95-7066. National Emission Standards for Hazardous Air Pollutant Emissions From the Production of Acrylonitrile Butadiene Styrene (ABS) Resin, Styrene Acrylonitrile (SAN) Resin, Methyl Methacrylate Acrylonitrile Butadiene Styrene (MABS) Resin, ...  

  • [Federal Register Volume 60, Number 60 (Wednesday, March 29, 1995)]
    [Proposed Rules]
    [Pages 16090-16111]
    From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
    [FR Doc No: 95-7066]
    
    
    
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    ENVIRONMENTAL PROTECTION AGENCY
    40 CFR Part 63
    
    [AD-FRL-5175-9]
    RIN 2060-AE37
    
    
    National Emission Standards for Hazardous Air Pollutant Emissions 
    From the Production of Acrylonitrile Butadiene Styrene (ABS) Resin, 
    Styrene Acrylonitrile (SAN) Resin, Methyl Methacrylate Acrylonitrile 
    Butadiene Styrene (MABS) Resin, Methyl Methacrylate Butadiene Styrene 
    (MBS) Resin, Polystyrene Resin, Poly (Ethylene Terephthalate) (PET) 
    Resin, and Nitrile Resin (Group IV Polymers and Resins)
    
    AGENCY: Environmental Protection Agency (EPA).
    
    ACTION: Proposed rule and notice of public hearing.
    
    ----------------------------------------------------------------------- [[Page 16091]] 
    
    
    SUMMARY: The proposed rule would reduce emissions of organic hazardous 
    air pollutants (HAP) from existing and new facilities that manufacture 
    one or more of the following Group IV polymers and resins: 
    Acrylonitrile butadiene styrene (ABS) resin, styrene acrylonitrile 
    (SAN) resin, methyl methacrylate acrylonitrile butadiene styrene (MABS) 
    resin, methyl methacrylate butadiene styrene (MBS) resin, polystyrene 
    resin, poly (ethylene terephthalate) (PET) resin, and nitrile resin. 
    The EPA is in the process of developing standards for a wide range of 
    types of polymer and resin production facilities. The polymers and 
    resins covered by this proposed rule are thermoplastics, and with two 
    exceptions, use styrene as the dominant feedstock. These thermoplastics 
    are basically intermediate products used to produce automotive plastic 
    parts, appliances and appliance parts, housewares, polyester fibers, 
    packing and containers, soft drink bottles, and toys. In the production 
    of thermoplastics, a variety of organic HAP are used as monomers or are 
    created as by-products. The organic HAP emitted by the facilities 
    covered by this proposed rule include styrene, acrylonitrile, 
    butadiene, ethylene glycol, methanol, acetaldehyde, and dioxane. Some 
    of these pollutants are considered to be mutagens and carcinogens, and 
    all can cause reversible or irreversible toxic effects following 
    exposure. The proposed rule is estimated to reduce organic HAP 
    emissions from existing facilities by 11,750 megagrams per year (Mg/
    yr). The emission reductions achieved by these standards, when combined 
    with the emission reductions achieved by other similar standards, will 
    achieve the primary goal of the Clean Air Act (Act) as amended in 1990, 
    which is to ``enhance the quality of the Nation's air resources so as 
    to promote the public health and welfare and the productive capacity of 
    its population''.
        The proposed rule implements section 112(d) of the Act, which 
    requires the Administrator or Administrator's designee, hereafter 
    referred to as Administrator, to regulate emissions of HAP listed in 
    section 112(b) of the Act. The intent of this rule is to protect the 
    public by requiring the maximum degree of reduction in emissions of 
    organic HAP from new and existing major sources, taking into 
    consideration the cost of achieving such emission reduction, and any 
    non-air quality, health and environmental impacts, and energy 
    requirements.
        Under today's action, the EPA is also proposing to revise subpart 
    DDD of 40 CFR part 60 by removing all references to polystyrene and PET 
    facilities contained therein. This proposed action is being taken 
    because today's proposed rule would supersede the requirements 
    specified in subpart DDD of 40 CFR part 60 for polystyrene and PET 
    facilities.
        Finally, under today's action, the EPA is proposing to add nitrile 
    resin production to the source category list under section 112(c) of 
    the Act and to the source category schedule under section 112(e) of the 
    Act with a promulgation date no later than November 15, 2000.
    
    DATES: Comments. Comments must be received on or before May 30, 1995.
        Public Hearing. If anyone contacts the EPA requesting to speak at a 
    public hearing by April 19, 1995, a public hearing will be held on 
    April 28, 1995 beginning at 10 a.m. Persons interested in attending the 
    hearing should call Ms. Marguerite Thweatt at (919) 541-5607 to verify 
    that a hearing will be held.
        Request to Speak at Hearing. Persons wishing to present oral 
    testimony must contact the EPA by April 19, 1995 by contacting Ms. 
    Marguerite Thweatt; Organic Chemicals Group, (MD-13), U. S. 
    Environmental Protection Agency, Research Triangle Park, North Carolina 
    27711, telephone number (919) 541-5607.
    
    ADDRESSES: Comments. Comments should be submitted (in duplicate, if 
    possible) to: Air Docket Section (LE-131), Attention: Docket No. A-92-
    45, U.S. Environmental Protection Agency, 401 M Street SW., Washington, 
    DC 20460. The EPA requests that a separate copy also be sent to the 
    contact person listed below. The public hearing, if required, will be 
    held at the EPA's Office of Administration Auditorium, Research 
    Triangle Park, North Carolina.
        The docket is located at the above address in room M-1500, 
    Waterside Mall (ground floor), and may be inspected from 8 a.m. to 4 
    p.m., Monday through Friday; telephone number (202) 382-7548. A 
    reasonable fee may be charged for copying docket materials.
    
    FOR FURTHER INFORMATION CONTACT: For information concerning the 
    proposed rule, contact Mr. Leslie Evans at (919) 541-5410, Organic 
    Chemicals Group, Emission Standards Division (MD-13), U.S. 
    Environmental Protection Agency, Research Triangle Park, North Carolina 
    27711.
    
    SUPPLEMENTARY INFORMATION: The proposed regulatory text is not included 
    in this Federal Register document, but is available in Docket No. A-92-
    45, on the Technology Transfer Network (TTN), or from the EPA contact 
    person designated in this notice. The TTN, EPA's electronic bulletin 
    board, provides information and technology exchange in various areas of 
    air pollution control. The service is free, except for the cost of a 
    telephone call. Dial (919) 541-5742 for up to a 14,400 bps modem. If 
    more information on the TTN is needed, call the HELP line at (919) 541-
    5384.
        In addition to the proposed regulatory text, the Basis and Purpose 
    Document, which contains the rationale for the various components of 
    the standard, is available in the docket (Docket No. A-92-45, Category 
    II-A), and on the TTN. This document is entitled Hazardous Air 
    Pollutant Emissions From Process Units in the Thermoplastics 
    Manufacturing Industry--Basis and Purpose Document for Proposed 
    Standards, March 1995, and has been assigned document number EPA-453/R-
    95-004a.
        Other materials related to this rulemaking, including technical 
    memoranda, are available for review in the docket. Some of these 
    memoranda have been compiled into a single document, the Supplementary 
    Information Document (SID), to allow interested parties more convenient 
    access to the information. The SID is available in the docket (Docket 
    No. A-92-45, Category II-A) and from the EPA Library by calling (919) 
    541-2777. The document is entitled Hazardous Air Pollutant Emissions 
    From Process Units in the Thermoplastics Manufacturing Industry--
    Supplementary Information Document for Proposed Standards, March 1995, 
    and has been assigned document number EPA-453/R-95-003a.
        The information presented in this preamble is organized as follows:
    
    I. List of Affected Source Categories
    II. Background
        A. Summary of Considerations Made in Developing This Rule
        B. Regulatory Background
    III. Authority for National Emission Standards for Hazardous Air 
    Pollutants (NESHAP) Decision Process
        A. Source of Authority for NESHAP Development
        B. Criteria for Development of NESHAP
    IV. Summary of Proposed Standards
        A. Source Categories To Be Regulated
        B. Relationship to Other Rules
        C. Pollutants To Be Regulated
        D. Affected Emission Points
        E. Format of the Standards
        F. Proposed Standards
        G. Compliance and Performance Test Provisions and Monitoring 
    Requirements
        H. Recordkeeping and Reporting Requirements
    V. Solicitation of Comments
    VI. Summary of Environmental, Energy, Cost, and Economic Impacts
        A. Facilities Affected by These NESHAP
        B. Primary Air Impacts
        C. Non-Air Impacts [[Page 16092]] 
        D. Energy Impacts
        E. Cost Impacts
        F. Economic Impacts
    VII. Administrative Requirements
        A. Public Hearing
        B. Docket
        C. Executive Order 12866
        D. Enhancing the Intergovernmental Partnership Under Executive 
    Order 12875
        E. Paperwork Reduction Act
        F. Regulatory Flexibility Act
        G. Miscellaneous
    
    I. List of Affected Source Categories
    
        Section 112 of the Act requires that the EPA evaluate and control 
    emissions of HAP. The control of HAP is achieved through promulgation 
    of emission standards under sections 112(d) and 112(f) of the Act and 
    work practice and equipment standards under section 112(h) of the Act 
    for categories of sources that emit HAP. On July 16, 1992, the EPA 
    published an initial list of major and area source categories to be 
    regulated, as required under section 112(c) of the Act. Included on 
    that list were major sources emitting HAP from ABS, SAN, MABS, MBS, 
    polystyrene, and PET. Nitrile resin production is being added to the 
    source category list under section 112(c) of the Act because, based on 
    information obtained during the gathering of HAP emission data for this 
    proposed rule, the one facility identified as producing nitrile resins 
    was determined to be a major source. Further, the EPA decided to 
    include nitrile resin production under today's proposed rule because of 
    similarities in process operations, emission characteristics, and 
    control device applicability and costs with the various styrene-based 
    resin source categories. For the purpose of this notice, these seven 
    polymer and resin source categories are collectively referred to as the 
    Group IV polymers and resins or the Group IV thermoplastics.
        The EPA identified a total of 66 facilities producing one or more 
    of the Group IV thermoplastics. Twenty facilities were identified that 
    produced thermoplastics using multiple processes and, thus, fall within 
    multiple subcategories. For example, six of the PET facilities use both 
    the continuous terephthalic acid (TPA) process and the continuous 
    dimethyl terephthalate (DMT) process.
        All of the facilities considered in the analysis supporting today's 
    proposed rule are believed to be major sources according to the 1990 
    Amendments criterion of emitting or of having the potential to emit 10 
    tons per year (tons/yr) of any one HAP or 25 tons/yr of combined HAP. 
    (A year, for the purposes of compliance with this rule, is any 
    consecutive twelve month period or 365 rolling days). The proposed rule 
    would apply to all major sources that produce any of the seven 
    thermoplastics identified in this notice. Area sources would not be 
    subject to this proposed rule.
        In developing the background information to support the proposed 
    rule, the EPA chose to subcategorize four of the seven source 
    categories for purposes of analyzing the maximum achievable control 
    technology (MACT) floors and developing regulatory alternatives. A 
    source category was subcategorized to account for major differences in 
    production methods, raw material usage, or both. Table 1 summarizes the 
    subcategories developed.
    
          Table 1.--Subcategorization of Group IV Polymers and Resinsa      
    ------------------------------------------------------------------------
                                                                 Number of  
         Source category                Subcategory            facilities in
                                                               subcategoryb 
    ------------------------------------------------------------------------
    ABS......................  Continuous mass..............               5
                               Continuous emulsion..........               2
                               Batch emulsion...............               4
                               Batch suspension.............               2
                               Batch latex..................               1
    SAN......................  Continuous...................               3
                               Batch........................               2
                               ASA/AMSAN....................               1
    Polystyrene..............  Continuous...................              22
                               Batch........................              11
                               EPS..........................               7
    PET......................  TPA, continuous..............              12
                               TPA, batch...................               1
                               DMT, continuous..............              10
                               DMT, batch...................             10 
    ------------------------------------------------------------------------
    a As discussed in the text, subcategorization was not needed for MABS,  
      MBS, and nitrile facilities. Thus, these source categories are not    
      shown in this table.                                                  
    b Number of facilities include one or more process units of each        
      described subcategory. Some facilities use more than one type of      
      production method or raw material (process). Therefore, it is         
      incorrect to sum these numbers to calculate the total number of       
      facilities within a source category.                                  
    ASA=acrylonitrile styrene acrylate.                                     
    AMSAN=alpha methyl styrene acrylonitrile.                               
    EPS=expandable polystyrene.                                             
    TPA=terephthalic acid.                                                  
    DMT=dimethyl terephthalate.                                             
    
        No subcategorization was found to be justified for the three 
    facilities producing MBS. Only one facility was found to produce MABS 
    and only one to produce nitrile resins. Hereafter, for purposes of this 
    preamble and the proposed standards, the terms ``subcategory'' and 
    ``subcategories'' include the production of MBS, MABS, and nitrile even 
    though these are source categories.
        Upon inspection (see Section IV, Summary of Proposed Standards), it 
    may appear that subcategorization does not affect the outcome of the 
    proposed standards since the same level of control is required across 
    most of the subcategories for a given type of emission point (e.g., 
    storage vessel, process vent, etc.). In fact, subcategorization does 
    affect the proposed level of control for individual types of emission 
    points. As the development of the proposed standards 
    [[Page 16093]] progressed beyond the technical analyses and the 
    structure of the regulation was examined, the EPA considered different 
    options that would create fewer subcategories for defining the source 
    categories.
        In previous rules, the EPA considered by-products, co-products, and 
    intermediates to be products of a process. In the implementation of 
    these previous rules, there has been confusion over the meaning of the 
    terms ``product'' and ``to produce'' and the correct way to decide 
    whether a source ``produces'' a listed chemical and is subject to the 
    standard.
        This confusion arises because of the complexity, diversity, and the 
    highly integrated nature of the subject industries.
        Because of this confusion, applicability will be based on the 
    primary product that is produced by a thermoplastic product process 
    unit. By-products, co-products, and isolated intermediates would not be 
    considered in determining applicability. For the purposes of this rule, 
    the EPA does not consider wastes to be products. Also, impurities or 
    trace contaminants that are coincidentally processed and are not 
    isolated are not considered to be a product.
        The primary product of the thermoplastic product process unit is 
    determined only once, and the determination would be based on the 
    product that represents the largest percentage of the total mass 
    produced by the thermoplastic product process unit.
    
