04-27087. Harmonization With the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions
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AGENCY:
Research and Special Programs Administration (RSPA), DOT.
ACTION:
Final rule.
SUMMARY:
RSPA is amending the Hazardous Materials Regulations (HMR) to maintain alignment with international standards by incorporating various amendments, including changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. Because of recent changes to the International Maritime Dangerous Goods Code (IMDG Code), the International Civil Aviation Organization's Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), and the United Nations Recommendations on the Transport of Dangerous Goods (UN Recommendations), these revisions are necessary to facilitate the transport of hazardous materials in international commerce.
DATES:
The effective date of these amendments is January 1, 2005
Delayed Compliance Date: Unless otherwise specified, compliance with the amendments adopted in this final rule is required beginning January 1, 2006.
Incorporation by Reference Date: The incorporation by reference of the publications adopted in § 171.7 of this final rule have been approved by the Director of the Federal Register as of January 1, 2005.
Start Further InfoFOR FURTHER INFORMATION CONTACT:
Charles Betts, Office of Hazardous Materials Standards, telephone (202) 366-8553, or Shane Kelley, International Standards, telephone (202) 366-0656, Research and Special Programs Administration, U.S. Department of Transportation, 400 Seventh Street, SW., Washington, DC 20590-0001.
End Further Info End Preamble Start Supplemental InformationSUPPLEMENTARY INFORMATION:
Contents
I. Background
II. Overview of Changes in this Final Rule
III. Overview of Amendments Not Being Considered for Adoption in this Final Rule
IV. Section-By-Section Review
V. Regulatory Analyses and Notices
A. Statutory/Legal Authority for this Rulemaking
B. Executive Order 12866 and DOT Regulatory Policies and Procedures
E. Regulatory Flexibility Act, Executive Order 13272, and DOT Regulatory Policies and Procedures
F. Paperwork Reduction Act
G. Regulatory Identifier Number (RIN)
H. Unfunded Mandates Reform Act
I. Environmental Assessment
J. Privacy Act
I. Background
On December 21, 1990, RSPA (we) published a final rule (Docket HM-181; 55 FR 52402) based on the UN Recommendations, which comprehensively revised the Hazardous Materials Regulations (HMR), 49 CFR Parts 171 to 180, for harmonization with international standards. Since publication of the 1990 final rule we have issued five additional international harmonization final rules (Dockets HM-215A, 59 FR 67390; HM-215B, 62 FR 24690; HM-215C, 64 FR 10742; HM-215D, 66 FR 33316; and HM-215E, 68 FR 44992). The rules provided additional harmonization with international transportation requirements by more fully aligning the HMR with the corresponding biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions.
The UN Recommendations are not regulations, but rather are recommendations issued by the UN Committee of Experts on the Transport of Dangerous Goods (TDG) and on the Globally Harmonized System of Classification and Labeling (GHS). These recommendations are amended and updated biennially by the UN Committee of Experts. They serve as the basis for National, regional, and international modal regulations; specifically, the IMDG Code issued by the International Maritime Organization (IMO), and the ICAO Technical Instructions issued by the ICAO. In 49 CFR 171.12, the HMR authorize domestic transportation of hazardous materials shipments prepared in accordance with the IMDG Code if all or part of the transportation is by vessel, subject to certain conditions and limitations. In § 171.11, subject to certain conditions and limitations, the HMR authorize the offering, acceptance and transport of hazardous materials by aircraft, and by motor vehicle either before or after being transported by aircraft, provided the shipment is in accordance with the ICAO Technical Instructions.
The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation and at the same time ensures the safety of people, property and the environment. While the intent of the harmonization rulemakings is to align the HMR with international standards, we review and consider each amendment on its own merit. Each amendment is considered on the basis of the overall impact on transportation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without diminishing the level of safety currently provided by the HMR and without imposing undue burdens on the regulated public. In our efforts to continue to align the HMR with international requirements, this final rule incorporates changes into the HMR based on the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. Petitions for rulemaking concerning harmonization with international standards and additional measures concerning facilitation of international transportation are also addressed in this final rule and serve as the basis of certain amendments. Other amendments are based on feedback from the regulated industry, other DOT modal administrations and our initiative. Also included are various editorial clarifications. Unless otherwise stated, the revisions are for harmonization with international standards.
II. Overview of Changes in This Final Rule
Amendments to the HMR in this final rule include, but are not limited to the following:
—Amendments to the Hazardous Materials Table (HMT) which add, revise or remove certain proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, bulk packaging requirements, passenger and cargo aircraft maximum quantity limitations and vessel stowage provisions. Start Printed Page 76045
—Amendments to the List of Marine Pollutants.
—Revisions and additions of special provisions.
—Removal of the air eligibility marking requirement.
—Addition of a “KEEP AWAY FROM HEAT” marking requirement for packages offered for transportation by air.
—Amendment to require that aerosols that are carried aboard an aircraft in accordance with § 175.10(a)(4) have their release devices protected by a cap or other suitable means.
—A grandfather provision to allow the shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72.
— A provision to require that the word “overpack” be marked on overpacks to indicate that inside packages comply with prescribed specifications.
—An amendment to the criteria for classification of materials that are corrosive to metals.
—Revision of the limited quantity provisions for Class 6.1, PG II materials and for materials with a subsidiary hazard of 6.1, PG II.
—Amendments to the packaging requirements for materials classified as Division 6.1, Packing Group I, Hazard Zone A or Hazard Zone B.
—Revision of the organic peroxide packaging requirements in order to have one consolidated packaging section for organic peroxides. The revised section will include three separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs, respectively. Additionally, the packaging tables will be updated through the amendments to the organic peroxide requirements that will add, revise, or delete certain entries in the organic peroxide tables.
III. Overview of Amendments Not Being Considered for Adoption in This Final Rule
This final rule makes changes to the HMR based on amendments to the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. However, we are not adopting all of the amendments to those documents into the HMR. In many cases, amendments to the international regulation have not been adopted because of the framework or structure of the HMR. In several cases, we are handling certain amendments in separate rulemakings. For example, all amendments related to infectious substances are being handled under Docket HM-226A. In some instances, such as the amendment to ICAO Technical Instructions to allow certain oxygen generators aboard passenger carrying aircraft, we do not believe the amendment to be in the interest of public safety.
One of the goals of this rulemaking is to continue to maintain consistency between the HMR and the international requirements. We are not striving to make the HMR identical to the international regulations but rather striving to remove or avoid potential barriers to international transportation.
Below is a listing of those significant amendments to the international regulations that we have not included in this final rule with a brief explanation of why the amendment was not included:
- Requirements for infectious substances and genetically modified micro-organisms;
[Amendments to the HMR related to infectious substances will be addressed in a future rulemaking under Docket HM-226A. Several other federal agencies regulate genetically modified micro-organisms; thus we do not plan to adopt provisions for their transport in the HMR.]
- Compressed gas cylinders;
[Amendments to the HMR related to compressed gas cylinders will be addressed in a future rulemaking under Docket HM-220E.]
- Environmentally hazardous substances;
[Delay in action pending further amendments to the international regulations.]
- Hazardous materials security;
[Amendments to the HMR related to the UN Model Regulation's hazardous materials security requirements were promulgated in a rulemaking under the HM-232 Docket series.]
- Requirements for radioactive materials;
[Amendments to the HMR related to Class 7 (radioactive) materials are being addressed in a rulemaking under the HM-230 Docket series.]
- Non-specification bulk packagings;
[We are not adopting the new requirements in the UN Recommendations for non-specification bulk packagings including the additional inspection, testing and marking requirements. We are unsure about the cost impacts of imposing these additional amendments and, therefore, are not adopting any additional amendments at this time.]
- The reference to EN 10028-3, Part 3 for defining steel grain size relevant to the definition of fine grain steel;
[We do not believe there is a need to adopt the European standard EN 10028-3, Part 3 because this standard is equivalent to ASTM E 112-96 (IBR, see § 171.7 of this subchapter). In addition, the ASTM standard is currently referenced in the HMR and is more commonly used and recognized in the U.S.]
- Bulk authorization for UN0331, UN0332 and UN3375;
[For several years, we have authorized, under exemption, the transport of certain blasting agents in bulk packagings. We are currently reviewing those exemptions to determine if they should be included in the HMR. The amendments in the UN Recommendations related to the bulk authorizations for UN0331, UN0332 and UN3375 will be included in that review.]
- The removal of wooden barrel requirements;
[The removal of the wooden barrel requirements (2C1 and 2C2) may be considered in a future rulemaking.]
- The 24-hour gasket relaxation requirement;
[A requirement that removable head packagings for liquids not be drop tested until at least 24 hours after filling and closing to allow for any possible gasket relaxation was adopted in the thirteenth revised edition of the UN Model Regulations. We have conducted testing in coordination with drum manufacturers and have determined that this requirement is not substantiated by the results of the tests conducted. Therefore, we are not adopting into the HMR amendments relative to the 24-hour gasket relaxation requirement. We also opposed this requirement when it was considered by the UN TDG Sub-Committee.]
- Authorization to transport protective breathing equipment (PBE's) with an oxygen generator as cargo onboard a passenger-carrying aircraft.
[We do not believe that oxygen generators should be transported aboard passenger carrying aircraft. Therefore, we are not adopting the ICAO amendment that would allow oxygen generators in protective breathing equipment to be transported in passenger carrying aircraft.]
IV. Section-By-Section Review
Part 171
Section 171.7
Paragraph (a)(3) (incorporation by reference materials) is updated to include the most recent editions of the Start Printed Page 76046ICAO Technical Instructions, the IMDG Code and the UN Recommendations. The updated editions of these standards become effective January 1, 2005. Additionally, the International Maritime Organization (IMO) recommends authorizing a one-year transition period, with a delayed compliance date of January 1, 2006, for the use of the updated edition (Amendment 32) of the IMDG Code.
The updated additions are as follows:
—The ICAO Technical Instructions, 2005-2006 Edition.
—The IMDG Code, Amendment 32.
—The UN Recommendations, Thirteenth Edition.
—The UN Manual of Tests and Criteria, 4th Revised Edition.
Paragraph (b) (list of informational materials not requiring incorporation by reference) is revised by adding an additional reference for a new method for determining the size of an emergency-relief device for portable tanks transporting organic peroxides. This revision is based on a petition for rulemaking numbered P-1428. The petition was submitted by the Organic Peroxides Producers Safety Division of the Society of the Plastics Industry, Inc.
One commenter recommended that we revise the “Note to Paragraph (h)(3)(vi)” in § 173.225 to maintain format consistency with the incorporation by reference entry for “Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology” found in § 171.7(a). We disagree. The reference to a second example of a test method for venting sizing is not found in § 171.7(a) as a material incorporated by reference. Rather, it is found in § 171.7(b) as informational material not requiring incorporation by reference. Therefore, for clarification we are revising § 171.7(b) to include the reference to the “American Institute of Chemical Engineers Process Safety Progress Journal.” In addition, we are revising the “Note to Paragraph (h)(3)(vi)” in § 173.225 to include a reference to § 171.7(b), list of informational materials not requiring incorporation by reference.
Section 171.8
The definition for “salvage packaging” is revised to include the term “non-conforming.” The term “non-conforming” was added to the definition by the UN Committee of Experts in December 2000 to accommodate the use of salvage packaging for. Occasionally an undamaged package is found to be tested to a performance level which is less than that required for the specific substance it contains (e.g., a drum tested to PG II standards containing a PG I substance). In other instances, the package is found to be a non-performance tested packaging containing a regulated substance. In these situations, it may not be safe or practical to transfer the material to the correct packaging to continue on to the consignee in order to ensure compliance with the HMR. Therefore, the use of salvage packaging to contain “non-conforming” packages will minimize the risk to those handling the package during its transport back to the shipper or to an appropriate disposal location.
Section 171.11
Paragraph (d)(15) is revised to clarify that the limitations therein also apply to oxygen generators contained in personal breathing equipment. In addition, paragraph (d)(17) is revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d).
Section 171.12
In § 171.12, paragraph (b)(20) is revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d).
Section 171.12a
Paragraph (a) is revised to clarify the requirements for the return to Canada of bulk packagings that correspond to DOT or UN Specifications. Paragraph (b)(9)(ii) is revised to indicate that the shipping certification must be completed for shipments from Canada that enter the U.S. Paragraph (b)(18) is revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.22 must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d).
Section 171.14
Paragraphs (d) and (d)(1) are revised to authorize a delayed implementation date for the amendments in this final rule. The effective date of this final rule is January 1, 2005. We are also, authorizing a delayed compliance date of January 1, 2006, which is comparable to the transitional provisions provided in the final rule published under Docket HM-215E. The delayed mandatory compliance date offers sufficient time to implement the new requirements.
Paragraph (d)(2) is revised to authorize certain intermixing of old and new requirements.
Part 172
Section 172.101
The regulatory text preceding the Hazardous Materials Table is revised as follows:
Paragraph (c)(11) and the corresponding note to paragraph (c)(11) are amended to revise a section reference. The reference to § 173.225(c) in the first sentence is revised to read § 173.225(b) and the reference to § 173.225(c)(2) in the note to paragraph (c)(11) is revised to read § 173.225(b)(2).
Paragraph (d)(4) is revised by adding a statement indicating that when the abbreviation “Comb liq.” is found in the “Hazard class or division” column of the Hazardous Materials Table (column 3), the material falls into the “Combustible liquid” hazard class.
Paragraph (i)(3) of this section is revised to specify that Column 7 of the Hazardous Materials Table contains additional bulk packaging authorizations and limitations for the use of UN portable tanks.
§ 172.101 The Hazardous Materials Table (HMT). In this final rule we made various amendments to the HMT. Readers should review all changes for a complete understanding of the Table amendments. The HMT has been reprinted in its entirety due to the numerous changes. Under this final rule the changes to the HMT for the purpose of harmonizing with international standards, unless otherwise stated, include, but are not limited to the following:
- We revised several entries by adding the qualifying word “liquid.” This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries are as follows:
UN1392 Alkaline earth metal amalgam
UN1420 Potassium metal alloys
UN1422 Potassium sodium alloys
UN1701 Xylyl bromide
UN1742 Boron trifluoride acetic acid complex
UN1743 Boron trifluoride propionic acid complex
UN2235 Chlorobenzyl chlorides
UN2236 3-Chloro-4-methylphenyl isocyanate
UN2306 Nitrobenzotrifluorides
UN2445 Lithium alkyls
UN2552 Hexafluoroacetone hydrate
UN2937 alpha-Methylbenzyl alcohol Start Printed Page 76047
UN3276 Nitriles, toxic, n.o.s.
UN3278 Organophosphorus compound, toxic, n.o.s.
UN3280 Organoarsenic compound, n.o.s.
UN3282 Organometallic compound, toxic, n.o.s.
UN3281 Metal carbonyls, n.o.s.
- We revised several entries by adding the qualifying word “solid.” This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries are as follows:
UN1445 Barium chlorate
UN1447 Barium perchlorate
UN1459 Chlorate and magnesium chloride mixture
UN1470 Lead perchlorate
UN1578 Chloronitrobenzenes
UN1579 4-Chloro-o-toluidine hydrochloride
UN1650 beta-Naphthylamine
UN1680 Potassium cyanide
UN1689 Sodium cyanide
UN1690 Sodium fluoride
UN1697 Chloroacetophenone
UN1709 2,4-Toluylenediamine
UN1812 Potassium fluoride
UN1843 Ammonium dinitro-o-cresolate
UN2074 Acrylamide
UN2239 Chlorotoluidines
UN2261 Xylenols
UN2446 Nitrocresols
UN2662 Hydroquinone
UN3283 Selenium compound, n.o.s.
- We revised several entries by removing the qualifying word “solid.” This action provides consistency with the Thirteenth Revised Edition of the UN Recommendations. The affected entries are as follows:
UN1489 Potassium perchlorate, solid
UN1598 Dinitro-o-cresol, solid
UN1638 Mercury iodide, solid
UN1740 Hydrogendifluorides, n.o.s. solid
UN2439 Sodium hydrogendifluoride, solid
- We deleted several entries. This action removes from the HMR the solution form of entries that are not identified as solutions in the Thirteenth Revised Edition of the UN Recommendations. The deleted entries are as follows:
UN1489 Potassium perchlorate, solution
UN1598 Dinitro-o-cresol, solution
UN1638 Mercury iodide, solution
UN1740 Hydrogendifluorides, n.o.s. solutions
UN2439 Sodium hydrogendifluoride solution
- We revised the proper shipping name “Butadienes, stabilized,” UN1010 to read “Butadienes, stabilized or Butadienes and hydrocarbon mixture, stabilized, containing more than 40% butadienes.”
- We revised the proper shipping name “Potassium hydrogendifluoride, solid,” UN1811 to read “Potassium hydrogendifluoride, solid.”
- We revised the proper shipping name “Refrigerating machines, containing non-flammable, non-toxic, liquefied gas or ammonia solution (UN2672),” UN2857 to read “Refrigerating machines containing non-flammable, non-toxic gases or ammonia solutions (UN2672).”
- We removed four references to IB52 and four references to T23 from column 7 of the HMT. This change is necessary because IB52 and T23 have been relocated to § 173.225. The affected entries are:
UN3109 Organic peroxide type F, liquid
UN3110 Organic peroxide type F, solid
UN3119 Organic peroxide type F, liquid, temperature controlled
UN3120 Organic peroxide type F, solid, temperature controlled
- IP5 is removed from column 7 of the HMT for the following UN entries:
UN1791 Hypochlorite solution
UN2014 Hydrogen peroxide, aqueous solution with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary).
UN3149 Hydrogen peroxide and peroxyacetic acid mixture with acid(s), water and not more than 5% peroxyacetic acid.
- We deleted several entries. This action is consistent with the deletion of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations that we are proposing to adopt into the HMR. The entries affected are:
UN2003 Metal alkyls, water-reactive, n.o.s. or Metal aryls, water-reactive, n.o.s.
UN3049 Metal alkyl halides, water-reactive, n.o.s. or Metal aryl halides, water-reactive, n.o.s.
UN3050 Metal alkyl hydrides, water-reactive, n.o.s. or Metal aryl hydrides, water-reactive, n.o.s.
UN3207 Organometallic compound or Compound solution or Compound dispersion, water-reactive, flammable, n.o.s.
UN3203 Pyrophoric organometallic compound, water-reactive, n.o.s., liquid Pyrophoric organometallic compound, water-reactive, n.o.s., solid
UN3372 Organometallic compound, solid, water-reactive, flammable, n.o.s.
- We added the following new entries. Many of these entries are the liquid or solid form of entries that are already listed in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. The new entries are as follows:
UN3377 Sodium perborate monohydrate
UN3378 Sodium carbonate peroxyhydrate
UN3379 Desensitized explosives, liquid, n.o.s.
UN3380 Desensitized explosives, solid, n.o.s.
UN3401 Alkali metal amalgam, solid
UN3402 Alkaline earth metal amalgam, solid
UN3403 Potassium metal alloys, solid
UN3404 Potassium sodium alloys, solid
UN3405 Barium chlorate solution
UN3406 Barium perchlorate solution
UN3407 Chlorate and magnesium chloride mixture solution
UN3408 Lead perchlorate solution
UN3409 Chloronitrobenzenes, liquid
UN3410 4-Chloro-o-toluidine hydrochloride solution
UN3411 beta-Naphthylamine solution
UN3413 Potassium cyanide solution
UN3414 Sodium cyanide solution
UN3415 Sodium fluoride solution
UN3416 Chloroacetophenone, liquid
UN3417 Xylyl bromide, solid
UN3418 2,4-Toluylenediamine solution
UN3419 Boron trifluoride acetic acid complex, solid
UN3420 Boron trifluoride propionic, acid complex, solid
UN3421 Potassium hydrogendifluoride solution
UN3422 Potassium fluoride solution
UN3423 Tetramethylammonium hydroxide, solid
UN3424 Ammonium dinitro-o-cresolate solution
UN3425 Bromoacetic acid, solid
UN3426 Acrylamide solution
UN3427 Chlorobenzyl chlorides, solid
UN3428 3-Chloro-4-Methylphenyl isocyanate, solid
UN3429 Chloro-toluidines, liquid
UN3430 Xylenols, liquids
UN3431 Nitrobenzotrifluorides, solid
UN3432 Polychlorinated biphenyls, solid
UN3433 Lithium alkyls, solid
UN3434 Nitrocresols, liquid
UN3435 Hydroquinone solution
UN3436 Hexafluoroacetone hydrate, solid Start Printed Page 76048
UN3437 Chlorocresols, solid
UN3438 alpha-Methylbenzyl alcohol, solid
UN3439 Nitriles, toxic, solid, n.o.s.
UN3440 Selenium compound, liquid, n.o.s.
UN3441 Chlorodinitrobenzenes, solid
UN3442 Dichloroanilines, solid
UN3443 Dinitrobenzenes, solid
UN3444 Nicotine hydrochloride, solid
UN3445 Nicotine sulphate, solid
UN3446 Nitrotoluenes, solid
UN3447 Nitroxylenes, solid
UN3448 Tear gas substance, solid, n.o.s.
UN3449 Bromobenzyl cyanides, solid
UN3450 Diphenylchloroarsine, solid
UN3451 Toluidines, solid
UN3452 Xylidines, solid
UN3453 Phosphoric acid, solid
UN3454 Dinitrotoluenes, solid
UN3455 Cresols, solid
UN3456 Nitrosyl-sulphuric acid, solid
UN3457 Chloronitrotoluenes, solid
UN3458 Nitroanisoles, solid
UN3459 Nitrobromobenzenes, solid
UN3460 N-Ethylbenzyltoluidines, solid
UN3461 Aluminium alkyl halides, solid
UN3462 Toxins, extracted from living sources, solid, n.o.s.
UN3464 Organophosphorus compound, toxic, solid, n.o.s.
UN3465 Organoarsenic compound, solid, n.o.s.
UN3466 Metal carbonyls, solid, n.o.s.
UN3467 Organometallic compound, toxic, solid, n.o.s.
UN3468 Hydrogen in a metal hydride storage system
A commenter stated that by adding the shipping names for desensitized explosives under identification numbers UN3379 and UN3380, approvals should be modified to authorize the use of classifications for the applicable hazardous materials. The commenter also noted that due to these additions, the definitions for flammable solids and flammable liquids require revision to account for the new shipping names. We do not anticipate a significant number of explosives being assigned to these shipping names. Therefore, we disagree with the commenter's contention that each holder of an EX number request an updated shipping classification. In addition, we do not agree with the commenter's request to revise the definitions of flammable solid and flammable liquid to include the additional proper shipping names. The definitions of flammable solid and flammable liquid adequately describe materials assigned to those shipping names. Additionally, shipping names are not found under hazard class definitions, but rather, in the HMT.
- We added the following new generic entries for materials that are toxic by inhalation. These new names will replace the existing generic entries in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries are as follows:
UN3381 Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.
UN3382 Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.
UN3383 Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.
UN3384 Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.
UN3385 Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.
UN3386 Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.
UN3387 Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.
UN3388 Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.
UN3389 Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50.
UN3390 Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50.
- We added the following new generic entries for organometallic substances. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. The new entries are as follows:
UN3391 Organometallic substance, solid, pyrophoric
UN3392 Organometallic substance, liquid, pyrophoric
UN3393 Organometallic substance, solid, pyrophoric, water-reactive
UN3394 Organometallic substance, liquid, pyrophoric, water-reactive
UN3395 Organometallic substance, solid, water-reactive
UN3396 Organometallic substance, solid, water-reactive, flammable
UN3397 Organometallic substance, solid, water-reactive, self-heating
UN3398 Organometallic substance, liquid, water-reactive
UN3399 Organometallic substance, liquid, water-reactive, flammable
UN3400 Organometallic substance, solid, self-heating
In addition, we are continuing to allow the use of the following specific Organometallic entries: UN1366, UN1370, UN2005, UN2445, UN3051, UN3052, UN3053, and UN3076. However, we anticipate removing these entries from the HMT by January 1, 2007.
- The U.N. Recommendations have adopted a rationalized approach for the assignment of UN portable tank instructions for solid materials. Based on that rationalized approach, we made several changes to UN portable tank authorizations in the HMR. These changes are summarized as follows. For a more specific identification of the affected shipping descriptions, refer to the UN report located in the public Docket.
For Division 4.1, Packing Group I materials, the use of UN portable tanks is not authorized.
For Division 4.3 materials with a subsidiary class of 6.1, in Packing Group I, the use of portable tanks is not authorized.
For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group II, Special Provisions T3 is specified.
For Division 4.2, Packing Group I materials, T21 and TP7 is specified.
For Division 4.3, Packing Group I materials, T9 and TP7 is specified.
For Division 5.1, Packing Group I materials, the use of UN portable tanks is not authorized.
For Division 6.1 and Class 8, Packing Group I materials, T6 is specified.
For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group III, Special Provisions T1 is specified.Start Printed Page 76049
- Several entries in the HMT have been revised by amending column 9B to read “forbidden” so that the materials are no longer authorized for transport aboard cargo aircraft. The entries have been revised because they meet the criteria of either Zone C or Zone D inhalation toxicity. All other Zone C and Zone D toxic by inhalation materials listed in the HMR are currently already forbidden from transport aboard passenger and cargo aircraft (these materials are already forbidden from transport aboard passenger aircraft). The entries to be revised include:
Zone C
UN2204 Carbonyl sulfide
UN1023 Coal gas, compressed
UN1064 Methyl mercaptan
UN1048 Hydrogen bromide, anhydrous
UN1079 Sulfur dioxide
Zone D
UN1005 Ammonia, anhydrous
UN3318 Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia
UN1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C
UN1040 Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C
UN2191 Sulfuryl fluoride
Also, see § 172.102 for additional HMT amendments.
Appendix B to § 172.101
In Appendix B to § 172.101, List of Marine Pollutants, we removed the entries “Diphenyl oxide and biphenyl phenyl ether mixtures,” “Isoamyl mercaptan,” “Pentanethiols,” and “Tetrachlorophenol.” We revised the entry “2, 6-Di-tert-Butylphenol” and we added the entry “Chloropicrin.”
Section 172.102
We amended § 172.102, Special Provisions, as follows:
- Several entries in the HMT are revised by adding special provisions A3, A6, A7, A9, A10, N3, and N36 to align this section with the equivalent special provisions in the ICAO Technical Instructions (13, 2, 5, 4, 7, 21, and 3 respectively). We removed the “A” special provisions for several entries because we have determined that the materials to which the provisions apply are currently not authorized for transportation on either passenger or cargo aircraft.
The following entries are revised by adding special provision A3:
UN1154 Diethylamine
UN1788 Hydrobromic acid, not more than 49% strength
UN1789 Hydrochloric acid
UN2031 Nitric acid, other than red fuming, with more than 70% nitric acid
UN2604 Boron trifluoride diethyl etherate
- The following entries are revised by adding A6:
UN1111 Amyl mercaptan
UN1228 Mercaptans, liquid, flammable, toxic, n.o.s.
UN1760 Corrosive liquid, n.o.s.
UN1903 Disinfectants, liquid, corrosive, n.o.s.
UN2031 Nitric acid, other than red fuming, with not more than 70% nitric acid
UN2054 Morpholine
UN2347 Butyl mercaptan
UN2363 Ethyl mercaptan
UN2402 Propanethiols
UN2801 Dye, liquid, corrosive, n.o.s.
UN2920 Corrosive liquid, flammable, n.o.s.
UN2922 Corrosive liquid, toxic, n.o.s.
UN3071 Mercaptans, liquid, toxic, flammable, n.o.s.
UN3093 Corrosive liquid, oxidizing, n.o.s.
UN3093 Corrosive liquid, oxidizing, n.o.s.
UN3094 Corrosive liquid, water-reactive, n.o.s.
UN3094 Corrosive liquid, water-reactive, n.o.s.
UN3098 Oxidizing liquid, corrosive, n.o.s.
UN3099 Oxidizing liquid, toxic, n.o.s.
UN3139 Oxidizing liquid, n.o.s.
UN3145 Alkylphenols, liquid, n.o.s. (including C2-C12 homologues)
UN3264 Corrosive liquid, acidic, inorganic, n.o.s.
UN3265 Corrosive liquid, acidic, organic, n.o.s.
UN3266 Corrosive liquid, basic, inorganic, n.o.s.
UN3267 Corrosive liquid, basic, organic, n.o.s.
UN3301 Corrosive liquid, self-heating, n.o.s.
- The following entries are revised by adding special provision A7:
UN1167 Divinyl ether, stabilized
UN1277 Propylamine
UN1389 Alkali metal amalgam, liquid
UN1389 Alkali metal amalgam, solid
UN1391 Alkali metal dispersion or Alkaline earth metal dispersion
UN1407 Cesium or Caesium
UN1420 Potassium metal alloys
UN1421 Alkali metal alloy, liquid, n.o.s.
UN1422 Potassium sodium alloys
UN1431 Sodium methylate
UN1796 Nitrating acid mixture with not more than 50% nitric acid
UN1796 Nitrating acid mixture with more than 50% nitric acid
UN1826 Nitrating acid mixture, spent with not more than 50% nitric acid
UN1826 Nitrating acid mixture, spent with more than 50% nitric acid
UN1828 Sulphur chlorides
UN1938 Bromoacetic acid
UN2257 Potassium
UN2749 Tetramethylsilane
UN3093 Corrosive liquid, oxidizing, n.o.s.
UN3093 Corrosive liquid, oxidizing, n.o.s.
UN3094 Corrosive liquid, water-reactive, n.o.s.
UN3094 Corrosive liquid, water-reactive, n.o.s.
UN3205 Alkaline earth metal alcoholates, n.o.s.
UN3205 Alkaline earth metal alcoholates, n.o.s.
UN3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s.
UN3206 Alkali metal alcoholates, self-heating, corrosive, n.o.s.
UN3208 Metallic substance, water-reactive, n.o.s.
UN3208 Metallic substance, water-reactive, n.o.s.
UN3208 Metallic substance, water-reactive, n.o.s.
UN3209 Metallic substance, water-reactive, self-heating, n.o.s.
UN3209 Metallic substance, water-reactive, self-heating, n.o.s.
UN3209 Metallic substance, water-reactive, self-heating, n.o.s.
- The following entries are revised by adding special provision A9:
UN1449 Barium peroxide
UN1452 Calcium chlorate
UN3212 Hypochlorites, inorganic, n.o.s.
- The following entries are revised by adding special provision A10:
UN1828 Sulphur chlorides
UN2401 Piperidine
- The following entry is revised by adding special provision N3:
UN2817 Ammonium hydrogendifluoride solution
- The following entries are revised by adding special provision N36:
UN1184 Ethylene dichloride
UN1732 Antimony pentafluoride
UN1777 Fluorosulphonic acid
UN2699 Trifluoroacetic acid
- The following entries are revised by removing certain “A” special provisions since the materials themselves are forbidden for transportation aboard passenger and cargo aircraft:
UN1541 Acetone cyanohydrin, stabilized (remove A3)
UN1722 Allyl chloroformate (remove A3)
UN2692 Boron tribromide (remove A3, A7)
UN1744 Bromine or Bromine solutions (remove A3, A6)
UN2484 tert-Butyl isocyanate (remove A7)
UN2485 n-Butyl isocyanate (remove A7)
UN1752 Chloroacetyl chloride (remove A3, A6, A7)
UN1754 Chlorosulfonic acid (with or without sulfur trioxide) (remove A3, A6, A10)
UN2382 Dimethylhydrazine, symmetrical (remove A7)
UN1182 Ethyl chloroformate (remove A3, A6, A7)
UN2481 Ethyl isocyanate (remove A7)
UN2014 Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary) (remove A3, A6)
UN2015 Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more than 60 percent hydrogen peroxide (remove A3, A6)
NA9206 Methyl phosphonic dichloride (remove A3)
UN2534 Methylchlorosilane (remove A2, A3, A7)
UN2304 Naphthalene, molten (remove A1)
UN1670 Perchloromethyl mercaptan (remove A3, A7)
UN1810 Phosphorus oxychloride (remove A7)
UN2740 n-Propyl chloroformate (remove A3, A6, A7)
UN1829 Sulfur trioxide, stabilized (remove A7)
UN1831 Sulfuric acid, fuming with 30 percent or more free sulfur trioxide (remove A3, A6, A7)
UN1834 Sulfuryl chloride (remove A3)
UN1836 Thionyl chloride (remove A7)
UN2474 Thiophosgene (remove A7)
UN1838 Titanium tetrachloride (remove A3, A6)
UN2441 Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric (remove A7, A8, A19, A20)
UN2442 Trichloroacetyl chloride (remove A3, A7)
UN1295 Trichlorosilane (remove A7)
UN2438 Trimethylacetyl chloride (remove A3, A6, A7)
- Paragraph (b)(3) of this section is amended to specify that a “B” code refers to a special provision that applies only to certain bulk packaging requirements and that, unless otherwise stated, does not apply to UN, IM Specification portable tanks or IBCs.
- Paragraph (b)(4) of this section is amended to specify that a code containing the letters “IB” or “IP” refers to a special provision that applies only to transportation in IBCs.
- Paragraph (b)(7) of this section is amended to specify that a code containing the letter “T” refers to a special provision which applies only to transportation in UN or IM Specification portable tanks.
- Paragraph (b)(8) is redesignated (b)(9) and a new paragraph (b)(8) is added to specify that a code containing the letters “TP” refers to a special provision that is in addition to those provided by the portable tank instructions or the requirements in part 178.
- Special Provision 47 is revised to include an additional exception currently in the UN Model Regulations specifying that a leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags.
- Special Provision 135 is revised to expand the applicability of the proper shipping names “Vehicle, flammable liquid powered” and “Vehicle, flammable gas powered” to include hybrid electric vehicles.
- Special Provision 137 is revised to expand the exception for “Cotton, dry”.
- Special Provision 143 is removed and relocated to § 173.219 so that the limitations on the types of hazardous materials authorized apply to both self-inflating and non-self-inflating life-saving appliances.
- Special Provision 153 is relocated to new paragraph (k) in § 173.115 and revised to include amended classification criteria for aerosols containing flammable constituents consistent with criteria in the UN Model Regulations. The revised criteria include methods for the classification of aerosols based on the percentage of flammable components. One commenter agreed with the removal of Special Provision 153 and the relocation of classification criteria for aerosols to § 173.115(k).
- New Special Provision 163 is added to specify that Ammonium Nitrate Emulsions are required to satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18.
- New Special Provision 164 is added to specify that an approval is required for “Desensitized explosives, liquid, n.o.s.” and “Desensitized explosives, solid, n.o.s.”
- New Special Provision 165 is added to the calcium hypochlorite PG II and the PG III entries for UN1748 and UN2880 to specify the danger of exothermic decomposition and require shading from direct sunlight and sources of heat during transportation. One commenter agreed with our efforts to harmonize the HMR with UN Recommendations, but was concerned with the intent of Special Provision 165. This commenter agreed that calcium hypochlorite should be shaded from direct sunlight but questioned the ambient heat and ventilation provisions. The commenter stated that calcium hypochlorite is currently transported in closed cargo transport units, thus, satisfying the requirement to protect this hazardous material from direct sunlight. However, since the cargo transport units are not ventilated by fan or induced ventilation, and the cargo transport units would be subjected to ambient heat, a violation of Special Provision 165 appears imminent. We disagree. We feel Special Provision 165 provides latitude for compliance with the ventilation and ambient heat requirements. Proper ventilation and protection from ambient heat can be achieved during the loading process of the cargo transport units and throughout the transportation cycle by allowing adequate space for air movement around the calcium hypochlorite packages. We do agree; however, that cargo transport units themselves should not be required to be shaded from direct sunlight. Therefore, we have revised the regulatory text accordingly.
- New Special Provision 166 is added to the PG II entry for calcium hypochlorite, UN2880 and UN1748 to indicate that calcium hypochlorite in the non-friable tablet form may be transported as a PG III material.
- New Special Provision 167 is added to the new entry for “Hydrogen in a metal hydride storage system” to specify that such storage systems shall always be considered as containing hydrogen.
- New Special Provision 170 is added to Organometallic substances entries (UN3391, UN3392, UN3393, and UN3394). The special provision requires air to be eliminated from the vapor space by nitrogen or other means.
- New Special Provision 171 is added to the UN2880 PG III entry. Since UN2880 also covers mixtures of hydrated calcium hypochlorite in any concentration, some formulations in other than tablet form (e.g., in granular form) may meet the criteria for classification in Division 5.1, Packing Group III when subjected to the relevant test in the UN Manual of Tests and Criteria. The PG III entry for calcium hypochlorite is only authorized when the material is offered in the non-friable tablet form or for granular or powdered Start Printed Page 76051mixtures. This entry is not authorized for the pure form of “Calcium hypochlorite, hydrated”. We also recognize that some formulations, when tested, do not meet the criteria for classification in Division 5.1. In light of this, we added a new Special Provision 171 to the UN2880, PG III entry in the HMT to allow for the possibility to classify powdered or granular mixtures of hydrated calcium hypochlorite in Packing Group III when data indicate that the mixture meets the criteria for assignment to PG III. One commenter supports the revisions that align calcium hypochlorite entries in the HMT with UN Recommendations. However, this commenter requested the addition of Special Provision 171 to the entry, “Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry, (UN1748)” for consistent alignment with the UN Recommendations. We agree. After further review of the UN Recommendations, we have determined that the UN Special Provision 316 is equivalent to the proposed Special Provision 171 in Docket HM-215G, and is applicable to both the “dry” and “hydrated” calcium hypochlorite entries. Therefore, we are assigning Special Provision 171 to the “Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry, (UN1748)” entry.
- Special Provision A11 is currently assigned to UN 2983, Ethylene oxide and Propylene oxide mixtures and UN 1411, Lithium aluminum hydride, ethereal. In the ICAO Technical Instructions these substances are only authorized for transport in metal cylinders. A11 states “For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. In the NPRM, we proposed to harmonize with the applicable ICAO Technical Instruction particular packing requirement (PPR 8), however discussions with the ICAO Dangerous Goods Panel and further analysis of ICAO PPR 8 has revealed that the requirement may need to be amended. Our analysis showed that other packagings, including glass inner packagings, are authorized, and as such restricting packagings to only specification cylinders appears unnecessarily restrictive. As such we are not proposing to amend Special Provision A11 in this final rule.
- Consistent with ICAO, we are adding a proper shipping name to the HMT for “Receptacles, small containing gas, 2.2 with a subsidiary of 5.1.” A new “A” code (A14) is added to prohibit this material from being transported as a limited quantity or consumer commodity in accordance with § 173.306 aboard an aircraft. This new “A” code has also been added to the following additional shipping names: “Oxygen, compressed,” Carbon dioxide and oxygen mixtures,” “Nitrous oxide”, “Compressed gas oxidizing,” and “Liquefied gas, oxidizing.”
- For consistency, the authorization in Special Provision B69 to allow dry sodium or potassium cyanide in siftproof, water-resistant fiberboard IBCs is relocated to new Special Provision IP20.
- Paragraph (c)(4) of this section is amended by relocating “Table 2.—Organic Peroxide IBC Code (IB52)” to paragraph (e) of § 173.225 and renaming it the “Organic Peroxide IBC Table.” Table 3.—IP Codes is redesignated Table 2.—IP Codes. The wording of paragraph (c)(4) is revised to indicate that Table 3.—IP Codes had been redesignated Table 2.—IP Codes. All references to IB52 in the HMR are removed and replaced with “Organic Peroxide IBC Table” or “§ 173.225(e),” as applicable.
- Paragraph (c)(7) is amended by relocating the Portable Tank Code T50 Table to § 173.313 and renaming it “UN Portable Tank Table for Liquefied Compressed Gases.” The T50 Table and its description is removed from paragraph (c)(7)(iv) and replaced with a statement indicating that the new “UN Portable Tank Table for Liquefied Compressed Gases” is found in § 173.313. All references to T50 in the HMR are removed and replaced with “UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” In addition, paragraph (c)(7) is amended by relocating Portable Tank Code T23 to paragraph (g) of § 173.225 and renaming it the “Organic Peroxide Portable Tank Table.” Portable Tank Code T23 and its description found in paragraph (c)(7)(iii) are removed and paragraphs (c)(7)(iv)-(c)(7)(vii) are redesignated (c)(7)(iii)-(c)(7)(vi), respectively. All references to T23 in the HMR are removed and replaced with “Organic Peroxide Portable Tank Table” or “§ 173.225(g),” as applicable.
- New paragraph (c)(8) is added to provide an introduction to the “TP” codes (i.e., portable tank special provisions). The existing paragraph (c)(8) is redesignated paragraph (c)(9).
- New Special IBC Packing Provision IP13 is added to specify that transportation by vessel in IBCs is prohibited.
- New Special IBC Packing Provision IP14 is added to specify that air must be eliminated from the vapor space by nitrogen purging or other means.
- New Special IBC Packing Provision IP20 is added to specify that dry sodium cyanide and potassium cyanide are also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles.
- Portable tank Special Provision TP3 is revised to include the maximum degree of filling (in %) for solids transported above their melting points.
- Special Provision TP6 is revised by removing the word “event” and replacing it with the word “incident.”
- Portable tank Special Provision TP9 is removed from column (7) of the HMT for all materials that reference a T code special provision. Special provision TP9 states that a material with TP9 in Column (7) may only be transported in a portable tank if approved by the Associate Administrator. A material that has been given a T code does not require approval and is not subject to Special Provision TP9.
- In the NPRM we proposed adoption of a new portable tank special provision, TP33, by adding the new provision to certain entries in the HMT. However, we neglected to include the text of the provision itself. We are correcting this omission in this final rule.
Section 172.202
We are editorially revising paragraph (a)(2)(iii) by removing the examples that illustrate the optional provision to enter primary and subsidiary hazard class or division names on shipping papers for domestic shipments. In the HM-215E response to appeals final rule (69 FR 34604) that was published on June 22, 2004, we reinstated the provision which was removed in a previous rulemaking (68 FR 44992). During the process of correcting a printing error in one of the examples, we determined that the regulatory text is complete and sufficient without the use of examples.
In the NPRM [69 FR 34741] we proposed to amend paragraph (a)(5)(i) to require the quantity shown on a shipping paper for an explosive article, such as Cartridges, small arms, to be the net mass of the entire article rather than the net mass of the explosive contained in the article. Commenters generally support the proposal, suggesting that it will provide for consistency across modes of transportation and for more accurate calculations. However, several of these commenters note that, for certain explosive articles that contain very small amounts of an explosive, showing the net mass of the article rather than of the explosive contained in the article could misrepresent the transportation risk associated with the article. Two commenters state that, Start Printed Page 76052because shippers have historically calculated the net mass based on the actual explosive material contained in the article rather than the entire article, the clarification proposed in the NPRM could cause increased confusion for shippers.
Internationally, as well, there is some concern that, at least for large explosive articles, the quantity indicated on the shipping paper should be the net mass of the explosive substances contained in the article rather than the net mass of the article itself. As suggested by some commenters to the NPRM, a number of the members of UN Transport of Dangerous Goods Sub-Committee agree using the net mass of the entire article rather than the net mass of the explosive material contained in the article may not appropriately communicate the explosive hazard to emergency responders. Until this issue is resolved through a change to the UN Model Recommendations, we are, in this final rule, amending paragraph (a)(5)(i) to clarify that for explosive articles the quantity shown on a shipping paper may be expressed in terms of the net mass of the article or the net mass of the explosive substances contained in the article. It should be noted, however, that for purposes of determining the per-package quantity limitations shown in Column 9 of the HMT, § 172.101(j)(3) specifies that when articles or devices are specifically listed by name, the net quantity limitation applies to the entire article or device rather than to its hazardous components. This would include explosive articles listed by name in the HMT. For example, in the case of a listed explosive article weighing 15 kg and containing 500 grams of explosive substance, the weight shown on the shipping paper may be 500 grams or 15 kg, but the weight used for purposes of compliance with Column (9) of the HMT must be 15 kg as required by § 172.101(j)(3).
Particularly for large articles, the quantity indicated on the shipping paper should be the net mass of the explosive substances contained in the article. For small explosive articles, such as Cartridges, small arms, we believe that the net mass of the article can be used to satisfy the total quantity requirement in § 172.202(a)(5)(i). As a practical matter, it is easier, and in certain instances necessary, for an offeror to provide the net mass of the article and the net explosive mass. For example, as previously stated, the net mass of an article must be used to ensure compliance with the per package quantity limitations set forth in Column 9 of the § 172.101 Hazardous Materials Table for transport aboard aircraft or passenger rail (see § 172.101(j)(3)). However, for operational purposes, such as for stowage and segregation of large quantities of explosives or determining the quantity of explosives that can be transported on a vessel [see § 176.142(b)], the net explosive mass of the explosive substances contained in articles is needed.
Section 172.203
Paragraph (f) is revised by including the passenger and cargo aircraft limitation certification statement that is found in § 172.204. This aligns the HMR with the ICAO TI (see 4.1.5.8.1(b) of the ICAO TI). A new paragraph (i)(3) is added to specify additional shipping paper description requirements for a hazardous material consigned under an “n.o.s.” entry when offered for transportation by vessel. In addition, paragraph (m)(2) is revised to specify that the phrase “Poison Inhalation Hazard” or “Toxic Inhalation Hazard” is not required to be repeated if it otherwise appears in the shipping description. Finally, in paragraph (o)(3), the reference to § 173.225(c)(2) is amended to read § 173.225(b)(2).
One commenter felt the requirement to add a segregation code on the shipping paper for “n.o.s.” entries is unnecessary and unduly burdensome. In addition, the commenter is concerned that there may not be sufficient space on the shipping paper to indicate this notation. If, however, this requirement is adopted, the commenter requested an example of the required entry on shipping papers. We disagree. We do not feel this additional requirement is unnecessary or overly burdensome. The additional shipping paper description requirements apply only to hazardous material consigned under an “n.o.s.” entry when offered for transportation by vessel. We believe that consignors should be familiar with the hazards and segregation risks of their shipments, specifically “n.o.s.” materials that are not assigned segregation groups. By indicating the need to segregate such materials on the shipping paper, the consignor increases the likelihood that appropriate stowage procedures are followed, ensuring the safety of the vessel and its cargo. We also do not agree that there is inadequate space available on shipping papers to include the segregation group. However, we do agree that an example of the required entry should be presented for clarity and uniformity. Therefore, as recommended by the commenter, we are adding the example “IMDG Code segregation group—1 Acids” to § 172.203.
Section 172.204 and Section 172.321—Air Eligibility Marking
Under HM-215E (68 FR 44992), the air eligibility marking was adopted into the HMR as new § 172.321. Since publication of that final rule, the ICAO's Dangerous Goods Panel removed the air eligibility marking requirement from the ICAO Technical Instructions. In lieu of this marking, ICAO adopted a requirement that the shipping paper certification statement include the statement “I declare that all of the applicable air transport requirements have been met” when a hazardous material is offered for air transportation. Additionally, the revised section provided examples of the applicable air transport requirements that must be met. Based on this action, we revised the air eligibility marking requirement by making it optional rather than mandatory and adding the additional shipping paper certification statement for shipments going by aircraft. Therefore, we revised § 172.204(c)(3) by requiring that the statement “I declare that all of the applicable air transport requirements have been met” be included on the shipping paper in addition to the current certification statement when a hazardous material is offered for air transportation. Additionally, the revised section provides examples of the applicable air transport requirements that must be met and various section references. In order to allow shippers to expend stocks of preprinted shipping papers containing the previous certification statement, we are providing an additional ten month transitional provision for the new certification statement. Two commenters support RSPA's decision requiring shippers to sign the certification declaring compliance with requirements for air transportation. Additionally, several commenters agree with the revision to make the air eligibility marking optional. However, some commenters suggest making the marking “permissible” instead of “optional” to avoid potential confusion. We disagree. We are removing the requirement for shippers to mark packages acceptable for air transport with the air eligibility marking. This revision does not prohibit the use of the marking.
Section 172.315
Section 172.315 is amended to ensure that packages containing limited quantities which are transported by air are marked with the proper shipping name. Although the amendment was not proposed in this rulemaking, it was previously proposed and adopted under Start Printed Page 76053HM-215E (68 FR 45000) but was omitted due to an editorial error during publication. The amendment provides harmonization with the ICAO Technical Instructions, which do not allow the UN number within a square-on-point border as a substitute for the proper shipping name. Note that this amendment does not preclude the ID number/square-on-point border from appearing on a package transported by air, it simply ensures that the proper shipping name is also required.
Section 172.317
A new § 172.317 is added to require a “KEEP AWAY FROM HEAT” handling mark on packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 when such packages are transported by air.
Part 173
Section 173.3
The NPRM proposed to revise the requirements for use of salvage drums to include packages of hazardous materials that are found not to conform with the requirements of the HMR. In addition, the NPRM proposed to clarify that salvage drums may only be used for damaged, defective, non-conforming, or leaking packages identified as such after the packages have been placed in transportation. One commenter suggests that the phrase “after having been placed in transportation” as used in the NPRM is confusing and requests that we clarify the phrase using the terms “pre-transportation functions” and “transportation functions” as defined in a final rule published under Docket HM-223 October 30, 2003 (68 FR 61905). In response to this comment, in this final rule, we modified § 173.3(c) to clarify that salvage drums are to be used for damaged, defective, non-conforming, or leaking packages identified during transportation as “transportation” is defined in § 5102(12) of Federal hazardous materials transportation law—that is, the movement of property and loading, unloading, or storage incidental to the movement. When the HM-223 final rule becomes effective, the statutory definition for “transportation” will be added to § 171.8 of the HMR, as will definitions for “movement,” “loading incidental to movement,” “unloading incidental to movement,” and “storage incidental to movement.” Note that a package found to be leaking prior to its being placed in transportation may not be packaged in a salvage drum. Instead, it must be repackaged into an authorized packaging in accordance with applicable HMR requirements.
Section 173.24
For consistency with the UN Recommendations, paragraphs (g)(4) and (g)(5) are revised to clarify the following:
(A) That IBCs (subject to the requirements in § 173.24(g)) are permitted to be vented to reduce internal pressure; and
(B) That venting of IBCs is not conditional upon whether a bulk special provision is indicated for a particular hazardous material in the § 172.101 hazardous materials table.
In addition, paragraph (i) is revised to clarify that other general requirements specific to air transportation apply and are found in § 173.27.
Section 173.25
Paragraph (a)(2) is revised by removing the requirement to mark an overpack with the air eligibility marking. In addition, in paragraph (a)(4), we are amending the HMR to require overpacks to be marked with the word “OVERPACK” or, alternatively, until October 1, 2007, with a statement indicating that inside packages comply with prescribed specifications. This is in response to adoption by the United Nations of the “OVERPACK” marking to indicate that packages within an overpack comply with prescribed specifications when specification markings on inside packagings within the overpack are not visible.
Section 173.27
Paragraph (i) is revised to indicate that the air eligibility mark has been removed. This section references a new requirement for shippers to place the following statement at the end of the certification statement when a hazardous material is authorized for air transportation: “I declare that all applicable air transport requirements have been met.”
Section 173.28
In paragraph (c)(2), we deleted the words “or a UN 1H1 plastic drum” in order to harmonize the HMR with the UN Model Regulations and remove a source of confusion within the regulated community regarding the reconditioning of a non-bulk packaging.
Section 173.115
In § 173.115, a new paragraph (k) is added (see discussion under § 172.102, Special Provision 153). One commenter noted that the proposed new § 173.115(k) would not allow aerosols to contain corrosive substances of Packing Group II. The commenter further noted that UN Special Provision 63 allows aerosols to contain corrosive substances of Packing Group II and requested we harmonize with the UN Special Provision 63 in this regard. We agree with the commenter and further note that currently, the HMR authorizes a proper shipping name of “Aerosols, corrosive Packing Group II or III, each not exceeding 1 L capacity”. We are amending § 173.115(k) accordingly to clarify that aerosols may contain corrosive substances of Packing Group II.
Section 173.120 and Appendix H to Part 173
A commenter noted that under section § 173.120(a)(3), the reference to Appendix H for sustained combustibility tests directs the reader to Figures 5.1 and 5.2 found in the UN Recommendations. These figures are no longer in the UN Recommendations, but, rather, are located in section 32.5.2 of the Fourth Revised Edition of the UN Manual of Tests and Criteria. We agree with the commenter. Therefore, we are amending Appendix H to Part 173 to reference the UN Manual of Tests and Criteria.
Section 173.128
In paragraph (d)(1)(i), the section reference is revised to read § 173.225(c). In addition, in paragraphs (d)(1)(ii) and (d)(1)(iii), the section reference is revised to read § 173.225(b).
Section 173.132
In paragraph (b)(1), we revised the definition of LD50 for acute oral toxicity to indicate that adult albino rats may be tested without regard to gender. The current definition for LD50 for acute oral toxicity in § 173.132(b)(1) is based on the Organization for Economic Co-Operation and Development (OECD) Test Guideline (TG) 401. The OECD has agreed to three test methods that will replace the current TG 401. The United Kingdom, Germany and the United States of America took the lead in the development of the three alternative tests that OECD has now adopted and published in the OECD Guidelines for the Testing of Chemicals. In a continuing attempt to improve the estimate of acute oral toxicity while reducing the number of animals used per test, three alternative TGs have been developed and implemented to replace TG 401. The three TGs are the Fixed Dose Procedure (FDP, TG 420), the Acute Toxic Class Method (ATCM, TG 423), and the Up-and-Down Procedure (UDP, TG 425). The text is consistent Start Printed Page 76054with the text in the 13th revised edition of the UN Model Regulations.
Section 173.136
We added a new paragraph (d) to provide a grandfather clause that will allow for the continued shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72 without retesting.
Section 173.137
In paragraph (c)(2), we propose to eliminate the references to ASTM G 31-72 as an acceptable test description and add a statement indicating an acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37.
Sections 173.150, 173.151, 173.152, 173.153 and 173.154
We are allowing most Division 6.1, Packing Group II materials to be transported under the limited quantity provisions when the packagings contain not more than 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids. However, consistent with the limited quantity authorization for Division 6.1, Packing Group III, we are not providing a labeling exception for these materials. We are also not allowing these materials to be shipped as consumer commodities. In addition, we revised the limited quantity sections for the other hazard classes of materials to take into account materials with a subsidiary hazard of 6.1 Packing Group II. One commenter agreed with the amendment allowing numerous Class 3, PG II materials with Class 8 and other subsidiary hazards to be transported as limited quantities.
Section 173.185
In § 173.185, we amended paragraphs (c)(3) and (e)(6), to require those lithium cell and battery design types that are required to be subjected to the UN performance tests to be of a type that is proven to meet the requirements of the performance tests specified in the UN Manual of Tests and Criteria, Fourth Revised Edition. These cells and batteries are currently required to be of a type that is proven to meet the tests in the third revised edition. We also proposed a grandfather provision that would authorize a lithium cell or battery that was transported prior to the effective date of this rule that is of a type proven to meet the UN performance tests in the third revised edition to not be required to be retested in accordance with the tests in the fourth revised edition. One commenter supported this approach and stated that it is both necessary and appropriate to allow continued transport of cells and batteries tested and qualified under the UN lithium battery design qualification tests in accordance with the UN Manual of Tests and Criteria, Third Revised Edition. The commenter further stated that providing a grandfather provision for previously tested cells and batteries would avoid the need and expense of requalifying these cells and batteries in accordance with the new tests prescribed in the Fourth Revised Edition of the UN Manual of Tests and Criteria. After further consideration, we believe that authorizing an indefinite period for the transport of batteries that were tested in accordance with the UN Manual of Tests and Criteria, Third Revised Edition, 1999 may not be in the best interest of safety. The tests in the UN Manual of Tests and Criteria, Fourth Revised Edition provide a slightly higher level of safety and we believe that further consideration needs to be taken in considering whether at some point in time all applicable lithium batteries and cell design types should be proven to meet the requirements of the UN Manual of Tests and Criteria, Fourth Revised Edition. As a result, we will issue a proposal shortly specifically to address the full unrestricted adoption of the Fourth Revised Edition of the UN Manual of Tests and Criteria.
Section 173.186
In § 173.186, in paragraph (e), we amended the gross weight for UN 4G outer packages authorized for the transportation of strike-anywhere matches, to be consistent with the UN Model Regulations by increasing the weight from 27 kg (60 pounds) to 30 kg (66 pounds).
Section 173.187
We revised § 173.187 to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This change eliminates the need for DOT Exemption “DOT-E 11548.”
Sections 173.211, 173.212, and 173.213
We revised these sections to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This change removed the need for DOT Exemption “DOT-E 11548.”
Section 173.219
We revised § 173.219 for consistency with the UN Model Regulations and the ICAO Technical Instructions. Included in the revision is an allowance for self-inflating life-saving appliances to contain cartridges, power devices of Division 1.4S, for purposes of the self-inflating mechanism. In addition, we provided an exception from regulation for life-saving appliances containing only carbon dioxide cylinders not exceeding 100 cm3 capacity, provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg. Finally, the limitations currently found in Special Provision 143 are relocated to § 173.219 (see preamble discussion under Special Provision 143).
Section 173.220
Paragraph (b)(2) is amended to harmonize the requirements for transporting flammable gas powered vehicles by air with the requirements of Packing Instruction 900 of the ICAO Technical Instructions.
Section 173.224
Paragraph (b)(4) of this section is amended to include the new references for § 173.225. The section reference to § 173.225(e) for the authorization of bulk packagings is replaced with § 173.225(f) for IBCs and § 173.225(h) for other bulk packagings.
Section 173.225
This section is amended to update the Organic Peroxide Table and eliminate special provisions IB52 and T23 from § 172.102(c). The purpose of the change is to consolidate the packaging requirements for organic peroxides into one section and to have separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs. The changes are as follows:
Paragraph (a) is revised by adding paragraphs (b) and (b)(6), which state that bulk packagings may require a lower control temperature than those specified for non-bulk packagings and that an organic peroxide not identified in either the Organic Peroxide Table, Organic Peroxide IBC Table, or Organic Peroxide Portable Tank Table must be approved under § 173.128(c).
Paragraph (b) is revised to eliminate all IBC and other bulk packaging authorizations from column 6 of the Organic Peroxide Table. Various obsolete entries were also removed. The current paragraph (b), “Organic Peroxide Table,” is moved to paragraph (c) and the current paragraph (c), “New organic peroxides, formulations and samples,” is moved to paragraph (b).
The notes following the Organic Peroxide Table are changed as follows:
- Revise note 22 to indicate that ethylbenzene with greater than or equal to 25% of dilutant type A is acceptable. Start Printed Page 76055
- Revise note 23 to indicate that methyl isobutyl keytone with greater than or equal to 19% of dilutant type A is acceptable.
- Add a new note 29 to identify materials which are not included in the UN Model Regulations and note that a Competent Authority approval is required for international transportation.
- Remove Notes 9, 11, and 14 following the Organic Peroxide Table.
In addition, The Packing Method Table found in paragraph (d), is revised by replacing the 200 kg maximum quantity for solids and combination packagings listed in OP8 with a 400 kg maximum quantity. Note 2, following the table, is revised to allow 200 kg of solid material per box and up to 400 kg of material per authorized combination packaging. The note also indicates that the outer packaging must be a box (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and each inner packaging must be of plastics or fiber with a maximum net mass of 25 kg. Paragraph (d)(3) is clarified by revising the text to state that the maximum content acceptable for glass receptacles used as inner packagings of a combination packaging is 0.5 kg for solids or 0.5 L for liquids.
A new paragraph (e) is added to include the new “Organic Peroxide IBC Table” that replaces the current “Table 2.—Organic Peroxide IBC Code (IB52)” in § 172.102(c)(4). The new table is revised to add an organic peroxide, “Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water.” In addition, the new Organic Peroxide IBC Table identifies, by technical name, those organic peroxides authorized for transportation in the IBCs that are specifically listed in the table.
A new paragraph (f) is added to include the current IBC requirements contained in paragraph (e)(5) of this section. Paragraph (f) also includes requirements that are specific to organic peroxides packaged in IBCs.
A new paragraph (g) is added to include the new “Organic Peroxide Portable Tank Table,” that replaces the current “Portable Tank Code T23” found in § 172.102(c)(7)(iii). The new table is identical to the current table except that for UN 3109, in the entry for Pinanyl hydroperoxyde, 50% is replaced by 56% and all references to self-reactive materials are removed. In addition, the Organic Peroxide Portable Tank Table provides certain portable tank requirements and identifies, by technical name, those organic peroxides authorized for transportation in the bulk packagings listed in the new paragraph (h).
The current paragraph (e) is redesignated as paragraph (h). Paragraph (h) establishes requirements that are specific to organic peroxides packaged in certain bulk packagings. Additionally, the new “Note to Paragraph (h)(3)(vi)” is revised to include changes brought forth by petition for rulemaking P-1428. The petition proposed to amend the current paragraph (e)(3)(vi) and allow for a second but equally acceptable example of an emergency-relief device sizing method to be added to the HMR. We agreed with the petitioner and added a statement to the new paragraph (h)(3)(vi) indicating that an additional example of an emergency-relief device sizing method can be found in the “American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2)” as referenced in § 171.7(b).
The changes to this section altered the order of the paragraphs within this section; therefore, various citations were changed. Also, paragraphs referencing IB52 or TP23 are revised to indicate that those provisions no longer exist and the updated requirements are found in paragraph (e) and (g), respectively. A commenter requested that § 173.225 be revised to allow for increased industry flexibility, regulatory uniformity, and to better align with the UN Recommendations. We agree and have made the following revisions:
- Added wording to 173.225(a) to show that organic peroxides that are not identified in the organic peroxide table, but are in paragraph (b)(3) are not subject to the requirements of § 173.128.
- Removed Note 1 from both entries of tert-Butyl cumyl peroxide and Note 11 from Dicumyl peroxide.
- Removed the sentence “The additional requirements in paragraph (h)(5)(i) and (h)(5)(ii) of this section also apply” from § 173.225(f) and renumbered (f)(i) and (f)(ii) as (f)(1) and (f)(2), respectively.
- Revised the introductory text to Paragraph (h) to indicate that the bulk packagings that follow are for materials authorized for transport in a bulk packaging by Paragraph (h) and organic peroxides listed in the Organic Peroxide Portable Tank Table.
- Removed two occurrences of the term “Type F” from Paragraph (h)(3) to broaden the applicability of the provisions.
- Removed statement from § 173.225(h)(3)(xii) indicating that DOT Specification 57 portable tanks are not subject to the requirements of paragraphs (h)(3)(ii) and (h)(3)(iv) of this section.
Sections 173.226 and 173.227
We revised the packaging requirements of §§ 173.226 and 173.227 for materials poisonous by inhalation, Division 6.1, Packing Group I, Hazardous Zone A and Hazard Zone B. These amendments have: Reduced the hydrostatic test pressure of the inner drum in a drum-within-a-drum configuration authorized in § 173.226(b); standardized the minimum thickness requirements of the inner drums in the drum-within-a-drum configuration authorized in §§ 173.226(b) and 173.227(b); clarified the test requirements for inner packaging systems in § 173.226(b)(2)(iv); and in § 173.226(d) added a provision to authorize transportation of PIH materials in single packages when subjected to additional operational controls and approved by the Associate Administrator. Section 173.226(c)(2) is reformatted for ease of understanding. We removed an expired transitional date from paragraph (a) that allows the transport of welded cylinders filled before October 1, 2003 for the purpose of reprocessing or disposal of cylinders's content until December 31, 2003. One commenter recommended that we include a provision in § 173.227(b) to allow for the testing of the outer drum of a drum-in-drum package as either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids. We agree and have revised § 173.227(b) accordingly. Another commenter suggested that we increase the minimum thickness of a UN 1A1 drum in PIH service from .69 mm to 1.0 mm. Increasing the minimum thickness of a UN 1A1 drum in PIH service was not proposed in this rulemaking and inclusion of such a requirement is beyond the scope of this rulemaking. However, we are reviewing this request for consideration in a future rulemaking.
Section 173.249
Paragraph (c) is revised to be consistent with the current “Bromine” entry in the § 172.101 “Hazardous Material Table” that authorizes the use of a UN portable tank conforming to tank code T22. A commenter suggested that we include a provision authorizing the returning of a tank containing bromine residue. We agree that such a provision is necessary and have amended § 173.249 accordingly.
Sections 173.306 and 173.307
To add clarity to the HMR, the text currently found in § 173.306(i) is removed and replaced with the text Start Printed Page 76056currently found in § 173.307(a)(5). Since § 173.306 is devoted exclusively to limited quantities of compressed gases, relocating § 173.307(a)(5) to § 173.306 makes the exception easier to find.
Section 173.313
A new § 173.313 is added to serve as the new location for the Portable Tank Code T50 Table. The table is renamed “UN Portable Tank Table for Liquefied Compressed Gases.” The table provides the maximum allowable working pressures, bottom opening requirements, pressure relief requirements and degree of filling requirements for liquefied compressed gases permitted for transport in portable tanks. The change relocates these packaging requirements to Part 173, which is a more appropriate location, and makes the special provisions less cumbersome. In addition, the new UN Portable Tank Table for Liquefied Compressed Gases is amended by revising the Column 3 heading to read “Minimum design pressure (bar) * * *” The values in column 3 are actually minimum values, however the title of the column is misleading because it uses the term “Maximum allowable working pressure (bar) * * *”
Section 173.315
In paragraph (a), the reference to “portable tank provision T50 in § 172.102” is revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.”
Section 173.323
After further considering the proposed changes to the packaging authorizations for ethylene oxide in § 173.323, we noted that the total quantity per package of ethylene oxide authorized for transport when glass inner receptacles are used was proposed to be increased from 100 grams to 2.5 kg. Due to the extremely flammable and explosive properties of ethylene oxide and the fragile properties of glass, after further consideration we have chosen not to adopt the 2.5 kg outer package limit found in the UN Recommendations and to retain our current outer package limit of 100 grams. The total quantity per package when metal inner receptacles are used will remain unchanged from the proposed 2.5 kg. In this rule, paragraphs (b)(1)-(b)(3) are revised and consolidated for consistency with current international requirements for the transportation of ethylene oxide in combination packagings. Paragraphs (b)(1)-(b)(3) provide the current authorizations for glass, aluminum, and metal receptacles respectively. Amendments to this section include (1) removing the HMR limitation of 12 inner receptacles per outer package currently applied to aluminum and other metal receptacles, (2) removing the overpack restriction in (b)(2) which specifies a maximum of 10 boxes per overpack, (3) requiring a hot water bath test for all inner receptacles, (4) removing the pressure relief device and burst pressure requirements currently applied to metal receptacles, (5) applying the same outer package authorizations consistently to all inner packaging types and allowing any outer package authorized in § 172.201(b), and (6) requiring all inner packagings to be suitably cushioned (the top and bottom pad and perimeter liner requirement currently only applied to outer packages containing aluminum inner packagings is removed). Though we are eliminating the option to utilize certain packaging authorizations for glass and aluminum inner packagings, we believe that this change will have little or no economic impact on the ethylene oxide industry because of the amount of materials that are transported in international commerce. 3M Package Engineering requested that we reduce the maximum quantity of ethylene oxide permitted in any metal inner packaging from 340 g (12 ounces) to 200 g (7 ounces). They stated that such a change would more adequately align the HMR with international standards. We agree that such a change would align the HMR with international requirements. However, allowing a metal inner packaging to contain a maximum quantity of 340 g (12 ounces) does not limit compliance with international requirements. In addition, we cannot adopt the 200 g (7 ounces) limitation in this rulemaking because such a change would be more restrictive then the requirements we proposed. We may consider adopting the 200 g (7 ounces) limitation in a future rulemaking.
Part 175
Section 175.10
Consistent with an amendment to the ICAO TI, we are requiring that aerosol cans that are carried aboard an aircraft in accordance with § 175.10(a)(4) have their release devices protected by a cap or other suitable means. In addition, the ICAO Dangerous Goods Panel will convene a series of working groups to develop recommendations for consideration during the 20th session of the Dangerous Goods Panel to further review this issue. These recommendations may lead to additional amendments to the ICAO TI. Finally, we note that non-flammable gases (e.g., nitrogen) other than carbon dioxide are used for the operation of mechanical limbs. Consistent with an amendment to the ICAO TI, we are proposing to provide an exception from the HMR for mechanical limbs that are powered by any Division 2.2 gas. One commenter recommended that the release device requirements added to § 175.10 also be incorporated into Part 173. Specifically, they requested that aerosol cans that are transported in commerce be protected by a cap or other suitable means to prevent inadvertent release. They indicated that this change should be coordinated with the Federal Aviation Administration (FAA). We disagree. Section 173.24(b)(1) states that each package used for the shipment of hazardous materials must be constructed, maintained, filled, its contents so limited, and closed, so that under conditions normally incident to transportation there will be no identifiable release of hazardous materials to the environment. We feel this section adequately addresses the commenter's concerns, and allows shippers the flexibility to properly protect aerosol cans.
Section 175.85
In § 175.85, a new paragraph (j) is added to specify the cargo location of a package bearing the “KEEP AWAY FROM HEAT” handling marking.
Part 176
Section 176.2
Certain definitions are revised. The definitions for “Explosive article” and “Explosive substance” are revised to remove an incorrect reference. The definition for “Magazine” is revised to include a compartment in the vessel. The definition for “Magazine” is also revised to specify vessel storage location and accessibility. The term “Transport unit” is revised to read “Cargo transport unit” to be consistent with Amendment 32 of the IMDG Code. In addition, in the definition “In containers or the like” the term “transport unit” is removed and the term “cargo transport unit” is added in its place.
Section 176.27
In this section, the words “transport unit” are replaced with the words “transport vehicle” in each place they appear to be consistent with the removal of the term “transport unit” from the definitions in § 176.2.
Section 176.63
Paragraph (e) is revised to align the definition of “Closed cargo transport unit” to be consistent with the Start Printed Page 76057definition in Amendment 32 of the IMDG Code.
