    mean value of 49 deg.F. This wide variability was a surprise to the 
    staff because welds similar to WF-70 were reported to have a mean value 
    of -4.8 deg.F and a standard deviation of 19.7 deg.F. The staff 
    believes that the large uncertainty in unirradiated reference 
    temperature for WF-70 weld metal is due to the low upper-shelf behavior 
    of the material and that the definition of unirradiated reference 
    temperature in the ASME Code is not applicable for material with low 
    upper-shelf behavior like WF-70 weld metal. The licensee has proposed 
    to determine the unirradiated reference temperature from drop weight 
    and fracture toughness tests instead of the method defined in Section 
    III of the ASME Code. The licensee proposes to define the unirradiated 
    reference temperature as equal to the sum of: (a) the mean value for 
    the nilductility transition temperature, TNDT, from the drop 
    weight test data from WF-70 and WF-209-1 weld and (b) the two standard 
    deviation value determined from the drop weight test data. This method 
    results in a mean value for the TNDT of -56 deg.F and a standard 
    deviation of 14.8 deg.F for WF-70 weld metal. Using these values of 
    TNDT and standard deviation, the unirradiated reference 
    temperature is -26 deg.F for WF-70 weld metal. Since the licensee has 
    not followed the method in Section III of the ASME Code, the licensee's 
    method for determining the unirradiated reference temperature of WF-70 
    does not meet the requirements of 10 CFR 50.61. The licensee has, 
    therefore, requested an exemption from the requirement to determine the 
    unirradiated reference temperature (initial RTNDT) in accordance 
    with NB-2331 of Section III of the ASME Boiler and Pressure Vessel Code 
    (ASME Code), as specified in 10 CFR 50.61(b)(2)(i).
    
    Increase in RTPTS and Margin
    
        The increase in RTPTS for each beltline material, except WF-70 
    weld metal, was determined using the chemistry factor tables in the PTS 
    rule. The increase in RTPTS for WF-70 weld metal was determined 
    from Charpy impact tests on WF-70 weld metal irradiated in the Zion 
    Units 1 and 2 surveillance capsules. The increase in RTPTS for WF-
    70 weld metal was determined using the methodology documented in 
    Section 2.1 of RG 1.99, Revision 2.
        The amount of margin for each beltline plate and forging was the 
    amount identified in the PTS rule for base metal with measured 
    unirradiated reference temperature. The amount of margin for each 
    beltline weld, with the exception of WF-70, was the amount identified 
    in the PTS rule for weld metal with generic values of unirradiated 
    reference temperature. The amount of margin for WF-70 weld metal was 
    determined using the standard deviation for the increase in RTPTS 
    from irradiation in RG 1.99, Revision 2, when credible surveillance 
    data is available. This results in a margin value of 28 deg.F for WF-70 
    weld metal.
        Paragraph 10 CFR 50.61(b)(3) requires that RTPTS values which 
    are modified by surveillance data be approved by the Director, Office 
    of Nuclear Reactor Regulation. The staff believes that using the 
    methodology in RG 1.99, Revision 2 for determining the increase in 
    RTPTS from surveillance material is an acceptable alternative to 
    the value determined from the chemistry factor tables in the PTS rule. 
    The staff believes that the amount of margin for WF-70 should be the 
    amount determined using the standard deviation for the increase in 
    RTPTS from irradiation in RG 1.99, Revision 2. This results in a 
    margin value of 28 deg.F and an unirradiated reference temperature of 
    -26 deg.F for WF-70. The reasons for not including the uncertainty of 
    the unirradiated reference temperature in the margin, but adding it to 
    the TNDT will be discussed in the Staff Evaluation of Unirradiated 
    Reference Temperature for WF-70.
    
    RTPTS at Expiration of the Zion 1 and 2 licenses
    
        The licensee has projected that at the expiration of their 
    licenses, WF-70 weld metal in Units 1 and 2 will have RTPTS values 
    of 230 deg.F and 172 deg.F, respectively. Both these values are 
    significantly below the PTS screening criteria in the PTS rule. As a 
    result of the licensee's evaluation of WF-70 weld metal, the limiting 
    material in Unit 1 is a circumferential weld fabricated using WF-154 
    weld metal and the limiting material in Unit 2 is a circumferential 
    weld fabricated using SA-1769 weld metal. The RTPTS values for 
    these welds at the expiration of the Units 1 and 2 licenses are 
    268 deg.F and 269 deg.F, respectively. Both of these values are 
    significantly below the PTS screening criterion, 300 deg.F, in the PTS 
    rule.
    