    II. Background
    
    A. Summary of Considerations Made in Developing This Rule
    
        The Act was created, in part, ``to protect and enhance the quality 
    of the Nation's air resources so as to promote public health and 
    welfare and the productive capacity of its population'' (section 
    101(b)(1) of the Act). As such, this regulation protects the public 
    health by reducing emissions of some of the HAP listed in section 
    112(b)(1) of the Act.
        The HAP listed in section 112(b)(1) of the Act emitted by the 
    thermoplastic facilities covered by this proposed rule include styrene, 
    acrylonitrile, butadiene, ethylene glycol, methanol, acetaldehyde, and 
    dioxane. Some of these pollutants are considered to be mutagens and 
    carcinogens, and all can cause reversible or irreversible toxic effects 
    following exposure. The potential toxic effects include eye, nose, 
    throat, and skin irritation; liver and kidney toxicity, and 
    neurotoxicity. These effects can range from mild to severe. In extreme 
    circumstances, death can result from exposure. These adverse health 
    effects are associated with a wide range of ambient concentrations and 
    exposure times and are influenced by source-specific characteristics 
    such as emission rates and local meteorological conditions. Health 
    impacts are also dependent on multiple factors that affect human 
    variability such as genetics, age, health status (e.g., presence of 
    pre-existing disease) and lifestyle. Due to the volatility and 
    relatively low potential for bioaccumulation of these pollutants, air 
    emissions are not expected to deposit in land or water and cause 
    subsequent adverse human health or ecosystem effects.
        The EPA does not have the type of current detailed data on each of 
    the thermoplastic facilities covered by this rule, and the people 
    living around the facilities, that would be necessary to conduct an 
    analysis to determine the actual population exposures to the organic 
    HAP emitted from these facilities and resulting health effects. 
    Therefore, the EPA does not know the extent to which the adverse health 
    effects described above occur in the populations surrounding these 
    facilities. However, to the extent the adverse effects do occur, the 
    promulgated standard will substantially reduce emissions and exposures 
    to the level achievable with maximum achievable control technology.
        The alternatives considered in the development of this regulation, 
    including those alternatives selected as standards for new and existing 
    sources, are based on process and emissions data received from the 
    existing facilities known by the EPA to be in operation.
        Regulatory alternatives more stringent than the MACT floor were 
    selected when they were judged to be reasonable ``taking into 
    consideration the cost of achieving such emission reduction, and any 
    non-air quality health and environmental impacts and energy 
    requirements'' (Section 112(d)(2) of the Act). In most instances, the 
    proposed standards reflect regulatory alternatives that are judged to 
    be reasonable and are equivalent to or more stringent than the MACT 
    floor. In a few instances, the MACT floor was found to have a 
    relatively high cost. In these cases, the MACT floor was chosen because 
    a less costly, yet otherwise reasonable, regulatory alternative was not 
    available.
        The proposed standards give existing facilities 3 years from the 
    date of promulgation to comply. This is the maximum amount allowed by 
    the Act. Based on the number of existing sources affected by this rule, 
    the EPA believes that required retrofits or other actions can be 
    achieved in the timeframe allotted. New facilities are required to 
    comply with the standard upon start-up. The EPA sees no reason why new 
    facilities would not be able to comply with the requirements of the 
    standards upon start-up.
        Included in the proposed rule are methods for determining initial 
    compliance as well as monitoring, recordkeeping, and reporting 
    requirements. All of these components are necessary to ensure that 
    affected sources will comply with the standards both initially and over 
    time. However, the EPA has made every effort to simplify the 
    requirements in the rule. This rule refers extensively to the HON (40 
    CFR part 63, subparts F, G, and H). In doing so, this rule has 
    benefited from the extensive public debate and participation 
    experienced in the HON rulemaking. The EPA has also attempted to 
    maintain consistency with existing regulations by either incorporating 
    text from existing regulations or referencing the applicable sections, 
    depending on which method would be least confusing for a given 
    situation.
        Representatives from other interested EPA offices and programs, 
    including State and Regional environmental agency personnel, 
    participated in the regulatory development process as members of the 
    Work Group. The Work Group is involved in the regulatory development 
    process, and is given opportunities to review and comment on the 
    regulation before proposal and promulgation. Therefore, the EPA 
    believes that the implication to other EPA offices and programs has 
    been adequately considered during the development of these standards. 
    In addition, the EPA has met with some members of industry concerning 
    these standards. Finally, industry, regulatory authorities, and 
    environmental groups will have the opportunity to comment on the 
    proposed standards and provide additional information during the public 
    comment period following proposal.
        These standards will result in an organic HAP emission reduction of 
    11,750 Mg/yr for existing facilities and 7,395 Mg/yr for new sources. 
    The emission reductions achieved by these standards, when combined with 
    the emission reductions achieved by other standards mandated by the 
    Act, will achieve the primary goal of the Clean Air Act, which is to 
    ``enhance the quality of the Nation's air resources so as to promote 
    the public health and welfare and the productive capacity of its 
    population.'' [[Page 16094]] 
    
    B. Regulatory Background
    
        In 1990 (55 FR 51010, December 11, 1990), the EPA promulgated new 
    source performance standards (NSPS) affecting four types of polymer 
    manufacturing facilities (subpart DDD of 40 CFR part 60). Two of these 
    four types--polystyrene and PET--are being affected by today's proposed 
    rule. In addition, polystyrene manufacturing facilities may be subject 
    to State regulations as the result of a control techniques guideline 
    (CTG) document (EPA-450/3-83-008, November 1983; Docket No. A-92-45, 
    Category II-A) addressing, in part, polystyrene manufacturing.
        For polystyrene, subpart DDD applies to those facilities that use a 
    continuous process to manufacture general purpose or high impact 
    polystyrene. Facilities that produce general purpose or high impact 
    polystyrene using a batch process were not covered under subpart DDD 
    because information at that time indicated that no new facilities would 
    be constructed using batch processes to produce general purpose or high 
    impact polystyrene. Subpart DDD also applies to all facilities that 
    manufacture expandable polystyrene (EPS), regardless of the process 
    used.
        For general purpose or high impact polystyrene facilities using a 
    continuous process and all facilities producing EPS, subpart DDD 
    requires control of continuous process volatile organic compound (VOC) 
    emissions from each material recovery section. The standard for 
    material recovery section process emissions is: (1) Limit the emissions 
    of total organic compounds (TOC) (minus methane and ethane) to 0.0036 
    kilograms (kg) of TOC per megagram (Mg) of product (0.0036 pounds (lbs) 
    TOC/1,000 lbs of product) from each material recovery section, (2) 
    limit the outlet gas temperature from each final condenser in each 
    material recovery section to -25 degrees Celcius (-25 deg. C) (-13 deg. 
    Fahrenheit (-13 deg. F)), or (3) reduce emissions from each material 
    recovery section by 98 weight percent or to 20 parts per million by 
    volume (ppmv). Modified or reconstructed affected facilities with 
    uncontrolled emission rates at or below 0.05 kg TOC per Mg of product 
    were exempted from this part of subpart DDD.
        Like subpart DDD, the CTG applies to material recovery section 
    continuous process emissions at polystyrene facilities using a 
    continuous process. The CTG's recommended emission limit is 0.12 kg 
    TOC/Mg of product.
        Subpart DDD also requires control of VOC emissions from equipment 
    leaks from polystyrene facilities using a continuous process and from 
    all EPS facilities. With one exception, subpart DDD's standards for 
    equipment leaks are the same as those for synthetic organic chemical 
    manufacturing industry (SOCMI) facilities under subpart VV of 40 CFR 
    part 60. The one exception concerns polymer pumps that are designed 
    with a ``bleed port.'' Such pumps are exempted from the definition of a 
    ``visible leak of fluid,'' but the exemption expires when the existing 
    pump is replaced or reconstructed.
        As mentioned previously, subpart DDD also applies to PET facilities 
    that use either a DMT or TPA continuous process. Subpart DDD does not 
    apply to PET facilities that use a batch process because the EPA did 
    not expect any new PET facilities to be constructed using a batch 
    process. For PET facilities using a continuous process, subpart DDD 
    only requires control of selected process emissions. Standards were not 
    proposed or promulgated for equipment leak emissions at PET facilities 
    because available information at that time showed that equipment leak 
    components at facilities using the continuous TPA process were in heavy 
    liquid service and that continuous DMT facilities were already covered 
    by the SOCMI equipment leak standards (subpart VV of 40 CFR part 60).
        Table 2 summarizes subpart DDD requirements for process emissions 
    for new, modified, or reconstructed PET facilities. For both DMT and 
    TPA continuous facilities, subpart DDD limits ethylene glycol emissions 
    from the polymerization reaction section by requiring compliance with 
    an emission rate limit (0.02 kg TOC/Mg of product) and an ethylene 
    glycol weight percent concentration limit (either 0.35 or 6.0 percent 
    depending on the type of process) for the cooling water in the cooling 
    tower. In addition, subpart DDD limits process emissions from the 
    material recovery section at continuous DMT facilities and from the raw 
    material preparation section at continuous TPA facilities.
    
                                         Table 2.--Summary of NSPS Pet Standards                                    
    ----------------------------------------------------------------------------------------------------------------
                           Affected                          Number of end    Type of vacuum                        
         Process           facility          Viscosity         finishers         producer             Standard      
    ----------------------------------------------------------------------------------------------------------------
    DMT..............  Material          Low.............  ................  ................  0.018 kg TOC/Mg of   
                        Recovery.                                                               product OR limit    
                                                                                                temperature to +37  
                                                                                                deg.F from each     
                                                                                                final condenser in  
                                                                                                the material        
                                                                                                recovery section.   
                                         High............  Single..........  ................  (same as above).     
                                                           Multiple........  ................  (same as above).     
    DMT..............  Poly- merization  Low.............  ................  Not steam jets..  0.02 kg TOC/Mg of    
                        Reaction.                                                               product.            
                                                                             Steam jets......  0.02 kg TOC/Mg of    
                                                                                                product AND 0.35    
                                                                                                percent ethylene    
                                                                                                glycol by weight in 
                                                                                                the effluent exiting
                                                                                                the vacuum system.  
                                         High............  Single..........  Not steam jets..  0.02 kg TOC/Mg of    
                                                                                                product.            
                                                                             Steam jets......  0.02 kg TOC/Mg of    
                                                                                                product AND 0.35    
                                                                                                percent ethylene    
                                                                                                glycol by weight in 
                                                                                                the effluent exiting
                                                                                                the vacuum system.  
                                                           Multiple........  Not steam jets..  0.02 kg TOC/Mg of    
                                                                                                product.            
                                                                             Steam jets......  0.02 kg TOC/Mg of    
                                                                                                product AND 6.0     
                                                                                                percent ethylene    
                                                                                                glycol by weight in 
                                                                                                the cooling water in
                                                                                                the cooling tower.  
    TPA..............  Raw Materials     Low.............  ................  ................  0.04 kg TOC/Mg of    
                        Preparation.                                                            product.            
                                         High............  Single..........  ................  (same as above).     
    [[Page 16095]]                                                                                                  
                                                                                                                    
                                         ................  Multiple........  ................  (same as above).     
    TPA..............  Polymerization    Low.............  ................  Not steam jets..  0.02 kg TOC/Mg of    
                        Reaction.                                                               product.            
                                                                             Steam jets......  0.02 kg TOC/Mg of    
                                                                                                product AND 0.35    
                                                                                                percent ethylene    
                                                                                                glycol by weight in 
                                                                                                the effluent exiting
                                                                                                the vacuum system.  
                                         High............  Single..........  Not steam jets..  0.02 kg TOC/Mg of    
                                                                                                product.            
                                                                             Steam jets......  0.02 kg TOC/Mg of    
                                                                                                product AND 0.35    
                                                                                                percent ethylene    
                                                                                                glycol by weight in 
                                                                                                the effluent exiting
                                                                                                the vacuum system.  
                                                           Multiple........  Not steam jets..  0.02 kg TOC/Mg of    
                                                                                                product.            
                                                                             Steam jets......  0.02 kg TOC/Mg of    
                                                                                                product AND 6.0     
                                                                                                percent ethylene    
                                                                                                glycol by weight in 
                                                                                                the cooling water in
                                                                                                the cooling tower.  
    ----------------------------------------------------------------------------------------------------------------
    Key:                                                                                                            
    DMT = dimethyl terephthalate.                                                                                   
    TPA = terephthalic acid.                                                                                        
    
        In a manner similar to polystyrene facilities, subpart DDD has 
    uncontrolled emission rate thresholds at or below which modified or 
    reconstructed PET facilities are exempt. Table 3 summarizes these 
    threshold emission rates.
    
                Table 3.--Summary of Pet Threshold Emission Rates           
    ------------------------------------------------------------------------
                                                               Uncontrolled 
                                                              emission rate,
         Production process            Process section          kg TOC/Mg   
                                                                 producta   
    ------------------------------------------------------------------------
    Poly(ethylene                Material Recovery.........  0.12b,c        
     terephthalate), dimethyl    Polymerization Reaction...  1.80c,d,e      
     terephthalate process.                                                 
    Poly(ethylene                Raw Materials.............  g              
     terephthalate),             Preparation...............  1.80c,e,h      
     terephthalic acid process.                                             
                                 Polymerization Reaction...  3.92c,f,h      
    ------------------------------------------------------------------------
    a``Uncontrolled emission rate'' refers to the emission rate of a vent   
      stream that vents directly to the atmosphere and to the emission rate 
      of a vent stream to the atmosphere that would occur in the absence of 
      any add-on control devices but after any material recovery devices    
      that constitute part of the normal material recovery operations in a  
      process line where potential emissions are recovered for recycle or   
      resale.                                                               
    bEmission rate applies to continuous emissions only.                    
    cApplies to modified or reconstructed affected facilities only.         
    dIncludes emissions from the cooling water tower.                       
    eApplies to a process line producing low viscosity poly(ethylene        
      terephthalate).                                                       
    ffApplies to a process line producing high viscosity poly(ethylene      
      terephthalate).                                                       
    gSee footnote h.                                                        
    hApplies to the sum of emissions to the atmosphere from the             
      polymerization reaction section (including emissions from the cooling 
      water tower) and the raw materials preparation section (i.e., the     
      esterifiers).                                                         
    
        In 1994 (59 FR 46350, September 8, 1994), the EPA promulgated 
    national emission standards for hazardous air pollutants (NESHAP) for 
    industrial process cooling towers (40 CFR part 63, subpart G). This 
    rule prohibits the use of chromium-based water treatment chemicals in 
    industrial process cooling towers. Owners and operators of existing 
    industrial process cooling towers must comply within 18 months of 
    September 8, 1994, while owners and operators of new industrial process 
    cooling towers must comply by September 8, 1994 or at initial start-up, 
    depending on when construction was commenced.
    