Section 176.76
Paragraph (i) is revised to clarify that for container ships, a distance equivalent to one container space athwartships (i.e., in the direction of the breadth of the vessel) away from possible sources of ignition applied in any direction satisfies the requirement that a cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 °C transported on deck be stowed “away from” possible ignition sources. This is consistent with Amendment 32 of the IMDG Code. In addition, in paragraphs (h) and (i), the words “transport unit” are removed and replaced with the words “cargo transport unit” in each place they appear to be consistent with Amendment 32 of the IMDG.
Section 176.83
Paragraph (l) is revised to correct an error pertaining to the Segregation Table that sets forth the general requirements for segregation of containers on board hatchless container vessels. In addition, throughout the section the words “transport units” are removed and replaced with the words “cargo transport units” in each place they appear to be consistent with Amendment 32 of the IMDG. A new paragraph (m) is added to specify the provisions for segregation groups.
Section 176.84
Paragraph (a) is revised to specify the various chemical groups listed in the segregation table. In the paragraph (b) Table of Provisions, we added eleven new provisions (codes) for certain stowage and segregation requirements for hazardous materials that are transported by vessel. In addition, in paragraph (c)(2) Provisions for the stowage of Class 1 (explosive) materials, we revised three notes. The terms “separated from” and “away from” in the codes are defined in § 176.83 of the HMR.
Code 133 is added to the entries “Barium chlorate solution,” UN3405; “Barium perchlorate solution,” UN3406; and “Chlorate and magnesium chloride mixture solution,” UN3407, that requires the material to be stowed “separated from” sulfur.
Code 134 is added to the entry “Aluminum alkyl halides, solid,” UN3461, that requires the material to be stowed “separated from” UN2716.
Code 135 is added to the entries “Methylamine, aqueous solution,” UN1235 and “Trimethylamine, aqueous solutions,” UN1297, that requires the material to be stowed “separated from” mercury and mercury compounds.
Code 136 is added to the entry “Tributylphosphane,” UN3254, that requires the material to be stowed “separated from” carbon tetrachloride.
Code 137 is added to the entries “Arsenic compounds, liquid, n.o.s.,” UN1556 and “Arsenic compounds, solid, n.o.s.,” UN1557, that requires arsenic sulphides to be stowed “separated from” acids.
Code 138 is added to the entries for UN1448; UN1456; UN1479; UN1482; UN1490; UN1503; UN1515; UN3085; UN3087; UN3098; UN3099; UN3139; and UN3214, that requires the material to be stowed “separated from” peroxides.
Code 139 is added to the entry “1, 4-Butynediol,” UN2716, that requires the material to be stowed “separated from” mercury salts.
Code 140 is added to the entry “1, 4-Butynediol,” UN2716, that requires the material to be stowed “separated from” UN3052 and UN3461.
Code 141 is added to the entries for UN1732; UN1755; UN1806; UN1908; UN2433; UN2859; and UN2861, that requires the material to be stowed “away from” radioactive materials.
Code 142 is added to the entries for UN1748; UN2208; and UN2880, that requires packages in cargo transport units to be stowed so as to allow for adequate air circulation throughout the cargo.
Code 143 is added to the entry for Organometallic Substance, Liquid, Pyrophoric, UN3392, prohibiting transportation on any vessel carrying explosives (except explosives in Division 1.4, compatibility group S.
Note 19E is revised to specify that materials under entries NA0331; UN0004; UN0222; UN0241; and UN0402 must be stowed “away from” explosives containing chlorates or perchlorates.
Note 22E is revised to specify that materials under the entry “Explosive, blasting, type C,” must be stowed “away from” ammonium compounds and explosives containing ammonium compounds or salts.
Note 23E is revised to specify that materials under entries UN0247; UN0395; UN0396; UN0397; UN0398; UN0399; UN0400; UN0449; and UN0450 must be “separated from” Division 1.4 and “separated longitudinally by an intervening complete compartment or hold from” Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J.
A commenter questioned how adequate air circulation was achieved in a cargo transport unit. In addition, the commenter stated that it fails to understand why air circulation is necessary in a closed cargo transport unit, as indicated by Stowage Provision 142. Stowage Provision 142 indicates that packages in cargo transport units must be stowed so as to allow for adequate air circulation throughout the cargo. We feel cargo transport units that are properly loaded will allow for the adequate circulation of air by natural means so as to safeguard against excessive heat buildup within the cargo.
Section 176.116
In paragraph (c), the words “transport units” are revised to read “cargo transport units.” In addition, a new paragraph (f) is added to specify the under deck stowage requirements of Class 1 (explosive) materials allocated stowage categories 09 and 10.
Sections 176.122 and 176.124
Sections 176.122 and 176.124 are removed and reserved.
Section 176.128
In § 176.128, the section heading and section are revised.
Section 176.132
Section 176.132 is removed and reserved.
Section 176.133
Section 176.133 is revised to clarify the construction and stowage location requirements for magazine stowage type C.
Section 176.136
Section 176.136 is revised to clarify the special stowage requirements of Class 1 (explosive) materials. In addition, minor editorial revisions are made.
Section 176.138
Paragraph (a) is removed and reserved to be consistent with Amendment 32 of the IMDG Code. This paragraph currently requires Class 1 (explosive) material that is stowed on deck to be carried as close to the vessel's centerline as practicable.(See also change to § 176.170.)
Section 176.142
Paragraph (a) is revised to remove “Pyrophoric organometallic compound, water-reactive, n.o.s.” from the list of liquid hazardous materials of extreme flammability that may not be transported in a vessel carrying Class 1 (explosive) materials. Additionally, we added to the above list the following new liquid entries: Start Printed Page 76058
- “Organometallic substance, liquid, pyrophoric, UN3392”
- “Organometallic substance, liquid, pyrophoric, water-reactive, UN3394”
These changes are consistent with Amendment 32 of the IMDG Code.
Section 176.144
In this section, the words “transport unit” are replaced with the words “cargo transport unit” in each place they appear to be consistent with the definition in Amendment 32 of the IMDG Code. Additional notes are added to Table 176.144(a)—“Authorized Mixed Stowage For Explosives” to address additional exceptions for mixed stowage of Class 1 materials.
Section 176.146
In § 176.146, in paragraph (d)(1), the wording “transport units” is revised to read “cargo transport units.”
Section 176.168
In § 176.168, in the title before the section heading, the wording “TRANSPORT UNITS AND SHIPBORNE BARGES” are revised to read “CARGO TRANSPORT UNITS AND SHIPBORNE BARGES.”
Section 176.170
A new paragraph (b) is added to prohibit freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, from being stowed in the outermost row of containers. This change is consistent with Amendment 32 of the IMDG Code.
Section 176.174
Paragraphs (a) and (b) are revised to remove the references to portable magazines. This change is consistent with Amendment 32 of the IMDG Code.
Section 176.600
In § 176.600, in paragraph (a), the wording “closed transport units” is revised to read “closed cargo transport units.”
Part 178
Section 178.274
Paragraph (f)(v) is revised to more clearly specify the rated flow capacity marking required to be placed on every UN portable tank's pressure relief device.
Section 178.275
Paragraph (i)(2) is revised to more clearly specify the combined delivery capacity of UN portable tank's pressure relief systems.
Section 178.276
In paragraph (a)(4)(ii)(A), the reference to “portable tank special provision T50” is revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” In addition, paragraph (d), the reference to “portable tank special provision T50 in § 172.102(c)(7)” is revised to read “UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” Finally, in paragraph (e)(3), the reference to “portable tank special provision T50 in § 172.102” is revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.”
Section 178.602
Paragraph (b) is revised to clarify the requirements applicable to filling packaging other than bags in preparation for testing.
Section 178.603
Paragraph (c) is revised to add a definition indicating that a minimum specific gravity for solutions of water and anti-freeze is 0.95 for testing at 18 °C (0 °F) or lower. Additionally, in paragraph (e), we specify the drop test height for liquids in single packagings and for inner packagings of combination packagings, when the test is performed in water.
Section 178.810
Paragraph (b)(3) is revised to specify that water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are acceptable test liquids for use when conducting IBC drop tests. This is consistent with our amendment to § 178.603(c)(1) regarding the testing of non-bulk packages. In addition, we added a sentence to clarify that when conditioning is required by § 178.810(b), the conditioning specified in § 178.802 (which requires a higher temperature) does not apply.We received a comment from the Reusable Industrial Packaging Association (RIPA) concerning this revision. RIPA believes that RSPA intended to clarify that water/antifreeze solutions with a minimum specific gravity of 0.95 are equivalent for testing purposes to IBCs containing only water, thereby eliminating the need to adjust the drop height of test units. RIPA stated that § 178.810(b)(3) should be revised to indicate that this solution may be considered equivalent to water for testing purposes. We agree and have revised the section accordingly.
Part 180
Section 180.350
Paragraph (c) is revised to expand the definition of routine maintenance of IBCs to include flexible, plastic and textile IBCs.
Section 180.352
Paragraph (d)(1)(iv) is revised to require persons other than the owner of metal, rigid plastics, and composite IBCs to mark the IBC indicating routine maintenance has been performed when such maintenance is performed. A new paragraph (d)(1)(v) is added to this section. This paragraph states that retests and inspections performed under paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the tests and inspections required by paragraph (b) of this section. This addition incorporates changes made to the 12th revised edition of the Transport of Dangerous Goods Model Regulations into the HMR. Three commenters requested that we revise § 180.352 to distinguish requirements applicable to repair and routine maintenance of IBCs. We agree and have revised § 180.352 creating a new paragraph entitled, “Requirements applicable to routine maintenance of IBCs.”
V. Regulatory Analyses and Notices
A. Statutory/Legal Authority for This Rulemaking
This final rule is published under the following statutory authorities:
1. 49 U.S.C. 5103(b) authorizes the Secretary of Transportation to prescribe regulations for the safe transportation, including security, of hazardous material in intrastate, interstate, and foreign commerce. This final rule amends regulations to maintain alignment with international standards by incorporating various amendments, including changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. To this end, as discussed in detail earlier in this preamble, the final rule amends the HMR to more fully align it with the biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions to facilitate the transport of hazardous materials in international commerce.
2. 49 U.S.C. 5120(b) authorizes the Secretary of Transportation to ensure that, to the extent practicable, regulations governing the transportation of hazardous materials in commerce are consistent with standards adopted by international authorities. This final rule amends the HMR to maintain alignment with international standards by incorporating various amendments to facilitate the transport of hazardous material in international commerce. To this end, as discussed in detail earlier in this preamble, the final rule incorporates changes into the HMR Start Printed Page 76059based on the Thirteenth Revised Edition of the UN Recommendation, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation; at the same time, harmonization ensures the safety of people, property, and the environment by reducing the potential for confusion and misunderstanding that could result if shippers and transporters were required to comply with two or more conflicting sets of regulatory requirements. While the intent of this rulemaking is to align the HMR with international standards, we review and consider each amendment on its own merit based on its overall impact on transportation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without sacrificing the current HMR level of safety and without imposing undue burdens on the regulated public. Thus, as discussed in detail earlier in this preamble, there are several instances where we elected not to adopt a specific provision of the UN Recommendations, the IMDG Code or the ICAO Technical Instructions; further, we are maintaining a number of current exceptions for domestic transportation that should minimize the compliance burden on the regulated community.
B. Executive Order 12866 and DOT Regulatory Policies and Procedures
This final rule is not considered a significant regulatory action under section 3(f) of Executive Order 12866 and, therefore, was not reviewed by the Office of Management and Budget. This final rule is not considered a significant rule under the Regulatory Policies and Procedures of the Department of Transportation [44 FR 11034]. Benefits resulting from the adoption of the amendments in this final rule include enhanced transportation safety resulting from the consistency of domestic and international hazard communications and continued access to foreign markets by domestic shippers of hazardous materials. This final rule applies to offerors and carriers of hazardous materials, such as chemical manufacturers, chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, radiopharmaceutical companies, and training companies.
The majority of amendments in this final rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America. For example, cost savings will be realized by shippers and carriers as a result of the following:
—Eliminating the air eligibility marking requirement.
—Amendments allowing numerous Class 3, PG II materials with a Class 8 sub-risk and others to be transported as a limited quantity.
—Allowing cylinders to be used for many more substances than currently authorized.
—Allowing salvage packagings to be used for non-conforming packages; and generally minimizing differences between U.S. and international hazardous materials transportation regulations.
We are authorizing a delayed effective date and a one-year transition period to allow for training of employees and to ease any burden on entities affected by the amendments. The total net increase in costs to businesses in implementing this rulemaking is considered to be minimal and a regulatory evaluation is available for review in the Docket.
C. Executive Order 13132
This final rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13132 (“Federalism”). This final rule preempts State, local and Indian tribe requirements but does not propose any regulation that has substantial direct effects on the States, the relationship between the national government and the States, or the distribution of power and responsibilities among the various levels of government. Therefore, the consultation and funding requirements of Executive Order 13132 do not apply.
The Federal hazardous material transportation law, 49 U.S.C. 5101-5127, contains an express preemption provision (49 U.S.C. 5125(b)) that preempts State, local, and Indian tribe requirements on certain covered subjects. Covered subjects are:
(1) The designation, description, and classification of hazardous materials;
(2) The packing, repacking, handling, labeling, marking, and placarding of hazardous materials;
(3) The preparation, execution, and use of shipping documents related to hazardous materials and requirements related to the number, contents, and placement of those documents;
(4) The written notification, recording, and reporting of the unintentional release in transportation of hazardous; and
(5) The design, manufacture, fabrication, marking, maintenance, recondition, repair, or testing of a packaging or container represented, marked, certified, or sold as qualified for use in transporting hazardous material.
This final rule addresses covered subject items (1), (2), (3), and (5) above and preempts State, local, and Indian tribe requirements not meeting the “substantively the same” standard. This final rule is necessary to incorporate changes adopted in international standards, effective January 1, 2005. If the changes in this final rule are not adopted in the HMR, U.S. companies, including numerous small entities competing in foreign markets, are at an economic disadvantage. These companies are forced to comply with a dual system of regulations. The changes in this rulemaking are intended to avoid this result. Federal hazardous materials transportation law provides at section 5125(b)(2) that, if DOT issues a regulation concerning any of the covered subjects, DOT must determine and publish in the Federal Register the effective date of Federal preemption. The effective date may not be earlier than the 90th day following the date of issuance of the final rule and not later than two years after the date of issuance. The effective date of Federal preemption is March 21, 2005.
D. Executive Order 13175
This final rule was analyzed in accordance with the principles and criteria contained in Executive Order 13175 (“Consultation and Coordination with Indian Tribal Governments”). Because this final rule does not have tribal implications, does not impose substantial direct compliance costs, and is required by statute, the funding and consultation requirements of Executive Order 13175 do not apply.
E. Regulatory Flexibility Act, Executive Order 13272, and DOT Procedures and Policies
The Regulatory Flexibility Act (5 U.S.C. 601 et seq.) requires an agency to review regulations to assess their impact on small entities, unless the agency determines that a rule is not expected to have a significant impact on a substantial number of small entities. This final rule facilitates the transportation of hazardous materials in international commerce by providing consistency with international standards. This final rule applies to offerors and carriers of hazardous materials, some of whom are small entities, such as chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, and Start Printed Page 76060training companies. As discussed above, under Executive Order 12866, the majority of amendments in this final rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America.
Many companies will realize economic benefits as a result of these amendments. Additionally, the changes brought forth by this final rule will relive U.S. companies, including small entities competing in foreign markets, from the burden of complying with a dual system of regulations. Therefore, I certify that these amendments will not, if promulgated, have a significant economic impact on a substantial number of small entities.
This final rule has been developed in accordance with Executive Order 13272 (“Proper Consideration of Small Entities in Agency Rulemaking”) and DOT's procedures and policies to promote compliance with the Regulatory Flexibility Act to ensure that potential impacts of draft rules on small entities are properly considered.
F. Paperwork Reduction Act
Under the Paperwork Reduction Act of 1995, no person is required to respond to a collection of information unless it displays a valid Office of Management and Budget (OMB) control number. Section 1320.8(d), Title 5, Code of Federal Regulations requires that RSPA provide interested members of the public and affected agencies an opportunity to comment on information collection and recordkeeping requests. RSPA currently has two approved information collections affecting this final rule: OMB Control Number 2137-0557, “Approvals for Hazardous Materials” with 25,605 burden hours and $562,837.40 burden costs; and OMB Control Number 2137-0613, “Subsidiary Hazard Class & Number/Type of Packagings” with 63,309 burden hours and $216,705 burden costs.
There are minor editorial changes under this rule. However, there is no net increase in burden for OMB Control Number 2137-0557 or OMB Control Number 2137-0613. We estimate that the total information collection and recordkeeping burden as follows:
“Approvals for Hazardous Materials”
OMB Number 2137-0557:
Total Annual Number of Respondents: 3,523.
Total Annual Responses: 3,874.8.
Total Annual Burden Hours: 25,605.
Total Annual Burden Cost: $562,837.40.
“Subsidiary Hazard Class & Number/Type of Packagings”
OMB Number 2137-0613:
Total Annual Number of Respondents: 250,000.
Total Annual Responses: 6,337,500.
Total Annual Burden Hours: 17,604.
Total Annual Burden Cost: $216,705.
Total First Year Burden Hours: 45,705.
Total First Year Burden Cost: $1,115,992.
Requests for a copy of this information collection should be directed to Deborah Boothe or T. Glenn Foster, Office of Hazardous Materials Standards (DHM-10), Research and Special Programs Administration, Room 8422, 400 Seventh Street, SW., Washington, DC 20590-0001, telephone (202) 366-8553.
G. Regulatory Identifier Number (RIN)
A regulation identifier number (RIN) is assigned to each regulatory action listed in the Unified Agenda of Federal Regulations. The Regulatory Information Service Center publishes the Unified Agenda in April and October of each year. The RIN contained in the heading of this document can be used to cross-reference this action with the Unified Agenda.
H. Unfunded Mandates Reform Act
This final rule does not impose unfunded mandates under the Unfunded Mandates Reform Act of 1995. It does not result in costs of $120.7 million or more to either State, local or tribal governments, in the aggregate, or to the private sector, and is the least burdensome alternative that achieves the objective of the rule.
I. Environmental Assessment
The National Environmental Policy Act of 1969 (NEPA) requires Federal agencies to consider the consequences of major Federal actions and prepare a detailed statement on actions significantly affecting the quality of the human environment. We developed an assessment to determine the effects of these revisions on the environment and whether a more comprehensive environmental impact statement may be required. Our findings conclude that there are no significant environmental impacts associated with this final rule. Consistency in the regulations for the transportation of hazardous materials aids in the shipper's understanding of what is required and permits shippers to more easily comply with safety regulations and avoid the potential for environmental damage or contamination. For interested parties, an environmental assessment is available in the public docket.
J. Privacy Act
Anyone is able to search the electronic form of any written communications and comments received into any of our dockets by the name of the individual submitting the document (or signing the document, if submitted on behalf of an association, business, labor union, etc.). You may review DOT's complete Privacy Act Statement in the Federal Register published on April 11, 2000 (Volume 65, Number 70; Pages 19477-78) or you may visit http://dms.dot.gov.
Start List of SubjectsList of Subjects
49 CFR Part 171
- Exports
- Hazardous materials transportation
- Hazardous waste
- Imports
- Incorporation by reference
- Reporting and recordkeeping requirements
49 CFR Part 172
- Education
- Hazardous materials transportation
- Hazardous waste
- Incorporation by reference
- Labeling
- Markings
- Packaging and containers
- Reporting and recordkeeping requirements
49 CFR Part 173
- Hazardous materials transportation
- Incorporation by reference
- Packaging and containers
- Radioactive materials
- Reporting and recordkeeping requirements
- Uranium
49 CFR Part 175
- Air carriers
- Hazardous materials transportation
- Incorporation by reference
- Radioactive materials
- Reporting and recordkeeping requirements
49 CFR Part 176
- Hazardous materials transportation
- Incorporation by reference
- Maritime carriers
- Radioactive materials
- Reporting and recordkeeping requirements
49 CFR Part 178
- Hazardous materials transportation
- Incorporation by reference
- Motor vehicle safety
- Packaging and containers
- Reporting and recordkeeping requirements
49 CFR Part 180
- Hazardous materials transportation
- Motor carriers
- Motor vehicle safety
- Packaging and containers
- Railroad safety
- Reporting and recordkeeping requirements
In consideration of the foregoing, 49 CFR Chapter I is amended as follows:
End Amendment Part Start PartPART 171—GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS
End Part Start Amendment Part1. The authority citation for part 171 continues to read as follows:
End Amendment Part Start Amendment Part2. In § 171.7, in the paragraph (a)(3) table, the following changes are made:
End Amendment Part Start Amendment Parta. Under the entry “International Civil Aviation Organization (ICAO),” the existing entry is revised;
End Amendment Part Start Amendment Partb. Under the entry “International Maritime Organization (IMO),” the entry “International Maritime Dangerous Goods (IMDG) Code, 2002 Consolidated Edition, as amended by Amendment 31 (English edition)” is removed and one entry is added in its place;
End Amendment Part Start Amendment Partc. Under the entry “United Nations,” the entry “UN Recommendations on the Transport of Dangerous Goods, Twelfth Revised Edition (2001)” is revised;
End Amendment Part Start Amendment Partd. Under the entry “United Nations,” the entry “UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Third Revised Edition (1999)” is revised; and
End Amendment Part Start Amendment Parte. In paragraph (b), a new entry “American Institute of Chemical Engineers (AIChE),” 3 Park Avenue New York, NY 10016-5991, Process Safety Progress Journal, Vol. 21, No. 2, “Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology” is added in alphabetical order.
End Amendment PartThe revisions and additions read as follows:
Reference material.(a) * * *
(3) Table of material incorporated by reference. * * *
Source and name of material 49 CFR reference * * * * * * * International Civil Aviation Organization (ICAO), * * * * * * * Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), 2005-2006 Edition 171.8; 171.11; 172.202; 172.401; 172.512; 172.602; 173.320; 175.33; 178.3. International Maritime Organization (IMO), * * * * * * * International Maritime Dangerous Goods Code (IMDG Code), 2004 Edition, Incorporating Amendment 32-04 (English Edition), Volumes 1 and 2 171.12; 172.202; 172.401; 172.502; 172.602; 173.21; 176.2; 176.5; 176.11; 176.27; 176.30; 178.3. * * * * * * * United Nations, * * * * * * * UN Recommendations on the Transport of Dangerous Goods, Thirteenth Revised Edition (2003), Volumes I and II 171.12; 172.202; 172.401; 172.502; 173.22; 173.24; 173.24b; 173.197; Part 173, appendix H; 178.274; 178.801. UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Fourth Revised Edition, (2003) 172.102; 173.21; 173.56; 173.57; 173.58; 173.115; 173.124; 173.125; 173.127; 173.128; 173.185. * * * * * * * (b) List of informational materials not requiring incorporation by reference. * * *
Source and name of material 49 CFR reference * * * * * * * American Institute of Chemical Engineers (AIChE), Start Printed Page 76062 3 Park Avenue New York, NY 10016-5991 Process Safety Progress Journal, Vol. 21, No. 2 Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology Note to § 173. 225(h)(3)(vi). * * * * * * * 3. In § 171.8, the definition for “Salvage packaging” is revised to read as follows:
End Amendment PartDefinitions and abbreviations.* * * * *Salvage packaging means a special packaging conforming to § 173.3 of this subchapter into which damaged, defective, leaking, or non-conforming hazardous materials packages, or hazardous materials that have spilled or leaked, are placed for purposes of transport for recovery or disposal.
* * * * *4. In § 171.11, paragraphs (d)(15) and (d)(17) are revised to read as follows:
End Amendment PartUse of ICAO Technical Instructions.* * * * *(d) * * *
(15) A chemical oxygen generator, including when fitted in protective breathing equipment or other apparatus, is forbidden for transportation aboard a passenger-carrying aircraft and must be approved, classed, described and packaged in accordance with the requirements of this subchapter for transportation on cargo-only aircraft. A chemical oxygen generator that has been used or spent is also forbidden for transportation on a passenger aircraft and cargo aircraft only.
* * * * *(17) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
5. In § 171.12, paragraph (b)(20) is revised to read as follows:
End Amendment PartImport and export shipments.* * * * *(b) * * *
(20) A self-reactive substance that is not identified by technical name in the Self-Reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
* * * * *6. In § 171.12a, paragraphs (a), (b)(9), and (b)(18) are revised to read as follows:
End Amendment PartCanadian shipments and packagings.(a) Scope and applicability. This section sets forth provisions for the transportation by rail or highway of shipments of hazardous materials which conform to the regulations of the Government of Canada but which may differ from the requirements of this subchapter with regard to hazard communication, classification or packaging. Except as provided in paragraph (b)(5)(iv) of this section, the provisions apply only to shipments which originate in Canada and either terminate in the U.S. or transit the U.S. to a Canadian or foreign destination, and to the return to Canada of bulk packagings that meet the requirements of a DOT or UN Specification and other bulk packagings containing only residues of hazardous materials that were originally imported into the U.S. Reciprocal provisions, applicable to exports from the U.S., appear in the regulations of the Government of Canada.
(b) * * *
(9) For hazardous waste as defined in this subchapter—
(i) The word “Waste” must precede the proper shipping name on shipping papers and packages; and
(ii) The requirements of § 172.204 of this subchapter with respect to the shipper's certification and § 172.205 of this subchapter with respect to hazardous waste manifests are applicable;
* * * * *(18) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
* * * * *7. In § 171.14, paragraphs (d) introductory text, (d)(1), and (d)(2) are revised to read as follows:
End Amendment PartTransitional provisions for implementing certain requirements.* * * * *(d) A final rule published in the Federal Register on December 20, 2004, effective January 1, 2005, resulted in revisions to this subchapter. During the transition period, until January 1, 2006, as provided in paragraph (d)(1) of this section, a person may elect to comply with either the applicable requirements of this subchapter in effect on December 31, 2004, or the requirements published in the December 20, 2004, final rule.
(1) Transition dates. The effective date of the final rule published on December 20, 2004, is January 1, 2005. A delayed compliance date of January 1, 2006 is authorized. On and after January 1, 2006, all applicable regulatory requirements adopted in the final rule in effect on January 1, 2005 must be met.
(2) Intermixing old and new requirements. Marking, labeling, placarding, and shipping paper descriptions must conform to either the old requirements of this subchapter in effect on December 31, 2004, or the new requirements of this subchapter in the final rule without intermixing communication elements, except that intermixing is permitted, during the applicable transition period, for packaging, hazard communication, and handling provisions, as follows:
* * * * *PART 172—HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND TRAINING REQUIREMENTS
End Part Start Amendment Part8. The authority citation for part 172 continues to read as follows:
End Amendment Part Start Amendment Part9. In § 172.101, the following amendments are made:
End Amendment Part Start Amendment Parta. Paragraph (c)(11) is revised;
End Amendment Part Start Amendment Partb. Paragraph (d)(4) is revised;
End Amendment Part Start Amendment Partc. Paragraph (i)(3) is revised;
End Amendment Part Start Amendment Partd. Hazardous Materials Table is revised as set forth below:
End Amendment PartPurpose and use of hazardous materials table.* * * * *(c) * * *
(11) Except for a material subject to or prohibited by § 173.21, 173.54, 173.56(d), 173.56(e), 173.224(c) or 173.225(b) of this subchapter, a material that is considered to be a hazardous waste or a sample of a material for which the hazard class is uncertain and must be determined by testing may be assigned a tentative proper shipping name, hazard class, identification number and packing group, if applicable, based on the shipper's tentative determination according to:
(i) Defining criteria in this subchapter;
(ii) The hazard precedence prescribed in § 173.2a of this subchapter;
(iii) The shipper's knowledge of the material;
(iv) In addition to paragraphs (c)(11)(i) through (iii) of this section, for a sample of a material other than a waste, the following must be met:
(A) Except when the word “Sample” already appears in the proper shipping name, the word “Sample” must appear as part of the proper shipping name or in association with the basic description on the shipping paper.
(B) When the proper shipping description for a sample is assigned a “G” in Column (1) of the § 172.101 Table, and the primary constituent(s) for which the tentative classification is based are not known, the provisions requiring a technical name for the constituent(s) do not apply; and
(C) A sample must be transported in a combination packaging that conforms to the requirements of this subchapter that are applicable to the tentative packing group assigned, and may not exceed a net mass of 2.5 kg (5.5 pounds) per package.
Note to Paragraph (c)(11): For the transportation of self-reactive, organic peroxide and explosive samples, see §§ 173.224(c)(3), 173.225(b)(2) and 173.56(d) of this subchapter, respectively.
* * * * *(d) * * *
(4) When an entry in this column reads “Comb liq”, the material is assigned to the hazard class “Combustible liquid.” Additionally, each reference to a Class 3 material is modified to read “Combustible liquid” when that material is reclassified in accordance with § 173.150 (e) or (f) of this subchapter or has a flash point above 60.5 °C (141 °F) but below 93 °C (200 °F).
* * * * *(i) * * *
(3) Bulk packaging. Column 8C specifies the section in part 173 of this subchapter that prescribes packaging requirements for bulk packagings, subject to the limitations, requirements and additional authorizations of Column 7. A “None” in this column means bulk packagings are not authorized, except as may be provided by special provisions in Column 7. Additional authorizations and limitations for use of UN portable tanks are set forth in Column 7. For each reference in this column to a material that is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter “A” or “W” and that is offered for transportation or transported by a mode in which its transportation is not otherwise subject to the requirements of this subchapter:
* * * * *Start Printed Page 76150§ 172.101 Hazardous Materials Table
Symbols Hazardous materials descriptions and proper shipping names Hazard class or Division Identification Numbers PG Label Codes Special provisions (§172.102) (8) Packaging (§173.***) (9) Quantity limitations (10) Vessel stowage Exceptions Non-bulk Bulk Passenger aircraft/rail Cargo air- craft only Location Other (1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B) (10A) (10B) Accellerene, see p-Nitrosodimethylaniline Accumulators, electric, see Batteries, wet etc Accumulators, pressurized, pneumatic or hydraulic (containing non-flamable gas), see Articles pressurized, pneumatic or hydraulic (containing non-flamable gas) Acetal 3 UN1088 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E Acetaldehyde 3 UN1089 I 3 A3, B16, T11, TP2, TP7 None 201 243 Forbidden 30 L E A Acetaldehyde ammonia 9 UN1841 III 9 IB8, IP3, IP7, T1, TP33 155 204 240 200 kg 200 kg A 34 Acetaldehyde oxime 3 UN2332 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A Acetic acid, glacial or Acetic acid solution, with more than 80 percent acid, by mass 8 UN2789 II 8, 3 A3, A6, A7, A10, B2, IB2, T7, TP2 154 202 243 1 L 30 L A Acetic acid solution, not less than 50 percent but not more than 80 percent acid, by mass 8 UN2790 II 8 A3, A6, A7, A10, B2, IB2, T7, TP2 154 202 242 1 L 30 L A Acetic acid solution, with more than 10 percent and less than 50 percent acid, by mass 8 UN2790 III 8 IB3, T4, TP1 154 203 242 5 L 60 L A Acetic anhydride 8 UN1715 II 8, 3 A3, A6, A7, A10, B2, IB2, T7, TP2 154 202 243 1 L 30 L A 40 Acetone 3 UN1090 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Acetone cyanohydrin, stabilized 6.1 UN1541 I 6.1 2, B9, B14, B32, B76, B77, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 25, 40, 52, 53 Acetone oils 3 UN1091 II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B Acetonitrile 3 UN1648 II 3 IB2, T7, TP2 150 202 242 5 L 60 L B 40 Acetyl acetone peroxide with more than 9 percent by mass active oxygen Forbidden Acetyl benzoyl peroxide, solid, or with more than 40 percent in solution Forbidden Acetyl bromide 8 UN1716 II 8 B2, IB2, T8, TP2, TP12 154 202 242 1 L 30 L C 40 Acetyl chloride 3 UN1717 II 3, 8 A3, A6, A7, IB1, N34, T8, TP2, TP12 150 202 243 1 L 5 L B 40 Acetyl cyclohexanesulfonyl peroxide, with more than 82 percent wetted with less than 12 percent water Forbidden Acetyl iodide 8 UN1898 II 8 B2, IB2, T7, TP2, TP13 154 202 242 1 L 30 L C 40 Acetyl methyl carbinol 3 UN2621 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Acetyl peroxide, solid, or with more than 25 percent in solution Forbidden Acetylene, dissolved 2.1 UN1001 2.1 None 303 None Forbidden 15 kg D 25, 40, 57 Acetylene (liquefied) Forbidden Acetylene silver nitrate Forbidden Acetylene tetrabromide, see Tetrabromoethane Acid butyl phosphate, see Butyl acid phosphate Acid, sludge, see Sludge acid Acridine 6.1 UN2713 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Acrolein dimer, stabilized 3 UN2607 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40 Acrolein, stabilized 6.1 UN1092 I 6.1, 3 1, B9, B14, B30, B42, B72, B77, T22, TP2, TP7, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Acrylamide, solid 6.1 UN2074 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 12 Acrylamide solution 6.1 UN3426 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 12 Acrylic acid, stabilized 8 UN2218 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L C 25, 40 Acrylonitrile, stabilized 3 UN1093 I 3, 6.1 B9, T14, TP2, TP13 None 201 243 Forbidden 30 L E 40 Actuating cartridge, explosive, see Cartridges, power device Adhesives, containing a flammable liquid 3 UN1133 I 3 B42, T11, TP1, TP8, TP27 150 201 143 1 L 30 L B II 3 149, B52, IB2, T4, TP1, TP8 150 173 242 5 L 60 L B Start Printed Page 76065 III 3 B1, B52, IB3, T2, TP1 150 173 242 60 L 220 L A Adiponitrile 6.1 UN2205 III 6.1 IB3, T3, TP1 153 203 241 60 L 220 L A Aerosols, corrosive, Packing Group II or III, (each not exceeding 1 L capacity) 2.2 UN1950 2.2, 8 153, A34 306 None None 75 kg 150 kg A 48, 87, 126 Aerosols, flammable, (each not exceeding 1 L capacity) 2.1 UN1950 2.1 153, N82 306 None None 75 kg 150 kg A 48, 87, 126 Aerosols, flammable, n.o.s. (engine starting fluid) (each not exceeding 1 L capacity) 2.1 UN1950 2.1 153, N82 306 304 None Forbidden 150 kg A 48, 87, 126 Aerosols, non-flammable, (each not exceeding 1 L capacity) 2.2 UN1950 2.2 153 306 None None 75 kg 150 kg A 48, 87, 126 Aerosols, poison, each not exceeding 1 L capacity 2.2 UN1950 2.2, 6.1 153 306 None None Forbidden Forbidden A 48, 87, 126 I Air bag inflators, or Air bag modules, or Seat-belt pretensioners. 1.4G UN0503 II 1.4G 161 None 62 None Forbidden 75 kg 02 Air bag inflators, or Air bag modules, or Seat-belt pretensioners. 9 UN3268 III 9 160 166 166 166 25 kg 100 kg A Air, compressed 2.2 UN1002 2.2 78 306 302 302 75 kg 150 kg A Air, refrigerated liquid, (cryogenic liquid) 2.2 UN1003 2.2, 5.1 T75, TP5, TP22 320 316 318, 319 Forbidden 150 kg D 51 Air, refrigerated liquid, (cryogenic liquid) non-pressurized 2.2 UN1003 2.2, 5.1 T75, TP5, TP22 320 316 318, 319 Forbidden Forbidden D 51 Aircraft engines (including turbines), see Engines, internal combustion Aircraft evacuation slides, see Life saving appliances etc Aircraft hydraulic power unit fuel tank (containing a mixture of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel) 3 UN3165 I 3, 6.1, 8 None 172 None Forbidden 42 L E Aircraft survival kits, see Life saving appliances etc G Alcoholates solution, n.o.s., in alcohol 3 UN3274 II 3, 8 IB2 150 202 243 1 L 5 L B Alcoholic beverages 3 UN3065 II 3 24, 149, B1, IB2, T4, TP1 150 202 242 5 L 60 L A III 3 24, B1, IB3, N11, T2, TP1 150 203 242 60 L 220 L A Alcohols, n.o.s. 3 UN1987 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L E II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A G Alcohols, flammable, toxic, n.o.s. 3 UN1986 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L E 40 II 3, 6.1 IB2, T11, TP2, TP27 150 202 243 1 L 60 L B 40 III 3, 6.1 B1, IB3, T7, TP1, TP28 None 203 242 60 L 220 L A Aldehydes, n.o.s. 3 UN1989 I 3 T11, TP1, TP27 None 201 243 1 L 30 L E II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A G Aldehydes, flammable, toxic, n.o.s. 3 UN1988 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L E 40 II 3, 6.1 IB2, T11, TP2, TP27 150 202 243 1 L 60 L B 40 III 3, 6.1 B1, IB3, T7, TP1, TP28 150 203 242 60 L 220 L A Aldol 6.1 UN2839 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 12 G Alkali metal alcoholates, self-heating, corrosive, n.o.s. 4.2 UN3206 II 4.2, 8 64, A7, IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg B III 4.2, 8 64, A7, IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg B Alkali metal alloys, liquid, n.o.s. 4.3 UN1421 I 4.3 A2, A3, A7, B48, N34 None 201 244 Forbidden 1 L D 52 Alkali metal amalgam, liquid 4.3 UN1389 I 4.3 A2, A3, A7, N34 None 201 244 Forbidden 1 L D 40, 52 Alkali metal amalgam, solid 4.3 UN3401 I 4.3 IB4, IP1, N40, T9, TP7, TP33 None 211 242 Forbidden 15 kg D 52 Alkali metal amides 4.3 UN1390 II 4.3 A6, A7, A8, A19, A20, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg E 40, 52 Alkali metal dispersions, or Alkaline earth metal dispersions 4.3 UN1391 I 4.3 A2, A3, A7 None 201 244 Forbidden 1 L D 52 Alkaline corrosive liquids, n.o.s., see Caustic alkali liquids, n.o.s. G Alkaline earth metal alcoholates, n.o.s. 4.2 UN3205 II 4.2 65, A7, IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg B III 4.2 65, A7, IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg B Alkaline earth metal alloys, n.o.s. 4.3 UN1393 II 4.3 A19, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg E 52 Alkaline earth metal amalgams, liquid 4.3 UN1392 I 4.3 A19, N34, N40 None 201 244 Forbidden 1 L E 40, 52 Start Printed Page 76066 Alkaline earth metal amalgams, solid 4.3 UN3402 I 4.3 A19, N34, N40, T9, TP7, TP33 None 211 242 Forbidden 15 kg D 52 G Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s. 6.1 UN3140 I 6.1 A4, T14, TP2, TP27 None 201 243 1 L 30 L A II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L A III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A G Alkaloids, solid, n.o.s. [or] Alkaloid salts, solid, n.o.s. [poisonous] 6.1 UN1544 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with more than 5 percent free sulfuric acid 8 UN2584 II 8 B2, IB2, T8, TP2, TP12, TP13 154 202 242 1 L 30 L B Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid with not more than 5 percent free sulfuric acid 8 UN2586 III 8 IB3, T4, TP1 154 203 241 5 L 60 L B Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, with more than 5 percent free sulfuric acid 8 UN2583 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid with not more than 5 percent free sulfuric acid 8 UN2585 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Alkylphenols, liquid, n.o.s. (including C2-C12 homologues) 8 UN3145 I 8 A6, T14, TP2 None 201 243 0.5 L 2.5 L B II 8 IB2, T11, TP2, TP27 154 202 242 1 L 30 L B III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A Alkylphenols, solid, n.o.s. (including C2-C12 homologues) 8 UN2430 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg B III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Alkylsulfuric acids 8 UN2571 II 8 B2, IB2, T8, TP2, TP12, TP13, TP28 154 202 242 1 L 30 L C 14 Allethrin, see Pesticides, liquid, toxic, n.o.s. Allyl acetate 3 UN2333 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40 Allyl alcohol 6.1 UN1098 I 6.1, 3 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Allyl bromide 3 UN1099 I 3, 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L B 40 Allyl chloride 3 UN1100 I 3, 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L E 40 Allyl chlorocarbonate, see Allyl chloroformate Allyl chloroformate 6.1 UN1722 I 6.1, 3, 8 2, B9, B14, B32, B74, N41, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Allyl ethyl ether 3 UN2335 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40 Allyl formate 3 UN2336 I 3, 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L E 40 Allyl glycidyl ether 3 UN2219 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Allyl iodide 3 UN1723 II 3, 8 A3, A6, IB1, N34, T7, TP2, TP13 150 202 243 1 L 5 L B 40 Allyl isothiocyanate, stabilized 6.1 UN1545 II 6.1, 3 A3, A7, IB2, T7, TP2 None 202 243 Forbidden 60 L D 40 Allylamine 6.1 UN2334 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Start Printed Page 76067 Allyltrichlorosilane, stabilized 8 UN1724 II 8, 3 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 243 Forbidden 30 L C 40 Aluminum alkyl halides, liquid 4.2 UN3052 I 4.2, 4.3 B9, B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D 134 Aluminium alkyl halides, solid 4.2 UN3461 I 4.2, 4.3 T21, TP7, TP33 None 181 244 Forbidden Forbidden D 134 Aluminum alkyl hydrides 4.2 UN3076 I 4.2, 4.3 B9, B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D Aluminum alkyls 4.2 UN3051 I 4.2, 4.3 B9, B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D Aluminum borohydride or Aluminum borohydride in devices 4.2 UN2870 I 4.2, 4.3 B11, T21, TP7, TP33 None 181 244 Forbidden Forbidden D Aluminum bromide, anhydrous 8 UN1725 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 40 Aluminum bromide, solution 8 UN2580 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Aluminum carbide 4.3 UN1394 II 4.3 A20, IB7, IP2, N41, T3, TP33 151 212 242 15 kg 50 kg A 52 Aluminum chloride, anhydrous 8 UN1726 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 40 Aluminum chloride, solution 8 UN2581 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Aluminum dross, wet or hot Forbidden Aluminum ferrosilicon powder 4.3 UN1395 II 4.3, 6.1 A19, IB5, IP2, T3, TP33 151 212 242 15 kg 50 kg A 39, 40, 52, 53, 85, 103 III 4.3, 6.1 A19, A20, IB4 151 213 241 25 kg 100 kg A 39, 40, 52, 53, 85, 103 Aluminum hydride 4.3 UN2463 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E D Aluminum, molten 9 NA9260 III 9 IB3, T1, TP3 None None 247 Forbidden Forbidden D Aluminum nitrate 5.1 UN1438 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Aluminum phosphate solution, see Corrosive liquids, etc Aluminum phosphide 4.3 UN1397 I 4.3, 6.1 A8, A19, N40 None 211 242 Forbidden 15 kg E 40, 52, 85 Aluminum phosphide pesticides 6.1 UN3048 I 6.1 A8, IB7, IP1, T6, TP33 None 211 242 Forbidden 15 kg E 40, 85 Aluminum powder, coated 4.1 UN1309 II 4.1 IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg A 13, 39, 52, 53, 74, 101 III 4.1 IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A 13, 39, 52, 53, 74, 101 Aluminum powder, uncoated 4.3 UN1396 II 4.3 A19, A20, IB7, IP2, T3, TP33 151 212 242 15 kg 50 kg A 39, 52, 53 III 4.3 A19, A20, IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg A 39, 52, 53 Aluminum resinate 4.1 UN2715 III 4.1 IB6, T1, TP33 151 213 240 25 kg 100 kg A Aluminum silicon powder, uncoated 4.3 UN1398 III 4.3 A1, A19, IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg A 39, 40, 52, 53, 85, 103 Aluminum smelting by-products or Aluminum remelting by-products 4.3 UN3170 II 4.3 128, B115, IB7, IP2, T3, TP33 None 212 242 15 kg 50 kg B 85, 103 III 4.3 128, B115, IB8, IP4, T1, TP33 None 213 241 25 kg 100 kg B 85, 103 Amatols, see Explosives, blasting, type B G Amines, flammable, corrosive, n.o.s. or Polyamines, flammable, corrosive, n.o.s. 3 UN2733 I 3, 8 T14, TP1, TP27 None 201 243 0.5 L 2.5 L D 40 II 3, 8 IB2, T11, TP1, TP27 150 202 243 1 L 5 L B 40 III 3, 8 B1, IB3, T7, TP1, TP28 150 203 242 5 L 60 L A 40 G Amines, liquid, corrosive, flammable, n.o.s. or Polyamines, liquid, corrosive, flammable, n.o.s. 8 UN2734 I 8, 3 A3, A6, N34, T14, TP2, TP27 None 201 243 0.5 L 2.5 L A 52 II 8, 3 IB2, T11, TP2, TP27 None 202 243 1 L 30 L A 52 G Amines, liquid, corrosive, n.o.s., or Polyamines, liquid, corrosive, n.o.s. 8 UN2735 I 8 A3, A6, B10, N34, T14, TP2, TP27 None 201 243 0.5 L 2.5 L A 52 II 8 B2, IB2, T11, TP1, TP27 154 202 242 1 L 30 L A 52 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 52 G Amines, solid, corrosive, n.o.s., or Polyamines, solid, corrosive n.o.s. 8 UN3259 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg A 52 Start Printed Page 76068 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 52 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 52 2-Amino-4-chlorophenol 6.1 UN2673 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 2-Amino-5-diethylaminopentane 6.1 UN2946 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 2-Amino-4,6-Dinitrophenol, wetted with not less than 20 percent water by mass 4.1 UN3317 I 4.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg E 28, 36 2-(2-Aminoethoxy) ethanol 8 UN3055 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A N-Aminoethylpiperazine 8 UN2815 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 12 + Aminophenols (o-; m-; p-) 6.1 UN2512 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Aminopropyldiethanolamine, see Amines, etc n-Aminopropylmorpholine, see Amines, etc Aminopyridines (o-; m-; p-) 6.1 UN2671 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 12, 40 I Ammonia, anhydrous 2.3 UN1005 2.3, 8 4, T50 None 304 314, 315 Forbidden Forbidden D 40, 57 D Ammonia, anhydrous 2.2 UN1005 2.2 13, T50 None 304 314, 315 Forbidden Forbidden D 40, 57 D Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia 2.2 UN3318 2.2 13, T50 None 304 314, 315 Forbidden Forbidden D 40, 57 I Ammonia solution, relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia 2.3 UN3318 2.3, 8 4, T50 None 304 314, 315 Forbidden Forbidden D 40, 57 Ammonia solutions, relative density between 0.880 and 0.957 at 15 degrees C in water, with more than 10 percent but not more than 35 percent ammonia 8 UN2672 III 8 IB3, IP8, T7, TP1 154 203 241 5 L 60 L A 40, 85 Ammonia solutions, relative density less than 0.880 at 15 degrees C in water, with more than 35 percent but not more than 50 percent ammonia 2.2 UN2073 2.2 306 304 314, 315 Forbidden 150 kg E 40, 57 Ammonium arsenate 6.1 UN1546 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 53 Ammonium azide Forbidden Ammonium bifluoride, solid, see Ammonium hydrogen difluoride, solid Ammonium bifluoride solution, see Ammonium hydrogen difluoride, solution Ammonium bromate Forbidden Ammonium chlorate Forbidden Ammonium dichromate 5.1 UN1439 II 5.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A 52 Ammonium dinitro-o-cresolate, solid 6.1 UN1843 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 36, 65, 66, 77 Ammonium dinitro-o-cresolate solution 6.1 UN3424 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 36, 66, 78, 91 III 6.1 IB2, T7, TP2 153 203 241 60 L 220 L A 36, 66, 78, 91 Ammonium fluoride 6.1 UN2505 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Ammonium fluorosilicate 6.1 UN2854 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Ammonium fulminate Forbidden Ammonium hydrogen sulfate 8 UN2506 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 40 Ammonium hydrogendifluoride, solid 8 UN1727 II 8 IB8, IP2, IP4, N34, T3, TP33 154 212 240 15 kg 50 kg A 25, 40, 52 Ammonium hydrogendifluoride, solution 8 UN2817 II 8, 6.1 IB2, N34, T8, TP2, TP12, TP13 154 202 243 1 L 30 L B 40 III 8, 6.1 IB3, N3, T4, TP1, TP12, TP13 154 203 241 5 L 60 L B 40, 95 Ammonium hydrosulfide, solution, see Ammonium sulfide solution D Ammonium hydroxide, see Ammonia solutions, etc Ammonium metavanadate 6.1 UN2859 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 44, 89, 100, 141 Ammonium nitrate based fertilizer 5.1 UN2067 III 5.1 52, 150, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg B 48, 59, 60, 66, 117 Start Printed Page 76069 A W Ammonium nitrate based fertilizer 9 UN2071 III 9 132, IB8, IP3 155 213 240 200 kg 200 kg A Ammonium nitrate emulsion or Ammonium nitrate suspension or Ammonium nitrate gel, intermediate for blasting explosives 5.1 UN3375 II 147, 163 None 214 214 Forbidden Forbidden D 48, 59, 60, 66, 124 D Ammonium nitrate-fuel oil mixture containing only prilled ammonium nitrate and fuel oil 1.5D NA0331 II 1.5D None 62 None Forbidden Forbidden 10 19E Ammonium nitrate, liquid (hot concentrated solution) 5.1 UN2426 5.1 B5, T7 None None 243 Forbidden Forbidden D 59, 60 Ammonium nitrate, with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance 1.1D UN0222 II 1.1D None 62 None Forbidden Forbidden 10 19E Ammonium nitrate, with not more than 0.2% total combustible material, including any organic substance, calculated as carbon to the exclusion of any other added substance 5.1 UN1942 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 48, 59, 60, 116 Ammonium nitrite Forbidden Ammonium perchlorate 1.1D UN0402 II 1.1D 107 None 62 None Forbidden Forbidden 10 19E Ammonium perchlorate 5.1 UN1442 II 5.1 107, A9, IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg E 58, 69 Ammonium permanganate Forbidden Ammonium persulfate 5.1 UN1444 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Ammonium picrate, dry or wetted with less than 10 percent water, by mass 1.1D UN0004 II 1.1D None 62 None Forbidden Forbidden 10 5E, 19E Ammonium picrate, wetted with not less than 10 percent water, by mass 4.1 UN1310 I 4.1 23, A2, N41 None 211 None 0.5 kg 0.5 kg D 28, 36 Ammonium polysulfide, solution 8 UN2818 II 8, 6.1 IB2, T7, TP2, TP13 154 202 243 1 L 30 L B 12, 40, 52 III 8, 6.1 IB3, T4, TP1, TP13 154 203 241 5 L 60 L B 12, 40, 52 Ammonium polyvanadate 6.1 UN2861 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 44, 89, 100, 141 Ammonium silicofluoride, see Ammonium fluorosilicate Ammonium sulfide solution 8 UN2683 II 8, 6.1, 3 IB1, T7, TP2, TP13 154 202 243 1 L 30 L B 12, 22, 52, 100 Ammunition, blank, see Cartridges for weapons, blank Ammunition, illuminating with or without burster, expelling charge or propelling charge 1.2G UN0171 II 1.2G 62 None Forbidden Forbidden 03 Ammunition, illuminating with or without burster, expelling charge or propelling charge 1.3G UN0254 II 1.3G 62 None Forbidden Forbidden 03 Ammunition, illuminating with or without burster, expelling charge or propelling charge 1.4G UN0297 II 1.4G 62 None Forbidden 75 kg 02 Ammunition, incendiary liquid or gel, with burster, expelling charge or propelling charge 1.3J UN0247 II 1.3J 62 None Forbidden Forbidden 04 23E Ammunition, incendiary (water-activated contrivances) with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge 1.2H UN0243 II 1.2H 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Ammunition, incendiary, white phosphorus, with burster, expelling charge or propelling charge 1.3H UN0244 II 1.3H 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.2G UN0009 II 1.2G 62 None Forbidden Forbidden 03 Ammunition, incendiary with or without burster, expelling charge, or propelling charge 1.3G UN0010 II 1.3G 62 None Forbidden Forbidden 03 Ammunition, incendiary with or without burster, expelling charge or propelling charge 1.4G UN0300 II 1.4G 62 None Forbidden 75 kg 02 Ammunition, practice 1.4G UN0362 II 1.4G 62 None Forbidden 75 kg 02 Ammunition, practice 1.3G UN0488 II 1.3G 62 None Forbidden Forbidden 03 Ammunition, proof 1.4G UN0363 II 1.4G 62 None Forbidden 75 kg 02 Ammunition, rocket, see Warheads, rocket etc Ammunition, SA (small arms), see Cartridges for weapons, etc Ammunition, smoke (water-activated contrivances), white phosphorus, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0248) Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides, with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc. (UN 0249) Ammunition smoke, white phosphorus with burster,expelling charge, or propelling charge 1.2H UN0245 II 1.2H 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Ammunition, smoke, white phosphorus with burster, expelling charge, or propelling charge 1.3H UN0246 II 1.3H 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Ammunition, smoke with or without burster, expelling charge or propelling charge 1.2G UN0015 II 1.2G 62 None Forbidden Forbidden 8E, 17E, 20E Ammunition, smoke with or without burster, expelling charge or propelling charge 1.3G UN0016 II 1.3G 62 None Forbidden Forbidden 8E, 17E, 20E Start Printed Page 76070 Ammunition, smoke with or without burster, expelling charge or propelling charge 1.4G UN0303 II 1.4G 62 None Forbidden 75 kg 7E, 8E, 14E, 15E, 17E Ammunition, sporting, see Cartridges for weapons, etc. (UN 0012; UN 0328; UN 0339) Ammunition, tear-producing, non-explosive, without burster or expelling charge, non-fuzed 6.1 UN2017 II 6.1, 8 None 212 None Forbidden 50 kg E 13, 40 Ammunition, tear-producing with burster, expelling charge or propelling charge 1.2G UN0018 II 1.2G, 8, 6.1 62 None Forbidden Forbidden 8E, 17E, 20E Ammunition, tear-producing with burster, expelling charge or propelling charge 1.3G UN0019 II 1.3G, 8, 6.1 62 None Forbidden Forbidden 8E, 17E, 20E Ammunition, tear-producing with burster, expelling charge or propelling charge 1.4G UN0301 II 1.4G, 8, 6.1 62 None Forbidden 75 kg 7E, 8E, 14E, 15E, 17E Ammunition, toxic, non-explosive, without burster or expelling charge, non-fuzed 6.1 UN2016 II 6.1 None 212 None Forbidden 100 kg E 13, 40 Ammunition, toxic (water-activated contrivances), with burster, expelling charge or propelling charge, see Contrivances, water-activated, etc G Ammunition, toxic with burster, expelling charge, or propelling charge 1.2K UN0020 II 1.2K, 6.1 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E G Ammunition, toxic with burster, expelling charge, or propelling charge 1.3K UN0021 II 1.3K, 6.1 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Amyl acetates 3 UN1104 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Amyl acid phosphate 8 UN2819 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Amyl butyrates 3 UN2620 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Amyl chlorides 3 UN1107 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Amyl formates 3 UN1109 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Amyl mercaptans 3 UN1111 II 3 A3, A6, IB2, T4, TP1 None 202 242 5 L 60 L B 95, 102 n-Amyl methyl ketone 3 UN1110 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Amyl nitrate 3 UN1112 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40 Amyl nitrites 3 UN1113 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 40 Amylamines 3 UN1106 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A Amyltrichlorosilane 8 UN1728 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Anhydrous ammonia, see Ammonia, anhydrous Anhydrous hydrofluoric acid, see Hydrogen fluoride, anhydrous + Aniline 6.1 UN1547 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40, 52 Aniline hydrochloride 6.1 UN1548 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Aniline oil, see Aniline Anisidines 6.1 UN2431 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Anisole 3 UN2222 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Anisoyl chloride 8 UN1729 II 8 B2, B4, IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Anti-freeze, liquid, see Flammable liquids, n.o.s. Antimonous chloride, see Antimony trichloride Antimony compounds, inorganic, liquid, n.o.s. 6.1 UN3141 III 6.1 35, IB3, T7, TP1, TP28 153 203 241 60 L 220 L A Antimony compounds, inorganic, solid, n.o.s. 6.1 UN1549 III 6.1 35, IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Antimony lactate 6.1 UN1550 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Antimony pentachloride, liquid 8 UN1730 II 8 B2, IB2, T7, TP2 None 202 242 1 L 30 L C 40 Antimony pentachloride, solutions 8 UN1731 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C 40 III 8 IB3, T4, TP1 154 203 241 5 L 60 L C 40 Start Printed Page 76071 Antimony pentafluoride 8 UN1732 II 8, 6.1 A3, A6, A7, A10, IB2, N3, N36, T7, TP2 None 202 243 Forbidden 30 L D 44, 89, 100, 141 Antimony potassium tartrate 6.1 UN1551 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Antimony powder 6.1 UN2871 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Antimony sulfide and a chlorate, mixtures of Forbidden Antimony sulfide, solid, see Antimony compounds, inorganic, n.o.s. Antimony trichloride, liquid 8 UN1733 II 8 B2, IB2 154 202 242 1 L 30 L C 40 Antimony trichloride, solid 8 UN1733 II 8 IB8, IP2, IP4 154 212 240 15 kg 50 kg A 40 Aqua ammonia, see Ammonia solution, etc Argon, compressed 2.2 UN1006 2.2 306 302 314, 315 75 kg 150 kg A Argon, refrigerated liquid (cryogenic liquid) 2.2 UN1951 2.2 T75, TP5 320 316 318 50 kg 500 kg B Arsenic 6.1 UN1558 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Arsenic acid, liquid 6.1 UN1553 I 6.1 T20, TP2, TP7, TP13 None 201 243 1 L 30 L B 46 Arsenic acid, solid 6.1 UN1554 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Arsenic bromide 6.1 UN1555 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 12, 40 Arsenic chloride, see Arsenic trichloride Arsenic compounds, liquid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s. 6.1 UN1556 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40, 137 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40, 137 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L B 40, 137 Arsenic compounds, solid, n.o.s. inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s. 6.1 UN1557 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 137 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 137 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 137 Arsenic pentoxide 6.1 UN1559 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Arsenic sulfide and a chlorate, mixtures of Forbidden Arsenic trichloride 6.1 UN1560 I 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden B 40 Arsenic trioxide 6.1 UN1561 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Arsenic, white, solid, see Arsenic trioxide Arsenical dust 6.1 UN1562 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Arsenical pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2760 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Arsenical pesticides, liquid, toxic 6.1 UN2994 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Arsenical pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN2993 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Arsenical pesticides, solid, toxic 6.1 UN2759 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Arsenious acid, solid, see Arsenic trioxide Arsenious and mercuric iodide solution, see Arsenic compounds, liquid, n.o.s. Arsine 2.3 UN2188 2.3, 2.1 1 None 192 245 Forbidden Forbidden D 40 Articles, explosive, extremely insensitive or Articles, EEI 1.6N UN0486 II 1.6N 101 None 62 None Forbidden Forbidden 07 Start Printed Page 76072 G Articles, explosive, n.o.s. 1.4S UN0349 II 1.4S 101 None 62 None 25 kg 100 kg 05 G Articles, explosive, n.o.s. 1.4B UN0350 II 1.4B 101 None 62 None Forbidden Forbidden 06 G Articles, explosive, n.o.s. 1.4C UN0351 II 1.4C 101 None 62 None Forbidden 75 kg 06 G Articles, explosive, n.o.s. 1.4D UN0352 II 1.4D 101 None 62 None Forbidden 75 kg 06 G Articles, explosive, n.o.s. 1.4G UN0353 II 1.4G 101 None 62 None Forbidden 75 kg 06 G Articles, explosive, n.o.s. 1.1L UN0354 II 1.1L 101 None 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E G Articles, explosive, n.o.s. 1.2L UN0355 II 1.2L 101 None 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E G Articles, explosive, n.o.s. 1.3L UN0356 II 1.3L 101 None 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E G Articles, explosive, n.o.s. 1.1C UN0462 II 1.1C 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.1D UN0463 II 1.1D 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.1E UN0464 II 1.1E 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.1F UN0465 II 1.1F 101 None 62 None Forbidden Forbidden 08 G Articles, explosive, n.o.s. 1.2C UN0466 II 1.2C 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.2D UN0467 II 1.2D 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.2E UN0468 II 1.2E 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.2F UN0469 II 1.2F 101 None 62 None Forbidden Forbidden 08 G Articles, explosive, n.o.s. 1.3C UN0470 II 1.3C 101 None 62 None Forbidden Forbidden 07 G Articles, explosive, n.o.s. 1.4E UN0471 II 1.4E 101 None 62 None Forbidden 75 kg 06 G Articles, explosive, n.o.s. 1.4F UN0472 II 1.4F 101 None 62 None Forbidden Forbidden 08 Articles, pressurized pneumatic or hydraulic containing non-flammable gas 2.2 UN3164 2.2 306 302, 304 None No limit No limit A Articles, pyrophoric 1.2L UN0380 II 1.2L None 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Articles, pyrotechnic for technical purposes 1.1G UN0428 II 1.1G None 62 None Forbidden Forbidden 07 Articles, pyrotechnic for technical purposes 1.2G UN0429 II 1.2G None 62 None Forbidden Forbidden 07 Articles, pyrotechnic for technical purposes 1.3G UN0430 II 1.3G None 62 None Forbidden Forbidden 07 Articles, pyrotechnic for technical purposes 1.4G UN0431 II 1.4G None 62 None Forbidden 75 kg 06 Articles, pyrotechnic for technical purposes 1.4S UN0432 II 1.4S None 62 None 25 kg 100 kg 05 D Asbestos 9 NA2212 III 9 156, IB8, IP2, IP4 155 216 240 200 kg 200 kg A 34, 40 Ascaridole (organic peroxide) Forbidden D Asphalt, at or above its flash point 3 NA1999 III 3 IB3, T1, TP3 150 203 247 Forbidden Forbidden D D Asphalt, cut back, see Tars, liquid, etc Automobile, motorcycle, tractor, other self-propelled vehicle, engine, or other mechanical apparatus, see Vehicles or Battery etc A G Aviation regulated liquid, n.o.s. 9 UN3334 9 A35 155 204 No limit No limit A A G Aviation regulated solid, n.o.s. 9 UN3335 9 A35 155 204 No limit No limit A Azaurolic acid (salt of) (dry) Forbidden Azido guanidine picrate (dry) Forbidden 5-Azido-1-hydroxy tetrazole Forbidden Azido hydroxy tetrazole (mercury and silver salts) Forbidden 3-Azido-1,2-Propylene glycol dinitrate Forbidden Azidodithiocarbonic acid Forbidden Azidoethyl nitrate Forbidden 1-Aziridinylphosphine oxide-(tris), see Tris-(1-aziridinyl) phosphine oxide, solution Azodicarbonamide 4.1 UN3242 II 4.1 38, IB8, T3, TP33 151 212 240 Forbidden Forbidden D 12, 52, 53, 74 Azotetrazole (dry) Forbidden Barium 4.3 UN1400 II 4.3 A19, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg E 52 Barium alloys, pyrophoric 4.2 UN1854 I 4.2 T21, TP7, TP33 None 181 None Forbidden Forbidden D Barium azide, dry or wetted with less than 50 percent water, by mass 1.1A UN0224 II 1.1A, 6.1 111, 117 None 62 None Forbidden Forbidden 12 Start Printed Page 76073 Barium azide, wetted with not less than 50 percent water, by mass 4.1 UN1571 I 4.1, 6.1 162, A2 None 182 None Forbidden 0.5 kg D 28 Barium bromate 5.1 UN2719 II 5.1, 6.