[Federal Register Volume 59, Number 249 (Thursday, December 29, 1994)]
[Unknown Section]
[Page 0]
From the Federal Register Online via the Government Publishing Office [www.gpo.gov]
[FR Doc No: 94-31175]
[[Page Unknown]]
[Federal Register: December 29, 1994]
_______________________________________________________________________
Part II
Department of Transportation
_______________________________________________________________________
Research and Special Programs Administration
_______________________________________________________________________
49 CFR Part 171, et al.
Implementation of the United Nations Recommendations, International
Maritime Dangerous Goods Code, and International Civil Aviation
Organization's Technical Instructions; Final Rule
DEPARTMENT OF TRANSPORTATION
Research and Special Programs Administration
49 CFR Parts 171, 172, 173, 175, 176, 177, 178
[Docket No. HM-215A; Amdt Nos. 171-131, 172-139, 173-241, 175-52, 176-
36, 177-84, 178-106]
RIN 2137-AC42
Implementation of the United Nations Recommendations,
International Maritime Dangerous Goods Code, and International Civil
Aviation Organization's Technical Instructions
AGENCY: Research and Special Programs Administration (RSPA), DOT.
ACTION: Final rule.
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SUMMARY: This final rule amends the Hazardous Materials Regulations to
maintain alignment with corresponding provisions of international
standards. Because of recent changes to the International Maritime
Dangerous Goods Code (IMDG Code), the International Civil Aviation
Organization's Technical Instructions for the Safe Transport of
Dangerous Goods by Air (ICAO Technical Instructions), and the United
Nations Recommendations on the Transport of Dangerous Goods (UN
Recommendations), these revisions are necessary to facilitate the
transport of hazardous materials in international commerce.
DATES: Effective: October 1, 1995.
Compliance date: Compliance with the regulations, as amended
herein, is authorized as of January 1, 1995.
Incorporation by reference: The incorporation by reference of
certain publications listed in these amendments has been approved by
the Director of the Federal Register as of October 1, 1995.
FOR FURTHER INFORMATION CONTACT: Bob Richard, Assistant International
Standards Coordinator, telephone (202) 366-0586, Beth Romo or John
Gale, Office of Hazardous Materials Standards, telephone (202) 366-
8553, Hazardous Materials Safety, Research and Special Programs
Administration, U.S. Department of Transportation, 400 Seventh Street,
SW., Washington, DC 20590-0001.
SUPPLEMENTARY INFORMATION:
I. Background
On December 21, 1990, the Research and Special Programs
Administration (RSPA) published a final rule [Docket HM-181; 55 FR
52402] which comprehensively revised the Hazardous Materials
Regulations (HMR), 49 CFR Parts 171 to 180, with respect to hazard
communication, classification, and packaging requirements, based on the
UN Recommendations. One intended effect of the rule was to facilitate
the international transportation of hazardous materials by ensuring a
basic consistency between the HMR and international regulations.
The UN Recommendations are not regulations, but are recommendations
issued by the UN Committee of Experts on the Transport of Dangerous
Goods. These recommendations are amended and updated biennially by the
Committee of Experts and are distributed to nations throughout the
world. They serve as the basis for international modal regulations;
specifically the IMDG Code, issued by the International Maritime
Organization (IMO), and the ICAO Technical Instructions. In 49 CFR
171.12, the HMR authorize shipments prepared in accordance with the
IMDG Code if all or part of the transportation is by vessel, subject to
certain conditions and limitations. Offering, accepting and
transporting hazardous materials by aircraft, in conformance with the
ICAO Technical Instructions, and by motor vehicle either before or
after being transported by aircraft, are authorized in Sec. 171.11
(with certain exceptions).
On December 22, 1992, RSPA issued an interim final rule [Docket HM-
215; 57 FR 60738] amending Sec. 171.7 by incorporating the 1993-1994
edition of the ICAO Technical Instructions and Amendment 26 to the IMDG
Code. This rulemaking action authorized the use of the updated
international regulations, effective January 1, 1993. Amendment 26
promulgated numerous miscellaneous changes to the IMDG Code regarding
classification, labeling, packaging, and documentation. The 1993-1994
edition of the ICAO Technical Instructions contained amendments
relating to the seventh revised edition of the UN Recommendations, as
well as changes specific to air transportation.
The HMR, as revised under Docket HM-181, are largely based on the
sixth revised edition of the UN Recommendations. Selected provisions
from the seventh and eighth revised editions of the UN Recommendations
have been incorporated into the HMR under subsequent Docket HM-181
rulemaking actions.
On July 18, 1994, RSPA issued a Notice of Proposed Rulemaking
(NPRM) (Docket HM-215A; 59 FR 36488), which proposed changes to more
fully align the HMR with the seventh and eighth revised editions of the
UN Recommendations. Such changes would provide consistency with the
international air and sea transport requirements which, effective
January 1, 1995, will be aligned with the eighth revised edition of the
UN Recommendations.
II. Summary of Comments
RSPA received nearly 120 comments to the proposed rule from
chemical manufacturers and distributors, carriers, model rocket users,
and industry associations representing hazardous materials offerors,
carriers, and packaging manufacturers and reconditioners. Commenters
supported RSPA's effort to align the HMR with international standards
to provide consistency and facilitate the international transportation
of hazardous materials. Major issues identified by commenters included:
(1) The purported need for a delay in the effective date of the final
rule to allow an orderly transition from old to new requirements; (2)
possible expansion of proposed provisions to allow reuse of certain UN
standard packagings without leakproofness testing; (3) a request from
model rocket users to clarify proposed packaging requirements for model
rockets; (4) proposed removal of an exception for shipments transported
within a port area; (5) reciprocal treatment of foreign-manufactured
packagings; (6) proposed changes in criteria for corrosivity testing;
and (7) proposed subsidiary labeling and terminology changes. A more
detailed discussion of the comments and rulemaking actions in response
to these comments is provided in the following summary.
III. Summary of Regulatory Changes by Section
Part 171
Section 171.7. Various standards, such as those issued by the
International Organization for Standardization (ISO), the American
Society for Testing and Materials (ASTM), and Transport Canada, are
added or updated, and the most current versions of the ICAO Technical
Instructions, the IMDG Code, and the UN Recommendations are
incorporated.
Section 171.8. New definitions for ``Asphyxiant gas,'' ``Gas,''
``Oxidizing gas'' and ``Siftproof packaging'' are added, and
definitions for ``Box,'' ``Liquid,'' ``Overpack,'' ``Solid'' and ``UN
standard packaging'' are revised for consistency with the seventh and
eighth revised editions of the UN Recommendations. Two commenters asked
RSPA to delete the word ``Small'' in the proposed revision of the
definition for ``box''. These commenters claimed that the term was
ambiguous and could lead to differing interpretations by various
enforcement agencies. RSPA agrees and is replacing the wording ``Small
holes'' with the phrase ``Holes appropriate to the size and use of the
packaging''. One of the commenters further asked RSPA to clarify
whether the openings in the box may be designed for uses other than for
ease of handling or opening. RSPA believes the wording ``such as ease
of handling or opening, or to meet classification requirements''
proposed in the NPRM offers sufficient examples of uses for openings
and, therefore, is not amending this text in the final rule. The
definition for ``UN standard packaging'' is revised to clarify that it
applies to both U.S.-manufactured and foreign-manufactured packagings
and to delete reference to Subparts L and M of Part 178.
Section 171.11. Paragraph (d)(5) is adopted as proposed to include
the word ``toxic'' as an appropriate reference to a poison.
Section 171.12. Paragraph (b) is revised as proposed. RSPA is
amending Secs. 171.12(b) and 176.27(c) to reference IMDG Code
requirements for a container packing certification for freight
containers and transport units intended for carriage by vessel. This
requirement applies to persons who load hazardous materials for
transportation (including freight forwarders, freight consolidators and
non-vessel operating common carriers) or transport hazardous materials
by vessel. A freight container packing certification requirement was
adopted several years ago under Amendment 24 to the IMDG Code and
became effective worldwide on January 1, 1994, as mandated under the
International Convention on Safety of Life at Sea (SOLAS Convention).
When hazardous materials are packed into a freight container or
transport vehicle for transportation by vessel, those responsible for
packing the unit must provide a certificate or declaration to the
carrier attesting that the container is suitable for transport, that it
contains compatible materials in packages that have been properly
inspected, packed, and secured, and the container and packages are
properly marked, labeled, and placarded. This certification may appear
either in a separate document or in a signed statement provided on the
dangerous goods shipping document. Because the U.S. is a signatory to
the SOLAS Convention, RSPA is adopting a similar container packing
certification requirement under the HMR.
In the NPRM, RSPA proposed removal of wording in paragraph (c)
which allows hazardous materials being imported into or exported from
the U.S. to comply with IMDG Code regulations in port areas. Commenters
responding to this proposal opposed the removal of this wording; they
claimed that a requirement for hazardous materials being imported into
or exported from the U.S. to comply with the HMR in a port area would
impose an economic burden on the industry and would be a barrier to
trade. Paragraph (c) is not being revised in this final rule. RSPA
plans to address the port area issue in greater detail in a future
rulemaking proceeding.
Section 171.14. This section is revised to provide a delayed
implementation date for amendments adopted in this final rule. RSPA
also is removing obsolete transition dates provided under the Docket
HM-181 final rule and its subsequent revisions. A new paragraph (a)
contains all remaining transition provisions for implementing changes
adopted under the Docket HM-181 final rules.
The effective date of this final rule is October 1, 1995. However,
RSPA is authorizing a voluntary compliance date of January 1, 1995,
which is consistent with the effective date of new requirements for
international air and vessel shipments and will allow shippers to
prepare their international shipments in accordance with the new ICAO,
IMDG, and HMR provisions. RSPA also is authorizing, in new paragraph
(b), a delay in mandatory compliance with the new requirements, until
October 1, 1996. RSPA believes that an effective date of October 1,
1995, with an additional one-year delay until October 1, 1996, offers a
sufficient phase-in period to implement new provisions and deplete
current stocks of shipping papers, labels and placards, and containers
affected by the new requirements. The October 1, 1996 implementation
date also is consistent with certain Docket HM-181 transition
provisions for maintenance and use of packagings. In addition,
paragraph (b)(2) permits intermixing of old and new hazard
communication requirements and reflects certain intermixing provisions
authorized by the Docket HM-181 final rule.
Part 172
Sections 172.101 and 172.102. RSPA is revising the Hazardous
Materials Table (HMT) and the list of special provisions in
Sec. 172.102 for basic conformance with the eighth revised edition of
the UN Recommendations, the ICAO Technical Instructions (1995-1996
edition) and the 27th edition of the IMDG Code.
The IM tank authorizations are revised for consistency with the
changes in Chapter 12 of the seventh and eighth revised editions of the
UN Recommendations. These changes can be found in the ``T-note''
authorizations that are listed in Column 7 of the HMT.
The aircraft quantity limitations in Column 9 and the vessel
stowage requirements in Column 10 are revised for consistency with the
ICAO Technical Instructions and IMDG Code, respectively. In
Sec. 172.101(k)(1)-(k)(5), revised definitions of the vessel stowage
codes, which are prescribed in the Sec. 172.101 Table, are adopted as
proposed for consistency with the IMDG Code. This revision broadens
current stowage provisions for hazardous materials on cargo vessels to
apply to hazardous materials (such as propane) on passenger vessels
carrying a limited number of passengers. RSPA received two comments
supporting this proposed change.
Changes to the HMT are quite extensive--approximately 33% of the
entries in the HMT are changed. Therefore, RSPA is republishing the
entire HMT in this final rule, but does not believe it is necessary to
discuss every change in this section review. However, in order to
facilitate the reader's understanding of the changes to the HMT, RSPA
is providing a list of all entries that are added, deleted, or made
more restrictive. This list includes all changes in (1) the shipping
name, (2) IM tank authorization, (3) subsidiary labeling, (4)
classification, and (5) packaging. In addition, a discussion of the
more substantive changes is provided.
Numerous editorial changes are made to the HMT to correct
misspellings and errors and to provide more consistency. A corrected
typographical error is not shown in the list of significant changes. In
addition, new generic entries are added for self-heating liquids and
solids. Specific entries for self-reactive materials are removed from
the HMT and replaced with new generic entries.
As discussed in the NPRM, the UN Recommendations, ICAO Technical
Instructions, and IMDG Code have replaced the term ``poisonous'' with
the term ``toxic.'' RSPA proposed to amend proper shipping names in the
HMT that contain the word ``poisonous'' by replacing ``poisonous'' with
the word ``toxic'' to conform to international terminology. For
example, the proper shipping name ``Flammable liquid, poisonous,
n.o.s.'' would read ``Flammable liquid, toxic, n.o.s.''. However, RSPA
also proposed to revise Sec. 172.101(c)(3) to allow the use of the word
``poisonous'' interchangeably with the word ``toxic''. Numerous
commenters provided diverse opinions on this proposal. Highway carriers
and the American Trucking Associations (ATA) believed that emergency
responders would be at greater risk because the word ``toxic'' is
overused and minimizes the seriousness of the poison hazard. They
recommended reinstating ``Poison'' or ``Poisonous'' entries for
domestic transportation. Another commenter thought that the option to
use either term would force emergency response personnel and end users
to deal with situations involving the same product bearing different
labels or placards, depending on shipper preference. On the other hand,
chemical manufacturers and their associations, such as the Chemical
Manufacturers Association (CMA), supported the proposal to allow
interchangeable use of either term. Other commenters, such as the
Hazardous Materials Advisory Council (HMAC) agreed with interchangeable
use, but only for as long as required to deplete stocks of preprinted
materials and conduct training. RSPA believes the interchangeable use
of ``poison'' and ``toxic'' for domestic transportation will provide
flexibility and, therefore, is adopting as proposed the provision to
permit use of either term.
The eighth revised edition of the UN Recommendations added entries
and assigned new UN I.D. numbers for elevated temperature materials.
RSPA is changing the I.D. numbers for elevated temperature materials in
the HMT to correspond with those in the UN Recommendations. RSPA
received comments requesting that RSPA not adopt the proposed
identification numbers for elevated temperature materials. The
commenters noted that the old identification numbers have only been
required since October 1, 1993, and that switching them after only one
year will cause confusion and non-compliance. Another commenter
requested an extended transition period for the change in
identification numbers for elevated temperature materials in order to
dispose of large supplies of markings. With the extended transition
period being provided in this final rule, RSPA believes that any
confusion related to the change of identification numbers will be
minimal. Therefore, RSPA is not accepting commenters' requests and has
adopted the shipping descriptions for elevated temperature materials as
proposed. In addition, RSPA is revising the HOT mark illustrated in
Sec. 172.325(c) to reflect the new UN identification number assigned to
``Elevated temperature material, liquid, n.o.s.''
Currently under the HMR, air bags are assigned to the Division 4.1
hazard class and the proper shipping name is limited to ``Air bag
inflators'' or ``Air bag modules.'' Based on changes in the UN
Recommendations, RSPA is revising the proper shipping name for air bags
to include seat belt pre-tensioners and modules. The new proper
shipping name is ``Air bag inflators or Air bag modules or Seat-belt
modules or Seat-belt pre-tensioners.'' This entry also reflects a
change in classification from Division 4.1 to Class 9, adoption of a
new UN number, and removal of the ``D'' in Column 1.
Two new domestic entries are added for ``toy caps'' and ``model
rocket motors''. Model rocket motors containing 30 grams or less
propellant are classed as Division 1.4S while items containing more
than 30 grams but not more than 62.5 grams of propellant are classed as
Division 1.4C. RSPA received numerous comments requesting a different
packing method for these materials. The commenters requested packing
method E-146(b) instead of packing method E-114 for these materials.
RSPA has not adopted this request to allow the use of packing method E-
146 for these materials, but has modified packing method E-114 to allow
plastic bags as inner packagings.
Two new entries for ``Batteries, containing sodium'' and ``Cells,
containing sodium'' are added in the HMT based on the UN
Recommendations entry (UN 3292). Since these materials were previously
authorized only under the terms of an exemption or competent authority
approval, RSPA is adding a new packaging section, Sec. 173.189, that
prescribes general packaging and transport requirements for these
materials consistent with the UN Recommendations.
Currently, in Column 1, a ``+'' is assigned to certain materials
meeting the criteria of Division 6.1, Packing Group I, toxic by
inhalation, but classed in another hazard class. The eighth revised
edition of the UN Recommendations incorporated revisions to the hazard
classification of these materials to Division 6.1, Packing Group I,
toxic by inhalation. Therefore, the ``+'' is removed from Column 1 for
any liquid poison by inhalation (PIH) material newly classed in
Division 6.1, Packing Group I.
The shipping name ``acetonitrile'' replaces the name ``methyl
cyanide.'' The hazard class for ``Formaldehyde solutions'' currently
shown as Class 9 is revised to Class 8. Numerous generic pesticide
entries are revised to remove the ``n.o.s.'' from the shipping names.
Revised generic shipping descriptions for Division 4.3 materials
are prefaced by the words ``water-reactive'' in lieu of the words
``substances which in contact with water emit''. The prefix of the
identification number for ``Polyester resin kits'' is changed to ``UN''
from ``NA'' and Special Provision 40 is added in Column 7 that
specifies contents and packaging requirements for polyester resin kits.
In addition, Special Provision 117 is removed from the entry
corresponding to ``UN0150.''
The entry for alcoholic beverages is revised in Column 7 to include
Special Provision 24, to indicate that alcoholic beverages with more
than 70 percent alcohol by volume are assigned Packing Group II and
alcoholic beverages containing more than 24 percent but not more than
70 percent alcohol are assigned Packing Group III. In addition,
Sec. 173.150 is revised to increase (to five liters per inner
packaging) the quantity of alcoholic beverage in a packaging excepted
from the HMR and to provide an exception adopted in the UN
Recommendations to permit Packing Group III alcoholic beverages
transported in receptacles of 250 L (66 gallons) or less to be excepted
from the HMR unless transported by air. One commenter requested that
the shipping name ``ethanol'' also include Special Provision 24 because
distilled spirits can be shipped under either ``alcoholic beverages''
or ``ethanol''. RSPA is not accepting this request. As the commenter
noted, the addition of Special Provision 24 is simply a procedural
modification of the existing classification procedure for alcoholic
beverages. RSPA considers this commenter's request outside the scope of
this rulemaking.
RSPA received a comment requesting that the shipping name
``polystyrene beads expandable evolving flammable vapors'', be retained
for domestic transportation. The commenter noted that the name had only
been required since October 1, 1993, and that it is not cost-efficient
to change in such a short period of time. RSPA is not accepting this
request but believes that the lengthy transition period should offset
any additional cost that may be incurred by the shipper.
Several comments were received that objected to the proposal to
remove from the HMT the entry ``Propellant explosive, solid, NA0274,
1.3C''. These commenters requested that this entry be retained because
it allowed them to ship these 1.3C explosives by cargo only aircraft.
RSPA is not adopting this suggestion and is removing this entry from
the HMT. RSPA believes that there is not sufficient justification to
create a domestic exception for Division 1.3 substances or to allow
these explosive substances to be transported by cargo only aircraft
when no other Division 1.3 substance is allowed to be transported by
aircraft.
Several comments were received regarding the shipping name
``azodicarbonamide'', a self-reactive material. Commenters believed
that listing this material was ``superfluous'' considering the new
classification scheme for self-reactive materials. RSPA concurs and has
removed this entry from the HMR.
One commenter requested several editorial changes to the shipping
name ``Jet perforating guns, charged, without detonator'', which are
adopted in this final rule. However, one suggestion, to remove the
words ``without detonator'' from the shipping description, is not
adopted. The commenter stated that packing method US006 allows
detonators to be transported in jet perforating guns; therefore, the
words ``without detonator'' should be removed from the shipping name.
However, US006 only allows detonators to be transported with, not in,
jet perforating guns.
RSPA received comments disagreeing with the removal of the shipping
name ``Petroleum oil''. Commenters stated that the name was important
for compliance with the Oil Pollution Act requirements in 49 CFR Part
130, and requested that a domestic shipping description be added. RSPA
concurs and is retaining the proper shipping name ``Petroleum oil''
with an identification number ``NA1270''.
One commenter suggested that RSPA provide a non-bulk packaging
exception for ``Resin solution'' comparable to the exception provided
for paint under Sec. 173.173 of the HMR. The commenter claimed that an
exception from the performance packaging requirements is provided for
certain resin solutions under the UN Recommendations and the IMDG Code.
The commenter stated that U.S. companies need the exception for Resin
solutions to compete in the international marketplace. RSPA agrees with
the commenter's suggestion and is adding in the Sec. 172.101 Table for
the entry ``Resin solution'', in Column 8A, ``Sec. 173.173''. RSPA also
is amending the section heading and the introductory text of paragraph
(b) of Sec. 173.173 to include resins.
In the notice, RSPA proposed to add several generic proper shipping
names including the words, ``organic'', ``inorganic'', ``acid'', or
``base''. In addition, RSPA proposed new identification numbers for
generic shipping descriptions for liquefied gases. RSPA received
several comments on these proposals. Many of the commenters were
opposed to these new terms claiming that the information would not
provide any additional information to emergency responders and would be
very costly to implement. If adopted, commenters requested that RSPA
provide guidance on the definition of these terms. One commenter
suggested that ASTM Test Methods D-664 and D-2896 should be used to
determine if a material is an acid or a base. Comments were received
that supported the use of these terms, and RSPA received numerous
comments supporting international harmonization of transportation
regulations.
RSPA understands the concerns expressed by those commenters that
terms such as ``inorganic'' and ``organic'' provide little useful
information to emergency responders. However, RSPA believes that more
harm and confusion would be caused by adopting different shipping names
for domestic and international transportation for these numerous
generic shipping descriptions than would be caused if these shipping
names were adopted. Therefore, RSPA is adopting, as proposed, and
without domestic exceptions, the generic shipping descriptions bearing
the words ``inorganic'', ``organic'', ``acid'', and/or ``base'' and the
new identification number for liquefied gases. In addition, the
extended transition period being provided in this final rule will give
industry adequate time to revise their shipping papers and package
markings. The following provides some general guidance on the
definition of these terms.
For acids and bases, RSPA believes that the ASTM methods referenced
by commenters would be an acceptable method for determining if a
material is an acid or base. However, RSPA is not requiring persons to
use those methods. For an aqueous solution, the use of pH and litmus
paper is an acceptable method for determining if a material is an acid
or base. For a non-aqueous solution, shippers must use their knowledge
of the constituents of the material and make a determination as to
whether a material is an acid or base. For a material that is neither
an acid nor a base, the correct shipping name will be ``Corrosive
liquid, n.o.s.''. The definition of an ``organic'' is a compound with
carbon atoms bonded to other carbon, nitrogen or hydrogen atoms (e.g.,
amines, acid chlorides, acetic acids, phenols). An ``inorganic'' is any
pure element or any compound that does not have carbon atoms bonded to
other carbon, nitrogen or hydrogen atoms (e.g., sodium hydroxide,
sulfuric acid). Shippers must make a determination, based on the
constituents of their material, if their material is inorganic or
organic.
In the NPRM, RSPA proposed to add three new proper shipping names
to the HMT for samples of non-pressurized gases in Divisions 2.1 and
2.3. In response to the NPRM, one commenter urged RSPA to remove the
proposed entries for gas samples in the HMT. The commenter claimed that
non-pressurized flammable gases are not subject to the HMR and that
including gas samples under the HMR would increase shipping costs and
delay shipments. The commenter also recommended that RSPA adopt
criteria in Sec. 173.115 to limit the definition of Division 2.1 to
gases which exert a pressure of 280 kPa (41 psia) or greater at 20
deg.C (68 deg.F). Alternatively, the commenter recommended that RSPA
add a packaging exception for gas samples in quantities less than two
liters in each receptacle and remove proposed Special Provision 35 and
the non-bulk packaging references to Secs. 173.302 and 173.304 for the
gas sample entries in the HMT.
RSPA disagrees with the commenter's recommendation to remove the
entries for gas samples because these materials are currently regulated
under the HMR. The commenter's understanding of Division 2.1 criteria
is incorrect. Non-pressurized gas samples are presently subject to the
HMR if they meet the hazard class criteria in Sec. 173.115. Division
2.1 or 2.3 materials are not limited to gases which exert a pressure of
at least 280 kPa (41 psi) at 20 deg.C (68 deg.F). RSPA simply is
providing more descriptive proper shipping names for non-pressurized
gas samples. Therefore, RSPA is adopting the gas sample entries as
proposed. In addition, RSPA is retaining the non-bulk packaging
references in the Table for persons who want to ship larger quantities
of gas samples. However, RSPA agrees with the commenter concerning the
need to address gas samples in the exceptions and is removing proposed
Special Provision 35 and revising the provisions in Sec. 173.306 to
specifically address gas samples.
One commenter submitted data indicating that ``Diphenylmethane-
4,4'diisocyanate'' does not meet Division 6.1, Packing Group III
criteria under the HMR. Another commenter verified that ``2-Bromo-2-
nitropropane-1,3-diol'' does not meet the criteria for Division 6.1
under the HMR. The commenter requested that RSPA add an ``I'' in the
first column of the Sec. 172.101 Table for the entry ``2-Bromo-2-
nitropropane-1,3-diol'' to distinguish it from a domestically regulated
hazardous material. RSPA agrees that these materials are not hazardous
materials in domestic transportation. However, to facilitate
international transportation, RSPA is retaining the entries for
Diphenylmethane-4,4'diisocyanate and 2-Bromo-2-nitropropane-1,3-diol
and adding an ``I'' in the first column to indicate that these
materials are regulated in international transportation.
One commenter requested that RSPA remove the poison inhalation
hazard (PIH) designation for ``Allyl isothiocyanate, stabilized''
because the material does not meet the PIH criteria in Sec. 173.133.
Based on supporting data submitted by the commenter, RSPA agrees with
the assessment and is removing the PIH designation for Allyl
isothiocyanate, stabilized, in the HMT.
RSPA received one comment regarding the hazard zone designation for
``Allyl chloroformate.'' The commenter provided information which
indicates that the hazard zone for allyl chloroformate should be Zone B
and not Zone A. RSPA agrees that the hazard zone designation for allyl
chloroformate should be ``Zone B'' and is amending the hazard zone
designation for this material rather than issuing an approval under
Sec. 172.101(l)(2). In addition, data provided by a commenter indicates
that the hazard zone for trichloroacetyl chloride is Zone B, not Zone
A, as previously indicated on the HMT. Therefore, RSPA is modifying
this shipping description to indicate that trichloroacetyl chloride is
a Hazard Zone B PIH material.
One commenter objected to RSPA's proposal to add a proper shipping
name for ``Pentachlorophenols'' classed as Division 6.1, Packing Group
II when an existing entry ``Chlorophenols, solid'' carries a Division
6.1, Packing Group III classification. The commenter contended that the
``Keep Away From Food'' label adequately conveys the nature of hazard
posed by these materials. RSPA added ``Pentachlorophenols'' in the HMT
and designated it as Division 6.1, PG II based on the UN
Recommendations. However, according to Sec. 172.101(c)(12), if it has
been determined that a material meets the definition of a hazard class,
packing group, or hazard zone other than the class, packing group, or
hazard zone shown in association with the proper shipping name, another
shipping description shall be selected that appropriately describes the
material. Therefore, RSPA is adding the entry for Pentachlorophenols as
proposed.
RSPA received several comments requesting that Maneb and Maneb
preparations that do not meet the definition of any hazard class, be
excepted from the HMR when transported by motor vehicle, rail car, or
aircraft. Commenters noted that Special Provision 140 of the UN
Recommendations allows the competent authority to deregulate Maneb. In
addition, the commenters noted that exemption DOT E-11037 allows this
material to be shipped unregulated. RSPA concurs and has added Special
Provision 53 to Maneb (UN2968) which states that Maneb not meeting the
definition of Division 4.3 or any other hazard class is not subject to
the HMR when transported by aircraft, motor vehicle, or rail car.
RSPA received a comment requesting that it add the shipping
description ``Dangerous goods in apparatus/ machinery'' to the HMT. The
commenter stated that this shipping name, which is listed in the ICAO
Technical Instructions but not the UN Recommendations, is very sensible
and will be beneficial to both shippers and carriers alike. RSPA agrees
that this name would be beneficial to the industry but believes that
the packaging provision, for both air and ground transport, should be
subject to appropriate public notice and comment. Therefore, RSPA is
not adopting, in this rule, this commenter's suggestion to add the
shipping name ``Dangerous goods in apparatus/machinery'' to the HMT.
However, shipments described and prepared in accordance with the ICAO
Technical Instructions and Sec. 171.11 may be transported domestically
by aircraft and by motor vehicle either before or after being
transported by aircraft.
One commenter suggested that RSPA incorporate an IM tank
authorization into the HMR for 2-Ethyhexyl-
chloroformate equivalent to the tank authorization under the IMDG Code
and under an approval (SA-9407006) issued by OHMS. RSPA is adding
Special Provision T12 in Column 7 of the HMT for 2-
Ethyhexylchloroformate which eliminates the need for an approval.
In the NPRM, RSPA proposed to add subsidiary labeling requirements
for Class 2 materials. As a result, subsidiary labels were added in
Column 6 of the HMT for Class 2 materials, including Chlorine, meeting
more than one hazard class. RSPA proposed to add Corrosive and Oxidizer
subsidiary labels for Chlorine. One commenter contended that the yellow
Oxidizer label is more visible than the black and white Poison gas
label and may cause confusion in determining the primary hazard. RSPA
has determined that the Corrosive subsidiary label is necessary because
of the material's effects on skin tissue; however, RSPA is removing the
Oxidizer subsidiary label for Chlorine because it is unnecessary.
One commenter objected to the proposal to change the order of the
descriptive words in the basic shipping description to coincide with
the precedence of hazards. The commenter cited limited safety benefit
and high costs as reasons not to adopt the proposed changes. Though
RSPA agrees that these changes have limited safety benefit, RSPA
believes that adoption of a domestic-only name for these descriptions
is not justified. In addition, most of the costs the commenter cited
should be ameliorated by the lengthy transition period being provided.
RSPA proposed to add new entries for solid materials containing
flammable, corrosive, or toxic liquids in the NPRM. One commenter
requested clarification on whether these new entries included solid
materials that were previously not regulated. The commenter stated that
RSPA's intent was not adequately clarified in the special provisions
designated for the materials. Another commenter requested clarification
of the phrase ``packaging must correspond to a design type that has
passed a leakproof test at the Packing Group II level'' in Special
Provisions 47, 48, and 49.
RSPA is adding the entries for solid materials containing
flammable, corrosive, or toxic liquids in this rule to provide shippers
with additional generic entries to describe solids that contain liquids
that are either flammable, corrosive, or toxic (e.g., soil contaminated
with toxic material from an underground storage tank) and have not been
tested to verify the hazard class. However, if free liquid is present
at the time the material is loaded, these shipping descriptions may not
be used. The new entries are not intended to regulate non-hazardous
materials (i.e., those materials that do not meet any hazard class
definition). The phrase regarding the leakproof test is intended to
have these materials transported in a packaging whose ``design type''
has been leakproof tested. Therefore, only the design, not every
packaging, need be subjected to the leakproof test.
One commenter objected to RSPA's proposed amendment to require a
CORROSIVE subsidiary label in addition to a POISON GAS primary label on
packages containing dry sulfur dioxide. The commenter stated that the
material is not corrosive to carbon or stainless steel, and the
commenter expressed concern that addition of a CORROSIVE label will
require more frequent cargo tank inspections under Sec. 180.407.
In the context of Sec. 180.407, corrosive lading means that a
material has a corrosive effect on a cargo tank. It is the shipper's
responsibility to determine whether a material is corrosive to the
material of construction of a cargo tank. Because of the corrosive
effects dry sulfur dioxide has on skin tissue, RSPA is adopting the
Class 8 subsidiary label as proposed.
RSPA received several comments requesting new bulk packagings for
chlorosulfonic acid, dimethyl sulfate, and titanium tetrachloride. RSPA
is not accepting these comments because they are beyond the scope of
this rulemaking.
RSPA is making several changes to the IBC authorizations in the HMT
based on petitions for reconsideration received to Docket HM-181E. RSPA
will handle all other petitions received to Docket HM-181E in a future
Federal Register publication. The following materials will be allowed,
through a revised Special Provision B110, to be transported in IBCs
authorized in Sec. 173.242(d): UN2030, UN2014, U3149, UN2078, UN1790,
UN2076, UN2022. In addition, Special Provision B100, which does not
allow the use of IBCs, is removed from ``Chloropicrin mixtures, n.o.s,
6.1, UN1583, Packing Group III''. Special Provision B53 also is revised
to indicate that it does not apply to IBCs.
The following tables identify those entries that are: (1) Deleted;
(2) significantly changed; or (3) added. An entry is considered
significantly changed if there is a change in (1) the shipping name,
(2) IM tank authorization, (3) subsidiary labeling, (4) classification,
or (5) packaging. Each entry is identified by its identification number
which, along with the cross-reference table appearing in the HMR prior
to the HMT, can be used to identify the affected entries. Unless
otherwise indicated, the identification numbers are ``UN'' numbers:
List of Entries Deleted From the Sec. 172.101 Table
----------------------------------------------------------------------------------------------------------------
NA1086................. 0416 **1270 1705 2497 3030-3043
NA2255*................ .............. .............. .............. .............. .......................
NA2810*................ 1118 1271 1864 2553 NA9259*
NA2811*................ 1255 1584 2207 2860 NA9276*
0273................... 1256 1592 2229 2951-2955 .......................
0274................... 1257 1703 2449 2970-2973 .......................
----------------------------------------------------------------------------------------------------------------
*See new entry added by the UN recommendations.
**See new NA number (NA1270).
List of Entries Significantly Changed
--------------------------------------------------------------------------------------------------------------------------------------------------------
NA1760.................................. 1322 1474 1731 2006 2379 2534 2818
NA1986.................................. 1325 1475 1740 2022 2382 2557 2821
NA2922.................................. 1328 1477 1747 2029-2030 2383 2564 2823
1030.................................... .............. .............. .............. .............. .............. .............. ..............
1106.................................... 1334 1481 1750 2047 2386 2571 2826
1125.................................... 1336 1482 1751 2051 2389 2583 2834
1135.................................... 1337 1483 1752 2076 2399 2584 2837
1143.................................... 1344 1489 1755 2189 2401 2585 2841
1154.................................... 1348 1502 1757 2194 2407 2586 2845
1158.................................... 1349 1506 1761 2195 2417 2604 2846
1160.................................... 1350 1508 1773 2196 2418 2606 2857
1162.................................... 1353 1511 1783 2198 2420 2610 2869
1167.................................... 1354 1517 1787 2206 2421 2616 2874
1198.................................... 1355 1549 1788 2209 2427 2619 2881
1202.................................... 1356 1564 1789 2211 2428 2626 2904-2905
1210.................................... 1357 1566 1809 2218 2429 2670 2921-2930
1214.................................... 1361 1570 1811 2219 2430 2677 2938
1221.................................... 1364 1588 1814 2232 2438 2679 2945-2946
1228.................................... 1373 1589 1816 2242 2445 2681 2965
1235.................................... 1378 1590 1819 2251 2461 2684 2985-2988
1265.................................... 1395 1599 1824 2257 2478 2693 2991-3021
1268.................................... 1402 1601 1888 2258 2482 2733 3024-3027
1274.................................... 1408 1602 1908 2260 2484 2734 3049-3050
1277.................................... 1409 1605 1922 2264 2485 2735 3065-3066
1282.................................... 1415 1613 1952 2267 2495 2741 3071
1289.................................... 1418 1614 1953 2270 2501 2742 3079
1296.................................... 1420 1648 1954 2276 2502 2757-2787 3084
1297.................................... 1428 1660 1955 2332 2517 2789 3086-3088
1298.................................... 1454 1708 1956 2337 2521 2796 3094
1308.................................... 1455 1715 1975 2343 2526 2801 3096
1310.................................... 1458 1719 1986 2351 2529 2810 3098-3100
1320.................................... 1459 1722 1988 2359 2530 2813 3119-3150
1321.................................... 1462 1724 1992 2361 2533 2817 1717
--------------------------------------------------------------------------------------------------------------------------------------------------------
List of Additions to the Sec. 172.101 Table
------------------------------------------------------------------------
UN # Shipping name
------------------------------------------------------------------------
0491. CHARGES, PROPELLING.
0492. SIGNALS, RAILWAY TRACK, EXPLOSIVE.
0493. SIGNALS, RAILWAY TRACK, EXPLOSIVE.
0494. JET PERFORATING GUNS, CHARGED, oil well, without detonator.
0495. PROPELLANT, LIQUID.
0496. OCTONAL.
0497. PROPELLANT, LIQUID.
0498. PROPELLANT, SOLID.
0499. PROPELLANT, SOLID.
1851. MEDICINE, LIQUID, TOXIC, N.O.S.
1990. BENZALDEHYDE.
3155. PENTACHLOROPHENOL.
3156. COMPRESSED GAS, OXIDIZING, N.O.S.
3157. LIQUEFIED GAS, OXIDIZING, N.O.S.
3158. GAS, REFRIGERATED LIQUID, N.O.S.
3159. 1,1,1,2-TETRAFLUOROETHANE.
3160. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S.
3161. LIQUEFIED GAS, FLAMMABLE, N.O.S.
3162. LIQUEFIED GAS, TOXIC, N.O.S.
3163. LIQUEFIED GAS, N.O.S.
3164. ARTICLES, PRESSURIZED PNEUMATIC or HYDRAULIC (containing non-
flammable gas).
3166. ENGINES, INTERNAL COMBUSTION, including when fitted in machinery
or vehicles.
3167. GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated
liquid.
3168. GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not
refrigerated liquid.
3169. GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated
liquid.
3170. ALUMINIUM PROCESSING BY-PRODUCTS.
3171. BATTERY-POWERED VEHICLE or BATTERY-POWERED EQUIPMENT (wet
battery).
3174. TITANIUM DISULPHIDE.
3175. SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S.
3176. FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S.
3178. FLAMMABLE SOLID, INORGANIC, N.O.S.
3179. FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S.
3180. FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S.
3181. METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.
3182. METAL HYDRIDES, FLAMMABLE, N.O.S.
3183. SELF-HEATING LIQUID, ORGANIC, N.O.S.
3184. SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S.
3185. SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S.
3186. SELF-HEATING LIQUID, INORGANIC, N.O.S.
3187. SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S.
3188. SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S.
3189. METAL POWDER, SELF-HEATING, N.O.S.
3190. SELF-HEATING SOLID, INORGANIC, N.O.S.
3191. SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S.
3192. SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.
3194. PYROPHORIC LIQUID, INORGANIC, N.O.S.
3200. PYROPHORIC SOLID, INORGANIC, N.O.S.
3203. PYROPHORIC ORGANOMETALLIC COMPOUND, N.O.S.
3205. ALKALINE EARTH METAL ALCOHOLATES, N.O.S.
3206. ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S.
3207. ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND
DISPERSION, WATER-REACTIVE, FLAMMABLE, N.O.S.
3208. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
3209. METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S.
3210. CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3211. PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3212. HYPOCHLORITES, INORGANIC, N.O.S.
3213. BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3214. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3215. PERSULPHATES, INORGANIC, N.O.S.
3216. PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3217. PERCARBONATES, INORGANIC, N.O.S.
3218. NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3219. NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3220. PENTAFLUOROETHANE.
3221. SELF-REACTIVE LIQUID TYPE B.
3222. SELF-REACTIVE SOLID TYPE B.
3223. SELF-REACTIVE LIQUID TYPE C.
3224. SELF-REACTIVE SOLID TYPE C.
3225. SELF-REACTIVE LIQUID TYPE D.
3226. SELF-REACTIVE SOLID TYPE D.
3227. SELF-REACTIVE LIQUID TYPE E.
3228. SELF-REACTIVE SOLID TYPE E.
3229. SELF-REACTIVE LIQUID TYPE F.
3230. SELF-REACTIVE SOLID TYPE F.
3231. SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED.
3232. SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED.
3233. SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED.
3234. SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED.
3235. SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED.
3236. SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED.
3237. SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED.
3238. SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED.
3239. SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED.
3240. SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED.
3241. 2-BROMO-2-NITROPROPANE-1,3-DIOL.
3242. AZODICARBONAMIDE.
3243. SOLIDS CONTAINING TOXIC LIQUID, N.O.S.
3244. SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S.
3246. METHANESULPHONYL CHLORIDE.
3247. SODIUM PEROXOBORATE, ANHYDROUS.
3248. MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.
3249. MEDICINE, SOLID, TOXIC, N.O.S.
3250. CHLOROACETIC ACID, MOLTEN.
3251. ISOSORBIDE-5-MONONITRATE.
3252. DIFLUOROMETHANE.
3253. DISODIUM TRIOXOSILICATE, PENTAHYDRATE.
3254. TRIBUTYLPHOSPHANE.
3255. tert-BUTYL HYPOCHLORITE.
3256. ELEVATED TEMPERATURE LIQUID, N.O.S. with flash point above 37.8
deg.C, at or above its flash point.
3257. ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 deg.C and
below its flash point.
3258. ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 deg.C.
3259. AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE,
N.O.S.
3260. CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
3261. CORROSIVE, SOLID, ACIDIC, ORGANIC, N.O.S.
3262. CORROSIVE, SOLID, BASIC, INORGANIC, N.O.S.
3263. CORROSIVE, SOLID, BASIC, ORGANIC, N.O.S.
3264. CORROSIVE, LIQUID, ACIDIC, INORGANIC, N.O.S.
3265. CORROSIVE, LIQUID, ACIDIC, ORGANIC, N.O.S.
3266. CORROSIVE, LIQUID, BASIC, INORGANIC, N.O.S.
3267. CORROSIVE, LIQUID, BASIC, ORGANIC, N.O.S.
3268. AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRE-TENSIONERS
or SEAT-BELT MODULES.
3269. POLYESTER RESIN KIT.
3270. NITROCELLULOSE MEBRANE FILTERS.
3271. ETHERS, N.O.S.
3272. ESTERS, N.O.S.
3273. NITRILES, FLAMMABLE, TOXIC, N.O.S.
3274. ALCOHOLATES SOLUTION, N.O.S., in alcohol.
3275. NITRILES, TOXIC, FLAMMABLE, N.O.S.
3276. NITRILES, TOXIC, N.O.S.
3277. CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.
3278. ORGANOPHOSPHORUS COMPOUND, TOXIC N.O.S.
3279. ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S.
3280. ORGANOARSENIC COMPOUND, N.O.S.
3281. METAL CARBONYLS, N.O.S.
3282. ORGANOMETALLIC COMPOUND, TOXIC N.O.S.
3283. SELENIUM COMPOUND, N.O.S.
3284. TELLURIUM COMPOUND, N.O.S.
3285. VANADIUM COMPOUND, N.O.S.
3286. FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S.
3287. TOXIC LIQUID, INORGANIC, N.O.S.
3288. TOXIC SOLID, INORGANIC, N.O.S.
3289. TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.
3290. TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S.
3292. BATTERIES, CONTAINING SODIUM, or CELLS, CONTAINING SODIUM.
3293. HYDRAZINE,AQUEOUS SOLUTION with not more than 37% hydrazine, by
mass.
3294. HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45%
hydrogen cyanide.
3295. HYDROCARBONS, LIQUID, N.O.S.
3296. HEPTAFLUOROPROPANE.
3297. ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more
than 8.8% ethylene oxide.
3298. ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than
7.9% ethylene oxide.
3299. ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than
5.6% ethylene oxide.
3300. ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87%
ethylene oxide.
3301. CORROSIVE LIQUID, SELF-HEATING, N.O.S.
------------------------------------------------------------------------
Appendix B to Sec. 172.101. In the NPRM, RSPA proposed the addition
of two notes which are consistent with recent IMO decisions. The first,
Note 4, allows a material meeting criteria for a marine pollutant in
the IMDG Code but not listed in Appendix B of Sec. 172.101, to be
transported as a marine pollutant. Note 5 allows the Associate
Administrator for Hazardous Materials Safety to except from HMR
requirements a material listed in Appendix B of the HMR that does not
meet the IMDG Code criteria for a marine pollutant. In addition, RSPA
proposed to amend the HMR's List of Marine Pollutants by adding or
removing a number of materials. Commenters to these proposals generally
supported the proposed changes. One commenter questioned the addition
of Notes 4 and 5. However, the majority of commenters addressing these
proposed changes supported the addition of these notes. RSPA is
adopting these notes for consistency with IMDG Code provisions. Note 4
is consistent with the 27th Amendment to the IMDG Code, which allows
the use of criteria for designating marine pollutants. Note 5 provides
flexibility so that if a substance does not meet the IMDG Code criteria
for a marine pollutant the Associate Administrator may except it from
the HMR marine pollutant requirements.
Other commenters thought it more appropriate to address these
proposals under Docket HM-211; Marine Pollutants. RSPA disagrees;
handling marine pollutant issues in Docket HM-215A will facilitate the
harmonization of the HMR with the IMDG Code in conjunction with the
January 1, 1995 implementation date for the 27th Amendment to that
Code.
Section 172.102. Special Provisions 24, 26, 32, 34-37, 39, 40, 43-
52 and 54 are added to Sec. 172.102, Special Provisions 16, 23, B53,
and B110 are revised, and Special Provisions 25, 41, and A33 are
removed. These special provisions relate to certain materials'
classifications and any special packaging requirements that are
necessary to safely transport these materials.
Section 172.203. One commenter addressing proposed changes to the
marine pollutant provisions requested relief from certain shipping
paper requirements for specific hydrocarbon compounds which fall under
the requirements of 49 CFR Part 130, which prescribes prevention and
response requirements for the transportation of oil. This commenter
believed that petroleum products subject to Part 130 should be exempt
from the requirement in Sec. 172.203(l) to indicate on a shipping paper
that the material is also a marine pollutant. RSPA partially agrees
with the commenter that hazardous materials that are subject to 49 CFR
Part 130 should not be subject to the marine pollutant shipping paper
requirements of Sec. 172.203(l)(2). Therefore, RSPA is revising
Sec. 172.203(l)(2) to except petroleum products that are subject to the
provisions of 49 CFR Part 130 when transported in bulk by road or rail.
A new paragraph (o) is added to require additional information to
be included in the shipping paper description for organic peroxides and
self-reactive materials. In addition, paragraphs (k) and (m) are
revised based on changes to the HMT. In paragraph (k), the list of
shipping names requiring technical names is revised based on changes to
the HMT. In paragraph (m), the reference to ``Poison'' is modified to
include an alternative reference to ``Toxic.''
Section 172.204. RSPA proposed to amend the certification statement
in paragraph (a)(2) by adding ``placarded'' as a condition for
declaring a shipment to be properly prepared for transportation. The
intent of this proposed change is to provide consistency with
international declarations and enable one shipper certification
statement to be used for both domestic and export shipments so that
different preprinted forms are not needed. Commenters supported this
proposed change for certifying an international shipment, but were
divided as to whether it is appropriate for domestic transportation.
Several commenters suggested that paragraph (a)(1) be deleted because
it is no longer required. Other commenters believed that paragraph
(a)(1) should be retained for domestic purposes without the addition of
``placarded'' to the certification. According to these commenters,
certifying that a shipment has been properly placarded is inconsistent
with the provisions in Sec. 172.506 that a shipper must offer and a
carrier must affix the required placards for transportation by highway.
RSPA believes that the addition of ``placarded'' in the certification
would not apply to shipments for which the offeror has no control over
affixing placards. However, in this rule, RSPA is retaining paragraph
(a)(1) for domestic purposes and is adopting paragraph (a)(2) as
proposed for use in either domestic or international transportation. In
addition, paragraph (a)(2) is amended by removing the provision to
indicate the mode of transportation in the shipper's certification.
This revision is consistent with the multimodal approach adopted in the
UN Recommendations, ICAO and IMDG Code.
Section 172.320. Section 172.320 is adopted as proposed to
authorize all product codes that are traceable to an ``EX-number'' to
be marked on boxes of explosives in lieu of the EX number.
Section 172.325. The identification number ``9259'' shown in the
HOT marking illustration in paragraph (c) is revised to read ``3257''
to reflect the new UN number assigned to ``Elevated temperature
material, liquid, n.o.s.''
Section 172.400a. A new paragraph (c) is adopted as proposed to
state that a subsidiary POISON label is not required on a package
bearing a primary CORROSIVE label if the poison hazard of the material
inside is based solely on corrosive destruction of tissue and is not
due to systemic poisoning. In addition, based on the merit of comments,
RSPA is adding a new paragraph (d) to allow the use of a POISON label
in place of a KEEP AWAY FROM FOOD label for domestic transportation of
Division 6.1 PG III materials.
Section 172.402. Paragraph (a)(2) is adopted as proposed to
incorporate certain subsidiary labeling provisions in the subsidiary
labeling table in paragraph (a)(2). These provisions require subsidiary
hazard labeling for Class 8 Packing Group III materials and Class 3
Packing Group III materials except for Class 3 Packing Group III
materials having a flash point at or above 38 deg.C (100 deg.F) when
transported by highway or rail. In addition, paragraph (a)(1) is
revised to clarify that if Column 6 of the Sec. 172.101 Table indicates
a subsidiary label for which there is an exception in paragraph (a)(2)
of Sec. 172.402, the exception applies. This revision is based on the
merit of comments urging consistency in subsidiary labeling provisions.
In the NPRM, RSPA discussed a change adopted in the eighth revised
edition of the UN Recommendations which removed the STOW AWAY FROM
FOODSTUFFS label and placard and replaced them with the POISON label
and placard for materials having either a primary or secondary hazard
in Division 6.1 Packing Group III. As noted previously, RSPA is
addressing this issue in a rulemaking action under Docket HM-217;
however, RSPA believes that a package containing a material meeting
Division 6.1 Packing Group III criteria as either a primary or
subsidiary hazard should bear a label which communicates a warning that
the material must be kept separate from foodstuffs when transported
domestically by any mode. This was discussed in the preamble of the
notice, and the proposed changes to the Sec. 172.101 Table included the
addition of a KEEP AWAY FROM FOOD label in Column 6 for each affected
entry. However, RSPA inadvertently neglected, in the Sec. 172.402(a)(2)
proposed regulatory text changes, to remove the ``N'' at the
intersection of row ``III'' and column ``6.1'' and replace it with an
``X''. Commenters on this issue opposed any required domestic labeling
of materials having a subsidiary hazard of Division 6.1 Packing Group
III. Both HMAC and the Conference on Safe Transportation of Hazardous
Articles (COSTHA) stated that any proposed changes should be deferred
for consideration under Docket HM-217. In addition, COSTHA noted
potential changes to UN toxicity classification criteria and claimed
that adopting harmonized toxicity criteria will decrease the number of
liquids in Division 6.1 Packing Group III. COSTHA encouraged RSPA not
to revise provisions for the labeling and placarding of Division 6.1
Packing Group III materials until the UN and DOT have completed
harmonization efforts.
The preamble section review in the NPRM clearly expressed RSPA's
intent to revise Sec. 172.402(a)(2) to replace the ``N'' with an ``X''
(which would have the effect of requiring subsidiary labeling for
materials having a Division 6.1 Packing Group III subsidiary hazard).
RSPA believes that materials having a primary or secondary hazard of
Division 6.1 PG III pose a risk not only of food contamination, but
also dermal and inhalation hazards sufficient to warrant hazard
communication. Therefore, RSPA is adopting the requirement for
subsidiary hazard labeling for Division 6.1 Packing Group III materials
when transported in any mode.
Also, new subsidiary labeling requirements for Class 2 materials
are added as paragraphs (f) and (g). Several commenters requested
clarification of proposed paragraph (f) regarding a Division 2.2
material that meets the definition of an oxidizer. RSPA is clarifying
in this final rule that a Division 2.2 material may meet the definition
of an oxidizing gas, as defined in Sec. 171.8.
Section 172.411. A requirement specifying a minimum height for the
compatibility group letter on certain EXPLOSIVE labels is removed.
Section 172.416. Section 172.416 is revised to allow the use of the
words ``TOXIC GAS'' on the POISON GAS label.
Section 172.430. Section 172.430 is revised to allow the use of the
word ``TOXIC'' on the POISON label.
Section 172.540. Section 172.540 is revised to allow the use of the
words ``TOXIC GAS'' on the POISON GAS placard.
Section 172.547. Section 172.547 is revised to reduce the size
requirement for the word ``spontaneously'' in the ``SPONTANEOUSLY
COMBUSTIBLE'' placard from 25 mm to 12 mm.
Section 172.554. Section 172.554 is revised to allow the use of the
word ``TOXIC'' on the POISON placard.
Part 173
Section 173.2a. Consistent with the UN Recommendations, the
Precedence of Hazards Table is adopted as proposed to account for
combinations of Division 4.2 and Class 8 materials which currently are
denoted as impossible combinations. In addition, two new notes are
added at the end of the paragraph (b) table. Note 1 specifies that, for
materials having multiple risks which are not listed by technical name
in the Sec. 172.101 Table, the most stringent packaging group must be
used. Note 2 is added to specify the class assignment for a material
which meets the definition of Class 8 and has an inhalation toxicity by
dusts and mists at the Packing Group I level.
Section 173.21. A revised reference to the Sec. 173.224 self-
reactive materials table is adopted as proposed to reflect changes to
the table.
Section 173.22. Revised paragraph (a)(3)(i) is adopted as proposed
to indicate that the marking appearing on the bottom of a metal or
plastic drum in accordance with Sec. 178.503 is not an acceptable means
of determining if the drum is an authorized packaging. Paragraph (a)(2)
is revised to recognize packagings manufactured outside the U.S. as
provided in Sec. 173.24(d)(2), and paragraph (a)(4) is revised to limit
notification provisions to packagings manufactured in the U.S.
Section 173.24. Paragraph (d) is adopted as proposed to specify the
conditions under which foreign-manufactured packagings may be used. The
revision stipulates the conditions under which foreign-manufactured UN
packagings may be filled and used in the U.S. Only packagings from
countries affording the same degree of acceptance to U.S.-manufactured
packagings may be used. Several commenters did not realize that this
proposed revision applies to empty packagings being imported into the
U.S. for filling. They thought that the proposal applied to packagings
already filled with a hazardous material before being imported into the
U.S. Provisions concerning the import of filled packagings are
contained in Secs. 171.11, 171.12, and 171.12a and are not amended in
this final rule. Other commenters expressed concern as to the ability
of U.S. shippers to determine which countries recognize U.S.
packagings. Two commenters suggested that RSPA periodically publish a
notice in the Federal Register, listing those countries that do not
recognize U.S. manufactured UN standard packagings. Several commenters
objected to the issue of reciprocity being addressed in a rulemaking
action, claiming this is a political issue. One alternative suggested
by commenters is to consider and resolve such issues at the UN or by
the competent authorities of the countries involved. RSPA agrees that
every effort should be made by the competent authority of each country
involved to resolve reciprocity issues. RSPA would only resort to
declaring a country as not providing reciprocal treatment for UN
standard packaging manufactured in the U.S. in a Federal Register
notice after exhausting attempts to resolve differences through
negotiation.
In addition, revised paragraph (e)(4)(ii) is adopted as proposed to
prohibit hazardous materials from being packed or mixed with other
hazardous or nonhazardous materials in the same outer packaging if such
materials are capable of reacting with each other and causing the
evolution of ``asphyxiant gases.''
Section 173.25. Paragraph (a) is adopted as proposed to refer to
the definition of ``Overpack'' in Sec. 171.8, which also is amended to
provide examples of suitable overpacks. Commenters generally supported
the proposed revision; however, based on several comments, there
appears to be confusion regarding the current provisions for overpacks,
specifically concerning the marking, labeling and use of shrink- or
stretch-wrapped pallets. Currently, shrinkwrap is considered an
overpack when consolidating packages on a pallet. The overpack must be
marked and labeled for each hazardous material contained therein unless
markings and labels representative of each hazardous material are
visible. If packages are stacked and banded on a pallet, the packages
should be positioned, when possible, so that the markings and labels
are visible on the outside of the stack.
Paragraph (b) is added as proposed to authorize shrink-wrapped or
stretch-wrapped trays as outer packagings for inner packagings prepared
under limited quantity or consumer commodity provisions if the
completed package is capable of meeting the Packing Group III
performance level and the gross weight of the package does not exceed
20 kg. This proposal generated opposition from carriers, who claimed
that shrink wrap as an outer packaging does not provide adequate
protection from the rigors of transportation and should not be
authorized. However, at least one of these commenters was referring to
a shrink-wrapped pallet rather than a package limited to 20 kg (44
pounds) gross weight. On the other hand, commenters such as COSTHA
strongly supported this proposal, but requested that RSPA maintain
consistency with the UN Recommendations by authorizing the use of
shrink-wrapped or stretch-wrapped trays as outer packagings without
imposing a requirement that these completed packagings be capable of
passing Packing Group III performance tests.
Section 173.28. RSPA is not adopting a proposed revision to
paragraph (b)(1), based on the merit of a comment suggesting the
sentence duplicates the provisions of Sec. 173.24(d) and should only
apply to the reuse of packagings required to meet performance
standards, not to the reuse of all packagings. The Association of
Container Reconditioners (ACR) urged RSPA to revise the footnote to the
table in paragraph (b)(4), to restore the minimum thicknesses to what
was required when the final rule was published on December 21, 1990.
ACR pointed out that in corrections and amendments made in 1991, the
footnote to the table in paragraph (b)(4) had been revised to allow
reuse of metal drums with a minimum wall thickness of 0.8 mm and
minimum head thickness of 1.1 mm. ACR asked that the note be revised to
reference minimum thicknesses of 0.82 mm and 1.09 mm. Since these
changes were not proposed in the NPRM, RSPA is not revising the minimum
thicknesses at this time; however, the number ``0'' has been added
after the last digit in each instance for clarity.
A commenter expressed confusion over the requirement for the
nominal or minimum thickness to be permanently marked on a packaging
that is to be reused. The commenter stated that it appeared that the
marking could be either the nominal or minimum thickness. Paragraph
(b)(4) has been revised to clarify that the nominal thickness is marked
on metal packagings, and the minimum thickness must be marked on
plastic packagings which are to be reused.
New paragraph (b)(7) is added to waive requirements for leaktesting
prior to each reuse to certain packagings used in limited operations.
The NPRM proposed to waive retesting requirements for stainless steel,
monel, or nickel drums, which are constructed with a thickness at least
one and one half times the minimum required by Sec. 173.28(b)(4), and
which are refilled with the same or similar compatible contents and
transported by a private carrier, contract carrier, or common carrier
in a transport vehicle or freight container used exclusively for such
service, within a distribution chain controlled by the offeror.
Commenters overwhelmingly supported RSPA's proposed paragraph
(b)(7). Numerous commenters suggested that RSPA extended the provisions
of paragraph (b)(7) to plastic drums in addition to stainless steel,
monel, and nickel drums. The commenters cited the high costs that would
be incurred by plastic drum users if leak testing were required prior
to each use. Many commenters stated that the leak test itself could
cause damage to plastic drums over time, due to the bulging of the
packaging caused by internal pressure. Commenters asked that RSPA
revise paragraph (b)(7) to be more consistent with the UN
Recommendations, which require leak testing for plastic drums only
after reconditioning.
RSPA recognizes that the UN Recommendations do not require a
packaging to be leakproofness tested before it is reused for transport,
but only after it is reconditioned. However, RSPA notes that the UN
Recommendations, at section 9.6.7.2., limit the period of use for
plastic drums and jerricans to five years from the date of manufacture.
The HMR do not currently place a limit on the period of use for plastic
drums. RSPA believes that under certain controlled conditions, plastic
drums can be used safely without leak testing prior to each reuse.
Upon further consideration of the leakproofness testing
requirements for plastic drums, RSPA has determined that the types of
damage to plastic drums caused by normal transportation stresses
include puncture, abrasion of plastic material, and loose or damaged
closures. RSPA believes that these types of damage can be detected by a
thorough visual examination by a person who is qualified to identify
such damage. RSPA also believes that damage to plastic drums from
abrasion, puncture, and damaged fittings can be minimized with careful
handling. For that reason, RSPA believes that plastic drums used in
distribution chains controlled by the offeror can be used safely
without leak testing prior to each reuse. However, damage caused by
incompatibility of the product being shipped with the plastic of the
drum would not be detected through an external visual examination.
Because such damage can happen and worsen over time, RSPA believes that
after five years of use, a plastic drum should be subjected to a leak
test prior to each reuse for the shipment of liquid hazardous
materials.
New paragraph Sec. 173.28(b)(7) authorizes the reuse, without leak
testing, of certain drums including those constructed of stainless
steel, monel, nickel, and plastic. In order to ensure an appropriate
level of safety, when stainless steel, monel, or nickel drums are
reused without undergoing leakproofness testing, they are required to
meet more stringent thickness standards than prescribed in paragraph
(b)(4). Plastic drums may be reused without undergoing leakproofness
testing only for five years from the date of manufacture, consistent
with the UN Recommendations. After five years from the date of
manufacture, such drums could continue to be used only if leakproofness
tested prior to each reuse. Metal and plastic drums can only be reused
without leak testing when refilled with the same or similar contents,
and transported by a private carrier, contract carrier, or common
carrier in a transport vehicle or freight container used exclusively
for such service, within a distribution chain controlled by the
offeror. As proposed in the NPRM, other packagings could qualify only
if approved by the Associate Administrator for Hazardous Materials
Safety. In any case, a packaging which, upon visual examination, shows
evidence of a reduction in integrity must be reconditioned and, if
applicable, leak tested, before being reused.
RSPA does not agree with commenters who suggested that the waiver
of leak testing requirements be extended to metal drums other than
those made from stainless steel, monel, and nickel. Transportation
stresses typically can cause leakage, from the chime seams of these
drums, that is most appropriately detected through the performance of a
leakproofness test.
In addition, paragraph (c)(1)(i) is revised to clarify that only
external coatings must be removed when reconditioning metal drums.
Section 173.33. Paragraph (c)(5) is amended as proposed to limit
the provisions of the paragraph to materials in Packing Groups I and II
of Division 6.1.
Section 173.52. The descriptions of Compatibility Group B is
revised to clarify that detonators and similar articles are included
within this description even if they do not contain primary explosives.
In addition, in the descriptions for Compatibility Groups E and F, the
word ``gel'' is added to clarify that articles with a propelling charge
containing gel may not be classified in Compatibility Group E or F.
Section 173.59. The definitions ``powder, smokeless,''
``propellants,'' and ``charges, propelling'' are revised and
definitions for ``charges, propelling, for cannon,'' ``propellent,
liquid,'' and ``propellant, solid'' are added.
Section 173.60. Paragraph (b)(15) is added to require all plastic
packagings to be static-resistant.
Section 173.62. The Explosives Table is amended to add new
descriptions for Class 1 materials. In addition, the packing method for
UN0075 and UN0143 is revised to E-159. The Table of Packing Methods is
editorially revised to change the reference to steel and aluminum boxes
from 4A1 or 4A2 to 4A and 4B1 or 4B2 to 4B. Several packing methods are
revised by authorizing aluminum boxes (4B) as an alternate packaging.
For clarity, the entire Explosive Packing Methods Table has been
reprinted along with the Table of Particular Packaging Requirements and
Exceptions. Paragraph (e) is revised to update the military packaging
exception to allow explosives packaged prior to January 1, 1990, to be
transported in accordance with the packaging provisions in effect on
that date.
Section 173.115. The definition of a Division 2.2 gas is expanded
to include asphyxiant and oxidizing gases. However, based on comments
received, the definition is revised to be more consistent with the
definition in the UN Recommendations. In addition, the definitions of
asphyxiant gas and oxidizing gas proposed in the NPRM have been moved
to Sec. 171.8.
Section 173.120. RSPA received several comments supporting the new
exceptions for Class 3 materials. Some of these commenters requested
that these exceptions be extended to the definition of combustible
liquids. Through RSPA agrees that similar exceptions should be adopted
for the definition of combustible liquid, the exceptions have been
established for materials with a flash point of 141 deg.F or below.
The tests may not be appropriate for a material with a flash point of
below 200 deg.F. Therefore, RSPA is unable to adopt this suggestion.
However, if data is provided to support adoption of these test methods,
or a modified form thereof, RSPA will initiate a new rulemaking action
to adopt these exceptions for combustible liquids.
Section 173.121. Criteria for including viscous Class 3 materials
in Packing Group III is revised. Several modifications to the method
are provided when the temperature of the flash point is too low for the
standard procedures. The table in Sec. 173.121(b)(1)(iv) is amended for
consistency with the eighth revision of the UN Recommendations.
Section 173.124. The definition of self-reactive materials is
revised to conform to the changes in the UN Recommendations, which now
contains ``generic'' shipping descriptions. Seven types of self-
reactive material (Types A-G) are defined in paragraph (a)(2). The
procedure for assigning a specific self-reactive material to a generic
type is set forth in paragraph (a)(2)(vi). If a self-reactive material
is identified by technical name in the Self-Reactive Materials Table in
Sec. 173.224, the generic type is assigned in that Table. The lengthy
process by which importing and exporting countries agree on the
packaging requirements or assignment of a shipping description for a
new self-reactive material is avoided by using this procedure.
Section 173.128. Editorial revisions are made in paragraphs (a),
(c)(2) and (c)(3), paragraph (b)(7) is clarified and procedures for
obtaining approvals are clarified in revised paragraph (d).
Section 173.136. RSPA received several comments on the adoption of
the OECD Guidelines in the definition of Class 8 (corrosive materials).
Some commenters supported the proposed change, while others opposed it
and requested that RSPA not adopt it. Those that opposed the change to
the Class 8 definition cited problems with retesting of chemicals
tested under the old definition, moistening of solid materials before
testing, and ``full thickness testing.'' The changes adopted in this
final rule to the definition of Class 8 are a refinement of the
existing definition. RSPA will not require the retesting of materials
that have been classified under the test method previously found in
Appendix A of Part 173. In addition, the new definition will not expand
significantly the number of materials subject to the HMR. Although the
OECD Guidelines require appropriate moistening of a solid material
before application to the skin, this minuscule amount of liquid should
have no effect on the outcome of the test. In addition, review of some
past testing of corrosive solids indicates that moistening is already
being used as a vehicle to assure good contact with the skin. As stated
by one commenter, the new definition will provide standardization in
classifying these materials; make more definitive information available
to emergency responders, drivers, cargo handlers, and others; and will
facilitate the safe handling and emergency response procedures for
corrosive materials. Therefore, RSPA is adopting the changes to the
definition of Class 8 and assignment of Class 8 Packing Groups, as
proposed.
Section 173.150. RSPA proposed to add language in the introductory
text of Sec. 173.150(b) to specifically address combustible liquids in
the limited quantity provisions. RSPA received a comment in opposition
to this proposal stating that there is no difference in the way
combustible liquids that are hazardous substances or hazardous wastes
(versus non-hazardous substances or non-hazardous wastes) are treated
under the current wording of these provisions. However, combustible
liquids in non-bulk packagings that meet the definition of a hazardous
substance, hazardous waste, or marine pollutant currently are subject
to shipping paper, marking, placarding and other requirements set forth
in Sec. 173.150(f)(3). RSPA is adopting the proposed language to
clarify that combustible liquids are eligible for the limited quantity
exceptions if they are packaged accordingly.
Section 173.152. The limited quantity provisions for organic
peroxides are amended by increasing the authorized net capacity per
inner packaging for Type D, E, or F liquid and solid organic peroxides
and Type B or C solid organic peroxides. However, the authorized net
capacity for liquid Type B or C organic peroxides is decreased from 30
ml to 25 ml per inner packaging.
Section 173.158. Based on the merits of a comment and a petition
for rulemaking (P-1170), a new paragraph (f)(3) is added for nitric
acid of 70 percent or less to authorize combination packagings
consisting of inner plastic packagings individually overpacked in
tightly closed metal packagings, and further packed in an outer
packaging, such as a drum or box. This packaging currently is
authorized for transportation in cargo aircraft only, but there is no
comparable authorization for transport in other modes. Offerors of
nitric acid in plastic packagings are reminded of the compatibility
requirements specified in Sec. 173.24(e).
Section 173.164. Certain exceptions for mercury (metallic and
articles containing mercury), are revised, and a 4H2 solid plastic box
is authorized as an outer packaging, consistent with the ICAO Technical
Instructions.
Section 173.166. This section is amended to limit its applicability
to air bag inflators and modules showing certain specified results when
subjected to a bonfire test. Airbag modules and inflators not meeting
the test criteria must be transported as explosives. RSPA received
several comments on the transportation of airbags, many of which were
outside the scope of this rulemaking. One commenter requested that RSPA
revise proposed proper shipping names for airbags, but did not provide
sufficient justification for adding a domestic-only proper shipping
name for these commodities. The comments requesting new packaging
authorization and removal of the Ex-number marking requirements have
been denied because they are considered beyond the scope of this
rulemaking.
Section 173.168. RSPA proposed the addition of a separate section
to define a ``nonspillable battery,'' establish separate requirements
for nonspillable batteries (as opposed to the requirements for wet
batteries contained in Sec. 173.159), and provide vibration and
pressure differential testing criteria. Except when transporting a
wheelchair or other battery-powered mobility aid equipped with a
nonspillable battery by air as checked baggage, a nonspillable battery
which is protected against short circuits, securely packaged and
durably marked is not subject to any other HMR requirements. After
further deliberation, RSPA has decided not to create a separate section
for nonspillable batteries and, therefore, provisions for these
batteries will remain in Sec. 173.159.
Section 173.171. Paragraph (a) is revised as proposed to clarify
that smokeless powder must be examined and approved as both Division
1.3 and Division 4.1.
Section 173.185. RSPA is amending the requirements for lithium
batteries consistent with changes in the UN Recommendations. While the
new requirements apply more severe test requirements to lithium
batteries, they also allow batteries with higher quantities of lithium
to be transported without being subject to the regulations, provided
specified criteria are met. Existing batteries previously allowed to be
transported as Class 9 batteries may continue to be transported under
the present requirements indefinitely if the present requirements are
met. One commenter to this section asked why rechargeable batteries are
no longer specifically mentioned in the section. Rechargeable batteries
are no longer mentioned in the section because such batteries are being
treated in the same manner as other lithium batteries.
Section 173.189. RSPA received two comments on the proposed
transport of sodium batteries. One commenter requested that sodium
batteries installed in motor vehicles be excepted from the HMR, and the
other requested that sodium batteries be allowed to contain
polysulfides. RSPA concurs with these commenters and has revised this
proposed section accordingly.
Section 173.196. RSPA is adopting the proposed revision to
paragraph (f) to clarify that either the inner receptacle or the outer
packaging for infectious substances must be capable of withstanding the
prescribed pressure differential.
Section 173.211-213. These sections are adopted as proposed to
change packaging identification codes (for steel boxes from 4A1 to 4A2
to 4A and for aluminum boxes from 4B1 and 4B2 to 4B) for consistency
with international requirements.
Section 173.224. This section is revised based on the UN
Recommendations. Paragraph (b) sets forth the Self-Reactive Materials
Table which identifies the technical name for specific self-reactive
materials, the identification number which is used to select the
appropriate generic shipping description, specifications for
concentrations of the self-reactive material, packing methods that may
be used, temperature control requirements, and additional special
provisions. The existing packing methods for self-reactive materials
are replaced with the packing methods for organic peroxides which are
prescribed in Sec. 173.225.
Paragraph (c) sets forth procedures for new self-reactive
materials, formulations and samples. New self-reactive materials and
formulations of currently identified self-reactive materials must be
approved in accordance with the provisions in Sec. 173.124(a)(2)(vi).
Paragraph (c)(4) contains provisions for the shipping of samples of new
formulations. Paragraph (d) specifies that self-reactive materials of
Type F may be transported in bulk only under the approval of the
Associate Administrator for Hazardous Materials Safety.
Section 173.225. In Sec. 173.225, paragraph (a) is revised to
prohibit the use of metallic non-bulk packagings meeting a Packing
Group I packaging standard. Paragraph (c)(5) is added to authorize the
transportation of mixtures of organic peroxides that are specifically
identified in the Organic Peroxides Table without approval by the
Associate Administrator for Hazardous Materials Safety. In addition,
the Organic Peroxide Table is revised to add new organic peroxides
adopted in the UN Recommendations. Several miscellaneous changes, based
on comments, have been made to the Table. In addition, for use
domestically, RSPA is adding 12 new organic peroxides that are not
listed in the UN Recommendations but have been approved by RSPA for
domestic transportation.
Section 173.304. In the paragraph (a)(2) table, for the entry
``carbon dioxide,'' an erroneous reference to a DOT-311800 cylinder is
corrected to authorize a DOT-3T1800 cylinder for carbon dioxide.
Section 173.306. In paragraph (a)(3)(v), the hot water immersion
test for aerosols and small gas receptacles includes a reference
temperature of 50 deg.C (122 deg.F) in addition to the reference
temperature of 55 deg.C (131 deg.F). A reference temperature of
50 deg.C is permitted if the liquid phase of the materials contained in
the receptacle does not exceed 95 percent of the capacity of the
receptacle at 50 deg.C. In addition, provisions are added for plastic
receptacles or contents which are sensitive to heat.
Appendix A to Part 173. Appendix A, which provides a method of
testing corrosion to skin, is removed and reserved for consistency with
changes to the definition and packing group assignment for Class 8
materials.
Appendix E to Part 173. New criteria are added for self-reactive
materials possessing explosive properties, and an editorial change is
made to clarify that powders of metals or metal alloys that can be
ignited are classified in Division 4.1.
Appendix F to Part 173. In paragraph 1., an editorial revision is
made to correctly reference Division 5.1.
Appendix H to Part 173. A new Appendix H is added to Part 173 to
provide a method of testing for combustibility. This method outlines a
procedure for determining if a material can sustain combustion if
heated under test conditions and exposed to an external source of
flame.
Part 175
Section 175.10. The phrase ``environmental restoration or
protection'' is added as an exception in paragraph (a)(12) to clarify
that certain aircraft operations pertaining to environmental
restoration may be conducted under the provisions of this paragraph.
Exceptions for carbon dioxide (dry ice) are consolidated into paragraph
(a)(13) to except this material from regulation from Part 175 when it
is used as a refrigerant for a package, intended for use in food or
beverage service aboard an aircraft, or used to pack perishables in
carry-on baggage. Based on the merit of two comments, proposed
paragraph (a)(4) more closely adopts the language of the ICAO Technical
Instructions to permit non-radioactive medicinal or toilet articles
(including aerosols) in either carry-on baggage or checked baggage. It
also permits aerosols in Division 2.2 having no subsidiary risk, if
intended for sporting or home use, in checked baggage. In addition, a
new paragraph (a)(26) is added to except from regulation small medical
or clinical mercury thermometers carried by passengers or crew members
for personal use.
Section 175.33. Paragraph (a)(1) is revised to require that a
compatibility group letter for a Class 1 material be included in the
written notification to the pilot-in-command. RSPA also proposed to add
a new paragraph (a)(9) to require an aircraft operator to include an
air waybill number where one has been issued. However, based on the
merit of a comment from the Air Transport Association, RSPA agrees that
the placement of an airway bill number on the notification does nothing
to enhance safety. Therefore, this proposed requirement is not adopted.
Part 176
Section 176.27. RSPA proposed the addition of a new paragraph (c)
to reference a container packing certificate required under the
provisions of the SOLAS Convention and the IMDG Code. Commenters to
this proposal did not object to its addition, but suggested that the
certification contain a reference to the section outlining the
requirements rather than a certification that each of the requirements
have been met. RSPA agrees, and is revising proposed paragraph (c)(2).
In addition, the Hazardous Materials Advisory Council (HMAC) and the
Chemical Manufacturers Association (CMA) asked RSPA to clarify that the
container packing certificate is to be presented to the vessel carrier
at the time the hazardous materials are offered for transportation by
vessel. A clarification is added in paragraph (c)(1) in response to
this request.
Section 176.76. A new paragraph (i) is adopted as proposed to
address the transport of fumigated transport units on vessels. These
fumigation requirements are in addition to the fumigation requirements
contained in Sec. 173.9. The new vessel requirements are generally
consistent with the IMDG Code requirements for transporting fumigated
transport units and are consistent with Special Permits currently being
issued by the Coast Guard for U.S. maritime transport of fumigated
transport units.