    III. Authority for National Emission Standards for Hazardous Air 
    Pollutants (NESHAP) Decision Process
    
    A. Source of Authority for NESHAP Development
    
        Section 112 of the Act gives the EPA the authority to establish 
    national standards to reduce air emissions from sources that emit one 
    or more HAP. Section 112(b) contains a list of HAP to be regulated by 
    NESHAP. Section 112(c) directs the EPA to use this pollutant list to 
    develop and publish a list of source categories for which NESHAP will 
    be developed. The EPA must list all known source categories and 
    subcategories of ``major sources'' (defined below) that emit one or 
    more of the listed HAP. A major source is defined in section 112(a) as 
    any stationary source or group of stationary sources located within a 
    contiguous area and under common control that emits or has the 
    potential to emit in the aggregate, considering controls, 10 tons/yr or 
    more of any one HAP or 25 tons/yr or more of any combination of HAP. 
    This list of source categories was published in the Federal Register on 
    July 16, 1992 (57 FR 31576) and includes ABS, SAN, MABS, MBS, 
    polystyrene, and PET. Today's action proposes to add nitrile resin 
    production to this list.
    
    B. Criteria for Development of NESHAP
    
        The NESHAP are to be developed to control HAP emissions from both 
    new and existing sources according to the statutory directives set out 
    in section [[Page 16096]] 112(d) of the Act. The statute requires the 
    standards to reflect the maximum degree of reduction in emissions of 
    HAP that is achievable for new or existing sources. This control level 
    is referred to as MACT. Consideration of control levels more stringent 
    than the MACT floor (described below) must reflect consideration of the 
    cost of achieving the emission reduction, any non-air quality, health, 
    and environmental impacts, and energy requirements.
        The MACT floor is the least stringent level allowed for MACT 
    standards. For new sources, the standards for a source category or 
    subcategory ``shall not be less stringent than the emission control 
    that is achieved in practice by the best controlled similar source, as 
    determined by the Administrator'' (section 112(d)(3) of the Act). 
    Existing source standards shall be no less stringent than the average 
    emission limitation achieved by the best performing 12 percent of the 
    existing sources for categories and subcategories with 30 or more 
    sources or the average emission limitation achieved by the best 
    performing 5 sources for categories or subcategories with fewer than 30 
    sources (section 112(d)(3) of the Act). These two minimum levels of 
    control define the MACT floor for new and existing sources.
        Two interpretations have been evaluated by the EPA for representing 
    the MACT floor for existing sources. One interpretation is that the 
    MACT floor is represented by the worst performing source of the best 12 
    percent performing sources. The second interpretation is that the MACT 
    floor is represented by the ``average emission limitation achieved'' by 
    the best performing sources, where the ``average'' is based on a 
    measure of central tendency, such as the arithmetic mean, median, or 
    mode. This latter interpretation is referred to as the ``higher floor 
    interpretation.'' In a June 6, 1994 Federal Register notice (59 FR 
    29196), the EPA presented its interpretation of the statutory language 
    concerning the MACT floor for existing sources. Based on a review of 
    the statute, legislative history, and public comments, the EPA believes 
    that the ``higher floor interpretation'' is a better reading of the 
    statutory language. The determination of the MACT floor for existing 
    sources under today's rule followed the ``higher floor 
    interpretation.''
    
    IV. Summary of Proposed Standards
    
    A. Source Categories To Be Regulated
    
        Today's proposed standards would regulate organic HAP process 
    emissions from facilities in one of the 18 thermoplastic subcategories 
    listed below, provided that a facility is determined to be a major 
    source. For this proposed rule, an affected source is defined as one of 
    the following:
         All organic HAP emission points at a facility using a 
    continuous emulsion process to produce ABS.
         All organic HAP emission points at a facility using a 
    continuous mass process to produce ABS.
         All organic HAP emission points at a facility using a 
    batch emulsion process to produce ABS.
         All organic HAP emission points at a facility using a 
    batch suspension process to produce ABS.
         All organic HAP emission points at a facility using a 
    batch latex process to produce ABS.
         All organic HAP emission points at a facility producing 
    MABS.
         All organic HAP emission points at a facility producing 
    MBS.
         All organic HAP emission points at a facility using a 
    continuous process to produce SAN.
         All organic HAP emission points at a facility using a 
    batch process to produce SAN.
         All organic HAP emission points at a facility producing 
    ASA/AMSAN.
         All organic HAP emission points at a facility using a 
    continuous process to produce polystyrene.
         All organic HAP emission points at a facility using a 
    batch process to produce polystyrene.
         All organic HAP emission points at a facility producing 
    EPS.
         All organic HAP emission points at a facility using a 
    continuous TPA process to produce PET and any collocated solid state 
    processes.
         All organic HAP emission points at a facility using a 
    batch TPA process to produce PET and any collocated solid state 
    processes.
         All organic HAP emission points at a facility using a 
    continuous DMT process to produce PET and any collocated solid state 
    processes.
         All organic HAP emission points at a facility using a 
    batch DMT process to produce PET and any collocated solid state 
    processes.
         All organic HAP emission points at a facility producing 
    nitrile resins.
        The proposed rule regulates emissions from solid state PET 
    processes if they are collocated with a TPA or DMT fed PET process, but 
    does not regulate emissions from independently located solid state PET 
    processes (i.e., those that purchase low molecular weight PET from an 
    off-site source). As part of the rulemaking, information was submitted 
    by the industry for collocated solid state PET processes, but none was 
    submitted for independently located solid state PET processes.
    
        (Note: The data request did not distinguish solid state as a 
    separate process which might have precipitated companies not 
    submitting data concerning PET produced by this process.)
    
        In addition, the EPA believes that independently located solid 
    state PET processes are likely to be non-major sources because there is 
    not a significant source of organic HAP emissions from the solid state 
    process. The emissions from a solid state process are typically the 
    result of release of residual monomer in the low molecular weight PET. 
    For these reasons, the EPA chose not to include independently located 
    solid state PET processes in today's proposed rule.
    
    B. Relationship to Other Rules
    
        Sources subject to the proposed rule are also subject to other 
    existing rules. In some cases, the proposed rule supersedes existing 
    rules and affected sources are no longer required to comply with the 
    existing rule. In other cases, there is no conflict between the 
    existing rule and the proposed rule, and in these cases, the affected 
    source must comply with both rules.
        Sources subject to the proposed rule and subject to the NESHAP for 
    Certain Processes Subject to the Negotiated Regulation for Equipment 
    Leaks (40 CFR part 63, subpart I) are required to continue to comply 
    with subpart I until the compliance date of the proposed rule. After 
    the compliance date of the proposed rule, compliance with the proposed 
    rule will constitute compliance with subpart I.
        Sources subject to the proposed rule may have storage vessels 
    subject to the NSPS for Volatile Organic Liquid Storage Vessels (40 CFR 
    part 60, subpart Kb). After the compliance date for the proposed rule, 
    such storage vessels are only subject to the proposed rule and are no 
    longer required to comply with subpart Kb.
        Some sources subject to the proposed rule that produce PET or 
    polystyrene are also subject to the NSPS for Polymers Manufacturing (40 
    CFR part 60, subpart DDD). After the compliance date for the proposed 
    rule, such sources are only subject to the proposed rule and are no 
    longer required to comply with subpart DDD. As part of this rulemaking, 
    the EPA is proposing to modify subpart DDD to exclude reference to the 
    manufacture of polystyrene and PET.
        Sources subject to the proposed rule may have cooling towers 
    subject to the NESHAP for Industrial Cooling Towers [[Page 16097]] (40 
    CFR part 63, subpart Q). There is no conflict between the requirements 
    of subpart Q and the proposed rule. Therefore, sources subject to both 
    rules must comply with both rules.
    
    C. Pollutants To Be Regulated
    
        The subcategories covered by today's proposed rule emit a variety 
    of organic HAP. Among the most significant emissions of organic HAP are 
    the following: Styrene, acrylonitrile, and butadiene from styrene-based 
    resin production, which includes the production of ABS, SAN, MABS, MBS, 
    and polystyrene; acrylonitrile from nitrile resin production; and 
    ethylene glycol, methanol, acetaldehyde, and dioxane from PET 
    production. The proposed standards would regulate emissions of these 
    compounds, as well as a variety of other organic HAP that are emitted.
    
    D. Affected Emission Points
    
        Emissions from the following types of emission points (i.e. 
    emission source types) are being covered by today's proposed rule: 
    storage vessels, process vents, equipment leaks, wastewater operations, 
    heat exchange systems and process contact cooling towers.
    
    E. Format of the Standards
    
        As discussed in more detail in Section IV.F, Proposed Standards, 
    the Hazardous Organic NESHAP (HON) (subparts F, G, H, and I of 40 CFR 
    part 63), the polymer manufacturing NSPS (subpart DDD of 40 CFR part 
    60), and the Batch Processes Alternative Control Techniques (ACT) 
    document (EPA 453/R-93-017, November 1993; Docket No. A-92-45, Category 
    II-A) provided a basis for selection of the proposed formats. In most 
    instances, the format of today's proposed standards is the same as 
    those found in the HON, Batch Processes ACT, and subpart DDD. The 
    following paragraphs summarize the selected formats, including those 
    that are different from the HON, Batch Processes ACT, and subpart DDD. 
    The formats and their selection are discussed in more detail in the 
    Basis and Purpose Document for this proposed regulation (Docket No. A-
    92-45, Category II-A).
        For storage vessels, the format of the proposed standards is 
    dependent on the method selected to comply with the standards. If tank 
    improvements (e.g., internal or external floating roofs with proper 
    seals and fittings) are selected, the format is a combination of 
    design, equipment, work practice, and operational standards. If a 
    closed vent system and control device are selected, the format is a 
    combination of design and equipment standards.
        For process vents, the format of the proposed standards is also 
    dependent on the method selected to comply with the standards. If a 
    flare is selected, the format is a combination of equipment and 
    operating specifications. If a control device other than a flare is 
    used, the formats are a percent reduction and an outlet concentration.
        For equipment leaks, the proposed standards incorporate several 
    formats: Equipment, design, base performance levels (e.g., maximum 
    allowable percent leaking valves), work practices, and operational 
    practices. Different formats are necessary for different types of 
    equipment because of the nature of the equipment, available control 
    techniques, and applicability of the measurement method.
        For wastewater streams requiring control, the proposed standards 
    incorporate several formats: Equipment, operational, work practice, and 
    emission standards. The particular format selected depends on which 
    portion of the wastewater stream is involved. For transport and 
    handling equipment, the selected format is a combination of equipment 
    standards and work practices. For the reduction of organic HAP from the 
    wastewater stream itself, several alternative formats are included, 
    including five alternative numerical emission limit formats (overall 
    percent reduction for total volatile organic HAP (VOHAP), individual 
    organic HAP percent reduction, effluent concentration limit for total 
    VOHAP, individual VOHAP effluent concentration limits, and mass removal 
    for organic HAP) and equipment design and operation standard for a 
    steam stripper. For vapor recovery and destruction devices other than 
    flares, the format is a weight percent reduction. For flares, the 
    format is a combination of equipment and operating specifications.
        Finally, a work practice standard is adopted for all cooling water/
    process heat exchange systems at Group IV resin facilities. This 
    standard requires a leak detection and repair program to detect and 
    repair leaks of organic HAP into cooling tower water. In addition, the 
    proposed standards include a work practice standard that prohibits the 
    use of cooling tower water in contact condensers in vacuum systems 
    located at PET facilities.
    
    F. Proposed Standards
    
        With relatively few exceptions, the standards being proposed under 
    today's action for storage vessels, continuous process vents, equipment 
    leaks, wastewater operations, and heat exchange systems are the same as 
    those promulgated for the corresponding types of emission points at 
    facilities subject to the HON (subparts F, G, H, and I). The proposed 
    standards also require emissions from certain batch process vents to be 
    reduced by at least 90 percent or to be controlled in a flare that 
    meets the requirements of Sec. 63.11(b) of subpart A of 40 CFR part 63. 
    (The criteria used to determine which batch process vents require 
    control was based on the approach described in the Batch Processes 
    ACT.) The standards being proposed today for certain continuous process 
    vents from polystyrene facilities and from PET facilities using a 
    continuous process require the same levels of control as were 
    promulgated for these facilities under subpart DDD of 40 CFR part 60. 
    Finally, for PET facilities, the proposed standards would prohibit the 
    use of cooling tower water in contact condensers in the vacuum systems 
    and would require that all vacuum system wastewater containing any of 
    the organic HAP identified in Table 9 of the HON wastewater provisions 
    be controlled to the same level of control as required under the HON, 
    regardless of the wastewater stream's organic HAP content or flowrate.
        Under the proposed standards, emissions from existing or new batch 
    process vents, heat exchange systems not including process contact 
    cooling towers, and equipment leaks are required to be controlled to 
    the levels specified in the proposed standards. Emissions from existing 
    storage vessels, continuous process vents, process wastewater streams, 
    and process contact cooling towers are required to be controlled to the 
    levels specified in the proposed standards or alternatively, the 
    emissions averaging compliance approach specified in the rule may be 
    used. Emissions from new storage vessels, continuous process vents, 
    process wastewater streams, and process contact cooling towers are 
    required to be controlled to the levels specified in the proposed 
    standards. The emissions averaging compliance approach may not be used 
    for new sources.
        Tables 4 and 5 summarize the level of control being proposed under 
    today's proposed standards. For those types of emission points where 
    the level of control is the same as the HON, this is indicated in the 
    table by the acronym ``HON.'' Similarly, where the proposed level of 
    control is the same as promulgated under subpart DDD of 40 CFR part 60, 
    this is indicated by the use of the words ``same as under subpart 
    DDD.'' Finally, where the proposed [[Page 16098]] level of control is 
    more stringent than the level of control in the HON or in subpart DDD 
    for that type of emission point, the words ``MACT floor'' are used.
    