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Barium chlorate, solid 5.1 UN1445 II 5.1, 6.1 A9, IB6, IP2, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Barium chlorate, solution 5.1 UN3405 II 5.1, 6.1 A9, IB2, N34, T4, TP1 152 202 243 1 L 5 L A 56, 58, 133 III 5.1, 6.1 A9, IB2, N34, T4, TP1 152 203 242 2.5 L 30 L A 56, 58, 133 Barium compounds, n.o.s. 6.1 UN1564 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Barium cyanide 6.1 UN1565 I 6.1 IB7, IP1, N74, N75, T6, TP33 None 211 242 5 kg 50 kg A 40, 52 Barium hypochlorite with more than 22 percent available chlorine 5.1 UN2741 II 5.1, 6.1 A7, A9, IB8, IP2, IP4, N34, T3, TP33 152 212 None 5 kg 25 kg B 4, 52, 56, 58, 106 Barium nitrate 5.1 UN1446 II 5.1, 6.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A Barium oxide 6.1 UN1884 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Barium perchlorate, solid 5.1 UN1447 II 5.1, 6.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Barium perchlorate, solution 5.1 UN3406 II 5.1, 6.1 IB2, T4, TP1 152 202 243 1 L 5 L A 56, 58, 133 III 5.1, 6.1 IB2, T4, TP1 152 203 242 2.5 L 30 L A 56, 58, 133 Barium permanganate 5.1 UN1448 II 5.1, 6.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D 56, 58, 138 Barium peroxide 5.1 UN1449 II 5.1, 6.1 A9, IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 56, 75 Barium selenate, see Selenates or Selenites Barium selenite, see Selenates or Selenites Batteries, containing sodium 4.3 UN3292 II 4.3 189 189 189 Forbidden No limit A Batteries, dry, containing potassium hydroxide solid, electric, storage 8 UN3028 III 8 None 213 None 25 kg gross 230 kg gross A Batteries, wet, filled with acid, electric storage 8 UN2794 III 8 159 159 159 30 kg gross No limit A Batteries, wet, filled with alkali, electric storage 8 UN2795 III 8 159 159 159 30 kg gross No limit A Batteries, wet, non-spillable, electric storage 8 UN2800 III 8 159 159 159 No Limit No Limit A Batteries, dry, not subject to the requirements of this subchapter 130 Battery fluid, acid 8 UN2796 II 8 A3, A7, B2, B15, IB2, N6, N34, T8, TP2, TP12 154 202 242 1 L 30 L B Battery fluid, alkali 8 UN2797 II 8 B2, IB2, N6, T7, TP2, TP28 154 202 242 1 L 30 L A 29 Battery lithium type, see Lithium batteries etc Battery-powered vehicle or Battery-powered equipment 9 UN3171 9 134 220 220 None No limit No limit Battery, wet, filled with acid or alkali with vehicle or mechanical equipment containing an internal combustion engine, see Vehicle, etc. or Engines, internal combustion, etc + Benzaldehyde 9 UN1990 III 9 IB3, T2, TP1 155 203 241 100 L 220 L A Benzene 3 UN1114 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Benzene diazonium chloride (dry) Forbidden Benzene diazonium nitrate (dry) Forbidden Benzene phosphorus dichloride, see Phenyl phosphorus dichloride Benzene phosphorus thiodichloride, see Phenyl phosphorus thiodichloride Benzene sulfonyl chloride 8 UN2225 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 40 Benzene triozonide Forbidden Benzenethiol, see Phenyl mercaptan Benzidine 6.1 UN1885 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Benzol, see Benzene Benzonitrile 6.1 UN2224 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40, 52 Benzoquinone 6.1 UN2587 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Benzotrichloride 8 UN2226 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 40 Benzotrifluoride 3 UN2338 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Benzoxidiazoles (dry) Forbidden Benzoyl azide Forbidden Benzoyl chloride 8 UN1736 II 8 B2, IB2, T8, TP2, TP12, TP13 154 202 242 1 L 30 L C 40 Benzyl bromide 6.1 UN1737 II 6.1, 8 A3, A7, IB2, N33, N34, T8, TP2, TP12, TP13 153 202 243 1 L 30 L D 13, 40 Start Printed Page 76074 Benzyl chloride 6.1 UN1738 II 6.1, 8 A3, A7, B70, IB2, N33, N42, T8, TP2, TP12, TP13 153 202 243 1 L 30 L D 13, 40 Benzyl chloride unstabilized 6.1 UN1738 II 6.1, 8 A3, A7, B8, B11, IB2, N33, N34, N43, T8, TP2, TP12, TP13 153 202 243 1 L 30 L D 13, 40 Benzyl chloroformate 8 UN1739 I 8 A3, A6, B4, N41, T10, TP2, TP12, TP13 None 201 243 Forbidden 2.5 L D 40 Benzyl iodide 6.1 UN2653 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 12, 40 Benzyldimethylamine 8 UN2619 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L A 40, 48 Benzylidene chloride 6.1 UN1886 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 40 Beryllium compounds, n.o.s. 6.1 UN1566 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Beryllium nitrate 5.1 UN2464 II 5.1, 6.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A Beryllium, powder 6.1 UN1567 II 6.1, 4.1 IB8, IP2, IP4, T3, TP33 153 212 242 15 kg 50 kg A Bicyclo [2,2,1] hepta-2,5-diene, stabilized or 2,5-Norbornadiene, stabilized 3 UN2251 II 3 IB2, T7, TP2 150 202 242 5 L 60 L D Biphenyl triozonide Forbidden Bipyridilium pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2782 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L E II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Bipyridilium pesticides, liquid, toxic 6.1 UN3016 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Bipyridilium pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3015 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 21, 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 21, 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 21, 40 Bipyridilium pesticides, solid, toxic 6.1 UN2781 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Bis (Aminopropyl) piperazine, see Corrosive liquid, n.o.s. Bisulfate, aqueous solution 8 UN2837 II 8 A7, B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L A III 8 A7, IB3, N34, T4, TP1 154 203 241 5 L 60 L A Bisulfites, aqueous solutions, n.o.s. 8 UN2693 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40, 52 Black powder, compressed or Gunpowder, compressed or Black powder, in pellets or Gunpowder, in pellets 1.1D UN0028 II 1.1D None 62 None Forbidden Forbidden 10 Black powder or Gunpowder, granular or as a meal 1.1D UN0027 II 1.1D None 62 None Forbidden Forbidden 10 D Black powder for small arms 4.1 NA0027 I 4.1 70 None 170 None Forbidden Forbidden E Blasting agent, n.o.s., see Explosives, blasting etc Blasting cap assemblies, see Detonator assemblies, non-electric, for blasting Blasting caps, electric, see Detonators, electric for blasting Blasting caps, non-electric, see Detonators, non-electric, for blasting Bleaching powder, see Calcium hypochlorite mixtures, etc I Blue asbestos (Crocidolite) or Brown asbestos (amosite, mysorite) 9 UN2212 II 9 156, IB8, IP2, IP4, T3, TP33 155 216 240 Forbidden Forbidden A 34, 40 Bombs, photo-flash 1.1F UN0037 II 1.1F 62 None Forbidden Forbidden 08 Bombs, photo-flash 1.1D UN0038 II 1.1D 62 None Forbidden Forbidden 03 Start Printed Page 76075 Bombs, photo-flash 1.2G UN0039 II 1.2G 62 None Forbidden Forbidden 03 Bombs, photo-flash 1.3G UN0299 II 1.3G 62 None Forbidden Forbidden 03 Bombs, smoke, non-explosive, with corrosive liquid, without initiating device 8 UN2028 II 8 None 160 None Forbidden 50 kg E 40 Bombs, with bursting charge 1.1F UN0033 II 1.1F 62 None Forbidden Forbidden 08 Bombs, with bursting charge 1.1D UN0034 II 1.1D 62 None Forbidden Forbidden 03 Bombs, with bursting charge 1.2D UN0035 II 1.2D 62 None Forbidden Forbidden 03 Bombs, with bursting charge 1.2F UN0291 II 1.2F 62 None Forbidden Forbidden 08 Bombs with flammable liquid, with bursting charge 1.1J UN0399 II 1.1J 62 None Forbidden Forbidden 04 23E Bombs with flammable liquid, with bursting charge 1.2J UN0400 II 1.2J 62 None Forbidden Forbidden 04 23E Boosters with detonator 1.1B UN0225 II 1.1B None 62 None Forbidden Forbidden 11 Boosters with detonator 1.2B UN0268 II 1.2B None 62 None Forbidden Forbidden 07 Boosters, without detonator 1.1D UN0042 II 1.1D None 62 None Forbidden Forbidden 07 Boosters, without detonator 1.2D UN0283 II 1.2D None 62 None Forbidden Forbidden 07 Borate and chlorate mixtures, see Chlorate and borate mixtures Borneol 4.1 UN1312 III 4.1 A1, IB8, IP3, T1, TP33 None 213 240 25 kg 100 kg A + Boron tribromide 8 UN2692 I 8, 6.1 2, B9, B14, B32, B74, N34, T20, TP2, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden C 12 Boron trichloride 2.3 UN1741 2.3, 8 3, B9, B14 None 304 314 Forbidden Forbidden D 25, 40 Boron trifluoride 2.3 UN1008 2.3 2, B9, B14 None 302 314, 315 Forbidden Forbidden D 40 Boron trifluoride acetic acid complex, liquid 8 UN1742 II 8 B2, B6, IB2, T8, TP2, TP12 154 202 242 1 L 30 L A Boron trifluoride acetic acid complex, solid 8 UN3419 II 8 B2, B6, IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Boron trifluoride diethyl etherate 8 UN2604 I 8, 3 A3, A19, T10, TP2 None 201 243 0.5 L 2.5 L D 40 Boron trifluoride dihydrate 8 UN2851 II 8 IB2, T7, TP2 154 212 240 15 kg 50 kg B 12, 40, Boron trifluoride dimethyl etherate 4.3 UN2965 I 4.3, 8, 3 A19, T10, TP2, TP7 None 201 243 Forbidden 1 L D 21, 28, 40, 49, 100 Boron trifluoride propionic acid complex, liquid 8 UN1743 II 8 B2, IB2, T8, TP2, TP12 154 202 242 1 L 30 L A Boron trifluoride propionic acid complex, solid 8 UN3420 II 8 B2, IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Box toe gum, see Nitrocellulose etc Bromates, inorganic, aqueous solution, n.o.s. 5.1 UN3213 II 5.1 IB2, T4, TP1 152 202 242 1 L 5 L B 56, 58, 133 III 5.1 IB2, T4, TP1 152 203 241 2.5 L 30 L B 56, 58, 133 Bromates, inorganic, n.o.s. 5.1 UN1450 II 5.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Bromine azide Forbidden + Bromine or Bromine solutions 8 UN1744 I 8, 6.1 1, B9, B64, B85, N34, N43, T22, TP2, TP10, TP12, TP13 None 226 249 Forbidden Forbidden 12, 40, 66, 74, 89, 90 Bromine chloride 2.3 UN2901 2.3, 8, 5.1 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40, 89, 90 + Bromine pentafluoride 5.1 UN1745 I 5.1, 6.1, 8 1, B9, B14, B30, B72, T22, TP2, TP12, TP13, TP38, TP44 None 228 244 Forbidden Forbidden D 25, 40, 66, 90 + Bromine trifluoride 5.1 UN1746 I 5.1, 6.1, 8 2, B9, B14, B32, B74, T22, TP2, TP12, TP13, TP38, TP45 None 228 244 Forbidden Forbidden D 25, 40, 66, 90 4-Bromo-1,2-dinitrobenzene Forbidden 4-Bromo-1,2-dinitrobenzene (unstable at 59 degrees C) Forbidden 1-Bromo-3-chloropropane 6.1 UN2688 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 1-Bromo-3-methylbutane 3 UN2341 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 1-Bromo-3-nitrobenzene (unstable at 56 degrees C) Forbidden 2-Bromo-2-nitropropane-1,3-diol 4.1 UN3241 III 4.1 46, IB8, IP3 151 213 None 25 kg 50 kg C 12, 25, 40 Bromoacetic acid, solid 8 UN3425 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 154 212 240 15 kg 50 kg A Bromoacetic acid solution 8 UN1938 II 8 A7, B2, IB2, T7, TP2 154 202 242 1 L 30 L A 40 III 8 B2, IB3, T7, TP2 154 203 241 5 L 60 L A 40 + Bromoacetone 6.1 UN1569 II 6.1, 3 2, T20, TP2, TP13 None 193 245 Forbidden Forbidden D 40 Start Printed Page 76076 Bromoacetyl bromide 8 UN2513 II 8 B2, IB2, T8, TP2, TP12 154 202 242 1 L 30 L C 40, 53 Bromobenzene 3 UN2514 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Bromobenzyl cyanides, liquid 6.1 UN1694 I 6.1 T14, TP2, TP13 None 201 243 Forbidden 30 L D 12, 40, 52 Bromobenzyl cyanides, solid 6.1 UN3449 I 6.1 T6, TP33 None 211 242 5 kg 50 kg D 12, 40, 52 1-Bromobutane 3 UN1126 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 2-Bromobutane 3 UN2339 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B 40 Bromochloromethane 6.1 UN1887 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 2-Bromoethyl ethyl ether 3 UN2340 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Bromoform 6.1 UN2515 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 12, 40 Bromomethylpropanes 3 UN2342 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 2-Bromopentane 3 UN2343 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Bromopropanes 3 UN2344 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 III 3 IB3, T2, TP1 150 203 242 60 L 220 L A 3-Bromopropyne 3 UN2345 II 3 IB2, T4, TP1 150 202 242 5 L 60 L D 40 Bromosilane Forbidden Bromotoluene-alpha, see Benzyl bromide Bromotrifluoroethylene 2.1 UN2419 2.1 None 304 314, 315 Forbidden 150 kg B 40 Bromotrifluoromethane or Refrigerant gas, R 13B1. 2.2 UN1009 2.2 T50 306 304 314, 315 75 kg 150 kg A Brucine 6.1 UN1570 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A Bursters, explosive 1.1D UN0043 II 1.1D None 62 None Forbidden Forbidden 07 Butadienes, stabilized or Butadienes and Hydrocarbon mixture, stabilized containing more than 40% butadienes 2.1 UN1010 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Butane see also Petroleum gases, liquefied 2.1 UN1011 2.1 19, T50 306 304 314, 315 Forbidden 150 kg E 40 Butane, butane mixtures and mixtures having similar properties in cartridges each not exceeding 500 grams, see Receptacles, etc Butanedione 3 UN2346 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 1,2,4-Butanetriol trinitrate Forbidden Butanols 3 UN1120 II 3 IB2, T4, TP1, TP29 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A tert-Butoxycarbonyl azide Forbidden Butyl acetates 3 UN1123 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Butyl acid phosphate 8 UN1718 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Butyl acrylates, stabilized 3 UN2348 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Butyl alcohols, see Butanols Butyl benzenes 3 UN2709 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A n-Butyl bromide, see 1-Bromobutane n-Butyl chloride, see Chlorobutanes D sec-Butyl chloroformate 6.1 NA2742 I 6.1, 3, 8 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 1 L 30 L A 12, 13, 22, 25, 40, 48, 100 n-Butyl chloroformate 6.1 UN2743 I 6.1, 8, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden A 12, 13, 21, 25, 40, 100 Butyl ethers, see Dibutyl ethers Butyl ethyl ether, see Ethyl butyl ether n-Butyl formate 3 UN1128 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B tert-Butyl hydroperoxide, with more than 90 percent with water Forbidden tert-Butyl hypochlorite 4.2 UN3255 I 4.2, 8 None 211 243 Forbidden Forbidden D N-n-Butyl imidazole 6.1 UN2690 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A tert-Butyl isocyanate 6.1 UN2484 I 6.1, 3 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Start Printed Page 76077 n-Butyl isocyanate 6.1 UN2485 I 6.1, 3 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Butyl mercaptans 3 UN2347 II 3 A3, A6, IB2, T4, TP1 150 202 242 5 L 60 L D 52, 95 n-Butyl methacrylate, stabilized 3 UN2227 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Butyl methyl ether 3 UN2350 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Butyl nitrites 3 UN2351 I 3 T11, TP1, TP8, TP27 150 201 243 1 L 30 L E 40 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40 tert-Butyl peroxyacetate, with more than 76 percent in solution Forbidden n-Butyl peroxydicarbonate, with more than 52 percent in solution Forbidden tert-Butyl peroxyisobutyrate, with more than 77 percent in solution Forbidden Butyl phosphoric acid, see Butyl acid phosphate Butyl propionates 3 UN1914 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 5-tert-Butyl-2,4,6-trinitro-m-xylene or Musk xylene 4.1 UN2956 III 4.1 159 None 223 None Forbidden Forbidden D D12, 25, 48, 127 Butyl vinyl ether, stabilized 3 UN2352 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 n-Butylamine 3 UN1125 II 3, 8 IB2, T7, TP1 150 202 242 1 L 5 L B 40 N-Butylaniline 6.1 UN2738 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 74 tert-Butylcyclohexylchloroformate 6.1 UN2747 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 12, 13, 25 Butylene see also Petroleum gases, liquefied 2.1 UN1012 2.1 19, T50 306 304 314, 315 Forbidden 150 kg E 40 1,2-Butylene oxide, stabilized 3 UN3022 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 27, 49 Butyltoluenes 6.1 UN2667 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Butyltrichlorosilane 8 UN1747 II 8, 3 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 243 Forbidden 30 L C 40 1,4-Butynediol 6.1 UN2716 III 6.1 A1, IB8, IP3, T1, TP33 None 213 240 100 kg 200 kg A 52, 53, 70, 139, 140 Butyraldehyde 3 UN1129 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Butyraldoxime 3 UN2840 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Butyric acid 8 UN2820 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 12 Butyric anhydride 8 UN2739 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Butyronitrile 3 UN2411 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40 Butyryl chloride 3 UN2353 II 3, 8 IB2, T8, TP2, TP12, TP13 150 202 243 1 L 5 L C 40 Cacodylic acid 6.1 UN1572 II 6.1 IB8, IP2, IP4,T3, TP33 153 212 242 25 kg 100 kg E 52 Cadmium compounds 6.1 UN2570 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Caesium hydroxide 8 UN2682 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 29 Caesium hydroxide solution 8 UN2681 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 29 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 29 Calcium 4.3 UN1401 II 4.3 IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg E 52 Calcium arsenate 6.1 UN1573 II 6.1 IB8, IP2, IP4, T3, TP33 152 212 242 25 kg 100 kg A Calcium arsenate and calcium arsenite, mixtures, solid 6.1 UN1574 II 6.1 IB8, IP2, IP4, T3, TP33 152 212 242 25 kg 100 kg A Calcium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. Calcium carbide 4.3 UN1402 I 4.3 A1, A8, B55, B59, IB4, IP1, N34, T9, TP7, TP33 None 211 242 Forbidden 15 kg B 52 II 4.3 A1, A8, B55, B59, IB7, IP2, N34, T3, TP33 151 212 241 15 kg 50 kg B 52 Calcium chlorate 5.1 UN1452 II 5.1 A9, IB8, IP2, IP4, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Calcium chlorate aqueous solution 5.1 UN2429 II 5.1 A2, IB2, N41, T4, TP1 152 202 242 1 L 5 L B 56, 58, 133 Start Printed Page 76078 III 5.1 A2, IB2, N41, T4, TP1 152 203 241 2.5 L 30 L B 56, 68, 133 Calcium chlorite 5.1 UN1453 II 5.1 A9, IB8, IP2, IP4, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Calcium cyanamide with more than 0.1 percent of calcium carbide 4.3 UN1403 III 4.3 A1, A19, IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg A 52 Calcium cyanide 6.1 UN1575 I 6.1 IB7, IP1, N79, N80, T6, TP33 None 211 242 5 kg 50 kg A 40, 52 Calcium dithionite or Calcium hydrosulfite 4.2 UN1923 II 4.2 A19, A20, IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg E 13 Calcium hydride 4.3 UN1404 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Calcium hydrosulfite, see Calcium dithionite Calcium hypochlorite, dry or Calcium hypochlorite mixtures dry with more than 39 percent available chlorine (8.8 percent available oxygen) 5.1 UN1748 II 5.1 165, 166, A7, A9, IB8, IP2, IP4, IP13, N34, W9 152 212 None 5 kg 25 kg D 4, 25, 48, 52, 56, 58, 69, 142 III 5.1 165, 171, A7, A9, IB8, IP4, IP13, N34, W9 152 213 240 25 kg 100 kg D 4, 25, 48, 52, 56, 58, 69, 142 Calcium hypochlorite, hydrated or Calcium hypochlorite, hydrated mixtures, with not less than 5.5 percent but not more than 16 percent water 5.1 UN2880 II 5.1 165, 166, IB8, IP2, IP4, IP13, W9 152 212 240 5 kg 25 kg D 4, 25, 48, 52, 56, 58, 69, 142 III 5.1 165, 171, IB8, IP4, IP13, W9 152 213 240 25 kg 100 kg D 4, 25, 48, 52, 56, 58, 69, 142 Calcium hypochlorite mixtures, dry, with more than 10 percent but not more than 39 percent available chlorine 5.1 UN2208 III 5.1 165, A1, A29, IB8, IP3, IP13, N34, W9 152 213 240 25 kg 100 kg D 4, 25, 48, 52, 56, 58, 69, 142 Calcium manganese silicon 4.3 UN2844 III 4.3 A1, A19, IB8, IP2, IP4, T1, TP33 151 213 241 25 kg 100 kg A 52, 85, 103 Calcium nitrate 5.1 UN1454 III 5.1 34, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A A Calcium oxide 8 UN1910 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Calcium perchlorate 5.1 UN1455 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Calcium permanganate 5.1 UN1456 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D 56, 58, 138 Calcium peroxide 5.1 UN1457 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 56, 75 Calcium phosphide 4.3 UN1360 I 4.3, 6.1 A8, A19, N40 None 211 242 Forbidden 15 kg E 40, 52, 85 Calcium, pyrophoric or Calcium alloys, pyrophoric 4.2 UN1855 I 4.2 None 187 None Forbidden Forbidden D Calcium resinate 4.1 UN1313 III 4.1 A1, A19, IB6, T1, TP33 None 213 240 25 kg 100 kg A Calcium resinate, fused 4.1 UN1314 III 4.1 A1, A19, IB4, T1, TP33 None 213 240 25 kg 100 kg A Calcium selenate, see Selenates or Selenites Calcium silicide 4.3 UN1405 II 4.3 A19, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg B 52, 85, 103 III 4.3 A1, A19, IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg B 52, 85, 103 Camphor oil 3 UN1130 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Camphor, synthetic 4.1 UN2717 III 4.1 A1, IB8, IP3, T1, TP33 None 213 240 25 kg 100 kg A Cannon primers, see Primers, tubular Caproic acid 8 UN2829 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Caps, blasting, see Detonators, etc Carbamate pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2758 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 Start Printed Page 76079 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Carbamate pesticides, liquid, toxic 6.1 UN2992 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Carbamate pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN2991 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Carbamate pesticides, solid, toxic 6.1 UN2757 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Carbolic acid, see Phenol, solid or Phenol, molten Carbolic acid solutions, see Phenol solutions I Carbon, activated 4.2 UN1362 III 4.2 IB8, IP3, T1, TP33 None 213 241 0.5 kg 0.5 kg A 12 I Carbon, animal or vegetable origin 4.2 UN1361 II 4.2 IB6, T3, TP33 None 212 242 Forbidden Forbidden A 12 III 4.2 IB8, IP3, T1, TP33 None 213 241 Forbidden Forbidden A 12 Carbon bisulfide, see Carbon disulfide Carbon dioxide 2.2 UN1013 2.2 306 302, 304 302, 314, 315 75 kg 150 kg A Carbon dioxide and nitrous oxide mixtures 2.2 UN1015 2.2 306 None 314, 315 75 kg 150 kg A Carbon dioxide and oxygen mixtures, compressed 2.2 UN1014 2.2, 5.1 77, A14 306 304 314, 315 75 kg 150 kg A Carbon dioxide, refrigerated liquid 2.2 UN2187 2.2 T75, TP5 306 304 314, 315 50 kg 500 kg B A W Carbon dioxide, solid or Dry ice 9 UN1845 III None 217 217 240 200 kg 200 kg C 40 Carbon disulfide 3 UN1131 I 3, 6.1 B16, T14, TP2, TP7, TP13 None 201 243 Forbidden Forbidden D 18, 40, 115 Carbon monoxide, compressed 2.3 UN1016 2.3, 2.1 4 None 302 314, 315 Forbidden 25 kg D 40 Carbon monoxide and hydrogen mixture, compressed 2.3 UN2600 2.3, 2.1 6 None 302 302 Forbidden Forbidden D 40, 57 D Carbon monoxide, refrigerated liquid (cryogenic liquid) 2.3 NA9202 2.3, 2.1 4, T75, TP5 None 316 318 Forbidden Forbidden D Carbon tetrabromide 6.1 UN2516 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 25 Carbon tetrachloride 6.1 UN1846 II 6.1 IB2, N36, T7, TP2 153 202 243 5 L 60 L A 40 Carbonyl chloride, see Phosgene Carbonyl fluoride 2.3 UN2417 2.3, 8 2 None 302 None Forbidden Forbidden D 40 Carbonyl sulfide 2.3 UN2204 2.3, 2.1 3, B14 None 304 314, 315 Forbidden Forbidden D 40 Cartridge cases, empty primed, see Cases, cartridge, empty, with primer Cartridges, actuating, for aircraft ejector seat catapult, fire extinguisher, canopy removal or apparatus, see Cartridges, power device Cartridges, explosive, see Charges, demolition Cartridges, flash 1.1G UN0049 II 1.1G None 62 None Forbidden Forbidden 07 Cartridges, flash 1.3G UN0050 II 1.3G None 62 None Forbidden 75 kg 07 Cartridges for weapons, blank 1.1C UN0326 II 1.1C None 62 None Forbidden Forbidden 07 Cartridges for weapons, blank 1.2C UN0413 II 1.2C None 62 None Forbidden Forbidden 07 Cartridges for weapons, blank or Cartridges, small arms, blank 1.4S UN0014 II None 63 62 None 25 kg 100 kg 05 Cartridges for weapons, blank or Cartridges, small arms, blank 1.3C UN0327 II 1.3C None 62 None Forbidden Forbidden 07 Cartridges for weapons, blank or Cartridges, small arms, blank 1.4C UN0338 II 1.4C None 62 None Forbidden 75 kg 06 Cartridges for weapons, inert projectile 1.2C UN0328 II 1.2C None 62 None Forbidden Forbidden 03 Cartridges for weapons, inert projectile or Cartridges, small arms 1.4S UN0012 II None 63 62 None 25 kg 100 kg 05 Cartridges for weapons, inert projectile or Cartridges, small arms 1.4C UN0339 II 1.4C None 62 None Forbidden 75 kg 06 Cartridges for weapons, inert projectile or Cartridges, small arms 1.3C UN0417 II 1.3C None 62 None Forbidden Forbidden 06 Cartridges for weapons, with bursting charge 1.1F UN0005 II 1.1F None 62 None Forbidden Forbidden 08 Cartridges for weapons, with bursting charge 1.1E UN0006 II 1.1E None 62 None Forbidden Forbidden 03 Cartridges for weapons, with bursting charge 1.2F UN0007 II 1.2F None 62 None Forbidden Forbidden 08 Cartridges for weapons, with bursting charge 1.2E UN0321 II 1.2E None 62 None Forbidden Forbidden 03 Cartridges for weapons, with bursting charge 1.4F UN0348 II 1.4F None 62 None Forbidden Forbidden 08 Cartridges for weapons, with bursting charge 1.4E UN0412 II 1.4E None 62 None Forbidden 75 kg 02 Start Printed Page 76080 Cartridges, oil well 1.3C UN0277 II 1.3C None 62 None Forbidden Forbidden 07 Cartridges, oil well 1.4C UN0278 II 1.4C None 62 None Forbidden 75 kg 06 Cartridges, power device 1.3C UN0275 II 1.3C None 62 None Forbidden 75 kg 07 Cartridges, power device 1.4C UN0276 II 1.4C 110 None 62 None Forbidden 75 kg 06 Cartridges, power device 1.4S UN0323 II 1.4S 110 63 62 None 25 kg 100 kg 05 Cartridges, power device 1.2C UN0381 II 1.2C None 62 None Forbidden Forbidden 07 Cartridges, safety, blank, see Cartridges for weapons, blank (UN 0014) Cartridges, safety, see Cartridges for weapons, other than blank or Cartridges, power device (UN 0323) Cartridges, signal 1.3G UN0054 II 1.3G None 62 None Forbidden 75 kg 07 Cartridges, signal 1.4G UN0312 II 1.4G None 62 None Forbidden 75 kg 06 Cartridges, signal 1.4S UN0405 II 1.4S None 62 None 25 kg 100 kg 05 D Cartridges, small arms ORM-D None 63 None None 30 kg gross 30 kg gross A D Cartridges power device (used to project fastening devices) ORM-D None 63 None None 30 kg gross 30 kg gross A Cartridges, sporting, see Cartridges for weapons, other than blank Cartridges, starter, jet engine, see Cartridges, power device Cases, cartridge, empty with primer 1.4S UN0055 II 1.4S 50 None 62 None 25 kg 100 kg 05 Cases, cartridges, empty with primer 1.4C UN0379 II 1.4C 50 None 62 None Forbidden 75 kg 06 Cases, combustible, empty, without primer 1.4C UN0446 II 1.4C None 62 None Forbidden 75 kg 06 Cases, combustible, empty, without primer 1.3C UN0447 II 1.3C None 62 None Forbidden Forbidden 07 Casinghead gasoline see Gasoline A W Castor beans or Castor meal or Castor pomace or Castor flake 9 UN2969 II None IB8, IP2, IP4, T3, TP33 155 204 240 No limit No limit E 34, 40 G Caustic alkali liquids, n.o.s. 8 UN1719 II 8 B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L A 29 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 29 Caustic potash, see Potassium hydroxide etc Caustic soda, (etc.) see Sodium hydroxide etc Cells, containing sodium 4.3 UN3292 II 4.3 189 189 189 25 kg gross No limit A Celluloid, in block, rods, rolls, sheets, tubes, etc., except scrap 4.1 UN2000 III 4.1 None 213 240 25 kg 100 kg A Celluloid, scrap 4.2 UN2002 III 4.2 IB8, IP3 None 213 241 Forbidden Forbidden D Cement, see Adhesives containing flammable liquid Cerium, slabs, ingots, or rods 4.1 UN1333 II 4.1 IB8, IP2, IP4, N34 None 212 240 15 kg 50 kg A 74, 91 Cerium, turnings or gritty powder 4.3 UN3078 II 4.3 A1, IB7, IP2, T3, TP33 151 212 242 15 kg 50 kg E 52 Cesium or Caesium 4.3 UN1407 I 4.3 A7, A19, IB4, IP1, N34, N40 None 211 242 Forbidden 15 kg D 52 Cesium nitrate or Caesium nitrate 5.1 UN1451 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A D Charcoal briquettes, shell, screenings, wood, etc. 4.2 NA1361 III 4.2 IB8, T1, TP33 151 213 240 25 kg 100 kg A 12 Charges, bursting, plastics bonded 1.1D UN0457 II 1.1D None 62 None Forbidden Forbidden 07 Charges, bursting, plastics bonded 1.2D UN0458 II 1.2D None 62 None Forbidden Forbidden 07 Charges, bursting, plastics bonded 1.4D UN0459 II 1.4D None 62 None Forbidden 75 kg 06 Charges, bursting, plastics bonded 1.4S UN0460 II 1.4S None 62 None 25 kg 100 kg 05 Charges, demolition 1.1D UN0048 II 1.1D None 62 None Forbidden Forbidden 03 Charges, depth 1.1D UN0056 II 1.1D None 62 None Forbidden Forbidden 03 Charges, expelling, explosive, for fire extinguishers, see Cartridges, power device Charges, explosive, commercial without detonator 1.1D UN0442 II 1.1D None 62 None Forbidden Forbidden 07 Charges, explosive, commercial without detonator 1.2D UN0443 II 1.2D None 62 None Forbidden Forbidden 07 Charges, explosive, commercial without detonator 1.4D UN0444 II 1.4D None 62 None Forbidden 75 kg 06 Charges, explosive, commercial without detonator 1.4S UN0445 II 1.4S None 62 None 25 kg 100 kg 05 Charges, propelling 1.1C UN0271 II 1.1C None 62 None Forbidden Forbidden 07 Charges, propelling 1.3C UN0272 II 1.3C None 62 None Forbidden Forbidden 07 Charges, propelling 1.2C UN0415 II 1.2C None 62 None Forbidden Forbidden 07 Charges, propelling 1.4C UN0491 II 1.4C None 62 None Forbidden 75 kg 06 Charges, propelling, for cannon 1.3C UN0242 II 1.3C None 62 None Forbidden Forbidden 10 Charges, propelling, for cannon 1.1C UN0279 II 1.1C None 62 None Forbidden Forbidden 10 Charges, propelling, for cannon 1.2C UN0414 II 1.2C None 62 None Forbidden Forbidden 10 Charges, shaped, flexible, linear 1.4D UN0237 II 1.4D None 62 None Forbidden 75 kg 06 Charges, shaped, flexible, linear 1.1D UN0288 II 1.1D 101 None 62 None Forbidden Forbidden 07 Charges, shaped, without detonator 1.1D UN0059 II 1.1D None 62 None Forbidden Forbidden 07 Charges, shaped, without detonator 1.2D UN0439 II 1.2D None 62 None Forbidden Forbidden 07 Charges, shaped, without detonator 1.4D UN0440 II 1.4D None 62 None Forbidden 75 kg 06 Start Printed Page 76081 Charges, shaped, without detonator 1.4S UN0441 II 1.4S None 62 None 25 kg 100 kg 05 Charges, supplementary explosive 1.1D UN0060 II 1.1D None 62 None Forbidden Forbidden 10 D Chemical kit 8 NA1760 II 8 154 161 None 1 L 30 L B 40 Chemical kits 9 UN3316 9 15 161 161 None 10 kg 10 kg A Chloral, anhydrous, stabilized 6.1 UN2075 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 40 Chlorate and borate mixtures 5.1 UN1458 II 5.1 A9, IB8, IP2, IP4, N34, T3, TP33 152 212 240 5 kg 25 kg A 56, 58 III 5.1 A9, IB8, IP3, N34, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Chlorate and magnesium chloride mixture, solid 5.1 UN1459 II 5.1 A9, IB8, IP2, IP4, N34, T3, TP33 152 212 240 5 kg 25 kg A 56, 58 Chlorate and magnesium chloride mixture solution 5.1 UN3407 II 5.1 A9, IB2, N34, T4, TP1 152 202 242 1 L 5 L A 56, 58, 133 III 5.1 A9, IB2, N34, T4, TP1 152 203 241 2.5 L 30 L A 56, 58, 133 Chlorate and magnesium chloride mixture, solid 5.1 UN1459 III 5.1 A9, IB8, IP3, N34, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Chlorate of potash, see Potassium chlorate Chlorate of soda, see Sodium chlorate Chlorates, inorganic, aqueous solution, n.o.s. 5.1 UN3210 II 5.1 IB2, T4, TP1 152 202 242 1 L 5 L B 56, 58, 133 III 5.1 IB2, T4, TP1 152 203 241 2.5 L 30 L B 56, 58, 133 Chlorates, inorganic, n.o.s. 5.1 UN1461 II 5.1 A9, IB6, IP2, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Chloric acid aqueous solution, with not more than 10 percent chloric acid 5.1 UN2626 II 5.1 IB2, T4, TP1 None 229 None Forbidden Forbidden D 56, 58 Chloride of phosphorus, see Phosphorus trichloride Chloride of sulfur, see Sulfur chloride Chlorinated lime, see Calcium hypochlorite mixtures, etc Chlorine 2.3 UN1017 2.3, 8 2, B9, B14, T50, TP19 None 304 314, 315 Forbidden Forbidden D 40, 51, 55, 62, 68, 89, 90 Chlorine azide Forbidden D Chlorine dioxide, hydrate, frozen 5.1 NA9191 II 5.1, 6.1 None 229 None Forbidden Forbidden E Chlorine dioxide (not hydrate) Forbidden Chlorine pentafluoride 2.3 UN2548 2.3, 5.1, 8 1, B7, B9, B14 None 304 314 Forbidden Forbidden D 40, 89, 90 Chlorine trifluoride 2.3 UN1749 2.3, 5.1, 8 2, B7, B9, B14 None 304 314 Forbidden Forbidden D 40, 89, 90 Chlorite solution 8 UN1908 II 8 A3, A6, A7, B2, IB2, N34, T7, TP2, TP24 154 202 242 1 L 30 L B 26, 44, 89, 100, 141 III 8 A3, A6, A7, B2, IB3, N34, T4, TP2, TP24 154 203 241 5 L 60 L B 26, 44, 89, 100, 141 Chlorites, inorganic, n.o.s. 5.1 UN1462 II 5.1 A7, IB6, IP2, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b 2.1 UN2517 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 3-Chloro-4-methylphenyl isocyanate, liquid 6.1 UN2236 II 6.1 IB2 153 202 243 5 L 60 L B 40 3-Chloro-4-methylphenyl isocyanate, solid 6.1 UN3428 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 40 1-Chloro-1,2,2,2-tetrafluoroethane or Refrigerant gas R 124 2.2 UN1021 2.2 T50 306 304 314, 315 75 kg 150 kg A 4-Chloro-o-toluidine hydrochloride, solid 6.1 UN1579 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 4-Chloro-o-toluidine hydrochloride, solution 6.1 UN3410 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a 2.2 UN1983 2.2 T50 306 304 314, 315 75 kg 150 kg A Chloroacetic acid, molten 6.1 UN3250 II 6.1, 8 IB1, T7, TP3, TP28 None 202 243 Forbidden Forbidden C 40 Chloroacetic acid, solid 6.1 UN1751 II 6.1, 8 A3, A7, IB8, IP4, N34, T3, TP33 153 212 242 15 kg 50 kg A 40 Chloroacetic acid, solution 6.1 UN1750 II 6.1, 8 A7, IB2, N34, T7, TP2 153 202 243 1 L 30 L C 40 Start Printed Page 76082 Chloroacetone, stabilized 6.1 UN1695 I 6.1, 3, 8 2, B9, B14, B32, B74, N12, N32, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 21, 40, 100 Chloroacetone (unstabilized) Forbidden + Chloroacetonitrile 6.1 UN2668 II 6.1, 3 2, B9, B14, B32, B74, IB99, T20, TP2, TP38, TP45 None 227 244 Forbidden Forbidden A 12, 40, 52 Chloroacetophenone, liquid CN 6.1 UN3416 II 6.1 A3, IB2, N12, N32, N33, T7, TP2, TP13 None 202 243 Forbidden 60 L D 12, 40 Chloroacetophenone, solid (CN) 6.1 UN1697 II 6.1 A3, IB8, IP2, IP4, N12, N32, N33, N34, T3, TP33 TP2, TP13 None 212 None Forbidden 100 kg D 12, 40 Chloroacetyl chloride 6.1 UN1752 I 6.1, 8 2, B3, B8, B9, B14, B32, B74, B77, N34, N43, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Chloroanilines, liquid 6.1 UN2019 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 52 Chloroanilines, solid 6.1 UN2018 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Chloroanisidines 6.1 UN2233 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Chlorobenzene 3 UN1134 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Chlorobenzol, see Chlorobenzene Chlorobenzotrifluorides 3 UN2234 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40 Chlorobenzyl chlorides, liquid 6.1 UN2235 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Chlorobenzyl chlorides, solid 6.1 UN3427 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Chlorobutanes 3 UN1127 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Chlorocresols solution 6.1 UN2669 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 12 III 6.1 IB3, T7, TP2 153 203 241 60 L 220 L A 12 Chlorocresols, solid 6.1 UN3437 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 12 Chlorodifluorobromomethane or Refrigerant gas R 12B1 2.2 UN1974 2.2 T50 306 304 314, 315 75 kg 150 kg A Chlorodifluoromethane and chloropentafluoroethane mixture or Refrigerant gas R 502 with fixed boiling point, with approximately 49 percent chlorodifluoromethane 2.2 UN1973 2.2 T50 306 304 314, 315 75 kg 150 kg A Chlorodifluoromethane or Refrigerant gas R 22 2.2 UN1018 2.2 T50 306 304 314, 315 75 kg 150 kg A + Chlorodinitrobenzenes, liquid. 6.1 UN1577 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 91 Chlorodinitro-benzenes, solid 6.1 UN3441 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 91 2-Chloroethanal 6.1 UN2232 I 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Chloroform 6.1 UN1888 III 6.1 IB3, N36, T7, TP2 153 203 241 60 L 220 L A 40 G Chloroformates, toxic, corrosive, flammable, n.o.s. 6.1 UN2742 II 6.1, 8, 3 5, IB1, T7, TP2 153 202 243 1 L 30 L A 12, 13, 21, 25, 40, 100 G Chloroformates, toxic, corrosive, n.o.s. 6.1 UN3277 II 6.1, 8 IB2, T8, TP2, TP13, TP28 153 202 243 1 L 30 L A 12, 13, 25, 40 Chloromethyl chloroformate 6.1 UN2745 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L A 12, 13, 21, 25, 40, 100 Chloromethyl ethyl ether 3 UN2354 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40 Chloronitroanilines 6.1 UN2237 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A + Chloronitrobenzene, liquid ortho 6.1 UN3409 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Start Printed Page 76083 + Chloronitrobenzenes, solid meta or para 6.1 UN1578 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Chloronitrotoluenes, liquid 6.1 UN2433 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 44, 89, 100, 141 Chloronitrotoluenes, solid 6.1 UN3457 III 6.1 IB8, IP3,T1, TP33 153 213 240 25 kg 200 kg A Chloropentafluoroethane or Refrigerant gas R 115 2.2 UN1020 2.2 T50 306 304 314, 315 75 kg 150 kg A Chlorophenolates, liquid or Phenolates, liquid 8 UN2904 III 8 IB3 154 203 241 5 L 60 L A Chlorophenolates, solid or Phenolates, solid 8 UN2905 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Chlorophenols, liquid 6.1 UN2021 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Chlorophenols, solid 6.1 UN2020 III 6.1 IB8, IP3, T1, TP1, TP33 153 213 240 100 kg 200 kg A Chlorophenyltrichlorosilane 8 UN1753 II 8 A7, B2, B6, IB2, N34, T7, TP2 None 202 242 Forbidden 30 L C 40 + Chloropicrin 6.1 UN1580 I 6.1 2, B7, B9, B14, B32, B46, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Chloropicrin and methyl bromide mixtures 2.3 UN1581 2.3 2, B9, B14, T50 None 193 314, 315 Forbidden Forbidden D 25, 40 Chloropicrin and methyl chloride mixtures 2.3 UN1582 2.3 2, T50 None 193 245 Forbidden Forbidden D 25, 40 Chloropicrin mixture, flammable (pressure not exceeding 14.7 psia at 115 degrees F flash point below 100 degrees F) see Toxic liquids, flammable, etc Chloropicrin mixtures, n.o.s. 6.1 UN1583 I 6.1 5 None 201 243 Forbidden Forbidden C 40 II 6.1 IB2 153 202 243 Forbidden Forbidden C 40 III 6.1 IB3 153 203 241 Forbidden Forbidden C 40 D Chloropivaloyl chloride 6.1 NA9263 I 6.1, 8 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden B 40 Chloroplatinic acid, solid 8 UN2507 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Chloroprene, stabilized 3 UN1991 I 3, 6.1 B57, T14, TP2, TP13 None 201 243 Forbidden 30 L D 40 Chloroprene, uninhibited Forbidden 1-Chloropropane 3 UN1278 II 3 IB2, IP8, N34, T7, TP2 None 202 242 Forbidden 60 L E 2-Chloropropane 3 UN2356 I 3 N36, T11, TP2, TP13 150 201 243 1 L 30 L E 3-Chloropropanol-1 6.1 UN2849 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 2-Chloropropene 3 UN2456 I 3 A3, N36, T11, TP2 150 201 243 1 L 30 L E 2-Chloropropionic acid 8 UN2511 III 8 IB3, T4, TP2 154 203 241 5 L 60 L A 8 2-Chloropyridine 6.1 UN2822 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 Chlorosilanes, corrosive, flammable, n.o.s. 8 UN2986 II 8, 3 IB2, T11, TP2, TP27 None 202 243 1 L 30 L C 40 Chlorosilanes, corrosive, n.o.s. 8 UN2987 II 8 B2, IB2, T14, TP2, TP27 154 202 242 1 L 30 L C 40 Chlorosilanes, flammable, corrosive, n.o.s. 3 UN2985 II 3, 8 IB1, T11, TP2, TP13, TP27 150 201 243 1 L 5 L B 40 Chlorosilanes, toxic, corrosive, n.o.s. 6.1 UN3361 II 6.1, 8 IB1, T11, TP2, TP13 153 202 243 1 L 30 L C 40 Chlorosilanes, toxic, corrosive, flammable, n.o.s. 6.1 UN3362 II 6.1, 3, 8 IB1, T11, TP2, TP13 153 202 243 1 L 30 L C 40, 125 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. 4.3 UN2988 I 4.3, 3, 8 A2, T10, TP2, TP7, TP13 None 201 244 Forbidden 1 L D 21, 28, 40, 49, 100 + Chlorosulfonic acid (with or without sulfur trioxide) 8 UN1754 I 8, 6.1 2, B9, B10, B14, B32, B74, T20, TP2, TP12, TP38, TP45 None 227 244 Forbidden Forbidden C 40 Chlorotoluenes 3 UN2238 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Chlorotoluidines, liquid 6.1 UN3429 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Chlorotoluidines, solid 6.1 UN2239 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Chlorotrifluoromethane and trifluoromethane azeotropic mixture or Refrigerant gas R 503 with approximately 60 percent chlorotrifluoromethane 2.2 UN2599 2.2 306 304 314, 315 75 kg 150 kg A Chlorotrifluoromethane or Refrigerant gas R 13 2.2 UN1022 2.2 306 304 314, 315 75 kg 150 kg A Start Printed Page 76084 Chromic acid solution 8 UN1755 II 8 B2, IB2, T8, TP2, TP12 154 202 242 1 L 30 L C 40, 44, 89, 100, 141 III 8 IB3, T4, TP1, TP12 154 203 241 5 L 60 L C 40, 44, 89, 100, 141 Chromic anhydride, see Chromium trioxide, anhydrous Chromic fluoride, solid 8 UN1756 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 52 Chromic fluoride, solution 8 UN1757 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Chromium nitrate 5.1 UN2720 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Chromium oxychloride 8 UN1758 I 8 A3, A6, A7, B10, N34, T10, TP2, TP12 None 201 243 0.5 L 2.5 L C 40, 66, 74, 89, 90 Chromium trioxide, anhydrous 5.1 UN1463 II 5.1, 8 IB8, IP4, T3, TP33 None 212 242 5 kg 25 kg A Chromosulfuric acid 8 UN2240 I 8 A3, A6, A7, B4, B6, N34, T10, TP2, TP12, TP13 None 201 243 0.5 L 2.5 L B 40, 66, 74, 89, 90 Chromyl chloride, see Chromium oxychloride Cigar and cigarette lighters, charged with fuel, see Lighters or Lighter refills containing flammable gas. Coal briquettes, hot Forbidden Coal gas, compressed 2.3 UN1023 2.3, 2.1 3 None 302 314, 315 Forbidden Forbidden D 40 Coal tar distillates, flammable 3 UN1136 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Coal tar dye, corrosive, liquid, n.o.s, see Dyes, liquid or solid, n.o.s. or Dye intermediates, liquid or solid, corrosive, n.o.s. Coating solution (includes surface treatments or coatings used for industrial or other purposes such as vehicle undercoating, drum or barrel lining) 3 UN1139 I 3 T11, TP1, TP8, TP27 150 201 243 1 L 30 L E II 3 149, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Cobalt naphthenates, powder 4.1 UN2001 III 4.1 A19, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A Cobalt resinate, precipitated 4.1 UN1318 III 4.1 A1, A19, IB6, T1, TP33 151 213 240 25 kg 100 kg A Coke, hot Forbidden Collodion, see Nitrocellulose etc D G Combustible liquid, n.o.s. Comb liq NA1993 III None IB3, T1, T4, TP1 150 203 241 60 L 220 L A G Components, explosive train, n.o.s. 1.2B UN0382 II 1.2B 101 None 62 None Forbidden Forbidden 11 G Components, explosive train, n.o.s. 1.4B UN0383 II 1.4B 101 None 62 None Forbidden 75 kg 06 G Components, explosive train, n.o.s. 1.4S UN0384 II 1.4S 101 None 62 None 25 kg 100 kg 05 G Components, explosive train, n.o.s. 1.1B UN0461 II 1.1B 101 None 62 None Forbidden Forbidden 11 Composition B, see Hexolite, etc D G Compounds, cleaning liquid 8 NA1760 I 8 A7, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40 II 8 B2, IB2, N37, T11, TP2, TP27 154 202 242 1 L 30 L B 40 III 8 IB3, N37, T7, TP1, TP28 154 203 241 5 L 60 L A 40 D G Compounds, cleaning liquid 3 NA1993 I 3 T11, TP1 150 201 243 1 L 30 L E II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, B52, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A D G Compounds, tree killing, liquid or Compounds, weed killing, liquid 8 NA1760 I 8 A7, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40 Start Printed Page 76085 II 8 B2, IB2, N37, T11, TP2, TP27 154 202 242 1 L 30 L B 40 III 8 IB3, N37, T7, TP1, TP28 154 203 241 5 L 60 L A 40 D G Compounds, tree killing, liquid or Compounds, weed killing, liquid 3 NA1993 I 3 T11, TP1 150 201 243 1 L 30 L E II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, B52, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A D G Compounds, tree killing, liquid or Compounds, weed killing, liquid 6.1 NA2810 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40 G Compressed gas, flammable, n.o.s. 2.1 UN1954 2.1 306 302, 305 314, 315 Forbidden 150 kg D 40 G Compressed gas, n.o.s. 2.2 UN1956 2.2 306, 307 302, 305 314, 315 75 kg 150 kg A G Compressed gas, oxidizing, n.o.s. 2.2 UN3156 2.2, 5.1 A14 306 302 314, 315 75 kg 150 kg D G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 UN3304 2.3, 8 1 None 192 245 Forbidden Forbidden D 40 G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 UN3304 2.3, 8 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 UN3304 2.3, 8 3, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G I Compressed gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 UN3304 2.3, 8 4 None 302, 305 314, 315 Forbidden Forbidden D 40 G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 UN3305 2.3, 2.1, 8 1 None 192 245 Forbidden Forbidden D 17, 40 G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 UN3305 2.3, 2.1, 8 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 17, 40 G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 UN3305 2.3, 2.1, 8 3, B14 None 302, 305 314, 315 Forbidden Forbidden D 17, 40 G I Compressed gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 UN3305 2.3, 2.1, 8 4 None 302, 305 314, 315 Forbidden Forbidden D 17, 40 G Compressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone A 2.3 UN1953 2.3, 2.1 1 None 192 245 Forbidden Forbidden D 40 G Compressed gas, toxic, flammable, n.o.s. Inhalation hazard Zone B 2.3 UN1953 2.3, 2.1 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C 2.3 UN1953 2.3, 2.1 3, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D 2.3 UN1953 2.3, 2.1 4 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone A 2.3 UN1955 2.3 1 None 192 245 Forbidden Forbidden D 40 G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone B 2.3 UN1955 2.3 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone C 2.3 UN1955 2.3 3, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, n.o.s. Inhalation Hazard Zone D 2.3 UN1955 2.3 4 None 302, 305 314, 315 Forbidden Forbidden D 40 G I Compressed gas, toxic, oxdizing, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 UN3306 2.3, 5.1, 8 1 None 192 244 Forbidden Forbidden D 40, 89, 90 G I Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 UN3306 2.3, 5.1, 8 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 40, 89, 90 G I Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 UN3306 2.3, 5.1, 8 3, B14 None 302, 305 314, 315 Forbidden Forbidden D 40, 89, 90 G I Compressed gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 UN3306 2.3, 5.1, 8 4 None 302, 305 314, 315 Forbidden Forbidden D 40, 89, 90 G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A 2.3 UN3303 2.3, 5.1 1 None 192 245 Forbidden Forbidden D 40 G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B 2.3 UN3303 2.3, 5.1 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C 2.3 UN3303 2.3, 5.1 3, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Compressed gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D 2.3 UN3303 2.3, 5.1 4 None 302, 305 314, 315 Forbidden Forbidden D 40 Start Printed Page 76086 D Consumer commodity ORM-D None 156, 306 156, 306 None 30 kg gross 30 kg gross A Contrivances, water-activated, with burster, expelling charge or propelling charge 1.2L UN0248 II 1.2L 101 None 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Contrivances, water-activated, with burster, expelling charge or propelling charge 1.3L UN0249 II 1.3L 101 None 62 None Forbidden Forbidden 08 8E, 14E, 15E, 17E Copper acetoarsenite 6.1 UN1585 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Copper acetylide Forbidden Copper amine azide Forbidden Copper arsenite 6.1 UN1586 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Copper based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2776 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Copper based pesticides, liquid, toxic 6.1 UN3010 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Copper based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3009 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Copper based pesticides, solid, toxic 6.1 UN2775 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Copper chlorate 5.1 UN2721 II 5.1 A1, IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Copper chloride 8 UN2802 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Copper cyanide 6.1 UN1587 II 6.1 IB8, IP2, IP4, T3, TP33 153 204 242 25 kg 100 kg A 52 Copper selenate, see Selenates or Selenites Copper selenite, see Selenates or Selenites Copper tetramine nitrate Forbidden A W Copra 4.2 UN1363 III 4.2 IB8, IP3, IP7 None 213 241 Forbidden Forbidden A 13, 19, 48, 119 Cord, detonating, flexible 1.1D UN0065 II 1.1D 102 63(a) 62 None Forbidden Forbidden 07 Cord, detonating, flexible 1.4D UN0289 II 1.4D None 62 None Forbidden 75 kg 06 Cord detonating or Fuse detonating metal clad 1.2D UN0102 II 1.2D None 62 None Forbidden Forbidden 07 Cord, detonating or Fuse, detonating metal clad 1.1D UN0290 II 1.1D None 62 None Forbidden Forbidden 07 Cord, detonating, mild effect or Fuse, detonating, mild effect metal clad 1.4D UN0104 II 1.4D None 62 None Forbidden 75 kg 06 Cord, igniter 1.4G UN0066 II 1.4G None 62 None Forbidden 75 kg 06 Cordeau detonant fuse, see Cord, detonating, etc; Cord, detonating, flexible Cordite, see Powder, smokeless G Corrosive liquid, acidic, inorganic, n.o.s. 8 UN3264 I 8 A6, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40 II 8 A6, B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L B 40 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40 G Corrosive liquid, acidic, organic, n.o.s. 8 UN3265 I 8 A6, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40 Start Printed Page 76087 II 8 B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L B 40 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40 G Corrosive liquid, basic, inorganic, n.o.s. 8 UN3266 I 8 A6, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40, 52 II 8 B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L B 40, 52 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40, 52 G Corrosive liquid, basic, organic, n.o.s. 8 UN3267 I 8 A6, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40, 52 II 8 B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L B 40, 52 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40, 52 G Corrosive liquid, self-heating, n.o.s. 8 UN3301 I 8, 4.2 A6, B10 None 201 243 0.5 L 2.5 L D II 8, 4.2 B2, IB1 154 202 242 1 L 30 L D G Corrosive liquids, flammable, n.o.s. 8 UN2920 I 8, 3 A6, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L C 25, 40 II 8, 3 B2, IB2, T11, TP2, TP27 None 202 243 1 L 30 L C 25, 40 G Corrosive liquids, n.o.s. 8 UN1760 I 8 A6, A7, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B 40 II 8 B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L B 40 III 8 IB3, T7, TP1, TP28 154 203 241 5 L 60 L A 40 G Corrosive liquids, oxidizing, n.o.s. 8 UN3093 I 8, 5.1 A6, A7 None 201 243 Forbidden 2.5 L C 89 II 8, 5.1 A6, A7, IB2 None 202 243 1 L 30 L C 89 G Corrosive liquids, toxic, n.o.s. 8 UN2922 I 8, 6.1 A7, A6, B10, T14, TP2, TP13, TP27 None 201 243 0.5 L 2.5 L B 40 II 8, 6.1 B3, IB2, T7, TP2 154 202 243 1 L 30 L B 40 III 8, 6.1 IB3, T7, TP1, TP28 154 203 241 5 L 60 L B 40 G Corrosive liquids, water-reactive, n.o.s. 8 UN3094 I 8, 4.3 A6, A7 None 201 243 Forbidden 1 L E II 8, 4.3 A6, A7 None 202 243 1 L 5 L E G Corrosive solid, acidic, inorganic, n.o.s. 8 UN3260 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg B III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A G Corrosive solid, acidic, organic, n.o.s. 8 UN3261 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg B III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A G Corrosive solid, basic, inorganic, n.o.s. 8 UN3262 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B 52 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg B 52 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 52 G Corrosive solid, basic, organic, n.o.s. 8 UN3263 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B 52 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg B 52 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 52 G Corrosive solids, flammable, n.o.s. 8 UN2921 I 8, 4.1 IB6, T6, TP33 None 211 242 1 kg 25 kg B 12, 25 II 8, 4.1 IB8, IP2, IP4, T3, TP33 None 212 242 15 kg 50 kg B 12, 25 G Corrosive solids, n.o.s. 8 UN1759 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg B II 8 128, IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A III 8 128, IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A G Corrosive solids, oxidizing, n.o.s. 8 UN3084 I 8, 5.1 T6, TP33 None 211 242 1 kg 25 kg C II 8, 5.1 IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg C G Corrosive solids, self-heating, n.o.s. 8 UN3095 I 8, 4.2 T6, TP33 None 211 243 1 kg 25 kg C Start Printed Page 76088 II 8, 4.2 IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg C G Corrosive solids, toxic, n.o.s. 8 UN2923 I 8, 6.1 IB7, T6, TP33 None 211 242 1 kg 25 kg B 40 II 8, 6.1 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg B 40 III 8, 6.1 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg B 40, 95 G Corrosive solids, water-reactive, n.o.s. 8 UN3096 I 8, 4.3 IB4, IP1, T6, TP33 None 211 243 1 kg 25 kg D II 8, 4.3 IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg D D W Cotton 9 NA1365 9 137, IB8, IP2, IP4, W41 None None None No limit No limit A A W Cotton waste, oily 4.2 UN1364 III 4.2 IB8, IP3, IP7 None 213 None Forbidden Forbidden A 54 A I W Cotton, wet 4.2 UN1365 III 4.2 IB8, IP3, IP7 None 204 241 Forbidden Forbidden A Coumarin derivative pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN3024 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Coumarin derivative pesticides, liquid, toxic 6.1 UN3026 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40 Coumarin derivative pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3025 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP1, TP28 153 203 242 60 L 220 L A 40 Coumarin derivative pesticides, solid, toxic 6.1 UN3027 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Cresols, liquid 6.1 UN2076 II 6.1, 8 IB2, IP2, IP4, T7, TP2 153 202 243 1 L 30 L B Cresols, solid 6.1 UN3455 II 6.1, 8 IB8, IP2, IP4, T3, TP33 153 212 242 15 kg 50 kg B Cresylic acid 6.1 UN2022 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L B Crotonaldehyde, stabilized 6.1 UN1143 I 6.1, 3 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden B 40 Crotonic acid liquid 8 UN2823 III 8 IB8, T1 154 203 241 5 L 60 L A 12 Crotonic acid, solid 8 UN2823 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 12 Crotonylene 3 UN1144 I 3 T11, TP2 150 201 243 1 L 30 L E Cupriethylenediamine solution 8 UN1761 II 8, 6.1 IB2, T7, TP2 154 202 243 1 L 30 L A III 8, 6.1 IB3, T7, TP1, TP28 154 203 242 5 L 60 L A 95 Cutters, cable, explosive 1.4S UN0070 II 1.4S None 62 None 25 kg 100 kg 05 Cyanide or cyanide mixtures, dry, see Cyanides, inorganic, solid, n.o.s. Cyanide solutions, n.o.s. 6.1 UN1935 I 6.1 B37, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40, 52 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L A 40, 52 III 6.1 IB3, T7, TP2, TP13, TP28 153 203 241 60 L 220 L A 40, 52 Cyanides, inorganic, solid, n.o.s. 6.1 UN1588 I 6.1 IB7, IP1, N74, N75, T6, TP33 None 211 242 5 kg 50 kg A 52 Start Printed Page 76089 II 6.1 IB8, IP2, IP4, N74, N75, T3, TP33 153 212 242 25 kg 100 kg A 52 III 6.1 IB8, IP3, N74, N75, T1, TP33 153 213 240 100 kg 200 kg A 52 Cyanogen 2.3 UN1026 2.3, 2.1 2 None 304 245 Forbidden Forbidden D 40 Cyanogen bromide 6.1 UN1889 I 6.1, 8 A6, A8, T6, TP33 None 211 242 1 kg 15 kg D 40 Cyanogen chloride, stabilized 2.3 UN1589 2.3, 8 1 None 192 245 Forbidden Forbidden D 40 Cyanuric chloride 8 UN2670 II 8 IB8, IP2, IP4, T3, TP33 None 212 240 15 kg 50 kg A 12, 40 Cyanuric triazide Forbidden Cyclobutane 2.1 UN2601 2.1 306 304 314, 315 Forbidden 150 kg B 40 Cyclobutyl chloroformate 6.1 UN2744 II 6.1, 8, 3 IB1, T7, TP2, TP13 153 202 243 1 L 30 L A 12, 13, 21, 25, 40, 100 1,5,9-Cyclododecatriene 6.1 UN2518 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 40 Cycloheptane 3 UN2241 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Cycloheptatriene 3 UN2603 II 3, 6.1 IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40 Cycloheptene 3 UN2242 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B Cyclohexane 3 UN1145 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E Cyclohexanone 3 UN1915 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Cyclohexene 3 UN2256 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E Cyclohexenyltrichlorosilane 8 UN1762 II 8 A7, B2, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Cyclohexyl acetate 3 UN2243 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Cyclohexyl isocyanate 6.1 UN2488 I 6.1, 3 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Cyclohexyl mercaptan 3 UN3054 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40, 95 Cyclohexylamine 8 UN2357 II 8, 3 IB2, T7, TP2 None 202 243 1 L 30 L A 40 Cyclohexyltrichlorosilane 8 UN1763 II 8 A7, B2, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Cyclonite and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Cyclonite and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Cyclonite and octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Cyclonite, see Cyclotrimethylenetrinitramine, etc Cyclooctadiene phosphines, see 9-Phosphabicyclononanes Cyclooctadienes 3 UN2520 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Cyclooctatetraene 3 UN2358 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Cyclopentane 3 UN1146 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E Cyclopentane, methyl, see Methylcyclopentane Cyclopentanol 3 UN2244 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Cyclopentanone 3 UN2245 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Cyclopentene 3 UN2246 II 3 IB2, IP8, T7, TP2 150 202 242 5 L 60 L E Cyclopropane 2.1 UN1027 2.1 T50 306 304 314, 315 Forbidden 150 kg E 40 Cyclotetramethylene tetranitramine (dry or unphlegmatized) (HMX) Forbidden Cyclotetramethylenetetranitramine, desensitized or Octogen, desensitized or HMX, desensitized 1.1D UN0484 II 1.1D None 62 None Forbidden Forbidden 10 Cyclotetramethylenetetranitramine, wetted or HMX, wetted or Octogen, wetted with not less than 15 percent water, by mass 1.1D UN0226 II 1.1D None 62 None Forbidden Forbidden 10 Cyclotrimethylenetrinitramine and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Cyclotrimethylenenitramine and octogen, mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Cyclotrimethylenetrinitramine and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Cyclotrimethylenetrinitramine, desensitized or Cyclonite, desensitized or Hexogen, desensitized or RDX, desensitized 1.1D UN0483 II 1.1D None 62 None Forbidden Forbidden 10 Cyclotrimethylenetrinitramine, wetted or Cyclonite, wetted or Hexogen, wetted or RDX, wetted with not less than 15 percent water by mass 1.1D UN0072 II 1.1D None 62 None Forbidden Forbidden 10 Cymenes 3 UN2046 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Dangerous Goods in Machinery or Dangerous Goods in Apparatus 9 UN3363 136 None 222 None No limit No limit A Decaborane 4.1 UN1868 II 4.1, 6.1 A19, A20, IB6, IP2, T3, TP33 None 212 None Forbidden 50 kg A 74 Decahydronaphthalene 3 UN1147 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A n-Decane 3 UN2247 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Start Printed Page 76090 Deflagrating metal salts of aromatic nitroderivatives, n.o.s. 1.3C UN0132 II 1.3C None 62 None Forbidden Forbidden 10 5E Delay electric igniter, see Igniters Depth charges, see Charges, depth G Desensitized explosive, liquid, n.o.s. 3 UN3379 I 3 164 None 201 None Forbidden Forbidden D 36 G Desensitized explosive, solid, n.o.s. 4.1 UN3380 I 4.1 164 None 211 None Forbidden Forbidden D 28, 36 Detonating relays, see Detonators, etc Detonator assemblies, non-electric for blasting 1.1B UN0360 II 1.1B None 62 None Forbidden Forbidden 11 Detonator assemblies, non-electric, for blasting 1.4B UN0361 II 1.4B 103 63(f), 63(g) 62 None Forbidden 75 kg 06 Detonator, assemblies, non-electric for blasting 1.4S UN0500 II 1.4S 63(f), 63(g) 62 None 25 kg 100 kg 05 Detonators, electric, for blasting 1.1B UN0030 II 1.1B 63(f), 63(g) 62 None Forbidden Forbidden 11 Detonators, electric, for blasting 1.4B UN0255 II 1.4B 103 63(f), 63(g) 62 None Forbidden 75 kg 06 Detonators, electric for blasting 1.4S UN0456 II 1.4S 63(f), 63(g) 62 None 25 kg 100 kg 05 Detonators for ammunition 1.1B UN0073 II 1.1B None 62 None Forbidden Forbidden 11 Detonators for ammunition 1.2B UN0364 II 1.2B None 62 None Forbidden Forbidden 11 Detonators for ammunition 1.4B UN0365 II 1.4B 103 None 62 None Forbidden 75 kg 06 Detonators for ammunition 1.4S UN0366 II 1.4S None 62 None 25 kg 100 kg 05 Detonators, non-electric, for blasting 1.1B UN0029 II 1.1B None 62 None Forbidden Forbidden 11 Detonators, non-electric, for blasting 1.4B UN0267 II 1.4B 103 63(f), 63(g) 62 None Forbidden 75 kg 06 Detonators, non-electric, for blasting 1.4S UN0455 II 1.4S 63(f), 63(g) 62 None 25 kg 100 kg 5 Deuterium, compressed 2.1 UN1957 2.1 306 302 None Forbidden 150 kg E 40 Devices, small, hydrocarbon gas powered or Hydrocarbon gas refills for small devices with release device 2.1 UN3150 2.1 306 304 None 1 kg 15 kg B 40 Di-n-amylamine 3 UN2841 III 3, 6.1 B1, IB3, T4, TP1 150 203 242 60 L 220 L A Di-n-butyl peroxydicarbonate, with more than 52 percent in solution Forbidden Di-n-butylamine 8 UN2248 II 8, 3 IB2, T7, TP2 None 202 243 1 L 30 L A 2,2-Di-(tert-butylperoxy) butane, with more than 55 percent in solution Forbidden Di-(tert-butylperoxy) phthalate, with more than 55 percent in solution Forbidden 2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more than 42 percent with inert solid Forbidden Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent with water Forbidden 1,2-Di-(dimethylamino)ethane 3 UN2372 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Di-2-ethylhexyl phosphoric acid, see Diisooctyl acid phosphate Di-(1-hydroxytetrazole) (dry) Forbidden Di-(1-naphthoyl) peroxide Forbidden a,a'-Di-(nitroxy) methylether Forbidden Di-(beta-nitroxyethyl) ammonium nitrate Forbidden Diacetone alcohol 3 UN1148 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Diacetone alcohol peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass Forbidden Diacetyl, see Butanedione Diacetyl peroxide, solid, or with more than 25 percent in solution Forbidden Diagnostic specimen 6.2 A82 134 199 None 4 L or 4 kg 4 L or 4 kg A 40 Diallylamine 3 UN2359 II 3, 6.1, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 21, 40, 100 Diallylether 3 UN2360 II 3, 6.1 IB2, N12, T7, TP1, TP13 150 202 243 1 L 60 L E 40 4,4'-Diaminodiphenyl methane 6.1 UN2651 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A p-Diazidobenzene Forbidden 1,2-Diazidoethane Forbidden 1,1'-Diazoaminonaphthalene Forbidden Diazoaminotetrazole (dry) Forbidden Diazodinitrophenol (dry) Forbidden Diazodinitrophenol, wetted with not less than 40 percent water or mixture of alcohol and water, by mass 1.1A UN0074 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 Diazodiphenylmethane Forbidden Diazonium nitrates (dry) Forbidden Start Printed Page 76091 Diazonium perchlorates (dry) Forbidden 1,3-Diazopropane Forbidden Dibenzyl peroxydicarbonate, with more than 87 percent with water Forbidden Dibenzyldichlorosilane 8 UN2434 II 8 B2, IB2, T7, TP2, TP13 154 202 242 1 L 30 L C 40 Diborane 2.3 UN1911 2.3, 2.1 1 None 302 None Forbidden Forbidden D 40, 57 D Diborane mixtures 2.1 NA1911 2.1 5 None 302 245 Forbidden Forbidden D 40, 57 Dibromoacetylene Forbidden 1,2-Dibromobutan-3-one 6.1 UN2648 II 6.1 IB2 153 202 243 5 L 60 L B 40 Dibromochloropropane 6.1 UN2872 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A A Dibromodifluoromethane , R12B2 9 UN1941 III None T11, TP2 155 203 241 100 L 220 L A 25 1,2-Dibromoethane, see Ethylene dibromide Dibromomethane 6.1 UN2664 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Dibutyl ethers 3 UN1149 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Dibutylaminoethanol 6.1 UN2873 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A N,N'-Dichlorazodicarbonamidine (salts of) (dry) Forbidden 1,1-Dichloro-1-nitroethane 6.1 UN2650 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 12, 40, 74 D 3,5-Dichloro-2,4,6-trifluoropyridine 6.1 NA9264 I 6.1 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden A 40 Dichloroacetic acid 8 UN1764 II 8 A3, A6, A7, B2, IB2, N34, T8, TP2, TP12 154 202 242 1 L 30 L A 1,3-Dichloroacetone 6.1 UN2649 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 12, 40 Dichloroacetyl chloride 8 UN1765 II 8 A3, A6, A7, B2, B6, IB2, N34, T7, TP2 154 202 242 1 L 30 L D 40 Dichloroacetylene Forbidden + Dichloroanilines, liquid 6.1 UN1590 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 Dichloroanilines, solid 6.1 UN3442 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 + o-Dichlorobenzene 6.1 UN1591 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 2,2'-Dichlorodiethyl ether 6.1 UN1916 II 6.1, 3 IB2, N33, N34, T7, TP2 153 202 243 5 L 60 L A Dichlorodifluoromethane and difluoroethane azeotropic mixture or Refrigerant gas R 500 with approximately 74 percent dichlorodifluoromethane 2.2 UN2602 2.2 T50 306 304 314, 315 75 kg 150 kg A Dichlorodifluoromethane or Refrigerant gas R 12 2.2 UN1028 2.2 T50 306 304 314, 315 75 kg 150 kg A Dichlorodimethyl ether, symmetrical 6.1 UN2249 I 6.1, 3 None 201 243 Forbidden Forbidden 40 1,1-Dichloroethane 3 UN2362 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 1,2-Dichloroethane, see Ethylene dichloride Dichloroethyl sulfide Forbidden 1,2-Dichloroethylene 3 UN1150 II 3 IB2, T7, TP2 150 202 242 5 L 60 L B Dichlorofluoromethane or Refrigerant gas R21 2.2 UN1029 2.2 T50 306 304 314, 315 75 kg 150 kg A Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts 5.1 UN2465 II 5.1 28, IB8, IP4, T3, TP33 152 212 240 5 kg 25 kg A 13 Dichloroisopropyl ether 6.1 UN2490 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B Dichloromethane 6.1 UN1593 III 6.1 IB3, IP8, N36, T7, TP2 153 203 241 60 L 220 L A Dichloropentanes 3 UN1152 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Dichlorophenyl isocyanates 6.1 UN2250 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 25, 40, 48 Dichlorophenyltrichlorosilane 8 UN1766 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 1,2-Dichloropropane 3 UN1279 II 3 IB2, N36, T4, TP1 150 202 242 5 L 60 L B 1,3-Dichloropropanol-2 6.1 UN2750 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 12, 40 Dichloropropene and propylene dichloride mixture, see 1,2- Dichloropropane Dichloropropenes 3 UN2047 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Dichlorosilane 2.3 UN2189 2.3, 2.1, 8 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 17, 40 1,2-Dichloro-1,1,2,2- tetrafluoroethane or Refrigerant gas R 114 2.2 UN1958 2.2 T50 306 304 314, 315 75 kg 150 kg A Dichlorovinylchloroarsine Forbidden Dicycloheptadiene, see Bicyclo [2,2,1] hepta-2,5-diene, stabilized Dicyclohexylamine 8 UN2565 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Start Printed Page 76092 Dicyclohexylammonium nitrite 4.1 UN2687 III 4.1 IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A 48 Dicyclopentadiene 3 UN2048 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Didymium nitrate 5.1 UN1465 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A D Diesel fuel 3 NA1993 III None 144, B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A I Diesel fuel 3 UN1202 III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A Diethanol nitrosamine dinitrate (dry) Forbidden Diethoxymethane 3 UN2373 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 3,3-Diethoxypropene 3 UN2374 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Diethyl carbonate 3 UN2366 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Diethyl cellosolve, see Ethylene glycol diethyl ether Diethyl ether or Ethyl ether 3 UN1155 I 3 T11, TP2 150 201 243 1 L 30 L E 40 Diethyl ketone 3 UN1156 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Diethyl peroxydicarbonate, with more than 27 percent in solution Forbidden Diethyl sulfate 6.1 UN1594 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L C Diethyl sulfide 3 UN2375 II 3 IB2, T7, TP1, TP13 None 202 243 5 L 60 L E Diethylamine 3 UN1154 II 3, 8 A3, IB2, N34, T7, TP1 150 202 243 1 L 5 L E 40 2-Diethylaminoethanol 8 UN2686 II 8, 3 B2, IB2, T7, TP2 None 202 243 1 L 30 L A 3-Diethyamino-propylamine. 