Part 177
Section 177.841. Revised paragraph (e)(3) is adopted as proposed to
specify requirements for separating Division 6.1 Packing Group III
materials from foodstuffs, consistent with provisions in Sec. 177.848.
Part 178
Section 178.2. Changes to paragraphs (a) and (e) are adopted as
proposed. Paragraph (a) is revised to clarify that Part 178
requirements for UN standard packagings apply only to packagings
manufactured in the U.S. See Sec. 173.24(d)(2) for foreign-manufactured
packagings. A new paragraph (e) is added to include definitions for
``manufacturer'' and ``specification markings.'' These new definitions
specify who is to be identified through a specification marking as the
``manufacturer'' and clarify the manufacturer's responsibility under
Part 178.
Section 178.3. One commenter thought that the location of
manufacture should be immaterial to the use of the ``USA'' mark. This
commenter stated that the ``USA'' mark should be described as simply
indicating compliance with Part 178, regardless of where the packaging
is physically manufactured and asked RSPA to clarify the use of the
marking ``USA'' for a DOT specification or UN specification packaging
that is manufactured in the U.S. or in another country. RSPA believes
that a ``USA'' marked packaging should be manufactured and marked only
in the U.S., and that packagings manufactured in the U.S. must be
marked ``USA'' and comply with Part 178.
Section 178.502. In paragraph (a) introductory text and paragraph
(a)(1), the terms ``type'' or ``types'' of packagings are revised for
consistency with international regulations to read ``kind'' or
``kinds'' of packagings.
Section 178.503. As proposed in the NPRM, this section is revised
to incorporate changes in the UN Recommendations with regard to the
marking of non-bulk packagings. Consistent with the UN Recommendations,
each packaging certified to a UN standard must have a series of
markings which describe the packaging and its characteristics. The
Steel Shipping Container Institute (SSCI) objected to the lower weight
limit for packagings which would be required to be marked on the top or
side, suggesting that a capacity limit, such as 30 liters, would be
more appropriate. SSCI pointed out that, if all packagings over 30 kg
are required to be marked on the side or top, packagings as small as 5
gallons, if they are used to ship very dense products, must be marked
this way. In the UN Recommendations, and as proposed in the NPRM, the
threshold of 30 kg above which packagings must be marked on the top or
a side is intended to represent the maximum weight that a person can
reasonably be expected to lift in order to see the markings on the
bottom of a package. The important consideration is weight, rather than
capacity, and therefore the 30 kg size limit, after which markings must
be applied on the top or side, is adopted in this final rule. This
requirement has been moved to Sec. 178.3(a)(5) to appear with related
marking requirements.
Currently, Sec. 178.503 requires that metal or plastic drums or
jerricans intended for reuse be marked with the minimum thickness of
the packaging material. Consistent with the UN Recommendations, in this
final rule metal drums and jerricans intended for reuse must be marked
with the nominal thickness. The nominal thickness marked must be in
accordance with ISO 3574; that is, the nominal thickness marked may
only exceed the actual minimum thickness of the packaging material by
the tolerance specified in ISO 3574. A commenter suggested that RSPA
clarify, for a metal packaging marked with a nominal thickness, what
the minimum thickness must be. In this final rule, a table indicating
what minimum thickness corresponds to the nominal thickness specified
in ISO Standard 3574, for various packaging capacities, has been added
to a new Appendix C to Part 178. Packagings to be used are still
subject to the minimum thickness requirements of Sec. 173.28. Because
the eighth revised edition of the UN Recommendations did not address
thickness requirements for plastic packagings, plastic drums and
jerricans intended for reuse must continue to be marked with the
minimum thickness of the packaging material.
In additional to the full marking on the top or side of a metal
drum having a capacity greater than 100 liters, paragraph (a)(10)
requires a permanent marking of the drum characteristics on the bottom
of the drum. The country authorizing the mark and the name and address
of the manufacturer are not required as part of this permanent mark.
This marking identifies the packaging as it was originally
manufactured, and may not necessarily be used to determine compliance
with packaging requirements. For example, if a non-removable head drum
has been converted to a removable head drum, this conversion is not
reflected in the marking on the bottom of the drum, but is evident in
the top or side marking. For drums marked permanently on the bottom,
the top or side mark is not required to be permanent (i.e., able to
withstand the reconditioning process). RSPA is not adopting a
commenter's suggestion that the permanent marking on the bottom of a
drum not be required if the markings appearing on the top or side of
the packaging are permanent. RSPA believes this type of change should
be considered first by the UN Committee of Experts.
As proposed in the NPRM, the additional permanent marking on the
bottom of a drum would have applied to plastic drums as well as metal
drums. Several commenters objected to this proposal as it applied to
plastic drums. RSPA notes that the UN Recommendations do not require
plastic drums to bear the additional permanent marking on the bottom of
the drum, and most plastic drums are permanently marked on the side.
Based on the merit of comments, and consistent with the UN
Recommendations, RSPA is limiting the additional marking requirement of
paragraph (a)(10) to metal drums with a capacity greater than 100
liters.
Based on comments from ACR, the marking requirements for metal
drums with a capacity greater than 100 liters have been revised in this
final rule for greater consistency with the UN Recommendations, and for
clarity. As proposed in the NPRM, the permanent marking requirements of
paragraph (a)(10) would have applied only to those metal drums
``intended for reuse or reconditioning as a single packaging or the
outer packaging of a composite packaging.'' ACR stated that the
determination of suitability for reuse or reconditioning is not made by
the manufacturer. RSPA agrees, and the qualifier ``intended for reuse
or reconditioning'' is not adopted in this final rule.
A commenter was concerned that a semi-permanent label would not be
considered ``durable'' for purposes of the UN marking. RSPA would
consider the use of a printed label to satisfy the requirement for
``durable'' markings, provided the label can withstand the rigors of
normal transportation.
Paragraph (c) specifies additional requirements for markings on
reconditioned metal drums. The paragraph requires that reconditioners
reapply markings which no longer appear on drums after the
reconditioning process. A reconditioner can duplicate the original
markings or apply markings which reflect a lower performance level, but
cannot apply markings which identify a performance level greater than
that for which the original design type had been tested and marked.
A new paragraph (d) clarifies marking requirements for
remanufactured packagings. Based on a comment from ACR, paragraph (d)
specifies that required markings need not be permanent on
remanufactured metal drums for which there is no change to the
packaging type, and no replacement of integral structural components.
All other remanufactured metal drums must be permanently marked on the
top or side. This paragraph was not proposed in the NPRM, but is
considered necessary to ensure that packagings can be properly marked
after remanufacture, when it may not be possible to permanently mark on
the bottom.
Section 178.512. Standards for steel boxes and aluminum boxes are
consolidated by removing the distinction between unlined/uncoated steel
or aluminum boxes and steel or aluminum boxes having an inner liner or
coating. Therefore, both unlined and lined steel boxes are identified
as 4A and unlined and lined aluminum boxes are identified as 4B.
Corresponding revisions are reflected in the packaging authorizations
of Part 173.
Section 178.513. A new paragraph is added to the standards for
natural wood boxes to specify fastening requirements.
Section 178.516. Paragraph (b)(1) contains an updated reference to
ISO Standard 535-1976(E). Paragraph (b)(2) is revised to authorize the
ends of fiberboard boxes to be constructed of suitable materials other
than wood, which is already authorized. As proposed in the NPRM,
paragraph (b)(3)(iii) is redesignated as (b)(4) to clarify that the
requirement for water-resistant adhesive applies to all box closures,
and not only the manufacturer's joint. In its comments, 3M suggested
that RSPA include ASTM D5570, Standard Test Method for Water Resistance
of Tape and Adhesives Used as a Box Closure, as a standard for
determining the water resistance of adhesives used in 4G boxes. Since
RSPA did not propose such a standard in the NPRM, the suggestion is not
adopted in this final rule.
Section 178.521. In paragraph (b)(2), the term ``water-resistant''
is revised to ``waterproof'', and examples of a waterproof ply or
barrier are provided.
Section 178.522. A composite packaging consisting of a plastic
receptacle in a protective plastic drum is designated as 6HH in the
current HMR standards. The UN Recommendations recently adopted a new
composite packaging standard to authorize a plastic receptacle in a
protective plastic box. Therefore, in paragraph (b)(3), the previous
6HH composite packaging is redesignated at 6HH1 and the new composite
packaging (the plastic receptacle in a protective plastic box) is
designated as 6HH2.
Section 178.601. Paragraph (b) is adopted as proposed to limit the
responsibility of shippers to those packaging assembly functions they
actually perform or are responsible for performing. A revision to
paragraph (b)(2) removes the shipper responsibility provision regarding
packaging fabrication and testing functions not performed by the
shipper. Only one commenter did not favor this proposal. The Society of
the Plastics Industry believed that a shipper should share some
responsibility for compliance, such as obtaining a certification from
the packaging manufacturer for each type of packaging used in hazardous
materials service. Paragraph (g)(2)(i) is revised to clarify that
selective testing under Variation 2 requires the fragile inner
packagings to contain liquids. A new sentence is added to the end of
paragraph (g)(2)(vi) to clarify that where outer packagings are not
leakproof or siftproof and consequently require some type of leakproof
liner, plastic bag or other means of containment, sufficient absorbent
material must be placed inside the liner or bag. A new paragraph (k) is
added to permit several tests to be performed on one sample if the
validity of test results is not affected and if approved by the
Associate Administrator for Hazardous Materials Safety. Newly
designated paragraph (l) is revised as proposed to clarify
recordkeeping requirements and provide consistency with test report
requirements in the UN Recommendations. One commenter requested
clarification of the methods by which a test method is ``maintained''
at each location where a packaging is manufactured. This commenter
asked if a manufacturer's central office could maintain records when
multiple locations are involved and provide access through a computer
data base or fax. ``Maintained'' as provided in Sec. 178.601(l) is
limited to hard copies of test reports or electronic storage of reports
at each manufacturing location. Inspectors cannot conduct inspections
without test records to compare to the packages. Therefore, the company
may maintain records at a central office so long as the company is
capable of providing hard copy reports in a timely manner to an
inspector at the time of inspection. SSCI pointed out that paragraph
(l)(10) is redundant with paragraph (l)(1) in that both require an
identification of the address of the test facility. RSPA agrees, and
paragraph (l)(10), as adopted, requires the title, rather than the
address, of the signatory to be included.
Section 178.602. In paragraph (c) a reference to
``Sec. 178.603(d)(2)'' is corrected to read ``Sec. 178.603(e)''.
Section 178.603. In paragraph (a), a new provision is added to
require that the drop test be performed using the package orientation
most likely to result in failure if more than one orientation is
possible. Paragraph (c) is revised to clarify that the cold drop test
outlined in this paragraph applies only to plastic packagings, and
applies to combination packagings with inner plastic bags only when the
inner packagings are intended to contain liquids. A revision to
paragraph (f)(1) clarifies that inner packagings of combination
packagings are not required to be vented to reach equilibrium after the
drop test.
Section 178.604. For consistency with a change in the UN
Recommendations, the length of time to conduct a leakproofness test,
other than for production testing, is specified as five minutes in
revised paragraph (d).
Section 178.606. For consistency with the UN Recommendations, a
phrase is added in paragraph (c)(1) to clarify that the force to be
applied, when a test sample contains a non-hazardous liquid with a
specific gravity different from the hazardous liquid intended for
transport, must be calculated based on the specific gravity that will
be marked on the packaging.
Appendix C to Part 178. A new Appendix C is added to Part 178 to
incorporate a table indicating the corresponding nominal and minimum
thicknesses for packagings of varying capacities, in accordance with
ISO Standard 3574.
Rulemaking Analyses and Notices
A. Executive Order 12866 and DOT Regulatory Policies and Procedures
This final rule is not considered to be a significant regulatory
action under section 3(f) of Executive Order 12866 and was not reviewed
by the Office of Management and Budget. The rule is not considered
significant under the Regulatory Policies and Procedures of the
Department of Transportation [44 FR 11034]. A regulatory evaluation is
available for review in the Docket.
B. Executive Order 12612
This final rule has been analyzed in accordance with the principles
and criteria contained in Executive Order 12612 (``Federalism'').
Federal law expressly preempts State, local, and Indian tribe
requirements applicable to the transportation of hazardous material
that cover certain covered subjects and are not substantively the same
as Federal requirements. 49 U.S.C. 5125(b)(1). These subjects are:
(A) The designation, description, and classification of hazardous
materials;
(B) The packing, repacking, handling, labeling, marking, and
placarding of hazardous material;
(C) The preparation, execution, and use of shipping documents
pertaining to hazardous material and requirements respecting the
number, content, and placement of such documents;
(D) The written notification, recording, and reporting of the
unintentional release in transportation of hazardous material; and
(E) The design, manufacturing, fabrication, marking, maintenance,
reconditioning, repairing, or testing of a package or container which
is represented, marked, certified, or sold as qualified for use in the
transportation of hazardous material.
This final rule concerns classification, packaging, labeling,
marking, shipping documentation, and manufacture of packaging for
hazardous material. Therefore, this final rule preempts State, local,
or Indian tribe requirements that are not substantively the same as
Federal requirements on these subjects.
Section 5125(b)(2) of title 49 U.S.C. provides that when DOT issues
a regulation concerning any of the covered subjects, DOT must determine
and publish in the Federal Register the effective date of Federal
preemption. That effective date may not be earlier than the 90th day
following the date of issuance of the final rule and not later than two
years after the date of issuance. RSPA has determined that the
effective date of Federal preemption for these requirements will be
October 1, 1995. Thus, RSPA lacks discretion in this area, and
preparation of a federalism assessment is not warranted.
C. Regulatory Flexibility Act
This rule incorporates changes introduced in the seventh and eighth
revised editions of the UN Recommendations, the 1993-1994 and 1995-1996
ICAO Technical Instructions, and Amendments 26 and 27 to the IMDG Code.
It applies to offerors and carriers of hazardous materials and
facilitates the transportation of hazardous materials in international
commerce by providing consistency with international requirements. If
this rule is not adopted, U.S. companies, including numerous small
entities competing in foreign markets, will be forced to comply with a
dual system of regulation, to their economic disadvantage. Therefore, I
certify that this rule will not have a significant economic impact on a
substantial number of small entities.
D. Paperwork Reduction Act
The requirements for information collection have been approved by
the Office of Management and Budget (OMB) under the provisions of the
Paperwork Reduction Act of 1980 (Pub. L. 95-511) under OMB control
number 2137-0034 for shipping papers and 2137-0557 for approvals.
E. Regulation Identifier Number (RIN)
A regulation identifier number (RIN) is assigned to each regulatory
action listed in the Unified Agenda of Federal Regulations. The
Regulatory Information Service Center publishes the Unified Agenda in
April and October of each year. The RIN number contained in the heading
of this document can be used to cross-reference this action with the
Unified Agenda.
List of Subjects
49 CFR Part 171
Exports, Hazardous materials transportation, Hazardous waste,
Imports, Incorporation by reference, Reporting and recordkeeping
requirements.
49 CFR Part 172
Hazardous materials transportation, Hazardous waste, Labels,
Markings, Packaging and containers, Reporting and recordkeeping
requirements.
49 CFR Part 173
Hazardous materials transportation, Packaging and containers,
Radioactive materials, Reporting and recordkeeping requirements,
Uranium.
49 CFR Part 175
Air carriers, Hazardous materials transportation, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 176
Hazardous materials transportation, Maritime carriers, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 177
Hazardous materials transportation, Motor carriers, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 178
Hazardous materials transportation, Motor vehicles safety,
Packaging and containers, Reporting and recordkeeping requirements.
In consideration of the foregoing, 49 CFR Chapter I is amended as
follows:
PART 171--GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS
1. The authority citation for Part 171 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
2. In the Sec. 171.7(a)(3) Table, under the entry American Society
for Testing and Materials, a new entry is added in numerical order;
under the entry International Organization for Standardized, three new
entries are added at the end of existing entries; and a new entry is
added in alphabetical order, to read as follows:
Sec. 171.7 Reference material.
(a) * * *
(3) Table of material incorporated by reference. * * *
------------------------------------------------------------------------
49 CFR
Source and name of material reference
------------------------------------------------------------------------
* * * * * * *
American Society for Testing and Materials
* * * * * * *
ASTM G 31-72 (Reapproved 1990) Standard Practice for
Laboratory Immersion Corrosion Testing of Metals.......... 173.137
* * * * * * *
International Organization for Standardization
* * * * * * *
ISO 3574-1986(E) Cold-reduced carbon steel sheet of
commercial and drawing qualities.......................... 178.503
ISO 2592-1973(E) Petroleum products--Determination of flash
and fire points--Cleveland open cup method................ 173.120
ISO 9328-1--1991(E) Steel plates and strips for pressure
purposes--Technical delivery conditions--Part 1: General
requirements.............................................. 173.137
* * * * * * *
Organization for Economic Cooperation and Development
(OECD)
OECD Publications and Information Center, 2001 L
Street, Suite 700, Washington, DC 20036
OECD Guideline for Testing of Chemicals, No.404
``Acute Dermal Irritation/Corrosion'', 1992....... 173.137
* * * * * * *
------------------------------------------------------------------------
* * * * *
Sec. 171.7 [Amended]
3. In addition, in Sec. 171.7, in the table in paragraph (a)(3),
the following changes are made:
a. In the entry ASTM D 56-79, the wording ``D 56-79 Standard Method
of Test for Flash Point by Tag Closed Tester'' is revised to read ``D
56-93 Standard Test Method for Flash Point by Tag Closed Tester''.
b. In the entry ASTM D 93-80, the wording ``D 93-80 Standard Method
of Test for Flash Point by Pensky Martens Closed Tester'' is revised to
read ``D 93-90 Standard Test Methods for Flash Point by Pensky-Martens
Closed Tester''.
c. In the entry ASTM D 3278-78, the wording ``D 3278-78 Flash Point
of Liquids by Setaflash Closed Tester'' is revised to read ``ASTM D
3278-89 Standard Test Methods for Flash Point of Liquids by Setaflash
Closed-Cup Apparatus''.
d. In the entry ASTM D 4359-84, the wording ``D 4359-84'' is
revised to read ``ASTM D 4359-90''.
e. Under International Civil Aviation Organization (ICAO), for the
entry ``Technical Instructions for the Safe Transport of Dangerous
Goods by Air'', the date ``1993-1994'' is revised to read ``1995-
1996''.
f. Under International Maritime Organization (IMO), the entry
``International Maritime Dangerous Goods (IMDG) Code, 1990 Consolidated
Edition, as amended by Amendment 26 thereto'' is amended by removing
the wording ``Amendment 26 thereto'' and adding in its place the
wording ``Amendment 27 (1994)''.
g. Under International Organization for Standardization, the
wording ``ISO-535-1976(E) Paper and Board--Determination of Water
Absorption--Cobb Method'' is revised to read ``ISO-535-1991(E) Paper
and board--Determination of water absorptiveness--Cobb method''.
h. Under Transport Canada, the entry ``Transportation of Dangerous
Goods Regulations, as of July 1, 1985, incorporating Registration
Numbers SOR/85-77, SOR/85-585 and SOR/85-609'' is revised to read
``Transportation of Dangerous Goods Regulations, 1 July 1985, SOR/85/
77, incorporating the following Registration Numbers: SOR/85-314, SOR/
85-585, SOR/85-609, SOR/86-526, SOR/88-635, SOR/87-335, SOR/87-186,
SOR/89-39, SOR/89-294, SOR/90-847, SOR/91-711, SOR/91-712, SOR/92-447,
SOR/92-600, SOR/93-203, SOR/93-274, SOR/93-525, SOR/94-146 and SOR/94-
264 (English edition)''.
i. Under United Nations, for the entry ``UN Recommendations on the
Transport of Dangerous Goods, Sixth Revised Edition (1989)'' the
wording ``Sixth Revised Edition (1989)'' is revised to read ``Eighth
Revised Edition (1993)''.
j. Under United Nations, for the entry ``UN Recommendations on the
Transport of Dangerous Goods, Tests and Criteria, Second Edition,
1990'', in column 2, the references ``173.124;'' ``173.128;''
``173.166;'' and ``173.185'' are added in appropriate numerical order.
4. In Sec. 171.8, the following definitions are added or revised,
as indicated, in appropriate alphabetical order to read as follows:
Sec. 171.8 Definitions and abbreviations.
[Add:]
* * * * *
Asphyxiant gas means a gas which dilutes or replaces oxygen
normally in the atmosphere.
* * * * *
Gas means a material which has a vapor pressure greater than 300
kPa (43.5 psi) at 50 deg.C (122 deg.F) or is completely gaseous at
20 deg.C (68 deg.F) at a standard pressure of 101.3 kPa (14.7 psi).
* * * * *
Oxidizing gas means a gas which may, generally by providing oxygen,
cause or contribute to the combustion of other material more than air
does.
* * * * *
Siftproof packaging means a packaging impermeable to dry contents,
including fine solid material produced during transportation.
* * * * *
[Revise:]
* * * * *
Box means a packaging with complete rectangular or polygonal faces,
made of metal, wood, plywood, reconstituted wood, fiberboard, plastic,
or other suitable material. Holes appropriate to the size and use of
the packaging, for purposes such as ease of handling or opening, or to
meet classification requirements, are permitted as long as they do not
compromise the integrity of the packaging during transportation, and
are not otherwise prohibited in this subchapter.
* * * * *
Liquid means a material, other than an elevated temperature
material, with a melting point or initial melting point of 20 deg.C
(68 deg.F) or lower at a standard pressure of 101.3 kPa (14.7 psi). A
viscous material for which a specific melting point cannot be
determined must be subjected to the procedures specified in ASTM D 4359
``Standard Test Method for Determining Whether a Material is Liquid or
Solid''.
* * * * *
Overpack, except as provided in subpart K of part 178 of this
subchapter, means an enclosure that is used by a single consignor to
provide protection or convenience in handling of a package or to
consolidate two or more packages. Overpack does not include a transport
vehicle, freight container, or aircraft unit load device. Examples of
overpacks are one or more packages:
(1) Placed or stacked onto a load board such as a pallet and
secured by strapping, shrink wrapping, stretch wrapping, or other
suitable means; or
(2) Placed in a protective outer packaging such as a box or crate.
* * * * *
Solid means a material which is not a gas or a liquid.
* * * * *
UN standard packaging means a packaging conforming to standards in
the UN Recommendations on the Transport of Dangerous Goods.
* * * * *
Sec. 171.11 [Amended]
5. In Sec. 171.11, in the last sentence of paragraph (d)(5), the
wording ``Poison'' is revised to read ``Poison or Toxic''.
Sec. 171.12 [Amended]
6. In Sec. 171.12, in paragraph (b) introductory text, in the
second sentence, the wording ``stowed and segregated, and certified in
accordance with the IMDG Code'' is revised to read ``stowed and
segregated, and certified (including a container packing certification,
if applicable) in accordance with the IMDG Code''.
7. Section 171.14 is revised to read as follows:
Sec. 171.14 Transitional provisions for implementing requirements
based on the UN Recommendations.
General. The purpose of the provisions of this section is to
provide an orderly transition to new requirements based on the UN
Recommendations, so as to minimize any burdens associated with them.
Subsequent final rules may implement different time requirements than
the transitional provisions in this section. When the effective date
section or regulatory text of a final rule imposes a compliance date
earlier or later than that which would be required under this section,
the transition date in this section does not apply.
(a) A rule published in the Federal Register on December 21, 1990,
effective October 1, 1991, resulted in a comprehensive revision of this
subchapter based on the UN Recommendations. Final rules published in
the Federal Register on December 20, 1991 effective October 1, 1991,
October 1, 1992 effective October 1, 1992, September 24, 1993 effective
October 1, 1993, and September 22, 1994 effective September 22, 1994,
further revised the December 21, 1990 final rule. Prior to an
applicable transition date in paragraph (a)(1) of this section, a
person may elect to comply with either the applicable requirements of
this subchapter in effect on September 30, 1991, or the requirements of
this subchapter appearing in the December 20, 1990 rule, as revised in
final rules published in the Federal Register on December 20, 1991,
October 1, 1992, September 24, 1993, and September 22, 1994.
(1) Transition dates. The following transition dates apply only to
requirements in the December 21, 1990 rule, as revised in the December
20, 1991, October 1, 1992, September 24, 1993, and September 22, 1994
final rules:
(i) January 1, 1995. On January 1, 1995, all applicable regulatory
requirements, including those pertaining to classification (see
Sec. 173.134 of this subchapter), hazard communication, and packaging,
are effective for Division 6.2 materials (infectious substances) other
than regulated medical waste and infectious substances affecting
animals only.
(ii) October 1, 1995. On October 1, 1995, all applicable regulatory
requirements, including those pertaining to classification (see
Sec. 173.134 of this subchapter), hazard communication, and packaging
are effective for regulated medical waste (Division 6.2) and infectious
substances affecting animals only (Division 6.2).
(iii) October 1, 1996. On October 1, 1996, requirements in Parts
172 and 173 of this subchapter for maintenance and use of packagings
that were not previously in effect are effective. (DOT specification
packagings removed from Part 178 of this subchapter by the December 21,
1990 final rule and packaging authorizations removed from Part 173 of
this subchapter by the December 21, 1990 final rule may no longer be
used in place of new packaging requirements.)
(2) Other transitional provisions--(i) Packages filled prior to
October 1, 1991. Notwithstanding the marking and labeling provisions of
Subparts D and E, respectively, of Part 172, and the packaging
provisions of Part 173 and Subpart B of Part 172 of this subchapter, a
package may be offered for transportation and transported prior to
October 1, 2001, if it--
(A) Conforms to the old requirements of this subchapter in effect
on September 30, 1991;
(B) Is filled with hazardous materials prior to October 1, 1991;
(C) Is marked ``Inhalation Hazard'', if appropriate, in accordance
with Sec. 172.313 of this subchapter or Special Provision 13, as
assigned in the Sec. 172.101 Table; and
(D) Is not emptied and refilled on or after October 1, 1991.
(ii) Transitional placarding provisions. Until October 1, 2001,
placards which conform to specifications for placards in effect on
September 30, 1991, may be used in place of the placards specified in
Subpart F of Part 172 of this subchapter, in accordance with the
following table:
Placard Substitution Table
------------------------------------------------------------------------
Hazard class or Old (Sept. 30, 1991)
division number Current placard name placard name
------------------------------------------------------------------------
Division 1.1........... Explosives 1.1......... Explosives A.
Division 1.2........... Explosives 1.2......... Explosives A.
Division 1.3........... Explosives 1.3......... Explosives B.
Division 1.4........... Explosives 1.4......... Dangerous.
Division 1.5........... Explosives 1.5......... Blasting agents.
Division 1.6........... Explosives 1.6......... Dangerous.
Division 2.1........... Flammable gas.......... Flammable gas.
Division 2.2........... Nonflammable gas....... Nonflammable gas.
Division 2.3........... Poison gas............. Poison gas.
Class 3................ Flammable.............. Flammable.
Combustible liquid..... Combustible............ Combustible.
Division 4.1........... Flammable solid........ Flammable solid.
Division 4.2........... Spontaneously Flammable solid.
combustible.
Division 4.3........... Dangerous when wet..... Flammable solid W.
Division 5.1........... Oxidizer............... Oxidizer.
Division 5.2........... Organic peroxide....... Organic peroxide.
Division 6.1, PG I and Poison................. Poison.
II.
Division 6.1, PG III... Keep away from food.... (none required).
Class 7................ Radioactive............ Radioactive.
Class 8................ Corrosive.............. Corrosive.
Class 9................ Class 9................ (none required).
------------------------------------------------------------------------
(b) A rule published in the Federal Register on December 29, 1994,
effective October 1, 1995, resulted in further revisions to this
subchapter based on the UN Recommendations. During the transition
period provided in paragraph (b)(1) of this section, a person may elect
to comply with either the applicable requirements of this subchapter in
effect on September 30, 1995, the applicable requirements based on the
transition dates provided in paragraph (a)(1) of this section, or the
requirements of this subchapter appearing in the December 29, 1994,
final rule.
(1) Transition date. On October 1, 1996, all applicable regulatory
requirements adopted in the December 29, 1994, final rule must be met.
(2) Intermixing old and new requirements. Prior to the transition
date in paragraph (b)(1) of this section, it is recommended that hazard
communication requirements be consistent where practicable, i.e.,
marking, labeling, placarding, and shipping paper descriptions should
conform to either the old requirements of this subchapter in effect on
September 30, 1995, or new requirements of this subchapter added or
revised by the December 29, 1994, rule, without intermixing of
communication elements. However, intermixing is permitted, during the
applicable transition period, for packaging, hazard communication, and
handling provisions, as follows:
(i) If either shipping names or identification numbers are
identical, a shipping paper may display the old shipping description
even if the package is marked and labeled under the new shipping
description;
(ii) If either shipping names or identification numbers are
identical, a shipping paper may display the new shipping description
even if the package is marked and labeled under the old shipping
description; and
(iii) Either old or new placards may be used regardless of whether
old or new shipping descriptions and package markings are used.
PART 172--HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS
MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND
TRAINING REQUIREMENTS
8. The authority citation for part 172 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
9. In Sec. 172.101, paragraphs (c)(3), (c)(13) and (k)(1) through
(k)(5) are revised and, in paragraph (g), a new sentence is added as
the last sentence to read as follows:
Sec. 172.101 Purpose and use of hazardous materials table.
* * * * *
(c) * * *
(3) The word ``poison'' or ``poisonous'' may be used
interchangeably with the word ``toxic'' when only domestic
transportation is involved. The abbreviation ``n.o.i.'' or
``n.o.i.b.n.'' may be used interchangeably with ``n.o.s.''.
* * * * *
(13) Self-reactive materials and organic peroxides. A generic
proper shipping name for a self-reactive material or an organic
peroxide, as listed in Column 2 of the Table, must be selected based on
the material's technical name and concentration, in accordance with the
provisions of Secs. 173.224 or 173.225 of this subchapter,
respectively.
* * * * *
(g) * * * No label is required for a material classed as a
combustible liquid or for a Class 3 material that is reclassed as a
combustible liquid.
* * * * *
(k) * * *
(1) Stowage category ``A'' means the material may be stowed ``on
deck'' or ``under deck'' on a cargo vessel and on a passenger vessel.
(2) Stowage category ``B'' means--
(i) The material may be stowed ``on deck'' or ``under deck'' on a
cargo vessel and on a passenger vessel carrying a number of passengers
limited to not more than the larger of 25 passengers, or one passenger
per each three meters of overall vessel length; and
(ii) ``On deck only'' on passenger vessels in which the number of
passengers specified in paragraph (k)(2)(i) of this section is
exceeded.
(3) Stowage category ``C'' means the material must be stowed ``on
deck only'' on a cargo vessel and on a passenger vessel.
(4) Stowage category ``D'' means the material must be stowed ``on
deck only'' on a cargo vessel and on a passenger vessel carrying a
number of passengers limited to not more than the larger of 25
passengers or one passenger per each three meters of overall vessel
length, but the material is prohibited on passenger vessels in which
the limiting number of passengers is exceeded.
(5) Stowage category ``E'' means the material may be stowed ``on
deck'' or ``under deck'' on a cargo vessel and on a passenger vessel
carrying a number of passengers limited to not more than the larger of
25 passengers, or one passenger per each three meters of overall vessel
length, but is prohibited from carriage on passenger vessels in which
the limiting number of passengers is exceeded.
* * * * *
Sec. 172.101 [Amended]
10. In addition, in Sec. 172.101, the following changes are made:
a. In paragraph (c)(11) introductory text, the wording
``Secs. 173.21, 173.51, 173.56(d), or 173.56(e)(1)'' is revised to read
``Secs. 173.21, 173.51, 173.56(d), 173.56(e)(1), 173.124(a)(2)(iii) or
173.128(c)''; and the wording ``hazard class and identification
number,'' is revised to read ``hazard class, identification number, and
packing group,''.
b. In paragraph (c)(12)(iii), the last sentence is removed.
11. In Sec. 172.101, the Hazardous Materials Table is revised to
read as follows:
Sec. 172.101 Purpose and use of hazardous materials table.
* * * * *
BILLING CODE 4910-60-P
Sec. 172.101 Hazardous Materials Table
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
(8) Packaging authorizations (9) Quantity limitations (10) Vessel stowage
(Sec. 173.***) -------------------------- requirements
Hazard Identification Packing Label(s) required (if Special ---------------------------------- ---------------------
Symbols Hazardous materials descriptions and proper shipping names class or Numbers group not excepted) provisions Passenger Cargo Other
Division Exceptions Non-bulk Bulk aircraft or aircraft Vessel stowage
packaging packaging railcar only stowage provisions
(1) (2).......................................................... (3) (4) (5) (6)................... (7)............. (8A) (8B) (8C) (9A)....... (9B)....... (10A).. (10B)
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
....... Accellerene, see p-Nitrosodimethylaniline.................... ........... .............. ...................... ................ ........... ........... .......
....... Accumulators, electric, see Batteries, wet etc............... ........... .............. ...................... ................ ........... ........... .......
D...... Accumulators, pressurized, pneumatic or hydraulic (containing 2.2 NA1956 NONFLAMMABLE GAS...... ................ 306 306 None No limit... No limit... A......
non-flammable gas).
....... Acetal....................................................... 3 UN1088 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... Acetaldehyde................................................. 3 UN1089 I FLAMMABLE LIQUID...... A3, B16, T20, None 201 243 Forbidden.. 30 L....... E......
T26, T29.
A...... Acetaldehyde ammonia......................................... 9 UN1841 III CLASS 9............... ................ 155 204 240 200 kg..... 200 kg..... A...... 34
....... Acetaldehyde oxime........................................... 3 UN2332 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Acetic acid, glacial or Acetic acid solution, with more than 8 UN2789 II CORROSIVE, FLAMMABLE A3, A6, A7, A10 154 202 243 1 L........ 30 L....... A......
80 percent acid, by mass. LIQUID. B2, T8.
....... Acetic acid solution, with more than 10 percent but not more 8 UN2790 II CORROSIVE............. A3, A6, A7, A10 154 202 242 1 L........ 30 L....... A......
than 80 percent acid, by mass. B2, T8.
....... Acetic anhydride............................................. 8 UN1715 II CORROSIVE, FLAMMABLE A3, A6, A7, A10, 154 202 243 1 L........ 30 L....... A...... 40
LIQUID. B2, T8.
....... Acetone...................................................... 3 UN1090 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Acetone cyanohydrin, stabilized.............................. 6.1 UN1541 I POISON................ 2, A3, B9, B14, None 227 244 Forbidden.. 30 L....... D...... 25, 40, 49
B32, B76, B77,
N34, T38, T43,
T45.
....... Acetone oils................................................. 3 UN1091 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
....... Acetonitrile................................................. 3 UN1648 II FLAMMABLE LIQUID...... T14............. 150 202 242 1 L........ 60 L....... B...... 40
....... Acetyl acetone peroxide with more than 9 percent by mass Forbidden .............. ...................... ................ ........... ........... .......
active oxygen.
....... Acetyl benzoyl peroxide, solid, or with more than 40 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Acetyl bromide............................................... 8 UN1716 II CORROSIVE............. B2, T12, T26.... 154 202 242 1 L........ 30 L....... C...... 40
....... Acetyl chloride.............................................. 3 UN1717 II FLAMMABLE LIQUID, A3, A6, A7, None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE. B100, N34, T18,
T26.
....... Acetyl cyclohexanesulfonyl peroxide, with more than 82 Forbidden .............. ...................... ................ ........... ........... .......
percent wetted with less than 12 percent water.
....... Acetyl iodide................................................ 8 UN1898 II CORROSIVE............. B2, B101, T9.... 154 202 242 1 L........ 30 L....... C...... 40
....... Acetyl methyl carbinol....................................... 3 UN2621 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Acetyl peroxide, solid, or with more than 25 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Acetylene, dissolved......................................... 2.1 UN1001 FLAMMABLE GAS......... ................ None 303 None Forbidden.. 15 kg...... D...... 25, 40, 57
....... Acetylene (liquefied)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Acetylene silver nitrate..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Acetylene tetrabromide, see Tetrabromoethane................. ........... .............. ...................... ................ ........... ........... .......
....... Acid butyl phosphate, see Butyl acid phosphate............... ........... .............. ...................... ................ ........... ........... .......
....... Acid, sludge, see Sludge acid................................ ........... .............. ...................... ................ ........... ........... .......
....... Acridine..................................................... 6.1 UN2713 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Acrolein dimer, stabilized................................... 3 UN2607 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Acrolein, inhibited.......................................... 6.1 UN1092 I POISON, FLAMMABLE 1, B9, B12, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B42, B72,
B77, T38, T43,
T44.
....... Acrylamide................................................... 6.1 UN2074 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 12
....... Acrylic acid, inhibited...................................... 8 UN2218 II CORROSIVE, FLAMMABLE B2, T8.......... 154 202 243 1 L........ 30 L....... C...... 25, 40
LIQUID.
....... Acrylonitrile, inhibited..................................... 3 UN1093 I FLAMMABLE LIQUID, B9, T18, T26.... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Actuating cartridge, explosive, see Cartridges, power device. ........... .............. ...................... ................ ........... ........... .......
....... Adhesives, containing a flammable liquid..................... 3 UN1133 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Adiponitrile................................................. 6.1 UN2205 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Aerosols, corrosive, Packing Group II or III, (each not 2.2 UN1950 NONFLAMMABLE GAS, A34............. 306 None None 75 kg...... 150 kg..... A...... 40, 48, 85
exceeding 1 L capacity). CORROSIVE.
....... Aerosols, flammable, (each not exceeding 1 L capacity)....... 2.1 UN1950 FLAMMABLE GAS......... N82............. 306 None None 75 kg...... 150 kg..... A...... 40, 48, 85
....... Aerosols, non-flammable, (each not exceeding 1 L capacity)... 2.2 UN1950 NONFLAMMABLE GAS...... ................ 306, 307 None None 75 kg...... 150 kg..... A...... 48, 85
....... Aerosols, poison, each not exceeding 1 L capacity............ 2.2 UN1950 NONFLAMMABLE GAS...... ................ 306 None None Forbidden.. Forbidden.. A...... 40, 48, 85
....... Air bag inflators or Air bag modules or Seat-belt pre- 9 UN3268 III CLASS 9............... ................ 166 166 166 25 kg...... 100 kg..... A......
tensioners or Seat-belt modules.
....... Air, compressed.............................................. 2.2 UN1002 NONFLAMMABLE GAS...... ................ 306 302 302 75 kg...... 150 kg..... A......
....... Air, refrigerated liquid, (cryogenic liquid)................. 2.2 UN1003 NONFLAMMABLE GAS, ................ 320 316 318, 319 Forbidden.. 150 kg..... D...... 51
OXIDIZER.
....... Air, refrigerated liquid, (cryogenic liquid) non-pressurized. 2.2 UN1003 NONFLAMMABLE GAS, ................ 320 316 318, 319 Forbidden.. Forbidden.. D...... 51
OXIDIZER.
....... Aircraft evacuation slides, see Life saving appliances etc... ........... .............. ...................... ................ ........... ........... .......
....... Aircraft hydraulic power unit fuel tank (containing a mixture 3 UN3165 I FLAMMABLE LIQUID, ................ None 172 None Forbidden.. 42 L....... E......
of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel). POISON, CORROSIVE.
....... Aircraft survival kits, see Life saving appliances etc....... ........... .............. ...................... ................ ........... ........... .......
....... Alcoholates solution, n.o.s., in alcohol..................... 3 UN3274 II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Alcoholic beverages.......................................... 3 UN3065 II FLAMMABLE LIQUID...... 24, B1, T1...... 150 202 242 5 L........ 60 L....... A......
............................................................. ........... .............. III FLAMMABLE LIQUID...... 24, B1, N11, T1. 150 203 242 60 L....... 220 L...... A......
....... Alcohols, n.o.s.............................................. 3 UN1987 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Alcohols, toxic, n.o.s....................................... 3 UN1986 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... None 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Aldehydes, n.o.s............................................. 3 UN1989 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Aldehydes, toxic, n.o.s...................................... 3 UN1988 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Aldol........................................................ 6.1 UN2839 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12
D...... Aldrin, liquid............................................... 6.1 NA2762 II POISON................ ................ None 202 243 5 L........ 60 L....... B......
D...... Aldrin, solid................................................ 6.1 NA2761 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
....... Alkali metal alcoholates, self-heating, corrosive, n.o.s..... 4.2 UN3206 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... B......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... B......
COMBUSTIBLE,
CORROSIVE.
....... Alkali metal alloys, liquid, n.o.s........................... 4.3 UN1421 I DANGEROUS WHEN WET.... A2, A3, B48, N34 None 201 244 Forbidden.. 1 L........ D......
....... Alkali metal amalgams........................................ 4.3 UN1389 I DANGEROUS WHEN WET.... A2, A3, N34..... None 201 244 Forbidden.. 1 L........ D......
....... Alkali metal amides.......................................... 4.3 UN1390 II DANGEROUS WHEN WET.... A6, A7, A8, A19, None 212 241 15 kg...... 50 kg...... E...... 40
A20, B101.
....... Alkali metal dispersions, or Alkaline earth metal dispersions 4.3 UN1391 I DANGEROUS WHEN WET.... A2, A3.......... None 201 244 Forbidden.. 1 L........ D......
....... Alkaline corrosive liquids, n.o.s., see Caustic alkali ........... .............. ...................... ................ ........... ........... .......
liquids, n.o.s..
....... Alkaline earth metal alcoholates, n.o.s...................... 4.2 UN3205 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... B......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 15 kg...... 100 kg..... B......
COMBUSTIBLE.
....... Alkaline earth metal alloys, n.o.s........................... 4.3 UN1393 II DANGEROUS WHEN WET.... A19, B100....... None 212 241 15 kg...... 50 kg...... E......
....... Alkaline earth metal amalgams................................ 4.3 UN1392 I DANGEROUS WHEN WET.... A19, N34, N40... None 211 242 Forbidden.. 15 kg...... D......
....... Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s.. 6.1 UN3140 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... A......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. 6.1 UN1544 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
poisonous.
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid 8 UN2584 II CORROSIVE............. B2, T8, T27..... 154 202 242 1 L........ 30 L....... B......
with more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid 8 UN2586 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... B......
with not more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, 8 UN2583 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
with more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid 8 UN2585 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
with not more than 5 percent free sulfuric acid.
....... Alkylphenols, liquid, n.o.s. (including C2-C12 homologues)... 8 UN3145 I CORROSIVE............. T8.............. None 201 243 0.5 L...... 2.5 L...... B......
............................................................. ........... .............. II CORROSIVE............. T8.............. 154 202 242 1 L........ 30 L....... B......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Alkylphenols, solid, n.o.s. (including C2-C12 homologues).... 8 UN2430 I CORROSIVE............. T8.............. None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 213 240 25 kg...... 100 kg..... A......
....... Alkylsulfuric acids.......................................... 8 UN2571 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 14
....... Allethrin, see Pesticides, liquid, toxic, n.o.s.............. ........... .............. ...................... ................ ........... ........... .......
....... Allyl acetate................................................ 3 UN2333 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Allyl alcohol................................................ 6.1 UN1098 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, B77, T38,
T43, T45.
....... Allyl bromide................................................ 3 UN1099 I FLAMMABLE LIQUID, T18............. None 201 243 Forbidden.. 30 L....... B...... 40
POISON.
....... Allyl chloride............................................... 3 UN1100 I FLAMMABLE LIQUID, T18, T26........ None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Allyl chlorocarbonate, see Allyl chloroformate............... ........... .............. ...................... ................ ........... ........... .......
....... Allyl chloroformate.......................................... 6.1 UN1722 I POISON, FLAMMABLE 2, A3, B9, B14, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID, CORROSIVE. B32, B74, N41,
T38, T43, T45.
....... Allyl ethyl ether............................................ 3 UN2335 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Allyl formate................................................ 3 UN2336 I FLAMMABLE LIQUID, T18, T26........ None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Allyl glycidyl ether......................................... 3 UN2219 III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Allyl iodide................................................. 3 UN1723 II FLAMMABLE LIQUID, A3, A6, B100, None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE. N34, T18.
....... Allyl isothiocyanate, stabilized............................. 6.1 UN1545 II POISON................ A3, A7.......... None 202 243 Forbidden.. 60 L....... D...... 40
....... Allylamine................................................... 6.1 UN2334 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, T38, T43,
T45.
....... Allyltrichlorosilane, stabilized............................. 8 UN1724 II CORROSIVE, FLAMMABLE A7, B2, B6, N34, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T8, T26.
....... Aluminum alkyl halides....................................... 4.2 UN3052 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Aluminum alkyl hydrides...................................... 4.2 UN3076 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Aluminum alkyls.............................................. 4.2 UN3051 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Aluminum borohydride or Aluminum borohydride in devices...... 4.2 UN2870 I SPONTANEOUSLY B11............. None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE,
DANGEROUS WHEN WET.
....... Aluminum bromide, anhydrous.................................. 8 UN1725 II CORROSIVE............. B106............ 154 212 240 15 kg...... 50 kg...... A...... 40
....... Aluminum bromide, solution................................... 8 UN2580 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Aluminum carbide............................................. 4.3 UN1394 II DANGEROUS WHEN WET.... A20, B101, B106, None 212 242 15 kg...... 50 kg...... A......
N41.
....... Aluminum chloride, anhydrous................................. 8 UN1726 II CORROSIVE............. B106............ 154 212 240 15 kg...... 50 kg...... A...... 40
....... Aluminum chloride, solution.................................. 8 UN2581 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Aluminum dross, wet or hot................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Aluminum ferrosilicon powder................................. 4.3 UN1395 II DANGEROUS WHEN WET, A19, B108....... None 212 242 15 kg...... 50 kg...... A...... 40, 85, 103
POISON.
............................................................. ........... .............. III DANGEROUS WHEN WET, A19, A20........ None 213 241 25 kg...... 100 kg..... A...... 40, 85, 103
KEEP AWAY FROM FOOD.
....... Aluminum hydride............................................. 4.3 UN2463 I DANGEROUS WHEN WET.... A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... E......
D...... Aluminum, molten............................................. 9 NA9260 III CLASS 9............... ................ None None 247 Forbidden.. Forbidden.. D......
....... Aluminum nitrate............................................. 5.1 UN1438 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Aluminum phosphate solution, see Corrosive liquids, etc...... ........... .............. ...................... ................ ........... ........... .......
....... Aluminum phosphide........................................... 4.3 UN1397 I DANGEROUS WHEN WET, A8, A19, B100, None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON. N40.
....... Aluminum phosphide pesticides................................ 6.1 UN3048 I POISON................ A8.............. None 211 242 Forbidden.. 15 kg...... E...... 40, 85
....... Aluminum powder, coated...................................... 4.1 UN1309 II FLAMMABLE SOLID....... ................ 151 212 240 15 kg...... 50 kg...... A...... 13, 39, 101
............................................................. ........... .............. III FLAMMABLE SOLID....... ................ 151 213 240 25 kg...... 100 kg..... A...... 13, 39, 101
....... Aluminum powder, uncoated.................................... 4.3 UN1396 II DANGEROUS WHEN WET.... A19, A20, B108.. None 212 242 15 kg...... 50 kg...... A...... 39
............................................................. ........... .............. III DANGEROUS WHEN WET.... A19, A20........ None 213 241 25 kg...... 100 kg..... A...... 39
....... Aluminum processing by-products.............................. 4.3 UN3170 II DANGEROUS WHEN WET.... ................ None 212 242 15 kg...... 50 kg...... B...... 85, 103
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 213 241 25 kg...... 100 kg..... B...... 85, 103
....... Aluminum resinate............................................ 4.1 UN2715 III FLAMMABLE SOLID....... ................ 151 213 240 25 kg...... 100 kg..... A......
....... Aluminum silicon powder, uncoated............................ 4.3 UN1398 III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... A...... 40, 85, 103
....... Amatols, see Explosives, blasting, type B.................... ........... .............. ...................... ................ ........... ........... .......
....... Amines, flammable, corrosive, n.o.s. or Polyamines, 3 UN2733 I FLAMMABLE LIQUID, T42............. None 201 243 0.5 L...... 2.5 L...... D...... 40
flammable, corrosive, n.o.s.. CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1, T8, T31..... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, 8 UN2734 I CORROSIVE, FLAMMABLE A3, A6, N34, T8, None 201 243 0.5 L...... 2.5 L...... A......
liquid, corrosive, flammable, n.o.s.. LIQUID. T31.
............................................................. ........... .............. II CORROSIVE, FLAMMABLE T8, T31......... None 202 243 1 L........ 30 L....... A......
LIQUID.
....... Amines, liquid, corrosive, n.o.s, or Polyamines, liquid, 8 UN2735 I CORROSIVE............. A3, A6, B10, None 201 243 0.5 L...... 2.5 L...... A......
corrosive, n.o.s.. N34, T42.
............................................................. ........... .............. II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Amines, solid, corrosive, n.o.s., or Polyamines, solid, 8 UN3259 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... A......
corrosive n.o.s..
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... 2-Amino-4-chlorophenol....................................... 6.1 UN2673 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... 2-Amino-5-diethylaminopentane................................ 6.1 UN2946 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... 2-(2-Aminoethoxy) ethanol.................................... 8 UN3055 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... N-Aminoethylpiperazine....................................... 8 UN2815 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 12
....... Aminophenols (o-; m-; p-).................................... 6.1 UN2512 III KEEP AWAY FROM FOOD... T1.............. 153 213 240 100 kg..... 200 kg..... A......
....... Aminopropyldiethanolamine, see Amines,etc.................... ........... .............. ...................... ................ ........... ........... .......
....... n-Aminopropylmorpholine, see Amines, etc..................... ........... .............. ...................... ................ ........... ........... .......
....... Aminopyridines (o-; m-; p-).................................. 6.1 UN2671 II POISON................ T7.............. None 212 242 25 kg...... 100 kg..... B...... 12, 40
I...... Ammonia, anhydrous, liquefied or Ammonia solutions, relative 2.3 UN1005 POISON GAS, CORROSIVE. 4............... None 304 314, 315 Forbidden.. 25 kg...... D...... 40, 57
density less than 0.880 at 15 degrees C in water, with more
than 50 percent ammonia.
D...... Ammonia, anhydrous, liquefied or Ammonia solutions, relative 2.2 UN1005 NONFLAMMABLE GAS...... 13.............. None 304 314, 315 Forbidden.. 25 kg...... D...... 40, 57
density less than 0.880 at 15 degrees C in water, with more
than 50 percent ammonia.
....... Ammonia solutions, relative density between 0.880 and 0.957 8 UN2672 III CORROSIVE............. T14............. 154 203 241 5 L........ 60 L....... A...... 40, 85
at 15 degrees C in water, with more than 10 percent but not
more than 35 percent ammonia.
....... Ammonia solutions, relative density less than 0.880 at 15 2.2 UN2073 NONFLAMMABLE GAS...... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40, 57
degrees C in water, with more than 35 percent but not more
than 50 percent ammonia.
....... Ammonium arsenate............................................ 6.1 UN1546 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ammonium azide............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium bifluoride, solid, see Ammonium hydrogen difluoride, ........... .............. ...................... ................ ........... ........... .......
solid.
....... Ammonium bifluoride solution, see Ammonium hydrogen ........... .............. ...................... ................ ........... ........... .......
difluoride, solution.
....... Ammonium bromate............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium chlorate............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium dichromate.......................................... 5.1 UN1439 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A......
....... Ammonium dinitro-o-cresolate................................. 6.1 UN1843 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... B...... 36, 65, 66,
77
....... Ammonium fluoride............................................ 6.1 UN2505 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Ammonium fluorosilicate...................................... 6.1 UN2854 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Ammonium fulminate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium hydrogen sulfate.................................... 8 UN2506 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 40
....... Ammonium hydrogendifluoride, solid........................... 8 UN1727 II CORROSIVE............. B106, N34....... 154 212 240 15 kg...... 50 kg...... A...... 25, 26, 40
....... Ammonium hydrogendifluoride, solution........................ 8 UN2817 II CORROSIVE, POISON..... N34, T15........ None 202 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY T8.............. 154 203 241 5 L........ 60 L....... B...... 40, 95
FROM FOOD.
....... Ammonium hydrosulfide, solution, see Ammonium sulfide ........... .............. ...................... ................ ........... ........... .......
solution.
D...... Ammonium hydroxide, see Ammonia solutions, etc............... ........... .............. ...................... ................ ........... ........... .......
....... Ammonium metavanadate........................................ 6.1 UN2859 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Ammonium nitrate fertilizers................................. 5.1 NA2072 III OXIDIZER.............. 7............... 152 213 240 25 kg...... 100 kg..... B...... 48, 59, 60,
117
....... Ammonium nitrate fertilizers; uniform non-segregating 5.1 UN2067 III OXIDIZER.............. 52.............. 152 213 240 25 kg...... 100 kg..... B...... 48, 59, 60,
mixtures of ammonium nitrate with added matter which is 117
inorganic and chemically inert towards ammonium nitrate,
with not less than 90 percent ammonium nitrate and not more
than 0.2 percent combustible material (including organic
material calculated as carbon), or with more than 70 percent
but less than 90 percent ammonium nitrate and not more than
0.4 percent total combustible material..
AW..... Ammonium nitrate fertilizers: uniform non-segregating 9 UN2071 III CLASS 9............... ................ 155 213 240 200 kg..... 200 kg..... A......
mixtures of nitrogen/phosphate or nitrogen/potash types or
complete fertilizers of nitrogen/ phosphate/potash type,
with not more than 70 percent ammonium nitrate and not more
than 0.4 percent total added combustible material or with
not more than 45 percent ammonium nitrate with unrestricted
combustible material.
D...... Ammonium nitrate-fuel oil mixture containing only prilled 1.5D NA0331 II EXPLOSIVE 1.5D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
ammonium nitrate and fuel oil.
....... Ammonium nitrate, liquid (hot concentrated solution)......... 5.1 UN2426 OXIDIZER.............. B5, B100, T25... None None 243 Forbidden.. Forbidden.. D...... 59, 60
D...... Ammonium nitrate mixed fertlizers............................ 5.1 NA2069 III OXIDIZER.............. 10.............. 152 213 240 25 kg...... 100 kg..... B...... 48, 59, 60,
117
....... Ammonium nitrate, with more than 0.2 percent combustible 1.1D UN0222 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
substances, including any organic substance calculated as
carbon, to the exclusion of any other added substance.
....... Ammonium nitrate, with not more than 0.2 percent of 5.1 UN1942 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A...... 48, 59, 60,
combustible substances, including any organic substance 116
calculated as carbon, to the exclusion of any other added
substance.
....... Ammonium nitrite............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium perchlorate......................................... 1.1D UN0402 II EXPLOSIVE 1.1D........ 107............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
....... Ammonium perchlorate......................................... 5.1 UN1442 II OXIDIZER.............. 107, A9......... 152 212 242 5 kg....... 25 kg...... E...... 58, 69, 106
....... Ammonium permanganate........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Ammonium persulfate.......................................... 5.1 UN1444 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Ammonium picrate, dry or wetted with less than 10 percent 1.1D UN0004 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
water, by mass.
....... Ammonium picrate, wetted with not less than 10 percent water, 4.1 UN1310 I FLAMMABLE SOLID....... 23, A2, N41..... None 211 None 0.5 kg..... 0.5 kg..... D...... 28, 36
by mass.
....... Ammonium polysulfide, solution............................... 8 UN2818 II CORROSIVE, POISON..... T14............. None 202 243 1 L........ 30 L....... B...... 12, 26, 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY T7.............. 154 203 241 5 L........ 60 L....... B...... 12, 26, 40
FROM FOOD.
....... Ammonium polyvanadate........................................ 6.1 UN2861 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ammonium silicofluoride, see Ammonium fluorosilicate......... ........... .............. ...................... ................ ........... ........... .......
....... Ammonium sulfide solution.................................... 8 UN2683 II CORROSIVE, POISON, T14............. None 202 243 1 L........ 30 L....... B...... 12, 22, 26,
FLAMMABLE LIQUID. 100
....... Ammunition, blank, see Cartridges for weapons, blank......... ........... .............. ...................... ................ ........... ........... .......
....... Ammunition, illuminating with or without burster, expelling 1.2G UN0171 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
charge or propelling charge.
....... Ammunition, illuminating with or without burster, expelling 1.3G UN0254 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
charge or propelling charge.
....... Ammunition, illuminating with or without burster, expelling 1.4G UN0297 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
charge or propelling charge.
....... Ammunition, incendiary liquid or gel, with burster, expelling 1.3J UN0247 II EXPLOSIVE 1.3J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 13E,
charge or propelling charge. 23E
....... Ammunition, incendiary (water-activated contrivances) with ........... .............. ...................... ................ ........... ........... .......
burster, expelling charge or propelling charge, see
Contrivances, water-activated, etc..
....... Ammunition, incendiary, white phosphorus, with burster, 1.2H UN0243 II EXPLOSIVE 1.2H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
expelling charge or propelling charge. 15E, 17E
....... Ammunition, incendiary, white phosphorus, with burster, 1.3H UN0244 II EXPLOSIVE 1.3H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
expelling charge or propelling charge. 15E, 17E
....... Ammunition, incendiary with or without burster, expelling 1.2G UN0009 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
charge, or propelling charge.
....... Ammunition, incendiary with or without burster, expelling 1.3G UN0010 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
charge, or propelling charge.
....... Ammunition, incendiary with or without burster, expelling 1.4G UN0300 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
charge or propelling charge.
....... Ammunition, practice......................................... 1.4G UN0362 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
....... Ammunition, practice......................................... 1.3G UN0488 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Ammunition, proof............................................ 1.4G UN0363 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
....... Ammunition, rocket, see Warheads, rocket etc................. ........... .............. ...................... ................ ........... ........... .......
....... Ammunition, SA (small arms), see Cartridges for weapons, etc. ........... .............. ...................... ................ ........... ........... .......
....... Ammunition, smoke (water-activated contrivances), white ........... .............. ...................... ................ ........... ........... .......
phosphorus, with burster, expelling charge or propelling
charge, see Contrivances, water-activated, etc. (UN 0248).
....... Ammunition, smoke (water-activated contrivances), without ........... .............. ...................... ................ ........... ........... .......
white phosphorus or phosphides, with burster, expelling
charge or propelling charge, see Contrivances, water-
activated, etc. (UN 0249).
....... Ammunition smoke, white phosphorus with burster,expelling 1.2H UN0245 II EXPLOSIVE 1.2H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
charge, or propelling charge. 15E, 17E
....... Ammunition, smoke, white phosphorus with burster, expelling 1.3H UN0246 II EXPLOSIVE 1.3H........ ................ 62 None Forbidden.. Forbidden.. E...... 8E, 14E,
charge, or propelling charge. 15E, 17E
....... Ammunition, smoke with or without burster, expelling charge 1.2G UN0015 II EXPLOSIVE 1.2G, ................ 62 None Forbidden.. Forbidden.. E...... 17E, 20E
or propelling charge. CORROSIVE.
....... Ammunition, smoke with or without burster, expelling charge 1.3G UN0016 II EXPLOSIVE 1.3G, ................ 62 None Forbidden.. Forbidden.. E...... 17E, 20E
or propelling charge. CORROSIVE.
....... Ammunition, smoke with or without burster, expelling charge 1.4G UN0303 II EXPLOSIVE 1.4G, ................ 62 None Forbidden.. 75 kg...... E...... 17E, 20E
or propelling charge. CORROSIVE.
....... Ammunition, sporting, see Cartridges for weapons, etc. (UN ........... .............. ...................... ................ ........... ........... .......
0012; UN 0328; UN 0339).
....... Ammunition, tear-producing, non-explosive, without burster or 6.1 UN2017 II POISON, CORROSIVE..... ................ None 212 None Forbidden.. 50 kg...... E...... 13, 40
expelling charge, non-fuzed.
....... Ammunition, tear-producing with burster, expelling charge or 1.2G UN0018 II EXPLOSIVE 1.2G, ................ 62 None Forbidden.. Forbidden.. E...... 20E
propelling charge. CORROSIVE, POISON.
....... Ammunition, tear-producing with burster, expelling charge or 1.3G UN0019 II EXPLOSIVE 1.3G, ................ 62 None Forbidden.. Forbidden.. E...... 17E, 20E
propelling charge. CORROSIVE, POISON.
....... Ammunition, tear-producing with burster, expelling charge or 1.4G UN0301 II EXPLOSIVE 1.4G, ................ 62 None Forbidden.. 75 kg...... E...... 17E, 20E
propelling charge. CORROSIVE, POISON.
....... Ammunition, toxic, non-explosive, without burster or 6.1 UN2016 II POISON................ ................ None 212 None Forbidden.. 100 kg..... E...... 13, 40
expelling charge, non-fuzed.
....... Ammunition, toxic (water-activated contrivances), with ........... .............. ...................... ................ ........... ........... .......
burster, expelling charge or propelling charge, see
Contrivances, water-activated, etc..
....... Ammunition, toxic with burster, expelling charge, or 1.2K UN0020 II EXPLOSIVE 1.2K, POISON ................ 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
propelling charge. 11E, 17E
....... Ammunition, toxic with burster, expelling charge, or 1.3K UN0021 II EXPLOSIVE 1.3K, POISON ................ 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
propelling charge. 11E, 17E
....... Amyl acetates................................................ 3 UN1104 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl acid phosphate.......................................... 8 UN2819 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Amyl alcohols................................................ 3 UN1105 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B3, T1...... 150 203 242 60 L....... 220 L...... A......
....... Amyl butyrates............................................... 3 UN2620 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl chlorides............................................... 3 UN1107 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Amyl formates................................................ 3 UN1109 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl mercaptans.............................................. 3 UN1111 II FLAMMABLE LIQUID...... A3, T8.......... None 202 242 5 L........ 60 L....... B...... 95, 102
....... Amyl methyl ketone........................................... 3 UN1110 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Amyl nitrate................................................. 3 UN1112 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Amyl nitrites................................................ 3 UN1113 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 40
....... Amylamines................................................... 3 UN1106 II FLAMMABLE LIQUID, T1.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1.............. 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... n-Amylene.................................................... 3 UN1108 I FLAMMABLE LIQUID...... T14............. 150 201 243 1 L........ 30 L....... E......
....... Amyltrichlorosilane.......................................... 8 UN1728 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Anhydrous ammonia see Ammonia, anhydrous, liquefied.......... ........... .............. ...................... ................ ........... ........... .......
....... Anhydrous hydrofluoric acid, see Hydrogen fluoride, anhydrous ........... .............. ...................... ................ ........... ........... .......
+...... Aniline...................................................... 6.1 UN1547 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... Aniline hydrochloride........................................ 6.1 UN1548 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Aniline oil, see Aniline..................................... ........... .............. ...................... ................ ........... ........... .......
....... Anisidines................................................... 6.1 UN2431 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Anisole...................................................... 3 UN2222 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Anisoyl chloride............................................. 8 UN1729 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... C...... 40
....... Anti-freeze, liquid, see Flammable liquids, n.o.s............ ........... .............. ...................... ................ ........... ........... .......
....... Antimonous chloride, see Antimony trichloride................ ........... .............. ...................... ................ ........... ........... .......
....... Antimony compounds, inorganic, liquid, n.o.s................. 6.1 UN3141 III KEEP AWAY FROM FOOD... 35, T7.......... 153 203 241 60 L....... 220 L...... A......
....... Antimony compounds, inorganic, solid, n.o.s.................. 6.1 UN1549 III KEEP AWAY FROM FOOD... 35.............. 153 213 240 100 kg..... 200 kg..... A......
....... Antimony lactate............................................. 6.1 UN1550 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony pentachloride, liquid............................... 8 UN1730 II CORROSIVE............. B2, T8, T26..... None 202 242 1 L........ 30 L....... C...... 40
....... Antimony pentachloride, solutions............................ 8 UN1731 II CORROSIVE............. B2, T8, T27..... 154 202 242 1 L........ 30 L....... C...... 40
............................................................. ........... .............. III CORROSIVE............. T7, T26......... 154 203 241 5 L........ 60 L....... C...... 40
....... Antimony pentafluoride....................................... 8 UN1732 II CORROSIVE, POISON..... A3, A6, A7, A10, None 202 243 Forbidden.. 30 L....... D...... 40
N3, T12, T26.
....... Antimony potassium tartrate.................................. 6.1 UN1551 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony powder.............................................. 6.1 UN2871 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Antimony sulfide and a chlorate, mixtures of................. Forbidden .............. ...................... ................ ........... ........... .......
....... Antimony sulfide, solid, see Antimony compounds, inorganic, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
D...... Antimony tribromide, solid................................... 8 NA1549 II CORROSIVE............. ................ 154 212 240 25 kg...... 100 kg..... A...... 13
D...... Antimony tribromide, solution................................ 8 NA1549 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 13
....... Antimony trichloride, liquid................................. 8 UN1733 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 40
....... Antimony trichloride, solid.................................. 8 UN1733 II CORROSIVE............. B106............ 154 212 240 15 kg...... 50 kg...... A...... 40
D...... Antimony trifluoride, solid.................................. 8 NA1549 II CORROSIVE............. ................ 154 212 240 25 kg...... 25 kg...... A...... 13
D...... Antimony trifluoride solution................................ 8 NA1549 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 13
....... Aqua ammonia, see Ammonia solution, etc...................... ........... .............. ...................... ................ ........... ........... .......
....... Argon, compressed............................................ 2.2 UN1006 NONFLAMMABLE GAS...... ................ 306 302 314, 315 75 kg...... 150 kg..... A......
....... Argon, refrigerated liquid (cryogenic liquid)................ 2.2 UN1951 NONFLAMMABLE GAS...... ................ 320 316 318 50 kg...... 500 kg..... B......
....... Arsenic...................................................... 6.1 UN1558 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic acid, liquid......................................... 6.1 UN1553 I POISON................ T18, T27........ None 201 243 1 L........ 30 L....... B...... 46
....... Arsenic acid, solid.......................................... 6.1 UN1554 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic bromide.............................................. 6.1 UN1555 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 12, 40
....... Arsenic chloride, see Arsenic trichloride.................... ........... .............. ...................... ................ ........... ........... .......
....... Arsenic compounds, liquid, n.o.s. including arsenates n.o.s.; 6.1 UN1556 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic
compounds of arsenic, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... B...... 40
....... Arsenic compounds, solid, n.o.s. including arsenates, n.o.s.; 6.1 UN1557 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic
compounds of arsenic, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Arsenic pentoxide............................................ 6.1 UN1559 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Arsenic sulfide.............................................. 6.1 NA1557 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic sulfide and a chlorate, mixtures of.................. Forbidden .............. ...................... ................ ........... ........... .......
....... Arsenic trichloride.......................................... 6.1 UN1560 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
B74, T38, T43,
T45.
....... Arsenic trioxide............................................. 6.1 UN1561 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Arsenic trisulfide........................................... 6.1 NA1557 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenic, white, solid, see Arsenic trioxide.................. ........... .............. ...................... ................ ........... ........... .......
....... Arsenical dust............................................... 6.1 UN1562 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Arsenical pesticides, liquid, flammable, toxic, flash point 3 UN2760 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Arsenical pesticides, liquid, toxic.......................... 6.1 UN2994 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Arsenical pesticides, liquid, toxic, flammable flashpoint not 6.1 UN2993 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Arsenical pesticides, solid, toxic........................... 6.1 UN2759 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Arsenious acid, solid, see Arsenic trioxide.................. ........... .............. ...................... ................ ........... ........... .......
....... Arsenious and mercuric iodide solution, see Arsenic ........... .............. ...................... ................ ........... ........... .......
compounds, liquid, n.o.s..
....... Arsine....................................................... 2.3 UN2188 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Articles, explosive, extremely insensitive or Articles, EEI.. 1.6N UN0486 II EXPLOSIVE 1.6N........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.4S UN0349 II EXPLOSIVE 1.4S........ 101............. None 62 None 25 kg...... 100 kg..... A......
....... Articles, explosive, n.o.s................................... 1.4B UN0350 II EXPLOSIVE 1.4B........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.4C UN0351 II EXPLOSIVE 1.4C........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.4D UN0352 II EXPLOSIVE 1.4D........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.4G UN0353 II EXPLOSIVE 1.4G........ 101............. None 62 None Forbidden.. Forbidden.. A...... 24E
....... Articles, explosive, n.o.s................................... 1.1L UN0354 II EXPLOSIVE 1.1L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, explosive, n.o.s................................... 1.2L UN0355 II EXPLOSIVE 1.2L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, explosive, n.o.s................................... 1.3L UN0356 II EXPLOSIVE 1.3L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, explosive, n.o.s................................... 1.1C UN0462 II EXPLOSIVE 1.1C........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.1D UN0463 II EXPLOSIVE 1.1D........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.1E UN0464 II EXPLOSIVE 1.1E........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.1F UN0465 II EXPLOSIVE 1.1F........ 101............. None 62 None Forbidden.. Forbidden.. E......
....... Articles, explosive, n.o.s................................... 1.2C UN0466 II EXPLOSIVE 1.2C........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.2D UN0467 II EXPLOSIVE 1.2D........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.2E UN0468 II EXPLOSIVE 1.2E........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.2F UN0469 II EXPLOSIVE 1.2F........ 101............. None 62 None Forbidden.. Forbidden.. E......
....... Articles, explosive, n.o.s................................... 1.3C UN0470 II EXPLOSIVE 1.3C........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Articles, explosive, n.o.s................................... 1.4E UN0471 II EXPLOSIVE 1.4E........ 101............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Articles, explosive, n.o.s................................... 1.4F UN0472 II EXPLOSIVE 1.4F........ 101............. None 62 None Forbidden.. Forbidden.. E......
....... Articles, pressurized pneumatic or Hydraulic containing non- 2.2 UN3164 NONFLAMMABLE GAS...... ................ 306 302, 304 None No limit... No limit... A......
flammable gas.
....... Articles, pyrophoric......................................... 1.2L UN0380 II EXPLOSIVE 1.2L........ ................ None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Articles, pyrotechnic for technical purposes................. 1.1G UN0428 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Articles, pyrotechnic for technical purposes................. 1.2G UN0429 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Articles, pyrotechnic for technical purposes................. 1.3G UN0430 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Articles, pyrotechnic for technical purposes................. 1.4G UN0431 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Articles, pyrotechnic for technical purposes................. 1.4S UN0432 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
D...... Asbestos..................................................... 9 NA2212 III CLASS 9............... ................ 155 216 240 200 kg..... 200 kg..... A...... 34, 40
....... Ascaridole (organic peroxide)................................ Forbidden .............. ...................... ................ ........... ........... .......
D...... Asphalt, at or above its flashpoint.......................... 3 NA1999 III FLAMMABLE LIQUID...... ................ 150 203 247 Forbidden.. Forbidden.. D......
D...... Asphalt, cut back, see Tars, liquid, etc..................... ........... .............. ...................... ................ ........... ........... .......
....... Automobile, motorcycle, tractor, or other self-propelled ........... .............. ...................... ................ ........... ........... .......
vehicle, engine, or other mechanical apparatus. see Engines
or Battery etc..
....... Azaurolic acid (salt of) (dry)............................... Forbidden .............. ...................... ................ ........... ........... .......
....... Azido guanidine picrate (dry)................................ Forbidden .............. ...................... ................ ........... ........... .......
....... 5-Azido-1-hydroxy tetrazole.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Azido hydroxy tetrazole (mercury and silver salts)........... Forbidden .............. ...................... ................ ........... ........... .......
....... 3-Azido-1,2-Propylene glycol dinitrate....................... Forbidden .............. ...................... ................ ........... ........... .......
....... Azidodithiocarbonic acid..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Azidoethyl nitrate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 1-Aziridinylphosphine oxide-(tris), see Tris-(1-aziridinyl) ........... .............. ...................... ................ ........... ........... .......
phosphine oxide, solution.
....... Azotetrazole (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Barium....................................................... 4.3 UN1400 II DANGEROUS WHEN WET.... A19, B100....... None 212 241 15 kg...... 50 kg...... E......
....... Barium alloys, pyrophoric.................................... 4.2 UN1854 I SPONTANEOUSLY ................ None 181 None Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Barium azide, dry or wetted with less than 50 percent water, 1.1A UN0224 II EXPLOSIVE 1.1A, POISON 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
by mass.
....... Barium azide, wetted with not less than 50 percent water, by 4.1 UN1571 I FLAMMABLE SOLID, A2.............. None 182 None Forbidden.. 0.5 kg..... D...... 28
mass. POISON.
....... Barium bromate............................................... 5.1 UN2719 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Barium chlorate.............................................. 5.1 UN1445 II OXIDIZER, POISON...... A9, N34, T8..... None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Barium compounds, n.o.s...................................... 6.1 UN1564 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Barium cyanide............................................... 6.1 UN1565 I POISON................ N74, N75........ None 211 242 5 kg....... 50 kg...... A...... 26, 40
....... Barium hypochlorite with more than 22 percent available 5.1 UN2741 II OXIDIZER, POISON...... A7, A9, N34..... 152 212 None 5 kg....... 25 kg...... B...... 56, 58, 106
chlorine.
....... Barium nitrate............................................... 5.1 UN1446 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A......
....... Barium oxide................................................. 6.1 UN1884 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Barium perchlorate........................................... 5.1 UN1447 II OXIDIZER, POISON...... T8.............. None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Barium permanganate.......................................... 5.1 UN1448 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Barium peroxide.............................................. 5.1 UN1449 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Barium selenate, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
....... Barium selenite, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
D...... Barium styphnate............................................. 1.1A NA0473 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Batteries, containing sodium................................. 4.3 UN3292 II DANGEROUS WHEN WET.... ................ 189 189 189 Forbidden.. No limit... A......
....... Batteries, dry, containing potassium hydroxide solid, 8 UN3028 III CORROSIVE............. ................ None 213 None 25 kg gross 230 kg A......
electric, storage. gross.
....... Batteries, wet, filled with acid, electric storage........... 8 UN2794 III CORROSIVE............. ................ 159 159 159 25 kg gross No limit... A......
....... Batteries, wet, filled with alkali, electric storage......... 8 UN2795 III CORROSIVE............. ................ 159 159 159 25 kg gross No limit... A......
....... Batteries, wet, non-spillable, electric storage.............. 8 UN2800 III CORROSIVE............. ................ 159 159 159 No Limit... No Limit... A......
....... Battery, dry, not subject to the requirements of this ........... .............. ...................... ................ ........... ........... .......
subchapter.
....... Battery fluid, acid.......................................... 8 UN2796 II CORROSIVE............. A3, A7, B2, B15, 154 202 242 1 L........ 30 L....... B......
N6, N34, T9,
T27.
....... Battery fluid, alkali........................................ 8 UN2797 II CORROSIVE............. B2, N6, T8...... 154 202 242 1 L........ 30 L....... A......
....... Battery lithium type, see Lithium batteries etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Battery-powered vehicle or Battery-powered equipment wet 9 UN3171 CLASS 9............... ................ 220 220 None No limit... No limit... A......
battery.
....... Battery, wet, filled with acid or alkali with automobile (or ........... .............. ...................... ................ ........... ........... .......
named self-propelled vehicle or mechanical equipment
containing internal combustion engine) see Vehicles, self-
propelled etc..
....... Battery, wet, with wheelchair, see Wheelchair, electric...... ........... .............. ...................... ................ ........... ........... .......
....... Benzaldehyde................................................. 9 UN1990 III CLASS 9............... ................ 155 203 241 100 L...... 220 L...... A......
....... Benzene...................................................... 3 UN1114 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... B...... 40
....... Benzene diazonium chloride (dry)............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Benzene diazonium nitrate (dry).............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Benzene phosphorus dichloride, see Phenyl phosphorus ........... .............. ...................... ................ ........... ........... .......
dichloride.
....... Benzene phosphorus thiodichloride, see Phenyl phosphorus ........... .............. ...................... ................ ........... ........... .......
thiodichloride.
....... Benzene sulfonyl chloride.................................... 8 UN2225 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Benzene triozonide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Benzenethiol, see Phenyl mercaptan........................... ........... .............. ...................... ................ ........... ........... .......
....... Benzidine.................................................... 6.1 UN1885 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Benzoic derivative pesticides, liquid, flammable, toxic, 3 UN2770 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... E......
flash point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Benzoic derivative pesticides, liquid, toxic................. 6.1 UN3004 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Benzoic derivative pesticides, liquid, toxic, flammable, 6.1 UN3003 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Benzoic derivative pesticides, solid toxic................... 6.1 UN2769 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Benzol, see Benzene.......................................... ........... .............. ...................... ................ ........... ........... .......