     Table 4.--Summary of Proposed Standards for Existing Sources in Relationship to Subparts G and H of 40 CFR Part
                                          63 and Subpart DDD of 40 CFR Part 60                                      
    ----------------------------------------------------------------------------------------------------------------
                                                           Type of emission point                                   
                      ----------------------------------------------------------------------------------------------
       Subcategory                                                                                    Heat exchange 
                        Storage vessels      Process vents       Equipment leaks     Wastewater          systems    
    ----------------------------------------------------------------------------------------------------------------
    ABS, continuous    HON.............  HON..................  HON.............  HON.............  HON for heat    
     emulsion.                                                                                       exchange       
                                                                                                     systems.       
    ABS, continuous    HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     mass.                                Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    ABS, batch         HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     emulsion.                            Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    ABS, batch         HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     suspension.                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    ABS, latex.......  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    MABS.............  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    MBS..............  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: MACT Floor                                          exchange       
                                          Batch Process Vents:                                       systems.       
                                          90 percent reduction                                                      
                                          or compliant flare.                                                       
    SAN, continuous..  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    SAN, batch.......  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    ASA/AMSAN........  MACT Floor......  MACT Floor...........  HON.............  No control......  HON for heat    
                                                                                                     exchange       
                                                                                                     systems.       
    Polystyrene,       MACT Floor......  Continuous Process     HON.............  HON.............  HON for heat    
     continuous.                          Vents from material                                        exchange       
                                          recovery: same as                                          systems.       
                                          subpart DDD Other                                                         
                                          Continuous Process                                                        
                                          vents: HON Batch                                                          
                                          Process Vents: 90                                                         
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    Polystyrene,       HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     batch.                               Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    Expandable         HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     polystyrene.                         Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    PET-TPA,           HON.............  Continuous Process     HON.............  HON for           No cooling tower
     continuous.                          Vents from raw                           wastewater        water allowed  
                                          material preparation                     (including all    in vacuum      
                                          and polymerization                       vacuum system     system contact 
                                          reaction sections:                       generated         condensers. HON
                                          same as subpart DDD                      wastewater).a.    for heat       
                                          Other Continuous                                           exchange       
                                          Process vents: HON                                         systems.       
                                          Batch Process Vents:                                                      
                                          90 percent reduction                                                      
                                          or compliant flare.                                                       
    PET-TPA, batch -   HON.............  Continuous Process     HON.............  HON for           No cooling tower
     DMT, batch.                          Vents: HON Batch                         wastewater        water allowed  
                                          Process Vents: 90                        (including all    in vacuum      
                                          percent reduction or                     vacuum system     system contact 
                                          compliant flare.                         generated         condensers. HON
                                                                                   wastewater)..     for heat       
                                                                                                     exchange       
                                                                                                     systems.       
    PET-DMT,           HON.............  Continuous Process     HON.............  HON for           No cooling tower
     continuous.                          Vents from material                      wastewater        water allowed  
                                          recovery and                             (including all    in vacuum      
                                          polymerization                           vacuum system     system contact 
                                          reaction sections:                       generated         condensers. HON
                                          same as subpart DDD                      wastewater).a.    for heat       
                                          Other Continuous                                           exchange       
                                          Process vents: HON                                         systems.       
                                          Batch Process Vents:                                                      
                                          90 percent reduction                                                      
                                          or compliant flare.                                                       
    [[Page 16099]]                                                                                                  
                                                                                                                    
    Nitrile..........  MACT Floor......  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          compliant flare.                                                          
    ----------------------------------------------------------------------------------------------------------------
    a Vacuum system wastewater streams containing any organic HAP identified in Table 9 of the HON wastewater       
      provisions (subpart G) shall be considered Group 1 and are required to be controlled.                         
    
    
     Table 5.--Summary of Proposed Standards for New Sources in Relationship to Subparts G & H of 40 CFR Part 63 and
                                              Subpart DDD of 40 CFR Part 60                                         
    ----------------------------------------------------------------------------------------------------------------
                                                           Type of emission point                                   
                      ----------------------------------------------------------------------------------------------
       Subcategory                                                                                    Heat exchange 
                        Storage vessels      Process vents       Equipment leaks     Wastewater          systems    
    ----------------------------------------------------------------------------------------------------------------
    ABS, continuous    HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     emulsion.                            Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    ABS, continuous    Regulatory        Continuous Process     HON.............  HON.............  HON for heat    
     mass.              Alternative 2a.   Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    ABS. batch         HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     emulsion.                            Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    ABS. batch         HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     suspension.                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    ABS, latex.......  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    MABS.............  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    MBS..............  HON.............  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    SAN, continuous..  MACT Floor......  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    SAN, batch.......  HON.............  MACT Floor...........  HON.............  HON.............  HON for heat    
                                                                                                     exchange       
                                                                                                     systems.       
    ASA/AMSAN........  MACT Floor......  MACT Floor...........  HON.............  No control......  HON for heat    
                                                                                                     exchange       
                                                                                                     systems.       
    Polystyrene,       MACT Floor......  Continuous Process     HON.............  HON.............  HON for heat    
     continuous.                          Vents from material                                        exchange       
                                          recovery: Same as                                          systems.       
                                          subpart DDD Other                                                         
                                          Continuous Process                                                        
                                          Vents: HON Batch                                                          
                                          Process Vents: 90                                                         
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    Polystyrene,       HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     batch.                               Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    Expandable         HON.............  Continuous Process     HON.............  HON.............  HON for heat    
     polystyrene.                         Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    PET--TPA,          HON.............  Continuous Process     HON.............  HON for           No cooling tower
     continuous.                          Vents from raw                           wastewater        water allowed  
                                          material preparation                     (including all    in vacuum      
                                          and polymerization                       vacuum system     system contact 
                                          reaction sections:                       generated         condensers. HON
                                          same as subpart DDD                      wastewater).b.    for heat       
                                          Other Continuous                                           exchange       
                                          Process Vents: HON                                         systems.       
                                          Batch Process Vents:                                                      
                                          90 percent reduction                                                      
                                          or a compliant flare.                                                     
    [[Page 16100]]                                                                                                  
                                                                                                                    
    PET--TPA, batch--  HON.............  Continuous Process     HON.............  HON for           No cooling tower
     DMT, batch.                          Vents: HON Batch                         wastewater        water allowed  
                                          Process Vents: 90                        (including all    in vacuum      
                                          percent reduction or                     vacuum system     system contact 
                                          a compliant flare.                       generated         condensers. HON
                                                                                   wastewater).b.    for heat       
                                                                                                     exchange       
                                                                                                     systems.       
    PET--DMT,          HON.............  Continuous Process     HON.............  HON for           No cooling tower
     continuous.                          Vents from material                      wastewater        water allowed  
                                          recovery and                             (including all    in vacuum      
                                          polymerization                           vacuum system     system contact 
                                          reaction sections:                       generated         condensers. HON
                                          same as subpart DDD                      wastewater).b.    for heat       
                                          Other Continuous                                           exchange       
                                          Process Vents: HON                                         systems.       
                                          Batch Process Vents:                                                      
                                          90 percent reduction                                                      
                                          or a compliant flare.                                                     
    Nitrile..........  MACT Floor......  Continuous Process     HON.............  HON.............  HON for heat    
                                          Vents: HON Batch                                           exchange       
                                          Process Vents: 90                                          systems.       
                                          percent reduction or                                                      
                                          a compliant flare.                                                        
    ----------------------------------------------------------------------------------------------------------------
    aThe proposed standard is more stringent than the MACT floor, which is more stringent than the HON.             
    bVacuum system wastewater streams containing any organic HAP identified in Table 9 of the HON wastewater        
      provisions (subpart G) shall be considered Group 1 and are required to be controlled.                         
    
    1. Storage vessels
        Tables 6 and 7 summarize the proposed standards for existing and 
    new storage vessels, respectively. The proposed standards would require 
    owners and operators to first determine whether or not a storage vessel 
    was required to be controlled. This is done through the application of 
    certain criteria to each storage vessel. For those storage vessels 
    determined to require control, the proposed rule then specifies the 
    level of control required.
    
            Table 6.--Proposed Standards for Existing Storage Vessels       
    ------------------------------------------------------------------------
          Subcategory        Applicability criteriaa     Level of Controlb  
    ------------------------------------------------------------------------
    All ABS SAN, continuous  Vapor pressure 0.75 psia and         <11.1 psia:="" polystyrene,="" batch="" all="" capacity="">40,000 gallonsc.      internal floating    
     noted below).           Vapor pressure 1.9 psia and         2. external floating  
                              capacity 20,000 gallonsc.     3. an external        
                                                       floating roof        
                                                       converted to an      
                                                       internal floating    
                                                       roof; or             
                                                      4. a closed vent      
                                                       system and control   
                                                       device.              
                                                      If vapor pressure 11.1 psia: a  
                                                       closed vent system   
                                                       and control deviced  
    ASA/AMSAN..............  AMST for capacities 10,200 gallons.                        
                             Styrene/acrylonitrile    98 percent reduction. 
                              for capacities 1,000 gallons.                             
                             Acrylonitrile for        98 percent reduction. 
                              capacities 20,000 gallons.                            
                             Any other chemical:....  If vapor pressure is  
                               Vapor pressure <11.1 psia:="" thn-eq="">0.75 psia and    1. fixed roof and     
                              capacity 40,000 gallonsc.      roof; or             
                               Vapor pressure 1.9 psia and      roof; or             
                              capacity 20,000 gallonsc.      floating roof        
                                                       converted to an      
                                                       internal floating    
                                                       roof; or             
                                                      4. a closed vent      
                                                       system and control   
                                                       device.              
                                                      If vapor pressure 11.1 psia: a  
                                                       closed vent system   
                                                       and control device0d 
    Nitrile................  Control all              (same as the HON level
                              acrylonitrile storage    of control).         
                              vessels 3,500 gallons.                             
    Polystyrene, continuous  Vapor pressure 0.28      (same as the HON level
                              psia and capacity 20,000 gallons.                        
                             Vapor pressure 2.08 psia and                              
                              capacity 10,000 but less                            
                              than 20,000 gallons.                          
    ------------------------------------------------------------------------
    aStorage vessels that meet the criteria are defined as Group 1 storage  
      vessels and control of their emissions would be required. Storage     
      vessels that do not meet the criteria are defined as Group 2 storage  
      vessels and control of their emissions is not required.               
    bRequired for Group 1 storage vessels only.                             
    cThe applicability criteria for these subcategories are the same as in  
      the HON.                                                              
    dThe level of control is the same as the HON.                           
    KEY: AMST = alpha methyl styrene.                                       
    
    
                                                                            
    [[Page 16101]]                                                          
              Table 7.--Proposed Standards for New Storage Vessels          
    ------------------------------------------------------------------------
          Subcategory        Applicability criteriaa     Level of controlb  
    ------------------------------------------------------------------------
    All ABS (except CM)      Vapor pressure 0.1 psia and          <11.1 psia:="" polystyrene,="" batch="" all="" capacity="">40,000 gallonsc.      internal floating    
     noted below).           Vapor pressure 1.9 psia and         2. external floating  
                              capacity 10,000 gallonsc.     3. an external        
                                                       floating roof        
                                                       converted to an      
                                                       internal floating    
                                                       roof; or             
                                                      4. a closed vent      
                                                       system and control   
                                                       device.              
                                                      If vapor pressure 11.1 psia: a  
                                                       closed vent system   
                                                       and control deviced. 
    ABS, CM................  VP  1.9 psia  (same as the HON level
                              and capacity 10,000 gallons and                         
                              <12,000 gallons.="" styrene="" for="" capacities="">12,000                             
                              gallons.                                      
                             VP  0.0782                          
                              psia and 12,000 gallons.                            
    SAN, continuous........  VP  0.0735    90 percent reduction. 
                              to <0.1 psia="" and="" capacity="">600,000 gallons.                           
                             VP  0.1 to    (same as the HON level
                              <1.45 psia="" and="">40,000 gallons.                            
                             VP  1.45 to   98 percent reduction. 
                              <14.7 psia="" and="" capacity="">8,000 to <40,000 gallons.="" asa/ams................="" amst="" for="" capacities="">10,200 gallons.                        
                             Styrene/acrylonitrile    98 percent reduction. 
                              for capacities 1,000 gallons.                             
                             Acrylonitrile for        98 percent reduction. 
                              capacities 20,000 gallons.                            
                             Any other chemical:....  (same as the HON level
                             Vapor pressure 0.1 psia and                               
                              capacity 40,000 gallonsc.                           
                             Vapor pressure 1.9 psia and                               
                              capacity 10,000 gallonsc.                           
    Nitrile................  Control all              (same as the HON level
                              acrylonitrile storage    of control).         
                              vessels                            
                              3,500 gallons.                                
    Polystyrene, continuous  Vapor pressure  0.78 psia and        of control).         
                              capacity                           
                              29,000 gallons.                               
                             Vapor pressure  0.09 psia and                             
                              capacity                           
                              12,000 gallons but                            
                              less than 29,000                              
                              gallons.                                      
                             Vapor pressure  1.1 psia and                              
                              capacity                           
                              5,170 gallons but less                        
                              than 12,000 gallons.                          
    ------------------------------------------------------------------------
    aStorage vessels that meet the criteria are defined as Group 1 storage  
      vessels and control of their emissions would be required. Storage     
      vessels that do not meet the criteria are defined as Group 2 storage  
      vessels and control of their emissions is not required.               
    bRequired for Group 1 storage vessels only.                             
    cThe applicability criteria for these subcategories are the same as     
      those in the HON.                                                     
    d The level of control is the same as in the HON.                       
    KEY: CM = continuous mass; VP = vapor pressure.                         
    