    Staff Evaluation of Unirradiated Reference Temperature for WF-70
    
        As discussed previously, the licensee and the B&WOG have concluded 
    that determination of unirradiated reference temperature via the CVN 
    procedure of NB-2331 of Section III of the ASME Code is not appropriate 
    for the Zion beltline welds fabricated with WF-70 weld metal. The staff 
    recognizes that the ASME Code procedure, when applied to lower upper 
    shelf materials such as WF-70, may not produce a reasonable 
    determination of unirradiated reference temperature. The staff has, 
    therefore, encouraged the licensee to pursue alternate approaches to 
    determine the unirradiated reference temperature for WF-70. The 
    approach selected by the licensee and the B&WOG involves analysis of 
    WF-70 fracture toughness data in accordance with the Draft ASTM 
    Standard on Fracture Toughness in the Transition Range (Draft 5, Rev. 
    3-3-93). The purpose of the licensee's analysis is to demonstrate that 
    the above methodology ``bounds'' the fracture toughness data and can be 
    indexed to the ASME fracture toughness reference curves. The indexing 
    to either the KIC or KIR curves is used to show that the 
    reference temperature determined from drop weight tests provides an 
    appropriate unirradiated reference temperature for WF-70.
        At a meeting with the licensee on June 9, 1993, the staff 
    acknowledged the merit of the ASTM approach and encouraged the licensee 
    to pursue it to completion. At that time, the staff also indicated that 
    the licensee should consider constraint adjustments and strain rate 
    effects on the data. In particular, the staff questioned the basis for 
    directly indexing the Babcock and Wilcox (B&W) dynamic fracture 
    toughness data to the ASME KIR curve with respect to the differing 
    strain rates involved in generation of the data. The licensee 
    subsequently submitted a B&W report (BAW-2202, September, 1993) which 
    addresses its revised analysis for the determination of the 
    unirradiated reference temperature.
        The staff has independently evaluated the data provided in BAW-2202 
    and the previous report (BAW-2100, January, 1993) in accordance with 
    the Draft ASTM Standard on Fracture Toughness in the Transition Range. 
    The staff analysis, presented in the attached Figure 1, considered both 
    constraint and rate effects on the data. Figure 1 presents the B&W 
    dynamic fracture toughness data as the open symbols. The solid symbols 
    represent the same data constraint corrected using the procedure 
    suggested by Anderson and Dodds, 1993. The ASTM curves (Kjc 
    median, 95% CL and lower bound) were derived from the constraint-
    corrected data at 0 deg.F where it can be seen that the magnitude of 
    the correction was small. It is seen that the ASTM Kjc lower bound 
    curve effectively bounds all of the data with the possible exception of 
    the constraint-corrected point at +132 deg.F. However, the specimen at 
    +132 deg.F exhibited a significant amount of ductile tearing prior to 
    failure by cleavage. It is known that the Anderson-Dodds procedure will 
    ``over-correct'' for constraint in such instances.
        With respect to strain rate effects, the B&W dynamic data were 
    generated at a rate of approximately 7 x 104 ksi in/sec. 
    This rate is on the threshold of the rates achieved in the crack arrest 
    tests which constitute the ASME KIR curve. Figure 1 also shows a 
    direct comparison between the B&W dynamic fracture toughness data and 
    some recently available crack arrest data on WF-70 from the ORNL. While 
    the crack arrest data are generally conservative in comparison to the 
    B&W data, it is seen that the ASTM Kjc lower bound curve also 
    bounds the ORNL data. On the basis of this analysis, the staff finds 
    the methodology of indexing the B&W dynamic data to the KIR curve 
    acceptable.
        In conclusion, the staff analysis which addresses constraint and 
    rate effects has shown the fracture toughness based procedure for 
    determination of unirradiated reference temperature to be acceptable 
    for WF-70. As shown in Figure 1, the ASME KIR curve, with a 
    reference temperature of -26 deg.F bounds all of the constraint-
    adjusted data and the ASTM curves up to approximately 140 deg.F. This 
    analysis therefore supports an unirradiated reference temperature of 
    -26 deg.F for the WF-70 material.
        Other procedures for determination of RTNDT may serve as 
    acceptable alternatives to NB-2331 contingent on staff review and 
    approval. However, it should be noted that the staff acceptance of the 
    alternative procedure in this evaluation was contingent on the analysis 
    of a significant amount of fracture toughness data for the WF-70 weld 
    metal. Acceptance of such a procedure in a case where little or no 
    fracture toughness data were available would be difficult in the 
    absence of an officially sanctioned consensus standard.
        As part of the resolution of low-upper-shelf reference temperature 
    issues on a generic basis, the ASME Code has tasked the Failure Modes 
    of Components Committee of the Pressure Vessel Research Council (PVRC) 
    to consider alternate procedures for the determination of unirradiated 
    reference temperature. To this end, the PVRC recently held a \1/2\ day 
    workshop on ``KIR Curves and RTNDT'' on October 11, 1993, 
    where the ASTM fracture toughness based approach was highlighted. As a 
    result of the workshop, it is expected that the Committee will be able 
    to make recommendations to the ASME Code by December 31, 1994.
    