....... Benzonitrile................................................. 6.1 UN2224 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 26, 40
....... Benzoquinone................................................. 6.1 UN2587 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Benzotrichloride............................................. 8 UN2226 II CORROSIVE............. B2, B101, T15... 154 202 242 1 L........ 30 L....... A...... 40
....... Benzotrifluoride............................................. 3 UN2338 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Benzoxidiazoles (dry)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Benzoyl azide................................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Benzoyl chloride............................................. 8 UN1736 II CORROSIVE............. B2, T9, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Benzyl bromide............................................... 6.1 UN1737 II POISON, CORROSIVE..... A3, A7, N33, None 202 243 1 L........ 30 L....... D...... 13, 40
N34, T12, T26.
....... Benzyl chloride.............................................. 6.1 UN1738 II POISON, CORROSIVE..... A3, A7, B41, None 202 243 1 L........ 30 L....... D...... 13, 40
B70, N33, N43,
T12, T26.
....... Benzyl chloride unstabilized................................. 6.1 UN1738 II POISON, CORROSIVE..... A3, A7, B8, B11, None 202 243 1 L........ 30 L....... D...... 13, 40
N33, N34, N43,
T12, T26.
....... Benzyl chloroformate......................................... 8 UN1739 I CORROSIVE............. A3, A6, B4, N41, None 201 243 Forbidden.. 2.5 L...... D...... 40
T18, T26.
....... Benzyl iodide................................................ 6.1 UN2653 II POISON................ T8.............. None 202 243 5 L........ 60 L....... B...... 12, 40
....... Benzyldimethylamine.......................................... 8 UN2619 II CORROSIVE, FLAMMABLE B2, T1.......... 154 202 243 1 L........ 30 L....... A...... 40, 48
LIQUID.
....... Benzylidene chloride......................................... 6.1 UN1886 II POISON................ T8.............. None 202 243 5 L........ 60 L....... D...... 40
....... Beryllium compounds, n.o.s................................... 6.1 UN1566 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Beryllium nitrate............................................ 5.1 UN2464 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A......
....... Beryllium, powder............................................ 6.1 UN1567 II POISON, FLAMMABLE ................ None 212 242 15 kg...... 50 kg...... A......
SOLID.
....... Biphenyl triozonide.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Bipyridilium pesticides, liquid, flammable, toxic, flash 3 UN2782 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... E......
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Bipyridilium pesticides, liquid, toxic....................... 6.1 UN3016 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Bipyridilium pesticides, liquid, toxic, flammable, flashpoint 6.1 UN3015 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 21, 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 21, 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 21, 40
FLAMMABLE LIQUID.
....... Bipyridilium pesticides, solid, toxic........................ 6.1 UN2781 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Bis (Aminopropyl) piperazine, see Corrosive liquid, n.o.s.... ........... .............. ...................... ................ ........... ........... .......
....... Bisulfate, aqueous solution.................................. 8 UN2837 II CORROSIVE............. A7, B2, N34, T8, 154 202 242 1 L........ 30 L....... A......
T26.
............................................................. ........... .............. III CORROSIVE............. A7, N34, T7, T26 154 203 241 5 L........ 60 L....... A......
....... Bisulfites, aqueous solutions, n.o.s......................... 8 UN2693 III CORROSIVE............. T8.............. 154 203 241 1 L........ 30 L....... A...... 26, 40
....... Black powder, compressed or Gunpowder, compressed or Black 1.1D UN0028 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
powder, in pellets or Gunpowder, in pellets.
....... Black powder or Gunpowder, granular or as a meal............. 1.1D UN0027 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 10E, 26E
....... Blasting agent, n.o.s., see Explosives, blasting etc......... ........... .............. ...................... ................ ........... ........... .......
....... Blasting cap assemblies, see Detonator assemblies, non- ........... .............. ...................... ................ ........... ........... .......
electric, for blasting.
....... Blasting caps, electric, see Detonators, electric for ........... .............. ...................... ................ ........... ........... .......
blasting.
....... Blasting caps, non-electric, see Detonators, non-electric, ........... .............. ...................... ................ ........... ........... .......
for blasting.
....... Bleaching powder, see Calcium hypochlorite mixtures, etc..... ........... .............. ...................... ................ ........... ........... .......
I...... Blue asbestos (Crocidolite) or Brown asbestos (amosite, 9 UN2212 II CLASS 9............... ................ 155 216 240 Forbidden.. Forbidden.. A...... 34, 40
mysorite).
....... Bombs, photo-flash........................................... 1.1F UN0037 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Bombs, photo-flash........................................... 1.1D UN0038 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Bombs, photo-flash........................................... 1.2G UN0039 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Bombs, photo-flash........................................... 1.3G UN0299 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Bombs, smoke, non-explosive, with corrosive liquid, without 8 UN2028 II CORROSIVE............. ................ None 160 None Forbidden.. 50 kg...... E...... 40
initiating device.
....... Bombs, with bursting charge.................................. 1.1F UN0033 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Bombs, with bursting charge.................................. 1.1D UN0034 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Bombs, with bursting charge.................................. 1.2D UN0035 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Bombs, with bursting charge.................................. 1.2F UN0291 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Bombs with flammable liquid, with bursting charge............ 1.1J UN0399 II EXPLOSIVE 1.1J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Bombs with flammable liquid, with bursting charge............ 1.2J UN0400 II EXPLOSIVE 1.2J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
D...... Boosters with detonator...................................... 1.4B NA0350 II EXPLOSIVE 1.4B........ 115............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Boosters with detonator...................................... 1.1B UN0225 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Boosters with detonator...................................... 1.2B UN0268 II EXPLOSIVE 1.2B........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 7E
....... Boosters, without detonator.................................. 1.1D UN0042 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Boosters, without detonator.................................. 1.2D UN0283 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Borate and chlorate mixtures, see Chlorate and borate ........... .............. ...................... ................ ........... ........... .......
mixtures.
....... Borneol...................................................... 4.1 UN1312 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... A......
+...... Boron tribromide............................................. 8 UN2692 I CORROSIVE, POISON..... 2, A3, A7, B9, None 227 244 Forbidden.. 2.5 L...... C...... 12
B14, B32, B74,
N34, T38, T43,
T45.
....... Boron trichloride............................................ 2.3 UN1741 POISON GAS, CORROSIVE. 3, 25, B9, B14.. None 304 314 Forbidden.. Forbidden.. D...... 25, 40
....... Boron trifluoride............................................ 2.3 UN1008 POISON GAS............ 2, B9, B14...... None 302 314, 315 Forbidden.. Forbidden.. D...... 40
....... Boron trifluoride acetic acid complex........................ 8 UN1742 II CORROSIVE............. B2, B6, T9, T27. 154 202 242 1 L........ 30 L....... A......
....... Boron trifluoride diethyl etherate........................... 8 UN2604 I CORROSIVE, FLAMMABLE A19, T8, T26.... None 201 243 0.5 L...... 2.5 L...... D...... 40
LIQUID.
....... Boron trifluoride dihydrate.................................. 8 UN2851 II CORROSIVE............. T9, T27......... 154 212 240 15 kg...... 50 kg...... B...... 12, 40,
....... Boron trifluoride dimethyl etherate.......................... 4.3 UN2965 I DANGEROUS WHEN WET, A19, T12, T26... None 201 243 Forbidden.. 1 L........ D...... 21, 28, 40,
CORROSIVE, FLAMMABLE 49, 100
LIQUID.
....... Boron trifluoride propionic acid complex..................... 8 UN1743 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... A......
....... Box toe gum, see Nitrocellulose etc.......................... ........... .............. ...................... ................ ........... ........... .......
....... Bromates, inorganic, aqueous solution, n.o.s................. 5.1 UN3213 II OXIDIZER.............. T8.............. 152 2O2 242 1 L........ 5 L........ B...... 56, 58, 106
....... Bromates, inorganic, n.o.s................................... 5.1 UN1450 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Bromine azide................................................ Forbidden .............. ...................... ................ ........... ........... .......
+...... Bromine or Bromine solutions................................. 8 UN1744 I CORROSIVE, POISON..... 1, A3, A6, B9, None 226 249 Forbidden.. 2.5 L...... D...... 12, 40, 66,
B12, B64, B85, 74, 89, 90
N34, N43, T18,
T41.
....... Bromine chloride............................................. 2.3 UN2901 POISON GAS, CORROSIVE, 2, B9, B12, B14. None 304 314, 315 Forbidden.. Forbidden.. D...... 40, 89, 90
OXIDIZER.
+...... Bromine pentafluoride........................................ 5.1 UN1745 I OXIDIZER, POISON, 1, B9, B14, B30, None 228 244 Forbidden.. Forbidden.. D...... 25, 40, 66,
CORROSIVE. B72, T38, T43, 90
T44.
+...... Bromine trifluoride.......................................... 5.1 UN1746 I OXIDIZER, POISON, 2, B9, B14, B32, None 228 244 Forbidden.. Forbidden.. D...... 25, 40, 66,
CORROSIVE. B74, T38, T43, 90
T45.
....... 4-Bromo-1,2-dinitrobenzene................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C.)....... Forbidden .............. ...................... ................ ........... ........... .......
....... 1-Bromo-3-methylbutane....................................... 3 UN2341 III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... 1-Bromo-3-nitrobenzene (unstable at 56 degrees C)............ Forbidden .............. ...................... ................ ........... ........... .......
I...... 2-Bromo-2-nitropropane-1,3-diol.............................. 6.1 UN3241 III KEEP AWAY FROM FOOD... 46.............. 153 213 240 50 kg...... 50 kg...... C...... 12, 25, 40
....... Bromoacetic acid, solid...................................... 8 UN1938 II CORROSIVE............. A7, N34, T9..... 154 212 240 15 kg...... 50 kg...... A......
....... Bromoacetic acid, solution................................... 8 UN1938 II CORROSIVE............. B2, T9.......... 154 202 242 1 L........ 30 L....... A...... 40
+...... Bromoacetone................................................. 6.1 UN1569 II POISON................ 2............... None 193 245 Forbidden.. Forbidden.. D...... 40
....... Bromoacetyl bromide.......................................... 8 UN2513 II CORROSIVE............. B2, T9, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Bromobenzene................................................. 3 UN2514 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Bromobenzyl cyanides, liquid................................. 6.1 UN1694 I POISON................ T18............. None 201 243 Forbidden.. 30 L....... D...... 12, 40
....... Bromobenzyl cyanides, solid.................................. 6.1 UN1694 I POISON................ T18............. None 211 242 Forbidden.. 50 kg...... D...... 12, 40
....... 2-Bromobutane................................................ 3 UN2339 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B...... 40
....... Bromochloromethane........................................... 6.1 UN1887 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... 2-Bromoethyl ethyl ether..................................... 3 UN2340 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Bromoform.................................................... 6.1 UN2515 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 12, 40
....... Bromomethylpropanes.......................................... 3 UN2342 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
....... 2-Bromopentane............................................... 3 UN2343 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... 2-Bromopropanes.............................................. 3 UN2344 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B...... 40
....... 3-Bromopropyne............................................... 3 UN2345 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... D...... 40
....... Bromosilane.................................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Bromotoluene-alpha, see Benzyl bromide....................... ........... .............. ...................... ................ ........... ........... .......
....... Bromotrifluoroethylene....................................... 2.1 UN2419 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Bromotrifluoromethane, R13B1................................. 2.2 UN1009 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Brucine...................................................... 6.1 UN1570 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
....... Bursters, explosive.......................................... 1.1D UN0043 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Butadienes, inhibited........................................ 2.1 UN1010 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Butane or Butane mixtures see also Petroleum gases, liquefied 2.1 UN1011 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Butane, butane mixtures and mixtures having similar ........... .............. ...................... ................ ........... ........... .......
properties in cartridges each not exceeding 500 grams, see
Receptacles, etc..
....... Butanedione.................................................. 3 UN2346 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... 1,2,4-Butanetriol trinitrate................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Butanols..................................................... 3 UN1120 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... tert-Butoxycarbonyl azide.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Butoxyl...................................................... 3 UN2708 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyl acetates............................................... 3 UN1123 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyl acid phosphate......................................... 8 UN1718 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Butyl alcohols, see Butanols................................. ........... .............. ...................... ................ ........... ........... .......
....... Butyl benzenes............................................... 3 UN2709 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... n-Butyl bromide.............................................. 3 UN1126 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B...... 40
....... n-Butyl chloride, see Chlorobutanes.......................... ........... .............. ...................... ................ ........... ........... .......
D...... sec-Butyl chloroformate...................................... 6.1 NA2742 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 1 L........ 30 L....... A...... 12, 13, 22,
LIQUID, CORROSIVE. B74, T38, T43, 25, 40,
T45. 48, 100
....... n-Butyl chloroformate........................................ 6.1 UN2743 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 1 L........ 30 L....... A...... 12, 13, 21,
B74, T38, T43, 25, 40,
T45. 100
....... Butyl ethers, see Dibutyl ethers............................. ........... .............. ...................... ................ ........... ........... .......
....... Butyl ethyl ether, see Ethyl butyl ether..................... ........... .............. ...................... ................ ........... ........... .......
....... n-Butyl formate.............................................. 3 UN1128 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... tert-Butyl hydroperoxide, with more than 90 percent with Forbidden .............. ...................... ................ ........... ........... .......
water.
....... tert-Butyl hypochlorite...................................... 4.2 UN3255 I SPONTANEOUSLY ................ None 211 243 Forbidden.. Forbidden.. D......
COMBUSTIBLE,
CORROSIVE.
....... N-n-Butyl imidazole.......................................... 6.1 UN2690 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... tert-Butyl isocyanate........................................ 6.1 UN2484 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B72, T38,
T43, T44.
....... n-Butyl isocyanate........................................... 6.1 UN2485 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. 30 L....... D...... 40
LIQUID. B30, B72, B77,
T38, T43, T44.
....... Butyl mercaptans............................................. 3 UN2347 II FLAMMABLE LIQUID...... A3, T8.......... 150 202 242 5 L........ 60 L....... D...... 26, 95
....... n-Butyl methacrylate......................................... 3 UN2227 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyl methyl ether........................................... 3 UN2350 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Butyl nitrites............................................... 3 UN2351 I FLAMMABLE LIQUID...... T8.............. 150 201 243 1 L........ 30 L....... E...... 40
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A...... 40
....... tert-Butyl peroxyacetate, with more than 76 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... n-Butyl peroxydicarbonate, with more than 52 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... tert-Butyl peroxyisobutyrate, with more than 77 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Butyl phosphoric acid, see Butyl acid phosphate.............. ........... .............. ...................... ................ ........... ........... .......
....... 5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene.......... 4.1 UN2956 III FLAMMABLE SOLID....... ................ None 214 None Forbidden.. Forbidden.. D...... 12
....... Butyl vinyl ether, inhibited................................. 3 UN2352 II FLAMMABLE LIQUID...... B101, T7........ 150 202 242 5 L........ 60 L....... B...... 40
....... Butylacrylate................................................ 3 UN2348 III FLAMMABLE LIQUID...... B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
....... n-Butylamine................................................. 3 UN1125 II FLAMMABLE LIQUID, B101, T8........ None 202 242 1 L........ 5 L........ B...... 40
CORROSIVE.
....... N-Butylaniline............................................... 6.1 UN2738 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... tert-Butylcyclohexylchloroformate............................ 6.1 UN2747 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 12, 13, 25
....... Butylene see also Petroleum gases, liquefied................. 2.1 UN1012 FLAMMABLE GAS......... 19.............. None 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... 1,2-Butylene oxide, stabilized............................... 3 UN3022 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 49
....... Butylpropionate.............................................. 3 UN1914 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyltoluenes................................................ 6.1 UN2667 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Butyltrichlorosilane......................................... 8 UN1747 II CORROSIVE, FLAMMABLE A7, B2, B6, N34, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T8, T26.
....... 1,4-Butynediol............................................... 6.1 UN2716 III KEEP AWAY FROM FOOD... A1.............. None 213 240 100 kg..... 200 kg..... A...... 61, 70
....... Butyraldehyde................................................ 3 UN1129 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Butyraldoxime................................................ 3 UN2840 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Butyric acid................................................. 8 UN2820 III CORROSIVE............. T1.............. 154 203 241 5 L........ 60 L....... A...... 12
....... Butyric anhydride............................................ 8 UN2739 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... Butyronitrile................................................ 3 UN2411 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Butyryl chloride............................................. 3 UN2353 II FLAMMABLE LIQUID, B100, T9, T26... None 202 243 1 L........ 5 L........ C...... 40
CORROSIVE.
....... Cacodylic acid............................................... 6.1 UN1572 II POISON................ ................ None 212 242 25 kg...... 100 kg..... E...... 26
....... Cadmium compounds............................................ 6.1 UN2570 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Caesium hydroxide............................................ 8 UN2682 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Caesium hydroxide solution................................... 8 UN2681 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Calcium...................................................... 4.3 UN1401 II DANGEROUS WHEN WET.... B100............ None 212 241 15 kg...... 50 kg...... E......
....... Calcium arsenate............................................. 6.1 UN1573 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Calcium arsenate and calcium arsenite, mixtures, solid....... 6.1 UN1574 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Calcium arsenite, solid...................................... 6.1 NA1574 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Calcium bisulfite solution, see Bisulfites, inorganic, ........... .............. ...................... ................ ........... ........... .......
aqueous solutions, n.o.s..
....... Calcium carbide.............................................. 4.3 UN1402 I DANGEROUS WHEN WET.... A1, A8, B55, N34 None 211 242 Forbidden.. 15 kg...... B......
............................................................. ........... .............. II DANGEROUS WHEN WET.... A1, A8, B55, None 212 241 15 kg...... 50 kg...... B......
B101, B106, N34.
....... Calcium chlorate............................................. 5.1 UN1452 II OXIDIZER.............. N34............. 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Calcium chlorate aqueous solution............................ 5.1 UN2429 II OXIDIZER.............. A2, N41, T8..... 152 202 242 1 L........ 5 L........ B...... 56, 58, 106
....... Calcium chlorite............................................. 5.1 UN1453 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Calcium cyanamide with more than 0.1 percent of calcium 4.3 UN1403 III DANGEROUS WHEN WET.... A1, A19, B105... None 213 241 25 kg...... 100 kg..... A......
carbide.
....... Calcium cyanide.............................................. 6.1 UN1575 I POISON................ N79, N80........ None 211 242 5 kg....... 50 kg...... A...... 26, 40
....... Calcium dithionite or Calcium hydrosulfite................... 4.2 UN1923 II SPONTANEOUSLY A19, A20........ None 212 241 15 kg...... 50 kg...... E...... 13
COMBUSTIBLE.
....... Calcium hydride.............................................. 4.3 UN1404 I DANGEROUS WHEN WET.... A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... E......
....... Calcium hydrosulfite, see Calcium dithionite................. ........... .............. ...................... ................ ........... ........... .......
....... Calcium hypochlorite, dry or Calcium hypochlorite mixtures 5.1 UN1748 II OXIDIZER.............. A7, A9, N34..... 152 212 None 5 kg....... 25 kg...... D...... 48, 56, 58,
dry with more than 39 percent available chlorine (8.8 69, 106,
percent available oxygen). 118
....... Calcium hypochlorite, hydrated or Calcium hypochlorite, 5.1 UN2880 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 50, 56, 58,
hydrated mixtures, with not less than 5.5 percent but not 69, 106
more than 10 percent water.
....... Calcium hypochlorite mixtures, dry, with more than 10 percent 5.1 UN2208 III OXIDIZER.............. A1, A29, B103, 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 69,
but not more than 39 percent available chlorine. N34. 106
....... Calcium manganese silicon.................................... 4.3 UN2844 III DANGEROUS WHEN WET.... A1, A19, B105, None 213 241 25 kg...... 100 kg..... A...... 85, 103
B106.
....... Calcium nitrate.............................................. 5.1 UN1454 III OXIDIZER.............. 34.............. 152 213 240 25 kg...... 100 kg..... A......
A...... Calcium oxide................................................ 8 UN1910 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Calcium perchlorate.......................................... 5.1 UN1455 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Calcium permanganate......................................... 5.1 UN1456 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Calcium peroxide............................................. 5.1 UN1457 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Calcium phosphide............................................ 4.3 UN1360 I DANGEROUS WHEN WET, A8, A19, B100, None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON. N40.
....... Calcium, pyrophoric or Calcium alloys, pyrophoric............ 4.2 UN1855 I SPONTANEOUSLY ................ None 187 None Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Calcium resinate............................................. 4.1 UN1313 III FLAMMABLE SOLID....... A1, A19......... None 213 240 25 kg...... 100 kg..... A......
....... Calcium resinate, fused...................................... 4.1 UN1314 III FLAMMABLE SOLID....... A1, A19......... None 213 240 25 kg...... 100 kg..... A......
....... Calcium selenate, see Selenates or Selenites................. ........... .............. ...................... ................ ........... ........... .......
....... Calcium silicide............................................. 4.3 UN1405 II DANGEROUS WHEN WET.... A19, B106, B108. None 212 241 15 kg...... 50 kg...... B...... 85, 103
............................................................. ........... .............. III DANGEROUS WHEN WET.... A1, A19......... None 213 241 25 kg...... 100 kg..... B...... 85, 103
....... Camphor oil.................................................. 3 UN1130 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Camphor, synthetic........................................... 4.1 UN2717 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... A......
....... Cannon primers, see Primers, tubular......................... ........... .............. ...................... ................ ........... ........... .......
....... Caproic acid................................................. 8 UN2829 III CORROSIVE............. T1.............. 154 203 241 5 L........ 60 L....... A......
....... Caps, blasting, see Detonators, etc.......................... ........... .............. ...................... ................ ........... ........... .......
....... Carbamate pesticides, liquid, flammable, toxic, flash point 3 UN2758 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Carbamate pesticides, liquid, toxic.......................... 6.1 UN2992 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Carbamate pesticides, liquid, toxic, flammable, flash point 6.1 UN2991 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Carbamate pesticides, solid, toxic........................... 6.1 UN2757 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Carbolic acid, see Phenol, solid or Phenol, molten........... ........... .............. ...................... ................ ........... ........... .......
....... Carbolic acid solutions, see Phenol solutions................ ........... .............. ...................... ................ ........... ........... .......
I...... Carbon, activated............................................ 4.2 UN1362 III SPONTANEOUSLY ................ None 213 241 0.5 kg..... 0.5 kg..... A...... 12
COMBUSTIBLE.
I...... Carbon, animal or vegetable origin........................... 4.2 UN1361 II SPONTANEOUSLY ................ None 212 242 Forbidden.. Forbidden.. A...... 12
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A...... 12
COMBUSTIBLE.
....... Carbon bisulfide, see Carbon disulfide....................... ........... .............. ...................... ................ ........... ........... .......
....... Carbon dioxide............................................... 2.2 UN1013 NONFLAMMABLE GAS...... ................ 306 302, 304 302, 314, 75 kg...... 150 kg..... A......
315
....... Carbon dioxide and nitrous oxide mixtures.................... 2.2 UN1015 NONFLAMMABLE GAS...... ................ 306 None 314, 315 75 kg...... 150 kg..... A......
....... Carbon dioxide and oxygen mixtures........................... 2.2 UN1014 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Carbon dioxide, refrigerated liquid.......................... 2.2 UN2187 NONFLAMMABLE GAS...... B43............. 306 304 314, 315 50 kg...... 500 kg..... B......
AW..... Carbon dioxide, solid or Dry ice............................. 9 UN1845 III None.................. B12............. 217 217 240 200 kg..... 200 kg..... C...... 40
....... Carbon disulfide............................................. 3 UN1131 I FLAMMABLE LIQUID, B16, T18, T26, None 201 243 Forbidden.. Forbidden.. D...... 18, 40, 115
POISON. T29.
....... Carbon monoxide.............................................. 2.3 UN1016 POISON GAS, FLAMMABLE 4............... None 302 314, 315 Forbidden.. 25 kg...... D...... 40
GAS.
....... Carbon monoxide and hydrogen mixture......................... 2.3 UN2600 POISON GAS, FLAMMABLE 6............... None 302 302 Forbidden.. Forbidden.. D...... 40
GAS.
D...... Carbon monoxide, refrigerated liquid (cryogenic liquid)...... 2.3 NA9202 POISON GAS, FLAMMABLE 4............... None 316 318 Forbidden.. Forbidden.. D......
GAS.
....... Carbon tetrabromide.......................................... 6.1 UN2516 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 25
....... Carbon tetrachloride......................................... 6.1 UN1846 II POISON................ N36, T8......... None 202 243 5 L........ 60 L....... A...... 40
....... Carbonyl chloride, see Phosgene.............................. ........... .............. ...................... ................ ........... ........... .......
....... Carbonyl fluoride............................................ 2.3 UN2417 POISON GAS, CORROSIVE. 2............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Carbonyl sulfide............................................. 2.3 UN2204 POISON GAS, FLAMMABLE 3, 25, B14...... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
GAS.
....... Cartridge cases, empty primed, see Cases, cartridge, empty, ........... .............. ...................... ................ ........... ........... .......
with primer.
....... Cartridges, actuating, for aircraft ejector seat catapult, ........... .............. ...................... ................ ........... ........... .......
fire extinguisher, canopy removal or apparatus, see
Cartridges, power device.
....... Cartridges, explosive, see Charges, demolition............... ........... .............. ...................... ................ ........... ........... .......
....... Cartridges, flash............................................ 1.1G UN0049 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges, flash............................................ 1.3G UN0050 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Cartridges for weapons, blank................................ 1.1C UN0326 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, blank................................ 1.2C UN0413 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, blank or Cartridges, small arms, 1.4S UN0014 II None.................. 112............. None 62 None 25 kg...... 100 kg..... A......
blank.
....... Cartridges for weapons, blank or Cartridges, small arms, 1.3C UN0327 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
blank.
....... Cartridges for weapons, blank or Cartridges, small arms, 1.4C UN0338 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
blank.
....... Cartridges for weapons, inert projectile..................... 1.2C UN0328 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, inert projectile or Cartridges, small 1.4S UN0012 II None.................. 112............. None 62 None 25 kg...... 100 kg..... A......
arms.
....... Cartridges for weapons, inert projectile or Cartridges, small 1.4C UN0339 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... B......
arms.
....... Cartridges for weapons, inert projectile or Cartridges, small 1.3C UN0417 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
arms.
....... Cartridges for weapons, with bursting charge................. 1.1F UN0005 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Cartridges for weapons, with bursting charge................. 1.1E UN0006 II EXPLOSIVE 1.1E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, with bursting charge................. 1.2F UN0007 II EXPLOSIVE 1.2F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Cartridges for weapons, with bursting charge................. 1.2E UN0321 II EXPLOSIVE 1.2E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges for weapons, with bursting charge................. 1.4F UN0348 II EXPLOSIVE 1.4F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Cartridges for weapons, with bursting charge................. 1.4E UN0412 II EXPLOSIVE 1.4E........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, oil well......................................... 1.3C UN0277 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges, oil well......................................... 1.4C UN0278 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, power device..................................... 1.3C UN0275 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Cartridges, power device..................................... 1.4C UN0276 II EXPLOSIVE 1.4C........ 110............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, power device..................................... 1.4S UN0323 II EXPLOSIVE 1.4S........ 110, 112........ None 62 None 25 kg...... 100 kg..... A......
....... Cartridges, power device..................................... 1.2C UN0381 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cartridges, safety, blank, see Cartridges for weapons, blank ........... .............. ...................... ................ ........... ........... .......
(UN 0014).
....... Cartridges, safety, see Cartridges for weapons, other than ........... .............. ...................... ................ ........... ........... .......
blank or Cartridges, power device (UN 0323).
....... Cartridges, signal........................................... 1.3G UN0054 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Cartridges, signal........................................... 1.4G UN0312 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cartridges, signal........................................... 1.4S UN0405 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
D...... Cartridges, small arms....................................... ORM-D .............. None.................. 112............. 230 None None 30 kg gross 30 kg gross A......
....... Cartridges, sporting, see Cartridges for weapons, other than ........... .............. ...................... ................ ........... ........... .......
blank.
....... Cartridges, starter, jet engine, see Cartridges, power device ........... .............. ...................... ................ ........... ........... .......
....... Cases, cartridge, empty with primer.......................... 1.4S UN0055 II EXPLOSIVE 1.4S........ 50.............. None 62 None 25 kg...... 100 kg..... A......
....... Cases, cartridges, empty with primer......................... 1.4C UN0379 II EXPLOSIVE 1.4C........ 50.............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cases, combustible, empty, without primer.................... 1.4C UN0446 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cases, combustible, empty, without primer.................... 1.3C UN0447 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Casinghead gasoline see Gasoline............................. ........... .............. ...................... ................ ........... ........... .......
AW..... Castor beans or Castor meal or Castor pomace or Castor flake. 9 UN2969 II None.................. ................ 155 204 240 No limit... No limit... E...... 34, 40
....... Caustic alkali liquids, n.o.s................................ 8 UN1719 II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Caustic potash, see Potassium hydroxide etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Caustic soda, (etc.) see Sodium hydroxide etc................ ........... .............. ...................... ................ ........... ........... .......
....... Cells, containing sodium..................................... 4.3 UN3292 II DANGEROUS WHEN WET.... ................ 189 189 189 25 kg...... No limit... A......
....... Celluloid, in block, rods, rolls, sheets, tubes, etc., except 4.1 UN2000 III FLAMMABLE SOLID....... ................ None 213 240 25 kg...... 100 kg..... A......
scrap.
....... Celluloid, scrap............................................. 4.2 UN2002 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Cement, see Adhesives containing flammable liquid............ ........... .............. ...................... ................ ........... ........... .......
....... Cerium, slabs, ingots, or rods............................... 4.1 UN1333 II FLAMMABLE SOLID....... N34............. None 212 240 15 kg...... 50 kg...... A...... 74, 91
....... Cerium, turnings or gritty powder............................ 4.3 UN3078 II DANGEROUS WHEN WET.... A1, B105, B106, None 212 242 15 kg...... 50 kg...... E......
B109.
....... Cesium or Caesium............................................ 4.3 UN1407 I DANGEROUS WHEN WET.... A19, B100, N34, None 211 242 Forbidden.. 15 kg...... D......
N40.
....... Cesium nitrate or Caesium nitrate............................ 5.1 UN1451 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
D...... Charcoal briquettes, shell, screenings, wood, etc............ 4.2 NA1361 III SPONTANEOUSLY ................ 151 213 240 25 kg...... 100 kg..... A...... 12
COMBUSTIBLE.
....... Charges, bursting, plastics bonded........................... 1.1D UN0457 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, bursting, plastics bonded........................... 1.2D UN0458 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, bursting, plastics bonded........................... 1.4D UN0459 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, bursting, plastics bonded........................... 1.4S UN0460 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Charges, demolition.......................................... 1.1D UN0048 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, depth............................................... 1.1D UN0056 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Charges, expelling, explosive, for fire extinguishers, see ........... .............. ...................... ................ ........... ........... .......
Cartridges, power device.
....... Charges, explosive, commercial without detonator............. 1.1D UN0442 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, explosive, commercial without detonator............. 1.2D UN0443 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, explosive, commercial without detonator............. 1.4D UN0444 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, explosive, commercial without detonator............. 1.4S UN0445 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Charges, propelling.......................................... 1.1C UN0271 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, propelling.......................................... 1.3C UN0272 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, propelling.......................................... 1.2C UN0415 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, propelling.......................................... 1.4C UN0491 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 1E, 5E
....... Charges, propelling, for cannon.............................. 1.3C UN0242 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Charges, propelling, for cannon.............................. 1.1C UN0279 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Charges, propelling, for cannon.............................. 1.2C UN0414 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Charges, shaped, commercial, without detonator............... 1.1D UN0059 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, shaped, commercial without detonator................ 1.2D UN0439 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Charges, shaped, commercial without detonator................ 1.4D UN0440 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, shaped, commercial without detonator................ 1.4S UN0441 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Charges, shaped, flexible, linear............................ 1.4D UN0237 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Charges, shaped, flexible, linear............................ 1.1D UN0288 II EXPLOSIVE 1.1D........ 101............. None 62 None Forbidden.. Forbidden.. B......
....... Charges, supplementary explosive............................. 1.1D UN0060 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
D...... Chemical kit................................................. 8 NA1760 II CORROSIVE............. ................ 154 161 None 1 L........ 30 L....... B...... 40
....... Chemical kits (must be classified and labelled according to ........... .............. ...................... ................ ........... ........... .......
the hazard class of the constituent(s) and must meet the
requirements of special provision 15 in 172.102(c)(1)).
....... Chloral, anhydrous, inhibited................................ 6.1 UN2075 II POISON................ B101, T14....... None 202 243 5 L........ 60 L....... D...... 40
....... Chlorate and borate mixtures................................. 5.1 UN1458 II OXIDIZER.............. A9, N34......... 152 212 240 5 kg....... 25 kg...... A...... 56, 58, 106
............................................................. ........... .............. III OXIDIZER.............. A9, N34......... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 106
....... Chlorate and magnesium chloride mixtures..................... 5.1 UN1459 II OXIDIZER.............. A9, N34, T8..... 152 212 240 5 kg....... 25 kg...... A...... 56, 58, 106
............................................................. ........... .............. III OXIDIZER.............. A9, N34, T8..... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 106
....... Chlorate of potash, see Potassium chlorate................... ........... .............. ...................... ................ ........... ........... .......
....... Chlorate of soda, see Sodium chlorate........................ ........... .............. ...................... ................ ........... ........... .......
....... Chlorates, inorganic, aqueous solution, n.o.s................ 5.1 UN3210 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 56, 58, 106
....... Chlorates, inorganic, n.o.s.................................. 5.1 UN1461 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Chloric acid aqueous solution, with not more than 10 percent 5.1 UN2626 II OXIDIZER.............. T25............. None 229 None Forbidden.. Forbidden.. D...... 56, 58, 106
chloric acid.
....... Chloride of phosphorus, see Phosphorus trichloride........... ........... .............. ...................... ................ ........... ........... .......
....... Chloride of sulfur, see Sulfur chloride...................... ........... .............. ...................... ................ ........... ........... .......
....... Chlorinated lime, see Calcium hypochlorite mixtures, etc..... ........... .............. ...................... ................ ........... ........... .......
....... Chlorine..................................................... 2.3 UN1017 POISON GAS, CORROSIVE. 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40, 51, 55,
62, 68,
89, 90
....... Chlorine azide............................................... Forbidden .............. ...................... ................ ........... ........... .......
D...... Chlorine dioxide, hydrate, frozen............................ 5.1 NA9191 II OXIDIZER, POISON...... ................ None 229 None Forbidden.. Forbidden.. E......
....... Chlorine dioxide (not hydrate)............................... Forbidden .............. ...................... ................ ........... ........... .......
....... Chlorine pentafluoride....................................... 2.3 UN2548 POISON GAS, OXIDIZER, 1, B7, B9, B14.. None 304 314 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE.
....... Chlorine trifluoride......................................... 2.3 UN1749 POISON GAS, OXIDIZER, 2, 25, B7, B9, None 304 314 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE. B14.
....... Chlorite solution with more than 5 percent but less than 16 8 UN1908 III CORROSIVE............. A3, A6, A7, B2, 154 203 241 5 L........ 60 L....... B...... 26
percent available chlorine. N34, T8.
....... Chlorite solution with not less than 16 percent available 8 UN1908 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... B...... 26
chlorine. N34, T8.
....... Chlorites, inorganic, n.o.s.................................. 5.1 UN1462 II OXIDIZER.............. A7, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... 1-Chloro-3-bromopropane...................................... 6.1 UN2688 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... 1-Chloro-1,1-difluoroethane, see Chlorodifluoroethanes....... ........... .............. ...................... ................ ........... ........... .......
....... 1-Chloro-1,1-difluoroethanes, R142b.......................... 2.1 UN2517 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... 3-Chloro-4-methylphenyl isocyanate........................... 6.1 UN2236 II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
....... 1-Chloro-1,2,2,2-tetrafluoroethane, R124..................... 2.2 UN1021 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... 4-Chloro-o-toluidine hydrochloride........................... 6.1 UN1579 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... 1-Chloro-2,2,2-trifluoroethane, R133a........................ 2.2 UN1983 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chloroacetic acid, molten.................................... 6.1 UN3250 II POISON, CORROSIVE..... T9.............. None 202 243 Forbidden.. Forbidden.. C...... 40
....... Chloroacetic acid, solid..................................... 6.1 UN1751 II POISON, CORROSIVE..... A3, A7, N34..... None 212 242 15 kg...... 50 kg...... A...... 40
....... Chloroacetic acid, solution.................................. 6.1 UN1750 II POISON, CORROSIVE..... A7, N34, T8, T27 None 202 243 1 L........ 30 L....... C...... 40
+...... Chloroacetone, stabilized.................................... 6.1 UN1695 II POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, N12, N32,
N34, T38, T43,
T45.
....... Chloroacetone (unstabilized)................................. Forbidden .............. ...................... ................ ........... ........... .......
+...... Chloroacetonitrile........................................... 6.1 UN2668 II POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 60 L....... A...... 12, 26, 40
LIQUID. B74, T38, T43,
T45.
....... Chloroacetophenone (CN), liquid.............................. 6.1 UN1697 II POISON................ A3, N12, N32, None 202 243 Forbidden.. 60 L....... D...... 12, 40
N33.
....... Chloroacetophenone (CN), solid............................... 6.1 UN1697 II POISON................ A3, N12, N32, None 212 None Forbidden.. 100 kg..... D...... 12, 40
N33, N34.
....... Chloroacetyl chloride........................................ 6.1 UN1752 I POISON, CORROSIVE..... 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. D...... 40
B3, B8, B9,
B14, B32, B74,
B77, N34, N43,
T38, T43, T45.
....... Chloroanilines, liquid....................................... 6.1 UN2019 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Chloroanilines, solid........................................ 6.1 UN2018 II POISON................ T14, T38........ None 212 242 25 kg...... 100 kg..... A......
....... Chloroanisidines............................................. 6.1 UN2233 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Chlorobenzene................................................ 3 UN1134 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Chlorobenzol, see Chlorobenzene.............................. ........... .............. ...................... ................ ........... ........... .......
....... Chlorobenzotrifluorides...................................... 3 UN2234 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Chlorobenzyl chlorides....................................... 6.1 UN2235 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A......
....... Chlorobutanes................................................ 3 UN1127 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... B......
....... Chlorocresols, liquid........................................ 6.1 UN2669 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12
....... Chlorocresols, solid......................................... 6.1 UN2669 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 12
....... Chlorodifluorobromomethane, R12B1............................ 2.2 UN1974 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chlorodifluoromethane and chloropentafluoroethane mixture 2.2 UN1973 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
with fixed boiling point, with approximately 49 percent
chlorodifluoromethane, R502.
....... Chlorodifluoromethane, R22................................... 2.2 UN1018 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chlorodinitrobenzenes........................................ 6.1 UN1577 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A...... 91
....... 2-Chloroethanal.............................................. 6.1 UN2232 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, T38, T43,
T45.
....... Chloroform................................................... 6.1 UN1888 III KEEP AWAY FROM FOOD... N36, T14........ 153 203 241 5 L........ 60 L....... A...... 40
....... Chloroformates, toxic, corrosive, flammable, n.o.s........... 6.1 UN2742 II POISON, CORROSIVE, 5............... None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
FLAMMABLE LIQUID. 25, 40,
100
....... Chloroformates, toxic, corrosive, n.o.s...................... 6.1 UN3277 II POISON, CORROSIVE..... T12, T26........ None 202 243 1 L........ 30 L....... A...... 12, 13, 25,
40
....... Chloromethyl chloroformate................................... 6.1 UN2745 II POISON, CORROSIVE..... T18............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... Chloromethyl ethyl ether..................................... 3 UN2354 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Chloronitroanilines.......................................... 6.1 UN2237 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
+...... Chloronitrobenzene, ortho, liquid............................ 6.1 UN1578 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
+...... Chloronitrobenzenes meta or para, solid...................... 6.1 UN1578 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Chloronitrotoluenes liquid................................... 6.1 UN2433 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A......
....... Chloronitrotoluenes, solid................................... 6.1 UN2433 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Chloropentafluoroethane, R115................................ 2.2 UN1020 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Chlorophenolates, liquid or Phenolates, liquid............... 8 UN2904 III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A......
....... Chlorophenolates, solid or Phenolates, solid................. 8 UN2905 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Chlorophenols, liquid........................................ 6.1 UN2021 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Chlorophenols, solid......................................... 6.1 UN2020 III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Chlorophenyltrichlorosilane.................................. 8 UN1753 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
+...... Chloropicrin................................................. 6.1 UN1580 I POISON................ 2, B7, B9, B14, None 227 244 Forbidden.. Forbidden.. D...... 40
B32, B46, B74,
T38, T43, T45.
....... Chloropicrin and methyl bromide mixtures..................... 2.3 UN1581 POISON GAS............ 2, B9, B14...... None 193 314, 315 Forbidden.. Forbidden.. D...... 25, 40
....... Chloropicrin and methyl chloride mixtures.................... 2.3 UN1582 POISON GAS............ 2............... None 193 245 Forbidden.. Forbidden.. D...... 25, 40
....... Chloropicrin mixture, flammable (pressure not exceeding 14.7 ........... .............. ...................... ................ ........... ........... .......
psia at 115 degrees F flash point below 100 degrees F) see
Toxic liquids, flammable, etc..
....... Chloropicrin mixtures, n.o.s................................. 6.1 UN1583 I POISON................ 5............... None 201 243 Forbidden.. Forbidden.. C...... 40
............................................................. ........... .............. II POISON................ ................ None 202 243 Forbidden.. Forbidden.. C...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 Forbidden.. Forbidden.. C...... 40
D...... Chloropivaloyl chloride...................................... 6.1 NA9263 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
B74, T38, T43,
T45.
....... Chloroplatinic acid, solid................................... 8 UN2507 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Chloroprene, inhibited....................................... 3 UN1991 I FLAMMABLE LIQUID, B57, T15........ None 201 243 Forbidden.. 30 L....... D...... 40
POISON.
....... Chloroprene, uninhibited..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Chloropropane.............................................. 3 UN2356 I FLAMMABLE LIQUID...... N36, T14........ 150 201 243 1 L........ 30 L....... E......
....... 3-Chloropropanol-1........................................... 6.1 UN2849 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A......
....... 2-Chloropropene.............................................. 3 UN2456 I FLAMMABLE LIQUID...... A3, N36, T20.... 150 201 243 1 L........ 30 L....... E......
....... 2-Chloropropionic acid....................................... 8 UN2511 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A...... 8
....... 2-Chloropyridine............................................. 6.1 UN2822 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Chlorosilanes, corrosive, flammable, n.o.s................... 8 UN2986 II CORROSIVE, FLAMMABLE B100............ None 202 243 1 L........ 30 L....... C...... 40
LIQUID.
....... Chlorosilanes, corrosive, n.o.s.............................. 8 UN2987 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... C...... 40
....... Chlorosilanes, flammable, corrosive, n.o.s................... 3 UN2985 II FLAMMABLE LIQUID, B100, T18, T26.. None 201 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Chlorosilanes, water-reactive, flammable, corrosive, n.o.s... 4.3 UN2988 I DANGEROUS WHEN WET, A2.............. None 201 244 Forbidden.. 1 L........ D...... 21, 28, 40,
FLAMMABLE LIQUID, 49, 100
CORROSIVE.
+...... Chlorosulfonic acid (with or without sulfur trioxide)........ 8 UN1754 I CORROSIVE, POISON..... 2, A3, A6, A10, None 227 244 Forbidden.. Forbidden.. C...... 40
B9, B10, B14,
B32, B74, T38,
T43, T45.
....... Chlorotoluenes............................................... 3 UN2238 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Chlorotoluidines liquid...................................... 6.1 UN2239 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Chlorotoluidines solid....................................... 6.1 UN2239 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Chlorotrifluoromethane and trifluoromethane azeotropic 2.2 UN2599 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
mixture with approximately 60 percent
chlorotrifluoromethane, R503.
....... Chlorotrifluoromethane, R13.................................. 2.2 UN1022 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Chromic acid, solid.......................................... 5.1 NA1463 II OXIDIZER, CORROSIVE... ................ None 212 242 5 kg....... 25 kg...... A......
....... Chromic acid solution........................................ 8 UN1755 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 40
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 60 L....... C...... 40
....... Chromic anhydride, see Chromium trioxide, anhydrous.......... ........... .............. ...................... ................ ........... ........... .......
....... Chromic fluoride, solid...................................... 8 UN1756 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 26
....... Chromic fluoride, solution................................... 8 UN1757 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Chromium nitrate............................................. 5.1 UN2720 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Chromium oxychloride......................................... 8 UN1758 I CORROSIVE............. A3, A6, A7, B10, None 201 243 0.5 L...... 2.5 L...... C...... 40, 66, 74,
N34, T12, T26. 89, 90
....... Chromium trioxide, anhydrous................................. 5.1 UN1463 II OXIDIZER, CORROSIVE... B106............ None 212 242 5 kg....... 25 kg...... A......
....... Chromosulfuric acid.......................................... 8 UN2240 I CORROSIVE............. A3, A6, A7, B4, None 201 243 0.5 L...... 2.5 L...... B...... 40, 66, 74,
B6, N34, T12, 89, 90
T27.
....... Chromyl chloride, see Chromium oxychloride................... ........... .............. ...................... ................ ........... ........... .......
....... Cigar and cigarette lighters, charged with fuel, see Lighters ........... .............. ...................... ................ ........... ........... .......
for cigars, cigarettes, etc..
....... Coal briquettes, hot......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Coal gas..................................................... 2.3 UN1023 POISON GAS, FLAMMABLE 3............... None 302 314, 315 Forbidden.. 25 kg...... D...... 40
GAS.
....... Coal tar distillates, flammable.............................. 3 UN1136 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or ........... .............. ...................... ................ ........... ........... .......
solid, n.o.s. or Dye intermediates, liquid or solid, n.o.s.,
corrosive.
....... Coating solution............................................. 3 UN1139 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Cobalt naphthenates, powder.................................. 4.1 UN2001 III FLAMMABLE SOLID....... A19............. 151 213 240 25 kg...... 100 kg..... A......
....... Cobalt resinate, precipitated................................ 4.1 UN1318 III FLAMMABLE SOLID....... A1, A19......... 151 213 240 25 kg...... 100 kg..... A......
....... Coke, hot.................................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Collodion, see Nitrocellulose etc............................ ........... .............. ...................... ................ ........... ........... .......
D...... Combustible liquid, n.o.s.................................... Combustible NA1993 III None.................. T1.............. 150 203 241 60 L....... 220 L...... A......
liquid
....... Components, explosive train, n.o.s........................... 1.2B UN0382 II EXPLOSIVE 1.2B........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 6E
....... Components, explosive train, n.o.s........................... 1.4B UN0383 II EXPLOSIVE 1.4B........ 101............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Components, explosive train, n.o.s........................... 1.4S UN0384 II EXPLOSIVE 1.4S........ 101............. None 62 None 25 kg...... 100 kg..... A......
....... Components, explosive train, n.o.s........................... 1.1B UN0461 II EXPLOSIVE 1.1B........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 6E
....... Composition B, see Hexolite, etc............................. ........... .............. ...................... ................ ........... ........... .......
D...... Compounds, cleaning liquid................................... 8 NA1760 I CORROSIVE............. A7, B10, T42.... None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, N37, T14.... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. N37, T7......... 154 203 241 5 L........ 60 L....... A...... 40
D...... Compounds, cleaning liquid................................... 3 NA1993 I FLAMMABLE LIQUID...... T42............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
D...... Compounds, tree killing, liquid or Compounds, weed killing, 8 NA1760 I CORROSIVE............. A7, B10, T42.... None 201 243 0.5 L...... 2.5 L...... B...... 40
liquid.
............................................................. ........... .............. II CORROSIVE............. B2, N37, T14.... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. N37, T7......... 154 203 241 5 L........ 60 L....... A...... 40
D...... Compounds, tree killing, liquid or Compounds, weed killing, 3 NA1993 I FLAMMABLE LIQUID...... T42............. 150 201 243 1 L........ 30 L....... E......
liquid.
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
D...... Compounds, tree killing, liquid or Compounds, weed killing, 6.1 NA2810 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
liquid.
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A...... 40
....... Compressed gas, oxidizing, n.o.s............................. 2.2 UN3156 NONFLAMMABLE GAS, ................ 306 302 314, 315 75 kg...... 150 kg..... D......
OXIDIZER.
....... Compressed gases, flammable, n.o.s........................... 2.1 UN1954 FLAMMABLE GAS......... ................ 306 302, 305 314, 315 Forbidden.. 150 kg..... D...... 40
....... Compressed gases, n.o.s...................................... 2.2 UN1956 NONFLAMMABLE GAS...... ................ 306, 307 302, 305 314, 315 75 kg...... 150 kg..... A......
....... Compressed gases, toxic, flammable, n.o.s. Inhalation hazard 2.3 UN1953 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40, 95
Zone A. GAS.
....... Compressed gases, toxic, flammable, n.o.s. Inhalation hazard 2.3 UN1953 POISON GAS, FLAMMABLE 2, B9, B14...... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
Zone B. GAS.
....... Compressed gases, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN1953 POISON GAS, FLAMMABLE 3, B14.......... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
Zone C. GAS.
....... Compressed gases, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN1953 POISON GAS, FLAMMABLE 4............... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
Zone D. GAS.
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone A..... 2.3 UN1955 POISON GAS............ 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone B..... 2.3 UN1955 POISON GAS............ 2, B9, B14...... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone C..... 2.3 UN1955 POISON GAS............ 3, B14.......... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
....... Compressed gases, toxic, n.o.s. Inhalation Hazard Zone D..... 2.3 UN1955 POISON GAS............ 4............... None 302, 305 314, 315 Forbidden.. Forbidden.. D...... 40
D...... Consumer commodity........................................... ORM-D .............. None.................. ................ 156, 306 156, 306 None 30 kg gross 30 kg gross A......
....... Contrivances, water-activated, with burster, expelling charge 1.2L UN0248 II EXPLOSIVE 1.2L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
or propelling charge. 11E, 17E
....... Contrivances, water-activated, with burster, expelling charge 1.3L UN0249 II EXPLOSIVE 1.3L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
or propelling charge. 11E, 17E
....... Copper acetoarsenite......................................... 6.1 UN1585 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Copper acetylide............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Copper amine azide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Copper arsenite.............................................. 6.1 UN1586 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Copper based pesticides, liquid, flammable, toxic, flash 3 UN2776 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Copper based pesticides, liquid, toxic....................... 6.1 UN3010 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Copper based pesticides, liquid, toxic, flammable flashpoint 6.1 UN3009 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Copper based pesticides, solid, toxic........................ 6.1 UN2775 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Copper chlorate.............................................. 5.1 UN2721 II OXIDIZER.............. A1.............. 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Copper chloride.............................................. 8 UN2802 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Copper cyanide............................................... 6.1 UN1587 II POISON................ ................ None 204 242 25 kg...... 100 kg..... A...... 26
....... Copper selenate, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
....... Copper selenite, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
....... Copper tetramine nitrate..................................... Forbidden .............. ...................... ................ ........... ........... .......
AW..... Copra........................................................ 4.2 UN1363 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A...... 13, 19, 48,
COMBUSTIBLE. 119
....... Cord, detonating, flexible................................... 1.1D UN0065 II EXPLOSIVE 1.1D........ 102............. 63(a) 62 None Forbidden.. Forbidden.. B......
....... Cord, detonating, flexible................................... 1.4D UN0289 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cord detonating or Fuse detonating metal clad................ 1.2D UN0102 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cord, detonating or Fuse, detonating metal clad.............. 1.1D UN0290 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Cord, detonating, mild effect or Fuse, detonating, mild 1.4D UN0104 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
effect metal clad.
....... Cord, igniter................................................ 1.4G UN0066 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Cordeau detonant fuse, see Cord, detonating, etc.; Cord, ........... .............. ...................... ................ ........... ........... .......
detonating, flexible.
....... Cordite, see Powder, smokeless............................... ........... .............. ...................... ................ ........... ........... .......
....... Corrosive liquid, acidic, inorganic, n.o.s................... 8 UN3264 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, acidic, organic, n.o.s..................... 8 UN3265 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, basic, inorganic, n.o.s.................... 8 UN3266 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, basic, organic, n.o.s...................... 8 UN3267 I CORROSIVE............. B10............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquid, self-heating, n.o.s........................ 8 UN3301 I CORROSIVE, B10............ None 201 243 0.5 L...... 2.5 L...... D......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II CORROSIVE, B2.............. 154 202 242 1 L........ 30 L....... D......
SPONTANEOUSLY
COMBUSTIBLE.
....... Corrosive liquids, flammable, n.o.s.......................... 8 UN2920 I CORROSIVE, FLAMMABLE B10, T42........ None 201 243 0.5 L...... 2.5 L...... C...... 25, 40
LIQUID.
............................................................. ........... .............. II CORROSIVE, FLAMMABLE B2, T15, T26.... None 202 243 1 L........ 30 L....... C...... 25, 40
LIQUID.
....... Corrosive liquids, n.o.s..................................... 8 UN1760 I CORROSIVE............. A7, B10, T42.... None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE............. B2, T14......... 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A...... 40
....... Corrosive liquids, oxidizing, n.o.s.......................... 8 UN3093 I CORROSIVE, OXIDIZER... ................ None 201 243 Forbidden.. 2.5 L...... C...... 89
............................................................. ........... .............. II CORROSIVE, OXIDIZER... ................ None 202 243 1 L........ 30 L....... C...... 89
....... Corrosive liquids, toxic, n.o.s.............................. 8 UN2922 I CORROSIVE, POISON..... A7, B10......... None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II CORROSIVE, POISON..... B3.............. None 202 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY ................ 154 203 241 5 L........ 60 L....... B...... 40
FROM FOOD.
....... Corrosive liquids, water-reactive, n.o.s..................... 8 UN3094 I CORROSIVE, DANGEROUS ................ None 201 243 Forbidden.. 1 L........ E......
WHEN WET.
............................................................. ........... .............. II CORROSIVE, DANGEROUS ................ None 202 243 1 L........ 5 L........ E......
WHEN WET.
....... Corrosive solid, acidic, inorganic, n.o.s.................... 8 UN3260 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solid, acidic, organic, n.o.s...................... 8 UN3261 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solid, basic, inorganic, n.o.s..................... 8 UN3262 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solid, basic, organic, n.o.s....................... 8 UN3263 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solids, flammable, n.o.s........................... 8 UN2921 I CORROSIVE, FLAMMABLE B106............ None 211 242 1 kg....... 25 kg...... B...... 12, 25
SOLID.
............................................................. ........... .............. II CORROSIVE, FLAMMABLE ................ None 212 242 15 kg...... 50 kg...... B...... 12, 25
SOLID.
....... Corrosive solids, n.o.s...................................... 8 UN1759 I CORROSIVE............. ................ None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Corrosive solids, oxidizing, n.o.s........................... 8 UN3084 I CORROSIVE, OXIDIZER... B100............ None 211 242 1 kg....... 25 kg...... C......
............................................................. ........... .............. II CORROSIVE, OXIDIZER... B100............ None 212 242 15 kg...... 50 kg...... C......
....... Corrosive solids, self-heating, n.o.s........................ 8 UN3095 I CORROSIVE, B100............ None 211 243 1 kg....... 25 kg...... C......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II CORROSIVE, ................ None 212 242 15 kg...... 50 kg...... C......
SPONTANEOUSLY
COMBUSTIBLE.
....... Corrosive solids, toxic, n.o.s............................... 8 UN2923 I CORROSIVE, POISON..... ................ None 211 242 1 kg....... 25 kg...... B...... 40
............................................................. ........... .............. II CORROSIVE, POISON..... ................ None 212 240 15 kg...... 50 kg...... B...... 40
............................................................. ........... .............. III CORROSIVE, KEEP AWAY ................ 154 213 240 25 kg...... 100 kg..... B...... 40, 95
FROM FOOD.
....... Corrosive solids, water-reactive, n.o.s...................... 8 UN3096 I CORROSIVE, DANGEROUS B105............ None 211 243 1 kg....... 25 kg...... D......
WHEN WET.
............................................................. ........... .............. II CORROSIVE, DANGEROUS B105............ None 212 242 15 kg...... 50 kg...... D......
WHEN WET.
DW..... Cotton....................................................... 9 .............. CLASS 9............... W41............. None None None No limit... No limit... A......
AIW.... Cotton waste, oily........................................... 4.2 UN1364 III SPONTANEOUSLY N9.............. None 213 None Forbidden.. Forbidden.. A...... 54
COMBUSTIBLE.
AIW.... Cotton, wet.................................................. 4.2 .............. III SPONTANEOUSLY ................ None 204 241 Forbidden.. Forbidden.. A......
COMBUSTIBLE.
....... Coumarin derivative pesticides, liquid, flammable, toxic, 3 UN3024 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
flashpoint less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
....... Coumarin derivative pesticides, liquid, toxic................ 6.1 UN3026 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A...... 40
....... Coumarin derivative pesticides, liquid, toxic, flammable 6.1 UN3025 I POISON, FLAMMABLE ................ None 201 243 1 L........ 30 L....... B...... 40
flashpoint less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE ................ None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1.............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Coumarin derivative pesticides, solid, toxic................. 6.1 UN3027 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Cresols...................................................... 6.1 UN2076 II POISON, CORROSIVE..... B110, T8........ None 202 243 1 L........ 30 L....... B......
....... Cresylic acid................................................ 6.1 UN2022 II POISON, CORROSIVE..... T8.............. None 202 243 1 L........ 30 L....... B......
....... Crotonaldehyde, stabilized................................... 6.1 UN1143 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... B...... 40
LIQUID. B74, B77, T38,
T43, T45.
....... Crotonic acid liquid......................................... 8 UN2823 III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A...... 12
....... Crotonic acid, solid......................................... 8 UN2823 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 12
....... Crotonylene.................................................. 3 UN1144 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Cupriethylenediamine solution................................ 8 UN1761 II CORROSIVE, POISON..... T8, T26......... None 202 243 1 L........ 30 L....... A...... 95
............................................................. ........... .............. III CORROSIVE, KEEP AWAY T7.............. 154 203 242 5 L........ 60 L....... A...... 95
FROM FOOD.
....... Cutters, cable, explosive.................................... 1.4S UN0070 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Cyanide or cyanide mixtures, dry, see Cyanides, inorganic, ........... .............. ...................... ................ ........... ........... .......
solid, n.o.s..
....... Cyanide solutions, n.o.s..................................... 6.1 UN1935 I POISON................ B37, T18, T26... None 201 243 1 L........ 30 L....... B...... 40, 52
............................................................. ........... .............. II POISON................ T18, T26........ None 202 243 5 L........ 60 L....... A...... 40, 52
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T18, T26........ 153 203 241 60 L....... 220 L...... A...... 40, 52
....... Cyanides, inorganic, solid, n.o.s............................ 6.1 UN1588 I POISON................ N74, N75........ None 211 242 5 kg....... 50 kg...... A...... 52
............................................................. ........... .............. II POISON................ N74, N75........ None 212 242 25 kg...... 100 kg..... A...... 52
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N74, N75........ 153 213 240 100 kg..... 200 kg..... A...... 52
....... Cyanogen bromide............................................. 6.1 UN1889 I POISON, CORROSIVE..... A6, A8.......... None 211 242 Forbidden.. Forbidden.. D...... 40
....... Cyanogen chloride, inhibited................................. 2.3 UN1589 POISON GAS, CORROSIVE. 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
....... Cyanogen, liquefied.......................................... 2.3 UN1026 POISON GAS, FLAMMABLE 2............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Cyanuric chloride............................................ 8 UN2670 II CORROSIVE............. ................ None 212 240 15 kg...... 50 kg...... A...... 12, 40
....... Cyanuric triazide............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Cyclobutane.................................................. 2.1 UN2601 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Cyclobutyl chloroformate..................................... 6.1 UN2744 II POISON, CORROSIVE..... T18............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... 1,5,9-Cyclododecatriene...................................... 6.1 UN2518 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Cycloheptane................................................. 3 UN2241 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Cycloheptatriene............................................. 3 UN2603 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Cycloheptene................................................. 3 UN2242 II FLAMMABLE LIQUID...... B1, T7.......... 150 202 242 5 L........ 60 L....... B......
....... Cyclohexane.................................................. 3 UN1145 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... E......
....... Cyclohexanone................................................ 3 UN1915 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclohexene.................................................. 3 UN2256 II FLAMMABLE LIQUID...... B101, T7........ 150 202 242 5 L........ 60 L....... E......
....... Cyclohexenyltrichlorosilane.................................. 8 UN1762 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C...... 40
T26.
....... Cyclohexyl acetate........................................... 3 UN2243 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Cyclohexyl isocyanate........................................ 6.1 UN2488 II POISON................ 2, B9, B14, B32, None 227 244 5 L........ 60 L....... D...... 40
B74, B77, T38,
T43, T45.
....... Cyclohexyl mercaptan......................................... 3 UN3054 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40, 95
....... Cyclohexylamine.............................................. 8 UN2357 II CORROSIVE, FLAMMABLE B100, T8, T26... None 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Cyclohexyltrichlorosilane.................................... 8 UN1763 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C...... 40
T26.
....... Cyclonite and cyclotetramethylenetetranitramine mixtures, ........... .............. ...................... ................ ........... ........... .......
wetted or desensitized see RDX and HMX mixtures, wetted or
desensitized etc.ed.
....... Cyclonite and HMX mixtures, wetted or desensitized see RDX ........... .............. ...................... ................ ........... ........... .......
and HMX mixtures, wetted or desensitized etc..
....... Cyclonite and octogen mixtures, wetted or desensitized see ........... .............. ...................... ................ ........... ........... .......
RDX and HMX mixtures, wetted or desensitized etc..
....... Cyclonite, see Cyclotrimethylenetrinitramine, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Cyclooctadiene phosphines, see 9-Phosphabicyclononanes....... ........... .............. ...................... ................ ........... ........... .......
....... Cyclooctadienes.............................................. 3 UN2520 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclooctatetraene............................................ 3 UN2358 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Cyclopentane................................................. 3 UN1146 II FLAMMABLE LIQUID...... B101, T14....... 150 202 242 5 L........ 60 L....... E......
....... Cyclopentane, methyl, see Methylcyclopentane................. ........... .............. ...................... ................ ........... ........... .......
....... Cyclopentanol................................................ 3 UN2244 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclopentanone............................................... 3 UN2245 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Cyclopentene................................................. 3 UN2246 II FLAMMABLE LIQUID...... B101, T13....... 150 202 242 5 L........ 60 L....... E......
....... Cyclopropane, liquefied...................................... 2.1 UN1027 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Cyclotetramethylene tetranitramine (dry or unphlegmatized) Forbidden .............. ...................... ................ ........... ........... .......
(HMX).
....... Cyclotetramethylenetetranitramine, desensitized or Octogen, 1.1D UN0484 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
desensitized or HMX, desensitized.
....... Cyclotetramethylenetetranitramine, wetted or HMX, wetted or 1.1D UN0226 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Octogen, wetted with not less than 15 percent water, by mass.
....... Cyclotrimethylenenitramine and octogen, mixtures, wetted or ........... .............. ...................... ................ ........... ........... .......
desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Cyclotrimethylenetrinitramine and ........... .............. ...................... ................ ........... ........... .......
cyclotetramethylenetetranitramine mixtures, wetted or
desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Cyclotrimethylenetrinitramine and HMX mixtures, wetted or ........... .............. ...................... ................ ........... ........... .......
desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Cyclotrimethylenetrinitramine, desensitized or Cyclonite, 1.1D UN0483 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
desensitized or Hexogen, desensitized or RDX, desensitized.
....... Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or 1.1D UN0072 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Hexogen, wetted or RDX, wetted with not less than 15 percent
water by mass.
....... Cymenes...................................................... 3 UN2046 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Decaborane................................................... 4.1 UN1868 II FLAMMABLE SOLID, A19, A20........ None 212 None Forbidden.. 50 kg...... A......
POISON.
....... Decahydronaphthalene......................................... 3 UN1147 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... n-Decane..................................................... 3 UN2247 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Deflagrating metal salts of aromatic nitroderivatives, n.o.s. 1.3C UN0132 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Delay electric igniter, see Igniters......................... ........... .............. ...................... ................ ........... ........... .......
D...... Denatured alcohol............................................ 3 NA1986 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... E...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... 150 203 242 60 L....... 220 L...... E...... 40
AWAY FROM FOOD.
D...... Denatured alcohol............................................ 3 NA1987 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Depth charges, see Charges, depth............................ ........... .............. ...................... ................ ........... ........... .......
....... Detonating relays, see Detonators, etc....................... ........... .............. ...................... ................ ........... ........... .......
....... Detonator assemblies, non-electric for blasting.............. 1.1B UN0360 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonator assemblies, non-electric, for blasting............. 1.4B UN0361 II EXPLOSIVE 1.4B........ 103............. 63(f), 62 None Forbidden.. 75 kg...... A...... 24E
63(g)
....... Detonators, electric, for blasting........................... 1.1B UN0030 II EXPLOSIVE 1.1B........ ................ 63(f), 62 None Forbidden.. Forbidden.. B...... 2E, 6E
63(g)
....... Detonators, electric, for blasting........................... 1.4B UN0255 II EXPLOSIVE 1.4B........ 103............. 63(f), 62 None Forbidden.. 75 kg...... A...... 24E
63(g)
....... Detonators, electric for blasting............................ 1.4S UN0456 II EXPLOSIVE 1.4S........ 104............. 63(f), 62 None 25 kg...... 100 kg..... A......
63(g)
....... Detonators for ammunition.................................... 1.1B UN0073 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonators for ammunition.................................... 1.2B UN0364 II EXPLOSIVE 1.2B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonators for ammunition.................................... 1.4B UN0365 II EXPLOSIVE 1.4B........ 103............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Detonators for ammunition.................................... 1.4S UN0366 II EXPLOSIVE 1.4S........ 104............. None 62 None 25 kg...... 100 kg..... A......
....... Detonators, non-electric, for blasting....................... 1.1B UN0029 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Detonators, non-electric, for blasting....................... 1.4B UN0267 II EXPLOSIVE 1.4B........ 103............. 63(f), 62 None Forbidden.. 75 kg...... A...... 24E
63(g)
....... Detonators, non-electric for blasting........................ 1.4S UN0455 II EXPLOSIVE 1.4S........ 104............. None 62 None 25 kg...... 100 kg..... A......
....... Deuterium.................................................... 2.1 UN1957 FLAMMABLE GAS......... ................ 306 302 None Forbidden.. 150 kg..... E...... 40
....... Devices, small, hydrocarbon gas powered or Hydrocarbon gas 2.1 UN3150 FLAMMABLE GAS......... ................ 306 304 None Forbidden.. 150 kg..... B...... 40
refills for small devices with release device.
....... Di-n-amylamine............................................... 3 UN2841 III FLAMMABLE LIQUID, KEEP B1, T8.......... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Di-n-butyl peroxydicarbonate, with more than 52 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Di-n-butylamine.............................................. 8 UN2248 II CORROSIVE, FLAMMABLE T8.............. None 202 243 1 L........ 30 L....... A......
LIQUID.
....... 2,2-Di-(tert-butylperoxy) butane, with more than 55 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Di-(tert-butylperoxy) phthalate, with more than 55 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... 2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more Forbidden .............. ...................... ................ ........... ........... .......
than 42 percent with inert solid.
....... Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent Forbidden .............. ...................... ................ ........... ........... .......
with water.
....... 1,2-Di-(dimethylamino)ethane................................. 3 UN2372 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Di-2-ethylhexyl phosphoric acid, see Diisooctyl acid ........... .............. ...................... ................ ........... ........... .......
phosphate.
....... Di-(1-hydroxytetrazole) (dry)................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Di-(1-naphthoyl) peroxide.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... a,a'-Di-(nitroxy) methylether................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Di-(beta-nitroxyethyl) ammonium nitrate...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diacetone alcohol............................................ 3 UN1148 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diacetone alcohol peroxides, with more than 57 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution with more than 9 percent hydrogen peroxide, less
than 26 percent diacetone alcohol and less than 9 percent
water; total active oxygen content more than 9 percent by
mass.
....... Diacetyl, see Butanedione.................................... ........... .............. ...................... ................ ........... ........... .......
....... Diacetyl peroxide, solid, or with more than 25 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Diallylamine................................................. 3 UN2359 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 21, 40, 100
POISON, CORROSIVE.
....... Diallylether................................................. 3 UN2360 II FLAMMABLE LIQUID, N12, T8......... None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... 4,4'-Diaminodiphenyl methane................................. 6.1 UN2651 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... p-Diazidobenzene............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,2-Diazidoethane............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... 1,1'-Diazoaminonaphthalene................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazoaminotetrazole (dry).................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazodinitrophenol (dry)..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazodinitrophenol, wetted with not less than 40 percent 1.1A UN0074 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
water or mixture of alcohol and water, by mass.
....... Diazodiphenylmethane......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazonium nitrates (dry)..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diazonium perchlorates (dry)................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,3-Diazopropane............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Dibenzyl peroxydicarbonate, with more than 87 percent with Forbidden .............. ...................... ................ ........... ........... .......
water.
....... Dibenzyldichlorosilane....................................... 8 UN2434 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Diborane..................................................... 2.3 UN1911 POISON GAS, FLAMMABLE 1............... None 302 None Forbidden.. Forbidden.. D...... 40, 57
GAS.
....... Diborane mixtures............................................ 2.1 NA1911 FLAMMABLE GAS......... 5............... None 302 245 Forbidden.. Forbidden.. D...... 40, 57
....... Dibromoacetylene............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Dibromobenzene............................................... 3 UN2711 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1,2-Dibromobutan-3-one....................................... 6.1 UN2648 II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
....... Dibromochloropropane......................................... 6.1 UN2872 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
A...... Dibromodifluoromethane, R12B2................................ 9 UN1941 III None.................. T22............. 155 203 241 100 L...... 220 L...... A...... 25
....... 1,2-Dibromoethane, see Ethylene dibromide.................... ........... .............. ...................... ................ ........... ........... .......
....... Dibromomethane............................................... 6.1 UN2664 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Dibutyl ethers............................................... 3 UN1149 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dibutylaminoethanol.......................................... 6.1 UN2873 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... N,N'-Dichlorazodicarbonamidine (salts of) (dry).............. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,1-Dichloro-1-nitroethane................................... 6.1 UN2650 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12, 40
D...... 3,5-Dichloro-2,4,6-trifluoropyridine......................... 6.1 NA9264 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. A...... 40, 95
B74, T38, T43,
T45.
....... Dichloroacetic acid.......................................... 8 UN1764 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... A......
N34, T9, T27.
....... 1,3-Dichloroacetone.......................................... 6.1 UN2649 II POISON................ ................ None 212 242 25 kg...... 100 kg..... B...... 12, 40
....... Dichloroacetyl chloride...................................... 8 UN1765 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... D...... 40
B6, N34, T8,
T26.
....... Dichloroacetylene............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Dichloroanilines, liquid..................................... 6.1 UN1590 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Dichloroanilines, solid...................................... 6.1 UN1590 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A...... 40
....... o-Dichlorobenzene............................................ 6.1 UN1591 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
D...... Dichlorobutene............................................... 8 NA2920 I CORROSIVE, FLAMMABLE ................ None 201 243 0.5 L...... 2.5 L...... C...... 12, 21, 25,
LIQUID. 40, 48
....... 2,2'-Dichlorodiethyl ether................................... 6.1 UN1916 II POISON, FLAMMABLE N33, N34, T8.... None 202 243 5 L........ 60 L....... A......
LIQUID.
....... Dichlorodifluoromethane and difluoroethane azeotropic mixture 2.2 UN2602 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
with approximately 74 percent dichlorodifluoromethane, R500.
....... Dichlorodifluoromethane, R12................................. 2.2 UN1028 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Dichlorodimethyl ether, symmetrical.......................... 6.1 UN2249 I POISON................ T25............. None 201 243 Forbidden.. Forbidden.. D...... 40
....... 1,1-Dichloroethane........................................... 3 UN2362 II FLAMMABLE LIQUID...... B101, T7........ 150 202 242 5 L........ 60 L....... B...... 40
....... 1,2-Dichloroethane, see Ethylene dichloride.................. ........... .............. ...................... ................ ........... ........... .......
....... Dichloroethyl sulfide........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Dichloroethylene............................................. 3 UN1150 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... B......
....... Dichlorofluoromethane, R21................................... 2.2 UN1029 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid 5.1 UN2465 II OXIDIZER.............. 28.............. 152 212 240 5 kg....... 25 kg...... A...... 13
salts.
....... Dichloroisopropyl ether...................................... 6.1 UN2490 II POISON................ T8.............. None 202 243 5 L........ 60 L....... B......
....... Dichloromethane.............................................. 6.1 UN1593 III KEEP AWAY FROM FOOD... N36, T13........ 153 203 241 60 L....... 220 L...... A......
....... Dichloropentanes............................................. 3 UN1152 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dichlorophenyl isocyanates................................... 6.1 UN2250 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 25, 40, 48
....... Dichlorophenyltrichlorosilane................................ 8 UN1766 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Dichloropropane, see Propylene dichloride.................... ........... .............. ...................... ................ ........... ........... .......
....... 1,3-Dichloropropanol-2....................................... 6.1 UN2750 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12, 40
....... Dichloropropene and propylene dichloride mixture, see ........... .............. ...................... ................ ........... ........... .......
Propylene dichloride.
....... Dichloropropenes............................................. 3 UN2047 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Dichlorosilane............................................... 2.3 UN2189 POISON GAS, FLAMMABLE 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 17, 40
GAS, CORROSIVE.
....... Dichlorotetrafluoroethane, R114.............................. 2.2 UN1958 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Dichlorovinylchloroarsine.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dicycloheptadiene, see 2,5-Norbornadiene..................... ........... .............. ...................... ................ ........... ........... .......
....... Dicyclohexylamine............................................ 8 UN2565 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Dicyclohexylammonium nitrite................................. 4.1 UN2687 III FLAMMABLE SOLID....... ................ 153 213 240 25 kg...... 100 kg..... A...... 48
....... Dicyclopentadiene............................................ 3 UN2048 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Didymium nitrate............................................. 5.1 UN1465 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
D...... Dieldrin..................................................... 6.1 NA2761 II POISON................ ................ None 212 242 0.5 kg..... 5 kg....... A...... 40
D...... Diesel fuel.................................................. 3 NA1993 III None.................. B1.............. 150 203 242 60 L....... 220 L...... A......
....... Diethanol nitrosamine dinitrate (dry)........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Diethoxymethane.............................................. 3 UN2373 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... 3,3-Diethoxypropene.......................................... 3 UN2374 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Diethyl carbonate............................................ 3 UN2366 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diethyl cellosolve, see Ethylene glycol diethyl ether........ ........... .............. ...................... ................ ........... ........... .......
....... Diethyl ether or Ethyl ether................................. 3 UN1155 I FLAMMABLE LIQUID...... T21............. 150 201 243 1 L........ 30 L....... E...... 40
....... Diethyl ketone............................................... 3 UN1156 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Diethyl peroxydicarbonate, with more than 27 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Diethyl sulfate.............................................. 6.1 UN1594 II POISON................ B101, T14....... None 202 243 5 L........ 60 L....... C......
....... Diethyl sulfide.............................................. 3 UN2375 II FLAMMABLE LIQUID...... B101, T14....... None 202 243 1 L........ 60 L....... E......
....... Diethylamine................................................. 3 UN1154 II FLAMMABLE LIQUID, B101, N34, T8... None 202 243 1 L........ 5 L........ E...... 40
CORROSIVE.
....... Diethylaminoethanol.......................................... 3 UN2686 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diethylaminopropylamine...................................... 3 UN2684 III FLAMMABLE LIQUID, B1, T8.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... N,N-Diethylaniline........................................... 6.1 UN2432 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Diethylbenzene............................................... 3 UN2049 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diethyldichlorosilane........................................ 8 UN1767 II CORROSIVE, FLAMMABLE A7, B6, B100, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. N34, T8, T26.