        a. Applicability criteria. For most existing and new storage 
    vessels, the proposed criteria for determining which storage vessels 
    are to be controlled are identical to the criteria from the HON storage 
    vessel provisions and are based on storage vessel capacity and vapor 
    pressure of the stored material. Typically, the vapor pressures and 
    storage vessel capacity criteria that determine Group 1 or Group 2 
    status are different for existing and new sources. As in the HON, if a 
    storage vessel meets the applicability criteria and is required to be 
    controlled under today's proposed rule, it is referred to as a Group 1 
    storage vessel. If a storage vessel is not required to apply controls, 
    it is referred to as a Group 2 storage vessel.
        For new ABS, continuous mass facilities, the applicability criteria 
    also rely on vapor pressure and storage vessel capacity, but use 
    different levels of each for defining a Group 1 storage vessel (see 
    Table 7).
        For new continuous SAN facilities, the proposed standards for 
    storage vessels rely on five different combinations of vapor pressure 
    and storage vessel capacity to determine Group 1 storage vessels. These 
    combinations of vapor pressure and storage vessel capacity are shown in 
    Table 7.
        For existing continuous polystyrene facilities, the proposed 
    standards for storage vessels rely on two combinations of vapor 
    pressure and storage vessel capacity to determine Group 1 storage 
    vessels. These combinations of vapor pressure and storage vessel 
    capacity are shown in Table 6.
        For new continuous polystyrene facilities, the proposed standards 
    for storage vessels rely on three combinations of vapor pressure and 
    storage vessel capacity to determine Group 1 storage vessels. These 
    combinations of vapor pressure and storage vessel capacity are shown in 
    Table 7.
        For existing and new ASA/AMSAN facilities, the proposed standards 
    for storage vessels have two parts to the applicability criteria. The 
    first part identifies specific chemical and storage vessel capacity 
    combinations. The second part applies vapor pressure and storage vessel 
    capacity applicability criteria for storage vessels containing 
    chemicals not specifically identified.
        For existing and new nitrile facilities, all acrylonitrile storage 
    vessels with capacities greater than or equal to 3,500 gallons are 
    required to be controlled. For all other chemicals, the applicability 
    criteria are the same as in the HON.
        b. Level of control. Except for the subcategories discussed below, 
    the level of control required for storage vessels determined to be 
    Group 1 storage vessels under the appropriate applicability criteria 
    being proposed in today's rule is either technical modification to the 
    tank (e.g., the installation of an internal floating roof) 
    [[Page 16102]] or the use of a closed vent system and control device 
    that is generally required to achieve at least 95 percent emission 
    reduction. (This is the same level of control as required under the 
    HON.) For all subcategories, storage vessels determined to be Group 2 
    are not required to be controlled.
        For new continuous SAN facilities, different levels of control for 
    two of the five applicability criteria combinations are being proposed. 
    For the applicability combination of vapor pressure greater than 0.0735 
    but less than 0.1 pounds per square inch absolute (psia) and storage 
    vessel capacity greater than or equal to 600,000 gallons, the proposed 
    standard would require an emission reduction of 90 percent or more. For 
    the applicability combination of vapor pressure greater than or equal 
    to 1.45 but less than 14.7 psia and storage vessel capacity greater 
    than or equal to 8,000 gallons but less than 40,000 gallons, the 
    proposed standard would require an emission reduction of 98 percent or 
    more.
        For ASA/AMSAN facilities, different levels of control for storage 
    vessels determined to be Group 1 based on the specific chemical/storage 
    vessel capacity combination criteria are being proposed. For these 
    storage vessels, the level of control being proposed is 98 percent.
    2. Process Vents
        As for storage vessels, the proposed standards for process vents 
    require owners and operators to first determine whether or not a 
    process vent (or set of process vents) requires control and, if so, 
    then specifies the level of control required.
        a. Applicability criteria. Tables 8 and 9 summarize the proposed 
    applicability criteria for continuous and batch process vents at 
    existing and new facilities, respectively. As for storage vessels, 
    process vents that meet the applicability criteria are referred to as 
    Group 1 process vents and those that do not are referred to as Group 2 
    process vents. With the exceptions discussed below, the proposed rule 
    would require control of only those process vents determined to be 
    Group 1 process vents under the appropriate criteria.
    
    
                                    Table 8.--Summary of Proposed Process Vent Applicability Criteria for Existing Facilities                               
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                 Process vents                                     Subcategory                                        Applicability criteria                
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Continuous Unit Operations............  All (except as specified below).........................  TREa  1.                                   
                                            MBS.....................................................  TREa  3.7.                                 
                                            ASA/AMSAN...............................................  None. All vents are required to be controlled.        
                                            Polystyrene, continuous: material recovery..............  None. Must meet standard.                             
                                            PET/DMT, continuous: material recovery..................  0.12 kg TOC per Mg productb.                          
                                            PET/DMT, continuous: polymerization reaction............  None. Must meet standard.                             
                                            PET/TPA, continuous: raw material preparation and         None. Must meet standard.                             
                                             polymerization reaction.                                                                                       
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    
    
    Batch Unit Operations.................  All.....................................................       Stream volatility          Flowrate regression   
                                                                                                                                           equationc        
                                                                                                     -------------------------------------------------------
                                                                                                      Low.......................  (0.00437) AE--51.6d.      
                                                                                                      Moderate..................  (0.00187) AE--14.0d.      
                                                                                                      High......................  (0.00081) AE--8.5d.       
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    aThe total resource effectiveness (TRE) value is a reflection of the cost effectiveness of controlling an individual process vent. There are different  
      TRE coefficients for existing and new process vents.                                                                                                  
    bIf emissions from the described process vents are greater than the applicability criteria, control is required.                                        
    cIf actual stream flowrate (standard cubic meters per minute) is less than the flowrate calculated by the regression equation, the process vent is      
      required to be controlled.                                                                                                                            
    dAE = annual emissions in kilograms per year.                                                                                                           
                                                                                                                                                            
    
    
                                      Table 9.--Summary of Proposed Process Vent Applicability Criteria for New Facilities                                  
    --------------------------------------------------------------------------------------------------------------------------------------------------------
                 Process vents                                     Subcategory                                        Applicability criteria                
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    Continuous Unit Operations............  All (except as specified below).........................  TREa  1                                    
                                            SAN, batch..............................................  None. Must meet standard.                             
                                            ASA/AMSAN...............................................  None. All vents are required to be controlled.        
                                            Polystyrene, continuous: material recovery..............  None. Must meet standard.                             
                                            PET/DMT, continuous: material recovery and                None. Must meet standard.                             
                                             polymerization reaction.                                                                                       
                                            PET/TPA, continuous: Raw material preparation and         None. Must meet standard.                             
                                             polymerization reaction.                                                                                       
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    
    
    Batch Unit Operations.................  All (except as specified below).........................       Stream volatility      Flowrate regression       
                                                                                                                                   equationb                
                                                                                                     -------------------------------------------------------
                                                                                                      Low.......................  (0.00437) AE--51.6c.      
                                                                                                      Moderate..................  (0.00187) AE--14.0c.      
                                                                                                      High......................  (0.00081) AE--8.5c.       
                                            SAN, batch..............................................  None......................  Must meet standard.       
    --------------------------------------------------------------------------------------------------------------------------------------------------------
    aThe total resource effectiveness (TRE) value is a reflection of the cost effectiveness of controlling an individual process vent. There are different  
      TRE coefficients for existing and new process vents.                                                                                                  
    bIf actual stream flowrate (standard cubic meters per minute) is less than the flowrate calculated by the regression equation, the process vent is      
      required to be controlled.                                                                                                                            
    cAE=annual emissions in kilograms per year.                                                                                                             
    
    
    [[Page 16103]]
    
        Except for certain PET and polystyrene continuous process vents, 
    Group 1 continuous process vents are determined by comparing each 
    process vent's total resource effectiveness (TRE) value to a TRE value 
    of unity. The TRE is a reflection of the costs and other associated 
    impacts of controlling an individual process vent. It is determined 
    based on process vent stream characteristics such as emissions (mass 
    per hour), heat content, and flowrate. The procedure in the proposed 
    rule for determining Group 1 process vents is the same procedure as in 
    the HON.
        Except for continuous process vents at existing MBS facilities, 
    continuous process vents with a TRE value of 1 or less would be 
    classified as a Group 1 process vent. For continuous process vents at 
    existing MBS facilities, a TRE value of 3.7 or less defines a Group 1 
    process vent.
        As seen in Tables 8 and 9, there are no applicability criteria 
    specified for several subcategories. At these facilities, a Group 1/
    Group 2 determination does not need to be made and all process vents 
    are required to be controlled.
        For process vents associated with the material recovery section 
    from existing PET facilities using a continuous DMT process, Group 1 
    process vents are determined by comparing uncontrolled emission rates 
    with threshold emission rates. Process vents associated with the 
    material recovery section at an existing PET facility using a 
    continuous DMT process would be considered Group 1 process vents if the 
    uncontrolled emission rate is greater than 0.12 kg TOC per Mg of 
    product (see Table 8). For other process vents at existing and new 
    polystyrene and PET facilities (see Tables 8 and 9), there are no 
    applicability criteria. These process vents must meet the proposed 
    standards.
        For process vents from batch unit operations, the process vent is 
    first characterized as to its volatility--low, medium, or high. Next, 
    the estimate of the stream's annual emissions is entered in the 
    appropriate flowrate regression equation. If the actual flowrate is 
    less than the calculated flowrate, then the batch process vent is a 
    Group 1 vent under these standards, and control is required. As seen in 
    Tables 8 and 9, the batch process vent applicability criteria are the 
    same for existing and new sources, except for new SAN batch facilities.
        For new SAN batch facilities, there are no applicability criteria 
    for individual process vent streams; all process vents are subject to 
    control in that the proposed standard for these facilities requires an 
    overall emission reduction of 84 percent from all process vents.
        A batch process vent that is combined with a continuous process 
    vent prior to a control or recovery device is not required to comply 
    with the batch process vent provisions if there are no emissions to the 
    atmosphere up until the point the batch vent stream is combined with 
    the continuous vent stream. The combined vent would be required to 
    comply with the continuous process vent provisions. The presence of a 
    batch process vent in a continuous process vent stream would 
    necessitate that all applicability tests and performance tests be 
    conducted while the batch process vent is emitting (i.e. at maximum 
    operating conditions).
        b. Level of control. For continuous process vents, most of the 
    facilities are required to control Group 1 process vents by at least 98 
    percent. If a flare is used, it must meet the design and operating 
    requirements of Sec. 63.11(b) of subpart A of 40 CFR part 63. 
    Exceptions to this are described in the paragraphs below.
        For continuous process emissions from the material recovery section 
    of polystyrene plants using a continuous process, the proposed 
    standards would (1) limit the emissions of TOC (minus methane and 
    ethane) to 0.0036 kg TOC/Mg per megagram (Mg) of product (0.0036 pounds 
    (lbs) TOC/1,000 lbs of product) from each material recovery section, or 
    (2) limit the outlet gas temperature from each final condenser in each 
    material recovery section to -25 deg.C (-13 deg.F), or (3) reduce 
    emissions from each material recovery section by 98 weight percent or 
    to 20 ppmv. These are the same requirements as in subpart DDD.
        For PET facilities using a continuous TPA process, the proposed 
    standards would limit continuous process vent emissions from (1) the 
    raw material preparation section to 0.04 kg TOC/Mg of product and (2) 
    the polymerization reaction section to 0.02 kg TOC/Mg of product. 
    Similarly, for PET facilities using a continuous DMT process, the 
    proposed standards would limit (1) continuous process vent emissions 
    from the material recovery section to 0.018 kg TOC/Mg of product or the 
    temperature to 37 deg.F from each final condenser in the material 
    recovery section and (2) continuous process vent emissions from the 
    polymerization reaction section to 0.02 kg TOC/Mg of product. These are 
    also the same requirements that are in subpart DDD, with the exception 
    that cooling tower emissions would not be considered as part of the 
    polymerization reaction section.
        For Group 1 continuous process emissions from other process 
    sections at polystyrene and PET facilities, the proposed standards 
    would require emission reduction by at least 98 percent or control by a 
    flare that meets the requirements of Sec. 63.11(b) of subpart A of 40 
    CFR part 63.
        For batch process vents, the proposed standards would require Group 
    1 process vents from batch unit operations to be controlled by at least 
    90 percent.
        There are three subcategories where the proposed standards are 
    based on the MACT floor. These subcategories are existing MBS 
    facilities, existing and new ASA/AMSAN facilities, and new SAN, batch 
    facilities.
        For existing MBS facilities, the proposed standards require 
    continuous process vents at facilities to either (1) meet an emission 
    level of 0.000590 kg of emissions per megagram of product for all 
    continuous process vents or (2) control all continuous process vents 
    with a total resource effectiveness (TRE) of 3.7 or less by at least 98 
    percent. The TRE is to be calculated for each process vent using the 
    same TRE coefficients as for other existing sources. The development of 
    the MACT floor and applicability criteria for MBS existing sources is 
    documented in Docket No. A-92-45, Category II-B and in the SID.
        For both existing and new ASA/AMSAN facilities, the proposed rule 
    requires all process vents (continuous and batch) at both existing and 
    new facilities to control emissions by at least 98 percent.
        For new SAN, batch facilities, the proposed rule requires an 
    overall emission reduction of 84 percent of process vent emissions.
    3. Equipment Leaks
        For all the subcategories, both existing and new facilities would 
    be required to implement a leak detection and repair (LDAR) program. 
    With a few exceptions, the LDAR program being proposed is the same as 
    that specified in the National Emission Standards for Organic HAP for 
    Equipment Leaks (40 CFR part 63, subpart H) and the National Emission 
    Standards for Organic HAP for Certain Processes Subject to the 
    Negotiated Regulation for Equipment Leaks (40 CFR part 63, subpart I). 
    Under the proposed standards, work practice requirements to reduce 
    emissions from equipment that are in volatile HAP service for 300 or 
    more hours per year (hr/yr) are specified. The proposed standards 
    define ``in volatile HAP service'' as being in contact with or 
    containing process fluid that contains a total of 5 percent or more 
    total HAP. Equipment [[Page 16104]] subject to the proposed standards 
    are: Valves, pumps, compressors, connectors, pressure relief devices, 
    open-ended valves or lines, sampling connection systems, 
    instrumentation systems, agitators, surge control vessels, bottoms 
    receivers, and closed-vent systems and control devices.
        Affected sources currently complying with the NESHAP for Certain 
    Processes Subject to the Negotiated Regulation for Equipment Leaks (40 
    CFR part 63, subpart I) are required to continue to comply with subpart 
    I until the compliance date of today's proposed rule. Further, affected 
    sources complying with subpart I through a quality improvement program 
    shall be allowed to continue these programs without interruption as 
    part of complying with today's proposed rule. In other words, becoming 
    subject to today's proposed rule does not restart or reset the 
    ``compliance clock'' as it relates to reduced burden earned through a 
    quality improvement program.
    4. Wastewater
        Except for ASA/AMSAN facilities, the proposed standards require 
    owners and operators to determine for each wastewater stream at its 
    point of generation whether it is a Group 1 or Group 2 wastewater 
    stream. As for process vents, Group 1 wastewater streams are required 
    to be controlled, while Group 2 wastewater streams are not required to 
    be controlled. The wastewater stream characteristics used to make the 
    Group 1/Group 2 applicability determination are flowrate and organic 
    HAP concentration. The proposed criteria for determining Group 1 
    wastewater streams are presented in Table 10 and are the same criteria 
    used in the HON. The level of control required for Group 1 wastewater 
    streams is dependent upon the organic HAP constituents in the 
    wastewater stream. The levels of control proposed for these standards 
    are the same as those for the HON. The proposed rule would not control 
    wastewater emissions from any existing or new ASA/AMSAN facilities.
    