    Irradiation Temperature and Surveillance Material Test Results
    
        The methods of calculating the increase in RTPTS in the PTS 
    rule and in RG 1.99, Revision 2 were empirically derived from 
    surveillance data from U.S. commercially operated nuclear reactor 
    vessels. The methods are valid for a nominal irradiation temperature of 
    550 deg.F. Irradiation below 525 deg.F is considered to produce 
    embrittlement greater than the values predicted in the PTS rule and RG 
    1.99, Revision 2.
        In its response to GL 92-01, the licensee reported that the cold 
    leg temperature during nuclear systems power operation varied linearly 
    between 547.0 deg.F at 0 percent power and 529.4 deg.F at 100 percent 
    power. Hence, irradiation occurred at temperatures exceeding 525 deg.F 
    and the methodologies in the PTS rule and RG 1.99, Revision 2 are 
    applicable to Zion Units 1 and 2.
        Regulatory Guide and 1.99, Revision 2 indicates that about a best-
    fit line to the surveillance data, scatter should be less than 28 deg.F 
    for welds and for fluence of two or more orders of magnitude, the 
    scatter should be less than 56 deg.F. Zion 1 has four irradiated 
    surveillance data points and Zion 2 has three irradiated surveillance 
    data points from WF-70 weld metal. The maximum difference between the 
    measured increase in reference temperature and the best fit line is 
    20 deg.F. Since this is less than 28 deg.F, the increase in RTPTS 
    and the associated standard deviation may be based on the methodology 
    in Section 2.1 of RG 1.99, Revision 2.
    
    Conclusions
    
        Based on the Zion 1 and 2 irradiation temperature and surveillance 
    data, the methodologies in the PTS rule and RG 1.99, Revision 2 are 
    applicable to Zion 1 and 2. As a result of its review, the staff 
    concludes that the licensee's method of determining the unirradiated 
    reference temperature is an acceptable alternative to the method 
    described in NB-2331 of Section III of the ASME Code because staff and 
    licensee analyses indicate that the fracture toughness data are bounded 
    by the ASME KIR curve with an unirradiated reference temperature 
    of -26 deg.F. However, since the unirradiated reference temperature was 
    not determined in accordance with the method in Section III of the ASME 
    Code, an exemption to the PTS rule is required. The RTPTS values 
    for all beltline materials will be below the PTS screening criteria 
    when the Zion 1 and 2 licenses expire. 10 CFR 50.12(a)(1) allows the 
    Commission to grant exemptions which are authorized by law, will not 
    present an undue risk to the public health and safety, and are 
    consistent with the common defense and security. Since the licensee's 
    method of determining the unirradiated reference temperature is an 
    acceptable alternative to the method in NB-2331 of Section III of the 
    ASME Code, RTPTS values for WF-70 weld metal that are calculated 
    using the licensee's method are authorized by law and will not present 
    an undue risk to the public health and safety and are consistent with 
    the common defense and security. For the same reason, the staff finds 
    that application of the regulation would not serve the underlying 
    purpose of the rule, which is to ensure that reactor pressure vessels 
    in service are not susceptible to fracture as a result of pressurized 
    thermal shock. On this basis, the staff finds that the licensee has 
    demonstrated that there are special circumstances present as required 
    by 10 CFR 50.12(a)(2).
    
    References
    
        (1) ``Properties of Weld Wire Heat Number 72105 (Weld Metals WF-
    70 and WF-209-1), BAW-2100, January, 1993.
        (2) ``Test Practice (Method) for Fracture Toughness in the 
    Transition Range,'' Draft 5, Rev. 3-3-93, presented at the ASTM E08 
    Committee Meetings, Atlanta, GA, May, 1993.
        (3) ``Fracture Toughness Characterization of WF-70 Weld Metal,'' 
    BAW-2202, September, 1993.
        (4) ``Simple Constraint Corrections for Subsize Fracture 
    Toughness Specimens,'' T.L. Anderson and R.H. Dodds, Jr., ASTM STP 
    1024, 1993, pp. 93-105.
    
    IV
        Accordingly, the Commission has determined that, pursuant to 10 CFR 
    50.12, an exemption is authorized by law and will not endanger life or 
    property or the common defense and security and is otherwise in the 
    public interest and hereby grants the following exemption with respect 
    to a requirement of 10 CFR 50.61:
        For Zion Nuclear Power Station, Units 1 and 2, the licensee's 
    method of determining the unirradiated reference temperature (initial 
    RTNDT) from drop weight and fracture toughness tests is an 
    acceptable alternative to the method in NB-2331 of Section III of the 
    ASME Code as specified in 10 CFR 50.61(b)(2)(i).
        Pursuant to 10 CFR 51.32, the Commission has determined that the 
    granting of the subject exemption will not have a significant effect on 
    the quality of the human environment (59 FR 4727).
    
        Dated at Rockville, Maryland this 22nd day of February 1994.
    
        This exemption is effective upon issuance.
    
        For the Nuclear Regulatory Commission.
    Jack W. Roe,
    Director, Director of Reactor Projects III/IV/V, Office of Nuclear 
    Reactor Regulation.
    [FR Doc. 94-4555 Filed 2-28-94; 8:45 am]
    BILLING CODE 7590-01-M
    
    
    

Document Information

Published:
03/01/1994
Department:
Nuclear Regulatory Commission
Entry Type:
Uncategorized Document
Document Number:
94-4555
Pages:
0-0 (1 pages)
Docket Numbers:
Federal Register: March 1, 1994, Docket Nos. 50-295 and 50-304