....... Diethylene glycol dinitrate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Diethyleneglycol dinitrate, desensitized with not less than 1.1D UN0075 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 4E, 21E
25 percent non-volatile water-insoluble phlegmatizer, by
mass.
....... Diethylenetriamine........................................... 8 UN2079 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A...... 40
....... N,N-Diethylethylenediamine................................... 8 UN2685 II CORROSIVE, FLAMMABLE T8.............. None 202 243 1 L........ 30 L....... A......
LIQUID.
....... Diethylgold bromide.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Diethylthiophosphoryl chloride............................... 8 UN2751 II CORROSIVE............. B2, T8.......... None 212 240 15 kg...... 50 kg...... C...... 40
....... Diethylzinc.................................................. 4.2 UN1366 I SPONTANEOUSLY B11, T28, T40... None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE.
....... Difluorochloroethanes, see 1-Chloro-1,1-difluoroethanes...... ........... .............. ...................... ................ ........... ........... .......
....... 1,1-Difluoroethane, R152a.................................... 2.1 UN1030 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... 1,1-Difluoroethylene, R1132a................................. 2.1 UN1959 FLAMMABLE GAS......... ................ 306 304 None Forbidden.. 150 kg..... E...... 40
....... Difluoromethane.............................................. 2.1 UN3252 FLAMMABLE GAS......... ................ 306 302 314, 315 Forbidden.. 150 kg..... D...... 40
....... Difluorophosphoric acid, anhydrous........................... 8 UN1768 II CORROSIVE............. A6, A7, B2, N5, None 202 242 1 L........ 30 L....... A...... 40
N34, T9, T27.
....... 2,3-Dihydropyran............................................. 3 UN2376 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... 1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic Forbidden .............. ...................... ................ ........... ........... .......
acid).
....... Diiodoacetylene.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Diisobutyl ketone............................................ 3 UN1157 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diisobutylamine.............................................. 3 UN2361 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Diisobutylene, isomeric compounds............................ 3 UN2050 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Diisooctyl acid phosphate.................................... 8 UN1902 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Diisopropyl ether............................................ 3 UN1159 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... E...... 40
....... Diisopropylamine............................................. 3 UN1158 II FLAMMABLE LIQUID, B101, T8........ None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Diisopropylbenzene hydroperoxide, with more than 72 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Diketene, inhibited.......................................... 6.1 UN2521 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40, 49
LIQUID. B74, T38, T43,
T45.
....... 1,2-Dimethoxyethane.......................................... 3 UN2252 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... 1,1-Dimethoxyethane.......................................... 3 UN2377 II FLAMMABLE LIQUID...... T13............. 150 202 242 5 L........ 60 L....... B......
....... Dimethyl carbonate........................................... 3 UN1161 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Dimethyl chlorothiophosphate, see Dimethyl thiophosphoryl ........... .............. ...................... ................ ........... ........... .......
chloride.
....... 2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 Forbidden .............. ...................... ................ ........... ........... .......
percent with water.
....... Dimethyl disulfide........................................... 3 UN2381 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Dimethyl ether............................................... 2.1 UN1033 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Dimethyl-N-propylamine....................................... 3 UN2266 II FLAMMABLE LIQUID, T14, T26........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Dimethyl sulfate............................................. 6.1 UN1595 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, B77, T38,
T43, T45.
....... Dimethyl sulfide............................................. 3 UN1164 II FLAMMABLE LIQUID...... B100, T14....... None 202 242 5 L........ 60 L....... E...... 40
....... Dimethyl thiophosphoryl chloride............................. 6.1 UN2267 II POISON, CORROSIVE..... T7.............. None 202 243 1 L........ 30 L....... B...... 25
....... Dimethylamine, anhydrous..................................... 2.1 UN1032 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... D...... 40
....... Dimethylamine solution....................................... 3 UN1160 II FLAMMABLE LIQUID, T8, T34......... None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... 2-Dimethylaminoacetonitrile.................................. 3 UN2378 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... A...... 26, 40
POISON.
....... 2-Dimethylaminoethanol....................................... 8 UN2051 II CORROSIVE, FLAMMABLE B2, T8.......... 154 202 243 1 L........ 30 L....... A......
LIQUID.
....... Dimethylaminoethyl methacrylate.............................. 6.1 UN2522 II POISON................ T8.............. None 202 243 5 L........ 60 L....... B...... 40
....... N,N-Dimethylaniline.......................................... 6.1 UN2253 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... 2,3-Dimethylbutane........................................... 3 UN2457 II FLAMMABLE LIQUID...... T13............. 150 202 242 5 L........ 60 L....... E......
....... 1,3-Dimethylbutylamine....................................... 3 UN2379 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Dimethylcarbamoyl chloride................................... 8 UN2262 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A...... 40
....... Dimethylcyclohexanes......................................... 3 UN2263 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Dimethylcyclohexylamine...................................... 8 UN2264 II CORROSIVE, FLAMMABLE B2, T8.......... 154 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Dimethyldichlorosilane....................................... 3 UN1162 II FLAMMABLE LIQUID, B77, T15, T26... None 202 243 Forbidden.. Forbidden.. B...... 40
CORROSIVE.
....... Dimethyldiethoxysilane....................................... 3 UN2380 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Dimethyldioxanes............................................. 3 UN2707 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... N,N-Dimethylformamide........................................ 3 UN2265 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dimethylhexane dihydroperoxide (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dimethylhydrazine, symmetrical............................... 6.1 UN2382 I POISON, FLAMMABLE 2, A7, B9, B14, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B32, B74, B77,
T38, T43, T45.
....... Dimethylhydrazine, unsymmetrical............................. 6.1 UN1163 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 21, 38, 40,
LIQUID, CORROSIVE. B74, B79, T38, 100
T43, T45.
....... 2,2-Dimethylpropane.......................................... 2.1 UN2044 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Dimethylzinc................................................. 4.2 UN1370 I SPONTANEOUSLY B11, B16, T28, None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. T29, T40.
....... Dinitro-o-cresol, solid...................................... 6.1 UN1598 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Dinitro-o-cresol, solution................................... 6.1 UN1598 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... 1,3-Dinitro-5,5-dimethyl hydantoin........................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitro-7,8-dimethylglycoluril (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... 1,3-Dinitro-4,5-dinitrosobenzene............................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry).... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4-Dinitro-1,3,5-trimethylbenzene........................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitroanilines.............................................. 6.1 UN1596 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A...... 91
....... Dinitrobenzenes, liquid...................................... 6.1 UN1597 II POISON................ 11, T14......... None 202 243 5 L........ 60 L....... A...... 91
....... Dinitrobenzenes, solid....................................... 6.1 UN1597 II POISON................ 11.............. None 212 242 25 kg...... 100 kg..... A...... 91
....... Dinitrochlorobenzene, see Chlorodinitrobenzene............... ........... .............. ...................... ................ ........... ........... .......
....... 1,2-Dinitroethane............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... 1,1-Dinitroethane (dry)...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrogen tetroxide, liquefied.............................. 2.3 UN1067 POISON GAS, OXIDIZER, 1, B7, B12, B14, None 336 314 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE. B45, B46, B61,
B66, B67, B77.
....... Dinitroglycoluril or Dingu................................... 1.1D UN0489 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Dinitromethane............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrophenol, dry or wetted with less than 15 percent water, 1.1D UN0076 II EXPLOSIVE 1.1D, POISON ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Dinitrophenol solutions...................................... 6.1 UN1599 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 36
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 36
....... Dinitrophenol, wetted with not less than 15 percent water, by 4.1 UN1320 I FLAMMABLE SOLID, 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
mass. POISON. A20, N41.
....... Dinitrophenolates alkali metals, dry or wetted with less than 1.3C UN0077 II EXPLOSIVE 1.3C, POISON ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
15 percent water, by mass.
....... Dinitrophenolates, wetted with not less than 15 percent 4.1 UN1321 I FLAMMABLE SOLID, 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
water, by mass. POISON. A20, N41.
....... Dinitropropylene glycol...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitroresorcinol, dry or wetted with less than 15 percent 1.1D UN0078 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... 2,4-Dinitroresorcinol (heavy metal salts of) (dry)........... Forbidden .............. ...................... ................ ........... ........... .......
....... 4,6-Dinitroresorcinol (heavy metal salts of) (dry)........... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitroresorcinol, wetted with not less than 15 percent 4.1 UN1322 I FLAMMABLE SOLID....... 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
water, by mass. A20, N41.
....... 3,5-Dinitrosalicylic acid (lead salt) (dry).................. Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrosobenzene............................................. 1.3C UN0406 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Dinitrosobenzylamidine and salts of (dry).................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,2-Dinitrostilbene.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Dinitrotoluenes, liquid...................................... 6.1 UN2038 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... Dinitrotoluenes, molten...................................... 6.1 UN1600 II POISON................ B100, T14....... None 202 243 Forbidden.. Forbidden.. C......
....... Dinitrotoluenes, solid....................................... 6.1 UN2038 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... A......
....... 1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry)........ Forbidden .............. ...................... ................ ........... ........... .......
....... Dioxane...................................................... 3 UN1165 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Dioxolane.................................................... 3 UN1166 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Dipentene.................................................... 3 UN2052 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Diphenylamine chloroarsine................................... 6.1 UN1698 I POISON................ ................ None 201 None Forbidden.. Forbidden.. D...... 40
....... Diphenylchloroarsine, liquid................................. 6.1 UN1699 I POISON................ A8, B14, B32, None 201 243 Forbidden.. 30 L....... D...... 40
N33, N34.
....... Diphenylchloroarsine, solid.................................. 6.1 UN1699 I POISON................ A8, B14, B32, None 211 242 Forbidden.. 15 kg...... D...... 40
N33, N34.
....... Diphenyldichlorosilane....................................... 8 UN1769 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C...... 40
T26.
I...... Diphenylmethane-4,4'diisocyanate............................. 6.1 UN2489 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 48
....... Diphenylmethyl bromide....................................... 8 UN1770 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... D...... 40
....... Dipicryl sulfide, dry or wetted with less than 10 percent 1.1D UN0401 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Dipicryl sulfide, wetted with not less than 10 percent water, 4.1 UN2852 I FLAMMABLE SOLID....... A2, N41......... None 211 None Forbidden.. 0.5 kg..... D...... 28
by mass.
....... Dipicrylamine, see Hexanitrodiphenylamine.................... ........... .............. ...................... ................ ........... ........... .......
....... Dipropionyl peroxide, with more than 28 percent in solution.. Forbidden .............. ...................... ................ ........... ........... .......
....... Dipropyl ether............................................... 3 UN2384 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Dipropyl ketone.............................................. 3 UN2710 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Dipropylamine................................................ 3 UN2383 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Disinfectants, liquid, corrosive n.o.s....................... 8 UN1903 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... B......
............................................................. ........... .............. III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A......
....... Disinfectants, liquid, toxic, n.o.s.......................... 6.1 UN3142 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... A...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Disinfectants, solid, toxic, n.o.s........................... 6.1 UN1601 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Disodium trioxosilicate, pentahydrate........................ 8 UN3253 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Dispersant gases, n.o.s. see Refrigerant gases, n.o.s........ ........... .............. ...................... ................ ........... ........... .......
....... Dithiocarbamate pesticides, liquid, flammable, toxic, flash 3 UN2772 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Dithiocarbamate pesticides, liquid, toxic.................... 6.1 UN3006 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Dithiocarbamate pesticides, liquid, toxic, flammable, 6.1 UN3005 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Dithiocarbamate pesticides, solid, toxic..................... 6.1 UN2771 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Divinyl ether, inhibited..................................... 3 UN1167 I FLAMMABLE LIQUID...... T14............. None 201 243 5 L........ 60 L....... E...... 40
D...... Dodecylbenzenesulfonic acid.................................. 8 NA2584 II CORROSIVE............. B2.............. 154 202 242 1 L........ 30 L....... B...... 9
....... Dodecyltrichlorosilane....................................... 8 UN1771 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Dry ice, see Carbon dioxide, solid........................... ........... .............. ...................... ................ ........... ........... .......
....... Dyes, liquid, corrosive n.o.s. or Dye intermediates, liquid, 8 UN2801 II CORROSIVE............. 11, B2, T14..... 154 202 242 1 L........ 30 L....... A......
corrosive, n.o.s..
............................................................. ........... .............. III CORROSIVE............. 11, T7.......... 154 203 241 5 L........ 60 L....... A......
....... Dyes, liquid, toxic, n.o.s or Dye intermediates, liquid, 6.1 UN1602 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
toxic, n.o.s..
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220........ A......
....... Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, 8 UN3147 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
corrosive, n.o.s..
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, 6.1 UN3143 I POISON................ A5.............. None 211 242 5 kg....... 50 kg...... A......
toxic, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Dynamite, see Explosive, blasting, type A.................... ........... .............. ...................... ................ ........... ........... .......
....... Electrolyte (acid or alkali) for batteries, see Battery ........... .............. ...................... ................ ........... ........... .......
fluid, acid or Battery fluid, alkali.
....... Elevated temperature liquid, flammable, n.o.s., with flash 3 UN3256 III FLAMMABLE LIQUID...... T1.............. None None 247 Forbidden.. Forbidden.. A......
point above 37.8 C, at or above its flash point.
....... Elevated temperature liquid, n.o.s., at or above 100 C and 9 UN3257 III CLASS 9............... T1.............. None None 247 Forbidden.. Forbidden.. A...... 85
below its flash point.
....... Elevated temperature solid, n.o.s., at or above 240 C, see 9 UN3258 III CLASS 9............... ................ 247(h)(4) None 247 Forbidden.. Forbidden.. A...... 85
section 173.247(h)(4).
....... Engine starting fluid, with flammable gas.................... 2.1 UN1960 FLAMMABLE GAS......... ................ None 304 None Forbidden.. 150 kg..... D...... 40
....... Engines, internal combustion, including when fitted in 9 UN3166 CLASS 9............... ................ 220 220 None Forbidden.. No limit... A......
machinery or vehicles.
....... Environmentally hazardous substances, liquid, n.o.s.......... 9 UN3082 III CLASS 9............... 8, N50, T1...... 155 203 241 None....... None....... A......
....... Environmentally hazardous substances, solid, n.o.s........... 9 UN3077 III CLASS 9............... 8, N50, B54..... 155 213 240 None....... None....... A......
....... Epibromohydrin............................................... 6.1 UN2558 I POISON................ T18, T26........ None 201 243 Forbidden.. Forbidden.. D...... 40
....... Epichlorohydrin.............................................. 6.1 UN2023 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... 1,2-Epoxy-3-ethoxypropane.................................... 3 UN2752 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Esters, n.o.s................................................ 3 UN3272 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Etching acid, liquid, n.o.s., see Hydrofluoric acid, solution ........... .............. ...................... ................ ........... ........... .......
etc..
....... Ethane, compressed........................................... 2.1 UN1035 FLAMMABLE GAS......... ................ 306 304 302 Forbidden.. 150 kg..... E...... 40
D...... Ethane-Propane mixture, refrigerated liquid.................. 2.1 NA1961 FLAMMABLE GAS......... ................ None 316 314, 315 Forbidden.. Forbidden.. D...... 40
....... Ethane, refrigerated liquid.................................. 2.1 UN1961 FLAMMABLE GAS......... ................ None None 315 Forbidden.. Forbidden.. D...... 40
....... Ethanol amine dinitrate...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl 3 UN1170 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... A......
alcohol solutions.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethanolamine or Ethanolamine solutions....................... 8 UN2491 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Ether, see Diethyl ether..................................... ........... .............. ...................... ................ ........... ........... .......
....... Ethers, n.o.s................................................ 3 UN3271 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl acetate................................................ 3 UN1173 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl acrylate, inhibited.................................... 3 UN1917 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Ethyl alcohol, see Ethanol................................... ........... .............. ...................... ................ ........... ........... .......
....... Ethyl aldehyde, see Acetaldehyde............................. ........... .............. ...................... ................ ........... ........... .......
....... Ethyl amyl ketone............................................ 3 UN2271 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... N-Ethyl-N-benzylaniline...................................... 6.1 UN2274 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Ethyl borate................................................. 3 UN1176 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl bromide................................................ 6.1 UN1891 II POISON................ B100, T17....... None 202 243 5 L........ 60 L....... B...... 40, 85
....... Ethyl bromoacetate........................................... 6.1 UN1603 II POISON................ T14............. None 202 243 Forbidden.. Forbidden.. D...... 40
....... Ethyl butyl ether............................................ 3 UN1179 II FLAMMABLE LIQUID...... B1, B101, T1.... 150 202 242 5 L........ 60 L....... B......
....... Ethyl butyrate............................................... 3 UN1180 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl chloride............................................... 2.1 UN1037 FLAMMABLE GAS......... B63, B77........ None 322 314, 315 Forbidden.. 150 kg..... B...... 40
....... Ethyl chloroacetate.......................................... 6.1 UN1181 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Ethyl chloroformate.......................................... 6.1 UN1182 I POISON, FLAMMABLE 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. D...... 21, 40, 100
LIQUID, CORROSIVE. B9, B14, B32,
B74, N34, T38,
T43, T45.
....... Ethyl 2-chloropropionate..................................... 3 UN2935 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Ethyl chlorothioformate...................................... 8 UN2826 II CORROSIVE, POISON, 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. A...... 40
FLAMMABLE LIQUID. B74, T38, T43,
T45.
....... Ethyl crotonate.............................................. 3 UN1862 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl cyanoacetate........................................... 6.1 UN2666 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 26
....... Ethyl ether, see Diethyl ether............................... ........... .............. ...................... ................ ........... ........... .......
....... Ethyl fluoride............................................... 2.1 UN2453 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Ethyl formate................................................ 3 UN1190 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E......
....... Ethyl hydroperoxide.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethyl isobutyrate............................................ 3 UN2385 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
+...... Ethyl isocyanate............................................. 3 UN2481 I FLAMMABLE LIQUID, 1, A7, B9, B14, None 226 244 Forbidden.. 30 L....... D...... 40
POISON. B30, B72, T38,
T43, T44.
....... Ethyl lactate................................................ 3 UN1192 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl mercaptan.............................................. 3 UN2363 I FLAMMABLE LIQUID...... T21............. None 201 243 Forbidden.. 30 L....... E...... 95, 102
....... Ethyl methacrylate........................................... 3 UN2277 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl methyl ether........................................... 2.1 UN1039 FLAMMABLE GAS......... B63............. None 324 314, 315 Forbidden.. 150 kg..... B...... 40
....... Ethyl methyl ketone or Methyl ethyl ketone................... 3 UN1193 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl nitrite solutions...................................... 3 UN1194 I FLAMMABLE LIQUID, ................ None 201 None Forbidden.. Forbidden.. E...... 40, 105
POISON.
....... Ethyl orthoformate........................................... 3 UN2524 III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Ethyl oxalate................................................ 6.1 UN2525 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Ethyl perchlorate............................................ Forbidden .............. ...................... ................ ........... ........... .......
D...... Ethyl phosphonothioic dichloride, anhydrous.................. 6.1 NA2927 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
B74, T38, T43,
T45.
D...... Ethyl phosphonous dichloride, anhydrous pyrophoric liquid.... 6.1 NA2845 I POISON, SPONTANEOUSLY 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. B74, T38, T43,
T45.
D...... Ethyl phosphorodichloridate.................................. 6.1 NA2927 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
B74, T38, T43,
T45.
....... Ethyl propionate............................................. 3 UN1195 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Ethyl propyl ether........................................... 3 UN2615 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... E......
....... Ethyl silicate, see Tetraethyl silicate...................... ........... .............. ...................... ................ ........... ........... .......
....... Ethylacetylene, inhibited.................................... 2.1 UN2452 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Ethylamine................................................... 2.1 UN1036 FLAMMABLE GAS......... B77............. None 321 314, 315 Forbidden.. 150 kg..... D...... 40
....... Ethylamine, aqueous solution with not less than 50 percent 3 UN2270 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 5 L........ B...... 40
but not more than 70 percent ethylamine. CORROSIVE.
....... N-Ethylaniline............................................... 6.1 UN2272 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... 2-Ethylaniline............................................... 6.1 UN2273 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Ethylbenzene................................................. 3 UN1175 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... N-Ethylbenzyltoluidines liquid............................... 6.1 UN2753 III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A......
....... N-Ethylbenzyltoluidines solid................................ 6.1 UN2753 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... 2-Ethylbutanol............................................... 3 UN2275 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 2-Ethylbutyl acetate......................................... 3 UN1177 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 2-Ethylbutyraldehyde......................................... 3 UN1178 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Ethyldichloroarsine.......................................... 6.1 UN1892 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, T38, T43,
T45.
....... Ethyldichlorosilane.......................................... 4.3 UN1183 I DANGEROUS WHEN WET, A2, A3, A7, N34, None 201 244 Forbidden.. 1 L........ D...... 21, 28, 40,
CORROSIVE, FLAMMABLE T18, T26. 49, 100
LIQUID.
....... Ethylene, acetylene and propylene in mixtures, refrigerated 2.1 UN3138 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. Forbidden.. D...... 40
liquid with at least 71.5 percent ethylene with not more
than 22.5 percent acetylene and not more than 6 percent
propylene.
....... Ethylene chlorohydrin........................................ 6.1 UN1135 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, T38, T43,
T45.
....... Ethylene, compressed......................................... 2.1 UN1962 FLAMMABLE GAS......... ................ 306 304 302 Forbidden.. 150 kg..... E...... 40
....... Ethylene diamine diperchlorate............................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethylene dibromide........................................... 6.1 UN1605 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, B77, T38,
T43, T45.
....... Ethylene dibromide and methyl bromide liquid mixtures, see ........... .............. ...................... ................ ........... ........... .......
Methyl bromide and ethylene dibromide, liquid mixtures.
....... Ethylene dichloride.......................................... 3 UN1184 II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... B...... 40
POISON.
....... Ethylene glycol diethyl ether................................ 3 UN1153 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol dinitrate.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Ethylene glycol monobutyl ether.............................. 6.1 UN2369 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Ethylene glycol monoethyl ether.............................. 3 UN1171 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol monoethyl ether acetate...................... 3 UN1172 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol monomethyl ether............................. 3 UN1188 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene glycol monomethyl ether acetate..................... 3 UN1189 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ethylene oxide and carbon dioxide mixture with more than 87 2.3 UN3300 POISON GAS, FLAMMABLE 4............... None 304 314, 315 Forbidden.. 75 kg...... D...... 40
percent ethylene oxide. GAS.
....... Ethylene oxide and carbon dioxide mixtures with more than 9 2.1 UN1041 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 25 kg...... B...... 40
percent but not more than 87 percent ethylene oxide.
....... Ethylene oxide and carbon dioxide mixtures with not more than 2.2 UN1952 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
9 percent ethylene oxide.
....... Ethylene oxide and chlorotetrafluoroethane mixture with not 2.2 UN3297 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
more than 8.8 percent ethylene oxide.
....... Ethylene oxide and dichlorodifluoromethane mixture, with not 2.2 UN3070 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
more than 12.5 percent ethylene oxide.
....... Ethylene oxide and pentafluoroethane mixture with not more 2.2 UN3298 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
than 7.9 percent ethylene oxide.
....... Ethylene oxide and propylene oxide mixtures, with not more 3 UN2983 I FLAMMABLE LIQUID, 5, A11, N4, N34, None 201 243 Forbidden.. 30 L....... E...... 40
than 30 percent ethylene oxide. POISON. T24, T29.
....... Ethylene oxide and tetrafluoroethane mixture with not more 2.2 UN3299 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
than 5.6 percent ethylene oxide.
....... Ethylene oxide or Ethylene oxide with nitrogen up to a total 2.3 UN1040 POISON GAS, FLAMMABLE 4, 25........... None 323 323 Forbidden.. 25 kg...... D...... 40
pressure of 1MPa (10 bar) at 50 degrees C. GAS.
....... Ethylene, refrigerated liquid (cryogenic liquid)............. 2.1 UN1038 FLAMMABLE GAS......... ................ None 316 318, 319 Forbidden.. Forbidden.. D...... 40
....... Ethylenediamine.............................................. 8 UN1604 II CORROSIVE, FLAMMABLE T14............. 154 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Ethyleneimine, inhibited..................................... 6.1 UN1185 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B72, B77, N25,
N32, T38, T43,
T44.
....... Ethylhexaldehyde, see Octyl aldehydes etc.................... ........... .............. ...................... ................ ........... ........... .......
....... 2-Ethylhexyl chloroformate................................... 6.1 UN2748 II POISON, CORROSIVE..... T12............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
....... 2-Ethylhexylamine............................................ 3 UN2276 III FLAMMABLE LIQUID, B1, T2.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Ethylphenyldichlorosilane.................................... 8 UN2435 II CORROSIVE............. A7, B2, N34, T8, None 202 242 Forbidden.. 30 L....... C......
T26.
....... 1-Ethylpiperidine............................................ 3 UN2386 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... N-Ethyltoluidines............................................ 6.1 UN2754 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Ethyltrichlorosilane......................................... 3 UN1196 II FLAMMABLE LIQUID, A7, B100, N34, None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE. T15, T26.
....... Etiologic agent, see Infectious substances, etc.)............ ........... .............. ...................... ................ ........... ........... .......
....... Explosive articles, see Articles, explosive , n.o.s. etc..... ........... .............. ...................... ................ ........... ........... .......
....... Explosive, blasting, type A.................................. 1.1D UN0081 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 21E
....... Explosive, blasting, type B.................................. 1.1D UN0082 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type B or Agent blasting, Type B........ 1.5D UN0331 II EXPLOSIVE 1.5D........ 105, 106........ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type C.................................. 1.1D UN0083 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type D.................................. 1.1D UN0084 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, blasting, type E.................................. 1.1D UN0241 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
....... Explosive, blasting, type E or Agent blasting, Type E........ 1.5D UN0332 II EXPLOSIVE 1.5D........ 105, 106........ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Explosive, forbidden. See Sec. 173.54........................ Forbidden .............. ...................... ................ ........... ........... .......
D...... Explosive pest control devices............................... 1.1E NA0006 II EXPLOSIVE 1.1E........ ................ None 62 None Forbidden.. Forbidden.. E......
D...... Explosive pest control devices............................... 1.4E NA0412 II EXPLOSIVE 1.4E........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Explosive substances, see Substances, explosive, n.o.s. etc.. ........... .............. ...................... ................ ........... ........... .......
....... Explosives, slurry, see Explosive, blasting, type E.......... ........... .............. ...................... ................ ........... ........... .......
....... Explosives, water gels, see Explosive, blasting, type E...... ........... .............. ...................... ................ ........... ........... .......
....... Extracts, aromatic, liquid................................... 3 UN1169 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Extracts, flavoring, liquid.................................. 3 UN1197 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Fabric with animal or vegetable oil, see Fibers or fabrics, ........... .............. ...................... ................ ........... ........... .......
etc..
....... Ferric arsenate.............................................. 6.1 UN1606 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ferric arsenite.............................................. 6.1 UN1607 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Ferric chloride, anhydrous................................... 8 UN1773 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Ferric chloride, solution.................................... 8 UN2582 III CORROSIVE............. B15, T8......... 154 203 241 5 L........ 60 L....... A......
....... Ferric nitrate............................................... 5.1 UN1466 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Ferrocerium.................................................. 4.1 UN1323 II FLAMMABLE SOLID....... A19............. 151 212 240 15 kg...... 50 kg...... A......
....... Ferrosilicon, with 30 percent or more but less than 90 4.3 UN1408 III DANGEROUS WHEN WET, A1, A19......... None 213 240 25 kg...... 100 kg..... A...... 13, 40, 85,
percent silicon. KEEP AWAY FROM FOOD. 103
....... Ferrous arsenate............................................. 6.1 UN1608 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Ferrous chloride, solid...................................... 8 NA1759 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
D...... Ferrous chloride, solution................................... 8 NA1760 II CORROSIVE............. B3.............. 154 202 242 1 L........ 30 L....... B...... 40
....... Ferrous metal borings or Ferrous metal shavings or Ferrous 4.2 UN2793 III SPONTANEOUSLY A1, A19, B101... None 213 241 25 kg...... 100 kg..... A......
metal turnings or Ferrous metal cuttings in a form liable to COMBUSTIBLE.
self-heating.
....... Fertilizer ammoniating solution with free ammonia............ 2.2 UN1043 NONFLAMMABLE GAS...... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
AIW.... Fibers or Fabrics, animal or vegetable or Synthentic, n.o.s. 4.2 UN1373 III SPONTANEOUSLY ................ None 213 241 Forbidden.. Forbidden.. A......
with animal or vegetable oil. COMBUSTIBLE.
....... Fibers or Fabrics impregnated with weakly nitrated 4.1 UN1353 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... D......
nitrocellulose, n.o.s..
....... Films, nitrocellulose base, from which gelatine has been ........... .............. ...................... ................ ........... ........... .......
removed; film scrap, see Celluloid scrap.
....... Films, nitrocellulose base, gelatine coated (except scrap)... 4.1 UN1324 III FLAMMABLE SOLID....... ................ None 183 None 25 kg...... 100 kg..... D...... 91
....... Fire extinguisher charges, corrosive liquid.................. 8 UN1774 II CORROSIVE............. N41............. 154 202 None 1 L........ 30 L....... A......
....... Fire extinguisher charges, expelling, explosive, see ........... .............. ...................... ................ ........... ........... .......
Cartridges, power device.
....... Fire extinguishers containing compressed or liquefied gas.... 2.2 UN1044 NONFLAMMABLE GAS...... ................ 309 309 None 75 kg...... 150 kg..... A......
....... Firelighters, solid with flammable liquid.................... 4.1 UN2623 II FLAMMABLE SOLID....... A19............. None 212 None 15 kg...... 50 kg...... A...... 119
............................................................. ........... .............. III FLAMMABLE SOLID....... A1, A19......... None 213 None 25 kg...... 100 kg..... A...... 119
....... Fireworks.................................................... 1.1G UN0333 II EXPLOSIVE 1.1G........ 108............. None 62 None Forbidden.. Forbidden.. B......
....... Fireworks.................................................... 1.2G UN0334 II EXPLOSIVE 1.2G........ 108............. None 62 None Forbidden.. Forbidden.. B......
....... Fireworks.................................................... 1.3G UN0335 II EXPLOSIVE 1.3G........ 108............. None 62 None Forbidden.. Forbidden.. B......
....... Fireworks.................................................... 1.4G UN0336 II EXPLOSIVE 1.4G........ 108............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fireworks.................................................... 1.4S UN0337 II EXPLOSIVE 1.4S........ 108............. None 62 None 25 kg...... 100 kg..... A......
W...... Fish meal, stabilized or Fish scrap, stabilized.............. 9 UN2216 III None.................. ................ 155 218 218 No limit... No limit... A...... 88
....... Fish meal, unstablized or Fish scrap, unstabilized........... 4.2 UN1374 II SPONTANEOUSLY A1, A19......... None 212 241 15 kg...... 50 kg...... A...... 119, 120
COMBUSTIBLE.
....... Fissile radioactive materials, see Radioactive material, ........... .............. ...................... ................ ........... ........... .......
fissile, n.o.s..
....... Flammable compressed gas, see Compressed or Liquefied gas, ........... .............. ...................... ................ ........... ........... .......
flammable, etc..
....... Flammable compressed gas (small receptacles not fitted with a ........... .............. ...................... ................ ........... ........... .......
dispersion device, not refillable), see Receptacles, etc..
....... Flammable gas in lighters, see Lighters or lighter refills, ........... .............. ...................... ................ ........... ........... .......
containing flammable gas.
....... Flammable liquid, toxic, corrosive, n.o.s.................... 3 UN3286 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 2.5 L...... E...... 21, 40, 100
POISON, CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 5 L........ B...... 21, 40, 100
POISON, CORROSIVE.
....... Flammable liquids, corrosive, n.o.s.......................... 3 UN2924 I FLAMMABLE LIQUID, T42............. None 201 243 0.5 L...... 2.5 L...... E...... 40
CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, T15, T26........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1, T15, T26.... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Flammable liquids, n.o.s..................................... 3 UN1993 I FLAMMABLE LIQUID...... T42............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 203 242 60 L....... 220 L...... A......
....... Flammable liquids, toxic, n.o.s.............................. 3 UN1992 I FLAMMABLE LIQUID, T42............. None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T18............. None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T18......... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Flammable solid, corrosive, inorganic, n.o.s................. 4.1 UN3180 II FLAMMABLE SOLID, A1, B106........ 151 212 242 15 kg...... 50 kg...... D...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE SOLID, A1, B106........ 151 213 242 25 kg...... 100 kg..... D...... 40
CORROSIVE.
....... Flammable solid, inorganic, n.o.s............................ 4.1 UN3178 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... B......
....... Flammable solid, organic, molten, n.o.s...................... 4.1 UN3176 II FLAMMABLE SOLID....... T9.............. 151 212 240 Forbidden.. Forbidden.. C......
............................................................. ........... .............. III FLAMMABLE SOLID....... T9.............. 151 213 240 Forbidden.. Forbidden.. C......
....... Flammable solid, toxic, inorganic, n.o.s..................... 4.1 UN3179 II FLAMMABLE SOLID, A1, B106........ 151 212 242 15 kg...... 50 kg...... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE SOLID, KEEP A1, B106........ 151 213 242 25 kg...... 100 kg..... B...... 40
AWAY FROM FOOD.
....... Flammable solids, corrosive, organic, n.o.s.................. 4.1 UN2925 II FLAMMABLE SOLID, A1, B106........ None 212 242 15 kg...... 50 kg...... D...... 40
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE SOLID, A1, B106........ 151 213 242 25 kg...... 100 kg..... D...... 40
CORROSIVE.
....... Flammable solids, organic, n.o.s............................. 4.1 UN1325 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... B......
....... Flammable solids, toxic, organic, n.o.s...................... 4.1 UN2926 II FLAMMABLE SOLID, A1, B106........ None 212 242 15 kg...... 50 kg...... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE SOLID, KEEP A1, B106........ 151 213 242 25 kg...... 100 kg..... B...... 40
AWAY FROM FOOD.
....... Flares, aerial............................................... 1.3G UN0093 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Flares, aerial............................................... 1.4G UN0403 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Flares, aerial............................................... 1.4S UN0404 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Flares, aerial............................................... 1.1G UN0420 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, aerial............................................... 1.2G UN0421 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, airplane, see Flares, aerial......................... ........... .............. ...................... ................ ........... ........... .......
....... Flares, signal, see Cartridges, signal....................... ........... .............. ...................... ................ ........... ........... .......
....... Flares, surface.............................................. 1.3G UN0092 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Flares, surface.............................................. 1.1G UN0418 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, surface.............................................. 1.2G UN0419 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Flares, water-activated, see Contrivances, water-activated, ........... .............. ...................... ................ ........... ........... .......
etc..
....... Flash powder................................................. 1.1G UN0094 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
....... Flash powder................................................. 1.3G UN0305 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
....... Flue dusts, poisonous, see Arsenical dust.................... ........... .............. ...................... ................ ........... ........... .......
....... Fluoric acid, see Hydrofluoric acid, solution, etc........... ........... .............. ...................... ................ ........... ........... .......
....... Fluorine, compressed......................................... 2.3 UN1045 POISON GAS, OXIDIZER, 1............... None 302 None Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE.
....... Fluoroacetic acid............................................ 6.1 UN2642 I POISON................ B100............ None 211 242 1 kg....... 15 kg...... E......
....... Fluoroanilines............................................... 6.1 UN2941 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A......
....... Fluorobenzene................................................ 3 UN2387 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... B......
....... Fluoroboric acid............................................. 8 UN1775 II CORROSIVE............. A6, A7, B2, B15, 154 202 242 1 L........ 30 L....... A......
N3, N34, T15,
T27.
....... Fluorophosphoric acid anhydrous.............................. 8 UN1776 II CORROSIVE............. A6, A7, B2, N3, None 202 242 1 L........ 30 L....... A......
N34, T9, T27.
....... Fluorosilicates, n.o.s....................................... 6.1 UN2856 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Fluorosilicic acid........................................... 8 UN1778 II CORROSIVE............. A6, A7, B2, B15, None 202 242 1 L........ 30 L....... A......
N3, N34, T12,
T27.
....... Fluorosulfonic acid.......................................... 8 UN1777 I CORROSIVE............. A3, A6, A7, A10, None 201 243 0.5 L...... 2.5 L...... D...... 40
B6, B10, B41,
N3, T9, T27.
....... Fluorotoluenes............................................... 3 UN2388 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Forbidden materials. See 173.21.............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Formaldehyde, solutions, flammable........................... 3 UN1198 III FLAMMABLE LIQUID, B1, T8.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Formaldehyde, solutions, with not less than 25 percent 8 UN2209 III CORROSIVE............. T1.............. 154 203 241 5 L........ 60 L....... A......
formaldehyde.
....... Formalin, see Formaldehyde, solutions........................ ........... .............. ...................... ................ ........... ........... .......
....... Formic acid.................................................. 8 UN1779 II CORROSIVE............. B2, B12, B28, T8 154 202 242 1 L........ 30 L....... A...... 40
....... Fracturing devices, explosive, without detonators for oil 1.1D UN0099 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
wells.
....... Fuel, aviation, turbine engine............................... 3 UN1863 I FLAMMABLE LIQUID...... T7.............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
D...... Fuel oil (No. 1, 2, 4, 5, or 6).............................. 3 NA1993 III FLAMMABLE LIQUID...... B1.............. 150 203 242 60 L....... 220 L...... A......
....... Fulminate of mercury (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminate of mercury, wet, see Mercury fulminate, etc........ ........... .............. ...................... ................ ........... ........... .......
....... Fulminating gold............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminating mercury.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminating platinum......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminating silver........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Fulminic acid................................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Fumaryl chloride............................................. 8 UN1780 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C...... 8, 40
....... Furan........................................................ 3 UN2389 I FLAMMABLE LIQUID...... T18............. None 201 243 1 L........ 30 L....... E...... 40
....... Furfural..................................................... 3 UN1199 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Furfuryl alcohol............................................. 6.1 UN2874 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A...... 26, 74
....... Furfurylamine................................................ 3 UN2526 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Fuse, detonating, metal clad, see Cord, detonating, metal ........... .............. ...................... ................ ........... ........... .......
clad.
....... Fuse, detonating, mild effect, metal clad, see Cord, ........... .............. ...................... ................ ........... ........... .......
detonating, mild effect, metal clad.
....... Fuse, igniter tubular metal clad............................. 1.4G UN0103 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuse, instantaneous, non-detonating or Quickmatch............ 1.3G UN0101 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuse, safety................................................. 1.4S UN0105 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
D...... Fusee (railway or highway)................................... 4.1 NA1325 II FLAMMABLE SOLID....... ................ None 184 None 15 kg...... 50 kg...... B......
....... Fusel oil.................................................... 3 UN1201 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Fuses, tracer, see Tracers for ammunition.................... ........... .............. ...................... ................ ........... ........... .......
....... Fuzes, combination, percussion and time, see Fuzes, ........... .............. ...................... ................ ........... ........... .......
detonating (UN 0257, UN 0367); Fuzes, igniting (UN 0317, UN
0368).
....... Fuzes, detonating............................................ 1.1B UN0106 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Fuzes, detonating............................................ 1.2B UN0107 II EXPLOSIVE 1.2B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Fuzes, detonating............................................ 1.4B UN0257 II EXPLOSIVE 1.4B........ 116............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuzes, detonating............................................ 1.4S UN0367 II EXPLOSIVE 1.4S........ 116............. None 62 None 25 kg...... 100 kg..... A......
....... Fuzes, detonating, with protective features.................. 1.1D UN0408 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuzes, detonating, with protective features.................. 1.2D UN0409 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuzes, detonating, with protective features.................. 1.4D UN0410 II EXPLOSIVE 1.4D........ 116............. None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuzes, igniting.............................................. 1.3G UN0316 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Fuzes, igniting.............................................. 1.4G UN0317 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Fuzes, igniting.............................................. 1.4S UN0368 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Galactsan trinitrate......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Gallium...................................................... 8 UN2803 III CORROSIVE............. ................ None 162 240 20 kg...... 20 kg...... B...... 48
....... Gas generator assemblies (aircraft), containing a non- 2.2 .............. NONFLAMMABLE GAS...... ................ None 335 None 75 kg...... 150 kg..... A......
flammable non-toxic gas and a propellant cartridge.
D...... Gas identification set....................................... 2.3 NA9035 POISON GAS............ 6............... None 194 None Forbidden.. Forbidden.. D......
....... Gas oil or Diesel fuel or Heating oil, light................. 3 UN1202 III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Gas, refrigerated liquid, n.o.s.............................. 2.2 UN3158 NONFLAMMABLE GAS...... ................ 306 304 314, 315 50 kg...... 500 kg..... D......
....... Gas sample, non-pressurized, flammable, n.o.s., not 2.1 UN3167 FLAMMABLE GAS......... ................ 306 302, 304 None 1 L........ 5 L........ D......
refrigerated liquid.
....... Gas sample, non-pressurized, toxic, flammable, n.o.s., not 2.3 UN3168 POISON GAS, FLAMMABLE ................ 306 302 None Forbidden.. 1 L........ D......
refrigerated liquid. GAS.
....... Gas sample, non-pressurized, toxic, n.o.s., not refrigerated 2.3 UN3169 POISON GAS............ ................ 306 302, 304 None Forbidden.. 1 L........ D......
liquid.
D...... Gasohol gasoline mixed with ethyl alcohol, with not more than 3 NA1203 II FLAMMABLE LIQUID...... ................ 150 202 242 5 L........ 60 L....... E......
20 percent alcohol.
....... Gasoline..................................................... 3 UN1203 II FLAMMABLE LIQUID...... B33, B101, T8... 150 202 242 5 L........ 60 L....... E......
....... Gasoline, casinghead, see Gasoline........................... ........... .............. ...................... ................ ........... ........... .......
....... Gelatine, blasting, see Explosive, blasting, type A.......... ........... .............. ...................... ................ ........... ........... .......
....... Gelatine dynamites, see Explosive, blasting, type A.......... ........... .............. ...................... ................ ........... ........... .......
....... Germane...................................................... 2.3 UN2192 POISON GAS, FLAMMABLE 2, 25........... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Glycerol-1,3-dinitrate....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Glycerol gluconate trinitrate................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Glycerol lactate trinitrate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Glycerol alpha-monochlorohydrin.............................. 6.1 UN2689 III KEEP AWAY FROM FOOD... T2.............. 153 203 241 60 L....... 220 L...... A......
....... Glyceryl trinitrate, see Nitroglycerin, etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Glycidaldehyde............................................... 3 UN2622 II FLAMMABLE LIQUID, T8.............. 150 202 243 1 L........ 60 L....... A...... 40
POISON.
D...... Grenades, empty primed....................................... 1.4S NA0349 II None.................. ................ None 62 None 25 kg...... 100 kg..... A......
....... Grenades, hand or rifle, with bursting charge................ 1.1D UN0284 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades, hand or rifle, with bursting charge................ 1.2D UN0285 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades, hand or rifle, with bursting charge................ 1.1F UN0292 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Grenades, hand or rifle, with bursting charge................ 1.2F UN0293 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Grenades, illuminating, see Ammunition, illuminating, etc.... ........... .............. ...................... ................ ........... ........... .......
....... Grenades, practice, hand or rifle............................ 1.4S UN0110 II EXPLOSIVE 1.4S........ ................ 62 None 25 kg...... 100 kg..... A......
....... Grenades, practice, hand or rifle............................ 1.3G UN0318 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades, practice, hand or rifle............................ 1.2G UN0372 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B......
....... Grenades practice Hand or rifle.............................. 1.4G UN0452 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 24E
....... Grenades, smoke, see Ammunition, smoke, etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Guanidine nitrate............................................ 5.1 UN1467 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A...... 73
....... Guanyl nitrosaminoguanylidene hydrazine (dry)................ Forbidden .............. ...................... ................ ........... ........... .......
....... Guanyl nitrosaminoguanylidene hydrazine, wetted with not less 1.1A UN0113 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
than 30 percent water, by mass.
....... Guanyl nitrosaminoguanyltetrazene (dry)...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Guanyl nitrosaminoguanyltetrazene, wetted or Tetrazene, 1.1A UN0114 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
wetted with not less than 30 percent water or mixture of
alcohol and water, by mass.
....... Gunpowder, compressed or Gunpowder in pellets, see Black ........... .............. ...................... ................ ........... ........... .......
powder (UN 0028).
....... Gunpowder, granular or as a meal, see Black powder (UN 0027). ........... .............. ...................... ................ ........... ........... .......
....... Hafnium powder, dry.......................................... 4.2 UN2545 I SPONTANEOUSLY B100............ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY A19, A20, B100, None 212 241 15 kg...... 50 kg...... D......
COMBUSTIBLE. N34.
............................................................. ........... .............. III SPONTANEOUSLY B100............ None 213 241 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Hafnium powder, wetted with not less than 25 percent water (a 4.1 UN1326 II FLAMMABLE SOLID....... A6, A19, A20, None 212 241 15 kg...... 50 kg...... E......
visible excess of water must be present) (a) mechanically N34.
produced, particle size less than 53 microns; (b) chemically
produced, particle size less than 840 microns.
....... Halogenated irritating liquids, n.o.s........................ 6.1 UN1610 I POISON................ T42............. None 201 243 Forbidden.. Forbidden.. D...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... D...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... D...... 40
....... Hand signal device, see Signal devices, hand................. ........... .............. ...................... ................ ........... ........... .......
....... Hazardous substances, liquid or solid, n.o.s., see ........... .............. ...................... ................ ........... ........... .......
Environmentally hazardous substances, etc..
D...... Hazardous waste, liquid, n.o.s............................... 9 NA3082 III CLASS 9............... ................ 155 203 241 No limit... No limit... A......
D...... Hazardous waste, solid, n.o.s................................ 9 NA3077 III CLASS 9............... B54............. 155 213 240 No limit... No limit... A......
....... Helium, compressed........................................... 2.2 UN1046 NONFLAMMABLE GAS...... ................ 306 302 302, 314 75 kg...... 150 kg..... A...... 85
....... Helium-oxygen mixture, see Rare gases and oxygen mixtures.... ........... .............. ...................... ................ ........... ........... .......
....... Helium, refrigerated liquid (cryogenic liquid)............... 2.2 UN1963 NONFLAMMABLE GAS...... ................ 320 316 318 50 kg...... 500 kg..... B......
....... Heptafluoropropane........................................... 2.2 UN3296 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... n-Heptaldehyde............................................... 3 UN3056 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Heptanes..................................................... 3 UN1206 II FLAMMABLE LIQUID...... T2.............. 150 202 242 5 L........ 60 L....... B......
....... n-Heptene.................................................... 3 UN2278 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... B......
....... Hexachloroacetone............................................ 6.1 UN2661 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... B...... 12, 40
....... Hexachlorobenzene............................................ 6.1 UN2729 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A......
....... Hexachlorobutadiene.......................................... 6.1 UN2279 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Hexachlorocyclopentadiene.................................... 6.1 UN2646 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, B77, T38,
T43, T45.
....... Hexachlorophene.............................................. 6.1 UN2875 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Hexadecyltrichlorosilane..................................... 8 UN1781 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8.
....... Hexadienes................................................... 3 UN2458 II FLAMMABLE LIQUID...... B101, T7........ None 202 242 5 L........ 60 L....... B......
....... Hexaethyl tetraphosphate and compressed gas mixtures......... 2.3 UN1612 POISON GAS............ 3............... None 334 None Forbidden.. Forbidden.. D...... 40
....... Hexaethyl tetraphosphate liquid.............................. 6.1 UN1611 I POISON................ A4.............. None 201 243 1 L........ 30 L....... E...... 40
............................................................. ........... .............. II POISON................ N76............. None 202 243 5 L........ 60 L....... E...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N77............. None 203 241 60 L....... 220 L...... E...... 40
....... Hexaethyl tetraphosphate, solid.............................. 6.1 UN1611 I POISON................ ................ None 211 242 Forbidden.. 15 kg...... E...... 40
............................................................. ........... .............. II POISON................ N76............. None 212 242 25 kg...... 100 kg..... E...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N77............. 153 213 240 100 kg..... 200 kg..... E...... 40
....... Hexafluoroacetone............................................ 2.3 UN2420 POISON GAS, CORROSIVE. 2, B9, B14...... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Hexafluoroacetone hydrate.................................... 6.1 UN2552 II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
....... Hexafluoroethane, R116....................................... 2.2 UN2193 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Hexafluorophosphoric acid.................................... 8 UN1782 II CORROSIVE............. A6, A7, B2, N3, None 202 242 1 L........ 30 L....... A......
N34, T9, T27.
D...... Hexafluoropropylene oxide.................................... 2.2 NA1956 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Hexafluoropropylene, R1216................................... 2.2 UN1858 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Hexaldehyde.................................................. 3 UN1207 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Hexamethylene diisocyanate................................... 6.1 UN2281 II POISON................ B101, T14....... None 202 243 5 L........ 60 L....... B...... 13, 40
....... Hexamethylene triperoxide diamine (dry)...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexamethylenediamine, solid.................................. 8 UN2280 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 12
....... Hexamethylenediamine solution................................ 8 UN1783 II CORROSIVE............. T8.............. None 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Hexamethyleneimine........................................... 3 UN2493 II FLAMMABLE LIQUID, B101, T8........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Hexamethylenetetramine....................................... 4.1 UN1328 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Hexamethylol benzene hexanitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanes...................................................... 3 UN1208 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... E......
....... 2,2',4,4',6,6'-Hexanitro-3,3'-dihydroxyazobenzene (dry)...... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitroazoxy benzene....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... N,N'-(hexanitrodiphenyl) ethylene dinitramine (dry).......... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrodiphenyl urea....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,2',3',4,4',6-Hexanitrodiphenylamine........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrodiphenylamine or Dipicrylamine or Hexyl............. 1.1D UN0079 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... 2,3',4,4',6,6'-Hexanitrodiphenylether........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitroethane.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrooxanilide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hexanitrostilbene............................................ 1.1D UN0392 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Hexanoic acid, see Corrosive liquids, n.o.s.................. ........... .............. ...................... ................ ........... ........... .......
....... Hexanols..................................................... 3 UN2282 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1-Hexene..................................................... 3 UN2370 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... E......
....... Hexogen and cyclotetramethylenetetranitramine mixtures, ........... .............. ...................... ................ ........... ........... .......
wetted or desensitized see RDX and HMX mixtures, wetted or
desensitized etc..
....... Hexogen and HMX mixtures, wetted or desensitized see RDX and ........... .............. ...................... ................ ........... ........... .......
HMX mixtures, wetted or desensitized etc..
....... Hexogen and octogen mixtures, wetted or desensitized see RDX ........... .............. ...................... ................ ........... ........... .......
and HMX mixtures, wetted or desensitized etc..
....... Hexogen, see Cyclotrimethylenetrinitramine, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Hexolite, or Hexotol dry or wetted with less than 15 percent 1.1D UN0118 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Hexotonal.................................................... 1.1D UN0393 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Hexyl, see Hexanitrodiphenylamine............................ ........... .............. ...................... ................ ........... ........... .......
....... Hexyltrichlorosilane......................................... 8 UN1784 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... High explosives, see individual explosives' entries.......... ........... .............. ...................... ................ ........... ........... .......
....... HMX, see Cyclotetramethylenetetranitramine, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Hydrazine, anhydrous or Hydrazine aqueous solutions with more 8 UN2029 I CORROSIVE, FLAMMABLE A3, A6, A7, A10, None 201 243 Forbidden.. 2.5 L...... D...... 21, 40, 42,
than 64 percent hydrazine, by mass. LIQUID, POISON. B16, B53, T25. 100
....... Hydrazine, aqueous solution with not more than 37 percent 6.1 UN3293 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
hydrazine, by mass.
....... Hydrazine azide.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine chlorate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine dicarbonic acid diazide............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine hydrate or Hydrazine aqueous solutions, with not 8 UN2030 II CORROSIVE, POISON..... B16, B53, B110, None 202 243 Forbidden.. 30 L....... D...... 40, 42, 82
less than 37 percent but not more than 64 percent hydrazine, T15.
by mass.
....... Hydrazine perchlorate........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrazine selenate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hydriodic acid, anhydrous, see Hydrogen iodide, anhydrous.... ........... .............. ...................... ................ ........... ........... .......
....... Hydriodic acid, solution..................................... 8 UN1787 II CORROSIVE............. A3, A6, B2, N41, 154 202 242 1 L........ 30 L....... C......
T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 60 L....... C...... 8
....... Hydrobromic acid, anhydrous, see Hydrogen bromide, anhydrous. ........... .............. ...................... ................ ........... ........... .......
....... Hydrobromic acid solution, with more than 49 percent 8 UN1788 II CORROSIVE............. B2, B15, N41, 154 202 242 Forbidden.. Forbidden.. C......
hydrobromic acid. T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 Forbidden.. Forbidden.. C...... 8
....... Hydrobromic acid solution, with not more than 49 percent 8 UN1788 II CORROSIVE............. A3, A6, B2, B15, 154 202 242 1 L........ 30 L....... C......
hydrobromic acid. N41, T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 30 L....... C...... 8
....... Hydrocarbon gases, compressed, n.o.s. or Hydrocarbon gases 2.1 UN1964 FLAMMABLE GAS......... ................ 306 302 314, 315 Forbidden.. 150 kg..... E...... 40
mixtures, compressed, n.o.s..
....... Hydrocarbon gases, liquefied, n.o.s. or Hydrocarbon gases 2.1 UN1965 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
mixtures, liquefied, n.o.s..
....... Hydrocarbons, liquid, n.o.s.................................. 3 UN3295 I FLAMMABLE LIQUID...... T8, T31......... 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Hydrochloric acid, anhydrous, see Hydrogen chloride, ........... .............. ...................... ................ ........... ........... .......
anhydrous.
....... Hydrochloric acid, solution.................................. 8 UN1789 II CORROSIVE............. A3, A6, B3, B15, 154 202 242 1 L........ 30 L....... C......
N41, T9, T27.
............................................................. ........... .............. III CORROSIVE............. T8, T26......... 154 203 241 5 L........ 60 L....... C...... 8
....... Hydrocyanic acid, anhydrous, see Hydrogen cyanide etc........ ........... .............. ...................... ................ ........... ........... .......
....... Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, 6.1 UN1613 I POISON................ 2, B12, B61, None 195 244 Forbidden.. Forbidden.. D...... 40
aqueous solutions with not more than 20 percent hydrogen B65, B77, B82.
cyanideic acid.
D...... Hydrocyanic acid, aqueous solutions with less than 5 percent 6.1 NA1613 II POISON................ B12, T18, T26... None 195 243 Forbidden.. 5 L........ D...... 40
hydrogen cyanideacid.
....... Hydrocyanic acid, liquefied, see Hydrogen cyanide, etc....... ........... .............. ...................... ................ ........... ........... .......
....... Hydrocyanic acid (prussic), unstabilized..................... Forbidden .............. ...................... ................ ........... ........... .......
....... Hydrofluoric acid and Sulfuric acid mixtures................. 8 UN1786 I CORROSIVE, POISON..... A6, A7, B15, None 201 243 Forbidden.. 2.5 L...... D...... 40, 95
B23, N5, N34,
T18, T27.
....... Hydrofluoric acid, anhydrous, see Hydrogen fluoride, ........... .............. ...................... ................ ........... ........... .......
anhydrous.
....... Hydrofluoric acid, solution, with more than 60 percent 8 UN1790 I CORROSIVE, POISON..... A6, A7, B4, B12, None 201 243 0.5 L...... 2.5 L...... D...... 12, 40
strength. B15, B23, N5,
N34, T18, T27.
....... Hydrofluoric acid, solution, with not more than 60 percent 8 UN1790 II CORROSIVE, POISON..... A6, A7, B12, None 202 243 1 L........ 30 L....... D...... 12, 40
strength. B15, B110, N5,
N34, T18, T27.
....... Hydrofluoroboric acid, see Fluoboric acid.................... ........... .............. ...................... ................ ........... ........... .......
....... Hydrofluorosilicic acid, see Fluorosilicic acid.............. ........... .............. ...................... ................ ........... ........... .......
....... Hydrogen and Methane mixtures, compressed.................... 2.1 UN2034 FLAMMABLE GAS......... ................ 306 302 302, 314, Forbidden.. 150 kg..... E...... 40
315
....... Hydrogen bromide, anhydrous.................................. 2.3 UN1048 POISON GAS, CORROSIVE. 3, B14.......... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Hydrogen chloride, anhydrous................................. 2.3 UN1050 POISON GAS, CORROSIVE. 3............... None 304 None Forbidden.. Forbidden.. D...... 40
....... Hydrogen chloride, refrigerated liquid....................... 2.3 UN2186 POISON GAS, CORROSIVE. 3, B6, B43...... None None 314, 315 Forbidden.. Forbidden.. B...... 40
....... Hydrogen, compressed......................................... 2.1 UN1049 FLAMMABLE GAS......... ................ 306 302 302, 314 Forbidden.. 150 kg..... E...... 40, 57
....... Hydrogen cyanide, solution in alcohol with not more than 45 6.1 UN3294 I POISON, FLAMMABLE T18, T26........ None 201 243 Forbidden.. Forbidden.. D...... 40
percent hydrogen cyanide. LIQUID.
....... Hydrogen cyanide, stabilized with less than 3 percent water.. 6.1 UN1051 I POISON, FLAMMABLE 1, B12, B35, None 195 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B61, B65, B77,
B82.
....... Hydrogen cyanide, stabilized, with less than 3 percent water 6.1 UN1614 I POISON................ 5............... None 195 None Forbidden.. Forbidden.. D...... 25, 40
and absorbed in a porous inert material.
....... Hydrogen fluoride, anhydrous................................. 8 UN1052 I CORROSIVE, POISON..... 3, B7, B12, B46, None 163 243 Forbidden.. Forbidden.. D...... 40
B71, B77, T24,
T27.
....... Hydrogen iodide, anhydrous................................... 2.3 UN2197 POISON GAS............ 3, 25, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Hydrogen iodide solution, see Hydriodic acid, solution....... ........... .............. ...................... ................ ........... ........... .......
....... Hydrogen peroxide and peroxyacetic acid mixtures, stabilized 5.1 UN3149 II OXIDIZER, CORROSIVE... A2, A3, A6, B12, None 202 243 1 L........ 5 L........ D...... 25, 66, 75,
with acids, water and not more than 5 percent peroxyacetic B53, B104, 106
acid. B110, T14.
....... Hydrogen peroxide, aqueous solutions with more than 40 5.1 UN2014 II OXIDIZER, CORROSIVE... 12, A3, A6, B12, None 202 243 Forbidden.. Forbidden.. D...... 25, 66, 75,
percent but not more than 60 percent hydrogen peroxide B53, B80, B81, 106
(stabilized as necessary). B85, B104,
B110, T14, T37.
....... Hydrogen peroxide, aqueous solutions with not less than 8 5.1 UN2984 III OXIDIZER.............. 17, A1, B104, 152 203 241 2.5 L...... 30 L....... B...... 25, 75, 106
percent but less than 20 percent hydrogen peroxide T8, T37.
(stabilized as necessary).
....... Hydrogen peroxide, aqueous solutions with not less than 20 5.1 UN2014 II OXIDIZER, CORROSIVE... A2, A3, A6, B12, None 202 243 1 L........ 5 L........ D...... 25, 66, 75,
percent but not more than 40 percent hydrogen peroxide B53, B104, 106
(stabilized as necessary). B110, T14, T37.
....... Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous 5.1 UN2015 I OXIDIZER, CORROSIVE... 12, A3, A6, B12, None 201 243 Forbidden.. Forbidden.. D...... 25, 66, 75,
solutions, stabilized with more than 60 percent hydrogen B53, B80, B81, 106
peroxide. B85, T15, T37.
....... Hydrogen, refrigerated liquid (cryogenic liquid)............. 2.1 UN1966 FLAMMABLE GAS......... ................ None 316 318, 319 Forbidden.. Forbidden.. D...... 40
....... Hydrogen selenide, anhydrous................................. 2.3 UN2202 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Hydrogen sulfate, see Sulfuric acid.......................... ........... .............. ...................... ................ ........... ........... .......
....... Hydrogen sulfide, liquefied.................................. 2.3 UN1053 POISON GAS, FLAMMABLE 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
GAS.
....... Hydrogendifluorides, n.o.s. solid............................ 8 UN1740 II CORROSIVE............. N3, N34......... None 212 240 15 kg...... 50 kg...... A...... 25, 26, 40
............................................................. ........... .............. III CORROSIVE............. N3, N34......... 154 213 240 25 kg...... 100 kg..... A...... 25, 26, 40
....... Hydrogendifluorides, n.o.s. solutions........................ 8 UN1740 II CORROSIVE............. N3, N34......... None 202 242 1 L........ 30 L....... A...... 25, 26, 40
............................................................. ........... .............. III CORROSIVE............. N3, N34......... 154 203 241 5 L........ 60 L....... A...... 25, 26, 40
....... Hydroquinone................................................. 6.1 UN2662 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Hydrosilicofluoric acid, see Fluorosilicic acid.............. ........... .............. ...................... ................ ........... ........... .......
....... Hydroxyl amine iodide........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Hydroxylamine sulfate........................................ 8 UN2865 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Hypochlorite solutions with more than 5 percent but less than 8 UN1791 III CORROSIVE............. B104, N34, T7... 154 203 241 5 L........ 60 L....... B...... 26
16 percent available chlorine.
....... Hypochlorite solutions with 16 percent or more available 8 UN1791 II CORROSIVE............. A7, B2, B15, 154 202 242 1 L........ 30 L....... B...... 26
chlorine. N34, T7.
....... Hypochlorites, inorganic, n.o.s.............................. 5.1 UN3212 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... D...... 48, 56, 58,
69, 106,
116, 118
....... Hyponitrous acid............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Igniter fuse, metal clad, see Fuse, igniter, tubular, metal ........... .............. ...................... ................ ........... ........... .......
clad.
....... Igniters..................................................... 1.1G UN0121 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Igniters..................................................... 1.2G UN0314 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Igniters..................................................... 1.3G UN0315 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. A......
....... Igniters..................................................... 1.4G UN0325 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Igniters..................................................... 1.4S UN0454 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... 3,3'-Iminodipropylamine...................................... 8 UN2269 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Infectious substances, affecting animals only................ 6.2 UN2900 INFECTIOUS SUBSTANCE.. ................ 196 196 None 50 mL or 50 4 L or 4 kg B......
g.
....... Infectious substances, affecting humans...................... 6.2 UN2814 INFECTIOUS SUBSTANCE.. ................ 196 196 None 50 mL or 50 4 L or 4 kg B......
g.
....... Inflammable, see Flammable................................... ........... .............. ...................... ................ ........... ........... .......
....... Initiating explosives (dry).................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Inositol hexanitrate (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Insecticide gases flammable n.o.s............................ 2.1 NA1954 FLAMMABLE GAS......... ................ 306 304 314, 315 75 kg...... 150 kg..... D......
....... Insecticide gases, n.o.s..................................... 2.2 UN1968 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Insecticide gases, toxic, n.o.s.............................. 2.3 UN1967 POISON GAS............ 3............... None 193, 334 245 Forbidden.. Forbidden.. D...... 40
....... Inulin trinitrate (dry)...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iodine azide (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iodine monochloride.......................................... 8 UN1792 II CORROSIVE............. B6, N41, T8, T26 None 212 240 Forbidden.. 50 kg...... D...... 40, 66, 74,
89, 90
....... Iodine pentafluoride......................................... 5.1 UN2495 I OXIDIZER, POISON, ................ None 205 243 Forbidden.. 2.5 L...... D...... 25, 40, 66,
CORROSIVE. 90
....... 2-Iodobutane................................................. 3 UN2390 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Iodomethylpropanes........................................... 3 UN2391 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Iodopropanes................................................. 3 UN2392 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Iodoxy compounds (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iridium nitratopentamine iridium nitrate..................... Forbidden .............. ...................... ................ ........... ........... .......
....... Iron chloride, see Ferric chloride........................... ........... .............. ...................... ................ ........... ........... .......
....... Iron oxide, spent, or Iron sponge, spent obtained from coal 4.2 UN1376 III SPONTANEOUSLY B18............. None 213 240 Forbidden.. Forbidden.. E......
gas purification. COMBUSTIBLE.
....... Iron pentacarbonyl........................................... 6.1 UN1994 I POISON, FLAMMABLE 1, B9, B14, B30, None 192 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B72, B77, T38,
T43, T44.
....... Iron sesquichloride, see Ferric chloride..................... ........... .............. ...................... ................ ........... ........... .......
....... Irritating material, see Tear gas substances, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Isobutane or Isobutane mixtures see also Petroleum gases, 2.1 UN1969 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
liquefied.
....... Isobutanol or Isobutyl alcohol............................... 3 UN1212 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isobutyl acetate............................................. 3 UN1213 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isobutyl acrylate............................................ 3 UN2527 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isobutyl alcohol, see Isobutanol............................. ........... .............. ...................... ................ ........... ........... .......
....... Isobutyl aldehyde, see Isobutyraldehyde...................... ........... .............. ...................... ................ ........... ........... .......
D...... Isobutyl chloroformate....................................... 6.1 NA2742 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 1 L........ 30 L....... A...... 12, 13, 22,
LIQUID, CORROSIVE. B74, T38, T43, 25, 40,
T45. 48, 100
....... Isobutyl formate............................................. 3 UN2393 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isobutyl isobutyrate......................................... 3 UN2528 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Isobutyl isocyanate.......................................... 3 UN2486 II FLAMMABLE LIQUID, 1, B9, B14, B30, None 226 244 1 L........ 60 L....... D...... 40
POISON. B72, T38, T43,
T44.
....... Isobutyl methacrylate........................................ 3 UN2283 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isobutyl propionate.......................................... 3 UN2394 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... B......
....... Isobutylamine................................................ 3 UN1214 II FLAMMABLE LIQUID, B101, T8........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Isobutylene see also Petroleum gases, liquefied.............. 2.1 UN1055 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Isobutyraldehyde or Isobutyl aldehyde........................ 3 UN2045 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 40
....... Isobutyric acid.............................................. 3 UN2529 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Isobutyric anhydride......................................... 3 UN2530 III FLAMMABLE LIQUID, B1, T1.......... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Isobutyronitrile............................................. 3 UN2284 II FLAMMABLE LIQUID, T17............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Isobutyryl chloride.......................................... 3 UN2395 II FLAMMABLE LIQUID, B100, T9, T26... None 202 243 1 L........ 5 L........ C...... 40
CORROSIVE.
....... Isocyanates, flammable, toxic, n.o.s. or Isocyanate 3 UN2478 II FLAMMABLE LIQUID, 5, A3, A7, T15.. None 202 243 1 L........ 60 L....... D...... 40
solutions, flammable, toxic, n.o.s. flashpoint less than 23 POISON.
degrees C.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8.......... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Isocyanates, toxic, flammable, n.o.s. or Isocyanate 6.1 UN3080 II POISON, FLAMMABLE T15............. None 202 243 5 L........ 60 L....... D...... 25, 40, 48
solutions, toxic, flammable, n.o.s., flash point not less LIQUID.
than 23 degrees C but not more than 61 degrees C and boiling
point less than 300 degrees C.
....... Isocyanates, toxic, n.o.s. or Isocyanate, solutions, toxic, 6.1 UN2206 II POISON................ T15............. None 202 243 5 L........ 60 L....... D...... 25, 40, 48
n.o.s., flash point more than 61 degrees C and boiling point
less than 300 degrees C.
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... D...... 25, 40, 48
....... Isocyanatobenzotrifluorides.................................. 6.1 UN2285 II POISON................ 5, B101, T14.... None 202 243 5 L........ 60 L....... B...... 25, 40, 48
....... Isoheptenes.................................................. 3 UN2287 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Isohexenes................................................... 3 UN2288 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... Isooctane, see Octanes....................................... ........... .............. ...................... ................ ........... ........... .......
....... Isooctenes................................................... 3 UN1216 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Isopentane, see n-Pentane.................................... ........... .............. ...................... ................ ........... ........... .......
....... Isopentanoic acid, see Corrosive liquids, n.o.s.............. ........... .............. ...................... ................ ........... ........... .......
....... Isopentenes.................................................. 3 UN2371 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Isophorone diisocyanate...................................... 6.1 UN2290 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... B...... 40
....... Isophoronediamine............................................ 8 UN2289 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
....... Isoprene, inhibited.......................................... 3 UN1218 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Isopropanol or Isopropyl alcohol............................. 3 UN1219 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropenyl acetate.......................................... 3 UN2403 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropenylbenzene........................................... 3 UN2303 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl acetate............................................ 3 UN1220 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropyl acid phosphate..................................... 8 UN1793 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A......
....... Isopropyl alcohol, see Isopropanol........................... ........... .............. ...................... ................ ........... ........... .......
....... Isopropyl butyrate........................................... 3 UN2405 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl chloroacetate...................................... 3 UN2947 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl chloroformate...................................... 6.1 UN2407 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
LIQUID, CORROSIVE. B74, B77, T38,
T43, T45.
....... Isopropyl 2-chloropropionate................................. 3 UN2934 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropyl isobutyrate........................................ 3 UN2406 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
+...... Isopropyl isocyanate......................................... 3 UN2483 I FLAMMABLE LIQUID, 1, B9, B14, B30, None 226 244 Forbidden.. 30 L....... D...... 40
POISON. B72, T38, T43,
T44.
....... Isopropyl mercaptan, see Propanethiols....................... ........... .............. ...................... ................ ........... ........... .......
....... Isopropyl nitrate............................................ 3 UN1222 II FLAMMABLE LIQUID...... T25............. 150 202 None 5 L........ 60 L....... D......
....... Isopropyl phosphoric acid, see Isopropyl acid phosphate...... ........... .............. ...................... ................ ........... ........... .......
....... Isopropyl propionate......................................... 3 UN2409 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Isopropylamine............................................... 3 UN1221 I FLAMMABLE LIQUID, T20............. None 201 243 0.5 L...... 2.5 L...... E......
CORROSIVE.
....... Isopropylbenzene............................................. 3 UN1918 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Isopropylcumyl hydroperoxide, with more than 72 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Isosorbide dinitrate mixture with not less than 60 percent 4.1 UN2907 II FLAMMABLE SOLID....... ................ None 212 None 15 kg...... 50 kg...... E......
lactose, mannose, starch or calcium hydrogen phosphate.
....... Isosorbide-5-mononitrate..................................... 4.1 UN3251 III FLAMMABLE SOLID....... ................ 151 213 240 Forbidden.. Forbidden.. D...... 12
....... Isothiocyanic acid........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Jet fuel, see Fuel aviation, turbine engine.................. ........... .............. ...................... ................ ........... ........... .......
....... Jet perforating guns, charged oil well, without detonator.... 1.1D UN0124 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Jet perforating guns, charged, oil well, without detonator... 1.4D UN0494 II EXPLOSIVE 1.4D........ 114............. None 62 None Forbidden.. 300 kg..... A...... 24E
....... Jet perforators, see Charges, shaped, commercial etc......... ........... .............. ...................... ................ ........... ........... .......
....... Jet tappers, without detonator, see Charges, shaped ........... .............. ...................... ................ ........... ........... .......
commercial, etc..
....... Jet thrust igniters, for rocket motors or Jato, see Igniters. ........... .............. ...................... ................ ........... ........... .......
....... Jet thrust unit (Jato), see Rocket motors.................... ........... .............. ...................... ................ ........... ........... .......
....... Kerosene..................................................... 3 UN1223 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Ketones, liquid, n.o.s....................................... 3 UN1224 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Krypton, compressed.......................................... 2.2 UN1056 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Krypton, refrigerated liquid (cryogenic liquid).............. 2.2 UN1970 NONFLAMMABLE GAS...... ................ 320 None None 50 kg...... 500 kg..... B......
....... Lacquer base or lacquer chips, nitrocellulose, dry, see ........... .............. ...................... ................ ........... ........... .......
Nitrocellulose, etc. (UN 2557).
....... Lacquer base or lacquer chips, plastic, wet with alcohol or ........... .............. ...................... ................ ........... ........... .......
solvent, see Nitrocellulose (UN 2059, UN 2060, UN 2555,
UN2556) or Paint etc. (UN1263).
....... Lead acetate................................................. 6.1 UN1616 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Lead arsenates............................................... 6.1 UN1617 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Lead arsenites............................................... 6.1 UN1618 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Lead azide (dry)............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Lead azide, wetted with not less than 20 percent water or 1.1A UN0129 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
mixture of alcohol and water, by mass.
....... Lead compounds, soluble, n.o.s............................... 6.1 UN2291 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Lead cyanide................................................. 6.1 UN1620 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26
....... Lead dioxide................................................. 5.1 UN1872 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A...... 34
....... Lead dross, see Lead sulfate, with more than 3 percent free ........... .............. ...................... ................ ........... ........... .......
acid.
D...... Lead mononitroresorcinate.................................... 1.1A NA0473 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Lead nitrate................................................. 5.1 UN1469 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A......
....... Lead nitroresorcinate (dry).................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Lead perchlorate, solid...................................... 5.1 UN1470 II OXIDIZER, POISON...... T8.............. None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Lead perchlorate, solution................................... 5.1 UN1470 II OXIDIZER, POISON...... T8.............. None 202 243 1 L........ 5 L........ A...... 56, 58, 106
....... Lead peroxide, see Lead dioxide.............................. ........... .............. ...................... ................ ........... ........... .......
....... Lead phosphite, dibasic...................................... 4.1 UN2989 II FLAMMABLE SOLID....... ................ None 212 240 5 kg....... 25 kg...... B...... 34
............................................................. ........... .............. III FLAMMABLE SOLID....... ................ 151 213 240 15 kg...... 50 kg...... B...... 34
....... Lead picrate (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Lead styphnate (dry)......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Lead styphnate, wetted or Lead trinitroresorcinate, wetted 1.1A UN0130 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
with not less than 20 percent water or mixture of alcohol
and water, by mass.
....... Lead sulfate with more than 3 percent free acid.............. 8 UN1794 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Lead trinitroresorcinate, see Lead styphnate, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Life-saving appliances, not self inflating containing 9 UN3072 None.................. ................ None 219 None No limit... No limit... A......
dangerous goods as equipment.
....... Life-saving appliances, self inflating....................... 9 UN2990 None.................. ................ None 219 None No limit... No limit... A......
....... Lighter replacement cartridges containing liquefied petroleum ........... .............. ...................... ................ ........... ........... .......
gases (and similar devices, each not exceeding 65 grams),
see Lighters or lighter refillsetc. containing flammable gas.
D...... Lighters for cigars, cigarettes, etc., with lighter fluids... 3 NA1226 II FLAMMABLE LIQUID...... N10............. None 21 None Forbidden.. Forbidden.. B......
....... Lighters, fuse............................................... 1.4S UN0131 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Lighters or Lighter refills cigarettes, containing flammable 2.1 UN1057 FLAMMABLE GAS......... N10............. None 21, 308 None 1 kg....... 15 kg...... B...... 40
gas.
....... Lime, unslaked, see Calcium oxide............................ ........... .............. ...................... ................ ........... ........... .......
....... Liquefied gas, flammable, n.o.s.............................. 2.1 UN3161 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... D...... 40
....... Liquefied gas, n.o.s......................................... 2.2 UN3163 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Liquefied gas, oxidizing, n.o.s.............................. 2.2 UN3157 NONFLAMMABLE GAS, ................ 306 304 314, 315 75 kg...... 150 kg..... D......
OXIDIZER.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
Zone A. GAS.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
Zone B. GAS.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 3, B14.......... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
Zone C. GAS.
....... Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard 2.3 UN3160 POISON GAS, FLAMMABLE 4............... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
Zone D. GAS.
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A........ 2.3 UN3162 POISON GAS............ 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone B........ 2.3 UN3162 POISON GAS............ 2, B9, B14...... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone C........ 2.3 UN3162 POISON GAS............ 3, B14.......... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone D........ 2.3 UN3162 POISON GAS............ 4............... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Liquefied gases, non-flammable charged with nitrogen, carbon 2.2 UN1058 NONFLAMMABLE GAS...... ................ 306 304 None 75 kg...... 150 kg..... A......
dioxide or air.
....... Liquefied hydrocarbon gas, see Hydrocarbon gases, liquefied, ........... .............. ...................... ................ ........... ........... .......
n.o.s., etc..