3 UN2684 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A + N, N-Diethylaniline 6.1 UN2432 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Diethylbenzene 3 UN2049 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Diethyldichlorosilane 8 UN1767 II 8, 3 A7, B6, IB2, N34, T7, TP2, TP13 None 202 243 Forbidden 30 L C 40 Diethylene glycol dinitrate Forbidden Diethyleneglycol dinitrate, desensitized with not less than 25 percent non-volatile water-insoluble phlegmatizer, by mass 1.1D UN0075 II 1.1D None 62 None Forbidden Forbidden 13 21E Diethylenetriamine 8 UN2079 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 40, 52 N,N-Diethylethylenediamine 8 UN2685 II 8, 3 IB2, T7, TP2 None 202 243 1 L 30 L A Diethylgold bromide Forbidden Diethylthiophosphoryl chloride 8 UN2751 II 8 B2, IB2, T7, TP2 None 212 240 15 kg 50 kg D 12, 40 Diethylzinc 4.2 UN1366 I 4.2, 4.3 B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D 18 Difluorochloroethanes, see 1-Chloro-1,1-difluoroethanes 1,1-Difluoroethane or Refrigerant gas R 152a 2.1 UN1030 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 1,1-Difluoroethylene or Refrigerant gas R 1132a 2.1 UN1959 2.1 306 304 None Forbidden 150 kg E 40 Difluoromethane or Refrigerant gas R 32 2.1 UN3252 2.1 T50 306 302 314, 315 Forbidden 150 kg D 40 Difluorophosphoric acid, anhydrous 8 UN1768 II 8 A6, A7, B2, IB2, N5, N34, T8, TP2, TP12 None 202 242 1 L 30 L A 40 2,3-Dihydropyran 3 UN2376 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 1,8-Dihydroxy-2,4,5,7-tetranitroanthraquinone (chrysamminic acid) Forbidden Diiodoacetylene Forbidden Diisobutyl ketone 3 UN1157 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Diisobutylamine 3 UN2361 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A Diisobutylene, isomeric compounds 3 UN2050 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Diisooctyl acid phosphate 8 UN1902 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Diisopropyl ether 3 UN1159 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 40 Diisopropylamine 3 UN1158 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B Diisopropylbenzene hydroperoxide, with more than 72 percent in solution Forbidden Diketene, stabilized 6.1 UN2521 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 26, 27, 40 1,2-Dimethoxyethane 3 UN2252 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 1,1-Dimethoxyethane 3 UN2377 II 3 IB2, T7, TP1 150 202 242 5 L 60 L B Dimethyl carbonate 3 UN1161 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Dimethyl chlorothiophosphate, see Dimethyl thiophosphoryl chloride Start Printed Page 76093 2,5-Dimethyl-2,5-dihydroperoxy hexane, with more than 82 percent with water Forbidden Dimethyl disulfide 3 UN2381 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Dimethyl ether 2.1 UN1033 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Dimethyl-N-propylamine 3 UN2266 II 3, 8 IB2, T7, TP2, TP13 150 202 243 1 L 5 L B 40 Dimethyl sulfate 6.1 UN1595 I 6.1, 8 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Dimethyl sulfide 3 UN1164 II 3 IB2, IP8, T7, TP2 150 202 242 5 L 60 L E 40 Dimethyl thiophosphoryl chloride 6.1 UN2267 II 6.1, 8 IB2, T7, TP2 153 202 243 1 L 30 L B 25 Dimethylamine, anhydrous 2.1 UN1032 2.1 T50 None 304 314, 315 Forbidden 150 kg D 40 Dimethylamine solution 3 UN1160 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 2-Dimethylaminoacetonitrile 3 UN2378 II 3, 6.1 IB2, T7, TP1 150 202 243 1 L 60 L A 52, 40 2-Dimethylaminoethanol 8 UN2051 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L A 2-Dimethylaminoethyl acrylate 6.1 UN3302 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 25 2-Dimethylaminoethyl methacrylate 6.1 UN2522 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 40 N,N-Dimethylaniline 6.1 UN2253 II 6.1 IB1, T7, TP2 153 202 243 5 L 60 L A 2,3-Dimethylbutane 3 UN2457 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E 1,3-Dimethylbutylamine 3 UN2379 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B Dimethylcarbamoyl chloride 8 UN2262 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 40 Dimethylcyclohexanes 3 UN2263 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B N,N-Dimethylcyclohexylamine 8 UN2264 II 8, 3 B2, IB2, T7, TP2 154 202 243 1 L 30 L A 40 Dimethyldichlorosilane 3 UN1162 II 3, 8 B77, IB2, T7, TP2, TP13 None 202 243 Forbidden Forbidden B 40 Dimethyldiethoxysilane 3 UN2380 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Dimethyldioxanes 3 UN2707 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A N,N-Dimethylformamide 3 UN2265 III 3 B1, IB3, T2, TP2 150 203 242 60 L 220 L A Dimethylhexane dihydroperoxide (dry) Forbidden Dimethylhydrazine, symmetrical 6.1 UN2382 I 6.1, 3 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40, 74 Dimethylhydrazine, unsymmetrical 6.1 UN1163 I 6.1, 3, 8 2, B7, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 21, 38, 40, 100 2,2-Dimethylpropane 2.1 UN2044 2.1 306 304 314, 315 Forbidden 150 kg E 40 Dimethylzinc 4.2 UN1370 I 4.2, 4.3 B11, B16, T21, TP2, TP7 None 181 244 Forbidden Forbidden D 18 Dinitro-o-cresol 6.1 UN1598 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 1,3-Dinitro-5,5-dimethyl hydantoin Forbidden Dinitro-7,8-dimethylglycoluril (dry) Forbidden 1,3-Dinitro-4,5-dinitrosobenzene Forbidden 1,4-Dinitro-1,1,4,4-tetramethylolbutanetetranitrate (dry) Forbidden 2,4-Dinitro-1,3,5-trimethylbenzene Forbidden Dinitroanilines 6.1 UN1596 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 91 Dinitrobenzenes, liquid 6.1 UN1597 II 6.1 11, IB2, T7, TP2 153 202 243 5 L 60 L A 91 III 6.1 11, IB3, T7, TP2 153 203 241 60 L 220 L A 91 Dinitrobenzenes, solid 6.1 UN3443 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 91 Dinitrochlorobenzene, see Chlorodinitrobenzene 1,2-Dinitroethane Forbidden 1,1-Dinitroethane (dry) Forbidden Dinitrogen tetroxide 2.3 UN1067 2.3, 5.1, 8 1, B7, B14, B45, B46, B61, B66, B67, B77, T50, TP21 None 336 314 Forbidden Forbidden D 40, 89, 90 Dinitroglycoluril or Dingu 1.1D UN0489 II 1.1D None 62 None Forbidden Forbidden 10 Dinitromethane Forbidden Dinitrophenol, dry or wetted with less than 15 percent water, by mass 1.1D UN0076 II 1.1D, 6.1 None 62 None Forbidden Forbidden 10 5E Dinitrophenol solutions 6.1 UN1599 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 36 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 36 Dinitrophenol, wetted with not less than 15 percent water, by mass 4.1 UN1320 I 4.1, 6.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg E 28, 36 Dinitrophenolates alkali metals, dry or wetted with less than 15 percent water, by mass 1.3C UN0077 II 1.3C, 6.1 None 62 None Forbidden Forbidden 10 5E Dinitrophenolates, wetted with not less than 15 percent water, by mass 4.1 UN1321 I 4.1, 6.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg E 28, 36 Start Printed Page 76094 Dinitropropylene glycol Forbidden Dinitroresorcinol, dry or wetted with less than 15 percent water, by mass 1.1D UN0078 II 1.1D None 62 None Forbidden Forbidden 10 5E 2,4-Dinitroresorcinol (heavy metal salts of) (dry) Forbidden 4,6-Dinitroresorcinol (heavy metal salts of) (dry) Forbidden Dinitroresorcinol, wetted with not less than 15 percent water, by mass 4.1 UN1322 I 4.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg E 28, 36 3,5-Dinitrosalicylic acid (lead salt) (dry) Forbidden Dinitrosobenzene 1.3C UN0406 II 1.3C None 62 None Forbidden Forbidden 10 Dinitrosobenzylamidine and salts of (dry) Forbidden 2,2-Dinitrostilbene Forbidden Dinitrotoluenes, liquid 6.1 UN2038 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Dinitrotoluenes, solid 6.1 UN3454 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Dinitrotoluenes, molten 6.1 UN1600 II 6.1 T7, TP3 None 202 243 Forbidden Forbidden C 1,9-Dinitroxy pentamethylene-2,4, 6,8-tetramine (dry) Forbidden Dioxane 3 UN1165 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Dioxolane 3 UN1166 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Dipentene 3 UN2052 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Diphenylamine chloroarsine 6.1 UN1698 I 6.1 T6, TP33 None 201 None Forbidden Forbidden D 40 Diphenylchloroarsine, liquid 6.1 UN1699 I 6.1 A8, B14, B32, N33, N34, T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L D 40 Diphenyl-chloroarsine, solid 6.1 UN3450 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg D 40 Diphenyldichlorosilane 8 UN1769 II 8 A7, B2, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Diphenylmethyl bromide 8 UN1770 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg D 40 Dipicryl sulfide, dry or wetted with less than 10 percent water, by mass 1.1D UN0401 II 1.1D None 62 None Forbidden Forbidden 10 Dipicryl sulfide, wetted with not less than 10 percent water, by mass 4.1 UN2852 I 4.1 162, A2, N41, N84 None 211 None Forbidden 0.5 kg D 28 Dipicrylamine, see Hexanitrodiphenylamine Dipropionyl peroxide, with more than 28 percent in solution Forbidden Di-n-propyl ether 3 UN2384 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Dipropyl ketone 3 UN2710 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Dipropylamine 3 UN2383 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B G Disinfectant, liquid, corrosive, n.o.s. 8 UN1903 I 8 A6, A7, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L B G Disinfectants, liquid, corrosive n.o.s. 8 UN1903 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L B III 8 IB3, T4, TP1 154 203 241 5 L 60 L A G Disinfectants, liquid, toxic, n.o.s. 6.1 UN3142 I 6.1 A4, T14, TP2, TP27 None 201 243 1 L 30 L A 40 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L A 40 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40 G Disinfectants, solid, toxic, n.o.s. 6.1 UN1601 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Disodium trioxosilicate 8 UN3253 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A G Dispersant gases, n.o.s. see Refrigerant gases, n.o.s. Divinyl ether, stabilized 3 UN1167 I 3 A7, T11, TP2 None 201 243 1 L 30 L E 40 Dodecyltrichlorosilane 8 UN1771 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Dry ice, see Carbon dioxide, solid G Dyes, liquid, corrosive, n.o.s. or Dye intermediates, liquid, corrosive, n.o.s. 8 UN2801 I 8 11, A6, B10, T14, TP2, TP27 None 201 243 0.5 L 2.5 L A II 8 11, B2, IB2, T11, TP2, TP27 154 202 242 1 L 30 L A Start Printed Page 76095 III 8 11, IB3, T7, TP1, TP28 154 203 241 5 L 60 L A G Dyes, liquid, toxic, n.o.s. or Dye intermediates, liquid, toxic, n.o.s. 6.1 UN1602 I 6.1 None 201 243 1 L 30 L A II 6.1 IB2 153 202 243 5 L 60 L A III 6.1 IB3 153 203 241 60 L 220 L A G Dyes, solid, corrosive, n.o.s. or Dye intermediates, solid, corrosive, n.o.s. 8 UN3147 I 8 IB7, IP1, T6, TP33 None 211 242 1 kg 25 kg A II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A G Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s. 6.1 UN3143 I 6.1 A5, IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Dynamite, see Explosive, blasting, type A Electrolyte (acid or alkali) for batteries, see Battery fluid, acid or Battery fluid, alkali Elevated temperature liquid, flammable, n.o.s., with flash point above 37.8 C, at or above its flash point 3 UN3256 III 3 IB1, T3, TP3, TP29 None None 247 Forbidden Forbidden A Elevated temperature liquid, n.o.s., at or above 100 C and below its flash point (including molten metals, molten salts, etc.) 9 UN3257 III 9 IB1, T3, TP3, TP29 None None 247 Forbidden Forbidden A 85 Elevated temperature solid, n.o.s., at or above 240 C, see § 173.247(h)(4) 9 UN3258 III 9 247(h) (4) None 247 Forbidden Forbidden A 85 Engines, internal combustion, flammable gas powered 9 UN3166 9 135 220 220 220 Forbidden No limit A Engines, internal combustion, flammable liquid powered 9 UN3166 9 135 220 220 220 No limit No limit A G Environmentally hazardous substances, liquid, n.o.s. 9 UN3082 III 9 8, 146, IB3, T4, TP1, TP29 155 203 241 No limit No limit A G Environmentally hazardous substances, solid, n.o.s. 9 UN3077 III 9 8, 146, B54, IB8, IP3, N20, T1, TP33 155 213 240 No limit No limit A Epibromohydrin 6.1 UN2558 I 6.1, 3 T14, TP2, TP13 None 201 243 Forbidden Forbidden D 40 + Epichlorohydrin 6.1 UN2023 II 6.1, 3 IB2, T7, TP2, TP13 153 202 243 5 L 60 L A 40 1,2-Epoxy-3-ethoxypropane 3 UN2752 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Esters, n.o.s. 3 UN3272 II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Etching acid, liquid, n.o.s., see Hydrofluoric acid, solution etc Ethane 2.1 UN1035 2.1 306 304 302 Forbidden 150 kg E 40 D Ethane-Propane mixture, refrigerated liquid 2.1 NA1961 2.1 T75, TP5 None 316 314, 315 Forbidden Forbidden D 40 Ethane, refrigerated liquid 2.1 UN1961 2.1 T75, TP5 None None 315 Forbidden Forbidden D 40 Ethanol amine dinitrate Forbidden Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl alcohol solutions 3 UN1170 II 3 24, IB2, T4, TP1 150 202 242 5 L 60 L A III 3 24, B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethanolamine or Ethanolamine solutions 8 UN2491 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Ether, see Diethyl ether Ethers, n.o.s. 3 UN3271 II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Ethyl acetate 3 UN1173 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Ethyl acrylate, stabilized 3 UN1917 II 3 IB2, T4, TP1, TP13 150 202 242 5 L 60 L B 40 Ethyl alcohol, see Ethanol Ethyl aldehyde, see Acetaldehyde Ethyl amyl ketone 3 UN2271 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A N-Ethylbenzyltoluidines, solid 6.1 UN3460 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A N-Ethyl-N-benzylaniline 6.1 UN2274 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Ethyl borate 3 UN1176 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Ethyl bromide 6.1 UN1891 II 6.1 IB2, IP8, T7, TP2, TP13 153 202 243 5 L 60 L B 40, 85 Ethyl bromoacetate 6.1 UN1603 II 6.1, 3 IB2, T7, TP2 None 202 243 Forbidden Forbidden D 40 Ethyl butyl ether 3 UN1179 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B Ethyl butyrate 3 UN1180 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethyl chloride 2.1 UN1037 2.1 B77, T50 None 322 314, 315 Forbidden 150 kg B 40 Ethyl chloroacetate 6.1 UN1181 II 6.1, 3 IB2, T7, TP2 153 202 243 5 L 60 L A Start Printed Page 76096 Ethyl chloroformate 6.1 UN1182 I 6.1, 3, 8 2, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 21, 40, 100 Ethyl 2-chloropropionate 3 UN2935 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A + Ethyl chlorothioformate 8 UN2826 II 8, 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP38, TP45 None 227 244 Forbidden Forbidden A 40 Ethyl crotonate 3 UN1862 II 3 IB2, T4, TP2 150 202 242 5 L 60 L B Ethyl ether, see Diethyl ether Ethyl fluoride or Refrigerant gas R161 2.1 UN2453 2.1 306 304 314, 315 Forbidden 150 kg E 40 Ethyl formate 3 UN1190 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E Ethyl hydroperoxide Forbidden Ethyl isobutyrate 3 UN2385 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B + Ethyl isocyanate 3 UN2481 I 3, 6.1 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40, 52 Ethyl lactate 3 UN1192 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethyl mercaptan 3 UN2363 I 3 A6, T11, TP2, TP13 None 201 243 Forbidden 30 L E 95, 102 Ethyl methacrylate, stabilized 3 UN2277 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Ethyl methyl ether 2.1 UN1039 2.1 None 201 314, 315 Forbidden 150 kg B 40 Ethyl methyl ketone or Methyl ethyl ketone 3 UN1193 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Ethyl nitrite solutions 3 UN1194 I 3, 6.1 None 201 None Forbidden Forbidden E 40, 105 Ethyl orthoformate 3 UN2524 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethyl oxalate 6.1 UN2525 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Ethyl perchlorate Forbidden D Ethyl phosphonothioic dichloride, anhydrous 6.1 NA2927 I 6.1, 8 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 D Ethyl phosphonous dichloride, anhydrous pyrophoric liquid 6.1 NA2845 I 6.1, 4.2 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 18 D Ethyl phosphorodichloridate 6.1 NA2927 I 6.1, 8 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Ethyl propionate 3 UN1195 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Ethyl propyl ether 3 UN2615 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E Ethyl silicate, see Tetraethyl silicate Ethylacetylene, stabilized 2.1 UN2452 2.1 None 304 314, 315 Forbidden 150 kg B 40 Ethylamine 2.1 UN1036 2.1 B77, T50 None 321 314, 315 Forbidden 150 kg D 40 Ethylamine, aqueous solution with not less than 50 percent but not more than 70 percent ethylamine 3 UN2270 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40 N-Ethylaniline 6.1 UN2272 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52, 74 2-Ethylaniline 6.1 UN2273 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52, 74 Ethylbenzene 3 UN1175 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B N-Ethylbenzyltoluidines liquid 6.1 UN2753 III 6.1 IB3, T7, TP1 153 203 241 60 L 220 L A 2-Ethylbutanol 3 UN2275 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 2-Ethylbutyl acetate 3 UN1177 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 2-Ethylbutyraldehyde 3 UN1178 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B Ethyldichloroarsine 6.1 UN1892 I 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Ethyldichlorosilane 4.3 UN1183 I 4.3, 8, 3 A2, A3, A7, N34, T10, TP2, TP7, TP13 None 201 244 Forbidden 1 L D 21, 28, 40, 49, 100 Start Printed Page 76097 Ethylene, acetylene and propylene in mixture, refrigerated liquid with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene 2.1 UN3138 2.1 T75, TP5 None 304 314, 315 Forbidden Forbidden D 40, 57 Ethylene chlorohydrin 6.1 UN1135 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Ethylene 2.1 UN1962 2.1 306 304 302 Forbidden 150 kg E 40 Ethylene diamine diperchlorate Forbidden Ethylene dibromide 6.1 UN1605 I 6.1 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Ethylene dibromide and methyl bromide liquid mixtures, see Methyl bromide and ethylene dibromide, liquid mixtures Ethylene dichloride 3 UN1184 II 3, 6.1 IB2, N36, T7, TP1 150 202 243 1 L 60 L B 40 Ethylene glycol diethyl ether 3 UN1153 II 3 IB2, T4, TP1 150 202 242 5 L 60 L A III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethylene glycol dinitrate Forbidden Ethylene glycol monoethyl ether 3 UN1171 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethylene glycol monoethyl ether acetate 3 UN1172 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethylene glycol monomethyl ether 3 UN1188 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethylene glycol monomethyl ether acetate 3 UN1189 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Ethylene oxide and carbon dioxide mixture with more than 87 percent ethylene oxide 2.3 UN3300 2.3, 2.1 4 None 304 314, 315 Forbidden Forbidden D 40 Ethylene oxide and carbon dioxide mixtures with more than 9 percent but not more than 87 percent ethylene oxide 2.1 UN1041 2.1 T50 306 304 314, 315 Forbidden 25 kg B 40 Ethylene oxide and carbon dioxide mixtures with not more than 9 percent ethylene oxide 2.2 UN1952 2.2 306 304 314, 315 75 kg 150 kg A Ethylene oxide and chlorotetrafluoroethane mixture with not more than 8.8 percent ethylene oxide 2.2 UN3297 2.2 T50 306 304 314, 315 75 kg 150 kg A Ethylene oxide and dichlorodifluoromethane mixture, with not more than 12.5 percent ethylene oxide 2.2 UN3070 2.2 T50 306 304 314, 315 75 kg 150 kg A Ethylene oxide and pentafluoroethane mixture with not more than 7.9 percent ethylene oxide 2.2 UN3298 2.2 T50 306 304 314, 315 75 kg 150 kg A Ethylene oxide and propylene oxide mixtures , with not more than 30 percent ethylene oxide 3 UN2983 I 3, 6.1 5, A11, N4, N34, T14, TP2, TP7, TP13 None 201 243 Forbidden 30 L E 40 Ethylene oxide and tetrafluoroethane mixture with not more than 5.6 percent ethylene oxide 2.2 UN3299 2.2 T50 306 304 314, 315 75 kg 150 kg A Ethylene oxide or Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 degrees C 2.3 UN1040 2.3, 2.1 4, T50, TP20 None 323 323 Forbidden Forbidden D 40 Ethylene, refrigerated liquid (cryogenic liquid) 2.1 UN1038 2.1 T75, TP5 None 316 318, 319 Forbidden Forbidden D 40 Ethylenediamine 8 UN1604 II 8, 3 IB2, T7, TP2 154 202 243 1 L 30 L A 40 Ethyleneimine, stabilized 6.1 UN1185 I 6.1, 3 1, B9, B14, B30, B72, B77, N25, N32, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Ethylhexaldehyde, see Octyl aldehydes etc 2-Ethylhexyl chloroformate 6.1 UN2748 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L A 12, 13, 21, 25, 40, 100 2-Ethylhexylamine 3 UN2276 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40 Ethylphenyldichlorosilane 8 UN2435 II 8 A7, B2, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 1-Ethylpiperidine 3 UN2386 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B N-Ethyltoluidines 6.1 UN2754 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Ethyltrichlorosilane 3 UN1196 II 3, 8 A7, IB1, N34, T7, TP2, TP13 150 202 243 1 L 5 L B 40 Etiologic agent, see Infectious substances, etc Explosive articles, see Articles, explosive , n.o.s. etc Explosive, blasting, type A 1.1D UN0081 II 1.1D None 62 None Forbidden Forbidden 10 21E, 29E Explosive, blasting, type B 1.1D UN0082 II 1.1D None 62 None Forbidden Forbidden 10 29E Explosive, blasting, type B or Agent blasting, Type B 1.5D UN0331 II 1.5D 105, 106 None 62 None Forbidden Forbidden 10 29E Explosive, blasting, type C 1.1D UN0083 II 1.1D 123 None 62 None Forbidden Forbidden 10 22E Explosive, blasting, type D 1.1D UN0084 II 1.1D None 62 None Forbidden Forbidden 10 Explosive, blasting, type E 1.1D UN0241 II 1.1D None 62 None Forbidden Forbidden 10 19E, 29E Explosive, blasting, type E or Agent blasting, Type E 1.5D UN0332 II 1.5D 105, 106 None 62 None Forbidden Forbidden 10 29E Explosive, forbidden. See § 173.54 Forbidden Explosive substances, see Substances, explosive, n.o.s. etc Start Printed Page 76098 Explosives, slurry, see Explosive, blasting, type E Explosives, water gels, see Explosive, blasting, type E Extracts, aromatic, liquid 3 UN1169 II 3 149, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Extracts, flavoring, liquid 3 UN1197 II 3 149, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Fabric with animal or vegetable oil, see Fibers or fabrics, etc Ferric arsenate 6.1 UN1606 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Ferric arsenite 6.1 UN1607 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Ferric chloride, anhydrous 8 UN1773 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Ferric chloride, solution 8 UN2582 III 8 B15, IB3, T4, TP1 154 203 241 5 L 60 L A Ferric nitrate 5.1 UN1466 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Ferrocerium 4.1 UN1323 II 4.1 59, A19, IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg A Ferrosilicon with 30 percent or more but less than 90 percent silicon 4.3 UN1408 III 4.3, 6.1 A1, A19, B6, IB8, IP4, IP7, T1, TP33 151 213 240 25 kg 100 kg A 13, 40, 52, 53, 85, 103 Ferrous arsenate 6.1 UN1608 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A D Ferrous chloride, solid 8 NA1759 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A D Ferrous chloride, solution 8 NA1760 II 8 B3, IB2, T11, TP2, TP27 154 202 242 1 L 30 L B 40 Ferrous metal borings or Ferrous metal shavings or Ferrous metal turnings or Ferrous metal cuttings in a form liable to self-heating 4.2 UN2793 III 4.2 A1, A19, IB8, IP3, IP7 None 213 241 25 kg 100 kg A Fertilizer ammoniating solution with free ammonia 2.2 UN1043 2.2 306 304 314, 315 Forbidden 150 kg E 40 A I W Fibers, animal or Fibers, vegetable burnt, wet or damp. 4.2 UN1372 III 151 213 240 Forbidden Forbidden A I W Fibers, vegetable, dry 4.1 UN3360 4.1 137 151 213 240 No Limit No Limit A A W Fibers or Fabrics, animal or vegetable or Synthetic, n.o.s. with animal or vegetable oil 4.2 UN1373 III 4.2 137, IB8, IP3, T1, TP33 None 213 241 Forbidden Forbidden A Fibers or Fabrics impregnated with weakly nitrated nitrocellulose, n.o.s. 4.1 UN1353 III 4.1 A1, IB8, IP3 None 213 240 25 kg 100 kg D Films, nitrocellulose base, from which gelatine has been removed; film scrap, see Celluloid scrap Films, nitrocellulose base, gelatine coated (except scrap) 4.1 UN1324 III 4.1 None 183 None 25 kg 100 kg D 28 Fire extinguisher charges, corrosive liquid 8 UN1774 II 8 N41 154 202 None 1 L 30 L A Fire extinguisher charges, expelling, explosive, see Cartridges, power device Fire extinguishers containing compressed or liquefied gas 2.2 UN1044 2.2 18, 110 309 309 None 75 kg 150 kg A Firelighters, solid with flammable liquid 4.1 UN2623 III 4.1 A1, A19 None 213 None 25 kg 100 kg A 52 Fireworks 1.1G UN0333 II 1.1G 108 None 62 None Forbidden Forbidden 07 Fireworks 1.2G UN0334 II 1.2G 108 None 62 None Forbidden Forbidden 07 Fireworks 1.3G UN0335 II 1.3G 108 None 62 None Forbidden Forbidden 07 Fireworks 1.4G UN0336 II 1.4G 108 None 62 None Forbidden 75 kg 06 Fireworks 1.4S UN0337 II 1.4S 108 None 62 None 25 kg 100 kg 05 First aid kits 9 UN3316 9 15 161 161 None 10 kg 10 kg A W Fish meal, stabilized or Fish scrap, stabilized 9 UN2216 III None 155, IB8, IP3, T1, TP33 155 218 218 No limit No limit B 88, 122, 128 Fish meal, unstablized or Fish scrap, unstabilized 4.2 UN1374 II 4.2 155, A1, A19, IB8, IP2, IP4, T3, TP33 None 212 241 15 kg 50 kg B 18, 128 Fissile radioactive materials, see Radioactive material, fissile, n.o.s. Flammable compressed gas, see Compressed or Liquefied gas, flammable, etc Flammable compressed gas (small receptacles not fitted with a dispersion device, not refillable), see Receptacles, etc Flammable gas in lighters, see Lighters or lighter refills, cigarettes, containing flammable gas Start Printed Page 76099 G Flammable liquid, toxic, corrosive, n.o.s. 3 UN3286 I 3, 6.1, 8 T14, TP2, TP13, TP27 None 201 243 Forbidden 2.5 L E 21, 40, 100 II 3, 6.1, 8 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 5 L B 21, 40, 100 G Flammable liquids, corrosive, n.o.s. 3 UN2924 I 3, 8 T14, TP2 None 201 243 0.5 L 2.5 L E 40 II 3, 8 IB2, T11, TP2, TP27 150 202 243 1 L 5 L B 40 III 3, 8 B1, IB3, T7, TP1, TP28 150 203 242 5 L 60 L A 40 G Flammable liquids, n.o.s. 3 UN1993 I 3 T11, TP1, TP27 150 201 243 1 L 30 L E II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, B52, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A G Flammable liquids, toxic, n.o.s. 3 UN1992 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L E 40 II 3, 6.1 IB2, T7, TP2, TP13 150 202 243 1 L 60 L B 40 III 3, 6.1 B1, IB3, T7, TP1, TP28 150 203 242 60 L 220 L A G Flammable solid, corrosive, inorganic, n.o.s. 4.1 UN3180 II 4.1, 8 A1, IB6, IP2, T3, TP33 151 212 242 15 kg 50 kg D 40 III 4.1, 8 A1, IB6, T1, TP33 151 213 242 25 kg 100 kg D 40 G Flammable solid, inorganic, n.o.s. 4.1 UN3178 II 4.1 A1, IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg B III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg B G Flammable solid, organic, molten, n.o.s. 4.1 UN3176 II 4.1 IB1, T3, TP3, TP26 151 212 240 Forbidden Forbidden C III 4.1 IB1, T1, TP3, TP26 151 213 240 Forbidden Forbidden C G Flammable solid, oxidizing, n.o.s. 4.1 UN3097 II 4.1, 5.1 131 None 214 214 Forbidden Forbidden E 40 III 4.1, 5.1 131, T1, TP33 None 214 214 Forbidden Forbidden D 40 G Flammable solid, toxic, inorganic, n.o.s. 4.1 UN3179 II 4.1, 6.1 A1, IB6, IP2, T3, TP33 151 212 242 15 kg 50 kg B 40 III 4.1, 6.1 A1, IB6, T1, TP33 151 213 242 25 kg 100 kg B 40 G Flammable solids, corrosive, organic, n.o.s. 4.1 UN2925 II 4.1, 8 A1, IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg D 40 III 4.1, 8 A1, IB6, T1, TP33 151 213 242 25 kg 100 kg D 40 G Flammable solids, organic, n.o.s. 4.1 UN1325 II 4.1 A1, IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg B III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg B G Flammable solids, toxic, organic, n.o.s. 4.1 UN2926 II 4.1, 6.1 A1, IB6, IP2, T3, TP33 151 212 242 15 kg 50 kg B 40 III 4.1, 6.1 A1, IB6, T1, TP33 151 213 242 25 kg 100 kg B 40 Flares, aerial 1.3G UN0093 II 1.3G None 62 None Forbidden 75 kg 07 Flares, aerial 1.4G UN0403 II 1.4G None 62 None Forbidden 75 kg 06 Flares, aerial 1.4S UN0404 II 1.4S None 62 None 25 kg 100 kg 05 Flares, aerial 1.1G UN0420 II 1.1G None 62 None Forbidden Forbidden 07 Flares, aerial 1.2G UN0421 II 1.2G None 62 None Forbidden Forbidden 07 Flares, airplane, see Flares, aerial Flares, signal, see Cartridges, signal Flares, surface 1.3G UN0092 II 1.3G None 62 None Forbidden 75 kg 07 Flares, surface 1.1G UN0418 II 1.1G None 62 None Forbidden Forbidden 07 Flares, surface 1.2G UN0419 II 1.2G None 62 None Forbidden Forbidden 07 Flares, water-activated, see Contrivances, water-activated, etc Flash powder 1.1G UN0094 II 1.1G None 62 None Forbidden Forbidden 15 Flash powder 1.3G UN0305 II 1.3G None 62 None Forbidden Forbidden 15 Flue dusts, poisonous, see Arsenical dust Fluoric acid, see Hydrofluoric acid, etc Fluorine, compressed 2.3 UN1045 2.3, 5.1, 8 1 None 302 None Forbidden Forbidden D 40, 89, 90 Fluoroacetic acid 6.1 UN2642 I 6.1 IB7, IP1, T6, TP33 None 211 242 1 kg 15 kg E Fluoroanilines 6.1 UN2941 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Fluorobenzene 3 UN2387 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Start Printed Page 76100 Fluoroboric acid 8 UN1775 II 8 A6, A7, B2, B15, IB2, N3, N34, T7, TP2 154 202 242 1 L 30 L A Fluorophosphoric acid anhydrous 8 UN1776 II 8 A6, A7, B2, IB2, N3, N34, T8, TP2, TP12 None 202 242 1 L 30 L A Fluorosilicates, n.o.s. 6.1 UN2856 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Fluorosilicic acid 8 UN1778 II 8 A6, A7, B2, B15, IB2, N3, N34, T8, TP2, TP12 None 202 242 1 L 30 L A Fluorosulfonic acid 8 UN1777 I 8 A3, A6, A7, A10, B6, B10, N3, N36, T10, TP2, TP12 None 201 243 0.5 L 2.5 L D 40 Fluorotoluenes 3 UN2388 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Forbidden materials. See § 173.21 Forbidden Formaldehyde, solutions, flammable 3 UN1198 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40 Formaldehyde, solutions, with not less than 25 percent formaldehyde 8 UN2209 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Formalin, see Formaldehyde, solutions Formic acid 8 UN1779 II 8 B2, B28, IB2, T7, TP2 154 202 242 1 L 30 L A 40 Fracturing devices, explosive, without detonators for oil wells 1.1D UN0099 II 1.1D None 62 None Forbidden Forbidden 07 Fuel, aviation, turbine engine 3 UN1863 I 3 144, T11, TP1, TP8, TP28 150 201 243 1 L 30 L E II 3 144, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A D Fuel oil (No. 1, 2, 4, 5, or 6) 3 NA1993 III 3 144, B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Fuel system components (including fuel control units (FCU), carburetors, fuel lines, fuel pumps) see Dangerous Goods in Apparatus or Dangerous Goods in Machinery Fulminate of mercury (dry) Forbidden Fulminate of mercury, wet, see Mercury fulminate, etc Fulminating gold Forbidden Fulminating mercury Forbidden Fulminating platinum Forbidden Fulminating silver Forbidden Fulminic acid Forbidden Fumaryl chloride 8 UN1780 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C 8, 40 Fumigated lading, see §§ 172.302(g), 173.9 and 176.76(h) Fumigated transport vehicle or freight container see 173.9 Furaldehydes 6.1 UN1199 II 6.1, 3 IB2, T7, TP2 153 202 243 5 L 60 L A Furan 3 UN2389 I 3 T12, TP2, TP13 None 201 243 1 L 30 L E 40 Furfuryl alcohol 6.1 UN2874 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52, 74 Furfurylamine 3 UN2526 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40 Fuse, detonating, metal clad, see Cord, detonating, metal clad Fuse, detonating, mild effect, metal clad, see Cord, detonating, mild effect, metal clad Fuse, igniter tubular metal clad 1.4G UN0103 II 1.4G None 62 None Forbidden 75 kg 06 Fuse, non-detonating instantaneous or quickmatch 1.3G UN0101 II 1.3G None 62 None Forbidden Forbidden 07 Fuse, safety 1.4S UN0105 II 1.4S None 62 None 25 kg 100 kg 05 D Fusee (railway or highway) 4.1 NA1325 II 4.1 None 184 None 15 kg 50 kg B Fusel oil 3 UN1201 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Fuses, tracer, see Tracers for ammunition Fuzes, combination, percussion and time, see Fuzes, detonating (UN0257, UN0367); Fuzes, igniting (UN0317, UN0368) Fuzes, detonating 1.1B UN0106 II 1.1B None 62 None Forbidden Forbidden 11 Fuzes, detonating 1.2B UN0107 II 1.2B None 62 None Forbidden Forbidden 11 Fuzes, detonating 1.4B UN0257 II 1.4B 116 None 62 None Forbidden 75 kg 06 Fuzes, detonating 1.4S UN0367 II 1.4S 116 None 62 None 25 kg 100 kg 05 Fuzes, detonating, with protective features 1.1D UN0408 II 1.1D None 62 None Forbidden Forbidden 07 Fuzes, detonating, with protective features 1.2D UN0409 II 1.2D None 62 None Forbidden Forbidden 07 Fuzes, detonating, with protective features 1.4D UN0410 II 1.4D 116 None 62 None Forbidden 75 kg 06 Start Printed Page 76101 Fuzes, igniting 1.3G UN0316 II 1.3G None 62 None Forbidden Forbidden 07 Fuzes, igniting 1.4G UN0317 II 1.4G None 62 None Forbidden 75 kg 06 Fuzes, igniting 1.4S UN0368 II 1.4S None 62 None 25 kg 100 kg 05 Galactsan trinitrate Forbidden Gallium 8 UN2803 III 8 T1, TP33 None 162 240 20 kg 20 kg B 48 Gas cartridges, (flammable) without a release device, non-refillable 2.1 UN2037 2.1 306 304 None 1 kg 15 kg B 40 Gas generator assemblies (aircraft), containing a non-flammable non-toxic gas and a propellant cartridge 2.2 2.2 None 335 None 75 kg 150 kg A D Gas identification set 2.3 NA9035 2.3 6 None 194 None Forbidden Forbidden D Gas oil 3 UN1202 III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A G Gas, refrigerated liquid, flammable, n.o.s. (cryogenic liquid) 2.1 UN3312 2.1 T75, TP5 None 316 318 Forbidden Forbidden D 40 G Gas, refrigerated liquid, n.o.s. (cryogenic liquid) 2.2 UN3158 2.2 T75, TP5 320 316 318 50 kg 500 kg D G Gas, refrigerated liquid, oxidizing, n.o.s. (cryogenic liquid) 2.2 UN3311 2.2, 5.1 T75, TP5, TP22 320 316 318 Forbidden Forbidden D Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid 2.1 UN3167 2.1 306 302, 304 None 1 L 5 L D Gas sample, non-pressurized, toxic, flammable, n.o.s., not refrigerated liquid 2.3 UN3168 2.3, 2.1 6 306 302 None Forbidden 1 L D Gas sample, non-pressurized, toxic, n.o.s., not refrigerated liquid 2.3 UN3169 2.3 6 306 302, 304 None Forbidden 1 L D D Gasohol gasoline mixed with ethyl alcohol, with not more than 20 percent alcohol 3 NA1203 II 3 144 150 202 242 5 L 60 L E Gasoline 3 UN1203 II 3 139, B33, B101, T8 150 202 242 5 L 60 L E Gasoline, casinghead, see Gasoline Gelatine, blasting, see Explosive, blasting, type A Gelatine dynamites, see Explosive, blasting, type A Germane 2.3 UN2192 2.3, 2.1 2 None 302 245 Forbidden Forbidden D 40 Glycerol-1,3-dinitrate Forbidden Glycerol gluconate trinitrate Forbidden Glycerol lactate trinitrate Forbidden Glycerol alpha-monochlorohydrin 6.1 UN2689 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Glyceryl trinitrate, see Nitroglycerin, etc Glycidaldehyde 3 UN2622 II 3, 6.1 IB2, IP8, T7, TP1 150 202 243 1 L 60 L A 40 Grenades, hand or rifle, with bursting charge 1.1D UN0284 II 1.1D 62 None Forbidden Forbidden 07 Grenades, hand or rifle, with bursting charge 1.2D UN0285 II 1.2D 62 None Forbidden Forbidden 07 Grenades, hand or rifle, with bursting charge 1.1F UN0292 II 1.1F 62 None Forbidden Forbidden 08 Grenades, hand or rifle, with bursting charge 1.2F UN0293 II 1.2F 62 None Forbidden Forbidden 08 Grenades, illuminating, see Ammunition, illuminating, etc Grenades, practice, hand or rifle 1.4S UN0110 II 1.4S 62 None 25 kg 100 kg 05 Grenades, practice, hand or rifle 1.3G UN0318 II 1.3G 62 None Forbidden Forbidden 07 Grenades, practice, hand or rifle 1.2G UN0372 II 1.2G 62 None Forbidden Forbidden 07 Grenades practice Hand or rifle 1.4G UN0452 II 1.4G 62 None Forbidden 75 kg 06 Grenades, smoke, see Ammunition, smoke, etc Guanidine nitrate 5.1 UN1467 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 73 Guanyl nitrosaminoguanylidene hydrazine (dry) Forbidden Guanyl nitrosaminoguanylidene hydrazine, wetted with not less than 30 percent water, by mass 1.1A UN0113 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 Guanyl nitrosaminoguanyltetrazene (dry) Forbidden Guanyl nitrosaminoguanyltetrazene, wetted or Tetrazene, wetted with not less than 30 percent water or mixture of alcohol and water, by mass 1.1A UN0114 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 Gunpowder, compressed or Gunpowder in pellets, see Black powder (UN 0028) Gunpowder, granular or as a meal, see Black powder (UN 0027) Hafnium powder, dry 4.2 UN2545 I 4.2 None 211 242 Forbidden Forbidden D II 4.2 A19, A20, IB6, IP2, N34, T3, TP33 None 212 241 15 kg 50 kg D III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg D Hafnium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns 4.1 UN1326 II 4.1 A6, A19, A20, IB6, IP2, N34, T3, TP33 None 212 241 15 kg 50 kg E 74 Hand signal device, see Signal devices, hand Hazardous substances, liquid or solid, n.o.s., see Environmentally hazardous substances, etc D G Hazardous waste, liquid, n.o.s. 9 NA3082 III 9 IB3, T2, TP1 155 203 241 No limit No limit A D G Hazardous waste, solid, n.o.s. 9 NA3077 III 9 B54, IB8, IP2, T1, TP33 155 213 240 No limit No limit A Heating oil, light 3 UN1202 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Helium, compressed 2.2 UN1046 2.2 306 302 302, 314 75 kg 150 kg A 85 Helium-oxygen mixture, see Rare gases and oxygen mixtures Helium, refrigerated liquid (cryogenic liquid) 2.2 UN1963 2.2 T75, TP5 320 316 318 50 kg 500 kg B Heptafluoropropane or Refrigerant gas R 227 2.2 UN3296 2.2 T50 306 304 314, 315 75 kg 150 kg A Start Printed Page 76102 n-Heptaldehyde 3 UN3056 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Heptanes 3 UN1206 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B n-Heptene 3 UN2278 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Hexachloroacetone 6.1 UN2661 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L B 12, 40 Hexachlorobenzene 6.1 UN2729 III 6.1 B3, IB8, IP3, T1, TP33 153 203 241 60 L 220 L A Hexachlorobutadiene 6.1 UN2279 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Hexachlorocyclopentadiene 6.1 UN2646 I 6.1 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Hexachlorophene 6.1 UN2875 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Hexadecyltrichlorosilane 8 UN1781 II 8 A7, B2, B6, IB2, N34, T7, TP2 None 202 242 Forbidden 30 L C 40 Hexadienes 3 UN2458 II 3 IB2, T4, TP1 None 202 242 5 L 60 L B Hexaethyl tetraphosphate and compressed gas mixtures 2.3 UN1612 2.3 3 None 334 None Forbidden Forbidden D 40 Hexaethyl tetraphosphate, liquid 6.1 UN1611 II 6.1 IB2, N76, T7, TP2 153 202 243 5 L 60 L E 40 Hexaethyl tetraphosphate, solid 6.1 UN1611 II 6.1 IB8, IP2, IP4, N76 153 212 242 25 kg 100 kg E 40 Hexafluoroacetone 2.3 UN2420 2.3, 8 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40 Hexafluoroacetone hydrate, liquid 6.1 UN2552 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L B 40 Hexafluoroacetone hydrate, solid 6.1 UN3436 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 40 Hexafluoroethane, or Refrigerant gas R 116 2.2 UN2193 2.2 306 304 314, 315 75 kg 150 kg A Hexafluorophosphoric acid 8 UN1782 II 8 A6, A7, B2, IB2, N3, N34, T8, TP2, TP12 None 202 242 1 L 30 L A Hexafluoropropylene compressed or Refrigerant gas R 1216 2.2 UN1858 2.2 T50 306 304 314, 315 75 kg 150 kg A Hexaldehyde 3 UN1207 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Hexamethylene diisocyanate 6.1 UN2281 II 6.1 IB2, T7, TP2, TP13 153 202 243 5 L 60 L C 13, 40 Hexamethylene triperoxide diamine (dry) Forbidden Hexamethylenediamine, solid 8 UN2280 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 12 Hexamethylenediamine solution 8 UN1783 II 8 IB2, T7, TP2 None 202 242 1 L 30 L A III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Hexamethyleneimine 3 UN2493 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40 Hexamethylenetetramine 4.1 UN1328 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A Hexamethylol benzene hexanitrate Forbidden Hexanes 3 UN1208 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 2,2',4,4',6,6'- Hexanitro-3,3'-dihydroxyazobenzene (dry) Forbidden Hexanitroazoxy benzene Forbidden N,N'-(hexanitrodiphenyl) ethylene dinitramine (dry) Forbidden Hexanitrodiphenyl urea Forbidden 2,2',3',4,4',6-Hexanitrodiphenylamine Forbidden Hexanitrodiphenylamine or Dipicrylamine or Hexyl 1.1D UN0079 II 1.1D None 62 None Forbidden Forbidden 10 2,3',4,4',6,6'-Hexanitrodiphenylether Forbidden Hexanitroethane Forbidden Hexanitrooxanilide Forbidden Hexanitrostilbene 1.1D UN0392 II 1.1D None 62 None Forbidden Forbidden 10 Hexanoic acid, see Corrosive liquids, n.o.s. Hexanols 3 UN2282 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 74 1-Hexene 3 UN2370 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E Hexogen and cyclotetramethylenetetranitramine mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Hexogen and HMX mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Hexogen and octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc Start Printed Page 76103 Hexogen, see Cyclotrimethylenetrinitramine, etc Hexolite, or Hexotol dry or wetted with less than 15 percent water, by mass 1.1D UN0118 II 1.1D None 62 None Forbidden Forbidden 10 Hexotonal 1.1D UN0393 II 1.1D None 62 None Forbidden Forbidden 10 Hexyl, see Hexanitrodiphenylamine Hexyltrichlorosilane 8 UN1784 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 High explosives, see individual explosives' entries HMX, see Cyclotetramethylenete tranitramine, etc Hydrazine, anhydrous 8 UN2029 I 8, 3, 6.1 A3, A6, A7, A10, B7, B16, B53 None 201 243 Forbidden 2.5 L D 40, 125 Hydrazine, aqueous solution with not more than 37 percent hydrazine, by mass 6.1 UN3293 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Hydrazine azide Forbidden Hydrazine chlorate Forbidden Hydrazine dicarbonic acid diazide Forbidden Hydrazine aqueous solution, with more than 37% hydrazine, by mass 8 UN2030 I 8, 6.1 151, B16, B53, T10, TP2, TP13 None 201 243 Forbidden 2.5 L D 40 II 8, 6.1 B16, B53, IB2, T7, TP2, TP13 None 202 243 Forbidden 30 L D 40 III 8, 6.1 B16, B53, IB3, T4, TP1 154 203 241 5 L 60 L D 40 Hydrazine perchlorate Forbidden Hydrazine selenate Forbidden Hydriodic acid, anhydrous, see Hydrogen iodide, anhydrous Hydriodic acid 8 UN1787 II 8 A3, A6, B2, IB2, N41, T7, TP2 154 202 242 1 L 30 L C III 8 IB3, T4, TP1 154 203 241 5 L 60 L C 8 Hydrobromic acid, anhydrous, see Hydrogen bromide, anhydrous Hydrobromic acid, with more than 49 percent hydrobromic acid 8 UN1788 II 8 B2, B15, IB2, N41, T7, TP2 154 202 242 Forbidden Forbidden C III 8 IB3, T4, TP1 154 203 241 Forbidden Forbidden C 8 Hydrobromic acid, with not more than 49 percent hydrobromic acid 8 UN1788 II 8 A3, A6, B2, B15, IB2, N41, T7, TP2 154 202 242 1 L 30 L C III 8 A3, IB3, T4, TP1 154 203 241 5 L 60 L C 8 Hydrocarbon gas mixture, compressed, n.o.s. 2.1 UN1964 2.1 306 302 314, 315 Forbidden 150 kg E 40 Hydrocarbon gas mixture, liquefied, n.o.s. 2.1 UN1965 2.1 T50 306 304 314, 315 Forbidden 150 kg E 40 Hydrocarbons, liquid, n.o.s. 3 UN3295 I 3 144, T11, TP1, TP8, TP28 150 201 243 1 L 30 L E II 3 144, IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 144, B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Hydrochloric acid, anhydrous, see Hydrogen chloride, anhydrous Hydrochloric acid 8 UN1789 II 8 A3, A6, B3, B15, IB2, N41, T8, TP2, TP12 154 202 242 1 L 30 L C III 8 A3, IB3, T4, TP1, TP12 154 203 241 5 L 60 L C 8 Hydrocyanic acid, anhydrous, see Hydrogen cyanide etc Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, aqueous solutions with not more than 20 percent hydrogen cyanide 6.1 UN1613 I 6.1 2, B61, B65, B77, B82, T20, TP2, TP13 None 195 244 Forbidden Forbidden D 40 D Hydrocyanic acid, aqueous solutions with less than 5 percent hydrogen cyanide 6.1 NA1613 II 6.1 IB1, T14, TP2, TP13, TP27 None 195 243 Forbidden 5 L D 40 Hydrocyanic acid, liquefied, see Hydrogen cyanide, etc Hydrocyanic acid (prussic), unstabilized Forbidden Hydrofluoric acid and Sulfuric acid mixtures 8 UN1786 I 8, 6.1 A6, A7, B15, B23, N5, N34, T10, TP2, TP12, TP13 None 201 243 Forbidden 2.5 L D 40 Hydrofluoric acid, anhydrous, see Hydrogen fluoride, anhydrous Hydrofluoric acid, with more than 60 percent strength 8 UN1790 I 8, 6.1 A6, A7, B4, B15, B23, N5, N34, T10, TP2, TP12, TP13 None 201 243 0.5 L 2.5 L D 12, 40 Hydrofluoric acid, with not more than 60 percent strength 8 UN1790 II 8, 6.1 A6, A7, B15, IB2, N5, N34, T8, TP2, TP12 154 202 243 1 L 30 L D 12, 40 Hydrofluoroboric acid, see Fluoroboric acid Hydrofluorosilicic acid, see Fluorosilicic acid Start Printed Page 76104 Hydrogen and Methane mixtures, compressed 2.1 UN2034 2.1 306 302 302, 314, 315 Forbidden 150 kg E 40, 57 Hydrogen bromide, anhydrous 2.3 UN1048 2.3, 8 3, B14 None 304 314, 315 Forbidden Forbidden D 40 Hydrogen chloride, anhydrous 2.3 UN1050 2.3, 8 3 None 304 None Forbidden Forbidden D 40 Hydrogen chloride, refrigerated liquid 2.3 UN2186 2.3, 8 3, B6 None None 314, 315 Forbidden Forbidden B 40 Hydrogen, compressed 2.1 UN1049 2.1 306 302 302, 314 Forbidden 150 kg E 40, 57 Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide 6.1 UN3294 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Hydrogen cyanide, stabilized with less than 3 percent water 6.1 UN1051 I 6.1, 3 1, B35, B61, B65, B77, B82 None 195 244 Forbidden Forbidden D 40 Hydrogen cyanide, stabilized, with less than 3 percent water and absorbed in a porous inert material 6.1 UN1614 I 6.1 5 None 195 None Forbidden Forbidden D 25, 40 Hydrogen fluoride, anhydrous 8 UN1052 I 8, 6.1 3, B7, B46, B71, B77, T10, TP2 None 163 243 Forbidden Forbidden D 40 Hydrogen in a metal hydride storage system 2.1 UN3468 2.1 167 None 214 None Forbidden Forbidden D Hydrogen iodide, anhydrous 2.3 UN2197 2.3 3, B14 None 304 314, 315 Forbidden Forbidden D 40 Hydrogen iodide solution, see Hydriodic acid, solution Hydrogen peroxide and peroxyacetic acid mixtures, stabilized with acids, water and not more than 5 percent peroxyacetic acid 5.1 UN3149 II 5.1, 8 145, A2, A3, A6, B53, IB2, IP5, T7, TP2, TP6, TP24 None 202 243 1 L 5 L D 25, 66, 75 Hydrogen peroxide, aqueous solutions with more than 40 percent but not more than 60 percent hydrogen peroxide (stabilized as necessary) 5.1 UN2014 II 5.1, 8 12, B53, B80, B81, B85, IB2, T7, TP2, TP6, TP24, TP37 None 202 243 Forbidden Forbidden D 25, 66, 75 Hydrogen peroxide, aqueous solutions with not less than 20 percent but not more than 40 percent hydrogen peroxide (stabilized as necessary) 5.1 UN2014 II 5.1, 8 A2, A3, A6, B53, IB2, IP5, T7, TP2, TP6, TP24, TP37 None 202 243 1 L 5 L D 25, 66, 75 Hydrogen peroxide, aqueous solutions with not less than 8 percent but less than 20 percent hydrogen peroxide (stabilized as necessary) 5.1 UN2984 III 5.1 A1, IB2, IP5, T4, TP1, TP6, TP24, TP37 152 203 241 2.5 L 30 L B 25, 66, 75 Hydrogen peroxide, stabilized or Hydrogen peroxide aqueous solutions, stabilized with more than 60 percent hydrogen peroxide 5.1 UN2015 I 5.1, 8 12, B53, B80, B81, B85, T10, TP2, TP6, TP24, TP37 None 201 243 Forbidden Forbidden D 25, 66, 75 Hydrogen, refrigerated liquid (cryogenic liquid) 2.1 UN1966 2.1 T75, TP5 None 316 318, 319 Forbidden Forbidden D 40 Hydrogen selenide, anhydrous 2.3 UN2202 2.3, 2.1 1 None 192 245 Forbidden Forbidden D 40 Hydrogen sulfate, see Sulfuric acid Hydrogen sulfide 2.3 UN1053 2.3, 2.1 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40 Hydrogendifluorides, n.o.s. 8 UN1740 II 8 IB8, IP2, IP4, N3, N34, T3, TP33 None 212 240 15 kg 50 kg A 25, 40, 52 III 8 IB8, IP3, N3, N34, T1, TP33 154 213 240 25 kg 100 kg A 25, 40, 52 Hydroquinone, solid 6.1 UN2662 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Hydroquinone solution 6.1 UN3435 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Hydrosilicofluoric acid, see Fluorosilicic acid Hydroxyl amine iodide Forbidden Hydroxylamine sulfate 8 UN2865 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Start Printed Page 76105 Hypochlorite solutions 8 UN1791 II 8 A7, B2, B15, IB2, IP5, N34, T7, TP2, TP24 154 202 242 1 L 30 L B 26 III 8 IB3, N34, T4, TP2, TP24 154 203 241 5 L 60 L B 26 Hypochlorites, inorganic, n.o.s. 5.1 UN3212 II 5.1 A9, IB8, IP2, IP4, T3, TP33 152 212 240 5 kg 25 kg D 4, 48, 52, 56, 58, 69, 106, 116 118 Hyponitrous acid Forbidden Igniter fuse, metal clad, see Fuse, igniter, tubular, metal clad Igniters 1.1G UN0121 II 1.1G None 62 None Forbidden Forbidden 07 Igniters 1.2G UN0314 II 1.2G None 62 None Forbidden Forbidden 07 Igniters 1.3G UN0315 II 1.3G None 62 None Forbidden Forbidden 07 Igniters 1.4G UN0325 II 1.4G None 62 None Forbidden 75 kg 06 Igniters 1.4S UN0454 II 1.4S None 62 None 25 kg 100 kg 05 3,3'-Iminodipropylamine 8 UN2269 III 8 IB3, T4, TP2 154 203 241 5 L 60 L A G Infectious substances, affecting animals only 6.2 UN2900 6.2 A81, A82 134 196 None 50 mL or 50 g 4 L or 4 kg B 40 G Infectious substances, affecting humans 6.2 UN2814 6.2 A81, A82 134 196 None 50 mL or 50 g 4 L or 4 kg B 40 Inflammable, see Flammable Initiating explosives (dry) Forbidden Inositol hexanitrate (dry) Forbidden G Insecticide gases, n.o.s. 2.2 UN1968 2.2 306 304 314, 315 75 kg 150 kg A G Insecticide gases, flammable, n.o.s. 2.1 UN3354 2.1 T50 306 304 314, 315 Forbidden 150 kg D 40 G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone A 2.3 UN3355 2.3, 2.1 1 None 192 245 Forbidden Forbidden D 40 G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone B 2.3 UN3355 2.3, 2.1 2, B9, B14 None 302, 305 314, 315 Forbidden Forbidden D 40 G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone C 2.3 UN3355 2.3, 2.1 3, B14 None 302, 305 314, 315 Forbidden Forbidden D G Insecticide gases, toxic, flammable, n.o.s. Inhalation hazard Zone D 2.3 UN3355 2.3, 2.1 4 None 302, 305 314, 315 Forbidden Forbidden D G Insecticide gases, toxic, n.o.s. 2.3 UN1967 2.3 3 None 193, 334 245 Forbidden Forbidden D 40 Inulin trinitrate (dry) Forbidden Iodine azide (dry) Forbidden Iodine monochloride 8 UN1792 II 8 B6, IB8, IP2, IP4, N41, T7, TP2 None 212 240 Forbidden 50 kg D 40, 66, 74, 89, 90 Iodine pentafluoride 5.1 UN2495 I 5.1, 6.1, 8 None 205 243 Forbidden Forbidden D 25, 40, 52, 66, 90 2-Iodobutane 3 UN2390 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Iodomethylpropanes 3 UN2391 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Iodopropanes 3 UN2392 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Iodoxy compounds (dry) Forbidden Iridium nitratopentamine iridium nitrate Forbidden Iron chloride, see Ferric chloride Iron oxide, spent, or Iron sponge, spent obtained from coal gas purification 4.2 UN1376 III 4.2 B18, IB8, IP3, T1, TP33 None 213 240 Forbidden Forbidden E Iron pentacarbonyl 6.1 UN1994 I 6.1, 3 1, B9, B14, B30, B72, B77, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Iron sesquichloride, see Ferric chloride Irritating material, see Tear gas substances, etc Isobutane see also Petroleum gases, liquefied 2.1 UN1969 2.1 19, T50 306 304 314, 315 Forbidden 150 kg E 40 Isobutanol or Isobutyl alcohol 3 UN1212 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isobutyl acetate 3 UN1213 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isobutyl acrylate, stabilized 3 UN2527 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isobutyl alcohol, see Isobutanol Isobutyl aldehyde, see Isobutyraldehyde D Isobutyl chloroformate 6.1 NA2742 I 6.1, 3, 8 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 1 L 30 L A 12, 13, 22, 25, 40, 48, 100 Isobutyl formate 3 UN2393 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isobutyl isobutyrate 3 UN2528 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Start Printed Page 76106 + Isobutyl isocyanate 3 UN2486 I 3, 6.1 1, B9, B14, B30, B72, T22, TP2, TP13, TP27 None 226 244 Forbidden Forbidden D 40 Isobutyl methacrylate, stabilized 3 UN2283 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isobutyl propionate 3 UN2394 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L B Isobutylamine 3 UN1214 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40 Isobutylene see also Petroleum gases, liquefied 2.1 UN1055 2.1 19, T50 306 304 314, 315 Forbidden 150 kg E 40 Isobutyraldehyde or Isobutyl aldehyde 3 UN2045 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 40 Isobutyric acid 3 UN2529 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A Isobutyronitrile 3 UN2284 II 3, 6.1 IB2, T7, TP2, TP13 150 202 243 1 L 60 L E 40 Isobutyryl chloride 3 UN2395 II 3, 8 IB1, T7, TP2 150 202 243 1 L 5 L C 40 G Isocyanates, flammable, toxic, n.o.s. or Isocyanate solutions, flammable, toxic, n.o.s. flash point less than 23 degrees C 3 UN2478 II 3, 6.1 5, A3, A7, IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L D 40 III 3, 6.1 5, A3, A7, IB3, T7, TP1, TP13, TP28 150 203 242 60 L 220 L A G Isocyanates, toxic, flammable, n.o.s. or Isocyanate solutions, toxic, flammable, n.o.s., flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C 6.1 UN3080 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 25, 40, 48 G Isocyanates, toxic, n.o.s. or Isocyanate solutions, toxic, n.o.s., flash point more than 61 degrees C and boiling point less than 300 degrees C 6.1 UN2206 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L E 25, 40, 48 III 6.1 IB3, T7, TP1, TP13, TP28 153 203 241 60 L 220 L E 25, 40, 48 Isocyanatobenzotrifluorides 6.1 UN2285 II 6.1, 3 5, IB2, T7, TP2 153 202 243 5 L 60 L D 25, 40, 48 Isoheptenes 3 UN2287 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isohexenes 3 UN2288 II 3 IB2, IP8, T11, TP1 150 202 242 5 L 60 L E Isooctane, see Octanes Isooctenes 3 UN1216 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isopentane, see Pentane Isopentanoic acid, see Corrosive liquids, n.o.s. Isopentenes 3 UN2371 I 3 T11, TP2 150 201 243 1 L 30 L E Isophorone diisocyanate 6.1 UN2290 III 6.1 IB3, T4, TP2 153 203 241 60 L 220 L B 40 Isophoronediamine 8 UN2289 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Isoprene, stabilized 3 UN1218 I 3 T11, TP2 150 201 243 1 L 30 L E Isopropanol or Isopropyl alcohol 3 UN1219 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isopropenyl acetate 3 UN2403 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isopropenylbenzene 3 UN2303 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isopropyl acetate 3 UN1220 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isopropyl acid phosphate 8 UN1793 III 8 IB2, T4, TP1 154 213 240 25 kg 100 kg A Isopropyl alcohol, see Isopropanol Isopropyl butyrate 3 UN2405 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isopropyl chloroacetate 3 UN2947 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isopropyl chloroformate 6.1 UN2407 I 6.1, 3, 8 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP44 None 227 244 Forbidden Forbidden B 40 Isopropyl 2-chloropropionate 3 UN2934 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isopropyl isobutyrate 3 UN2406 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B + Isopropyl isocyanate 3 UN2483 I 3, 6.1 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Isopropyl mercaptan, see Propanethiols Isopropyl nitrate 3 UN1222 II 3 IB99 150 202 None 5 L 60 L D Isopropyl phosphoric acid, see Isopropyl acid phosphate Isopropyl propionate 3 UN2409 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Isopropylamine 3 UN1221 I 3, 8 T11, TP2 None 201 243 0.5 L 2.5 L E Isopropylbenzene 3 UN1918 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Isopropylcumyl hydroperoxide, with more than 72 percent in solution Forbidden Start Printed Page 76107 Isosorbide dinitrate mixture with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate 4.1 UN2907 II 4.1 IB6, IP2, N85 None 212 None 15 kg 50 kg E 28, 36 Isosorbide-5-mononitrate 4.1 UN3251 III 4.1 66, IB8 151 213 240 Forbidden Forbidden D 12 Isothiocyanic acid Forbidden Jet fuel, see Fuel aviation, turbine engine D Jet perforating guns, charged oil well, with detonator 1.1D NA0124 II 1.1D 55, 56 None 62 None Forbidden Forbidden 07 D Jet perforating guns, charged oil well, with detonator 1.4D NA0494 II 1.4D 55, 56 None 62 None Forbidden Forbidden 06 Jet perforating guns, charged oil well, without detonator 1.1D UN0124 II 1.1D 55 None 62 None Forbidden Forbidden 07 Jet perforating guns, charged, oil well, without detonator 1.4D UN0494 II 1.4D 55, 114 None 62 None Forbidden 300 kg 06 Jet perforators, see Charges, shaped, etc Jet tappers, without detonator, see Charges, shaped, etc Jet thrust igniters, for rocket motors or Jato, see Igniters Jet thrust unit (Jato), see Rocket motors Kerosene 3 UN1223 III 3 144, B1, IB3, T2, TP2 150 203 242 60 L 220 L A G Ketones, liquid, n.o.s. 3 UN1224 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L E II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Krypton, compressed 2.2 UN1056 2.2 306 302 None 75 kg 150 kg A Krypton, refrigerated liquid (cryogenic liquid) 2.2 UN1970 2.2 T75, TP5 320 None None 50 kg 500 kg B Lacquer base or lacquer chips, nitrocellulose, dry, see Nitrocellulose, etc. (UN 2557) Lacquer base or lacquer chips, plastic, wet with alcohol or solvent, see Nitrocellulose (UN2059, UN2555, UN2556, UN2557) or Paint etc.(UN1263) Lead acetate 6.1 UN1616 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Lead arsenates 6.1 UN1617 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Lead arsenites 6.1 UN1618 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Lead azide (dry) Forbidden Lead azide, wetted with not less than 20 percent water or mixture of alcohol and water, by mass 1.1A UN0129 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 Lead compounds, soluble, n.o.s. 6.1 UN2291 III 6.1 138, IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Lead cyanide 6.1 UN1620 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 52 Lead dioxide 5.1 UN1872 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Lead dross, see Lead sulfate, with more than 3 percent free acid Lead nitrate 5.1 UN1469 II 5.1, 6.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A Lead nitroresorcinate (dry) Forbidden Lead perchlorate, solid 5.1 UN1470 II 5.1, 6.