             Table 10.--Proposed Wastewater Applicability Criteriaab        
    ------------------------------------------------------------------------
          Existing source criteria               New source criteria        
    ------------------------------------------------------------------------
    VOHAPc concentration      Same as existing criteria          
     10,000 ppmw.                                and                        
            or                           for a subset of organic            
    VOHAPc concentration       HAP...VOHAPc concentration 10 ppmw and flowrate  10 liters per minute.            eq>0.02 liters per minute.        
    ------------------------------------------------------------------------
    a Wastewater streams meeting these criteria are considered Group 1      
      wastewater streams and control is required.                           
    b There are exemptions for minimal flowrates and concentrations.        
    c VOHAP=volatile organic HAP.                                           
    
        The proposed standards require owners and operators to comply with 
    the maintenance wastewater requirements in Sec. 63.105 of subpart F of 
    this part. These provisions require owners and operators to include a 
    description of procedures for managing wastewaters generated during 
    maintenance in their start-up, shutdown and malfunction plan. The 
    start-up, shutdown, and malfunction plan is required under subpart A of 
    40 CFR part 63.
    5. Heat Exchange Systems and Process Contact Cooling Towers
        Today's proposed standards would require a monitoring program to 
    detect leakage of organic HAP from the process into the cooling water. 
    The proposed monitoring program is the same as that in the HON (subpart 
    F of this part). The proposed rule would also prohibit the use of 
    cooling tower water in contact condensers in the vacuum systems at PET 
    facilities. Further, if a wastewater stream is generated from the 
    vacuum system and it contains any of the organic HAP identified in 
    Table 9 of the HON wastewater provisions (subpart G), the proposed rule 
    would require it to be controlled regardless of its organic HAP 
    concentration or flowrate. The level of control required is the same as 
    that for a Group 1 wastewater stream.
        These provisions for control of emissions from process contact 
    cooling towers are independent of the provisions of the NESHAP for 
    Industrial Cooling Towers (40 CFR part 63, subpart Q) which may also be 
    applicable to these cooling towers.
        The EPA solicits comments on the emission reduction potential, 
    costs, and technical feasibility of all control options for process 
    contact cooling towers at PET facilities. Any comments on alternate 
    control options should address the emissions from the cooling tower, 
    the emissions from any wastewater discharged from the equipment 
    required by the control option, and any ``reactor process'' or 
    ``distillation column'' vent emissions associated with the option.
    6. Emissions Averaging
        Today's proposed standards would apply essentially the same 
    emissions averaging scheme as has been adopted by the HON, although the 
    emissions averaging provisions of the proposed rule are entirely 
    contained in the proposed rule instead of referring to the subpart G 
    emissions averaging provisions. Under the proposed rule, emissions 
    averaging would be allowed among five collocated existing emission 
    points belonging to the same subcategory. This number may be increased 
    by three additional points if pollution prevention measures are to be 
    used to control emission points to be included in the average. However, 
    emissions from batch process vents and equipment leaks would not be 
    allowed to be averaged. The owner or operator must demonstrate that the 
    averaging scheme will not result in greater hazard or risk relative to 
    strict compliance with the standards in the absence of averaging.
        The EPA specifically requests comments on the selection of the 
    limit of (5, or 8 if pollution prevention measures are used) emission 
    points to be allowed per subcategory for purposes of averaging in this 
    proposed rule. Will this limit preclude known opportunities within real 
    facilities to generate cost-effective credits within a category or 
    subcategory? Any comments on this need to address specifics on the 
    emission and cost quantities computed, with detailed calculations and 
    references to show how these quantities were determined.
        The EPA is including emissions from process contact cooling towers 
    and vacuum system wastewater at existing PET facilities in the 
    emissions averaging procedures for the proposed rule. As noted earlier, 
    the proposed standards would (1) prohibit existing PET facilities from 
    using cooling tower water in the contact condensers associated with 
    vacuum systems, and (2) would require the control of any wastewater 
    stream generated by the vacuum system containing organic HAP listed on 
    Table 9 of the wastewater provisions in [[Page 16105]] subpart G of 
    this part to the level required for a Group 1 process wastewater 
    stream. Control is required regardless of the organic HAP concentration 
    and flowrate of the stream.
        The proposed prohibition for cooling tower water would eliminate 
    organic HAP emissions from the process contact cooling towers since the 
    cooling tower water would not come in contact with the organic HAP 
    generated by the process. If an owner or operator elected to comply 
    with the proposed emissions averaging procedures, the owner or operator 
    could elect not to eliminate process contact cooling tower water from 
    the vacuum system. This would create a debit; that is, organic HAP 
    emissions would now occur from the cooling tower, whereas, under the 
    proposed rule, no organic HAP emissions would occur. Thus, the proposed 
    emissions averaging procedures only include process contact cooling 
    towers in the equation for the calculation of debits. On the other 
    hand, since the proposed standard would eliminate organic HAP emissions 
    from the cooling tower, there is no opportunity for an owner or 
    operator to control cooling tower emissions to a level more stringent 
    than the proposed rule. Thus, the proposed emissions averaging 
    procedures for calculating credits do not include process contact 
    cooling towers. The EPA is specifically requesting information on 
    methodologies which could be used to estimate emissions from process 
    contact cooling towers.
        The EPA requests comments on all aspects of the implementation of 
    emissions averaging and on ways that the emissions averaging provisions 
    can be made more flexible without reducing the emission reduction. A 
    discussion of the rationale for the proposed emissions averaging 
    provisions is contained in Chapter 4 of the Basis and Purpose Document.
    
    G. Compliance and Performance Test Provisions and Monitoring 
    Requirements
    
        Compliance and performance test provisions and monitoring 
    requirements contained in today's proposed rule are very similar to 
    those found in the HON (subpart G of part 63). Each type of emission 
    point is discussed briefly in the paragraphs below. Also, significant 
    differences from the parameter monitoring requirements found in subpart 
    G are discussed.
    1. Continuous Process Vents
        The proposed regulations for process vents from continuous unit 
    operations (continuous process vents) require the owner or operator to 
    either calculate a TRE index value to determine whether each continuous 
    process vent is a Group 1 or Group 2 vent, or the owner or operator can 
    elect to comply with the control requirements without calculating the 
    TRE index. The TRE index value is determined after the last recovery 
    device in the process or prior to venting to the atmosphere. The TRE 
    calculation involves an emissions test or engineering assessment and 
    use of the TRE equations in the proposed rule.
        Performance test provisions are included for Group 1 continuous 
    process vents to verify that the control device achieves the required 
    performance. Monitoring provisions necessary to demonstrate compliance 
    are also included in the proposed rule.
        Compliance provisions for continuous process vents at polystyrene 
    and PET facilities are included in the proposed rule. For owners or 
    operators electing to comply with a kg TOC/Mg of product limit, 
    procedures to demonstrate compliance are provided. Also, procedures are 
    included in the proposed rule to demonstrate compliance with the 
    requirement to reduce overall process vent emissions (continuous and 
    batch) by 84 percent for new SAN, batch facilities.
    2. Batch Process Vents
        Similar to the provisions for continuous process vents, there is a 
    procedure for determining which batch process vents are Group 1 and 
    which are Group 2. This procedure is based on annual emissions and 
    annual average flowrate of the batch process vent. Equations for 
    estimating annual emissions and annual average flowrates are provided 
    in the proposed rule.
        Performance test provisions are included for Group 1 batch process 
    vents to verify that the control or recovery device achieves the 
    required performance. Monitoring provisions necessary to demonstrate 
    compliance are also included in the proposed rule.
        For Group 2 batch process vents, the proposed rule requires owners 
    and operators to establish a batch cycle limitation. The batch cycle 
    limitation limits the number of batch cycles that can be accomplished 
    for a given batch unit operation per year (i.e., for the operations 
    that feed a single batch process vent). This enforceable limitation 
    ensures that a Group 2 batch process vent does not become a Group 1 
    batch process vent as a result of running more batches than anticipated 
    when the group determination was made. The determination of the batch 
    cycle limitation is not tied to any previous production amounts. An 
    affected source may set the batch cycle limitation at any level it 
    desires as long as the batch process vent remains a Group 2 batch 
    process vent. Alternatively the proposed rule would allow owners and 
    operators to declare any Group 2 batch process vent to be a Group 1 
    batch process vent. In such cases, control of the batch process vent is 
    required.
        As described earlier, procedures are included in the proposed rule 
    to demonstrate compliance with the requirement to reduce overall 
    process vent emissions (continuous and batch) by 84 percent for new 
    SAN, batch facilities.
    3. Storage Vessels
        Monitoring and compliance provisions include periodic visual 
    inspections of vessels, roof seals, and fittings, as well as internal 
    inspections. If a control device is used, the owner or operator must 
    identify the appropriate monitoring procedures to be followed in order 
    to demonstrate compliance. Monitoring parameters and procedures for 
    many of the control devices likely to be used are already identified in 
    other parts of the proposed rule. Reports and records of inspections, 
    repairs, and other information necessary to determine compliance are 
    also required by the proposed rule.
    4. Wastewater
        For demonstrating compliance with the various requirements, the 
    proposed rule allows the owners or operators to either conduct 
    performance tests or to document compliance using engineering 
    calculations. Appropriate compliance and monitoring provisions are 
    included in the regulation.
    5. Equipment Leaks
        The proposed rule retains the use of Method 21 to detect leaks. 
    Method 21 requires a portable organic vapor analyzer to monitor for 
    leaks from equipment in use. A ``leak'' is a concentration specified in 
    the regulation for the type of equipment being monitored and is based 
    on the instrument response to methane (the calibration gas) in air. The 
    observed screening value may require adjustment for response factor 
    relative to methane if the weighted response factor of the stream 
    exceeds a specified multiplier. The proposed rule requires the use of 
    Method 18 to determine the organic content of a process stream. Test 
    procedures using either a gas or a liquid for pressure testing the 
    batch system are specified to test for leaks.
    [[Page 16106]]
    
    6. Heat Exchange Systems
        Monitoring of cooling water is required to detect leaks in non-
    contact heat exchange systems. If a leak is detected, the heat exchange 
    system must be repaired.
    7. Process Contact Cooling Towers
        Owners and operators of affected sources subject to these 
    provisions are required to indicate in their Implementation Plan and 
    Notification of Compliance Status reports that cooling tower water will 
    not be used in contact condensers associated with vacuum systems.
    8. Continuous Parameter Monitoring
        When compared to the HON, the proposed rule contains two 
    significant differences related to continuous parameter monitoring. 
    First, the proposed rule does not allow any excused excursions. The 
    proposed rule, as did subpart G, requires at least 75 percent of 
    monitoring data to constitute a valid days worth of data for continuous 
    and batch process vents. Failure to have a valid day's worth of 
    monitoring data is considered an excursion. The criteria for 
    determining a valid day's or hour's worth of data are provided in the 
    proposed rule. Second, the procedure for determining the parameter 
    monitoring level for continuous and batch process vents is both more 
    specific and restrictive than the procedure in subpart G because it 
    relies exclusively on performance tests.
    