....... Liquefied natural gas, see Methane, etc. (UN 1972)........... ........... .............. ...................... ................ ........... ........... .......
....... Liquefied petroleum gas see Petroleum gases, liquefied....... ........... .............. ...................... ................ ........... ........... .......
....... Lithium...................................................... 4.3 UN1415 I DANGEROUS WHEN WET.... A7, A19, B100, None 211 244 Forbidden.. 15 kg...... E......
N45.
....... Lithium acetylide ethylenediamine complex, see Water reactive ........... .............. ...................... ................ ........... ........... .......
solid etc..
....... Lithium alkyls............................................... 4.2 UN2445 I SPONTANEOUSLY B11, T28, T40... None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE,
DANGEROUS WHEN WET.
....... Lithium aluminum hydride..................................... 4.3 UN1410 I DANGEROUS WHEN WET.... A19, B100,...... None 211 242 Forbidden.. 15 kg...... E......
....... Lithium aluminum hydride, ethereal........................... 4.3 UN1411 I DANGEROUS WHEN WET, A2, A3, A11, N34 None 201 244 Forbidden.. 1 L........ D...... 40
FLAMMABLE LIQUID.
....... Lithium batteries, contained in equipment.................... 9 UN3091 II CLASS 9............... 18, 29, A12..... 185(i) 185 None Forbidden.. See A12.... A......
....... Lithium battery.............................................. 9 UN3090 II CLASS 9............... 29.............. 185 185 None Forbidden.. 35 kg gross A......
....... Lithium borohydride.......................................... 4.3 UN1413 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Lithium ferrosilicon......................................... 4.3 UN2830 II DANGEROUS WHEN WET.... A19, B105, B106. None 212 241 15 kg...... 50 kg...... E...... 40, 85, 103
....... Lithium hydride.............................................. 4.3 UN1414 I DANGEROUS WHEN WET.... A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... E......
....... Lithium hydride, fused solid................................. 4.3 UN2805 II DANGEROUS WHEN WET.... A8, A19, A20, None 212 241 15 kg...... 50 kg...... E......
B101, B106.
....... Lithium hydroxide, monohydrate or Lithium hydroxide, solid... 8 UN2680 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Lithium hydroxide, solution.................................. 8 UN2679 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A...... 96
....... Lithium hypochlorite, dry or Lithium hypochlorite mixtures, 5.1 UN1471 II OXIDIZER.............. A9, N34......... 152 212 240 5 kg....... 25 kg...... A...... 48, 56, 58,
dry. 69, 106,
116
....... Lithium in cartridges, see Lithium........................... ........... .............. ...................... ................ ........... ........... .......
....... Lithium nitrate.............................................. 5.1 UN2722 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Lithium nitride.............................................. 4.3 UN2806 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Lithium peroxide............................................. 5.1 UN1472 II OXIDIZER.............. A9, N34......... 152 212 None 5 kg....... 25 kg...... A...... 13, 75, 106
....... Lithium silicon.............................................. 4.3 UN1417 II DANGEROUS WHEN WET.... A19, A20, B100.. None 212 241 15 kg...... 50 kg...... A...... 85, 103
....... LNG, see Methane etc. (UN 1972).............................. ........... .............. ...................... ................ ........... ........... .......
....... London purple................................................ 6.1 UN1621 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... LPG, see Petroleum gases, liquefied.......................... ........... .............. ...................... ................ ........... ........... .......
....... Lye, see Sodium hydroxide, solutions......................... ........... .............. ...................... ................ ........... ........... .......
....... Magnesium alkyls............................................. 4.2 UN3053 I SPONTANEOUSLY B11, T28, T29, None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. T40.
....... Magnesium aluminum phosphide................................. 4.3 UN1419 I DANGEROUS WHEN WET, A19, B100, N34, None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON. N40.
+...... Magnesium arsenate........................................... 6.1 UN1622 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Magnesium bisulfite solution, see Bisulfites, aqueous ........... .............. ...................... ................ ........... ........... .......
solutions, n.o.s..
....... Magnesium bromate............................................ 5.1 UN1473 II OXIDIZER.............. A1.............. 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Magnesium chlorate........................................... 5.1 UN2723 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Magnesium diamide............................................ 4.2 UN2004 II SPONTANEOUSLY A8, A19, A20.... None 212 241 15 kg...... 50 kg...... C......
COMBUSTIBLE.
....... Magnesium diphenyl........................................... 4.2 UN2005 I SPONTANEOUSLY ................ None 187 244 Forbidden.. Forbidden.. C......
COMBUSTIBLE.
....... Magnesium dross, wet or hot.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Magnesium fluorosilicate..................................... 6.1 UN2853 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Magnesium granules, coated particle size not less than 149 4.3 UN2950 III DANGEROUS WHEN WET.... A1, A19, B108... None 213 240 25 kg...... 100 kg..... A......
microns.
....... Magnesium hydride............................................ 4.3 UN2010 I DANGEROUS WHEN WET.... A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... E......
....... Magnesium or Magnesium alloys with more than 50 percent 4.1 UN1869 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A...... 39
magnesium in pellets, turnings or ribbons.
....... Magnesium nitrate............................................ 5.1 UN1474 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Magnesium perchlorate........................................ 5.1 UN1475 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Magnesium peroxide........................................... 5.1 UN1476 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Magnesium phosphide.......................................... 4.3 UN2011 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Magnesium, powder or Magnesium alloys, powder................ 4.3 UN1418 I DANGEROUS WHEN WET, A19, B56........ None 211 244 Forbidden.. 15 kg...... A...... 39
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, A19, B56, B100.. None 212 241 15 kg...... 50 kg...... A...... 39
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, A19, B56........ None 213 241 25 kg...... 100 kg..... A...... 39
SPONTANEOUSLY
COMBUSTIBLE.
....... Magnesium scrap, see Magnesium, etc. (UN 1869)............... ........... .............. ...................... ................ ........... ........... .......
....... Magnesium silicide........................................... 4.3 UN2624 II DANGEROUS WHEN WET.... A19, A20, B105, None 212 241 15 kg...... 50 kg...... B...... 85, 103
B106.
....... Magnetized material, see section 173.21...................... ........... .............. ...................... ................ ........... ........... .......
D...... Maleic acid.................................................. 8 NA2215 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Maleic anhydride............................................. 8 UN2215 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A......
....... Malononitrile................................................ 6.1 UN2647 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 12
....... Mancozeb (manganese ethylenebisdithiocarbamate complex with ........... .............. ...................... ................ ........... ........... .......
zinc) see Maneb.
....... Maneb or Maneb preparations with not less than 60 percent 4.2 UN2210 III SPONTANEOUSLY A1, A19, B105... None 213 242 25 kg...... 100 kg..... A...... 34
maneb. COMBUSTIBLE,
DANGEROUS WHEN WET.
....... Maneb stabilized or Maneb preparations, stabilized against 4.3 UN2968 III DANGEROUS WHEN WET.... 53, A1, A19, None 213 242 25 kg...... 100 kg..... B...... 34
self-heating. B108.
....... Manganese nitrate............................................ 5.1 UN2724 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Manganese resinate........................................... 4.1 UN1330 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Mannitan tetranitrate........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Mannitol hexanitrate (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
D...... Mannitol hexanitrate, wetted or Nitromannite, wetted with not 1.1A NA0133 II EXPLOSIVE 1.1A........ 111............. None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
less than 40 percent water, by mass or mixture of alcohol
and water.
....... Marine pollutants, liquid or solid, n.o.s., see ........... .............. ...................... ................ ........... ........... .......
Environmentally hazardous substances, liquid or solid,
n.o.s..
....... Matches, block, see Matches, 'strike anywhere'............... ........... .............. ...................... ................ ........... ........... .......
....... Matches, fusee............................................... 4.1 UN2254 III FLAMMABLE SOLID....... ................ 186 186 None Forbidden.. Forbidden.. A......
....... Matches, safety (book, card or strike on box)................ 4.1 UN1944 III FLAMMABLE SOLID....... ................ 186 186 None 25 kg...... 100 kg..... A......
....... Matches, strike anywhere..................................... 4.1 UN1331 III FLAMMABLE SOLID....... ................ 186 186 None Forbidden.. Forbidden.. B......
....... Matches, wax, Vesta.......................................... 4.1 UN1945 III FLAMMABLE SOLID....... ................ 186 186 None 25 kg...... 100 kg..... B......
....... Matting acid, see Sulfuric acid.............................. ........... .............. ...................... ................ ........... ........... .......
....... Medicine, liquid, flammable, toxic, n.o.s.................... 3 UN3248 II FLAMMABLE LIQUID, 36.............. None 202 None 1 L........ 5 L........ B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP 36.............. 150 203 None 5 L........ 5 L........ A......
AWAY FROM FOOD.
....... Medicine, liquid, toxic, n.o.s............................... 6.1 UN1851 II POISON................ ................ 153 202 243 5 L........ 5 L........ C...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 5 L........ 5 L........ C...... 40
....... Medicine, solid, toxic, n.o.s................................ 6.1 UN3249 II POISON................ 36.............. 153 212 None 5 kg....... 5 kg...... C...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... 36.............. 153 213 None 5 kg....... 5 kg....... C...... 40
D...... Medicines, corrosive, liquid, n.o.s.......................... 8 NA1760 II CORROSIVE............. B3.............. 154 202 242 1 L........ 30 L....... B...... 40
............................................................. ........... .............. III CORROSIVE............. ................ 154 203 241 5 L........ 60 L....... A...... 40
D...... Medicines, corrosive, solid, n.o.s........................... 8 NA1759 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
............................................................. ........... .............. III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
D...... Medicines, flammable, liquid, n.o.s.......................... 3 NA1993 I FLAMMABLE LIQUID...... ................ 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... ................ 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1.............. 150 203 242 60 L....... 220 L...... A......
D...... Medicines, flammable, solid, n.o.s........................... 4.1 NA1325 II FLAMMABLE SOLID....... ................ 151 212 240 15 kg...... 50 kg...... B......
D...... Medicines, oxidizing substance, solid, n.o.s................. 5.1 NA1479 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... B...... 56, 58, 69,
106
....... Memtetrahydrophthalic anhydride, see Corrosive liquids, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan 3 UN1228 II FLAMMABLE LIQUID, T13............. None 202 243 Forbidden.. 60 L....... B...... 40, 95
mixtures, liquid, flammable, toxic, n.o.s.. POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8.......... 150 203 242 5 L........ 220 L...... A...... 40, 95
AWAY FROM FOOD.
....... Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan 6.1 UN3071 II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... C...... 40, 121
mixtures, liquid, toxic, flammable, n.o.s., flash point not LIQUID.
less than 23 degrees C.
....... 5-Mercaptotetrazol-1-acetic acid............................. 1.4C UN0448 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 1E, 5E, 24E
....... Mercuric arsenate............................................ 6.1 UN1623 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercuric chloride............................................ 6.1 UN1624 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercuric compounds, see Mercury compounds, etc............... ........... .............. ...................... ................ ........... ........... .......
....... Mercuric nitrate............................................. 6.1 UN1625 II POISON................ N73............. None 212 242 25 kg...... 100 kg..... A......
+...... Mercuric potassium cyanide................................... 6.1 UN1626 I POISON................ N74, N75........ None 211 242 5 kg....... 50 kg...... A...... 26
....... Mercuric sulfocyanate, see Mercury thiocyanate............... ........... .............. ...................... ................ ........... ........... .......
....... Mercurol, see Mercury nucleate............................... ........... .............. ...................... ................ ........... ........... .......
....... Mercurous azide.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Mercurous compounds, see Mercury compounds, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Mercurous nitrate............................................ 6.1 UN1627 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
A, W... Mercury...................................................... 8 UN2809 III CORROSIVE............. ................ 164 164 240 35 kg...... 35 kg...... B...... 40, 97
....... Mercury acetate.............................................. 6.1 UN1629 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury acetylide............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Mercury ammonium chloride.................................... 6.1 UN1630 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury based pesticides, liquid, flammable, toxic, flash 3 UN2778 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B...... 40
AWAY FROM FOOD.
....... Mercury based pesticides, liquid, toxic...................... 6.1 UN3012 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Mercury based pesticides, liquid, toxic, flammable, 6.1 UN3011 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Mercury based pesticides, solid, toxic....................... 6.1 UN2777 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Mercury benzoate............................................. 6.1 UN1631 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury bromides............................................. 6.1 UN1634 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury compounds, liquid, n.o.s............................. 6.1 UN2024 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ ................ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... B...... 40
....... Mercury compounds, solid, n.o.s.............................. 6.1 UN2025 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
A...... Mercury contained in manufactured articles................... 8 UN2809 I CORROSIVE............. ................ None 164 None No limit... No limit... B...... 40, 97
....... Mercury cyanide.............................................. 6.1 UN1636 II POISON................ N74, N75........ None 212 242 25 kg...... 100 kg..... A...... 26
....... Mercury fulminate, wetted with not less than 20 percent 1.1A UN0135 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
water, or mixture of alcohol and water, by mass.
....... Mercury gluconate............................................ 6.1 UN1637 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury iodide............................................... 6.1 UN1638 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury iodide aquabasic ammonobasic (Iodide of Millon's Forbidden .............. ...................... ................ ........... ........... .......
base).
....... Mercury iodide, solution..................................... 6.1 UN1638 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
....... Mercury nitride.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Mercury nucleate............................................. 6.1 UN1639 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury oleate............................................... 6.1 UN1640 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury oxide................................................ 6.1 UN1641 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury oxycyanide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Mercury oxycyanide, desensitized............................. 6.1 UN1642 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26, 91
....... Mercury potassium iodide..................................... 6.1 UN1643 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury salicylate........................................... 6.1 UN1644 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
+...... Mercury sulfates............................................. 6.1 UN1645 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mercury thiocyanate.......................................... 6.1 UN1646 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Mesityl oxide................................................ 3 UN1229 III FLAMMABLE LIQUID...... B1, T1.......... None 203 242 60 L....... 220 L...... A......
....... Metal alkyl halides, n.o.s. or Metal aryl halides, n.o.s..... 4.2 UN3049 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
....... Metal alkyl hydrides, n.o.s. or Metal aryl hydrides, n.o.s... 4.2 UN3050 I SPONTANEOUSLY B9, B11, T28, None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE. T29, T40.
D...... Metal alkyl, solution, n.o.s................................. 3 NA9195 II FLAMMABLE LIQUID...... ................ 150 202 242 1 L........ 4 L........ B......
....... Metal alkyls, n.o.s. or Metal aryls, n.o.s................... 4.2 UN2003 I SPONTANEOUSLY B11, T42........ None 181 244 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Metal carbonyls, n.o.s....................................... 6.1 UN3281 I POISON................ ................ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Metal catalyst, dry.......................................... 4.2 UN2881 I SPONTANEOUSLY N34............. None 187 None Forbidden.. Forbidden.. C......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY N34............. None 187 None Forbidden.. 50 kg...... C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY N34............. None 187 None 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Metal catalyst, wetted with a visible excess of liquid....... 4.2 UN1378 II SPONTANEOUSLY A2, A8, N34..... None 212 None Forbidden.. 50 kg...... C......
COMBUSTIBLE.
....... Metal hydrides, flammable, n.o.s............................. 4.1 UN3182 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... E......
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... E......
....... Metal hydrides, water reactive, n.o.s........................ 4.3 UN1409 I DANGEROUS WHEN WET.... A19, N34, N40... None 211 242 Forbidden.. 15 kg...... D......
............................................................. ........... .............. II DANGEROUS WHEN WET.... A19, N34, N40... None 212 242 15 kg...... 50 kg...... D......
....... Metal powder, self-heating, n.o.s............................ 4.2 UN3189 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... C.....
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Metal powders, flammable, n.o.s.............................. 4.1 UN3089 II FLAMMABLE SOLID....... ................ 151 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III FLAMMABLE SOLID....... ................ 151 213 240 25 kg...... 100 kg..... B......
....... Metal salts of methyl nitramine (dry)........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Metal salts of organic compounds, flammable, n.o.s........... 4.1 UN3181 II FLAMMABLE SOLID....... A1.............. 151 212 240 15 kg...... 50 kg...... B...... 40
............................................................. ........... .............. III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... B...... 40
....... Metaldehyde.................................................. 4.1 UN1332 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Metallic substance, water-reactive, n.o.s.................... 4.3 UN3208 I DANGEROUS WHEN WET.... ................ None 211 242 Forbidden.. 15 kg...... E...... 40
............................................................. ........... .............. II DANGEROUS WHEN WET.... ................ None 212 242 15 kg...... 50 kg...... E...... 40
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 213 241 25 kg...... 100 kg..... E...... 40
....... Metallic substance, water-reactive, self-heating, n.o.s...... 4.3 UN3209 I DANGEROUS WHEN WET, ................ None 211 242 Forbidden.. 15 kg...... E...... 40
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 212 242 15 kg...... 50 kg...... E...... 40
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 213 242 25 kg...... 100 kg..... E...... 40
SPONTANEOUSLY
COMBUSTIBLE.
....... Methacrylaldehyde............................................ 3 UN2396 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Methacrylic acid, inhibited.................................. 8 UN2531 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... A......
+..... Methacrylonitrile, inhibited................................. 3 UN3079 I FLAMMABLE LIQUID, 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... D...... 12, 40, 48
POISON. B74, T38, T43,
T45.
....... Methallyl alcohol............................................ 3 UN2614 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methane and hydrogen, mixtures, see Hydrogen and methane, ........... .............. ...................... ................ ........... ........... .......
mixtures, etc..
....... Methane, compressed or Natural gas, compressed (with high 2.1 UN1971 FLAMMABLE GAS......... ................ 306 302 302 Forbidden.. 150 kg..... E...... 40
methane content).
....... Methane, refrigerated liquid (cryogenic liquid) or Natural 2.1 UN1972 FLAMMABLE GAS......... ................ None None 318 Forbidden.. Forbidden.. D...... 40
gas, refrigerated liquid (cryogenic liquid), with high
methane content).
....... Methanesulfonyl chloride..................................... 6.1 UN3246 I POISON, CORROSIVE..... T24, T26........ None 201 243 0.5 L...... 2.5 L...... D...... 40
I...... Methanol, or Methyl alcohol.................................. 3 UN1230 II FLAMMABLE LIQUID, T8.............. 150 202 242 1 L........ 60 L....... B...... 40
POISON.
D...... Methanol, or Methyl alcohol.................................. 3 UN1230 II FLAMMABLE LIQUID...... T8.............. 150 202 242 1 L........ 60 L....... B...... 40
....... Methazoic acid............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 4-Methoxy-4-methylpentan-2-one............................... 3 UN2293 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1-Methoxy-2-propanol......................................... 3 UN3092 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... Methoxymethyl isocyanate..................................... 3 UN2605 I FLAMMABLE LIQUID, 1, B9, B14, B30, None 226 244 Forbidden.. 30 L....... D...... 40
POISON. B72, T38, T43,
T44.
....... Methyl acetate............................................... 3 UN1231 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... B......
....... Methyl acetylene and propadiene mixtures, stabilized......... 2.1 UN1060 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Methyl acrylate, inhibited................................... 3 UN1919 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl alcohol, see Methanol................................. ........... .............. ...................... ................ ........... ........... .......
....... Methyl allyl chloride........................................ 3 UN2554 II FLAMMABLE LIQUID...... B101, T8........ 150 202 242 5 L........ 60 L....... E......
....... Methyl amyl ketone, see Amyl methyl ketone................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl benzoate.............................................. 6.1 UN2938 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Methyl bromide............................................... 2.3 UN1062 POISON GAS............ 3, B14.......... None 193 314, 315 Forbidden.. 25 kg...... D...... 40
....... Methyl bromide and chloropicrin mixtures with more than 2 ........... .............. ...................... ................ ........... ........... .......
percent chloropicrin, see Chloropicrin and methyl bromide
mixtures.
....... Methyl bromide and chloropicrin mixtures with not more than 2 ........... .............. ...................... ................ ........... ........... .......
percent chloropicrin, see Methyl bromide.
....... Methyl bromide and ethylene dibromide mixtures, liquid....... 6.1 UN1647 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... C...... 40
B74, N65, T38,
T43, T45.
....... Methyl bromoacetate.......................................... 6.1 UN2643 II POISON................ B100, T8........ None 202 243 5 L........ 60 L....... D...... 40
....... 2-Methyl-1-butene............................................ 3 UN2459 I FLAMMABLE LIQUID...... T14............. None 201 243 1 L........ 30 L....... E......
....... 2-Methyl-2-butene............................................ 3 UN2460 II FLAMMABLE LIQUID...... T14............. None 202 242 5 L........ 60 L....... E......
....... 3-Methyl-1-butene............................................ 3 UN2561 I FLAMMABLE LIQUID...... T20............. None 201 243 1 L........ 30 L....... E......
....... Methyl tert-butyl ether...................................... 3 UN2398 II FLAMMABLE LIQUID...... B101, T14....... 150 202 242 5 L........ 60 L....... E......
....... Methyl butyrate.............................................. 3 UN1237 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl chloride.............................................. 2.1 UN1063 FLAMMABLE GAS......... ................ 306 304 314, 315 5 kg....... 100 kg..... D...... 40
....... Methyl chloride and chloropicrin mixtures, see Chloropicrin ........... .............. ...................... ................ ........... ........... .......
and methyl chloride mixtures.
....... Methyl chloride and methylene chloride mixtures.............. 2.1 UN1912 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... D...... 40
....... Methyl chloroacetate......................................... 6.1 UN2295 II POISON................ T11............. None 202 243 5 L........ 60 L....... C......
....... Methyl chlorocarbonate, see Methyl chloroformate............. ........... .............. ...................... ................ ........... ........... .......
....... Methyl chloroform, see 1,1,1-Trichloroethane................. ........... .............. ...................... ................ ........... ........... .......
....... Methyl chloroformate......................................... 6.1 UN1238 I POISON, FLAMMABLE 1, A3, A6, A7, None 226 244 Forbidden.. Forbidden.. D...... 21, 40, 100
LIQUID, CORROSIVE. B9, B14, B30,
B72, N34, T38,
T43, T44.
....... Methyl chloromethyl ether.................................... 6.1 UN1239 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B72, T38, T43,
T44.
....... Methyl 2-chloropropionate.................................... 3 UN2933 III FLAMMABLE LIQUID...... B1, T7.......... 150 203 242 60 L....... 220 L...... A......
....... Methyl dichloroacetate....................................... 6.1 UN2299 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Methyl ethyl ether, see Ethyl methyl ether................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl ethyl ketone, see Ethyl methyl ketone................. ........... .............. ...................... ................ ........... ........... .......
....... Methyl ethyl ketone peroxide, in solution with more than 9 Forbidden .............. ...................... ................ ........... ........... .......
percent by mass active oxygen.
....... 2-Methyl-5-ethylpyridine..................................... 6.1 UN2300 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Methyl fluoride.............................................. 2.1 UN2454 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Methyl formate............................................... 3 UN1243 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
....... Methyl iodide................................................ 6.1 UN2644 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. A...... 12, 40
B74, T38, T43,
T45.
....... Methyl isobutyl carbinol..................................... 3 UN2053 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methyl isobutyl ketone....................................... 3 UN1245 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl isobutyl ketone peroxide, in solution with more than 9 Forbidden .............. ...................... ................ ........... ........... .......
percent by mass active oxygen.
....... Methyl isocyanate............................................ 6.1 UN2480 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 26, 40
LIQUID. B30, B72, T38,
T43, T44.
....... Methyl isopropenyl ketone, inhibited......................... 3 UN1246 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
+...... Methyl isothiocyanate........................................ 3 UN2477 II FLAMMABLE LIQUID, 2, B9, B14, B32, None 227 244 Forbidden.. 60 L....... A......
POISON. B74, T38, T43,
T45.
....... Methyl isovalerate........................................... 3 UN2400 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl magnesium bromide, in ethyl ether..................... 4.3 UN1928 I DANGEROUS WHEN WET, ................ None 201 243 Forbidden.. 1 L........ D......
FLAMMABLE LIQUID.
....... Methyl mercaptan............................................. 2.3 UN1064 POISON GAS, FLAMMABLE 3, 25, B7, B9, None 304 314, 315 Forbidden.. 25 kg...... D...... 40
GAS. B14.
....... Methyl mercaptopropionaldehyde, see Thia-4-pentanal.......... ........... .............. ...................... ................ ........... ........... .......
....... Methyl methacrylate monomer, inhibited....................... 3 UN1247 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B...... 40
....... Methyl nitramine (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl nitrate............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl nitrite............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl norbornene dicarboxylic anhydride, see Corrosive ........... .............. ...................... ................ ........... ........... .......
liquids, n.o.s..
....... Methyl orthosilicate......................................... 6.1 UN2606 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 30 L....... E...... 40
LIQUID. B74, T38, T43,
T45.
D...... Methyl parathion liquid...................................... 6.1 NA3018 II POISON................ N76, T14........ None 202 243 Forbidden.. 1 L........ A...... 40
D...... Methyl parathion solid....................................... 6.1 NA2783 II POISON................ N77............. None 212 242 25 kg...... 100 kg..... A...... 40
D...... Methyl phosphonic dichloride................................. 6.1 NA9206 I POISON, CORROSIVE..... 2, A3, B9, B14, None 227 244 Forbidden.. Forbidden.. C......
B32, B74, N34,
N43, T38, T43,
T45.
....... Methyl phosphonothioic dichloride, anhydrous, see Corrosive ........... .............. ...................... ................ ........... ........... .......
liquid, n.o.s..
D...... Methyl phosphonous dichloride, pyrophoric liquid............. 6.1 NA2845 I POISON, SPONTANEOUSLY 2, B9, B14, B16, None 227 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE. B32, B74, T38,
T43, T45.
....... Methyl picric acid (heavy metal salts of).................... Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl propionate............................................ 3 UN1248 II FLAMMABLE LIQUID...... B101, T2........ 150 202 242 5 L........ 60 L....... B......
....... Methyl propyl ether.......................................... 3 UN2612 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... E...... 40
....... Methyl propyl ketone......................................... 3 UN1249 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Methyl sulfate, see Dimethyl sulfate......................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl sulfide, see Dimethyl sulfide......................... ........... .............. ...................... ................ ........... ........... .......
....... Methyl trichloroacetate...................................... 6.1 UN2533 III KEEP AWAY FROM FOOD... 45, T1.......... 153 203 241 60 L....... 220 L...... A......
....... Methyl trimethylol methane trinitrate........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methyl vinyl ketone.......................................... 3 UN1251 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Methylal..................................................... 3 UN1234 II FLAMMABLE LIQUID...... T14............. None 202 242 5 L........ 60 L....... E......
....... Methylamine, anhydrous....................................... 2.1 UN1061 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Methylamine, aqueous solution................................ 3 UN1235 II FLAMMABLE LIQUID, B1, T8.......... 150 202 243 1 L........ 5 L........ E...... 41
CORROSIVE.
....... Methylamine dinitramine and dry salts thereof................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methylamine nitroform........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methylamine perchlorate (dry)................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Methylamyl acetate........................................... 3 UN1233 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... N-Methylaniline.............................................. 6.1 UN2294 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... alpha-Methylbenzyl alcohol................................... 6.1 UN2937 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... 3-Methylbutan-2-one.......................................... 3 UN2397 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... N-Methylbutylamine........................................... 3 UN2945 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Methylchlorosilane........................................... 2.3 UN2534 POISON GAS, FLAMMABLE 2, A2, A3, A7, None 226 314, 315 Forbidden.. Forbidden.. D...... 17, 40
GAS, CORROSIVE. B9, B14, N34.
....... Methylcyclohexane............................................ 3 UN2296 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Methylcyclohexanols, flammable............................... 3 UN2617 III FLAMMABLE LIQUID...... B1, T2.......... 150 203 242 60 L....... 220 L...... A......
....... Methylcyclohexanone.......................................... 3 UN2297 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methylcyclopentane........................................... 3 UN2298 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
D...... Methyldichloroarsine......................................... 6.1 NA1556 I POISON................ 2............... None 192 None Forbidden.. Forbidden.. D...... 40, 95
....... Methyldichlorosilane......................................... 4.3 UN1242 I DANGEROUS WHEN WET, A2, A3, A7, B6, None 201 243 Forbidden.. 1 L........ D...... 21, 28, 40,
CORROSIVE, FLAMMABLE B77, N34, T16, 49, 100
LIQUID. T26.
....... Methylene chloride, see Dichloromethane...................... ........... .............. ...................... ................ ........... ........... .......
....... Methylene glycol dinitrate................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Methylfuran................................................ 3 UN2301 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... a-Methylglucoside tetranitrate............................... Forbidden .............. ...................... ................ ........... ........... .......
....... a-Methylglycerol trinitrate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 5-Methylhexan-2-one.......................................... 3 UN2302 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methylhydrazine.............................................. 6.1 UN1244 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 21, 40, 49,
LIQUID, CORROSIVE. B72, B77, N34, 100
T38, T43, T44.
....... Methylmorpholine............................................. 3 UN2535 II FLAMMABLE LIQUID, B6, T8.......... None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Methylpentadienes............................................ 3 UN2461 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... 2-Methylpentan-2-ol.......................................... 3 UN2560 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Methylpentanes, see Hexanes.................................. ........... .............. ...................... ................ ........... ........... .......
....... Methylphenyldichlorosilane................................... 8 UN2437 II CORROSIVE............. T8, T26......... 154 202 242 1 L........ 30 L....... C...... 40
....... 1-Methylpiperidine........................................... 3 UN2399 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Methyltetrahydrofuran........................................ 3 UN2536 II FLAMMABLE LIQUID...... B101, T7........ 150 202 242 5 L........ 60 L....... B......
....... Methyltrichlorosilane........................................ 3 UN1250 I FLAMMABLE LIQUID, A7, B6, B77, None 201 243 Forbidden.. 2.5 L...... B...... 40
CORROSIVE. N34, T14, T26.
....... alpha-Methylvaleraldehyde.................................... 3 UN2367 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... Mine rescue equipment containing carbon dioxide, see Carbon ........... .............. ...................... ................ ........... ........... .......
dioxide.
....... Mines with bursting charge................................... 1.1F UN0136 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Mines with bursting charge................................... 1.1D UN0137 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Mines with bursting charge................................... 1.2D UN0138 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Mines with bursting charge................................... 1.2F UN0294 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Mixed acid, see Nitrating acid, mixtures etc................. ........... .............. ...................... ................ ........... ........... .......
....... Mobility aids, see Wheel chair, electric..................... ........... .............. ...................... ................ ........... ........... .......
D...... Model rocket motor........................................... 1.4C NA0276 II EXPLOSIVE 1.4C........ 51.............. None 62 None Forbidden.. 75 kg...... A...... 24E
D...... Model rocket motor........................................... 1.4S NA0323 II EXPLOSIVE 1.4S........ 51.............. None 62 None 25 kg...... 100 kg..... A...... 9E
....... Molybdenum pentachloride..................................... 8 UN2508 III CORROSIVE............. T8, T26......... 154 213 240 25 kg...... 100 kg..... C...... 40
....... Monochloroacetone (unstabilized)............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Monochloroethylene, see Vinyl chloride, inhibited............ ........... .............. ...................... ................ ........... ........... .......
....... Monoethanolamine, see Ethanolamine, solutions................ ........... .............. ...................... ................ ........... ........... .......
....... Monoethylamine, see Ethylamine............................... ........... .............. ...................... ................ ........... ........... .......
....... Morpholine................................................... 3 UN2054 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Morpholine, aqueous, mixture, see Corrosive liquids, n.o.s... ........... .............. ...................... ................ ........... ........... .......
....... Motor fuel anti-knock compounds see Motor fuel anti-knock ........... .............. ...................... ................ ........... ........... .......
mixtures.
+...... Motor fuel anti-knock mixtures............................... 6.1 UN1649 I POISON, FLAMMABLE 14, B9, B12, None 201 244 Forbidden.. 30 L....... D...... 25, 40
LIQUID. B90, T26, T39.
....... Motor spirit, see Gasoline................................... ........... .............. ...................... ................ ........... ........... .......
....... Muriatic acid, see Hydrochloric acid solution................ ........... .............. ...................... ................ ........... ........... .......
....... Musk xylene, see 5-tert-Butyl2,4,6-trinitro-m-xylene......... ........... .............. ...................... ................ ........... ........... .......
....... Naphtha see Petroleum distallate n.o.s....................... ........... .............. ...................... ................ ........... ........... .......
....... Naphthalene, crude or Naphthalene, refined................... 4.1 UN1334 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Naphthalene diozonide........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Naphthalene, molten.......................................... 4.1 UN2304 III FLAMMABLE SOLID....... A1, T8.......... 151 213 241 Forbidden.. Forbidden.. C......
....... beta-Naphthylamine........................................... 6.1 UN1650 II POISON................ T12, T26........ None 212 242 25 kg...... 100 kg..... A......
....... alpha-Naphthylamine.......................................... 6.1 UN2077 III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Naphthylamineperchlorate..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Naphthylthiourea............................................. 6.1 UN1651 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Naphthylurea................................................. 6.1 UN1652 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Natural gases (with high methane content), see Methane, etc. ........... .............. ...................... ................ ........... ........... .......
(UN 1971, UN 1972).
....... Neohexane, see Hexanes....................................... ........... .............. ...................... ................ ........... ........... .......
....... Neon, compressed............................................. 2.2 UN1065 NONFLAMMABLE GAS...... ................ 306 302 302 75 kg...... 150 kg..... A......
....... Neon, refrigerated liquid (cryogenic liquid)................. 2.2 UN1913 NONFLAMMABLE GAS...... ................ 320 316 None 50 kg...... 500 kg..... B......
....... New explosive or explosive device, see sections 173.51 and ........... .............. ...................... ................ ........... ........... .......
173.56.
....... Nickel carbonyl.............................................. 6.1 UN1259 I POISON, FLAMMABLE 1............... None 198 None Forbidden.. Forbidden.. D...... 18, 40
LIQUID.
....... Nickel cyanide............................................... 6.1 UN1653 II POISON................ N74, N75........ None 212 242 25 kg...... 100 kg..... A...... 26
....... Nickel nitrate............................................... 5.1 UN2725 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Nickel nitrite............................................... 5.1 UN2726 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A...... 56, 58
....... Nickel picrate............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nicotine..................................................... 6.1 UN1654 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
....... Nicotine compounds, liquid, n.o.s. or Nicotine preparations, 6.1 UN3144 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... B...... 40
liquid, n.o.s..
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... B...... 40
....... Nicotine compounds, solid, n.o.s. or Nicotine preparations, 6.1 UN1655 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
solid, n.o.s..
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nicotine hydrochloride or Nicotine hydrochloride solution.... 6.1 UN1656 II POISON................ ................ None 202 243 5 L........ 60 L....... A......
....... Nicotine salicylate.......................................... 6.1 UN1657 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Nicotine sulfate, solid...................................... 6.1 UN1658 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Nicotine sulfate, solution................................... 6.1 UN1658 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Nicotine tartrate............................................ 6.1 UN1659 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Nitrated paper (unstable).................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrates, inorganic, aqueous solution, n.o.s................. 5.1 UN3218 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 46
............................................................. ........... .............. III OXIDIZER.............. T8.............. 152 203 241 2.5 L...... 30 L....... B...... 46
....... Nitrates, inorganic, n.o.s................................... 5.1 UN1477 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 46
............................................................. ........... .............. III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A...... 46
....... Nitrates of diazonium compounds.............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrating acid mixtures, spent with more than 50 percent 8 UN1826 I CORROSIVE, OXIDIZER... T12, T27........ None 158 243 Forbidden.. 2.5 L...... D...... 40, 66
nitric acid.
....... Nitrating acid mixtures spent with not more than 50 percent 8 UN1826 II CORROSIVE............. B2, B100, T12, None 158 242 Forbidden.. 30 L....... D...... 40
nitric acid. T27.
....... Nitrating acid mixtures with more than 50 percent nitric acid 8 UN1796 I CORROSIVE, OXIDIZER... T12, T27........ None 158 243 Forbidden.. 2.5 L...... D...... 40, 66
....... Nitrating acid mixtures with not more than 50 percent nitric 8 UN1796 II CORROSIVE............. B2, T12, T27.... None 158 242 Forbidden.. 30 L....... D...... 40
acid.
....... Nitric acid other than red fuming, with more than 70 percent 8 UN2031 I CORROSIVE............. B12, B47, B53, None 158 243 Forbidden.. 2.5 L...... D...... 44, 66, 89,
nitric acid. T9, T27. 90, 110,
111
....... Nitric acid other than red fuming, with not more than 70 8 UN2031 II CORROSIVE............. B2, B12, B47, None 158 242 Forbidden.. 30 L....... D...... 44, 66, 89,
percent nitric acid. B53, T9, T27. 90, 110,
111
+...... Nitric acid, red fuming...................................... 8 UN2032 I CORROSIVE, OXIDIZER, 2, B9, B32, B74, None 227 244 Forbidden.. Forbidden.. D...... 40, 66, 74,
POISON. T38, T43, T45. 89, 90
....... Nitric oxide................................................. 2.3 UN1660 POISON GAS, OXIDIZER, 1, 25, B12, B37, None 337 None Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE. B46, B50, B60,
B77.
....... Nitric oxide and dinitrogen tetroxide mixtures or Nitric 2.3 UN1975 POISON GAS, OXIDIZER, 1, 25, B7, B9, None 337 None Forbidden.. Forbidden.. D...... 40, 89, 90
oxide and nitrogen dioxide mixtures. CORROSIVE. B12, B14, B45,
B46, B61, B66,
B67, B77.
....... Nitriles, flammable, toxic, n.o.s............................ 3 UN3273 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... E...... 40, 52
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T14............. None 202 243 1 L........ 60 L....... B...... 40, 52
POISON.
....... Nitriles, toxic, flammable, n.o.s............................ 6.1 UN3275 I POISON, FLAMMABLE ................ None 201 243 1 L........ 30 L....... B...... 40
LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Nitriles, toxic, n.o.s....................................... 6.1 UN3276 I POISON................ ................ None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Nitrites, inorganic, aqueous solution, n.o.s................. 5.1 UN3219 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 46, 56, 58
............................................................. ........... .............. III OXIDIZER.............. T8.............. 152 203 241 2.5 L...... 30 L....... B...... 46, 56, 58
....... Nitrites, inorganic, n.o.s................................... 5.1 UN2627 II OXIDIZER.............. 33.............. 152 212 None 5 kg....... 25 kg...... A...... 46, 56, 58
....... 3-Nitro-4-chlorobenzotrifluoride............................. 6.1 UN2307 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... 6-Nitro-4-diazotoluene-3-sulfonic acid (dry)................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitro isobutane triol trinitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... N-Nitro-N-methylglycolamide nitrate.......................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2-Nitro-2-methylpropanol nitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitro urea................................................... 1.1D UN0147 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... N-Nitroaniline............................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroanilines (o-; m-; p-;).................................. 6.1 UN1661 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Nitroanisole................................................. 6.1 UN2730 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A......
....... Nitrobenzene................................................. 6.1 UN1662 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... m-Nitrobenzene diazonium perchlorate......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrobenzenesulfonic acid.................................... 8 UN2305 II CORROSIVE............. ................ 154 202 242 1 L........ 30 L....... A......
....... Nitrobenzol, see Nitrobenzene................................ ........... .............. ...................... ................ ........... ........... .......
....... 5-Nitrobenzotriazol.......................................... 1.1D UN0385 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 19E
....... Nitrobenzotrifluorides....................................... 6.1 UN2306 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... Nitrobromobenzenes liquid.................................... 6.1 UN2732 III KEEP AWAY FROM FOOD... T8, T38......... 153 203 241 60 L....... 220 L...... A......
....... Nitrobromobenzenes solid..................................... 6.1 UN2732 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nitrocellulose, dry or wetted with less than 25 percent water 1.1D UN0340 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 4E, 27E
(or alcohol), by mass.
....... Nitrocellulose membrane filters.............................. 4.1 UN3270 II FLAMMABLE SOLID....... 43, A1.......... 151 212 240 1 kg....... 15 kg...... D......
....... Nitrocellulose, plasticized with not less than 18 percent 1.3C UN0343 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
plasticizing substance, by mass.
....... Nitrocellulose, solution, flammable with not more than 12.6 3 UN2059 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
percent nitrogen, by mass, and not more than 55 percent
nitrocellulose.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Nitrocellulose, unmodified or plasticized with less than 18 1.1D UN0341 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 4E, 27E
percent plasticizing substance, by mass.
....... Nitrocellulose, wetted with not less than 25 percent alcohol, 1.3C UN0342 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Nitrocellulose with alcohol with not less than 25 percent 4.1 UN2556 II FLAMMABLE SOLID....... ................ 151 212 None 1 kg....... 15 kg...... D...... 28
alcohol by mass, and with not more than 12.6 percent
nitrogen, by dry mass.
....... Nitrocellulose, with not more than 12.6 percent nitrogen, by 4.1 UN2557 II FLAMMABLE SOLID....... 44.............. 151 212 None 1 kg....... 15 kg...... D...... 28
dry mass, or Nitrocellulose mixture with pigment or
Nitrocellulose mixture with plasticizer or Nitrocellulose
mixture with pigment and plasticizer.
....... Nitrocellulose with water with not less than 25 percent 4.1 UN2555 II FLAMMABLE SOLID....... ................ 151 212 None 15 kg...... 50 kg...... E...... 28
water, by mass.
....... Nitrochlorobenzene, see Chloronitrobenzenes etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Nitrocresols................................................. 6.1 UN2446 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nitroethane.................................................. 3 UN2842 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Nitroethyl nitrate........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroethylene polymer........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrogen, compressed......................................... 2.2 UN1066 NONFLAMMABLE GAS...... ................ 306 302 314, 315 75 kg...... 150 kg..... A......
....... Nitrogen dioxide, liquefied see Dinitrogen tetroxide, ........... .............. ...................... ................ ........... ........... .......
liquefied.
....... Nitrogen fertilizer solution, see Fertilizer ammoniating ........... .............. ...................... ................ ........... ........... .......
solution etc..
....... Nitrogen, mixtures with rare gases, see Rare gases and ........... .............. ...................... ................ ........... ........... .......
nitrogen mixtures.
....... Nitrogen peroxide, see Dinitrogen tetroxide, liquefied....... ........... .............. ...................... ................ ........... ........... .......
....... Nitrogen, refrigerated liquid cryogenic liquid............... 2.2 UN1977 NONFLAMMABLE GAS...... ................ 320 316 318 50 kg...... 500 kg..... D......
....... Nitrogen tetroxide and nitric oxide mixtures, see Nitric ........... .............. ...................... ................ ........... ........... .......
oxide and nitrogen tetroxide mixtures.
....... Nitrogen tetroxide, see Dinitrogen tetroxide, liquefied...... ........... .............. ...................... ................ ........... ........... .......
....... Nitrogen trichloride......................................... Forbidden .............. ...................... ................ ........... ........... .......
D...... Nitrogen trifluoride......................................... 2.2 UN2451 NONFLAMMABLE GAS, ................ None 302 None Forbidden.. 25 kg...... D...... 40
OXIDIZER.
I...... Nitrogen trifluoride......................................... 2.3 UN2451 POISON GAS, OXIDIZER.. ................ None 302 None Forbidden.. 25 kg...... D...... 40
....... Nitrogen triiodide........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrogen triiodide monoamine................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrogen trioxide............................................ 2.3 UN2421 POISON GAS, OXIDIZER, 1............... None 336 245 Forbidden.. Forbidden.. D...... 40, 89, 90
CORROSIVE.
....... Nitroglycerin, desensitized with not less than 40 percent non- 1.1D UN0143 II EXPLOSIVE 1.1D, POISON ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 4E, 21E
volatile water insoluble phlegmatizer, by mass.
....... Nitroglycerin, liquid, not desensitized...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroglycerin, solution in alcohol, with more than 1 percent 3 UN3064 II FLAMMABLE LIQUID...... N8.............. None 202 None Forbidden.. 5 L........ E......
but not more than 5 percent nitroglycerin.
....... Nitroglycerin, solution in alcohol, with more than 1 percent 1.1D UN0144 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E, 21E
but not more than 10 percent nitrogylcerin.
....... Nitroglycerin solution in alcohol with not more than 1 3 UN1204 II FLAMMABLE LIQUID...... N34, T25........ None 202 None 5 L........ 60 L....... B......
percent nitroglycerin.
....... Nitroguanidine nitrate....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitroguanidine or Picrite, dry or wetted with less than 20 1.1D UN0282 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
percent water, by mass.
....... Nitroguanidine, wetted or Picrite, wetted with not less than 4.1 UN1336 I FLAMMABLE SOLID....... 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28
20 percent water, by mass. A20, N41.
....... 1-Nitrohydantoin............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrohydrochloric acid....................................... 8 UN1798 I CORROSIVE............. A3, B10, N41, None 201 243 Forbidden.. 2.5 L...... D...... 40, 66, 74,
T18, T27. 89, 90
....... Nitromannite (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Nitromannite, wetted, see Mannitol hexanitrate, etc.......... ........... .............. ...................... ................ ........... ........... .......
....... Nitromethane................................................. 3 UN1261 II FLAMMABLE LIQUID...... T25............. 150 202 None Forbidden.. 60 L....... A......
....... Nitromuriatic acid, see Nitrohydrochloric acid............... ........... .............. ...................... ................ ........... ........... .......
....... Nitronaphthalene............................................. 4.1 UN2538 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Nitrophenols (o-; m-; p-;)................................... 6.1 UN1663 III KEEP AWAY FROM FOOD... T8, T38......... 153 213 240 100 kg..... 200 kg..... A......
....... m-Nitrophenyldinitro methane................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Nitropropanes................................................ 3 UN2608 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... p-Nitrosodimethylaniline..................................... 4.2 UN1369 II SPONTANEOUSLY A19, A20, B101, None 212 241 15 kg...... 50 kg...... D...... 34
COMBUSTIBLE. N34.
D...... Nitrosoguanidine............................................. 1.1A NA0473 II EXPLOSIVE 1.1A........ 111, 117........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Nitrostarch, dry or wetted with less than 20 percent water, 1.1D UN0146 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Nitrostarch, wetted with not less than 20 percent water, by 4.1 UN1337 I FLAMMABLE SOLID....... 23, A8, A19, None 211 None 1 kg....... 15 kg...... D...... 28
mass. A20, N41.
....... Nitrosugars (dry)............................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Nitrosyl chloride............................................ 2.3 UN1069 POISON GAS, CORROSIVE. 3, B14.......... None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Nitrosylsulfuric acid........................................ 8 UN2308 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... D...... 40, 66, 74,
N34, T9, T27. 89, 90
....... Nitrotoluenes, liquid o-; m-; p-;............................ 6.1 UN1664 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Nitrotoluenes, solid m-, or p-............................... 6.1 UN1664 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Nitrotoluidines (mono)....................................... 6.1 UN2660 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Nitrotriazolone or NTO....................................... 1.1D UN0490 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Nitrous oxide and carbon dioxide mixtures, see Carbon dioxide ........... .............. ...................... ................ ........... ........... .......
and nitrous oxide mixtures.
....... Nitrous oxide, compressed.................................... 2.2 UN1070 NONFLAMMABLE GAS, ................ 306 304 314, 315 75 kg...... 150 kg..... A...... 40
OXIDIZER.
....... Nitrous oxide, refrigerated liquid........................... 2.2 UN2201 NONFLAMMABLE GAS...... B6.............. None 304 314, 315 75 kg...... 150 kg..... B...... 40
....... Nitroxylenes, (o-; m-; p-)................................... 6.1 UN1665 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Nitroxylol, see Nitroxylenes................................. ........... .............. ...................... ................ ........... ........... .......
....... Nonanes...................................................... 3 UN1920 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Nonflammable gas, n.o.s., see Compressed or Liquefied gases, ........... .............. ...................... ................ ........... ........... .......
etc. (UN 1955, UN 1956).
....... Nonliquefied gases, see Compressed gases, etc................ ........... .............. ...................... ................ ........... ........... .......
....... Nonliquefied hydrocarbon gas, see Hydrocarbon gases, ........... .............. ...................... ................ ........... ........... .......
compressed, n.o.s..
....... Nonyltrichlorosilane......................................... 8 UN1799 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... 2,5-Norbornadiene or Dicycloheptadiene....................... 3 UN2251 II FLAMMABLE LIQUID...... ................ 150 202 242 5 L........ 60 L....... D......
....... Nordhausen acid, see Sulfuric acid, fuming etc............... ........... .............. ...................... ................ ........... ........... .......
....... Octadecyltrichlorosilane..................................... 8 UN1800 II CORROSIVE............. A7, B2, B6 N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8.
....... Octadiene.................................................... 3 UN2309 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
....... 1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acid..... Forbidden .............. ...................... ................ ........... ........... .......
....... Octafluorobut-2-ene.......................................... 2.2 UN2422 NONFLAMMABLE GAS...... ................ None 304 314, 315 75 kg...... 150 kg..... A......
....... Octafluorocyclobutane, RC318................................. 2.2 UN1976 NONFLAMMABLE GAS...... ................ None 304 314, 315 75 kg...... 150 kg..... A......
....... Octafluoropropane, R218...................................... 2.2 UN2424 NONFLAMMABLE GAS...... ................ None 304 314, 315 75 kg...... 150 kg..... A......
....... Octanes...................................................... 3 UN1262 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Octogen, see Cyclotetramethylene tetranitramine, etc......... ........... .............. ...................... ................ ........... ........... .......
....... Octolite or Octol, dry or wetted with less than 15 percent 1.1D UN0266 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Octonal...................................................... 1.1D UN0496 EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Octyl aldehydes, flammable................................... 3 UN1191 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
+...... tert-Octyl mercaptan......................................... 6.1 UN3023 II POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. 60 L....... B...... 40, 102
LIQUID. B74, T38, T43,
T45.
....... Octyltrichlorosilane......................................... 8 UN1801 II CORROSIVE............. A7, B2, B6, N34, None 202 242 Forbidden.. 30 L....... C...... 40
T8, T26.
....... Oil gas...................................................... 2.3 UN1071 POISON GAS, FLAMMABLE 6............... None 304 314, 315 Forbidden.. 150 kg..... D...... 40
GAS.
....... Oleum, see Sulfuric acid, fuming............................. ........... .............. ...................... ................ ........... ........... .......
....... Organic peroxide type A, liquid or solid..................... Forbidden .............. ...................... ................ ........... ........... .......
....... Organic peroxide type B, liquid.............................. 5.2 UN3101 II ORGANIC PEROXIDE, 53.............. 152 225 None Forbidden.. Forbidden.. D...... 12, 40
EXPLOSIVE.
....... Organic peroxide type B, liquid, temperature controlled...... 5.2 UN3111 II ORGANIC PEROXIDE, 53.............. None 225 None Forbidden.. Forbidden.. D...... 2, 40
EXPLOSIVE.
....... Organic peroxide type B, solid............................... 5.2 UN3102 II ORGANIC PEROXIDE, 53.............. 152 225 None Forbidden.. Forbidden.. D...... 12, 40
EXPLOSIVE.
....... Organic peroxide type B, solid, temperature controlled....... 5.2 UN3112 II ORGANIC PEROXIDE, 53.............. None 225 None Forbidden.. Forbidden.. D...... 2, 40
EXPLOSIVE.
....... Organic peroxide type C, liquid.............................. 5.2 UN3103 II ORGANIC PEROXIDE...... ................ 152 225 None 5 L........ 10 L....... D...... 12, 40
....... Organic peroxide type C, liquid, temperature controlled...... 5.2 UN3113 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type C, solid............................... 5.2 UN3104 II ORGANIC PEROXIDE...... ................ 152 225 None 5 kg....... 10 kg...... D...... 12, 40
....... Organic peroxide type C, solid, temperature controlled....... 5.2 UN3114 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type D, liquid.............................. 5.2 UN3105 II ORGANIC PEROXIDE...... ................ 152 225 None 5 L........ 10 L....... D...... 12, 40
....... Organic peroxide type D, liquid, temperature controlled...... 5.2 UN3115 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type D, solid............................... 5.2 UN3106 II ORGANIC PEROXIDE...... ................ 152 225 None 5 kg....... 10 kg...... D...... 12, 40
....... Organic peroxide type D, solid, temperature controlled....... 5.2 UN3116 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type E, liquid.............................. 5.2 UN3107 II ORGANIC PEROXIDE...... ................ 152 225 None 10 L....... 25 L....... D...... 12, 40
....... Organic peroxide type E, liquid, temperature controlled...... 5.2 UN3117 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type E, solid............................... 5.2 UN3108 II ORGANIC PEROXIDE...... ................ 152 225 None 10 kg...... 25 kg...... D...... 12, 40
....... Organic peroxide type E, solid, temperature controlled....... 5.2 UN3118 II ORGANIC PEROXIDE...... ................ None 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type F, liquid.............................. 5.2 UN3109 II ORGANIC PEROXIDE...... ................ 152 225 225 10 L....... 25 L....... D...... 12, 40
....... Organic peroxide type F, liquid, temperature controlled...... 5.2 UN3119 II ORGANIC PEROXIDE...... ................ 225 225 None Forbidden.. Forbidden.. D...... 2, 40
....... Organic peroxide type F, solid............................... 5.2 UN3110 II ORGANIC PEROXIDE...... T42............. 152 225 None 10 kg...... 25 kg...... D...... 12, 40
....... Organic peroxide type F, solid, temperature controlled....... 5.2 UN3120 II ORGANIC PEROXIDE...... ................ 225 225 None Forbidden.. Forbidden.. D...... 2, 40
D...... Organic phosphate, mixed with compressed gas or Organic 2.3 NA1955 POISON GAS............ 3............... None 334 None Forbidden.. Forbidden.. D...... 40
phosphate compound, mixed with compressed gas or Organic
phosphorus compound, mixed with compressed gas.
....... Organoarsenic compound, n.o.s................................ 6.1 UN3280 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Organochlorine pesticides liquid, flammable, toxic, flash 3 UN2762 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Organochlorine pesticides, liquid, toxic..................... 6.1 UN2996 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Organochlorine pesticides, liquid, toxic, flammable, 6.1 UN2995 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Organochlorine pesticides, solid toxic....................... 6.1 UN2761 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Organometallic compound or Compound solution or Compound 4.3 UN3207 I DANGEROUS WHEN WET, ................ None 201 244 Forbidden.. 1 L........ E...... 40
dispersion, water-reactive, flammable, n.o.s.. FLAMMABLE LIQUID.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 202 243 1 L........ 5 L........ E...... 40
FLAMMABLE LIQUID.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 203 242 5 L........ 60 L....... E...... 40
FLAMMABLE LIQUID.
....... Organometallic compound, toxic n.o.s......................... 6.1 UN3282 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Organophosphorus compound, toxic, flammable, n.o.s........... 6.1 UN3279 I POISON, FLAMMABLE ................ None 201 243 1 L........ 30 L....... B...... 40
LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Organophosphorus compound, toxic n.o.s....................... 6.1 UN3278 I POISON................ ................ None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Organophosphorus pesticides, liquid, flammable, toxic, flash 3 UN2784 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Organophosphorus pesticides, liquid, toxic................... 6.1 UN3018 I POISON................ N76, T42........ None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ N76, T14........ None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N76, T14........ 153 203 241 60 L....... 220 L...... A...... 40
....... Organophosphorus pesticides, liquid, toxic, flammable, 6.1 UN3017 I POISON, FLAMMABLE N76, T42........ None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE N76, T14........ None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, N76, T14.... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Organophosphorus pesticides, solid, toxic.................... 6.1 UN2783 I POISON................ N77............. None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ N77............. None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... N77............. 153 213 240 100 kg..... 200 kg..... A...... 40
....... Organotin compounds, liquid, n.o.s........................... 6.1 UN2788 I POISON................ A3, N33, N34, None 201 243 1 L........ 30 L....... B...... 40
T42.
............................................................. ........... .............. II POISON................ A3, N33, N34, None 202 243 5 L........ 60 L....... A...... 40
T14.
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Organotin compounds, solid, n.o.s............................ 6.1 UN3146 I POISON................ A5.............. None 211 242 5 kg....... 50 kg...... B...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Organotin pesticides, liquid, flammable, toxic, flash point 3 UN2787 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
....... Organotin pesticides, liquid, toxic.......................... 6.1 UN3020 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Organotin pesticides, liquid, toxic, flammable, flashpoint 6.1 UN3019 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Organotin pesticides, solid, toxic........................... 6.1 UN2786 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Orthonitroaniline, see Nitroanilines etc..................... ........... .............. ...................... ................ ........... ........... .......
....... Osmium tetroxide............................................. 6.1 UN2471 I POISON................ A8, B100, N33, None 211 242 5 kg....... 50 kg...... B...... 40
N34.
AD..... Other regulated substances, liquid, n.o.s.................... 9 NA3082 III CLASS 9............... ................ 155 203 241 No limit... No limit... A......
AD..... Other regulated substances, solid, n.o.s..................... 9 NA3077 III CLASS 9............... B54............. 155 213 240 No limit... No limit... A......
....... Oxidizing liquid, corrosive, n.o.s........................... 5.1 UN3098 I OXIDIZER, CORROSIVE... ................ None 201 244 Forbidden.. 2.5 L...... D...... 34, 56, 58,
69, 106
............................................................. ........... .............. II OXIDIZER, CORROSIVE... ................ None 202 243 1 L........ 5 L........ B...... 34, 56, 58,
69, 106
............................................................. ........... .............. III OXIDIZER, CORROSIVE... ................ 152 203 242 2.5 L...... 30 L....... B...... 34, 56, 58,
69, 106
....... Oxidizing liquid, n.o.s...................................... 5.1 UN3139 II OXIDIZER.............. A2.............. 152 202 242 1 L........ 5 L........ B...... 56, 58, 69,
106
............................................................. ........... .............. III OXIDIZER.............. A2.............. 152 203 241 2.5 L...... 30 L....... B...... 56, 58, 69,
106
....... Oxidizing liquid, toxic, n.o.s............................... 5.1 UN3099 I OXIDIZER, POISON...... ................ None 201 244 Forbidden.. 2.5 L...... D...... 56, 58, 95,
106
............................................................. ........... .............. II OXIDIZER, POISON...... ................ None 202 243 1 L........ 5 L........ B...... 56, 58, 95,
106
............................................................. ........... .............. III OXIDIZER, KEEP AWAY ................ 152 203 242 2.5 L...... 30 L....... B...... 56, 58, 95,
FROM FOOD. 106
....... Oxidizing solid, corrosive, n.o.s............................ 5.1 UN3085 I OXIDIZER, CORROSIVE... ................ None 211 242 1 kg....... 15 kg...... D...... 13, 34, 56,
58, 69,
106
............................................................. ........... .............. II OXIDIZER, CORROSIVE... ................ None 212 242 5 kg....... 25 kg...... B...... 13, 34, 56,
58, 69,
106
............................................................. ........... .............. III OXIDIZER, CORROSIVE... ................ 152 213 240 25 kg...... 100 kg..... B...... 13, 34, 56,
58, 69,
106
....... Oxidizing solid, flammable, n.o.s............................ 5.1 UN3137 I OXIDIZER, FLAMMABLE ................ None 214 214 Forbidden.. Forbidden.. .......
SOLID.
....... Oxidizing solid, n.o.s....................................... 5.1 UN1479 I OXIDIZER.............. ................ None 211 242 1 kg....... 15 kg...... D...... 56, 58, 69,
106
............................................................. ........... .............. II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... B...... 56, 58, 69,
106
............................................................. ........... .............. III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... B...... 56, 58, 69,
106
....... Oxidizing solid, self-heating, n.o.s......................... 5.1 UN3100 II OXIDIZER, ................ None 214 214 Forbidden.. Forbidden.. .......
SPONTANEOUSLY
COMBUSTIBLE.
....... Oxidizing solid, toxic, n.o.s................................ 5.1 UN3087 I OXIDIZER, POISON...... ................ None 211 242 1 kg....... 15 kg...... D...... 56, 58, 69,
95, 106
............................................................. ........... .............. II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... B...... 56, 58, 69,
95, 106
............................................................. ........... .............. III OXIDIZER, KEEP AWAY ................ 152 213 240 25 kg...... 100 kg..... B...... 56, 58, 69,
FROM FOOD. 95, 106
....... Oxidizing solid, water-reactive, n.o.s....................... 5.1 UN3121 OXIDIZER, DANGEROUS ................ None 214 214 Forbidden.. Forbidden.. .......
WHEN WET.
....... Oxygen and carbon dioxide mixtures, see Carbon dioxide and ........... .............. ...................... ................ ........... ........... .......
oxygen mixtures.
....... Oxygen, compressed........................................... 2.2 UN1072 NONFLAMMABLE GAS, ................ 306 302 314, 315 75 kg...... 150 kg..... A......
OXIDIZER.
....... Oxygen difluoride............................................ 2.3 UN2190 POISON GAS, OXIDIZER, 1............... None 304 None Forbidden.. Forbidden.. D...... 13, 40, 89,
CORROSIVE. 90
....... Oxygen, mixtures with rare gases, see Rare gases and oxygen ........... .............. ...................... ................ ........... ........... .......
mixtures.
....... Oxygen, refrigerated liquid (cryogenic liquid)............... 2.2 UN1073 NONFLAMMABLE GAS, ................ 320 316 318 Forbidden.. Forbidden.. D......
OXIDIZER.
....... Paint including paint, lacquer, enamel, stain, shellac 3 UN1263 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
solutions, varnish, polish, liquid filler, and liquid
lacquer base.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Paint or Paint related material.............................. 8 UN3066 II CORROSIVE............. B2, N71, T14.... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. B52, N71, T7.... 154 203 241 5 L........ 60 L....... A......
....... Paint related material including paint thinning, drying, 3 UN1263 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
removing, or reducing compound.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Paper, unsaturated oil treated incompletely dried (including 4.2 UN1379 III SPONTANEOUSLY B101, B106...... None 213 241 Forbidden.. Forbidden.. A......
carbon paper). COMBUSTIBLE.
....... Paraformaldehyde............................................. 4.1 UN2213 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Paraldehyde.................................................. 3 UN1264 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Paranitroaniline, solid, see Nitroanilines etc............... ........... .............. ...................... ................ ........... ........... .......
D...... Parathion.................................................... 6.1 NA2783 I POISON................ T42............. None 201 243 Forbidden.. 1 L........ A...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 Forbidden.. 5 L........ A...... 40
D...... Parathion and compressed gas mixture......................... 2.3 NA1967 POISON GAS............ 3............... None 334 245 Forbidden.. Forbidden.. E...... 40
....... Paris green, solid, see Copper acetoarsenite................. ........... .............. ...................... ................ ........... ........... .......
A,W.... PCB, see Polychlorinated biphenyls........................... ........... .............. ...................... ................ ........... ........... .......
+...... Pentaborane.................................................. 4.2 UN1380 I SPONTANEOUSLY 1............... None 205 245 Forbidden.. Forbidden.. D......
COMBUSTIBLE, POISON.
....... Pentachloroethane............................................ 6.1 UN1669 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Pentachlorophenol............................................ 6.1 UN3155 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Pentaerythrite tetranitrate (dry)............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Pentaerythrite tetranitrate or Pentaerythritol tetranitrate 1.1D UN0411 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
or PETN, with not less than 7 percent wax by mass.
D...... Pentaerythrite tetranitrate, wetted or Pentaerythritol 1.1D UN0150 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
tetranitrate, wetted, or PETN, wetted with not less than 25
percent water, by mass, or Pentaerythrite tetranitrate, or
Pentaerythritol tetranitrate or PETN, desensitized with not
less than 15 percent phlegmatizer by mass.
....... Pentaerythritol tetranitrate, see Pentaerythrite ........... .............. ...................... ................ ........... ........... .......
tetranitrate, etc..
....... Pentafluoroethane............................................ 2.2 UN3220 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Pentamethylheptane........................................... 3 UN2286 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Pentan-2,4-dione............................................. 3 UN2310 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Pentanes..................................................... 3 UN1265 I FLAMMABLE LIQUID...... T20............. 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T20............. 150 202 242 5 L........ 60 L....... E......
....... Pentanitroaniline (dry)...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 1-Pentol..................................................... 8 UN2705 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... B...... 38
....... Pentolite, dry or wetted with less than 15 percent water, by 1.1D UN0151 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
mass.
....... Percarbonates, inorganic, n.o.s.............................. 5.1 UN3217 III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A...... 13
....... Perchlorates, inorganic, aqueous solution, n.o.s............. 5.1 UN3211 II OXIDIZER.............. T8.............. 152 202 242 1 L........ 5 L........ B...... 46, 56, 58
....... Perchlorates, inorganic, n.o.s............................... 5.1 UN1481 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 46, 56
............................................................. ........... .............. III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A...... 46, 56
....... Perchloric acid, with more than 72 percent acid by mass...... Forbidden .............. ...................... ................ ........... ........... .......
....... Perchloric acid with more than 50 percent but not more than 5.1 UN1873 I OXIDIZER, CORROSIVE... A2, A3, N41, T9, None 201 243 Forbidden.. 2.5 L...... D...... 66
72 percent acid, by mass. T27.
....... Perchloric acid with not more than 50 percent acid by mass... 8 UN1802 II CORROSIVE, OXIDIZER... N41, T9......... None 202 243 Forbidden.. 30 L....... C...... 66
....... Perchloroethylene, see Tetrachloroethylene................... ........... .............. ...................... ................ ........... ........... .......
....... Perchloromethyl mercaptan.................................... 6.1 UN1670 I POISON................ 2, A3, A7, B9, None 227 244 Forbidden.. Forbidden.. D...... 40
B14, B32, B74,
N34, T38, T43,
T45.
....... Perchloryl fluoride.......................................... 2.3 UN3083 POISON GAS, OXIDIZER.. 2, 25, B9, B12, None 302 314, 315 Forbidden.. Forbidden.. D...... 40
B14.
....... Percussion caps, see Primers, cap type....................... ........... .............. ...................... ................ ........... ........... .......
....... Perfluoro-2-butene, see Octafluorobut-2-ene.................. ........... .............. ...................... ................ ........... ........... .......
....... Perfluoroethyl vinyl ether................................... 2.1 UN3154 FLAMMABLE GAS......... ................ 306 302, 304, 314, 315 Forbidden.. 150 kg..... E...... 40
305
....... Perfluoromethyl vinyl ether.................................. 2.1 UN3153 FLAMMABLE GAS......... ................ 306 302, 304, 314, 315 Forbidden.. 150 kg..... E...... 40
305
....... Perfumery products with flammable solvents................... 3 UN1266 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 15 L....... 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Permanganates, inorganic, aqueous solution, n.o.s............ 5.1 UN3214 II OXIDIZER.............. 26, T8.......... 152 2O2 242 1 L........ 5 L........ D...... 56, 58, 69,
106, 107
....... Permanganates, inorganic, n.o.s.............................. 5.1 UN1482 II OXIDIZER.............. 26, A30......... 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
............................................................. ........... .............. III OXIDIZER.............. 26, A30......... 152 213 240 25 kg...... 100 kg..... D...... 56, 58, 69,
106, 107
....... Peroxides, inorganic, n.o.s.................................. 5.1 UN1483 II OXIDIZER.............. A7, A20, N34.... None 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
............................................................. ........... .............. III OXIDIZER.............. A7, A20, N34.... 152 213 240 25 kg...... 100 kg..... A...... 13, 75, 106
....... Peroxyacetic acid, with more than 43 percent and with more Forbidden .............. ...................... ................ ........... ........... .......
than 6 percent hydrogen peroxide.
....... Persulfates, inorganic, aqueous solution, n.o.s.............. 5.1 UN3216 III OXIDIZER.............. T2.............. 152 203 241 2.5 L...... 30 L....... A......
....... Persulfates, inorganic, n.o.s................................ 5.1 UN3215 III OXIDIZER.............. ................ 152 213 240 25 kg...... 100 kg..... A......
....... Pesticides, liquid, flammable, toxic, (flashpoint less than 3 UN3021 I FLAMMABLE LIQUID, B5.............. None 201 243 Forbidden.. 30 L....... B......
23 degrees C). POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B......
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... B......
AWAY FROM FOOD.
....... Pesticides, liquid, toxic, flammable, n.o.s. flashpoint not 6.1 UN2903 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Pesticides, liquid, toxic, n.o.s............................. 6.1 UN2902 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Pesticides, solid, toxic, n.o.s.............................. 6.1 UN2588 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... PETN, see Pentaerythrite tetranitrate........................ ........... .............. ...................... ................ ........... ........... .......
....... PETN/TNT, see Pentolite, etc................................. ........... .............. ...................... ................ ........... ........... .......
....... Petrol, see Gasoline......................................... ........... .............. ...................... ................ ........... ........... .......
....... Petroleum crude oil.......................................... 3 UN1267 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Petroleum distillates, n.o.s. or Petroleum products, n.o.s... 3 UN1268 I FLAMMABLE LIQUID...... T8, T31......... 150 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Petroleum gases, liquefied or Liquefied petroleum gas........ 2.1 UN1075 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
D...... Petroleum oil................................................ 3 NA1270 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Phenacyl bromide............................................. 6.1 UN2645 II POISON................ B106............ None 212 242 25 kg...... 100 kg..... B...... 40
....... Phenetidines................................................. 6.1 UN2311 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Phenol, molten............................................... 6.1 UN2312 II POISON................ B14, B100, T8... None 202 243 Forbidden.. Forbidden.. B...... 40
+...... Phenol, solid................................................ 6.1 UN1671 II POISON................ N78, T14........ None 212 242 25 kg...... 100 kg..... A......
....... Phenol solutions............................................. 6.1 UN2821 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Phenolsulfonic acid, liquid.................................. 8 UN1803 II CORROSIVE............. B2, N41, T8..... 154 202 242 1 L........ 30 L....... C...... 14
....... Phenoxy pesticides, liquid, flammable, toxic, flash point 3 UN2766 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Phenoxy pesticides, liquid, toxic............................ 6.1 UN3000 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Phenoxy pesticides, liquid, toxic, flammable, flashpoint not 6.1 UN2999 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Phenoxy pesticides, solid, toxic............................. 6.1 UN2765 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Phenyl chloroformate......................................... 6.1 UN2746 II POISON, CORROSIVE..... T12............. None 202 243 1 L........ 30 L....... A...... 12, 13, 21,
25, 40,
100
+...... Phenyl isocyanate............................................ 6.1 UN2487 II POISON................ 2, A3, B9, B14, None 227 244 5 L........ 60 L....... D...... 40
B32, B74, B77,
N33, N34, T38,
T43, T45.
....... Phenyl mercaptan............................................. 6.1 UN2337 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 26, 40
LIQUID. B74, B77, T38,
T43, T45.
....... Phenyl phosphorus dichloride................................. 8 UN2798 II CORROSIVE............. B2, B15, T8, T26 154 202 242 Forbidden.. 30 L....... B...... 40
....... Phenyl phosphorus thiodichloride............................. 8 UN2799 II CORROSIVE............. B2, B15, T8, T26 154 202 242 Forbidden.. 30 L....... B...... 40
....... Phenyl urea pesticides, liquid, flammable, toxic, flash point 3 UN2768 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Phenyl urea pesticides, liquid, toxic........................ 6.1 UN3002 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Phenyl urea pesticides, liquid, toxic, flammable, flash point 6.1 UN3001 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Phenyl urea pesticides, solid, toxic......................... 6.1 UN2767 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Phenylacetonitrile, liquid................................... 6.1 UN2470 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 26
....... Phenylacetyl chloride........................................ 8 UN2577 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C...... 40
....... Phenylcarbylamine chloride................................... 6.1 UN1672 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
B74, T38, T43,
T45.
....... m-Phenylene diaminediperchlorate (dry)....................... Forbidden .............. ...................... ................ ........... ........... .......
....... Phenylenediamines (o-; m-; p-;).............................. 6.1 UN1673 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Phenylhydrazine.............................................. 6.1 UN2572 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 40
....... Phenylmercuric acetate....................................... 6.1 UN1674 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Phenylmercuric compounds, n.o.s.............................. 6.1 UN2026 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Phenylmercuric hydroxide..................................... 6.1 UN1894 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Phenylmercuric nitrate....................................... 6.1 UN1895 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Phenyltrichlorosilane........................................ 8 UN1804 II CORROSIVE............. A7, B6, N34, T8. None 202 242 Forbidden.. 30 L....... C...... 40
....... Phosgene..................................................... 2.3 UN1076 POISON GAS, CORROSIVE. 1, B7, B46...... None 192 314 Forbidden.. Forbidden.. D...... 40
....... 9-Phosphabicyclononanes or Cyclooctadiene phosphines......... 4.2 UN2940 II SPONTANEOUSLY A19............. None 212 241 15 kg...... 50 kg...... A......
COMBUSTIBLE.
....... Phosphine.................................................... 2.3 UN2199 POISON GAS, FLAMMABLE 1............... None 192 245 Forbidden.. Forbidden.. D...... 40
GAS.
....... Phosphoric acid.............................................. 8 UN1805 III CORROSIVE............. A7, N34, T7..... 154 203 241 5 L........ 60 L....... A......
....... Phosphoric acid triethyleneimine, see Tris-(1- ........... .............. ...................... ................ ........... ........... .......
aziridiyl)phosphine oxide, solution.
....... Phosphoric anhydride, see Phosphorus pentoxide............... ........... .............. ...................... ................ ........... ........... .......
....... Phosphorous acid............................................. 8 UN2834 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A...... 48
....... Phosphorus, amorphous........................................ 4.1 UN1338 III FLAMMABLE SOLID....... A1, A19, B1, B9, None 213 243 25 kg...... 100 kg..... A...... 74
B12, B26.
....... Phosphorus bromide, see Phosphorus tribromide................ ........... .............. ...................... ................ ........... ........... .......
....... Phosphorus chloride, see Phosphorus trichloride.............. ........... .............. ...................... ................ ........... ........... .......
....... Phosphorus heptasulfide, free from yellow or white phosphorus 4.1 UN1339 II FLAMMABLE SOLID....... A20, N34........ None 212 240 15 kg...... 50 kg...... B...... 74
....... Phosphorus oxybromide........................................ 8 UN1939 II CORROSIVE............. B8, B106, N41, None 212 240 Forbidden.. 50 kg...... C...... 12, 40
N43.
....... Phosphorus oxybromide, molten................................ 8 UN2576 II CORROSIVE............. B2, B8, N41, None 202 242 Forbidden.. Forbidden.. C...... 40
N43, T8, T27.
+...... Phosphorus oxychloride....................................... 8 UN1810 II CORROSIVE, POISON..... 2, A7, B9, B14, None 227 244 Forbidden.. 30 L....... C...... 40
B32, B74, B77,
N34, T38, T43,
T45.
....... Phosphorus pentabromide...................................... 8 UN2691 II CORROSIVE............. A7, B106, N34... 154 212 240 Forbidden.. 50 kg...... B...... 12, 40
....... Phosphorus pentachloride..................................... 8 UN1806 II CORROSIVE............. A7, B106, N34... None 212 240 Forbidden.. 50 kg...... C...... 40
....... Phosphorus pentafluoride..................................... 2.3 UN2198 POISON GAS, CORROSIVE. 1............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Phosphorus pentasulfide, free from yellow or white phosphorus 4.3 UN1340 II DANGEROUS WHEN WET, A20, B59, B101.. None 212 242 15 kg...... 50 kg...... B...... 74
FLAMMABLE SOLID.
....... Phosphorus pentoxide......................................... 8 UN1807 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A......
....... Phosphorus sesquisulfide, free from yellow or white 4.1 UN1341 II FLAMMABLE SOLID....... A20, N34........ None 212 240 15 kg...... 50 kg...... B...... 74
phosphorus.
....... Phosphorus tribromide........................................ 8 UN1808 II CORROSIVE............. A3, A6, A7, B2, None 202 242 Forbidden.. 30 L....... C...... 40
B25, N34, N43,
T8.
+...... Phosphorus trichloride....................................... 8 UN1809 I CORROSIVE, POISON..... 2, A3, A7, B9, None 227 244 Forbidden.. 2.5 L...... C...... 40
B14, B15, B32,
B74, B77, N34,
T38, T43, T45.
....... Phosphorus trioxide.......................................... 8 UN2578 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 12
....... Phosphorus trisulfide, free from yellow or white phosphorus.. 4.1 UN1343 II FLAMMABLE SOLID....... A20, N34........ None 212 240 15 kg...... 50 kg...... B...... 74
....... Phosphorus, white dry or Phosphorus, white, under water or 4.2 UN1381 I SPONTANEOUSLY B9, B12, B26, None 188 243 Forbidden.. Forbidden.. E......