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Lead perchlorate, solution 5.1 UN3408 III 5.1, 6.1 IB2, T4, TP1 152 203 242 2.5 L 30 L A 56, 58 II 5.1, 6.1 IB2, T4, TP1 152 202 243 1 L 5 L A 56, 58 Lead peroxide, see Lead dioxide Lead phosphite, dibasic 4.1 UN2989 II 4.1 IB8, IP2, IP4, T3, TP33 None 212 240 5 kg 25 kg B 34 III 4.1 IB8, IP3, T1, TP33 151 213 240 15 kg 50 kg B 34 Lead picrate (dry) Forbidden Lead styphnate (dry) Forbidden Lead styphnate, wetted or Lead trinitroresorcinate, wetted with not less than 20 percent water or mixture of alcohol and water, by mass 1.1A UN0130 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 Lead sulfate with more than 3 percent free acid 8 UN1794 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Lead trinitroresorcinate, see Lead styphnate, etc Life-saving appliances, not self inflating containing dangerous goods as equipment 9 UN3072 None None 219 None No limit No limit A Life-saving appliances, self inflating 9 UN2990 None None 219 None No limit No limit A Lighter replacement cartridges containing liquefied petroleum gases (and similar devices, each not exceeding 65 grams), see Lighters or lighter refills etc. containing flammable gas Lighters, fuse 1.4S UN0131 II 1.4S None 62 None 25 kg 100 kg 05 Lighters or Lighter refills containing flammable gas 2.1 UN1057 2.1 N10 None 21, 308 None 1 kg 15 kg B 40 Lime, unslaked, see Calcium oxide G Liquefied gas, flammable, n.o.s. 2.1 UN3161 2.1 T50 306 304 314, 315 Forbidden 150 kg D 40 G Liquefied gas, n.o.s. 2.2 UN3163 2.2 T50 306 304 314, 315 75 kg 150 kg A G Liquefied gas, oxidizing, n.o.s. 2.2 UN3157 2.2, 5.1 A14 306 304 314, 315 75 kg 150 kg D Start Printed Page 76108 G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 UN3308 2.3, 8 1 None 192 245 Forbidden Forbidden D 40 G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 UN3308 2.3, 8 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40 G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 UN3308 2.3, 8 3, B14 None 304 314, 315 Forbidden Forbidden D 40 G I Liquefied gas, toxic, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 UN3308 2.3, 8 4 None 304 314, 315 Forbidden Forbidden D 40 G I Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 UN3309 2.3, 2.1, 8 1 None 192 245 Forbidden Forbidden D 17, 40 G I Liquefied gas toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 UN3309 2.3, 2.1, 8 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 17, 40 G I Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 UN3309 2.3, 2.1, 8 3, B14 None 304 314, 315 Forbidden Forbidden D 17, 40 G I Liquefied gas, toxic, flammable, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 UN3309 2.3, 2.1, 8 4 None 304 314, 315 Forbidden Forbidden D 17, 40 G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone A 2.3 UN3160 2.3, 2.1 1 None 192 245 Forbidden Forbidden D 40 G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone B 2.3 UN3160 2.3, 2.1 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone C 2.3 UN3160 2.3, 2.1 3, B14 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, flammable, n.o.s. Inhalation Hazard Zone D 2.3 UN3160 2.3, 2.1 4 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone A 2.3 UN3162 2.3 1 None 192 245 Forbidden Forbidden D 40 G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone B 2.3 UN3162 2.3 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone C 2.3 UN3162 2.3 3, B14 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, n.o.s. Inhalation Hazard Zone D 2.3 UN3162 2.3 4 None 304 314, 315 Forbidden Forbidden D 40 G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone A 2.3 UN3310 2.3, 5.1, 8 1 None 192 245 Forbidden Forbidden D 40, 89, 90 G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone B 2.3 UN3310 2.3, 5.1, 8 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40, 89, 90 G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone C 2.3 UN3310 2.3, 5.1, 8 3, B14 None 304 314, 315 Forbidden Forbidden D 40, 89, 90 G I Liquefied gas, toxic, oxidizing, corrosive, n.o.s. Inhalation Hazard Zone D 2.3 UN3310 2.3, 5.1, 8 4 None 304 314, 315 Forbidden Forbidden D 40, 89, 90 G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone A 2.3 UN3307 2.3, 5.1 1 None 192 245 Forbidden Forbidden D 40 G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone B 2.3 UN3307 2.3, 5.1 2, B9, B14 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone C 2.3 UN3307 2.3, 5.1 3, B14 None 304 314, 315 Forbidden Forbidden D 40 G Liquefied gas, toxic, oxidizing, n.o.s. Inhalation Hazard Zone D 2.3 UN3307 2.3, 5.1 4 None 304 314, 315 Forbidden Forbidden D 40 Liquefied gases, non-flammable charged with nitrogen, carbon dioxide or air 2.2 UN1058 2.2 306 304 None 75 kg 150 kg A Liquefied hydrocarbon gas, see Hydrocarbon gas mixture, liquefied, n.o.s. Liquefied natural gas, see Methane, etc. (UN 1972) Liquefied petroleum gas see Petroleum gases, liquefied Lithium 4.3 UN1415 I 4.3 A7, A19, IB4, IP1, N45 None 211 244 Forbidden 15 kg E 52 Lithium acetylide ethylenediamine complex, see Water reactive solid etc Lithium alkyls, liquid 4.2 UN2445 I 4.2, 4.3 B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D Lithium alkyls, solid 4.2 UN3433 I 4.2, 4.3 B11, T21, TP7, TP33 None 181 244 Forbidden Forbidden D Start Printed Page 76109 Lithium aluminum hydride 4.3 UN1410 I 4.3 A19 None 211 242 Forbidden 15 kg E 52 Lithium aluminum hydride, ethereal 4.3 UN1411 I 4.3, 3 A2, A3, A11, N34 None 201 244 Forbidden 1 L D 40 Lithium batteries, contained in equipment 9 UN3091 II 9 29, A54, A55, A102, A104 185 185 None 5 kg 5 kg A Lithium batteries packed with equipment 9 UN3091 II 9 29, A54, A55, A101, A103 185 185 None 5 kg gross 35 kg gross A Lithium battery 9 UN3090 II 9 29, A54, A55, A100 185 185 None 5 kg gross 35 kg gross A Lithium borohydride 4.3 UN1413 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Lithium ferrosilicon 4.3 UN2830 II 4.3 A19, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg E 40, 85, 103 Lithium hydride 4.3 UN1414 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Lithium hydride, fused solid 4.3 UN2805 II 4.3 A8, A19, A20, IB4, T3, TP33 151 212 241 15 kg 50 kg E 52 Lithium hydroxide 8 UN2680 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Lithium hydroxide, solution 8 UN2679 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 29 III 8 IB3, T4, TP2 154 203 241 5 L 60 L A 29, 96 Lithium hypochlorite, dry with more than 39% available chlorine (8.8% available oxygen) or Lithium hypochlorite mixtures, dry with more than 39% available chlorine (8.8% available oxygen) 5.1 UN1471 II 5.1 A9, IB8, IP2, IP4, N34 152 212 240 5 kg 25 kg A 4, 48, 52, 56, 58, 69, 106, 116 Lithium in cartridges, see Lithium Lithium nitrate 5.1 UN2722 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Lithium nitride 4.3 UN2806 I 4.3 A19, IB4, IP1, N40 None 211 242 Forbidden 15 kg E Lithium peroxide 5.1 UN1472 II 5.1 A9, IB6, IP2, N34, T3, TP33 152 212 None 5 kg 25 kg A 13, 52, 66, 75 Lithium silicon 4.3 UN1417 II 4.3 A19, A20, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg A 85, 103 LNG, see Methane etc. (UN 1972) London purple 6.1 UN1621 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A LPG, see Petroleum gases, liquefied Lye, see Sodium hydroxide, solutions Magnesium alkyls 4.2 UN3053 I 4.2, 4.3 B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D 18 Magnesium aluminum phosphide 4.3 UN1419 I 4.3, 6.1 A19, N34, N40 None 211 242 Forbidden 15 kg E 40, 52, 85 + Magnesium arsenate 6.1 UN1622 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Magnesium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. Magnesium bromate 5.1 UN1473 II 5.1 A1, IB8, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Magnesium chlorate 5.1 UN2723 II 5.1 IB8, IP2, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Magnesium diamide 4.2 UN2004 II 4.2 A8, A19, A20, IB6, T3, TP33 None 212 241 15 kg 50 kg C Magnesium diphenyl 4.2 UN2005 I 4.2 T21, TP7, TP33 None 187 244 Forbidden Forbidden C Magnesium dross, wet or hot Forbidden Magnesium fluorosilicate 6.1 UN2853 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Magnesium granules, coated, particle size not less than 149 microns 4.3 UN2950 III 4.3 A1, A19, IB8, IP4, T1, TP33 151 213 240 25 kg 100 kg A 52 Magnesium hydride 4.3 UN2010 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Magnesium or Magnesium alloys with more than 50 percent magnesium in pellets, turnings or ribbons 4.1 UN1869 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A 39, 52, 53, 74, 101 Magnesium nitrate 5.1 UN1474 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Magnesium perchlorate 5.1 UN1475 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Magnesium peroxide 5.1 UN1476 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 66, 75 Magnesium phosphide 4.3 UN2011 I 4.3, 6.1 A19, N40 None 211 None Forbidden 15 kg E 40, 52, 85 Magnesium, powder or Magnesium alloys, powder 4.3 UN1418 I 4.3, 4.2 A19, B56 None 211 244 Forbidden 15 kg A 39, 52 II 4.3, 4.2 A19, B56, IB5, IP2, T3, TP33 None 212 241 15 kg 50 kg A 39, 52 III 4.3, 4.2 A19, B56, IB8, IP4, T1, TP33 None 213 241 25 kg 100 kg A 39, 52 Start Printed Page 76110 Magnesium scrap, see Magnesium, etc. (UN 1869) Magnesium silicide 4.3 UN2624 II 4.3 A19, A20, IB7, IP2, T3, TP33 151 212 241 15 kg 50 kg B 85, 103 Magnetized material, see § 173.21 Maleic anhydride 8 UN2215 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Maleic anhydride, molten 8 UN2215 III 8 T4, TP3 None 213 240 Forbidden Forbidden A Malononitrile 6.1 UN2647 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 12 Mancozeb (manganese ethylenebisdithiocarbamate complex with zinc) see Maneb Maneb or Maneb preparations with not less than 60 percent maneb 4.2 UN2210 III 4.2, 4.3 57, A1, A19, IB6, T1, TP33 None 213 242 25 kg 100 kg A 34 Maneb stabilized or Maneb preparations, stabilized against self-heating 4.3 UN2968 III 4.3 54, A1, A19, IB8, IP4, T1, TP33 151 213 242 25 kg 100 kg B 34, 52 Manganese nitrate 5.1 UN2724 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Manganese resinate 4.1 UN1330 III 4.1 A1, IB6, T1, TP33 151 213 240 25 kg 100 kg A Mannitan tetranitrate Forbidden Mannitol hexanitrate (dry) Forbidden Mannitol hexanitrate, wetted or Nitromannite, wetted with not less than 40 percent water, or mixture of alcohol and water, by mass 1.1D UN0133 II 1.1D 121 None 62 None Forbidden Forbidden 10 Marine pollutants, liquid or solid, n.o.s., see Environmentally hazardous substances, liquid or solid, n.o.s. Matches, block, see Matches, 'strike anywhere' Matches, fusee 4.1 UN2254 III 4.1 186 186 None Forbidden Forbidden A Matches, safety (book, card or strike on box) 4.1 UN1944 III 4.1 186 186 None 25 kg 100 kg A Matches, strike anywhere 4.1 UN1331 III 4.1 186 186 None Forbidden Forbidden B Matches, wax, Vesta 4.1 UN1945 III 4.1 186 186 None 25 kg 100 kg B Matting acid, see Sulfuric acid Medicine, liquid, flammable, toxic, n.o.s. 3 UN3248 II 3, 6.1 36, IB2 150 202 None 1 L 5 L B 40 III 3, 6.1 36, IB3 150 203 None 5 L 5 L A Medicine, liquid, toxic, n.o.s. 6.1 UN1851 II 6.1 36 153 202 243 5 L 5 L C 40 III 6.1 36 153 203 241 5 L 5 L C 40 Medicine, solid, toxic, n.o.s. 6.1 UN3249 II 6.1 36, T3, TP33 153 212 None 5 kg 5 kg C 40 III 6.1 36, T1, TP33 153 213 None 5 kg 5 kg C 40 Memtetrahydrophthalic anhydride, see Corrosive liquids, n.o.s. Mercaptans, liquid, flammable, n.o.s. or Mercaptan mixture, liquid, flammable, n.o.s. 3 UN3336 I 3 T11, TP2 150 201 243 1 L 30 L E 95 II 3 IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B 95 III 3 B1, B52, IB3, T4, TP1, TP29 150 203 241 60 L 220 L B 95 Mercaptans, liquid, flammable, toxic, n.o.s. or Mercaptan mixtures, liquid, flammable, toxic, n.o.s. 3 UN1228 II 3, 6.1 IB2, T11, TP2, TP27 None 202 243 Forbidden 60 L B 40, 95 III 3, 6.1 A6, B1, IB3, T7, TP1, TP28 150 203 242 5 L 220 L A 40, 95 Mercaptans, liquid, toxic, flammable, n.o.s. or Mercaptan mixtures, liquid, toxic, flammable, n.o.s. , flash point not less than 23 degrees C 6.1 UN3071 II 6.1, 3 A6, IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L C 40, 121 5-Mercaptotetrazol-1-acetic acid 1.4C UN0448 II 1.4C None 62 None Forbidden 75 kg 09 Mercuric arsenate 6.1 UN1623 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercuric chloride 6.1 UN1624 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercuric compounds, see Mercury compounds, etc Mercuric nitrate 6.1 UN1625 II 6.1 IB8, IP2, IP4, N73, T3, TP33 153 212 242 25 kg 100 kg A + Mercuric potassium cyanide 6.1 UN1626 I 6.1 IB7, IP1, N74, N75, T6, TP33 None 211 242 5 kg 50 kg A 52 Mercuric sulfocyanate, see Mercury thiocyanate Mercurol, see Mercury nucleate Mercurous azide Forbidden Mercurous compounds, see Mercury compounds, etc Mercurous nitrate 6.1 UN1627 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A A W Mercury 8 UN2809 III 8 164 164 240 35 kg 35 kg B 40, 97 Start Printed Page 76111 Mercury acetate 6.1 UN1629 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury acetylide Forbidden Mercury ammonium chloride 6.1 UN1630 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury based pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2778 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Mercury based pesticides, liquid, toxic 6.1 UN3012 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Mercury based pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3011 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Mercury based pesticides, solid, toxic 6.1 UN2777 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Mercury benzoate 6.1 UN1631 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury bromides 6.1 UN1634 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury compounds, liquid, n.o.s. 6.1 UN2024 I 6.1 None 201 243 1 L 30 L B 40 II 6.1 IB2 153 202 243 5 L 60 L B 40 III 6.1 IB3 153 203 241 60 L 220 L B 40 Mercury compounds, solid, n.o.s. 6.1 UN2025 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A A Mercury contained in manufactured articles 8 UN2809 III 8 None 164 None No limit No limit B 40, 97 Mercury cyanide 6.1 UN1636 II 6.1 IB8, IP2, IP4, N74, N75, T3, TP33 153 212 242 25 kg 100 kg A 52 Mercury fulminate, wetted with not less than 20 percent water, or mixture of alcohol and water, by mass 1.1A UN0135 II 1.1A 111, 117 None 62 None Forbidden Forbidden 12 Mercury gluconate 6.1 UN1637 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury iodide 6.1 UN1638 II 6.1 IB2, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury iodide aquabasic ammonobasic (Iodide of Millon's base) Forbidden Mercury nitride Forbidden Mercury nucleate 6.1 UN1639 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury oleate 6.1 UN1640 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury oxide 6.1 UN1641 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury oxycyanide Forbidden Mercury oxycyanide, desensitized 6.1 UN1642 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 52, 91 Mercury potassium iodide 6.1 UN1643 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury salicylate 6.1 UN1644 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A + Mercury sulfates 6.1 UN1645 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mercury thiocyanate 6.1 UN1646 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Mesityl oxide 3 UN1229 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A G Metal carbonyls, liquid, n.o.s. 6.1 UN3281 I 6.1 5, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40 Start Printed Page 76112 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40 G Metal carbonyls, solid, n.o.s. 6.1 UN3466 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg D 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg B 40 Metal catalyst, dry 4.2 UN2881 I 4.2 N34, T21, TP7, TP33 None 187 None Forbidden Forbidden C II 4.2 IB6, IP2, N34, T3, TP33 None 187 242 Forbidden 50 kg C III 4.2 IB8, IP3, N34, T1, TP33 None 187 241 25 kg 100 kg C Metal catalyst, wetted with a visible excess of liquid 4.2 UN1378 II 4.2 A2, A8, IB1, N34, T3, TP33 None 212 None Forbidden 50 kg C Metal hydrides, flammable, n.o.s. 4.1 UN3182 II 4.1 A1, IB4, T3, TP33 151 212 240 15 kg 50 kg E III 4.1 A1, IB4, T1, TP33 151 213 240 25 kg 100 kg E Metal hydrides, water reactive, n.o.s. 4.3 UN1409 I 4.3 A19, N34, N40 None 211 242 Forbidden 15 kg D 52 II 4.3 A19, IB4, N34, N40, T3, TP33 151 212 242 15 kg 50 kg D 52 Metal powder, self-heating, n.o.s. 4.2 UN3189 II 4.2 IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg C III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg C Metal powders, flammable, n.o.s. 4.1 UN3089 II 4.1 IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg B III 4.1 IB6, T1, TP33 151 213 240 25 kg 100 kg B Metal salts of methyl nitramine (dry) Forbidden G Metal salts of organic compounds, flammable, n.o.s. 4.1 UN3181 II 4.1 A1, IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg B 40 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg B 40 Metaldehyde 4.1 UN1332 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A G Metallic substance, water-reactive, n.o.s. 4.3 UN3208 I 4.3 A7, IB4 None 211 242 Forbidden 15 kg E 40 II 4.3 A7, IB7, IP2, T3, TP33 151 212 242 15 kg 50 kg E 40 III 4.3 A7, IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg E 40 G Metallic substance, water-reactive, self-heating, n.o.s. 4.3 UN3209 I 4.3, 4.2 A7 None 211 242 Forbidden 15 kg E 40 II 4.3, 4.2 A7, IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg E 40 III 4.3, 4.2 A7, IB8, IP4, T1, TP33 None 213 242 25 kg 100 kg E 40 Methacrylaldehyde, stabilized 3 UN2396 II 3, 6.1 45, IB2, T7, TP1, TP13 150 202 243 1 L 60 L E 40 Methacrylic acid, stabilized 8 UN2531 II 8 IB2, T7, TP1, TP18, TP30 154 202 242 1 L 30 L C 40 + Methacrylonitrile, stabilized 3 UN3079 I 3, 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 12, 40, 48 Methallyl alcohol 3 UN2614 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methane and hydrogen, mixtures, see Hydrogen and methane, mixtures, etc Methane, compressed or Natural gas, compressed (with high methane content) 2.1 UN1971 2.1 306 302 302 Forbidden 150 kg E 40 Methane, refrigerated liquid (cryogenic liquid) or Natural gas, refrigerated liquid (cryogenic liquid), with high methane content) 2.1 UN1972 2.1 T75, TP5 None None 318 Forbidden Forbidden D 40 Methanesulfonyl chloride 6.1 UN3246 I 6.1, 8 2, B9, B14, B32, B74, T20, TP2, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Start Printed Page 76113 + I Methanol 3 UN1230 II 3, 6.1 IB2, T7, TP2 150 202 242 1 L 60 L B 40 D Methanol 3 UN1230 II 3 IB2, T7, TP2 150 202 242 1 L 60 L B 40 Methazoic acid Forbidden 4-Methoxy-4-methylpentan-2-one 3 UN2293 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 1-Methoxy-2-propanol 3 UN3092 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A + Methoxymethyl isocyanate 3 UN2605 I 3, 6.1 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Methyl acetate 3 UN1231 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyl acetylene and propadiene mixtures, stabilized 2.1 UN1060 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Methyl acrylate, stabilized 3 UN1919 II 3 IB2, T4, TP1, TP13 150 202 242 5 L 60 L B Methyl alcohol, see Methanol Methyl allyl chloride 3 UN2554 II 3 IB2, T4, TP1, TP13 150 202 242 5 L 60 L E Methyl amyl ketone, see Amyl methyl ketone Methyl bromide 2.3 UN1062 2.3 3, B14, T50 None 193 314, 315 Forbidden Forbidden D 40 Methyl bromide and chloropicrin mixtures with more than 2 percent chloropicrin, see Chloropicrin and methyl bromide mixtures Methyl bromide and chloropicrin mixtures with not more than 2 percent chloropicrin, see Methyl bromide Methyl bromide and ethylene dibromide mixtures, liquid 6.1 UN1647 I 6.1 2, B9, B14, B32, B74, N65, T20, TP2, TP13, TP38, TP44 None 227 244 Forbidden Forbidden C 40 Methyl bromoacetate 6.1 UN2643 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L D 40 2-Methlybutanal 3 UN3371 II 3IB2, T4, TP1 150 202 242 5 L 60 L B 2-Methyl-1-butene 3 UN2459 I 3 T11, TP2 None 201 243 1 L 30 L E 2-Methyl-2-butene 3 UN2460 II 3 IB2, IP8, T7, TP1 None 202 242 5 L 60 L E 3-Methyl-1-butene 3 UN2561 I 3 T11, TP2 None 201 243 1 L 30 L E Methyl tert-butyl ether 3 UN2398 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E Methyl butyrate 3 UN1237 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyl chloride, or Refrigerant gas R 40 2.1 UN1063 2.1 T50 306 304 314, 315 5 kg 100 kg D 40 Methyl chloride and chloropicrin mixtures, see Chloropicrin and methyl chloride mixtures Methyl chloride and methylene chloride mixtures 2.1 UN1912 2.1 T50 306 304 314, 315 Forbidden 150 kg D 40 Methyl chloroacetate 6.1 UN2295 I 6.1, 3 T14, TP2, TP13 None 201 243 1 L 30 L D Methyl chlorocarbonate, see Methyl chloroformate Methyl chloroform, see 1,1,1-Trichloroethane Methyl chloroformate 6.1 UN1238 I 6.1, 3, 8 1, B9, B14, B30, B72, N34, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 21, 40, 100 Methyl chloromethyl ether 6.1 UN1239 I 6.1, 3 1, B9, B14, B30, B72, T22, TP2, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Methyl 2-chloropropionate 3 UN2933 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methyl dichloroacetate 6.1 UN2299 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Methyl ethyl ether, see Ethyl methyl ether Methyl ethyl ketone, see Ethyl methyl ketone Methyl ethyl ketone peroxide, in solution with more than 9 percent by mass active oxygen Forbidden 2-Methyl-5-ethylpyridine 6.1 UN2300 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Methyl fluoride, or Refrigerant gas R 41 2.1 UN2454 2.1 306 304 314, 315 Forbidden 150 kg E 40 Methyl formate 3 UN1243 I 3 T11, TP2 150 201 243 1 L 30 L E 2-Methyl-2-heptanethiol 6.1 UN3023 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40, 102 Methyl iodide 6.1 UN2644 I 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden A 12, 40 Methyl isobutyl carbinol 3 UN2053 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methyl isobutyl ketone 3 UN1245 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyl isobutyl ketone peroxide, in solution with more than 9 percent by mass active oxygen Forbidden Methyl isocyanate 6.1 UN2480 I 6.1, 3 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40, 52 Methyl isopropenyl ketone, stabilized 3 UN1246 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Start Printed Page 76114 Methyl isothiocyanate 6.1 UN2477 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden A Methyl isovalerate 3 UN2400 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyl magnesium bromide, in ethyl ether 4.3 UN1928 I 4.3, 3 None 201 243 Forbidden 1 L D Methyl mercaptan 2.3 UN1064 2.3, 2.1 3, B7, B9, B14, T50 None 304 314, 315 Forbidden Forbidden D 40 Methyl mercaptopropionaldehyde, see Thia-4-pentanal Methyl methacrylate monomer, stabilized 3 UN1247 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 Methyl nitramine (dry) Forbidden Methyl nitrate Forbidden Methyl nitrite Forbidden Methyl norbornene dicarboxylic anhydride, see Corrosive liquids, n.o.s. Methyl orthosilicate 6.1 UN2606 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden E 40 D Methyl phosphonic dichloride 6.1 NA9206 I 6.1, 8 2, B9, B14, B32, B74, N34, N43, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden C Methyl phosphonothioic dichloride, anhydrous, see Corrosive liquid, n.o.s. D Methyl phosphonous dichloride, pyrophoric liquid 6.1 NA2845 I 6.1, 4.2 2, B9, B14, B16, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 18 Methyl picric acid (heavy metal salts of) Forbidden Methyl propionate 3 UN1248 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyl propyl ether 3 UN2612 II 3 IB2, IP8, T7, TP2 150 202 242 5 L 60 L E 40 Methyl propyl ketone 3 UN1249 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyl sulfate, see Dimethyl sulfate Methyl sulfide, see Dimethyl sulfide Methyl trichloroacetate 6.1 UN2533 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Methyl trimethylol methane trinitrate Forbidden Methyl vinyl ketone, stabilized 6.1 UN1251 I 6.1, 3, 8 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden B 40 Methylal 3 UN1234 II 3 IB2, IP8, T7, TP2 None 202 242 5 L 60 L E Methylamine, anhydrous 2.1 UN1061 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Methylamine, aqueous solution 3 UN1235 II 3, 8 B1, IB2, T7, TP1 150 202 243 1 L 5 L E 135 Methylamine dinitramine and dry salts thereof Forbidden Methylamine nitroform Forbidden Methylamine perchlorate (dry) Forbidden Methylamyl acetate 3 UN1233 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A N-Methylaniline 6.1 UN2294 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A alpha-Methylbenzyl alcohol, liquid 6.1 UN2937 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A alpha-Methylbenzyl alcohol, solid 6.1 UN3438 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 3-Methylbutan-2-one 3 UN2397 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B N-Methylbutylamine 3 UN2945 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40 Methylchlorosilane 2.3 UN2534 2.3, 2.1, 8 2, B9, B14, N34 None 226 314, 315 Forbidden Forbidden D 17, 40 Methylcyclohexane 3 UN2296 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B Methylcyclohexanols, flammable 3 UN2617 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methylcyclohexanone 3 UN2297 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methylcyclopentane 3 UN2298 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B D Methyldichloroarsine 6.1 NA1556 I 6.1 2, T20, TP4, TP12, TP13, TP38, TP45 None 192 None Forbidden Forbidden D 40 Start Printed Page 76115 Methyldichlorosilane 4.3 UN1242 I 4.3, 8, 3 A2, A3, A7, B6, B77, N34, T10, TP2, TP7, TP13 None 201 243 Forbidden 1 L D 21, 28, 40, 49, 100 Methylene chloride, see Dichloromethane Methylene glycol dinitrate Forbidden 2-Methylfuran 3 UN2301 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E a-Methylglucoside tetranitrate Forbidden a-Methylglycerol trinitrate Forbidden 5-Methylhexan-2-one 3 UN2302 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methylhydrazine 6.1 UN1244 I 6.1, 3, 8 1, B7, B9, B14, B30, B72, B77, N34, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 21, 40, 49, 100 4-Methylmorpholine or n-methylmorpholine 3 UN2535 II 3, 8 B6, IB2, T7, TP1 150 202 243 1 L 5 L B 40 Methylpentadienes 3 UN2461 II 3 IB2, T4, TP1 150 202 242 5 L 60 L E 2-Methylpentan-2-ol 3 UN2560 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Methylpentanes, see Hexanes Methylphenyldichlorosilane 8 UN2437 II 8 IB2, T7, TP2, TP13 154 202 242 1 L 30 L C 40 1-Methylpiperidine 3 UN2399 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B Methyltetrahydrofuran 3 UN2536 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Methyltrichlorosilane 3 UN1250 I 3, 8 A7, B6, B77, N34, T11, TP2, TP13 None 201 243 Forbidden 2.5 L B 40 alpha-Methylvaleraldehyde 3 UN2367 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B Mine rescue equipment containing carbon dioxide, see Carbon dioxide Mines with bursting charge 1.1F UN0136 II 1.1F 62 None Forbidden Forbidden 08 Mines with bursting charge 1.1D UN0137 II 1.1D 62 None Forbidden Forbidden 03 Mines with bursting charge 1.2D UN0138 II 1.2D 62 None Forbidden Forbidden 03 Mines with bursting charge 1.2F UN0294 II 1.2F 62 None Forbidden Forbidden 08 Mixed acid, see Nitrating acid, mixtures etc Mobility aids, see Battery powered equipment or Battery powered vehicle' D Model rocket motor 1.4C NA0276 II 1.4C 51 None 62 None Forbidden 75 kg 06 D Model rocket motor 1.4S NA0323 II 1.4S 51 None 62 None 25 kg 100 kg 05 Molybdenum pentachloride 8 UN2508 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg C 40 Monochloroacetone (unstabilized) Forbidden Monochloroethylene, see Vinyl chloride, stabilized Monoethanolamine, see Ethanolamine, solutions Monoethylamine, see Ethylamine Morpholine 8 UN2054 I 8, 3 A6, T10, TP2 None 201 243 0.5 L 2.5 L A Morpholine, aqueous, mixture, see Corrosive liquids, n.o.s. Motor fuel anti-knock compounds see Motor fuel anti-knock mixtures + Motor fuel anti-knock mixtures 6.1 UN1649 I 6.1, 3 14, 151, B9, B90, T14, TP2, TP13 None 201 244 Forbidden 30 L D 25, 40 Motor spirit, see Gasoline Muriatic acid, see Hydrochloric acid Musk xylene, see 5-tert-Butyl-2,4,6-trinitro-m-xylene Naphtha see Petroleum distillates n.o.s. Naphthalene, crude or Naphthalene, refined 4.1 UN1334 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A Naphthalene diozonide Forbidden beta-Naphthylamine 6.1 UN1650 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A beta-Naphthylamine, solid 6.1 UN1650 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A beta-Naphthylamine solution 6.1 UN3411 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A III 6.1 IB2, T7, TP2 153 203 241 60 L 220 L A alpha-Naphthylamine 6.1 UN2077 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Naphthalene, molten 4.1 UN2304 III 4.1 IB1, T1, TP3 151 213 241 Forbidden Forbidden C Naphthylamineperchlorate Forbidden Naphthylthiourea 6.1 UN1651 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Naphthylurea 6.1 UN1652 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Natural gases (with high methane content), see Methane, etc. (UN 1971, UN 1972) Neohexane, see Hexanes Neon, compressed 2.2 UN1065 2.2 306 302 302 75 kg 150 kg A Neon, refrigerated liquid (cryogenic liquid) 2.2 UN1913 2.2 T75, TP5 320 316 None 50 kg 500 kg B New explosive or explosive device, see §§ 173.51 and 173.56 Nickel carbonyl 6.1 UN1259 I 6.1, 3 1 None 198 None Forbidden Forbidden D 18, 40 Start Printed Page 76116 Nickel cyanide 6.1 UN1653 II 6.1 IB8, IP2, IP4, N74, N75, T3, TP33 153 212 242 25 kg 100 kg A 52 Nickel nitrate 5.1 UN2725 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Nickel nitrite 5.1 UN2726 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Nickel picrate Forbidden Nicotine 6.1 UN1654 II 6.1 IB2 153 202 243 5 L 60 L A Nicotine compounds, liquid, n.o.s. or Nicotine preparations, liquid, n.o.s. 6.1 UN3144 I 6.1 A4 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L B 40 Nicotine compounds, solid, n.o.s. or Nicotine preparations, solid, n.o.s. 6.1 UN1655 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Nicotine hydrochloride liquid or solution 6.1 UN1656 II 6.1 IB2 153 202 243 5 L 60 L A III 6.1 IB3 153 203 241 60 L 220 L A Nicotine hydrochloride, solid 6.1 UN3444 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nicotine salicylate 6.1 UN1657 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nicotine sulfate solution 6.1 UN1658 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A III 6.1 IB3, T7, TP2 153 203 241 60 L 220 L A Nicotine sulphate, solid 6.1 UN3445 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nicotine tartrate 6.1 UN1659 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nitrated paper (unstable) Forbidden Nitrates, inorganic, aqueous solution, n.o.s. 5.1 UN3218 II 5.1 58, IB2, T4, TP1 152 202 242 1 L 5 L B 56, 58, 133 III 5.1 58, IB2, T4, TP1 152 203 241 2.5 L 30 L B 56, 58, 133 Nitrates, inorganic, n.o.s. 5.1 UN1477 II 5.1 IB8, IP2, IP4, T3, TP33 152 212 240 5 kg 25 kg A 56, 58 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Nitrates of diazonium compounds Forbidden Nitrating acid mixtures, spent with more than 50 percent nitric acid 8 UN1826 I 8, 5.1 A7, T10, TP2, TP12, TP13 None 158 243 Forbidden 2.5 L D 40, 66 Nitrating acid mixtures spent with not more than 50 percent nitric acid 8 UN1826 II 8 A7, B2, IB2, T8, TP2, TP12 None 158 242 Forbidden 30 L D 40 Nitrating acid mixtures with more than 50 percent nitric acid 8 UN1796 I 8, 5.1 A7, T10, TP2, TP12, TP13 None 158 243 Forbidden 2.5 L D 40, 66 Nitrating acid mixtures with not more than 50 percent nitric acid 8 UN1796 II 8 A7, B2, IB2, T8, TP2, TP12, TP13 None 158 242 Forbidden 30 L D 40 Nitric acid other than red fuming, with more than 70 percent nitric acid 8 UN2031 I 8, 5.1 A3, B47, B53, T10, TP2, TP12, TP13 None 158 243 Forbidden 2.5 L D 44, 66, 89, 90, 110, 111 Nitric acid other than red fuming, with not more than 70 percent nitric acid 8 UN2031 II 8 A6, B2, B47, B53, IB2, T8, TP2, TP12 None 158 242 Forbidden 30 L D 44, 66, 89, 90, 110, 111 + Nitric acid, red fuming 8 UN2032 I 8, 5.1, 6.1 2, B9, B32, B74, T20, TP2, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40, 66, 74, 89, 90 Nitric oxide, compressed 2.3 UN1660 2.3, 5.1, 8 1, B37, B46, B50, B60, B77 None 337 None Forbidden Forbidden D 40, 89, 90 Start Printed Page 76117 Nitric oxide and dinitrogen tetroxide mixtures or Nitric oxide and nitrogen dioxide mixtures 2.3 UN1975 2.3, 5.1, 8 1, B7, B9, B14, B45, B46, B61, B66, B67, B77 None 337 None Forbidden Forbidden D 40, 89, 90 G Nitriles, flammable, toxic, n.o.s. 3 UN3273 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L E 40, 52 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40, 52 G Nitriles, toxic, flammable, n.o.s. 6.1 UN3275 I 6.1, 3 5, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40, 52 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40, 52 G Nitriles, toxic, liquid, n.o.s. 6.1 UN3276 I 6.1 5, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 52 G Nitriles, toxic, solid, n.o.s. 6.1 UN3439 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg D 52 G Nitriles, toxic, liquid, n.o.s. 6.1 UN3276 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 52 G Nitriles, toxic, solid, n.o.s. 6.1 UN3439 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 52 G Nitriles, toxic, liquid, n.o.s. 6.1 UN3276 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 52 G Nitriles, toxic, solid, n.o.s. 6.1 UN3439 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Nitrites, inorganic, aqueous solution, n.o.s. 5.1 UN3219 II 5.1 IB1, T4, TP1 152 202 242 1 L 5 L B 46, 56, 58, 133 III 5.1 IB2, T4, TP1 152 203 241 2.5 L 30 L B 46, 56, 58, 133 Nitrites, inorganic, n.o.s. 5.1 UN2627 II 5.1 33, IB8, IP4, T3, TP33 152 212 None 5 kg 25 kg A 46, 56, 58, 133 3-Nitro-4-chlorobenzotrifluoride 6.1 UN2307 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 6-Nitro-4-diazotoluene-3-sulfonic acid (dry) Forbidden Nitro isobutane triol trinitrate Forbidden N-Nitro-N-methylglycolamide nitrate Forbidden 2-Nitro-2-methylpropanol nitrate Forbidden Nitro urea 1.1D UN0147 II 1.1D None 62 None Forbidden Forbidden 10 N-Nitroaniline Forbidden + Nitroanilines (o-; m-; p-;) 6.1 UN1661 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nitroanisole, liquid 6.1 UN2730 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Nitroanisoles, solid 6.1 UN3458 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A + Nitrobenzene 6.1 UN1662 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 m-Nitrobenzene diazonium perchlorate Forbidden Nitrobenzenesulfonic acid 8 UN2305 II 8 B2, B4, IB8, IP2, IP4, T3, TP33 154 202 242 1 L 30 L A Nitrobenzol, see Nitrobenzene 5-Nitrobenzotriazol 1.1D UN0385 II 1.1D None 62 None Forbidden Forbidden 10 Nitrobenzotrifluorides, liquid 6.1 UN2306 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 Nitrobenzotrifluorides, solid 6.1 UN3431 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 Nitrobromobenzenes, liquid 6.1 UN2732 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Nitrobromobenzenes, solid 6.1 UN3459 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Nitrocellulose, dry or wetted with less than 25 percent water (or alcohol), by mass 1.1D UN0340 II 1.1D None 62 None Forbidden Forbidden 13 27E Nitrocellulose membrane filters, with not more than 12.6% nitrogen, by dry mass 4.1 UN3270 II 4.1 43, A1 151 212 240 1 kg 15 kg D Nitrocellulose, plasticized with not less than 18 percent plasticizing substance, by mass 1.3C UN0343 II 1.3C None 62 None Forbidden Forbidden 10 Nitrocellulose, solution, flammable with not more than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose 3 UN2059 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L E II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Nitrocellulose, unmodified or plasticized with less than 18 percent plasticizing substance, by mass 1.1D UN0341 II 1.1D None 62 None Forbidden Forbidden 13 27E Nitrocellulose, wetted with not less than 25 percent alcohol, by mass 1.3C UN0342 II 1.3C None 62 None Forbidden Forbidden 10 Nitrocellulose with alcohol with not less than 25 percent alcohol by mass, and with not more than 12.6 percent nitrogen, by dry mass 4.1 UN2556 II 4.1 151 212 None 1 kg 15 kg D 28 Nitrocellulose, with not more than 12.6 percent nitrogen, by dry mass, or Nitrocellulose mixture with pigment or Nitrocellulose mixture with plasticizer or Nitrocellulose mixture with pigment and plasticizer 4.1 UN2557 II 4.1 44 151 212 None 1 kg 15 kg D 28 Nitrocellulose with water with not less than 25 percent water, by mass 4.1 UN2555 II 4.1 151 212 None 15 kg 50 kg E 28 Nitrochlorobenzene, see Chloronitrobenzenes etc Nitrocresols, solid 6.1 UN2446 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Nitrocresols, liquid 6.1 UN3434 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Nitroethane 3 UN2842 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Start Printed Page 76118 Nitroethyl nitrate Forbidden Nitroethylene polymer Forbidden Nitrogen, compressed 2.2 UN1066 2.2 306 302 314, 315 75 kg 150 kg A Nitrogen dioxide, see Dinitrogen tetroxide Nitrogen fertilizer solution, see Fertilizer ammoniating solution etc Nitrogen, mixtures with rare gases, see Rare gases and nitrogen mixtures Nitrogen peroxide, see Dinitrogen tetroxide Nitrogen, refrigerated liquid cryogenic liquid 2.2 UN1977 2.2 T75, TP5 320 316 318 50 kg 500 kg D Nitrogen tetroxide and nitric oxide mixtures, see Nitric oxide and nitrogen tetroxide mixtures Nitrogen tetroxide, see Dinitrogen tetroxide Nitrogen trichloride Forbidden Nitrogen trifluoride 2.2 UN2451 2.2, 5.1 None 302 None 75 kg 150 kg D 40 Nitrogen triiodide Forbidden Nitrogen triiodide monoamine Forbidden Nitrogen trioxide 2.3 UN2421 2.3, 5.1, 8 1 None 336 245 Forbidden Forbidden D 40, 89, 90 Nitroglycerin, desensitized with not less than 40 percent non-volatile water insoluble phlegmatizer, by mass 1.1D UN0143 II 1.1D, 6.1 125 None 62 None Forbidden Forbidden 13 21E Nitroglycerin, liquid, not desensitized Forbidden Nitroglycerin mixture, desensitized, liquid, flammable, n.o.s. with not more than 30 percent nitroglycerin, by mass 3 UN3343 3 129 None 214 None Forbidden Forbidden D Nitroglycerin mixture, desensitized, liquid, n.o.s. with not more than 30% nitroglycerin, by mass 3 UN3357 II 3 142 None 202 243 5 L 60 L E Nitroglycerin mixture, desensitized, solid, n.o.s. with more than 2 percent but not more than 10 percent nitroglycerin, by mass 4.1 UN3319 II 4.1 118 None None None Forbidden 0.5 kg E Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 5 percent nitroglycerin 3 UN3064 II 3 N8 None 202 None Forbidden 5 L E Nitroglycerin, solution in alcohol, with more than 1 percent but not more than 10 percent nitrogylcerin 1.1D UN0144 II 1.1D None 62 None Forbidden Forbidden 10 21E Nitroglycerin solution in alcohol with not more than 1 percent nitroglycerin 3 UN1204 II 3 IB2, N34 150 202 None 5 L 60 L B Nitroguanidine nitrate Forbidden Nitroguanidine or Picrite, dry or wetted with less than 20 percent water, by mass 1.1D UN0282 II 1.1D None 62 None Forbidden Forbidden 10 Nitroguanidine, wetted or Picrite, wetted with not less than 20 percent water, by mass 4.1 UN1336 I 4.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg E 28 1-Nitrohydantoin Forbidden Nitrohydrochloric acid 8 UN1798 I 8 A3, B10, N41, T10, TP2, TP12, TP13 None 201 243 Forbidden 2.5 L D 40, 66, 74, 89, 90 Nitromannite (dry) Forbidden Nitromannite, wetted, see Mannitol hexanitrate, etc Nitromethane 3 UN1261 II 3 150 202 None Forbidden 60 L A Nitromuriatic acid, see Nitrohydrochloric acid Nitronaphthalene 4.1 UN2538 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A 4-Nitrophenylhydrazine, with not less than 30% water, by mass 4.1 UN3376 I 4.1 164, A8, A19, A20, N41 None 211 None Forbidden 15 kg E 36 + Nitrophenols (o-; m-; p-;) 6.1 UN1663 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A m-Nitrophenyldinitro methane Forbidden Nitropropanes 3 UN2608 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A p-Nitrosodimethylaniline 4.2 UN1369 II 4.2 A19, A20, IB6, IP2, N34, T3, TP33 None 212 241 15 kg 50 kg D 34 Nitrostarch, dry or wetted with less than 20 percent water, by mass 1.1D UN0146 II 1.1D None 62 None Forbidden Forbidden 10 Nitrostarch, wetted with not less than 20 percent water, by mass 4.1 UN1337 I 4.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg D 28 Nitrosugars (dry) Forbidden Nitrosyl chloride 2.3 UN1069 2.3, 8 3, B14 None 304 314, 315 Forbidden Forbidden D 40 Nitrosylsulfuric acid, liquid 8 UN2308 II 8 A3, A6, A7, B2, IB2, N34, T8, TP2, TP12 154 202 242 1 L 30 L D 40, 66, 74, 89, 90 Start Printed Page 76119 Nitrosylsulphuric acid, solid 8 UN3456 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg D 40, 66, 74, 89, 90 Nitrotoluenes, liquid 6.1 UN1664 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Nitrotoluenes, solid 6.1 UN3446 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nitrotoluidines (mono) 6.1 UN2660 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Nitrotriazolone or NTO 1.1D UN0490 II 1.1D None 62 None Forbidden Forbidden 10 Nitrous oxide and carbon dioxide mixtures, see Carbon dioxide and nitrous oxide mixtures Nitrous oxide 2.2 UN1070 2.2, 5.1 A14 306 304 314, 315 75 kg 150 kg A 40 Nitrous oxide, refrigerated liquid 2.2 UN2201 2.2, 5.1 B6, T75, TP5, TP22 None 304 314, 315 Forbidden Forbidden B 40 Nitroxylenes, liquid 6.1 UN1665 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Nitroxylenes, solid 6.1 UN3447 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Nitroxylol, see Nitroxylenes Nonanes 3 UN1920 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Non-flammable gas, n.o.s., see Compressed gas, etc. or Liquefied gas, etc Nonliquefied gases, see Compressed gases, etc Nonliquefied hydrocarbon gas, see Hydrocarbon gas mixture, compressed, n.o.s. Nonyltrichlorosilane 8 UN1799 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Nordhausen acid, see Sulfuric acid, fuming etc 2,5-Norbornadiene, stabilized, see Bicyclo 2,2,1 hepta-2,5-diene, stabilized Octadecyltrichlorosilane 8 UN1800 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Octadiene 3 UN2309 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B 1,7-Octadine-3,5-diyne-1,8-dimethoxy-9-octadecynoic acid Forbidden Octafluorobut-2-ene or Refrigerant gas R 1318 2.2 UN2422 2.2 None 304 314, 315 75 kg 150 kg A Octafluorocyclobutane, or Refrigerant gas RC 318 2.2 UN1976 2.2 T50 None 304 314, 315 75 kg 150 kg A Octafluoropropane or Refrigerant gas R 218 2.2 UN2424 2.2 T50 None 304 314, 315 75 kg 150 kg A Octanes 3 UN1262 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Octogen, etc. see Cyclotetramethylene tetranitramine, etc. Octolite or Octol, dry or wetted with less than 15 percent water, by mass 1.1D UN0266 II 1.1D None 62 None Forbidden Forbidden 10 Octonal 1.1D UN0496 1.1D None 62 None Forbidden Forbidden 10 Octyl aldehydes 3 UN1191 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Octyltrichlorosilane 8 UN1801 II 8 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 242 Forbidden 30 L C 40 Oil gas, compressed 2.3 UN1071 2.3, 2.1 6 None 304 314, 315 Forbidden 25 kg D 40 Oleum, see Sulfuric acid, fuming Organic peroxide type A, liquid or solid Forbidden G Organic peroxide type B, liquid 5.2 UN3101 II 5.2, 1 53 152 225 None Forbidden Forbidden D 12, 40, 52, 53 G Organic peroxide type B, liquid, temperature controlled 5.2 UN3111 II 5.2, 1 53 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type B, solid 5.2 UN3102 II 5.2, 1 53 152 225 None Forbidden Forbidden D 12, 40, 52, 53 G Organic peroxide type B, solid, temperature controlled 5.2 UN3112 II 5.2, 1 53 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type C, liquid 5.2 UN3103 II 5.2 152 225 None 5 L 10 L D 12, 40, 52, 53 G Organic peroxide type C, liquid, temperature controlled 5.2 UN3113 II 5.2 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type C, solid 5.2 UN3104 II 5.2 152 225 None 5 kg 10 kg D 12, 40, 52, 53 G Organic peroxide type C, solid, temperature controlled 5.2 UN3114 II 5.2 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type D, liquid 5.2 UN3105 II 5.2 152 225 None 5 L 10 L D 12, 40, 52, 53 G Organic peroxide type D, liquid, temperature controlled 5.2 UN3115 II 5.2 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type D, solid 5.2 UN3106 II 5.2 152 225 None 5 kg 10 kg D 12, 40, 52, 53 G Organic peroxide type D, solid, temperature controlled 5.2 UN3116 II 5.2 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type E, liquid 5.2 UN3107 II 5.2 152 225 None 10 L 25 L D 12, 40, 52, 53 Start Printed Page 76120 G Organic peroxide type E, liquid, temperature controlled 5.2 UN3117 II 5.2 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type E, solid 5.2 UN3108 II 5.2 152 225 None 10 kg 25 kg D 12, 40, 52, 53 G Organic peroxide type E, solid, temperature controlled 5.2 UN3118 II 5.2 None 225 None Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type F, liquid 5.2 UN3109 II 5.2 IP5 152 225 225 10 L 25 L D 12, 40, 52, 53 G Organic peroxide type F, liquid, temperature controlled 5.2 UN3119 II 5.2 IP5 None 225 225 Forbidden Forbidden D 2, 40, 52, 53 G Organic peroxide type F, solid 5.2 UN3110 II 5.2 TP33 152 225 225 10 kg 25 kg D 12, 40, 52, 53 G Organic peroxide type F, solid, temperature controlled 5.2 UN3120 II 5.2 TP33 None 225 225 Forbidden Forbidden D 2, 52, 53 D Organic phosphate, mixed with compressed gas or Organic phosphate compound, mixed with compressed gas or Organic phosphorus compound, mixed with compressed gas 2.3 NA1955 2.3 3 None 334 None Forbidden Forbidden D 40 Organic pigments, self-heating 4.2 UN3313 II 4.2 IB8, IP2, IP4, T3, TP33 None 212 241 15 kg 50 kg C III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg C G Organoarsenic compound, liquid, n.o.s. 6.1 UN3280 I 6.1 5, T14, TP2, TP13, TP27 None 211 242 5 kg 50 kg B II 6.1 IB2, T11, TP2, TP27 153 212 242 25 kg 100 kg B III 6.1 IB3, T7, TP1, TP28 153 213 240 100 kg 200 kg A G Organoarsenic compound, solid, n.o.s. 6.1 UN3465 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Organochlorine pesticides liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2762 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Organochlorine pesticides, liquid, toxic 6.1 UN2996 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Organochlorine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN2995 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Organochlorine pesticides, solid, toxic 6.1 UN2761 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 G Organometallic compound, toxic, liquid, n.o.s. 6.1 UN3282 I 6.1 T14, TP2, TP13, TP27 None 211 242 5 kg 50 kg B II 6.1 IB2, T11, TP2, TP27 153 212 242 25 kg 100 kg B III 6.1 IB3, T7, TP1, TP28 153 213 240 100 kg 200 kg A G Organometallic compound, toxic, solid, n.o.s. 6.1 UN3467 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B Start Printed Page 76121 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A G Organometallic substance, liquid, pyrophoric 4.2 UN3392 I 4.2 B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D 143 G Organometallic substance, liquid, pyrophoric, water-reactive 4.2 UN3394 I 4.2, 4.3 B11, T21, TP2, TP7 None 181 244 Forbidden Forbidden D G Organometallic substance, liquid, water-reactive 4.3 UN3398 I 4.3 T13, TP2, TP7 None 201 244 Forbidden Forbidden E 40, 52 II 4.3 IB1, T7, TP2, TP7 None 202 243 1 L 5 L E 40, 52 III 4.3 IB2, T7, TP2, TP7 None 203 242 5 L 60 L E 40, 52 G Organometallic substance, liquid, water-reactive, flammable 4.3 UN3399 I 4.3, 3 T13, TP2, TP7 None 201 244 Forbidden Fobidden E 40, 52 II 4.3, 3 IB1, T7, TP2, TP7 None 202 243 Forbidden Forbidden E 40, 52 III 4.3, 3 IB2, T7, TP2, TP7 None 203 242 Forbidden Forbidden E 40, 52 G Organometallic substance, solid, pyrophoric 4.2 UN3391 I 4.2 T21, TP7, TP33 None 181 244 Forbidden Forbidden D G Organometallic substance, solid, pyrophoric, water-reactive 4.2 UN3393 I 4.2, 4.3 B11, T21, TP7, TP33 None 181 244 Forbidden Forbidden D 52 G Organometallic substance, solid, self-heating 4.2 UN3400 II 4.2 IB6, T3, TP33 None 212 242 15 kg 50 kg C III 4.2 IB8, T1, TP33 None 203 242 25 kg 100 kg C G Organometallic substance, solid, water-reactive 4.3 UN3395 I 4.3 N40, T9, TP7, TP33 None 211 242 Forbidden Forbidden E 40, 52 II 4.3 IB4, T3, TP33 151 212 242 15 kg 50 kg E 40, 52 III 4.3 IB6, T1, TP33 151 213 241 25 kg 100 kg E 40, 52 G Organometallic substance, solid, water-reactive, flammable 4.3 UN3396 I 4.3, 4.1 N40, T9, TP7, TP33 None 211 242 Forbidden Forbidden E 40, 52 II 4.3, 4.1 IB4, T3, TP33 151 212 242 15 kg 50 kg E 40, 52 III 4.3, 4.1 IB6, T1, TP33 151 213 241 25 kg 100 kg E 40, 52 G Organometallic substance, solid, water-reactive, self-heating 4.3 UN3397 I 4.3, 4.2 N40, T9, TP7, TP33 None 211 242 Forbidden Forbidden E 40, 52 II 4.3, 4.2 IB4, T3, TP33 None 212 242 15 kg 50 kg E 40, 52 III 4.3, 4.2 IB6, T1, TP33 None 213 241 25 kg 100 kg E 40, 52 Organophosphorus compound, toxic, flammable, n.o.s. 6.1 UN3279 I 6.1, 3 5, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 G Organophosphorus compound, toxic, liquid, n.o.s. 6.1 UN3278 I 6.1 5, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A G Organophosphorus compound, toxic, solid, n.o.s. 6.1 UN3464 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Organophosphorus pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2784 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Organophosphorus pesticides, liquid, toxic 6.1 UN3018 I 6.1 N76, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, N76, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, N76, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Organophosphorus pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3017 I 6.1, 3 N76, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, N76, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, N76, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Organophosphorus pesticides, solid, toxic 6.1 UN2783 I 6.1 IB7, IP1, N77, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, N77, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, N77, T1, TP33 153 213 240 100 kg 200 kg A 40 Start Printed Page 76122 Organotin compounds, liquid, n.o.s. 6.1 UN2788 I 6.1 A3, N33, N34, T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 A3, IB2, N33, N34, T11, TP2, TP13, TP27 153 202 243 5 L 60 L A 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Organotin compounds, solid, n.o.s. 6.1 UN3146 I 6.1 A5, IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Organotin pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2787 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Organotin pesticides, liquid, toxic 6.1 UN3020 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Organotin pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3019 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Organotin pesticides, solid, toxic 6.1 UN2786 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Orthonitroaniline, see Nitroanilines etc Osmium tetroxide 6.1 UN2471 I 6.1 A8, IB7, IP1, N33, N34, T6, TP33 None 211 242 5 kg 50 kg B 40 D G Other regulated substances, liquid, n.o.s. 9 NA3082 III 9 IB3, T2, TP1 155 203 241 No limit No limit A D G Other regulated substances, solid, n.o.s. 9 NA3077 III 9 B54, IB8, IP2, T1, TP33 155 213 240 No limit No limit A G Oxidizing liquid, corrosive, n.o.s. 5.1 UN3098 I 5.1, 8 A6 None 201 244 Forbidden 2.5 L D 13, 56, 58, 106, 138 II 5.1, 8 IB1 None 202 243 1 L 5 L B 34, 56, 58, 106, 138 III 5.1, 8 IB2 152 203 242 2.5 L 30 L B 34, 56, 58, 106, 138 G Oxidizing liquid, n.o.s. 5.1 UN3139 I 5.1 127, A2, A6 None 201 243 Forbidden 2.5 L D 56, 58, 106, 138 II 5.1 127, A2, IB2 152 202 242 1 L 5 L B 56, 58, 106, 138 III 5.1 127, A2, IB2 152 203 241 2.5 L 30 L B 56, 58, 106, 138 Start Printed Page 76123 G Oxidizing liquid, toxic, n.o.s. 5.1 UN3099 I 5.1, 6.1 A6 None 201 244 Forbidden 2.5 L D 56, 58, 106, 138 II 5.1, 6.1 IB1 152 202 243 1 L 5 L B 56, 58, 95, 106, 138 III 5.1, 6.1 IB2 152 203 242 2.5 L 30 L B 56, 58, 95, 106, 138 G Oxidizing solid, corrosive, n.o.s. 5.1 UN3085 I 5.1, 8 None 211 242 1 kg 15 kg D 13, 56, 58, 106, 138 II 5.1, 8 IB6, IP2, T3, TP33 None 212 242 5 kg 25 kg B 13, 34, 56, 58, 106, 138 III 5.1, 8 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg B 13, 34, 56, 58, 106, 138 G Oxidizing solid, flammable, n.o.s. 5.1 UN3137 I 5.1, 4.1 None 214 214 Forbidden Forbidden G Oxidizing solid, n.o.s. 5.1 UN1479 I 5.1 IB5, IP1 None 211 242 1 kg 15 kg D 56, 58, 106, 138 II 5.1 IB8, IP2, IP4, T3, TP33 152 212 240 5 kg 25 kg B 56, 58, 106, 138 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg B 56, 58, 106, 138 G Oxidizing solid, self-heating, n.o.s. 5.1 UN3100 I 5.1, 4.2 None 214 214 Forbidden Forbidden II 5.1, 4.2 None 214 214 Forbidden Forbidden G Oxidizing solid, toxic, n.o.s. 5.1 UN3087 I 5.1, 6.1 None 211 242 1 kg 15 kg D 56, 58, 106, 138 II 5.1, 6.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg B 56, 58, 95, 106, 138 III 5.1, 6.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg B 56, 58, 95, 106, 138 G Oxidizing solid, water-reactive, n.o.s. 5.1 UN3121 5.1, 4.3 None 214 214 Forbidden Forbidden Oxygen and carbon dioxide mixtures, see Carbon dioxide and oxygen mixtures Oxygen, compressed 2.2 UN1072 2.2, 5.1 A14, A52 306 302 314, 315 75 kg 150 kg A Oxygen difluoride, compressed 2.3 UN2190 2.3, 5.1, 8 1 None 304 None Forbidden Forbidden D 13, 40, 89, 90 Oxygen generator, chemical (including when contained in associated equipment, e.g., passenger service units (PSUs), portable breathing equipment (PBE), etc). 5.1 UN3356 II 5.1 60, A51 None 212 None Forbidden 25 kg gross D 56, 58, 69, 106 + Oxygen generator, chemical, spent 9 NA3356 III 9 61 None 213 None Forbidden Forbidden A Oxygen, mixtures with rare gases, see Rare gases and oxygen mixtures Oxygen, refrigerated liquid (cryogenic liquid) 2.2 UN1073 2.2, 5.1 T75, TP5, TP22 320 316 318 Forbidden Forbidden D Paint including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base 3 UN1263 I 3 T11, TP1, TP8 150 201 243 1 L 30 L E II 3 149, B52, IB2, T4, TP1, TP8 150 173 242 5 L 60 L B III 3 B1, B52, IB3, T2, TP1 150 173 242 60 L 220 L A Paint or Paint related material 8 UN3066 II 8 B2, IB2, T7, TP2 154 173 242 1 L 30 L A III 8 B52, IB3, T4, TP1 154 173 241 5 L 60 L A Paint related material including paint thinning, drying, removing, or reducing compound 3 UN1263 I 3 T11, TP1, TP8 150 201 243 1 L 30 L E II 3 149, B52, IB2, T4, TP1, TP8 150 173 242 5 L 60 L B Start Printed Page 76124 III 3 B1, B52, IB3, T2, TP1 150 173 242 60 L 220 L A Paper, unsaturated oil treated incompletely dried (including carbon paper) 4.2 UN1379 III 4.2 IB8, IP3 None 213 241 Forbidden Forbidden A Paraformaldehyde 4.1 UN2213 III 4.1 A1, IB8, IP3, T1, TP33 151 213 240 25 kg 100 kg A Paraldehyde 3 UN1264 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Paranitroaniline, solid, see Nitroanilines etc D Parathion and compressed gas mixture 2.3 NA1967 2.3 3 None 334 245 Forbidden Forbidden E 40 Paris green, solid, see Copper acetoarsenite A W PCB, see Polychlorinated biphenyls + Pentaborane 4.2 UN1380 I 4.2, 6.1 1 None 205 245 Forbidden Forbidden D Pentachloroethane 6.1 UN1669 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 Pentachlorophenol 6.1 UN3155 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Pentaerythrite tetranitrate (dry) Forbidden Pentaerythrite tetranitrate mixture, desensitized, solid, n.o.s. with more than 10 percent but not more than 20 percent PETN, by mass 4.1 UN3344 II 4.1 118, N85 None 214 None Forbidden Forbidden E Pentaerythrite tetranitrate or Pentaerythritol tetranitrate or PETN, with not less than 7 percent wax by mass 1.1D UN0411 II 1.1D None 62 None Forbidden Forbidden 10 Pentaerythrite tetranitrate, wetted or Pentaerythritol tetranitrate, wetted, or PETN, wetted with not less than 25 percent water, by mass, or Pentaerythrite tetranitrate, or Pentaerythritol tetranitrate or PETN, desensitized with not less than 15 percent phlegmatizer by mass 1.1D UN0150 II 1.1D 121 None 62 None Forbidden Forbidden 10 Pentaerythritol tetranitrate, see Pentaerythrite tetranitrate, etc Pentafluoroethane or Refrigerant gas R 125 2.2 UN3220 2.2 T50 306 304 314, 315 75 kg 150 kg A Pentamethylheptane 3 UN2286 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Pentane-2,4-dione 3 UN2310 III 3, 6.1 B1, IB3, T4, TP1 150 203 242 60 L 220 L A Pentanes 3 UN1265 I 3 T11, TP2 150 201 243 1 L 30 L E II 3 IB2, IP8, T4, TP1 150 202 242 5 L 60 L E Pentanitroaniline (dry) Forbidden Pentanols 3 UN1105 II 3 IB2, T4, TP1, TP29 150 202 242 5 L 60 L B III 3 B1, B3, IB3, T2, TP1 150 203 242 60 L 220 L A 1-Pentene (n-amylene) 3 UN1108 I 3 T11, TP2 150 201 243 1 L 30 L E 1-Pentol 8 UN2705 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L B 26, 27 Pentolite, dry or wetted with less than 15 percent water, by mass 1.1D UN0151 II 1.1D None 62 None Forbidden Forbidden 10 Pepper spray, see Aerosols, etc. or Self-defense spray, non-pressurized Perchlorates, inorganic, aqueous solution, n.o.s. 5.1 UN3211 II 5.1 IB2, T4, TP1 152 202 242 1 L 5 L B 56, 58, 133 III 5.1 IB2, T4, TP1 152 202 241 2.5 L 30 L B 56, 58, 69, 133 Perchlorates, inorganic, n.o.s. 5.1 UN1481 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Perchloric acid, with more than 72 percent acid by mass Forbidden Perchloric acid with more than 50 percent but not more than 72 percent acid, by mass 5.1 UN1873 I 5.1, 8 A2, A3, N41, T10, TP1, TP12 None 201 243 Forbidden 2.5 L D 66 Perchloric acid with not more than 50 percent acid by mass 8 UN1802 II 8, 5.1 IB2, N41, T7, TP2 None 202 243 Forbidden 30 L C 66 Perchloroethylene, see Tetrachloroethylene Perchloromethyl mercaptan 6.1 UN1670 I 6.1 2, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Perchloryl fluoride 2.3 UN3083 2.3, 5.1 2, B9, B14 None 302 314, 315 Forbidden Forbidden D 40 Percussion caps, see Primers, cap type Perfluoro-2-butene, see Octafluorobut-2-ene Perfluoro(ethyl vinyl ether) 2.1 UN3154 2.1 306 302, 304, 305 314, 315 Forbidden 150 kg E 40 Start Printed Page 76125 Perfluoro(methyl vinyl ether) 2.1 UN3153 2.1 T50 306 302, 304, 305 314, 315 Forbidden 150 kg E 40 Perfumery products with flammable solvents 3 UN1266 II 3 149, IB2, T4, TP1, TP8 150 202 242 15 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Permanganates, inorganic, aqueous solution, n.o.s. 5.1 UN3214 II 5.1 26, IB2, T4, TP1 152 202 242 1 L 5 L D 56, 58, 133, 138 Permanganates, inorganic, n.o.s. 5.1 UN1482 II 5.1 26, A30, IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D 56, 58, 138 III 5.1 26, A30, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg D 56, 58, 138 Peroxides, inorganic, n.o.s. 5.1 UN1483 II 5.1 A7, A20, IB6, IP2, N34, T3, TP33 None 212 242 5 kg 25 kg A 13, 52, 66, 75 III 5.1 A7, A20, IB8, IP3, N34, T1, TP33 152 213 240 25 kg 100 kg A 13, 52, 66, 75 Peroxyacetic acid, with more than 43 percent and with more than 6 percent hydrogen peroxide Forbidden Persulfates, inorganic, aqueous solution, n.o.s. 5.1 UN3216 III 5.1 IB2, T4, TP1, TP29 152 203 241 2.5 L 30 L A 56, 133 Persulfates, inorganic, n.o.s. 5.1 UN3215 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 G Pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN3021 I 3, 6.1 B5, T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B G Pesticides, liquid, toxic, flammable, n.o.s. flash point not less than 23 degrees C 6.1 UN2903 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2 153 203 242 60 L 220 L A 40 G Pesticides, liquid, toxic, n.o.s. 6.1 UN2902 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 G Pesticides, solid, toxic, n.o.s. 6.1 UN2588 I 6.1 IB7, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 PETN, see Pentaerythrite tetranitrate PETN/TNT, see Pentolite, etc Petrol, see Gasoline Petroleum crude oil 3 UN1267 I 3 144, T11, TP1, TP8 150 201 243 1 L 30 L E II 3 144, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 144, B1, IB3, T2, TP1 150 203 242 60 L 220 L A Petroleum distillates, n.o.s. or Petroleum products, n.o.s. 3 UN1268 I 3 144, T11, TP1, TP8 150 201 243 1 L 30 L E II 3 144, IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 144, B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Petroleum gases, liquefied or Liquefied petroleum gas 2.1 UN1075 2.1 T50 306 304 314, 315 Forbidden 150 kg E 40 D Petroleum oil 3 NA1270 I 3 144, T11, TP1 None 201 243 1 L 30 L E II 3 144, IB2, T7, TP1, TP8, TP28 150 202 242 5 L 60 L B III 3 144, B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Phenacyl bromide 6.1 UN2645 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B 40 + Phenetidines 6.1 UN2311 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Phenol, molten 6.1 UN2312 II 6.1 B14, T7, TP3 None 202 243 Forbidden Forbidden B 40 + Phenol, solid 6.1 UN1671 II 6.1 IB8, IP2, IP4, N78, T3, TP33 153 212 242 25 kg 100 kg A Phenol solutions 6.1 UN2821 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Start Printed Page 76126 Phenolsulfonic acid, liquid 8 UN1803 II 8 B2, IB2, N41, T7, TP2 154 202 242 1 L 30 L C 14 Phenoxyacetic acid derivative pesticide, liquid, flammable, toxic flash point less than 23 degrees C 3 UN3346 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Phenoxyacetic acid derivative pesticide, liquid, toxic 6.1 UN3348 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Phenoxyacetic acid derivative pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3347 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Phenoxyacetic acid derivative pesticide, solid, toxic 6.1 UN3345 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Phenyl chloroformate 6.1 UN2746 II 6.1, 8 IB2, T7, TP2, TP13 153 202 243 1 L 30 L A 12, 13, 21, 25, 40, 100 Phenyl isocyanate 6.1 UN2487 I 6.1, 3 2, B9, B14, B32, B74, B77, N33, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Phenyl mercaptan 6.1 UN2337 I 6.1, 3 2, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden B 40, 52 Phenyl phosphorus dichloride 8 UN2798 II 8 B2, B15, IB2, T7, TP2 154 202 242 Forbidden 30 L B 40 Phenyl phosphorus thiodichloride 8 UN2799 II 8 B2, B15, IB2, T7, TP2 154 202 242 Forbidden 30 L B 40 Phenylacetonitrile, liquid 6.1 UN2470 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52 Phenylacetyl chloride 8 UN2577 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C 40 Phenylcarbylamine chloride 6.1 UN1672 I 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 40 m-Phenylene diaminediperchlorate (dry) Forbidden + Phenylenediamines (o-; m-; p-;) 6.1 UN1673 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Phenylhydrazine 6.1 UN2572 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 Phenylmercuric acetate 6.1 UN1674 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Phenylmercuric compounds, n.o.s. 6.1 UN2026 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Phenylmercuric hydroxide 6.1 UN1894 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Phenylmercuric nitrate 6.1 UN1895 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Phenyltrichlorosilane 8 UN1804 II 8 A7, B6, IB2, N34, T7, TP2 None 202 242 Forbidden 30 L C 40 Phosgene 2.3 UN1076 2.3, 8 1, B7, B46 None 192 314 Forbidden Forbidden D 40 Start Printed Page 76127 9-Phosphabicyclononanes or Cyclooctadiene phosphines 4.2 UN2940 II 4.2 A19, IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg A Phosphine 2.3 UN2199 2.3, 2.1 1 None 192 245 Forbidden Forbidden D 40 Phosphoric acid solution 8 UN1805 III 8 A7, IB3, N34, T4, TP1 154 203 241 5 L 60 L A Phosphoric acid, solid 8 UN3453 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Phosphoric acid triethyleneimine, see Tris-(1-aziridiyl)phosphine oxide, solution Phosphoric anhydride, see Phosphorus pentoxide Phosphorous acid 8 UN2834 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 48 Phosphorus, amorphous 4.1 UN1338 III 4.1 A1, A19, B1, B9, B26, IB8, IP3, T1, TP33 None 213 243 25 kg 100 kg A 74 Phosphorus bromide, see Phosphorus tribromide Phosphorus chloride, see Phosphorus trichloride Phosphorus heptasulfide, free from yellow or white phosphorus 4.1 UN1339 II 4.1 A20, IB4, N34, T3, TP33 None 212 240 15 kg 50 kg B 74 Phosphorus oxybromide 8 UN1939 II 8 B8, IB8, IP2, IP4, N41, N43, T3, TP33 None 212 240 Forbidden 50 kg C 12, 40 Phosphorus oxybromide, molten 8 UN2576 II 8 B2, B8, IB1, N41, N43, T7, TP3, TP13 None 202 242 Forbidden Forbidden C 40 + Phosphorus oxychloride 8 UN1810 II 8, 6.1 2, B9, B14, B32, B74, B77, N34, T20, TP2, TP38, TP45 None 227 244 Forbidden Forbidden C 40 Phosphorus pentabromide 8 UN2691 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 154 212 240 Forbidden 50 kg B 12, 40, 53, 55 Phosphorus pentachloride 8 UN1806 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 None 212 240 Forbidden 50 kg C 40, 44, 89, 100, 141 Phosphorus 2.3 UN2198 2.3, 8 2, B9, B14 None 302, 304 314, 315 Forbidden Forbidden D 40 Phosphorus pentasulfide, free from yellow or white phosphorus 4.3 UN1340 II 4.3, 4.1 A20, B59, IB4, T3, TP33 151 212 242 15 kg 50 kg B 74 Phosphorus pentoxide 8 UN1807 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 154 212 240 15 kg 50 kg A Phosphorus sesquisulfide, free from yellow or white phosphorus 4.1 UN1341 II 4.1 A20, IB4, N34, T3, TP33 None 212 240 15 kg 50 kg B 74 Phosphorus tribromide 8 UN1808 II 8 A3, A6, A7, B2, B25, IB2, N34, N43, T7, TP2 None 202 242 Forbidden 30 L C 40 Phosphorus trichloride 6.1 UN1809 I 6.1, 8 2, B9, B14, B15, B32, B74, B77, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden C 40 Phosphorus trioxide 8 UN2578 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 12 Phosphorus trisulfide, free from yellow or white phosphorus 4.1 UN1343 II 4.1 A20, IB4, N34, T3, TP33 None 212 240 15 kg 50 kg B 74 Phosphorus, white dry or Phosphorus, white, under water or Phosphorus white, in solution or Phosphorus, yellow dry or Phosphorus, yellow, under water or Phosphorus, yellow, in solution 4.2 UN1381 I 4.2, 6.1 B9, B26, N34, T9, TP3, TP31 None 188 243 Forbidden Forbidden E Phosphorus white, molten 4.2 UN2447 I 4.2, 6.1 B9, B26, N34, T21, TP3, TP7, TP26 None 188 243 Forbidden Forbidden D Phosphorus (white or red) and a chlorate, mixtures of Forbidden Phosphoryl chloride, see Phosphorus oxychloride Phthalic anhydride with more than .05 percent maleic anhydride 8 UN2214 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Picolines 3 UN2313 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A 40 Picric acid, see Trinitrophenol, etc Picrite, see Nitroguanidine, etc Picryl chloride, see Trinitrochlorobenzene Pine oil 3 UN1272 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A alpha-Pinene 3 UN2368 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Piperazine 8 UN2579 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 12, 52 Piperidine 8 UN2401 I 8, 3 A10, T10, TP2 None 201 243 0.5 L 2.5 L B 52 Pivaloyl chloride, see Trimethylacetyl chloride Start Printed Page 76128 Plastic molding compound in dough, sheet or extruded rope form evolving flammable vapor 9 UN3314 III 9 32, IB8, IP3, IP7 155 221 221 100 kg 200 kg A 85, 87 Plastic solvent, n.o.s., see Flammable liquids, n.o.s. Plastics, nitrocellulose-based, self-heating, n.o.s. 4.2 UN2006 III 4.2 None 213 None Forbidden Forbidden C Poisonous gases, n.o.s., see Compressed or liquefied gases, flammable or toxic, n.o.s. Polyalkylamines, n.o.s., see Amines, etc Polychlorinated biphenyls, liquid 9 UN2315 II 9 9, 81, 140, IB3, T4, TP1 155 202 241 100 L 220 L A 95 Polychlorinated biphenyls, solid 9 UN3432 II 9 9, 81, 140, IB8, T3, TP33 155 212 240 100 kg 200 kg A 95 Polyester resin kit 3 UN3269 3 40, 149 152 225 None 5 kg 5 kg B Polyhalogenated biphenyls, liquid or Polyhalogenated terphenyls liquid 9 UN3151 II 9 IB2 155 204 241 100 L 220 L A 95 Polyhalogenated biphenyls, solid or Polyhalogenated terphenyls, solid 9 UN3152 II 9 IB8, IP2, IP4, T3, TP33 155 204 241 100 kg 200 kg A 95 Polymeric beads, expandable, evolving flammable vapor 9 UN2211 III 9 32, IB8, IP3, IP7, T1, TP33 155 221 221 100 kg 200 kg A 85, 87 Potassium 4.3 UN2257 I 4.3 A7, A19, A20, B27, IB4, IP1, N6, N34, T9, TP7, TP33 None 211 244 Forbidden 15 kg D 52 Potassium arsenate 6.1 UN1677 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Potassium arsenite 6.1 UN1678 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Potassium bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. Potassium borohydride 4.3 UN1870 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Potassium bromate 5.1 UN1484 II 5.1 IB8, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Potassium carbonyl Forbidden Potassium chlorate 5.1 UN1485 II 5.1 A9, IB8, IP4, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Potassium chlorate, aqueous solution 5.1 UN2427 II 5.1 A2, IB2, T4, TP1 152 202 241 1 L 5 L B 56, 58, 133 III 5.1 A2, IB2, T4, TP1 152 203 241 2.5 L 30 L B 56, 58, 69, 133 Potassium chlorate mixed with mineral oil, see Explosive, blasting, type C Potassium cuprocyanide 6.1 UN1679 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 52 Potassium cyanide, solid 6.1 UN1680 I 6.1 B69, B77, IB7, IP1, N74, N75, T6, TP33 None 211 242 5 kg 50 kg B 52 Potassium cyanide solution 6.1 UN3413 I 6.1 B69, B77, N74, N75, T14, TP2, TP13 None 201 243 1 L 30 L B 52 II 6.1 B69, B77, IB2, N74, N75, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 52 III 6.1 B69, B77, IB3, N74, N75, T7, TP2, TP13, TP28 153 203 241 60 L 220 L A 52 Potassium dichloro isocyanurate or Potassium dichloro-s-triazinetrione, see Dichloroisocyanuric acid, dry or Dichloroisocyanuric acid salts etc Potassium dithionite or Potassium hydrosulfite 4.2 UN1929 II 4.2 A8, A19, A20, IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg E 13 Potassium fluoride, solid 6.1 UN1812 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Potassium fluoride solution 6.1 UN3422 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52 Potassium fluoroacetate 6.1 UN2628 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg E Potassium fluorosilicate 6.1 UN2655 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Potassium hydrate, see Potassium hydroxide, solid Potassium hydrogen fluoride, see Potassium hydrogen difluoride Potassium hydrogen fluoride solution, see Corrosive liquid, n.o.s. Start Printed Page 76129 Potassium hydrogen sulfate 8 UN2509 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 154 212 240 15 kg 50 kg A Potassium hydrogendifluoride solid 8 UN1811 II 8, 6.1 IB8, IP2, IP4, N3, N34, T3, TP33 154 212 240 15 kg 50 kg A 25, 40, 52 Potassium hydrogendifluoride solution 8 UN3421 II 8, 6.1 IB2, N3, N34, T7, TP2 154 202 243 1 L 30 L A 25, 40, 52 III 8, 6.1 IB3, N3, N34, T4, TP1 154 203 241 5 L 60 L A 40, 52 Potassium hydrosulfite, see Potassium dithionite Potassium hydroxide, liquid, see Potassium hydroxide solution Potassium hydroxide, solid 8 UN1813 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Potassium hydroxide, solution 8 UN1814 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Potassium hypochlorite, solution, see Hypochlorite solutions, etc Potassium, metal alloys, liquid 4.3 UN1420 I 4.3 A7, A19, A20, B27 None 201 244 Forbidden 1 L E 40, 52 Potassium, metal alloys, solid 4.3 UN3403 I 4.3 A19, A20, B27, IB4, IP1, T9, TP7, TP33 None 211 244 Forbidden 15 kg D Potassium metal, liquid alloy, see Alkali metal alloys, liquid, n.o.s. Potassium metavanadate 6.1 UN2864 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Potassium monoxide 8 UN2033 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 29 Potassium nitrate 5.1 UN1486 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Potassium nitrate and sodium nitrite mixtures 5.1 UN1487 II 5.1 B78, IB8, IP4, T3, TP33 152 212 240 5 kg 25 kg A 56, 58 Potassium nitrite 5.1 UN1488 II 5.1 IB8, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Potassium perchlorate 5.1 UN1489 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Potassium permanganate 5.1 UN1490 II 5.1 IB8, IP4, T3, TP33 152 212 240 5 kg 25 kg D 56, 58, 138 Potassium peroxide 5.1 UN1491 I 5.1 A20, IB6, IP1, N34 None 211 None Forbidden 15 kg B 13, 52, 66, 75 Potassium persulfate 5.1 UN1492 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Potassium phosphide 4.3 UN2012 I 4.3, 6.1 A19, N40 None 211 None Forbidden 15 kg E 40, 52, 85 Potassium selenate, see Selenates or Selenites Potassium selenite, see Selenates or Selenites Potassium sodium alloys, solid 4.3 UN3404 I 4.3 A19, B27, N34, N40, T9, TP7, TP33 None 211 244 Forbidden 15 kg D 52 Potassium sodium alloys, liquid 4.3 UN1422 I 4.3 A7, A19, B27, N34, N40, T9, TP3, TP7, TP31 None 201 244 Forbidden 1 L E 40, 52 Potassium sulfide, anhydrous or Potassium sulfide with less than 30 percent water of crystallization 4.2 UN1382 II 4.2 A19, A20, B16, IB6, IP2, N34, T3, TP33 None 212 241 15 kg 50 kg A 52 Potassium sulfide, hydrated with not less than 30 percent water of crystallization 8 UN1847 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 52 Potassium superoxide 5.1 UN2466 I 5.1 A20, IB6, IP1 None 211 None Forbidden 15 kg B 13, 52, 66, 75 Powder cake, wetted or Powder paste, wetted with not less than 17 percent alcohol by mass 1.1C UN0433 II 1.1C None 62 None Forbidden Forbidden 10 Powder cake, wetted or Powder paste, wetted with not less than 25 percent water, by mass 1.3C UN0159 II 1.3C None 62 None Forbidden Forbidden 10 Powder paste, see Powder cake, etc Powder, smokeless 1.1C UN0160 II 1.1C None 62 None Forbidden Forbidden 26E Powder, smokeless 1.3C UN0161 II 1.3C None 62 None Forbidden Forbidden 26E Power device, explosive, see Cartridges, power device Primers, cap type 1.4S UN0044 II None None 62 None 25 kg 100 kg 05 Primers, cap type 1.1B UN0377 II 1.1B None 62 None Forbidden Forbidden 11 Primers, cap type 1.4B UN0378 II 1.4B None 62 None Forbidden 75 kg 06 Primers, small arms, see Primers, cap type Primers, tubular 1.3G UN0319 II 1.3G None 62 None Forbidden Forbidden 07 Primers, tubular 1.4G UN0320 II 1.4G None 62 None Forbidden 75 kg 06 Primers, tubular 1.4S UN0376 II None None 62 None 25 kg 100 kg 05 Printing ink, flammable or Printing ink related material (including printing ink thinning or reducing compound), flammable 3 UN1210 I 3 T11, TP1, TP8 150 173 243 1 L 30 L E II 3 149, IB2, T4, TP1, TP8 150 173 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 173 242 60 L 220 L A Start Printed Page 76130 Projectiles, illuminating, see Ammunition, illuminating, etc Projectiles, inert with tracer 1.4S UN0345 II 1.4S 62 None 25 kg 100 kg 01 Projectiles, inert, with tracer 1.3G UN0424 II 1.3G 62 None Forbidden Forbidden 03 Projectiles, inert, with tracer 1.4G UN0425 II 1.4G 62 None Forbidden 75 kg 02 Projectiles, with burster or expelling charge 1.2D UN0346 II 1.2D 62 None Forbidden Forbidden 03 Projectiles, with burster or expelling charge 1.4D UN0347 II 1.4D 62 None Forbidden 75 kg 02 Projectiles, with burster or expelling charge 1.2F UN0426 II 1.2F 62 None Forbidden Forbidden 08 Projectiles, with burster or expelling charge 1.4F UN0427 II 1.4F 62 None Forbidden Forbidden 08 Projectiles, with burster or expelling charge 1.2G UN0434 II 1.2G 62 None Forbidden Forbidden 03 Projectiles, with burster or expelling charge 1.4G UN0435 II 1.4G 62 None Forbidden 75 kg 02 Projectiles, with bursting charge 1.1F UN0167 II 1.1F 62 None Forbidden Forbidden 08 Projectiles, with bursting charge 1.1D UN0168 II 1.1D 62 None Forbidden Forbidden 03 Projectiles, with bursting charge 1.2D UN0169 II 1.2D 62 None Forbidden Forbidden 03 Projectiles, with bursting charge 1.2F UN0324 II 1.2F 62 None Forbidden Forbidden 08 Projectiles, with bursting charge 1.4D UN0344 II 1.4D 62 None Forbidden 75 kg 02 Propadiene, stabilized 2.1 UN2200 2.1 None 304 314, 315 Forbidden 150 kg B 40 Propadiene mixed with methyl acetylene, see Methyl acetylene and propadiene mixtures, stabilized Propane see also Petroleum gases, liquefied 2.1 UN1978 2.1 19, T50 306 304 314, 315 Forbidden 150 kg E 40 Propanethiols 3 UN2402 II 3 A6, IB2, T4, TP1, TP13 