96-5374. Transportation of Hydrogen Sulfide by Pipeline  

  • [Federal Register Volume 61, Number 46 (Thursday, March 7, 1996)]
    [Proposed Rules]
    [Pages 9133-9136]
    From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
    [FR Doc No: 96-5374]
    
    
    
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    DEPARTMENT OF TRANSPORTATION
    
    Research and Special Programs Administration
    
    49 CFR Parts 191 and 192
    
    [Docket No. PS-106; Notice 3]
    RIN 2137-AB63
    
    
    Transportation of Hydrogen Sulfide by Pipeline
    
    AGENCY: Research and Special Programs Administration (RSPA).
    
    ACTION: Withdrawal of notice of proposed rulemaking (NPRM).
    
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    SUMMARY: In response to three National Transportation Safety Board 
    (NTSB) Safety Recommendations, RSPA issued an Advance Notice of 
    Proposed Rulemaking (ANPRM) followed by a Notice of Proposed Rulemaking 
    (NPRM) that proposed changes in the Pipeline Safety Regulations to 
    address the hazard of excessive levels of hydrogen sulfide (H2S) 
    in natural gas transmission pipelines. In a final review of information 
    and comment from all sources, including advice from the Technical 
    Pipeline Safety Standards Committee (TPSSC), RSPA determined that a 
    regulation to address H2S in transmission lines is not warranted. 
    Therefore, the NPRM is withdrawn.
    
    FOR FURTHER INFORMATION CONTACT: Mike Israni, (202) 366-4571, regarding 
    the subject matter of this notice, or the Dockets Unit, (202) 366-4453, 
    regarding copies of this notice or other material in the docket as 
    referenced above.
    
    SUPPLEMENTARY INFORMATION:
    
    Background
    
        H2S is a colorless and flammable gas which is hazardous to 
    life and health at concentrations above 300 parts per million (ppm) . 
    At concentrations of 1000 ppm in air it can cause immediate 
    unconsciousness and death. The Occupational Safety and Health 
    Administration has established an upper concentration level of 10 ppm 
    for prolonged (8 hours) workplace exposure.
        The current regulations in 49 CFR Parts 192 and 195 address 
    H2S only with respect to its corrosive effect on pipelines, as 
    follows:
         Sec. 192.125(d) states that copper pipe that does not have 
    an internal corrosion resistant lining may not be used to carry gas 
    that has an average H2S content of over 0.3 grains per 100 
    standard cubic feet (SCF) of gas.
         Sec. 192.475 states that corrosive gas may not be 
    transported by pipeline unless the corrosive effect of the gas on the 
    pipeline has been investigated and steps have been taken to minimize 
    internal corrosion. In addition, gas containing more than 0.1 grains of 
    H2S per 100 SCF may not be stored in pipe-type or bottle-type 
    holders.
         Sec. 195.418 states that no operator may transport any 
    hazardous liquid that would corrode the pipe or other pipeline 
    components unless it has investigated the corrosive effect of the 
    hazardous liquid on the system and taken adequate steps to mitigate 
    corrosion.
    
    NTSB Recommendations
    
        As a result of the NTSB investigation of an August 1987 accidental 
    release of H2S into a gas supply to Lone Star Gas Company in 
    Texas, and after learning of 11 additional H2S releases since 1977 
    (none of which involved any fatalities or serious injuries), NTSB 
    issued three Safety Recommendations to RSPA (P-88-1, -2 and -3) which 
    called for (-1) establishing a maximum allowable concentration of 
    H2S in natural gas pipeline systems, (-2) requiring operators to 
    report all incidents in which concentrations of H2S exceed this 
    maximum, and (-3) requiring operators to install equipment to 
    automatically detect and shut off the flow of gas when H2S 
    concentrations exceed the maximum.
    
    Advance Notice of Proposed Rulemaking (ANPRM)
    