    H. Recordkeeping and Reporting Requirements
    
        The general recordkeeping and reporting requirements of this 
    subpart are very similar to those found in subpart G of 40 CFR part 63. 
    The proposed rule also relies on the provisions of subpart A of 40 CFR 
    part 63. A table included in the proposed rule designates which 
    sections of subpart A apply to the proposed rule. Specific 
    recordkeeping and reporting requirements for each type of emission 
    point are also included in the proposed rule.
        The proposed rule requires sources to keep records and submit 
    reports of information necessary to document compliance. Records must 
    be kept for 5 years. The following six types of reports must be 
    submitted to the Administrator as appropriate: (1) Initial 
    Notification, (2) Implementation Plan (if an operating permit 
    application has not been submitted or, for new sources, an application 
    for approval of construction or reconstruction), (3) Emissions 
    Averaging Plan, (4) Notification of Compliance Status, (5) Periodic 
    Reports, and (6) other reports. The requirements for each of the six 
    types of reports are summarized below. In addition, sources complying 
    with the equipment leak requirements contained in subpart H must follow 
    the recordkeeping and reporting requirements of subpart H.
    1. Initial Notification
        The Initial Notification is due 120 days after the date of 
    promulgation for existing sources. For new sources, it is due 180 days 
    before commencement of construction or reconstruction, or 45 days after 
    promulgation, whichever is later. The notification must list the 
    thermoplastic processes that are subject to the proposed rule, and 
    which provisions may apply (e.g., continuous process vents, batch 
    process vents, storage vessels, wastewater, and/or equipment leak 
    provisions). A detailed identification of emission points is not 
    necessary for the Initial Notification. The notification, however, must 
    include a statement of whether the affected source expects that it can 
    achieve compliance by the specified compliance date.
    2. Implementation Plan
        The Implementation Plan details how the affected source plans to 
    comply. An Implementation Plan would be required only for affected 
    sources that have not yet submitted an operating permit application or 
    for new sources that have not yet submitted the same information as 
    part of their application for approval of construction or 
    reconstruction.
        The Implementation Plan would be due 12 months prior to the date of 
    compliance. For new sources, Implementation Plans would be submitted 
    with the Notification of Compliance Status.
        The information in the Implementation Plan should be incorporated 
    into the affected source's operating permit application. The terms and 
    conditions of the plan, as approved by the permit authority, would then 
    be incorporated into the operating permit.
        The Implementation Plan would include a list of emission points 
    subject to the continuous process vents, batch process vents, storage 
    vessels, wastewater, heat exchange systems, process contact cooling 
    towers, and equipment leak provisions and, as applicable, whether each 
    emission point (e.g., storage vessel or process vent) is Group 1 or 
    Group 2. The control technology or method of compliance planned for 
    each Group 1 emission point must be specified.
        The plan must also certify that appropriate testing, monitoring, 
    reporting, and recordkeeping will be done for each Group 1 emission 
    point. If an affected source requests approval to monitor a unique 
    parameter, a rationale must be included.
    3. Emissions Averaging Plan
        The Emissions Averaging Plan would be due 18 months prior to the 
    date of compliance. New sources are not allowed to comply through the 
    use of emissions averaging.
        For points included in emissions averaging, the Emissions Averaging 
    Plan would include: an identification of all points in the average and 
    whether they are Group 1 or Group 2 points; the specific control 
    technique or pollution prevention measure that will be applied to each 
    point; the control efficiency for each control used in the average; the 
    projected credit or debit generated by each point; and the overall 
    expected credits and debits. The plan must include a demonstration that 
    the emissions averaging scheme will not result in greater hazard or 
    risk than if the emission points would comply with the standards in the 
    absence of averaging. The plan must also certify that the same types of 
    testing, monitoring, reporting, and recordkeeping that are required by 
    the proposed rule for Group 1 points will be done for all points (both 
    Group 1 and Group 2) included in an emissions average. If an affected 
    source requests approval to monitor a unique parameter or use a unique 
    recordkeeping and reporting system, a rationale must be included in the 
    Emissions Averaging Plan.
    4. Notification of Compliance Status
        The Notification of Compliance Status would be required 150 days 
    after the affected source's compliance date. It contains the 
    information for Group 1 emission points and for all emission points in 
    emissions averages, necessary to demonstrate that compliance has been 
    achieved. Such information includes, but is not limited to, the results 
    of any performance tests for continuous and/or batch process vents and 
    wastewater emission points; one complete test report for each test 
    method used for a particular kind of emission point; TRE determinations 
    for continuous process vents; group determinations for batch process 
    vents; design analyses for storage vessels and wastewater emission 
    points; monitored parameter levels for each emission point and 
    supporting data for the designated level; and values of all parameters 
    used to calculate emission credits and debits for emissions 
    averaging. [[Page 16107]] 
    5. Periodic Reports
        Generally, Periodic Reports would be submitted semiannually. 
    However, there are two exceptions. First, quarterly reports must be 
    submitted for all points included in an emissions average. Second, if 
    monitoring results show that the parameter values for an emission point 
    are above the maximum or below the minimum established levels for more 
    than 1 percent of the operating time in a reporting period, or the 
    monitoring system is out of service for more than 5 percent of the 
    time, the regulatory authority may request that the owner or operator 
    submit quarterly reports for that emission point. After 1 year, 
    semiannual reporting can be resumed, unless the regulatory authority 
    requests continuation of quarterly reports.
        All Periodic Reports would include information required to be 
    reported under the recordkeeping and reporting provisions for each 
    emission point. For emission points involved in emissions averages, the 
    report would include the results of the calculations of credits and 
    debits for each month and for the quarter. For continuously monitored 
    parameters, the data on those periods when the parameters are above the 
    maximum or below the minimum established levels are included in the 
    reports. Periodic Reports would also include results of any performance 
    tests conducted during the reporting period and instances when required 
    inspections revealed problems. Additional information the affected 
    source is required to report under its operating permit or 
    Implementation Plan would also be described in Periodic Reports.
    6. Other Reports
        Other reports required under the proposed rule include: reports of 
    start-up, shutdown, and malfunction; process changes that change the 
    compliance status of process vents; and requests for extensions of 
    repair and notifications of inspections for storage vessels and 
    wastewater.
        In addition, quarterly reporting of the number of batch cycles 
    accomplished for Group 2 batch process vents is required. Every fourth 
    quarterly report would be required to include the total batch cycles 
    accomplished during the previous 12 months, and a statement whether the 
    owner or operator is in compliance with the batch cycle limitation.
    
    V. Solicitation of Comments
    
        The Administrator welcomes comments from interested persons on any 
    aspect of the proposed rule, and on any statement in the preamble or 
    the referenced supporting documents. The proposed rule was developed on 
    the basis of information available. The Administrator is specifically 
    requesting factual information that may support either the approach 
    taken in the proposed standards or an alternate approach. To receive 
    proper consideration, documentation or data should be provided.
        Specifically, the EPA is requesting comments and data on several 
    aspects of the proposed rule. First, the EPA solicits comments and data 
    on the technical feasibility and costs for emission control techniques 
    for the vacuum system and associated process contact cooling towers 
    used in PET production as described in Section IV.F.5 of this preamble 
    and in the Basis and Purpose Document, Chapter 6. Second, the EPA 
    solicits comments on several aspects of the emissions averaging 
    provisions as described in Section IV.F.6 of this preamble and in the 
    Basis and Purpose Document, Chapter 4. The emissions averaging 
    provisions in this proposed rule are modeled after those in the HON. 
    The EPA is interested in comments on all aspects, but is especially 
    interested in comments on the limitation of the number of emission 
    points allowed in an average and on ways that the implementation of 
    emissions averaging can be made more flexible without reducing the 
    emission reduction. Third, the EPA solicits comments related to the use 
    of subpart DDD emission limits and the proposed modification to subpart 
    DDD. Fourth, and finally, in some instances, the EPA has required 
    control more stringent than that required by the MACT floor. In these 
    instances, the EPA has judged the impacts to be reasonable. The EPA 
    specifically solicits comments on these decisions.
    
    VI. Summary of Environmental, Energy, Cost, and Economic Impacts
    
        This section presents the air, non-air environmental (water and 
    solid waste), energy, cost, and economic impacts resulting from the 
    control of organic HAP emissions under this rule.
    
    A. Facilities Affected by These NESHAP
    
        The proposed rule would affect ABS, SAN, MABS, MBS, polystyrene, 
    PET, and nitrile facilities that are major sources in themselves, or 
    that are located at a major source. Based on available information, all 
    of the facilities at which these thermoplastics are produced were 
    judged to be major sources for the purpose of developing these 
    standards. (Final determination of major source status occurs as part 
    of the compliance determination process undertaken by each individual 
    source.)
        Impacts are presented relative to a baseline reflecting the level 
    of control in the absence of the rule. The current level of control was 
    well understood because emissions and control data were collected on 
    each facility included in the analysis. The impacts estimates were 
    determined for both existing facilities and new facilities (i.e., those 
    that are expected to begin operation through 1999).
        The expected growth rate in each of the seven source categories was 
    analyzed (see Docket No. A-92-45, Category II-B) and the SID. Based on 
    this analysis, the following average annual growth rates (percent per 
    year) through 1999 were estimated:
         ABS--4 percent.
         SAN--4 percent.
         MABS--3 percent.
         MBS--3 percent.
         Polystyrene--3 percent.
         PET--10 percent for bottle-grade resins and 4 percent for 
    other PET resins.
         Nitrile--3 percent.
        The impacts for existing sources were estimated by bringing each 
    facility's control level up to the proposed standards. For new sources, 
    impacts were based on identifying the number of new facilities required 
    to meet the expected growth within the source category, identifying the 
    types of facilities (e.g., batch versus continuous) that would be 
    built, and then selecting a subset of the existing facilities to 
    represent the expected growth. The impacts on these ``new'' facilities 
    were determined by applying the proposed standards for new sources to 
    the selected subset of facilities assuming the existing level of 
    control. This methodology is discussed in detail in Docket No. A-92-45, 
    Category II-B and the SID.
    
    B. Primary Air Impacts
    
        The proposed standards are estimated to reduce organic HAP 
    emissions from all existing sources by 11,750 Mg/yr from a baseline 
    level of 24,780 Mg/yr. This is a 47 percent reduction. For new 
    facilities, the proposed standards are estimated to reduce organic HAP 
    emissions by 7,395 Mg/yr from a baseline level of 14,920 Mg/yr, for a 
    50 percent reduction. Table 11 summarizes the organic HAP emission 
    reductions for each individual subcategory.
    
                                                                            
    [[Page 16108]]                                                          
                                Table 11.--Organic HAP Emissions and Emission Reductions                            
    ----------------------------------------------------------------------------------------------------------------
                                                   Existing sources                         New sources             
                                       -----------------------------------------------------------------------------
                Subcategory                            Emission                               Emission              
                                         Baseline,    reduction,    Percent     Baseline,    Reduction,    Percent  
                                           Mg/yr        Mg/yr      reduction      Mg/yr        Mg/yr      reduction 
    ----------------------------------------------------------------------------------------------------------------
    ABS, continuous mass..............          240          190          80%           95           87          92%
    ABS, continuous emulsion a........        1,110         >180         >16%          400         >115         >29%
    ABS, batch emulsion...............          500           56          11%           35           15          43%
    ABS, batch suspension.............           15            5          33%           13            5          38%
    ABS, latex........................            3            2          67%           --           --           --
    SAN, continuous...................          110           65          60%           40           25          63%
    SAN, batch........................           35           13          37%           20            6          30%
    ASA/AMSAN.........................          100           94          94%           --           --           --
    MABSa.............................           86          >38         >44%           --           --           --
    MBS...............................          190          130          68%           20           16          80%
    Polystyrene, continuous...........        1,440        1,060          74%          330          240          73%
    Polystyrene, batch................          190          130          68%           --           --           --
    Expandable polystyrene............          450           92          20%           --           --           --
    PET-TPA, continuous...............        6,090        2,400          40%        6,090        2,200          36%
    PET-TPA, batcha...................        1,310           >6          >1%        1,310           >6          >1%
    PET-DMT, continuous...............        4,480        2,330          52%        3,190        1,810          57%
    PET-DMT, batch....................        8,400        4,950          59%        3,380        2,870          85%
    Nitrile...........................           30           10          33%           --           --           --
                                       -----------------------------------------------------------------------------
          Totalsb.....................       24,780       11,750          47%       14,920        7,395         50% 
    ----------------------------------------------------------------------------------------------------------------
    --No new growth projected, therefore no impacts expected.                                                       
    a A portion of the emission reductions for this subcategory are confidential business information.              
    b Total values are affected by the subcategories for which some data are confidential business information.     
    
    C. Non-Air Impacts
    
        The proposed standards are not expected to generate any adverse 
    water impacts. Depending on the methods selected to comply with the 
    proposed prohibition of cooling tower water in contact condensers, the 
    amount of wastewater generated at PET facilities could decrease.
        The proposed standards are not expected to increase the generation 
    of solid waste at any Group IV thermoplastic facility.
    
    D. Energy Impacts
    
        Energy impacts include increased energy use (fuel) for the 
    operation of control equipment, energy credits attributable to the 
    prevention of organic HAP emissions from equipment leaks, and emissions 
    of particulates, sulfur dioxides (SOx), and nitrogen oxide (NOx) 
    (secondary air impacts) associated with increased energy use. Under 
    today's proposed rule, energy use is expected to increase by 
    approximately 30,000 barrels of oil per year for existing sources and 
    44,000 for new sources. The emissions of secondary air pollutants 
    associated with this energy increase are 70 Mg/yr for existing sources 
    and 80 Mg/yr for new sources. At the same time, energy credits 
    attributable to the prevention of organic HAP emissions from equipment 
    leaks are approximately 17,000 barrels of oil per year for existing 
    sources and 8,000 for new sources. This results in a net increase of 
    approximately 13,000 barrels of oil per year for existing sources and 
    36,000 for new sources.
        These figures are related to the control of process vents, 
    wastewater operations, and equipment leaks. Energy impacts related to 
    storage vessels were not estimated since many storage vessels would be 
    controlled through the use of internal floating roofs which do not have 
    any associated energy impacts. Further, the estimates above do not 
    include the projected energy savings associated with control of 
    emissions from process contact cooling towers and vacuum system 
    wastewater associated with the manufacture of PET. The majority of 
    existing vacuum systems are operated with steam jets, which are very 
    energy intensive. The precise affect of the proposed rule on the use of 
    steam jets cannot be predicted with accuracy. However, it is 
    anticipated by the EPA that compliance with the proposed rule will, in 
    almost all cases, decrease the energy demand of the vacuum systems.
        Given the relatively small energy impacts projected for the control 
    of process vents, wastewater operations, and equipment leaks and the 
    projected energy savings associated with control of vacuum system air 
    emissions, the EPA has judged the energy impacts associated with 
    today's proposed rule to be acceptable.
    
    E. Cost Impacts
    
        Cost impacts include the capital costs of new control equipment, 
    the cost of energy (supplemental fuel, steam, and electricity) required 
    to operate control equipment, operation and maintenance costs, and the 
    cost savings generated by reducing the loss of valuable product in the 
    form of emissions. Also, cost impacts include the costs of monitoring, 
    recordkeeping, and reporting associated with the proposed standards. 
    Average cost effectiveness ($/Mg of pollutant removed) is also 
    presented as part of cost impacts and is determined by dividing the 
    annual cost by the annual emission reduction. Table 12 presents the 
    estimated capital and annual costs and average cost effectiveness by 
    subcategory.
    