150 202 242 5 L 60 L E 95, 102 n-Propanol or Propyl alcohol, normal 3 UN1274 II 3 B1, IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Propellant, liquid 1.3C UN0495 II 1.3C 37 None 62 None Forbidden Forbidden 10 Propellant, liquid 1.1C UN0497 II 1.1C 37 None 62 None Forbidden Forbidden 10 Propellant, solid 1.1C UN0498 II 1.1C None 62 None Forbidden Forbidden 26E Propellant, solid 1.3C UN0499 II 1.3C None 62 None Forbidden Forbidden 26E Propellant, solid 1.4C UN0501 1.4C None 62 None Forbidden Forbidden A 24E Propionaldehyde 3 UN1275 II 3 IB2, T7, TP1 150 202 242 5 L 60 L E Propionic acid 8 UN1848 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Propionic anhydride 8 UN2496 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Propionitrile 3 UN2404 II 3, 6.1 IB2, T7, TP1, TP13 None 202 243 Forbidden 60 L E 40 Propionyl chloride 3 UN1815 II 3, 8 IB1, T7, TP1 150 202 243 1 L 5 L B 40 n-Propyl acetate 3 UN1276 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Propyl alcohol, see Propanol n-Propyl benzene 3 UN2364 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A n-Propyl chloroformate 6.1 UN2740 I 6.1, 3, 8 2, B9, B14, B32, B74, B77, N34, T20, TP2, TP13, TP38, TP44 None 227 244 Forbidden Forbidden B 21, 40, 100 Propyl chloride see 1-Chloropropane Propyl formates 3 UN1281 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B n-Propyl isocyanate 6.1 UN2482 I 6.1, 3 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 Propyl mercaptan, see Propanethiols n-Propyl nitrate 3 UN1865 II 3 IB99 150 202 None 5 L 60 L D 44, 89, 90, 100 Propylamine 3 UN1277 II 3, 8 A7, IB2, N34, T7, TP1 150 202 243 1 L 5 L E 40 Propylene see also Petroleum gases, liquefied 2.1 UN1077 2.1 19, T50 306 304 314, 315 Forbidden 150 kg E 40 Propylene chlorohydrin 6.1 UN2611 II 6.1, 3 IB2, T7, TP2, TP13 153 202 243 5 L 60 L A 12, 40, 48 Propylene oxide 3 UN1280 I 3 A3, N34, T11, TP2, TP7 None 201 243 1 L 30 L E 40 Propylene tetramer 3 UN2850 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 1,2-Propylenediamine 8 UN2258 II 8, 3 A3, A6, IB2, N34, T7, TP2 None 202 243 1 L 30 L A 40 Propyleneimine, stabilized 3 UN1921 I 3, 6.1 A3, N34, T14, TP2, TP13 None 201 243 1 L 30 L B 40 Start Printed Page 76131 Propyltrichlorosilane 8 UN1816 II 8, 3 A7, B2, B6, IB2, N34, T7, TP2, TP13 None 202 243 Forbidden 30 L C 40 Prussic acid, see Hydrogen cyanide Pyrethroid pesticide, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN3350 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Pyrethroid pesticide, liquid toxic 6.1 UN3352 I 6.1 T14, TP2, TP13, TP27 None 211 242 1 L 30 L A 40 II 6.1 IB2, T11, TP2, TP27 153 212 242 5 L 60 L A 40 III 6.1 IB3, T7, TP2, TP28 153 213 240 60 L 220 L A 40 Pyrethroid pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3351 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 IB3, T7, TP2, TP28 153 203 241 60 L 220 L B 40 Pyrethroid pesticide, solid, toxic 6.1 UN3349 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Pyridine 3 UN1282 II 3 IB2, T4, TP2 None 202 242 5 L 60 L B 21, 100 Pyridine perchlorate Forbidden G Pyrophoric liquid, inorganic, n.o.s. 4.2 UN3194 I 4.2 None 181 244 Forbidden Forbidden D 18 G Pyrophoric liquids, organic, n.o.s. 4.2 UN2845 I 4.2 B11, T22, TP2, TP7 None 181 244 Forbidden Forbidden D 18 G Pyrophoric metals, n.o.s., or Pyrophoric alloys, n.o.s. 4.2 UN1383 I 4.2 B11, T21, TP7, TP33 None 187 242 Forbidden Forbidden D G Pyrophoric solid, inorganic, n.o.s. 4.2 UN3200 I 4.2 T21, TP7, TP33 None 187 242 Forbidden Forbidden D G Pyrophoric solids, organic, n.o.s. 4.2 UN2846 I 4.2 None 187 242 Forbidden Forbidden D Pyrosulfuryl chloride 8 UN1817 II 8 B2, IB2, T8, TP2, TP12 154 202 242 1 L 30 L C 40 Pyroxylin solution or solvent, see Nitrocellulose Pyrrolidine 3 UN1922 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40 Quebrachitol pentanitrate Forbidden Quicklime, see Calcium oxide Quinoline 6.1 UN2656 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 12 R 12, see Dichlorodifluoromethane R 12B1, see Chlorodifluorobromomethane R 13, see Chlorotrifluoromethane R 13B1, see Bromotrifluoromethane R 14, see Tetrafluoromethane R 21, see Dichlorofluoromethane R 22, see Chlorodifluoromethane R 114, see Dichlorotetrafluoroethane R 115, see Chloropentafluoroethane R 116, see Hexafluoroethane R 124, see Chlorotetrafluoroethane R 133a, see Chlorotrifluoroethane R 152a, see Difluoroethane R 500, see Dichlorodifluoromethane and difluorethane, etc R 502, see Chlorodifluoromethane and chloropentafluoroethane mixture, etc R 503, see Chlorotrifluoromethane and trifluoromethane, etc Radioactive material, excepted package-articles manufactured from natural uranium or depleted uranium or natural thorium 7 UN2909 None 422, 426 422, 426 422, 426 A Radioactive material, excepted package-empty packaging 7 UN2908 Empty 422, 428 422, 428 422, 428 A Radioactive material, excepted package-instruments or articles 7 UN2911 None 422, 424 422, 424 A Radioactive material, excepted package-limited quantity of material 7 UN2910 None 421, 422 421, 422 421, 422 A Radioactive material, low specific activity (LSA-I) non fissile or fissile-excepted 7 UN2912 7 A56, T5, TP4, W7 421, 422, 428 427 427 A 95, 129 Radioactive material, low specific activity (LSA-II) non fissile or fissile-excepted 7 UN3321 7 A56, T5, TP4, W7 421, 422, 428 427 427 A 95, 129 Radioactive material, low specific activity (LSA-III) non fissile or fissile excepted 7 UN3322 7 A56, T5, TP4, W7 421, 422, 428 427 427 A 95, 129 Start Printed Page 76132 Radioactive material, surface contaminated objects (SCO-I or SCO-II) non fissile or fissile-excepted 7 UN2913 7 A56 421, 422, 428 427 427 A 95 Radioactive material, transported under special arrangement, non fissile or fissile excepted 7 UN2919 7 A56, 139 A 95, 105 Radioactive material, transported under special arrangement, fissile 7 UN3331 7 A56, 139 A 95, 105 Radioactive material, Type A package, fissile non-special form 7 UN3327 7 A56, W7, W8 453 417 417 A 95, 105, 131 Radioactive material, Type A package non-special form, non fissile or fissile-excepted 7 UN2915 7 A56, W7, W8 415 415 A 95, 130 Radioactive material, Type A package, special form non fissile or fissile-excepted 7 UN3332 7 A56, W7, W8 415, 476 415, 476 A 95 Radioactive material, Type A package, special form, fissile 7 UN3333 7 A56, W7, W8 453 417, 476 417, 476 A 95, 105 Radioactive material, Type B(M) package, fissile 7 UN3329 7 A56 453 417 417 A 95, 105 Radioactive material, Type B(M) package non fissile or fissile-excepted 7 UN2917 7 A56 416 416 A 95, 105 Radioactive material, Type B(U) package, fissile 7 UN3328 7 A56 453 417 417 A 95, 105 Radioactive material, Type B(U) package non fissile or fissile-excepted 7 UN2916 7 A56 416 416 A 95, 105 Radioactive material, uranium hexafluoride non fissile or fissile-excepted 7 UN2978 7, 8 423 420, 427 420, 427 A 95, 132 I Radioactive material, uranium hexafluoride, fissile 7 UN2977 7, 8 453 417, 420 417, 420 A 95, 132 A W Rags, oily 4.2 UN1856 III 4.2 151 213 240 Forbidden Forbidden A Railway torpedo, see Signals, railway track, explosive Rare gases and nitrogen mixtures, compressed 2.2 UN1981 2.2 306 302 None 75 kg 150 kg A Rare gases and oxygen mixtures, compressed 2.2 UN1980 2.2 79 306 302 None 75 kg 150 kg A Rare gases mixtures, compressed 2.2 UN1979 2.2 306 302 None 75 kg 150 kg A RC 318, see Octafluorocyclobutane RDX and cyclotetramethylenetetranitramine, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized RDX and HMX mixtures, wetted with not less than 15 percent water by mass or RDX and HMX mixtures, desensitized with not less than 10 percent phlegmatizer by mass 1.1D UN0391 II 1.1D None 62 None Forbidden Forbidden 10 RDX and Octogen mixtures, wetted or desensitized see RDX and HMX mixtures, wetted or desensitized etc RDX, see Cyclotrimethylene trinitramine, etc Receptacles, small, containing gas (gas cartridges) flammable, without release device, not refillable and not exceeding 1 L capacity 2.1 UN2037 2.1 306 304 None 1 kg 15 kg B 40 Receptacles, small, containing gas (gas cartridges) non-flammable, without release device, not refillable and not exceeding 1 L capacity 2.2 UN2037 2.2 306 304 None 1 kg 15 kg B 40 2.2, 5.1 A14 306 304 None 1 kg 15 kg B 40 Red phosphorus, see Phosphorus, amorphous Refrigerant gas R 404A 2.2 UN3337 2.2 T50 306 304 314, 315 75 kg 150 kg A Refrigerant gas R 407A 2.2 UN3338 2.2 T50 306 304 314, 315 75 kg 150 kg A Refrigerant gas R 407B 2.2 UN3339 2.2 T50 306 304 314, 315 75 kg 150 kg A Refrigerant gas R 407C 2.2 UN3340 2.2 T50 306 304 314, 315 75 kg 150 kg A G Refrigerant gases, n.o.s. 2.2 UN1078 2.2 T50 306 304 314, 315 75 kg 150 kg A D Refrigerant gases, n.o.s. or Dispersant gases, n.o.s. 2.1 NA1954 2.1 T50 306 304 314, 315 Forbidden 150 kg D 40 Refrigerating machines, containing flammable, non-toxic, liquefied gas 2.1 UN3358 2.1 306 306 306 Forbidden Forbidden C 40 Refrigerating machines, containing non-flammable, non-toxic, or ammonia solution (UN2672) 2.2 UN2857 2.2 A53 306, 307 306 306, 307 450 kg 450 kg A Regulated medical waste 6.2 UN3291 II 6.2 A13 134 197 197 No limit No limit A 40 Release devices, explosive 1.4S UN0173 II 1.4S None 62 None 25 kg 100 kg 05 Resin solution, flammable 3 UN1866 I 3 B52, T11, TP1, TP8, TP28 150 201 243 1 L 30 L E II 3 149, B52, IB2, T4, TP1, TP8 150 173 242 5 L 60 L B III 3 B1, B52, IB3, T2, TP1 150 173 242 60 L 220 L A Start Printed Page 76133 Resorcinol 6.1 UN2876 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Rifle grenade, see Grenades, hand or rifle, etc Rifle powder, see Powder, smokeless (UN 0160) Rivets, explosive 1.4S UN0174 II 1.4S None 62 None 25 kg 100 kg 05 Road asphalt or tar liquid, see Tars, liquid, etc Rocket motors 1.3C UN0186 II 1.3C 109 None 62 None Forbidden 220 kg 03 Rocket motors 1.1C UN0280 II 1.1C 109 None 62 None Forbidden Forbidden 03 Rocket motors 1.2C UN0281 II 1.2C 109 None 62 None Forbidden Forbidden 03 Rocket motors, liquid fueled 1.2J UN0395 II 1.2J 109 None 62 None Forbidden Forbidden 04 23E Rocket motors, liquid fueled 1.3J UN0396 II 1.3J 109 None 62 None Forbidden Forbidden 04 23E Rocket motors with hypergolic liquids with or without an expelling charge 1.3L UN0250 II 1.3L 109 None 62 None Forbidden Forbidden 08 8E, 14E, 15E Rocket motors with hypergolic liquids with or without an expelling charge 1.2L UN0322 II 1.2L 109 None 62 None Forbidden Forbidden 08 8E, 14E, 15E Rockets, line-throwing 1.2G UN0238 II 1.2G None 62 None Forbidden Forbidden 07 Rockets, line-throwing 1.3G UN0240 II 1.3G None 62 None Forbidden 75 kg 07 Rockets, line-throwing 1.4G UN0453 II 1.4G None 62 None Forbidden 75 kg 06 Rockets, liquid fueled with bursting charge 1.1J UN0397 II 1.1J None 62 None Forbidden Forbidden 04 23E Rockets, liquid fueled with bursting charge 1.2J UN0398 II 1.2J None 62 None Forbidden Forbidden 04 23E Rockets, with bursting charge 1.1F UN0180 II 1.1F None 62 None Forbidden Forbidden 08 Rockets, with bursting charge 1.1E UN0181 II 1.1E None 62 None Forbidden Forbidden 03 Rockets, with bursting charge 1.2E UN0182 II 1.2E None 62 None Forbidden Forbidden 03 Rockets, with bursting charge 1.2F UN0295 II 1.2F None 62 None Forbidden Forbidden 08 Rockets, with expelling charge 1.2C UN0436 II 1.2C None 62 None Forbidden Forbidden 03 Rockets, with expelling charge 1.3C UN0437 II 1.3C None 62 None Forbidden Forbidden 03 Rockets, with expelling charge 1.4C UN0438 II 1.4C None 62 None Forbidden 75 kg 02 Rockets, with inert head 1.3C UN0183 II 1.3C None 62 None Forbidden Forbidden 03 Rockets, with inert head 1.2C UN0502 1.2C None 62 None Forbidden Forbidden B 1E, 5E Rosin oil 3 UN1286 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Rubber solution 3 UN1287 II 3 149, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B Rubber scrap or shoddy, powdered or granulated, not exceeding 840 microns and rubber contend exceeding 45% 4.1 UN1345 II 4.1 IB8, IP2, IP4, T3, TP33 151 212 240 15 kg 50 kg A Rubber solution 3 UN1287 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Rubidium 4.3 UN1423 I 4.3 22, A7, A19, IB4, IP1, N34, N40, N45 None 211 242 Forbidden 15 kg D 52 Rubidium hydroxide 8 UN2678 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 29 Rubidium hydroxide solution 8 UN2677 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 29 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 29 Safety fuse, see Fuse, safety Sand acid, see Fluorosilicic acid Seed cake, containing vegetable oil solvent extractions and expelled seeds, with not more than 10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined 4.2 UN1386 III None IB8, IP3, IP7, N7 None 213 241 Forbidden Forbidden A 13 I Seed cake with more than 1.5 percent oil and not more than 11 percent moisture 4.2 UN1386 III None IB8, IP3, IP7, N7 None 213 241 Forbidden Forbidden E 13 I Seed cake with not more than 1.5 percent oil and not more than 11 percent moisture 4.2 UN2217 III None IB8, IP3, IP7, N7 None 213 241 Forbidden Forbidden A 13 Selenates or Selenites 6.1 UN2630 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg E Selenic acid 8 UN1905 I 8 IB7, IP1, N34, T6, TP33 None 211 242 Forbidden 25 kg A Selenium compound, solid, n.o.s. 6.1 UN3283 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B Selenium compound, liquid, n.o.s. 6.1 UN3440 I 6.1 T14, TP2, TP27 None 201 243 1 L 30 L B Selenium compound, solid, n.o.s. 6.1 UN3283 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B Selenium compound, liquid, n.o.s. 6.1 UN3440 II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L B Selenium compound, solid, n.o.s. 6.1 UN3283 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Selenium compound, liquid, n.o.s. 6.1 UN3440 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A Selenium disulfide 6.1 UN2657 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Selenium hexafluoride 2.3 UN2194 2.3, 8 1 None 302 None Forbidden Forbidden D 40 Selenium nitride Forbidden Selenium oxychloride 8 UN2879 I 8, 6.1 A3, A6, A7, N34, T10, TP2, TP12, TP13 None 201 243 0.5 L 2.5 L E 40 Self-defense spray, aerosol, see Aerosols, etc Start Printed Page 76134 + A D Self-defense spray, non-pressurized 9 NA3334 III 9 A37 155 203 None No limit No limit A G Self-heating liquid, corrosive, inorganic, n.o.s. 4.2 UN3188 II 4.2, 8 IB2 None 202 243 1 L 5 L C III 4.2, 8 IB2 None 203 241 5 L 60 L C G Self-heating liquid, corrosive, organic, n.o.s. 4.2 UN3185 II 4.2, 8 IB2 None 202 243 1 L 5 L C III 4.2, 8 IB2 None 203 241 5 L 60 L C G Self-heating liquid, inorganic, n.o.s. 4.2 UN3186 II 4.2 IB2 None 202 242 1 L 5 L C III 4.2 IB2 None 203 241 5 L 60 L C G Self-heating liquid, organic, n.o.s. 4.2 UN3183 II 4.2 IB2 None 202 242 1 L 5 L C III 4.2 IB2 None 203 241 5 L 60 L C G Self-heating liquid, toxic, inorganic, n.o.s. 4.2 UN3187 II 4.2, 6.1 IB2 None 202 243 1 L 5 L C III 4.2, 6.1 IB2 None 203 241 5 L 60 L C G Self-heating liquid, toxic, organic, n.o.s. 4.2 UN3184 II 4.2, 6.1 IB2 None 202 243 1 L 5 L C III 4.2, 6.1 IB2 None 203 241 5 L 60 L C G Self-heating solid, corrosive, inorganic, n.o.s. 4.2 UN3192 II 4.2, 8 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C III 4.2, 8 IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg C G Self-heating, solid, corrosive, organic, n.o.s. 4.2 UN3126 II 4.2, 8 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C III 4.2, 8 IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg C G Self-heating solid, inorganic, n.o.s. 4.2 UN3190 II 4.2 IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg C III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg C G Self-heating, solid, organic, n.o.s. 4.2 UN3088 II 4.2 IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg C III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg C G Self-heating, solid, oxidizing, n.o.s. 4.2 UN3127 4.2, 5.1 None 214 214 Forbidden Forbidden G Self-heating solid, toxic, inorganic, n.o.s. 4.2 UN3191 II 4.2, 6.1 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C III 4.2, 6.1 IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg C G Self-heating, solid, toxic, organic, n.o.s. 4.2 UN3128 II 4.2, 6.1 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg C III 4.2, 6.1 IB8, IP3, T1, TP33 None 213 242 25 kg 100 kg C Self-propelled vehicle, see Engines or Batteries etc G Self-reactive liquid type B 4.1 UN3221 II 4.1 53 None 224 None Forbidden Forbidden D 52, 53 G Self-reactive liquid type B, temperature controlled 4.1 UN3231 II 4.1 53 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive liquid type C 4.1 UN3223 II 4.1 None 224 None 5 L 10 L D 52, 53 G Self-reactive liquid type C, temperature controlled 4.1 UN3233 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive liquid type D 4.1 UN3225 II 4.1 None 224 None 5 L 10 L D 52, 53 G Self-reactive liquid type D, temperature controlled 4.1 UN3235 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive liquid type E 4.1 UN3227 II 4.1 None 224 None 10 L 25 L D 52, 53 G Self-reactive liquid type E, temperature controlled 4.1 UN3237 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive liquid type F 4.1 UN3229 II 4.1 T23 None 224 None 10 L 25 L D 52, 53 G Self-reactive liquid type F, temperature controlled 4.1 UN3239 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive solid type B 4.1 UN3222 II 4.1 53 None 224 None Forbidden Forbidden D 52, 53 G Self-reactive solid type B, temperature controlled 4.1 UN3232 II 4.1 53 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive solid type C 4.1 UN3224 II 4.1 None 224 None 5 kg 10 kg D 52, 53 G Self-reactive solid type C, temperature controlled 4.1 UN3234 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 Start Printed Page 76135 G Self-reactive solid type D 4.1 UN3226 II 4.1 None 224 None 5 kg 10 kg D 52, 53 G Self-reactive solid type D, temperature controlled 4.1 UN3236 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive solid type E 4.1 UN3228 II 4.1 None 224 None 10 kg 25 kg D 52, 53 G Self-reactive solid type E, temperature controlled 4.1 UN3238 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 G Self-reactive solid type F 4.1 UN3230 II 4.1 None 224 None 10 kg 25 kg D 52, 53 G Self-reactive solid type F, temperature controlled 4.1 UN3240 II 4.1 None 224 None Forbidden Forbidden D 2, 52, 53 Shale oil 3 UN1288 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L B II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Shaped charges, see Charges, shaped, etc Signal devices, hand 1.4G UN0191 II 1.4G None 62 None Forbidden 75 kg 06 Signal devices, hand 1.4S UN0373 II 1.4S None 62 None 25 kg 100 kg 05 Signals, distress, ship 1.1G UN0194 II 1.1G None 62 None Forbidden Forbidden 07 Signals, distress, ship 1.3G UN0195 II 1.3G None 62 None Forbidden 75 kg 07 Signals, highway, see Signal devices, hand Signals, railway track, explosive 1.1G UN0192 II 1.1G None 62 None Forbidden Forbidden 07 Signals, railway track, explosive 1.4S UN0193 II 1.4S None 62 None 25 kg 100 kg 05 Signals, railway track, explosive 1.3G UN0492 1.3G None 62 None Forbidden Forbidden 07 Signals, railway track, explosive 1.4G UN0493 1.4G None 62 None Forbidden 75 kg 06 Signals, ship distress, water-activated, see Contrivances, water-activated, etc Signals, smoke 1.1G UN0196 II 1.1G None 62 None Forbidden Forbidden 07 Signals, smoke 1.4G UN0197 II 1.4G None 62 None Forbidden 75 kg 06 Signals, smoke 1.2G UN0313 II 1.2G None 62 None Forbidden Forbidden 07 Signals, smoke 1.3G UN0487 II 1.3G None 62 None Forbidden Forbidden 07 Silane 2.1 UN2203 2.1 None 302 None Forbidden Forbidden E 40, 57, 104 Silicofluoric acid, see Fluorosilicic acid Silicon chloride, see Silicon tetrachloride Silicon powder, amorphous 4.1 UN1346 III 4.1 A1, IB8, IP3, T1, TP33 None 213 240 25 kg 100 kg A 74 Silicon tetrachloride 8 UN1818 II 8 A3, A6, B2, B6, IB2, T7, TP2, TP7 154 202 242 1 L 30 L C 40 Silicon tetrafluoride 2.3 UN1859 2.3, 8 2 None 302 None Forbidden Forbidden D 40 Silver acetylide (dry) Forbidden Silver arsenite 6.1 UN1683 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Silver azide (dry) Forbidden Silver chlorite (dry) Forbidden Silver cyanide 6.1 UN1684 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40, 52 Silver fulminate (dry) Forbidden Silver nitrate 5.1 UN1493 II 5.1 IB8, IP4, T3, TP33 152 212 242 5 kg 25 kg A Silver oxalate (dry) Forbidden Silver picrate (dry) Forbidden Silver picrate, wetted with not less than 30 percent water, by mass 4.1 UN1347 I 4.1 23 None 211 None Forbidden Forbidden D 28, 36 Sludge, acid 8 UN1906 II 8 A3, A7, B2, IB2, N34, T8, TP2, TP12, TP28 None 202 242 Forbidden 30 L C 14 D Smokeless powder for small arms (100 pounds or less) 4.1 NA3178 I 4.1 16 None 171 None Forbidden 7.3 kg A Soda lime with more than 4 percent sodium hydroxide 8 UN1907 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Sodium 4.3 UN1428 I 4.3 A7, A8, A19, A20, B9, B48, B68, IB4, IP1, N34, T9, TP7, TP33, TP46 None 211 244 Forbidden 15 kg D 52 Sodium aluminate, solid 8 UN2812 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Sodium aluminate, solution 8 UN1819 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Sodium aluminum hydride 4.3 UN2835 II 4.3 A8, A19, A20, IB4, T3, TP33 151 212 242 Forbidden 50 kg E 52 Sodium ammonium vanadate 6.1 UN2863 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Sodium arsanilate 6.1 UN2473 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Sodium arsenate 6.1 UN1685 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Start Printed Page 76136 Sodium arsenite, aqueous solutions 6.1 UN1686 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A III 6.1 IB3, T4, TP2 153 203 241 60 L 220 L A Sodium arsenite, solid 6.1 UN2027 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Sodium azide 6.1 UN1687 II 6.1 IB8, IP2, IP4 153 212 242 25 kg 100 kg A 36, 52, 91 Sodium bifluoride, see Sodium hydrogendifluoride Sodium bisulfite, solution, see Bisulfites, aqueous solutions, n.o.s. Sodium borohydride 4.3 UN1426 I 4.3 N40 None 211 242 Forbidden 15 kg E 52 Sodium borohydride and sodium hydroxide solution, with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass 8 UN3320 II 8 B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L A 52 III 8 B2, IB3, N34, T4, TP2 154 203 241 5 L 60 L A 52 Sodium bromate 5.1 UN1494 II 5.1 IB8, IP4, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Sodium cacodylate 6.1 UN1688 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 52 Sodium carbonate peroxyhydrate 5.1 UN3378 II 5.1 IB8, IP2, IP4, T3, TP33 152 212 240 5 kg 25 kg A 13, 48, 75 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 13, 48, 75 Sodium chlorate 5.1 UN1495 II 5.1 A9, IB8, IP4, N34, T3, TP33 152 212 240 5 kg 25 kg A 56, 58 Sodium chlorate, aqueous solution 5.1 UN2428 II 5.1 A2, IB2, T4, TP1 152 202 241 1 L 5 L B 56, 58, 133 III 5.1 A2, IB2, T4, TP1 152 203 241 2.5 L 30 L B 56, 58, 69, 133 Sodium chlorate mixed with dinitrotoluene, see Explosive blasting, type C Sodium chlorite 5.1 UN1496 II 5.1 A9, IB8, IP2, IP4, N34, T3, TP33 None 212 242 5 kg 25 kg A 56, 58 Sodium chloroacetate 6.1 UN2659 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Sodium cuprocyanide, solid 6.1 UN2316 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 52 Sodium cuprocyanide, solution 6.1 UN2317 I 6.1 T14, TP2, TP13 None 201 243 1 L 30 L B 40, 52 Sodium cyanide, solid 6.1 UN1689 I 6.1 B69, B77, IB7, N74, N75, T6, TP33 None 211 242 5 kg 50 kg B 52 Sodium cyanide solution 6.1 UN3414 I 6.1 B69, B77, N74, N75, T14, TP2, TP13 None 201 243 1 L 30 L B 52 II 6.1 B69, B77, IB2, N74, N75, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 52 III 6.1 B69, B77, IB3, N74, N75, T7, TP2, TP13, TP28 153 203 241 60 L 220 L A 52 Sodium dichloroisocyanurate or Sodium dichloro-s-triazinetrione, see Dichloroisocyanuric acid etc Sodium dinitro-o-cresolate, dry or wetted with less than 15 percent water, by mass 1.3C UN0234 II 1.3C None 62 None Forbidden Forbidden 10 5E Sodium dinitro-o-cresolate, wetted with not less than 10% water, by mass 4.1 UN3369 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Sodium dinitro-o-cresolate, wetted with not less than 15 percent water, by mass 4.1 UN1348 I 4.1, 6.1 23, A8, A19, A20, N41 None 211 None 1 kg 15 kg E 28, 36 Sodium dithionite or Sodium hydrosulfite 4.2 UN1384 II 4.2 A19, A20, IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg E 13 Sodium fluoride, solid 6.1 UN1690 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Sodium fluoride solution 6.1 UN3415 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 52 Sodium fluoroacetate 6.1 UN2629 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg E Sodium fluorosilicate 6.1 UN2674 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Sodium hydrate, see Sodium hydroxide, solid Sodium hydride 4.3 UN1427 I 4.3 A19, N40 None 211 242 Forbidden 15 kg E 52 Start Printed Page 76137 Sodium hydrogendifluoride 8 UN2439 II 8 IB8, IP2, IP4, N3, N34, T3, TP33 154 212 240 15 kg 50 kg A 12, 25, 40, 52 Sodium hydrosulfide, with less than 25 percent water of crystallization 4.2 UN2318 II 4.2 A7, A19, A20, IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg A Sodium hydrosulfide with not less than 25 percent water of crystallization 8 UN2949 II 8 A7, IB8, IP2, IP4, T7, TP2 154 212 240 15 kg 50 kg A 52 Sodium hydrosulfite, see Sodium dithionite Sodium hydroxide, solid 8 UN1823 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Sodium hydroxide solution 8 UN1824 II 8 B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L A III 8 IB3, N34, T4, TP1 154 203 241 5 L 60 L A Sodium hypochlorite, solution, see Hypochlorite solutions etc Sodium metal, liquid alloy, see Alkali metal alloys, liquid, n.o.s. Sodium methylate 4.2 UN1431 II 4.2, 8 A7, A19, IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg B Sodium methylate solutions in alcohol 3 UN1289 II 3, 8 IB2, T7, TP1, TP8 150 202 243 1 L 5 L B III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A Sodium monoxide 8 UN1825 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A Sodium nitrate 5.1 UN1498 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Sodium nitrate and potassium nitrate mixtures 5.1 UN1499 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Sodium nitrite 5.1 UN1500 III 5.1, 6.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Sodium pentachlorophenate 6.1 UN2567 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Sodium perborate monohydrate 5.1 UN3377 III 5.1 IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 13, 48, 75 Sodium perchlorate 5.1 UN1502 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Sodium permanganate 5.1 UN1503 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D 56, 58, 138 Sodium peroxide 5.1 UN1504 I 5.1 A20, IB5, IP1, N34 None 211 None Forbidden 15 kg B 13, 52, 66, 75 Sodium peroxoborate, anhydrous 5.1 UN3247 II 5.1 IB8, IP4, T3, TP33 152 212 240 5 kg 25 kg A 13, 25 Sodium persulfate 5.1 UN1505 III 5.1 A1, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Sodium phosphide 4.3 UN1432 I 4.3, 6.1 A19, N40 None 211 None Forbidden 15 kg E 40, 52, 85 Sodium picramate, dry or wetted with less than 20 percent water, by mass 1.3C UN0235 II 1.3C None 62 None Forbidden Forbidden 10 5E Sodium picramate, wetted with not less than 20 percent water, by mass 4.1 UN1349 I 4.1 23, A8, A19, N41 None 211 None Forbidden 15 kg E 28, 36 Sodium picryl peroxide Forbidden Sodium potassium alloys, see Potassium sodium alloys Sodium selenate, see Selenates or Selenites Sodium sulfide, anhydrous or Sodium sulfide with less than 30 percent water of crystallization 4.2 UN1385 II 4.2 A19, A20, IB6, IP2, N34, T3, TP33 None 212 241 15 kg 50 kg A 52 Sodium sulfide, hydrated with not less than 30 percent water 8 UN1849 II 8 IB8, IP2, IP4, T3, TP33 154 212 240 15 kg 50 kg A 26 Sodium superoxide 5.1 UN2547 I 5.1 A20, IB6, IP1, N34 None 211 None Forbidden 15 kg E 13, 52, 66, 75 Sodium tetranitride Forbidden G Solids containing corrosive liquid, n.o.s. 8 UN3244 II 8 49, IB5, T3, TP33 154 212 240 15 kg 50 kg B 40 G Solids containing flammable liquid, n.o.s. 4.1 UN3175 II 4.1 47, IB6, IP2, T3, TP33 151 212 240 15 kg 50 kg B G Solids containing toxic liquid, n.o.s. 6.1 UN3243 II 6.1 48, IB2, T2, TP33 153 212 240 25 kg 100 kg B 40 Sounding devices, explosive 1.2F UN0204 II 1.2F None 62 None Forbidden Forbidden 08 Sounding devices, explosive 1.1F UN0296 II 1.1F None 62 None Forbidden Forbidden 08 Sounding devices, explosive 1.1D UN0374 II 1.1D None 62 None Forbidden Forbidden 07 Sounding devices, explosive 1.2D UN0375 II 1.2D None 62 None Forbidden Forbidden 07 Spirits of salt, see Hydrochloric acid Squibs, see Igniters etc Stannic chloride, anhydrous 8 UN1827 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L C Stannic chloride pentahydrate 8 UN2440 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A Start Printed Page 76138 Stannic phosphide 4.3 UN1433 I 4.3, 6.1 A19, N40 None 211 242 Forbidden 15 kg E 40, 52, 85 Steel swarf, see Ferrous metal borings, etc Stibine 2.3 UN2676 2.3, 2.1 1 None 304 None Forbidden Forbidden D 40 Storage batteries, wet, see Batteries, wet etc Strontium arsenite 6.1 UN1691 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Strontium chlorate 5.1 UN1506 II 5.1 A1, A9, IB8, IP2, IP4, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Strontium nitrate 5.1 UN1507 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Strontium perchlorate 5.1 UN1508 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Strontium peroxide 5.1 UN1509 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 66, 75 Strontium phosphide 4.3 UN2013 I 4.3, 6.1 A19, N40 None 211 None Forbidden 15 kg E 40, 52, 85 Strychnine or Strychnine salts 6.1 UN1692 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 Styphnic acid, see Trinitroresorcinol, etc Styrene monomer, stabilized 3 UN2055 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A G Substances, explosive, n.o.s. 1.1L UN0357 II 1.1L 101 None 62 None Forbidden Forbidden 8E, 14E, 15E, 17E G Substances, explosive, n.o.s. 1.2L UN0358 II 1.2L 101 None 62 None Forbidden Forbidden 8E, 14E, 15E, 17E G Substances, explosive, n.o.s. 1.3L UN0359 II 1.3L 101 None 62 None Forbidden Forbidden 8E, 14E, 15E, 17E G Substances, explosive, n.o.s. 1.1A UN0473 II 1.1A 101, 111 None 62 None Forbidden Forbidden 12 G Substances, explosive, n.o.s. 1.1C UN0474 II 1.1C 101 None 62 None Forbidden Forbidden 10 G Substances, explosive, n.o.s. 1.1D UN0475 II 1.1D 101 None 62 None Forbidden Forbidden 10 G Substances, explosive, n.o.s. 1.1G UN0476 II 1.1G 101 None 62 None Forbidden Forbidden 08 G Substances, explosive, n.o.s. 1.3C UN0477 II 1.3C 101 None 62 None Forbidden Forbidden 10 G Substances, explosive, n.o.s. 1.3G UN0478 II 1.3G 101 None 62 None Forbidden Forbidden 08 G Substances, explosive, n.o.s. 1.4C UN0479 II 1.4C 101 None 62 None Forbidden 75 kg 09 G Substances, explosive, n.o.s. 1.4D UN0480 II 1.4D 101 None 62 None Forbidden 75 kg 09 G Substances, explosive, n.o.s. 1.4S UN0481 II 1.4S 101 None 62 None 25 kg 75 kg 05 G Substances, explosive, n.o.s. 1.4G UN0485 II 1.4G 101 None 62 None Forbidden 75 kg 08 G Substances, explosive, very insensitive, n.o.s., or Substances, EVI, n.o.s. 1.5D UN0482 II 1.5D 101 None 62 None Forbidden Forbidden 10 Substituted nitrophenol pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2780 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Substituted nitrophenol pesticides, liquid, toxic 6.1 UN3014 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Substituted nitrophenol pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3013 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 B1, IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Substituted nitrophenol pesticides, solid, toxic 6.1 UN2779 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 Start Printed Page 76139 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Sucrose octanitrate (dry) Forbidden Sulfamic acid 8 UN2967 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A D Sulfur 9 NA1350 III 9 10, IB8, IP2 None None 240 No limit No limit A 19, 74 I Sulfur 4.1 UN1350 III 4.1 30, IB8, IP3, T1, TP33 None None 240 No limit No limit A 19, 74 Sulfur and chlorate, loose mixtures of Forbidden Sulfur chlorides 8 UN1828 I 8 5, A3, A7, A10, B10, B77, N34, T20, TP2, TP12 None 201 243 Forbidden 2.5 L C 40 Sulfur dichloride, see Sulfur chlorides Sulfur dioxide 2.3 UN1079 2.3, 8 3, B14, T50, TP19 None 304 314, 315 Forbidden Forbidden D 40 Sulfur dioxide solution, see Sulfurous acid Sulfur hexafluoride 2.2 UN1080 2.2 306 304 314, 315 75 kg 150 kg A D Sulfur, molten 9 NA2448 III 9 30, IB3, T1, TP3 None 213 247 Forbidden Forbidden C 61 I Sulfur, molten 4.1 UN2448 III 4.1 30, IB1, T1, TP3 None 213 247 Forbidden Forbidden C 61 Sulfur tetrafluoride 2.3 UN2418 2.3, 8 1 None 302 245 Forbidden Forbidden D 40, 52 + Sulfur trioxide, stabilized 8 UN1829 I 8, 6.1 2, B9, B14, B32, B49, B74, B77, N34, T20, TP4, TP12, TP13, TP25, TP26, TP38, TP45 None 227 244 Forbidden Forbidden A 40 Sulfuretted hydrogen, see Hydrogen sulfide Sulfuric acid, fuming with less than 30 percent free sulfur trioxide 8 UN1831 I 8 B84, N34, T20, TP2, TP12, TP13 None 201 243 Forbidden 2.5 L C 14, 40 + Sulfuric acid, fuming with 30 percent or more free sulfur trioxide 8 UN1831 I 8, 6.1 2, A3, A6, A7, B9, B14, B32, B74, B77, B84, N34, T20, TP2, TP12, TP13 None 227 244 Forbidden Forbidden C 14, 40 Sulfuric acid, spent 8 UN1832 II 8 A3, A7, B2, B83, B84, IB2, N34, T8, TP2, TP12 None 202 242 Forbidden 30 L C 14 Sulfuric acid with more than 51 percent acid 8 UN1830 II 8 A3, A7, B3, B83, B84, IB2, N34, T8, TP2, TP12 154 202 242 1 L 30 L C 14 Sulfuric acid with not more than 51% acid 8 UN2796 II 8 A3, A7, B2, B15, IB2, N6, N34, T8, TP2, TP12 154 202 242 1 L 30 L B Sulfuric and hydrofluoric acid mixtures, see Hydrofluoric and sulfuric acid mixtures Sulfuric anhydride, see Sulfur trioxide, stabilized Sulfurous acid 8 UN1833 II 8 B3, IB2, T7, TP2 154 202 242 1 L 30 L B 40 + Sulfuryl chloride 8 UN1834 I 8, 6.1 1, B6, B9, B10, B14, B30, B74, B77, N34, T22, TP2, TP12, TP38, TP44 None 226 244 Forbidden Forbidden C 40 Sulfuryl fluoride 2.3 UN2191 2.3 4 None 304 314, 315 Forbidden Forbidden D 40 Tars, liquid including road asphalt and oils, bitumen and cut backs 3 UN1999 II 3 149, B13, IB2, T3, TP3, TP29 150 202 242 5 L 60 L B III 3 B1, B13, IB3, T1, TP3 150 203 242 60 L 220 L A Tear gas candles 6.1 UN1700 II 6.1, 4.1 None 340 None Forbidden 50 kg D 40 Tear gas cartridges, see Ammunition, tear-producing, etc D Tear gas devices with more than 2 percent tear gas substances, by mass 6.1 NA1693 I 6.1 None 340 None Forbidden Forbidden D 40 II 6.1 None 340 None Forbidden Forbidden D 40 Tear gas devices, with not more than 2 percent tear gas substances, by mass, see Aerosols, etc Tear gas grenades, see Tear gas candles G Tear gas substances, liquid, n.o.s. 6.1 UN1693 I 6.1 None 201 None Forbidden Forbidden D 40 II 6.1 IB2 None 202 None Forbidden 5 L D 40 G Tear gas substance, solid, n.o.s. 6.1 UN3448 I 6.1 T6, TP33 None 211 242 Forbidden Forbidden D 40 II 6.1 IB8, IP2, IP4, T3, TP33 None 212 242 Forbidden 25 kg D 40 Tellurium compound, n.o.s. 6.1 UN3284 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B Start Printed Page 76140 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Tellurium hexafluoride 2.3 UN2195 2.3, 8 1 None 302 None Forbidden Forbidden D 40 Terpene hydrocarbons, n.o.s. 3 UN2319 III 3 B1, IB3, T4, TP1, TP29 150 203 242 60 L 220 L A Terpinolene 3 UN2541 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Tetraazido benzene quinone Forbidden Tetrabromoethane 6.1 UN2504 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A 1,1,2,2-Tetrachloroethane 6.1 UN1702 II 6.1 IB2, N36, T7, TP2 153 202 243 5 L 60 L A 40 Tetrachloroethylene 6.1 UN1897 III 6.1 IB3, N36, T4, TP1 153 203 241 60 L 220 L A 40 Tetraethyl dithiopyrophosphate 6.1 UN1704 II 6.1 IB2, T7, TP2 153 212 242 25 kg 100 kg D 40 Tetraethyl silicate 3 UN1292 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Tetraethylammonium perchlorate (dry) Forbidden Tetraethylenepentamine 8 UN2320 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A 1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a 2.2 UN3159 2.2 T50 306 304 314, 315 75 kg 150 kg A Tetrafluoroethylene, stabilized 2.1 UN1081 2.1 306 304 None Forbidden 150 kg E 40 Tetrafluoromethane or Refrigerant gas R 14 2.2 UN1982 2.2 None 302 None 75 kg 150 kg A 1,2,3,6-Tetrahydrobenzaldehyde 3 UN2498 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Tetrahydrofuran 3 UN2056 II 3 IB2, T4, TP1 None 202 242 5 L 60 L B Tetrahydrofurfurylamine 3 UN2943 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Tetrahydrophthalic anhydrides with more than 0.05 percent of maleic anhydride 8 UN2698 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 1,2,3,6-Tetrahydropyridine 3 UN2410 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Tetrahydrothiophene 3 UN2412 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Tetramethylammonium hydroxide, solid 8 UN3423 II 8 B2, IB8, IP2, IP4, T3, TP33 154 213 240 15 kg 50 kg A 52 Tetramethylammonium hydroxide solution 8 UN1835 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L A 52 III 8 B2, IB3, T7, TP2 154 203 241 5 L 60 L A 52 Tetramethylene diperoxide dicarbamide Forbidden Tetramethylsilane 3 UN2749 I 3 A7, T14, TP2 None 201 243 Forbidden 30 L D Tetranitro diglycerin Forbidden Tetranitroaniline 1.1D UN0207 II 1.1D None 62 None Forbidden Forbidden 10 + Tetranitromethane 5.1 UN1510 I 5.1, 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP44 None 227 None Forbidden Forbidden D 40, 66 2,3,4,6-Tetranitrophenol Forbidden 2,3,4,6-Tetranitrophenyl methyl nitramine Forbidden 2,3,4,6-Tetranitrophenylnitramine Forbidden Tetranitroresorcinol (dry) Forbidden 2,3,5,6-Tetranitroso-1,4-dinitrobenzene Forbidden 2,3,5,6-Tetranitroso nitrobenzene (dry) Forbidden Tetrapropylorthotitanate 3 UN2413 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A Tetrazene, see Guanyl nitrosaminoguanyltetrazene Tetrazine (dry) Forbidden Tetrazol-1-acetic acid 1.4C UN0407 II 1.4C None 62 None Forbidden 75 kg 09 1H-Tetrazole 1.1D UN0504 1.1D None 62 None Forbidden Forbidden B 1E, 5E Tetrazolyl azide (dry) Forbidden Tetryl, see Trinitrophenylmethylnitramine A I W Textile waste, wet 4.2 UN1857 III 4.2 151 213 240 Forbidden Forbidden A Thallium chlorate 5.1 UN2573 II 5.1, 6.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Thallium compounds, n.o.s. 6.1 UN1707 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Thallium nitrate 6.1 UN2727 II 6.1, 5.1 IB6, IP2, T3, TP33 153 212 242 5 kg 25 kg A 4-Thiapentanal 6.1 UN2785 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L D 25, 49 Thioacetic acid 3 UN2436 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Thiocarbamate pesticide, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2772 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 Start Printed Page 76141 II 3, 6.1 IB2, T11, TP13, TP27 150 202 243 1 L 60 L B 40 Thiocarbamate pesticide, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN3005 I 6.1, 3 T14, TP2, TP13 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Thiocarbamate pesticide, liquid, toxic 6.1 UN3006 I 6.1 T14, TP2, TP13 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Thiocarbamate pesticides, solid, toxic 6.1 UN2771 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Thiocarbonylchloride, see Thiophosgene Thioglycol 6.1 UN2966 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Thioglycolic acid 8 UN1940 II 8 A7, B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L A Thiolactic acid 6.1 UN2936 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Thionyl chloride 8 UN1836 I 8 B6, B10, N34, T10, TP2, TP12, TP13 None 201 243 Forbidden Forbidden C 40 Thiophene 3 UN2414 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B 40 + Thiophosgene 6.1 UN2474 II 6.1 2, B9, B14, B32, B74, N33, N34, T20, TP2, TP38, TP45 None 227 244 Forbidden Forbidden B 40, 52 Thiophosphoryl chloride 8 UN1837 II 8 A3, A7, B2, B8, B25, IB2, N34, T7, TP2 None 202 242 Forbidden 30 L C 40 Thiourea dioxide 4.2 UN3341 II 4.2 IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg D III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg D Tin chloride, fuming, see Stannic chloride, anhydrous Tin perchloride or Tin tetrachloride, see Stannic chloride, anhydrous Tinctures, medicinal 3 UN1293 II 3 IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Tinning flux, see Zinc chloride Titanium disulphide 4.2 UN3174 III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg A Titanium hydride 4.1 UN1871 II 4.1 A19, A20, IB4, N34, T3, TP33 None 212 241 15 kg 50 kg E Titanium powder, dry 4.2 UN2546 I 4.2 None 211 242 Forbidden Forbidden D II 4.2 A19, A20, IB6, IP2, N5, N34, T3, TP33 None 212 241 15 kg 50 kg D III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg D Titanium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns 4.1 UN1352 II 4.1 A19, A20, IB6, IP2, N34, T3, TP33 None 212 240 15 kg 50 kg E 74 Titanium sponge granules or Titanium sponge powders 4.1 UN2878 III 4.1 A1, IB8, IP3, T1, TP33 None 213 240 25 kg 100 kg D 74 + Titanium tetrachloride 8 UN1838 II 8, 6.1 2, B7, B9, B14, B32, B74, B77, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden C 40 Titanium trichloride mixtures 8 UN2869 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 154 212 240 15 kg 50 kg A 40 III 8 A7, IB8, IP3, N34, T1, TP33 154 213 240 25 kg 100 kg A 40 Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric 4.2 UN2441 I 4.2, 8 N34 None 181 244 Forbidden Forbidden D 40 TNT mixed with aluminum, see Tritonal TNT, see Trinitrotoluene, etc Toluene 3 UN1294 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B + Toluene diisocyanate 6.1 UN2078 II 6.1 IB2, T7, TP2, TP13 153 202 243 5 L 60 L D 25, 40 Toluene sulfonic acid, see Alkyl, or Aryl sulfonic acid etc + Toluidines, liquid 6.1 UN1708 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Start Printed Page 76142 Toluidines, solid 6.1 UN3451 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 2,4-Toluylenediamine, solid or 2,4-Toluenediamine, solid 6.1 UN1709 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 2,4-Toluylenediamine solution or 2,4-Toluenediamine solution 6.1 UN3418 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Torpedoes, liquid fueled, with inert head 1.3J UN0450 II 1.3J 62 None Forbidden Forbidden 04 23E Torpedoes, liquid fueled, with or without bursting charge 1.1J UN0449 II 1.1J 62 None Forbidden Forbidden 04 23E Torpedoes with bursting charge 1.1E UN0329 II 1.1E 62 None Forbidden Forbidden 03 Torpedoes with bursting charge 1.1F UN0330 II 1.1F 62 None Forbidden Forbidden 08 Torpedoes with bursting charge 1.1D UN0451 II 1.1D 62 None Forbidden Forbidden 03 G Toxic by inhalation liquid, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 6.1 UN3381 I 6.1 1, B9, B14, B30, B72, T22, TP2, TP13, TP27, TP38, TP44 None 226 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, n.o.s. with an inhalation toxicity toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 6.1 UN3382 I 6.1 2, B9, B14, B32, B74, T20, TP2, TP13, TP27, TP38, TP4527, TP38, TP4513 None 227 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 6.1 UN3383 I 6.1, 3 1, B9, B14, B30, B72, T22, TP2, TP13, TP27, TP38, TP44 None 226 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, flammable, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 6.1 UN3384 I 6.1, 3 2, B9, B14, B32, B74, T20, TP2, TP13, TP27, TP38, TP45 None 227 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 6.1 UN3385 I 6.1, 4.3 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, water-reactive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 6.1 UN3386 I 6.1, 4.3 2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP44 None 227 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 6.1 UN3387 I 6.1, 5.1 1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44 None 226 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, oxidizing, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 6.1 UN3388 I 6.1, 5.1 2, B9, B14, B32, T20, TP2, TP13, TP38, TP44 None 227 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50 6.1 UN3389 I 6.1, 8 1, B9, B14, B30, B72, T22, TP2, TP13, TP27, TP38, TP44 None 226 244 Forbidden Forbidden D 40 G Toxic by inhalation liquid, corrosive, n.o.s. with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50 6.1 UN3390 I 6.1, 8 2, B9, B14, B32, B74, T20, TP2, TP13, TP27, TP38, TP45 None 227 244 Forbidden Forbidden D 40 G Toxic liquid, corrosive, inorganic, n.o.s. 6.1 UN3289 I 6.1, 8 T14, TP2, TP13, TP27 None 201 243 0.5 L 2.5 L A II 6.1, 8 IB2, T11, TP2, TP27 153 202 243 1 L 30 L A G Toxic liquid, inorganic, n.o.s. 6.1 UN3287 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L A II 6.1 IB2, T11, TP2, TP27 153 202 243 5 L 60 L A III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A G Toxic liquids, corrosive, organic, n.o.s. 6.1 UN2927 I 6.1, 8 T14, TP2, TP13, TP27 None 201 243 0.5 L 2.5 L B 40 II 6.1, 8 IB2, T11, TP2, TP27 153 202 243 1 L 30 L B 40 Start Printed Page 76143 G Toxic liquids, flammable, organic, n.o.s. 6.1 UN2929 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 G Toxic, liquids, organic, n.o.s. 6.1 UN2810 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1 IB3, T7, TP1, TP28 153 203 241 60 L 220 L A 40 G Toxic liquids, oxidizing, n.o.s. 6.1 UN3122 I 6.1, 5.1 A4 None 201 243 Forbidden 2.5 L C II 6.1, 5.1 IB2 153 202 243 1 L 5 L C G Toxic liquids, water-reactive, n.o.s. 6.1 UN3123 I 6.1, 4.3 A4 None 201 243 Forbidden 1 L E 40 II 6.1, 4.3 IB2 None 202 243 1 L 5 L E 40 G Toxic solid, corrosive, inorganic, n.o.s. 6.1 UN3290 I 6.1, 8 IB7, T6, TP33 None 211 242 1 kg 25 kg A II 6.1, 8 IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg A G Toxic solid, inorganic, n.o.s. 6.1 UN3288 I 6.1 IB7, T6, TP33 None 211 242 5 kg 50 kg A II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A G Toxic solids, corrosive, organic, n.o.s. 6.1 UN2928 I 6.1, 8 IB7, T6, TP33 None 211 242 1 kg 25 kg B 40 II 6.1, 8 IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg B 40 G Toxic solids, flammable, organic, n.o.s. 6.1 UN2930 I 6.1, 4.1 IB6, T6, TP33 None 211 242 1 kg 15 kg B II 6.1, 4.1 IB8, IP2, IP4, T3, TP33 153 212 242 15 kg 50 kg B G Toxic solids, organic, n.o.s. 6.1 UN2811 I 6.1 IB7, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A G Toxic solids, oxidizing, n.o.s. 6.1 UN3086 I 6.1, 5.1 T6, TP33 None 211 242 1 kg 15 kg C II 6.1, 5.1 IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg C G Toxic solids, self-heating, n.o.s. 6.1 UN3124 I 6.1, 4.2 A5, T6, TP33 None 211 242 5 kg 15 kg D 40 II 6.1, 4.2 IB6, IP2, T3, TP33 None 212 242 15 kg 50 kg D 40 G Toxic solids, water-reactive, n.o.s. 6.1 UN3125 I 6.1, 4.3 A5, T6, TP33 None 211 242 5 kg 15 kg D 40 II 6.1, 4.3 IB6, IP2, T3, TP33 153 212 242 15 kg 50 kg D 40 G Toxins, extracted from living sources, liquid, n.o.s. 6.1 UN3172 I 6.1 141 None 201 243 1 L 30 L B 40 II 6.1 141, IB2 None 202 243 5 L 60 L B 40 III 6.1 141, IB3 153 203 241 60 L 220 L B 40 Toxins, extracted from living sources, solid, n.o.s. 6.1 UN3462 I 6.1 141, IB7, IP1, T6, TP33 None 211 243 5 kg 50 kg B II 6.1 141, IB8, IP2, IP4, T3, TP33 None 212 243 25 kg 100 kg B III 6.1 141, IB8, IP3, T1, TP33 153 213 241 100 kg 200 kg A D Toy Caps 1.4S NA0337 II 1.4S None 62 None 25 kg 100 kg 05 Tracers for ammunition 1.3G UN0212 II 1.3G None 62 None Forbidden Forbidden 07 Tracers for ammunition 1.4G UN0306 II 1.4G None 62 None Forbidden 75 kg 06 Tractors, see Vehicle, etc Tri-(b-nitroxyethyl) ammonium nitrate Forbidden Triallyl borate 6.1 UN2609 III 6.1 IB3 153 203 241 60 L 220 L A 13 Triallylamine 3 UN2610 III 3, 8 B1, IB3, T4, TP1 None 203 242 5 L 60 L A 40 Triazine pesticides, liquid, flammable, toxic, flash point less than 23 degrees C 3 UN2764 I 3, 6.1 T14, TP2, TP13, TP27 None 201 243 Forbidden 30 L B 40 II 3, 6.1 IB2, T11, TP2, TP13, TP27 150 202 243 1 L 60 L B 40 Triazine pesticides, liquid, toxic 6.1 UN2998 I 6.1 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 Start Printed Page 76144 III 6.1 IB3, T7, TP2, TP28 153 203 241 60 L 220 L A 40 Triazine pesticides, liquid, toxic, flammable, flash point not less than 23 degrees C 6.1 UN2997 I 6.1, 3 T14, TP2, TP13, TP27 None 201 243 1 L 30 L B 40 II 6.1, 3 IB2, T11, TP2, TP13, TP27 153 202 243 5 L 60 L B 40 III 6.1, 3 IB3, T7, TP2, TP28 153 203 242 60 L 220 L A 40 Triazine pesticides, solid, toxic 6.1 UN2763 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 40 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A 40 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Tributylamine 6.1 UN2542 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Tributylphosphane 4.2 UN3254 I 4.2 T21, TP7, TP33 None 211 242 Forbidden Forbidden D 136 Trichloro-s-triazinetrione dry, with more than 39 percent available chlorine, see Trichloroisocyanuric acid, dry Trichloroacetic acid 8 UN1839 II 8 A7, IB8, IP2, IP4, N34, T3, TP33 154 212 240 15 kg 50 kg A Trichloroacetic acid, solution 8 UN2564 II 8 A3, A6, A7, B2, IB2, N34, T7, TP2 154 202 242 1 L 30 L B III 8 A3, A6, A7, IB3, N34, T4, TP1 154 203 241 5 L 60 L B 8 + Trichloroacetyl chloride 8 UN2442 II 8, 6.1 2, B9, B14, B32, B74, N34, T20, TP2, TP38, TP45 None 227 244 Forbidden Forbidden D 40 Trichlorobenzenes, liquid 6.1 UN2321 III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Trichlorobutene 6.1 UN2322 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 25, 40 1,1,1-Trichloroethane 6.1 UN2831 III 6.1 IB3, N36, T4, TP1 153 203 241 60 L 220 L A 40 Trichloroethylene 6.1 UN1710 III 6.1 IB3, N36, T4, TP1 153 203 241 60 L 220 L A 40 Trichloroisocyanuric acid, dry 5.1 UN2468 II 5.1 IB8, IP4, T3, TP33 152 212 240 5 kg 25 kg A 13 Trichloromethyl perchlorate Forbidden Trichlorosilane 4.3 UN1295 I 4.3, 3, 8 N34, T14, TP2, TP7, TP13 None 201 244 Forbidden Forbidden D 21, 28, 40, 49, 100 Tricresyl phosphate with more than 3 percent ortho isomer 6.1 UN2574 II 6.1 A3, IB2, N33, N34, T7, TP2 153 202 243 5 L 60 L A Triethyl phosphite 3 UN2323 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Triethylamine 3 UN1296 II 3, 8 IB2, T7, TP1 150 202 243 1 L 5 L B 40 Triethylenetetramine 8 UN2259 II 8 B2, IB2, T7, TP2 154 202 242 1 L 30 L B 40, 52 Trifluoroacetic acid 8 UN2699 I 8 A3, A6, A7, B4, N3, N34, N36, T10, TP2, TP12 None 201 243 0.5 L 2.5 L B 12, 40 Trifluoroacetyl chloride 2.3 UN3057 2.3, 8 2, B7, B9, B14, T50, TP21 None 304 314, 315 Forbidden Forbidden D 40 Trifluorochloroethylene, stabilized 2.3 UN1082 2.3, 2.1 3, B14, T50 None 304 314, 315 Forbidden Forbidden D 40 Trifluoromethane or Refrigerant gas R 23 2.2 UN1984 2.2 306 304 314, 315 75 kg 150 kg A 1,1,1-Trifluoroethane or Refrigerant gas, R 143a 2.1 UN2035 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Trifluoromethane, refrigerated liquid 2.2 UN3136 2.2 T75, TP5 306 None 314, 315 50 kg 500 kg D 2-Trifluoromethylaniline 6.1 UN2942 III 6.1 IB3 153 203 241 60 L 220 L A 3-Trifluoromethylaniline 6.1 UN2948 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A 40 Triformoxime trinitrate Forbidden Triisobutylene 3 UN2324 III 3 B1, IB3, T4, TP1 150 203 242 60 L 220 L A Triisopropyl borate 3 UN2616 II 3 IB2, T4, TP1 150 202 242 5 L 60 L A III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Start Printed Page 76145 D Trimethoxysilane 6.1 NA9269 I 6.1, 3 2, B9, B14, B32, B74, T20, TP4, TP12, TP13, TP38, TP45 None 227 244 Forbidden Forbidden E 40 Trimethyl borate 3 UN2416 II 3 IB2, T7, TP1 150 202 242 5 L 60 L B Trimethyl phosphite 3 UN2329 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 1,3,5-Trimethyl-2,4,6-trinitrobenzene Forbidden Trimethylacetyl chloride 6.1 UN2438 I 6.1, 8, 3 2, B3, B9, B14, B32, B74, N34, T20, TP2, TP13, TP38, TP45 None 227 244 Forbidden Forbidden D 25, 40 Trimethylamine, anhydrous 2.1 UN1083 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Trimethylamine, aqueous solutions with not more than 50 percent trimethylamine by mass 3 UN1297 I 3, 8 T11, TP1 None 201 243 0.5 L 2.5 L D 40, 135 II 3, 8 B1, IB2, T7, TP1 150 202 243 1 L 5 L B 40, 41 III 3, 8 B1, IB3, T7, TP1 150 203 242 5 L 60 L A 40, 41 1,3,5-Trimethylbenzene 3 UN2325 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Trimethylchlorosilane 3 UN1298 II 3, 8 A3, A7, B77, IB2, N34, T7, TP2, TP13 150 202 243 1 L 5 L E 40 Trimethylcyclohexylamine 8 UN2326 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Trimethylene glycol diperchlorate Forbidden Trimethylhexamethylene diisocyanate 6.1 UN2328 III 6.1 IB3, T4, TP2, TP13 153 203 241 60 L 220 L B Trimethylhexamethylenediamines 8 UN2327 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Trimethylol nitromethane trinitrate Forbidden Trinitro-meta-cresol 1.1D UN0216 II 1.1D None 62 None Forbidden Forbidden 10 5E 2,4,6-Trinitro-1,3-diazobenzene Forbidden 2,4,6-Trinitro-1,3,5-triazido benzene (dry) Forbidden Trinitroacetic acid Forbidden Trinitroacetonitrile Forbidden Trinitroamine cobalt Forbidden Trinitroaniline or Picramide 1.1D UN0153 II 1.1D None 62 None Forbidden Forbidden 10 Trinitroanisole 1.1D UN0213 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrobenzene (picryl chloride), wetted, with not less than 10% water by mass 4.1 UN3365 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Trinitrobenzene, wetted, with not less than 10% water, by mass 4.1 UN3367 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Trinitrobenzene, dry or wetted with less than 30 percent water, by mass 1.1D UN0214 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrobenzene, wetted with not less than 30 percent water, by mass 4.1 UN1354 I 4.1 23, A2, A8, A19, N41 None 211 None 0.5 kg 0.5 kg E 28 Trinitrobenzenesulfonic acid 1.1D UN0386 II 1.1D None 62 None Forbidden Forbidden 10 5E Trinitrobenzoic acid, dry or wetted with less than 30 percent water, by mass 1.1D UN0215 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrobenzoic acid, wetted with not less than 10% water by mass 4.1 UN3368 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Trinitrobenzoic acid, wetted with not less than 30 percent water, by mass 4.1 UN1355 I 4.1 23, A2, A8, A19, N41 None 211 None 0.5 kg 0.5 kg E 28 Trinitrochlorobenzene or Picryl chloride 1.1D UN0155 II 1.1D None 62 None Forbidden Forbidden 10 Trinitroethanol Forbidden Trinitroethylnitrate Forbidden Trinitrofluorenone 1.1D UN0387 II 1.1D None 62 None Forbidden Forbidden 10 Trinitromethane Forbidden 1,3,5-Trinitronaphthalene Forbidden Trinitronaphthalene 1.1D UN0217 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrophenetole 1.1D UN0218 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrophenol (picric acid), wetted, with not less than 10 percent water by mass 4.1 UN3364 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Trinitrophenol or Picric acid, dry or wetted with less than 30 percent water, by mass 1.1D UN0154 II 1.1D None 62 None Forbidden Forbidden 10 5E Trinitrophenol, wetted with not less than 30 percent water, by mass 4.1 UN1344 I 4.1 23, A8, A19, N41 None 211 None 1 kg 15 kg E 28, 36 2,4,6-Trinitrophenyl guanidine (dry) Forbidden 2,4,6-Trinitrophenyl nitramine Forbidden 2,4,6-Trinitrophenyl trimethylol methyl nitramine trinitrate (dry) Forbidden Trinitrophenylmethylnitramine or Tetryl 1.1D UN0208 II 1.1D None 62 None Forbidden Forbidden 10 Trinitroresorcinol or Styphnic acid, dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass 1.1D UN0219 II 1.1D None 62 None Forbidden Forbidden 10 5E Trinitroresorcinol, wetted or Styphnic acid, wetted with not less than 20 percent water, or mixture of alcohol and water by mass 1.1D UN0394 II 1.1D None 62 None Forbidden Forbidden 10 5E 2,4,6-Trinitroso-3-methyl nitraminoanisole Forbidden Trinitrotetramine cobalt nitrate Forbidden Trinitrotoluene and Trinitrobenzene mixtures or TNT and trinitrobenzene mixtures or TNT and hexanitrostilbene mixtures or Trinitrotoluene and hexanitrostilnene mixtures 1.1D UN0388 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrotoluene mixtures containing Trinitrobenzene and Hexanitrostilbene or TNT mixtures containing trinitrobenzene and hexanitrostilbene 1.1D UN0389 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrotoluene or TNT, dry or wetted with less than 30 percent water, by mass 1.1D UN0209 II 1.1D None 62 None Forbidden Forbidden 10 Trinitrotoluene (TNT), wetted, with not less than 10 percent water by mass 4.1 UN3366 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Start Printed Page 76146 Trinitrotoluene, wetted with not less than 30 percent water, by mass 4.1 UN1356 I 4.1 23, A2, A8, A19, N41 None 211 None 0.5 kg 0.5 kg E 28 Tripropylamine 3 UN2260 III 3, 8 B1, IB3, T4, TP1 150 203 242 5 L 60 L A 40 Tripropylene 3 UN2057 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Tris-(1-aziridinyl)phosphine oxide, solution 6.1 UN2501 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A III 6.1 IB3, T4, TP1 153 203 241 60 L 220 L A Tris, bis-bifluoroamino diethoxy propane (TVOPA) Forbidden Tritonal 1.1D UN0390 II 1.1D None 62 None Forbidden Forbidden 10 Tungsten hexafluoride 2.3 UN2196 2.3, 8 2 None 338 None Forbidden Forbidden D 40 Turpentine 3 UN1299 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Turpentine substitute 3 UN1300 I 3 T11, TP1, TP8, TP27 None 201 243 1 L 30 L B II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Undecane 3 UN2330 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Urea hydrogen peroxide 5.1 UN1511 III 5.1, 8 A1, A7, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 13 Urea nitrate, dry or wetted with less than 20 percent water, by mass 1.1D UN0220 II 1.1D 119 None 62 None Forbidden Forbidden 10 Urea nitrate, wetted, with not less than 10 percent water by mass 4.1 UN3370 I 4.1 162, A8, A19, N41, N84 None 211 None 0.5 kg 0.5 kg E 36 Urea nitrate, wetted with not less than 20 percent water, by mass 4.1 UN1357 I 4.1 23, 39, A8, A19, N41 None 211 None 1 kg 15 kg E 28, 36 Urea peroxide, see Urea hydrogen peroxide Valeraldehyde 3 UN2058 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Valeric acid, see Corrosive liquids, n.o.s. Valeryl chloride 8 UN2502 II 8, 3 A3, A6, A7, B2, IB2, N34, T7, TP2 154 202 243 1 L 30 L C 40 Vanadium compound, n.o.s. 6.1 UN3285 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg B II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg B III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A Vanadium oxytrichloride 8 UN2443 II 8 A3, A6, A7, B2, B16, IB2, N34, T7, TP2 154 202 242 Forbidden 30 L C 40 Vanadium pentoxide, non-fused form 6.1 UN2862 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 40 Vanadium tetrachloride 8 UN2444 I 8 A3, A6, A7, B4, N34, T10, TP2 None 201 243 Forbidden 2.5 L C 40 Vanadium trichloride 8 UN2475 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A 40 Vanadyl sulfate 6.1 UN2931 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Vehicle, flammable gas powered 9 UN3166 9 135, 157 220 220 220 Forbidden No limit A Vehicle, flammable liquid powered 9 UN3166 9 135, 157 220 220 220 No limit No limit A Very signal cartridge, see Cartridges, signal Vinyl acetate, stabilized 3 UN1301 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Vinyl bromide, stabilized 2.1 UN1085 2.1 T50 306 304 314, 315 Forbidden 150 kg B 40 Vinyl butyrate, stabilized 3 UN2838 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Vinyl chloride, stabilized 2.1 UN1086 2.1 21, B44, T50 306 304 314, 315 Forbidden 150 kg B 40 Vinyl chloroacetate 6.1 UN2589 II 6.1, 3 IB2, T7, TP2 153 202 243 5 L 60 L A Vinyl ethyl ether, stabilized 3 UN1302 I 3 A3, T11, TP2 None 201 243 1 L 30 L D Vinyl fluoride, stabilized 2.1 UN1860 2.1 306 304 314, 315 Forbidden 150 kg E 40 Vinyl isobutyl ether, stabilized 3 UN1304 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B Vinyl methyl ether, stabilized 2.1 UN1087 2.1 B44, T50 306 304 314, 315 Forbidden 150 kg B 40 Vinyl nitrate polymer Forbidden Vinylidene chloride, stabilized 3 UN1303 I 3 T12, TP2, TP7 150 201 243 1 L 30 L E 40 Start Printed Page 76147 Vinylpyridines, stabilized 6.1 UN3073 II 6.1, 3, 8 IB1, T7, TP2, TP13 153 202 243 1 L 30 L B 40 Vinyltoluenes, stabilized 3 UN2618 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Vinyltrichlorosilane, stabilized 3 UN1305 I 3, 8 A3, A7, B6, N34, T11, TP2, TP13 None 201 243 Forbidden 2.5 L B 40 Warheads, rocket with burster or expelling charge 1.4D UN0370 II 1.4D None 62 None Forbidden 75 kg 02 Warheads, rocket with burster or expelling charge 1.4F UN0371 II 1.4F None 62 None Forbidden Forbidden 08 Warheads, rocket with bursting charge 1.1D UN0286 II 1.1D None 62 None Forbidden Forbidden 03 Warheads, rocket with bursting charge 1.2D UN0287 II 1.2D None 62 None Forbidden Forbidden 03 Warheads, rocket with bursting charge 1.1F UN0369 II 1.1F None 62 None Forbidden Forbidden 08 Warheads, torpedo with bursting charge 1.1D UN0221 II 1.1D None 62 None Forbidden Forbidden 03 G Water-reactive liquid, corrosive, n.o.s. 4.3 UN3129 I 4.3, 8 None 201 243 Forbidden 1 L D II 4.3, 8 IB1 None 202 243 1 L 5 L E 85 III 4.3, 8 IB2 None 203 242 5 L 60 L E G Water-reactive liquid, n.o.s. 4.3 UN3148 I 4.3 None 201 244 Forbidden 1 L E 40 II 4.3 IB1 None 202 243 1 L 5 L E 40 III 4.3 IB2 None 203 242 5 L 60 L E 40 G Water-reactive liquid, toxic, n.o.s. 4.3 UN3130 I 4.3, 6.1 A4 None 201 243 Forbidden 1 L D II 4.3, 6.1 IB1 None 202 243 1 L 5 L E 85 III 4.3, 6.1 IB2 None 203 242 5 L 60 L E 85 G Water-reactive solid, corrosive, n.o.s. 4.3 UN3131 I 4.3, 8 IB4, IP1, N40 None 211 242 Forbidden 15 kg D II 4.3, 8 IB6, IP2, T3, TP33 151 212 242 15 kg 50 kg E 85 III 4.3, 8 IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg E 85 G Water-reactive solid, flammable, n.o.s. 4.3 UN3132 I 4.3, 4.1 IB4, N40 None 211 242 Forbidden 15 kg D II 4.3, 4.1 IB4, T3, TP33 151 212 242 15 kg 50 kg E III 4.3, 4.1 IB6, T1, TP33 151 213 241 25 kg 100 kg E G Water-reactive solid, n.o.s. 4.3 UN2813 I 4.3 IB4, N40 None 211 242 Forbidden 15 kg E 40 II 4.3 IB7, IP2, T3, TP33 151 212 242 15 kg 50 kg E 40 III 4.3 IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg E 40 G Water-reactive, solid, oxidizing, n.o.s. 4.3 UN3133 II 4.3, 5.1 None 214 214 Forbidden Forbidden E 40 III 4.3, 5.1 None 214 214 Forbidden Forbidden E 40 G Water-reactive solid, self-heating, n.o.s. 4.3 UN3135 I 4.3, 4.2 N40 None 211 242 Forbidden 15 kg E II 4.3, 4.2 IB5, IP2, T3, TP33 None 212 242 15 kg 50 kg E III 4.3, 4.2 IB8, IP4, T1, TP33 None 213 241 25 kg 100 kg E G Water-reactive solid, toxic, n.o.s. 4.3 UN3134 I 4.3, 6.1 A8, IB4, IP1, N40 None 211 242 Forbidden 15 kg D II 4.3, 6.1 IB5, IP2, T3, TP33 151 212 242 15 kg 50 kg E 85 III 4.3, 6.1 IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg E 85 Wheel chair, electric, see Battery powered vehicle or Battery powered equipment White acid, see Hydrofluoric acid I White asbestos (chrysotile, actinolite, anthophyllite, tremolite) 9 UN2590 III 9 156, IB8, IP2, IP3, T1, TP33 155 216 240 200 kg 200 kg A 34, 40 Wood preservatives, liquid 3 UN1306 II 3 149, IB2, T4, TP1, TP8 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A 40 A I W Wool waste, wet 4.2 UN1387 III 4.2 151 213 240 Forbidden Forbidden A Xanthates 4.2 UN3342 II 4.2 IB6, IP2, T3, TP33 None 212 241 15 kg 50 kg D 40 III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg D 40 Xenon 2.2 UN2036 2.2 306 302 None 75 kg 150 kg A Xenon, refrigerated liquid (cryogenic liquids) 2.2 UN2591 2.2 T75, TP5 320 None None 50 kg 500 kg B Xylenes 3 UN1307 II 3 IB2, T4, TP1 150 202 242 5 L 60 L B III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L A Xylenols, solid 6.1 UN2261 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Xylenols, liquid 6.1 UN3430 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Xylidines, liquid 6.1 UN1711 II 6.1 IB2, T7, TP2 153 202 243 5 L 60 L A Start Printed Page 76148 Xylidines, solid 6.1 UN3452 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Xylyl bromide, liquid 6.1 UN1701 II 6.1 A3, A6, A7, IB2, N33, T7, TP2, TP13 None 340 None Forbidden 60 L D 40 Xylyl bromide, solid 6.1 UN3417 II 6.1 A3, A6, A7, IB8, IP2, IP4, N33, T3, TP33 None 340 None 25 kg 100 kg B 40 p-Xylyl diazide Forbidden Zinc ammonium nitrite 5.1 UN1512 II 5.1 IB8, IP4, T3, TP33 None 212 242 5 kg 25 kg E Zinc arsenate or Zinc arsenite or Zinc arsenate and zinc arsenite mixtures 6.1 UN1712 II 6.1 IB8, IP2, IP4, T3, TP33 153 212 242 25 kg 100 kg A Zinc ashes 4.3 UN1435 III 4.3 A1, A19, IB8, IP4, T1, TP33 151 213 241 25 kg 100 kg A Zinc bisulfite solution, see Bisulfites, aqueous solutions, n.o.s. Zinc bromate 5.1 UN2469 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A 56, 58 Zinc chlorate 5.1 UN1513 II 5.1 A9, IB8, IP2, IP4, N34, T3, TP33 152 212 242 5 kg 25 kg A 56, 58 Zinc chloride, anhydrous 8 UN2331 III 8 IB8, IP3, T1, TP33 None 213 240 25 kg 100 kg A Zinc chloride, solution 8 UN1840 III 8 IB3, T4, TP1 154 203 241 5 L 60 L A Zinc cyanide 6.1 UN1713 I 6.1 IB7, IP1, T6, TP33 None 211 242 5 kg 50 kg A 52 Zinc dithionite or Zinc hydrosulfite 9 UN1931 III None IB8, IP3, T1, TP33 155 204 240 100 kg 200 kg A 49 Zinc ethyl, see Diethylzinc Zinc fluorosilicate 6.1 UN2855 III 6.1 IB8, IP3, T1, TP33 153 213 240 100 kg 200 kg A 52 Zinc hydrosulfite, see Zinc dithionite Zinc muriate solution, see Zinc chloride, solution Zinc nitrate 5.1 UN1514 II 5.1 IB8, IP4, T3, TP33 152 212 240 5 kg 25 kg A Zinc permanganate 5.1 UN1515 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg D 56, 58, 138 Zinc peroxide 5.1 UN1516 II 5.1 IB6, IP2, T3, TP33 152 212 242 5 kg 25 kg A 13, 52, 66, 75 Zinc phosphide 4.3 UN1714 I 4.3, 6.1 A19, N40 None 211 None Forbidden 15 kg E 40, 52, 85 Zinc powder or Zinc dust 4.3 UN1436 I 4.3, 4.2 A19, IB4, IP1, N40 None 211 242 Forbidden 15 kg A 52, 53 II 4.3, 4.2 A19, IB7, IP2, T3, TP33 None 212 242 15 kg 50 kg A 52, 53 III 4.3, 4.2 IB8, IP4, T1, TP33 None 213 242 25 kg 100 kg A 52, 53 Zinc resinate 4.1 UN2714 III 4.1 A1, IB6, T1, TP33 151 213 240 25 kg 100 kg A Zinc selenate, see Selenates or Selenites Zinc selenite, see Selenates or Selenites Zinc silicofluoride, see Zinc fluorosilicate Zirconium, dry, coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns) 4.1 UN2858 III 4.1 A1 151 213 240 25 kg 100 kg A Zirconium, dry, finished sheets, strip or coiled wire 4.2 UN2009 III 4.2 A1, A19 None 213 240 25 kg 100 kg D Zirconium hydride 4.1 UN1437 II 4.1 A19, A20, IB4, N34, T3, TP33 None 212 240 15 kg 50 kg E Zirconium nitrate 5.1 UN2728 III 5.1 A1, A29, IB8, IP3, T1, TP33 152 213 240 25 kg 100 kg A Zirconium picramate, dry or wetted with less than 20 percent water, by mass 1.3C UN0236 II 1.3C None 62 None Forbidden Forbidden 10 5E Zirconium picramate, wetted with not less than 20 percent water, by mass 4.1 UN1517 I 4.1 23, N41 None 211 None 1 kg 15 kg D 28, 36 Zirconium powder, dry 4.2 UN2008 I 4.2 T21, TP7, TP33 None 211 242 Forbidden Forbidden D II 4.2 A19, A20, IB6, IP2, N5, N34, T3, TP33 None 212 241 15 kg 50 kg D Start Printed Page 76149 III 4.2 IB8, IP3, T1, TP33 None 213 241 25 kg 100 kg D Zirconium powder, wetted with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns 4.1 UN1358 II 4.1 A19, A20, IB6, IP2, N34, T3, TP33 None 212 241 15 kg 50 kg E 74 Zirconium scrap 4.2 UN1932 III 4.2 IB8, IP3, N34, T1, TP33 None 213 240 Forbidden Forbidden D Zirconium suspended in a liquid 3 UN1308 I 3 None 201 243 Forbidden Forbidden B II 3 IB2 None 202 242 5 L 60 L B III 3 B1, IB2 150 203 242 60 L 220 L B Zirconium tetrachloride 8 UN2503 III 8 IB8, IP3, T1, TP33 154 213 240 25 kg 100 kg A * * * * *10. In Appendix B to § 172.101, the List of Marine Pollutants is amended by removing three entries, revising one entry and adding one entry in appropriate alphabetical order to read as follows:
End Amendment PartAppendix B to § 172.101—List of Marine Pollutants.