        The RSPA responded to the NTSB recommendations by issuing an ANPRM 
    on June 7,1989 (54 FR 24361). Because the Pipeline Safety Regulations 
    do not require any monitoring of H2S levels in natural gas 
    pipeline systems, the ANPRM included a request for information to be 
    used in assessing the need for any such regulations. The ANPRM provided 
    background information and discussion on gas wells having significant 
    concentrations of H2S (sour gas), on the toxicity of H2S, and 
    on the effects of H2S with regard to sulfide stress and stress 
    corrosion cracking of line pipe. It discussed two H2S incidents in 
    California (1983 and 1984) and one in Texas (1987) that were reported 
    by NTSB, and mentioned some instances where workers were overcome by 
    H2S at a sour gas field in Canada. It quoted the aforementioned 
    three NTSB Safety Recommendations (P-88-1, -2 and -3), summarized the 
    aforementioned Federal Regulations (49 CFR 192.125, 192.475 and 
    195.418), discussed state regulations on H2S (California General 
    Order 58; Michigan Rules 299, 460 and 81; and Texas Rule 36), and 
    mentioned seven sections in Canadian Standard Z184-1975 that deal with 
    sour gas. For additional information on the above items refer to the 
    ANPRM which is available in the docket.
        In its request for information, the ANPRM included four questions 
    as follows:
        Question 1. What factors should be considered in determining the 
    need for a maximum allowable concentration of H2S in natural gas 
    pipeline systems? What should this concentration be?
        Question 2. Describe events you know of in which H2S has been 
    released from,
    
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    or into, a pipeline in dangerous amounts and what were the H2S 
    concentrations? What were the consequences of such releases? What would 
    be the burden associated with mandatory reporting of such events?
        Question 3. If you are an operator receiving gas from a producer, 
    do you have automatic H2S detection and shut-off equipment? Do 
    these devices work reliably? For such operators that do not have this 
    equipment, what costs and other burdens can be associated with 
    requiring use of the equipment?
        Question 4. Which pipelines transporting sour gas should be subject 
    to an H2S monitoring requirement? Should rural gas gathering lines 
    be subject to H2S monitoring requirements, even though they are 
    not now subject to any of the part 192 safety standards?
        RSPA received 54 responses to the ANPRM, mostly from natural gas 
    and hazardous liquid operators. Question 1 produced a wide variety of 
    suggestions for assessing the need for a maximum level of H2S. In 
    addition, most commenters suggested a maximum allowable H2S 
    concentration in the range of 0.25 to 1.0 grains per 100 SCF of natural 
    gas. The suggested factors for assessing the need for a maximum 
    allowable H2S level included such things as the kind of pipeline 
    system (gathering, transmission or distribution); operating conditions 
    (pressure, temperature, rate of flow); presence of contaminants 
    (H2O, CO2, hydrocarbon liquids, inhibitors); time interval of 
    H2S intrusion; piping materials; piping age; gas destination; 
    weather conditions; and provisions for ``grandfathering.'' With regard 
    to a maximum allowable H2S level, RSPA felt that an upper limit of 
    1 grain per 100 SCF of natural gas would be appropriate because it is 
    consistent with the limit set by OSHA and several states.
        With regard to question 2, the commenters indicated that H2S 
    releases have not been widespread, significant, or a recurring problem. 
    On the matter of burden associated with mandatory reporting, most 
    distribution operators, as well as many transmission operators, 
    indicated little burden, but they questioned the usefulness of a 
    reporting requirement. However, in spite of this train of comment, RSPA 
    was of the opinion that a release of an excessive amount of H2S 
    into a pipeline system could result in a hazardous situation if there 
    is gas leakage from the piping.
        Response to question 3 from most operators was that H2S 
    detection equipment and allied gas shutoff equipment is generally 
    reliable, with per installation equipment cost in the $10,000 to 
    $30,000 range. Monthly operating cost for the most part was $1500, with 
    one operator reporting $3000. A large midwestern distribution operator 
    reported that it would cost $484,000 for equipment for its entire 
    system with an annual operating cost of $105,000. RSPA felt that, to 
    ensure public safety, high concentrations of H2S should be removed 
    from the gas before delivery to the transmission pipeline.
        On question 4 most commenters favored a location immediately 
    downstream of where the gas is treated for H2S removal as the 
    place for monitoring. Very few commenters thought that pipelines 
    carrying sour gas should not be monitored. Most commenters were opposed 
    to rural gathering lines being subject to H2S monitoring.
        RSPA agreed with most commenters that monitoring should be in the 
    interface between the gathering line and transmission line at a point 
    immediately downstream of the H2S removal facility. RSPA also 
    agreed that there is no need for monitoring equipment where 
    transmission pipelines are not receiving gas that could be subject to 
    H2S contamination. In addition, RSPA agreed with the commenters 
    who stated that regulation of H2S in gathering lines is 
    impractical because those pipelines are generally upstream of H2S 
    removal facilities.
    