                                                                                                                    
    [[Page 16109]]                                                                                                  
                                           Table 12.--Summary of Cost Impacts                                       
    ----------------------------------------------------------------------------------------------------------------
                                                Existing sources                           New sources              
                                   ---------------------------------------------------------------------------------
                                                    Total                                    Total                  
              Subcategory              Total        annual    Average cost-     Total        annual    Average cost-
                                      capital       costs,    effectiveness    capital       costs,    Effectiveness
                                    cost, $1000    $1000/yr       ($/Mg)     cost, $1000    $1000/yr       ($/Mg)   
    ----------------------------------------------------------------------------------------------------------------
    ABS, continuous mass..........          210          100           550           150           38           430 
    ABS, continuous emulsiona.....       >3,540       >1,300        <7,160>3,490       >1,730       <14,970 abs,="" batch="" emulsion...........="" 430="" 310="" 5,550="" 18="" 14="" 960="" abs,="" batch="" suspension.........="" 28="" 19="" 3,570="" 28="" 19="" 3,760="" abs,="" latex....................="" 0.5="" -0.5="" -240="" --="" --="" --="" san,="" continuous...............="" 450="" 160="" 2,520="" 180="" 38="" 1,490="" san,="" batch....................="" 80="" 33="" 2,520="" 1="" -1.3="" -210="" asa/amsan.....................="" 550="" 200="" 2,150="" --="" --="" --="">a.........................           90          >-2          >-50            --           --            -- 
    MBS...........................          550          360         2,720           440          234        14,200 
    Polystyrene, continuous.......          770          280           260           200           90           350 
    Polystyrene, batch............          300          160         1,270            --           --            -- 
    Expandable polystyrene........          110           50           540            --           --            -- 
    PET-TPA, continuous...........       40,790        2,970         1,230         2,160       -3,926        -1,770 
    PET-TPA, batcha...............          >30          >18        <3,180>30          >18        <3,180 pet-dmt,="" continuous...........="" 28,250="" 3,010="" 1,300="" 2,200="" -970="" -540="" pet-dmt,="" batch................="" 22,080="" 3,360="" 680="" 1,440="" -38="" -13="" nitrile.......................="" 9="" 7="" 660="" --="" --="" --="" ---------------------------------------------------------------------------------="">b.................       98,270       12,330         1,050        10,340       -2,750         -370  
    ----------------------------------------------------------------------------------------------------------------
    --No new growth projected, therefore no impacts expected.                                                       
    aA portion of the costs and/or emission reductions for this subcategory are confidential business information.  
    bTotal values are affected by the subcategories for which some data are confidential business information.      
    
        Under the proposed rule, it is estimated that total capital costs 
    for existing sources would be $98 million (1989 dollars), and total 
    annual costs would by $12.3 million (1989 dollars) per year. It is 
    expected that the actual compliance cost impacts of the proposed rule 
    would be less than presented because of the potential to use common 
    control devices, upgrade existing control devices, use other less 
    expensive control technologies, implement pollution prevention 
    technologies, or use emissions averaging. Since the effect of such 
    practices is highly site-specific and data were unavailable to estimate 
    how often the lower cost compliance practices could be utilized, it is 
    not possible to quantify the amount by which actual compliance costs 
    would be reduced.
    
    F. Economic Impacts
    
        The economic impact analysis for the selected regulatory 
    alternatives shows that the estimated price increases for the affected 
    chemicals range from 0.1 percent for nitrile to 2.8 percent for SAN. 
    Estimated decreases in output range from 0.1 percent for polystyrene to 
    4.6 percent for SAN. Net annual exports (exports minus imports) are 
    predicted to decrease by an average of 2.5 percent.
        As many as five PET facilities and one ABS facility are at risk of 
    discontinuing PET and ABS production, respectively, due to the burden 
    of compliance with the standard. This does not mean that the facilities 
    affected face the risk of closure. The facilities affected will 
    continue to produce other chemicals whose processes are not affected by 
    this standard.
        Three assumptions in the analysis likely lead to an overestimate of 
    the number of facilities at risk of discontinuing production of 
    affected chemicals. First, the economic analysis model assumes that all 
    PET and ABS facilities compete in a national market, though in reality 
    some facilities may be protected from some competitors by regional or 
    local trade barriers.
        Second, it is assumed that the facilities with the highest control 
    cost per unit of production also have the highest baseline production 
    costs per unit. This assumption may not always be true since the 
    baseline production costs per unit are not known, and thus the 
    estimated number of facilities that would discontinue production of 
    affected chemicals may be too high.
        Third, for the production of PET, the selected regulatory 
    alternative includes the control of organic HAP emissions from the 
    vacuum system and process contact cooling tower. Control of these 
    emissions is the highest cost item in the selected regulatory 
    alternative and is the biggest contributor to the risk of facilities 
    discontinuing PET production. The economic analysis is based on the use 
    of ethylene glycol jets to control these emissions. There are a number 
    of potential control technologies for these emissions that are expected 
    by the EPA to have lower costs, but costs for these control 
    technologies were not calculated. Ethylene glycol jets are being used 
    by at least two facilities and data were available from one facility. 
    The EPA has and will continue to investigate other control technologies 
    for control of these emissions. The EPA invites comment and data on 
    other control technologies.
        More detailed information concerning the economic impacts and 
    analysis are included in the Regulatory Impacts Analysis document 
    (Docket No. A-92-45, Category II-B).
    
    VII. Administrative Requirements
    
    A. Public Hearing
    
        A public hearing will be held, if requested, to discuss the 
    proposed standard in accordance with section 307(d)(5) of the Clean Air 
    Act. Persons wishing to make oral presentation on the proposed 
    standards for ABS, SAN, MABS, MBS, polystyrene, PET, and nitrile 
    production should contact the EPA at the address given in the ADDRESSES 
    section of this preamble. Oral presentations will be limited to 15 
    minutes each. Any member of the public may file a written statement 
    before, during, or within 30 days after the hearing. Written statements 
    should be addressed to the Air Docket Section address given in the 
    ADDRESSES section [[Page 16110]] of this preamble and should refer to 
    Docket No. A-92-45.
        A verbatim transcript of the hearing and written statements will be 
    available for public inspection and copying during normal working hours 
    at the EPA's Air Docket Section in Washington, DC (see ADDRESSES 
    section of this preamble).
    
    B. Docket
    
        The docket is an organized and complete file of all the information 
    submitted to or otherwise considered by the EPA in the development of 
    the proposed rule. The principal purposes of the docket are:
        (1) To allow interested parties to readily identify and locate 
    documents so that they can intelligently and effectively participate in 
    the rulemaking process; and
        (2) To serve as the record in case of judicial review (except for 
    interagency review materials (section 307(d)(7)(A)).
    
    C. Executive Order 12866
    
        Under Executive Order 12866, (58 FR 51735 (October 4, 1993)) the 
    Agency must determine whether the regulatory action is ``significant'' 
    and therefore subject to Office of Management and Budget (OMB) review 
    and the requirements of the Executive Order. The Order defines 
    ``significant regulatory action'' as one that is likely to result in a 
    rule that may:
        (1) Have an annual effect on the economy of $100 million or more or 
    adversely affect, in a material way, the economy, a sector of the 
    economy, productivity, competition, jobs, the environment, public 
    health or safety, or State, local, or tribal governments or 
    communities;
        (2) Create a serious inconsistency or otherwise interfere with an 
    action taken or planned by another agency;
        (3) Materially alter the budgetary impact of entitlements, grants, 
    user fees, or loan programs or the rights and obligations of recipients 
    thereof; or
        (4) Raise novel legal or policy issues arising out of legal 
    mandates, the President's priorities, or the principles set forth in 
    the Executive Order.
        Pursuant to the terms of the Executive Order, the OMB has notified 
    the EPA that it considers this a ``significant regulatory action'' 
    within the meaning of the Executive Order. The EPA submitted this 
    action to the OMB for review. Changes made in response to suggestions 
    or recommendations from the OMB were documented and included in the 
    public record.
    
    D. Enhancing the Intergovernmental Partnership Under Executive Order 
    12875
    
        In compliance with Executive Order 12875, we have involved State, 
    local, and tribal governments in the development of this rule. These 
    governments are not directly impacted by the rule; i.e. they are not 
    required to purchase control systems to meet the requirements of the 
    rule. However, they will be required to implement the rule; e.g. 
    incorporate the rule into permits and enforce the rule. They will 
    collect permit fees which will be used to offset the resource burden of 
    implementing the rule. Two representatives of the State governments 
    have been members of the EPA Work Group developing the rule. The Work 
    Group has met numerous times, and comments have been solicited from the 
    Work Group members, including the State representatives. Their comments 
    have been carefully considered in the rule development. In addition, 
    all States are encouraged to comment on this proposed rule during the 
    public comment period, and the EPA intends to fully consider these 
    comments in the final rulemaking.
    
    E. Paperwork Reduction Act
    
        The information collection requirements in this proposed rule have 
    been submitted for approval to the OMB under the Paperwork Reduction 
    Act, 44 U.S.C. 3501 et seq. An information collection request (ICR) 
    document has been prepared by the EPA (ICR No. 1737.01), and a copy may 
    be obtained from Sandy Farmer, Information Policy Branch, EPA, 401 M 
    Street SW (2136), Washington, DC 20460, or by calling (202) 260-2740. 
    The public reporting burden for this collection of information is 
    estimated to average 938 hours per response per year, including time 
    for reviewing instructions, searching existing data sources, gathering 
    and maintaining the data needed, and completing and reviewing the 
    collection of information.
        Send comments regarding the burden estimate or any other aspect of 
    this collection of information, including suggestions for reducing this 
    burden, to Chief, Information Policy Branch, 2136, U. S. Environmental 
    Protection Agency, 401 M Street SW, Washington, DC 20503, marked 
    ``Attention: Desk Officer for EPA.'' The final rule will respond to any 
    OMB or public comments on the information collection requirements 
    contained in this proposal.
    
    F. Regulatory Flexibility Act
    
        The Regulatory Flexibility Act (or RFA, Public Law 96-354, 
    September 19, 1980) requires Federal agencies to give special 
    consideration to the impact of regulation on small businesses. The RFA 
    specifies that a final regulatory flexibility analysis must be prepared 
    if a proposed regulation will have a significant economic impact on a 
    substantial number of small entities. To determine whether a final RFA 
    is required, a screening analysis, otherwise known as an initial RFA, 
    is necessary.
        Regulatory impacts are considered significant if:
        (1) Annual compliance costs increase total costs of production by 
    more than 5 percent, or
        (2) Annual compliance costs as a percent of sales are at least 20 
    percent (percentage points) higher for small entities, or
        (3) Capital cost of compliance represent a significant portion of 
    capital available to small entities, or
        (4) The requirements of the regulation are likely to result in 
    closures of small entities.
        A ``substantial number'' of small entities is generally considered 
    to be more than 20 percent of the small entities in the affected 
    industry.
        Consistent with Small Business Administration (SBA) size standards, 
    a thermoplastic producing firm is classified as a small entity if it 
    has less than 750 employees, and is unaffiliated with a larger entity. 
    Based upon this criterion, only one firm employs less than 750 workers.
        Data were available to examine two of the criteria: the potential 
    for closure, and a comparison of compliance costs as a percentage of 
    sales.
        For criterion one, the affected source is not expected to fall at 
    risk of closure from the regulation, thus this criterion is not met. 
    Also, the compliance costs were only 0.001 percent of total sales for 
    the affected source, and this does not meet criterion two.
        The affected firm is an MBS producer, and since the economics 
    analysis lead to the conclusion that no MBS facilities are at risk of 
    closure, this criterion is not met. Also, the compliance costs were 
    only 0.001 percent of total sales for the firm.
        In conclusion, and pursuant to section 605(b) of the Regulatory 
    Flexibility Act, 5 U.S.C. 605(b), the Administrator certifies that this 
    rule will not have a significant economic impact on a substantial 
    number of small entities. The basis for the certification is that the 
    economic impacts for small entities do not meet or exceed the criteria 
    in the [[Page 16111]] Guidelines to the Regulatory Flexibility Act of 
    1980, as shown above. Further information on the initial RFA is 
    available in the background information package (see SUPPLEMENTARY 
    INFORMATION section near the beginning of this preamble).
    
    G. Miscellaneous
    
        In accordance with section 117 of the Act, publication of this 
    proposal was preceded by consultation with appropriate advisory 
    committees, independent experts, and Federal departments and agencies. 
    The Administrator will welcome comments on all aspects of the proposed 
    regulation, including health, economic and technical issues, and on the 
    proposed test methods.
        This regulation will be reviewed 8 years from the date of 
    promulgation. This review will include an assessment of such factors as 
    evaluation of the residual health and environmental risks, any overlap 
    with other programs, the existence of alternative methods, 
    enforceability, improvements in emission control technology and health 
    data, and the recordkeeping and reporting requirements.
    
    List of Subjects in 40 CFR Part 63
    
        Environmental protection, Air pollution control, Hazardous 
    substances, Reporting and recordkeeping requirements.
    
        Dated: March 15, 1995.
    Carol M. Browner,
    Administrator.
    [FR Doc. 95-7066 Filed 3-28-95; 8:45 am]
    BILLING CODE 6560-50-P
    
    

Document Information

Published:
03/29/1995
Department:
Environmental Protection Agency
Entry Type:
Proposed Rule
Action:
Proposed rule and notice of public hearing.
Document Number:
95-7066
Dates:
Comments. Comments must be received on or before May 30, 1995.
Pages:
16090-16111 (22 pages)
Docket Numbers:
AD-FRL-5175-9
RINs:
2060-AE37: NESHAP: Polymers and Resins, Group IV
RIN Links:
https://www.federalregister.gov/regulations/2060-AE37/neshap-polymers-and-resins-group-iv
PDF File:
95-7066.pdf
CFR: (1)
40 CFR 63