Phosphorus white, in solution or Phosphorus, yellow dry or COMBUSTIBLE, POISON. N34, T15, T26,
Phosphorus, yellow, under water or Phosphorus, yellow, in T33.
solution.
....... Phosphorus white, molten..................................... 4.2 UN2447 I SPONTANEOUSLY B9, B12, B26, None 188 243 Forbidden.. Forbidden.. D......
COMBUSTIBLE, POISON. N34, T15, T26,
T29.
....... Phosphorus (white or red) and a chlorate, mixtures of........ Forbidden .............. ...................... ................ ........... ........... .......
....... Phosphoryl chloride, see Phosphorus oxychloride.............. ........... .............. ...................... ................ ........... ........... .......
....... Phthalic anhydride with more than .05 percent maleic 8 UN2214 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A......
anhydride.
....... Phthalimide derivative pesticides, liquid, flammable, toxic, 3 UN2774 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
flash point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Phthalimide derivative pesticides, liquid, toxic............. 6.1 UN3008 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Phthalimide derivative pesticides, liquid, toxic, flammable 6.1 UN3007 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Phthalimide derivative pesticides, solid, toxic.............. 6.1 UN2773 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Picolines.................................................... 3 UN2313 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Picric acid, see Trinitrophenol, etc......................... ........... .............. ...................... ................ ........... ........... .......
D...... Picric acid, wet, with not less than 10 percent water........ 4.1 NA1344 I FLAMMABLE SOLID....... A19, A20, N41... None 211 None Forbidden.. Forbidden.. D......
....... Picrite, see Nitroguanidine, etc............................. ........... .............. ...................... ................ ........... ........... .......
....... Picryl chloride, see Trinitrochlorobenzene................... ........... .............. ...................... ................ ........... ........... .......
....... Pine oil..................................................... 3 UN1272 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... alpha-Pinene................................................. 3 UN2368 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Piperazine................................................... 8 UN2579 III CORROSIVE............. T7.............. 154 213 240 25 kg...... 100 kg..... A...... 12
....... Piperidine................................................... 3 UN2401 II FLAMMABLE LIQUID, T2.............. None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Pivaloyl chloride, see Trimethylacetyl chloride.............. ........... .............. ...................... ................ ........... ........... .......
A...... Plastic molding material in dough, sheet or extruded rope 9 .............. III CLASS 9............... ................ 155 213 None 100 kg..... 200 kg..... A......
form.
....... Plastic solvent, n.o.s., see Flammable liquids, n.o.s........ ........... .............. ...................... ................ ........... ........... .......
....... Plastics, nitrocellulose-based, self-heating, n.o.s.......... 4.2 UN2006 III SPONTANEOUSLY ................ None 213 None Forbidden.. Forbidden.. C......
COMBUSTIBLE.
....... Poisonous gases, n.o.s., see Compressed or liquefied gases, ........... .............. ...................... ................ ........... ........... .......
flammable or toxic, n.o.s..
....... Polyalkylamines, n.o.s., see Amines, etc..................... ........... .............. ...................... ................ ........... ........... .......
AW..... Polychlorinated biphenyls.................................... 9 UN2315 II CLASS 9............... 9, 81........... 155 202 241 100 L...... 220 L...... A...... 34
....... Polyester resin kit.......................................... 3 UN3269 FLAMMABLE LIQUID...... 40.............. None 225 None 5 kg....... 5 kg....... B......
....... Polyhalogenated biphenyls, liquid or Polyhalogenated 9 UN3151 II CLASS 9............... ................ 155 204 241 100 L...... 220 L...... A...... 34
terphenyls liquid.
....... Polyhalogenated biphenyls, solid or Polyhalogenated 9 UN3152 II CLASS 9............... ................ 155 204 241 100 kg..... 200 kg..... A...... 34
terphenyls, solid.
....... Polymeric beads, expandable, evolving flammable vapor........ 9 UN2211 III None.................. 32.............. 155 221 240 100 kg..... 200 kg..... A...... 85, 87
....... Potassium.................................................... 4.3 UN2257 I DANGEROUS WHEN WET.... A19, A20, B27, None 211 244 1 kg....... 15 kg...... D......
B100, N6, N34,
T15, T26.
....... Potassium arsenate........................................... 6.1 UN1677 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Potassium arsenite........................................... 6.1 UN1678 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Potassium bisulfite solution, see Bisulfites, inorganic, ........... .............. ...................... ................ ........... ........... .......
aqueous solutions, n.o.s..
....... Potassium borohydride........................................ 4.3 UN1870 I DANGEROUS WHEN WET.... A19, N40........ None 211 242 Forbidden.. 15 kg...... E......
....... Potassium bromate............................................ 5.1 UN1484 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Potassium carbonyl........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Potassium chlorate........................................... 5.1 UN1485 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Potassium chlorate, aqueous solution......................... 5.1 UN2427 II OXIDIZER.............. A2, T8.......... 152 202 241 1 L........ 5 L........ B...... 56, 58, 106
....... Potassium chlorate mixed with mineral oil, see Explosive, ........... .............. ...................... ................ ........... ........... .......
blasting, type C.
....... Potassium cuprocyanide....................................... 6.1 UN1679 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26
....... Potassium cyanide............................................ 6.1 UN1680 I POISON................ B69, B77, N74, None 211 242 5 kg....... 50 kg...... B...... 52
N75, T18, T26.
....... Potassium dichloro isocyanurate or Potassium dichloro-s- ........... .............. ...................... ................ ........... ........... .......
triazinetrione, see Dichloroisocyanuric acid, dry or
Dichloroisocyanuric acid salts etc.
....... Potassium dithionite or Potassium hydrosulfite............... 4.2 UN1929 II SPONTANEOUSLY A8, A19, A20.... None 212 241 15 kg...... 50 kg...... E...... 13
COMBUSTIBLE.
....... Potassium fluoride........................................... 6.1 UN1812 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 26
....... Potassium fluoroacetate...................................... 6.1 UN2628 I POISON................ ................ None 211 242 5 kg....... 50 kg...... E......
....... Potassium fluorosilicate..................................... 6.1 UN2655 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Potassium hydrate, see Potassium hydroxide, solid............ ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydrogen fluoride, see Potassium hydrogen ........... .............. ...................... ................ ........... ........... .......
difluoride.
....... Potassium hydrogen fluoride solution, see Corrosive liquid, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Potassium hydrogen sulfate................................... 8 UN2509 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A......
....... Potassium hydrogendifluoride, solid.......................... 8 UN1811 II CORROSIVE, POISON..... B106, N3, N34, 154 212 240 15 kg...... 50 kg...... A...... 25, 26, 40
T8.
....... Potassium hydrogendifluoride, solution....................... 8 UN1811 II CORROSIVE, POISON..... N3, N34, T8..... 154 202 243 1 L........ 30 L....... A...... 26, 40, 95
....... Potassium hydrosulfite, see Potassium dithionite............. ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydroxide, liquid, see Potassium hydroxide solution ........... .............. ...................... ................ ........... ........... .......
....... Potassium hydroxide, solid................................... 8 UN1813 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Potassium hydroxide, solution................................ 8 UN1814 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Potassium hypochlorite, solution, see Hypochlorite solutions, ........... .............. ...................... ................ ........... ........... .......
etc..
....... Potassium, metal alloys...................................... 4.3 UN1420 I DANGEROUS WHEN WET.... A19, A20, B27... None 211 244 1 kg....... 15 kg...... D......
....... Potassium metal, liquid alloy, see Alkali metal alloys, ........... .............. ...................... ................ ........... ........... .......
liquid.
....... Potassium metavanadate....................................... 6.1 UN2864 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Potassium monoxide........................................... 8 UN2033 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Potassium nitrate............................................ 5.1 UN1486 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Potassium nitrate and sodium nitrite mixtures................ 5.1 UN1487 II OXIDIZER.............. B12, B78........ 152 212 240 5 kg....... 25 kg...... A...... 56, 58
....... Potassium nitrite............................................ 5.1 UN1488 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58
....... Potassium perchlorate, solid................................. 5.1 UN1489 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Potassium perchlorate, solution.............................. 5.1 UN1489 II OXIDIZER.............. ................ 152 202 242 1 L........ 5 L........ A...... 56, 58, 106
....... Potassium permanganate....................................... 5.1 UN1490 II OXIDIZER.............. B12............. 152 212 240 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Potassium peroxide........................................... 5.1 UN1491 I OXIDIZER.............. A20, N34........ None 211 None Forbidden.. 15 kg...... B...... 13, 75, 106
....... Potassium persulfate......................................... 5.1 UN1492 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Potassium phosphide.......................................... 4.3 UN2012 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Potassium salts of aromatic nitro-derivatives, explosive..... 1.3C UN0158 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Potassium selenate, see Selenates or Selenites............... ........... .............. ...................... ................ ........... ........... .......
....... Potassium selenite, see Selenates or Selenites............... ........... .............. ...................... ................ ........... ........... .......
....... Potassium sodium alloys...................................... 4.3 UN1422 I DANGEROUS WHEN WET.... A19, B27, N34, None 211 244 Forbidden.. 15 kg...... D......
N40, T15, T26.
....... Potassium sulfide, anhydrous or Potassium sulfide with less 4.2 UN1382 II SPONTANEOUSLY A19, A20, B16, None 212 241 15 kg...... 50 kg...... A......
than 30 percent water of crystallization. COMBUSTIBLE. B106, N34.
....... Potassium sulfide, hydrated with not less than 30 percent 8 UN1847 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A...... 26
water of crystallization.
....... Potassium superoxide......................................... 5.1 UN2466 I OXIDIZER.............. A20............. None 211 None Forbidden.. 15 kg...... B...... 13, 75, 106
....... Powder cake, wetted or Powder paste, wetted with not less 1.1C UN0433 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
than 17 percent alcohol by mass.
....... Powder cake, wetted or Powder paste, wetted with not less 1.3C UN0159 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
than 25 percent water, by mass.
....... Powder paste, see Powder cake, etc........................... ........... .............. ...................... ................ ........... ........... .......
....... Powder, smokeless............................................ 1.1C UN0160 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 10E, 26E
....... Powder, smokeless............................................ 1.3C UN0161 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 10E, 26E
....... Power device, explosive, see Cartridges, power device........ ........... .............. ...................... ................ ........... ........... .......
....... Primers, cap type............................................ 1.4S UN0044 II None.................. ................ None 62 None 25 kg...... 100 kg..... A......
....... Primers, cap type............................................ 1.1B UN0377 II EXPLOSIVE 1.1B........ ................ None 62 None Forbidden.. Forbidden.. B...... 2E, 6E
....... Primers, cap type............................................ 1.4B UN0378 II EXPLOSIVE 1.4B........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Primers, small arms, see Primers, cap type................... ........... .............. ...................... ................ ........... ........... .......
....... Primers, tubular............................................. 1.3G UN0319 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Primers, tubular............................................. 1.4G UN0320 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Primers, tubular............................................. 1.4S UN0376 II None.................. ................ None 62 None 25 kg...... 100 kg..... A......
....... Printing ink, flammable...................................... 3 UN1210 I FLAMMABLE LIQUID...... T8, T31......... 150 173 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T7, T30......... 150 173 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 173 242 60 L....... 220 L...... A......
....... Projectiles, illuminating, see Ammunition, illuminating, etc. ........... .............. ...................... ................ ........... ........... .......
....... Projectiles, inert with tracer............................... 1.4S UN0345 II EXPLOSIVE 1.4S........ ................ 62 None 25 kg...... 100 kg..... A...... 3E, 7E, 9E
....... Projectiles, inert, with tracer.............................. 1.3G UN0424 II EXPLOSIVE 1.3G........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, inert, with tracer.............................. 1.4G UN0425 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Projectiles, with burster or expelling charge................ 1.2D UN0346 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with burster or expelling charge................ 1.4D UN0347 II EXPLOSIVE 1.4D........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Projectiles, with burster or expelling charge................ 1.2F UN0426 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with burster or expelling charge................ 1.4F UN0427 II EXPLOSIVE 1.4F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with burster or expelling charge................ 1.2G UN0434 II EXPLOSIVE 1.2G........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with burster or expelling charge................ 1.4G UN0435 II EXPLOSIVE 1.4G........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Projectiles, with bursting charge............................ 1.1F UN0167 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with bursting charge............................ 1.1D UN0168 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with bursting charge............................ 1.2D UN0169 II EXPLOSIVE 1.2D........ ................ 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Projectiles, with bursting charge............................ 1.2F UN0324 II EXPLOSIVE 1.2F........ ................ 62 None Forbidden.. Forbidden.. E......
....... Projectiles, with bursting charge............................ 1.4D UN0344 II EXPLOSIVE 1.4D........ ................ 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Propadiene, inhibited........................................ 2.1 UN2200 FLAMMABLE GAS......... ................ None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Propadiene mixed with methyl acetylene, see Methyl acetylene ........... .............. ...................... ................ ........... ........... .......
and propadiene mixtures, stabilized.
....... Propane or Propane mixtures see also Petroleum gases, 2.1 UN1978 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
liquefied.
....... Propanethiols................................................ 3 UN2402 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... E...... 95, 102
....... n-Propanol or Propyl alcohol, normal......................... 3 UN1274 II FLAMMABLE LIQUID...... B1, T1.......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
D...... Propargyl alcohol............................................ 3 NA1986 II FLAMMABLE LIQUID, ................ None 202 243 Forbidden.. 1 L........ B...... 40
POISON.
D...... Propellant explosive, liquid................................. 1.1C NA0474 II EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
D...... Propellant explosive, liquid................................. 1.3C NA0477 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Propellant, liquid........................................... 1.3C UN0495 EXPLOSIVE 1.3C........ 37.............. None 62 None Forbidden.. Forbidden.. B......
....... Propellant, liquid........................................... 1.1C UN0497 EXPLOSIVE 1.1C........ 37.............. None 62 None Forbidden.. Forbidden.. B......
....... Propellant, solid............................................ 1.1C UN0498 EXPLOSIVE 1.1C........ ................ None 62 None Forbidden.. Forbidden.. A......
....... Propellant, solid............................................ 1.3C UN0499 EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. A......
....... Propionaldehyde.............................................. 3 UN1275 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... E......
....... Propionic acid............................................... 8 UN1848 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Propionic anhydride.......................................... 8 UN2496 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... Propionitrile................................................ 3 UN2404 II FLAMMABLE LIQUID, T14............. None 202 243 Forbidden.. 60 L....... E...... 40
POISON.
....... Propionyl chloride........................................... 3 UN1815 II FLAMMABLE LIQUID, B100, T8, T26... None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... n-Propyl acetate............................................. 3 UN1276 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Propyl alcohol, see Propanol................................. ........... .............. ...................... ................ ........... ........... .......
....... n-Propyl benzene............................................. 3 UN2364 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Propyl chloride.............................................. 3 UN1278 II FLAMMABLE LIQUID...... N34, T14........ None 202 242 Forbidden.. 60 L....... E......
....... n-Propyl chloroformate....................................... 6.1 UN2740 I POISON, FLAMMABLE 2, A3, A6, A7, None 227 244 Forbidden.. 2.5 L...... B...... 21, 40, 100
LIQUID, CORROSIVE. B9, B14, B32,
B74, B77, N34,
T38, T43, T45.
....... Propyl formates.............................................. 3 UN1281 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... n-Propyl isocyanate.......................................... 6.1 UN2482 I POISON, FLAMMABLE 1, A7, B9, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B72, T38,
T43, T44.
....... Propyl mercaptan, see Propanethiols.......................... ........... .............. ...................... ................ ........... ........... .......
....... n-Propyl nitrate............................................. 3 UN1865 II FLAMMABLE LIQUID...... T25............. 150 202 None 5 L........ 60 L....... D......
....... Propylamine.................................................. 3 UN1277 II FLAMMABLE LIQUID, N34, T14........ None 202 243 1 L........ 5 L........ E...... 40
CORROSIVE.
....... Propylene see also Petroleum gases, liquefied................ 2.1 UN1077 FLAMMABLE GAS......... 19.............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Propylene chlorohydrin....................................... 6.1 UN2611 II POISON................ T9.............. None 202 243 5 L........ 60 L....... A...... 12, 40, 48
....... Propylene dichloride......................................... 3 UN1279 II FLAMMABLE LIQUID...... N36, T1......... 150 202 242 5 L........ 60 L....... B......
....... Propylene oxide.............................................. 3 UN1280 I FLAMMABLE LIQUID...... A3, N34, T20, None 201 243 1 L........ 30 L....... E...... 40
T29.
....... Propylene tetramer........................................... 3 UN2850 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1,2-Propylenediamine......................................... 8 UN2258 II CORROSIVE, FLAMMABLE A3, A6, N34, T8. None 202 243 1 L........ 30 L....... A...... 40
LIQUID.
....... Propyleneimine, inhibited.................................... 3 UN1921 I FLAMMABLE LIQUID...... A3, N34, T25.... None 201 243 1 L........ 30 L....... B...... 40
....... Propyltrichlorosilane........................................ 8 UN1816 II CORROSIVE, FLAMMABLE A7, B2, B6, N34, None 202 243 Forbidden.. 30 L....... C...... 40
LIQUID. T8, T26.
....... Prussic acid, see Hydrogen cyanide........................... ........... .............. ...................... ................ ........... ........... .......
....... Pyridine..................................................... 3 UN1282 II FLAMMABLE LIQUID...... T8.............. None 202 242 5 L........ 60 L....... B...... 21, 100
....... Pyridine perchlorate......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Pyrophoric liquid, inorganic, n.o.s.......................... 4.2 UN3194 I SPONTANEOUSLY ................ None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE.
....... Pyrophoric liquids, organic, n.o.s........................... 4.2 UN2845 I SPONTANEOUSLY B11, T42........ None 181 244 Forbidden.. Forbidden.. D...... 18
COMBUSTIBLE.
....... Pyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s....... 4.2 UN1383 I SPONTANEOUSLY B11............. None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrophoric organometallic compound, n.o.s.................... 4.2 UN3203 I SPONTANEOUSLY ................ None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrophoric solid, inorganic, n.o.s........................... 4.2 UN3200 I SPONTANEOUSLY ................ None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrophoric solids, organic, n.o.s............................ 4.2 UN2846 I SPONTANEOUSLY ................ None 187 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
....... Pyrosulfuryl chloride........................................ 8 UN1817 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 40
....... Pyroxylin solution or solvent, see Nitrocellulose............ ........... .............. ...................... ................ ........... ........... .......
....... Pyrrolidine.................................................. 3 UN1922 II FLAMMABLE LIQUID, T1.............. None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Quebrachitol pentanitrate.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Quicklime, see Calcium oxide................................. ........... .............. ...................... ................ ........... ........... .......
....... Quinoline.................................................... 6.1 UN2656 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... A...... 12
....... R 114, see Dichlorotetrafluoroethane......................... ........... .............. ...................... ................ ........... ........... .......
....... R 115, see Chloropentafluoroethane........................... ........... .............. ...................... ................ ........... ........... .......
....... R 116, see Hexafluoroethane.................................. ........... .............. ...................... ................ ........... ........... .......
....... R 124, see Chlorotetrafluoroethane........................... ........... .............. ...................... ................ ........... ........... .......
....... R 133a, see Chlorotrifluoroethane............................ ........... .............. ...................... ................ ........... ........... .......
....... R 152a, see Difluoroethane................................... ........... .............. ...................... ................ ........... ........... .......
....... R 500, see Dichlorodifluoromethane and difluorethane, etc.... ........... .............. ...................... ................ ........... ........... .......
....... R 502, see Chlorodifluoromethane and chloropentafluoroethane ........... .............. ...................... ................ ........... ........... .......
mixture, etc..
....... R 503, see Chlorotrifluoromethane and trifluoromethane, etc.. ........... .............. ...................... ................ ........... ........... .......
....... R 12, see Dichlorodifluoromethane............................ ........... .............. ...................... ................ ........... ........... .......
....... R 12B1, see Chlorodifluorobromomethane....................... ........... .............. ...................... ................ ........... ........... .......
....... R 13, see Chlorotrifluoromethane............................. ........... .............. ...................... ................ ........... ........... .......
....... R 13B1, see Bromotrifluoromethane............................ ........... .............. ...................... ................ ........... ........... .......
....... R 14, see Tetrafluoromethane................................. ........... .............. ...................... ................ ........... ........... .......
....... R 21, see Dichlorofluoromethane.............................. ........... .............. ...................... ................ ........... ........... .......
....... R 22, see Chlorodifluoromethane.............................. ........... .............. ...................... ................ ........... ........... .......
....... Radioactive material, excepted package-articles manufactured 7 UN2910 None.................. ................ 421-1, 424 421-1, 421-1, ........... ........... A......
from natural or depleted uranium or natural thorium. 424 424
....... Radioactive material, excepted package-empty packaging....... 7 UN2910 EMPTY................. ................ 427 427 427 ........... ........... A......
....... Radioactive material, excepted package-instruments or 7 UN2910 None.................. ................ 421-1, 422 421-1, 421-1, ........... ........... A......
articles. 422 422
....... Radioactive material, excepted package-limited quantity of 7 UN2910 None.................. ................ 421, 421-1 421, 421- 421, 421- ........... ........... A......
material. 1 1
....... Radioactive material, fissile, n.o.s......................... 7 UN2918 RADIOACTIVE........... ................ 453 417 417 ........... ........... A...... 40, 95
....... Radioactive material, low specific activity, n.o.s. or 7 UN2912 RADIOACTIVE........... ................ 421, 422, 425 425 ........... ........... A......
Radioactive material, LSA, n.o.s.. 424
....... Radioactive material, n.o.s.................................. 7 UN2982 RADIOACTIVE........... ................ 421, 422, 415, 416 415, 416 ........... ........... A...... 40, 95
424
....... Radioactive material, special form, n.o.s.................... 7 UN2974 RADIOACTIVE........... ................ 421, 422 415, 416 415, 416 ........... ........... A......
....... Railway torpedo, see Signals, railway track, explosive....... ........... .............. ...................... ................ ........... ........... .......
....... Rare gases and nitrogen mixtures............................. 2.2 UN1981 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Rare gases and oxygen mixtures............................... 2.2 UN1980 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Rare gases, mixtures......................................... 2.2 UN1979 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... RC 318, see Octafluorocyclobutane............................ ........... .............. ...................... ................ ........... ........... .......
....... RDX and cyclotetramethylenetetranitramine, wetted or ........... .............. ...................... ................ ........... ........... .......
desensitized see RDX and HMX mixtures, wetted or
desensitized.
....... RDX and HMX mixtures, wetted with not less than 15 percent 1.1D UN0391 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water by mass or RDX and HMX mixtures, desensitized with not
less than 10 percent phlegmatizer by mass.
....... RDX and Octogen mixtures, wetted or desensitized see RDX and ........... .............. ...................... ................ ........... ........... .......
HMX mixtures, wetted or desensitized etc..
....... RDX, see Cyclotrimethylene trinitramine, etc................. ........... .............. ...................... ................ ........... ........... .......
....... Receptacles, small, containing gas flammable, without release 2.1 UN2037 FLAMMABLE GAS......... ................ 306 304 None 1 kg....... 15 kg...... B...... 40
device, not refillable and not exceeding 1 L capacity.
....... Receptacles, small, containing gas non-flammable, without 2.2 UN2037 NONFLAMMABLE GAS...... ................ 306 304 None 1 kg....... 15 kg...... B...... 40
release device, not refillable and not exceeding 1 L
capacity.
....... Red phosphorus, see Phosphorus, amorphous.................... ........... .............. ...................... ................ ........... ........... .......
....... Refrigerant gases, n.o.s..................................... 2.2 UN1078 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Refrigerant gases, n.o.s. or Dispersant gases, n.o.s......... 2.1 NA1954 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... D...... 40
D...... Refrigerating machine........................................ 3 NA1993 III FLAMMABLE LIQUID...... ................ 174 174 None 10 L....... 10 L....... A......
D...... Refrigerating machines, containing flammable, non-poisonous, 2.1 NA1954 FLAMMABLE GAS......... ................ 306 306 306 Forbidden.. 25 kg...... C...... 40
liquefied gas.
....... Refrigerating machines, containing non-flammable, non-toxic, 2.2 UN2857 NONFLAMMABLE GAS...... ................ 306, 307 306 306, 307 Forbidden.. 450 kg..... A......
liquefied gas or ammonia solutions (UN2073).
D...... Regulated medical waste...................................... 6.2 NA9275 II INFECTIOUS SUBSTANCE.. ................ 197 197 None Forbidden.. Forbidden.. E......
....... Release devices, explosive................................... 1.4S UN0173 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Resin solution, flammable.................................... 3 UN1866 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Resorcinol................................................... 6.1 UN2876 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Rifle grenade, see Grenades, hand or rifle, etc.............. ........... .............. ...................... ................ ........... ........... .......
....... Rifle powder, see Powder, smokeless (UN 0160)................ ........... .............. ...................... ................ ........... ........... .......
....... Rivets, explosive............................................ 1.4S UN0174 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Road asphalt or tar liquid, see Tars, liquid, etc............ ........... .............. ...................... ................ ........... ........... .......
....... Rocket motors................................................ 1.3C UN0186 II EXPLOSIVE 1.3C........ 109............. None 62 None Forbidden.. 220 kg..... B......
....... Rocket motors................................................ 1.1C UN0280 II EXPLOSIVE 1.1C........ 109............. None 62 None Forbidden.. Forbidden.. B......
....... Rocket motors................................................ 1.2C UN0281 II EXPLOSIVE 1.2C........ 109............. None 62 None Forbidden.. Forbidden.. B......
....... Rocket motors, liquid fueled................................. 1.2J UN0395 II EXPLOSIVE 1.2J........ 109............. None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rocket motors, liquid fueled................................. 1.3J UN0396 II EXPLOSIVE 1.3J........ 109............. None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rocket motors with hypergolic liquids with or without an 1.3L UN0250 II EXPLOSIVE 1.3L........ 109............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
expelling charge. 11E, 17E
....... Rocket motors with hypergolic liquids with or without an 1.2L UN0322 II EXPLOSIVE 1.2L........ 109............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
expelling charge. 11E, 17E
....... Rockets, line-throwing....................................... 1.2G UN0238 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, line-throwing....................................... 1.3G UN0240 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Rockets, line-throwing....................................... 1.4G UN0453 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Rockets, liquid fueled with bursting charge.................. 1.1J UN0397 II EXPLOSIVE 1.1J........ ................ None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rockets, liquid fueled with bursting charge.................. 1.2J UN0398 II EXPLOSIVE 1.2J........ ................ None 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Rockets, with bursting charge................................ 1.1F UN0180 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Rockets, with bursting charge................................ 1.1E UN0181 II EXPLOSIVE 1.1E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with bursting charge................................ 1.2E UN0182 II EXPLOSIVE 1.2E........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with bursting charge................................ 1.2F UN0295 II EXPLOSIVE 1.2F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Rockets, with expelling charge............................... 1.2C UN0436 II EXPLOSIVE 1.2C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with expelling charge............................... 1.3C UN0437 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rockets, with expelling charge............................... 1.4C UN0438 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Rockets, with inert head..................................... 1.3C UN0183 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Rosin oil.................................................... 3 UN1286 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Rubber solution.............................................. 3 UN1287 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Rubidium..................................................... 4.3 UN1423 I DANGEROUS WHEN WET.... 22, A7, A19, None 211 242 Forbidden.. 15 kg...... D......
B100, N34, N40,
N45.
....... Rubidium hydroxide........................................... 8 UN2678 II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... A......
....... Rubidium hydroxide solution.................................. 8 UN2677 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Safety fuse, see Fuse, safety................................ ........... .............. ...................... ................ ........... ........... .......
....... Samples, explosive, other than initiating explosives......... ........... UN0190 II ...................... 113............. None 62 None Forbidden.. Forbidden.. E...... 12E
....... Sand acid, see Fluorosilicic acid............................ ........... .............. ...................... ................ ........... ........... .......
....... Seed cake, containing vegetable oil solvent extractions and 4.2 UN1386 III None.................. N7.............. None 213 241 Forbidden.. Forbidden.. A...... 13
expelled seeds, with not more than 10 percent of oil and
when the amount of moisture is higher than 11 percent, with
not more than 20 percent of oil and moisture combined..
I...... Seed cake with more than 1.5 percent oil and not more than 11 4.2 UN1386 III None.................. N7.............. None 213 241 Forbidden.. Forbidden.. E...... 13
percent moisture.
I...... Seed cake with not more than 1.5 percent oil and not more 4.2 UN2217 III None.................. N7.............. None 213 241 Forbidden.. Forbidden.. A...... 13
than 11 percent moisture.
....... Selenates or Selenites....................................... 6.1 UN2630 I POISON................ ................ None 211 242 5 kg....... 50 kg...... E......
....... Selenic acid................................................. 8 UN1905 I CORROSIVE............. N34............. None 211 242 Forbidden.. 25 kg...... A......
....... Selenium compound, n.o.s..................................... 6.1 UN3283 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Selenium disulfide........................................... 6.1 UN2657 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Selenium hexafluoride........................................ 2.3 UN2194 POISON GAS, CORROSIVE. 1............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Selenium nitride............................................. Forbidden .............. ...................... ................ ........... ........... .......
D...... Selenium oxide............................................... 6.1 NA2811 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
....... Selenium oxychloride......................................... 8 UN2879 I CORROSIVE, POISON..... A3, A6, A7, N34, None 201 243 0.5 L...... 2.5 L...... E...... 40
T12, T27.
....... Selenium powder.............................................. 6.1 UN2658 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Self-heating liquid, corrosive, inorganic, n.o.s............. 4.2 UN3188 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating liquid, corrosive, organic, n.o.s............... 4.2 UN3185 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating liquid, inorganic, n.o.s........................ 4.2 UN3186 II SPONTANEOUSLY ................ None 202 242 1 L........ 5 L........ C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE.
....... Self-heating liquid, organic, n.o.s.......................... 4.2 UN3183 II SPONTANEOUSLY ................ None 202 242 1 L........ 5 L........ C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE.
....... Self-heating liquid, toxic, inorganic, n.o.s................. 4.2 UN3187 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-heating liquid, toxic, organic, n.o.s................... 4.2 UN3184 II SPONTANEOUSLY ................ None 202 243 1 L........ 5 L........ C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 203 241 5 L........ 60 L....... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-heating solid, corrosive, inorganic, n.o.s.............. 4.2 UN3192 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C.....
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating, solid, corrosive, organic, n.o.s............... 4.2 UN3126 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE,
CORROSIVE.
....... Self-heating solid, inorganic, n.o.s......................... 4.2 UN3190 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Self-heating, solid, organic, n.o.s.......................... 4.2 UN3088 II SPONTANEOUSLY B101............ None 212 241 15 kg...... 50 kg...... C......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY B101............ None 213 241 25 kg...... 100 kg..... C......
COMBUSTIBLE.
....... Self-heating, solid, oxidizing, n.o.s........................ 4.2 UN3127 SPONTANEOUSLY ................ None 214 214 Forbidden.. Forbidden.. .......
COMBUSTIBLE, OXIDIZER.
....... Self-heating solid, toxic, inorganic, n.o.s.................. 4.2 UN3191 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-heating, solid, toxic, organic, n.o.s................... 4.2 UN3128 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... C......
COMBUSTIBLE, POISON.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... C......
COMBUSTIBLE, KEEP
AWAY FROM FOOD.
....... Self-propelled vehicle, see Engines or Batteries etc......... ........... .............. ...................... ................ ........... ........... .......
....... Self-reactive liquid type B.................................. 4.1 UN3221 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 61
....... Self-reactive liquid type B, temperature controlled.......... 4.1 UN3231 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type C.................................. 4.1 UN3223 II FLAMMABLE SOLID....... ................ None 224 None 5 L........ 10 L....... D...... 61
....... Self-reactive liquid type C, temperature controlled.......... 4.1 UN3233 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type D.................................. 4.1 UN3225 II FLAMMABLE SOLID....... ................ None 224 None 5 L........ 10 L....... D...... 61
....... Self-reactive liquid type D, temperature controlled.......... 4.1 UN3235 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type E.................................. 4.1 UN3227 II FLAMMABLE SOLID....... ................ None 224 None 10 L....... 25 L....... D...... 61
....... Self-reactive liquid type E, temperature controlled.......... 4.1 UN3237 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive liquid type F.................................. 4.1 UN3229 II FLAMMABLE SOLID....... ................ None 224 None 10 L....... 25 L....... D...... 61
....... Self-reactive liquid type F, temperature controlled.......... 4.1 UN3239 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type B................................... 4.1 UN3222 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 61
....... Self-reactive solid type B, temperature controlled........... 4.1 UN3232 II FLAMMABLE SOLID....... 53.............. None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type C................................... 4.1 UN3224 II FLAMMABLE SOLID....... ................ None 224 None 5 kg....... 10 kg...... D...... 61
....... Self-reactive solid type C, temperature controlled........... 4.1 UN3234 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type D................................... 4.1 UN3226 II FLAMMABLE SOLID....... ................ None 224 None 5 kg....... 10 kg..... D...... 61
....... Self-reactive solid type D, temperature controlled........... 4.1 UN3236 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type E................................... 4.1 UN3228 II FLAMMABLE SOLID....... ................ None 224 None 10 kg...... 25 kg...... D...... 61
....... Self-reactive solid type E, temperature controlled........... 4.1 UN3238 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Self-reactive solid type F................................... 4.1 UN3230 II FLAMMABLE SOLID....... ................ None 224 None 10 kg...... 25 kg...... D...... 61
....... Self-reactive solid type F, temperature controlled........... 4.1 UN3240 II FLAMMABLE SOLID....... ................ None 224 None Forbidden.. Forbidden.. D...... 2, 61
....... Shale oil.................................................... 3 UN1288 I FLAMMABLE LIQUID...... T7.............. None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Shaped charges, commercial, see Charges, shaped, commercial ........... .............. ...................... ................ ........... ........... .......
etc..
....... Signal devices, hand......................................... 1.4G UN0191 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Signal devices, hand......................................... 1.4S UN0373 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Signals, distress, ship...................................... 1.1G UN0194 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, distress, ship...................................... 1.3G UN0195 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. 75 kg...... B......
....... Signals, highway, see Signal devices, hand; Fireworks, type D ........... .............. ...................... ................ ........... ........... .......
....... Signals, railway track, explosive............................ 1.1G UN0192 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, railway track, explosive............................ 1.4S UN0193 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A......
....... Signals, railway track, explosive............................ 1.3G UN0492 EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 8E
....... Signals, railway track, explosive............................ 1.4G UN0493 EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Signals, ship distress, water-activated, see Contrivances, ........... .............. ...................... ................ ........... ........... .......
water-activated, etc..
....... Signals, smoke............................................... 1.1G UN0196 II EXPLOSIVE 1.1G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, smoke............................................... 1.4G UN0197 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Signals, smoke............................................... 1.2G UN0313 II EXPLOSIVE 1.2G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Signals, smoke............................................... 1.3G UN0487 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Silane....................................................... 2.1 UN2203 FLAMMABLE GAS......... ................ None 302 None Forbidden.. Forbidden.. E...... 40, 57, 104
....... Silicofluoric acid, see Fluorosilicic acid................... ........... .............. ...................... ................ ........... ........... .......
....... Silicon chloride, see Silicon tetrachloride.................. ........... .............. ...................... ................ ........... ........... .......
....... Silicon powder, amorphous.................................... 4.1 UN1346 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... A......
....... Silicon tetrachloride........................................ 8 UN1818 II CORROSIVE............. A3, A6, B2, B6, 154 202 242 1 L........ 30 L....... C...... 40
T18, T26, T29.
....... Silicon tetrafluoride........................................ 2.3 UN1859 POISON GAS, CORROSIVE. 2, 25........... None 302 None Forbidden.. 25 kg...... D...... 40
....... Silver acetylide (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver arsenite.............................................. 6.1 UN1683 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Silver azide (dry)........................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver chlorite (dry)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Silver cyanide............................................... 6.1 UN1684 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26, 40
....... Silver fulminate (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver nitrate............................................... 5.1 UN1493 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A......
....... Silver oxalate (dry)......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver picrate (dry)......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Silver picrate, wetted with not less than 30 percent water, 4.1 UN1347 I FLAMMABLE SOLID....... ................ None 211 None Forbidden.. Forbidden.. D...... 28, 36
by mass.
....... Sludge, acid................................................. 8 UN1906 II CORROSIVE............. A3, A7, B2, N34, None 202 242 Forbidden.. 30 L....... C...... 14
T9, T27.
D...... Smokeless powder for small arms (100 pounds or less)......... 4.1 NA3178 I FLAMMABLE SOLID....... 16.............. None 171 None Forbidden.. Forbidden.. A......
....... Soda lime with more than 4 percent sodium hydroxide.......... 8 UN1907 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Sodium....................................................... 4.3 UN1428 I DANGEROUS WHEN WET.... A7, A8, A19, None 211 244 1 kg....... 15 kg...... D......
A20, B9, B48,
B68, N34, T15,
T29, T46.
....... Sodium aluminate, solid...................................... 8 UN2812 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Sodium aluminate, solution................................... 8 UN1819 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Sodium aluminum hydride...................................... 4.3 UN2835 II DANGEROUS WHEN WET.... A8, A19, A20, None 212 242 Forbidden.. 50 kg...... E......
B100.
....... Sodium ammonium vanadate..................................... 6.1 UN2863 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium arsanilate............................................ 6.1 UN2473 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Sodium arsenate.............................................. 6.1 UN1685 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium arsenite, aqueous solutions........................... 6.1 UN1686 II POISON................ T15............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T15............. 153 203 241 60 L....... 220 L...... A......
....... Sodium arsenite, solid....................................... 6.1 UN2027 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium azide................................................. 6.1 UN1687 II POISON................ B28............. None 212 242 25 kg...... 100 kg..... A...... 36, 52, 91
....... Sodium bifluoride, see Sodium hydrogendifluoride............. ........... .............. ...................... ................ ........... ........... .......
....... Sodium bisulfite, solution, see Bisulfites, aqueous ........... .............. ...................... ................ ........... ........... .......
solutions, n.o.s..
....... Sodium borohydride........................................... 4.3 UN1426 I DANGEROUS WHEN WET.... N40............. None 211 242 Forbidden.. 15 kg...... E......
....... Sodium bromate............................................... 5.1 UN1494 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium cacodylate............................................ 6.1 UN1688 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 26
....... Sodium chlorate.............................................. 5.1 UN1495 II OXIDIZER.............. A9, N34, T8..... 152 212 240 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium chlorate, aqueous solution............................ 5.1 UN2428 II OXIDIZER.............. A2, B6, T8...... 152 202 241 1 L........ 5 L........ B...... 56, 58, 106
....... Sodium chlorate mixed with dinitrotoluene, see Explosive ........... .............. ...................... ................ ........... ........... .......
blasting, type C.
....... Sodium chlorite.............................................. 5.1 UN1496 II OXIDIZER.............. A9, N34, T8..... None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium chloroacetate......................................... 6.1 UN2659 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Sodium cuprocyanide, solid................................... 6.1 UN2316 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 26
....... Sodium cuprocyanide, solution................................ 6.1 UN2317 I POISON................ T8, T26......... None 201 243 1 L........ 30 L....... B...... 26, 40
....... Sodium cyanide............................................... 6.1 UN1689 I POISON................ B69, B77, N74, None 211 242 5 kg....... 50 kg...... B...... 52
N75, T42.
....... Sodium dichloroisocyanurate or Sodium dichloro-s- ........... .............. ...................... ................ ........... ........... .......
triazinetrione, see Dichloroisocyanuric acid etc..
....... Sodium dinitro-o-cresolate, dry or wetted with less than 15 1.3C UN0234 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
percent water, by mass.
....... Sodium dinitro-o-cresolate, wetted with not less than 15 4.1 UN1348 I FLAMMABLE SOLID, 23, A8, A19, None 211 None 1 kg....... 15 kg...... E...... 28, 36
percent water, by mass. POISON. A20, N41.
....... Sodium dithionite or Sodium hydrosulfite..................... 4.2 UN1384 II SPONTANEOUSLY A19, A20, B106.. None 212 241 15 kg...... 50 kg...... E...... 13
COMBUSTIBLE.
....... Sodium fluoride.............................................. 6.1 UN1690 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 26
....... Sodium fluoroacetate......................................... 6.1 UN2629 I POISON................ ................ None 211 242 5 kg....... 50 kg...... E......
....... Sodium fluorosilicate........................................ 6.1 UN2674 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Sodium hydrate, see Sodium hydroxide, solid.................. ........... .............. ...................... ................ ........... ........... .......
....... Sodium hydride............................................... 4.3 UN1427 I DANGEROUS WHEN WET.... A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... E......
....... Sodium hydrogendifluoride.................................... 8 UN2439 II CORROSIVE............. B106, N3, N34... 154 212 240 15 kg...... 50 kg...... A...... 12, 25, 26,
40
....... Sodium hydrogendifluoride solution........................... 8 UN2439 II CORROSIVE............. N3, N34......... 154 202 242 1 L........ 30 L....... A...... 12, 25, 26,
40
D...... Sodium hydrosulfide, solution................................ 8 NA2922 II CORROSIVE, POISON..... B2.............. 154 202 243 1 L........ 30 L....... B...... 40, 95
....... Sodium hydrosulfide, with less than 25 percent water of 4.2 UN2318 II SPONTANEOUSLY A7, A19, A20.... None 212 241 15 kg...... 50 kg...... A......
crystallization. COMBUSTIBLE.
....... Sodium hydrosulfide with not less than 25 percent water of 8 UN2949 II CORROSIVE............. A7.............. 154 212 240 15 kg...... 50 kg...... A...... 26
crystallization.
....... Sodium hydrosulfite, see Sodium dithionite................... ........... .............. ...................... ................ ........... ........... .......
....... Sodium hydroxide, solid...................................... 8 UN1823 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Sodium hydroxide solution.................................... 8 UN1824 II CORROSIVE............. B2, N34, T8..... 154 202 242 1 L........ 30 L....... A......
............................................................. ........... .............. III CORROSIVE............. N34, T7......... 154 203 241 5 L........ 60 L....... A......
....... Sodium hypochlorite, solution, see Hypochlorite solutions ........... .............. ...................... ................ ........... ........... .......
etc..
....... Sodium metal, liquid alloy, see Alkali metal alloys, liquid, ........... .............. ...................... ................ ........... ........... .......
n.o.s..
....... Sodium methylate............................................. 4.2 UN1431 II SPONTANEOUSLY A19............. None 212 242 15 kg...... 50 kg...... B......
COMBUSTIBLE,
CORROSIVE.
....... Sodium methylate solutions in alcohol........................ 3 UN1289 II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 5 L........ B......
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1, T7, T30..... 150 203 242 5 L........ 60 L....... A......
CORROSIVE.
....... Sodium monoxide.............................................. 8 UN1825 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
....... Sodium nitrate............................................... 5.1 UN1498 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Sodium nitrate and potassium nitrate mixtures................ 5.1 UN1499 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Sodium nitrite............................................... 5.1 UN1500 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A...... 56, 58
....... Sodium pentachlorophenate.................................... 6.1 UN2567 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Sodium percarbonate.......................................... 5.1 UN2467 III OXIDIZER.............. 27, A1, A29..... 152 213 240 25 kg...... 100 kg..... A...... 13
....... Sodium perchlorate........................................... 5.1 UN1502 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Sodium permanganate.......................................... 5.1 UN1503 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Sodium peroxide.............................................. 5.1 UN1504 I OXIDIZER.............. A20, N34........ None 211 None Forbidden.. 15 kg...... B...... 13, 75, 106
....... Sodium peroxoborate, anhydrous............................... 5.1 UN3247 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 13, 25, 106
....... Sodium persulfate............................................ 5.1 UN1505 III OXIDIZER.............. A1.............. 152 213 240 25 kg...... 100 kg..... A......
....... Sodium phosphide............................................. 4.3 UN1432 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Sodium picramate, dry or wetted with less than 20 percent 1.3C UN0235 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Sodium picramate, wetted with not less than 20 percent water, 4.1 UN1349 I FLAMMABLE SOLID....... 23, A8, A19, N41 None 211 None Forbidden.. 15 kg...... E...... 28, 36
by mass.
....... Sodium picryl peroxide....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Sodium potassium alloys, see Potassium sodium alloys......... ........... .............. ...................... ................ ........... ........... .......
....... Sodium salts of aromatic nitro-derivatives, n.o.s. explosive. 1.3C UN0203 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Sodium selenate, see Selenates or Selenites.................. ........... .............. ...................... ................ ........... ........... .......
D...... Sodium selenite.............................................. 6.1 NA2630 II POISON................ ................ None 212 242 25 kg...... 100 kg..... E......
....... Sodium sulfide, anhydrous or Sodium sulfide with less than 30 4.2 UN1385 II SPONTANEOUSLY A19, A20, B106, None 212 241 15 kg...... 50 kg...... A......
percent water of crystallization. COMBUSTIBLE. N34.
....... Sodium sulfide, hydrated with not less than30 percent water.. 8 UN1849 II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... A...... 26
....... Sodium superoxide............................................ 5.1 UN2547 I OXIDIZER.............. A20, N34........ None 211 None Forbidden.. 15 kg...... E...... 13, 75, 106
....... Sodium tetranitride.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Solids containing corrosive liquid, n.o.s.................... 8 UN3244 II CORROSIVE............. 49.............. 154 212 240 15 kg...... 50 kg...... B...... 40
....... Solids containing flammable liquid, n.o.s.................... 4.1 UN3175 II FLAMMABLE SOLID....... 47.............. 151 212 240 15 kg...... 50 kg...... B......
....... Solids containing toxic liquid, n.o.s........................ 6.1 UN3243 II POISON................ 48.............. None 212 240 25 kg...... 100 kg..... B...... 40
....... Sounding devices, explosive.................................. 1.2F UN0204 II EXPLOSIVE 1.2F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Sounding devices, explosive.................................. 1.1F UN0296 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Sounding devices, explosive.................................. 1.1D UN0374 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Sounding devices, explosive.................................. 1.2D UN0375 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Spirits of salt, see Hydrochloric acid....................... ........... .............. ...................... ................ ........... ........... .......
....... Squibs, see Igniters etc..................................... ........... .............. ...................... ................ ........... ........... .......
....... Stannic chloride, anhydrous.................................. 8 UN1827 II CORROSIVE............. B2, T8, T26..... 154 202 242 1 L........ 30 L....... C......
....... Stannic chloride, pentahydrate............................... 8 UN2440 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
....... Stannic phosphide............................................ 4.3 UN1433 I DANGEROUS WHEN WET, A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Steel swarf, see Ferrous metal borings, etc.................. ........... .............. ...................... ................ ........... ........... .......
....... Stibine...................................................... 2.3 UN2676 POISON GAS, FLAMMABLE 1............... None 304 None Forbidden.. Forbidden.. D...... 40
GAS.
....... Storage batteries, wet, see Batteries, wet etc............... ........... .............. ...................... ................ ........... ........... .......
....... Strontium arsenite........................................... 6.1 UN1691 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Strontium chlorate........................................... 5.1 UN1506 II OXIDIZER.............. A1, A9, N34..... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Strontium nitrate............................................ 5.1 UN1507 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Strontium perchlorate........................................ 5.1 UN1508 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Strontium peroxide........................................... 5.1 UN1509 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Strontium phosphide.......................................... 4.3 UN2013 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Strychnine or Strychnine salts............................... 6.1 UN1692 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
....... Styphnic acid, see Trinitroresorcinol, etc................... ........... .............. ...................... ................ ........... ........... .......
....... Styrene monomer, inhibited................................... 3 UN2055 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Substances, explosive, n.o.s................................. 1.1L UN0357 II EXPLOSIVE 1.1L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Substances, explosive, n.o.s................................. 1.2L UN0358 II EXPLOSIVE 1.2L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Substances, explosive, n.o.s................................. 1.3L UN0359 II EXPLOSIVE 1.3L........ 101............. None 62 None Forbidden.. Forbidden.. E...... 2E, 8E,
11E, 17E
....... Substances, explosive, n.o.s................................. 1.1A UN0473 II EXPLOSIVE 1.1A........ 101, 111........ None 62 None Forbidden.. Forbidden.. E...... 2E, 6E
....... Substances, explosive, n.o.s................................. 1.1C UN0474 II EXPLOSIVE 1.1C........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.1D UN0475 II EXPLOSIVE 1.1D........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.1G UN0476 II EXPLOSIVE 1.1G........ 101............. None 62 None Forbidden.. Forbidden.. E...... 1E, 8E
....... Substances, explosive, n.o.s................................. 1.3C UN0477 II EXPLOSIVE 1.3C........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.3G UN0478 II EXPLOSIVE 1.3G........ 101............. None 62 None Forbidden.. Forbidden.. E...... 1E, 8E
....... Substances, explosive, n.o.s................................. 1.4C UN0479 II EXPLOSIVE 1.4C........ 101............. None 62 None Forbidden.. 75 kg...... A...... 1E, 5E
....... Substances, explosive, n.o.s................................. 1.4D UN0480 II EXPLOSIVE 1.4D........ 101............. None 62 None Forbidden.. 75 kg...... A...... 1E, 5E, 24E
....... Substances, explosive, n.o.s................................. 1.4S UN0481 II EXPLOSIVE 1.4S........ 101............. None 62 None 25 kg...... 75 kg...... A......
....... Substances, explosive, n.o.s................................. 1.4G UN0485 II EXPLOSIVE 1.4G........ 101............. None 62 None Forbidden.. 75 kg...... E...... 1E, 8E
....... Substances, explosive, very insensitive, n.o.s., or 1.5D UN0482 II EXPLOSIVE 1.5D........ 101............. None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Substances, EVI, n.o.s..
....... Substituted nitrophenol pesticides, liquid, flammable, toxic, 3 UN2780 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
flash point less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Substituted nitrophenol pesticides, liquid, toxic............ 6.1 UN3014 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Substituted nitrophenol pesticides, liquid, toxic, flammable 6.1 UN3013 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
flashpoint not less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, B1, T14......... 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Substituted nitrophenol pesticides, solid, toxic............. 6.1 UN2779 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Sucrose octanitrate (dry).................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Sulfamic acid................................................ 8 UN2967 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
D...... Sulfur....................................................... 9 NA1350 III CLASS 9............... 30, A1.......... None None 240 25 kg...... 100 kg..... A...... 19, 74
I...... Sulfur....................................................... 4.1 UN1350 III FLAMMABLE SOLID....... A1, N20, T1..... 151 213 240 25 kg...... 100 kg..... A...... 19, 74
....... Sulfur and chlorate, loose mixtures of....................... Forbidden .............. ...................... ................ ........... ........... .......
....... Sulfur chlorides............................................. 8 UN1828 I CORROSIVE............. 5, A3, B10, B77, None 201 243 Forbidden.. 2.5 L...... C...... 40
N34.
....... Sulfur dichloride, see Sulfur chlorides...................... ........... .............. ...................... ................ ........... ........... .......
....... Sulfur dioxide, liquefied.................................... 2.3 UN1079 POISON GAS, CORROSIVE. 3, B14.......... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Sulfur dioxide solution, see Sulfurous acid.................. ........... .............. ...................... ................ ........... ........... .......
....... Sulfur hexafluoride.......................................... 2.2 UN1080 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Sulfur, molten............................................... 9 NA2448 III CLASS 9............... T9, T38......... None 213 247 Forbidden.. Forbidden.. C...... 61
I...... Sulfur, molten............................................... 4.1 UN2448 III FLAMMABLE SOLID....... T9, T38......... None 213 247 Forbidden.. Forbidden.. C...... 61
....... Sulfur tetrafluoride......................................... 2.3 UN2418 POISON GAS, CORROSIVE. 1............... None 302 245 Forbidden.. 25 kg...... D...... 40
+...... Sulfur trioxide, inhibited................................... 8 UN1829 I CORROSIVE, POISON..... 2, A7, B9, B12, None 227 244 Forbidden.. 25 kg...... A...... 40
B14, B32, B49,
B74, B77, N34,
T38, T43, T45.
+, D... Sulfur trioxide, uninhibited................................. 8 NA1829 I CORROSIVE, POISON..... 2, A7, B9, B12, None 227 244 Forbidden.. 25 kg...... C...... 10, 40
B14, B32, B49,
B74, B77, N34,
T38, T43, T45.
....... Sulfuretted hydrogen, see Hydrogen sulfide, liquefied........ ........... .............. ...................... ................ ........... ........... .......
....... Sulfuric acid, fuming with less than 30 percent free sulfur 8 UN1831 I CORROSIVE............. A3, A7, B84, None 201 243 Forbidden.. 2.5 L...... C...... 14, 40
trioxide. N34, T18, T27.
+...... Sulfuric acid, fuming with 30 percent or more free sulfur 8 UN1831 I CORROSIVE, POISON..... 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. C...... 14, 40
trioxide. B9, B14, B32,
B74, B77, B84,
N34, T38, T43,
T45.
....... Sulfuric acid, spent......................................... 8 UN1832 II CORROSIVE............. A3, A7, B2, B83, None 202 242 Forbidden.. 30 L....... C...... 14
B84, N34, T9,
T27.
....... Sulfuric acid with more than 51 percent acid................. 8 UN1830 II CORROSIVE............. A3, A7, B3, B83, 154 202 242 1 L........ 30 L....... C...... 14
B84, N34, T9,
T27.
....... Sulfuric acid with not more than 51% acid.................... 8 UN2796 II CORROSIVE............. A3, A7, B2, B15, 154 202 242 1 L........ 30 L....... B......
N6, N34, T9,
T27.
....... Sulfuric and hydrofluoric acid mixtures, see Hydrofluoric and ........... .............. ...................... ................ ........... ........... .......
sulfuric acid mixtures.
....... Sulfuric anhydride, see Sulfur trioxide, inhibited........... ........... .............. ...................... ................ ........... ........... .......
....... Sulfurous acid............................................... 8 UN1833 II CORROSIVE............. B3, T8.......... 154 202 242 1 L........ 30 L....... B...... 40
+...... Sulfuryl chloride............................................ 8 UN1834 I CORROSIVE, POISON..... 1, A3, B6, B9, None 226 244 Forbidden.. Forbidden.. C...... 40
B10, B14, B30,
B74, B77, N34,
T38, T43, T44.
....... Sulfuryl fluoride............................................ 2.3 UN2191 POISON GAS............ 4............... None 304 314, 315 Forbidden.. 25 kg...... D...... 40
....... Tars, liquid including road asphalt and oils, bitumen and cut 3 UN1999 II FLAMMABLE LIQUID...... B13, T7, T30.... 150 202 242 5 L........ 60 L....... B......
backs.
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B13, T7, T30 150 203 242 60 L....... 220 L...... A......
....... Tear gas candles............................................. 6.1 UN1700 II POISON, FLAMMABLE ................ None 340 None Forbidden.. 50 kg...... D...... 40
SOLID.
....... Tear gas cartridges, see Ammunition, tear-producing, etc..... ........... .............. ...................... ................ ........... ........... .......
D...... Tear gas devices with more than 2 percent tear gas 6.1 NA1693 I POISON................ ................ None 340 None Forbidden.. Forbidden.. D...... 40
substances, by mass.
............................................................. ........... .............. II POISON................ ................ None 340 None Forbidden.. Forbidden.. D...... 40
....... Tear gas devices, with not more than 2 percent tear gas ........... .............. ...................... ................ ........... ........... .......
substances, by mass, see Aerosols, etc..
....... Tear gas grenades, see Tear gas candles...................... ........... .............. ...................... ................ ........... ........... .......
....... Tear gas substances, liquid, n.o.s........................... 6.1 UN1693 I POISON................ ................ None 201 None Forbidden.. Forbidden.. D...... 40
............................................................. ........... .............. II POISON................ ................ None 202 None Forbidden.. 5 L........ D...... 40
....... Tear gas substances, solid, n.o.s............................ 6.1 UN1693 I POISON................ ................ None 211 None Forbidden.. Forbidden.. D...... 40
............................................................. ........... .............. II POISON................ ................ None 212 None Forbidden.. 25 kg...... D...... 40
....... Tellurium compound, n.o.s.................................... 6.1 UN3284 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Tellurium hexafluoride....................................... 2.3 UN2195 POISON GAS, CORROSIVE. 1............... None 302 None Forbidden.. Forbidden.. D...... 40
....... Terpene hydrocarbons, n.o.s.................................. 3 UN2319 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Terpinolene.................................................. 3 UN2541 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetraazido benzene quinone................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetrabromoethane............................................. 6.1 UN2504 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Tetrachloroethane............................................ 6.1 UN1702 II POISON................ N36, T14........ None 202 243 5 L........ 60 L....... A...... 40
....... Tetrachloroethylene.......................................... 6.1 UN1897 III KEEP AWAY FROM FOOD... N36, T1......... 153 203 241 60 L....... 220 L...... A...... 40
....... Tetraethyl dithiopyrophosphate............................... 6.1 UN1704 II POISON................ ................ None 212 242 25 kg...... 100 kg..... D...... 40
D...... Tetraethyl lead, liquid...................................... 6.1 NA1649 I POISON, FLAMMABLE ................ None 201 None Forbidden.. Forbidden.. E...... 40
LIQUID.
D...... Tetraethyl pyrophosphate, liquid............................. 6.1 NA3018 I POISON................ ................ None 201 243 Forbidden.. 1 L........ A...... 40
D...... Tetraethyl pyrophosphate solid............................... 6.1 NA2783 I POISON................ N77............. None 211 242 Forbidden.. 50 kg...... A...... 40
....... Tetraethyl silicate.......................................... 3 UN1292 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetraethylammonium perchlorate (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetraethylenepentamine....................................... 8 UN2320 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... 1,1,1,2-Tetrafluoroethane.................................... 2.2 UN3159 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
....... Tetrafluoroethylene, inhibited............................... 2.1 UN1081 FLAMMABLE GAS......... ................ 306 304 None Forbidden.. 150 kg..... E...... 40
....... Tetrafluoromethane, R14...................................... 2.2 UN1982 NONFLAMMABLE GAS...... ................ None 302 None 75 kg...... 150 kg..... A......
....... 1,2,3,6-Tetrahydrobenzaldehyde............................... 3 UN2498 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetrahydrofuran.............................................. 3 UN2056 II FLAMMABLE LIQUID...... T8.............. None 202 242 5 L........ 60 L....... B......
....... Tetrahydrofurfurylamine...................................... 3 UN2943 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tetrahydrophthalic anhydrides with more than 0.05 percent of 8 UN2698 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
maleic anhydride.
....... 1,2,3,6-Tetrahydropyridine................................... 3 UN2410 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Tetrahydrothiophene.......................................... 3 UN2412 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Tetramethylammonium hydroxide................................ 8 UN1835 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... A......
....... Tetramethylene diperoxide dicarbamide........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Tetramethylsilane............................................ 3 UN2749 I FLAMMABLE LIQUID...... T21, T26........ None 201 243 Forbidden.. 30 L....... D......
....... Tetranitro diglycerin........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Tetranitroaniline............................................ 1.1D UN0207 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
+...... Tetranitromethane............................................ 5.1 UN1510 I OXIDIZER, POISON...... 2, B9, B14, B32, None 227 None Forbidden.. Forbidden.. D...... 40, 66, 106
B74, T38, T43,
T45.
....... 2,3,4,6-Tetranitrophenol..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,4,6-Tetranitrophenyl methyl nitramine.................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,4,6-Tetranitrophenylnitramine............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Tetranitroresorcinol (dry)................................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,5,6-Tetranitroso-1,4-dinitrobenzene...................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,3,5,6-Tetranitroso nitrobenzene (dry)...................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetrapropylorthotitanate..................................... 3 UN2413 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Tetrazene, see Guanyl nitrosaminoguanyltetrazene............. ........... .............. ...................... ................ ........... ........... .......
....... Tetrazine (dry).............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Tetrazol-1-acetic acid....................................... 1.4C UN0407 II EXPLOSIVE 1.4C........ ................ None 62 None Forbidden.. 75 kg...... A...... 1E, 5E, 24E
....... Tetrazolyl azide (dry)....................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Tetryl, see Trinitrophenylmethylnitramine.................... ........... .............. ...................... ................ ........... ........... .......
....... Thallium chlorate............................................ 5.1 UN2573 II OXIDIZER, POISON...... ................ None 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Thallium compounds, n.o.s.................................... 6.1 UN1707 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Thallium nitrate............................................. 6.1 UN2727 II POISON, OXIDIZER...... ................ None 212 242 5 kg....... 25 kg...... A......
D...... Thallium sulfate, solid...................................... 6.1 NA1707 II POISON................ ................ None 212 242 5 kg....... 50 kg...... A......
....... 4-Thiapentanal............................................... 6.1 UN2785 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... D...... 25, 49
....... Thioacetic acid.............................................. 3 UN2436 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Thiocarbonylchloride, see Thiophosgene....................... ........... .............. ...................... ................ ........... ........... .......
....... Thioglycol................................................... 6.1 UN2966 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
....... Thioglycolic acid............................................ 8 UN1940 II CORROSIVE............. A7, B2, N34, T8. 154 202 242 1 L........ 30 L....... A......
....... Thiolactic acid.............................................. 6.1 UN2936 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... A......
....... Thionyl chloride............................................. 8 UN1836 I CORROSIVE............. A7, B6, B10, None 201 243 Forbidden.. Forbidden.. C...... 40
N34, T42.
....... Thiophene.................................................... 3 UN2414 II FLAMMABLE LIQUID...... B101, T2........ 150 202 242 5 L........ 60 L....... B...... 40
+...... Thiophosgene................................................. 6.1 UN2474 II POISON................ 2, A7, B9, B14, None 227 244 Forbidden.. 60 L....... B...... 26, 40
B32, B74, N33,
N34, T38, T43,
T45.
....... Thiophosphoryl chloride...................................... 8 UN1837 II CORROSIVE............. A3, A7, B2, B8, None 202 242 Forbidden.. 30 L....... C...... 40
B25, B101, N34,
T12.
....... Thorium metal, pyrophoric.................................... 7 UN2975 RADIOACTIVE, ................ None 418 None Forbidden.. Forbidden.. D......
SPONTANEOUSLY
COMBUSTIBLE.
....... Thorium nitrate, solid....................................... 7 UN2976 RADIOACTIVE, OXIDIZER. ................ None 419 None Forbidden.. 15 kg...... A......
....... Tin chloride, fuming, see Stannic chloride, anhydrous........ ........... .............. ...................... ................ ........... ........... .......
....... Tin perchloride or Tin tetrachloride, see Stannic chloride, ........... .............. ...................... ................ ........... ........... .......
anhydrous.
....... Tinctures, medicinal......................................... 3 UN1293 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Tinning flux, see Zinc chloride.............................. ........... .............. ...................... ................ ........... ........... .......
....... Titanium disulphide.......................................... 4.2 UN3174 III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... A......
COMBUSTIBLE.
....... Titanium hydride............................................. 4.1 UN1871 II FLAMMABLE SOLID....... A19, A20, N34... None 212 241 15 kg...... 50 kg...... E......
....... Titanium powder, dry......................................... 4.2 UN2546 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY A19, A20, N5, None 212 241 15 kg...... 50 kg...... D......
COMBUSTIBLE. N34.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Titanium powder, wetted with not less than 25 percent water 4.1 UN1352 II FLAMMABLE SOLID....... A19, A20, N34... None 212 240 15 kg...... 50 kg...... E......
(a visible excess of water must be present) (a) mechanically
produced, particle size less than 53 microns; (b) chemically
produced, particle size less than 840 microns.
....... Titanium sponge granules or Titanium sponge powders.......... 4.1 UN2878 III FLAMMABLE SOLID....... A1.............. None 213 240 25 kg...... 100 kg..... D......
D...... Titanium sulfate solution.................................... 8 NA1760 II CORROSIVE............. B2, B15......... None 202 242 1 L........ 30 L....... B...... 40
+...... Titanium tetrachloride....................................... 8 UN1838 II CORROSIVE, POISON..... 2, A3, A6, B7, None 227 244 Forbidden.. 30 L....... C...... 40
B9, B14, B32,
B41, B74, B77,
N41, T38, T43,
T45.
....... Titanium trichloride mixtures................................ 8 UN2869 II CORROSIVE............. A7, B106, N34... 154 212 240 15 kg...... 50 kg...... A...... 40
............................................................. ........... .............. III CORROSIVE............. A7, N34......... 154 213 240 25 kg...... 100 kg..... A...... 40
....... Titanium trichloride, pyrophoric or Titanium trichloride 4.2 UN2441 I SPONTANEOUSLY A7, A8, A19, None 181 244 Forbidden.. Forbidden.. D...... 40
mixtures, pyrophoric. COMBUSTIBLE, A20, N34.
CORROSIVE.
....... TNT mixed with aluminum, see Tritonal........................ ........... .............. ...................... ................ ........... ........... .......
....... TNT, see Trinitrotoluene, etc................................ ........... .............. ...................... ................ ........... ........... .......
....... Toluene...................................................... 3 UN1294 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Toluene diisocyanate......................................... 6.1 UN2078 II POISON................ B110, T14....... None 202 243 5 L........ 60 L....... D...... 25, 40
....... Toluene sulfonic acid, see Alkyl, orAryl sulfonic acid etc... ........... .............. ...................... ................ ........... ........... .......
....... Toluidines liquid............................................ 6.1 UN1708 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Toluidines solid............................................. 6.1 UN1708 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... 2,4-Toluylenediamine or 2,4-Toluenediamine................... 6.1 UN1709 III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Torpedoes, liquid fueled, with inert head.................... 1.3J UN0450 II EXPLOSIVE 1.3J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Torpedoes, liquid fueled, with or without bursting charge.... 1.1J UN0449 II EXPLOSIVE 1.1J........ ................ 62 None Forbidden.. Forbidden.. E...... 7E, 16E,
23E
....... Torpedoes with bursting charge............................... 1.1E UN0329 II EXPLOSIVE 1.1E........ ................ 62 None Forbidden.. Forbidden.. B......
....... Torpedoes with bursting charge............................... 1.1F UN0330 II EXPLOSIVE 1.1F........ ................ 62 None Forbidden.. Forbidden.. B......
....... Torpedoes with bursting charge............................... 1.1D UN0451 II EXPLOSIVE 1.1D........ ................ 62 None Forbidden.. Forbidden.. B......
....... Toxic liquid, corrosive, inorganic, n.o.s.................... 6.1 UN3289 I POISON, CORROSIVE..... T42............. None 201 243 0.5 L...... 2.5 L...... A......
............................................................. ........... .............. II POISON, CORROSIVE..... T14............. None 202 243 1 L........ 30 L....... A......
....... Toxic liquid, corrosive, inorganic, n.o.s. Inhalation Hazard, 6.1 UN3289 I POISON, CORROSIVE..... 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. B...... 40
Packing Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquid, corrosive, inorganic, n.o.s. Inhalation Hazard, 6.1 UN3289 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
Packing Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquid, inorganic, n.o.s............................... 6.1 UN3287 I POISON................ T42............. None 201 243 1 L........ 30 L....... A......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Toxic liquid, inorganic, n.o.s. Inhalation Hazard, Packing 6.1 UN3287 I POISON................ 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. B...... 40
Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquid, inorganic, n.o.s. Inhalation Hazard, Packing 6.1 UN3287 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. B...... 40
Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquids, corrosive, organic, n.o.s..................... 6.1 UN2927 I POISON, CORROSIVE..... T42............. None 201 243 0.5 L...... 2.5 L...... B...... 40
............................................................. ........... .............. II POISON, CORROSIVE..... T42............. None 202 243 1 L........ 30 L....... B...... 40
....... Toxic liquids, corrosive, organic, n.o.s., inhalation hazard, 6.1 UN2927 I POISON, CORROSIVE..... 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquids, corrosive, organic, n.o.s., inhalation hazard, 6.1 UN2927 I POISON, CORROSIVE..... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquids, flammable, organic, n.o.s..................... 6.1 UN2929 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T15............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Toxic liquids, flammable, organic, n.o.s., inhalation hazard, 6.1 UN2929 I POISON, FLAMMABLE 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone A. LIQUID. B72, T38, T43,
T44.
....... Toxic liquids, flammable, organic, n.o.s., inhalation hazard, 6.1 UN2929 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Packing Group I, Zone B. LIQUID. B74, T38, T43,
T45.
....... Toxic, liquids, organic, n.o.s............................... 6.1 UN2810 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A...... 40
....... Toxic, liquids, organic, n.o.s. Inhalation hazard, Packing 6.1 UN2810 I POISON................ 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Group I, Zone A. B72, T38, T43,
T44.
....... Toxic, liquids, organic, n.o.s. Inhalation hazard, Packing 6.1 UN2810 I POISON................ 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 20, 40, 95
Group I, Zone B. B74, T38, T43,
T45.
....... Toxic liquids, oxidizing, n.o.s.............................. 6.1 UN3122 I POISON, OXIDIZER...... A4.............. None 201 243 Forbidden.. 2.5 L...... C......
............................................................. ........... .............. II POISON, OXIDIZER...... ................ None 202 243 1 L........ 5 L........ C......
....... Toxic liquids, oxidizing, n.o.s. Inhalation hazard, Packing 6.1 UN3122 I POISON, OXIDIZER...... 1, B9, B14, B30, None 226 244 Forbidden.. 2.5 L...... C......
Group I, Zone A. B72, T38, T43,
T44.
....... Toxic liquids, oxidizing, n.o.s. Inhalation Hazard, Packing 6.1 UN3122 I POISON, OXIDIZER...... 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. C......
Group I, Zone B. T38, T43, T45.
....... Toxic liquids, water-reative, n.o.s.......................... 6.1 UN3123 I POISON, DANGEROUS WHEN A4.............. None 201 243 Forbidden.. 1 L........ E...... 40
WET.
............................................................. ........... .............. II POISON, DANGEROUS WHEN ................ None 202 243 1 L........ 5 L........ E...... 40
WET.
....... Toxic liquids, water-reative, n.o.s. Inhalation hazard, 6.1 UN3123 I POISON, DANGEROUS WHEN 1, B9, B14, B30, None 226 244 Forbidden.. Forbidden.. E...... 40
packing group I, Zone A. WET. B72, T38, T43,
T44.
....... Toxic liquids, water-reative, n.o.s. Inhalation hazard, 6.1 UN3123 I POISON, DANGEROUS WHEN 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. E...... 40
packing group I, Zone B. WET. B74, T38, T43,
T45.
....... Toxic solid, corrosive, inorganic, n.o.s..................... 6.1 UN3290 I POISON, CORROSIVE..... ................ None 211 242 1 kg....... 25 kg...... A......
............................................................. ........... .............. II POISON, CORROSIVE..... ................ None 212 242 15 kg...... 50 kg...... A......
....... Toxic solid, inorganic, n.o.s................................ 6.1 UN3288 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Toxic solids, corrosive, organic, n.o.s...................... 6.1 UN2928 I POISON, CORROSIVE..... ................ None 211 242 1 kg....... 25 kg...... B...... 40
............................................................. ........... .............. II POISON, CORROSIVE..... ................ None 212 242 15 kg...... 50 kg...... B...... 40
....... Toxic solids, flammable, organic, n.o.s...................... 6.1 UN2930 I POISON, FLAMMABLE B106............ None 211 242 1 kg....... 15 kg...... B......
SOLID.
............................................................. ........... .............. II POISON, FLAMMABLE B106............ None 212 242 15 kg...... 50 kg...... B......
SOLID.
....... Toxic solids, organic, n.o.s................................. 6.1 UN2811 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Toxic solids, oxidizing, n.o.s............................... 6.1 UN3086 I POISON, OXIDIZER...... ................ None 211 242 1 kg....... 15 kg...... C......
............................................................. ........... .............. II POISON, OXIDIZER...... ................ None 212 242 15 kg...... 50 kg...... C......
....... Toxic solids, self-heating, n.o.s............................ 6.1 UN3124 I POISON, SPONTANEOUSLY A5, B100........ None 211 242 5 kg....... 15 kg...... D...... 40
COMBUSTIBLE.
............................................................. ........... .............. II POISON, SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... D...... 40
COMBUSTIBLE.
....... Toxic solids, water-reative, n.o.s........................... 6.1 UN3125 I POISON, DANGEROUS WHEN A5, B100........ None 211 242 5 kg....... 15 kg...... D...... 40
WET.
............................................................. ........... .............. II POISON, DANGEROUS WHEN B101............ None 212 242 15 kg...... 50 kg...... D...... 40
WET.
D...... Toy Caps..................................................... 1.4S NA0337 II EXPLOSIVE 1.4S........ ................ None 62 None 25 kg...... 100 kg..... A...... 9E
....... Tracers for ammunition....................................... 1.3G UN0212 II EXPLOSIVE 1.3G........ ................ None 62 None Forbidden.. Forbidden.. B......
....... Tracers for ammunition....................................... 1.4G UN0306 II EXPLOSIVE 1.4G........ ................ None 62 None Forbidden.. 75 kg...... A...... 24E
....... Tractors, see Vehicles, self propelled....................... ........... .............. ...................... ................ ........... ........... .......
....... Tri-(b-nitroxyethyl) ammonium nitrate........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Triallyl borate.............................................. 6.1 UN2609 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A...... 13
....... Triallylamine................................................ 3 UN2610 III FLAMMABLE LIQUID, B1, T1.......... None 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Triazine pesticides, liquid, flammable, toxic, flash point 3 UN2764 I FLAMMABLE LIQUID, ................ None 201 243 Forbidden.. 30 L....... B...... 40
less than 23 degrees C. POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1.............. 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Triazine pesticides, liquid, toxic........................... 6.1 UN2998 I POISON................ T42............. None 201 243 1 L........ 30 L....... B...... 40
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T14............. 153 203 241 60 L....... 220 L...... A...... 40
....... Triazine pesticides, liquid, toxic, flammable, flashpoint not 6.1 UN2997 I POISON, FLAMMABLE T42............. None 201 243 1 L........ 30 L....... B...... 40
less than 23 degrees C. LIQUID.
............................................................. ........... .............. II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
............................................................. ........... .............. III KEEP AWAY FROM FOOD, T14............. 153 203 242 60 L....... 220 L...... A...... 40
FLAMMABLE LIQUID.
....... Triazine pesticides, solid, toxic............................ 6.1 UN2763 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 40
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 40
....... Tributylamine................................................ 8 UN2542 III CORROSIVE............. T2.............. None 203 241 5 L........ 60 L....... A......
....... Tributylphosphane............................................ 4.2 UN3254 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
D...... mono-(Trichloro) tetra-(monopotassium dichloro)-penta-s- 5.1 NA2468 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 13
triazinetrione, dry (with more than 39 percent available
chlorine).
....... Trichloro-s-triazinetrione dry, with more than 39 percent ........... .............. ...................... ................ ........... ........... .......
available chlorine, see Trichloroisocyanuric acid, dry.
....... Trichloroacetic acid......................................... 8 UN1839 II CORROSIVE............. A7, N34......... 154 212 240 15 kg...... 50 kg...... A......
....... Trichloroacetic acid, solution............................... 8 UN2564 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 1 L........ 30 L....... B......
N34, T8.
............................................................. ........... .............. III CORROSIVE............. A3, A6, A7, N34, 154 203 241 5 L........ 60 L....... B...... 8
T7.
+...... Trichloroacetyl chloride..................................... 8 UN2442 II CORROSIVE, POISON..... 2, A3, A7, B9, None 227 244 Forbidden.. Forbidden.. D...... 40
B14, B32, B74,
N34, T38, T43,
T45.
....... Trichlorobenzenes, liquid.................................... 6.1 UN2321 III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Trichlorobutene.............................................. 6.1 UN2322 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 25, 40
....... 1,1,1-Trichloroethane........................................ 6.1 UN2831 III KEEP AWAY FROM FOOD... N36, T7......... 153 203 241 60 L....... 220 L...... A...... 40
....... Trichloroethylene............................................ 6.1 UN1710 III KEEP AWAY FROM FOOD... N36, T1......... 153 203 241 60 L....... 220 L...... A...... 40
....... Trichloroisocyanuric acid, dry............................... 5.1 UN2468 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A...... 13
....... Trichloromethyl perchlorate.................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trichlorosilane.............................................. 4.3 UN1295 I DANGEROUS WHEN WET, A7, N34, T24, None 201 244 Forbidden.. Forbidden.. D...... 21, 28, 40,
FLAMMABLE LIQUID, T26. 49, 100
CORROSIVE.