    The Notice of Proposed Rulemaking
    
        On the basis of its review and analysis of the information and 
    comments received from the ANPRM, RSPA published an NPRM on March 18, 
    1991 (56 FR 11490) proposing rule changes in parts 191 and 192. The 
    proposed changes were to (1) limit H2S levels in transmission 
    lines downstream of gas processing plants, sulfur recovery plants, and 
    storage fields to 1 grain per 100 SCF of natural gas; (2) require 
    reporting to RSPA if an excessive amount of H2S enters a 
    transmission line; and (3) require that operators of jurisdictional 
    onshore and offshore gas gathering lines containing over 31 grains of 
    H2S per 100 SCF of natural gas have written contingency plans for 
    any release of H2S into the atmosphere. For detail on the changes 
    in the regulations, refer to the NPRM which is available in the docket.
        RSPA received 30 responses to the NPRM; 23 from gas and hazardous 
    liquid pipeline operators, three from pipeline industry associations 
    (American Gas Association, Interstate Natural Gas Association, and 
    American Petroleum Institute), two from Federal government agencies 
    (NTSB and Minerals Management Service), one from a state pipeline 
    safety agency. (Kansas Corporation Commission), and one from a local 
    government (County of Santa Barbara). The following summarizes the 
    responses:
         General Comments--Several commenters, particularly 
    distribution system operators, supported limits on the amount of 
    H2S allowable in natural gas transmission pipelines. The 
    distribution operators were concerned about the regulations requiring 
    the installation of H2S monitoring equipment in their systems.
        NTSB commented that the term ``grains per 100 SCF of natural gas'' 
    should be replaced with ``parts per million'' (ppm). NTSB also 
    suggested that RSPA provide the scientific basis for the H2S 
    limits used in these regulations.
        Many commenters were concerned that a pending RSPA rulemaking for 
    redefining gas gathering lines would result in some lines being 
    reclassified as transmission lines, and the resulting affects of this 
    on any such lines that transport high concentration H2S natural 
    gas.
        The API was concerned about the definition of ``gathering lines'' 
    and ``production facilities'', and urged that RSPA adopt the API 
    proposed definitions of these terms (these proposed API definitions are 
    being taken into consideration by RSPA in the development of the 
    rulemaking for redefining ``gathering line'').
        Several commenters, especially Monterrey Pipeline Company, were 
    concerned about RSPA proposing regulations in spite of comments that 
    argued against the need for regulations for establishing a maximum 
    H2S level for natural gas in transmission pipelines. In contrast, 
    many commenters, such as Tenneco, felt that RSPA, in developing the 
    proposed regulations, had adequately balanced considerations of public 
    safety with the need for prudent operation of pipeline systems. The 
    Resources Management Department of the County of Santa Barbara 
    commended the effort by the RSPA to address the hazards of sour gas in 
    natural gas. Santa Barbara recommended three levels of protection 
    (operational procedures, H2S detectors, and mechanical means) with 
    standby/duplication at each level.
         Section 191.3--Several commenters noted that the NPRM 
    definition of an event involving the presence of H2S, as proposed 
    in the Sec. 191.3 definition of an H2S ``Incident,'' should be 
    limited to ``transmission pipelines downstream of gas processing 
    plants, sulfur recovery plants, or storage fields,'' wording
    