* * * * *Start Amendment PartList of Marine Pollutants
S, M, P (1) Marine Pollutant (2) [Remove:] Diphenyl oxide and biphenyl phenyl ether mixtures Isoamyl mercaptan Pentanethiols Tetrachlorophenol [Revise:] PP 2, 6-Di-tert-Butylphenol [Add:] * * * * * Chloropicrin * * * * * 11. In § 172.102:
End Amendment Part Start Amendment Parta. Paragraphs (b)(3), (b)(4), (b)(7) and (b)(8) are revised and a new paragraph (b)(9) is added.
End Amendment Part Start Amendment Partb. In paragraph (c)(1), Special Provisions 47, 135, and 137 are revised; Special Provisions 163, 164, 165, 166, 167, 170 and 171 are added; and Special Provision 143 and 153 are removed.
End Amendment Part Start Amendment Partc. In paragraph (c)(2), a new Special Provision A14 is added.
End Amendment Part Start Amendment Partd. The introductory text of paragraph (c)(3) is revised; in paragraph (c)(3) Special Provision B69 is revised and paragraph (c)(4) is revised.
End Amendment Part Start Amendment Parte. Paragraphs (c)(7)(viii) and (c)(8) are redesignated as paragraphs (c)(8) and (c)(9) respectively, the introductory paragraph of (c)(8) is revised, a new paragraph (c)(8)(ii) is added, Special Provisions TP3 and TP6 are revised and a new Special Provision TP32 and TP33 are added.
End Amendment Part Start Amendment Partf. Paragraph (c)(7) is revised.
End Amendment PartThe additions and revisions read as follows:
Special provisions.* * * * *(b) * * *
(3) A code containing the letter “B” refers to a special provision that applies only to bulk packaging requirements. Unless otherwise provided in this subchapter, these special provisions do not apply to UN, IM Specification portable tanks or IBCs.
(4) A code containing the letters “IB” or “IP” refers to a special provision that applies only to transportation in IBCs.
* * * * *(7) A code containing the letter “T” refers to a special provision which applies only to transportation in UN or IM Specification portable tanks.
(8) A code containing the letters “TP” refers to a portable tank special provision for UN or IM Specification portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter.
(9) A code containing the letter “W” refers to a special provision that applies only to transportation by water.
(c) * * *
(1) * * *
Code/Special Provisions
* * * * *47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Except when the liquids are fully absorbed in solid material contained in sealed bags, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed into a solid material are not subject to this subchapter provided there is no free liquid in the packet.
* * * * *135 The entries “Vehicle, flammable gas powered” or “Vehicle, flammable liquid powered,” as appropriate, must be used when internal combustion engines are installed in a vehicle. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries.
* * * * *137 Cotton, dry; flax, dry; and sisal, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, “Cotton Bales—Dimensions and Density” (IBR, see § 171.7 of this subchapter) to a density of not less than 360 kg/m3 (22.1 lb/ft3) for cotton, 400 kg/m3 (24.97 lb/ft3) for flax and 620 kg/m3 (38.71 lb/ft3) for sisal and transported in a freight container or closed transport vehicle.
* * * * *163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see § 171.7 of this subchapter).
164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation.
165 These substances are susceptible to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). During the course of transportation, these substances must be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas.
166 When transported in non-friable tablet form calcium hypochlorite, dry or hydrated, may be transported as a Packing Group III material.
167 These storage systems shall always be considered as containing hydrogen.
170 Air must be eliminated from the vapor space by nitrogen or other means.
171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in § 173.127.
(2) “A” codes. These provisions apply only to transportation by aircraft:
Code/Special Provisions
* * * * *A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with § 173.306 of this subchapter when transported aboard an aircraft.
* * * * *(3) “B” codes. These provisions apply only to bulk packagings. Except as otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs:
Code/Special Provisions
* * * * *B69 Dry sodium cyanide or potassium cyanide may be shipped in sift-proof weather-resistant metal covered hopper cars, covered motor vehicles, portable tanks or non-specification bins. Bins must approved by the Associate Administrator.
* * * * *(4) Table 1 and Table 2—IB Codes and IP Special IBC Packing Provisions. These provisions apply only to Start Printed Page 76151transportation in IBCs. When no IBC code is assigned in the § 172.101 Table for a specific proper shipping name, or in § 173.225(e) for Type F organic peroxides, an IBC may not be used unless authorized by the Associate Administrator. The letter “Z” shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in § 178.702(a)(2) of this subchapter to specify the material used for the outer packaging. Tables 1 and 2 follow:
Table 1.—IB Codes (IBC Codes)
IBC Code Authorized IBCs IB1 Authorized IBCs: Metal (31A, 31B and 31N). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized. B2 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130kPa at 55 °C (1.3 bar at 131 °F) are authorized. IB3 Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 3 for UN2672). IB4 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N). IB5 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1). IB6 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2). Additional Requirement: Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport. IB7 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F). Additional Requirement: Liners of wooden IBCs must be sift- proof. IB8 Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IB9 IBCs are only authorized if approved by the Associate Administrator. Table 2.—IP Codes
IBC Code Authorized IBCs IP1 IBCs must be packed in closed freight containers or a closed transport vehicle. IP2 When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. IP3 Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. IP4 Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. IP5 IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. IP6 Non-specification bulk bins are authorized. IP7 For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter. IP8 Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in § 178.814 of this subchapter at a test pressure that is not less than 1.5 times the vapor pressure of the contents at 55 °C (131 °F). IP13 Transportation by vessel in IBCs is prohibited. IP14 Air shall be eliminated from the vapor space by nitrogen or other means. IP20 Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. * * * * *(7) “T” codes. (i) These provisions apply to the transportation of hazardous materials in UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. Liquefied compressed gases are assigned to portable tank instruction T50. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75.
(ii) The following table specifies the portable tank requirements applicable to “T” Codes T1 through T22. Column 1 specifies the “T” Code. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by § 180.605 of this subchapter must be conducted. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of § 178.275(g)(3) of this subchapter for the pressure relief devices. When the word “Normal” is indicated, § 178.275(g)(3) of this subchapter does not apply. Column 5 references the applicable requirements for bottom openings in part 178 of this Start Printed Page 76152subchapter or references “Prohibited” which means bottom openings are prohibited. The table follows:
Table of Portable Tank T Codes T1-T22
[Portable tank codes T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.]
Portable tank instruction (1) Minimum test pressure (bar) (2) Minimum shell thickness (in mm-reference steel) (See § 178.274(d)) (3) Pressure-relief requirements (See § 178.275(g)) (4) Bottom opening requirements (See § 178.275(d)) (5) T1 1.5 § 178.274(d)(2) Normal § 178.275(d)(2)0 T2 1.5 § 178.274(d)(2) Normal § 178.275(d)(3) T3 2.65 § 178.274(d)(2) Normal § 178.275(d)(2) T4 2.65 § 178.274(d)(2) Normal § 178.275(d)(3) T5 2.65 § 178.274(d)(2) § 178.275(g)(3) Prohibited T6 4 § 178.274(d)(2) Normal § 178.275(d)(2) T7 4 § 178.274(d)(2) Normal § 178.275(d)(3) T8 4 § 178.274(d)(2) Normal Prohibited T9 4 6 mm Normal Prohibited T10 4 6 mm § 178.275(g)(3) Prohibited T11 6 § 178.274(d)(2) Normal § 178.275(d)(3) T12 6 § 178.274(d)(2) § 178.275(g)(3) § 178.275(d)(3) T13 6 6 mm Normal Prohibited T14 6 6 mm § 178.275(g)(3) Prohibited T15 10 § 178.274(d)(2) Normal § 178.275(d)(3) T16 10 § 178.274(d)(2) § 178.275(g)(3) § 178.275(d)(3) T17 10 6 mm Normal § 178.275(d)(3) T18 10 6 mm § 178.275(g)(3) § 178.275(d)(3) T19 10 6 mm § 178.275(g)(3) Prohibited T20 10 8 mm § 178.275(g)(3) Prohibited T21 10 10 mm Normal Prohibited T22 10 10 mm § 178.275(g)(3) Prohibited (iii) T50. When portable tank instruction T50 is referenced in Column (7) of the § 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of § 173.313 of this subchapter.
(iv) T75. When portable tank instruction T75 is referenced in Column (7) of the § 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of § 178.277 of this subchapter.
(v) UN and IM portable tank codes/special provisions. When a specific portable tank instruction is specified by a “T” Code in Column (7) of the § 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if:
(A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified);
(B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified);
(C) The alternative portable tank has a pressure relief device as specified in the “T” Code. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and
(D) With regard to bottom openings—
(1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or
(2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or
(3) When no bottom openings are authorized, the alternative portable tank must not have bottom openings.
(vi) Except when an organic peroxide is authorized under § 173.225(g), if a hazardous material is not assigned a portable tank “T” Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator.
(8) “TP” codes. (i) These provisions apply to the transportation of hazardous materials in IM and UN Specification portable tanks. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the § 172.101 Table.
(ii) The following is a list of the portable tank special provisions:
* * * * *Code/Special Provisions
* * * * *TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following:
Where: df and dr are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively.
* * * * *TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see § 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking Start Printed Page 76153into account the properties of the hazardous material to be transported.
* * * * *TP32 Portable tanks may be used subject to the following conditions:
a. Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar;
b. The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see § 171.7 of this subchapter) or an alternative means approved by the Associate Administrator.
TP33 The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.
* * * * *12. In § 172.202, paragraphs (a)(2)(iii) and (a)(5)(i) are revised to read as follows:
End Amendment PartDescription of hazardous material on shipping papers.(a) * * *
(2) * * *
(iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description.
(5) * * *
(i) For Class I materials, the quantity must be the net explosive mass. For an explosive that is an article, such as Cartridges, small arms, the net explosive mass may be expressed in terms of the net mass of either the article or the explosive materials contained in the article.
* * * * *13. In § 172.203, paragraphs (f), (m)(2) and (o)(3) are revised and a new paragraph (i)(3) is added to read as follows:
End Amendment PartAdditional description requirements.* * * * *(f) Transportation by air. A statement indicating that the shipment is within the limitations prescribed for either passenger and cargo aircraft or cargo aircraft only must be entered on the shipping paper.
* * * * *(i) * * *
(3) For a hazardous material consigned under an “n.o.s.” entry not included in the segregation groups listed in section 3.1.4 of the IMDG Code but belonging, in the opinion of the consignor, to one of these groups, the appropriate segregation group must be shown in association with the basic description (for example, IMDG Code segregation group—1 Acids). When no segregation group is applicable, there is no requirement to indicate that condition.
* * * * *(m) * * *
(2) For materials that are poisonous by inhalation (see § 171.8 of this subchapter), the words “Poison-Inhalation Hazard” or “Toxic-Inhalation Hazard” and the words “Zone A”, “Zone B”, “Zone C”, or “Zone D”, for gases or “Zone A” or “Zone B” for liquids, as appropriate, must be entered on the shipping description. The word “Poison” or “Toxic” or the phrase “Poison-Inhalation Hazard” or “Toxic Inhalation Hazard” need not be repeated if it otherwise appears in the shipping description.
* * * * *(o) * * *
(3) The word “SAMPLE” must be included in association with the basic description when a sample of a Division 4.1 (self-reactive) material (see § 173.224(c)(3) of this subchapter) or Division 5.2 (organic peroxide) material (see § 173.225(b)(2) of this subchapter) is offered for transportation.
14. In § 172.204, paragraph (c)(3) is revised to read as follows:
End Amendment PartShipper's certification.* * * * *(c) * * *
(3) Additional certification requirements. Effective October 1, 2006, each person who offers a hazardous material for transportation by air must add to the certification required in this section the following statement:
“I declare that all of the applicable air transport requirements have been met.”
(i) Each person who offers any package or overpack of hazardous materials for transport by air must ensure that:
(A) The articles or substances are not prohibited for transport by air (see the § 172.101 Table);
(B) The articles or substances are properly classed, marked and labeled and otherwise in a condition for transport as required by this subchapter;
(C) The articles or substances are packaged in accordance with all the applicable air transport requirements, including appropriate types of packaging that conform to the packing requirements and the “A” Special Provisions in § 172.102; inner packaging and maximum quantity per package limits; the compatibility requirements (see, for example, § 173.24 of this subchapter); and requirements for closure for both inner and outer packagings, absorbent materials, and pressure differential in § 173.27 of this subchapter. Other requirements may also apply. For example, single packagings may be prohibited, inner packaging may need to be packed in intermediate packagings, and certain materials may be required to be transported in packagings meeting a more stringent performance level.
(ii) [Reserved]
* * * * *14a. The introductory text of § 172.315 is revised to read as follows:
End Amendment PartPackages containing limited quantities.Except for transportation by aircraft or as otherwise provided in this subchapter, a package containing a limited quantity of hazardous materials is not required to be marked with the proper shipping name provided it is marked with the identification (ID) number, preceded by the letters “UN” or “NA,” as applicable, for the entry as shown in the § 172.101 Table, and placed within a square-on-point border in accordance with the following:
* * * * *15. A new § 172.317 is added to read as follows:
End Amendment PartKEEP AWAY FROM HEAT handling mark.(a) General. For transportation by aircraft, each package containing self-Start Printed Page 76154reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the KEEP AWAY FROM HEAT handling mark specified in this section.
(b) Location and design. The marking must be a rectangle measuring at least 105 mm (4.1 inches) in height by 74 mm (2.9 inches) in width. Markings with not less than half this dimension are permissible where the dimensions of the package can only bear a smaller mark.
(c) KEEP AWAY FROM HEAT handling mark. The KEEP AWAY FROM HEAT handling mark must conform to the following:
(1) Except for size, the KEEP AWAY FROM HEAT handling mark must appear as follows:
(2) The symbol, letters and border must be black and the background white, except for the starburst which must be red.
(3) The KEEP AWAY FROM HEAT handling marking required by paragraph (a) of this section must be durable, legible and displayed on a background of contrasting color.
[Removed]16. Section 172.321 is removed.
End Amendment Part Start PartPART 173—SHIPPERS—GENERAL REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS
End Part Start Amendment Part17. The authority citation for part 173 continues to read as follows:
End Amendment Part Start Amendment Part18. In § 173.3, paragraph (c) introductory text is revised to read as follows:
End Amendment PartPackaging and exceptions.* * * * *(c) Salvage drums. During transportation, as defined in 49 U.S.C. 5102(12), damaged or defective hazardous materials packages, hazardous materials packages that are found not to conform with the requirements of this subchapter, leaking hazardous materials packages, or hazardous materials that have spilled or leaked may be placed for repackaging or disposal in a metal or plastic removable head salvage drum that is compatible with the lading under the following conditions:
* * * * *19. In § 173.24, paragraphs (g) and (i) are revised to read as follows:
End Amendment PartGeneral requirements for packagings and packages.* * * * *(g) Venting. Venting of packagings, to reduce internal pressure which may develop by the evolution of gas from the contents, is permitted only when—
(1) Transportation by aircraft is not involved;
(2) Except as otherwise provided in this subchapter, the evolved gases are not poisonous, likely to create a flammable mixture with air or be an asphyxiant under normal conditions of transportation;
(3) The packaging is designed so as to preclude an unintentional release of hazardous materials from the receptacle;
(4) For bulk packagings, other than IBCs, venting is authorized for the specific hazardous material by a special provision in the § 172.101 table or by the applicable bulk packaging specification in part 178 of this subchapter; and
(5) Intermediate bulk packagings (IBCs) may be vented when required to reduce internal pressure that may develop by the evolution of gas subject to the requirements of paragraphs (g)(1) through (g)(3) of this section. The IBC Start Printed Page 76155must be of a type that has successfully passed (with the vent in place) the applicable design qualification tests with no release of hazardous material.
* * * * *(i) Air transportation. Packages offered or intended for transportation by aircraft are subject to requirements additional to those of other modes of transport (e.g., quantity limitations, requirements for absorbent material, pressure differential requirements, appropriate closure procedures, and specific packaging requirements) and must conform to the general requirements for transportation by aircraft in § 173.27.
20. In § 173.25, paragraphs (a)(2) and (a)(4) are revised to read as follows:
End Amendment PartAuthorized packagings and overpacks.(a) * * *
* * * * *(2) The overpack is marked with the proper shipping name and identification number, when applicable, and is labeled as required by this subchapter for each hazardous material contained therein, unless marking and labels representative of each hazardous material in the overpack are visible.
* * * * *(4) The overpack is marked with the word “OVERPACK” when specification packagings are required, unless specification markings on the inside packages are visible. Alternatively, until October 1, 2007, the overpack may be marked with a statement indicating that the “inside (inner) packages comply with prescribed specifications.”
* * * * *21. In § 173.27, paragraph (i) is revised to read as follows:
End Amendment PartGeneral requirements for transportation by aircraft.* * * * *(i) Effective October 1, 2006, each person who offers a hazardous material for transportation by aircraft must include the certification statement specified in § 172.204(c)(3).
22. In § 173.28, paragraph (c)(2) introductory text is revised to read as follows:
End Amendment PartReuse, reconditioning and remanufacture of packagings.* * * * *(c) * * *
(2) For the purpose of this subchapter, reconditioning of a non-bulk packaging other than a metal drum includes:
* * * * *23. In § 173.115, a new paragraph (k) is added to read as follows:
End Amendment PartClass 2, Division 2.1, 2.2 and 2.3—Definitions.* * * * *(k) The following applies to aerosols (see § 171.8 of this subchapter):
(1) An aerosol must be assigned to Division 2.1 if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more;
(2) An aerosol must be assigned to Division 2.2 if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g.
(3) Aerosols not meeting the provisions of paragraphs (a) or (b) of this section must be classed in accordance with the appropriate tests of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).
(4) Division 2.3 gases may not be transported in an aerosol container.
(5) When the contents are classified as Division 6.1 or Class 8, PG III, the aerosol must be assigned a subsidiary hazard of Division 6.1 or Class 8.
(6) Substances of Division 6.1, PG I or II, and substances of Class 8, PG I are forbidden from transportation in an aerosol container.
(7) Flammable components are Class 3 flammable liquids, Class 4.1 flammable solids, or Division 2.1 flammable gases. The chemical heat of combustion must be determined in accordance with the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).
24. In § 173.128, paragraph (d)(1) is revised to read as follows:
End Amendment PartClass 5, Division 5.2—Definitions and types.* * * * *(d) Approvals. (1) An organic peroxide must be approved, in writing, by the Associate Administrator, before being offered for transportation or transported, including assignment of a generic type and shipping description, except for—
(i) An organic peroxide which is identified by technical name in the Organic Peroxides Table in § 173.225(c);
(ii) A mixture of organic peroxides prepared according to § 173.225(b); or
(iii) An organic peroxide which may be shipped as a sample under the provisions of § 173.225(b).
* * * * *25. In 173.132, paragraph (b)(1) is revised to read as follows:
End Amendment PartClass 6, Division 6.1—Definitions.* * * * *(b) * * *
(1) LD50 (median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50% of young adult albino rats when administered by the oral route. The LD50 value is expressed in terms of mass of test substance per mass of test animal (mg/kg).
* * * * *26. In § 173.136, paragraph (d) is added to read as follows:
End Amendment PartClass 8—Definitions.* * * * *(d) Steel or aluminum corrosion test data produced no later than September 30, 2005, using the procedures of § 173.137(c)(2), in effect on September 30, 2004 (see 49 CFR 173.137 revised as of October 1, 2003), for appropriate steel or aluminum types may be used for classification and assignment of packing group for Class 8 materials corrosive to steel or aluminum.
27. In § 173.137, paragraph (c)(2) is revised to read as follows:
End Amendment PartClass 8—Assignment of packing group.* * * * *(c) * * *
* * * * *(2) That do not cause full thickness destruction of intact skin tissue but exhibit a corrosion on steel or aluminum surfaces exceeding 6.25 mm (0.25 inch) a year at a test temperature of 55 °C (130 °F). The corrosion must be determined in accordance with the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter).
28. In § 173.150, paragraph (a), the introductory text of paragraph (b), paragraph (b)(2) and paragraph (c) are revised to read as follows:
End Amendment PartExceptions for Class 3 (flammable) and combustible liquids.(a) General. Exceptions for hazardous materials shipments in the following paragraphs are permitted only if this section is referenced for the specific hazardous material in the § 172.101 Table of this subchapter.
(b) Limited quantities. Limited quantities of flammable liquids (Class 3) and combustible liquids are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging Start Printed Page 76156requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
* * * * *(2) For flammable liquids in Packing Group II, inner packagings not over 1.0 L (0.3 gallons) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) net capacity each, packed in a strong outer packaging.
* * * * *(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section and is a “consumer commodity” as defined in 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D material. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
* * * * *29. In 173.151, paragraphs (b) and (c), and the introductory text of paragraph (d) are revised to read as follows:
End Amendment PartExceptions for Class 4.* * * * *(b) Limited quantities of Division 4.1. Limited quantities of flammable solids (Division 4.1) in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
(1) For flammable solids in Packing Group II, inner packagings not over 1.0 kg (2.2 pounds) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 0.5 kg (1.1 pounds) net capacity each, packed in a strong outer packaging.
(2) For flammable solids in Packing Group III, inner packagings not over 5.0 kg (11 pounds) net capacity each, packed in a strong outer packaging.
(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and charcoal briquettes in packagings not exceeding 30 kg (66 pounds) gross weight, may be renamed “Consumer commodity” and reclassed as ORM-D material if the material is a “consumer commodity” as defined in 171.8 of this subchapter. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
(d) Limited quantities of Division 4.3. Limited quantities of dangerous when wet (Division 4.3) solids in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
* * * * *30. In § 173.152, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows:
End Amendment PartExceptions for Division 5.1 (oxidizers) and Division 5.2 (organic peroxides).* * * * *(b) Limited quantities. Limited quantities of oxidizers (Division 5.1) in Packing Group II and III and organic peroxides are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
(1) For oxidizers in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging.
* * * * *(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
31. In § 173.153, paragraph (b), and paragraph (c)(1) are revised to read as follows:
End Amendment PartExceptions for Division 6.1 (poisonous materials).* * * * *(b) Limited quantities. The exceptions in this paragraph do not apply to poison-by-inhalation materials. Limited quantities of poisonous materials (Division 6.1) in Packing Group II and III are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. Start Printed Page 76157The following combination packagings are authorized:
(1) For poisonous materials in Packing Group II, inner packagings not over 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids, packed in a strong outer packaging.
(2) For poisonous materials in Packing Group III, inner packagings not over 4 L (1.0 gallon) each for liquids or 5.0 kg (11 pounds) each for solids, packed in a strong outer packaging.
(c) * * *
(1) A limited quantity of poisonous material in Packing Group III which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D.
* * * * *32. In § 173.154, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows:
End Amendment PartExceptions for Class 8 (corrosive materials).* * * * *(b) Limited quantities. Limited quantities of corrosive materials (Class 8) in Packing Group II and III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
(1) For corrosive materials in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging.
* * * * *(c) Consumer commodities. Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
* * * * *33. In § 173.185, paragraphs (c)(3) and (e)(6) are revised to read as follows:
End Amendment PartLithium batteries and cells.* * * * *(c) * * *
(3) Each cell or battery is of the type proven to be non-dangerous by testing in accordance with Tests in the UN Manual of Tests and Criteria (IBR; see § 171.7 of this subchapter). Such testing must be carried out on each type of cell or battery prior to the initial transport of that type. A cell or battery and equipment containing a cell or battery which was first transported prior to January 1, 2006 and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested;
* * * * *(e) * * *
(6) Each cell or battery is of the type proven to meet the lithium battery requirements in the UN Manual of Tests and Criteria (IBR; see § 171.7 of this subchapter). A cell or battery and equipment containing a cell or battery which was first transported prior to January 1, 2006 and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested.
* * * * *34. In § 173.186, paragraph (e) is revised to read as follows:
End Amendment PartMatches.* * * * *(e) Packagings. Strike-anywhere matches must be tightly packed in securely closed chipboard, fiberboard, wooden, or metal inner packagings to prevent accidental ignition under conditions normally incident to transportation. Each inner packaging may contain no more than 700 strike-anywhere matches and must be packed in outer steel drums (1A2), aluminum drums (1B2), steel jerricans (3A2), wooden (4C1, 4C2), plywood (4D), reconstituted wood (4F) or fiberboard (4G) boxes, plywood (1D) or fiber (1G) drums. Gross weight of fiberboard boxes (4G) must not exceed 30 kg (66 pounds). Gross weight of other outer packagings must not exceed 45 kg (100 pounds).
35. In § 173.187, a new paragraph (f) is added to read as follows:
End Amendment PartPyrophoric solids, metals or alloys, n.o.s.* * * * *(f) In specification cylinders, as prescribed for any compressed gas, except for Specifications 8 and 3HT.
36. In § 173.211, paragraph (c) is revised to read as follows:
End Amendment PartNon-bulk packagings for solid hazardous materials in Packing Group I.* * * * *(c) Except for transportation by passenger aircraft, the following single packagings are authorized:
Steel drum: 1A1 or 1A2
Aluminum drum: 1B1 or 1B2
Metal drum other than steel or aluminum: 1N1 or 1N2
Plastic drum: 1H1 or 1H2
Fiber drum: 1G
Steel jerrican: 3A1 or 3A2
Plastic jerrican: 3H1 or 3H2
Aluminum jerrican: 3B1 or 3B2
Steel box with liner: 4A
Aluminum box with liner: 4B
Natural wood box, sift proof: 4C2
Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1
Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1
Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB2, 6PC or 6PG2
Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2
Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT
37. In § 173.212, paragraph (c) is revised to read as follows:
End Amendment PartNon-bulk packagings for solid hazardous materials in Packing Group III.* * * * *(c) Except for transportation by passenger aircraft, the following single packagings are authorized:
Steel drum: 1A1 or 1A2
Aluminum drum: 1B1 or 1B2
Plywood drum: 1D
Plastic drum: 1H1 or 1H2
Fiber drum: 1G
Metal drum other than steel or aluminum: 1N1 or 1N2 Start Printed Page 76158
Wooden barrel: 2C1 or 2C2
Steel jerrican: 3A1 or 3A2
Plastic jerrican: 3H1 or 3H2
Aluminum jerrican: 3B1 or 3B2
Steel box: 4A
Steel box with liner: 4A
Aluminum box: 4B
Aluminum box with liner: 4B
Natural wood box: 4C1
Natural wood box, sift proof: 4C2
Plywood box: 4D
Reconstituted wood box: 4F
Fiberboard box: 4G
Expanded plastic box: 4H1
Solid plastic box: 4H2
Bag, woven plastic: 5H1, 5H2 or 5H3
Bag, plastic film: 5H4
Bag, textile: 5L1, 5L2 or 5L3
Bag, paper, multiwall, water resistant: 5M2
Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1
Plastic receptacle in steel, aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2
Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1
Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB1, 6PC or 6PG2
Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2
Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT
38. In § 173.213, paragraph (c) is revised to read as follows:
End Amendment PartNon-bulk packagings for solid hazardous materials in Packing Group III.* * * * *(c) The following single packagings are authorized:
Steel drum: 1A1 or 1A2
Aluminum drum: 1B1 or 1B2
Plywood drum: 1D
Plastic drum: 1H1 or 1H2
Fiber drum: 1G
Metal drum other than steel or aluminum: 1N1 or 1N2
Wooden barrel: 2C1 or 2C2
Steel jerrican: 3A1 or 3A2
Plastic jerrican: 3H1 or 3H2
Aluminum jerrican: 3B1 or 3B2
Steel box: 4A
Steel box with liner: 4A
Aluminum box: 4B
Aluminum box with liner: 4B
Natural wood box: 4C1
Natural wood box, sift proof: 4C2
Plywood box: 4D
Reconstituted wood box: 4F
Fiberboard box: 4G
Expanded plastic box: 4H1
Solid plastic box: 4H2
Bag, woven plastic: 5H1, 5H2 or 5H3
Bag, plastic film: 5H4
Bag, textile: 5L1, 5L2 or 5L3
Bag, paper, multiwall, water resistant: 5M2
Plastic receptacle in steel, aluminum, plywood, fiber or plastic drum: 6HA1, 6HB1, 6HD1, 6HG1 or 6HH1
Plastic receptacle in steel, aluminum, wood, plywood or fiberboard box: 6HA2, 6HB2, 6HC, 6HD2 or 6HG2
Glass, porcelain or stoneware in steel, aluminum, plywood or fiber drum: 6PA1, 6PB1, 6PD1 or 6PG1
Glass, porcelain or stoneware in steel, aluminum, wooden or fiberboard box: 6PA2, 6PB1, 6PC or 6PG2
Glass, porcelain or stoneware in expanded or solid plastic packaging: 6PH1 or 6PH2
Cylinders, as prescribed for any compressed gas, except for Specification 8 and 3HT
39. Section 173.219 is revised to read as follows:
End Amendment PartLife-saving appliances.(a) A life-saving appliance, self-inflating or non-self-inflating, containing small quantities of hazardous materials that are required as part of the life-saving appliance must conform to the requirements of this section. Packagings must conform to the general packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter. The appliances must be packed, so that they cannot be accidentally activated and, except for life vests, the hazardous materials must be in inner packagings packed so as to prevent movement. The hazardous materials must be an integral part of the appliance and in quantities that do not exceed those appropriate for the actual appliance when in use.
(b) Life saving appliances may contain:
(1) Division 2.2 compressed gases, including oxygen. However, oxygen generators are not permitted;
(2) Signal devices (Class 1), which may include smoke and illumination signal flares;
(3) Electric storage batteries and lithium batteries (Life saving appliances containing lithium batteries must be transported in accordance with § 173.185.);
(4) First aid or repair kits conforming to the applicable material and quantity limitations of § 173.161 of this subchapter;
(5) Strike-anywhere matches;
(6) For self-inflating life saving appliances only, cartridges power device of Division 1.4S, for purposes of the self-inflating mechanism provided that the quantity of explosives per appliance does not exceed 3.2 g; or
(7) Limited quantities of other hazardous materials.
(c) Hazardous materials in life saving appliances must be packaged as follows:
(1) Division 2.2 compressed gases must be packaged in cylinders in accordance with the requirements of this subchapter;
(2) Signal devices (Class 1) must be in packagings that prevent them from being inadvertently activated;
(3) Strike-anywhere matches must be cushioned to prevent movement or friction in a metal or composition receptacle with a screw-type closure in a manner that prevents them from being inadvertently activated;
(4) Limited quantities of other hazardous materials must be packaged in accordance with the requirements of this subchapter; and
(5) For other than transportation by aircraft, life saving appliances containing no hazardous materials other than carbon dioxide cylinders with a capacity not exceeding 100 cm3 are not subject to the provisions of this subchapter provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg.
40. In § 173.220, paragraph (b)(2) is revised to read as follows:
End Amendment PartInternal combustion engines, self-propelled vehicles, mechanical equipment containing internal combustion engines, and battery powered vehicles or equipment.* * * * *(b) * * *
(2) Flammable liquefied or compressed gas fuel. (i) For transportation by motor vehicle, rail car or vessel, fuel tanks and fuel systems containing flammable liquefied or compressed gas fuel must be securely closed. For transportation by vessel, the requirements of §§ 176.78(k) and 176.905 of this subchapter apply.
(ii) For transportation by aircraft:
(A) Flammable gas-powered vehicles, machines, equipment or cylinders containing the flammable gas must be completely emptied of flammable gas. Lines from vessels to gas regulators, and gas regulators themselves, must also be drained of all traces of flammable gas. To ensure that these conditions are met, gas shut-off valves must be left open and connections of lines to gas regulators must be left disconnected upon delivery of the vehicle to the operator. Shut-off valves must be closed and lines reconnected at gas regulators before loading the vehicle aboard the aircraft; or alternatively
(B) Flammable gas powered vehicles, machines or equipment, which have Start Printed Page 76159cylinders (fuel tanks) that are equipped with electrically operated valves, may be transported under the following conditions:
(1) The valves must be in the closed position and in the case of electrically operated valves, power to those valves must be disconnected;
(2) After closing the valves, the vehicle, equipment or machinery must be operated until it stops from lack of fuel before being loaded aboard the aircraft;
(3) In no part of the system between the pressure receptacle and the shut off valve shall the pressure exceed more than 5% of the maximum allowable working pressure of the system; and
(4) There must not be any residual liquefied gas in the system, including the fuel tank.
41. In § 173.224, paragraph (b)(4) is revised to read as follows:
End Amendment PartPackaging and control and emergency temperatures for self-reactive materials.* * * * *(b) * * *
(4) Packing method. Column 4 specifies the highest packing method which is authorized for the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in § 173.225(d) defines the packing methods. Bulk packagings for Type F self-reactive substances are authorized by § 173.225(f) for IBCs and § 173.225(h) for bulk packagings other than IBCs. Additional bulk packagings are authorized if approved by the Associate Administrator.
* * * * *42. Section 173.225 is revised to read as follows:
End Amendment PartPackaging requirements and other provisions for organic peroxides.(a) General. When the § 172.101 table specifies that an organic peroxide must be packaged under this section, the organic peroxide must be packaged and offered for transportation in accordance with the provisions of this section. Each packaging must conform to the general requirements of subpart B of part 173 and to the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. No used material, other than production residues or regrind from the same production process, may be used in plastic packagings. Organic peroxides that require temperature control are subject to the provisions of § 173.21(f). When an IBC or bulk packaging is authorized and meets the requirements of paragraph (f) or (h) of this section, respectively, lower control temperatures than those specified for non-bulk packaging may be required. An organic peroxide not identified in paragraph (c), (e), or (g) of this section by technical name, or not assigned to a generic type in accordance with the provisions in paragraph (b)(3) of this section, must conform to the provisions of paragraph (c) of § 173.128.
(b) New organic peroxides, formulations and samples. (1) Except as provided for samples in paragraph (b)(2) of this section, no person may offer for transportation an organic peroxide that is not identified by technical name in the Organic Peroxides Table, Organic Peroxide IBC Table, or the Organic Peroxide Portable Tank Table of this section, or a formulation of one or more organic peroxides that are identified by technical name in one of those tables, unless the organic peroxide is assigned a generic type and shipping description and is approved by the Associate Administrator under the provisions of § 173.128(d) of this subchapter.
(2) Samples. Samples of new organic peroxides or new formulations of organic peroxides identified in the Organic Peroxides Table in paragraph (c) of this section, for which complete test data are not available, and that are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for organic peroxide Type C, packaged and offered for transportation, under the following conditions:
(i) Data available to the person offering the material for transportation must indicate that the sample would pose a level of hazard no greater than that of an organic peroxide Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation;
(ii) The sample must be packaged in accordance with packing method OP2, for a liquid or solid, respectively;
(iii) Packages of the organic peroxide may be offered for transportation and transported in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and
(iv) One of the following shipping descriptions must be assigned:
(A) Organic peroxide Type C, liquid, 5.2, UN 3103;
(B) Organic peroxide Type C, solid, 5.2, UN 3104;
(C) Organic peroxide Type C, liquid, temperature controlled, 5.2, UN 3113; or
(D) Organic peroxide Type C, solid, temperature controlled, 5.2, UN 3114.
(3) Mixtures. Mixtures of organic peroxides individually identified in the Organic Peroxides Table in paragraph (c) of this section may be classified as the same type of organic peroxide as that of the most dangerous component and be transported under the conditions for transportation given for this type. If the stable components form a thermally less stable mixture, the SADT of the mixture must be determined and the new control and emergency temperature derived under the provisions of § 173.21(f).
(c) Organic peroxides table. The following Organic Peroxides Table specifies by technical name those organic peroxides that are authorized for transportation and not subject to the approval provisions of § 173.128 of this part. An organic peroxide identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the table. The column headings of the Organic Peroxides Table are as follows:
(1) Technical name. The first column specifies the technical name.
(2) ID number. The second column specifies the identification (ID) number which is used to identify the proper shipping name in the § 172.101 table. The word “EXEMPT” appearing in the column denotes that the material is not regulated as an organic peroxide.
(3) Concentration of organic peroxide. The third column specifies concentration (mass percent) limitations, if any, in mixtures or solutions for the organic peroxide. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the lower and upper limits (i.e., “53-100” means from, and including, 53% to, and including 100%). See introductory paragraph of § 172.203(k) of this subchapter for additional description requirements for an organic peroxide that may qualify for more than one generic listing, depending on its concentration.
(4) Concentration of diluents. The fourth column specifies the type and concentration (mass percent) of diluent or inert solid, when required. Other types and concentrations of diluents may be used if approved by the Associate Administrator.
(i) The required mass percent of “Diluent type A” is specified in column 4a. A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150 °C at Start Printed Page 76160atmospheric pressure. Type A diluents may be used for desensitizing all organic peroxides.
(ii) The required mass percent of “Diluent type B” is specified in column 4b. A diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point, at atmospheric pressure, of less than 150 °C (302 °F) but at least 60 °C (140 °F), and a flash point greater than 5 °C (41 °F). Type B diluents may be used for desensitizing all organic peroxides, when specified in the organic peroxide tables, provided that the boiling point is at least 60 °C (140 °F) above the SADT of the peroxide in a 50 kg (110 lbs) package. A type A diluent may be used to replace a type B diluent in equal concentration.
(iii) The required mass percent of “Inert solid” is specified in column 4c. An inert solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic peroxide.
(5) Concentration of water. Column 5 specifies, in mass percent, the minimum amount of water, if any, which must be in formulation.
(6) Packing method. Column 6 specifies the highest packing method (largest packaging capacity) authorized for the organic peroxide. Lower numbered packing methods (smaller packaging capacities) are also authorized. For example, if OP3 is specified, then OP2 and OP1 are also authorized. The Table of Packing Methods in paragraph (d) of this section defines the non-bulk packing methods.
(7) Temperatures. Column 7a specifies the control temperature. Column 7b specifies the emergency temperature. Temperatures are specified only when temperature controls are required. (See § 173.21(f)).
(8) Notes. Column 8 specifies other applicable provisions, as set forth in notes following the table.
Organic Peroxide Table
Technical name ID number Concentration (mass %) Diluent (mass %) Water (mass %) Packing method Temperature (°C) Notes A B I Control Emergency (1) (2) (3) (4a) (4b) (4c) (5) (6) (7a) (7b) (8) Acetyl acetone peroxide UN3105 ≤42 ≥48 ≥8 OP7 2 Acetyl acetone peroxide [as a paste] UN3106 ≤32 OP7 21 Acetyl cyclohexanesulfonyl peroxide UN3112 ≤82 ≥12 OP4 −10 0 Acetyl cyclohexanesulfonyl peroxide UN3115 ≤32 ≥68 OP7 −10 0 tert-Amyl hydroperoxide UN3107 ≤88 ≥6 ≥6 OP8 tert-Amyl peroxyacetate UN3105 ≤62 ≥38 OP7 tert-Amyl peroxybenzoate UN3103 ≤100 OP5 tert-Amyl peroxy-2-ethylhexanoate UN3115 ≤100 OP7 +20 +25 tert-Amyl peroxy-2-ethylhexyl carbonate UN3105 ≤100 OP7 tert-Amyl peroxy isopropyl carbonate UN3103 ≤77 ≥23 OP5 tert-Amyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 0 +10 tert-Amyl peroxypivalate UN3113 ≤77 ≥23 OP5 +10 +15 tert-Amyl peroxy-3,5,5-trimethylhexanoate UN3101 ≤100 OP5 tert-Butyl cumyl peroxide UN3107 >42-100 OP8 9 tert-Butyl cumyl peroxide UN3108 ≤52 ≥48 OP8 9 n-Butyl-4,4-di-(tert-butylperoxy)valerate UN3103 >52-100 OP5 n-Butyl-4,4-di-(tert-butylperoxy)valerate UN3108 ≤52 ≥48 OP8 tert-Butyl hydroperoxide UN3103 >79-90 ≥10 OP5 13 tert-Butyl hydroperoxide UN3105 ≤80 ≥20 OP7 4, 13 tert-Butyl hydroperoxide UN3107 ≤79 >14 OP8 13, 16 tert-Butyl hydroperoxide UN3109 ≤72 ≥28 OP8 13 tert-Butyl hydroperoxide [and] Di-tert-butylperoxide UN3103 <82+>9 ≥7 OP5 13 tert-Butyl monoperoxymaleate UN3102 >52-100 OP5 tert-Butyl monoperoxymaleate UN3103 ≤52 ≥48 OP6 tert-Butyl monoperoxymaleate UN3108 ≤52 ≥48 OP8 tert-Butyl monoperoxymaleate [as a paste] UN3108 ≤52 OP8 tert-Butyl peroxyacetate UN3101 >52-77 ≥23 OP5 tert-Butyl peroxyacetate UN3103 >32-52 ≥48 OP6 tert-Butyl peroxyacetate UN3109 ≤32 ≥68 OP8 tert-Butyl peroxybenzoate UN3103 >77-100 OP5 Start Printed Page 76161 tert-Butyl peroxybenzoate UN3105 >52-77 ≥23 OP7 1 tert-Butyl peroxybenzoate UN3106 ≤52 ≥48 OP7 tert-Butyl peroxybutyl fumarate UN3105 ≤52 ≥48 OP7 tert-Butyl peroxycrotonate UN3105 ≤77 ≥23 OP7 tert-Butyl peroxydiethylacetate UN3113 ≤100 OP5 +20 +25 tert-Butyl peroxy-2-ethylhexanoate UN3113 >52-100 OP6 +20 +25 tert-Butyl peroxy-2-ethylhexanoate UN3117 >32-52 ≥48 OP8 +30 +35 tert-Butyl peroxy-2-ethylhexanoate UN3118 ≤52 ≥48 OP8 +20 +25 tert-Butyl peroxy-2-ethylhexanoate UN3119 ≤32 ≥68 OP8 +40 +45 tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane UN3106 ≤12+≤14 ≥14 ≥60 OP7 tert-Butyl peroxy-2-ethylhexanoate [and] 2,2-di-(tert-Butylperoxy)butane UN3115 ≤31+≤36 ≥33 OP7 +35 +40 tert-Butyl peroxy-2-ethylhexylcarbonate UN3105 ≤100 OP7 tert-Butyl peroxyisobutyrate UN3111 >52-77 ≥23 OP5 +15 +20 tert-Butyl peroxyisobutyrate UN3115 ≤52 ≥48 OP7 +15 +20 tert-Butylperoxy isopropylcarbonate UN3103 ≤77 ≥23 OP5 1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene UN3105 ≤77 ≥23 OP7 1-(2-tert-Butylperoxy isopropyl)-3-isopropenylbenzene UN3108 ≤42 ≥58 OP8 tert-Butyl peroxy-2-methylbenzoate UN3103 ≤100 OP5 tert-Butyl peroxyneodecanoate UN3115 >77-100 OP7 −5 +5 tert-Butyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 0 +10 tert-Butyl peroxyneodecanoate [as a stable dispersion in water] UN3119 ≤52 OP8 0 +10 tert-Butyl peroxyneodecanoate [as a stable dispersion in water (frozen)] UN3118 ≤42 OP8 0 +10 tert-Butyl peroxyneodecanoate UN3119 ≤32 ≥68 OP8 0 +10 tert-Butyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 0 +10 tert-Butyl peroxyneoheptanoate [as a stable dispersion in water] UN3117 ≤42 OP8 0 +10 tert-Butyl peroxypivalate UN3113 >67-77 ≥23 OP5 0 +10 tert-Butyl peroxypivalate UN3115 >27-67 ≥33 OP7 0 +10 tert-Butyl peroxypivalate UN3119 ≤27 ≥73 OP8 +30 +35 tert-Butylperoxy stearylcarbonate UN3106 ≤100 OP7 tert-Butyl peroxy-3,5,5-trimethylhexanoate UN3105 >32-100 OP7 Start Printed Page 76162 tert-Butyl peroxy-3,5,5-trimethylhexanoate UN3109 ≤32 ≥68 OP8 3-Chloroperoxybenzoic acid UN3102 >57-86 ≥14 OP1 3-Chloroperoxybenzoic acid UN3106 ≤57 ≥3 ≥40 OP7 3-Chloroperoxybenzoic acid UN3106 ≤77 ≥6 ≥17 OP7 Cumyl hydroperoxide UN3107 >90-98 ≤10 OP8 13 Cumyl hydroperoxide UN3109 ≤90 ≥10 OP8 13, 15 Cumyl peroxyneodecanoate UN3115 ≤77 ≥23 OP7 −10 0 Cumyl peroxyneodecanoate [as a stable dispersion in water] UN3119 ≤52 OP8 −10 0 Cumyl peroxyneoheptanoate UN3115 ≤77 ≥23 OP7 −10 0 Cumyl peroxypivalate UN3115 ≤77 ≥23 OP7 −5 +5 Cyclohexanone peroxide(s) UN3104 ≤91 ≥9 OP6 13 Cyclohexanone peroxide(s) UN3105 ≤72 ≥28 OP7 5 Cyclohexanone peroxide(s) [as a paste] UN3106 ≤72 OP7 5, 21 Cyclohexanone peroxide(s) Exempt ≤32 ≥68 Exempt Diacetone alcohol peroxides UN3115 ≤57 ≥26 ≥8 OP7 +40 +45 5 Diacetyl peroxide UN3115 ≤27 ≥73 OP7 +20 +25 8,13 Di-tert-amyl peroxide UN3107 ≤100 OP8 1,1-Di-(tert-amylperoxy)cyclohexane UN3103 ≤82 ≥18 OP6 Dibenzoyl peroxide UN3102 >51-100 ≤48 OP2 3 Dibenzoyl peroxide UN3102 >77-94 ≥6 OP4 3 Dibenzoyl peroxide UN3104 ≤77 ≥23 OP6 Dibenzoyl peroxide UN3106 ≤62 ≥28 ≥10 OP7 Dibenzoyl peroxide [as a paste] UN3106 >52-62 OP7 21 Dibenzoyl peroxide UN3106 >35-52 ≥48 OP7 Dibenzoyl peroxide UN3107 >36-42 ≥18 ≤40 OP8 Dibenzoyl peroxide [as a paste] UN3108 ≤56.5 ≥15 OP8 Dibenzoyl peroxide [as a paste] UN3108 ≤52 OP8 21 Dibenzoyl peroxide [as a stable dispersion in water] UN3109 ≤42 OP8 Dibenzoyl peroxide Exempt ≤35 ≥65 Exempt Di-(4-tert-butylcyclohexyl)peroxydicarbonate UN3114 ≤100 OP6 +30 +35 Di-(4-tert-butylcyclohexyl)peroxydicarbonate [as a stable dispersion in water] UN3119 ≤42 OP8 +30 +35 Di-tert-butyl peroxide UN3107 >52-100 OP8 Di-tert-butyl peroxide UN3109 ≤52 ≥48 OP8 24 Di-tert-butyl peroxyazelate UN3105 ≤52 ≥48 OP7 2,2-Di-(tert-butylperoxy)butane UN3103 ≤52 ≥48 OP6 1,6-Di-(tert-butylperoxycarbonyloxy)hexane UN3103 ≤72 ≥28 OP5 Start Printed Page 76163 1,1-Di-(tert-butylperoxy)cyclohexane UN3101 >80-100 OP5 1,1-Di-(tert-butylperoxy)cyclohexane UN3103 >52-80 ≥20 OP5 1,1-Di-(tert-butylperoxy)cyclohexane UN3105 >42-52 ≥48 OP7 1,1-Di-(tert-butylperoxy)cyclohexane UN3106 ≤42 ≥13 ≥45 OP7 1,1-Di-(tert-butylperoxy)cyclohexane UN3107 ≤27 ≥25 OP8 22 1,1-Di-(tert-butylperoxy)cyclohexane UN3109 ≤42 ≥58 OP8 1,1-Di-(tert-butylperoxy)cyclohexane UN3109 ≤25 ≥25 ≥50 OP8 29 1,1-Di-(tert-butylperoxy)cyclohexane UN3109 ≤13 ≥13 ≥74 OP8 Di-n-butyl peroxydicarbonate UN3115 >27-52 ≥48 OP7 −15 −5 Di-n-butyl peroxydicarbonate UN3117 ≤27 ≥73 OP8 −10 0 Di-n-butyl peroxydicarbonate [as a stable dispersion in water (frozen)] UN3118 ≤42 OP8 −15 −5 Di-sec-butyl peroxydicarbonate UN3113 >52-100 OP4 −20 −10 6 Di-sec-butyl peroxydicarbonate UN3115 ≤52 ≥48 OP7 −15 −5 Di-(2-tert-butylperoxyisopropyl)benzene(s) UN3106 >42-100 ≤57 OP7 1, 9 Di-(2-tert-butylperoxyisopropyl)benzene(s) Exempt ≤42 ≥58 Exempt Di-(tert-butylperoxy)phthalate UN3105 >42-52 ≥48 OP7 Di-(tert-butylperoxy)phthalate [as a paste] UN3106 ≤52 OP7 21 Di-(tert-butylperoxy)phthalate UN3107 ≤42 ≥58 OP8 2,2-Di-(tert-butylperoxy)propane UN3105 ≤52 ≥48 OP7 2,2-Di-(tert-butylperoxy)propane UN3106 ≤42 ≥13 ≥45 OP7 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3101 >90-100 OP5 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3103 >57-90 ≥10 OP5 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3103 ≤77 ≥23 OP5 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3110 ≤57 ≥43 OP8 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3107 ≤57 ≥43 OP8 1,1-Di-(tert-butylperoxy)-3,3,5-trimethylcyclohexane UN3107 ≤32 ≥26 ≥42 OP8 Dicetyl peroxydicarbonate UN3116 ≤100 OP7 +30 +35 Start Printed Page 76164 Dicetyl peroxydicarbonate [as a stable dispersion in water] UN3119 ≤42 OP8 +30 +35 Di-4-chlorobenzoyl peroxide UN3102 ≤77 ≥23 OP5 Di-4-chlorobenzoyl peroxide [as a paste] UN3106 ≤52 OP7 21 Di-4-chlorobenzoyl peroxide Exempt ≤32 ≥68 Exempt Dicumyl peroxide UN3110 >52-100 ≤48 OP8 Dicumyl peroxide Exempt ≤52 ≥48 Exempt Dicyclohexyl peroxydicarbonate UN3112 >91-100 OP3 +10 +15 Dicyclohexyl peroxydicarbonate UN3114 ≤91 ≥9 OP5 +10 +15 Dicyclohexyl peroxydicarbonate [as a stable dispersion in water] UN3119 ≤42 OP8 +15 +20 Didecanoyl peroxide UN3114 ≤100 OP6 +30 +35 2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propane UN3106 ≤42 ≥58 OP7 2,2-Di-(4,4-di(tert-butylperoxy)cyclohexyl)propane UN3107 ≤22 ≥78 OP8 Di-2,4-dichlorobenzoyl peroxide UN3102 ≤77 ≥23 OP5 Di-2,4-dichlorobenzoyl peroxide [as a paste with silicone oil] UN3106 ≤52 OP7 Di-(2-ethoxyethyl) peroxydicarbonate UN3115 ≤52 ≥48 OP7 −10 0 Di-(2-ethylhexyl) peroxydicarbonate UN3113 >77-100 OP5 −20 −10 Di-(2-ethylhexyl) peroxydicarbonate UN3115 ≤77 ≥23 OP7 −15 −5 Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water] UN3117 ≤62 OP8 −15 −5 Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water] UN3119 ≤52 OP8 −15 −5 Di-(2-ethylhexyl) peroxydicarbonate [as a stable dispersion in water (frozen)] UN3120 ≤52 OP8 −15 −5 2,2-Dihydroperoxypropane UN3102 ≤27 ≥73 OP5 Di-(1-hydroxycyclohexyl)peroxide UN3106 ≤100 OP7 Diisobutyryl peroxide UN3111 >32-52 ≥48 OP5 −20 −10 Diisobutyryl peroxide UN3115 ≤32 ≥68 OP7 −20 −10 Diisopropylbenzene dihydroperoxide UN3106 ≤82 ≥5 ≥5 OP7 17 Diisopropyl peroxydicarbonate UN3112 >52-100 OP2 −15 −5 Diisopropyl peroxydicarbonate UN3115 ≤52 ≥48 OP7 −20 −10 Diisopropyl peroxydicarbonate UN3115 ≤28 ≥72 OP7 −15 −5 Dilauroyl peroxide UN3106 ≤100 OP7 Start Printed Page 76165 Dilauroyl peroxide [as a stable dispersion in water] UN3109 ≤42 OP8 Di-(3-methoxybutyl) peroxydicarbonate UN3115 ≤52 ≥48 OP7 −5 +5 Di-(2-methylbenzoyl)peroxide UN3112 ≤87 ≥13 OP5 +30 +35 Di-(4-methylbenzoyl)peroxide [as a paste with silicone oil] UN3106 ≤52 OP7 Di-(3-methylbenzoyl) peroxide + Benzoyl (3-methylbenzoyl) peroxide + Dibenzoyl peroxide UN3115 ≤20+≤18+≤4 ≥58 OP7 +35 +40 2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane UN3102 >82-100 OP5 2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane UN3106 ≤82 ≥18 OP7 2,5-Dimethyl-2,5-di-(benzoylperoxy)hexane UN3104 ≤82 ≥18 OP5 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3105 >52-100 OP7 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3108 ≤77 ≥23 OP8 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane UN3109 ≤52 ≥48 OP8 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexane [as a paste] UN3108 ≤47 OP8 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3101 >86-100 OP5 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3103 >52-86 ≥14 OP5 2,5-Dimethyl-2,5-di-(tert-butylperoxy)hexyne-3 UN3106 ≤52 ≥48 OP7 2,5-Dimethyl-2,5-di-(2-ethylhexanoylperoxy)hexane UN3113 ≤100 OP5 +20 +25 2,5-Dimethyl-2,5-dihydroperoxyhexane UN3104 ≤82 ≥18 OP6 2,5-Dimethyl-2,5-di-(3,5,5-trimethylhexanoylperoxy)hexane UN3105 ≤77 ≥23 OP7 1,1-Dimethyl-3-hydroxybutylperoxyneoheptanoate UN3117 ≤52 ≥48 OP8 0 +10 Dimyristyl peroxydicarbonate UN3116 ≤100 OP7 +20 +25 Dimyristyl peroxydicarbonate [as a stable dispersion in water] UN3119 ≤42 OP8 +20 +25 Di-(2-neodecanoylperoxyisopropyl)benzene UN3115 ≤52 ≥48 OP7 −10 0 Di-n-nonanoyl peroxide UN3116 ≤100 OP7 0 +10 Di-n-octanoyl peroxide UN3114 ≤100 OP5 +10 +15 Di-(2-phenoxyethyl)peroxydicarbonate UN3102 >85-100 OP5 Di-(2-phenoxyethyl)peroxydicarbonate UN3106 ≤85 ≥15 OP7 Dipropionyl peroxide UN3117 ≤27 ≥73 OP8 +15 +20 Start Printed Page 76166 Di-n-propyl peroxydicarbonate UN3113 ≤100 OP3 −25 −15 Di-n-propyl peroxydicarbonate UN3113 ≤77 ≥23 OP5 −20 −10 Disuccinic acid peroxide UN3102 >72-100 OP4 18 Disuccinic acid peroxide UN3116 ≤72 ≥28 OP7 +10 +15 Di-(3,5,5-trimethylhexanoyl)peroxide UN3115 >38-82 ≥18 OP7 0 +10 Di-(3,5,5-trimethylhexanoyl)peroxide [as a stable dispersion in water] UN3119 ≤52 OP8 +10 +15 Di-(3,5,5-trimethylhexanoyl)peroxide UN3119 ≤38 ≥62 OP8 +20 +25 Ethyl 3,3-di-(tert-amylperoxy)butyrate UN3105 ≤67 ≥33 OP7 Ethyl 3,3-di-(tert-butylperoxy)butyrate UN3103 >77-100 OP5 Ethyl 3,3-di-(tert-butylperoxy)butyrate UN3105 ≤77 ≥23 OP7 Ethyl 3,3-di-(tert-butylperoxy)butyrate UN3106 ≤52 ≥48 OP7 1-(2-ethylhexanoylperoxy)-1,3-Dimethylbutyl peroxypivalate UN3115 ≤52 ≥45 ≥10 OP7 −20 −10 tert-Hexyl peroxyneodecanoate UN3115 ≤71 ≥29 OP7 0 +10 tert-Hexyl peroxypivalate UN3115 ≤72 ≥28 OP7 +10 +15 Isopropyl sec-butyl peroxydicarbonat +Di-sec-butyl peroxydicarbonate+Di-isopropyl peroxydicarbonate UN3111 ≤52+≤28+≤22 OP5 −20 −10 Isopropyl sec-butyl peroxydicarbonate+Di-sec-butyl peroxydicarbonate+Di-isopropyl peroxydicarbonate UN3115 ≤32+≤15−18+≤12−15 ≥38 OP7 −20 −10 Isopropylcumyl hydroperoxide UN3109 ≤72 ≥28 OP8 13 p-Menthyl hydroperoxide UN3105 > 72-100 OP7 13 p-Menthyl hydroperoxide UN3109 ≤72 ≥28 OP8 Methylcyclohexanone peroxide(s) UN3115 ≤67 ≥33 OP7 +35 +40 Methyl ethyl ketone peroxide(s) UN3101 ≤52 ≥48 OP5 5, 13, 29 Methyl ethyl ketone peroxide(s) UN3105 ≤45 ≥55 OP7 5, 29 Methyl ethyl ketone peroxide(s) UN3107 ≤40 ≥60 OP8 7 Methyl isobutyl ketone peroxide(s) UN3105 ≤62 ≥19 OP7 5, 23 Organic peroxide, liquid, sample UN3103 OP2 12 Organic peroxide, liquid, sample, temperature controlled UN3113 OP2 12 Organic peroxide, solid, sample UN3104 OP2 12 Organic peroxide, solid, sample, temperature controlled UN3114 OP2 12 Start Printed Page 76167 Peroxyacetic acid, type D, stabilized UN3105 ≤43 OP7 13, 20 Peroxyacetic acid, type E, stabilized UN3107 ≤43 OP8 13, 20 Peroxyacetic acid, type F, stabilized UN3109 ≤43 OP8 13, 20, 28 Peroxyacetic acid or peracetic acid [with not more than 7% hydrogen peroxide] UN3107 ≤36 ≥15 OP8 13, 20, 28, 29 Peroxyacetic acid or peracetic acid [with not more than 20% hydrogen peroxide] Exempt ≤6 ≥60 Exempt 28, 29 Peroxyacetic acid or peracetic acid [with not more than 26% hydrogen peroxide] UN3109 ≤17 OP8 13, 20, 28, 29 Peroxylauric acid UN3118 ≤100 OP8 +35 +40 Pinanyl hydroperoxide UN3105 >56-100 OP7 13 Pinanyl hydroperoxide UN3109 ≤56 ≥44 OP8 Polyether poly-tert-butylperoxycarbonate UN3107 ≤52 ≥48 OP8 Tetrahydronaphthyl hydroperoxide UN3106 ≤100 OP7 1,1,3,3-Tetramethylbutyl hydroperoxide UN3105 ≤100 OP7 1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate UN3115 ≤100 OP7 +15 +20 1,1,3,3-Tetramethylbutyl peroxyneodecanoate UN3115 ≤72 ≥28 OP7 -5 +5 1,1,3,3-Tetramethylbutyl peroxyneodecanoate [as a stable dispersion in water] UN3119 ≤52 OP8 −5 +5 1,1,3,3-tetramethylbutyl peroxypivalate UN3115 ≤77 ≥23 OP7 0 +10 3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane UN3105 ≤42 ≥58 OP7 26 Notes
1. For domestic shipments, OP8 is authorized.
2. Available oxygen must be <4.7%.
3. For concentrations <80% OP5 is allowed. For concentrations of at least 80% but <85%, OP4 is allowed. For concentrations of at least 85%, maximum package size is OP2.