....... Tricresyl phosphate with more than 3 percent ortho isomer.... 6.1 UN2574 II POISON................ A3, N33, N34, T8 None 202 243 5 L........ 60 L....... A......
....... Triethyl phosphite........................................... 3 UN2323 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Triethylamine................................................ 3 UN1296 II FLAMMABLE LIQUID, B101, T8........ None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE.
....... Triethylenetetramine......................................... 8 UN2259 II CORROSIVE............. B2, T8.......... 154 202 242 1 L........ 30 L....... B...... 40
....... Trifluoroacetic acid......................................... 8 UN2699 I CORROSIVE............. A3, A6, A7, B4, None 201 243 0.5 L...... 2.5 L...... B...... 12, 40
N3, N34, T18,
T27.
....... Trifluoroacetyl chloride..................................... 2.3 UN3057 POISON GAS............ 2, 25, B9, B14.. None 304 314, 315 Forbidden.. Forbidden.. D...... 40
....... Trifluorochloroethylene, inhibited, R1113.................... 2.3 UN1082 POISON GAS............ 3, 25, B14...... None 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Trifluoroethane, compressed, R143............................ 2.1 UN2035 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Trifluoromethane............................................. 2.2 UN1984 NONFLAMMABLE GAS...... ................ 306 304 314, 315 75 kg...... 150 kg..... A......
D...... Trifluoromethane and chlorotrifluoromethane mixture (constant ........... .............. ...................... ................ ........... ........... .......
boiling mixture) (R-503). See Refrigerant gases, n.o.s..
....... Trifluoromethane, refrigerated liquid........................ 2.2 UN3136 NONFLAMMABLE GAS...... ................ 306 None 314, 315 50 kg...... 500 kg..... D......
....... 2-Trifluoromethylaniline..................................... 6.1 UN2942 III KEEP AWAY FROM FOOD... ................ 153 203 241 60 L....... 220 L...... A......
....... 3-Trifluoromethylaniline..................................... 6.1 UN2948 II POISON................ T14............. None 202 243 5 L........ 60 L....... A...... 40
....... Triformoxime trinitrate...................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Triisobutylene............................................... 3 UN2324 III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Triisocyanatoisocyanurate of isophoronediisocyanate, 3 UN2906 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
solution, with 70 percent, by mass.
....... Triisopropyl borate.......................................... 3 UN2616 II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... A......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
D...... Trimethoxysilane............................................. 6.1 NA9269 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. E...... 40
LIQUID. B74, T38, T43,
T45.
....... Trimethyl borate............................................. 3 UN2416 II FLAMMABLE LIQUID...... T14............. 150 202 242 5 L........ 60 L....... B......
....... Trimethyl phosphite.......................................... 3 UN2329 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... 1,3,5-Trimethyl-2,4,6-trinitrobenzene........................ Forbidden .............. ...................... ................ ........... ........... .......
....... Trimethylacetyl chloride..................................... 6.1 UN2438 I POISON, CORROSIVE, 2, A3, A6, A7, None 227 244 Forbidden.. Forbidden.. D...... 25, 40
FLAMMABLE LIQUID. B3, B9, B14,
B32, B74, N34,
T38, T43, T45.
....... Trimethylamine, anhydrous.................................... 2.1 UN1083 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Trimethylamine, aqueous solutions with not more than 50 3 UN1297 I FLAMMABLE LIQUID, T42............. None 201 243 0.5 L...... 2.5 L...... D...... 40, 41
percent trimethylamine by mass. CORROSIVE.
............................................................. ........... .............. II FLAMMABLE LIQUID, B1, T14......... None 202 243 1 L........ 5 L........ B...... 40, 41
CORROSIVE.
............................................................. ........... .............. III FLAMMABLE LIQUID, B1.............. 150 203 242 5 L........ 60 L....... A...... 40, 41
CORROSIVE.
....... 1,3,5-Trimethylbenzene....................................... 3 UN2325 III FLAMMABLE LIQUID...... B1, T1.......... None 203 242 60 L....... 220 L...... A......
....... Trimethylchlorosilane........................................ 3 UN1298 II FLAMMABLE LIQUID, A3, A7, B77, None 202 243 1 L........ 5 L........ E...... 40
CORROSIVE. N34, T14, T26.
....... Trimethylcyclohexylamine..................................... 8 UN2326 III CORROSIVE............. T2.............. 154 203 241 5 L........ 60 L....... A......
....... Trimethylene glycol diperchlorate............................ Forbidden .............. ...................... ................ ........... ........... .......
....... Trimethylhexamethylene diisocyanate.......................... 6.1 UN2328 III KEEP AWAY FROM FOOD... T8.............. 153 203 241 60 L....... 220 L...... B......
....... Trimethylhexamethylenediamines............................... 8 UN2327 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Trimethylol nitromethane trinitrate.......................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitro-meta-cresol......................................... 1.1D UN0216 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... 2,4,6-Trinitro-1,3-diazobenzene.............................. Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4,6-Trinitro-1,3,5-triazido benzene (dry).................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroacetic acid.......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroacetonitrile......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroamine cobalt......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroaniline or Picramide................................. 1.1D UN0153 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitroanisole.............................................. 1.1D UN0213 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitrobenzene, dry or wetted with less than 30 percent 1.1D UN0214 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Trinitrobenzene, wetted with not less than 30 percent water, 4.1 UN1354 I FLAMMABLE SOLID....... 23, A2, A8, A19, None 211 None 0.5 kg..... 0.5 kg..... E...... 28
by mass. N41.
....... Trinitrobenzenesulfonic acid................................. 1.1D UN0386 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. E...... 1E, 5E
....... Trinitrobenzoic acid, dry or wetted with less than 30 percent 1.1D UN0215 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Trinitrobenzoic acid, wetted with not less than 30 percent 4.1 UN1355 I FLAMMABLE SOLID....... 23, A2, A8, A19, None 211 None 0.5 kg..... 0.5 kg..... E...... 28
water, by mass. N41.
....... Trinitrochlorobenzene or Picryl chloride..................... 1.1D UN0155 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitroethanol.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitroethylnitrate......................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitrofluorenone........................................... 1.1D UN0387 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitromethane.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... 1,3,5-Trinitronaphthalene.................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitronaphthalene.......................................... 1.1D UN0217 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitrophenetole............................................ 1.1D UN0218 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitrophenol or Picric acid, dry or wetted with less than 1.1D UN0154 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
30 percent water, by mass.
....... Trinitrophenol, wetted with not less than 30 percent water, 4.1 UN1344 I FLAMMABLE SOLID....... 23, A8, A19, N41 None 211 None 1 kg....... 15 kg...... E...... 28, 36
by mass.
....... 2,4,6-Trinitrophenyl guanidine (dry)......................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4,6-Trinitrophenyl nitramine............................... Forbidden .............. ...................... ................ ........... ........... .......
....... 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate Forbidden .............. ...................... ................ ........... ........... .......
(dry).
....... Trinitrophenylmethylnitramine or Tetryl...................... 1.1D UN0208 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Trinitroresorcinol or Styphnic acid, dry or wetted with less 1.1D UN0219 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
than 20 percent water, or mixture of alcohol and water, by
mass.
....... Trinitroresorcinol, wetted or Styphnic acid, wetted with not 1.1D UN0394 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
less than 20 percent water, or mixture of alcohol and water
by mass.
....... 2,4,6-Trinitroso-3-methyl nitraminoanisole................... Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitrotetramine cobalt nitrate............................. Forbidden .............. ...................... ................ ........... ........... .......
....... Trinitrotoluene and Trinitrobenzene mixtures or TNT and 1.1D UN0388 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
trinitrobenzene mixtures or TNT and hexanitrostilbene
mixtures or Trinitrotoluene and hexanitrostilnene mixtures.
....... Trinitrotoluene mixtures containing Trinitrobenzene and 1.1D UN0389 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
Hexanitrostilbene or TNT mixtures containing trinitrobenzene
and hexanitrostilbene.
....... Trinitrotoluene or TNT, dry or wetted with less than 30 1.1D UN0209 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
percent water, by mass.
....... Trinitrotoluene, wetted with not less than 30 percent water, 4.1 UN1356 I FLAMMABLE SOLID....... 23, A2, A8, A19, None 211 None 0.5 kg..... 0.5 kg..... E...... 28
by mass. N41.
....... Tripropylamine............................................... 3 UN2260 III FLAMMABLE LIQUID, B1, T8.......... 150 203 242 5 L........ 60 L....... A...... 40
CORROSIVE.
....... Tripropylene................................................. 3 UN2057 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Tris-(1-aziridinyl)phosphine oxide, solution................. 6.1 UN2501 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Tris, bis-bifluoroamino diethoxy propane (TVOPA)............. Forbidden .............. ...................... ................ ........... ........... .......
....... Tritonal..................................................... 1.1D UN0390 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
....... Tungsten hexafluoride........................................ 2.3 UN2196 POISON GAS, CORROSIVE. 3............... None 338 None Forbidden.. Forbidden.. D...... 40
....... Turpentine................................................... 3 UN1299 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Turpentine substitute........................................ 3 UN1300 I FLAMMABLE LIQUID...... T1.............. None 201 243 1 L........ 30 L....... B......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Undecane..................................................... 3 UN2330 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Uranium hexafluoride, fissile excepted or non-fissile........ 7 UN2978 RADIOACTIVE, CORROSIVE ................ 421-2 420, 425 420, 425 ........... ........... .......
....... Uranium hexafluoride, fissile (with more than 1 percent U- 7 UN2977 RADIOACTIVE, CORROSIVE ................ 453 417, 420 417, 420 ........... ........... A......
235).
....... Uranium metal, pyrophoric.................................... 7 UN2979 RADIOACTIVE, ................ None 418 None ........... ........... D......
SPONTANEOUSLY
COMBUSTIBLE.
....... Uranyl nitrate hexahydrate solution.......................... 7 UN2980 RADIOACTIVE, CORROSIVE ................ 421, 425 415, 416, 415, 416, ........... ........... D......
417 417
....... Uranyl nitrate, solid........................................ 7 UN2981 RADIOACTIVE, OXIDIZER. ................ None 419 None Forbidden.. 15 kg...... A......
....... Urea hydrogen peroxide....................................... 5.1 UN1511 III OXIDIZER, CORROSIVE... A1, A7, A29..... 152 213 240 25 kg...... 100 kg..... A...... 13
....... Urea nitrate, dry or wetted with less than 20 percent water, 1.1D UN0220 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
by mass.
....... Urea nitrate, wetted with not less than 20 percent water, by 4.1 UN1357 I FLAMMABLE SOLID....... 39, A8, A19, N41 None 211 None 1 kg....... 15 kg...... A...... 28
mass.
....... Urea peroxide, see Urea hydrogen peroxide.................... ........... .............. ...................... ................ ........... ........... .......
....... Valeraldehyde................................................ 3 UN2058 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
....... Valeric acid, see Corrosive liquids, n.o.s................... ........... .............. ...................... ................ ........... ........... .......
....... Valeryl chloride............................................. 8 UN2502 II CORROSIVE, FLAMMABLE A3, A6, A7, B2, 154 202 243 1 L........ 30 L....... C...... 40
LIQUID. N34, T8.
....... Vanadium compound, n.o.s..................................... 6.1 UN3285 I POISON................ ................ None 211 242 5 kg....... 50 kg...... B......
............................................................. ........... .............. II POISON................ T14............. None 212 242 25 kg...... 100 kg..... B......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 213 240 100 kg..... 200 kg..... A......
....... Vanadium oxytrichloride...................................... 8 UN2443 II CORROSIVE............. A3, A6, A7, B2, 154 202 242 Forbidden.. 30 L....... C...... 40
B16, N34, T8,
T26.
....... Vanadium pentoxide, non-fused form........................... 6.1 UN2862 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
....... Vanadium tetrachloride....................................... 8 UN2444 I CORROSIVE............. A3, A6, A7, B4, None 201 243 Forbidden.. 2.5 L...... C...... 40
N34, T8, T26.
....... Vanadium trichloride......................................... 8 UN2475 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A...... 40
....... Vanadyl sulfate.............................................. 6.1 UN2931 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
D...... Vehicles, self-propelled including internal combustion ........... .............. ...................... ................ ........... ........... .......
engines or other apparatus containing an internal combustion
Engine or electric storage battery, see Engines etc. or
Battery powered etc. or Wheel chair, electric).
....... Very signal cartridge, see Cartridges, signal................ ........... .............. ...................... ................ ........... ........... .......
....... Vinyl acetate, inhibited..................................... 3 UN1301 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Vinyl bromide, inhibited..................................... 2.1 UN1085 FLAMMABLE GAS......... ................ 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Vinyl butyrate, inhibited.................................... 3 UN2838 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... B......
....... Vinyl chloride, inhibited or Vinyl chloride, stabilized...... 2.1 UN1086 FLAMMABLE GAS......... 21, B44......... 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Vinyl chloroacetate.......................................... 6.1 UN2589 II POISON, FLAMMABLE T14............. None 202 243 5 L........ 60 L....... A......
LIQUID.
....... Vinyl ethyl ether, inhibited................................. 3 UN1302 I FLAMMABLE LIQUID...... A3, B100, T14... None 201 243 1 L........ 30 L....... D......
....... Vinyl fluoride, inhibited.................................... 2.1 UN1860 FLAMMABLE GAS......... B43............. 306 304 314, 315 Forbidden.. 150 kg..... E...... 40
....... Vinyl isobutyl ether, inhibited.............................. 3 UN1304 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Vinyl methyl ether, inhibited................................ 2.1 UN1087 FLAMMABLE GAS......... B44............. 306 304 314, 315 Forbidden.. 150 kg..... B...... 40
....... Vinyl nitrate polymer........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Vinyl toluene, inhibited mixed isomers....................... 3 UN2618 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Vinylidene chloride, inhibited............................... 3 UN1303 I FLAMMABLE LIQUID...... T23, T29........ 150 201 243 1 L........ 30 L....... E...... 40
....... Vinylpyridines, inhibited.................................... 6.1 UN3073 II POISON, FLAMMABLE B100, T8........ None 202 243 5 L........ 60 L....... B...... 40
LIQUID.
....... Vinyltrichlorosilane......................................... 3 UN1305 I FLAMMABLE LIQUID, A3, A7, B6, N34, None 201 243 Forbidden.. 2.5 L...... B...... 40
CORROSIVE. T14, T26.
....... Warheads, rocket with burster or expelling charge............ 1.4D UN0370 II EXPLOSIVE 1.4D........ ................ None 62 None Forbidden.. 75 kg...... A...... 3E, 7E, 24E
....... Warheads, rocket with burster or expelling charge............ 1.4F UN0371 II EXPLOSIVE 1.4F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Warheads, rocket with bursting charge........................ 1.1D UN0286 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Warheads, rocket with bursting charge........................ 1.2D UN0287 II EXPLOSIVE 1.2D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Warheads, rocket with bursting charge........................ 1.1F UN0369 II EXPLOSIVE 1.1F........ ................ None 62 None Forbidden.. Forbidden.. E......
....... Warheads, torpedo with bursting charge....................... 1.1D UN0221 II EXPLOSIVE 1.1D........ ................ None 62 None Forbidden.. Forbidden.. B...... 3E, 7E
....... Water-reactive liquid, corrosive, n.o.s...................... 4.3 UN3129 I DANGEROUS WHEN WET, ................ None 201 243 Forbidden.. 1 L........ D......
CORROSIVE.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 202 243 1 L........ 5 L........ E...... 85
CORROSIVE.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 203 242 5 L........ 60 L....... E......
CORROSIVE.
....... Water-reactive liquid, n.o.s................................. 4.3 UN3148 I DANGEROUS WHEN WET.... ................ None 201 244 Forbidden.. 1 L........ E...... 40
............................................................. ........... .............. II DANGEROUS WHEN WET.... ................ None 202 243 1 L........ 5 L........ E...... 40
............................................................. ........... .............. III DANGEROUS WHEN WET.... ................ None 203 242 5 L........ 60 L....... E...... 40
....... Water-reactive liquid, toxic, n.o.s.......................... 4.3 UN3130 I DANGEROUS WHEN WET, A4.............. None 201 243 Forbidden.. 1 L........ D......
POISON.
............................................................. ........... .............. II DANGEROUS WHEN WET, ................ None 202 243 1 L........ 5 L........ E...... 85
POISON.
............................................................. ........... .............. III DANGEROUS WHEN WET, ................ None 203 242 5 L........ 60 L....... E...... 85
KEEP AWAY FROM FOOD.
....... Water-reactive solid, corrosive, n.o.s....................... 4.3 UN3131 I DANGEROUS WHEN WET, B100, N40....... None 211 242 Forbidden.. 15 kg...... D......
CORROSIVE.
............................................................. ........... .............. II DANGEROUS WHEN WET, B100............ None 212 242 15 kg...... 50 kg...... E...... 85
CORROSIVE.
............................................................. ........... .............. III DANGEROUS WHEN WET, B100............ None 213 241 25 kg...... 100 kg..... E...... 85
CORROSIVE.
....... Water-reactive solid, flammable, n.o.s....................... 4.3 UN3132 I DANGEROUS WHEN WET, B100, N40....... None 211 242 Forbidden.. 15 kg...... E......
FLAMMABLE SOLID.
............................................................. ........... .............. II DANGEROUS WHEN WET, B100............ None 212 242 15 kg...... 50 kg...... E......
FLAMMABLE SOLID.
............................................................. ........... .............. III DANGEROUS WHEN WET, B100............ None 213 241 25 kg...... 100 kg..... E......
FLAMMABLE SOLID.
....... Water-reactive solid, n.o.s.................................. 4.3 UN2813 I DANGEROUS WHEN WET.... B100, N40....... None 211 242 Forbidden.. 15 kg...... E...... 40
............................................................. ........... .............. II DANGEROUS WHEN WET.... B100............ None 212 242 15 kg...... 50 kg...... E...... 40
............................................................. ........... .............. III DANGEROUS WHEN WET.... B100............ None 213 241 25 kg...... 100 kg..... E...... 40
....... Water-reactive solid, oxidizing, n.o.s....................... 4.3 UN3133 DANGEROUS WHEN WET, ................ None 214 214 Forbidden.. Forbidden.. .......
OXIDIZER.
....... Water-reactive solid, self-heating, n.o.s.................... 4.3 UN3135 I DANGEROUS WHEN WET, B100, N40....... None 211 242 Forbidden.. 15 kg...... E......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, B100............ None 212 242 15 kg...... 50 kg...... E......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, B100............ None 213 241 25 kg...... 100 kg..... E......
SPONTANEOUSLY
COMBUSTIBLE.
....... Water-reactive solid, toxic, n.o.s........................... 4.3 UN3134 I DANGEROUS WHEN WET, A5, B101, N40... None 211 242 Forbidden.. 15 kg...... D......
POISON.
............................................................. ........... .............. II DANGEROUS WHEN WET, B105............ None 212 242 15 kg...... 50 kg...... E...... 85
POISON.
............................................................. ........... .............. III DANGEROUS WHEN WET, B105............ None 213 241 25 kg...... 100 kg..... E...... 85
KEEP AWAY FROM FOOD.
AD..... Wheel chair, electric ( spillable or non-spillable type 9 .............. III CLASS 9............... ................ 222 222 None No limit... No limit... A......
batteries).
....... White acid, see Hydrofluoric acid mixtures................... ........... .............. ...................... ................ ........... ........... .......
I...... White asbestos (chrysotile, actinolite, anthophyllite, 9 UN2590 III CLASS 9............... ................ 155 216 240 200 kg..... 200 kg..... A...... 34, 40
tremolite).
....... Wood preservatives, liquid................................... 3 UN1306 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B...... 40
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A...... 40
....... Xenon........................................................ 2.2 UN2036 NONFLAMMABLE GAS...... ................ 306 302 None 75 kg...... 150 kg..... A......
....... Xenon, refrigerated liquid (cryogenic liquids)............... 2.2 UN2591 NONFLAMMABLE GAS...... ................ 320 None None 50 kg...... 500 kg..... B......
....... Xylenes...................................................... 3 UN1307 II FLAMMABLE LIQUID...... T1.............. 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Xylenols..................................................... 6.1 UN2261 II POISON................ T8.............. None 212 242 25 kg...... 100 kg..... A......
....... Xylidines, solid............................................. 6.1 UN1711 II POISON................ T14............. None 212 242 25 kg...... 100 kg..... A......
....... Xylidines, solution.......................................... 6.1 UN1711 II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
....... Xylyl bromide................................................ 6.1 UN1701 II POISON................ A3, A6, A7, N33. None 340 None Forbidden.. 60 L....... D...... 40
....... p-Xylyl diazide.............................................. Forbidden .............. ...................... ................ ........... ........... .......
....... Zinc ammonium nitrite........................................ 5.1 UN1512 II OXIDIZER.............. ................ None 212 242 5 kg....... 25 kg...... E......
....... Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc 6.1 UN1712 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
arsenite mixtures..
....... Zinc ashes................................................... 4.3 UN1435 III DANGEROUS WHEN WET.... A1, A19, B108... None 213 241 25 kg...... 100 kg..... A......
....... Zinc bisulfite solution see Bisulfites, inorganic aqueous ........... .............. ...................... ................ ........... ........... .......
solutions, n.o.s..
....... Zinc bromate................................................. 5.1 UN2469 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A...... 56, 58, 106
....... Zinc chlorate................................................ 5.1 UN1513 II OXIDIZER.............. A9, N34......... 152 212 242 5 kg....... 25 kg...... A...... 56, 58, 106
....... Zinc chloride, anhydrous..................................... 8 UN2331 III CORROSIVE............. ................ None 213 240 25 kg...... 100 kg..... A......
....... Zinc chloride, solution...................................... 8 UN1840 III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Zinc cyanide................................................. 6.1 UN1713 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A...... 26
....... Zinc dithionite or Zinc hydrosulfite......................... 9 UN1931 III None.................. ................ 155 204 240 100 kg..... 200 kg..... A...... 49
....... Zinc ethyl, see Diethylzinc.................................. ........... .............. ...................... ................ ........... ........... .......
....... Zinc fluorosilicate.......................................... 6.1 UN2855 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A...... 26
....... Zinc hydrosulfite, see Zinc dithionite....................... ........... .............. ...................... ................ ........... ........... .......
....... Zinc muriate solution, see Zinc chloride, solution........... ........... .............. ...................... ................ ........... ........... .......
....... Zinc nitrate................................................. 5.1 UN1514 II OXIDIZER.............. ................ 152 212 240 5 kg....... 25 kg...... A......
....... Zinc permanganate............................................ 5.1 UN1515 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... D...... 56, 58, 69,
106, 107
....... Zinc peroxide................................................ 5.1 UN1516 II OXIDIZER.............. ................ 152 212 242 5 kg....... 25 kg...... A...... 13, 75, 106
....... Zinc phosphide............................................... 4.3 UN1714 I DANGEROUS WHEN WET, A19, N40........ None 211 None Forbidden.. 15 kg...... E...... 40, 85
POISON.
....... Zinc powder or Zinc dust..................................... 4.3 UN1436 I DANGEROUS WHEN WET, A19, B100, N40.. None 211 242 Forbidden.. 15 kg...... A......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. II DANGEROUS WHEN WET, A19, B108....... None 212 242 15 kg...... 50 kg...... A......
SPONTANEOUSLY
COMBUSTIBLE.
............................................................. ........... .............. III DANGEROUS WHEN WET, B108............ None 213 242 25 kg...... 100 kg..... A......
SPONTANEOUSLY
COMBUSTIBLE.
....... Zinc resinate................................................ 4.1 UN2714 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
....... Zinc selenate, see Selenates or Selenites.................... ........... .............. ...................... ................ ........... ........... .......
....... Zinc selenite, see Selenates or Selenites.................... ........... .............. ...................... ................ ........... ........... .......
....... Zinc silicofluoride, see Zinc fluorosilicate................. ........... .............. ...................... ................ ........... ........... .......
....... Zirconium, dry, coiled wire, finished metal sheets, strip 4.1 UN2858 III FLAMMABLE SOLID....... A1.............. 151 213 240 25 kg...... 100 kg..... A......
(thinner than 254 microns but not thinner than 18 microns).
....... Zirconium, dry, finished sheets, strip or coiled wire........ 4.2 UN2009 III SPONTANEOUSLY A1, A19......... None 213 240 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Zirconium hydride............................................ 4.1 UN1437 II FLAMMABLE SOLID....... A19, A20, N34... None 212 240 15 kg...... 50 kg...... E......
....... Zirconium nitrate............................................ 5.1 UN2728 III OXIDIZER.............. A1, A29......... 152 213 240 25 kg...... 100 kg..... A......
....... Zirconium picramate, dry or wetted with less than 20 percent 1.3C UN0236 II EXPLOSIVE 1.3C........ ................ None 62 None Forbidden.. Forbidden.. B...... 1E, 5E
water, by mass.
....... Zirconium picramate, wetted with not less than 20 percent 4.1 UN1517 I FLAMMABLE SOLID....... 23, N41......... None 211 None 1 kg....... 15 kg...... D...... 28, 36
water, by mass.
....... Zirconium powder, dry........................................ 4.2 UN2008 I SPONTANEOUSLY ................ None 211 242 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
............................................................. ........... .............. II SPONTANEOUSLY A19, A20, N5, None 212 241 15 kg...... 50 kg...... D......
COMBUSTIBLE. N34.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 25 kg...... 100 kg..... D......
COMBUSTIBLE.
....... Zirconium powder, wetted with not less than 25 percent water 4.1 UN1358 II FLAMMABLE SOLID....... A19, A20, N34... None 212 241 15 kg...... 50 kg...... E......
(a visible excess of water must be present) (a) mechanically
produced, particle size less than 53 microns; (b) chemically
produced, particle size less than 840 microns.
....... Zirconium scrap.............................................. 4.2 UN1932 III SPONTANEOUSLY N34............. None 213 240 Forbidden.. Forbidden.. D......
COMBUSTIBLE.
D...... Zirconium sulfate............................................ 8 NA9163 III CORROSIVE............. N34............. None 213 240 50 kg...... No limit... A......
....... Zirconium suspended in a liquid.............................. 3 UN1308 I FLAMMABLE LIQUID...... ................ None 201 243 Forbidden.. Forbidden.. B......
............................................................. ........... .............. II FLAMMABLE LIQUID...... ................ None 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1.............. 150 203 242 60 L....... 220 L...... B......
....... Zirconium tetrachloride...................................... 8 UN2503 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
BILLING CODE 4910-60-F
12. In Appendix B to Sec. 172.101, two notes are added to the notes
preceding the List of Marine Pollutants to read as follows:
Appendix B to Sec. 172.101--List of Marine Pollutants
* * * * *
4. If a material not listed in this appendix meets the criteria
for a marine pollutant, as provided in the General Introduction of
the IMDG Code, Guidelines for the Identification of Harmful
Substances in Packaged Form, the material may be transported as a
marine pollutant in accordance with the applicable requirements of
this subchapter.
5. If approved by the Associate Administrator for Hazardous
Materials Safety, a material listed in this appendix which does not
meet the criteria for a marine pollutant, as provided in the General
Introduction of the IMDG Code, Guidelines for the Identification of
Harmful Substances in Packaged Form, is excepted from the
requirements of this subchapter as a marine pollutant.
* * * * *
13. In addition, in Appendix B to Sec. 172.101, the List of Marine
Pollutants is amended by removing the entry ``Ammonium arsenate'' and
adding the following entries to the List of Marine Pollutants in
appropriate alphabetical order to read as follows:
Appendix B to Sec. 172.101--List of Marine Pollutants
* * * * *
------------------------------------------------------------------------
S.M.P.--(1) Marine pollutant--(2)
------------------------------------------------------------------------
[ADD:]
*****
Acetal.
Alkyl (C12-C14) dimethylamine.
Alkyl (C7-C9) nitrates.
n-Amylbenzene.
Benomyl.
Bromoacetone.
1-Butanethiol.
n-Butyl butyrate.
Carbendazim.
Chloroacetone, stabilized.
2-Chloro-6-nitrotoluene.
alpha-Chloropropylene.
Copper arsentate.
Copper chloride (solution).
Copper metal powder.
Cupric sulfate.
PP............................... 1,5,9-Cyclododecatriene.
Decyloxytetrahydrothiophene dioxide.
PP............................... Diethylbenzenes (mixed isomers).
Diisopropylnaphthalene.
Dimethyl glyoxal (butanedione).
Dimethyl sulphide.
4,4'-Diaminodiphenylmethane.
1,4-Di-tert-butylbenzene.
Dinoseb acetate.
Dodecyl diphenyl oxide
disulphonate.
Dodecyl hydroxypropyl sulfide.
1-Dodecylamine.
Epibromohydrin.
Epichlorohydrin.
Esfenvalerate.
Ethyl mercaptan.
1-Ethyl-2-methylbenzene.
2-Ethylhexyl nitrate.
Fenbutatin oxide.
n-Heptylbenzene.
n-Hexylbenzene.
Iron oxide, spent.
Isobenzan.
Isobutyl propionate.
Isobutyl isobutyrate.
Isobutyl butyrate.
Isobutylbenzene.
Isopropyltoluene.
1-Methyl-2-ethylbenzene.
3-Methylpyradine.
Mononitrobenzene (nitro benzene).
Nitrotoluenes (o-: m-: p-).
Oleylamine
n-Pentylbenzene.
d-Phenothrin.
Propachlor.
n-Propylbenzene.
Propanethiols.
Quizalofop.
Quizalofop-p-ethyl.
Tetrachlorvinphos.
Tetramethrin.
Tetramethylbenzenes.
Triisopropylated phenyl phosphates.
1,2,3-Trimethylbenzene.
1,2,4-Trimethylbenzene.
1,3,5-Trimethylbenzene.
*****
------------------------------------------------------------------------
14. In Sec. 172.102, in paragraph (c)(1), Special Provisions 25 and
41 are removed, Special Provisions 16 and 23 are revised, and Special
Provisions 24, 26, 32, 34 through 37, 39, 40, 43 through 52, and 54 are
added; in paragraph (c)(2), Special Provision A33 is removed; and in
paragraph (c)(3) Special Provisions B53 and B110 are revised to read as
follows:
Sec. 172.102 Special provisions.
* * * * *
(c) * * *
(1) * * *
* * * * *
16. This description applies to smokeless powder and other solid
propellants that are used as powder for small arms and have been
classed as Division 1.3 and 4.1 in accordance with Sec. 173.56 of this
subchapter.
* * * * *
23. This material may be transported under the provisions of
Division 4.1 only if it is so packed that the percentage of diluent
will not fall below that stated in the shipping description at any time
during transport.
24. Alcoholic beverages containing more than 70 percent alcohol by
volume must be transported as materials in Packing Group II. Alcoholic
beverages containing more than 24 percent but not more than 70 percent
alcohol by volume must be transported as materials in Packing Group
III.
* * * * *
26. This entry does not include ammonium permanganate, the
transport of which is prohibited except when approved by the Associate
Administrator for Hazardous Materials Safety.
* * * * *
32. These beads are made from polystyrene, poly(methyl
methacrylate) or other polymeric material.
* * * * *
34. The commercial grade of calcium nitrate fertilizer, when
consisting mainly of a double salt (calcium nitrate and ammonium
nitrate) containing not more than 10 percent ammonium nitrate and at
least 12 percent water of crystallization, is not subject to the
requirements of this subchapter.
35. Antimony sulphides and oxides which do not contain more than
0.5 percent of arsenic calculated on the total mass are not subject to
the requirements of this subchapter.
36. The maximum net quantity per package is 5 liters (1 gallon) or
5 kg (11 pounds).
37. Unless it can be demonstrated by testing that the sensitivity
of the substance in its frozen state is no greater than in its liquid
state, the substance must remain liquid during normal transport
conditions. It must not freeze at temperatures above -15 deg.C
(5 deg.F).
* * * * *
39. This substance may be carried under provisions other than those
of Class 1 only if it is so packed that the percentage of water will
not fall below that stated at any time during transport. When
phlegmatized with water and inorganic inert material, the content of
urea nitrate must not exceed 75 percent by mass and the mixture should
not be capable of being detonated by test 1(a)(i) or test 1(a) (ii) in
the UN Recommendations Tests and Criteria.
40. Polyester resin kits consist of two components: a base material
(Class 3, Packing Group II or III) and an activator (organic peroxide),
each separately packed in an inner packaging. The organic peroxide must
be type D, E, or F, not requiring temperature control, and be limited
to a quantity of 125 ml (4.22 ounces) per inner packaging if liquid,
and 500 g (1 pound) if solid. The components may be placed in the same
outer packaging provided they will not interact dangerously in the
event of leakage. Packing group will be II or III, according to the
criteria for Class 3, applied to the base material.
* * * * *
43. The nitrogen content of the nitrocellulose must not exceed 11.5
percent. Each single filter sheet must be packed between sheets of
glazed paper. The portion of glazed paper between the filter sheets
must not be less than 65 percent, by mass. The membrane filters/paper
arrangement must not be liable to propagate a detonation as tested by
one of the tests described in the UN Recommendations, Tests and
Criteria, Part I, Test series 1 (a).
44. The formulation must be prepared so that it remains homogeneous
and does not separate during transport. Formulations with low
nitrocellulose contents and neither showing dangerous properties when
tested for their ability to detonate, deflagrate or explode when heated
under defined confinement by the appropriate test methods and criteria
in the UN Recommendations, Tests and Criteria, nor being a flammable
solid when tested in accordance with Appendix E to Part 173 of this
subchapter (chips, if necessary, crushed and sieved to a particle size
of less than 1.25 mm) are not subject to this subchapter.
45. Temperature should be maintained between 18 deg.C (64.4 deg.F)
and 40 deg.C (104 deg.F). Tanks containing solidified methacrylic acid
must not be reheated during transport.
46. This material must be packed in accordance with packing method
OP6B (see Sec. 173.225 of this subchapter). During transport, it must
be protected from direct sunshine and stored (or kept) in a cool and
well-ventilated place, away from all sources of heat.
47. Mixtures of solids which are not subject to this subchapter and
flammable liquids may be transported under this entry without first
applying the classification criteria of Division 4.1, provided there is
no free liquid visible at the time the material is loaded or at the
time the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level.
48. Mixtures of solids which are not subject to this subchapter and
toxic liquids may be transported under this entry without first
applying the classification criteria of Division 6.1, provided there is
no free liquid visible at the time the material is loaded or at the
time the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level. This entry may not be used for solids
containing a Packing Group I liquid.
49. Mixtures of solids which are not subject to this subchapter and
corrosive liquids may be transported under this entry without first
applying the classification criteria of Class 8, provided there is no
free liquid visible at the time the material is loaded or at the time
the packaging or transport unit is closed. Each packaging must
correspond to a design type that has passed a leakproofness test at the
Packing Group II level.
50. Cases, cartridge, empty with primer which are made of metallic
or plastic casings and meeting the classification criteria of Division
1.4 are not regulated for domestic transportation.
51. This description applies to items previously described as ``Toy
propellant devices, Class C'' and includes reloadable kits.
52. Ammonium nitrate fertilizers may not meet the definition and
criteria of Class 1 (explosive) material (see Sec. 173.150 of this
subchapter).
* * * * *
54. Maneb or maneb preparations not meeting the definition of
Division 4.3 or any other hazard class are not subject to the
requirements of this subchapter when transported by motor vehicle, rail
car, or aircraft.
* * * * *
(c) * * *
(3) * * *
* * * * *
B53 Except for IBCs, packagings must be made of either aluminum or
steel.
* * * * *
B110 This material also may be packaged in IBCs authorized in
Sec. 173.242(d) of this subchapter.
* * * * *
15. In Sec. 172.203, the list of shipping names in paragraph (k)(3)
is revised and new paragraphs (l)(3) and (o) are added to read as
follows:
Sec. 172.203 Additional description requirements.
* * * * *
(k) * * *
(3) * * *
Alcoholates solution, n.o.s., in alcohol
Alcohols, toxic, n.o.s.
Aldehydes, toxic, n.o.s.
Alkali metal alcoholates, self-heating, corrosive, n.o.s.
Alkaline earth metal alcoholates, n.o.s.
Amines, flammable, corrosive, n.o.s. or Polyamines, flammable,
corrosive, n.o.s.
Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid,
corrosive, flammable, n.o.s.
Amines, liquid, corrosive, n.o.s. or Polyamines, liquid, corrosive,
n.o.s.
Amines, solid, corrosive, n.o.s. or Polyamines, solid, corrosive,
n.o.s.
Articles, explosive, n.o.s.
Caustic alkali liquids, n.o.s.
Charges, propelling
Chloroformates, toxic, corrosive, n.o.s.
Combustible liquid, n.o.s.
Components, explosive train, n.o.s.
Compounds, cleaning liquid, corrosive, flammable, toxic
Compounds, tree or weed killing, liquid, flammable, corrosive, toxic
Compressed or Liquefied gases, flammable, n.o.s.
Compressed or Liquefied gases, n.o.s.
Compressed or Liquefied gases, oxidizing, n.o.s.
Compressed or Liquefied gases, toxic, flammable, n.o.s.
Compressed or Liquefied gases, toxic, n.o.s.
Contrivances, water-activated
Corrosive, liquid, acidic, inorganic or organic, n.o.s.
Corrosive, liquid, basic, inorganic or organic, n.o.s.
Corrosive liquids, flammable, n.o.s.
Corrosive liquids, n.o.s.
Corrosive liquids, oxidizing, n.o.s.
Corrosive liquids, toxic, n.o.s.
Corrosive liquids, water-reactive, n.o.s.
Corrosive, solid, acidic, inorganic or organic, n.o.s.
Corrosive, solid, basic, inorganic or organic, n.o.s.
Corrosive solids, flammable, n.o.s.
Corrosive solids, n.o.s.
Corrosive solids, oxidizing, n.o.s.
Corrosive solids, self-heating, n.o.s.
Corrosive solids, toxic, n.o.s.
Corrosive solids, water-reactive, n.o.s.
Disinfectants, liquid, corrosive, n.o.s.
Disinfectants, liquid, toxic, n.o.s.
Disinfectants, solids, toxic, n.o.s.
Dispersant gas, n.o.s.
Dyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid,
corrosive, n.o.s.
Dyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic,
n.o.s.
Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid,
corrosive, n.o.s.
Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic,
n.o.s.
Environmentally hazardous substances, liquid or solid, n.o.s.
Flammable gases, solid, corrosive, n.o.s.
Flammable liquids, corrosive, n.o.s.
Flammable liquids, n.o.s.
Flammable liquids, toxic, corrosive, n.o.s.
Flammable liquids, toxic, n.o.s.
Flammable solids, corrosive, organic or inorganic, n.o.s.
Flammable solids, organic, molten, n.o.s.
Flammable solids, organic or inorganic, n.o.s.
Flammable solids, toxic, organic or inorganic, n.o.s.
Halogenated irritating liquids, n.o.s.
Hazardous waste, liquid or solid, n.o.s.
Hydrocarbons, liquid, n.o.s.
Infectious substances, affecting animals
Infectious substances, affecting humans
Insecticide gases, n.o.s.
Insecticide gases, toxic, n.o.s.
Isocyanates, flammable, toxic, n.o.s. or Isocyanates solutions,
flammable, toxic, n.o.s.
Isocyanates, toxic, flammable, n.o.s. or Isocyanates solutions,
toxic, flammable, n.o.s.
Medicines, liquid, flammable, toxic, n.o.s.
Medicines, liquid, toxic, n.o.s.
Medicine, solid, toxic, n.o.s.
Metal powder, self-heating, n.o.s.
Metal salts of organic compounds, flammable, n.o.s.
Metallic substance, water-reactive, n.o.s.
Metallic substance, water-reactive, self-heating, n.o.s.
Nitriles, flammable, toxic, n.o.s.
Nitriles, toxic, flammable, n.o.s.
Nitriles, toxic, n.o.s.
Organic peroxide type B, liquid
Organic peroxide type B, liquid, temperature controlled
Organic peroxide type B, solid
Organic peroxide type B, solid, temperature controlled
Organic peroxide type C, liquid
Organic peroxide type C, liquid, temperature controlled
Organic peroxide type C, solid
Organic peroxide type C, solid, temperature controlled
Organic peroxide type D, liquid
Organic peroxide type D, liquid, temperature controlled
Organic peroxide type D, solid
Organic peroxide type D, solid, temperature controlled
Organic peroxide type E, liquid
Organic peroxide type E, liquid, temperature controlled
Organic peroxide type E, solid
Organic peroxide type E, solid, temperature controlled
Organic peroxide type F, liquid
Organic peroxide type F, liquid, temperature controlled
Organic peroxide type F, solid
Organic peroxide type F, solid, temperature controlled
Organometallic compound, toxic, n.o.s.
Organometallic compound dispersion, water-reactive, flammable,
n.o.s.
Organometallic compound solution, water-reactive, flammable, n.o.s.
Other regulated substances, liquid, n.o.s.
Other regulated substances, solid, n.o.s.
Oxidizing liquid, corrosive, n.o.s.
Oxidizing liquid, n.o.s.
Oxidizing liquid, toxic, n.o.s.
Oxidizing solid, corrosive, n.o.s.
Oxidizing solid, flammable, n.o.s.
Oxidizing solid, n.o.s.
Oxidizing solid, self-heating, n.o.s.
Oxidizing solid, toxic, n.o.s.
Oxidizing solid, water-reactive, n.o.s.
Pesticides, liquid, flammable, toxic, n.o.s.
Pesticides, liquid, toxic, flammable, n.o.s.
Pesticides, liquid, toxic, n.o.s.
Pesticides, solid, toxic, n.o.s.
Propellant, liquid
Propellant, solid
Pyrophoric liquids, organic or inorganic, n.o.s.
Pyrophoric metals, n.o.s. or Pyrophoric alloys, n.o.s.
Pyrophoric organometallic compound, n.o.s.
Pyrophoric solids, organic or inorganic, n.o.s.
Refrigerant gases, n.o.s.
Samples, explosive (other than initiating explosives)
Self-heating liquid, corrosive, inorganic, n.o.s.
Self-heating liquid, corrosive, organic, n.o.s.
Self-heating liquid, inorganic, n.o.s.
Self-heating liquid, organic, n.o.s.
Self-heating liquid, toxic, inorganic, n.o.s.
Self-heating liquid, toxic, organic, n.o.s.
Self-heating solid, corrosive, inorganic, n.o.s.
Self-heating solid, corrosive, organic, n.o.s.
Self-heating solid, organic or inorganic, n.o.s.
Self-heating solid, oxidizing, n.o.s.
Self-heating solid, toxic, organic or inorganic, n.o.s.
Self-reactive liquid type B
Self-reactive liquid type B, temperature controlled
Self-reactive liquid type C
Self-reactive liquid type C, temperature controlled
Self-reactive liquid type D
Self-reactive liquid type D, temperature controlled
Self-reactive liquid type E
Self-reactive liquid type E, temperature controlled
Self-reactive liquid type F
Self-reactive liquid type F, temperature controlled
Self-reactive solid type B
Self-reactive solid type B, temperature controlled
Self-reactive solid type C
Self-reactive solid type C, temperature controlled
Self-reactive solid type D
Self-reactive solid type D, temperature controlled
Self-reactive solid type E
Self-reactive solid type E, temperature controlled
Self-reactive solid type F
Self-reactive solid type F, temperature controlled
Solids containing corrosive liquid, n.o.s.
Solids containing flammable liquid, n.o.s.
Solids containing toxic liquid, n.o.s.
Substances, explosive, n.o.s.
Substances, explosive, very insensitive (substances, EVI), n.o.s.
Tear gas substances, liquid or solid, n.o.s.
Toxic liquids, corrosive, organic or inorganic, n.o.s.
Toxic liquids, flammable, organic or inorganic, n.o.s.
Toxic liquids, organic or inorganic, n.o.s.
Toxic liquids, oxidizing, n.o.s.
Toxic liquids, water-reactive, n.o.s.
Toxic solids, corrosive, organic or inorganic, n.o.s.
Toxic solids, flammable, organic or inorganic, n.o.s.
Toxic solids, organic or inorganic, n.o.s.
Toxic solids, oxidizing, n.o.s.
Toxic solids, self-heating, n.o.s.
Toxic solids, water-reactive, n.o.s.
Water-reactive, liquid, corrosive, n.o.s.
Water-reactive, liquid, n.o.s.
Water-reactive, liquid, toxic, n.o.s.
Water-reactive, solid, corrosive, n.o.s.
Water-reactive, solid, flammable, n.o.s.
Water-reactive, solid, n.o.s.
Water-reactive, solid, oxidizing, n.o.s.
Water-reactive, solid, self-heating, n.o.s.
Water-reactive, solid, toxic, n.o.s.
* * * * *
(l) * * *
(3) Except for transportation by vessel, marine pollutants subject
to the provisions of 49 CFR 130.11 are excepted from the requirements
of paragraph (l) of this section if a phrase indicating the material is
an oil is placed in association with the basic description.
* * * * *
(o) Organic peroxides and self-reactive materials. The description
on a shipping paper for a Division 4.1 (self-reactive) material or a
Division 5.2 (organic peroxide) material must include the following
additional information, as appropriate:
(1) If notification or competent authority approval is required,
the shipping paper must contain a statement of approval of the
classification and conditions of transport.
(2) For Division 4.1 (self-reactive) and Division 5.2 (organic
peroxide) materials that require temperature control during transport,
the control and emergency temperature must be included on the shipping
paper.
(3) The word ``SAMPLE'' must be included in association with the
basic description when a sample of a Division 4.1 (self-reactive)
material (see Sec. 173.224(c)(4) of this subchapter) or Division 5.2
(organic peroxide) material (see Sec. 173.225(c)(4) of this subchapter)
is offered for transportation or transported.
Sec. 172.203 [Amended]
16. In addition, in Sec. 172.203, in paragraph (m)(1), the wording
``Poison'' is revised to read ``Poison or Toxic''.
Sec. 172.204 [Amended]
17. In Sec. 172.204, in paragraph (a)(2), the following changes are
made:
a. The wording ``packed, marked and labeled,'' is revised to read
``packed, marked and labeled/placarded,''.
b. The wording ``by [*]'' and footnote * at the end of paragraph
(a)(2) are removed.
Sec. 172.320 [Amended]
18. In Sec. 172.320, in paragraph (b), the wording ``or identifying
information'' is revised to read ``or identifying information, such as
a product code''.
19. In Sec. 172.325, in paragraph (c), the illustration at the end
of the paragraph is revised to read as follows:
Sec. 172.325 Elevated temperature materials.
* * * * *
(c) * * *
BILLING CODE 4910-60-P
TR29DE94.000
BILLING CODE 4910-60-C
20. In Sec. 172.400a, new paragraphs (c) and (d) are added to read
as follows:
Sec. 172.400a Exceptions from labeling
* * * * *
(c) Notwithstanding the provisions of Sec. 172.402(a), a subsidiary
hazard label is not required on a package containing a Class 8
(corrosive) material which has a subsidiary hazard of Division 6.1
(poisonous) if the toxicity of the material is based solely on the
corrosive destruction of tissue rather than systemic poisoning.
(d) For Division 6.1 Packing Group III materials, a POISON label
may be used in place of a KEEP AWAY FROM FOOD label.
21. In Sec. 172.402, paragraph (a)(1) is revised and new paragraphs
(f) and (g) are added to read as follows:
Sec. 172.402 Additional labeling requirements
(a) * * *
(1) Shall be labeled with primary and subsidiary hazard labels as
specified in Column 6 of the Sec. 172.101 Table (unless excepted in
paragraph (a)(2) of this section); and
* * * * *
(f) Division 2.2 materials. In addition to the label specified in
Column 6 of the Sec. 172.101 Table, each package of Division 2.2
material that also meets the definition for an oxidizing gas (see
Sec. 171.8 of this subchapter) must be labeled OXIDIZER.
(g) Division 2.3 materials. In addition to the label specified in
Column 6 of the Sec. 172.101 Table, each package of Division 2.3
material that also meets the definition for:
(1) Division 2.1, must be labeled Flammable Gas;
(2) Division 5.1, must be labeled Oxidizer; and
(3) Class 8, must be labeled Corrosive.
Sec. 172.402 [Amended]
22. In addition, in Sec. 172.402, the following changes are made:
a. In paragraph (a)(2), in the text preceding the table, the
wording ``For other than Class 2 or Class 1 materials (for subsidiary
labeling requirements for Class 1 materials see paragraph (e) of this
section)'' are revised to read ``For other than Class 1 or Class 2
materials (for subsidiary labeling requirements for Class 1 or Class 2
materials see paragraph (e) or paragraphs (f) and (g), respectively, of
this section)''.
b. In the paragraph (a)(2) table, for the entry ``III'', the
footnote reference ``N'' is removed and replaced with an ``X'' each
place it appears, and footnote N is removed.
c. In the paragraph (a)(2) table, in the column ``8'', for the
entry ``III'', the footnote reference ``**'' is removed and replaced
with ``X'', and footnote ** is removed and reserved.
d. In paragraph (a)(2), in the footnotes following the table, the
footnote identified as ``*'' is revised to read ``If the flash point of
a material is at or above 38 deg.C (100 deg.F), required for transport
by air or vessel only.''.
Sec. 172.411 [Amended]
23. In Sec. 172.411, in the third sentence of paragraph (d), the
wording ``measuring at least 12.7 mm (0.5 inches) in height'' is
removed.
24. In Sec. 172.416, a new sentence is added as the last sentence
of paragraph (b) to read as follows:
Sec. 172.416 POISON GAS label
* * * * *
(b) * * * The words ``TOXIC GAS'' may be used in lieu of the words
``POISON GAS''.
25. In Sec. 172.430, a new sentence is added as the last sentence
of paragraph (b) to read as follows:
Sec. 172.430 POISON label
* * * * *
(b) * * * The word ``TOXIC'' may be used in lieu of the word
``POISON''.
26. In Sec. 172.540, a new sentence is added to the end of
paragraph (b) to read as follows:
Sec. 172.540 POISON GAS placard
* * * * *
(b) * * * The words ``TOXIC GAS'' may be used in lieu of the words
``POISON GAS''.
Sec. 172.547 [Amended]
27. In Sec. 172.547, in paragraph (b), the wording ``25 mm (0.98
inches)'' is removed and replaced with ``12 mm (0.5 inch)''.
28. In Sec. 172.554, a new sentence is added to the end of
paragraph (b) to read as follows:
Sec. 172.554 POISON placard
* * * * *
(b) * * * The word ``TOXIC'' may be used in lieu of the word
``POISON''.
PART 173--SHIPPERS--GENERAL REQUIREMENTS FOR SHIPMENTS AND
PACKAGINGS
29. The authority citation for Part 173 continues to read as
follows:
Authority: 49 App. U.S.C. 5101-5127; 49 CFR 1.53.
30. In Sec. 173.2a, in the paragraph (b) table, two notes are added
at the end of the table following the footnotes to read as follows:
Sec. 173.2a Classification of a material having more than one hazard
* * * * *
(b) * * *
Precedence of Hazard Table
* * * * *
Note 1: The most stringent packing group assigned to a hazard of
the material takes precedence over other packing groups; for
example, a material meeting Class 3 PG II and Division 6.1 PG I
(oral toxicity) is classified as Class 3 PG I.
Note 2: A material which meets the definition of Class 8 and has
an inhalation toxicity by dusts and mists which meets criteria for
Packing Group I specified in Sec. 173.133(a)(1) must be classed as
Division 6.1 if the oral or dermal toxicity meets criteria for
Packing Group I or II. If the oral or dermal toxicity meets criteria
for Packing Group III or less, the material must be classed as Class
8.
* * * * *
Sec. 173.2a [Amended]
31. In addition, in the paragraph (b) table, the following changes
are made:
a. At the intersection of the line entry ``4.2 II'' and the column
entry ``8, I liquid'', the wording ``(\3\)'' is revised to read ``8''.
b. At the intersection of the line entry ``4.2 II'' and the column
entry ``8, II liquid'', the wording ``(\3\)'' is revised to read
``4.2''.
c. At the intersection of the line entry ``4.2 II'' and the column
entry ``8, III liquid'', the wording ``(\3\)'' is revised to read
``4.2''.
d. At the intersection of the line entry ``4.2 III'' and the column
entry ``8, I liquid'', the wording ``(\3\)'' is revised to read ``8''.
e. At the intersection of the line entry ``4.2 III'' and the column
entry ``8, II liquid'', the wording ``(\3\)'' is revised to read ``8''.
f. At the intersection of the line entry ``4.2 III'' and the column
entry ``8, III liquid'', the wording ``(\3\)'' is revised to read
``4.2''.
32. In Sec. 173.9, a new paragraph (e) is added to read as follows:
Sec. 173.9 Cars, truck bodies, freight containers, or trailers
containing lading which has been fumigated or treated with Class 3,
Division 2.1, 2.3, or 6.1 materials
* * * * *
(e) See Sec. 176.76(i) of this subchapter for requirements for
fumigated transport units on vessels.
Sec. 173.21 [Amended]
33. In Sec. 173.21, in the first sentence of paragraph (f)(2), the
wording ``Columns 4a and 4b,'' is revised to read ``Columns 5 and 6,''.
34. In Sec. 173.22, paragraphs (a)(2)(iii) and (a)(2)(iv) are
redesignated as paragraphs (a)(2)(iv) and (a)(2)(v), respectively, a
new paragraph (a)(2)(iii) is added, and paragraphs (a)(3)(i) and (a)(4)
are revised, to read as follows:
Sec. 173.22 Shipper's responsibility
(a) * * *
(2) * * *
(iii) National or international regulations based on the UN
Recommendations on the Transport of Dangerous Goods, as authorized in
Sec. 173.24(d)(2);
* * * * *
(3) * * *
(i) Except for the marking on the bottom of a metal or plastic drum
with a capacity over 100 liters which has been reconditioned,
remanufactured or otherwise converted, the manufacturer's
certification, specification, approval, or exemption marking (see
Secs. 178.2 and 179.1 of this subchapter); or
* * * * *
(4) For a DOT specification or UN standard packaging subject to the
requirements of part 178 of this subchapter, a person shall perform all
functions necessary to bring that package into compliance with part 178
of this subchapter, as identified by the packaging manufacturer or
subsequent distributor, in accordance with Sec. 178.2 of this
subchapter.
* * * * *
35. In Sec. 173.24, paragraph (d) is revised to read as follows:
Sec. 173.24 General requirements for packagings and packages.
* * * * *
(d) Specification packagings and UN standard packagings
manufactured outside the U.S.--(1) Specification packagings. A
specification packaging, including a UN standard packaging manufactured
in the United States, must conform in all details to the applicable
specification or standard in part 178 or part 179 of this subchapter.
(2) UN standard packagings manufactured outside the United States.
A UN standard packaging manufactured outside the United States, in
accordance with national or international regulations based on the UN
Recommendations on the Transport of Dangerous Goods, may be imported
and used as an authorized packaging under the provisions of paragraph
(c)(1) of this section, subject to the following conditions and
limitations:
(i) The packaging fully conforms to applicable provisions in the UN
Recommendations on the Transport of Dangerous Goods and the
requirements of this subpart, including reuse provisions;
(ii) The packaging is capable of passing the prescribed tests in
part 178 of this subchapter applicable to that standard; and
(iii) The competent authority of the country of manufacture
provides reciprocal treatment for UN standard packagings manufactured
in the U.S.
* * * * *
Sec. 173.24 [Amended]
36. In addition, in Sec. 173.24, the following changes are made:
a. In paragraph (c)(1), the wording ``(including U.N. standard
packagings)'' is revised to read ``(including U.N. standard packagings
manufactured in the United States)''.
b. In paragraph (e)(4)(ii), the wording ``flammable or poisonous
gases;'' is revised to read ``flammable, poisonous, or asphyxiant
gases;''.
37. In Sec. 173.25, paragraph (a) introductory text is revised and
a new paragraph (b) is added to read as follows:
Sec. 173.25 Authorized packages and overpacks.
(a) Authorized packages containing hazardous materials may be
offered for transportation in an overpack as defined in Sec. 171.8 of
this subchapter, if all of the following conditions are met:
* * * * *
(b) Shrink-wrapped or stretch-wrapped trays may be used as outer
packagings for inner packagings prepared in accordance with the limited
quantity provisions or consumer commodity provisions of this
subchapter, provided that the complete package is capable of meeting
performance standards at the Packing Group III performance level. Each
package may not exceed 20 kg (44 lbs) gross weight.
* * * * *
38. In Sec. 173.28, paragraph (b)(4) is revised and new paragraphs
(b)(7) and (c)(4) are added to read as follows:
Sec. 173.28 Reuse, reconditioning and remanufacture of packagings.
* * * * *
(b) * * *
(4) Metal and plastic drums and jerricans used as single packagings
or the outer packagings of composite packagings are authorized for
reuse only when they are marked in a permanent manner (e.g., embossed)
in millimeters with the nominal (for metal packagings) or minimum (for
plastic packagings) thickness of the packaging material, as required by
Sec. 178.503(a)(9) of this subchapter, and conform to the following
minimum thickness criteria:
------------------------------------------------------------------------
Minimum thickness Maximum capacity not over
of packaging -----------------------------------------------------
material Metal drum or jerrican Plastic drum or jerrican
------------------------------------------------------------------------
20 L.............. 0.63 mm (0.025 inch) 1.1 mm (0.043 inch)
30 L.............. 0.73 mm (0.029 inch) 1.1 mm (0.043 inch)
40 L.............. 0.73 mm (0.029 inch) 1.8 mm (0.071 inch)
60 L.............. 0.92 mm (0.036 inch) 1.8 mm (0.071 inch)
120 L............. 0.92 mm (0.036 inch) 2.2 mm (0.087 inch)
220 L............. 10.92 mm (0.036 inch) 2.2 mm (0.087 inch)
450 L............. 1.77 mm (0.070 inch) 5.0 mm (0.197 inch)
------------------------------------------------------------------------
\1\Metal drums or jerricans constructed with a minimum thickness of 0.80
mm (0.03 inch) body and 1.10 mm (0.043 inch) heads are authorized.
* * * * *
(7) Notwithstanding the provisions of paragraph (b)(2) of this
section, a packaging otherwise authorized for reuse may be reused
without being subjected to the leakproofness test with air provided the
packaging:
(i) Is refilled with a material compatible with the previous
lading;
(ii) Is offered for transportation or transported by a private
carrier, contract carrier, or by a common carrier in a transport
vehicle or freight container used exclusively for such service, within
a distribution chain controlled by the offeror; and
(iii) Is constructed of--
(A) stainless steel, monel or nickel with a thickness not less than
one and one-half times the minimum thickness prescribed in paragraph
(b)(4) of this section;
(B) plastic, provided the packaging is not refilled for reuse on a
date more than five years from the date of manufacture marked on the
packaging in accordance with Sec. 178.503(a)(6) of this subchapter; or
(C) another material or thickness, if approved by the Associate
Administrator for Hazardous Materials Safety for reuse without
retesting in accordance with the provisions of this paragraph.
(c) * * *
(4) The markings applied by the reconditioner may be different from
those applied by the manufacturer at the time of original manufacture,
but may not identify a greater performance capability than that for
which the original design type had been tested (for example, the
reconditioner may mark a drum which was originally marked as 1A1/Y1.8
as 1A1/Y1.2 or 1A1/Z2.0).
* * * * *
Sec. 173.28 [Amended]
39. In addition, in Sec. 173.28, the following changes are made:
a. In paragraph (c)(1)(i), the wording ``any coatings'' is revised
to read ``any external coatings''.
b. In paragraph (c)(3), in the first sentence, the reference
``Sec. 178.503(c)'' is revised to read ``Sec. 178.503 (c) and (d)''.
Sec. 173.33 [Amended]
40. In Sec. 173.33, in paragraph (c)(5), the wording ``Division
6.1'' is revised to read ``Division 6.1, Packing Group I or II''.
Sec. 173.52 [Amended]
41. In Sec. 173.52, in paragraph (b), Table 1, the following
changes are made:
a. In the second entry, the wording ``Some articles, such as
detonators for blasting, detonator assemblies for blasting and primers,
cap-type, are included, even though they do not contain primary
explosives.'' is added at the end of the entry following the wording
``features.''.
b. In the fifth and sixth entries, the wording ``, gel'' is added
immediately following the wording ``flammable liquid'' and immediately
preceding the wording ``or hypergolic liquid''.
42. In Sec. 173.59, the following definitions are added in
appropriate alphabetical order to read as follows:
Sec. 173.59 Descriptions of terms for explosives
* * * * *
Charges, propelling for cannon. Articles consisting of a propellant
charge in any physical form, with or without a casing, for use in a
cannon.
* * * * *
Propellant, liquid. Substances consisting of a deflagrating liquid
explosive, used for propulsion.
Propellant, solid. Substances consisting of a deflagrating solid
explosive, used for propulsion.
* * * * *
Sec. 173.59 [Amended]
43. In addition, in Sec. 173.59, the following changes are made:
a. For the description ``Charges, propelling'', the wording ``or
for reducing drag for projectiles'' is added immediately following ``in
cannon''.
b. For the description ``Powder, smokeless'', in the first
sentence, the word ``generally'' is removed, and the wording ``and
charges propelling for cannon'' is added at the end of the last
sentence, immediately following the wording ``charges, propelling''.
c. For the description ``Propellants'', the wording ``or for
reducing the drag of projectiles'' is added at the end of the sentence
immediately following the word ``propulsion''.
44. In Sec. 173.60, paragraph (b)(15) is added to read as follows:
Sec. 173.60 General packaging requirements for explosives
* * * * *
(b) * * *
(15) Plastic packagings must not be liable to generate or
accumulate sufficient static electricity that a discharge could cause
the packaged explosive to ignite or the packaged article to function.
45. In Sec. 173.62, paragraph (a) is revised, a new third sentence
is added after the second sentence in paragraph (b), the Explosives
Table in paragraph (b) is amended by adding or removing entries in
appropriate alpha-numerical sequence, and the Table of Packing Methods
in paragraph (c) and paragraph (d) are revised to read as follows:
Sec. 173.62 Specific packaging requirements
(a) Except as provided in paragraph (e) of this section, when the
Sec. 172.101 Table specifies that an explosive must be packaged in
accordance with this section, only non-bulk packagings which conform to
the provisions of paragraphs (b), (c), and (d) of this section, and the
applicable requirements in Secs. 173.60 and 173.61 may be used, unless
otherwise approved by the Associate Administrator for Hazardous
Materials Safety. (b) * * * However, the packing method authorized
under E-103 may be used in place of the packing method listed in the
Explosives Table. * * *
Explosives Table
------------------------------------------------------------------------
Identification
No. Packing methods
------------------------------------------------------------------------
[Remove]:
UN0075.......... US001.
UN0143.......... US001.
UN0273.......... E-158(a), (b), (c).
UN0274.......... E-158(a), (b), (c).
NA0273.......... E-22(a), (b), (c).
NA0274.......... E-22(a), (b), (c).
[Add]:
UN0075.......... E-159.
UN0143.......... E-159.
UN0491.......... E-158.
UN0492.......... E-151.
UN0493.......... E-151.
UN0494.......... US006.
UN0495.......... E-159.
UN0496.......... E-13.
UN0497.......... E-159.
UN0498.......... E-22.
UN0499.......... E-22.
NA0276.......... E-114.
NA0323.......... E-114.
NA0337.......... E-134.
------------------------------------------------------------------------
(c) * * *
Table of Packing Methods
----------------------------------------------------------------------------------------------------------------
Packing method Particular packaging exception/
(1) Inner packaging (2) Outer packaging (3) requirement (4)
----------------------------------------------------------------------------------------------------------------
E-1(a).......... Not necessary Bags:
Paper, multiwall, water
resistant (5M2)
Textile, sift-proof (5L2)
Textile, water resistant
(5L3)
Plastic, woven, sift-proof
(5H2)
Plastic, woven, water
resistant (5H3)
Plastic, film (5H4).
E-1(b).......... Bags: Barrels:
Paper, Kraft Wood, removable head (2C2)
Plastic Boxes:
Sheets: Wood, ordinary (4C1)
Plastic Plywood (4D)
Reconstituted wood (4F)
Drums:
Steel, removable head (1A2).
E-2............. Receptacles: Barrels: 1 for all entries; 2 for all
Metal Wood, removable head (2C2) entries except UN 0402.
Paper Boxes:
Plastic Fiberboard (4G)
Sheets: Wood, ordinary (4C1)
Plastic Plywood (4D)
Bags: Reconstituted wood (4F)
Paper, multiwall, water Drums:
resistant Fiber (1G)
Woven plastics Steel, removable head (1A2)
Note: Removable head plastic
drums (1H2) are authorized
for UN 0219
E-3............. Bags: Barrels: 3, 4, D1.
Plastic Wood, removable head (2C2)
Rubber Drums:
Textile Plastic, removable head
Rubberized textile (1H2)
Intermediate: Steel, removable head (1A2)
Bags:
Plastic
Rubber
Textile
Rubberized textile
Barrels:
Wood
Receptacles:
Plastic
E-4(a).......... Receptacles: Barrels:
Fiberboard Wood, removable head (2C2)
Metal Boxes:
Paper Steel (4A)
Plastic Fiberboard (4G)
Rubberized textile Natural wood, ordinary (4C1)
Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
E-4(b).......... Optional Drums:
Aluminum, removable head
(1B2)
Fiber (1G)
Steel, removable head (1A2)
Note: steel drums (1A2) must
be dust tight
E-5............. Bags: Boxes:
Plastic Fiberboard (4G)
Sheets: Wood, sift-proof (4C2)
Paper, kraft Plywood (4D)
Paper, waxed Reconstituted wood (4F)
E-6(a)(i)....... For wetted explosives: Barrels:
Bags: Wood, removable head (2C2)
Plastic Boxes:
Rubberized, textile Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Steel, removable head (1A2)
Fiber (1G)
E-6(a)(ii)...... For wetted explosives: Barrels:
Bags: Wood, removable head (2C2)
Rubber Drums:
Textile Steel, removable head (1A2)
Rubberized textile Fiber (1G)
Intermediate:
Bags:
Rubber
Rubberized textile
Plastics
E-6(b).......... For desensitized explosives: For desensitized explosives:
Same as for wetted explosives Same as for wetted
except that any fiberboard explosives except that any
boxes may be used as inner fiberboard boxes may be
packaging and any textile used as inner packagings
bags as intermediate and any textile bags as
packaging intermediate packaging
E-8............. Receptacles: Barrels: D15, D13.
Waterproof material Wood, removable head (2C2)
Sheets: Boxes:
Waterproof Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-9............. Bags: Bags: D13.
Oil-resistant Paper, multiwall water
Sheets: resistant (5M2)
Plastic Textile, sift-proof (5L2)
Cans: Textile, water resistant
Metal (5L3)
Woven plastic, without inner
lining or coating (5H1)
Woven plastic, sift-proof
(5H2)
Woven plastic, water
resistant (5H3)
Plastic film (5H4)
Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Note: If bags of 5H2, 5H3,
5H4, or 5M2 are used, no
inner packaging necessary
E-10............ Bags: Barrels:
Paper, waxed Wood, removable head (2C2)
Plastic Boxes:
Rubberized textile Wood, ordinary (4C1)
Sheets: Plywood (4D)
Paper, waxed Reconstituted wood (4F)
Plastic
Rubberized textile
E-11............ Bags: Barrels:
Paper, waxed Wood, removable head (2C2)
Plastic Boxes:
Rubberized textile Wood, ordinary (4C1)
Sheets: Fiberboard (4G)
Paper, waxed Plywood (4D)
Plastic Reconstituted wood (4F)
Textile Drums:
Rubberized textile Fiber (1G)
E-12............ Bags: Bags: D-14.
Oil-resistant Paper, multiwall, water
Sheets: resistant (5M2)
Plastic Woven plastic, without inner
lining or coating (5H1)
Woven plastic, sift-proof
(5H2)
Woven plastic, water
resistant (5H3)
Plastic film (5H4)
Textile, sift-proof (5L2)
Textile, water resistant
(5L3)
Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
Note: If bags of 5H2 or 5H3
are used, no inner
packaging is necessary
E-13(a)......... For wetted explosives: Barrels:
Bags: Wood, removable head (2C2)
Plastic Boxes:
Woven plastics Fiberboard (4G)
Paper, multiwall, water Wood, ordinary (4Cl)
resistant Plywood (4D)
Sheets: Reconstituted wood (4F)
Plastic Drums:
Fiber (1G)
E-13(b)......... For dry explosives: Barrels:
Bags: Wood, removable head (2C2)
Paper Boxes:
Plastic Fiberboard (4G)
Woven plastics Wood, ordinary (4Cl)
Paper, multiwall, water Plywood (4D)
resistant Reconstituted wood (4F)
Boxes: Drums:
Fiberboard Fiber (1G)
Sheets:
Plastic
E-15(a)......... Not necessary Drums:
Aluminum, removable head
(1B2)
Steel, removable head (1A2)
E-15(b)......... Bags: Barrels:
Waterproof paper Wood, removable head (2C2)
Plastic Boxes:
Rubberized textile Wood, ordinary (4Cl)
Sheets: Plywood (4D)
Plastic Reconstituted wood (4F)
Rubberized textile Fiberboard (4G)
Drums:
Fiber (1G)
E-17............ Cans: Boxes:
Metal Wood, ordinary (4C1)
Receptacles: Plywood (4D)
Glass Reconstituted wood (4F)
Plastic
E-18............ Bags: Barrels:
Paper Wood, removable head (2C2)
Plastic Boxes:
Sheets: Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
Plywood (1D)
Steel, removable head (1A2)
E-19(a)......... Not necessary Drums: 7.
Aluminum, removable head
(1B2)
Steel, removable head (1A2)
Plastic, removable head
(1H2)
E-19(b)......... Bags: Barrels:
Plastic Wood, removable head (2C2)
Sheets: Boxes:
Plastic Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
E-20............ Receptacles: Boxes: 55.
Metal Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Wood Plywood (4D)
Fiberboard Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Drums:
Fiber (1G)
E-21............ Boxes: Boxes: 2.
Fiberboard Wood, sift-proof (4C2)
Cans: Plywood (4D)
Metal Reconstituted wood (4F)
Receptacles:
Waterproof paper
Plastic
Note: Plastic used must not
be liable to generate static
electricity by contained
substances
E-22(a)......... Bags: Barrels: 11 for UN 0411.
Paper, kraft Wood, removable head (2C2)
Plastic Boxes:
Textile Fiberboard (4G)
Rubberized textile Wood, ordinary (4C1)
Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Drums:
Fiber (1G)
Plywood (1D)
E-22(b)......... Receptacles: Boxes: 10.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
E-22(c)......... Not necessary Drums: 8, 9, 10.
Steel, removable head (1A2)
Fiber (1G)
Plywood (1D)
Jerricans:
Steel (3A1)
Steel, removable head (3A2)
E-24(a)......... Bags: Boxes:
Rubber Fiberboard (4G)
Rubberized textile
Plastic
E-24(b)......... Bags: Drums:
Rubber Steel, removable head (1A2)
Rubberized textile with coating other than
Plastic lead
Intermediate:
Bags:
Rubber
Rubberized textile
Plastic
E-25............ Bags: Drums:
Plastic Fiber (1G)
Steel, removable head (1A2)
E-26............ Bags: Barrels: 53.
Plastic Wood, removable head (2C2)
Paper Boxes:
Paper, multiwall, water Fiberboard (4G)
resistant Wood, ordinary (4C1)
Sheets: Plywood (4D)
Plastic Reconstituted wood (4F)
Receptacles: Drums:
Metal Fiber (1G)
Paper Bags:
Plastic Plastic, sift-proof (5H2)
E-102........... Optional Boxes: 13, 48, 49.
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Expanded plastics (4H1)
Fiberboard (4G)
Plastics, solid (4H2)
Crates:
(For large articles)
Drums:
Steel, removable head (1A2)
Fiber (1G)
Aluminum, removable head
(1B2)
E-103........... Must be specifically
authorized by the Associate
Administrator for Hazardous
Materials Safety prior to
transportation. See Secs.
173.57 and 173.58. For an
international shipment, the
package must be marked with
``Packaging authorized by
competent authority of the
United States of America
(USA)''
E-106........... Not necessary Boxes: 49 for all entries except UN
Wood, ordinary (4C1) 0434 and UN 0435.
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
Drums:
Steel, removable head (1A2)
E-107(a)........ Not necessary Boxes: 57.
Note: This packaging method Fiberboard (4G)
is to be used for boosters Wood, ordinary (4C1)
which are finished articles Plywood (4D)
consisting of closed metal, Reconstituted wood (4F)
plastic, or fiberboard Steel (4A)
receptacles that contain a Aluminum (4B)
detonating explosive, or Note: This packaging method
consisting of a plastic- is to be used for boosters
bonded detonating explosive. which are finished articles
consisting of closed metal,
plastic, or fiberboard
receptacles that contain a
detonating explosive, or
consisting of a plastic-
bonded, detonating
explosive.
E-107(b)........ Receptacles: Boxes: 57.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Sheets: Reconstituted wood (4F)
Plastic Steel (4A)
Paper Aluminum (4B)
Note: This packaging method Note: This packaging method
is to be used for cast or is to be used for cast or
pressed boosters in tubes or pressed boosters in tubes
capsules without end or capsules without end
closures. closures.
E-108........... Receptacles Boxes 23.
Metal Wooden, ordinary (4C1)
Plastic Plywood (4D)
Wooden Reconstituted wood (4F)
Note: Dividing partitions in Steel (4A)
the outer packaging may be Aluminum (4B)
used in place of inner
packagings.
E-109........... Receptacles: Boxes: 28.
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Paper Steel (4A)
Fiberboard Aluminum (4B)
E-113........... Receptacles:
Fiberboard
Plastic
Metal Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Natural wood, with sift-proof
walls (4C2)
Steel (4A)
E-114........... Receptacles: Boxes: 60.
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Metal Plywood (4D)
Wood Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Natural wood, with sift-
proof walls (4C2)
Drums:
Steel, removable head (1A2)
E-115........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Paper, raft (for cartridge of Plywood (4D)
1.4G and 1.4S) Reconstituted wood (4F)
Plastic Steel (4A)
Wood Aluminum (4B)
Expanded plastics (4H1)
Plastics, solid (4H2)
E-116........... Bags: Boxes:
Plastic Fiberboard (4G)
Textile Wood, ordinary (4C1)
Boxes: Plywood (4D)
Fiberboard Reconstituted wood (4F)
Plastic Steel (4A)
Wood Aluminum (4B)
Note: (1) Bags are authorized
for small cases only. (2)
Dividing partitions in the
outer packaging may be used
in place of inner
packagings.
E-117........... Not necessary Boxes: 57.
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Fiberboard (4G)
Drums:
Steel, removable head
E-119........... Not necessary Boxes:
Wood, ordinary (4C1)
Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Fiberboard (4G)
Plastics, solid (4H2)
Drums:
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
Note: Packaging 4C1 is
authorized for cased
charges only.
E-120........... Tubes: Boxes: 30, 31.
Fiberboard Fiberboard (4G)
Other materials Wood, ordinary (4C1)
Note: Dividing partitions in Plywood (4D)
the outer packaging may be Reconstituted wood (4F)
used in place of inner
packagings.
E-121........... Not necessary Boxes: 32, 57.
Fiberboard (4G1)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
E-122........... Boxes: Boxes:
Metal Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Wood Plywood (4D)
Fiberboard Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
E-123........... Receptacles: Boxes: 35, 49.
Fiberboard Wood, ordinary (4C1), with
Metal metal liner
Plastics Plywood (4D)
Note: Dividing partitions in Reconstituted wood (4F)
the outer packaging may be Steel (4A)
used in place of inner Aluminum (4B)
packagings. Expanded plastics (4H1)
E-124........... Reels Boxes: 33.
Receptacles: Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Aluminum (4B)
Steel (4A)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
Fiber (1G)
E-125........... Bags: Boxes: 34.