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    similar to the NPRM proposed Sec. 192.631.
        Many commenters took the position that there is no need to expand 
    the definition of ``incident'' in Sec. 191.3 by adding an H2S 
    ``incident'' because people are not exposed to the H2S that may be 
    introduced into a pipeline downstream of a gas processing plant, sulfur 
    recovery plant, or storage field.
        The proposed addition to the definition of ``incident'' read ``An 
    event where hydrogen sulfide in excess of 20 grains per 100 standard 
    cubic feet of natural gas is released into a transmission pipeline''. 
    Interstate Natural Gas Association of America (INGAA) and Enron 
    commented that this wording should be revised to make it clear that it 
    is natural gas, containing a certain concentration of H2S, that 
    enters a transmission pipeline to create the reportable incident.
        United Gas Pipe Line Company (UGPL) commented that there was 
    nothing to quantify the extent of a release with respect to time. 
    According to UGPL, the small quantity of gas entering a transmission 
    pipeline during the 30 to 60 seconds required to activate shutoff would 
    constitute a reportable incident, even though it would be quickly 
    diluted by the large volume of sweet gas in the pipeline from other 
    sources, and therefore pose no hazard. On the other hand, the Minerals 
    Management Service (MMS) commented that a minimum level of 20 grains 
    per 100 SCF of natural gas (320 ppm) may be too high because at that 
    level the pipe would be subject to sulfide stress cracking. In 
    addition, MMS made reference to the high toxicity level at 20 grains of 
    H2S per 100 SCF (320 ppm) with the following description of 
    toxicity at 200 ppm from API RP 49, Table A.1: ``Burns eyes and throat. 
    At concentration between 200-500 ppm pulmonary edema which can be life 
    threatening almost always occurs.''
        The proposed addition to the definition of ``incident'' in 
    Sec. 191.3 included any release (into a transmission pipeline) of 
    natural gas containing in excess of 20 grains of H2S per 100 SCF 
    (320 ppm) a reportable incident. RSPA agreed that because of the 
    dilution mentioned previously, and because the gas would be contained 
    inside the piping (as indicated by many commenters), a hazardous 
    situation would be unlikely.
         Section 191.5--INGAA, Ocean Drilling and Exploration Co. 
    (ODECO), UGPL, and Colorado Interstate Gas (CIG) opposed the use of the 
    telephonic notice for reporting H2S incidents. CIG, INGAA and UGPL 
    suggested using the Sec. 191.25 Safety-Related Condition Report, and 
    ODECO favored a written report similar to that of Sec. 191.9. INGAA and 
    UGPL recommended that the reported information should address the 
    concentration instead of the amount of H2S, and the length of time 
    of the release. They also said that determining how far the H2S 
    had spread could be difficult.
         Section 192.631--Many commenters indicated that the 
    proposed Sec. 192.631, if taken literally, could require transmission 
    pipelines that are not immediately downstream of a gas processing 
    plant, sulfur recovery plant, or storage field, to be monitored for the 
    presence of H2S. Many transmission pipelines, especially those 
    belonging to gas distribution operators, are many miles downstream of 
    the point (gas processing plant, sulfur recovery plant or storage 
    field) where sour gas could be inadvertently released into the pipeline 
    and there is therefore no need for H2S monitoring. Alabama Gas 
    Corporation commented that the rule should be rephrased so that 
    monitoring is not required where there is no possibility of an H2S 
    release.
        Several commenters pointed out that the introductory phrase 
    ``Except as set forth in Sec. 192.633,'' should be deleted in proposed 
    Sec. 192.631 because there is no exception in Sec. 192.633 for 
    transmission pipelines. This introductory phrase was included in this 
    proposed rule because, in accordance with the current requirements in 
    Sec. 192.9, gathering lines must comply with rules that are applicable 
    to transmission pipelines. The introductory phrase was intended to 
    except gathering lines from having to comply with Sec. 192.631 so they 
    may carry sour gas by complying with Sec. 192.633.
        Okaloosa County Gas District recommended that OSHA standards on 
    H2S be implemented by limiting H2S to 0.625 grains per 100 
    SCF of natural gas. Transcontinental Gas Pipe Line Corporation 
    (Transco) commented that the proposed limit of 1 grain of H2S per 
    100 SCF of natural gas could conflict with existing gas purchase 
    contract limits and proposed ``grandfathering'' the conditions in 
    existing gas purchase contracts that do not exceed 2 grains of H2S 
    per 100 SCF of natural gas. The NTSB suggested that the maximum 
    permissible concentration of H2S should be 10 ppm (0.625 grains 
    per 100 SCF of natural gas), as established by OSHA, instead of 1 grain 
    of H2S per 100 SCF of natural gas (16 ppm). The MMS commented that 
    15.9 ppm (1 grain per 1000 SCF) is very conservative and appropriate 
    for transmission pipelines, and pointed out that 1 grain of H2S 
    per 100 SCF of natural gas (16 ppm), as specified in Sec. 192.631, is 
    the short term exposure limit established by OSHA as the `` * * * 
    employee's 15-minute time weighted average which shall not be exceeded 
    at any time during a work day * * * '' (54 FR 2920).
         Section 192.633--Several commenters supported the use of 
    the Texas Railroad Commission Rule 36 in developing regulations for 
    gathering lines that carry high concentrations of H2S. Pennzoil 
    was concerned that the regulations proposed in Sec. 192.633 may be 
    misinterpreted to apply to gathering lines in rural areas. As noted in 
    the NPRM, these regulations do not apply to gathering lines in rural 
    areas. In accordance with the applicability regulations in 
    Sec. 192.1(2), Part 192 does not apply to the onshore gathering of gas 
    outside one of the following areas:
        (i) An area within the limits of any incorporated or unincorporated 
    city, town, or village.
        (ii) Any designated residential or commercial area such as a 
    subdivision, business or shopping center, or community development.
        It should be noted that Sec. 192.633 applies to offshore gathering 
    lines since Sec. 192.1(2) only excepts onshore gathering lines from the 
    requirements of Part 192.
        Lone Star Gas Company (LSG) commented that Rule 36 was intended to 
    apply to production wells producing natural gas having high 
    concentrations of H2S; i.e., a single point source of possible 
    H2S release. LSG commented that applying the formula in proposed 
    Sec. 192.633(b)(1) to pipelines needed some clarification, particularly 
    regarding the term ``maximum volume of gas available for escape.'' LSG 
    also commented that Sec. 192.633(b)(2) should be clarified since Rule 
    36 requires a plat detailing the area around a production well which 
    again is a point source of possible escape of natural gas carrying high 
    concentrations of H2S. LSG argues that a pipeline subject to 
    Sec. 192.633(b)(2) is not a point source.
        Both LSG and Enron suggested that contingency plans proposed in 
    Sec. 192.633 be incorporated into Sec. 192.615 since such plans for 
    hydrogen sulfide emergencies would probably be incorporated into 
    emergency plans currently existing under Sec. 192.615. Both commenters 
    observed that many of the requirements in the proposed Sec. 192.633 
    were taken from Sec. 192.615 and no purpose is served by requiring that 
    the information be repeated. Enron commented that there is no reason to 
    differentiate between contingency plans for onshore as opposed to 
    offshore pipelines. According to Enron, current emergency plans exist 
    for onshore and
    