4. The diluent may be replaced by di-tert-butyl peroxide.
5. Available oxygen must be ≤9% with or without water.
6. For domestic shipments, OP5 is authorized.
7. Available oxygen must be ≤8.2% with or without water.
8. Only non-metallic packagings are authorized.
9. For domestic shipments this material maybe transported under the provisions of paragraph (h)(3)(xii) of this section.
10. [Reserved]
11. [Reserved]
12. Samples may only be offered for transportation under the provisions of paragraph (c)(2) of this section.
13. “Corrosive” subsidiary risk label is required.
14. [Reserved]
15. No “Corrosive” subsidiary risk label is required for concentrations below 80%.
16. With <6% di-tert-butyl peroxide.
17. With ≥8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene.
18. Addition of water to this organic peroxide will decrease its thermal stability.
19. [Reserved]
20. Mixtures with hydrogen peroxide, water and acid(s).
21. With diluent type A, with or without water.
22. With ≥36% diluent type A by mass, and in addition ethylbenzene.
23. With ≥19% diluent type A by mass, and in addition methyl isobutyl ketone.
24. Diluent type B with boiling point >100 C.
25. No “Corrosive” subsidiary risk label is required for concentrations below 56%.
26. Available oxygen must be ≤7.6%.
27. Formulations derived from distillation of peroxyacetic acid originating from peroxyacetic acid in a concentration of not more than 41% with water, total active oxygen less than or equal to 9.5% (peroxyacetic acid plus hydrogen peroxide).
28. For the purposes of this section, the names “Peroxyacetic acid” and “Peracetic acid” are synonymous.
29. For international transportation, shipments of this material must be accompanied by a Competent Authority approval from the Associate Administrator.
(d) Packing Method Table. Packagings for organic peroxides and self-reactive substances are listed in the Maximum Start Printed Page 76168Quantity per Packing Method Table. The packing methods are designated OP1 to OP8. The quantities specified for each packing method represent the maximum that is authorized.
(1) The following types of packagings are authorized:
(i) Drums: 1A1, 1A2, 1B1, 1B2, 1D, 1G, 1H1, 1H2;
(ii) Jerricans: 3A1, 3A2, 3B1, 3B2, 3H1, 3H2;
(iii) Boxes: 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2, 4A, 4B; or
(iv) Composite packagings with a plastic inner receptacle: 6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1, 6HH2.
(2) Metal packaging (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8.
(3) In combination packagings, glass receptacles are used only as inner packagings with a maximum content of 0.5 kg for solids or 0.5 L for liquids.
(4) The maximum quantity per packaging or package for Packing Methods OP1-OP8 must be as follows:
Maximum Quantity Per Packaging/Package
[For Packing Methods OP1 to OP8]
Maximum quantity Packing Method OP1 OP2 OP3 OP4 1 OP5 OP6 OP7 OP8 Solids and combination packagings (liquid and solid) (kg) 0.5 0.5/10 5 5 25 50 50 2 400 Liquids (L) 0.5 5 30 60 60 3 225 1 If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package. 2 60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg. 3 60 L for jerricans. (e) Organic Peroxide IBC Table. The following Organic Peroxide IBC Table specifies, by technical name, those organic peroxides that are authorized for transportation in certain IBCs and not subject to the approval provisions of § 173.128 of this part. Additional requirements for authorized IBCs are found in paragraph (f) of this section.
Organic Peroxide IBC Table
UN No. Organic peroxide Type of IBC Maximum quantity (litres) Control temperature Emergency temperature 3109 ORGANIC PEROXIDE, TYPE F, LIQUID tert-Butyl hydroperoxide, not more than 72% with water 31A 1250 tert-Butyl peroxyacetate, not more than 32% in diluent type A 31A 1250 31HA1 1000 tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 32% in diluent type A 31A 1250 31HA1 1000 Cumyl hydroperoxide, not more than 90% in diluent type A 31HA1 1250 Dibenzoyl peroxide, not more than 42% as a stable dispersion 31H1 1000 Di-tert-butyl peroxide, not more than 52% in diluent type B 31A 1250 31HA1 1000 1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A 31H1 1000 Dicumyl peroxide, less than or equal to 100% 31A 1250 31HA1 1000 Dilauroyl peroxide, not more than 42%, stable dispersion, in water 31HA1 1000 Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A 31HA1 1250 p-Menthyl hydroperoxide, not more than 72% in diluent type A 31HA1 1250 Peroxyacetic acid, stabilized, not more than 17% 31H1 1500 31HA1 1500 31A 1500 Peroxyacetic acid, with not more than 26% hydrogen peroxide 31A 1500 31HA1 1500 Peroxyacetic acid, type F, stabilized 31A 1500 31HA1 1500 3110 ORGANIC PEROXIDE TYPE F, SOLID Dicumyl peroxide, less than or equal to 100% 31A 2000 Start Printed Page 76169 31H1 31HA1 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B 31HA1 1000 +30 °C +35 °C 31A 1250 +30 °C +35 °C tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A 31A 1250 0 °C +10 °C tert-Butyl peroxyneodecanoate, not more than 42% stable dispersion, in water 31A 1250 −5 °C +5 °C tert-Butyl peroxypivalate, not more than 27% in diluent type B 31HA1 1000 +10 °C +15 °C 31A 1250 +10 °C +15 °C Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1250 −15 °C −5 °C Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water 31A 1250 +10 °C +15 °C Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1000 +30 °C +35 °C Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1000 +30 °C +35 °C Di-(2-ethylhexyl) peroxydicarbonate, not more than 52%, stable dispersion, in water 31A 1250 −20 °C −10 °C Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water 31HA1 1000 +15 °C +20 °C Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 38% in diluent type A 31HA1 1000 +10 °C +15 °C 31A 1250 +10 °C +15 °C Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water 31A 1250 +10 °C +15 °C 1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water 31A 1250 −5 °C +5 °C (f) IBCs. IBCs are authorized subject to the conditions and limitations of this section if the IBC type is authorized according to paragraph (e) of this section, as applicable, and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group II performance level. Type F organic peroxides or self-reactive substances are not authorized for transportation in IBCs other than those specified, unless approved by the Associate Administrator.
(1) IBCs shall be provided with a device to allow venting during transportation. The inlet to the pressure relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation.
(2) To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (h)(3)(v) of this section. The control and emergency temperatures specified in the Organic Peroxide IBC Table are based on a non-insulated IBC.
(g) Organic Peroxide Portable Tank Table. The following Organic Peroxide Portable Tank Table provides certain portable tank requirements and identifies, by technical name, those organic peroxides that are authorized for transportation in the bulk packagings listed in paragraph (h). Organic peroxides listed in this table, provided they meet the specific packaging requirements found in paragraph (h), are not subject to the approval provisions of § 173.128 of this part. Start Printed Page 76170
Start Printed Page 76172Organic Peroxide Portable Tank Table
UN No. Hazardous material Minimum test pressure (bar) Minimum shell thickness (mm-reference steel) See. . . Bottom opening requirements See. . . Pressure-relief requirements See. . . Filling limits Control temperature Emergency temperature 3109 ORGANIC PEROXIDE, TYPE F, LIQUID tert-Butyl hydroperoxide, not more than 72% with water *Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) Cumyl hydro-peroxide, not more than 90% in diluent type A 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) Di-tert-butyl peroxide, not more 32% in diluent type A 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) Dicumyl peroxide, less than or equal to 100% in diluent type B 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) Isopropyl cumyl hydroperoxide, not more 72% in diluent type A 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) p-Menthyl hydro-peroxide, not more 72% in diluent type A 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) Pinanyl hydro-peroxide, not more than 56% in diluent type A 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) 3110 ORGANIC PEROXIDE, TYPE F, SOLID Dicumyl peroxide less than or equal to 100% with inert solids *Maximum quantity per portable tank 2,000 kg 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) 3119 ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED tert-Butyl peroxyacetate, not more than 32% in diluent type B 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) +30 °C +35 °C tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent B 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) +15 °C +20 °C tert-Butylperoxypivalate, not more than 27% in diluent type B 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) +5 °C +10 °C tert-Butyl peroxy-3,5,5-trimethyl-hexanoate, not more than 32% in diluent type B 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) +35 °C +40 °C Start Printed Page 76171 Di-(3,5,5-trimethyl-hexanoyl) peroxide, not more than 38% in diluent type A 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) 0 °C +5 °C Peroxyacetic acid, distilled, stabilized, not more than 41% 4 § 178.274(d)(2) § 178.275(d)(3) § 178.275(g)(1) Not more than 90% at 59 °F (15 °C) +30 °C +35 °C (h) Bulk packagings other than IBCs. The following bulk packagings are authorized, subject to the conditions and limitations of this section, if the organic peroxide is listed in the Organic Peroxide Portable Tank Table and bulk packagings are authorized, or if the organic peroxide is specifically authorized for transport in a bulk packaging by this paragraph (h), and the bulk packaging conforms to the requirements of this subchapter:
(1) Rail cars. Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 fusion-weld tank car tanks are authorized. DOT 103W, 111A60F1 and 111A60W1 tank car tanks must have bottom outlets effectively sealed from inside. Gauging devices are required on DOT 103W tank car tanks. Riveted tank car tanks are not authorized.
(2) Cargo tanks. Specification MC 307, MC 310, MC 311, MC 312, DOT 407, and DOT 412 cargo tank motor vehicles with a tank design pressure of at least 172 kPa (25 psig) are authorized.
(3) Portable tanks. The following requirements apply to portable tanks intended for the transport of organic peroxides or self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of paragraph (g) of this section, are authorized. Type F organic peroxide or self-reactive substance formulations other than those indicated in the Organic Peroxide Portable Tank Table may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply:
(i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4 bar).
(ii) The portable tank must be fitted with temperature-sensing devices.
(iii) The portable tank must be fitted with pressure relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell.
(iv) The pressure relief devices must consist of reclosing devices fitted to prevent significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 °C (122 °F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The pressure relief devices must not allow liquid to escape in the event the portable tank is overturned in a loaded condition.
(v)(A) The emergency-relief devices may be of the reclosing or frangible types, or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula:
Where:
q = heat absorption (W)
A = wetted area (m2)
F = insulation factor (−)
(B) Insulation factor (F) in the formula in paragraph (h)(3)(v)(A) of this section equals 1 for non-insulated vessels and for insulated vessels F is calculated using the following formula:
Where:
U = K/L = heat transfer coefficient of the insulation (W·m−2·K−1); where K = heat conductivity of insulation layer (W·m−1·K−1), and L = thickness of insulation layer (m).
TPO = temperature of material at relieving conditions (K).
(vi) The start-to-discharge pressure of emergency-relief devices must be higher than that specified for the pressure relief devices in paragraph (h)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank.
Note to Paragraph (h)(3)(vi):
An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). A second example of a test method for venting sizing is given in the American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2) (Informational materials not requiring incorporation by reference, see § 171.7(b)).
(vii) For insulated portable tanks, the capacity and setting of emergency-relief devices must be determined assuming a loss of insulation from 1% of the surface area.
(viii) Vacuum-relief devices and reclosing devices on portable tanks used for flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided.
(ix) Service equipment such as devices and external piping must be designed and constructed so that no hazardous material remains in them after filling the portable tank.
(x) Portable tanks may be either insulated or protected by a sun-shield. If the SADT of the hazardous material in the portable tank is 55 °C (131 °F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal.
(xi) The degree of filling must not exceed 90% at 15 °C (59 °F).
(xii) DOT 57 metal portable tanks are authorized only for tert-butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s)), dicumyl peroxide and mixtures of two or more of these peroxides. DOT 57 portable tanks must conform to the venting requirements of paragraph (f) of this section. These portable tanks are not subject to any other requirements of paragraph (h) of this section.
(4) For tertiary butyl hydroperoxide (TBHP), each tank car, cargo tank or portable tank must contain 7.6 cm (3.0 inches) low density polyethylene (PE) saddles having a melt index of at least 0.2 grams per 10 minutes (for example see, ASTM D1238, condition E) as part of the lading, with a ratio of PE to TBHP over a range of 0.008 to 0.012 by mass. Alternatively, plastic or metal containers equipped with fusible plugs having a melting point between 69 °C (156 °F) and 71 °C (160 °F) and filled with a sufficient quantity of water to dilute the TBHP to 65% or less by mass may be used. The PE saddles must be visually inspected after each trip and, at a minimum, once every 12 months, and replaced when discoloration, fracture, severe deformation, or other indication of change is noted.
43. Section 173.226 is revised to read as follows:
End Amendment PartMaterials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A.Division 6.1, Packing Group I, Zone A poisonous by inhalation (see § 173.133) must be packed in non-bulk packagings in accordance with the following paragraphs:
(a) In seamless specification cylinders conforming to the requirements of § 173.40.
(b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 drums further packed in a 1A2 or 1H2 drum. Both inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package Start Printed Page 76173intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. All outer drums, even those tested to contain inner packaging or as single packagings for solids, must withstand a hydrostatic test pressure of 100 kPa (15 psig). The outer drum must have a minimum thickness of 1.35 mm (0.053 inch) for a 1A2 outer drum or 6.3 mm (0.248 inch) for a 1H2 outer drum. In addition, the inner drum must—
(1) Be capable of satisfactorily withstanding the hydrostatic pressure test in § 178.605 of this subchapter at a test pressure of 300 kPa (45 psig);
(2) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an internal air pressure of at least twice the vapor pressure at 55 °C (131 °F) of the material to be packaged;
(3) Have screw-type closures that are—
(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;
(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and
(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).
(4) Have a minimum thickness as follows:
(i) For a 1A1 or 1N1 drum, 1.3 mm (0.051 inch);
(ii) For a 1B1 drum, 3.9 mm (0.154 inch);
(iii) For a 1H1 drum, 3.16 mm (0.124 inch); and
(iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and the outer steel drum shall be 0.96 mm (0.0378 inch).
(5) Be isolated from the outer drum by a shock-mitigating, non-reactive material, which completely surrounds the inner packaging on all sides.
(c) In combination packagings, consisting of an inner packaging system and an outer packaging, as follows:
(1) Outer packagings:
Steel drum: 1A2
Aluminum drum: 1B2
Metal drum, other than steel or aluminum: 1N2
Plywood drum: 1D
Fiber drum: 1G
Plastic drum: 1H2
Steel box: 4A
Aluminum box: 4B
Natural wood box: 4C1 or 4C2
Plywood box: 4D
Reconstituted wood box: 4F
Fiberboard box: 4G
Expanded plastic box: 4H2
Solid plastic box: 4H2
(2) Inner packaging system. The inner packaging system consists of two packagings:
(i) an impact-resistant receptacle of glass, earthenware, plastic or metal securely cushioned with a non-reactive, absorbent material, and
(A) Capacity of each inner receptacle may not exceed 4 L (1 gallon).
(B) An inner receptacle that has a closure must have a closure which is physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation.
(ii) Packed within a leak-tight packaging of metal or plastic.
(iii) This combination packaging in turn is packed within the outer packaging.
(A) The total amount of liquid contained in the outer packaging may not exceed 16 L (4 gallons).
(iv) the inner packaging system must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level when subjected to the following tests:
(A) § 178.603—Drop Test
(B) § 178.604—Leakproofness Test
(C) § 178.605—Hydrostatic Pressure Test
(v) The inner packaging system must meet the above tests without the benefit of the outer packaging.
(vi) The leakproofness and hydrostatic pressure test may be conducted on either the inner receptacle or the outer packaging of the inner packaging system.
(vii) In addition to the requirements in § 173.226(b), the outer package must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level as applicable for the type of package being used.
(d) If approved by the Associate Administrator, 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, palletizes the drums, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.
(e) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with § 173.28 using a minimum test pressure as indicated in paragraph (b)(2) of this section.
44. Section 173.227 is revised to read as follows:
End Amendment PartMaterials poisonous by inhalation. Division 6.1, Packing Group I, Hazard Zone B.(a) In packagings as authorized in § 173.226 and seamless and welded specification cylinders conforming to the requirements of § 173.40.
(b) 1A1, 1B1, 1N1 or 1H1 drum or 6HA1 composite further packed in a 1A2 or 1H2 drum. Both the inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. The outer drum must have a minimum thickness of 1.35 mm (0.053 inches) for a 1A2 outer drum or 6.30 mm (0.248 inches) for a 1H2 outer drum. Outer 1A2 and 1H2 drums must withstand a hydrostatic test pressure of 100 kPa (15 psig). Capacity of the inner drum may not exceed 220 liters. In addition, the inner drum must conform to all of the following requirements:
(2) Have screw closures that are—
(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;
(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and
(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).
(3) Have a minimum thickness as follows:
(i) For a 1A1 drum, 0.69 mm (0.027 inch);
(ii) For a 1B1 drum, 2.79 mm (0.110 inch);
(iii) For a 1H1 drum, 1.14 mm (0.045 inch); or
(iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0625 inch), the outer steel drum shall be 0.70 mm (0.027 inch).
(4) Be isolated from the outer drum by a shock-mitigating, non-reactive Start Printed Page 76174material which completely surrounds the inner packaging on all sides.
(5) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with § 173.28 using a minimum test pressure as indicated in paragraph (b)(1) of this section.
(c) 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.
45. In § 173.249, paragraph (c) is revised to read as follows:
End Amendment PartBromine.* * * * *(c) UN portable tanks conforming to tank code T22 (see § 172.102 of this subchapter) or specification IM 101 portable tanks conforming with paragraphs (d) through (f) of this section. Except when transported as a residue, the total quantity in one tank may not be less than 88% nor more than 92% of the volume of the tank.
* * * * *46. In § 173.306, paragraphs (i) and (j) are removed and a new paragraph (i) is added to read as follows:
End Amendment PartLimited quantities of compressed gases.* * * * *(i) Aerosols with a capacity of less than 50 ml. Aerosols, as defined in § 171.8 of this subchapter, with a capacity not exceeding 50 ml and with a pressure not exceeding 970 kPa (141 psig) at 55 °C (131 °F), containing no hazardous materials other than a Division 2.2 gas, are not subject to the requirements of this subchapter.
* * * * *[Amended]47. In § 173.307, paragraph (a)(5) is removed.
End Amendment Part Start Amendment Part48. Section 173.313 is added to read as follows:
End Amendment PartUN Portable Tank Table for Liquefied Compressed Gases.The UN Portable Tank Table for Liquefied Compressed Gases is referenced in § 172.102(c)(7)(iii) of this subchapter for portable tanks that are used to transport liquefied compressed gases. The table applies to each liquefied compressed gas that is identified with Special Provision T50 in Column (7) of the § 172.101 Table. In addition to providing the UN identification number and proper shipping name, the table provides maximum allowable working pressures, bottom opening requirements, pressure relief device requirements, and degree of filling requirements for liquefied compressed gas permitted for transportation in a T50 portable tank. In the minimum test pressure column, “small” means a portable tank with a diameter of 1.5 meters or less when measured at the widest part of the shell, “sunshield” means a portable tank with a shield covering at least the upper third of the shell, “bare” means no sunshield or insulation is provided, and “insulated” means a complete cladding of sufficient thickness of insulating material necessary to provide a minimum conductance of not more than 0.67 w/m2/k. In the pressure relief requirements column, the word “Normal” denotes that a frangible disc as specified in § 178.276(e)(3) of this subchapter is not required.
UN Portable Tank Table for Liquefied Compressed Gases
UN No. Non-refrigerated liquefied compressed gases Minimum design pressure (bar) small; bare; sunshield; insulated Openings below liquid level Pressure relief requirements (See § 178.276(e)) Maximum filling density (kg/l) 1005 Ammonia, anhydrous 29.0 Allowed § 178.276(e)(3) 0.53 25.7 22.0 19.7 1009 Bromotrifluoromethane or Refrigerant gas R 13B1 38.0 Allowed Normal 1.13 34.0 30.0 27.5 1010 Butadienes, stabilized 7.5 Allowed Normal 0.55 7.0 7.0 7.0 1011 Butane 7.0 Allowed Normal 0.51 7.0 7.0 7.0 1012 Butylene 8.0 Allowed Normal 0.53 7.0 7.0 7.0 1017 Chlorine 19.0 Not § 178.276(e)(3) 1.25 17.0 Allowed 15.0 13.5 1018 Chlorodifluoromethane or Refrigerant gas R 22 26.0 Allowed Normal 1.03 24.0 21.0 19.0 1020 Chloropentafluoroethane or Refrigerant gas R 115 23.0 Allowed Normal 1.06 20.0 18.0 16.0 Start Printed Page 76175 1021 1-Chloro-1,2,2,2-tetrafluoroethane or Refrigerant gas R 124 10.3 Allowed Normal 1.2 9.8 7.9 7.0 1027 Cyclopropane 18.0 Allowed Normal 0.53 16.0 14.5 13.0 1028 Dichlorodifluoromethane or Refrigerant gas R 12 16.0 Allowed Normal 1.15 15.0 13.0 11.5 1029 Dichlorofluoromethane or Refrigerant gas R 21 7.0 Allowed Normal 1.23 7.0 7.0 7.0 1030 1,1-Difluoroethane or Refrigerant gas R 152a 16.0 Allowed Normal 0.79 14.0 12.4 11.0 1032 Dimethylamine, anhydrous 7.0 Allowed Normal 0.59 7.0 7.0 7.0 1033 Dimethyl ether 15.5 Allowed Normal 0.58 13.8 12.0 10.6 1036 Ethylamine 7.0 Allowed Normal 0.61 7.0 7.0 7.0 1037 Ethyl chloride 7.0 Allowed Normal 0.8 7.0 7.0 7.0 1040 Ethylene oxide with nitrogen up to a total pressure of 1MPa (10 bar) at 50 °C Only authorized in 10 bar insulated portable tanks— Not Allowed § 178.276(e)(3) 0.78 1041 Ethylene oxide and carbon dioxide mixture with more than 9% but not more than 87% ethylene oxide See MAWP definition in § 178.276(a) Allowed Normal See § 173.32(f) 1055 Isobutylene 8.1 Allowed Normal 0.52 7.0 7.0 7.0 1060 Methyl acetylene and propadiene mixture, stabilized 28.0 Allowed Normal 0.43 24.5 22.0 20.0 1061 Methylamine, anhydrous 10.8 Allowed Normal 0.58 9.6 7.8 7.0 1062 Methyl bromide 7.0 Not Allowed § 178.276(e)(3) 1.51 7.0 7.0 7.0 1063 Methyl chloride or Refrigerant gas R 40 14.5 Allowed Normal 0.81 12.7 11.3 10.0 1064 Methyl mercaptan 7.0 Not Allowed § 178.276(e)(3) 0.78 7.0 7.0 7.0 Start Printed Page 76176 1067 Dinitrogen tetroxide 7.0 Not Allowed § 178.276(e)(3) 1.3 7.0 7.0 7.0 1075 Petroleum gas, liquefied See MAWP definition in § 178.276(a) Allowed Normal See § 173.32(f) 1077 Propylene 28.0 Allowed Normal 0.43 24.5 22.0 20.0 1078 Refrigerant gas, n.o.s. See MAWP definition in § 178.276(a) Allowed Normal See § 173.32(f) 1079 Sulphur dioxide 11.6 Not Allowed § 178.276(e)(3) 1.23 10.3 8.5 7.6 1082 Trifluorochloroethylene, stabilized or Refrigerant gas R 1113 17.0 Not Allowed § 178.276(e)(3) 1.13 15.0 13.1 11.6 1083 Trimethylamine, anhydrous 7.0 Allowed Normal 0.56 7.0 7.0 7.0 1085 Vinyl bromide, stabilized 7.0 Allowed Normal 1.37 7.0 7.0 7.0 1086 Vinyl chloride, stabilized 10.6 Allowed Normal 0.81 9.3 8.0 7.0 1087 Vinyl methyl ether, stabilized 7.0 Allowed Normal 0.67 7.0 7.0 7.0 1581 Chloropicrin and methyl bromide mixture 7.0 Not Allowed § 178.276(e)(3) 1.51 7.0 7.0 7.0 1582 Chloropicrin and methyl chloride mixture 19.2 Not Allowed § 178.276(e)(3) 0.81 16.9 15.1 13.1 1858 Hexafluoropropylene compressed or Refrigerant gas R 1216 19.2 Allowed Normal 1.11 16.9 15.1 13.1 1912 Methyl chloride and methylene chloride mixture 15.2 Allowed Normal 0.811954 1954 n.o.s. 13.0 11.6 10.1 NA Insecticide gases, flammable, See MAWP definition in § 178.276(a) Allowed Normal § 173.32(f) 1958 1,2-Dichloro-1,1,2,2-tetrafluoroethane or Refrigerant gas R 114 7.0 Allowed Normal 1.3 7.0 7.0 7.0 1965 Hydrocarbon gas, mixture liquefied, n.o.s. See MAWP definition in 178.276(a) Allowed Normal See § 173.32(f) Start Printed Page 76177 1969 Isobutane 8.5 Allowed Normal 0.49 7.5 7.0 7.0 1973 Chlorodifluoromethane and chloropentafluoroethane mixture with fixed boiling point, with approximately 49% chlorodifluoromethane or Refrigerant gas R 502 28.3 Allowed Normal 1.05 25.3 22.8 20.3 1974 Chlorodifluorobromomethane or Refrigerant gas R 12B1 7.4 Allowed Normal 1.61 7.0 7.0 7.0 1976 Octafluorocyclobutane or Refrigerant gas RC 318 8.8 Allowed Normal 1.34 7.8 7.0 7.0 1978 Propane 22.5 Allowed Normal 0.42 20.4 18.0 16.5 1983 1-Chloro-2,2,2-trifluoroethane or Refrigerant gas R 133a 7.0 Allowed Normal 1.18 7.0 7.0 7.0 2035 1,1,1-Trifluoroethane compressed or Refrigerant gas R 143a 31.0 Allowed Normal 0.76 27.5 24.2 21.8 2424 Octafluoropropane or Refrigerant gas R 218 23.1 Allowed Normal 1.07 20.8 18.6 16.6 2517 1-Chloro-1,1-difluoroethane or Refrigerant gas R 142b 8.9 Allowed Normal 0.99 7.8 7.0 7.0 2602 Dichlorodifluoromethane and difluoroethane azeotropic mixture with approximately 74% dichlorodifluoromethane or Refrigerant gas R 500 20.0 Allowed Normal 1.01 18.0 16.0 14.5 3057 Trifluoroacetyl chloride 14.6 Not allowed § 178.276(e)(3) 1.17 12.9 11.3 9.9 3070 Ethylene oxide and dichlorodifluoromethane mixture with not more than 12.5% ethylene oxide 14.0 Allowed § 178.276(e)(3) 1.09 12.0 11.0 9.0 3153 Perfluoro (methyl vinyl ether) 14.3 Allowed Normal 1.14 13.4 11.2 10.2 3159 1,1,1,2-Tetrafluoroethane or Refrigerant gas R 134a 17.7 Allowed Normal 1.04 15.7 13.8 12.1 3161 Liquefied gas, flammable, n.o.s. See MAWP definition in § 178.276(a) Allowed Normal § 173.32(f) 3163 Liquefied gas, n.o.s. See MAWP definition in § 178.276(a) Allowed Normal § 173.32(f) Start Printed Page 76178 3220 Pentafluoroethane or Refrigerant gas R 125 34.4 Allowed Normal 0.95 30.8 27.5 24.5 3252 Difluoromethane or Refrigerant gas R 32 43.0 Allowed Normal 0.78 39.0 34.4 30.5 3296 Heptafluoropropane or Refrigerant gas R 227 16.0 Allowed Normal 1.2 14.0 12.5 11.0 3297 Ethylene oxide and chlorotetrafluoroethane mixture, with not more than 8.8% ethylene oxide 8.1 Allowed Normal 1.16 7.0 7.0 7.0 3298 Ethylene oxide and pentafluoroethane mixture, with not more than 7.9% ethylene oxide 25.9 Allowed Normal 1.02 23.4 20.9 18.6 3299 Ethylene oxide and tetrafluoroethane mixture, with not more than 5.6% ethylene oxide 16.7 Allowed Normal 1.03 14.7 12.9 11.2 3318 Ammonia solution, relative density less than 0.880 at 15 °C in water, with more than 50% ammonia See MAWP definition in § 178.276(a) Allowed § 178.276(e)(3) § 173.32(f) 3337 Refrigerant gas R 404A 31.6 Allowed Normal 0.84 28.3 25.3 22.5 3338 Refrigerant gas R 407A 31.3 Allowed Normal 0.95 28.1 25.1 22.4 3339 Refrigerant gas R 407B 33.0 Allowed Normal 0.95 29.6 26.5 23.6 3340 Refrigerant gas R 407C 29.9 Allowed Normal 0.95 26.8 23.9 21.3 49. In § 173.315, paragraph (a) introductory text is revised to read as follows:
End Amendment PartCompressed gases in cargo tanks and portable tanks.(a) Liquefied compressed gases that are transported in UN portable tanks must be loaded and offered for transportation in accordance with the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313. A liquefied compressed gas offered for transportation in a cargo tank motor vehicle or a portable tank must be prepared in accordance with this section, §§ 173.32 and 173.33 and subpart E or subpart G of part 180 of this subchapter, as applicable. For cryogenic liquids, see § 173.318. For marking requirements, see §§ 172.326 and 172.328 of this subchapter. Except for UN portable tanks, a liquefied compressed gas must be loaded and offered for transportation in accordance with the following table:
* * * * *50. In § 173.323, paragraph (b) is revised to read as follows:
End Amendment PartEthylene oxide.* * * * *(b) Ethylene oxide must be packaged in one of the following:
(1) In hermetically sealed glass or metal inner packagings suitably cushioned in an outer package authorized by § 173.201(b). The maximum quantity permitted in any glass inner packaging is 100 g (3.5 ounces), and the maximum quantity permitted in any metal inner packaging is 340 g (12 ounces). After filling, each inner packaging shall be determined to be leak-tight by placing the inner packaging in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapor pressure of ethylene oxide at 55 °C is achieved. The total quantity in any outer packaging Start Printed Page 76179shall not exceed 100 g (3.5 ounces), and the total quantity in any outer packaging containing only metal inner packagings shall not exceed 2.5 kg (5.5 pounds). Each completed package must be capable of passing all Packing Group I performance tests.
(2) In specification cylinders, as authorized for any compressed gas except acetylene. Pressurizing valves and insulation are required for cylinders over 4 L (1 gallon) capacity. Eductor tubes must be provided for cylinders over 19 L (5 gallons) capacity. Cylinders must be seamless or welded steel (not brazed) with a nominal capacity of no more than 115 L (30 gallons) and may not be liquid full below 82 °C (180 °F). Before each refilling, each cylinder must be tested for leakage at no less than 103.4 kPa (15 psig) pressure. In addition, each cylinder must be equipped with a fusible type relief device with yield temperature of 69 °C to 77 °C (157 °F to 170 °F). The capacity of the relief device and the effectiveness of the insulation must be such that the charged cylinder will not explode when tested by the method described in CGA Pamphlet C-14 or other equivalent method.
(3) In 1A1 steel drums of no more than 231 L (61 gallons) and meeting Packing Group I performance standards. The drum must be lagged of all welded construction with the inner shell having a minimum thickness of 1.7 mm (0.068 inches) and the outer shell having a minimum thickness of 2.4 mm (0.095 inches). Drums must be capable of withstanding a hydrostatic test pressure of 690 kPa (100 psig). Lagging must be of sufficient thickness so that the drum, when filled with ethylene oxide and equipped with the required pressure relief device, will not rupture when exposed to fire. The drum may not be liquid full below 85 °C (185 °F), and must be marked “THIS END UP” on the top head. Before each refilling, each drum must be tested for leakage at no less than 103 kPa (15 psig) pressure. Each drum must be equipped with a fusible type relief device with yield temperature of 69 °C to 77 °C (157 °F to 170 °F), and the capacity of the relief device must be such that the filled drum is capable of passing, without rupture, the test method described in CGA Pamphlet C-14 or other equivalent method.
* * * * *Start Amendment Part50a. In Appendix H to Part 173, the fifth sentence of paragraph 3. and paragraph 3.(a) are revised to read as follows:
End Amendment PartAppendix H to Part 173—Method of Testing for Sustained Combustibility
3. * * * A suitable apparatus is shown in Figure 32.5.2.1 of the UN Manual of Test and Criteria, and the essential dimensions are given in Figures 32.5.2.1 and 32.5.2.2 of the UN Manual and Tests and Criteria. * * *
(a) Gauge, for checking that the height of the center of the gas jet above the top of the test portion well is 2.2 mm (see Figure 32.5.2.1);
* * * * *Start PartPART 175—CARRIAGE BY AIRCRAFT
End Part Start Amendment Part51. The authority citation for part 175 continues to read as follows:
End Amendment Part Start Amendment Part52. In § 175.10, paragraphs (a)(4)(i), (a)(4)(iii), and (a)(18) are revised to read as follows:
End Amendment PartExceptions.(a) * * *
(4) * * *
(i) Non-radioactive medicinal and toilet articles (including aerosols) may be carried in checked or carry-on baggage. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release;
* * * * *(iii) Other aerosols in Division 2.2 with no subsidiary risk may be carried in checked baggage only. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release;
* * * * *(18) Compressed gas cylinders of Division 2.2 worn by passengers for the operation of mechanical limbs and spare cylinders of a similar size for the same purpose in sufficient quantities to ensure an adequate supply for the duration of the journey.
* * * * *53. Section 175.85 is revised by adding new paragraph (j) to read as follows:
End Amendment PartCargo location.* * * * *(j) A package bearing a KEEP AWAY FROM HEAT handling marking must be protected from direct sunshine and stored in a cool and ventilated place, away from sources of heat.
PART 176—CARRIAGE BY VESSEL
End Part Start Amendment Part54. The authority citation for part 176 continues to read as follows:
End Amendment Part Start Amendment Part55. In § 176.2:
End Amendment Part Start Amendment Parta. The definitions for “Explosive article”, “Explosive substance” and “Magazine” are revised.
End Amendment Part Start Amendment Partb. The term “Transport unit” is revised to read “Cargo transport unit”.
End Amendment Part Start Amendment Partc. In the definition “In containers or the like”, the term “transport unit” is removed and the term “cargo transport unit” is added in its place.
End Amendment PartThe revisions and additions read as follows:
* * * * *Cargo transport unit means a transport vehicle, a freight container or a portable tank. A closed cargo transport unit means a cargo transport unit in which the contents are totally enclosed by permanent structures. An open cargo transport unit means a cargo transport unit that is not a closed cargo transport unit. Cargo transport units with fabric sides or tops are not closed cargo transport units for the purposes of this part.
* * * * *Explosive article means an article or device which contains one or more explosive substances. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code.
* * * * *Explosive substance means a solid or liquid material, or a mixture of materials, which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to its surroundings. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code.
* * * * *In containers or the like means any clean, substantial, weatherproof box structure which can be secured to the vessel's structure, including a portable magazine or a closed cargo transport unit. Whenever this stowage is specified, stowage in deckhouses, mast lockers and oversized weatherproof packages (overpacks) is also acceptable.
* * * * *Magazine means an enclosure designed to protect certain goods of Class 1 (explosive) materials from damage by other cargo and adverse weather conditions during loading, unloading, and when in transit; and to prevent unauthorized access. A magazine may be a fixed structure or compartment in the vessel, a closed freight container, a closed transport vehicle, or a portable magazine. Magazines may be positioned in any part of the ship conforming with the relevant provisions for Class 1 (explosive) materials contained in Start Printed Page 76180Subpart G of this part provided that magazines which are fixed structures are sited so that their doors, where fitted, are easily accessible.
* * * * *Start Amendment Part56. Section 176.27 is revised to read as follows:
End Amendment PartCertificate.(a) A carrier may not transport a hazardous material by vessel unless a certificate prepared in accordance with § 172.204 of this subchapter has been received.
(b) In the case of an import or export shipment of a hazardous material that will not be transported by rail, highway, or air, the shipper may certify on the bill of lading or other shipping paper that the hazardous material is properly classed, described, marked, packaged, and labeled according to part 172 of this subchapter or in accordance with the requirements of the IMDG Code (IBR, see § 171.7 of this subchapter). See § 171.12 of this subchapter.
(c)(1) A person responsible for packing or loading a freight container or transport vehicle with packages of hazardous materials for transportation by a manned vessel in ocean or coastwise service, must provide the vessel operator, at the time the shipment is offered for transportation by vessel, with a signed container packing certificate stating, at a minimum, that—
(i) The freight container or transport vehicle is serviceable for the materials loaded therein, contains no incompatible goods, and is properly marked, labeled or placarded, as applicable; and
(ii) When the freight container or transport vehicle contains packages, those packages have been inspected prior to loading, are properly marked, labeled or placarded, as applicable; are not damaged; and are properly secured.
(2) The certification may appear on a shipping paper or on a separate document as a statement, such as “It is declared that the packing of the container has been carried out in accordance with the applicable provisions [of 49 CFR], [of the IMDG Code], or [of 49 CFR and the IMDG Code].”
57. In § 176.63, paragraph (e) is revised to read as follows:
End Amendment PartStowage locations.* * * * *(e) Closed cargo transport unit, for the purpose of stowage of Class 1 (explosive) materials on board a vessel, means a unit which fully encloses the contents by permanent structures and can be secured to the ship's structure, and includes a magazine. Cargo transport units with fabric sides or tops are not closed cargo transport units. Where this stowage is specified, stowage in small compartments such as deck-houses and mast lockers are acceptable alternatives. The floor of any closed cargo transport unit or compartment shall either be constructed of wood, close-boarded or so arranged that goods are stowed on sparred gratings, wooden pallets or dunnage. Provided that the necessary additional specifications are met, a closed cargo transport unit may be used for type “A” or “C” class 1 stowage or as a magazine.”
* * * * *58. In § 176.76, paragraphs (h) and (i) are revised to read as follows:
End Amendment PartTransport vehicles, freight containers, and portable tanks containing hazardous materials.* * * * *(h) A fumigated cargo transport unit may only be transported on board a vessel subject to the following conditions and limitations:
(1) The fumigated cargo transport unit may be placed on board a vessel only if at least 24 hours have elapsed since the unit was last fumigated;
(2) The fumigated cargo transport unit is accompanied by a document showing the date of fumigation and the type and amount of fumigant used;
(3) Prior to loading, the master is informed of the intended placement of the fumigated cargo transport unit on board the vessel and the information provided on the accompanying document;
(4) Equipment that is capable of detecting the fumigant and instructions for the equipment's use is provided on the vessel;
(5) The fumigated cargo transport unit must be stowed at least 5 m from any opening to accommodation spaces;
(6) Fumigated cargo transport units may only be transported on deck on vessels carrying more than 25 passengers; and
(7) Fumigants may not be added to cargo transport units while on board a vessel.
(i) A cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 °C transported on deck must be stowed “away from” possible sources of ignition. In the case of container ships, a distance equivalent to one container space athwartships away from possible sources of ignition applied in any direction will satisfy this requirement.
59. In § 176.83:
End Amendment Part Start Amendment Parta. Paragraphs (a)(5), (d), (e), (f)(1), (f)(3), (g)(1), (g)(2), (g)(3), and (l) are revised;
End Amendment Part Start Amendment Partb. The headings to paragraphs (g) and (f) and the title to Table 176.83(g) are revised; and
End Amendment Part Start Amendment Partc. A new paragraph (m) is added.
End Amendment PartThe revisions and additions read as follows:
Segregation.* * * * *(a) * * *
(5) Whenever hazardous materials are stowed together, whether or not in a cargo transport unit, the segregation of such hazardous materials from others must always be in accordance with the most restrictive requirements for any of the hazardous materials concerned.
* * * * *(d) Segregation in cargo transport units: Two hazardous materials for which any segregation is required may not be stowed in the same cargo transport unit.
(e) Segregation of hazardous materials stowed as breakbulk cargo from those packed in cargo transport units: (1) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in open cargo transport units in accordance with paragraph (c) of this section.
(2) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in closed cargo transport units in accordance with paragraph (c) of this section, except that:
(i) Where “away from” is required, no segregation between packages and the closed cargo transport units is required; and
(ii) Where “separated from” is required, the segregation between the packages and the closed cargo transport units may be the same as for “away from”.
(f) Segregation of cargo transport units on board container vessels: (1) Except for hatchless container ships, this paragraph applies to segregation of cargo transport units that are carried on board container vessels, or on other types of vessels, provided these cargo spaces are properly fitted for permanent stowage of containers during transport.
* * * * *(3) Segregation Table. Table § 176.83(f) sets forth the general requirements for segregation between cargo transport units on board container vessels.
* * * * *(g) Segregation of cargo transport units on board trailerships and trainships: (1) The requirements of this paragraph apply to the segregation of Start Printed Page 76181cargo transport units which are carried on board trailerships and trainships or in “roll-on/roll-off” cargo spaces.
(2) For trailerships and trainships which have spaces suitable for breakbulk cargo, containers, or any other method of stowage, the appropriate paragraph of this section applies to the relevant cargo space.
(3) Segregation Table. Table § 176.83(g) sets forth the general requirements for segregation between transport units on board trailerships and trainships.
Table 176.83(g).—Segregation of Cargo Transport Units on Board Trailerships and Trainships
* * * * *(1) Segregation of containers on board hatchless (open-top) container ships: (1) This paragraph applies to the segregation of cargo transport units that are transported on board hatchless container ships provided that the cargo spaces are properly fitted to give permanent stowage of the cargo transport units during transport.
(2) For container ships that have both hatchless container spaces and other spaces suitable for breakbulk cargo, conventional container stowage, or any other method of stowage, the appropriate requirements of this section apply to the relevant cargo space.
(3) Segregation Table. Table § 176.83(l)(3) sets forth the general requirements for segregation of cargo transport units on board hatchless container ships.
(4) In Table § 176.83(l)(3), a container space means a distance of not less than 6 m (20 feet) fore and aft or not less than 2.5 m (8 feet) athwartship.Start Printed Page 76182
Start Printed Page 76183TABLE 176.83(l)(3)—Segregation of Cargo Transport Units on Board Hatchless Container Ships
VERTICAL HORIZONTAL Segregation requirement Closed versus closed Closed versus open Open versus open Closed versus closed Closed versus open Open versus open On deck Under deck On deck Under deck On deck Under deck “Away from” 1. One on top of the other permitted Open on top of closed permitted Fore and AFT No restriction No restriction No restriction No restriction one container space one container space or one bulkhead Otherwise as for “Open versus open” Athwart-ships No restriction No restriction No restriction No restriction One container space One container space “Separated from” 2. Not in the same vertical line Fore and AFT One container space One container space or one bulkhead One container space one container space or one bulkhead One container space and not in or above same hold One bulkhead Not in the same vertical line As for “open versus open” Athwart-ships One container space One container space Two container spaces Two container spaces Two container spaces and not in or above same hold One bulkhead “Separated by a complete compartment or hold from” 3. Fore and AFT One container space and not in or above same hold One bulkhead One container space and not in or above same hold One bulkhead Two container spaces and not in or above same hold Two bulkheads Athwart-ships Two container spaces and not in or above same hold One bulkhead Two container spaces and not in or above same hold One bulkhead Tree container spaces and not in or above same hold Two bulkheads “Separated longitudinally by an intervening complete compartment or hold from” 4. Prohibited Fore and AFT Minimum horizontal distance of 24 m and not in or above same hold One bulkhead and minimum horizontal distance of 24 M* Minimum horizontal distance of 24 m and not in or above same hold Two bulkheads Minimum horizontal distance of 24 m and not in or above same hold Two bulkheads Athwart-ships Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited *Containers not less than 6 m (20 feet) from intervening bulkhead. Note: All bulkheads and decks must be resistant to fire and liquid. (m) Provisions for segregation groups: (1) For the purpose of segregation, materials having certain similar chemical properties have been grouped together in segregation groups. The segregation groups ( such as “acids”, “chlorates”, “permanganates”) and the entries allocated to each of these groups include the substances identified in section 3.1.4 of the IMDG Code. When column (10B) of the § 172.101 Table refers to a numbered stowage provision set forth in § 176.84(b) such as “Stow ‘away from’ acids”, that particular stowage/segregation requirement applies to all the materials allocated to the respective segregation group.
(2) Not all hazardous materials falling within a segregation group are listed by name in the regulations. These materials are shipped under “n.o.s.” entries. Although these “n.o.s.” entries are not listed themselves in the above groups, the shipper must decide whether allocation under a segregation group is appropriate. Mixtures, solutions or preparations containing hazardous materials falling within a segregation group and shipped under an “n.o.s.” entry are also considered to fall within that segregation group.
(3) The segregation groups described above do not address materials which fall outside the classification criteria of the hazardous materials regulations although it is recognized that some non-hazardous materials have certain chemical properties similar to hazardous materials listed in the segregation groups. A shipper or the person responsible for packing the materials into a cargo transport unit who does have knowledge of the chemical properties of such non-hazardous materials may identify a relevant segregation group and apply the segregation requirements for that segregation group.
60. In § 176.84, paragraph (a) is revised, in paragraph (b), Table of provisions, eleven new entries are added in appropriate numerical order and in paragraph (c)(2), three notes in the Provisions for the stowage of Class 1 (explosive) materials table are revised to read as follows: § 176.84 Other requirements for stowage and segregation for cargo vessels and passenger vessels.
End Amendment Part(a) General. When Column 10B of the § 172.101 Table refers to a numbered or alpha-numeric stowage provision for water shipments, the meaning and requirements of that provision are set forth in this section. Terms in quotation marks are defined in § 176.83. Other terms used in the table in this section such as “acids”, “chlorates” and “permanganates” indicate different chemical groups referred to here as segregation groups. Materials falling within a segregation group are considered to have certain similar chemical properties and, although not exhaustive in nature, the materials belonging to each group include those substances identified in section 3.1.4 of the IMDG Code as set forth in § 176.83(m).
(b) * * *
Code Provisions * * * * * 133 Stow “separated from” sulfur. 134 Stow “separated from” UN2716. 135 Stow “Separated from” mercury and mercury compounds. 136 Stow “Separated from” carbon tetrachloride. 137 For arsenic sulphides, Stow “separated from” acids. 138 Stow “Separated from” peroxides. 139 Stow “Separated from” mercury salts. 140 Stow “Separated from” UN3052 and UN3461. 141 Stow “away from” radioactive materials. 142 Packages in cargo transport units must be stowed so as to allow for adequate air circulation throughout the cargo. 143 Prohibited on any vessel carrying explosives (except explosives in Division 1.4, Compatibility group S). * * * * * * * * * *(c) * * *
(2) * * *
Note Provision * * * * * 19E “Away from” explosives containing chlorates or perchlorates. * * * * * 22E “Away from” ammonium compounds and explosives containing ammonium compounds or salts. 23E “Separated from” Division 1.4 and “separated longitudinally by an intervening complete compartment or hold from” Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J. * * * * * * * * * *Start Amendment Part61. In § 176.116, paragraph (c) is revised and a new paragraph (f) is added to read as follows:
End Amendment PartGeneral stowage conditions for Class 1 (explosive) materials.* * * * *(c) Security: All compartments, magazines, and cargo transport units containing Class 1 (explosive) materials must be locked or suitably secured in order to prevent unauthorized access.
* * * * *(f) Under deck stowage of Class 1 (explosive) materials allocated stowage categories 09 and 10:
(1) These Class 1 (explosive) materials must not be stowed in the same compartment or hold with other cargo that is readily combustible (such as items packaged in straw).
(2) The position of stowage of these Class 1 (explosive) materials must be such as to maintain direct access to the hatchway by not overstowing with other cargo except for other Class 1 (explosive) materials.
(3) In all cases, all cargo within the compartment or hold, including Class 1 (explosive) materials stowed in cargo transport units, must be secured so as to eliminate the possibility of significant movement. Where an entire deck is used as a magazine, the stowage must be so arranged that the Class 1 (explosive) materials stowed therein must be removed from the ship before working any cargo in any decks above or below the space in the same hold.
[Removed and Reserved]62. Section 176.122 is removed and reserved.
End Amendment Part[Removed and Reserved]63. Section 176.124 is removed and reserved.
End Amendment Part Start Amendment Part64. Section 176.128 is revised to read as follows:
End Amendment PartMagazine stowage types “A”, “C” and Special Stowage.(a) The stowage arrangements of Class 1 (explosive) substances and certain articles are subject to varying levels of containment, (except for compatibility group S substances), when stowed below deck. The levels are dependent on the hazard presented and the nature of the particular explosives involved. Columns (10A) and (10B) of the Hazardous Materials Table specify the stowage applicable to each substance or article. The different levels of containment are defined below as “A”, “C” and “Special”.
(b) Magazine stowage type “A”. Magazine stowage type A is required for those substances that must be kept clear of steelwork.
(c) Magazine stowage type “C”. Magazine stowage type C is required for Start Printed Page 76184those substances in compatibility group A.
(d) Special Stowage. Special Stowage is required for Explosive substances, n.o.s. in compatibility groups G or L, and for articles in compatibility groups G, H, L and K, which are particularly hazardous.
[Removed and Reserved]65. Section 176.132 is removed and reserved.
End Amendment Part Start Amendment Part66. Section 176.133 is revised to read as follows:
End Amendment PartMagazine stowage Type C.The construction requirements for magazine stowage type C are the same as for a closed cargo transport unit in § 176.63(e). In addition, the magazine must be located as near as practicable to the centerline of the vessel and must not be closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less.
67. Section 176.136 is revised to read as follows:
End Amendment PartSpecial stowage.(a) Special stowage is required for certain articles presenting both explosive and chemical hazards, such as smoke or lachrymatory (compatibility group G or H), toxic (compatibility group K), or substances and articles which present a special risk (compatibility group L). Except as permitted in paragraph (c) of this section, Class 1 (explosive) materials requiring special stowage must be stowed on deck unless such stowage is impracticable and the COTP authorizes special stowage below deck. Where on deck stowage is recommended and an alternative stowage below deck is permitted by the COTP, the stowage must always be subject to special stowage.
(b) Class 1 (explosive) materials for which special stowage is required must be stowed as far away as practicable from living, accommodation, and working areas, and may not be overstowed. Closed cargo transport units in which such Class 1 (explosive) materials are stowed may not be located closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less.
(c) Class 1 (explosive) materials in compatibility groups G and H may be transported in steel magazines or in freight containers. If a freight container is used for this purpose, the floor of the freight container must be leakproof; for example, an all-metal container may be used and a fillet of cement or other material worked across the bottom of the door opening.
(d) Class 1 (explosive) materials stowed in one compartment may not be of more than one compatibility group, except the COTP may allow Class 1 (explosive) materials of compatibility groups G and H in separate steel magazines to be stowed in the same compartment, not less than 3 m (10 feet) apart.
(e) Class 1 (explosive) materials in compatibility groups K and L must be stowed in a steel magazine regardless of the stowage position in the vessel.
68. In § 176.138, paragraph (a) is revised to read as follows:
End Amendment Part Start Amendment Part69. In § 176.142, paragraph (a) is revised to read as follows:
End Amendment PartHazardous materials of extreme flammability.(a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials:
Carbon disulfide UN1131 Class 3 Diethylzinc UN1366 Division 4.2 Dimethylzinc UN1370 Division 4.2 Magnesium alkys UN3053 Division 4.2 Methyl phosphonous di-chloride, pyrophoric liquid. NA2845 Division 6.1 Nickel carbonyl UN1259 Division 6.1 Pyrophoric liquid, inorganic, n.o.s. UN3194 Division 4.2 Pyrophoric liquid, organic, n.o.s. UN2845 Division 4.2 Organometallic substance, liquid, pyrophoric. UN3392 Division 4.2 Organometallic substance, liquid, pyrophoric, water-reactive. UN3394 Division 4.2 * * * * *70. In § 176.144, paragraphs (a), (b), (c) and (e) are revised to read as follows:
End Amendment PartSegregation of Class 1 (explosive) materials.(a) Except as provided in § 176.145 of this subchapter, stowage of Class 1 (explosive) materials within the same compartment, magazine, or cargo transport unit is subject to provisions contained in table 176.144(a).
Table 176.144(a)—Authorized Mixed Stowage for Explosives
[An “X” indicates that explosives in the two different compatibility groups reflected by the location of the “X” may not be stowed in the same compartment, magazine, or cargo transport unit]
Compatibility groups A B C D E F G H J K L N S A X X X X X X X X X X X X B X X X X X X X X X X X C X X 6 6 X 1 X X X X 4 D X X 6 6 X 1 X X X X 4 E X X 6 6 1 X X X X 4 F X X X X X X X X X X X X G X X 1 1 1 X X X X X X H X X X X X X X X X X X J X X X X X X X X X X X K X X X X X X X X X X X L X X X X X X X X X X 2 X X N X X 4 4 4 X X X X X X 3 5 S X X 5 Notes: 1. Explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of compatibility groups C, D, and E, provided no explosive substances are carried in the same compartment, magazine or cargo transport unit.Start Printed Page 76185 2. Explosives in compatibility group L may only be stowed in the same compartment, magazine or cargo transport unit with identical explosives within compatibility group L. 3. Different types of articles of Division 1.6, compatibility group N, may only be transported together when it is proven that there is no additional risk of sympathetic detonation between the articles. Otherwise they must be treated as division 1.1. 4. When articles of compatibility group N are transported with articles or substances of compatibility groups C, D or E, the goods of compatibility group N must be treated as compatibility group D. 5. When articles of compatibility group N are transported together with articles or substances of compatibility group S, the entire load must be treated as compatibility group N. 6. Any combination of articles in compatibility groups C, D and E must be treated as compatibility group E. Any combination of substances in compatibility groups C and D must be treated as the most appropriate compatibility group shown in Table 2 of § 173.52 taking into account the predominant characteristics of the combined load. This overall classification code must be displayed on any label or placard on a unit load or cargo transport unit as prescribed in subpart E (Labeling) and subpart F (Placarding). (b) Where Class 1 (explosive) materials of different compatibility groups are allowed to be stowed in the same compartment, magazine, or cargo transport unit, the stowage arrangements must conform to the most stringent requirements for the entire load.
(c) Where a mixed load of Class 1 (explosive) materials of different hazard divisions and/or stowage arrangements is carried within a compartment, magazine, or cargo transport unit, the entire load must be treated as belonging to the hazard division having the greatest hazard. (For example, if a load of Division 1.1 (explosive) materials is mixed with Division 1.3 (explosive) materials, the load is treated as a Division 1.1 (explosive) material as defined in § 173.50(b) of this subchapter and the stowage must conform to the most stringent requirements for the entire load).
* * * * *(e) Segregation on deck: When Class 1 (explosive) materials in different compatibility groups are carried on deck, they must be stored not less than 6 m (20 feet) apart unless they are allowed under Table 176.144(a) to be stowed in the same compartment, magazine, or cargo transport unit.
* * * * *71. In § 176.146, paragraph (d)(1) is revised to read as follows:
End Amendment PartSegregation from non-hazardous materials.* * * * *(d) In order to avoid contamination:
(1) An explosive substance or article which has a secondary POISON hazard label must be stowed “separated from” all foodstuffs, except when such materials are stowed in separate closed cargo transport units, the requirements for “away from” segregation apply.
* * * * *[Amended]72. In § 176.168, the undesignated center heading before § 176.168 is revised to read “CARGO TRANSPORT UNITS AND SHIPBORNE BARGES”.
End Amendment Part Start Amendment Part73. In § 176.170, a new paragraph (b) is added to read as follows:
End Amendment PartTransport of Class 1 (explosive) materials in freight containers.* * * * *(b) Freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, must not be stowed in the outermost row of containers.
* * * * *74. In § 176.174, paragraphs (a) and (b) are revised to read as follows:
End Amendment PartTransport of Class 1 (explosive) materials in shipborne barges.(a) Fixed magazines may be built within a shipboard barge. Freight containers may be used as magazines within a barge.
(b) Shipborne barges may be used for the carriage of all types of Class 1 (explosive) materials. When carrying Class 1 (explosive) materials requiring special stowage, the following requirements apply:
(1) Class 1 (explosive) materials in compatibility group G or H must be stowed in freight containers.
(2) Class 1 (explosive) materials in compatibility group K or L must be stowed in steel magazines.
* * * * *[Amended]75. In § 176.600, in paragraph (a), in the last sentence, the wording “closed transport units” is removed and the wording “closed cargo transport units” is added in its place.
End Amendment Part Start PartPART 178—SPECIFICATIONS FOR PACKAGINGS
End Part Start Amendment Part76. The authority citation for part 178 continues to read as follows:
End Amendment Part Start Amendment Part77. In § 178.274, paragraph (f)(l)(v) is revised to read as follows:
End Amendment PartSpecifications for UN portable tanks.* * * * *(f) * * *
(l) * * *
(v) The rated flow capacity of the spring loaded pressure relief devices, frangible disc or fusible elements in standard cubic meters of air per second (m3/s). For spring loaded pressure relief device the rated flow capacity shall be determined according to ISO 4126-1 (IBR, see § 171.1 of this subchapter); and
* * * * *78. In § 178.275, paragraph (i)(2) is revised to read as follows:
End Amendment PartSpecification for UN Portable Tanks intended for the transportation of liquid and solid hazardous materials.* * * * *(i) * * *
(2) The combined delivery capacity of the pressure relief system (taking into account the reduction of the flow when the portable tank is fitted with frangible-discs preceding spring-loaded pressure-relief devices or when the spring-loaded pressure-relief devices are provided with a device to prevent the passage of the flame), in condition of complete fire engulfment of the portable tank must be sufficient to limit the pressure in the shell to 20% above the start to discharge pressure limiting device (pressure relief device). The total required capacity of the relief devices may be determined using the formula in paragraph (i)(2)(i)(A) of this section or the table in paragraph (i)(2)(iii) of this section.
* * * * *79. In § 178.276, paragraphs (a)(4)(ii)(A), (d), and (e)(3) are revised to read as follows:
End Amendment PartRequirements for the design, construction, inspection and testing of portable tanks intended for the transportation of non-refrigerated liquefied compressed gases.(a) * * *
(4) * * *
(ii) * * *
(A) Not less than the pressure specified for each liquefied compressed gas listed in the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313; and
* * * * *(d) Bottom openings. Bottom openings are prohibited on portable tanks when the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313 of this subchapter indicates that bottom openings are not allowed. In Start Printed Page 76186this case, there may be no openings located below the liquid level of the shell when it is filled to its maximum permissible filling limit.
(e) * * *
(3) A portable tank intended for the transportation of certain liquefied compressed gases identified in the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313 of this subchapter must have a pressure relief device which conforms to the requirements of this subchapter. Unless a portable tank, in dedicated service, is fitted with a relief device constructed of materials compatible with the hazardous material, the relief device must be comprised of a frangible disc preceded by a reclosing device. The space between the frangible disc and the device must be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement must facilitate the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible disc must rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device.
* * * * *80. In § 178.602, paragraph (b) is revised to read as follows:
End Amendment PartPreparation of packagings and packages for testing.* * * * *(b) For the drop and stacking test, inner and single-unit receptacles other than bags must be filled to not less than 95% of maximum capacity (see § 171.8 of this subchapter) in the case of solids and not less than 98% of maximum in the case of liquids. Bags shall be filled to the maximum mass at which they may be used. The material to be transported in the packagings may be replaced by a non-hazardous material, except for chemical compatibility testing or where this would invalidate the results of the tests.
* * * * *81. In § 178.603, paragraphs (c) and (e)(2) introductory text are revised to read as follows:
End Amendment PartDrop test.* * * * *(c) Special preparation of test samples for the drop test.
(1) Testing of plastic drums, plastic jerricans, plastic boxes other than expanded polystyrene boxes, composite packagings (plastic material), and combination packagings with plastic inner packagings other than plastic bags intended to contain solids or articles must be carried out when the temperature of the test sample and its contents has been reduced to −18 °C (0 °F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are considered acceptable test liquids. Test samples prepared in this way are not required to be conditioned in accordance with § 178.602(d).
* * * * *(e) * * *
* * * * *(2) For liquids in single packagings and for inner packagings of combination packagings, if the test is performed with water:
* * * * *82. In § 178.810, paragraph (b)(3) is revised to read as follows:
End Amendment PartDrop test.* * * * *(b) Special preparation for the drop test.
* * * * *(3) Rigid plastic IBCs and composite IBCs with plastic inner receptacles must be conditioned for testing by reducing the temperature of the packaging and its contents to −18 °C (0 °F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at −18 °C (0 °F) or lower are considered acceptable test liquids, and may be considered equivalent to water for test purposes. IBCs conditioned in this way are not required to be conditioned in accordance with § 178.802.
* * * * *PART 180—CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS
End Part Start Amendment Part83. The authority citation for part 180 continues to read as follows:
End Amendment Part Start Amendment Part84. In § 180.350, paragraph (c) is revised to read as follows:
End Amendment PartApplicability and definitions.* * * * *(c) Routine maintenance of IBCs is the routine performance on:
(1) Metal, rigid plastic or composite IBCs of operations such as:
(i) Cleaning;
(ii) Removal and reinstallation or replacement of body closures (including associated gaskets), or of service equipment conforming to the original manufacturer's specifications provided that the leaktightness of the IBC is verified; or
(iii) Restoration of structural equipment not directly performing a hazardous material containment or discharge pressure retention function so as to conform to the design type (for example, the straightening of legs or lifting attachments), provided the containment function of the IBC is not affected.
(2) Plastics or textile flexible IBCs of operations, such as:
(i) Cleaning; or
(ii) Replacement of non-integral components, such as non-integral liners and closure ties, with components conforming to the original manufacturer's specification; provided that these operations do not adversely affect the containment function of the flexible IBC or alter the design type.
85. In § 180.352, paragraph (d)(1)(iv) is revised and a new paragraph (d)(1)(v) is added to read as follows:
End Amendment PartRequirements for retest and inspection of IBCs.* * * * *(d) * * *
(1) * * *
(iv) Retests and inspections performed in accordance with paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the requirements for the 2.5 and five year periodic tests and inspections required by paragraph (b) of this section, as applicable.
(A) The County in which the routine maintenance was carried out; and
(B) The name or authorized symbol of the party performing the routine maintenance.
(v) Retests and inspections performed in accordance with paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the requirements for the 2.5 and five year periodic tests and inspections required by paragraph (b) of this section, as applicable.
(e) Requirements applicable to routine maintenance of IBCs. Except for routine maintenance of metal, rigid plastics and composite IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing the routine maintenance shall durably mark the IBC near the manufacturer's UN design type marking to show the following:
(1) The County in which the routine maintenance was carried out; and
(2) The name or authorized symbol of the party performing the routine maintenance.
(f) Retest date. The date of the most recent periodic retest must be marked as Start Printed Page 76187provided in § 178.703(b) of this subchapter.
(g) Record retention. The owner or lessee of the IBC must keep records of periodic retests, initial and periodic inspections, and tests performed on the IBC if it has been repaired. Records must include design types and packaging specifications, test and inspection dates, name and address of test and inspection facilities, names or name of any persons conducting tests or inspections, and test or inspection specifics and results. Records must be kept for each packaging at each location where periodic tests are conducted, until such tests are successfully performed again or for at least 2.5 years from the date of the last test. These records must be made available for inspection by a representative of the Department on request.
* * * * *Issued in Washington, DC on November 24, 2004, under authority delegated in 49 CFR part 1.
Elaine E. Joost,
Acting Deputy Administrator, Research and Special Programs Administration.
BILLING CODE 4910-60-P Start Printed Page 76064
BILLING CODE 4910-01-S
BILLING CODE 4910-60-U
BILLING CODE 4910-60-U
BILLING CODE 4910-60-S
[FR Doc. 04-27087 Filed 12-17-04; 8:45 am]
BILLING CODE 4910-60-P
Document Information
- Effective Date:
- 1/1/2005
- Published:
- 12/20/2004
- Department:
- Research and Special Programs Administration
- Entry Type:
- Rule
- Action:
- Final rule.
- Document Number:
- 04-27087
- Dates:
- The effective date of these amendments is January 1, 2005
- Pages:
- 76043-76187 (145 pages)
- Docket Numbers:
- Docket No. RSPA-04-17036 (HM-215G)
- RINs:
- 2137-AD92
- Topics:
- Air carriers, Education, Exports, Hazardous materials transportation, Hazardous waste, Imports, Incorporation by reference, Labeling, Maritime carriers, Motor carriers, Motor vehicle safety, Packaging and containers, Radioactive materials, Railroad safety, Reporting and recordkeeping requirements, Uranium
- PDF File:
- 04-27087.pdf
- CFR: (76)
- 49 CFR 171.7
- 49 CFR 171.8
- 49 CFR 171.11
- 49 CFR 171.12
- 49 CFR 171.14
- More ...