Plastic Fiberboard (4G)
Sheets: Wood, ordinary (4C1)
Paper, Kraft Plywood (4D)
Plastic Reconstituted wood (4F)
Note: Reels may be used in Steel (4A)
place of inner packagings Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
E-126........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Note: Reels may be used in Wood, ordinary (4C1)
place of inner packagings Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (1B2)
E-127........... Receptacles: Boxes:
Fiberboard Wood, ordinary (4C1)
Metals Plywood (4D)
Plastics Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Fiberboard (4G)
E-128........... Boxes: Boxes: 23, 36.
Fiberboard Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Trays: Steel (4A)
Fiberboard Aluminum (4B)
Plastic Fiberboard (4G)
Wood
Cans:
Metal
Note: All inner packagings
must be fitted with dividing
partitions
E-129........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Sheets: Plywood (4D)
Paper Reconstituted wood (4F)
Drums:
Fiber (1G)
E-130........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Metal Plywood (4D)
Sheets: Reconstituted wood (4F)
Paper Steel (4A)
Aluminum (4B)
Expanded plastics (4H1)
Drums:
Fiber (1G)
Plastic, removable head
(1H2)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-133........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Sheets: Reconstituted wood (4F)
Paper, kraft Steel (4A)
Note: Dividing partitions in Aluminum (4B)
the outer package may be Expanded plastics (4H1)
used in place of inner Solid plastics (4H2)
packagings Drums:
Fiber (1G)
Plastic, removable head
(1H2)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-134........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
Aluminum (4B)
E-135........... Bags: Boxes:
Plastic Fiberboard (4G)
Reels Wood, ordinary (4C1)
Sheets: Plywood (4D)
Paper, kraft Reconstituted wood (4F)
Plastic
E-136........... Not necessary Boxes: 32, 57.
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Expanded solid (4H2)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
E-137........... Receptacles: Boxes: 56, 38 for UN 0106, 0107, 0257,
Fiberboard Wood, ordinary (4C1) 0367, 0408, 0409 and 0410 only.
Metal Plywood (4D)
Plastic Reconstituted wood (4F)
Wood Steel (4A)
Trays: Aluminum (4B)
Plastic Fiberboard (4G)
Wood Plastics, solid (4H2)
Note: Dividing partitions in Drums:
the outer packaging may be Steel, removable head (1A2)
used in place of inner
packagings
E-138........... Optional Boxes:
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Plastics, solid (4H2)
E-139........... Receptacles: Boxes: 28 for UN 0121 only.
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Fiberboard Steel (4A)
Aluminum (4B)
Drums:
Steel, removable head (1A2)
E-141........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Wood Plywood (4D)
Sheets: Reconstituted wood (4F)
Paper Steel (4A)
Trays: Aluminum (4B)
Plastic Solid plastics (4H2)
E-142........... Boxes: Boxes: 40, D11, D39.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Cans: Steel (4A)
Metal Aluminum (4B)
Trays:
Fiberboard, sleeved
Plastic, sleeved
Intermediate:
(Optional with inner boxes
but mandatory with trays.)
E-143........... Boxes: Boxes:
Fiberboard Wood, ordinary (4C1)
Metal Plywood (4D)
Wood Reconstituted wood (4F)
Tubes: Steel (4A)
Fiberboard Aluminum (4B)
Trays:
Plastic
E-145........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal (for rivets, Wood, ordinary (4C1)
explosives) Plywood (4D)
Plastic Reconstituted wood (4F)
Wood Steel (4A)
Aluminum (4B)
E-146(a)........ Not necessary Boxes:
Fiberboard (4G)
Plywood (4D)
Reconstituted wood (4F)
Wood, ordinary (4C1)
Steel (4A)
Aluminum (4B)
E-146(b)........ Not necessary Boxes:
Fiberboard (4G)
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
E-146(c)........ Not necessary Boxes:
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
E-147........... Receptacles: Boxes:
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Drums:
Fiber (1G)
E-149........... Optional Boxes: 42, 50.
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Solid plastics (4H2)
Steel (4A)
Aluminum (4B)
E-150........... Boxes: Boxes: 12.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Receptacles: Plywood (4D)
Metal Reconstituted wood (4F)
Plastic Steel (4A)
Sheets: Aluminum (4B)
Paper, kraft Expanded plastics (4H1)
Plastics, solid (4H2)
Drums:
Fiber (1G)
Steel, removable head (1A2)
Aluminum, removable head
(1B2)
Plastics, removable head
(1H2)
E-151........... Receptacles: Boxes: 43, 44, 45.
Metal Fiberboard (4G)
Plastic Wood, ordinary (4C1)
Wood Plywood (4D)
Fiberboard Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
Drums:
Fiber (1G)
E-153........... Sheets: Boxes: 46.
Fiberboard, corrugated Wood, ordinary (4C1)
Tubes: Plywood (4D)
Fiberboard Reconstituted wood (4F)
Intermediate: Steel (4A)
Receptacles: Aluminum (4B)
Fiberboard
Metal
Plastic
E-156........... Bags: Boxes:
Plastic Fiberboard (4G)
Boxes: Wood, ordinary (4C1)
Fiberboard Plywood (4D)
Tubes: Reconstituted wood (4F)
Fiberboard Steel (4A)
Plastic Aluminum (4B)
Metal
Note: Dividing partitions in
the outer packaging may be
used in place of inner
packaging
E-157........... Not necessary Boxes:
Wood, ordinary (4C1)
Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
E-158(a)........ Bags: Boxes: 8, 10.
Paper, kraft Fiberboard (4G)
Plastics Wood, ordinary (4C1)
Textile Wood, sift-proof (4C2)
Rubberized textile Plywood (4D)
Reconstituted wood (4F)
Solid plastics (4H2)
Drums:
Steel, removable head (1A2)
Fiber (1G)
Plywood (1D)
E-158(b)........ Receptacles: Boxes: 10.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastics Wood, sift-proof (4C2)
Plywood (4D)
Reconstituted wood (4F)
Solid plastics (4H2)
E-158(c)........ Not necessary Composite packagings:
Plastic receptacle with
outer solid plastic box
(6HH2)
E-159(a)........ Receptacles: Boxes: 58.
Plastics Natural wood, ordinary (4C1)
Intermediate: Plywood (4D)
Bags Reconstituted wood (4F)
Plastic, in metal cans Note: DOT Spec. MC-200,
motor vehicle container may
be used as the outer
packaging
E-159(b)........ Receptacles: Drums: 59.
Plastics Steel, removable head (1A2)
Intermediate: Aluminum, removable head
Drums (1B2)
Metal Note: DOT Spec. MC-200,
motor vehicle container may
be used as the outer
packaging
US002........... Receptacles: Boxes: D2, D3.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Paper Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
US003........... Receptacles: Boxes: D2, D3, D4, D10.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Intermediate: Reconstituted wood (4F)
Boxes: Steel (4A)
Fiberboard Aluminum (4B)
Wood
Sheets:
Paper, Kraft
Plastic
US004........... Receptacles: Boxes: D2, D5, D6, D7, D8.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Paper Plywood (4D)
Reconstituted wood (4F)
Steel (4A)
Aluminum (4B)
US005........... Boxes: Boxes: 13.
Fiberboard Fiberboard (4G)
Metal Wood, ordinary (4C1)
Plastic Plywood (4D)
Wood Reconstituted wood (4F)
Note: Metal clips or dividing Steel (4A)
partitions in the outer Aluminum (4B)
packaging may be used in Drums:
place of inner packagings Steel, removable head (1A2)
US006\1\........
----------------------------------------------------------------------------------------------------------------
\1\A jet perforating gun, charged, oil well may be transported under the following conditions:
a. Initiation devices carried on the same motor vehicle or offshore supply vessel must be segregated; each kind
from every other kind, and from any gun, tool or other supplies. Initiation devices must be carried in a
container having individual pockets for each such device or in a fully enclosed steel container lined with a
non-sparking material. No more than two initiation devices per gun may be carried on the same motor vehicle.
b. Each shaped charge affixed to the gun may not contain more than 112 g (4 ounces) of explosives.
c. Each shaped charge if not completely enclosed in glass or metal, must be fully protected by a metal cover
after installation in the gun.
d. A jet perforating gun classed as 1.1D or 1.4D may be transported by highway by private or contract carriers
engaged in oil well operations.
1. A motor vehicle transporting a gun must have specially built racks or carrying cases designed and constructed
so that the gun is securely held in place during transportation and is not subject to damage by contact, one
to the other or any other article or material carried in the vehicle, and;
2. The assembled gun packed on the vehicle may not extend beyond the body of the motor vehicle.
e. A jet perforating gun classed as 1.4D may be transported by a private offshore supply vessel only when the
gun is carried in a motor vehicle as specified in paragraph (d) of this packing method or on offshore down-
hole tool pallets provided that:
1. All the conditions specified in paragraphs (a), (b), and (c) of this packing method are met;
2. The total explosive contents do not exceed 9.1 kg (20 pounds) per pallet;
3. Each cargo vessel compartment may contain up to 90.8 kg (200 pounds) of explosive content if the segregation
requirements in Sec. 176.83(b)(3) of this subchapter are met; and
4. When more than one vehicle or pallet is stowed ``on deck'' a minimum horizontal separation of 3 m (9.8 feet)
must be provided.
(d) Table of particular packaging requirements or exceptions.
------------------------------------------------------------------------
Number identifying packaging Explanation of packaging requirement
requirement or exception or exception
------------------------------------------------------------------------
1................................ Water soluble substances must be
packed in waterproof receptacles.
2................................ Packages must be lead-free.
3................................ The barrels and drums must have a
watertight seal.
4................................ The intermediate and outer packagings
must be filled with water or an
appropriate water-saturated material
when the intermediate packaging is a
rubber or rubberized textile bag.
7................................ Metal drums used for powder paste
must be so constructed that
explosion is not possible by reason
of increase in internal pressure
from internal or external causes.
8................................ The inside of drums and jerricans
must be galvanized, painted or
otherwise protected. Bare steel may
not come into contact with smokeless
powder.
9................................ Drums or jerricans of steel must be
constructed without pockets or
crevices in which smokeless powder
could be trapped or nipped.
10............................... Metal receptacles must be so
constructed that the risk of
explosion, by reason of increase in
internal pressure from internal or
external causes, is reduced.
11............................... The inner packagings must be sealed.
12............................... Outer boxes of natural wood may be
provided with a tin-plate liner
having a sealed lid.
13............................... Open ends of inner packagings must be
fitted with padded end caps or the
outer packaging must be padded.
22............................... The inner packagings must be
separated from the outer packaging
by a gap of not less than 25 mm (1
inch) of cushioning material, e.g.,
sawdust, wood, wool.
28............................... Metal inner packagings must be padded
with cushioning material.
30............................... The shaped charges must be packed so
that contact between them is
prevented.
31............................... The conical cavities of the shaped
charges must face inward in pairs or
groups to minimize the shaped charge
(jetting) effect in the event of
accidental initiation.
32............................... The ends of the articles must be
sealed or the use of bags, plastics,
as inner packaging is mandatory.
33............................... The ends of the detonating cord must
be sealed and tied fast.
34............................... The ends of the detonating cord must
be sealed. Spaces must be filled
with packing material.
35............................... Packagings must be sealed against the
ingress of water.
36............................... The detonators must be cushioned to
prevent significant movement and
contact between them.
38............................... The detonating fuses must be
separated from each other in the
inner packaging.
41............................... The primers must be packed with shock-
absorbent layers of felt, paper or
plastic to prevent propagation
within the outer packaging.
42............................... The outer plastic packagings must be
reinforced with metal at corners and
edge.
43............................... The signals must be separated to
prevent contact with one another and
kept apart from the bottom, walls,
and lid of the outer packaging,
e.g., by cushioning material.
44............................... Where the signals are contained in
magazines for fitting into automatic
units, the magazine may replace the
inner packaging if adequate
cushioning material is used.
45............................... Tin-plate inner packagings must be
sealed.
46............................... The sounding device must be wrapped
individually in corrugated
fiberboard sheets or inserted in
fiberboard tubes.
47............................... Absorbent cushioning material must be
inserted.
48............................... Large articles without propelling
charge and without means of ignition
or initiation may be carried
unpacked.
49............................... Large articles without their means of
initiation, or with their means of
initiation containing at least two
effective protective features, may
be carried unpackaged.
50............................... Large articles without their means of
ignition may be carried unpackaged.
53............................... Bags, sift-proof (5H2) recommended
only for flake or prilled TNT in the
dry state and a maximum net mass of
30 kg (66 pounds).
55............................... Not more than 50 g (1.8 ounces) of a
substance may be packed in an inner
packaging.
56............................... Fiberboard boxes (4G) are not
authorized outer packagings for
UN0106 or UN0107.
57............................... Liner or inner coating is required
for metal outer packagings unless
another means, such as the use of an
inner packaging or cushioning
material protects the explosive
substance from contact with the
metal outer packaging during normal
conditions of transport.
58............................... Plastic receptacles must have taped
screw cap closures and be of not
more than 5 liters capacity each.
Each receptacle must be contained
within an intermediate packaging.
Each plastic bag must be surrounded
on all sides with at least 50 mm of
non-combustible absorbent cushioning
material: metal cans in the outer
packaging must also be cushioned
from each other in all directions.
Net mass of propellent must be
limited to 30 kg for each package.
59............................... The intermediate drum must be
surrounded on all sides with at
least 50 mm of non-combustible
absorbent cushioning material. A
composite packaging consisting of a
plastic receptacle in a metal drum
may be used instead of the inner and
intermediate packagings. The net
volume of propellent in each
packaging must not exceed 120
liters.
60............................... Plastic bags may be used as inner
packagings for model rocket motors.
D1............................... The intermediate packaging must be
entirely surrounded by wetted
cushioning material within the outer
packaging.
D2............................... Quantity limitations for all
detonators are as follows unless
specifically defined for each type
of detonator: (a) For detonators
containing no more than 10 g of
explosive (excluding ignition and
delay charges): (i) No more than 50
detonators may be packed in one
inner packaging. (ii) No more than
500 detonators may be packed in one
outer packaging. (b) For detonators
containing no more than 3 g of
explosive (excluding ignition and
delay charges): (i) No more than 100
detonators may be packed in one
inner packaging. (ii) No more than
1000 detonators may be packed in one
outer packaging. (c) There are no
quantity limitations for detonators
classed as 1.4B or 1.4S. The number
of detonators that may be packed in
each inner or outer (if inner
packaging is not required) packaging
is determined by: (i) The ability of
that package to pass certain tests
(see Sec. 173.57) that qualify the
detonators to be classed as 1.4B or
1.4S; or (ii) The gross weight
limitations of the packaging used.
D3............................... Inner packaging is not required for
electric detonators when packed in
pasteboard tubes, or when their leg
wires are wound on spools with the
caps either placed inside the spool
or securely taped to the wire on the
spool, so as to restrict freedom of
movement of the caps and to protect
them from impact forces. No more
than 500 electric blasting caps may
be contained in one outer packaging.
D4............................... Intermediate packagings are required
only for non-electric detonators
that are blasting caps or delay
connectors in metal tubes.
D5............................... Detonators are not required to be
attached to the safety fuse, metal-
clad mild detonating cord,
detonating cord, or shock tube.
D6............................... Inner packagings are not required if
the packing configuration restricts
freedom of movement of the caps and
protects them from impact forces.
D7............................... Quantity limitations for detonator
assemblies with detonating cord are:
(a) No more than 50 detonator
assemblies may be packed in one
inner packaging. (b) No more than
500 detonator assemblies may be
packed in one outer packaging.
D8............................... Quantity limitations for detonator
assemblies with safety fuse or shock
tube are: (a) No more than 50
detonator assemblies may be packed
in one inner packaging. (b) No more
than 1,000 detonator assemblies may
be packed in one outer packaging.
D9............................... Primers fitted with anvil,
composition not covered with a disc
of metal foil or other material
(varnished only). (a) The primers
must be packed in rows in single
layers in trays of fiberboard or
plastic. (b) Not more than 500
primers may be packed in an inner
packaging.
D10.............................. Detonators that are non-electric
(including percussion activated) or
detonating relays in metal tubes
must be packed as follows: (a) The
detonators must be packed in an
inner packaging with the open end of
any detonator covered with
appropriate cushioning material; (b)
Inner packagings must be snugly
packed in an intermediate packaging;
(c) Intermediate packagings must be
separated from the outside packaging
by at least 25 mm (1 inch) of
cushioning material; (d) Detonators
containing no more than 10 g of
explosive (excluding ignition and
delay charges) must be packed as
follows: (i) No more than 50
detonators in one inner packaging.
(ii) No more than 500 detonators in
one outer packaging. (e) Detonators
containing no more than 3 g of
explosive (excluding ignition and
delay charges) must be packed as
follows: (i) No more than 110
detonators in one inner packaging.
(ii) No more than 5,000 detonators
in one outer packaging.
D11.............................. Primers not fitted with an anvil,
composition covered, not more than
5,000 primers may be packed in an
inner packaging.
D12.............................. Large articles may be carried
unpackaged.
D13.............................. No inner packaging required for
drums, fiber (1G).
D14.............................. Inner packaging is not required with
fiberboard boxes (4G) for packaging
UN 0332.
D15.............................. Sheets, waterproof, when used, must
also be impervious to any liquid
explosive ingredients of the
substance.
------------------------------------------------------------------------
* * * * *
Sec. 173.62 [Amended]
46. In addition, in Sec. 173.62, in paragraph (e), the phrase
``January 1, 1988'' is removed and replaced with the phrase ``January
1, 1990'' each place it appears.
47. In Sec. 173.115, the heading and the introductory text of
paragraph (b) are revised to read as follows:
Sec. 173.115 Class 2, Divisions 2.1, 2.2, and 2.3--Definitions
* * * * *
(b) Division 2.2 (non-flammable, nonpoisonous compressed gas--
including compressed gas, liquefied gas, pressurized cryogenic gas,
compressed gas in solution, asphyxiant gas and oxidizing gas). For the
purpose of this subchapter, a non-flammable, nonpoisonous compressed
gas (Division 2.2) means any material (or mixture) which--
* * * * *
48. Section 173.120 is amended by revising paragraph (a) and adding
a sentence at the end of paragraph (b)(2) to read as follows:
Sec. 173.120 Class 3--Definitions
(a) Flammable liquid. For the purpose of this subchapter, a
flammable liquid (Class 3) means a liquid having a flash point of not
more than 60.5 deg.C (141 deg.F), or any material in a liquid phase
with a flash point at or above 37.8 deg.C (100 deg.F) that is
intentionally heated and offered for transportation or transported at
or above its flash point in a bulk packaging, with the following
exceptions:
(1) Any liquid meeting one of the definitions specified in
Sec. 173.115.
(2) Any mixture having one or more components with a flash point of
60.5 deg.C (141 deg.F) or higher, that make up at least 99 percent of
the total volume of the mixture, if the mixture is not offered for
transportation or transported at or above its flash point.
(3) Any liquid with a flash point greater than 35 deg.C (95 deg.F)
which does not sustain combustion. A procedure for determining if a
material sustains combustion when heated under test conditions and
exposed to an external source of flame is provided in Appendix H of
this part.
(4) Any liquid with a flash point greater than 35 deg.C (95 deg.F)
and with a fire point greater than 100 deg.C (212 deg.F) according to
ISO 2592.
(5) Any liquid with a flash point greater than 35 deg.C (95 deg.F)
which is in a water-miscible solution with a water content of more than
90 percent by mass.
(b) * * *
(2) * * * An elevated temperature material that meets the
definition of a Class 3 material because it is intentionally heated and
offered for transportation or transported at or above its flash point
may not be reclassed as a combustible liquid.
* * * * *
Sec. 173.120 [Amended]
49. In addition, in Sec. 173.120, the following changes are made:
a. In paragraph (c)(1)(i)(A), the wording ``ASTM D56-79'' is revised to
read ``ASTM D 56''.
b. In paragraphs (c)(1)(i)(B) and (c)(1)(ii)(B), the wording ``ASTM
D3278-78'' is revised to read ``ASTM D 3278''.
c. In paragraph (c)(1)(ii)(A), the wording ``ASTM D93-80'' is
revised to read ``ASTM D 93'' each place it appears.
50. Section 173.121 is amended by adding a parenthetical note at
the end of paragraph (b)(1)(ii) before the semicolon and revising the
paragraph (b)(1)(iv) table and paragraph (b)(2)(i) to read as follows:
Sec. 173.121 Class 3--Assignment of packing group
* * * * *
(b) * * *
(1) * * *
(ii) * * * (Note: The mixture is not necessarily required to bear a
POISON or CORROSIVE subsidiary risk label.);
* * * * *
(iv) * * *
------------------------------------------------------------------------
Jet
Flow time t in seconds diameter Flash point c.c.
in mm
------------------------------------------------------------------------
20<>60............. 4 above 17 deg.C (62.6 deg.F).
60<>100............ 4 above 10 deg.C (50 deg.F).
20<>32............. 6 above 5 deg.C (41 deg.F).
32<>44............. 6 above -1 deg.C (31.2 deg.F).
44<>100............ 6 above -5 deg.C (23 deg.F).
100<100 op5b="" azodicarbonamide="" formulation="" type="" c.............="" 3234=""><100 op6a="" azodicarbonamide="" formulation="" type="" d.............="" 3236=""><100 op7b="" 2,2'-azodi(2,4-dimethyl-4-methoxyvaleronitrile).="" 3236="" 100="" op7b="" -5="" +5="" 2,2'-azodi(2,4-dimethylvaleronitrile)...........="" 3236="" 100="" op7b="" +10="" +15="" 2,2'-azodi(ethyl="" 2-methylpropionate)............="" 3235="" 100="" op7a="" +20="" +25="" 1,1-azodi(hexahydrobenzonitrile)................="" 3236="" 100="" op7b="" 2,2\1\-azodi(isobutyronitrile)..................="" 3234="" 100="" op6b="" +40="" 45="" 2,2\1\-azodi(2-methylbutyronitrile).............="" 3236="" 100="" op7b="" +35="" +40="" benzene-1,3-disulphohydrazide,="" as="" a="" paste.......="" 3236="" 52="" op7b="" benzene="" sulphohydrazide.........................="" 3236="" 100="" op7b="" 4-(benzyl(ethyl)amino)-3-ethoxybenzenediazonium="" 3236="" 100="" op7b="" zinc="" chloride.="" 4-(benzyl(methyl)amino)-3-ethoxybenzenediazonium="" 3236="" 100="" op7b="" +40="" +45="" zinc="" chloride.="" 3-chloro-4-diethylamino-benzenediazonium="" zinc="" 3236="" 100="" op7b="" chloride.="" 2-diazo-1-naphthol-4-sulphochloride.............="" 3222="" 100="" op5b="" 2-diazo-1-naphthol-5-sulphochloride.............="" 3222="" 100="" op5b="" 2,5-diethoxy-4-morpholino-benzenediazonium="" zinc="" 3236="" 67-100="" op7b="" +35="" +40="" chloride.="" 2,5-diethoxy-4-morpholino-benzenediazonium="" zinc="" 3236="" 66="" op7b="" +40="" +45="" chloride.="" 2,5-diethoxy-4-morpholino-benzenediazonium="" 3236="" 100="" op7b="" +30="" +35="" tetrafluoroborate.="" 2,5-diethoxy-4-(phenylsulphonyl)benzenediazonium="" 3236="" 67="" op7b="" +40="" +45="" zinc="" chloride.="" 2,5-dimethoxy-4-(4-methylphenylsulphony)benzene-="" 3236="" 79="" op7b="" +40="" +45="" diazonium="" zinc="" chloride.="" 4-dimethylamino-6-(2-dimethylaminoethoxy)toluene-="" 3236="" 100="" op7b="" +40="" +45="" 2-diazonium="" zinc="" chloride.="" n,n'-dinitroso-n,n'-dimethyl-terephthalamide,="" as="" 3224="" 72="" op6b="" a="" paste.="" n,n'dinitrosopentamethylenetetramine............="" 3224="" 82="" op6b="" 1="" diphenyloxide-4,4#-disulphohydrazide............="" 3226="" 100="" op7b="" 4-dipropylaminobenzenediazonium="" zinc="" chloride...="" 3226="" 100="" op7b="" 2-(n,n-ethoxycarbonylphenylamino)-3-methoxy-4-(n-="" 3236="" 63-92="" op7b="" +40="" +45="" methyl-n-cyclohexylamino)benzenediazonium="" zinc="" chloride.="" 2-(n,n-ethoxycarbonylphenylamino)-3-methoxy-4-(n-="" 3236="" 62="" op7b="" +35="" +40="" methyl-n-cyclohexylamino)benzenediazonium="" zinc="" chloride.="" n-formyl-2-(nitromethylene)-1,3-perhydrothiazine="" 3236="" 100="" op7b="" +45="" +50="" 2-(2-hydroxyethoxy)-1-(pyrrolidin-1-yl)benzene-4-="" 3236="" 100="" op7b="" +45="" +50="" diazonium="" zinc="" chloride.="" 3-(2-hydroxyethoxy)-4-(pyrrolidin-1-="" 3236="" 100="" op7b="" +40="" +45="" yl)benzenediazonium="" zinc="" chloride.="" 2-(n,n-methylaminoethylcarbonyl)-4-(3,4-dimethyl-="" 3236="" 96="" op7b="" +45="" +50="" phenylsulphonyl)benzene-diazonium="" zinc="" chloride.="" 4-methylbenzenesulphonylhydrazide...............="" 3226="" 100="" op7b="" +40="" +45="" 3-methyl-4-(pyrrolidin-1-yl)="" benzenediazonium...="" tetrafluoroborate...............................="" 3234="" 95="" op6b="" +45="" +50="" 4-nitrosophenol.................................="" 3236="" 100="" op7b="" +35="" +40="" self-reactive="" liquid,="" sample....................="" 3223="" op2a="" 2="" self-reactive="" liquid,="" sample,="" temperature="" 3233="" op2a="" 2="" control.="" self-reactive="" solid,="" sample.....................="" 3224="" op2b="" 2="" self-reactive="" solid,="" sample,="" temperature="" control="" 3234="" op2b="" 2="" sodium="" 2-diazo-1-naphthol-4-sulphonate..........="" 3226="" 100="" op7b="" sodium="" 2-diazo-1-naphthol-5-sulphonate..........="" 3226="" 100="" op7b="" tetramine="" palladium="" (ii)="" nitrate................="" 3234="" 100="" op6b="" +30="" +35="" notes:="" 1.="" with="" a="" compatible="" diluent="" having="" a="" boiling="" point="" of="" not="" less="" than="" 150="" deg.="" c.="" 2.="" samples="" may="" only="" be="" offered="" for="" transportation="" when="" all="" available="" data="" indicate="" that="" the="" sample="" is="" no="" more="" dangerous="" than="" a="" self-reactive="" substance="" type="" c,="" and="" the="" sample="" is="" packaged="" using="" packaging="" method="" op2a="" for="" liquids="" or="" op2b="" for="" solids,="" as="" appropriate,="" in="" quantities="" less="" than="" 10="" kg="" per="" shipment,="" employing="" any="" necessary="" temperature="" controls.="" (c)="" new="" self-reactive="" materials,="" formulations="" and="" samples.="" (1)="" except="" as="" provided="" for="" samples="" in="" paragraph="" (c)(4)="" of="" this="" section,="" no="" person="" may="" offer,="" accept="" for="" transportation,="" or="" transport="" a="" self-="" reactive="" material="" which="" is="" not="" identified="" by="" technical="" name="" in="" the="" self-reactive="" materials="" table="" of="" this="" section,="" or="" a="" formulation="" of="" one="" or="" more="" self-reactive="" materials="" which="" are="" identified="" by="" technical="" name="" in="" the="" table,="" unless="" the="" self-reactive="" material="" is="" assigned="" a="" generic="" type="" and="" shipping="" description="" and="" is="" approved="" by="" the="" associate="" administrator="" for="" hazardous="" materials="" safety="" under="" the="" provisions="" of="" sec.="" 173.124(a)(2)(vii).="" (2)="" except="" as="" provided="" by="" an="" approval="" issued="" under="" sec.="" 173.124(a)(2)(vii),="" intermediate="" bulk="" and="" bulk="" packagings="" are="" not="" authorized.="" (3)="" non-bulk="" packagings="" are="" authorized="" as="" specified="" in="" the="" packing="" method="" table="" for="" generic="" types,="" as="" follows.="" column="" 1="" of="" the="" table="" specifies="" the="" generic="" type="" by="" identification="" number.="" column="" 2="" of="" the="" table="" specifies="" the="" generic="" proper="" shipping="" name="" from="" the="" sec.="" 172.101="" table.="" column="" 3="" of="" the="" table="" specifies="" the="" series="" of="" packing="" methods="" authorized="" for="" use.="" the="" table="" of="" packing="" methods="" in="" sec.="" 173.225(d)="" defines="" the="" packing="" methods.="" the="" packing="" method="" table="" for="" generic="" types="" is="" as="" follows:="" packing="" method="" table="" for="" generic="" types="" un="" no.="" proper="" shipping="" name="" packing="" method="" (1)="" (2).......................................="" (3)="" ------------------------------------------------------------------------="" 3221........="" self-reactive="" liquid="" type="" b...............="" op1a-op5a.="" 3222........="" self-reactive="" solid="" type="" b................="" op1b-op5b.="" 3223........="" self-reactive="" liquid="" type="" c...............="" op1a-op6a.="" 3224........="" self-reactive="" solid="" type="" c................="" op1b-op6b.="" 3225........="" self-reactive="" liquid="" type="" d...............="" op1a-op7a.="" 3226........="" self-reactive="" solid="" type="" d................="" op1b-op7b.="" 3227........="" self-reactive="" liquid="" type="" e...............="" op1a-op8a.="" 3228........="" self-reactive="" solid="" type="" e................="" op1b-op8b.="" 3229........="" self-reactive="" liquid="" type="" f...............="" op1a-op8a.="" 3230........="" self-reactive="" solid="" type="" f................="" op1b-op8b.="" 3231........="" self-reactive="" liquid="" type="" b,="" temperature="" op1a-op5a.="" controlled.="" 3232........="" self-reactive="" solid="" type="" b,="" temperature="" op1b-op6b.="" controlled.="" 3233........="" self-reactive="" liquid="" type="" c,="" temperature="" op1a-op6a.="" controlled.="" 3234........="" self-reactive="" solid="" type="" c,="" temperature="" op1b-op7b.="" controlled.="" 3235........="" self-reactive="" liquid="" type="" d,="" temperature="" op1a-op7a.="" controlled.="" 3236........="" self-reactive="" solid="" type="" d,="" temperature="" op1b-op8b.="" controlled.="" 3237........="" self-reactive="" liquid="" type="" e,="" temperature="" op1a-op8a.="" controlled.="" 3238........="" self-reactive="" solid="" type="" e,="" temperature="" op1b-op8b.="" controlled.="" 3239........="" self-reactive="" liquid="" type="" f,="" temperature="" op1a-op8a.="" controlled.="" 3240........="" self-reactive="" solid="" type="" f,="" temperature="" op1b-op8b.="" controlled.="" (4)="" samples.="" samples="" of="" new="" self-reactive="" materials="" or="" new="" formulations="" of="" self-reactive="" materials="" identified="" in="" the="" self-reactive="" materials="" table="" in="" paragraph="" (b)="" of="" this="" section,="" for="" which="" complete="" test="" data="" are="" not="" available,="" and="" which="" are="" to="" be="" transported="" for="" further="" testing="" or="" evaluation,="" may="" be="" assigned="" an="" appropriate="" shipping="" description="" for="" self-reactive="" materials="" type="" c,="" packaged="" and="" offered="" for="" transportation="" under="" the="" following="" conditions:="" (i)="" data="" available="" to="" the="" person="" offering="" the="" material="" for="" transportation="" must="" indicate="" that="" the="" sample="" would="" pose="" a="" level="" of="" hazard="" no="" greater="" than="" that="" of="" a="" self-reactive="" material="" type="" b="" and="" that="" the="" control="" temperature,="" if="" any,="" is="" sufficiently="" low="" to="" prevent="" any="" dangerous="" decomposition="" and="" sufficiently="" high="" to="" prevent="" any="" dangerous="" phase="" separation;="" (ii)="" the="" sample="" must="" be="" packaged="" in="" accordance="" with="" packing="" method="" op2a="" or="" op2b,="" for="" a="" liquid="" or="" a="" solid,="" respectively;="" (iii)="" packages="" of="" the="" self-reactive="" material="" may="" be="" offered="" for="" transportation="" and="" transported="" in="" a="" quantity="" not="" to="" exceed="" 10="" kg="" (22="" pounds)="" per="" transport="" vehicle;="" and="" (iv)="" one="" of="" the="" following="" shipping="" descriptions="" must="" be="" assigned:="" (a)="" self-reactive,="" liquid,="" type="" c,="" 4.1,="" un3223.="" (b)="" self-reactive,="" solid,="" type="" c,="" 4.1,="" un3224.="" (c)="" self-reactive,="" liquid,="" type="" c,="" temperature="" controlled,="" 4.1,="" un3233.="" (d)="" self-reactive,="" solid,="" type="" c,="" temperature="" controlled,="" 4.1,="" un3234.="" (d)="" self-reactive="" substances="" of="" type="" f="" may="" not="" be="" transported="" in="" bulk="" or="" intermediate="" bulk="" containers="" except="" as="" approved,="" in="" writing,="" by="" the="" associate="" administrator="" for="" hazardous="" materials="" safety.="" 73.="" in="" sec.="" 173.225,="" the="" fourth="" sentence="" of="" paragraph="" (a)="" and="" the="" organic="" peroxides="" table="" in="" paragraph="" (b)="" are="" revised,="" a="" new="" paragraph="" (c)(5)="" is="" added,="" and="" paragraph="" (e)(3)(ii)="" is="" revised="" to="" read="" as="" follows:="" sec.="" 173.225="" packaging="" requirements="" and="" other="" provisions="" for="" organic="" peroxides.="" (a)="" *="" *="" *="" to="" avoid="" unnecessary="" confinement,="" metallic="" non-bulk="" packagings="" meeting="" packing="" group="" i="" are="" not="" authorized.="" *="" *="" *="" (b)="" *="" *="" *="" billing="" code="" 4910-60-p="" organic="" peroxides="" table="" --------------------------------------------------------------------------------------------------------------------------------------------------------="" diluent="" (mass="" %)="" temperature(="" deg.c)="" technical="" name="" id="" number="" concentration="" ---------------------="" water="" packing="" ----------------------="" notes="" (mass="" %)="" a="" b="" i="" (mass="" %)="" method="" control="" emergency="" (1)="" (2)="" (3)="" (4a)="" (4b)="" (4c)="" (5)="" (6)="" (7a)="" (7b)="" (8)="" --------------------------------------------------------------------------------------------------------------------------------------------------------="" acetyl="" acetone="" peroxide......................="" un3105="">42 32 OP7B 21
Acetyl benzoyl peroxide...................... UN3105 45 82 32 88 62 96 100 OP7A +20 +25
tert-Amyl peroxy-2-ethylhexyl carbonate...... UN3105 100 OP7A
tert-Amyl peroxyneodecanoate................. UN3115 77 77 100 OP5A
2,2-Bis(4,4-di(tert- UN3107 25 42 - 100 OP7A 1, 9
tert-Butyl cumyl peroxide.................... UN3106 42 52 - 100 OP5A
n-Butyl-4,4-di-(tert-butylperoxy)valerate.... UN3106 >42 - 52 42 79 - 90 80 79 72 <82 +="">9 52 - 100 OP5B
tert-Butyl monoperoxymaleate................. UN3103 52 52 52 OP8B 21
tert-Butyl monoperoxymaleate as a paste...... UN3010 42 OP8B 21
tert-Butyl monoperoxyphthalate............... UN3102 100 OP5B
tert-Butyl peroxyacetate..................... UN3101 >52 - 77 32 - 52 32 32 22 77 - 100 52 - 77 52 52 77 100 OP5A +20 +25
tert-Butyl peroxydiethylacetate and.......... UN3105 33 33
tert-Butyl peroxy-2-ethylhexanoate........... UN3113 >52 - 100 OP6A +20 +25
tert-Butyl peroxy-2-ethylhexanoate........... UN3117 >32 - 52 52 32 32 32 31 36
tert-Butyl peroxy-2-ethylhexanoate and....... UN3106 12 14
tert-Butyl peroxy-2-ethylhexylcarbonate...... UN3105 100 OP7A
tert-Butyl peroxyisobutyrate................. UN3111 >52 - 77 52 77 77 42 100 OP5A
tert-Butyl peroxyneodecanoate................ UN3115 >77 - 100 OP7A -5 +5
tert-Butyl peroxyneodecanoate................ UN3115 77 42 OP8A 0 +10 21
tert-Butyl peroxyneodecanoate as a paste UN3118 42 OP8B 0 +10 21
(frozen).
tert-Butyl peroxyneoheptanoate............... UN3115 77 100 OP7B
tert-Butyl peroxypivalate.................... UN3113 >67 - 77 27 - 67 27 27 27 100 OP7B
tert-Butyl peroxy-3,5,5-trimethylhexanoate... UN3105 >32 - 100 OP7A
tert-Butyl peroxy-3,5,5-trimethylhexanoate... UN3109 32 32 57 - 86 72 57 90 - 98 90 77 77 77 91 72 32 72 OP7B 5, 21
Diacetone alcohol peroxides.................. UN3115 57 27 27 100 OP8A
1,1-Di-(tert-amylperoxy)cyclohexane.......... UN3103 82 51 - 100 77 - 94 77 62 35 - 52 36 - 42 36 - 42 35 52 - 62 OP7B 21
Dibenzoyl peroxide as a paste................ UN3108 56 52 OP8B 21
Dibenzoyl peroxide as a paste................ Exempt 50 87 100 OP6B +30 +35
Di-(4-tert-butylcyclohexyl)peroxydicarbonate UN3119 42 OP8A +30 +35 10
as a stable dispersion in water.
Di-tert-butyl peroxide....................... UN3107 >32 - 100 OP8A
Di-tert-butyl peroxide....................... UN3109 32 22 52 52 80 - 100 OP5A
1,1-Di-(tert-butylperoxy)cyclohexane......... UN3103 >52 - 80 52 42 27 25 13 27 - 52 27 52 - 100 OP4A -20 -10 6
Di-sec-butyl peroxydicarbonate............... UN3115 52 42 - 100 42 42 - 52 42 52 OP7B 21
2,2-Di-(tert-butylperoxy)propane............. UN3105 52 42 90 - 100 OP5A
trimethylcyclohexane.
1,1-Di-(tert-butylperoxy)-3,3,5- UN3103 >57 - 90 57 57 32 100 OP7B +20 +25
Dicetyl peroxydicarbonate as a stable UN3119 42 OP8A +30 +35 10
dispersion in water.
Di-4-chlorobenzoyl peroxide.................. UN3102 77 32 52 OP7B 21
Dicumyl peroxide............................. UN3109 >42 - 100 OP8A 7, 9, 11
Dicumyl peroxide............................. UN3110 >42 - 100 52 42 91 - 100 OP3B +5 +10
Dicyclohexyl peroxydicarbonate............... UN3114 91 100 OP6B +30 +35
2,2-Di-(4,4-di(tert- UN3106 42 77 52 OP7B
with silicone oil.
Di-(2-ethylhexyl) peroxydicarbonate.......... UN3113 >77 - 100 OP5A -20 -10
Di-(2-ethylhexyl) peroxydicarbonate.......... UN3115 77 OP7A -15 -5
Di-(2-ethylhexyl) peroxydicarbonate as a UN3117 42 OP8A -15 -5
stable dispersion in water.
Di-(2-ethylhexyl) peroxydicarbonate as a UN3118 42 OP8B -15 -5
stable dispersion in water (frozen).
Diethyl peroxydicarbonate.................... UN3115 27 27 100 OP7B
Diisobutyryl peroxide........................ UN3111 >32 - 52 32 82 52 - 100 OP2B -15 -5
Diisopropyl peroxydicarbonate................ UN3115 52 100 OP7A -10 0
Dilauroyl peroxide........................... UN3106 100 OP7B
Dilauroyl peroxide as a stable dispersion in UN3109 42 OP8A 10
water.
Di-(2-methylbenzoyl) peroxide................ UN3112 87 52 OP7B
silicone oil.
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane.... UN3102 >82 - 100 OP5B
2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane.... UN3104 82 82 52 - 100 OP7A
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne- UN3103 >52 - 100 OP5A
3.
2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane. UN3106 70 52 52 47 OP8B
as a paste.
2,5-Dimethyl-2,5-di-(2- UN3115 100 OP7A +20 +25
ethylhexanoylperoxy)hexane.
2,5-Dimethyl-2,5-dihydroperoxyhexane......... UN3104 82 77 52 100 OP7B +20 +25
Dimyristyl peroxydicarbonate as a stable UN3119 42 OP8A +20 +25
dispersion in water.
Dimyristyl peroxydicarbonate as a stable UN3119 42 +15 +25 10
dispersion in water.
Di-(2-neodecanoylperoxyisopropyl) benzene.... UN3115 52 100 OP7B 0 +10
Di-n-octanoyl peroxide....................... UN3114 100 OP5B +10 +15
Diperoxy azelaic acid........................ UN3116 27 13 - 42 13 85 - 100 OP5B
Di-(2-phenoxyethyl)peroxydicarbonate......... UN3106 85 27 100 OP4A -25 -15
Distearyl peroxydicarbonate.................. UN3106 87 72 - 100 OP4B 18
Disuccinic acid peroxide..................... UN3116 72 52 OP7B +30 +35 21
peroxide as a paste.
Di-(3,5,5-trimethylhexanoyl)peroxide......... UN3115 >38 - 82 38 38 38 52 OP8A +10 +15
stable dispersion in water.
Ethyl 3,3-di-(tert-amylperoxy)butyrate....... UN3105 67 77 - 100 OP5A
Ethyl 3,3-di-(tert-butylperoxy)butyrate...... UN3105 77 52 52 - 100 OP4B
tetraoxacyclononane.
3,3,6,6,9,9-Hexamethyl-1,2,4,5- UN3105 52 52 72 56 - 100 OP7A 13
p-Menthyl hydroperoxide...................... UN3109 < 56="">52 45 40 62 67 < 6="">36 43 OP7A 13, 20
Peroxyacetic acid, type E, stabilized........ UN3107 43 OP8A 13, 20
Peroxyacetic acid, type F, stabilized........ UN3109 43 OP8A 13, 20
Pinanyl hydroperoxide........................ UN3105 > 56 - 100 OP7A 13
Pinanyl hydroperoxide........................ UN3109 < 56="">100 OP7B
1,1,3,3-Tetramethylbutyl hydroperoxide....... UN3105 100 OP7A
1,1,3,3-Tetramethylbutylperoxy-2- UN3115 100 OP7A +20 +25
ethylhexanoate.
2,4,4-Trimethylpentyl-2-peroxyneodecanoate... UN3115 72 37 <4.7 percent.="" 3.="" for="" concentrations=""><80 percent="" op5b="" is="" allowed.="" for="" concentrations="" of="" at="" least="" 80="" percent="" but=""><85 percent,="" op4b="" is="" allowed.="" for="" concentrations="" of="" at="" least="" 85="" percent,="" maximum="" package="" size="" is="" op2b.="" 4.="" the="" diluent="" may="" be="" replaced="" by="" di-tert-butyl="" peroxide.="" 5.="" available="" oxygen="" must="" be="">9 percent.
6. For domestic shipments, OP5A is authorized.
7. This material may be transported in intermediate bulk containers
and bulk packagings under the provisions of Sec. 173.225(e).
8. Only non-metallic packagings are authorized.
9. For domestic shipments, this material may be transported in bulk
packagings under the provisions of Sec. 173.225(e)(3)(c)(ii).
10. This material may be transported in intermediate bulk containers
under the provisions of Sec. 173.225(e).
11. Up to 2000 kg per container authorized.
12. Samples may only be offered for transportation when all
available data indicate that the sample is no more dangerous than an
Organic Peroxide type C, and the sample is packaged using packaging
method OP2A for liquids or OP2B for solids, as appropriate, in
quantities less than 10 kg per shipment, employing any necessary
temperature controls.
13. ``Corrosive'' subsidiary risk label is required.
14. This material may be transported in bulk packagings under the
provisions of Sec. 173.225(e).
15. No ``Corrosive'' subsidiary risk label is required for
concentrations below 80%.
16. With <6% di-tert-butyl="" peroxide.="" 17.="" with=""><=8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene.="" 18.="" addition="" of="" water="" to="" this="" organic="" peroxide="" will="" decrease="" its="" thermal="" stability.="" 19.="" [reserved]="" 20.="" mixtures="" with="" hydrogen="" peroxide,="" water="" and="" acid(s).="" 21.="" with="" diluent="" type="" a,="" with="" or="" without="" water.="" 22.="" with="">36 percent, by mass, ethylbenzene.
23. With >19 percent, by mass, methyl isobutyl ketone.
(c) * * *
(5) Mixtures. Mixtures of organic peroxides individually identified
in the Organic Peroxides Table in paragraph (b) of this section may be
classified as the same type of organic peroxide as that of the most
dangerous component and be transported under the conditions for
transportation given for this type. If the stable components form a
thermally less stable mixture, the SADT of the mixture must be
determined and the new control and emergency temperature derived under
the provisions of Sec. 173.21(f).
* * * * *
(e) * * *
(3) * * *
(ii) Specification 57 metal portable tanks are authorized only for
tert-butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s),
dicumyl peroxide and mixtures of two or more of these peroxides.
* * * * *
Sec. 173.226 [Amended]
74. In Sec. 173.226(c)(1), in the entry for ``Steel box'', the
wording ``4A1 or 4A2'' is removed and the wording ``4A'' is added in
its place; and in the entry for ``Aluminum box'', the wording ``4B1 and
4B2'' is removed and the wording ``4B'' is added in its place.
Sec. 173.304 [Amended]
75. In Sec. 173.304, in the paragraph (a)(2) table, for the entry
``Carbon dioxide'', in Column 3, ``DOT-311800'' is removed and replaced
with ``DOT-3T1800''.
76. In Sec. 173.306, a new paragraph (a)(4) is added and paragraph
(a)(3)(v) is revised to read as follows:
Sec. 173.306 Limited quantities of compressed gases.
(a) * * *
(3) * * *
(v) Each container must be subjected to a test performed in a hot
water bath; the temperature of the bath and the duration of the test
must be such that the internal pressure reaches that which would be
reached at 55 deg.C (131 deg.F) (50 deg.C (122 deg.F) if the liquid
phase does not exceed 95% of the capacity of the container at 50 deg.C
(122 deg.F)). If the contents are sensitive to heat or if the
containers are made of plastic material which softens at this test
temperature, the temperature of the bath must be set at between
20 deg.C (68 deg.F) and 30 deg.C (86 deg.F) but, in addition, one
container in 2,000 must be tested at the higher temperature. No leakage
or permanent deformation of a container may occur, except that a
plastic container may be deformed through softening provided that it
does not leak.
* * * * *
(4) Gas samples must be transported under the following conditions:
(i) A gas sample may only be transported as non-pressurized gas
when its pressure corresponding to ambient atmospheric pressure in the
container is not more than 105 kPa absolute (15.22 psia).
(ii) Non-pressurized gases, toxic (or toxic and flammable) must be
packed in hermetically sealed glass or metal inner packagings of not
more than one L (0.3 gallons) overpacked in a strong outer packaging.
(iii) Non-pressurized gases, flammable must be packed in
hermetically-sealed glass or metal inner packagings of not more than
2.5 L (0.5 gallons) overpacked in a strong outer packaging.
* * * * *
Appendix A to Part 173 [Removed and Reserved]
77. Appendix A to part 173 is removed and reserved.
78. In Appendix E to part 173, paragraph 2.b.(4) is redesignated as
paragraph 2.b.(5) and a new paragraph 2.b.(4) is added to read as
follows:
Appendix E to Part 173--Guidelines for the Classification and
Packing Group Assignment of Class 4 Materials
* * * * *
2. * * *
b. * * *
(4) A self-reactive material shall be regarded as possessing
explosive properties when, in laboratory testing, its formulation is
determined to be liable to detonate, deflagrate rapidly or show a
violent effect when heated under confinement.
* * * * *
Appendix E to Part 173 [Amended]
79. In addition, in Appendix E to part 173, in paragraph
2.c.(3)(B), the wording ``Powders of metals or metal alloys are
classified when they can be ignited'' is revised to read ``Powders of
metals or metal alloys are classified in Division 4.1 when they can be
ignited''.
Appendix F to Part 173 [Amended]
80. In Appendix F to part 173, in paragraph 1., the phrase
``Division 4.1'' is removed and replaced with ``Division 5.1''.
81. Appendix H is added to part 173 to read as follows:
Appendix H to Part 173--Method of Testing for Sustained Combustibility
1. Method
The method describes a procedure for determining if the material
when heated under the test conditions and exposed to an external
source of flame applied in a standard manner sustains combustion.
2. Principle of the method
A metal block with a concave depression (test portion well) is
heated to a specified temperature. A specified volume of the
material under test is transferred to the well, and its ability to
sustain combustion is noted after application and subsequent removal
of a standard flame under specified conditions.
3. Apparatus
A combustibility tester consisting of a block of aluminum alloy
or other corrosion-resistant metal of high thermal conductivity is
used. The block has a concave well and a pocket drilled to take a
thermometer. A small gas jet assembly on a swivel is attached to the
block. The handle and gas inlet for the gas jet may be fitted at any
convenient angle to the gas jet. A suitable apparatus is shown in
Figure 5.1 of the UN Recommendations, and the essential dimensions
are given in Figures 5.1 and 5.2 of the UN Recommendations. The
following equipment is needed:
(a) Gauge, for checking that the height of the center of the gas
jet above the top of the test portion well is 2.2 mm (see Figure
5.1);
(b) Thermometer, mercury in glass, for horizontal operation,
with a sensitivity not less than 1 mm/ deg.C, or other measuring
device of equivalent sensitivity permitting reading at 0.5 deg.C
intervals. When in position in the block, the thermometer bulb must
be surrounded with thermally conducting thermoplastic compound;
(c) Hotplate, fitted with a temperature-control device. (Other
types of apparatus with suitable temperature-control facilities may
be employed to heat the metal block);
(d) Stopwatch, or other suitable timing device;
(e) Syringe, capable of delivering 2 ml to an accuracy of
0.1 ml; and
(f) Fuel source, butane test fuel.
4. Sampling
The sample must be representative of the material to be tested
and must be supplied and kept in a tightly closed container prior to
test. Because of the possibility of loss of volatile constituents,
the sample must receive only the minimum treatment necessary to
ensure its homogeneity. After removing each test portion, the sample
container must be immediately closed tightly to ensure that no
volatile components escape from the container; if this closure is
incomplete, an entirely new sample must be taken.
5. Procedure
Carry out the determination in triplicate.
WARNING--Do not carry out the test in a small confined area (for
example a glove box) because of the hazard of explosions.
(a) It is essential that the apparatus be set up in a completely
draft-free area (see warning) and in the absence of strong light to
facilitate observation of flash, flame, etc.
(b) Place the metal block on the hotplate or heat the metal
block by other suitable means so that its temperature, as indicated
by the thermometer placed in the metal block, is maintained at the
specified temperature within a tolerance of 1 deg.C. The
test temperature is 60.5 deg.C or 75 deg.C, (see (h)). Correct this
temperature for the difference in barometric pressure from the
standard atmospheric pressure (101.3 kPa) by raising the test
temperature for a higher pressure or lowering the test temperature
for a lower pressure by 1.0 deg.C for each 4 kPa difference. Ensure
that the top of the metal block is exactly horizontal. Use the gauge
to check that the jet is 2.2 mm above the top of the well when in
the test position.
(c) Light the butane test fuel with the jet away from the test
position (i.e. in the ``off'' position, away from the well). Adjust
the size of the flame so that it is 8 mm to 9 mm high and
approximately 5 mm wide.
(d) Using the syringe, take from the sample container at least 2
ml of the sample and rapidly transfer a test portion of 2 ml
0.1 ml to the well of the combustibility tester and
immediately start the timing device.
(e) After a heating time of 60 seconds (s), by which time the
test portion is deemed to have reached its equilibrium temperature,
and if the test fluid has not ignited, swing the test flame into the
test position over the edge of the pool of liquid. Maintain it in
this position for 15 s and then return it to the ``off'' position
while observing the behavior of the test portion. The test flame
must remain lighted throughout the test.
(f) For each test observe and record:
(i) whether there is ignition and sustained combustion or
flashing, or neither, of the test portion before the test flame is
moved into the test position;
(ii) whether the test portion ignites while the test flame is in
the test position, and, if so, how long combustion is sustained
after the test flame is returned to the ``off'' position.
(g) If sustained combustion interpreted in accordance with
paragraph 6. of this appendix is not found, repeat the complete
procedure with new test portions, but with a heating time of 30 s.
(h) If sustained combustion interpreted in accordance with
paragraph 6. of this appendix is not found at a test temperature of
60.5 deg.C (141 deg.F), repeat the complete procedure with new test
portions, but at a test temperature of 75 deg.C (167 deg.F).
6. Interpretation of observations
The material must be assessed either as not sustaining
combustion or as sustaining combustion. Sustained combustion must be
reported at either of the heating times if one of the following
occurs with either of the test portions:
(a) When the test flame is in the ``off'' position, the test
portion ignites and sustains combustion;
(b) The test portion ignites while the test flame is in the test
position for 15 s, and sustains combustion for more than 15 s after
the test flame has been returned to the ``off'' position.
Note to Paragraph 6. of this Appendix: Intermittent flashing may
not be interpreted as sustained combustion. Normally, at the end of
15 s, the combustion has either clearly ceased or continues. In
cases of doubt, the material must be deemed to sustain combustion.
Secs. 173.201, 173.202, 173.203, 173.211, 173.212, 173.213 [Amended]
82. In addition to the amendments set forth above, part 173 is
amended by removing the wording ``4A1 or 4A2'' and inserting in its
place ``4A'' each place it appears; removing the wording ``4B1 or 4B2''
and inserting in its place ``4B'' each place it appears; and by
removing the wording ``6HH'' and inserting in its place ``6HH1'' each
place it appears in the following sections:
a. Section 173.201(b) and (c)
b. Section 173.202(b) and (c)
c. Section 173.203(b) and (c)
d. Section 173.211(b) and (c)
e. Section 173.212(b) and (c)
f. Section 173.213(b) and (c)
PART 175--CARRIAGE BY AIRCRAFT
83. The authority citation for part 175 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
84. In Sec. 175.10, paragraphs (a)(4) introductory text and (a)(13)
are revised, paragraph (a)(17) is removed and reserved, and a new
paragraph (a)(26) is added to read as follows:
Sec. 175.10 Exceptions
(a) * * *
(4) Non-radioactive medicinal and toilet articles (including
aerosols) carried by a crew member or passenger in checked or carry-on
baggage. Also aerosols in Division 2.2, with no subsidiary risk, for
sporting or home use, when carried in checked baggage only, when:
* * * * *
(13) Carbon dioxide, solid (dry ice) when:
(i) In quantities not exceeding 2.3 kg (5.07 pounds) per package
packed as prescribed by Sec. 173.217 of this subchapter and used as a
refrigerant for the contents of the package. The package must be marked
with the name of the contents being cooled, the net weight of the dry
ice or an indication that the net weight is 2.3 kg (5.07 pounds) or
less, and also marked ``Carbon Dioxide, Solid'' or ``Dry Ice'';
(ii) Intended for use in food and beverage service aboard aircraft;
or
(iii) In quantities not exceeding 2 kg (4.4 pounds) per passenger
when used to pack perishables in carry-on baggage provided the package
permits the release of carbon dioxide gas.
* * * * *
(26) A small medical or clinical mercury thermometer for personal
use, when carried in protective cases by passengers or crew members.
Sec. 175.10 [Amended]
85. In addition, in Sec. 175.10, in paragraph (a)(12) introductory
text, the wording ``environmental restoration or protection,'' is added
immediately following ``weather control,'' and immediately preceding
``forest preservation''.
86. In Sec. 175.33, a new sentence is added in paragraph (a)(1)
introductory text after the first sentence to read as follows:
Sec. 175.33 Notification of pilot-in-command
(a) * * *
(1) * * * In the case of Class 1 material, the compatibility group
letter also must be shown. * * *
* * * * *
Sec. 175.33 [Amended]
87. In addition, in Sec. 175.33, in paragraph (a)(6), the word
``and'' at the end of the sentence is removed; and in paragraph (a)(7),
the period at the end of the sentence is removed and replaced with ``;
and''.
PART 176--CARRIAGE BY VESSEL
88. The authority citation for part 176 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
89. A new paragraph (c) is added in Sec. 176.27 to read as follows:
Sec. 176.27 Certificate
* * * * *
(c)(1) A person responsible for packing or loading a freight
container or transport vehicle containing hazardous materials for
transportation by a manned vessel in ocean or coastwise service, must
provide the vessel operator, at the time the shipment is offered for
transportation by vessel, with a signed container packing certificate
stating, at a minimum, that--
(i) The freight container or transport unit is serviceable for the
materials loaded therein, contains no incompatible goods, and is
properly marked, labeled or placarded, as applicable; and
(ii) When the freight container or transport unit contains
packages, those packages have been inspected prior to loading, are
properly marked, labeled or placarded, as applicable; are not damaged;
and are properly secured.
(2) The certification may appear on a shipping paper or on a
separate document as a statement such as ``It is declared that the
packing of the container has been carried out in accordance with the
provisions of 49 CFR 176.27(c)''.
90. In Sec. 176.76, a new paragraph (i) is added to read as
follows:
Sec. 176.76 Transport vehicles, freight containers, and portable tanks
containing hazardous materials.
* * * * *
(i) A fumigated transport unit may only be transported on board a
vessel subject to the following conditions and limitations:
(1) The fumigated transport unit may be placed on board a vessel
only if at least 24 hours have elapsed since the unit was last
fumigated;
(2) The fumigated transport unit is accompanied by a document
showing the date of fumigation and the type and amount of fumigant
used;
(3) Prior to loading, the master is informed of the intended
placement of the fumigated transport unit on board the vessel and the
information provided on the accompanying document;
(4) Equipment that is capable of detecting the fumigant and
instructions for the equipment's use is provided on the vessel;
(5) The fumigated transport unit must be stowed at least five
meters from any opening to accommodation spaces;
(6) Fumigated transport units may only be transported on deck on
vessels carrying more than 25 passengers; and
(7) Fumigants may not be added to transport units while on board a
vessel.
PART 177--CARRIAGE BY PUBLIC HIGHWAY
91. The authority citation for part 177 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
Sec. 177.841 [Amended]
92. In Sec. 177.841, in paragraph (e)(3), the wording ``is
separated as required in Sec. 177.848(e)(3) for classes identified with
the letter `O' in the Segregation Table for Hazardous Materials.'' is
revised to read ``is separated in a manner that, in the event of
leakage from packages under conditions normally incident to
transportation, commingling of hazardous materials with foodstuffs,
feed, or any other edible material would not occur.''.
PART 178--SPECIFICATIONS FOR PACKAGINGS
93. The authority citation for part 178 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
94. In Sec. 178.2, paragraph (a) is revised and paragraph (e) is
added to read as follows:
Sec. 178.2 Applicability and responsibility.
(a) Applicability. (1) The requirements of this part apply to
packagings manufactured--
(i) To a DOT specification, regardless of country of manufacture;
or
(ii) To a UN standard, for packagings manufactured within the
United States. For UN standard packagings manufactured outside the
United States, see Sec. 173.24(d)(2) of this subchapter. For UN
standard packagings for which standards are not prescribed in this
part, see Sec. 178.3(b).
(2) A manufacturer of a packaging subject to the requirements of
this part is primarily responsible for compliance with the requirements
of this part. However, any person who performs a function prescribed in
this part shall perform that function in accordance with this part.
* * * * *
(e) Definitions. For the purpose of this part--
Manufacturer means the person whose name and address or symbol
appears as part of the specification markings required by this part or,
for a packaging marked with the symbol of an approval agency, the
person on whose behalf the approval agency certifies the packaging.
Specification markings mean the packaging identification markings
required by this part including, where applicable, the name and address
or symbol of the packaging manufacturer or approval agency.
95. In Sec. 178.3, paragraph (a) introductory text, the first
sentence of paragraph (a)(2) and paragraph (b) are revised, a sentence
is added at the end of paragraph (a)(4), and a new paragraph (a)(5) is
added, to read as follows:
Sec. 178.3 Marking of packagings.
(a) Each packaging represented as manufactured to a DOT
specification or a UN standard must be marked with specification
markings conforming to the applicable specification, and with the
following:
* * * * *
(2) Unless otherwise specified in this part, with the name and
address or symbol of the packaging manufacturer or, where specifically
authorized, the symbol of the approval agency certifying compliance
with a UN standard. * * *
* * * * *
(4) * * * For packagings having a capacity of 5 L (1 gallon) or 5
kg (11 pounds) or less, letters and numerals must be of an appropriate
size.
(5) For packages with a gross mass of more than 30 kg (66 pounds),
the markings or a duplicate thereof must appear on the top or on a side
of the packaging.
(b) A UN standard packaging for which the UN standard is set forth
in this part may be marked with the United Nations symbol and other
specification markings only if it fully conforms to the requirements of
this part. A UN standard packaging for which the UN standard is not set
forth in this part may be marked with the United Nations symbol and
other specification markings for that standard as provided in the ICAO
Technical Instructions or Annex 1 of the IMDG Code subject to the
following conditions:
(1) The U.S. manufacturer must establish that the packaging
conforms to the applicable provisions of the ICAO Technical
Instructions or Annex 1 of the IMDG Code, respectively.
(2) If an indication of the name of the manufacturer or other
identification of the packaging as specified by the competent authority
is required, the name and address or symbol of the manufacturer or the
approval agency certifying compliance with the UN standard must be
entered. Symbols, if used, must be registered with the Associate
Administrator for Hazardous Materials Safety.
(3) The letters ``USA'' must be used to indicate the State
authorizing the allocation of the specification marks if the packaging
is manufactured in the United States.
* * * * *
Sec. 178.502 [Amended]
96. In Sec. 178.502, the following changes are made:
a. In the paragraph (a) introductory text, the word ``types'' is
revised to read ``kinds''.
b. In the paragraph (a)(1) introductory text and the first sentence
in paragraph (a)(3), the word ``type'' is revised to read ``kind''.
97. In Sec. 178.503, paragraph (d) is redesignated paragraph (e);
new paragraphs (a)(11) and (d) are added; paragraph (a) introductory
text, paragraphs (a)(9), (a)(10), and (c) are revised; and newly
designated paragraph (e)(3) is amended by revising the illustration, to
read as follows:
Sec. 178.503 Marking of packagings.
(a) A manufacturer must mark every packaging that is represented as
manufactured to meet a UN standard with the marks specified in this
section. The markings must be durable, legible and placed in a location
and of such a size relative to the packaging as to be readily visible,
as specified in Sec. 178.3(a). Except as otherwise provided in this
section, every reusable packaging liable to undergo a reconditioning
process which might obliterate the packaging marks must bear the marks
specified in paragraphs (a)(1) through (a)(6) and (a)(9) of this
section in a permanent form (e.g. embossed) able to withstand the
reconditioning process. A marking may be applied in a single line or in
multiple lines provided the correct sequence is used. As illustrated by
the examples in paragraph (e) of this section, the following
information must be presented in the correct sequence. Slash marks
should be used to separate this information. A packaging conforming to
a UN standard must be marked as follows:
* * * * *
(9) For metal or plastic drums or jerricans intended for reuse or
reconditioning as single packagings or the outer packagings of a
composite packaging, the thickness of the packaging material, expressed
in millimeters (rounded to the nearest 0.1 mm), as follows:
(i) Metal drums or jerricans must be marked with the nominal
thickness of the metal used in the body. The marked nominal thickness
must not exceed the minimum thickness of the steel used by more than
the thickness tolerance stated in ISO Standard 3574. (See Appendix C of
this part.) The unit of measure is not required to be marked. When the
nominal thickness of either head of a metal drum is thinner than that
of the body, the nominal thickness of the top head, body, and bottom
head must be marked (eg., ``1.0-1.2-1.0'' or ``0.9-1.0-1.0'').
(ii) Plastic drums or jerricans must be marked with the minimum
thickness of the packaging material. Minimum thicknesses of plastic
must be as determined in accordance with Sec. 173.28(b)(4). The unit of
measure is not required to be marked;
(10) In addition to the markings prescribed in paragraphs (a)(1)
through (a)(9) of this section, every new metal drum having a capacity
greater than 100 L must bear the marks described in paragraphs (a)(1)
through (a)(6), and (a)(9)(i) of this section, in a permanent form, on
the bottom. The markings on the top head or side of these packagings
need not be permanent, and need not include the thickness mark
described in paragraph (a)(9) of this section. This marking indicates a
drum's characteristics at the time it was manufactured, and the
information in paragraphs (a)(1) through (a)(6) of this section that is
marked on the top head or side must be the same as the information in
paragraphs (a)(1) through (a)(6) of this section permanently marked by
the original manufacturer on the bottom of the drum; and
(11) Rated capacity of the packaging expressed in liters may be
marked.
* * * * *
(c) Marking of reconditioned packagings. (1) If a packaging is
reconditioned, it shall be marked by the reconditioner near the marks
required in paragraphs (a)(1) through (6) of this section with the
following additional information:
(i) The name of the country in which the reconditioning was
performed (in the United States, use the letters ``USA'');
(ii) The name and address or symbol of the reconditioner. Symbols,
if used, must be registered with the Associate Administrator for
Hazardous Materials Safety;
(iii) The last two digits of the year of reconditioning;
(iv) The letter ``R''; and
(v) For every packaging successfully passing a leakproofness test,
the additional letter ``L''.
(2) When, after reconditioning, the markings required by paragraph
(a)(1) through (a)(5) of this section no longer appear on the top head
or the side of the metal drum, the reconditioner must apply them in a
durable form followed by the markings in paragraph (c)(1) of this
section. These markings may identify a different performance capability
than that for which the original design type had been tested and
marked, but may not identify a greater performance capability. The
markings applied in accordance with this paragraph may be different
from those which are permanently marked on the bottom of a drum in
accordance with paragraph (a)(10) of this section.
(d) Marking of remanufactured packagings. For remanufactured metal
drums, if there is no change to the packaging type and no replacement
or removal of integral structural components, the required markings
need not be permanent (e.g., embossed). Every other remanufactured drum
must bear the marks required in paragraphs (a)(1) through (a)(6) of
this section in a permanent form (e.g., embossed) on the top head or
side. If the metal thickness marking required in paragraph (a)(9)(i) of
this section does not appear on the bottom of the drum, or if it is no
longer valid, the remanufacturer also must mark this information in
permanent form.
(e) * * *
(3) * * *
BILLING CODE 4910-60-P
TR29DE94.001
BILLING CODE 4910-60-C
* * * * *
Sec. 178.503 [Amended]
98. In addition, in Sec. 178.503, the reference
``Sec. 178.503(a)(1) through (a)(10)'' following the illustration in
newly designated paragraph (e)(2) is revised to read
``Sec. 178.503(a)(1) through (a)(9)''.
Sec. 178.508 [Amended]
99. In Sec. 178.508, in paragraph (b)(2), the wording ``plywood or
plastic material'' is revised to read ``plywood, plastics, or other
suitable material''.
100. In Sec. 178.512, paragraphs (a)(3) and (a)(4) are removed and
paragraphs (a)(1), (a)(2), and (b)(2) are revised to read as follows:
Sec. 178.512 Standards for steel or aluminum boxes.
(a) * * *
(1) 4A for a steel box; and
(2) 4B for an aluminum box.
(b) * * *
(2) Boxes must be lined with fiberboard or felt packing pieces or
must have an inner liner or coating of suitable material in accordance
with subpart C of part 173 of this subchapter. If a double seamed metal
liner is used, steps must be taken to prevent the ingress of materials,
particularly explosives, into the recesses of the seams.
* * * * *
101. In Sec. 178.513, paragraphs (b)(2) and (b)(3) are redesignated
as paragraphs (b)(3) and (b)(4), respectively, and a new paragraph
(b)(2) is added to read as follows:
Sec. 178.513 Standards for boxes of natural wood.
* * * * *
(b) * * *
(2) Fastenings must be resistant to vibration experienced under
normal conditions of transportation. End grain nailing must be avoided
whenever practicable. Joints which are likely to be highly stressed
must be made using clenched or annular ring nails or equivalent
fastenings.
* * * * *
Sec. 178.516 [Amended]
102. In Sec. 178.516, the following changes are made:
a. In paragraph (b)(1), at the end of the second sentence, the
wording ``ISO International Standard 535-1976(E)'' is revised to read
``ISO International Standard 535''.
b. In paragraph (b)(2), at the end of the first sentence, the
wording ``of wood.'' is revised to read ``of wood or other suitable
material.''; and in the second sentence the wording ``or other suitable
material'' is added immediately following the word ``battens''.
c. Paragraphs (b)(4) and (b)(5) are redesignated as paragraphs
(b)(5) and (b)(6), and paragraph (b)(3)(iii) is redesignated as
paragraph (b)(4).
Sec. 178.521 [Amended]
103. In Sec. 178.521, in paragraph (b)(2), in the penultimate
sentence, the wording ``water-resistant ply or barrier must also be
placed'' is revised to read ``waterproof ply or barrier, such as
double-tarred kraft paper, plastics-coated kraft paper, plastics film
bonded to the inner surface of the bag, or one or more inner plastics
liners, must also be placed''.
104. In Sec. 178.522, paragraphs (a)(10) and (b)(3)(viii) are
revised, and paragraphs (a)(11) and (b)(3)(ix) are added to read as
follows:
Sec. 178.522 Standards for composite packagings with inner plastic
receptacles.
(a) * * *
(10) 6HH1 for a plastic receptacle within a protective plastic
drum; and
(11) 6HH2 for a plastic receptacle within a protective plastic box.
(b) * * *
(3) * * *
(viii) 6HH1: Protective packaging must conform to the requirements
for plastic drums, in Sec. 178.509(b).
(ix) 6HH2: Protective packaging must conform to the requirements
for plastic boxes, in Sec. 178.517(b).
* * * * *
Sec. 178.522 [Amended]
105. In addition, in Sec. 178.522, the following changes are made:
a. In paragraph (a)(9), the word ``and'' at the end of the
paragraph is removed.
b. In paragraph (b)(4), the wording ``6HH'' is revised to read
``6HH1''; and the wording ``, 6HH2'' is added immediately following
``6HG2''.
c. In paragraph (b)(5), the wording ``6HH'' is revised to read
``6HH1'', and the wording ``, 6HH2'' is added immediately following
``6HG2''.
106. In Sec. 178.601, paragraph (k) is redesignated as paragraph
(l) and revised, a new paragraph (k) is added, and paragraphs (b),
(g)(2)(i), and (g)(2)(vi) are revised to read as follows:
Sec. 178.601 General requirements.
* * * * *
(b) Responsibility. It is the responsibility of the packaging
manufacturer to assure that each package is capable of passing the
prescribed tests. To the extent that a package assembly function,
including final closure, is performed by the person who offers a
hazardous material for transportation, that person is responsible for
performing the function in accordance with Secs. 173.22 and 178.2 of
this subchapter.
* * * * *
(g) * * *
(2) * * *
(i) The outer packaging must have been successfully tested in
accordance with Sec. 178.603 with fragile (e.g. glass) inner packagings
containing liquids at the Packing Group I drop height;
* * * * *
(vi) When the outer packaging is intended to contain inner
packagings for liquids and is not leakproof, or is intended to contain
inner packagings for solids and is not siftproof, a means of containing
any liquid or solid contents in the event of leakage must be provided
in the form of a leakproof liner, plastic bag, or other equally
efficient means of containment. For packagings containing liquids, the
absorbent material required in paragraph (g)(2)(v) of this section must
be placed inside the means of containing liquid contents; and
* * * * *
(k) Number of test samples. Provided the validity of the test
results is not affected and with the approval of the Associate
Administrator for Hazardous Materials Safety, several tests may be
performed on one sample.
(l) Record retention. Following each design qualification test and
each periodic retest on a packaging, a test report must be prepared.
The test report must be maintained at each location where the packaging
is manufactured and each location where the design qualification tests
are conducted, for as long as the packaging is produced and for at
least two years thereafter, and at each location where the periodic
retests are conducted until such tests are successfully performed again
and a new test report produced. In addition, a copy of the test report
must be maintained by a person certifying compliance with this part.
The test report must be made available to a user of a packaging or a
representative of the Department upon request. The test report, at a
minimum, must contain the following information:
(1) Name and address of test facility;
(2) Name and address of applicant (where appropriate);
(3) A unique test report identification;
(4) Date of the test report;
(5) Manufacturer of the packaging;
(6) Description of the packaging design type (e.g. dimensions,
materials, closures, thickness, etc.), including methods of manufacture
(e.g. blow molding) and which may include drawing(s) and/or
photograph(s);
(7) Maximum capacity;
(8) Characteristics of test contents, e.g. viscosity and relative
density for liquids and particle size for solids;
(9) Test descriptions and results; and
(10) Signed with the name and title of signatory.
Sec. 178.601 [Amended]
107. In addition, in Sec. 178.601, the following changes are made:
a. In paragraph (g)(2) introductory text, the wording ``Inner
packagings'' are revised to read ``Articles or inner packagings''.
b. In paragraph (g)(5)(i), the reference ``Sec. 178.602'' is
revised to read ``Sec. 178.603''.
c. In paragraph (g)(5)(ii), the reference ``Sec. 178.603'' is
revised to read ``Sec. 178.604''.
Sec. 178.602 [Amended]
108. In Sec. 178.602, in the second sentence of paragraph (c), the
reference ``Sec. 178.603(d)(2)'' is revised to read
``Sec. 178.603(e)''.
109. In Sec. 178.603, in paragraph (a) introductory text, a
sentence is added following the second sentence, the first sentence in
paragraph (c) is revised, and paragraph (f)(1) is revised to read as
follows:
Sec. 178.603 Drop test.
(a) * * * Where more than one orientation is possible for a given
drop test, the orientation most likely to result in failure of the
packaging must be used.* * *
* * * * *
(c) * * * Testing of plastic drums, plastic jerricans, plastic
boxes other than expanded polystyrene boxes, composite packagings
(plastic material), and combination packagings with plastic inner
packagings other than plastic bags intended to contain solids or
articles must be carried out when the temperature of the test sample
and its contents has been reduced to -18 deg.C (0 deg.F) or lower. *
* *
* * * * *
(f) * * *
(1) For packagings containing liquid, each packaging does not leak
when equilibrium has been reached between the internal and external
pressures, except for inner packagings of combination packagings when
it is not necessary that the pressures be equalized;
* * * * *
Sec. 178.604 [Amended]
110. In Sec. 178.604, in paragraph (d), in the second sentence, the
wording ``for a period of time sufficient to pressurize the interior of
the packaging to the specified air pressure and to determine if there
is leakage of air from the packaging'' is revised to read ``, for other
than production testing, for a minimum time of five minutes''.
Sec. 178.606 [Amended]
111. In Sec. 178.606, in paragraph (c)(1), at the end of the first
sentence, the period is removed and replaced with a semicolon and the
phrase ``where the contents of the test sample are non-hazardous
liquids with specific gravities different from that of the liquid to be
transported, the force must be calculated based on the specific gravity
that will be marked on the packaging'' is added immediately following
the semicolon.
112. Appendix C is added to Part 178 to read as follows:
Appendix C to Part 178--Nominal and Minimum Thicknesses of Steel Drums
and Jerricans
For each listed packaging capacity, the following table compares
the ISO Standard 3574 nominal thickness with the corresponding ISO
Standard 3574 minimum thickness.
------------------------------------------------------------------------
ISO Corresponding
Maximum capacity (L) nominal ISO minimum
(mm) (mm)
------------------------------------------------------------------------
20........................................... 0.7 0.63
30........................................... 0.8 0.73
40........................................... 0.8 0.73
60........................................... 1.0 0.92
120.......................................... 1.0 0.92
220.......................................... 1.0 0.92
450.......................................... 1.9 1.77
------------------------------------------------------------------------
Issued in Washington, DC on December 14, 1994 under authority
delegated in 49 CFR part 1.
Ana Sol Gutierrez,
Deputy Administrator, Research and Special Programs Administration.
[FR Doc. 94-31175 Filed 12-28-94; 8:45 am]
BILLING CODE 4910-60-P