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    offshore pipelines and Part 192 does not outline differences that are 
    to exist between them.
    
    Technical Pipeline Safety Standards Committee
    
        RSPA presented the NPRM to the TPSSC for its consideration at a 
    meeting in Washington, DC on March 11, 1992. The TPSSC is RSPA's 
    statutory advisory committee for gas pipeline safety. It is composed of 
    15 members, representing industry, government, and the public, who are 
    technically qualified to evaluate gas pipeline safety. The TPSSC 
    expressed concerns about adopting the proposed changes in 49 CFR Part 
    192 to address H2S in natural gas transmission pipelines. The 
    TPSSC 's concerns centered around the need for such a regulation 
    considering the limited number of incidents involving the release of 
    H2S natural gas into transmission pipelines, and whether it would 
    increase safety, be cost effective and redundant to already existing 
    state regulations. Therefore, the TPSSC recommended that the incidence 
    of H2S in transmission lines did not warrant a rulemaking.
        On the basis of that finding, an analysis and review of the 
    comments to the NPRM, and further analysis of the comments to the 
    ANPRM, RSPA decided to re-consider the need for the proposed regulation 
    and concluded that the proposed H2S regulations are not warranted 
    because they are oriented/directed toward transmission lines. No 
    injuries or deaths have been attributed to H2S in natural gas 
    transmission lines. H2S releases into transmission lines to date 
    have been infrequent, have been of extremely brief duration, and have 
    involved only very minute amounts of H2S. H2S that is 
    released into a transmission line remains confined with very little 
    likelihood that there would happen to be a leak in the transmission 
    line at the same time and in the same general vicinity as the release. 
    And lastly, H2S released into a transmission line from a 
    processing plant would most likely be diluted by natural gas from other 
    sources.
        Rather than applying rule changes affecting transmission pipelines, 
    RSPA's regulatory efforts on H2S should be redirected to gathering 
    lines. The source of H2S is the gas well, and the gathering line 
    is the first pipeline facility downstream of the well. It is on 
    gathering lines transporting H2S laden natural gas from wells to 
    processing plants that regulations may be needed. Future development 
    with respect to H2S in gathering lines may be addressed in a later 
    rulemaking.
        On the basis of the foregoing, RSPA hereby withdraws the NPRM 
    proposing to limit H2S levels in natural gas in gas transmission 
    pipelines.
    
        Authority: 49 U.S.C. 60102 et seq.; 49 CFR 1.53.
    
        Issued in Washington, D.C. on March 4, 1996.
    Richard B Felder,
    Associate Administrator for Pipeline Safety.
    [FR Doc. 96-5374 Filed 3-6-96; 8:45 am]
    BILLING CODE 4910-60-P
    
    

Document Information

Published:
03/07/1996
Department:
Research and Special Programs Administration
Entry Type:
Proposed Rule
Action:
Withdrawal of notice of proposed rulemaking (NPRM).
Document Number:
96-5374
Pages:
9133-9136 (4 pages)
Docket Numbers:
Docket No. PS-106, Notice 3
RINs:
2137-AB63: Transportation of Hydrogen Sulfide by Pipeline
RIN Links:
https://www.federalregister.gov/regulations/2137-AB63/transportation-of-hydrogen-sulfide-by-pipeline
PDF File:
96-5374.pdf